WO2025067762A1 - Composite pane with integrated control component - Google Patents
Composite pane with integrated control component Download PDFInfo
- Publication number
- WO2025067762A1 WO2025067762A1 PCT/EP2024/072988 EP2024072988W WO2025067762A1 WO 2025067762 A1 WO2025067762 A1 WO 2025067762A1 EP 2024072988 W EP2024072988 W EP 2024072988W WO 2025067762 A1 WO2025067762 A1 WO 2025067762A1
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- WO
- WIPO (PCT)
- Prior art keywords
- pane
- control component
- electrically conductive
- functional
- composite pane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
- B32B17/10183—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer being not continuous, e.g. in edge regions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
- B32B17/1022—Metallic coatings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10293—Edge features, e.g. inserts or holes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
- B32B17/10348—Specific parts of the laminated safety glass or glazing being colored or tinted comprising an obscuration band
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3668—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties
- C03C17/3673—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties specially adapted for use in heating devices for rear window of vehicles
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/84—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
- H05B3/86—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields the heating conductors being embedded in the transparent or reflecting material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/202—Conductive
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/206—Insulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/4023—Coloured on the layer surface, e.g. ink
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/41—Opaque
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
- B32B2307/737—Dimensions, e.g. volume or area
- B32B2307/7375—Linear, e.g. length, distance or width
- B32B2307/7376—Thickness
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- B32B2605/00—Vehicles
- B32B2605/08—Cars
Definitions
- the invention relates to a composite pane with an integrated control component, in particular an integrated temperature sensor for a heating system, as well as a method for its production and the use of such a composite pane.
- Laminated panes made of two or more glass or polymer panes are used in a variety of ways, for example in buildings or in vehicles of all kinds, especially in motor vehicles as windscreens, rear windows, side windows and/or roof windows.
- one or more functional coatings are being applied to individual sides of the panes, for example, with infrared-reflecting, anti-reflective, or low-E properties.
- the use of panes with these functional coatings can, for example, improve climate comfort in vehicles and achieve energy savings.
- WO 2010/043598 A1 Another function of functional, electrically conductive layers in vehicle windows is to keep the field of vision free of ice and fogging.
- Electrical heating layers are known (see, for example, WO 2010/043598 A1), which cause targeted heating of the window by applying an electrical voltage.
- the electrical contacting of the heating layer is usually achieved via bus bars that typically run along the upper and lower edges of the window.
- the bus bars collect the current flowing through the electrical heating layer and conduct it to external leads that are connected to a voltage source.
- the voltage applied to the electric heating layer is usually controlled by external switches, which in vehicles are integrated, for example, into a dashboard. The aim is to achieve the most direct and reliable control and regulation of the heating layer possible.
- sensor buttons by a line or area electrode or by an arrangement of two coupled electrodes, for example as capacitive sensor buttons. Examples can be found in US 2007/0194216 A1. Surface electrodes for sensor switches can be integrated into glazing without additional components. It is known to form a sensor switch by means of separating lines in the functional layer to be controlled. For example, WO 2015/162107 discloses an electrical heating layer with an integrated sensor switch for its control. However, if a sensor switch is formed in a functional layer, this generally requires costly stripping of the functional layer using a laser beam to introduce the structuring separating lines. Furthermore, the sensor switch is limited to the design of the functional layer.
- the object of the invention is therefore to provide a composite pane with at least one functional, electrically conductive coating, in particular an internal heating coating, into which a control component intended for this purpose, in particular for forming a heating system, can be integrated in a simple, cost-effective manner in a functionally reliable and as unobtrusive a manner as possible.
- the composite pane with the integrated control components should be simple and cost-effective to manufacture.
- the invention relates to a composite pane, comprising at least a first pane with an inner surface III and an outer surface IV, a second pane with an inner surface II and an outer surface I.
- the first pane and the second pane are connected to one another over their surface by a thermoplastic intermediate layer.
- At least one functional, electrically conductive coating preferably a heating layer, is applied to at least part of the inner surface III of the first pane and is functionally connected to a control module.
- the control module comprises at least one control component, in particular a resistive or capacitive sensor.
- the control component is accommodated in a recess in the thermoplastic intermediate layer and is electrically insulated from the functional, electrically conductive coating by an insulating film arranged at least in the region of the recess.
- the inner side III of the first pane is arranged facing the inner side II of the second pane.
- a composite pane with a control module is provided with at least one discreetly integrated control component, in particular for a heating system with an internal, electrically conductive heating layer.
- the control component is mounted between the panes in a recess of the thermoplastic intermediate layer and is reliably electrically insulated from the heating layer by the insulation film, thus ensuring flawless and long-lasting functionality.
- the control module can comprise additional functional components, such as all necessary connections, lines to a power supply or communicative connections to a control unit and/or additional sensors.
- the control component is a thermistor, in particular a PTC thermistor or NTC thermistor.
- a thermistor is an electrical resistor whose value changes reproducibly with temperature.
- Thermistors are divided into the two groups mentioned above according to their temperature behavior: NTC thermistors, which have a negative temperature coefficient (NTC) and conduct electricity better when hot than when cold, and PTC thermistors, which have a positive temperature coefficient (PTC) and conduct electricity better when cold than when hot.
- NTC thermistors which have a negative temperature coefficient (NTC) and conduct electricity better when hot than when cold
- PTC thermistors which have a positive temperature coefficient (PTC) and conduct electricity better when cold than when hot.
- Metals, semiconducting ceramic materials, such as metal oxides or silicon, are used as resistance materials.
- the thermistor can, for example, be a small, wired chip for power supply and functional connection to a control unit, for example with a size (LxWxH) of approximately 1 mm x 0.5 mm x 0.5 mm.
- This size is given only as an example and is not to be understood as limiting.
- the size can be adapted to use in the selected intermediate layer of the laminated pane. This enables the integration of the thermistor with its functionality into the laminated pane according to the invention, namely into a recess in the intermediate layer, without this control component being destroyed during production or the (glass) panes breaking, for example, during lamination.
- the recess of the thermoplastic intermediate layer has a volume that is at least 10% larger, preferably at least 15% larger, and in particular at least 20% larger than the volume of the control component.
- the control component can also be referred to as a sensor element or switching element.
- the thermistors preferably used are usually almost wear-free, which ensures the reliability of the temperature measurement and/or the switching function by the thermistor for the long-term operation of a heating system with the heating layer.
- Thermistors are commercially available in suitable shapes, functions, and sizes.
- the thermistor can, for example, act as a temperature-dependent, self-switching switch in the control module to connect or disconnect the heating layer from the power supply. If a predefined limit temperature is exceeded, the thermistor can disconnect the heating layer from the voltage source and/or connect it if the temperature falls below a further limit temperature other than a lower limit temperature.
- the thermistor can therefore, for example, prevent impending overheating of the heating layer and any resulting delamination of the thermoplastic intermediate layer of the composite pane according to the invention, or automate the power supply to the heating layer if, for example, the outside temperature falls below 0 °C.
- the control component for example a thermistor, is designed not to directly connect or disconnect the electrically conductive layer, in particular the heating layer, to a voltage source, but is functionally coupled (connected) to a power connection, which is connected, for example, to a control unit or the on-board computer of a vehicle that controls or regulates the heating of the window pane.
- Activation or deactivation of the electrically operable heating layer can occur when the control module is set to a corresponding switching temperature or limit temperature. This also prevents unnecessary heating, for example of a windshield, by the heating layer and optimizes the energy consumption of the motor vehicle, which is an important aspect, especially in electric vehicles.
- Thermistors are proven, commercially available components that can advantageously be integrated cost-effectively.
- control component is thus functionally connected to a control unit, in particular a power electronics unit, such as an on-board computer of a vehicle.
- control component is functionally connected to one or more further, identical or different control components.
- control component is, for example, a thermistor
- this can be functionally connected to further sensors, for example temperature sensors of the same or different type, or for example to humidity sensors.
- further sensors for example temperature sensors of the same or different type, or for example to humidity sensors.
- the control component can be arranged in an edge region of the composite pane. Arranging the control component at the edge also has the advantage that the wiring and signal paths can be shortened.
- the edge is preferably understood to be an area of 1 cm to 25 cm from the edges of the pane.
- the edge is understood to be an area outside the legally defined central field of vision for a driver.
- the control components do not necessarily have to be arranged in the area of a conventional masking print (black print), since they can advantageously be integrated very discreetly and visually barely perceptibly into the laminated pane.
- the control component can be arranged approximately 20 mm from the edge of a masking area towards the center of the pane.
- the insulation film is a film containing polyethylene terephthalate (PET), preferably a film made of PET.
- PET polyethylene terephthalate
- This material has the advantage that it is commercially available as a film in various layer thicknesses and has already proven itself in use in composite panes, particularly in vehicle windows. This is primarily due to the advantageous material properties, in particular transparency, adhesive properties, and compatibility with the materials commonly used for the production of composite panes, particularly vehicle windows, such as glass and polyvinyl butyral films (PVB).
- the insulation film of the composite pane according to the invention preferably has a thickness of greater than 20 ⁇ m, particularly preferably from 20 ⁇ m to 100 ⁇ m, in particular from 25 ⁇ m to 60 ⁇ m, for example a thickness of 50 ⁇ m. These layer thicknesses are sufficient to reliably ensure the electrical insulation of the control components from the electrically conductive coating. The thinner the insulation film, the more inconspicuously it can be integrated into the composite pane.
- the insulation film, for example PET film can also be self-adhesive, which simplifies positioning and fixing in the desired arrangement in the region of the recess of the thermoplastic intermediate layer during production.
- the insulation film is preferably semi-transparent, especially transparent. This makes the area in which the control component is arranged less visually conspicuous.
- Transparent in the context of the invention means a light transmission TL (according to ISO 9050:2003) of at least 50%, preferably at least 60%, and especially preferably at least 70%.
- Semitransparent in the context of the invention means a light transmission TL of at most 50%, preferably at most 30%, and particularly preferably at most 10%.
- Transparent adhesive tape for example, can also be used as an insulation film.
- OCA Transparent adhesive tape
- a functional coating used as an electrical heating layer can, in principle, be any coating that can be electrically contacted. If the pane according to the invention is intended to allow visibility, as is the case, for example, with panes in window areas, the functional coating is preferably transparent. Particularly preferably, the functional electrically conductive coating is transparent. This is particularly important for laminated panes where particularly high transparency is required to meet requirements, such as windshields.
- Electrically conductive, functional coatings according to the invention are known, for example, from DE 20 2008 017 611 U1, EP 0 847 965 B1 or WO 2012/052315 A1. They typically contain one or more, for example two, three or four or even more, electrically conductive, functional layers.
- the functional layers preferably contain at least one metal, for example silver, gold, copper, nickel and/or chromium, or a metal alloy.
- the functional layers particularly preferably contain at least 90 wt. % of the metal, in particular at least 99.9 wt. % of the metal.
- the functional layers can consist of the metal or the metal alloy.
- the functional layers particularly preferably contain silver or a silver-containing alloy.
- Such functional layers have particularly advantageous electrical conductivity with simultaneous high transmission in the visible spectral range.
- the thickness of a functional layer is preferably from 5 nm to 50 nm, particularly preferably from 8 nm to 25 nm. In this range for the thickness of the functional layer, an advantageously high transmission in the visible spectral range and a particularly advantageous electrical conductivity are achieved.
- the functional electrically conductive coating is preferably a heating layer and, in particularly preferred embodiments, contains at least one silver layer (Ag).
- the functional coating is a layer or a layer structure of several individual layers with a total thickness of less than or equal to 2 pm, particularly preferably less than or equal to 1 pm, for example less than or equal to 0.5 pm, such as less than 400 nm or between 350 and 250 nm.
- bus bars intended for connection to a voltage source are connected to the functional electrically conductive coating in such a way that a current path for a heating current is formed between the bus bars.
- An advantageous functional coating according to the invention, used as an electrical heating layer, has, for example, a surface resistance of 0.4 ohms/square to 10 ohms/square.
- the functional coating according to the invention has a surface resistance of 0.5 ohms/square to 1 ohm/square. Coatings with such surface resistances are particularly suitable for heating vehicle windows with typical on-board voltages of 12 V to 48 volts or in electric vehicles with typical on-board voltages of up to 500 V.
- the busbar according to the invention is formed as a printed and fired-in conductive structure.
- the printed busbar preferably contains at least one metal, a metal alloy, a metal compound, and/or carbon, particularly preferably a precious metal, and in particular silver.
- the printing paste preferably contains metallic particles, metal particles, and/or carbon, and in particular precious metal particles such as silver particles.
- Electrical conductivity is preferably achieved by the electrically conductive particles.
- the particles can be contained in an organic and/or inorganic matrix such as pastes or inks, preferably as a printing paste with glass frits.
- the width of the first and second bus bars is preferably from 2 mm to 30 mm, particularly preferably from 4 mm to 20 mm, and in particular from 10 mm to 20 mm.
- Thinner bus bars lead to excessive electrical resistance and thus to excessive heating of the bus bars during operation.
- thinner Bus bars are difficult to produce using printing techniques such as screen printing.
- Thicker bus bars require an undesirably high amount of material.
- They lead to an excessive and unsightly restriction of the view through the pane.
- the length of the bus bar depends on the extent of the electrical heating layer. For a bus bar, which is typically designed in the form of a strip, the longer of its dimensions is referred to as the length and the shorter of its dimensions as the width.
- the third or additional bus bars can also be thinner, preferably from 0.6 mm to 5 mm.
- the layer thickness of the printed busbar is preferably from 5 pm to 40 pm, particularly preferably from 8 pm to 20 pm, and most preferably from 8 pm to 12 pm.
- Printed busbars with these thicknesses are technically easy to implement and have advantageous current-carrying capacity.
- the specific resistance pa of the bus bars is preferably between 0.8 pOhm cm and 7.0 pOhm cm, and particularly preferably between 1.0 pOhm cm and 2.5 pOhm cm. Bus bars with specific resistances in this range are technically simple to implement and exhibit advantageous current-carrying capacity.
- the electrical supply line to the functional, electrically conductive coating can also be designed as a flexible foil conductor (flat conductor, ribbon conductor).
- a flexible foil conductor refers to an electrical conductor whose width is significantly greater than its thickness.
- a foil conductor is, for example, a strip or ribbon containing or consisting of copper, tinned copper, aluminum, silver, gold, or alloys thereof.
- the foil conductor has, for example, a width of 2 mm to 16 mm and a thickness of 0.03 mm to 0.1 mm.
- the foil conductor can have an insulating, preferably polymeric, sheath, for example based on polyimide.
- Foil conductors suitable for contacting electrically conductive coatings in wafers have a total thickness of only 0.3 mm, for example. Such thin foil conductors can be easily embedded between the individual wafers in the thermoplastic intermediate layer.
- a foil conductor ribbon can contain several electrically insulated, conductive layers.
- thin metal wires can be used as electrical leads for the electrically conductive functional coating.
- the metal wires contain in particular copper, tungsten, gold, silver, or aluminum, or alloys of at least two of these metals.
- the alloys may also contain molybdenum, rhenium, osmium, iridium, palladium, or platinum.
- the functional, electrically conductive heating layer can extend over the entire surface of the first pane and/or the second pane, preferably only the first pane.
- the functional coating can also extend over only a portion of the surface of the first pane and/or the second pane, preferably only the first pane.
- the functional coating preferably extends over at least 50%, particularly preferably over at least 70%, and most particularly preferably over at least 90% of the inner surface of the first pane.
- the functional coating can have one or more uncoated zones in the inner region and/or the outer region. These zones can be permeable to electromagnetic radiation and are known, for example, as data transmission windows or communication windows.
- the functional coating can be applied to the surface of the substrate and the masking coating by means of vacuum-based vapor deposition.
- the functional coating is applied by means of physical vapor deposition (PVD) or chemical vapor deposition (CVD), in particular by means of physical vapor deposition.
- PVD physical vapor deposition
- CVD chemical vapor deposition
- Sputtering in particular magnetic field-assisted sputtering (magnetron sputtering)
- magnetic sputtering has proven particularly suitable for producing thin films on glass substrates.
- other types of physical vapor deposition can also be used, for example, thermal evaporation (evaporation), electron beam evaporation, laser beam evaporation,
- Arc evaporation or molecular beam epitaxy Arc evaporation or molecular beam epitaxy.
- Preferred CVD processes are plasma-enhanced chemical vapor deposition (PECVD) and atomic layer deposition (ALD).
- adhesion promoter layers can also be applied beneath the actual functional coating, for example adhesion promoter layers to improve the adhesion of the functional coating to the substrate, adjustment or smoothing layers to influence the morphology of the functional coating, or blocker layers to prevent alkali diffusion from the glass substrate into the To prevent functional layer deterioration.
- Suitable adhesion promoter layers are based, for example, on silicon nitride (SiN) or oxide (SiO) or aluminum nitride (AIN) or oxide (AlO)
- suitable adaptation layers are based, for example, on SnZnO or zinc oxide (ZnO)
- suitable blocker layers are based, for example, on NiCr or SiN.
- the invention further relates to a method for producing a composite pane as described above in various embodiments, comprising the steps
- thermoplastic film with at least one recess for forming an intermediate layer
- a composite pane with an internal heating coating can be provided in which a control component intended for this purpose, in particular for forming a heating system, can be integrated in a simple, cost-effective manner in a functionally reliable and as unobtrusive a manner as possible.
- the composite pane with the integrated control components can be manufactured simply and cost-effectively. This is particularly possible with the current mechanical and process engineering approach for the production of composite panes without the need for complex adjustments.
- the functional electrically conductive coating is applied to the inner surface (III) of the first pane and/or to the inner surface (II) of the second pane by means of physical vapor deposition (PVD) or chemical vapor deposition (CVD).
- PVD physical vapor deposition
- CVD chemical vapor deposition
- step B) the at least one recess is introduced into the thermoplastic film by cutting or punching.
- a recess can also be formed by forming the thermoplastic film in multiple pieces, omitting the partial area for the recess.
- control module in particular the control component, is functionally connected to one or more other, identical or different control components, for example, sensors and/or a control unit. If multiple control components are provided, each of them is preferably assigned a recess in the thermoplastic intermediate layer, and each of these is reliably electrically insulated from electrically conductive coatings on the inner surfaces of the panes by an insulating film.
- the invention also relates to the use of the composite pane according to the invention in buildings or in means of transport for traffic on land, in the air or on water, in particular in motor vehicles, for example as a windscreen, rear window, side windows and/or roof window.
- the first pane and/or the second pane preferably contain glass, particularly preferably flat glass, float glass, quartz glass, borosilicate glass, soda-lime glass, or clear plastics, preferably rigid clear plastics, in particular polyethylene, polypropylene, polycarbonate, polymethyl methacrylate, polystyrene, polyamide, polyester, polyvinyl chloride, and/or mixtures thereof.
- the first pane and/or the second pane are preferably transparent, particularly for use as a windshield or rear window of a vehicle or for other applications where high light transmission is desired.
- the thickness of the individual panes can vary widely and can thus be perfectly adapted to the requirements of the individual case. Standard thicknesses of 1.0 mm to 25 mm are preferred, with 1.4 mm to 2.5 mm being preferred for automotive glass.
- the composite pane can have any three-dimensional shape.
- the three-dimensional shape has no shadow zones, allowing it to be coated, for example, by cathode sputtering.
- the panes are preferably planar or, as in the case of vehicle windows, slightly or strongly curved in one or more directions of space.
- the panes can be colorless or colored.
- the panes are joined together to form the composite pane by at least one intermediate layer.
- the intermediate layer preferably contains at least one thermoplastic, preferably polyvinyl butyral (PVB), ethylene vinyl acetate (EVA) and/or polyethylene terephthalate (PET).
- the thermoplastic intermediate layer can also contain, for example, polyurethane (PU), polypropylene (PP), polyacrylate, polyethylene (PE), polycarbonate (PC), polymethyl methacrylate, polyvinyl chloride, polyacetate resin, casting resins, acrylates, fluorinated ethylene propylene, polyvinyl fluoride and/or ethylene tetrafluoroethylene, or copolymers or mixtures thereof.
- Typical layer thicknesses for commercially available PVB films are, for example, 0.76 mm or 1.14 mm, although this is not limiting for the invention.
- thermoplastic intermediate layer of the composite pane a recess is provided into which the control component, in particular a Thermistor, can be accommodated and positioned.
- This recess can be created, for example, by punching or cutting into the thermoplastic film from which the intermediate layer is formed during lamination.
- the thermoplastic film can also be formed in multiple pieces, leaving the position for the control component free, and form the intermediate layer with the recess.
- Figure 1 is a cross-sectional view of an embodiment of the composite pane according to the invention.
- Figure 2 is a plan view of the composite pane of Fig. 1,
- Figure 3 is a cross-sectional view of another embodiment of the composite pane according to the invention.
- Figure 1 shows a cross-sectional view of an embodiment of the composite pane 100 according to the invention, which comprises a first pane 1 with an inner surface III and an outer surface IV, a second pane 2 with an inner surface II and an outer surface I, which are joined to one another by a thermoplastic intermediate layer 4.
- a functional, electrically conductive coating 3, which is preferably a heating layer, is applied to the inner surface III of the first pane 1.
- the thermoplastic intermediate layer 4 accommodates a control component 6, which is electrically insulated from the functional electrically conductive coating 3 by an insulating film 5 arranged at least in the region of the recess 7.
- the thermoplastic intermediate layer 4 can be formed in multiple layers from several thermoplastic films arranged one above the other, into which the recess 7 has been precisely fitted.
- the recess 7 can be formed, for example, by punching or cutting.
- the intermediate layer 4 can also be formed in multiple pieces from film parts, omitting the position for the control component 6.
- the control component 6 is preferably a capacitive or resistive sensor, in particular a thermistor with electrical connections 8 (wired), which is functionally connected to the functional electrically conductive coating 3.
- a composite pane 100 is thus provided with an inconspicuously integrated control component 6, in particular for a heating system with an internal, electrically conductive coating 3 as the heating layer.
- the control component 6 is securely and non-destructively integrated and mounted between the first pane 1 and the second pane 2 in a recess 7 of the thermoplastic intermediate layer 4 and is reliably electrically insulated from the coating 3 by the insulating film 5, thus ensuring flawless and long-lasting functionality.
- the insulating film 5 is designed with an overlap to dimension the recess 7 in order to ensure the electrical insulation of the control components 6 from the electrically conductive coating 3 even in the event of a slight offset during production.
- the insulating film 5 can be a PET film, for example.
- the electrical connections of the functional coating 3 and any other cable and signal paths that may be present to a control unit, for example to the on-board computer of a vehicle, are not shown. These can be designed in the usual way.
- FIG. 2 shows a plan view of the composite pane 100 of Figure 1 in an indicated trapezoidal shape of a windshield.
- the windshield has a first side edge S1, a second side edge S2, a roof edge D and an engine edge M, as well as a central viewing area Z for a driver, which is defined by law.
- the designations are made solely with regard to an installation position in a vehicle.
- the thermistor as the control component 6 is arranged in an edge region R of the composite pane 100 outside the central viewing area Z and also outside a
- the control component 6 is arranged in the masking area 9. This enables rapid detection of temperatures and/or other measurement data, and the signal and line paths are not too long. If desired or necessary, the control component 6 can also be arranged at least partially in the masking area 9.
- Figure 3 shows a cross-sectional view of a further embodiment of the composite pane 100 according to the invention.
- a functional electrically conductive coating 3a is provided on the inner surface II of the second pane 2, against which the control component 6, for example the thermistor, is electrically insulated with an additional insulation film 5a.
- Control component e.g. thermistor
- Masking area e.g. black print
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Abstract
Description
Verbundscheibe mit integrierter Steuerkomponente Composite disc with integrated control component
Die Erfindung betrifft eine Verbundscheibe mit einer integrierten Steuerkomponente, insbesondere einem integrierten Temperatursensor für ein Heizsystem, sowie ein Verfahren zu deren Herstellung und die Verwendung einer solchen Verbundscheibe.The invention relates to a composite pane with an integrated control component, in particular an integrated temperature sensor for a heating system, as well as a method for its production and the use of such a composite pane.
Verbundscheiben aus zwei oder mehr gläsernen oder polymeren Scheiben werden in vielfältiger Weise, zum Beispiel in Gebäuden oder in Fahrzeugen aller Art, insbesondere in Kraftfahrzeugen als Windschutzscheibe, Heckscheibe, Seitenscheibe und/oder Dachscheibe eingesetzt. Laminated panes made of two or more glass or polymer panes are used in a variety of ways, for example in buildings or in vehicles of all kinds, especially in motor vehicles as windscreens, rear windows, side windows and/or roof windows.
In zunehmendem Maße werden auf einzelnen Seiten der Scheiben eine oder mehrere funktionelle Beschichtungen angeordnet, die beispielsweise infrarotreflektierende Eigenschaften, Antireflex-Eigenschaften oder Low-E-Eigenschaften aufweisen. Durch den Einsatz von Scheiben mit diesen funktionellen Beschichtungen können beispielsweise der Klima-Komfort in Fahrzeugen verbessert und Energieeinsparungen erzielt werden. Increasingly, one or more functional coatings are being applied to individual sides of the panes, for example, with infrared-reflecting, anti-reflective, or low-E properties. The use of panes with these functional coatings can, for example, improve climate comfort in vehicles and achieve energy savings.
Eine andere Funktion funktioneller, elektrisch leitfähiger Schichten zielt bei Fahrzeugscheiben darauf ab, das Sichtfeld frei von Eis und Beschlag zu halten. Bekannt sind elektrische Heizschichten (siehe z.B. WO 2010/043598 A1), die durch Anlegen einer elektrischen Spannung eine gezielte Erwärmung der Scheibe bewirken. WO 2003/024155 A2, US 2007/0082219 A1 , US 2007/0020465 A1 und WO 2012/052315 A1 offenbaren beispielsweise eine solche beheizbare, elektrisch leitfähige Beschichtung auf Metallbasis und insbesondere auf der Basis eines Schichtaufbaus von einer oder mehreren silberhaltigen Lagen. Die elektrische Kontaktierung der Heizschicht erfolgt üblicherweise über Sammelleiter, die typischerweise entlang der oberen und unteren Kante der Scheibe verlaufen. Die Sammelleiter sammeln den Strom, der durch die elektrische Heizschicht fließt und leiten ihn zu externen Zuleitungen, die mit einer Spannungsquelle verbunden sind. Die Spannung, die an der elektrischen Heizschicht anliegt, wird in aller Regel durch externe Schalter gesteuert, die bei Fahrzeugen beispielsweise in einem Armaturenbrett integriert sind. Wünschenswert ist eine möglichst unmittelbare und zuverlässige Kontrolle und Steuerung der Heizschicht zu erreichen. Another function of functional, electrically conductive layers in vehicle windows is to keep the field of vision free of ice and fogging. Electrical heating layers are known (see, for example, WO 2010/043598 A1), which cause targeted heating of the window by applying an electrical voltage. WO 2003/024155 A2, US 2007/0082219 A1, US 2007/0020465 A1 and WO 2012/052315 A1, for example, disclose such a heatable, electrically conductive coating based on metal and in particular based on a layer structure of one or more silver-containing layers. The electrical contacting of the heating layer is usually achieved via bus bars that typically run along the upper and lower edges of the window. The bus bars collect the current flowing through the electrical heating layer and conduct it to external leads that are connected to a voltage source. The voltage applied to the electric heating layer is usually controlled by external switches, which in vehicles are integrated, for example, into a dashboard. The aim is to achieve the most direct and reliable control and regulation of the heating layer possible.
Es ist weiterhin bekannt, Sensorschaltflächen durch eine Linien- oder Flächenelektrode oder durch eine Anordnung von zwei gekoppelten Elektroden auszubilden, beispielsweise als kapazitive Sensorschaltflächen. Beispiele finden sich in US 2007/0194216 A1. Flächenelektroden für Sensorschaltflächen können ohne weitere Bauelemente in eine Verglasung integriert werden. Bekannt ist es, eine Sensorschaltfläche durch Trennlinien in der zu steuernden Funktionsschicht selbst auszubilden. Beispielsweise offenbart WO 2015/162107 eine elektrische Heizschicht mit einer integrierten Sensorschaltfläche zu deren Steuerung. Wird eine Sensorschaltfläche in einer Funktionsschicht ausgebildet, erfordert dies in aller Regel aber eine kostenintensive Entschichtung der Funktionsschicht mittels Laserstrahl zum Einbringen der strukturierenden Trennlinien. Zudem ist die Sensorschaltfläche auf die Ausgestaltung der Funktionsschicht eingeschränkt. It is also known to form sensor buttons by a line or area electrode or by an arrangement of two coupled electrodes, for example as capacitive sensor buttons. Examples can be found in US 2007/0194216 A1. Surface electrodes for sensor switches can be integrated into glazing without additional components. It is known to form a sensor switch by means of separating lines in the functional layer to be controlled. For example, WO 2015/162107 discloses an electrical heating layer with an integrated sensor switch for its control. However, if a sensor switch is formed in a functional layer, this generally requires costly stripping of the functional layer using a laser beam to introduce the structuring separating lines. Furthermore, the sensor switch is limited to the design of the functional layer.
Es hat sich in Versuchen als problematisch herausgestellt, Komponenten, beispielsweise Sensoren für die Steuerung einer Heizschicht in die Verbundscheibe, also zwischen Außen - und Innenscheibe, zu integrieren, da die übliche thermoplastische Zwischenschicht nicht ausreichend ist, um eine elektrische Kontaktierung mit der Heizschicht sicher zu unterbinden. So ist die zuverlässige Steuerungsfunktion durch diese oder mit Hilfe dieser Steuerungskomponenten nicht sicher und dauerhaft gewährleistet. Ein zusätzliches Problem ergibt sich daraus, dass die Steuerungskomponenten im Herstellprozess, insbesondere durch den ausgeübten Druck zwischen den Scheiben während der Lamination zur Verbundscheibe, zerstört werden können oder durch die thermoplastische Zwischenschicht auf die elektrisch leitfähige Heizschicht gedrückt wird, mit den bereits genannten Folgen. Tests have shown that integrating components such as sensors for controlling a heating layer into the laminated pane, i.e. between the outer and inner panes, is problematic. This is because the usual thermoplastic intermediate layer is not sufficient to reliably prevent electrical contact with the heating layer. Therefore, reliable control functionality cannot be safely and permanently guaranteed by or with the aid of these control components. An additional problem arises from the fact that the control components can be destroyed during the manufacturing process, particularly due to the pressure exerted between the panes during lamination to form the laminated pane, or that the thermoplastic intermediate layer can press against the electrically conductive heating layer, with the consequences already mentioned.
Aufgabe der Erfindung ist es daher eine Verbundscheibe mit mindestens einer funktionellen, elektrisch leitfähigen Beschichtung, insbesondere einer innenliegenden Heizbeschichtung bereitzustellen, in der auf einfache, kostengünstige Weise eine hierfür vorgesehene Steuerungskomponente, insbesondere zur Bildung eines Heizsystems funktionell sicher und möglichst unauffällig integriert werden kann. Die Verbundscheibe mit der integrierten Steuerkomponenten soll dabei einfach und kostengünstig herzustellen sein. The object of the invention is therefore to provide a composite pane with at least one functional, electrically conductive coating, in particular an internal heating coating, into which a control component intended for this purpose, in particular for forming a heating system, can be integrated in a simple, cost-effective manner in a functionally reliable and as unobtrusive a manner as possible. The composite pane with the integrated control components should be simple and cost-effective to manufacture.
Diese und weitere Aufgaben werden durch eine Verbundscheibe gemäß Anspruch 1 gelöst. Bevorzugte Ausgestaltungen sind in den Unteransprüchen angegeben. These and other objects are achieved by a composite pane according to claim 1. Preferred embodiments are specified in the subclaims.
Die Erfindung betrifft eine Verbundscheibe, mindestens umfassend eine erste Scheibe mit einer innenliegenden Oberfläche III und einer äußeren Oberfläche IV, eine zweite Scheibe mit einer innenliegenden Oberfläche II und einer äußeren Oberfläche I. Die erste Scheibe und die zweite Scheibe sind durch eine thermoplastische Zwischenschicht flächig miteinander verbunden. Mindestens eine funktionelle, elektrisch leitfähige Beschichtung, bevorzugt eine Heizschicht, ist zumindest auf einem Teil der innenliegenden Oberfläche III der ersten Scheibe aufgebracht und mit einem Steuermodul funktionell verbunden. Das Steuermodul umfasst zumindest eine Steuerkomponente, insbesondere einen resistiven oder kapazitiven Sensor. Die Steuerkomponente ist in einer Ausnehmung in der thermoplastische Zwischenschicht aufgenommen und durch eine, mindestens im Bereich der Ausnehmung angeordnete Isolationsfolie zur funktionellen, elektrisch-leitfähigen Beschichtung hin, elektrisch isoliert. Die innenliegende Seite III der ersten Scheibe ist der innenliegenden Seite II der zweiten Scheibe zugewandt angeordnet. The invention relates to a composite pane, comprising at least a first pane with an inner surface III and an outer surface IV, a second pane with an inner surface II and an outer surface I. The The first pane and the second pane are connected to one another over their surface by a thermoplastic intermediate layer. At least one functional, electrically conductive coating, preferably a heating layer, is applied to at least part of the inner surface III of the first pane and is functionally connected to a control module. The control module comprises at least one control component, in particular a resistive or capacitive sensor. The control component is accommodated in a recess in the thermoplastic intermediate layer and is electrically insulated from the functional, electrically conductive coating by an insulating film arranged at least in the region of the recess. The inner side III of the first pane is arranged facing the inner side II of the second pane.
Erfindungsgemäß wird so eine Verbundscheibe mit einem Steuermodul mit mindestens einer unauffällig integrierten Steuerkomponenten, insbesondere für ein Heizsystem mit einer innenliegenden, elektrisch leitfähigen Heizschicht bereitgestellt. Die Steuerkomponente ist dabei zwischen den Scheiben in einer Ausnehmung der thermoplastischen Zwischenschicht gelagert und von der Heizschicht durch die Isolationsfolie sicher elektrisch isoliert, so dass eine einwandfreie und dauerhafte Funktionsfähigkeit gewährleistet ist. Das Steuermodul kann dabei weitere funktionelle Komponenten, wie alle notwendigen Anschlüsse, Leitungen an eine Stromversorgung oder kommunikative Verbindungen zu einer Steuereinheit und/oder auch weitere Sensoren umfassen. According to the invention, a composite pane with a control module is provided with at least one discreetly integrated control component, in particular for a heating system with an internal, electrically conductive heating layer. The control component is mounted between the panes in a recess of the thermoplastic intermediate layer and is reliably electrically insulated from the heating layer by the insulation film, thus ensuring flawless and long-lasting functionality. The control module can comprise additional functional components, such as all necessary connections, lines to a power supply or communicative connections to a control unit and/or additional sensors.
In einer bevorzugten Ausgestaltung der Erfindung ist die Steuerkomponente ein Thermistor, insbesondere ein Kaltleiter (PTC-Thermistor) oder ein Heißleiter (NTC- Thermistor). Ein Thermistor ist ein elektrischer Widerstand, dessen Wert sich mit der Temperatur reproduzierbar ändert. Thermistoren unterteilen sich in ihren Temperaturverhalten in die zwei genannten Gruppen, nämlich Heißleiter, welche über einen negativen Temperaturkoeffizienten (NTC) verfügen und im heißen Zustand besser elektrisch leiten als im kalten Zustand und in Kaltleiter, welche über einen positiven Temperaturkoeffizienten (PTC) verfügen und im kalten Zustand besser elektrisch leiten als im heißen Zustand. Als Widerstandsmaterial werden Metalle, halbleitende, keramische Werkstoffe, wie Metalloxide oder Silizium verwendet. Erfindungsgemäß kann der Thermistor beispielsweise als kleiner, zur Stromversorgung und funktionellen Verbindung zu einem Steuergerät, bedrahteter Chip, beispielsweise mit einer Baugröße (LxBxH) von ca. 1 mm x 0,5 mm x 0,5 mm ausgestaltet sein. Diese Baugröße ist nur beispielhaft genannt und nicht einschränkend zu verstehen. Die Baugröße kann auf die Verwendung in der jeweilig ausgewählten Zwischenschicht der Verbundscheibe angepasst werden. Dies ermöglicht die Integration des Thermistors mit dessen Funktionalität in die erfindungsgemäße Verbundscheibe, nämlich in eine Ausnehmung der Zwischenschicht ohne, dass es bei der Herstellung zur Zerstörung dieser Steuerkomponente oder zu einem Bruch der (Glas-) Scheiben, beispielsweise während der Lamination kommt. In a preferred embodiment of the invention, the control component is a thermistor, in particular a PTC thermistor or NTC thermistor. A thermistor is an electrical resistor whose value changes reproducibly with temperature. Thermistors are divided into the two groups mentioned above according to their temperature behavior: NTC thermistors, which have a negative temperature coefficient (NTC) and conduct electricity better when hot than when cold, and PTC thermistors, which have a positive temperature coefficient (PTC) and conduct electricity better when cold than when hot. Metals, semiconducting ceramic materials, such as metal oxides or silicon, are used as resistance materials. According to the invention, the thermistor can, for example, be a small, wired chip for power supply and functional connection to a control unit, for example with a size (LxWxH) of approximately 1 mm x 0.5 mm x 0.5 mm. This size is given only as an example and is not to be understood as limiting. The size can be adapted to use in the selected intermediate layer of the laminated pane. This enables the integration of the thermistor with its functionality into the laminated pane according to the invention, namely into a recess in the intermediate layer, without this control component being destroyed during production or the (glass) panes breaking, for example, during lamination.
Besonders bevorzugt weist die Ausnehmung der thermoplastischen Zwischenschicht ein um mindestens 10 % größeres, bevorzugt ein um mindestens 15 % größeres, insbesondere ein um mindestens 20 % größeres Volumen auf als das Volumen der Steuerkomponente. Hierdurch besteht bei der Anordnung der Steuerkomponente in die Ausnehmung und während der Herstellung der Verbundscheibe mehr Gestaltungsraum und die Prozesse werden vereinfacht. Insbesondere kommt es hierbei auch zu weniger Schädigungen am Thermistor oder der Verbundscheibe in Folge des Drucks beim Laminationsprozesses. Particularly preferably, the recess of the thermoplastic intermediate layer has a volume that is at least 10% larger, preferably at least 15% larger, and in particular at least 20% larger than the volume of the control component. This provides more design flexibility when arranging the control component in the recess and during the production of the composite pane, and the processes are simplified. In particular, this also results in less damage to the thermistor or the composite pane as a result of the pressure during the lamination process.
Die Steuerkomponente kann auch als Sensorelement oder Schaltelement bezeichnet werden. Vorteilhafterweise sind die bevorzugt eingesetzten Thermistoren gewöhnlich nahezu verschleißfrei, was die Zuverlässigkeit der Temperaturmessung, und/oder der Schaltfunktion durch den Thermistor für den Betrieb eines Heizsystems mit der Heizschicht auch langfristig gewährleistet. Thermistoren stehen in geeigneter Form, Funktion und Baugröße kommerziell zur Verfügung. Der Thermistor kann beispielsweise als temperaturabhängig selbstschaltender Schalter im Steuermodul die Verbindung oder die Trennung der Heizschicht von der Stromversorgung bewirken. Bei Überschreiten einer vorgebbaren Grenztemperatur kann der Thermistor die Heizschicht von der Spannungsquelle trennen und/oder bei Unterschreiten einer von einer unteren Grenztemperatur verschiedenen weiteren Grenztemperatur verbinden. Durch den Thermistor kann also beispielsweise eine drohende Überhitzung der Heizschicht und eine gegebenenfalls dadurch verursachte Delamination der thermoplastischen Zwischenschicht der erfindungsgemäßen Verbundscheibe verhindert werden oder die Bestromung der Heizschicht automatisiert erfolgen, wenn zum Beispiel 0 °C Außentemperatur unterschritten wird. Bevorzugt ist die Steuerkomponente, beispielsweise ein Thermistor, dazu ausgebildet, die elektrisch leitfähige Schicht, insbesondere Heizschicht, nicht direkt mit einer Spannungsquelle zu verbinden oder von dieser zu trennen, sondern ist mit einem Stromanschluss, der beispielsweise mit einem Steuergerät oder dem Bordcomputer eines Fahrzeugs verbunden ist, welches die Beheizung der Fensterscheibe steuert oder regelt funktionell gekoppelt (verbunden). Eine Aktivierung oder Deaktivierung der elektrisch betreibbaren Heizschicht kann dann erfolgen, wenn das Steuermodul auf eine entsprechende Schalttemperatur beziehungsweise Grenztemperatur eingestellt ist. Dadurch kann auch ein unnötiges Beheizen, beispielsweise einer Windschutzscheibe, durch die Heizschicht vermieden und der Energieverbrauch des Kraftfahrzeugs optimiert werden, was insbesondere bei Elektrofahrzeugen ein wichtiger Aspekt ist. Thermistoren sind bewährte, kommerziell erhältliche Bauteile, die vorteilhafterweise kostengünstig integrierbar sind. The control component can also be referred to as a sensor element or switching element. Advantageously, the thermistors preferably used are usually almost wear-free, which ensures the reliability of the temperature measurement and/or the switching function by the thermistor for the long-term operation of a heating system with the heating layer. Thermistors are commercially available in suitable shapes, functions, and sizes. The thermistor can, for example, act as a temperature-dependent, self-switching switch in the control module to connect or disconnect the heating layer from the power supply. If a predefined limit temperature is exceeded, the thermistor can disconnect the heating layer from the voltage source and/or connect it if the temperature falls below a further limit temperature other than a lower limit temperature. The thermistor can therefore, for example, prevent impending overheating of the heating layer and any resulting delamination of the thermoplastic intermediate layer of the composite pane according to the invention, or automate the power supply to the heating layer if, for example, the outside temperature falls below 0 °C. Preferably, the control component, for example a thermistor, is designed not to directly connect or disconnect the electrically conductive layer, in particular the heating layer, to a voltage source, but is functionally coupled (connected) to a power connection, which is connected, for example, to a control unit or the on-board computer of a vehicle that controls or regulates the heating of the window pane. Activation or deactivation of the electrically operable heating layer can occur when the control module is set to a corresponding switching temperature or limit temperature. This also prevents unnecessary heating, for example of a windshield, by the heating layer and optimizes the energy consumption of the motor vehicle, which is an important aspect, especially in electric vehicles. Thermistors are proven, commercially available components that can advantageously be integrated cost-effectively.
In einer bevorzugten Ausgestaltung der erfindungsgemäßen Verbundscheibe ist die Steuerkomponente also mit einer Steuereinheit, insbesondere einer Leistungselektronik, wie einem Bordcomputer eines Fahrzeugs funktionell verbunden. In a preferred embodiment of the composite pane according to the invention, the control component is thus functionally connected to a control unit, in particular a power electronics unit, such as an on-board computer of a vehicle.
In einer weiter bevorzugten Ausführungsform der Erfindung ist die Steuerkomponente mit einem oder mehreren weiteren, gleichen oder unterschiedlichen Steuerkomponenten funktionell verbunden ist. Ist die Steuerkomponente, beispielsweise ein Thermistor, so kann dieser mit weiteren Sensoren, beispielsweise Temperatursensoren, gleicher oder unterschiedlicher Art oder beispielsweise mit Feuchtigkeitssensoren funktionell verbunden sein. Dies hat den Vorteil, dass von einer entsprechend verbundenen Steuereinheit eine noch zuverlässigere Steuerung der Heizschicht, beispielsweise im Hinblick auf die Umgebungsbedingungen, erfolgen kann. Es ist zum Beispiel bisher üblich, zur Lieferung von Messdaten für die Steuerung auf der Außenscheibe eines Fahrzeugs Feuchtigkeitssensoren und/oder Temperatursensoren anzubringen. In a further preferred embodiment of the invention, the control component is functionally connected to one or more further, identical or different control components. If the control component is, for example, a thermistor, this can be functionally connected to further sensors, for example temperature sensors of the same or different type, or for example to humidity sensors. This has the advantage that an appropriately connected control unit can control the heating layer even more reliably, for example with regard to the ambient conditions. For example, it has previously been common practice to attach humidity sensors and/or temperature sensors to the outer window of a vehicle to supply measurement data for the control system.
Die Steuerkomponente kann in einem Randbereich der Verbundscheibe angeordnet sein. Eine randseitige Anordnung der Steuerkomponente hat auch den Vorteil, dass die Leitungs- und Signalwege kürzer ausgebildet sein können. Als randseitig wird erfindungsgemäß bevorzugt ein Bereich von 1 cm bis 25 cm ausgehend von den Scheibenkanten verstanden. Bei Windschutzscheiben wird als randseitig ein Bereich außerhalb des gesetzlich festgelegten zentralen Sichtfelds für einen Fahrer verstanden. Vorteilhafterweise muss die Anordnung der Steuerkomponenten nicht notwendigerweise im Bereich eines üblichen Maskierungsdrucks (Schwarzdrucks) erfolgen, da diese vorteilhafterweise ohnehin sehr unauffällig und optisch kaum wahrnehmbar in die Verbundscheibe integriert werden kann. In einer Ausgestaltung kann die Steuerkomponente ungefähr 20 mm ausgehend vom Rand eines Maskierungsbereichs Richtung Scheibenmitte angeordnet sein. Es ist jedoch dennoch möglich, dass die Anordnung der Steuerkomponenten so erfolgt, dass diese mindestens teilweise durch einen Schwarz -oder Dekordruck verdeckt werden. Dies kann gegebenenfalls nochmals das äußere Erscheinungsbild der Verbundscheibe verbessern. The control component can be arranged in an edge region of the composite pane. Arranging the control component at the edge also has the advantage that the wiring and signal paths can be shortened. According to the invention, the edge is preferably understood to be an area of 1 cm to 25 cm from the edges of the pane. For windshields, the edge is understood to be an area outside the legally defined central field of vision for a driver. Advantageously, the control components do not necessarily have to be arranged in the area of a conventional masking print (black print), since they can advantageously be integrated very discreetly and visually barely perceptibly into the laminated pane. In one embodiment, the control component can be arranged approximately 20 mm from the edge of a masking area towards the center of the pane. However, it is still possible to arrange the control components in such a way that they are at least partially concealed by a black or decorative print. This can possibly further improve the external appearance of the laminated pane.
In einer weiteren bevorzugten Ausgestaltung der erfindungsgemäßen Verbundscheibe ist die Isolationsfolie eine Folie, die Polyethylentherephtalat (PET) enthält, bevorzugt eine Folie, die aus PET besteht. Dieses Material hat den Vorteil, dass es als Folie in verschiedenen Schichtdicken kommerziell zur Verfügung steht und sich bereits im Einsatz in Verbundscheiben, insbesondere auch in Fahrzeugscheiben, bereits bewährt hat. Dies liegt vor allem an den vorteilhaften Materialeigenschaften, insbesondere Transparenz, Klebeigenschaften und der Kompatibilität mit den üblicherweise eingesetzten Materialien zur Herstellung von Verbundscheiben, insbesondere Fahrzeugscheiben, beispielsweise Glas und Polyvinylbutyral-Folien (PVB). In a further preferred embodiment of the composite pane according to the invention, the insulation film is a film containing polyethylene terephthalate (PET), preferably a film made of PET. This material has the advantage that it is commercially available as a film in various layer thicknesses and has already proven itself in use in composite panes, particularly in vehicle windows. This is primarily due to the advantageous material properties, in particular transparency, adhesive properties, and compatibility with the materials commonly used for the production of composite panes, particularly vehicle windows, such as glass and polyvinyl butyral films (PVB).
Die Isolationsfolie der erfindungsgemäßen Verbundscheibe weist bevorzugt eine Dicke von größer 20 pm, besonders bevorzugt von 20 pm bis 100 pm, insbesondere von 25 pm bis 60 pm, beispielsweise eine Dicke von 50 pm auf. Diese Schichtdicken sind ausreichend, um die elektrische Isolation der Steuerkomponenten von der elektrisch leitfähigen Beschichtung sicher zu gewährleisten. Je dünner die Isolationsfolie ausgebildet ist, desto unauffälliger kann diese optisch in die Verbundscheibe integriert werden. Die Isolationsfolie, beispielsweise PET-Folie, kann auch selbstklebend sein, was die Positionierung und Fixierung in der gewünschten Anordnung im Bereich der Ausnehmung der thermoplastischen Zwischenschicht während der Herstellung vereinfacht. The insulation film of the composite pane according to the invention preferably has a thickness of greater than 20 μm, particularly preferably from 20 μm to 100 μm, in particular from 25 μm to 60 μm, for example a thickness of 50 μm. These layer thicknesses are sufficient to reliably ensure the electrical insulation of the control components from the electrically conductive coating. The thinner the insulation film, the more inconspicuously it can be integrated into the composite pane. The insulation film, for example PET film, can also be self-adhesive, which simplifies positioning and fixing in the desired arrangement in the region of the recess of the thermoplastic intermediate layer during production.
Die Isolationsfolie ist bevorzugt semitransparent, insbesondere transparent. Auf diese Weise ist der Bereich, in dem die Steuerkomponente angeordnet ist, weniger optisch auffällig. „Transparent“ bedeutet im Sinne der Erfindung eine Lichttransmission TL (nach ISO 9050:2003) von mindestens 50 %, bevorzugt mindestens 60 % und besonders bevorzugt mindestens 70 %. Semitransparent (nach ISO 9050:2003) bedeutet im Sinne der Erfindung eine Lichttransmission TL von höchstens 50 % bevorzugt höchstens 30 % und besonders bevorzugt höchstens 10 %. The insulation film is preferably semi-transparent, especially transparent. This makes the area in which the control component is arranged less visually conspicuous. "Transparent" in the context of the invention means a light transmission TL (according to ISO 9050:2003) of at least 50%, preferably at least 60%, and especially preferably at least 70%. Semitransparent (according to ISO 9050:2003) in the context of the invention means a light transmission TL of at most 50%, preferably at most 30%, and particularly preferably at most 10%.
Als Isolationsfolie kann beispielsweise auch ein transparentes Klebeband (OCA) eingesetzt werden. Diese sind transparent, optisch unauffällig, also mit dem bloßen Auge kaum wahrnehmbar, und sind in geeigneter Ausgestaltung kommerziell erhältlich. Transparent adhesive tape (OCA), for example, can also be used as an insulation film. These are transparent, visually unobtrusive, i.e., barely visible to the naked eye, and are commercially available in suitable designs.
Eine als elektrische Heizschicht verwendete funktionelle Beschichtung kann prinzipiell jede Beschichtung sein, die elektrisch kontaktiert werden kann. Soll die erfindungsgemäße Scheibe die Durchsicht ermöglichen, wie es beispielsweise bei Scheiben im Fensterbereich der Fall ist, so ist die funktionelle Beschichtung bevorzugt transparent. Besonders bevorzugt ist die funktionelle elektrisch leitfähige Beschichtung transparent. Dies ist besonders für Verbundscheiben von Bedeutung bei denen die Transparenz besonders hoch sein muss, um den Anforderungen zu genügen, wie beispielsweise bei Windschutzscheiben. A functional coating used as an electrical heating layer can, in principle, be any coating that can be electrically contacted. If the pane according to the invention is intended to allow visibility, as is the case, for example, with panes in window areas, the functional coating is preferably transparent. Particularly preferably, the functional electrically conductive coating is transparent. This is particularly important for laminated panes where particularly high transparency is required to meet requirements, such as windshields.
Erfindungsgemäße elektrisch leitfähige, funktionelle Beschichtungen sind beispielsweise aus DE 20 2008 017 611 U1 , EP 0 847 965 B1 oder WO 2012/052315 A1 bekannt. Sie enthalten typischerweise eine oder mehrere, beispielsweise zwei, drei oder vier oder auch mehr elektrisch leitfähige, funktionelle Schichten. Die funktionellen Schichten enthalten bevorzugt zumindest ein Metall, beispielsweise Silber, Gold, Kupfer, Nickel und oder Chrom, oder eine Metalllegierung. Die funktionellen Schichten enthalten besonders bevorzugt mindestens 90 Gew. % des Metalls, insbesondere mindestens 99,9 Gew. % des Metalls. Die funktionellen Schichten können aus dem Metall oder der Metalllegierung bestehen. Die funktionellen Schichten enthalten besonders bevorzugt Silber oder eine silberhaltige Legierung. Solche funktionellen Schichten weisen eine besonders vorteilhafte elektrische Leitfähigkeit bei gleichzeitiger hoher Transmission im sichtbaren Spektralbereich auf. Die Dicke einer funktionellen Schicht beträgt bevorzugt von 5 nm bis 50 nm, besonders bevorzugt von 8 nm bis 25 nm. In diesem Bereich für die Dicke der funktionellen Schicht wird eine vorteilhaft hohe Transmission im sichtbaren Spektralbereich und eine besonders vorteilhafte elektrische Leitfähigkeit erreicht. Electrically conductive, functional coatings according to the invention are known, for example, from DE 20 2008 017 611 U1, EP 0 847 965 B1 or WO 2012/052315 A1. They typically contain one or more, for example two, three or four or even more, electrically conductive, functional layers. The functional layers preferably contain at least one metal, for example silver, gold, copper, nickel and/or chromium, or a metal alloy. The functional layers particularly preferably contain at least 90 wt. % of the metal, in particular at least 99.9 wt. % of the metal. The functional layers can consist of the metal or the metal alloy. The functional layers particularly preferably contain silver or a silver-containing alloy. Such functional layers have particularly advantageous electrical conductivity with simultaneous high transmission in the visible spectral range. The thickness of a functional layer is preferably from 5 nm to 50 nm, particularly preferably from 8 nm to 25 nm. In this range for the thickness of the functional layer, an advantageously high transmission in the visible spectral range and a particularly advantageous electrical conductivity are achieved.
Die funktionelle elektrisch leitfähige Beschichtung ist bevorzugt eine Heizschicht und enthält in besonders bevorzugten Ausgestaltungen mindestens eine Silberschicht (Ag). In einer vorteilhaften Ausgestaltung ist die funktionelle Beschichtung eine Schicht oder ein Schichtaufbau mehrerer Einzelschichten mit einer Gesamtdicke von kleiner oder gleich 2 pm, besonders bevorzugt kleiner oder gleich 1 pm, beispielsweise kleiner oder gleich 0,5 pm, wie kleiner 400 nm oder zwischen 350 und 250 nm. The functional electrically conductive coating is preferably a heating layer and, in particularly preferred embodiments, contains at least one silver layer (Ag). In an advantageous embodiment, the functional coating is a layer or a layer structure of several individual layers with a total thickness of less than or equal to 2 pm, particularly preferably less than or equal to 1 pm, for example less than or equal to 0.5 pm, such as less than 400 nm or between 350 and 250 nm.
In einer anderen bevorzugten Ausgestaltung ist vorgesehen, dass mindestens zwei zum Anschluss an eine Spannungsquelle vorgesehene Sammelleiter mit der funktionellen elektrisch leitfähigen Beschichtung so verbunden sind, dass zwischen den Sammelleitern ein Strompfad für einen Heizstrom geformt ist. In another preferred embodiment, it is provided that at least two bus bars intended for connection to a voltage source are connected to the functional electrically conductive coating in such a way that a current path for a heating current is formed between the bus bars.
Eine vorteilhafte erfindungsgemäße funktionelle Beschichtung, die als elektrische Heizschicht verwendet wird, weist beispielsweise einen Flächenwiderstand von 0,4 Ohm/Quadrat bis 10 Ohm/Quadrat auf. In einer besonders bevorzugten Ausgestaltung weist die erfindungsgemäße funktionelle Beschichtung einen Flächenwiderstand von 0,5 Ohm/Quadrat bis 1 Ohm/Quadrat auf. Beschichtungen mit derartigen Flächenwiderständen eignen sich besonders zur Beheizung von Fahrzeugscheiben bei typischen Bordspannungen von 12 V bis 48 Volt oder bei Elektrofahrzeugen mit typischen Bordspannungen von bis zu 500 V. An advantageous functional coating according to the invention, used as an electrical heating layer, has, for example, a surface resistance of 0.4 ohms/square to 10 ohms/square. In a particularly preferred embodiment, the functional coating according to the invention has a surface resistance of 0.5 ohms/square to 1 ohm/square. Coatings with such surface resistances are particularly suitable for heating vehicle windows with typical on-board voltages of 12 V to 48 volts or in electric vehicles with typical on-board voltages of up to 500 V.
In einer vorteilhaften Ausgestaltung ist der erfindungsgemäße Sammelleiter als aufgedruckte und eingebrannte leitfähige Struktur ausgebildet. Der aufgedruckte Sammelleiter enthält bevorzugt zumindest ein Metall, eine Metalllegierung, eine Metallverbindung und/oder Kohlenstoff, besonders bevorzugt ein Edelmetall und insbesondere Silber. Die Druckpaste enthält bevorzugt metallische Partikel Metallpartikel und/oder Kohlenstoff und insbesondere Edelmetallpartikel wie Silberpartikel. In an advantageous embodiment, the busbar according to the invention is formed as a printed and fired-in conductive structure. The printed busbar preferably contains at least one metal, a metal alloy, a metal compound, and/or carbon, particularly preferably a precious metal, and in particular silver. The printing paste preferably contains metallic particles, metal particles, and/or carbon, and in particular precious metal particles such as silver particles.
Die elektrische Leitfähigkeit wird bevorzugt durch die elektrisch leitenden Partikel erzielt. Die Partikel können sich in einer organischen und/oder anorganischen Matrix wie Pasten oder Tinten befinden, bevorzugt als Druckpaste mit Glasfritten. Electrical conductivity is preferably achieved by the electrically conductive particles. The particles can be contained in an organic and/or inorganic matrix such as pastes or inks, preferably as a printing paste with glass frits.
Die Breite des ersten und zweiten Sammelleiters beträgt bevorzugt von 2 mm bis 30 mm, besonders bevorzugt von 4 mm bis 20 mm und insbesondere von 10 mm bis 20 mm. Dünnere Sammelleiter führen zu einem zu hohen elektrischen Widerstand und damit zu einer zu hohen Erwärmung des Sammelleiters im Betrieb. Des Weiteren sind dünnere Sammelleiter nur schwer durch Drucktechniken wie Siebdruck herzustellen. Dickere Sammelleiter erfordern einen unerwünscht hohen Materialeinsatz. Des Weiteren führen sie zu einer zu großen und unästhetischen Einschränkung des Durchsichtbereichs der Scheibe. Die Länge des Sammelleiters richtet sich nach der Ausdehnung der elektrischen Heizschicht. Bei einem Sammelleiter, der typischerweise in Form eines Streifens ausgebildet ist, wird die längere seiner Dimensionen als Länge und die weniger lange seiner Dimensionen als Breite bezeichnet. Die dritten oder zusätzlichen Sammelleiter können auch dünner ausgestaltet sein, bevorzugt von 0,6 mm bis 5 mm. The width of the first and second bus bars is preferably from 2 mm to 30 mm, particularly preferably from 4 mm to 20 mm, and in particular from 10 mm to 20 mm. Thinner bus bars lead to excessive electrical resistance and thus to excessive heating of the bus bars during operation. Furthermore, thinner Bus bars are difficult to produce using printing techniques such as screen printing. Thicker bus bars require an undesirably high amount of material. Furthermore, they lead to an excessive and unsightly restriction of the view through the pane. The length of the bus bar depends on the extent of the electrical heating layer. For a bus bar, which is typically designed in the form of a strip, the longer of its dimensions is referred to as the length and the shorter of its dimensions as the width. The third or additional bus bars can also be thinner, preferably from 0.6 mm to 5 mm.
Die Schichtdicke des aufgedruckten Sammelleiters beträgt bevorzugt von 5 pm bis 40 pm, besonders bevorzugt von 8 pm bis 20 pm und ganz besonders bevorzugt von 8 pm bis 12 pm. Aufgedruckte Sammelleiter mit diesen Dicken sind technisch einfach zu realisieren und weisen eine vorteilhafte Stromtragfähigkeit auf. The layer thickness of the printed busbar is preferably from 5 pm to 40 pm, particularly preferably from 8 pm to 20 pm, and most preferably from 8 pm to 12 pm. Printed busbars with these thicknesses are technically easy to implement and have advantageous current-carrying capacity.
Der spezifische Widerstand pa der Sammelleiter beträgt bevorzugt von 0.8 pOhm cm bis 7.0 pOhm cm und besonders bevorzugt von 1.0 pOhm cm bis 2.5 pOhm cm. Sammelleiter mit spezifischen Widerständen in diesem Bereich sind technisch einfach zu realisieren und weisen eine vorteilhafte Stromtragfähigkeit auf. The specific resistance pa of the bus bars is preferably between 0.8 pOhm cm and 7.0 pOhm cm, and particularly preferably between 1.0 pOhm cm and 2.5 pOhm cm. Bus bars with specific resistances in this range are technically simple to implement and exhibit advantageous current-carrying capacity.
Die elektrische Zuleitung zur funktionellen elektrisch leitfähigen Beschichtung kann auch als flexibler Folienleiter (Flachleiter, Flachbandleiter) ausgebildet sein. Darunter wird ein elektrischer Leiter verstanden, dessen Breite deutlich größer ist als seine Dicke. Ein solcher Folienleiter ist beispielsweise ein Streifen oder Band enthaltend oder bestehend aus Kupfer, verzinntem Kupfer, Aluminium, Silber, Gold oder Legierungen davon. Der Folienleiter weist beispielsweise eine Breite von 2 mm bis 16 mm und eine Dicke von 0,03 mm bis 0,1 mm auf. Der Folienleiter kann eine isolierende, bevorzugt polymere Ummantelung, beispielsweise auf Polyimid-Basis aufweisen. Folienleiter, die sich zur Kontaktierung von elektrisch leitfähigen Beschichtungen in Scheiben eignen, weisen lediglich eine Gesamtdicke von beispielsweise 0,3 mm auf. Derart dünne Folienleiter können ohne Schwierigkeiten zwischen den einzelnen Scheiben in der thermoplastischen Zwischenschicht eingebettet werden. In einem Folienleiterband können sich mehrere voneinander elektrisch isolierte, leitfähige Schichten befinden. The electrical supply line to the functional, electrically conductive coating can also be designed as a flexible foil conductor (flat conductor, ribbon conductor). This refers to an electrical conductor whose width is significantly greater than its thickness. Such a foil conductor is, for example, a strip or ribbon containing or consisting of copper, tinned copper, aluminum, silver, gold, or alloys thereof. The foil conductor has, for example, a width of 2 mm to 16 mm and a thickness of 0.03 mm to 0.1 mm. The foil conductor can have an insulating, preferably polymeric, sheath, for example based on polyimide. Foil conductors suitable for contacting electrically conductive coatings in wafers have a total thickness of only 0.3 mm, for example. Such thin foil conductors can be easily embedded between the individual wafers in the thermoplastic intermediate layer. A foil conductor ribbon can contain several electrically insulated, conductive layers.
Alternativ können auch dünne Metalldrähte als elektrische Zuleitung für die elektrische leitfähige funktionelle Beschichtung verwendet werden. Die Metalldrähte enthalten insbesondere Kupfer, Wolfram, Gold, Silber oder Aluminium oder Legierungen mindestens zweier dieser Metalle. Die Legierungen können auch Molybdän, Rhenium, Osmium, Iridium, Palladium oder Platin enthalten. Alternatively, thin metal wires can be used as electrical leads for the electrically conductive functional coating. The metal wires contain in particular copper, tungsten, gold, silver, or aluminum, or alloys of at least two of these metals. The alloys may also contain molybdenum, rhenium, osmium, iridium, palladium, or platinum.
Die funktionelle elektrisch leitfähige Heizschicht (Beschichtung) kann sich über die gesamte Oberfläche der ersten Scheibe und/oder der zweiten Scheibe, bevorzugt nur der ersten Scheibe, erstrecken. Die funktionelle Beschichtung kann sich alternativ aber auch nur über einen Teil der Oberfläche der ersten Scheibe und/oder der zweiten Scheibe, bevorzugt nur der ersten Scheibe, erstrecken. Die funktionelle Beschichtung erstreckt sich bevorzugt über mindestens 50%, besonders bevorzugt über mindestens 70% und ganz besonders bevorzugt über mindestens 90% der innenseitigen Oberfläche der ersten Scheibe. Die funktionelle Beschichtung kann im inneren Bereich und/oder im äußeren Bereich eine oder mehrere unbeschichtete Zonen aufweisen. Diese Zonen können für elektromagnetische Strahlung durchlässig sein und sind beispielsweise als Datenübertragungsfenster oder Kommunikationsfenster bekannt. The functional, electrically conductive heating layer (coating) can extend over the entire surface of the first pane and/or the second pane, preferably only the first pane. Alternatively, the functional coating can also extend over only a portion of the surface of the first pane and/or the second pane, preferably only the first pane. The functional coating preferably extends over at least 50%, particularly preferably over at least 70%, and most particularly preferably over at least 90% of the inner surface of the first pane. The functional coating can have one or more uncoated zones in the inner region and/or the outer region. These zones can be permeable to electromagnetic radiation and are known, for example, as data transmission windows or communication windows.
Die funktionelle Beschichtung kann erfindungsgemäß mittels vakuumbasierter Gasphasenabscheidung auf die Oberfläche des Substrats und die Maskierungsbeschichtung aufgebracht. In einer bevorzugten Ausgestaltung wird die funktionelle Beschichtung mittels physikalischer Gasphasenabscheidung (PVD) oder chemischer Gasphasenabscheidung (CVD) aufgebracht, insbesondere mittels physikalischer Gasphasenabscheidung. Besonders bewährt hat sich die Kathodenzerstäubung (Sputtern), insbesondere die magnetfeldunterstütze Kathodenzerstäubung (Magnetronsputtern), die zur Erzeugung von Dünnschichten auf Glassubstraten verbreitet ist. Es können aber auch andere Arten der physikalischen Gasphasenabscheidung verwendet werden, beispielsweise Thermisches Verdampfen (Bedampfen), Elektronenstrahlverdampfen, Laserstrahlverdampfen,According to the invention, the functional coating can be applied to the surface of the substrate and the masking coating by means of vacuum-based vapor deposition. In a preferred embodiment, the functional coating is applied by means of physical vapor deposition (PVD) or chemical vapor deposition (CVD), in particular by means of physical vapor deposition. Sputtering, in particular magnetic field-assisted sputtering (magnetron sputtering), has proven particularly suitable for producing thin films on glass substrates. However, other types of physical vapor deposition can also be used, for example, thermal evaporation (evaporation), electron beam evaporation, laser beam evaporation,
Lichtbogenverdampfen oder Molekularstrahlepitaxie. Bevorzugte CVD-Verfahren sind die plasmaunterstützte chemische Gasphasenabscheidung (PECVD) und die Atomlagenabscheidung (ALD). Arc evaporation or molecular beam epitaxy. Preferred CVD processes are plasma-enhanced chemical vapor deposition (PECVD) and atomic layer deposition (ALD).
Unterhalb der eigentlichen funktionellen Beschichtung können auch weitere Beschichtungen aufgebracht werden, beispielsweise Haftvermittlerschichten, um die Haftung der funktionellen Beschichtung auf dem Substrat zu verbessern, Anpassungsoder Glättungsschichten, um die Morphologie der funktionellen Beschichtung zu beeinflussen, oder Blockerschichten, um Alkalidiffusion vom Glassubtrat in die Funktionsschicht zu verhindern. Geeignete Haftvermittlerschichten sind beispielsweise auf Basis von Siliziumnitrid (SiN) oder -oxid (SiO) oder Aluminiumnitrid (AIN) oder -oxid (AIO) ausgebildet, geeignete Anpassungsschichten beispielsweise auf Basis von SnZnO oder Zinkoxid (ZnO), geeignete Blockerschichten beispielsweise auf Basis von NiCr oder SiN. Further coatings can also be applied beneath the actual functional coating, for example adhesion promoter layers to improve the adhesion of the functional coating to the substrate, adjustment or smoothing layers to influence the morphology of the functional coating, or blocker layers to prevent alkali diffusion from the glass substrate into the To prevent functional layer deterioration. Suitable adhesion promoter layers are based, for example, on silicon nitride (SiN) or oxide (SiO) or aluminum nitride (AIN) or oxide (AlO), suitable adaptation layers are based, for example, on SnZnO or zinc oxide (ZnO), and suitable blocker layers are based, for example, on NiCr or SiN.
Die Erfindung betrifft weiterhin ein Verfahren zur Herstellung einer Verbundscheibe wie sie vorstehend in verschiedenen Ausgestaltungen beschrieben wurde, umfassend die Schritte The invention further relates to a method for producing a composite pane as described above in various embodiments, comprising the steps
A) Aufbringen einer funktionellen elektrisch leitfähigen Beschichtung auf mindestens einem Teil einer innenliegenden Oberfläche III einer ersten Scheibe und/oder auf einen Teil einer innenliegenden Oberfläche II einer zweiten Scheibe, A) applying a functional electrically conductive coating to at least a part of an inner surface III of a first pane and/or to a part of an inner surface II of a second pane,
B) Bereitstellen einer thermoplastischen Folie mit mindestens einer Ausnehmung zur Ausbildung einer Zwischenschicht, B) Providing a thermoplastic film with at least one recess for forming an intermediate layer,
C) Bereitstellen und Einsetzen einer Steuerkomponente in die Ausnehmung der thermoplastischen Folie, C) Providing and inserting a control component into the recess of the thermoplastic film,
D) Bereitstellen einer Isolationsfolie, D) Providing an insulation film,
E) Bereitstellen einer zweiten Scheibe mit einer innenliegenden Oberfläche II und einer äußeren Oberfläche I, E) providing a second disc having an inner surface II and an outer surface I,
F) Bilden einer Stapelfolge aus der ersten Scheibe, der Isolationsfolie, der thermoplastischen Folie mit der Steuerkomponenten, und der zweiten Scheibe, wobei die Isolationsfolie mindestens im Bereich der Ausnehmung der thermoplastischen Folie angeordnet wird und die Steuerkomponente von der elektrisch leitfähigen Beschichtung elektrisch isoliert angeordnet wird und F) forming a stacking sequence of the first pane, the insulating film, the thermoplastic film with the control component, and the second pane, wherein the insulating film is arranged at least in the region of the recess of the thermoplastic film and the control component is arranged electrically insulated from the electrically conductive coating and
G) Verbinden der innenliegenden Oberfläche III der ersten Scheibe mit der funktionellen Beschichtung über die thermoplastische Zwischenschicht mit der innenliegenden Oberfläche II der zweiten Scheibe unter Einwirkung von Hitze, Druck und/oder Vakuum. G) Bonding the inner surface III of the first pane with the functional coating via the thermoplastic intermediate layer to the inner surface II of the second pane under the influence of heat, pressure and/or vacuum.
Vorteilhafterweise kann so eine Verbundscheibe mit einer innenliegenden Heizbeschichtung bereitgestellt werden, in der auf einfache, kostengünstige Weise eine hierfür vorgesehene Steuerungskomponente, insbesondere zur Bildung eines Heizsystems funktionell sicher und möglichst unauffällig integriert werden kann. Die Verbundscheibe mit der integrierten Steuerkomponenten dabei einfach und kostengünstig herzustellen. Insbesondere ist dies mit der bisherigen maschinellen und verfahrenstechnischen Vorgehensweise zur Herstellung von Verbundscheiben möglich ohne das aufwändige Anpassungen nötig wären. Advantageously, a composite pane with an internal heating coating can be provided in which a control component intended for this purpose, in particular for forming a heating system, can be integrated in a simple, cost-effective manner in a functionally reliable and as unobtrusive a manner as possible. The composite pane with the integrated control components can be manufactured simply and cost-effectively. This is particularly possible with the current mechanical and process engineering approach for the production of composite panes without the need for complex adjustments.
In einer bevorzugten Ausgestaltung des Verfahrens wird die funktionelle elektrisch leitfähige Beschichtung mittels physikalischer Gasphasenabscheidung (PVD) oder chemischer Gasphasenabscheidung (CVD) auf die innenliegende Oberfläche (III) der ersten Scheibe und/oder auf die innenliegende Oberfläche (II) der zweiten Scheibe aufgebracht. In a preferred embodiment of the method, the functional electrically conductive coating is applied to the inner surface (III) of the first pane and/or to the inner surface (II) of the second pane by means of physical vapor deposition (PVD) or chemical vapor deposition (CVD).
Eine andere bevorzugte Ausführung des Verfahrens sieht vor, dass in Schritt B) die mindestens eine Ausnehmung durch Schneiden oder Stanzen in die thermoplastische Folie eingebracht wird. Alternativ kann eine Ausnehmung auch dadurch gebildet werden, dass die thermoplastische Folie mehrstückig, unter Auslassung des Teilbereichs für die Ausnehmung ausgebildet ist. Another preferred embodiment of the method provides that, in step B), the at least one recess is introduced into the thermoplastic film by cutting or punching. Alternatively, a recess can also be formed by forming the thermoplastic film in multiple pieces, omitting the partial area for the recess.
In einer weiteren Ausgestaltung wird das Steuermodul, insbesondere die Steuerungskomponente funktionell mit einer oder mehreren weiteren, gleichen oder unterschiedlichen Steuerkomponenten, beispielsweise Sensoren und/ oder einer Steuereinheit funktionell verbunden. Werden mehrere Steuerkomponenten vorgesehen, so ist diesen bevorzugt jeweils eine Ausnehmung in der thermoplastischen Zwischenschicht zugeordnet und diese jeweils zu elektrisch leitfähigen Beschichtungen durch eine Isolationsfolie sicher elektrisch von elektrisch leitfähigen Beschichtungen auf den innenliegenden Oberflächen der Scheiben isoliert. In a further embodiment, the control module, in particular the control component, is functionally connected to one or more other, identical or different control components, for example, sensors and/or a control unit. If multiple control components are provided, each of them is preferably assigned a recess in the thermoplastic intermediate layer, and each of these is reliably electrically insulated from electrically conductive coatings on the inner surfaces of the panes by an insulating film.
Die Erfindung betrifft auch die Verwendung der erfindungsgemäßen Verbundscheibe in Gebäuden oder in Fortbewegungsmitteln für den Verkehr auf dem Lande, in der Luft oder zu Wasser, insbesondere in Kraftfahrzeugen beispielsweise als Windschutzscheibe, Heckscheibe, Seitenscheiben und/oder Dachscheibe. The invention also relates to the use of the composite pane according to the invention in buildings or in means of transport for traffic on land, in the air or on water, in particular in motor vehicles, for example as a windscreen, rear window, side windows and/or roof window.
Als erste und zweite Scheibe sind im Grunde alle elektrisch isolierenden Substrate geeignet, die unter den Bedingungen der Herstellung und der Verwendung der erfindungsgemäßen Scheibe thermisch und chemisch stabil sowie dimensionsstabil sind. Die erste Scheibe und/oder die zweite Scheibe enthalten bevorzugt Glas, besonders bevorzugt Flachglas, Floatglas, Quarzglas, Borosilikatglas, Kalk-Natron-Glas, oder klare Kunststoffe, vorzugsweise starre klare Kunststoffe, insbesondere Polyethylen, Polypropylen, Polycarbonat, Polymethylmethacrylat, Polystyrol, Polyamid, Polyester, Polyvinylchlorid und/oder Gemische davon. Die erste Scheibe und/oder die zweite Scheibe sind bevorzugt transparent, insbesondere für die Verwendung der Scheibe als Windschutzscheide oder Rückscheibe eines Fahrzeugs oder anderen Verwendungen bei denen eine hohe Lichttransmission erwünscht ist. Basically, all electrically insulating substrates that are thermally and chemically stable and dimensionally stable under the conditions of manufacture and use of the disc according to the invention are suitable as the first and second discs. The first pane and/or the second pane preferably contain glass, particularly preferably flat glass, float glass, quartz glass, borosilicate glass, soda-lime glass, or clear plastics, preferably rigid clear plastics, in particular polyethylene, polypropylene, polycarbonate, polymethyl methacrylate, polystyrene, polyamide, polyester, polyvinyl chloride, and/or mixtures thereof. The first pane and/or the second pane are preferably transparent, particularly for use as a windshield or rear window of a vehicle or for other applications where high light transmission is desired.
Die Dicke der einzelnen Scheiben kann breit variieren und so hervorragend den Erfordernissen des Einzelfalls angepasst werden. Vorzugsweise werden Scheiben mit den Standardstärken von 1 ,0 mm bis 25 mm, bevorzugt von 1 ,4 mm bis 2,5 mm für Fahrzeugglas. The thickness of the individual panes can vary widely and can thus be perfectly adapted to the requirements of the individual case. Standard thicknesses of 1.0 mm to 25 mm are preferred, with 1.4 mm to 2.5 mm being preferred for automotive glass.
Die Verbundscheibe kann eine beliebige dreidimensionale Form aufweisen. Vorzugsweise hat die dreidimensionale Form keine Schattenzonen, so dass sie beispielsweise durch Kathodenzerstäubung beschichtet werden kann. Bevorzugt sind die Scheiben planar oder, wie bei Fahrzeugscheiben leicht oder stark in einer Richtung oder in mehreren Richtungen des Raumes gebogen. Die Scheiben können farblos oder gefärbt sein. The composite pane can have any three-dimensional shape. Preferably, the three-dimensional shape has no shadow zones, allowing it to be coated, for example, by cathode sputtering. The panes are preferably planar or, as in the case of vehicle windows, slightly or strongly curved in one or more directions of space. The panes can be colorless or colored.
Die Scheiben werden durch mindestens eine Zwischenschicht miteinander zur Verbundscheibe verbunden. Die Zwischenschicht enthält vorzugsweise mindestens einen thermoplastischen Kunststoff, bevorzugt Polyvinylbutyral (PVB), Ethylenvinylacetat (EVA) und / oder Polyethylenterephthalat (PET). Die thermoplastische Zwischenschicht kann aber auch beispielsweise Polyurethan (PU), Polypropylen (PP), Polyacrylat, Polyethylen (PE), Polycarbonat (PC), Polymethylmethacrylat, Polyvinylchlorid, Polyacetatharz, Gießharze, Acrylate, fluorinierte Ethylen-Propylene, Polyvinylfluorid und/oder Ethylen-Tetrafluorethylen, oder Copolymere oder Gemische davon enthalten. Übliche Schichtdicken für kommerziell erhältliche PVB-Folien sind zum Beispiel 0,76 mm oder 1 , 14 mm, wobei dies nicht beschränkend für die Erfindung ist. The panes are joined together to form the composite pane by at least one intermediate layer. The intermediate layer preferably contains at least one thermoplastic, preferably polyvinyl butyral (PVB), ethylene vinyl acetate (EVA) and/or polyethylene terephthalate (PET). However, the thermoplastic intermediate layer can also contain, for example, polyurethane (PU), polypropylene (PP), polyacrylate, polyethylene (PE), polycarbonate (PC), polymethyl methacrylate, polyvinyl chloride, polyacetate resin, casting resins, acrylates, fluorinated ethylene propylene, polyvinyl fluoride and/or ethylene tetrafluoroethylene, or copolymers or mixtures thereof. Typical layer thicknesses for commercially available PVB films are, for example, 0.76 mm or 1.14 mm, although this is not limiting for the invention.
In der thermoplastischen Zwischenschicht ist in der erfindungsgemäßen Verbundscheibe eine Ausnehmung vorgesehen, in die die Steuerkomponente, insbesondere ein Thermistor, aufgenommen und positioniert werden kann. Diese Ausnehmung kann beispielsweise durch Stanzen oder Schneiden in die thermoplastische Folie erzeugt sein, aus der die Zwischenschicht bei der Lamination ausgebildet wird. Alternativ, aber weniger bevorzugt, kann die thermoplastische Folie auch mehrstückig, unter Freilassung der Position für die Steuerkomponente, ausgebildet sein und die Zwischenschicht mit der Ausnehmung ausbilden. In the thermoplastic intermediate layer of the composite pane according to the invention, a recess is provided into which the control component, in particular a Thermistor, can be accommodated and positioned. This recess can be created, for example, by punching or cutting into the thermoplastic film from which the intermediate layer is formed during lamination. Alternatively, but less preferably, the thermoplastic film can also be formed in multiple pieces, leaving the position for the control component free, and form the intermediate layer with the recess.
Die verschiedenen Ausgestaltungen der Erfindung können einzeln oder in beliebigen Kombinationen realisiert sein. Insbesondere sind die vorstehend genannten, und nachstehend zu erläuternden Merkmale, nicht nur in den angegebenen Kombinationen, sondern auch in anderen Kombinationen oder in Alleinstellung einsetzbar, es sei denn sie sind explizit nur als Alternativen zueinander möglich und beschrieben, ohne den Rahmen der vorliegenden Erfindung zu verlassen. Dies gilt auch für Merkmale die nur zur Verbundscheibe oder nur zum Verfahren genannt sind. The various embodiments of the invention can be implemented individually or in any combination. In particular, the features mentioned above and those to be explained below can be used not only in the specified combinations, but also in other combinations or on their own, unless they are explicitly described and described as alternatives to one another without departing from the scope of the present invention. This also applies to features mentioned only for the composite pane or only for the method.
Die Erfindung wird nachfolgend anhand von Ausführungsbeispielen näher erläutert, wobei Bezug auf die beigefügten Figuren genommen wird. Es zeigen in vereinfachter, schematischer und nicht maßstabsgetreuer Darstellung: The invention is explained in more detail below using exemplary embodiments, with reference to the accompanying figures. They show, in simplified, schematic representations, not to scale:
Figur 1 eine Querschnittansicht eines Ausführungsbeispiels der erfindungsgemäßen Verbundscheibe, Figure 1 is a cross-sectional view of an embodiment of the composite pane according to the invention,
Figur 2 eine Draufsicht auf die Verbundscheibe von Fig. 1 , Figure 2 is a plan view of the composite pane of Fig. 1,
Figur 3 eine Querschnittansicht eines weiteren Ausführungsbeispiels der erfindungsgemäßen Verbundscheibe. Figure 3 is a cross-sectional view of another embodiment of the composite pane according to the invention.
Figur 1 zeigt eine Querschnittansicht eines Ausführungsbeispiels der erfindungsgemäßen Verbundscheibe 100, die eine erste Scheibe 1 mit einer innenliegenden Oberfläche I I I und einer äußeren Oberfläche IV, eine zweite Scheibe 2 mit einer innenliegenden Oberfläche I I und einer äußeren Oberfläche I aufweist, die durch eine thermoplastische Zwischenschicht 4 flächig miteinander verbunden sind. Auf der innenliegenden Oberfläche I I I der ersten Scheibe 1 ist eine funktionelle, elektrisch leitfähige Beschichtung 3 aufgebracht, die bevorzugt eine Heizschicht ist. In einer Ausnehmung 7 der thermoplastischen Zwischenschicht 4 ist eine Steuerkomponente 6 aufgenommen, welche durch eine, mindestens im Bereich der Ausnehmung 7 angeordnete, Isolationsfolie 5 zur funktionellen elektrisch-leitfähigen Beschichtung 3 hin elektrisch isoliert ist. Die thermoplastische Zwischenschicht 4 kann sowohl mehrlagig aus mehreren, flächig übereinander angeordneten thermoplastischen Folien ausgebildet sein in die passgenau die Ausnehmung 7 eingebracht wurde. Die Ausnehmung 7 kann beispielsweise mittels Stanzen oder Schneiden ausgebildet werden. Die Zwischenschicht 4 kann aber auch mehrstückig aus Folienteilen unter Auslassung der Position für die Steuerkomponente 6 ausgebildet werden. Die Steuerkomponente 6 ist bevorzugt ein kapazitiver oder resistiver Sensor, insbesondere ein mit elektrischen Anschlüssen 8 (bedrahteter) Thermistor, der mit der funktionellen elektrisch leitfähigen Beschichtung 3 funktionell, verbunden ist. Erfindungsgemäß wird so eine Verbundscheibe 100 mit einer unauffällig integrierten Steuerkomponenten 6, insbesondere für ein Heizsystem mit einer innenliegenden, elektrisch leitfähigen Beschichtung 3 als Heizschicht bereitgestellt. Die Steuerkomponente 6 ist dabei zwischen der ersten Scheibe 1 und der zweiten Scheibe 2 in einer Ausnehmung 7 der thermoplastischen Zwischenschicht 4 sicher und zerstörungsfrei integriert und gelagert und von der Beschichtung 3 durch die Isolationsfolie 5 zuverlässig elektrisch isoliert, so dass eine einwandfreie und dauerhafte Funktionsfähigkeit gewährleistet ist. Die Isolationsfolie 5 ist zur Dimensionierung der Ausnehmung 7 mit einem Überlapp ausgestaltet, um auch bei einem geringfügigen Versatz während der Herstellung die elektrische Isolierung der Steuerkomponenten 6 gegen die elektrisch leitfähige Beschichtung 3 sicherzustellen. Die Isolationsfolie 5 kann beispielsweise eine PET-Folie sein. Die elektrischen Anschlüsse der funktionellen Beschichtung 3 sowie weitere ggf. vorhandene Leitungs- und Signalwege zu einer Steuereinheit, beispielsweise zum Bordcomputer eines Fahrzeugs sind nicht dargestellt. Diese können in üblicher Art und Weise ausgestaltet sein. Figure 1 shows a cross-sectional view of an embodiment of the composite pane 100 according to the invention, which comprises a first pane 1 with an inner surface III and an outer surface IV, a second pane 2 with an inner surface II and an outer surface I, which are joined to one another by a thermoplastic intermediate layer 4. A functional, electrically conductive coating 3, which is preferably a heating layer, is applied to the inner surface III of the first pane 1. In a recess 7 The thermoplastic intermediate layer 4 accommodates a control component 6, which is electrically insulated from the functional electrically conductive coating 3 by an insulating film 5 arranged at least in the region of the recess 7. The thermoplastic intermediate layer 4 can be formed in multiple layers from several thermoplastic films arranged one above the other, into which the recess 7 has been precisely fitted. The recess 7 can be formed, for example, by punching or cutting. However, the intermediate layer 4 can also be formed in multiple pieces from film parts, omitting the position for the control component 6. The control component 6 is preferably a capacitive or resistive sensor, in particular a thermistor with electrical connections 8 (wired), which is functionally connected to the functional electrically conductive coating 3. According to the invention, a composite pane 100 is thus provided with an inconspicuously integrated control component 6, in particular for a heating system with an internal, electrically conductive coating 3 as the heating layer. The control component 6 is securely and non-destructively integrated and mounted between the first pane 1 and the second pane 2 in a recess 7 of the thermoplastic intermediate layer 4 and is reliably electrically insulated from the coating 3 by the insulating film 5, thus ensuring flawless and long-lasting functionality. The insulating film 5 is designed with an overlap to dimension the recess 7 in order to ensure the electrical insulation of the control components 6 from the electrically conductive coating 3 even in the event of a slight offset during production. The insulating film 5 can be a PET film, for example. The electrical connections of the functional coating 3 and any other cable and signal paths that may be present to a control unit, for example to the on-board computer of a vehicle, are not shown. These can be designed in the usual way.
Figur 2 zeigt eine Draufsicht auf die Verbundscheibe 100 von Figur 1 in einer angedeuteten Trapezform einer Windschutzscheibe. Die Windschutzscheibe weist eine erste Seitenkante S1 , eine zweite Seitenkante S2, eine Dachkante D und eine Motorkante M, sowie einen zentralen Sichtbereich Z für einen Fahrer auf, der gesetzlich festgelegt ist. Die Benennungen erfolgen lediglich im Hinblick auf eine Einbaulage in ein Fahrzeug. Der Thermistor als Steuerkomponente 6 ist in einem Randbereich R der Verbundscheibe 100 außerhalb des zentralen Sichtbereichs Z und auch außerhalb eines Maskierungsbereichs 9 angeordnet. Dies ermöglicht eine schnelle Detektion der Temperaturen und/oder anderer Messdaten außerdem sind die Signal- und Leitungswege nicht zu lang. Sofern gewünscht oder erforderlich kann die Steuerkomponente 6 aber auch mindestens teilweise im Maskierungsbereich 9 angeordnet sein. Figure 2 shows a plan view of the composite pane 100 of Figure 1 in an indicated trapezoidal shape of a windshield. The windshield has a first side edge S1, a second side edge S2, a roof edge D and an engine edge M, as well as a central viewing area Z for a driver, which is defined by law. The designations are made solely with regard to an installation position in a vehicle. The thermistor as the control component 6 is arranged in an edge region R of the composite pane 100 outside the central viewing area Z and also outside a The control component 6 is arranged in the masking area 9. This enables rapid detection of temperatures and/or other measurement data, and the signal and line paths are not too long. If desired or necessary, the control component 6 can also be arranged at least partially in the masking area 9.
Figur 3 zeigt eine Querschnittansicht eines weiteren Ausführungsbeispiels der erfindungsgemäßen Verbundscheibe 100. Der Unterschied zu der Ausgestaltung aus Figur 1 ist, dass hier zusätzlich auf der innenliegenden Oberfläche II der zweiten Scheibe 2 eine funktionelle elektrisch leitfähige Beschichtung 3a vorgesehen ist, gegen die die Steuerkomponente 6, also beispielsweise der Thermistor, mit einer zusätzlichen Isolationsfolie 5a elektrisch isoliert ist. Figure 3 shows a cross-sectional view of a further embodiment of the composite pane 100 according to the invention. The difference from the embodiment of Figure 1 is that here, in addition, a functional electrically conductive coating 3a is provided on the inner surface II of the second pane 2, against which the control component 6, for example the thermistor, is electrically insulated with an additional insulation film 5a.
Bezugszeichen liste Reference symbol list
100 Verbundscheibe 100 composite panes
1 erste Scheibe 1 first slice
2 zweite Scheibe 2 second disc
3 funktionelle, elektrisch leitfähige Beschichtung 3 functional, electrically conductive coating
3a funktionelle, elektrisch leitfähige Beschichtung 3a functional, electrically conductive coating
4 thermoplastische Zwischenschicht 4 thermoplastic intermediate layer
5 Isolationsfolie 5 Insulation foil
5a Isolationsfolie 5a Insulation foil
6 Steuerkomponente (beispielsweise Thermistor) 6 Control component (e.g. thermistor)
7 Ausnehmung 7 Recess
8 elektrischer Anschluss (Leitung/Draht) 8 electrical connection (cable/wire)
9 Maskierungsbereich (beispielsweise Schwarzdruck)9 Masking area (e.g. black print)
R Randbereich R edge area
Z Sichtbereich Z field of view
51 erste Seitenkante 51 first page edge
52 zweite Seitenkante 52 second side edge
D Dachkante D roof edge
M Motorkante M engine edge
I äußere Oberfläche der zweiten Scheibe 2 I outer surface of the second disc 2
II innenliegenden Oberfläche der zweiten Scheibe 2II inner surface of the second disc 2
III innenliegenden Oberfläche der ersten Scheibe 1III inner surface of the first disc 1
IV äußere Oberfläche der ersten Scheibe 1 IV Outer surface of the first disc 1
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP23200067.9 | 2023-09-27 | ||
| EP23200067 | 2023-09-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2025067762A1 true WO2025067762A1 (en) | 2025-04-03 |
Family
ID=88207667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2024/072988 Pending WO2025067762A1 (en) | 2023-09-27 | 2024-08-15 | Composite pane with integrated control component |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2025067762A1 (en) |
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| WO2003024155A2 (en) | 2001-09-07 | 2003-03-20 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Heatable vehicle window with different voltages in different heatable zones |
| EP0847965B1 (en) | 1996-12-12 | 2004-10-20 | Saint-Gobain Glass France | Glazing comprising a substrate furnished with a multiplicity of thin layers providing thermal insulation and/or solar protection |
| US20070020465A1 (en) | 2005-07-20 | 2007-01-25 | Thiel James P | Heatable windshield |
| US20070082219A1 (en) | 2003-11-28 | 2007-04-12 | Saint-Gobain Glass France | Transparent substrate which can be used alternatively or cumulatively for thermal control, electromagnetic armour and heated glazing |
| US20070194216A1 (en) | 2006-02-21 | 2007-08-23 | Exatec, Llc | Printable controls for a window assembly |
| WO2010043598A1 (en) | 2008-10-15 | 2010-04-22 | Saint-Gobain Glass France | Transparent object with a locally limited, structured, electrically heatable transparent area, method for the manufacture thereof and use thereof |
| DE202008017611U1 (en) | 2008-12-20 | 2010-04-22 | Saint-Gobain Sekurit Deutschland Gmbh & Co. Kg | Disc-shaped, transparent, electrically heatable composite material |
| WO2012052315A1 (en) | 2010-10-19 | 2012-04-26 | Saint-Gobain Glass France | Transparent sheet |
| WO2012126708A1 (en) * | 2011-03-22 | 2012-09-27 | Saint-Gobain Glass France | Method and arrangement for de-icing a transparent window using an electric heating device |
| WO2015162107A1 (en) | 2014-04-24 | 2015-10-29 | Saint-Gobain Glass France | Panel with illuminated switching surface and heating function |
| CN105578634A (en) * | 2016-02-02 | 2016-05-11 | 深圳新晶泉技术有限公司 | Electric heating laminated glass |
| CN206024142U (en) * | 2016-02-02 | 2017-03-15 | 深圳新晶泉技术有限公司 | Electrical heating laminated glass |
-
2024
- 2024-08-15 WO PCT/EP2024/072988 patent/WO2025067762A1/en active Pending
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0847965B1 (en) | 1996-12-12 | 2004-10-20 | Saint-Gobain Glass France | Glazing comprising a substrate furnished with a multiplicity of thin layers providing thermal insulation and/or solar protection |
| WO2003024155A2 (en) | 2001-09-07 | 2003-03-20 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Heatable vehicle window with different voltages in different heatable zones |
| US20070082219A1 (en) | 2003-11-28 | 2007-04-12 | Saint-Gobain Glass France | Transparent substrate which can be used alternatively or cumulatively for thermal control, electromagnetic armour and heated glazing |
| US20070020465A1 (en) | 2005-07-20 | 2007-01-25 | Thiel James P | Heatable windshield |
| US20070194216A1 (en) | 2006-02-21 | 2007-08-23 | Exatec, Llc | Printable controls for a window assembly |
| WO2010043598A1 (en) | 2008-10-15 | 2010-04-22 | Saint-Gobain Glass France | Transparent object with a locally limited, structured, electrically heatable transparent area, method for the manufacture thereof and use thereof |
| DE202008017611U1 (en) | 2008-12-20 | 2010-04-22 | Saint-Gobain Sekurit Deutschland Gmbh & Co. Kg | Disc-shaped, transparent, electrically heatable composite material |
| WO2012052315A1 (en) | 2010-10-19 | 2012-04-26 | Saint-Gobain Glass France | Transparent sheet |
| WO2012126708A1 (en) * | 2011-03-22 | 2012-09-27 | Saint-Gobain Glass France | Method and arrangement for de-icing a transparent window using an electric heating device |
| WO2015162107A1 (en) | 2014-04-24 | 2015-10-29 | Saint-Gobain Glass France | Panel with illuminated switching surface and heating function |
| CN105578634A (en) * | 2016-02-02 | 2016-05-11 | 深圳新晶泉技术有限公司 | Electric heating laminated glass |
| CN206024142U (en) * | 2016-02-02 | 2017-03-15 | 深圳新晶泉技术有限公司 | Electrical heating laminated glass |
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