WO2025065196A1 - Filter device and preparation system for nickel-cobalt-manganese precursor - Google Patents
Filter device and preparation system for nickel-cobalt-manganese precursor Download PDFInfo
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- WO2025065196A1 WO2025065196A1 PCT/CN2023/121276 CN2023121276W WO2025065196A1 WO 2025065196 A1 WO2025065196 A1 WO 2025065196A1 CN 2023121276 W CN2023121276 W CN 2023121276W WO 2025065196 A1 WO2025065196 A1 WO 2025065196A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/30—Combinations with other devices, not otherwise provided for
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- the present application relates to the technical field of battery precursor production equipment, and in particular to a filtering device and a preparation system for a nickel-cobalt-manganese precursor.
- the production quality of ternary cathode materials will directly affect the core indicators of lithium-ion batteries such as cycle characteristics, safety, battery energy density and cost.
- the production and preparation of nickel-cobalt-manganese precursors is an important link.
- the quality of nickel-cobalt-manganese precursors will directly affect the rate performance and safety performance of the cathode materials.
- the continuous method is mainly used to produce and prepare nickel-cobalt-manganese precursors.
- the reactor sometimes has an imbalance in the reaction system, which is manifested in the increase of large particles of the precursor, a sudden increase in the specific surface area, and the reaction is difficult to control until it is out of control.
- the precursor will have ball cracks, affecting product performance; it takes at least 3 days to discover it in time and make corresponding adjustments to stabilize it.
- the production cost and risk are greatly increased.
- foreign matter in the reactor is difficult to remove, inspect and analyze, which will not only affect the product quality of the entire production line, but also the risk of continued imbalance.
- the purpose of the present application is to provide a filtering device and a preparation system for a nickel-cobalt-manganese precursor, which can not only efficiently separate and recover foreign matter in the nickel-cobalt-manganese precursor, but also reduce the time wasted in reopening the reactor when an abnormality occurs.
- the present application provides a filtering device for nickel-cobalt-manganese precursor, comprising: a tank body, a filter screen, an iron remover, a filter inlet valve and a filter outlet valve; the tank body has an inlet and an outlet, and the inlet and the outlet are respectively arranged on the tank body along the first
- the filter inlet valve is arranged on the feed inlet, and the filter outlet valve is arranged on the discharge port;
- the filter screen is detachably arranged inside the tank body, and divides the inside of the tank body into a feed chamber and a discharge chamber along the first direction, wherein the feed chamber is connected with the feed inlet, and the discharge chamber is connected with the discharge port;
- the iron remover is installed on the side wall of the tank body and is located in the feed chamber.
- the iron remover includes a magnetic rod and a steel sleeve, the steel sleeve is sleeved on the magnetic rod, and the steel sleeve is installed on the side wall of the tank body.
- a mounting opening is further provided on the side wall of the tank body, and the iron remover can be detachably mounted on the mounting opening.
- the iron remover includes a mounting plate and a connecting piece
- the iron remover has a plurality of the magnetic bars and a plurality of the steel sleeves
- the mounting plate is provided with a plurality of mounting holes
- the plurality of the steel sleeves are respectively mounted on the plurality of mounting holes
- the plurality of the magnetic bars are respectively arranged in the plurality of the steel sleeves
- the mounting plate is detachably mounted on the mounting port
- the ends of the plurality of the magnetic bars facing away from the tank body are connected by the connecting piece.
- the can body includes a top cover and a can body, the top of the can body is open, the top cover is covered on the top of the can body, and the feed inlet is arranged on the top cover.
- an observation window is further provided on the top of the tank body, and the observation window is used to observe the internal conditions of the tank body.
- the tank body also includes a feed cover, which is trumpet-shaped, and the end of the feed cover with a smaller diameter is installed on the feed port and connected to the feed port, and the end of the feed cover with a larger diameter covers above the iron remover.
- a feed cover which is trumpet-shaped, and the end of the feed cover with a smaller diameter is installed on the feed port and connected to the feed port, and the end of the feed cover with a larger diameter covers above the iron remover.
- the present application also provides a preparation system for a nickel-cobalt-manganese precursor, comprising an aging tank, a discharge pipe, a transmission pipe, a feed pump, a reactor and a filtering device for the nickel-cobalt-manganese precursor as described above, wherein the reactor is connected to the feed inlet via the discharge pipe, the aging tank is connected to the discharge port, the aging tank is connected to the reactor via the transmission pipe, and the feed pump is arranged on the transmission pipe for pumping the material in the aging tank into the reactor.
- a flushing device and a waste tank are also included, and the side wall of the tank body is It also has a forward wash port, a backwash port, a slag discharge port and a slag discharge pipe.
- the forward wash port and the slag discharge port are arranged at intervals on the side wall of the feed chamber and are connected to the feed chamber.
- the backwash port is arranged on the side wall of the discharge chamber and is connected to the discharge chamber.
- the slag discharge pipe is connected to the discharge port and is connected to the discharge chamber.
- the forward wash port and the backwash port are respectively connected to the flushing device, and the slag discharge port and the slag discharge pipe are respectively connected to the waste tank.
- the filtering device of the nickel-cobalt-manganese precursor also includes a forward wash valve, a backwash valve, a first slag discharge valve and a second slag discharge valve.
- the forward wash valve is arranged on the forward wash port
- the backwash valve is arranged on the backwash port
- the first slag discharge valve is arranged on the slag discharge port
- the second slag discharge valve is arranged on the slag discharge pipe.
- the filtering device of the nickel-cobalt-manganese precursor further includes a forward wash pipeline and a back wash pipeline, wherein the forward wash pipeline is installed at the forward wash port and extends toward the filter screen, and the back wash pipeline is installed at the back wash port and extends toward the filter screen.
- it includes a plurality of the reaction kettles and a plurality of discharge valves
- the discharge pipeline has a plurality of branches
- the plurality of the reaction kettles are respectively connected to the plurality of branches
- the plurality of the discharge valves are respectively arranged on the plurality of branches.
- two stirring devices are further included, and the two stirring devices are respectively arranged in the reaction kettle and the aging tank.
- two liquid level measuring devices are further included, and the two liquid level measuring devices are respectively arranged in the reactor and the aging tank.
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Abstract
Description
本申请涉及电池前驱体生产设备技术领域,特别是涉及一种镍钴锰前驱体的过滤装置及制备系统。The present application relates to the technical field of battery precursor production equipment, and in particular to a filtering device and a preparation system for a nickel-cobalt-manganese precursor.
三元系正极材料作为锂离子电池产业前进的核心之一,其生产质量将会直接影响锂离子电池的循环特性、安全性、电池能量密度及成本等核心指标,生产制备镍钴锰前驱体是其中一个重要环节,镍钴锰前驱体的质量会直接影响正极材料的倍率性能和安全性能。As one of the core elements of the lithium-ion battery industry, the production quality of ternary cathode materials will directly affect the core indicators of lithium-ion batteries such as cycle characteristics, safety, battery energy density and cost. The production and preparation of nickel-cobalt-manganese precursors is an important link. The quality of nickel-cobalt-manganese precursors will directly affect the rate performance and safety performance of the cathode materials.
目前主要采用连续法生产制备镍钴锰前驱体,但是在制备系统的长时间运行下反应釜有时会出现反应体系失衡现象,具体表现为前驱体的大颗粒增多、比表突增、反应难以控制直至失控。现有的制备系统,若发现较晚,前驱体会出现球裂,影响产品性能;及时发现并做出相应调整至稳定,也至少需要3天,调整期间由于现场只能对异常反应釜物料进行放料处理,大大增加了生产的成本和风险,且反应釜内异物难以去除检查分析,不仅会影响整条产线的产品品质,还有继续失衡的风险。At present, the continuous method is mainly used to produce and prepare nickel-cobalt-manganese precursors. However, when the preparation system is running for a long time, the reactor sometimes has an imbalance in the reaction system, which is manifested in the increase of large particles of the precursor, a sudden increase in the specific surface area, and the reaction is difficult to control until it is out of control. In the existing preparation system, if it is discovered too late, the precursor will have ball cracks, affecting product performance; it takes at least 3 days to discover it in time and make corresponding adjustments to stabilize it. During the adjustment period, since the abnormal reactor materials can only be discharged on site, the production cost and risk are greatly increased. In addition, foreign matter in the reactor is difficult to remove, inspect and analyze, which will not only affect the product quality of the entire production line, but also the risk of continued imbalance.
发明内容Summary of the invention
本申请的目的是:提供一种镍钴锰前驱体的过滤装置及制备系统,其不仅能够将镍钴锰前驱体的异物高效分离和回收,并且还能够减少反应釜异常时重开浪费的时间。The purpose of the present application is to provide a filtering device and a preparation system for a nickel-cobalt-manganese precursor, which can not only efficiently separate and recover foreign matter in the nickel-cobalt-manganese precursor, but also reduce the time wasted in reopening the reactor when an abnormality occurs.
为了实现上述目的,本申请提供了一种镍钴锰前驱体的过滤装置,包括:罐体、滤网、除铁器、过滤进阀和过滤出阀;所述罐体具有入料口和出料口,所述入料口和所述出料口分别设置在所述罐体沿第一 方向的两端,所述过滤进阀设置在所述入料口上,所述过滤出阀设置在所述出料口上;所述滤网可拆卸设置在所述罐体的内部,且将所述罐体的内部沿所述第一方向分隔为进料腔和出料腔,其中所述进料腔与所述入料口连通,所述出料腔与所述出料口连通;所述除铁器安装在所述罐体的侧壁上,且位于所述进料腔内。In order to achieve the above-mentioned purpose, the present application provides a filtering device for nickel-cobalt-manganese precursor, comprising: a tank body, a filter screen, an iron remover, a filter inlet valve and a filter outlet valve; the tank body has an inlet and an outlet, and the inlet and the outlet are respectively arranged on the tank body along the first The filter inlet valve is arranged on the feed inlet, and the filter outlet valve is arranged on the discharge port; the filter screen is detachably arranged inside the tank body, and divides the inside of the tank body into a feed chamber and a discharge chamber along the first direction, wherein the feed chamber is connected with the feed inlet, and the discharge chamber is connected with the discharge port; the iron remover is installed on the side wall of the tank body and is located in the feed chamber.
在一些实施例中,所述除铁器包括磁棒和钢套,所述钢套套设于所述磁棒,且所述钢套安装在所述罐体的侧壁上。In some embodiments, the iron remover includes a magnetic rod and a steel sleeve, the steel sleeve is sleeved on the magnetic rod, and the steel sleeve is installed on the side wall of the tank body.
在一些实施例中,所述罐体的侧壁上还开设安装口,所述除铁器可拆卸安装在所述安装口上。In some embodiments, a mounting opening is further provided on the side wall of the tank body, and the iron remover can be detachably mounted on the mounting opening.
在一些实施例中,所述除铁器包括安装板和连接件,所述除铁器具有多个所述磁棒和多个所述钢套,所述安装板上设有多个安装孔,多个所述钢套分别安装在多个所述安装孔上,多个所述磁棒分别设置在多个所述钢套中,所述安装板可拆卸安装在所述安装口上,且多个所述磁棒背离所述罐体的一端通过所述连接件连接。In some embodiments, the iron remover includes a mounting plate and a connecting piece, the iron remover has a plurality of the magnetic bars and a plurality of the steel sleeves, the mounting plate is provided with a plurality of mounting holes, the plurality of the steel sleeves are respectively mounted on the plurality of mounting holes, the plurality of the magnetic bars are respectively arranged in the plurality of the steel sleeves, the mounting plate is detachably mounted on the mounting port, and the ends of the plurality of the magnetic bars facing away from the tank body are connected by the connecting piece.
在一些实施例中,所述罐体包括顶盖和罐身,所述罐身的顶部敞开,所述顶盖盖合于所述罐身的顶部,所述入料口设置在所述顶盖上。In some embodiments, the can body includes a top cover and a can body, the top of the can body is open, the top cover is covered on the top of the can body, and the feed inlet is arranged on the top cover.
在一些实施例中,所述罐体的顶部还开设有观察窗,所述观察窗用于观察所述罐体的内部情况。In some embodiments, an observation window is further provided on the top of the tank body, and the observation window is used to observe the internal conditions of the tank body.
在一些实施例中,所述罐体还包括入料罩,所述入料罩呈喇叭状,且所述入料罩口径小的一端安装在所述入料口,且与所述入料口连通,所述入料罩口径大的一端罩在所述除铁器上方。In some embodiments, the tank body also includes a feed cover, which is trumpet-shaped, and the end of the feed cover with a smaller diameter is installed on the feed port and connected to the feed port, and the end of the feed cover with a larger diameter covers above the iron remover.
为了实现同样的目的,本申请还提供了一种镍钴锰前驱体的制备系统,包括陈化槽、卸料管道、传输管道、打料泵、反应釜和如前所述的镍钴锰前驱体的过滤装置,所述反应釜通过所述卸料管道与所述入料口连接,所述陈化槽与所述出料口连接,所述陈化槽通过所述传输管道与所述反应釜连接,所述打料泵设置在所述传输管道上,用于将所述陈化槽中的物料泵送至所述反应釜中。In order to achieve the same purpose, the present application also provides a preparation system for a nickel-cobalt-manganese precursor, comprising an aging tank, a discharge pipe, a transmission pipe, a feed pump, a reactor and a filtering device for the nickel-cobalt-manganese precursor as described above, wherein the reactor is connected to the feed inlet via the discharge pipe, the aging tank is connected to the discharge port, the aging tank is connected to the reactor via the transmission pipe, and the feed pump is arranged on the transmission pipe for pumping the material in the aging tank into the reactor.
在一些实施例中,还包括冲洗装置和废物槽,所述罐体的侧壁上 还具有正洗口、反洗口、排渣口和排渣管道,所述正洗口和所述排渣口间隔设置在所述进料腔的侧壁上,且与所述进料腔相连通,所述反洗口设置在所述出料腔的侧壁上,且与所述出料腔相连通,所述排渣管道与所述出料口连接,且与所述出料腔相连通,所述正洗口与所述反洗口分别于所述冲洗装置连接,所述排渣口和所述排渣管道分别与所述废物槽连接。In some embodiments, a flushing device and a waste tank are also included, and the side wall of the tank body is It also has a forward wash port, a backwash port, a slag discharge port and a slag discharge pipe. The forward wash port and the slag discharge port are arranged at intervals on the side wall of the feed chamber and are connected to the feed chamber. The backwash port is arranged on the side wall of the discharge chamber and is connected to the discharge chamber. The slag discharge pipe is connected to the discharge port and is connected to the discharge chamber. The forward wash port and the backwash port are respectively connected to the flushing device, and the slag discharge port and the slag discharge pipe are respectively connected to the waste tank.
在一些实施例中,所述镍钴锰前驱体的过滤装置还包括正洗阀、反洗阀、第一排渣阀和第二排渣阀,所述正洗阀设置在所述正洗口上,所述反洗阀设置在所述反洗口上,所述第一排渣阀设置在所述排渣口上,所述第二排渣阀设置在所述排渣管道上。In some embodiments, the filtering device of the nickel-cobalt-manganese precursor also includes a forward wash valve, a backwash valve, a first slag discharge valve and a second slag discharge valve. The forward wash valve is arranged on the forward wash port, the backwash valve is arranged on the backwash port, the first slag discharge valve is arranged on the slag discharge port, and the second slag discharge valve is arranged on the slag discharge pipe.
在一些实施例中,所述镍钴锰前驱体的过滤装置还包括正洗管路和反洗管路,所述正洗管路安装在所述正洗口,且朝向所述滤网延伸,所述反洗管路安装在所述反洗口,且朝向所述滤网延伸。In some embodiments, the filtering device of the nickel-cobalt-manganese precursor further includes a forward wash pipeline and a back wash pipeline, wherein the forward wash pipeline is installed at the forward wash port and extends toward the filter screen, and the back wash pipeline is installed at the back wash port and extends toward the filter screen.
在一些实施例中,包括多个所述反应釜和多个卸料阀,所述卸料管道具有多个支路,多个所述反应釜分别与多个所述支路连接,多个所述卸料阀分别设置在多个所述支路上。In some embodiments, it includes a plurality of the reaction kettles and a plurality of discharge valves, the discharge pipeline has a plurality of branches, the plurality of the reaction kettles are respectively connected to the plurality of branches, and the plurality of the discharge valves are respectively arranged on the plurality of branches.
在一些实施例中,还包括两个搅拌装置,两个所述搅拌装置分别设置在所述反应釜和所述陈化槽中。In some embodiments, two stirring devices are further included, and the two stirring devices are respectively arranged in the reaction kettle and the aging tank.
在一些实施例中,还包括两个液位测量装置,两个所述液位测量装置分别设置在所述应釜和所述陈化槽中。In some embodiments, two liquid level measuring devices are further included, and the two liquid level measuring devices are respectively arranged in the reactor and the aging tank.
在一些实施例中,还包括控制装置,所述过滤进阀、所述过滤出阀和所述打料泵分别与所述控制装置电连接。In some embodiments, a control device is further included, and the filter inlet valve, the filter outlet valve and the feed pump are electrically connected to the control device respectively.
本申请实施例一种镍钴锰前驱体的过滤装置及制备系统与相关技术相比,其有益效果在于:该系统通过在反应釜与陈化槽之间增设镍钴锰前驱体的过滤装置,当出现异常情况时,打开过滤进阀和过滤出阀,使反应釜中的异常物料依次经过除铁器和滤网,由除铁器吸附磁性异物,由滤网将异物和大块物料拦截,过滤后的物料再进入到陈化槽中陈化,检修完反应釜后,再由打料泵将物料从陈化槽中泵送之反 应釜中,整个过程不仅能够将镍钴锰前驱体的异物高效分离和回收,并且还能够减少反应釜异常时重开浪费的时间。Compared with the related art, the filtering device and preparation system of the nickel-cobalt-manganese precursor of the embodiment of the present application has the following beneficial effects: the system adds a filtering device of the nickel-cobalt-manganese precursor between the reactor and the aging tank. When an abnormal situation occurs, the filter inlet valve and the filter outlet valve are opened to make the abnormal material in the reactor pass through the iron remover and the filter screen in turn, the iron remover absorbs the magnetic foreign matter, the filter screen intercepts the foreign matter and the bulk material, the filtered material enters the aging tank for aging, and after the reactor is repaired, the material is pumped out of the aging tank by the feed pump. In the reactor, the whole process can not only efficiently separate and recover foreign matter from the nickel-cobalt-manganese precursor, but also reduce the time wasted in reopening the reactor when an abnormality occurs.
图1是本申请实施例的所述镍钴锰前驱体的过滤装置的主体结构示意图;FIG1 is a schematic diagram of the main structure of the filtering device for the nickel-cobalt-manganese precursor according to an embodiment of the present application;
图2是本申请实施例的所述镍钴锰前驱体的过滤装置的内部结构示意图;FIG2 is a schematic diagram of the internal structure of the filtering device for the nickel-cobalt-manganese precursor according to an embodiment of the present application;
图3是本申请实施例的所述镍钴锰前驱体的过滤装置的爆炸图;FIG3 is an exploded view of the filtering device of the nickel-cobalt-manganese precursor according to an embodiment of the present application;
图4是本申请实施例的所述镍钴锰前驱体的制备系统主体结构示意图。FIG4 is a schematic diagram of the main structure of the system for preparing the nickel-cobalt-manganese precursor according to an embodiment of the present application.
图中,1、镍钴锰前驱体的过滤装置;11、罐体;111、入料口;112、出料口;113、进料腔;114、出料腔;115、安装口;116、顶盖;117、罐身;1171、正洗口;1172、反洗口;1173、排渣口;1174、排渣管道;1175、正洗管路;1176、反洗管路;118、观察窗;119、入料罩;12、滤网;13、除铁器;131、磁棒;132、钢套;133、安装板;134、连接件;14、过滤进阀;15、过滤出阀;16、正洗阀;17、反洗阀;18、第一排渣阀;19、第二排渣阀;2、陈化槽;3、卸料管道;4、传输管道;5、打料泵;6、反应釜;7、冲洗装置;8、废物槽;9、卸料阀;10、搅拌装置;X、第一方向。In the figure, 1. Filter device for nickel-cobalt-manganese precursor; 11. Tank body; 111. Feed inlet; 112. Discharge outlet; 113. Feed chamber; 114. Discharge chamber; 115. Installation port; 116. Top cover; 117. Tank body; 1171. Forward wash inlet; 1172. Backwash inlet; 1173. Slag discharge port; 1174. Slag discharge pipeline; 1175. Forward wash pipeline; 1176. Backwash pipeline; 118. Observation window; 119. Feed cover; 12. Filter; 13. Iron remover; 131. Magnetic rod; 132. Steel sleeve; 133. Mounting plate; 134. Connector; 14. Filter inlet valve; 15. Filter outlet valve; 16. Forward wash valve; 17. Backwash valve; 18. First slag discharge valve; 19. Second slag discharge valve; 2. Aging tank; 3. Discharge pipeline; 4. Transmission pipeline; 5. Feed pump; 6. Reactor; 7. Flushing device; 8. Waste tank; 9. Discharge valve; 10. Stirring device; X, first direction.
下面结合附图和实施例,对本申请的具体实施方式作进一步详细描述。以下实施例用于说明本申请,但不用来限制本申请的范围。The specific implementation methods of the present application are further described in detail below in conjunction with the accompanying drawings and examples. The following examples are used to illustrate the present application but are not intended to limit the scope of the present application.
在本申请的描述中,应当理解的是,本申请中采用的术语“上”“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。 In the description of the present application, it should be understood that the terms "upper", "top", "bottom", "inside", "outside", etc. used in the present application to indicate the orientation or position relationship are based on the orientation or position relationship shown in the drawings, and are only for the convenience of describing the present application and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation on the present application.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本申请的描述中,“多个”的含义是两个或两个以上,除非另有明确具体的限定。In addition, the terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of the features. In the description of this application, the meaning of "plurality" is two or more, unless otherwise clearly and specifically defined.
如图1-图3所示,本申请实施例优选实施例的一种镍钴锰前驱体的过滤装置1,包括:罐体11、滤网12、除铁器13、过滤进阀14和过滤出阀15;罐体11具有入料口111和出料口112,入料口111和出料口112分别设置在罐体11沿第一方向X的两端,过滤进阀14设置在入料口111上,过滤出阀15设置在出料口112上;滤网12可拆卸设置在罐体11的内部,且将罐体11的内部沿第一方向X分隔为进料腔113和出料腔114,其中进料腔113与入料口111连通,出料腔114与出料口112连通;除铁器13安装在罐体11的侧壁上,且位于进料腔113内。As shown in Figures 1 to 3, a filtering device 1 for a nickel-cobalt-manganese precursor of a preferred embodiment of the present application comprises: a tank body 11, a filter screen 12, an iron remover 13, a filter inlet valve 14 and a filter outlet valve 15; the tank body 11 has an inlet 111 and an outlet 112, the inlet 111 and the outlet 112 are respectively arranged at the two ends of the tank body 11 along the first direction X, the filter inlet valve 14 is arranged on the inlet 111, and the filter outlet valve 15 is arranged on the outlet 112; the filter screen 12 is detachably arranged inside the tank body 11, and divides the inside of the tank body 11 into a feed chamber 113 and a discharge chamber 114 along the first direction X, wherein the feed chamber 113 is connected to the inlet 111, and the discharge chamber 114 is connected to the discharge chamber 112; the iron remover 13 is installed on the side wall of the tank body 11, and is located in the feed chamber 113.
特别说明的是,滤网12的目数可以根据反应釜6的情况进行调整。It is particularly noted that the mesh size of the filter screen 12 can be adjusted according to the conditions of the reaction kettle 6 .
基于上述方案,该装置通过在罐体11中设置滤网12对异物和大块物料进行拦截,通过设置除铁器13对磁性异物进行吸附,进而对物料完成过滤操作。Based on the above scheme, the device intercepts foreign matter and bulk materials by setting a filter screen 12 in the tank body 11, and adsorbs magnetic foreign matter by setting an iron remover 13, thereby completing the filtering operation on the material.
如图1-图3所示,在一些实施例中,为了便于使用,除铁器13包括磁棒131和钢套132,钢套132套设于磁棒131,且钢套132安装在罐体11的侧壁上,在需要对钢套132上的磁性异物进行清理时,只需要将磁棒131从钢套132中抽出,再对钢套132进行清理即可。As shown in Figures 1 to 3, in some embodiments, for ease of use, the iron remover 13 includes a magnetic rod 131 and a steel sleeve 132. The steel sleeve 132 is sleeved on the magnetic rod 131, and the steel sleeve 132 is installed on the side wall of the tank body 11. When it is necessary to clean the magnetic foreign matter on the steel sleeve 132, it is only necessary to pull the magnetic rod 131 out of the steel sleeve 132 and then clean the steel sleeve 132.
如图2所示,在一些实施例中,为了便于使用,罐体11的侧壁上还开设安装口115,除铁器13可拆卸安装在安装口115上,当需要对除铁器13进行清理或者检查时,能够通过安装口115将除铁器13从罐体11中快速抽出。As shown in Figure 2, in some embodiments, for ease of use, an installation port 115 is further opened on the side wall of the tank body 11, and the iron remover 13 can be detachably installed on the installation port 115. When the iron remover 13 needs to be cleaned or inspected, the iron remover 13 can be quickly pulled out of the tank body 11 through the installation port 115.
如图2和图3所示,在一些实施例中,为了保证吸附效果,除铁器13包括安装板133和连接件134,除铁器具有多个磁棒131和多个钢套132,安装板133上设有多个安装孔,多个钢套132分别安装在多个安装 孔上,多个磁棒131分别设置在多个钢套132中,安装板133可拆卸安装在安装口115上,且多个磁棒131背离罐体11的一端通过连接件134连接,通过设置多个磁棒131和多个钢套132以增强对磁性异物的吸附效果,并且在进行除铁器13清理时,通过设置安装板133和连接件134,使得能够一次将多个磁棒131同时取出,提高清理效率。As shown in FIG. 2 and FIG. 3, in some embodiments, in order to ensure the adsorption effect, the iron remover 13 includes a mounting plate 133 and a connecting piece 134. The iron remover has a plurality of magnetic rods 131 and a plurality of steel sleeves 132. The mounting plate 133 is provided with a plurality of mounting holes. The plurality of steel sleeves 132 are respectively mounted on a plurality of mounting holes. On the hole, multiple magnetic bars 131 are respectively arranged in multiple steel sleeves 132, the mounting plate 133 is detachably mounted on the mounting port 115, and the ends of the multiple magnetic bars 131 facing away from the tank body 11 are connected by a connecting piece 134. By setting multiple magnetic bars 131 and multiple steel sleeves 132, the adsorption effect of magnetic foreign matter is enhanced, and when cleaning the iron remover 13, by setting the mounting plate 133 and the connecting piece 134, multiple magnetic bars 131 can be taken out at one time, thereby improving the cleaning efficiency.
如图2所示,在一些实施例中,为了便于使用,罐体11包括顶盖116和罐身117,罐身117的顶部敞开,顶盖116盖合于罐身117的顶部,入料口111设置在顶盖116上,通过将罐体11设置为便于拆装的顶盖116和罐身117,以便于对罐体11内部的结构进行拆装,并且由于针对不同的物料,需要设置不同目数的滤网12,将罐体11这样设计还便于更换滤网12。As shown in FIG. 2 , in some embodiments, for ease of use, the tank body 11 includes a top cover 116 and a tank body 117. The top of the tank body 117 is open, and the top cover 116 covers the top of the tank body 117. The feed port 111 is arranged on the top cover 116. By arranging the tank body 11 as a top cover 116 and a tank body 117 that are easy to disassemble and assemble, it is convenient to disassemble and assemble the internal structure of the tank body 11. In addition, since filters 12 with different mesh sizes need to be arranged for different materials, the tank body 11 is designed in this way to facilitate the replacement of the filter screen 12.
如图1所示,在一些实施例中,为了便于使用,罐体11的顶部还开设有观察窗118,观察窗118用于观察罐体11的内部情况,并且还能够通过观察窗118将异物取出进行分析,以便于确认反应釜6的问题所在。As shown in FIG. 1 , in some embodiments, for ease of use, an observation window 118 is provided on the top of the tank body 11 . The observation window 118 is used to observe the internal condition of the tank body 11 , and foreign matter can be removed through the observation window 118 for analysis to confirm the problem with the reactor 6 .
如图3所示,在一些实施例中,为了提高除铁器13的吸附效果,罐体11还包括入料罩119,入料罩119呈喇叭状,且入料罩119口径小的一端安装在入料口111,且与入料口111连通,入料罩119口径大的一端罩在除铁器13的上方,以增大与除铁器13的对应面积。As shown in Figure 3, in some embodiments, in order to improve the adsorption effect of the iron remover 13, the tank body 11 also includes a feed cover 119, which is trumpet-shaped, and the end of the feed cover 119 with a small diameter is installed on the feed port 111 and connected to the feed port 111, and the end of the feed cover 119 with a large diameter is covered above the iron remover 13 to increase the corresponding area with the iron remover 13.
如图4所示,本申请实施例优选实施例的一种镍钴锰前驱体的制备系统,包括陈化槽2、卸料管道3、传输管道4、打料泵5、反应釜6和如前的镍钴锰前驱体的过滤装置1,反应釜6通过卸料管道3与入料口111连接,陈化槽2与出料口112连接,陈化槽2通过传输管道4与反应釜6连接,打料泵5设置在传输管道4上,用于将陈化槽2中的物料泵送至反应釜6中。As shown in Figure 4, a preparation system of a nickel-cobalt-manganese precursor of a preferred embodiment of the present application includes an aging tank 2, a discharge pipe 3, a transmission pipe 4, a feed pump 5, a reactor 6 and a filtering device 1 for the nickel-cobalt-manganese precursor as described above, the reactor 6 is connected to the feed inlet 111 through the discharge pipe 3, the aging tank 2 is connected to the discharge port 112, the aging tank 2 is connected to the reactor 6 through the transmission pipe 4, and the feed pump 5 is arranged on the transmission pipe 4, for pumping the material in the aging tank 2 into the reactor 6.
基于上述方案,该系统通过在反应釜6与陈化槽2之间增设镍钴锰前驱体的过滤装置1,当出现异常情况时,打开过滤进阀14和过滤出阀15,使反应釜6中的异常物料依次经过除铁器13和滤网12,由除铁器13吸附磁性异物,由滤网12将异物和大块物料拦截,过滤后的物料再进 入到陈化槽2中陈化,检修完反应釜6后,再由打料泵5将物料从陈化槽2中泵送之反应釜6中,整个过程不仅能够将镍钴锰前驱体的异物高效分离和回收,并且还能够减少反应釜6异常时重开浪费的时间。Based on the above scheme, the system adds a filtering device 1 of the nickel-cobalt-manganese precursor between the reactor 6 and the aging tank 2. When an abnormal situation occurs, the filter inlet valve 14 and the filter outlet valve 15 are opened, so that the abnormal material in the reactor 6 passes through the iron remover 13 and the filter screen 12 in sequence, the iron remover 13 absorbs the magnetic foreign matter, and the filter screen 12 intercepts the foreign matter and bulk materials, and the filtered material enters The material is put into the aging tank 2 for aging. After the reactor 6 is repaired, the material is pumped from the aging tank 2 to the reactor 6 by the material pump 5. The whole process can not only efficiently separate and recover the foreign matter of the nickel-cobalt-manganese precursor, but also reduce the time wasted in reopening the reactor 6 when it is abnormal.
如图1-图4所示,在一些实施例中,为了便于对镍钴锰前驱体的过滤装置1进行维护,还包括冲洗装置7和废物槽8,罐体11的侧壁上还具有正洗口1171、反洗口1172、排渣口1173和排渣管道1174,正洗口1171和排渣口1173间隔设置在进料腔113的侧壁上,且与进料腔113相连通,所述反洗口1172设置在出料腔114的侧壁上,且与所述出料腔114相连通,所述排渣管道1174与罐体11的出料口112连接,且与出料腔114相连通,正洗口1171与反洗口1172分别与冲洗装置7连接,排渣口1173和排渣管道1174分别与废物槽8连接。As shown in Figures 1 to 4, in some embodiments, in order to facilitate the maintenance of the filtering device 1 of the nickel-cobalt-manganese precursor, a flushing device 7 and a waste tank 8 are also included. The side wall of the tank body 11 is also provided with a forward wash port 1171, a backwash port 1172, a slag discharge port 1173 and a slag discharge pipe 1174. The forward wash port 1171 and the slag discharge port 1173 are arranged at intervals on the side wall of the feed chamber 113 and are connected to the feed chamber 113. The backwash port 1172 is arranged on the side wall of the discharge chamber 114 and is connected to the discharge chamber 114. The slag discharge pipe 1174 is connected to the discharge port 112 of the tank body 11 and is connected to the discharge chamber 114. The forward wash port 1171 and the backwash port 1172 are respectively connected to the flushing device 7, and the slag discharge port 1173 and the slag discharge pipe 1174 are respectively connected to the waste tank 8.
如图1-图4,为了便于操作,镍钴锰前驱体的过滤装置1还包括正洗阀16、反洗阀17、第一排渣阀18和第二排渣阀19,正洗阀16设置在正洗口1171上,反洗阀17设置在反洗口1172上,第一排渣阀18设置在排渣口1173上,第二排渣阀19设置在排渣管道1174上。As shown in Figures 1 to 4, for ease of operation, the filtering device 1 of the nickel-cobalt-manganese precursor also includes a forward wash valve 16, a backwash valve 17, a first slag discharge valve 18 and a second slag discharge valve 19. The forward wash valve 16 is arranged on the forward wash port 1171, the backwash valve 17 is arranged on the backwash port 1172, the first slag discharge valve 18 is arranged on the slag discharge port 1173, and the second slag discharge valve 19 is arranged on the slag discharge pipe 1174.
在一些实施例中,为了提高对滤网12的冲洗效果,镍钴锰前驱体的过滤装置1还包括正洗管路1175和反洗管路1176,正洗管路1175安装在正洗口1171,且朝向滤网12延伸,反洗管路1176安装在反洗口,且朝向滤网12延伸。In some embodiments, in order to improve the flushing effect of the filter screen 12, the filtering device 1 of the nickel-cobalt-manganese precursor also includes a forward wash pipeline 1175 and a backwash pipeline 1176. The forward wash pipeline 1175 is installed at the forward wash port 1171 and extends toward the filter screen 12. The backwash pipeline 1176 is installed at the backwash port and extends toward the filter screen 12.
如图4所示,在一些实施例中,为了便于使用,包括多个反应釜6和多个卸料阀9,卸料管道3具有多个支路,多个反应釜6分别与多个支路连接,多个卸料阀9分别设置在多个支路上。As shown in FIG. 4 , in some embodiments, for ease of use, multiple reaction kettles 6 and multiple discharge valves 9 are included, the discharge pipeline 3 has multiple branches, the multiple reaction kettles 6 are respectively connected to the multiple branches, and the multiple discharge valves 9 are respectively arranged on the multiple branches.
如图4所示,在一些实施例中,为了便于使用,还包括两个搅拌装置10,两个搅拌装置10分别设置在反应釜6和陈化槽2中,以便于反应釜6和陈化槽2中的物料能够加工的更加充分。As shown in FIG. 4 , in some embodiments, for ease of use, two stirring devices 10 are further included. The two stirring devices 10 are respectively arranged in the reaction kettle 6 and the aging tank 2 so that the materials in the reaction kettle 6 and the aging tank 2 can be processed more fully.
如图4所示,在一些实施例中,为了便于使用,还包括两个液位测量装置(附图中未示出),两个液位测量装置分别设置在反应釜6和陈化槽2中,通过液位测量装置实时监测反应釜6和陈化槽2中的液位情况。 As shown in FIG. 4 , in some embodiments, for ease of use, two liquid level measuring devices (not shown in the drawings) are further included. The two liquid level measuring devices are respectively arranged in the reactor 6 and the aging tank 2. The liquid levels in the reactor 6 and the aging tank 2 are monitored in real time by the liquid level measuring devices.
在一些实施例中,为了便于使用,还包括控制装置(附图中未示出),过滤进阀14、过滤出阀15和打料泵5分别与控制装置电连接,通过控制装置实现自动化控制。In some embodiments, for ease of use, a control device (not shown in the drawings) is also included, and the filter inlet valve 14, the filter outlet valve 15 and the feed pump 5 are electrically connected to the control device respectively, and automatic control is achieved through the control device.
在一些实施例中,所述液位测量装置、所述打料泵(5)、卸料阀(9)、搅拌装置10、所述过滤进阀(14)、所述过滤出阀(15)、正洗阀(16)、反洗阀(17)、第一排渣阀(18)、第二排渣阀(19)分别与所述控制装置电连接,通过控制装置实现自动化控制。In some embodiments, the liquid level measuring device, the feed pump (5), the discharge valve (9), the stirring device 10, the filter inlet valve (14), the filter outlet valve (15), the forward wash valve (16), the backwash valve (17), the first slag discharge valve (18), and the second slag discharge valve (19) are electrically connected to the control device, respectively, and automatic control is achieved through the control device.
本申请的工作过程为:The working process of this application is:
1、当反应釜6出现异常,并已经失控时,关掉反应釜6,并进行以下步骤:A、停机放料,打开过滤进阀14、过滤出阀15和卸料阀9,其余阀门保持关闭,反应釜6开始卸料,当反应釜6上的液位测量装置显示液位达到要求时,关闭搅拌装置10;异常物料内的磁性异物通过除铁器13时被吸附,颗粒较大的物料和异物被滤网12拦截,剩余物料流至陈化槽2,反应釜6内物料放完后,关闭卸料阀9;B、打料重启,打开反应釜6,再打开打料泵5,混合陈化后的物料被打进反应釜6;C、自动清洁,关闭过滤进阀14、过滤出阀15和卸料阀9,依次打开第一排渣阀18和正洗阀16,进行正洗操作,拦截物冲洗至废物槽8,一段时间后,关闭正洗阀16,依次打开第二排渣阀19和反洗阀17,进行反洗操作,洗液流至废物槽8,一段时间后,关闭反洗阀17、第一排渣阀18和第二排渣阀19,拦截物在废物槽8制成浆料;1. When the reactor 6 is abnormal and out of control, turn off the reactor 6 and perform the following steps: A. Stop the machine to discharge the material, open the filter inlet valve 14, filter outlet valve 15 and discharge valve 9, and keep the other valves closed. The reactor 6 starts to discharge the material. When the liquid level measuring device on the reactor 6 shows that the liquid level reaches the requirement, turn off the stirring device 10; the magnetic foreign matter in the abnormal material is adsorbed when passing through the iron remover 13, and the larger particles and foreign matter are intercepted by the filter screen 12. The remaining material flows to the aging tank 2. After the material in the reactor 6 is discharged, close the discharge valve 9; B. Restart the material feeding. , open the reactor 6, then open the material pump 5, and the mixed and aged materials are pumped into the reactor 6; C, automatic cleaning, close the filter inlet valve 14, the filter outlet valve 15 and the discharge valve 9, open the first slag discharge valve 18 and the forward washing valve 16 in turn, perform the forward washing operation, and the intercepted material is washed to the waste tank 8. After a period of time, close the forward washing valve 16, open the second slag discharge valve 19 and the backwash valve 17 in turn, perform the backwash operation, and the washing liquid flows to the waste tank 8. After a period of time, close the backwash valve 17, the first slag discharge valve 18 and the second slag discharge valve 19, and the intercepted material is made into slurry in the waste tank 8;
2、当反应釜6出现异常,还未失控时,反应釜6保持开启,并进行以下步骤:A:放料与打料同时进行,依次打开过滤进阀14、过滤出阀15、卸料阀9、打料泵5,开始循环过滤,通过控制过滤进阀14与反应釜6的开度,使反应釜6上的液位测量装置显示液位不超过一定值,反应釜6内的异常物料通过卸流管道流至陈化槽2内与其余正常反应釜6料充分混合,稀释不稳定的镍钴锰前驱体,陈化槽2内混合的镍钴锰前驱体不断打进反应釜6内,不断进行置换将反应体系调整至稳定状态,大于滤网12空隙的异物被滤网12拦截;B:自动清洁:运行一段时间后, 依次关闭打料泵5、过滤进阀14、过滤出阀15和卸料阀9,依次打开第一排渣阀18和正洗阀16,进行正洗操作,拦截物冲洗至废物槽8,一段时间后,关闭正洗阀16,依次打开第二排渣阀19和反洗阀17,进行反洗操作,洗液流至废物槽8,一段时间后,关闭反洗阀17、第一排渣阀18和第二排渣阀19;C:跳转至A步直至反应釜6内物料稳定,满足生产要求时跳转到下一步;E:除铁器13维护,取出除铁器13的磁棒131,清洁磁性异物,清洁完后再回装。2. When the reactor 6 is abnormal but has not lost control, the reactor 6 remains open and the following steps are performed: A: Discharging and punching are performed simultaneously. The filter inlet valve 14, the filter outlet valve 15, the discharge valve 9, and the punching pump 5 are opened in sequence to start circulating filtration. By controlling the opening of the filter inlet valve 14 and the reactor 6, the liquid level measuring device on the reactor 6 displays that the liquid level does not exceed a certain value. The abnormal material in the reactor 6 flows through the discharge pipe to the aging tank 2 to be fully mixed with the rest of the normal reactor 6 materials to dilute the unstable nickel-cobalt-manganese precursor. The mixed nickel-cobalt-manganese precursor in the aging tank 2 is continuously punched into the reactor 6, and the reaction system is continuously replaced to adjust the reaction system to a stable state. Foreign matter larger than the gap of the filter screen 12 is intercepted by the filter screen 12; B: Automatic cleaning: After running for a period of time, Close the feed pump 5, filter inlet valve 14, filter outlet valve 15 and discharge valve 9 in sequence, open the first slag discharge valve 18 and forward wash valve 16 in sequence, perform forward wash operation, and flush the intercepted material to the waste tank 8. After a period of time, close the forward wash valve 16, open the second slag discharge valve 19 and backwash valve 17 in sequence, perform backwash operation, and the washing liquid flows to the waste tank 8. After a period of time, close the backwash valve 17, the first slag discharge valve 18 and the second slag discharge valve 19; C: Jump to step A until the material in the reactor 6 is stable, and jump to the next step when it meets the production requirements; E: Maintain the iron remover 13, take out the magnetic rod 131 of the iron remover 13, clean the magnetic foreign matter, and reinstall it after cleaning.
综上,本申请实施例提供一种镍钴锰前驱体的过滤装置及制备系统,其通过在反应釜6与陈化槽2之间增设镍钴锰前驱体的过滤装置1,当出现异常情况时,打开过滤进阀14和过滤出阀15,使反应釜6中的异常物料依次经过除铁器13和滤网12,由除铁器13吸附磁性异物,由滤网12将异物和大块物料拦截,过滤后的物料再进入到陈化槽2中陈化,检修完反应釜6后,再由打料泵5将物料从陈化槽2中泵送之反应釜6中,重新开始制备,整个过程不仅能够将镍钴锰前驱体的异物高效分离和回收,并且还能够减少反应釜6异常时重开浪费的时间。 In summary, the embodiment of the present application provides a filtering device and preparation system for a nickel-cobalt-manganese precursor, which adds a filtering device 1 for a nickel-cobalt-manganese precursor between the reactor 6 and the aging tank 2. When an abnormal situation occurs, the filter inlet valve 14 and the filter outlet valve 15 are opened, so that the abnormal material in the reactor 6 passes through the iron remover 13 and the filter screen 12 in turn, the magnetic foreign matter is adsorbed by the iron remover 13, and the foreign matter and large pieces of material are intercepted by the filter screen 12. The filtered material then enters the aging tank 2 for aging. After the reactor 6 is overhauled, the material is pumped from the aging tank 2 to the reactor 6 by the feed pump 5, and the preparation is restarted. The whole process can not only efficiently separate and recover the foreign matter in the nickel-cobalt-manganese precursor, but also can reduce the time wasted in reopening the reactor 6 when an abnormal situation occurs.
Claims (15)
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| CN202380010963.7A CN117500603B (en) | 2023-09-25 | 2023-09-25 | A filtering device and preparation system for nickel-cobalt-manganese precursor |
| PCT/CN2023/121276 WO2025065196A1 (en) | 2023-09-25 | 2023-09-25 | Filter device and preparation system for nickel-cobalt-manganese precursor |
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| PCT/CN2023/121276 WO2025065196A1 (en) | 2023-09-25 | 2023-09-25 | Filter device and preparation system for nickel-cobalt-manganese precursor |
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| CN117500603B (en) | 2025-05-09 |
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