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WO2025086125A1 - Composition pour le conditionnement de fibres de kératine - Google Patents

Composition pour le conditionnement de fibres de kératine Download PDF

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Publication number
WO2025086125A1
WO2025086125A1 PCT/CN2023/126365 CN2023126365W WO2025086125A1 WO 2025086125 A1 WO2025086125 A1 WO 2025086125A1 CN 2023126365 W CN2023126365 W CN 2023126365W WO 2025086125 A1 WO2025086125 A1 WO 2025086125A1
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WO
WIPO (PCT)
Prior art keywords
composition
composition according
ranging
hyaluronic acid
crosspolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/CN2023/126365
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English (en)
Inventor
Xiao Chen
Xiuxia Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Priority to PCT/CN2023/126365 priority Critical patent/WO2025086125A1/fr
Priority to FR2312862A priority patent/FR3154604B3/fr
Publication of WO2025086125A1 publication Critical patent/WO2025086125A1/fr
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/025—Explicitly spheroidal or spherical shape
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/0279—Porous; Hollow
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/008—Preparations for oily hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a composition for conditioning keratin fibers, in particular human keratin fibers such as the hair.
  • the present invention also relates to a cosmetic process for conditioning keratin fibers.
  • the keratin fibers such as the skin and the scalp, are likely to sweat, leading to sebum secretion.
  • US5137715A discloses a hair shampoo-conditioner composition consisting essentially of: (a) from about 1%to about 20%by weight of an anionic cleansing surfactant; (b) from about 0.1%to about 2.5%by weight of a substantially uncrosslinked polymeric amidoamine; and (c) a suitable carrier comprising water; wherein the composition has a pH in the range of from about 2.5 to less than 7.
  • An object of the present invention is thus to develop compositions for conditioning keratin fibers, which can reduce the issues caused by heavy sebum and deliver the hair a volumized look.
  • the present invention provides a composition for conditioning keratin fibers comprising:
  • composition according to the present invention can effectively anti-sebum and make the hair volumized.
  • keratin fibers includes human keratin fibers, especially the hair.
  • composition of the present invention comprises:
  • composition of the present invention comprises at least one spheric particles of lipophilically modified silica.
  • a “spheric particle” means a particle in the shape of sphere or at least approximate sphere, and/or a particle having an aspect ratio of about 0.9 to 1.1, e.g., about 0.95 to 1.05.
  • a particle is in the shape of sphere according to the conventional knowledge.
  • a given silica it is within the ordinary skill of persons in the art to distinguish the shape of sphere from other shapes of plate, rod, powder, strip, irregular shapes or the like, and from amorphous similar.
  • a “lipophilically modified” silica means one having subjected to lipophilic modification.
  • lipophilic modification means any organo-modification capable of bringing hydrophobic or lipophilic treatment to the silica.
  • a silica can be treated with a siloxane compound, e.g., hydroxydimethylsiloxane (or other silanes, such as silazane, etc. ) , through which the silanol group on the surface of the silica and the silanol group of the siloxane compound are condensed.
  • the lipophilically modified silica is selected from silica treated with a siloxane compound, preferably selected from silica silylate, silica dimethyl silylate, and mixtures thereof.
  • spheric particle of lipophilically modified silica can be the one available from company TOKUYAMA CORPORATION under the name of TL-10.
  • the spheric particles of lipophilically modified silica when being incorporated into the composition, can show an oil-absorbing capacity of 500 ml/100g or more, 600 ml/100g or more, or even 700 ml/100g or more.
  • the spheric particles of lipophilically modified silica is present in the composition according to the present invention in an amount ranging from 0.01 wt. %to 5 wt. %, preferably ranging from 0.3 wt. %to 2.5 wt. %, more preferably ranging from 0.5 wt. %to 1.5 wt. %, relative to the total weight of the composition.
  • composition of the present invention comprises at least one superabsorbent polymer chosen from starches grafted with an acrylic polymer.
  • superabsorbent polymer is intended to mean a polymer that is capable in its dry form of spontaneously absorbing at least 20 times its own weight of aqueous fluid, in particular of water and especially distilled water.
  • superabsorbent polymers are described in the work "Absorbent polymer technology, Studies in polymer science 8" by L. Brannon-Peppas and R. Harland, published by Elsevier, 1990.
  • said superabsorbent polymer is chosen from starches grafted with an acrylic homo-or copolymer, in particular starches grafted with sodium polyacrylate.
  • the acrylic polymer may be a homopolymer or a copolymer, in particular sodium polyacrylate.
  • polymers have a large capacity for absorbing and retaining water and aqueous fluids. After absorption of the aqueous liquid, the polymer particles thus engorged with aqueous fluid remain insoluble in the aqueous fluid and thus conserve their individualized particulate state.
  • the superabsorbent polymer may have a water-absorbing capacity ranging from 20 to 2000 times its own weight (i.e. 20 g to 2000 g of absorbed water per gram of absorbent polymer) , preferably from 30 to 1500 times and better still from 50 to 1000 times. These water absorption characteristics are defined under standard temperature (25°C) and pressure (760 mmHg, i.e. 100000 Pa) conditions and for distilled water.
  • the value of the water-absorbing capacity of a polymer may be determined by dispersing 0.5 g of polymer (s) in 150 g of a water solution, waiting for 20 minutes, filtering the unabsorbed solution through a 150 ⁇ m filter for 20 minutes and weighing the unabsorbed water.
  • the superabsorbent polymer used in the composition of the invention is in the form of particles.
  • the superabsorbent polymer has, in the dry or nonhydrated form, amean size of less than or equal to 100 ⁇ m and preferably less than or equal to 50 ⁇ m, for example ranging from 1 to 100 ⁇ m, preferably from 5 to 50 ⁇ m and better still from 7 to 30 ⁇ m.
  • the mean size of the particles corresponds to the mass-average diameter (D50) measured by laser particle size analysis or another equivalent method known to those skilled in the art. These particles, once hydrated, swell while forming soft particles having a mean size that can range from 10 ⁇ m to 2000 ⁇ m.
  • Such polymers are known for their gelling properties and are generally used in a form pre-swollen in aqueous phase.
  • the superabsorbent polymer (s) used comprise from 85%to 95%by weight of sodium polyacrylate and from 5%to 15%by weight of starch. Preferably, they are constituted of 90%by weight of sodium polyacrylate and 10%by weight of starch.
  • the number-average molecular weight of the superabsorbent polymer (s) used is greater than 1000 daltons.
  • Mention may particularly be made of starches grafted with an acrylic polymer and in particular with sodium polyacrylate, such as those sold under the name Sanfresh ST- 100MC by Sanyo Chemical Industries or Makimousse 25, Makimousse 12 or Makimousse 7 by Daito Kasei (INCI name: Sodium polyacrylate starch) .
  • the superabsorbent polymers used in the present invention may be crosslinked or non-crosslinked.
  • the superabsorbent polymers used in the present invention are preferably starches grafted with an acrylic homo-or copolymer, in particular sodium polyacrylate, which is in particulate form.
  • the superabsorbent polymer is chosen from starches grafted with an acrylic homopolymer, preferably in the form of particles having a mean size (or mean diameter) of less than or equal to 100 microns, more preferably in the form of particles, so that the hair will not get sticky to each other and will have a volumized look.
  • the composition of the present invention can deliver a non-wet and quick drying feeling.
  • the superabsorbent polymers have a good affinity on the skin, makes a good fixation of absorption beads, which can deliver a good oil control efficacy.
  • the superabsorbent polymer is present in the composition according to the present invention in an amount ranging from 0.01 wt. %to 5 wt. %, preferably ranging from 0.1 wt. %to 3 wt. %, more preferably ranging from 0.1 wt. %to 1 wt. %, most preferably ranging from 0.2 wt. %to 0.8 wt. %, relative to the total weight of the composition.
  • composition of the present invention comprises at least one hyaluronic acid crosspolymer.
  • Hyaluronic acid is a natural carbohydrate linear polysaccharide found in almost all living organisms. Its chemical structure is consisting of alternating repeating disaccharide units composed of D-glucuronic acid and N-acetylglucosamine linked together through alternating beta-1, 4 and beta-1, 3 glycosidic bonds. The number of repetitions can reach up to 10,000 with approximately from 10 2 to 10 4 kDa molecular weight.
  • hyaluronic acid encompasses all variants and combinations of variants of hyaluronic acid or hyaluronate, of various chain lengths and charge states, as well as with various chemical modifications. That is, the term also encompasses the various hyaluronate salts of hyaluronic acid with various counter ions, such as sodium hyaluronate.
  • HA is a highly hydrophilic macromolecule which plays a key role in the transport of water in skin maintaining the hydration and stabilizing the structure of epidermis and dermis. HA plays an important role in the structural characteristics of many tissues. Due to its unique coil structure in aqueous solutions, HA exhibits a highly effective moisturizing property since it can retain till 1000 times its weight in water.
  • Hyaluronic acid can be obtained from various sources of animal and non-animal origin.
  • Sources of non-animal origin include yeast and bacteria.
  • HA crosspolymer comprises crosslinks between the HA chains, which creates a continuous network of HA molecules which is held together by the covalent crosslinks, physical entangling of the HA chains and various interactions, such as electrostatic interactions, hydrogen bonding and van der Waals forces.
  • Crosslinking of the HA may be achieved by modification with a chemical crosslinking agent.
  • the chemical crosslinking agent may for example be selected from the group consisting of divinyl sulfone, multiepoxides and diepoxides.
  • the hyaluronic acid is crosslinked by a bi-or polyfunctional crosslinking agent comprising two or more glycidyl ether functional groups.
  • the chemical crosslinking agent is selected from the group consisting of 1, 4-butanediol diglycidyl ether (BDDE) , 1, 2-ethanediol diglycidyl ether (EDDE) , diepoxyoctane and mixture thereof.
  • the chemical crosslinking agent is 1, 4-butanediol diglycidyl ether (BDDE) .
  • the HA crosspolymer may be a gel, or a hydrogel. That is, it can be regarded as a water-insoluble, but substantially dilute crosslinked system of hyaluronic acid molecules when subjected to a liquid, typically an aqueous liquid.
  • the gel contains mostly liquid and can e.g. contain 90-99.9%water by weight, but it behaves like a solid due to a three-dimensional crosslinked HA network within the liquid. Due to its significant liquid content, the gel is structurally flexible and similar to a natural tissue.
  • Such a HA crosspolymer confers high gel strength, long duration and high biocompatibility.
  • crosslinking of HA to form the HA crosspolymer gel may for example be achieved by modification with a chemical crosslinking agent, for example BDDE (1, 4-butandiol diglycidylether) .
  • BDDE 1, 4-butandiol diglycidylether
  • the HA concentration and the extent of crosslinking affects the mechanical properties, e.g. the elastic modulus G, and stability properties of the gel.
  • HA crosspolymers are often characterized in terms of “degree of modification” , “crosslinking ratio” , and “degree of crosslinking” (Keene et al., Carbohydrate Polymers, 2013, 91, 410-418) .
  • the degree of modification (MoD) of HA generally ranges between 0.1 and 15 mole%.
  • the degree of modification (mole%) describes the amount of crosslinking agent (s) that is bound to HA, i.e. molar amount of bound crosslinking agent (s) relative to the total molar amount of repeating HA disaccharide units.
  • the degree of modification reflects to what degree the HA has been chemically modified by the crosslinking agent.
  • the degree of modification of HA crosspolymer with a chemical crosslinking agent is less than 15 mole%, preferably less than 1.9%, more preferably between 0.1 and 1.9 mole%.
  • HA crosspolymer may also be characterized by the cross-linker ratio or crosslinking ratio (CrR) .
  • the cross-linker ratio (CrR) describes the proportion of total bound cross-linking agent (HA-X-HA and HA-X) that has bound two (or more) disaccharides (only HA-X-HA) .
  • the cross-linker ratio (CrR) of HA generally ranges between 0.01 and 0.50. In a preferred embodiment, the CrR is less than 0.30, preferably between 0.10 and 0.20, more preferably 0.10 or 0.20.
  • HA crosspolymer may also be characterized by the degree of crosslinking (CrD) corresponding to the stoichiometric ratio between the cross-linking agent that are double-linked and HA disaccharide units.
  • CrD degree of crosslinking
  • the CrD is between 0.2 and 0.8, preferably between 0.2 and 0.5, more preferably between 0.2 and 0.4, even more preferably 0.2.
  • a BDDE (1, 4-butandiol diglycidylether) crosslinked HA gel may for example be prepared according to the method described in Examples 1 and 2 of published international patent application WO 97/04012.
  • the HA crosspolymer is preferably crosslinked by a chemical crosslinking agent, and the degree of modification of said HA crosspolymer with said chemical crosslinking agent is less than 15 mole%, preferably less than 1.9 mole%.
  • the degree of modification of said hyaluronic acid crosspolymer with said chemical crosslinking agent being in the range of0.1 mole%to less than 1.9 mole%.
  • the degree of modification with said chemical crosslinking agent is about 1.0 mole%.
  • the HA crosspolymer is sodium hyaluronate crosspolymer, which can be available as Hyacross TM from BLOOMAGE BIOTECHNOLOGY.
  • the HA crosspolymer When the HA crosspolymer is applied on hair root, there is less sticky. At the same time it can modify the hydrophobicity of hair root surface, and deliver a better anti-oil migration benefit.
  • the hyaluronic acid crosspolymer is present in the composition according to the present invention in an amount ranging from 0.01 wt. %to 5 wt. %, preferably ranging from 0.01 wt. %to 3 wt. %, more preferably ranging from 0.02 wt. %to 2 wt. %, most preferably ranging from 0.03 wt. %to 0.8 wt. %, relative to the total weight of the composition.
  • the weight ratio of the superabsorbent polymer to the hyaluronic acid crosspolymer is from 2 to 80, preferably from 2 to 50, more preferably from 2 to 30, so that a preferred balance of the viscosity of the composition and the preferred sensory delivered by the composition can be obtained, meanwhile a preferred usage experience can be achieved with the composition.
  • composition of the present invention may further comprise a continuous aqueous phase.
  • Said aqueous phase is preferably present in an amount ranging from 50 wt. %to 99 wt. %, more preferably from 70 wt. %to 99 wt. %, relative to the total weight of the composition.
  • the aqueous phase comprises water.
  • Water is preferably present in the composition of the present invention in an amount ranging from 50 wt. %to 99 wt. %, preferably from 60 wt. %to 99 wt. %, relative to the total weight of the composition.
  • the continuous aqueous phase comprises one or more organic solvent miscible with water (at room temperature 25°C) such as for example monoalcohols having from 2 to 6 carbon atoms such as ethanol, isopropanol; polyols having from 2 to 20 carbon atoms, preferably from 2 to 10 carbon atoms, and preferentially having from 2 to 6 carbon atoms, such as glycerin, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, caprylyl glycol, dipropylene glycol, diethylene glycol; glycol ethers (notably having from 3 to 16 carbon atoms) such as mono-, di-or tri-propylene glycol (C 1 -C 4 ) alkyl ethers, mono-, di-or tri-ethylene glycol (C 1 -C 4 ) alkyl ethers and mixtures thereof.
  • organic solvent miscible with water at room temperature 25°C
  • monoalcohols having from 2 to
  • the aqueous phase comprises one or more organic solvent miscible selected from monoalcohols having from 2 to 6 carbon atoms; polyols having from 2 to 20 carbon atoms; glycol ethers having from 3 to 16 carbon atoms, and mixtures thereof, more preferably selected from ethanol, glycerin, and mixtures thereof.
  • the composition of the present invention comprises from 0.1 wt. %to 50 wt.%, preferably from 1 wt. %to 45 wt. %, more preferably from 5 wt. %to 40 wt. %, even more preferably ranging from 10 wt. %to 40 wt. %, of an organic solvent miscible with water mentioned above, relative to the total weight of the composition.
  • composition of the present invention comprises one or more additional active ingredients for conditioning keratin fibers.
  • composition according to the present invention may also comprise additional adjuvants, such as fragrances, preservatives and so on.
  • the present invention provides a composition for conditioning keratin fibers comprising, relative to the total weight of the composition:
  • composition according to the present invention can be prepared by mixing ingredients a) to c) , as essential ingredients, as well as additional ingredient (s) , as explained above.
  • the method and means to mix the above essential and optional ingredients are not limited. Any conventional method and means can be used to mix the above essential and optional ingredients to prepare the composition according to the present invention.
  • composition of the present invention can be a leave-on product.
  • composition of the present invention can be used on both wet and dry hair and scalp right after wash or during daytime and deliver longer oil control efficacy.
  • the present invention provides a cosmetic process for conditioning keratin fibers comprising applying the composition according to the present invention onto said keratin fibers.
  • compositions of invention examples (IE. ) 1-2 and comparative examples (CE. ) 1-4 were prepared with the components listed in Table 2 (the contents are expressed as weight percentages with regard to the total weight of each composition, unless otherwise indicated) :
  • compositions of invention examples 1-2 are compositions according to the present invention.
  • Composition of comparative example 1 comprises sodium hyaluronate instead of at least one hyaluronic acid crosspolymer.
  • Composition of comparative example 2 does not comprise at least one spheric particle of lipophilically modified silica.
  • Composition of comparative example 3 does not comprise at least one superabsorbent polymer chosen from starches grafted with an acrylic polymer.
  • Composition of comparative example 4 does not comprise at least one hyaluronic acid crosspolymer.
  • composition of invention example 1 for example:
  • compositions of invention examples 1-2 and comparative examples 1-4 were evaluated in this test.
  • the hair swatch was then wrapped on a rigid rule, and artificial sebum homogeneously spread from the spatula to a calibrated length of 3 cm, that was separated from 1.5 cm from the support.
  • a timer was started and the sebum front was observed after 20 minutes, 40 minutes, 2 hours, 24 hours and 48 hours. The migration distance was measured and recorded at those time points.
  • compositions of invention examples 1-2 and comparative examples 1-4 were evaluated in this test.
  • each swatch was combed five times and the volume of each swatch was observed and scored from 1 to 5 according to the following criterion.
  • each composition of invention examples 1-2 have good anti-sebum performance and can deliver the hair a good volumized look.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Une composition de conditionnement des fibres de kératine comprend : a) au moins une particule sphérique de silice modifiée lipophiliquement ; b) au moins un polymère superabsorbant choisi parmi les amidons greffés avec un polymère acrylique ; et c) au moins un polymère réticulé d'acide hyaluronique. Un procédé cosmétique de conditionnement de fibres ee kératine comprend l'application de la composition sur lesdites fibres de kératine.
PCT/CN2023/126365 2023-10-25 2023-10-25 Composition pour le conditionnement de fibres de kératine Pending WO2025086125A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/CN2023/126365 WO2025086125A1 (fr) 2023-10-25 2023-10-25 Composition pour le conditionnement de fibres de kératine
FR2312862A FR3154604B3 (fr) 2023-10-25 2023-11-22 Composition pour la revitalisation des fibres kératineuses

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2023/126365 WO2025086125A1 (fr) 2023-10-25 2023-10-25 Composition pour le conditionnement de fibres de kératine

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Publication Number Publication Date
WO2025086125A1 true WO2025086125A1 (fr) 2025-05-01

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PCT/CN2023/126365 Pending WO2025086125A1 (fr) 2023-10-25 2023-10-25 Composition pour le conditionnement de fibres de kératine

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FR (1) FR3154604B3 (fr)
WO (1) WO2025086125A1 (fr)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7879910B1 (en) * 2006-10-10 2011-02-01 Jan Marini Skin Research, Inc. Compositions and methods for promoting lush hair growth
WO2013087926A1 (fr) * 2011-12-16 2013-06-20 L'oreal Composition cosmétique comprenant un polymère superabsorbant et des particules d'aérogel de silice
WO2013087928A1 (fr) * 2011-12-16 2013-06-20 L'oreal Composition cosmétique comprenant un polymère superabsorbant et une charge minérale matifiante en forme de lamelle ou de plaquette
CN113226482A (zh) * 2018-12-28 2021-08-06 株式会社资生堂 凝胶状化妆品
WO2022088057A1 (fr) * 2020-10-30 2022-05-05 L'oreal Composition pour le conditionnement de matières kératiniques
WO2022088065A1 (fr) * 2020-10-30 2022-05-05 L'oreal Composition pour le conditionnement de matières kératiniques

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5137715A (en) 1990-12-07 1992-08-11 Helene Curtis, Inc. Hair shampoo-conditioner composition
US5827937A (en) 1995-07-17 1998-10-27 Q Med Ab Polysaccharide gel composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7879910B1 (en) * 2006-10-10 2011-02-01 Jan Marini Skin Research, Inc. Compositions and methods for promoting lush hair growth
WO2013087926A1 (fr) * 2011-12-16 2013-06-20 L'oreal Composition cosmétique comprenant un polymère superabsorbant et des particules d'aérogel de silice
WO2013087928A1 (fr) * 2011-12-16 2013-06-20 L'oreal Composition cosmétique comprenant un polymère superabsorbant et une charge minérale matifiante en forme de lamelle ou de plaquette
CN113226482A (zh) * 2018-12-28 2021-08-06 株式会社资生堂 凝胶状化妆品
WO2022088057A1 (fr) * 2020-10-30 2022-05-05 L'oreal Composition pour le conditionnement de matières kératiniques
WO2022088065A1 (fr) * 2020-10-30 2022-05-05 L'oreal Composition pour le conditionnement de matières kératiniques

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FR3154604A3 (fr) 2025-05-02
FR3154604B3 (fr) 2025-12-12

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