WO2025065841A1 - Infrared microscopic nondestructive testing method for fabric fibers - Google Patents
Infrared microscopic nondestructive testing method for fabric fibers Download PDFInfo
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- WO2025065841A1 WO2025065841A1 PCT/CN2023/133226 CN2023133226W WO2025065841A1 WO 2025065841 A1 WO2025065841 A1 WO 2025065841A1 CN 2023133226 W CN2023133226 W CN 2023133226W WO 2025065841 A1 WO2025065841 A1 WO 2025065841A1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3563—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing solids; Preparation of samples therefor
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N2021/3595—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using FTIR
Definitions
- the invention relates to the technical field of textile detection, and in particular to an infrared microscopic textile fiber nondestructive detection method.
- Fabric fiber testing is an important assessment indicator of textile inspection quality and one of the main contents of clothing labeling.
- the detection of fabric fiber components includes qualitative analysis and quantitative analysis. The detection of fiber components still follows the traditional method of qualitative analysis first and quantitative analysis later.
- Qualitative analysis is to determine the type of fiber contained in the sample, usually referring to the fiber composition; quantitative analysis is to determine the amount of fiber contained, usually referring to the fiber content.
- the qualitative detection methods of textile fibers include microscopic observation, combustion method, chemical dissolution method, drug coloring method, melting point test method and infrared absorption spectroscopy.
- these methods have certain limitations.
- Microscopic observation and combustion methods can only identify natural fibers or synthetic fibers; although the chemical dissolution method can identify blended products, the organic solvents used in it have an impact on the health of the test personnel and also pollute the environment; infrared absorption spectroscopy has very high requirements for the test environment temperature, complex sample preparation, and long detection cycle, which cannot meet the requirements of rapid detection.
- the quantitative process including the concentration of reagents, test temperature, reaction time, equipment performance, operator experience, etc., has high requirements. Therefore, the process of fiber component detection is relatively cumbersome, and the uncertainty of the test results is relatively large.
- NIRS Near infrared spectroscopy
- NIRS Near infrared spectroscopy
- Qualitative analysis of near infrared spectroscopy is a method of using samples of known categories to establish a near infrared spectroscopy identification model and then examine whether unknown samples belong to this category of substances. It is mainly used for cluster analysis and discriminant analysis of substances.
- the existing technology lacks the ability to simultaneously acquire high-resolution infrared spectra and wide-spectrum infrared images to detect textures such as the coarse weave and interweaving patterns of fabric fibers, as well as joint detection technology for component analysis and pattern recognition. It is impossible to perform fine infrared spectral analysis of specific small areas, and it is impossible to perform joint detection of the interweaving patterns of detection objects within the field of view.
- the purpose of the present invention is to provide an infrared microscopic nondestructive testing method for fabric fibers in view of the problems in the prior art.
- An infrared microscopic nondestructive testing method for fabric fibers characterized in that: a fabric fiber detector including a Fourier infrared spectrum detection optical path and an infrared microscopic imaging optical path is used for testing, wherein the Fourier infrared spectrum detection optical path includes an infrared light source, a beam splitter, a moving mirror, a static mirror, a perforated reflector B, a perforated reflector A, a cassette microscope objective lens, a cassette microscope image lens and an infrared surface array, the orthogonal optical axis is perpendicular to the infrared optical axis, the beam splitter is placed at an angle of 45 degrees to the orthogonal optical axis, and the moving mirror mechanism controls the moving mirror to translate along the orthogonal optical axis.
- the Fourier infrared spectrum detection optical path includes an infrared light source, a beam splitter, a moving mirror, a static mirror, a perforated reflector B, a perfor
- the infrared microscopic imaging optical path and the Fourier infrared spectrum detection optical path multiplex an infrared light source, a perforated reflector B, a perforated reflector A, a cassette microscope objective lens, a cassette microscope image lens and an infrared surface array, and are also provided with a cutting-in mirror and a total reflecting mirror.
- the cutting-in mechanism controls the cutting-in mirror to cut in or out of the infrared optical axis.
- the infrared microscopic imaging optical path works, and when the cutting-in mirror cuts out of the infrared optical axis, the Fourier infrared spectrum detection optical path works.
- the infrared microscopic fabric detector is provided with a positioning cover, and the size of the positioning cover makes the fabric fiber sample be on the focal plane of the cassette microscope objective lens.
- Step 1 turn on the infrared light source, send instructions to the moving mirror mechanism, set the scanning step length and the starting and ending positions of the moving mirror along the orthogonal optical axis, and move the moving mirror to the starting position;
- Step 2 Control the cutting mirror to cut out the infrared light axis, and start the infrared array in the integration mode to perform Fourier infrared spectrum detection.
- Step 3 controlling the cutting mirror to cut into the infrared optical axis, and starting the infrared outer array working mode to the imaging mode, and performing infrared microscopic imaging detection;
- Step 4 performing spectral analysis on the reflectivity or infrared absorption of the fabric fiber sample to be tested obtained in step 2 to obtain the molecular composition and content in the fabric fiber; performing image processing and analysis on the infrared wide-spectrum image of the same fabric fiber sample to be tested obtained in step 3 to obtain the thickness and interweaving information of the fabric fiber, and assist in component determination and pattern recognition.
- the infrared microscopic fabric detector controls the turning on of the infrared light source through the equipped controller, sends instructions to the moving mirror mechanism, controls the cutting mirror to cut in or out of the infrared light axis, controls the working mode of the infrared outer array to the integration mode or the imaging mode, and receives its data.
- Step 2 comprises the following steps:
- Step 2.1 detecting the intensity value of the standard white plate reflection of each wavelength within the wavelength range
- the controller controls the moving mirror mechanism, controls the moving mirror to translate with the set scanning step length, and performs Fourier infrared spectrum detection at the same time. Any position of the scan corresponds to a certain infrared wavelength, the scanning step length corresponds to the spectral resolution, and the start and end positions of the scan correspond to the start and end wavelengths of the infrared detection.
- the controller records the intensity value of the standard white plate reflection of each wavelength within the detection wavelength range;
- Step 2.2 detect the intensity value of the reflection of the fabric fiber sample to be tested at each wavelength within the wavelength range, replace the standard white board with the fabric fiber sample to be tested, move the moving mirror in the opposite direction from the end position to the start position with the same step length, and perform Fourier infrared spectrum detection at the same time.
- the controller records the intensity value of the reflection of the fabric fiber sample to be tested at each wavelength within the detection wavelength range.
- Step 2.3 dividing the reflection intensity value of the tested fabric fiber sample measured in step 2.2 by the reflection intensity value of the standard white board measured in step 2.1, to obtain the reflectivity distribution of the tested fabric fiber sample within the detection wavelength range.
- a controller controls the turning on of the infrared light source, and controls the infrared array, specifies its working mode and receives its data.
- the infrared light emitted by the infrared light source along the infrared optical axis is divided into two paths by the beam splitter: one path is reflected by the beam splitter and then emitted to the moving mirror along the orthogonal optical axis, reflected by the moving mirror and then passed through the beam splitter; the other path passes through the beam splitter, emitted to the static mirror along the infrared optical axis, reflected by the static mirror and then reflected by the beam splitter;
- the moving mirror and the static mirror have different center distances to the beam splitter, resulting in an optical path difference.
- the two infrared lights are coherent lights, and after merging, they form an equi-inclined interference ring distribution.
- the center of the interference ring corresponds to the central main maximum infrared light intensity distribution of different wavelengths.
- a part of the main maximum infrared light corresponding to a specific wavelength reflected by the fabric fiber sample is folded back along the main optical axis, passes through the cassette microscope objective, passes through the central hole of the perforated reflector A, and then is focused to the infrared surface array through the cassette microscope image lens;
- the infrared array starts the integration mode under the control of the main controller, accumulates the intensity values of all pixels, and records the accumulated intensity values.
- the wide-spectrum infrared light emitted by the infrared light source along the infrared optical axis is reflected by the cutting-in mirror and turned to the cutting-in optical axis perpendicular to the infrared optical axis, and then reflected by the total reflection mirror and turned to the turning optical axis parallel to the infrared optical axis, and then reflected by the perforated reflector B and the perforated reflector A, and then turned to the main optical axis perpendicular to the orthogonal optical axis, and then focused to the fabric fiber sample on the focal plane by the cassette microscope objective lens, the wide-spectrum infrared light reflected by the fabric fiber sample is turned back along the main optical axis, passed through the cassette microscope objective lens, passed through the central hole of the perforated reflector A, and then focused and imaged onto the infrared surface array by the cassette microscope image lens,
- the cassette microscope contains an imaging secondary mirror and an imaging primary mirror
- the cassette microscope objective lens contains an object side primary mirror and an object side secondary mirror
- the cassette microscope image lens and the cassette microscope objective lens are both designed for infinite imaging, and are coaxially symmetrically placed conjugately on the main optical axis.
- the cassette microscope objective lens first reflects the light emitted by the textile fiber sample on its focal plane through the object side primary mirror and the object side secondary mirror in succession, and turns it into parallel light with a certain magnification, and then reflects it through the imaging secondary mirror and the imaging primary mirror of the cassette microscope, and reduces the parallel light according to the magnification of the cassette microscope and focuses it to form an infrared surface array on the focal plane.
- the surfaces of the imaging secondary mirror, the imaging primary mirror, the object side primary mirror, the object side secondary mirror, the moving mirror, the static mirror, the cutting-in mirror, the perforated reflector B, and the perforated reflector A are all coated with an infrared high-reflection film, which efficiently reflects infrared light within the emission range of the infrared light source.
- different magnification ratios of the cassette microscope image lens and the cassette microscope objective lens are used to obtain different image-object magnification ratios on the infrared surface array.
- the beam splitter is formed by bonding two identical thin infrared high-transmittance optical glasses, the bonding surface is coated with an infrared semi-reflective and semi-transparent film, and is placed at an angle of 45 degrees to the orthogonal optical axis.
- the fabric fiber detector uses a lithium battery as a driving power source.
- the fabric fiber detector is equipped with an operating handle for the operator to carry it.
- an infrared microscopic fabric fiber nondestructive testing method of the present invention utilizes a Fourier infrared spectrum detection optical path, an infrared microscopic imaging optical path multiplexing infrared light source, a holed reflector B, a holed reflector A, a cassette microscope objective lens, a cassette microscope image lens and an infrared surface array, and controls the cutting-in mirror to cut in or out of the infrared optical axis through a cutting-in mechanism, thereby realizing the switching of the infrared microscopic imaging optical path and the Fourier infrared spectrum detection optical path, obtaining a high-resolution infrared spectrum and a wide-spectrum infrared image of a completely overlapping detection target, realizing the texture detection of the coarse weaving, interweaving mode and the like at the same position of the fabric fiber, and the comprehensive detection of fiber component analysis and pattern recognition.
- the infrared microscopic fabric fiber nondestructive testing method of the present invention utilizes the multiplexing structure of the Fourier infrared spectrum detection optical path and the infrared microscopic imaging optical path, and provides a method for preparing a more compact and miniaturized fabric fiber detector.
- the present invention provides a compact and miniaturized fabric detector capable of rapid detection.
- the infrared microscopic nondestructive testing method for fabric fibers of the present invention adopts two working modes, performs precise infrared spectrum analysis and infrared wide-spectrum imaging simultaneously, and performs pattern recognition and component analysis of fabric fibers through information fusion, which has great application prospects in the field of on-site testing of fabric fibers.
- FIG1 is a flow chart of the infrared microscopic nondestructive testing method for textile fibers of the present invention
- FIG2 is a structural diagram of a fabric fiber detector used in the infrared microscopic fabric fiber nondestructive testing method of the present invention.
- a detector body 1 there are a detector body 1; a lithium battery 2; a charging port 3; a switch 4; a power supply line 5; a moving mirror 6; an orthogonal optical axis 7; a beam splitter 8; a moving mirror mechanism 9; a cutting mirror 10; a cutting mechanism 11; a main controller 12; an infrared light source 13; an operating handle 14; an infrared optical axis 15; a cutting optical axis 16; a static mirror 17; a total reflecting mirror 18; an infrared surface array 19; a cassette microscope 20; an imaging secondary mirror 21; an imaging primary mirror 22; a turning optical axis 23; a perforated reflector A 24; a perforated reflector B 25; an object side primary mirror 26; a primary optical axis 27; an object side secondary mirror 28; a fabric fiber sample 29; a positioning cover 30; and a cassette microscope objective lens 31.
- an infrared microscopic nondestructive testing method for fabric fibers of the present invention adopts a fabric fiber detector including a Fourier infrared spectrum detection optical path and an infrared microscopic imaging optical path for testing.
- the fabric fiber detector includes a detector body 1, including a lithium battery 2, a moving mirror 6, a beam splitter 8, a moving mirror mechanism 9, a cutting mirror 10, a cutting mechanism 11, a main controller 12, an infrared light source 13, a static mirror 17, a total reflector 18, an infrared surface array 19, a cassette microscope 20, a perforated reflector A 24, a perforated reflector B 25 and a cassette microscope objective 31.
- the cassette microscope 20 contains an imaging secondary mirror 21 and an imaging primary mirror 22.
- the cassette microscope objective lens 31 contains an object side primary mirror 26 and an object side secondary mirror 28. Both the cassette microscope 20 and the cassette microscope objective lens 31 are designed for infinite imaging and are placed coaxially symmetrically conjugately on the main optical axis 27.
- the cassette microscope objective lens 31 first reflects the light emitted by the fabric fiber sample 29 on its focal plane from the object side primary mirror 26 and the object side secondary mirror 28 in succession, and then turns it into parallel light with a certain magnification (the magnification of the cassette microscope objective lens 31, the magnification of this embodiment is 20), and then reflects the imaging secondary mirror 21 and the imaging primary mirror 22 of the cassette microscope 20, and the parallel light is reduced and focused to the infrared array 19 on the focal plane according to the magnification of the cassette microscope 20, the magnification of this embodiment is 5.
- Different magnification ratios of the cassette microscope image lens 20 and the cassette microscope objective lens 31 can be selected to obtain different image-object magnification ratios on the infrared surface array 19.
- the magnification ratio in this embodiment is 4.
- the moving mirror mechanism 9 can control the moving mirror 6 to translate along the orthogonal optical axis 7.
- the cutting mechanism 11 can control the cutting mirror 10 to cut into or out of the infrared optical axis 15.
- the infrared light source 13 can emit a wide spectrum infrared light within a certain range, which is 1000 cm-1-3300 cm-1 in this embodiment, and the corresponding infrared surface array 19 can sense the infrared light within this range and form an image.
- the imaging secondary mirror 21, the imaging primary mirror 22, the object primary mirror 26, the object secondary mirror 28, the moving mirror 6, the static mirror 17, the surface of the cutting mirror 10, the holed reflector B 25, and the holed reflector A 24 are all coated with infrared high-reflection films, which can efficiently reflect the infrared light within the emission range of the infrared light source 13.
- the Fourier infrared spectrum detection optical path is composed of an infrared light source 13, a beam splitter 8, a moving mirror 6, a static mirror 17, a perforated reflector B 25, a perforated reflector A 24, a cassette microscope objective 31, a cassette microscope image lens 20, and an infrared surface array 19.
- the orthogonal optical axis 7 is perpendicular to the infrared optical axis 15.
- the beam splitter 8 is formed by laminating two identical thin infrared high-transmittance optical glasses, and the laminating surface is coated with an infrared semi-reflective and semi-transmissive film, and is placed at an angle of 45 degrees to the orthogonal optical axis 7.
- the infrared light emitted by the infrared light source 13 along the infrared optical axis 15 is divided into two paths by the beam splitter 8: one path is reflected by the beam splitter 8 and then emitted to the moving mirror 6 along the orthogonal optical axis 7, reflected and returned by the moving mirror 6, and then passes through the beam splitter 8; the other path passes through the beam splitter 8, and is emitted to the static mirror 17 along the infrared optical axis 15, reflected and returned by the static mirror 17, and then reflected by the beam splitter 8.
- the moving mirror 6 and the static mirror 17 have different center distances to the beam splitter 8, resulting in an optical path difference.
- the two infrared lights are coherent lights, which form an equi-inclined interference ring distribution after merging.
- the center of the interference ring corresponds to the central main maximum infrared light intensity distribution of different wavelengths. At a certain detection moment, it is a certain wavelength value.
- the central main maximum infrared light After passing through the central hole of the perforated reflector B 25, only the central main maximum infrared light passes through, and then after being reflected by the perforated reflector A 24, it turns to the main optical axis 27 perpendicular to the orthogonal optical axis 7, and then is focused to the fabric fiber sample 29 on the focal plane through the cassette microscope objective 31.
- a part of the main maximum infrared light corresponding to a certain wavelength reflected by the fabric fiber sample 29 is turned back along the main optical axis 27, passes through the cassette microscope objective 31, passes through the central hole of the perforated reflector A 24, and then is focused to the infrared surface array 19 through the cassette microscope image lens 20.
- the infrared array 19 starts the integration mode under the control of the main controller 12, that is, the intensity values of all pixels are accumulated, which is equivalent to a unit detector, and the accumulated intensity value is recorded.
- the infrared microscopic imaging optical path and the Fourier infrared spectrum detection optical path multiplex the infrared light source 13, the perforated reflector B 25, the perforated reflector A 24, the cassette microscope objective 31, the cassette microscope image lens 20, and the infrared surface array 19.
- it contains a cutting mirror 10 and a total reflection mirror 18.
- the cutting mirror 10 cuts into the infrared optical axis 15 under the control of the cutting mechanism 11, the infrared microscopic imaging optical path works; conversely, when the cutting mirror 10 cuts out of the infrared optical axis 15 under the control of the cutting mechanism 11, the Fourier infrared spectrum detection optical path works.
- the wide-spectrum infrared light emitted by the infrared light source 13 along the infrared optical axis 15 is reflected by the cutting mirror 10, turned to the cutting optical axis 16 perpendicular to the infrared optical axis 15, and then reflected by the total reflection mirror 18 to the turning optical axis 23 parallel to the infrared optical axis 15, and then reflected by the hole reflector B 25 and the hole reflector A 24, and then turned to the main optical axis 27 perpendicular to the orthogonal optical axis 7, and then focused to the fabric fiber sample 29 on the focal plane by the cassette microscope objective lens 31, and the wide-spectrum infrared light reflected by the fabric fiber sample 29 is turned back along the main optical axis 27, passed through the cassette microscope objective lens 31, passed through the central hole of the hole reflector A 24, and then focused and imaged onto the infrared surface array 19 by the cassette microscope image lens 20.
- the infrared surface array 19 starts the imaging mode
- the lithium battery 2 has a charging interface 3 and a switch 4.
- the battery charger can charge the lithium battery 2 through the charging interface 3.
- the switch 4 When the switch 4 is turned on, the lithium battery 2 supplies power to the moving mirror mechanism 9, the cutting mechanism 11, the main controller 12, the infrared light source 13, and the infrared surface array 19 through the power supply line 5.
- the operator lifts the operating handle 14 to make the positioning cover 30 close to the fabric fiber sample 29.
- the size of the positioning cover 30 allows the fabric fiber sample 29 to be on the focal plane of the cassette microscope objective lens 31, which is convenient for on-site quick inspection.
- the controller 12 is used to turn on the infrared light source 13, control the infrared array 19, specify its working mode and receive its data.
- the controller 12 is also used to send instructions to the moving mirror mechanism 9 and the cutting mechanism 11, so as to control the scanning step length and the starting and ending positions of the moving mirror 6 along the orthogonal optical axis 7, and control the cutting mirror 10 to cut in and out of the infrared optical axis 15.
- the present invention provides an infrared microscopic nondestructive testing method for textile fibers, which specifically comprises the following steps:
- the lithium battery 2 Before on-site testing, the lithium battery 2 is charged through the charging interface 3. During on-site testing, the operator turns on the switch 4, and the lithium battery 2 powers the instrument.
- the controller 12 turns on the infrared light source 13, sends instructions to the moving mirror mechanism 9, sets the scanning step length and the starting and ending positions of the moving mirror 6 along the orthogonal optical axis 7, and moves the moving mirror 6 to the starting position.
- the controller 12 sends instructions to the cutting mechanism 11 to control the cutting mirror 10 to cut out the infrared light axis 15, and starts the working mode of the infrared array 19 to the integration mode.
- the operator lifts the operating handle 14 to make the positioning cover 30 close to a standard white board.
- the controller 12 sends instructions to the moving mirror mechanism 9 to control the moving mirror 6 to translate with the set scanning step length.
- Fourier infrared spectrum detection is carried out. At any position of the scan, it corresponds to a certain wavelength of infrared.
- the scanning step length corresponds to the spectral resolution, and the starting and ending positions of the scan correspond to the starting and ending wavelengths of the infrared detection.
- the detection ends when the moving mirror 6 translates to the end position.
- the controller 12 records the detection wavelength range, which is 1000 cm-1-3300cm-1 in this embodiment.
- the intensity value of the standard white board reflection at each wavelength within the detection wavelength range that is, the spectral distribution of the infrared light source 13.
- the standard white board is replaced with the fabric fiber sample 29 to be tested, and the moving mirror 6 moves in the opposite direction from the end position to the start position with the same step length, and Fourier infrared spectrum detection is performed at the same time, and the detection is terminated when the moving mirror 6 moves to the start position.
- the controller 12 records the intensity value of the reflection of the fabric fiber sample 29 to be tested at each wavelength within the detection wavelength range, and divides it with the intensity value of the reflection of the standard white board to obtain the reflectivity distribution of the fabric fiber sample 29 to be tested within the detection wavelength range.
- the controller 12 sends a command to the cutting mechanism 11, controls the cutting mirror 10 to cut into the infrared optical axis 15, and starts the working mode of the infrared outer array 19 to the imaging mode.
- the controller 12 records the wide-spectrum infrared image reflected by the fabric fiber sample 29 to be tested within the detection wavelength range.
- the image can remove the color interference of the fabric fiber, the image texture contains the thickness and interweaving information of the fabric fiber, and the image gray contains the composition information.
- the molecular composition and content in the fabric fiber can be obtained.
- image processing and analysis on the infrared wide-spectrum image of the same fabric fiber sample 29 obtained in step 3
- the thickness and interweaving information of the fabric fiber can be obtained, and the composition determination and pattern recognition can be assisted.
- the present invention discloses an infrared microscopic nondestructive testing method for fabric fibers.
- the method adopts a fabric fiber detector including a Fourier transform infrared spectrum detection optical path and an infrared microscopic imaging optical path for testing.
- the method adopts two working modes, namely, a Fourier transform spectrum detection mode and a wide-spectrum infrared reflection microscopic imaging mode, and reuses the infrared light source, infrared surface array, and cassette microscopic imaging system.
- a Fourier transform spectrum detection mode and a wide-spectrum infrared reflection microscopic imaging mode
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Abstract
Description
本发明涉及纺织物检测技术领域,具体涉及一种红外显微织物纤维无损检测方法。The invention relates to the technical field of textile detection, and in particular to an infrared microscopic textile fiber nondestructive detection method.
织物种类多样,包含棉、麻、毛/粘纤面料、丝制品、粘纤、羽绒面料等。织物纤维检测是纺织品检验质量的一项重要考核指标,是服装标识的主要内容之一。织物纤维组分的检测包括定性分析和定量分析,纤维组分的检测依旧按照先定性后定量的传统方法。There are many types of fabrics, including cotton, linen, wool/viscose fabrics, silk products, viscose, down fabrics, etc. Fabric fiber testing is an important assessment indicator of textile inspection quality and one of the main contents of clothing labeling. The detection of fabric fiber components includes qualitative analysis and quantitative analysis. The detection of fiber components still follows the traditional method of qualitative analysis first and quantitative analysis later.
定性分析是确定样品中所含纤维的种类,通常指纤维成分;定量分析是确定所含纤维的量,通常指纤维含量,Qualitative analysis is to determine the type of fiber contained in the sample, usually referring to the fiber composition; quantitative analysis is to determine the amount of fiber contained, usually referring to the fiber content.
目前纺织纤维定性的检测方法有显微镜观察法、燃烧法、化学溶解法、药品着色法、熔点试验法和红外吸收光谱法等。但这些方法都有一定的局限性。显微镜观察法和燃烧法只能鉴别天然纤维或合成纤维;化学溶解法虽然能鉴别混纺产品,但其使用的有机溶剂对检测人员身体健康有影响,而且还污染环境;红外吸收光谱对测试环境温度要求相当高,制样复杂,检测周期长,不能满足快速检测的要求。而定量的过程,包括试剂的浓度、试验温度、反应时间、设备性能、操作者的经验等都有较高要求。因此,纤维组分检测的过程比较繁琐,检测的结果不确定性比较大。At present, the qualitative detection methods of textile fibers include microscopic observation, combustion method, chemical dissolution method, drug coloring method, melting point test method and infrared absorption spectroscopy. However, these methods have certain limitations. Microscopic observation and combustion methods can only identify natural fibers or synthetic fibers; although the chemical dissolution method can identify blended products, the organic solvents used in it have an impact on the health of the test personnel and also pollute the environment; infrared absorption spectroscopy has very high requirements for the test environment temperature, complex sample preparation, and long detection cycle, which cannot meet the requirements of rapid detection. The quantitative process, including the concentration of reagents, test temperature, reaction time, equipment performance, operator experience, etc., has high requirements. Therefore, the process of fiber component detection is relatively cumbersome, and the uncertainty of the test results is relatively large.
近红外光谱分析技术(NIRS)主要用于800nm~2500nm范围电磁波的无损测量。不同于质谱、色谱分析技术,该技术无需提纯,已广泛应用于食品、农业、医药、炼油与化工等领域。近红外光谱的定性分析是利用已知类别的样品建立近红外光谱鉴别模型,再考察未知样品是否属于该类物质的一种方法,主要用于物质的聚类分析和判别分析。Near infrared spectroscopy (NIRS) is mainly used for non-destructive measurement of electromagnetic waves in the range of 800nm~2500nm. Unlike mass spectrometry and chromatography, this technology does not require purification and has been widely used in food, agriculture, medicine, oil refining and chemical industries. Qualitative analysis of near infrared spectroscopy is a method of using samples of known categories to establish a near infrared spectroscopy identification model and then examine whether unknown samples belong to this category of substances. It is mainly used for cluster analysis and discriminant analysis of substances.
现有技术中,缺乏利用同时获取高分辨红外光谱及宽谱红外图像,实现对织物纤维的粗织、交织方式等纹理探测,以及成分分析、模式识别的联合检测技术,无法对于特定的小区域的精细的红外光谱分析,无法对视场范围内的检测对象的交织方式的检测等的联合检测。The existing technology lacks the ability to simultaneously acquire high-resolution infrared spectra and wide-spectrum infrared images to detect textures such as the coarse weave and interweaving patterns of fabric fibers, as well as joint detection technology for component analysis and pattern recognition. It is impossible to perform fine infrared spectral analysis of specific small areas, and it is impossible to perform joint detection of the interweaving patterns of detection objects within the field of view.
本发明的目的在于,针对现有技术中的问题,提供一种红外显微织物纤维无损检测方法。The purpose of the present invention is to provide an infrared microscopic nondestructive testing method for fabric fibers in view of the problems in the prior art.
为此,本发明的上述目的通过以下技术方案实现:To this end, the above-mentioned purpose of the present invention is achieved through the following technical solutions:
一种红外显微织物纤维无损检测方法,其特征在于:采用包括傅立叶红外光谱探测光路、红外显微成像光路的织物纤维检测仪进行检测,其中,傅立叶红外光谱探测光路包括红外光源、分束器、动镜、静镜、带孔反射镜乙、带孔反射镜甲、卡式显微物镜、卡式显微像镜和红外面阵,正交光轴与红外光轴垂直,分束器与正交光轴夹角45度放置,动镜机构控制动镜沿正交光轴平移,An infrared microscopic nondestructive testing method for fabric fibers, characterized in that: a fabric fiber detector including a Fourier infrared spectrum detection optical path and an infrared microscopic imaging optical path is used for testing, wherein the Fourier infrared spectrum detection optical path includes an infrared light source, a beam splitter, a moving mirror, a static mirror, a perforated reflector B, a perforated reflector A, a cassette microscope objective lens, a cassette microscope image lens and an infrared surface array, the orthogonal optical axis is perpendicular to the infrared optical axis, the beam splitter is placed at an angle of 45 degrees to the orthogonal optical axis, and the moving mirror mechanism controls the moving mirror to translate along the orthogonal optical axis.
所述红外显微成像光路与傅立叶红外光谱探测光路复用红外光源、带孔反射镜乙、带孔反射镜甲、卡式显微物镜、卡式显微像镜和红外面阵,还设有切入镜和全反镜,切入机构控制切入镜切入或切出红外光轴,当切入镜切入红外光轴时,红外显微成像光路工作,当切入镜切出红外光轴时,傅立叶红外光谱探测光路工作;红外显微织物检测仪设置定位罩,定位罩的尺寸使织物纤维样品处于卡式显微物镜的焦面,The infrared microscopic imaging optical path and the Fourier infrared spectrum detection optical path multiplex an infrared light source, a perforated reflector B, a perforated reflector A, a cassette microscope objective lens, a cassette microscope image lens and an infrared surface array, and are also provided with a cutting-in mirror and a total reflecting mirror. The cutting-in mechanism controls the cutting-in mirror to cut in or out of the infrared optical axis. When the cutting-in mirror cuts in the infrared optical axis, the infrared microscopic imaging optical path works, and when the cutting-in mirror cuts out of the infrared optical axis, the Fourier infrared spectrum detection optical path works. The infrared microscopic fabric detector is provided with a positioning cover, and the size of the positioning cover makes the fabric fiber sample be on the focal plane of the cassette microscope objective lens.
当红外显微织物检测仪对织物纤维无损检测时,包括以下步骤:When the infrared microscopic fabric detector performs non-destructive testing on fabric fibers, the following steps are included:
步骤1,开启红外光源,给动镜机构发指令,设定控制动镜沿正交光轴平移的扫描步长和起终位置,并将动镜移动至起始位置;Step 1, turn on the infrared light source, send instructions to the moving mirror mechanism, set the scanning step length and the starting and ending positions of the moving mirror along the orthogonal optical axis, and move the moving mirror to the starting position;
步骤2,控制切入镜切出红外光轴,并启动红外面阵的工作模式为积分模式,进行傅立叶红外光谱探测,Step 2: Control the cutting mirror to cut out the infrared light axis, and start the infrared array in the integration mode to perform Fourier infrared spectrum detection.
步骤3,控制切入镜切入红外光轴,并启动红外面阵的工作模式为成像模式,进行红外显微成像探测;Step 3, controlling the cutting mirror to cut into the infrared optical axis, and starting the infrared outer array working mode to the imaging mode, and performing infrared microscopic imaging detection;
步骤4,将步骤2获取的待测织物纤维样品的反射率或红外吸收进行光谱分析,获得织物纤维中的分子组成及含量;将步骤3获得的同一待测织物纤维样品的红外宽谱图像进行图像处理分析,获得织物纤维的粗细和交织信息,并辅助进行成分确定和模式识别。Step 4, performing spectral analysis on the reflectivity or infrared absorption of the fabric fiber sample to be tested obtained in step 2 to obtain the molecular composition and content in the fabric fiber; performing image processing and analysis on the infrared wide-spectrum image of the same fabric fiber sample to be tested obtained in step 3 to obtain the thickness and interweaving information of the fabric fiber, and assist in component determination and pattern recognition.
在采用上述技术方案的同时,本发明还可以采用或者组合采用如下技术方案:While adopting the above technical solutions, the present invention may also adopt or combine the following technical solutions:
作为本发明的优选技术方案:红外显微织物检测仪通过配设的控制器控制开启红外光源,给动镜机构发指令,并控制切入镜切入或切出红外光轴,以及控制红外面阵的工作模式为积分模式或成像模式,并接收其数据。As a preferred technical solution of the present invention: the infrared microscopic fabric detector controls the turning on of the infrared light source through the equipped controller, sends instructions to the moving mirror mechanism, controls the cutting mirror to cut in or out of the infrared light axis, controls the working mode of the infrared outer array to the integration mode or the imaging mode, and receives its data.
作为本发明的优选技术方案:所述步骤2包括以下步骤:As a preferred technical solution of the present invention: Step 2 comprises the following steps:
步骤2.1,探测波长范围内各个波长的标准白板反射的强度值,控制器控制动镜机构,控制动镜以设定的扫描步长进行平移,同时进行傅立叶红外光谱探测,在扫描的任一位置,对应的是红外的某一波长,扫描的步长对应的是光谱分辨率,而扫描的起终位置,对应红外探测的起始和终止波长,当动镜平移到终止位置时结束探测,控制器记录探测波长范围内各个波长的标准白板反射的强度值;Step 2.1, detecting the intensity value of the standard white plate reflection of each wavelength within the wavelength range, the controller controls the moving mirror mechanism, controls the moving mirror to translate with the set scanning step length, and performs Fourier infrared spectrum detection at the same time. Any position of the scan corresponds to a certain infrared wavelength, the scanning step length corresponds to the spectral resolution, and the start and end positions of the scan correspond to the start and end wavelengths of the infrared detection. When the moving mirror translates to the end position, the detection ends, and the controller records the intensity value of the standard white plate reflection of each wavelength within the detection wavelength range;
步骤2.2,探测波长范围内各个波长的待测织物纤维样品反射的强度值,将标准白板换成待测织物纤维样品,动镜反向以相同的步长从终止位置移动到起始位置,同时进行傅立叶红外光谱探测,当动镜移动到起始位置时结束探测,控制器记录探测波长范围内各个波长的待测织物纤维样品反射的强度值,Step 2.2, detect the intensity value of the reflection of the fabric fiber sample to be tested at each wavelength within the wavelength range, replace the standard white board with the fabric fiber sample to be tested, move the moving mirror in the opposite direction from the end position to the start position with the same step length, and perform Fourier infrared spectrum detection at the same time. When the moving mirror moves to the start position, the detection ends, and the controller records the intensity value of the reflection of the fabric fiber sample to be tested at each wavelength within the detection wavelength range.
步骤2.3,将步骤2.2测得的待测织物纤维样品反射的强度值与步骤2.1测得的标准白板反射的强度值相除,得到待测织物纤维样品探测波长范围内的反射率分布。Step 2.3, dividing the reflection intensity value of the tested fabric fiber sample measured in step 2.2 by the reflection intensity value of the standard white board measured in step 2.1, to obtain the reflectivity distribution of the tested fabric fiber sample within the detection wavelength range.
作为本发明的优选技术方案:设有控制器,所述控制器控制开启红外光源,以及控制红外面阵,指定其工作模式并接收其数据。As a preferred technical solution of the present invention: a controller is provided, and the controller controls the turning on of the infrared light source, and controls the infrared array, specifies its working mode and receives its data.
作为本发明的优选技术方案:傅立叶红外光谱探测光路中,红外光源沿红外光轴发出的红外光,经分束器分为两路:一路经分束器反射后沿正交光轴射向动镜,经动镜反射折返,再穿过分束器;另一路穿过分束器,沿红外光轴射向静镜,经静镜反射折返,再经分束器反射;As a preferred technical solution of the present invention: in the Fourier infrared spectrum detection optical path, the infrared light emitted by the infrared light source along the infrared optical axis is divided into two paths by the beam splitter: one path is reflected by the beam splitter and then emitted to the moving mirror along the orthogonal optical axis, reflected by the moving mirror and then passed through the beam splitter; the other path passes through the beam splitter, emitted to the static mirror along the infrared optical axis, reflected by the static mirror and then reflected by the beam splitter;
动镜与静镜到分束器的中心距离不同,形成光路差,这两路红外光为相干光,汇合后形成等倾干涉环分布,动镜在沿正交光轴平移扫描的过程中,干涉环圆心对应不同波长的中心主极大红外光强分布,穿过带孔反射镜乙的中心孔后,仅通过中心主极大红外光,再经带孔反射镜甲反射后,转向与正交光轴垂直的主光轴,再经卡式显微物镜聚集至焦面上的织物纤维样品,织物纤维样品反射的一部分对应某一特定波长的主极大红外光沿主光轴折返,经卡式显微物镜,穿过带孔反射镜甲的中心孔,再经卡式显微像镜聚焦至红外面阵上;The moving mirror and the static mirror have different center distances to the beam splitter, resulting in an optical path difference. The two infrared lights are coherent lights, and after merging, they form an equi-inclined interference ring distribution. When the moving mirror is moving and scanning along the orthogonal optical axis, the center of the interference ring corresponds to the central main maximum infrared light intensity distribution of different wavelengths. After passing through the central hole of the perforated reflector B, only the central main maximum infrared light passes through, and then after being reflected by the perforated reflector A, it turns to the main optical axis perpendicular to the orthogonal optical axis, and then is focused to the fabric fiber sample on the focal plane through the cassette microscope objective. A part of the main maximum infrared light corresponding to a specific wavelength reflected by the fabric fiber sample is folded back along the main optical axis, passes through the cassette microscope objective, passes through the central hole of the perforated reflector A, and then is focused to the infrared surface array through the cassette microscope image lens;
红外面阵在主控制器的控制下启动积分模式,将所有像元的强度值进行累加,并记录该累加的强度值。The infrared array starts the integration mode under the control of the main controller, accumulates the intensity values of all pixels, and records the accumulated intensity values.
作为本发明的优选技术方案:红外显微成像光路中,红外光源沿红外光轴发出的宽谱红外光,经切入镜反射,转向与红外光轴垂直的切入光轴,再经全反镜反射转向与红外光轴平行的转折光轴,经带孔反射镜乙和带孔反射镜甲反射后,转向与正交光轴垂直的主光轴,再经卡式显微物镜聚集至焦面上的织物纤维样品,织物纤维样品反射的宽谱红外光沿主光轴折返,经卡式显微物镜,穿过带孔反射镜甲的中心孔,再经卡式显微像镜聚焦成像至红外面阵上,红外面阵在主控制器的控制下启动成像模式,并记录该宽谱红外图片供后续分析。As a preferred technical solution of the present invention: in the infrared microscopic imaging optical path, the wide-spectrum infrared light emitted by the infrared light source along the infrared optical axis is reflected by the cutting-in mirror and turned to the cutting-in optical axis perpendicular to the infrared optical axis, and then reflected by the total reflection mirror and turned to the turning optical axis parallel to the infrared optical axis, and then reflected by the perforated reflector B and the perforated reflector A, and then turned to the main optical axis perpendicular to the orthogonal optical axis, and then focused to the fabric fiber sample on the focal plane by the cassette microscope objective lens, the wide-spectrum infrared light reflected by the fabric fiber sample is turned back along the main optical axis, passed through the cassette microscope objective lens, passed through the central hole of the perforated reflector A, and then focused and imaged onto the infrared surface array by the cassette microscope image lens, and the infrared surface array starts the imaging mode under the control of the main controller, and records the wide-spectrum infrared picture for subsequent analysis.
作为本发明的优选技术方案:所述卡式显微像镜内含成像次镜和成像主镜,卡式显微物镜内含物方主镜和物方次镜,卡式显微像镜与卡式显微物镜均为无限远成像设计,在主光轴上同轴对称共轭放置,卡式显微物镜先将其焦面上的织物纤维样品发出的光线先后物方主镜、物方次镜反射后,变成有一定放大倍数的平行光,再经卡式显微像镜的成像次镜和成像主镜反射,将平行光按卡式显微像镜的倍率缩小聚焦成像至焦面上的红外面阵。As a preferred technical solution of the present invention: the cassette microscope contains an imaging secondary mirror and an imaging primary mirror, the cassette microscope objective lens contains an object side primary mirror and an object side secondary mirror, the cassette microscope image lens and the cassette microscope objective lens are both designed for infinite imaging, and are coaxially symmetrically placed conjugately on the main optical axis. The cassette microscope objective lens first reflects the light emitted by the textile fiber sample on its focal plane through the object side primary mirror and the object side secondary mirror in succession, and turns it into parallel light with a certain magnification, and then reflects it through the imaging secondary mirror and the imaging primary mirror of the cassette microscope, and reduces the parallel light according to the magnification of the cassette microscope and focuses it to form an infrared surface array on the focal plane.
作为本发明的优选技术方案:成像次镜、成像主镜、物方主镜、物方次镜、动镜、静镜、切入镜表面、带孔反射镜乙、带孔反射镜甲表面均镀有红外高反膜,红外高反膜对红外光源发射范围内的红外光进行高效反射。As a preferred technical solution of the present invention: the surfaces of the imaging secondary mirror, the imaging primary mirror, the object side primary mirror, the object side secondary mirror, the moving mirror, the static mirror, the cutting-in mirror, the perforated reflector B, and the perforated reflector A are all coated with an infrared high-reflection film, which efficiently reflects infrared light within the emission range of the infrared light source.
作为本发明的优选技术方案:卡式显微像镜与卡式显微物镜的不同倍率比,以在红外面阵上获得不同的像物放大比。As a preferred technical solution of the present invention: different magnification ratios of the cassette microscope image lens and the cassette microscope objective lens are used to obtain different image-object magnification ratios on the infrared surface array.
作为本发明的优选技术方案:分束器为两片相同的薄红外高透光学玻璃贴合而成,贴合面镀红外半反半透膜,与正交光轴夹角45度放置。As a preferred technical solution of the present invention: the beam splitter is formed by bonding two identical thin infrared high-transmittance optical glasses, the bonding surface is coated with an infrared semi-reflective and semi-transparent film, and is placed at an angle of 45 degrees to the orthogonal optical axis.
作为本发明的优选技术方案:织物纤维检测仪选用锂电池作为驱动电源。As a preferred technical solution of the present invention: the fabric fiber detector uses a lithium battery as a driving power source.
作为本发明的优选技术方案:织物纤维检测仪配设操作把手,供操作者手提。As a preferred technical solution of the present invention: the fabric fiber detector is equipped with an operating handle for the operator to carry it.
本发明具有以下有益效果:本发明的一种红外显微织物纤维无损检测方法,利用傅立叶红外光谱探测光路、红外显微成像光路复用红外光源、带孔反射镜乙、带孔反射镜甲、卡式显微物镜、卡式显微像镜和红外面阵,通过切入机构控制切入镜切入或切出红外光轴,实现红外显微成像光路与傅立叶红外光谱探测光路的切换,获取完全重叠的探测目标的高分辨红外光谱及宽谱红外图像,实现对织物纤维同一位置的粗织、交织方式等纹理探测,以及纤维成分分析、模式识别的综合检测。The present invention has the following beneficial effects: an infrared microscopic fabric fiber nondestructive testing method of the present invention utilizes a Fourier infrared spectrum detection optical path, an infrared microscopic imaging optical path multiplexing infrared light source, a holed reflector B, a holed reflector A, a cassette microscope objective lens, a cassette microscope image lens and an infrared surface array, and controls the cutting-in mirror to cut in or out of the infrared optical axis through a cutting-in mechanism, thereby realizing the switching of the infrared microscopic imaging optical path and the Fourier infrared spectrum detection optical path, obtaining a high-resolution infrared spectrum and a wide-spectrum infrared image of a completely overlapping detection target, realizing the texture detection of the coarse weaving, interweaving mode and the like at the same position of the fabric fiber, and the comprehensive detection of fiber component analysis and pattern recognition.
本发明的红外显微织物纤维无损检测方法,利用傅立叶红外光谱探测光路、红外显微成像光路的复用结构,为制备更紧凑、小型化的织物纤维检测仪提供了思路,通过配设的定位罩以及定位罩尺寸,快速将待测部分置物置于卡式显微物镜的焦面,能更快速的对织物进行检测,由此,本发明提供了一种能快速检测的紧凑、小型化织物检测仪。The infrared microscopic fabric fiber nondestructive testing method of the present invention utilizes the multiplexing structure of the Fourier infrared spectrum detection optical path and the infrared microscopic imaging optical path, and provides a method for preparing a more compact and miniaturized fabric fiber detector. By providing a positioning cover and the size of the positioning cover, the part to be tested can be quickly placed on the focal plane of the cassette microscope objective lens, so that the fabric can be detected more quickly. Therefore, the present invention provides a compact and miniaturized fabric detector capable of rapid detection.
本发明的一种红外显微织物纤维无损检测方法,采用两种工作模式,同时进行精准红外光谱分析及红外宽谱成像,通过信息融合进行织物纤维的模式识别和成分分析,在织物纤维现场检测领域极具应用前景。The infrared microscopic nondestructive testing method for fabric fibers of the present invention adopts two working modes, performs precise infrared spectrum analysis and infrared wide-spectrum imaging simultaneously, and performs pattern recognition and component analysis of fabric fibers through information fusion, which has great application prospects in the field of on-site testing of fabric fibers.
图1为本发明的红外显微织物纤维无损检测方法的流程图;FIG1 is a flow chart of the infrared microscopic nondestructive testing method for textile fibers of the present invention;
图2为本发明的红外显微织物纤维无损检测方法的所使用的织物纤维检测仪的结构图;FIG2 is a structural diagram of a fabric fiber detector used in the infrared microscopic fabric fiber nondestructive testing method of the present invention;
附图中,检测仪本体1;锂电池2;充电接口3;开关4;供电线5;动镜6;正交光轴7;分束器8;动镜机构9;切入镜10;切入机构11;主控制器12;红外光源13;操作把手14;红外光轴15;切入光轴16;静镜17;全反镜18;红外面阵19;卡式显微像镜20 ;成像次镜21;成像主镜22;转折光轴23;24带孔反射镜甲;带孔反射镜乙25;物方主镜26;主光轴27;物方次镜28;织物纤维样品29;定位罩30;卡式显微物镜31。In the accompanying drawings, there are a detector body 1; a lithium battery 2; a charging port 3; a switch 4; a power supply line 5; a moving mirror 6; an orthogonal optical axis 7; a beam splitter 8; a moving mirror mechanism 9; a cutting mirror 10; a cutting mechanism 11; a main controller 12; an infrared light source 13; an operating handle 14; an infrared optical axis 15; a cutting optical axis 16; a static mirror 17; a total reflecting mirror 18; an infrared surface array 19; a cassette microscope 20; an imaging secondary mirror 21; an imaging primary mirror 22; a turning optical axis 23; a perforated reflector A 24; a perforated reflector B 25; an object side primary mirror 26; a primary optical axis 27; an object side secondary mirror 28; a fabric fiber sample 29; a positioning cover 30; and a cassette microscope objective lens 31.
参照附图和具体实施例对本发明作进一步详细地描述。The present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.
如图1所示,本发明的一种红外显微织物纤维无损检测方法,采用包括傅立叶红外光谱探测光路、红外显微成像光路的织物纤维检测仪进行检测,织物纤维检测仪,包括检测仪本体1,包括锂电池2、动镜6、分束器8、动镜机构9、切入镜10、切入机构11、主控制器12、红外光源13、静镜17、全反镜18、红外面阵19、卡式显微像镜20、带孔反射镜甲24、带孔反射镜乙25和卡式显微物镜31。As shown in Figure 1, an infrared microscopic nondestructive testing method for fabric fibers of the present invention adopts a fabric fiber detector including a Fourier infrared spectrum detection optical path and an infrared microscopic imaging optical path for testing. The fabric fiber detector includes a detector body 1, including a lithium battery 2, a moving mirror 6, a beam splitter 8, a moving mirror mechanism 9, a cutting mirror 10, a cutting mechanism 11, a main controller 12, an infrared light source 13, a static mirror 17, a total reflector 18, an infrared surface array 19, a cassette microscope 20, a perforated reflector A 24, a perforated reflector B 25 and a cassette microscope objective 31.
所述卡式显微像镜20内含成像次镜21和成像主镜22。卡式显微物镜31内含物方主镜26和物方次镜28。卡式显微像镜20与卡式显微物镜31均为无限远成像设计,在主光轴27上同轴对称共轭放置。卡式显微物镜31先将其焦面上的织物纤维样品29发出的光线先后物方主镜26、物方次镜28反射后,变成有一定放大倍数(卡式显微物镜31倍率,本实施例倍率为20)的平行光,再经卡式显微像镜20的成像次镜21和成像主镜22反射,将平行光按卡式显微像镜20的倍率,本实施例倍率为5,缩小聚焦成像至焦面上的红外面阵19。可以选择卡式显微像镜20与卡式显微物镜31的不同倍率比,以在红外面阵19上获得不同的像物放大比,本实施例放大比为4。The cassette microscope 20 contains an imaging secondary mirror 21 and an imaging primary mirror 22. The cassette microscope objective lens 31 contains an object side primary mirror 26 and an object side secondary mirror 28. Both the cassette microscope 20 and the cassette microscope objective lens 31 are designed for infinite imaging and are placed coaxially symmetrically conjugately on the main optical axis 27. The cassette microscope objective lens 31 first reflects the light emitted by the fabric fiber sample 29 on its focal plane from the object side primary mirror 26 and the object side secondary mirror 28 in succession, and then turns it into parallel light with a certain magnification (the magnification of the cassette microscope objective lens 31, the magnification of this embodiment is 20), and then reflects the imaging secondary mirror 21 and the imaging primary mirror 22 of the cassette microscope 20, and the parallel light is reduced and focused to the infrared array 19 on the focal plane according to the magnification of the cassette microscope 20, the magnification of this embodiment is 5. Different magnification ratios of the cassette microscope image lens 20 and the cassette microscope objective lens 31 can be selected to obtain different image-object magnification ratios on the infrared surface array 19. The magnification ratio in this embodiment is 4.
所述动镜机构9可控制动镜6沿正交光轴7平移。切入机构11可控制切入镜10切入或切出红外光轴15。The moving mirror mechanism 9 can control the moving mirror 6 to translate along the orthogonal optical axis 7. The cutting mechanism 11 can control the cutting mirror 10 to cut into or out of the infrared optical axis 15.
所述红外光源13可发射一定范围内,本实施例为1000 cm-1-3300cm-1的宽谱红外光,与之对应的红外面阵19可感应这个范围内的红外光并成像。成像次镜21、成像主镜22、物方主镜26、物方次镜28、动镜6、静镜17、切入镜10表面、带孔反射镜乙25、带孔反射镜甲24表面均镀有红外高反膜,可对红外光源13发射范围内的红外光进行高效反射。The infrared light source 13 can emit a wide spectrum infrared light within a certain range, which is 1000 cm-1-3300 cm-1 in this embodiment, and the corresponding infrared surface array 19 can sense the infrared light within this range and form an image. The imaging secondary mirror 21, the imaging primary mirror 22, the object primary mirror 26, the object secondary mirror 28, the moving mirror 6, the static mirror 17, the surface of the cutting mirror 10, the holed reflector B 25, and the holed reflector A 24 are all coated with infrared high-reflection films, which can efficiently reflect the infrared light within the emission range of the infrared light source 13.
傅立叶红外光谱探测光路由红外光源13、分束器8、动镜6、静镜17、带孔反射镜乙25、带孔反射镜甲24、卡式显微物镜31、卡式显微像镜20、红外面阵19组成。正交光轴7与红外光轴15垂直,分束器8为两片相同的薄红外高透光学玻璃贴合而成,贴合面镀红外半反半透膜,与正交光轴7夹角45度放置。傅立叶红外光谱探测模式时,红外光源13沿红外光轴15发出的红外光,经分束器8分为两路:一路经分束器8反射后沿正交光轴7射向动镜6,经动镜6反射折返,再穿过分束器8;另一路穿过分束器8,沿红外光轴15射向静镜17,经静镜17反射折返,再经分束器8反射。动镜6与静镜17到分束器8的中心距离不同,形成光路差,因此这两路红外光为相干光,汇合后形成等倾干涉环分布,动镜6在沿正交光轴7平移或扫描的过程中,干涉环圆心对应不同波长的中心主极大红外光强分布,在某一探测瞬间,为某一特定波长值,穿过带孔反射镜乙25的中心孔后,仅通过中心主极大红外光,再经带孔反射镜甲24反射后,转向与正交光轴7垂直的主光轴27,再经卡式显微物镜31聚集至焦面上的织物纤维样品29,织物纤维样品29反射的一部分对应某一特定波长的主极大红外光沿主光轴27折返,经卡式显微物镜31,穿过带孔反射镜甲24的中心孔,再经卡式显微像镜20聚焦至红外面阵19上。红外面阵19在主控制器12的控制下启动积分模式,即将所有像元的强度值进行累加,相当于一个单元探测器,并记录该累加的强度值。The Fourier infrared spectrum detection optical path is composed of an infrared light source 13, a beam splitter 8, a moving mirror 6, a static mirror 17, a perforated reflector B 25, a perforated reflector A 24, a cassette microscope objective 31, a cassette microscope image lens 20, and an infrared surface array 19. The orthogonal optical axis 7 is perpendicular to the infrared optical axis 15. The beam splitter 8 is formed by laminating two identical thin infrared high-transmittance optical glasses, and the laminating surface is coated with an infrared semi-reflective and semi-transmissive film, and is placed at an angle of 45 degrees to the orthogonal optical axis 7. In the Fourier infrared spectrum detection mode, the infrared light emitted by the infrared light source 13 along the infrared optical axis 15 is divided into two paths by the beam splitter 8: one path is reflected by the beam splitter 8 and then emitted to the moving mirror 6 along the orthogonal optical axis 7, reflected and returned by the moving mirror 6, and then passes through the beam splitter 8; the other path passes through the beam splitter 8, and is emitted to the static mirror 17 along the infrared optical axis 15, reflected and returned by the static mirror 17, and then reflected by the beam splitter 8. The moving mirror 6 and the static mirror 17 have different center distances to the beam splitter 8, resulting in an optical path difference. Therefore, the two infrared lights are coherent lights, which form an equi-inclined interference ring distribution after merging. When the moving mirror 6 is translated or scanned along the orthogonal optical axis 7, the center of the interference ring corresponds to the central main maximum infrared light intensity distribution of different wavelengths. At a certain detection moment, it is a certain wavelength value. After passing through the central hole of the perforated reflector B 25, only the central main maximum infrared light passes through, and then after being reflected by the perforated reflector A 24, it turns to the main optical axis 27 perpendicular to the orthogonal optical axis 7, and then is focused to the fabric fiber sample 29 on the focal plane through the cassette microscope objective 31. A part of the main maximum infrared light corresponding to a certain wavelength reflected by the fabric fiber sample 29 is turned back along the main optical axis 27, passes through the cassette microscope objective 31, passes through the central hole of the perforated reflector A 24, and then is focused to the infrared surface array 19 through the cassette microscope image lens 20. The infrared array 19 starts the integration mode under the control of the main controller 12, that is, the intensity values of all pixels are accumulated, which is equivalent to a unit detector, and the accumulated intensity value is recorded.
红外显微成像光路与傅立叶红外光谱探测光路复用红外光源13、带孔反射镜乙25、带孔反射镜甲24、卡式显微物镜31、卡式显微像镜20、红外面阵19。此外,含有切入镜10、全反镜18。当切入镜10在切入机构11控制下切入红外光轴15时,红外显微成像光路工作;反之,当切入镜10在切入机构11控制下切出红外光轴15时,傅立叶红外光谱探测光路工作。在红外显微成像模式时,红外光源13沿红外光轴15发出的宽谱红外光,经切入镜10反射,转向与红外光轴15垂直的切入光轴16,再经全反镜18反射转向与红外光轴15平行的转折光轴23,经带孔反射镜乙25和带孔反射镜甲24反射后,转向与正交光轴7垂直的主光轴27,再经卡式显微物镜31聚集至焦面上的织物纤维样品29,织物纤维样品29反射的宽谱红外光沿主光轴27折返,经卡式显微物镜31,穿过带孔反射镜甲24的中心孔,再经卡式显微像镜20聚焦成像至红外面阵19上。红外面阵19在主控制器12的控制下启动成像模式,并记录该宽谱红外图片供后续分析。The infrared microscopic imaging optical path and the Fourier infrared spectrum detection optical path multiplex the infrared light source 13, the perforated reflector B 25, the perforated reflector A 24, the cassette microscope objective 31, the cassette microscope image lens 20, and the infrared surface array 19. In addition, it contains a cutting mirror 10 and a total reflection mirror 18. When the cutting mirror 10 cuts into the infrared optical axis 15 under the control of the cutting mechanism 11, the infrared microscopic imaging optical path works; conversely, when the cutting mirror 10 cuts out of the infrared optical axis 15 under the control of the cutting mechanism 11, the Fourier infrared spectrum detection optical path works. In the infrared microscopic imaging mode, the wide-spectrum infrared light emitted by the infrared light source 13 along the infrared optical axis 15 is reflected by the cutting mirror 10, turned to the cutting optical axis 16 perpendicular to the infrared optical axis 15, and then reflected by the total reflection mirror 18 to the turning optical axis 23 parallel to the infrared optical axis 15, and then reflected by the hole reflector B 25 and the hole reflector A 24, and then turned to the main optical axis 27 perpendicular to the orthogonal optical axis 7, and then focused to the fabric fiber sample 29 on the focal plane by the cassette microscope objective lens 31, and the wide-spectrum infrared light reflected by the fabric fiber sample 29 is turned back along the main optical axis 27, passed through the cassette microscope objective lens 31, passed through the central hole of the hole reflector A 24, and then focused and imaged onto the infrared surface array 19 by the cassette microscope image lens 20. The infrared surface array 19 starts the imaging mode under the control of the main controller 12, and records the wide-spectrum infrared picture for subsequent analysis.
所述锂电池2上有充电接口3和开关4。电池充电器可通过充电接口3对锂电池2冲电。当开关4接通时,锂电池2通过供电线5,对动镜机构9、切入机构11、主控制器12、红外光源13、红外面阵19进行供电。The lithium battery 2 has a charging interface 3 and a switch 4. The battery charger can charge the lithium battery 2 through the charging interface 3. When the switch 4 is turned on, the lithium battery 2 supplies power to the moving mirror mechanism 9, the cutting mechanism 11, the main controller 12, the infrared light source 13, and the infrared surface array 19 through the power supply line 5.
在现场检测时,操作者提操作把手14,使定位罩30紧贴织物纤维样品29,定位罩30的尺寸可使织物纤维样品29处于卡式显微物镜31的焦面上,方便现场快检。During on-site inspection, the operator lifts the operating handle 14 to make the positioning cover 30 close to the fabric fiber sample 29. The size of the positioning cover 30 allows the fabric fiber sample 29 to be on the focal plane of the cassette microscope objective lens 31, which is convenient for on-site quick inspection.
所述控制器12用于开启红外光源13,以及控制红外面阵19,指定其工作模式并接收其数据。控制器12还用于给动镜机构9和切入机构11发指令,从而控制动镜6沿正交光轴7平移的扫描步长和起终位置,以及控制切入镜10切入切出红外光轴15。The controller 12 is used to turn on the infrared light source 13, control the infrared array 19, specify its working mode and receive its data. The controller 12 is also used to send instructions to the moving mirror mechanism 9 and the cutting mechanism 11, so as to control the scanning step length and the starting and ending positions of the moving mirror 6 along the orthogonal optical axis 7, and control the cutting mirror 10 to cut in and out of the infrared optical axis 15.
本发明的一种红外显微织物纤维无损检测方法,具体包括以下步骤:The present invention provides an infrared microscopic nondestructive testing method for textile fibers, which specifically comprises the following steps:
(1) 仪器初始化(1) Instrument initialization
在现场检测前,通过充电接口3对锂电池2冲好。现场检测时,操作者打开开关4,锂电池2对仪器供电。控制器12开启红外光源13,给动镜机构9发指令,设定控制动镜6沿正交光轴7平移的扫描步长和起终位置,并将动镜6移动至起始位置。Before on-site testing, the lithium battery 2 is charged through the charging interface 3. During on-site testing, the operator turns on the switch 4, and the lithium battery 2 powers the instrument. The controller 12 turns on the infrared light source 13, sends instructions to the moving mirror mechanism 9, sets the scanning step length and the starting and ending positions of the moving mirror 6 along the orthogonal optical axis 7, and moves the moving mirror 6 to the starting position.
(2) 傅立叶红外光谱探测(2) Fourier transform infrared spectroscopy detection
控制器12给切入机构11发指令,控制切入镜10切出红外光轴15,并启动红外面阵19的工作模式为积分模式。操作者提操作把手14,使定位罩30紧贴一标准白板,控制器12给动镜机构9发指令,控制动镜6以设定的扫描步长进行平移。同时进行傅立叶红外光谱探测,在扫描的任一位置,对应的是红外的某一波长,扫描的步长对应的是光谱分辨率,而扫描的起终位置,对应红外探测的起始和终止波长。当动镜6平移到终止位置时结束探测。控制器12记录探测波长范围,本实施例为1000 cm-1-3300cm-1,内各个波长的标准白板反射的强度值,即红外光源13的光谱分布。The controller 12 sends instructions to the cutting mechanism 11 to control the cutting mirror 10 to cut out the infrared light axis 15, and starts the working mode of the infrared array 19 to the integration mode. The operator lifts the operating handle 14 to make the positioning cover 30 close to a standard white board. The controller 12 sends instructions to the moving mirror mechanism 9 to control the moving mirror 6 to translate with the set scanning step length. At the same time, Fourier infrared spectrum detection is carried out. At any position of the scan, it corresponds to a certain wavelength of infrared. The scanning step length corresponds to the spectral resolution, and the starting and ending positions of the scan correspond to the starting and ending wavelengths of the infrared detection. The detection ends when the moving mirror 6 translates to the end position. The controller 12 records the detection wavelength range, which is 1000 cm-1-3300cm-1 in this embodiment. The intensity value of the standard white board reflection at each wavelength within the detection wavelength range, that is, the spectral distribution of the infrared light source 13.
将标准白板换成待测织物纤维样品29,动镜6反向以相同的步长从终止位置移动到起始位置,同时进行傅立叶红外光谱探测,当动镜6移动到起始位置时结束探测。控制器12记录探测波长范围内各个波长的待测织物纤维样品29反射的强度值,将其与标准白板反射的强度值相除,得到待测织物纤维样品29探测波长范围内的反射率分布。The standard white board is replaced with the fabric fiber sample 29 to be tested, and the moving mirror 6 moves in the opposite direction from the end position to the start position with the same step length, and Fourier infrared spectrum detection is performed at the same time, and the detection is terminated when the moving mirror 6 moves to the start position. The controller 12 records the intensity value of the reflection of the fabric fiber sample 29 to be tested at each wavelength within the detection wavelength range, and divides it with the intensity value of the reflection of the standard white board to obtain the reflectivity distribution of the fabric fiber sample 29 to be tested within the detection wavelength range.
(3) 红外显微成像探测(3) Infrared microscopic imaging detection
控制器12给切入机构11发指令,控制切入镜10切入红外光轴15,并启动红外面阵19的工作模式为成像模式。控制器12记录下探测波长范围内的待测织物纤维样品29反射的宽谱红外图像。该图像可以去除织物纤维颜色干扰,图像纹理中含有织物纤维的粗细和交织信息,图像灰度中含有成分信息。The controller 12 sends a command to the cutting mechanism 11, controls the cutting mirror 10 to cut into the infrared optical axis 15, and starts the working mode of the infrared outer array 19 to the imaging mode. The controller 12 records the wide-spectrum infrared image reflected by the fabric fiber sample 29 to be tested within the detection wavelength range. The image can remove the color interference of the fabric fiber, the image texture contains the thickness and interweaving information of the fabric fiber, and the image gray contains the composition information.
(4) 织物纤维分析(4) Fabric fiber analysis
将步骤2获取的待测织物纤维样品29的反射率或红外吸收进行光谱分析,可得到织物纤维中的分子组成及含量。将步骤3获得的同一待测织物纤维样品29的红外宽谱图像进行图像处理分析,可得织物纤维的粗细和交织信息,并辅助进行成分确定和模式识别。By performing spectral analysis on the reflectivity or infrared absorption of the fabric fiber sample 29 obtained in step 2, the molecular composition and content in the fabric fiber can be obtained. By performing image processing and analysis on the infrared wide-spectrum image of the same fabric fiber sample 29 obtained in step 3, the thickness and interweaving information of the fabric fiber can be obtained, and the composition determination and pattern recognition can be assisted.
本发明的一种红外显微织物纤维无损检测方法,采用包括傅立叶红外光谱探测光路、红外显微成像光路的织物纤维检测仪进行检测,采用两种工作模式,即傅立叶变换光谱探测模式和宽谱红外反射显微成像模式,并复用其中的红外光源、红外面阵、及卡式显微物像系统。可在满足一定体积要求情况下,同时进行精准红外光谱分析及红外宽谱成像,通过信息融合进行织物纤维的模式识别和成分分析,满足市场监管需求。The present invention discloses an infrared microscopic nondestructive testing method for fabric fibers. The method adopts a fabric fiber detector including a Fourier transform infrared spectrum detection optical path and an infrared microscopic imaging optical path for testing. The method adopts two working modes, namely, a Fourier transform spectrum detection mode and a wide-spectrum infrared reflection microscopic imaging mode, and reuses the infrared light source, infrared surface array, and cassette microscopic imaging system. Under the condition of meeting certain volume requirements, accurate infrared spectrum analysis and infrared wide-spectrum imaging can be performed simultaneously. Pattern recognition and component analysis of fabric fibers can be performed through information fusion to meet market supervision needs.
上述具体实施方式用来解释说明本发明,仅为本发明的优选实施例,而不是对本发明进行限制,在本发明的精神和权利要求的保护范围内,对本发明做出的任何修改、等同替换、改进等,都落入本发明的保护范围。The above-mentioned specific implementation methods are used to explain the present invention and are only preferred embodiments of the present invention, rather than limiting the present invention. Any modifications, equivalent substitutions, improvements, etc. made to the present invention within the spirit of the present invention and the protection scope of the claims shall fall within the protection scope of the present invention.
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| CN105372225A (en) * | 2015-12-01 | 2016-03-02 | 中国科学院上海技术物理研究所 | System and method for analysis of Martian mineral component by using double multiplexing laser spectrum |
| CN107884339A (en) * | 2017-10-13 | 2018-04-06 | 中国科学院上海技术物理研究所 | A kind of adaptive laser spectrum and imaging method of suitable deep space micro-zone analysis |
| CN112567196A (en) * | 2018-09-03 | 2021-03-26 | 株式会社岛津制作所 | Interferometer moving mirror position measuring device and Fourier transform infrared spectrometer |
| CN110672550A (en) * | 2019-09-10 | 2020-01-10 | 中国科学院上海技术物理研究所 | Image spectrum analyzer for important biological resources in micro-area |
| CN114199805A (en) * | 2020-08-28 | 2022-03-18 | 中国科学院大连化学物理研究所 | Fourier transform infrared spectrum measuring device for in-situ monitoring chemical and chemical reaction |
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