WO2025047405A1 - Powdery oil or fat composition, food or beverage, method for producing powdery oil or fat composition, and method for improving emulsion stability of powdery oil or fat composition - Google Patents
Powdery oil or fat composition, food or beverage, method for producing powdery oil or fat composition, and method for improving emulsion stability of powdery oil or fat composition Download PDFInfo
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- WO2025047405A1 WO2025047405A1 PCT/JP2024/028858 JP2024028858W WO2025047405A1 WO 2025047405 A1 WO2025047405 A1 WO 2025047405A1 JP 2024028858 W JP2024028858 W JP 2024028858W WO 2025047405 A1 WO2025047405 A1 WO 2025047405A1
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings or cooking oils
- A23D9/007—Other edible oils or fats, e.g. shortenings or cooking oils characterised by ingredients other than fatty acid triglycerides
- A23D9/013—Other fatty acid esters, e.g. phosphatides
Definitions
- the present invention relates to a powdered oil composition, a food or drink, a method for producing a powdered oil composition, and a method for improving the emulsion stability of a powdered oil composition.
- Powdered oils and fats in which oily components are coated with water-soluble components, are widely used as processed ingredients for coffee and tea creams, confectioneries, soups, seasonings, etc. Powdered oils and fats are produced by drying an emulsion of edible oils and fats mixed with emulsifiers and excipients. For the emulsification to produce the above emulsions, milk proteins such as casein and whey have traditionally been used.
- Patent Document 1 discloses a method for producing powdered oils and fats, which comprises adding edible oils and fats and diacetyl tartaric acid ester monoglyceride to an aqueous solution of sodium caseinate with a pH of 7 or less, emulsifying the mixture by stirring to obtain an O/W emulsion of edible oils and fats, and then powdering the O/W emulsion.
- This method stabilizes the emulsion during production and solves problems such as discoloration due to heat during powderization and unpleasant odors due to decomposition.
- Patent Document 2 discloses a powdered oil and fat composition that contains an oily component, gum arabic, and sugars, and is characterized in that the weight ratio of the oily component to gum arabic is 2:1 to 1:5, and the weight ratio of gum arabic to sugars is 5:1 to 1:100.
- This powdered oil and fat composition does not contain proteins, does not exude the oily component, and has good solubility in water.
- the object of the present invention is to provide a powdered oil and fat composition that has excellent emulsion stability and good flavor, even if it does not contain milk proteins, etc.
- the present inventors have discovered that by adding a predetermined amount of one or more polysaccharides selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides to a powdered oil composition containing sap-derived polysaccharides, the off-flavor of the sap-derived polysaccharides is suppressed and emulsion stability immediately after production and after storage is improved, thereby completing the present invention.
- a powdered fat or oil composition comprising an edible fat or oil and the following components (A) and (B): Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots [2] A food or drink comprising the powdered oil or fat composition described in [1].
- a method for producing a powdered oil-and-fat composition comprising edible oil-and-fat, component (A): a sap-derived polysaccharide, and component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides, comprising:
- the above-mentioned production method in which the powdered oil or fat composition is produced through the following steps (a) to (c): (a) obtaining a mixture of an oil phase raw material containing an edible oil and fat and an aqueous phase raw material containing component (A), component (B), water, and an excipient; (b) emulsifying the mixture to obtain an oil-in-water emulsion; and (c) drying the emulsion.
- a method for improving the emulsion stability of a powdered oil or fat composition comprising comprising containing an edible oil or fat and the following component (A) and component (B): Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots
- the powdered oil and fat composition, food and drink, method for producing a powdered oil and fat composition, and method for improving emulsion stability of a powdered oil and fat composition of the present invention will be described below.
- Each embodiment disclosed in this specification can be combined with any other feature disclosed in this specification, and a combination of preferred embodiments is a more preferred embodiment.
- the expression "X to Y" indicating a numerical range means "X or more and Y or less”.
- any upper and lower limits of these upper and lower limits can be appropriately combined to obtain a suitable numerical range, and the numerical range obtained thereby is also considered to be disclosed.
- any numerical value within the numerical range may be replaced with a numerical value shown in the examples.
- the powdered oil and fat composition, food and drink, method for producing a powdered oil and fat composition, and method for improving the emulsion stability of a powdered oil and fat composition of the present invention are not limited to the embodiments and examples described below, and various modifications are possible within the scope of the invention without impairing the features and effects.
- the explanation may be omitted in the other embodiments.
- the off-flavor in the present invention refers to an undesirable flavor derived from component (A): sap-derived polysaccharides.
- the powdered oil and fat composition contains edible oil and fat and the following components (A) and (B).
- Component (A) is a sap-derived polysaccharide.
- the sap-derived polysaccharide is a polysaccharide contained in the sap secreted from the bark.
- gum arabic, gum ghatti, gum karaya, gum tragacanth, etc. can be suitably used as the sap-derived polysaccharide, and one or more of these sap-derived thickening polysaccharides can be used.
- gum arabic or gum ghatti is preferred from the viewpoint of improving emulsion stability, and gum arabic is more preferred.
- the content of component (A) in the powdered oil composition is preferably 5% by mass or more, more preferably 8% by mass or more, even more preferably 11% by mass or more, and even more preferably 13% by mass or more, with the entire powdered oil composition being 100% by mass. Furthermore, from the viewpoint of suppressing off-flavors, the content of component (A) in the powdered oil or fat composition is, relative to 100% by mass of the entire powdered oil or fat composition, preferably 23% by mass or less, more preferably 22% by mass or less, even more preferably 21% by mass or less, even more preferably 18% by mass or less, and even more preferably 16% by mass or less.
- the content of component (A) in the powdered oil or fat composition is preferably 5% by mass or more and 23% by mass or less, more preferably 8% by mass or more and 22% by mass or less, even more preferably 11% by mass or more and 21% by mass or less, still more preferably 13% by mass or more and 18% by mass or less, and even more preferably 13% by mass or more and 16% by mass or less, taking the total powdered oil or fat composition as 100% by mass.
- the ratio of edible oil to component (A) in the powdered oil composition is preferably 1.3 or more and 4.0 or less in mass ratio, more preferably 1.5 or more and 4.0 or less in mass ratio, even more preferably 1.8 or more and 4.0 or less in mass ratio, even more preferably 1.8 or more and 3.5 or less in mass ratio, even more preferably 1.9 or more and 3.1 or less in mass ratio, and particularly preferably 2.3 or more and 2.8 or less in mass ratio.
- Component (B) is one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides.
- plant seed-derived polysaccharides include tamarind seed gum, guar gum, locust bean gum, etc.
- examples of fruit-derived polysaccharides include fruit-derived pectin, cellulose, etc.
- examples of plant root-derived polysaccharides include sugar beet pectin and konjac mannan, etc.
- component (B) does not contain starch.
- Component (B) in this embodiment is preferably one or more selected from the group consisting of tamarind seed gum, guar gum, locust bean gum, and pectins such as fruit-derived pectin and sugar beet pectin, more preferably one or two selected from the group consisting of tamarind seed gum and fruit-derived pectin, and even more preferably tamarind seed gum.
- pectins such as fruit-derived pectin and sugar beet pectin
- pectins such as fruit-derived pectin and sugar beet pectin
- the content of component (B) in the powdered oil composition is preferably 0.1 mass % or more, more preferably 0.3 mass % or more, and even more preferably 0.4 mass % or more, with the total powdered oil composition being 100 mass %.
- the content of component (B) in the powdered oil composition is preferably 4 mass% or less, more preferably 2 mass% or less, even more preferably 1.5 mass% or less, and even more preferably 1.2 mass% or less, taking the entire powdered oil composition as 100 mass%.
- the content of component (B) in the powdered oil composition is preferably 0.1 mass % or more and 4 mass % or less, more preferably 0.1 mass % or more and 2 mass % or less, even more preferably 0.3 mass % or more and 1.5 mass % or less, and even more preferably 0.4 mass % or more and 1.2 mass % or less, taking the entire powdered oil composition as 100 mass %.
- the ratio of component (B) to the total of component (A) and component (B) in the powdered oil composition is preferably from the viewpoint of improving emulsion stability and suppressing off-flavors a mass ratio of 0.010 to 0.200, more preferably from the viewpoint of 0.010 to 0.150, even more preferably from the viewpoint of 0.015 to 0.130, even more preferably from the viewpoint of 0.020 to 0.095, and even more preferably from the viewpoint of 0.025 to 0.080.
- the powdered oil and fat composition of the present invention contains edible oil and fat.
- the edible oil and fat in this embodiment is not limited and may be appropriately selected.
- vegetable oils and fats such as rapeseed oil, soybean oil, palm oil, corn oil, linseed oil, perilla oil, safflower oil, sunflower oil, cottonseed oil, rice oil, peanut oil, shea fat, monkey fat, cacao butter, palm kernel oil, coconut oil, grape seed oil, macadamia nut oil, coconut oil, and evening primrose oil; animal oils and fats such as beef tallow, lard, milk fat, chicken oil, and fish oil; and synthetic oils and fats such as medium-chain fatty acid triglycerides.
- the edible oils and fats preferably contain one or more selected from the group consisting of rapeseed oil, soybean oil, palm oil, corn oil, palm kernel oil, and coconut oil, more preferably contain one or more selected from the group consisting of palm oil, palm kernel oil, and coconut oil, and even more preferably contain palm olein.
- the powdered oil-and-fat composition of the present invention may contain seasoning oil and flavor-improving oil in the edible oil-and-fat.
- the seasoning oil in this embodiment includes oil-and-fat that has been scented with spices, flavorings, etc., oil-and-fat that has been flavored by extracting some component, oil-and-fat that has been processed in some way, and also includes edible oil-and-fat that itself has a flavor, such as sesame oil.
- the flavor-enhancing oil refers to an edible fat and oil composition that has the functionality of improving the taste, aroma, umami, richness, and other flavors or masking unusual flavors when added to food.
- seasoning oils include flavor oils such as butter flavor oil, lemon flavor oil, almond flavor oil, and vanilla flavor oil; flavored edible oils and fats that have a fragrance themselves as extracted oils and fats, such as sesame oil, olive oil, almond oil, peanut oil, and roasted rapeseed oil; oils and fats flavored with aromatic vegetables or spices, such as chili oil, green onion oil, ginger oil, and garlic oil; flavored oils imparted with flavor by subjecting oils and fats to treatments such as heating and hydrogenation; grill oils and charcoal grilled flavor oils that impart a grilled meat flavor, and flavor-enhancing oils and fats include oils and fats containing n-6 fatty acids, which will be described later, and oils and fats containing oxidized oils, which will be described later.
- the powdered oil and fat of the present invention preferably contains, in the edible oil and fat, one or more selected from the group consisting of seasoning oils and flavor-enhancing oils, more preferably one or more selected from the group consisting of flavor oils, flavored edible oils and fats, oils and fats containing n-6 fatty acids, and oils and fats containing oxidized oils and fats, even more preferably one or more selected from the group consisting of lemon flavor oil, olive oil, sesame oil, oils and fats containing n-6 fatty acids, and oils and fats containing oxidized oils and fats, even more preferably one or more selected from the group consisting of olive oil, sesame oil, oils and fats containing n-6 fatty acids, and oils and fats containing oxidized oils and fats, even more preferably one or more selected from the group consisting of olive oil, sesame oil, oils and fats containing n-6 fatty acids, and oils and fats containing oxidized oils and fats, even more preferably one or more
- the lower limit of the content of the seasoning oil in the edible oil or fat is preferably 5% by mass or more, more preferably 10% by mass or more, even more preferably 20% by mass or more, still more preferably 30% by mass or more, even more preferably 50% by mass or more, and particularly preferably 80% by mass or more, based on 100% by mass of the entire edible oil or fat.
- the upper limit of the content of the seasoning oil in the edible oil or fat is 100% by mass or less, and may be 99.5% by mass or less, 99% by mass or less, 98% by mass or less, etc., based on 100% by mass of the entire edible oil or fat.
- the content of the seasoning oil in the edible oil is, relative to 100% by mass of the entire edible oil, preferably 5% by mass or more and 100% by mass or less, more preferably 10% by mass or more and 99.5% by mass or less, even more preferably 20% by mass or more and 99% by mass or less, still more preferably 30% by mass or more and 98% by mass or less, even more preferably 50% by mass or more and 98% by mass or less, and particularly preferably 80% by mass or more and 98% by mass or less.
- the lower limit of the content of the flavor-enhancing oil in the edible oil or fat is preferably 0.1 mass% or more, more preferably 0.2 mass% or more, even more preferably 0.4 mass% or more, still more preferably 1 mass% or more, and even more preferably 2 mass% or more, based on 100 mass% of the total edible oil or fat.
- the upper limit of the content of the flavor-enhancing oil in the edible oil or fat is preferably 100% by mass or less, more preferably 60% by mass or less, even more preferably 40% by mass or less, even more preferably 20% by mass or less, even more preferably 10% by mass or less, and particularly preferably 6% by mass or less, based on 100% by mass of the entire edible oil or fat.
- the content of the flavor-enhancing oil in the edible oil is, relative to 100% by mass of the entire edible oil, preferably 0.1% by mass or more and 100% by mass or less, more preferably 0.2% by mass or more and 60% by mass or less, even more preferably 0.4% by mass or more and 40% by mass or less, still more preferably 1% by mass or more and 20% by mass or less, even more preferably 2% by mass or more and 10% by mass or less, and particularly preferably 2% by mass or more and 6% by mass or less.
- the content of edible oils and fats in the powdered oil composition is preferably 15% by mass or more, more preferably 20% by mass or more, even more preferably 22% by mass or more, still more preferably 25% by mass or more, and even more preferably 28% by mass or more, taking the total powdered oil and fat composition as 100% by mass.
- the content of edible oils and fats in the powdered oil and fat composition is preferably 70% by mass or less, more preferably 65% by mass or less, even more preferably 60% by mass or less, still more preferably 55% by mass or less, even more preferably 50% by mass or less, and particularly preferably 45% by mass or less, taking the entire powdered oil and fat composition as 100% by mass.
- the content of edible oils and fats in the powdered oil composition is, with the entire powdered oil and fat composition being 100% by mass, preferably 15% by mass or more and 70% by mass or less, more preferably 20% by mass or more and 65% by mass or less, even more preferably 22% by mass or more and 60% by mass or less, still more preferably 25% by mass or more and 55% by mass or less, even more preferably 28% by mass or more and 50% by mass or less, and particularly preferably 28% by mass or more and 45% by mass or less.
- the edible fats and oils preferably include fats and oils containing at least one selected from the group consisting of n-6 long-chain highly unsaturated fatty acids and esters thereof (hereinafter sometimes referred to as "n-6 fatty acids, etc.”) (hereinafter sometimes referred to as "fat and oil containing n-6 fatty acids, etc.”).
- n-6 long-chain highly unsaturated fatty acid means a fatty acid having 18 or more carbon atoms and 3 or more double bonds.
- a long-chain highly unsaturated fatty acid having 20 to 24 carbon atoms and 4 to 6 double bonds is preferred.
- Examples of n-6 long-chain highly unsaturated fatty acids include arachidonic acid (AA) and docosatetraenoic acid (DTA), with arachidonic acid being preferred.
- Esters of n-6 long-chain highly unsaturated fatty acids include glycerol fatty acid esters, sucrose fatty acid esters, organic acid fatty acid esters, fatty acid alcohol esters, sphingolipids, sorbitan fatty acid esters, polypropylene fatty acid esters, sterol esters, etc., all of which contain n-6 long-chain highly unsaturated fatty acids. Of these, glycerol fatty acid esters are preferred.
- Glycerol fatty acid esters are esters that have glycerol as a constituent component, and specific examples include triacylglycerol (triglyceride), diacylglycerol (diglyceride), monoacylglycerol (monoglyceride), glycerophospholipid, and glyceroglycolipid.
- the above ester is preferably triacylglycerol.
- n-6 fatty acids, etc. there are no particular limitations on the origin of n-6 fatty acids, etc., and those obtained from various animals and plants, microorganisms, algae, etc. are commercially available, and those skilled in the art can use these known ones as appropriate.
- One type of n-6 fatty acid, etc. may be used alone, or multiple types may be used in combination.
- the fats and oils containing n-6 fatty acids and the like may be those that have been subjected to an oxidation treatment (oxidation-treated product).
- oxidation-treated product an oxidation treatment
- the peroxide value (hereinafter sometimes referred to as "POV") is used as an index of the degree of oxidation
- edible oils and fats generally available on the market have a peroxide value of about 0 to 10, and it is preferable that the peroxide value is increased to about 15 to 350.
- the range of the peroxide value may be 20 to 300, 30 to 270, 40 to 250, or 60 to 200.
- the peroxide value (POV) can be measured in accordance with "Standard Methods for the Analysis of Fats, Oils and Related Materials 2.5.2 Peroxide Value" (Japan Oil Chemists' Society).
- a preferred method is a heat treatment method.
- a heating means such as an electric heater, direct flame burner, microwave, steam, or hot air heater attached to the container.
- the conditions for the heat treatment but it is preferable to heat at 40°C to 200°C for 0.1 to 240 hours, and more preferably to heat at 80°C to 180°C for 0.5 to 72 hours.
- oxygen may be supplied by introducing oxygen from the open space of the container by stirring or by blowing oxygen in (e.g., bubbling). Air may be used as the oxygen source. This promotes the oxidation of the oils and fats containing the n-6 fatty acids and the like.
- the amount of oxygen supplied is preferably in the range of 0.001 L/min to 2 L/min per 1 kg of the oil and fat.
- the range is preferably 0.005 L/min to 10 L/min per 1 kg of the oil and fat, and more preferably 0.01 L/min to 5 L/min.
- the content of the oil or fat containing n-6 fatty acids, etc. in the powdered oil or fat composition is preferably 0.05% by mass or more, more preferably 0.08% by mass or more, even more preferably 0.1% by mass or more, and still more preferably 0.13% by mass or more, based on 100% by mass of the entire powdered oil or fat composition.
- the content of the oil or fat containing n-6 fatty acids and the like in the powdered oil or fat composition is, relative to 100% by mass of the entire powdered oil or fat composition, preferably 20% by mass or less, more preferably 10% by mass or less, even more preferably 5% by mass or less, still more preferably 2% by mass or less, even more preferably 1% by mass or less, particularly preferably 0.6% by mass or less, and especially preferably 0.4% by mass or less. That is, when the edible oil or fat contains an oil or fat containing n-6 fatty acids, etc., the content of the oil or fat containing n-6 fatty acids, etc.
- the powdered oil or fat composition is, based on 100% by mass of the entire powdered oil or fat composition, preferably from 0.05% by mass to 20% by mass, more preferably from 0.05% by mass to 10% by mass, even more preferably from 0.08% by mass to 5% by mass, still more preferably from 0.08% by mass to 2% by mass, still more preferably from 0.1% by mass to 1% by mass, particularly preferably from 0.1% by mass to 0.6% by mass, and especially preferably from 0.13% by mass to 0.4% by mass.
- the powdered oil-and-fat composition of the present invention may contain, in the edible oil-and-fat, oxidized oil-and-fat which is an oxidation product of one or more kinds of oil-and-fat selected from the group consisting of palm-based oil-and-fat and sunflower oil having a total content of ⁇ -carotene and ⁇ -carotene of 50 ppm by mass or more and 2000 ppm by mass or less, and preferably contains oxidized oil-and-fat which is an oxidation product of palm-based oil-and-fat having a total content of ⁇ -carotene and ⁇ -carotene of 50 ppm by mass or more and 2000 ppm by mass or less.
- the palm-based oil used in the oxidized oil may be any palm-based oil obtained from the fruit of the oil palm, and may be one that has been subjected to treatments such as molecular distillation, fractionation, degumming, deacidification, bleaching, and deodorization.
- the method of each treatment is not particularly limited, and methods that are usually used in the processing and refining of oils and fats can be adopted.
- the total content of ⁇ -carotene and ⁇ -carotene in the palm-based oil is 50 ppm by mass or more and 2000 ppm by mass or less, preferably 50 ppm by mass or more and 1500 ppm by mass or less, more preferably 50 ppm by mass or more and 1000 ppm by mass or less, and even more preferably 50 ppm by mass or more and 800 ppm by mass or less.
- the palm-based oil may be one type having a total content of ⁇ -carotene and ⁇ -carotene in the above range, or two or more types may be mixed and used so as to obtain the total content.
- the ⁇ -carotene and ⁇ -carotene contents in fats and oils can be measured by the method described in the Examples section or a method that will be understood by those skilled in the art to be equivalent thereto.
- the sunflower oil used for the oxidized oil is not particularly limited, but the proportion of oleic acid in the total amount of constituent fatty acids is preferably 70% by mass or more and 100% by mass or less, more preferably 75% by mass or more and 95% by mass or less, and even more preferably 80% by mass or more and 90% by mass or less.
- the sunflower oil has been subjected to a refining process.
- the content of oleic acid in the total amount of constituent fatty acids can be measured in accordance with the method described in "Standard Methods for the Analysis of Fats, Oils and Related Materials 2.5.23-2013 Fatty Acid Composition (Capillary Gas Chromatography Method)" (Japan Oil Chemists' Society).
- the oxidized oil or fat in the present invention is an oxidation product obtained by oxidizing one or more oils or fats selected from the group consisting of palm-based oils and sunflower oils, and the peroxide value (hereinafter sometimes referred to as "POV") is preferably 15 to 300, more preferably 25 to 290, even more preferably 40 to 270, and even more preferably 45 to 250.
- the peroxide value can be measured in accordance with the method described in "Standard Methods for the Analysis of Fats, Oils, and Related Materials 2.5.2 Peroxide Value" (Japan Oil Chemists' Society).
- the method for obtaining oxidized fats and oils may be any method capable of oxidizing palm-based fats and sunflower oil to bring the peroxide value within the above range, and is not limited thereto, but examples thereof include heat treatment. More specifically, from the viewpoint of industrial-scale production, it is preferable to place the raw fats and oils in a container such as a tank, and then heat treat the raw fats and oils using a heating means such as an electric heater, direct flame burner, microwave, steam, or hot air heater provided in the container.
- a heating means such as an electric heater, direct flame burner, microwave, steam, or hot air heater provided in the container.
- the conditions for the heat treatment are not limited, but are typically performed at a heating temperature of 50°C to 220°C for a heating time of 0.1 to 240 hours, and more typically at a heating temperature of 60°C to 160°C for a heating time of 1 to 100 hours.
- heating treatment is typically performed with an integrated amount of 200 to 20,000, more typically with an integrated amount of 220 to 18,000, and even more typically with an integrated amount of 240 to 15,000.
- the integrated amount of heating temperature (°C) x heating time (hours) can be calculated as heating temperature (°C) before the temperature change x heating time (hours) before the temperature change + heating temperature (°C) after the temperature change x heating time (hours) after the temperature change, or the integral value of the heating temperature (°C) over the heating time (hours).
- oxygen air
- oxygen air
- the oxygen source may be air, etc. This promotes the oxidation of the raw material oils and fats.
- the oxygen supply rate is preferably 0.001 to 2 L/min per 1 kg of raw oils and fats.
- the supply rate is 0.005 to 10 L/min per 1 kg of raw oils and fats, and 0.01 to 5 L/min is more preferable.
- the content of the oxidized oil/fat in the powdered oil/fat composition is preferably 0.1 mass% or more, more preferably 0.2 mass% or more, even more preferably 0.5 mass% or more, still more preferably 0.7 mass% or more, and even more preferably 0.9 mass% or more, based on 100 mass% of the entire powdered oil/fat composition.
- the content of oxidized oils and fats in the powdered oil and fat composition is preferably 5 mass % or less, more preferably 3 mass % or less, even more preferably 2 mass % or less, even more preferably 1.5 mass % or less, and even more preferably 1.2 mass % or less, taking the entire powdered oil and fat composition as 100 mass %.
- the content thereof is, relative to 100 mass% of the entire powdered oil or fat composition, preferably from 0.1 mass% to 5 mass%, more preferably from 0.2 mass% to 3 mass%, even more preferably from 0.5 mass% to 2 mass%, still more preferably from 0.7 mass% to 1.5 mass%, and even more preferably from 0.9 mass% to 1.2 mass%.
- the powdered oil or fat composition preferably contains an excipient.
- the excipient mainly coats the oily component to form the powdered oil and prevents the oily component from bleeding out.
- excipients are not limited, and those usually used in producing powdered oil can be used.
- sugars such as starch (starch octenyl succinate, etc.), starch syrup, powdered syrup, sucrose, glucose, maltose, lactose, fructose, galactose, trehalose, dextrin, sodium alginate, and carrageenan; sugar alcohols such as erythritol, sorbitol, mannitol, maltitol, lactitol, palatinit, and reduced starch syrup; wheat flour; proteins such as gelatin, acid casein, and sodium caseinate; and thickeners such as xanthan gum (excluding those contained in components (A) and (B)).
- the excipients may be used alone or in combination of two or more.
- the above-mentioned excipient is preferably one or more types selected from the group consisting of starch, sugars, thickeners and proteins, more preferably one or more types selected from the group consisting of starch octenyl succinate, corn syrup and dextrin, even more preferably one or two types selected from the group consisting of dextrin and starch octenyl succinate, and even more preferably dextrin.
- the powdered oil and fat composition of the present invention may contain milk proteins, particularly casein and its salts, but casein is an allergenic substance, so it is preferable not to add it from the viewpoint of allergen-free.
- the present invention is advantageous in that good emulsion stability can be achieved without including casein or its salts. Note that the present invention does not exclude embodiments that contain casein or its salts.
- the average molecular weight of the saccharide is preferably 400 or more and 20,000 or less, and more preferably 500 or more and 15,000 or less.
- the dextrose equivalent (DE) of the above sugars is preferably 5 or more and 50 or less, more preferably 7 or more and 40 or less, even more preferably 10 or more and 35 or less, even more preferably 10 or more and 30 or less, and even more preferably 11 or more and 25 or less.
- the content of the excipient in the powdered oil or fat composition is, from the viewpoint of improving emulsion stability and suppressing off-flavors, preferably 20% by mass or more, more preferably 25% by mass or more, even more preferably 30% by mass or more, even more preferably 35% by mass or more, and even more preferably 43% by mass or more, with the entire powdered oil or fat composition being 100% by mass.
- the content of the excipient in the powdered oil/fat composition is preferably 80% by mass or less, more preferably 75% by mass or less, and even more preferably 70% by mass or less, with the entire powdered oil/fat composition being 100% by mass.
- the content is preferably 20% by mass or more and 80% by mass or less, more preferably 25% by mass or more and 80% by mass or less, even more preferably 30% by mass or more and 75% by mass or less, still more preferably 35% by mass or more and 75% by mass or less, and even more preferably 43% by mass or more and 70% by mass or less, based on 100% by mass of the entire powdered oil or fat composition.
- the powdered oil composition may contain an emulsifier, but it is preferable that it does not contain one.
- the emulsifier refers to designated additives and existing additives whose main use is as an emulsifier, as stipulated in the labeling standards under the Food Sanitation Act.
- Such emulsifiers are not particularly limited as long as they are food-grade, and examples include glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, propylene glycol fatty acid esters, vegetable lecithin, egg yolk lecithin, etc.
- the powdered oil or fat composition may contain, within the scope of the invention, pH adjusters such as dipotassium hydrogen phosphate, dipotassium sulfate, trisodium citrate, and sodium hydroxide; antioxidants such as tocopherol; sweeteners other than the above-mentioned excipients; stabilizers; flavorings; colorants; calcium carbonate, titanium dioxide, etc.
- pH adjusters such as dipotassium hydrogen phosphate, dipotassium sulfate, trisodium citrate, and sodium hydroxide
- antioxidants such as tocopherol
- sweeteners other than the above-mentioned excipients such as tocopherol
- sweeteners other than the above-mentioned excipients
- stabilizers such as tocopherol
- flavorings such as tocopherol
- colorants such as calcium carbonate, titanium dioxide, etc.
- the powdered oil or fat composition of the present invention preferably contains an antioxidant.
- the antioxidant is preferably tocopherol, more preferably mixed tocopherol.
- the content of the antioxidant in the powdered oil or fat composition is, relative to 100% by mass of the entire powdered oil or fat composition, preferably from 0.01% by mass to 5% by mass, more preferably from 0.03% by mass to 4% by mass, even more preferably from 0.05% by mass to 3% by mass, and even more preferably from 0.08% by mass to 2.5% by mass.
- the powdered oil composition is preferably an oil-in-water dry emulsion type powdered oil composition.
- the oil-in-water dry emulsion type powdered oil composition refers to a powdered oil composition obtained by drying an oil-in-water emulsion. Note that full-fat type powdered oil compositions (powdered oil compositions obtained by powdering high-melting-point oils and fats by spray cooling or cooling and pulverizing) are not included in the above-mentioned oil-in-water dry emulsion type powdered oil composition.
- the median diameter of the fat globules (oil droplet globules) immediately after the production of the powdered oil or fat composition is, from the viewpoint of improving emulsion stability, preferably 8 ⁇ m or less, more preferably 6 ⁇ m or less, even more preferably 4 ⁇ m or less, even more preferably 3 ⁇ m or less, still more preferably 2.3 ⁇ m or less, particularly preferably 1.7 ⁇ m or less, and especially preferably 1.3 ⁇ m or less.
- the median diameter of the fat globules (oil droplet globules) immediately after production of the powdered oil or fat composition is preferably 0.1 ⁇ m or more, optionally 0.2 ⁇ m or more, optionally 0.3 ⁇ m or more, optionally 0.5 ⁇ m or more, or optionally 0.6 ⁇ m or more.
- the median diameter of fat globules (oil droplet globules) when the powdered oil or fat composition is stored at 60°C for one week is, from the viewpoint of improving emulsion stability, preferably 10 ⁇ m or less, more preferably 8 ⁇ m or less, even more preferably 6 ⁇ m or less, even more preferably 4 ⁇ m or less, still more preferably 3.3 ⁇ m or less, particularly preferably 2.8 ⁇ m or less, and especially preferably 2.0 ⁇ m or less.
- the median diameter of fat globules (oil droplet globules) when the powdered oil or fat composition is stored at 60°C for one week is preferably 0.1 ⁇ m or more, optionally 0.2 ⁇ m or more, optionally 0.3 ⁇ m or more, optionally 0.4 ⁇ m or more, optionally 0.6 ⁇ m or more, or optionally 0.9 ⁇ m or more.
- the change ratio of the median diameter of fat globules (oil droplet globules) when the powdered oil or fat composition is stored at 60°C for one week is, from the viewpoint of improving emulsion stability, preferably 2.00 or less, more preferably 1.80 or less, even more preferably 1.60 or less, even more preferably 1.50 or less, and even more preferably 1.40 or less.
- the change ratio after storage at 60°C can be determined as the ratio of the median diameter of fat globules (oil droplet globules) when the powdered oil composition is stored at 60°C for one week to the median diameter of fat globules (oil droplet globules) immediately after production, and it can be said that the smaller the change ratio, the better the emulsion stability after storage. Therefore, the lower limit of the change ratio after storage at 60°C is 1.00 or more, and may be 1.10 or more.
- the median diameter of fat globules in a powdered oil or fat composition can be measured by the following procedure. ⁇ Measurement of fat globule diameter> The fat globule size (median size) of the powdered oil composition is measured under the following conditions using a laser diffraction particle size analyzer (product name: LA-960, manufactured by Horiba, Ltd.) Note that the median size means the particle size that intersects with the 50% horizontal axis in a distribution curve with particle size on the horizontal axis and cumulative % on the vertical axis. (Measurement conditions) Refractive index: 1.60-0.5i Dispersion medium: Water
- the powdered oil and fat composition of the present invention can be used in foods and beverages such as instant creaming powder used in coffee, tea, chocolate drinks, milkshakes, etc.; ingredients of powdered foods such as powdered whipped cream and powdered soup; roux for curry, stew, etc.; fillings such as jam, cream, sauce, etc.; condiments such as seasoning powder; desserts such as frozen desserts, jellies, gummies, chocolate, etc.; and processed food materials such as confectionery, bread, noodles, and processed meat products.
- foods and beverages such as instant creaming powder used in coffee, tea, chocolate drinks, milkshakes, etc.
- ingredients of powdered foods such as powdered whipped cream and powdered soup
- roux for curry, stew, etc. fillings such as jam, cream, sauce, etc.
- condiments such as seasoning powder
- desserts such as frozen desserts, jellies, gummies, chocolate, etc.
- processed food materials such as confectionery, bread, noodles, and processed meat products
- the powdered oil composition is produced through the following steps (a) to (c) in the method for producing the powdered oil composition.
- steps (a) to (c) will be described in detail.
- step (a) a mixture is prepared by mixing water in an amount of typically 30 parts by mass or more and 300 parts by mass or less, and preferably 40 parts by mass or more and 200 parts by mass or less, with respect to a total of 100 parts by mass of edible fats and oils, component (A), component (B), and excipients.
- the step (a) preferably includes the following steps (a)-1 to (a)-3.
- (a)-1 A step of mixing component (A), component (B), an excipient and water to obtain an aqueous phase raw material
- (a)-2 A step of mixing edible oils and fats and, optionally, an emulsifier to obtain an oil phase raw material
- (a)-3 A step of mixing the aqueous phase raw material and the oil phase raw material to obtain a mixture.
- a general-purpose method can be used, for example, a homogenizer, homomixer, high-pressure emulsifier, high-pressure homogenizer, colloid mill, etc. is used to emulsify the mixture to obtain an oil-in-water emulsion.
- the powdered oil composition may contain other components in addition to those described above, if necessary.
- the other components may be mixed in either step (a) or step (b). From the viewpoint of dispersibility, it is preferable to mix them in step (a), and more preferably, it is preferable to mix them in step (a)-1 or step (a)-2 depending on the properties of the other components.
- a general-purpose method can be used, for example, a vacuum dryer, a vacuum freeze dryer, a vacuum belt dryer, a vacuum drum dryer, a spray dryer, etc. can be used to dry the emulsion.
- the method for improving the emulsion stability of a powdered oil-and-fat composition comprises containing an edible oil-and-fat, component (A): a sap-derived polysaccharide, and component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides.
- component (A) a sap-derived polysaccharide
- component (B) one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides.
- Detailed explanations of the edible oil-and-fat, component (A), and component (B) are omitted since they are the same as those explained in the section (Powdered oil-and-fat composition).
- the emulsion stability of the powdered oil composition can be indicated by the median diameter of the fat globules (oil droplet globules), and specifically, can be expressed as the ratio of the median diameter of the fat globules (oil droplet globules) when the powdered oil composition is stored at 60°C for one week to the median diameter of the fat globules (oil droplet globules) immediately after production.
- a powdered fat or oil composition comprising an edible fat or oil and the following components (A) and (B): Component (A): sap-derived polysaccharides Component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides [2]
- a method for producing a powdered oil-and-fat composition comprising edible oil-and-fat, component (A): a sap-derived polysaccharide, and component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides, comprising:
- the above-mentioned production method in which the powdered oil or fat composition is produced through the following steps (a) to (c): (a) obtaining a mixture of an oil phase raw material containing an edible oil or fat, and an aqueous phase raw material containing component (A), component (B), water, and an excipient; (b) emulsifying the mixture to obtain an oil-in-water emulsion; and (c) drying the emulsion.
- a method for improving the emulsion stability of a powdered oil or fat composition comprising comprising: Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots
- ⁇ Raw material 2 (aqueous phase raw material)>
- Component (B) polysaccharide derived from plant seeds ⁇ Tamarind seed gum 1: Greate (MP Gokyo Food & Chemical Co., Ltd.)
- ⁇ Tamarind seed gum 2 Glyloid 2A (MP Gokyo Food & Chemical Co., Ltd.)
- ⁇ -carotene and ⁇ -Carotene were quantified by high performance liquid chromatography (HPLC analysis). Specifically, 0.5 g of palm oil or oxidized product was weighed out, and then diluted to 10 mL with a mixture of acetone and tetrahydrofuran (a solution with a mass ratio of 1:1), and subjected to HPLC analysis, and the contents of ⁇ -carotene and ⁇ -carotene were quantified from the calibration curve.
- HPLC analysis high performance liquid chromatography
- the calibration curve was created from the peak areas when ⁇ -carotene (model number 035-17981) and ⁇ -carotene (model number 035-05531) reagents (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.) were used as quantitative standards and subjected to HPLC analysis at each predetermined concentration.
- the main analysis conditions are shown below.
- Powdered oil compositions were produced by the following method according to the compositions shown in Tables 2, 3, and 4.
- the composition indicates the blend ratio of the aqueous phase raw materials other than water to the oil phase raw materials, and corresponds to the composition ratio (content of each component) of the powdered oil composition finally obtained.
- aqueous phase raw material Dextrin and component (A), and in each example, component (B) were mixed with water to obtain an aqueous phase raw material. The amount of water was adjusted to 150 parts by mass per 100 parts by mass of the powdered oil composition to be obtained. 2. High-pressure emulsification and drying The aqueous phase raw material and the oil phase raw material (edible oil and fat) prepared in 1 above were combined and stirred to obtain a mixed liquid. The mixed liquid was treated at 500 bar with a high-pressure emulsifier (LAB-2000, manufactured by SPX FLOW) to obtain an oil-in-water emulsion.
- LAB-2000 high-pressure emulsifier
- the obtained emulsion was dried and powdered using a spray dryer (B-290, manufactured by Nippon Buchi Co., Ltd., INLET 175°C, pump output 50%, spray air flow rate 600 L/hour) to obtain each powdered oil and fat composition.
- a spray dryer B-290, manufactured by Nippon Buchi Co., Ltd., INLET 175°C, pump output 50%, spray air flow rate 600 L/hour
- the fat globule diameter (median diameter) of each powdered oil/fat composition was measured immediately after production and after one week of storage at 60°C under the following conditions using a laser diffraction particle size analyzer (LA-960, manufactured by Horiba, Ltd.).
- the median diameter means the particle diameter that intersects with the 50% horizontal axis in a distribution curve with particle diameter on the horizontal axis and cumulative % on the vertical axis.
- the measurement results are also shown in Tables 2 to 4. (Measurement conditions)
- ⁇ Flavor evaluation> A 10% by mass aqueous solution was prepared for each of the obtained powdered oil and fat compositions, and a flavor evaluation was performed. The obtained evaluation results are shown in Tables 2 to 4. The flavor evaluation was performed by four specially trained expert panelists according to the following evaluation indexes, and the evaluation results were determined by consensus. (Evaluation criteria) A score of 3 or above is considered a pass. 5: No off-flavors at all 4: Almost no off-flavors 3: Off-flavors are present, but weak 2: Off-flavors are present 1: Off-flavors are present, but strong
- Powdered oil and fat compositions were prepared according to the formulations shown in Table 2, and the fat globule diameter (median diameter) of each powdered oil and fat composition was measured immediately after production and after storage at 60° C. for one week, and the flavor of a 10% by mass aqueous solution was evaluated. The results are also shown in Table 2.
- a content of component (A) of 10 to 15 mass % was favorable (Examples 1-1 to 1-3, Examples 1-9, and 1-10). Furthermore, when tamarind seed gum 1 and pectin 1 were used in combination as component (B), the fold change in fat globule diameter after storage was as small as 1.19, and the emulsion stability was excellent (Example 1-10). Since a smaller fat globule diameter immediately after production is preferable from the viewpoint of emulsion stability, when the component (A) gum arabic 1 was 20% by mass and the component (B) tamarind seed gum 1 was 0.5 to 1.0% by mass, an excellent balance with off-flavors was obtained (Examples 1-5 and 1-6).
- Powdered oil and fat compositions were prepared according to the formulations shown in Table 3, and the fat globule diameter (median diameter) of each powdered oil and fat composition was measured immediately after production and after storage at 60° C. for one week, and the flavor of a 10% by mass aqueous solution was evaluated. The results are also shown in Table 3.
- Powdered oil and fat compositions were prepared according to the formulations shown in Table 4.
- the fat globule diameter (median diameter) of each powdered oil and fat composition was measured immediately after production and after storage at 60° C. for one week, and the flavor of a 10% by mass aqueous solution was evaluated. The results are also shown in Table 4.
- Example 3-4 the mass ratio of edible oil/fat to component (A) [edible oil/fat/component (A)] was 1.5, and as described above, it was an excellent powdered oil/fat composition.
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Abstract
Description
本発明は、粉末油脂組成物、飲食品、粉末油脂組成物の製造方法および粉末油脂組成物の乳化安定性を向上させる方法に関する。 The present invention relates to a powdered oil composition, a food or drink, a method for producing a powdered oil composition, and a method for improving the emulsion stability of a powdered oil composition.
コーヒー・紅茶用クリーム、菓子、スープ、調味料等の加工素材として、油性成分を水溶性成分で被覆した粉末油脂が広く用いられている。粉末油脂は、乳化剤や賦形剤と混合された食用油脂のエマルジョンを乾燥することにより製造される。上記エマルジョンを作製するための乳化には、従来、乳タンパク質であるカゼインやホエイ等が多く用いられてきた。特許文献1には、pHが7以下のカゼイン酸ナトリウム水溶液に、食用油脂とジアセチル酒石酸エステルモノグリセリドとを添加し、撹拌乳化して食用油脂のO/W型エマルジョンを得、次いでこのO/W型エマルジョンを粉末化することを特徴とする粉末油脂の製造方法が開示されている。この製造方法によれば、製造途中のエマルジョンの安定化を図るとともに、粉末化の際の熱による色焼けや分解による異臭等の問題が解決される。 Powdered oils and fats, in which oily components are coated with water-soluble components, are widely used as processed ingredients for coffee and tea creams, confectioneries, soups, seasonings, etc. Powdered oils and fats are produced by drying an emulsion of edible oils and fats mixed with emulsifiers and excipients. For the emulsification to produce the above emulsions, milk proteins such as casein and whey have traditionally been used. Patent Document 1 discloses a method for producing powdered oils and fats, which comprises adding edible oils and fats and diacetyl tartaric acid ester monoglyceride to an aqueous solution of sodium caseinate with a pH of 7 or less, emulsifying the mixture by stirring to obtain an O/W emulsion of edible oils and fats, and then powdering the O/W emulsion. This method stabilizes the emulsion during production and solves problems such as discoloration due to heat during powderization and unpleasant odors due to decomposition.
カゼインのような乳タンパク質を含まない粉末油脂もまた開発されている。特許文献2は、油性成分、アラビアガム及び糖類を含み、油性成分とアラビアガムとの重量比が2:1~1:5、かつアラビアガムと糖類との重量比が5:1~1:100であることを特徴とする粉末油脂組成物が開示されている。この粉末油脂組成物は、タンパク質を含まず、油性成分の滲み出しがなく、そして水への溶解性が良好である。 Powdered oils and fats that do not contain milk proteins such as casein have also been developed. Patent Document 2 discloses a powdered oil and fat composition that contains an oily component, gum arabic, and sugars, and is characterized in that the weight ratio of the oily component to gum arabic is 2:1 to 1:5, and the weight ratio of gum arabic to sugars is 5:1 to 1:100. This powdered oil and fat composition does not contain proteins, does not exude the oily component, and has good solubility in water.
しかしながら、近年食物アレルギーや、動物由来原料不使用の観点から、乳タンパク等を含まない食品のニーズが高まっている。そのため、特許文献1のようにカゼインを含む粉末油脂組成物は敬遠される傾向にある。一方で、特許文献2のように乳タンパクを用いず、代わりに樹液由来多糖類の一つであるアラビアガムと糖類を用いた粉末油脂組成物では、樹液由来多糖類の特有の異風味により、特に食品への使用において好ましいものではなかった。そこで、本発明の目的は、乳タンパク質等含まない場合であっても、乳化安定性に優れ、風味良好な粉末油脂組成物を提供することにある。 However, in recent years, there has been an increasing need for foods that do not contain milk proteins, etc., due to concerns about food allergies and the absence of animal-derived ingredients. For this reason, powdered oil and fat compositions that contain casein, such as those in Patent Document 1, tend to be avoided. On the other hand, a powdered oil and fat composition that does not use milk proteins, but instead uses gum arabic, a type of sap-derived polysaccharide, and sugars, as in Patent Document 2, is not particularly suitable for use in foods due to the distinctive off-flavor that is characteristic of sap-derived polysaccharides. Therefore, the object of the present invention is to provide a powdered oil and fat composition that has excellent emulsion stability and good flavor, even if it does not contain milk proteins, etc.
本発明者らは、鋭意研究の結果、樹液由来多糖類を含む粉末油脂組成物に、所定量の植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上を含ませることで、樹液由来多糖類の異風味が抑制され、製造直後および保存後の乳化安定性が向上することを見出し、本発明を完成させた。 As a result of intensive research, the present inventors have discovered that by adding a predetermined amount of one or more polysaccharides selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides to a powdered oil composition containing sap-derived polysaccharides, the off-flavor of the sap-derived polysaccharides is suppressed and emulsion stability immediately after production and after storage is improved, thereby completing the present invention.
すなわち、本発明によれば、以下の粉末油脂組成物、飲食品、粉末油脂組成物の製造方法および粉末油脂組成物の乳化安定性向上方法が提供される。
[1] 食用油脂と、以下の成分(A)および成分(B)を含有する、粉末油脂組成物。
成分(A):樹液由来多糖類
成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上
[2] [1]に記載の粉末油脂組成物を含む、飲食品。
[3] 食用油脂と、成分(A):樹液由来多糖類と、成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上、を含有する、粉末油脂組成物の製造方法であって、
前記粉末油脂組成物が、以下の(a)乃至(c)の工程を経て製造される、前記製造方法。
(a)食用油脂を含む油相原料と、成分(A)、成分(B)、水、及び賦形剤を含む水相原料との混合物を得る工程
(b)上記混合物を乳化させて水中油滴型エマルジョンを得る工程
(c)上記エマルジョンを乾燥する工程
[4] 食用油脂と、以下の(A)および成分(B)を含有させることを特徴とする、粉末油脂組成物の乳化安定性を向上させる方法。
成分(A):樹液由来多糖類
成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上
That is, according to the present invention, there are provided the following powdered oil or fat composition, food or drink, method for producing a powdered oil or fat composition, and method for improving the emulsion stability of a powdered oil or fat composition.
[1] A powdered fat or oil composition comprising an edible fat or oil and the following components (A) and (B):
Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots
[2] A food or drink comprising the powdered oil or fat composition described in [1].
[3] A method for producing a powdered oil-and-fat composition comprising edible oil-and-fat, component (A): a sap-derived polysaccharide, and component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides, comprising:
The above-mentioned production method, in which the powdered oil or fat composition is produced through the following steps (a) to (c):
(a) obtaining a mixture of an oil phase raw material containing an edible oil and fat and an aqueous phase raw material containing component (A), component (B), water, and an excipient; (b) emulsifying the mixture to obtain an oil-in-water emulsion; and (c) drying the emulsion.
[4] A method for improving the emulsion stability of a powdered oil or fat composition, comprising comprising containing an edible oil or fat and the following component (A) and component (B):
Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots
本発明によれば、乳タンパク質等を含まない場合であっても、異風味が抑制され、乳化安定性が向上した粉末油脂組成物を得ることができる。 According to the present invention, it is possible to obtain a powdered oil composition that suppresses off-flavors and has improved emulsion stability, even when it does not contain milk proteins, etc.
以下に、本発明の粉末油脂組成物、飲食品、粉末油脂組成物の製造方法および粉末油脂組成物の乳化安定性向上方法について具体的な態様を説明する。本明細書に開示された各々の態様は、本明細書に開示された他のいかなる特徴とも組み合わせることができ、好ましい態様の組み合わせは、より好ましい態様である。
本明細書において数値範囲を示す「X~Y」との表現は、「X以上Y以下」であることを意味している。また、数値範囲の上限値および下限値を示した時には、これらの上限値及び下限値の内、任意の上限値及び下限値を適時組み合わせて好適な数値範囲とすることができ、それにより得られた数値範囲も開示しているものとする。更にその数値範囲内の数値であれば、実施例で示されている数値に置き換えてもよい。
Specific embodiments of the powdered oil and fat composition, food and drink, method for producing a powdered oil and fat composition, and method for improving emulsion stability of a powdered oil and fat composition of the present invention will be described below. Each embodiment disclosed in this specification can be combined with any other feature disclosed in this specification, and a combination of preferred embodiments is a more preferred embodiment.
In this specification, the expression "X to Y" indicating a numerical range means "X or more and Y or less". In addition, when the upper and lower limits of a numerical range are indicated, any upper and lower limits of these upper and lower limits can be appropriately combined to obtain a suitable numerical range, and the numerical range obtained thereby is also considered to be disclosed. Furthermore, any numerical value within the numerical range may be replaced with a numerical value shown in the examples.
なお、本発明の粉末油脂組成物、飲食品、粉末油脂組成物の製造方法および粉末油脂組成物の乳化安定性向上方法は、後述の実施形態および実施例に限定するものではなく、発明の特徴および効果を損なわない範囲において、種々の変更が可能である。また、一実施形態について記載した特定の説明が他の実施形態についても当てはまる場合には、他の実施形態においてはその説明を省略している場合がある。
また、本発明における異風味とは、成分(A):樹液由来多糖類由来の好ましくない風味のことである。
The powdered oil and fat composition, food and drink, method for producing a powdered oil and fat composition, and method for improving the emulsion stability of a powdered oil and fat composition of the present invention are not limited to the embodiments and examples described below, and various modifications are possible within the scope of the invention without impairing the features and effects. In addition, when a specific explanation given for one embodiment is also applicable to other embodiments, the explanation may be omitted in the other embodiments.
Further, the off-flavor in the present invention refers to an undesirable flavor derived from component (A): sap-derived polysaccharides.
(粉末油脂組成物)
本実施形態において、粉末油脂組成物は食用油脂と、以下の成分(A)および成分(B)を含有する。
成分(A):樹液由来多糖類
成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上
(Powdered oil and fat composition)
In this embodiment, the powdered oil and fat composition contains edible oil and fat and the following components (A) and (B).
Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots
(成分(A))
成分(A)は樹液由来多糖類である。樹液由来多糖類とは、樹皮から分泌される樹液に含まれる多糖類のことである。本実施形態における樹液由来多糖類としては、例えば、アラビアガム、ガティガム、カラヤガム、トラガントガム等を好適に使用することができ、これらの樹液由来の増粘多糖類は1種又は2種以上を使用することができる。この中でも、乳化安定性を向上させる観点からアラビアガム又はガティガムが好ましく、アラビアガムを用いることがさらに好ましい。
(Component (A))
Component (A) is a sap-derived polysaccharide. The sap-derived polysaccharide is a polysaccharide contained in the sap secreted from the bark. In the present embodiment, for example, gum arabic, gum ghatti, gum karaya, gum tragacanth, etc. can be suitably used as the sap-derived polysaccharide, and one or more of these sap-derived thickening polysaccharides can be used. Among these, gum arabic or gum ghatti is preferred from the viewpoint of improving emulsion stability, and gum arabic is more preferred.
粉末油脂組成物中の成分(A)の含有量は、乳化安定性向上させる観点から、粉末油脂組成物全体を100質量%として、好ましくは5質量%以上であり、より好ましくは8質量%以上、さらに好ましくは11質量%以上、さらにより好ましくは13質量%以上である。
また、異風味を抑制する観点から、粉末油脂組成物中の成分(A)の含有量は、粉末油脂組成物全体を100質量%として、好ましくは23質量%以下であり、より好ましくは22質量%以下、さらに好ましくは21質量%以下、さらにより好ましくは18質量%以下、より一層好ましくは16質量%以下である。
すなわち、乳化安定性向上させる観点及び異風味を抑制する観点から、粉末油脂組成物中の成分(A)の含有量は、粉末油脂組成物全体を100質量%として、好ましくは5質量%以上23質量%以下であり、より好ましくは8質量%以上22質量%以下、さらに好ましくは11質量%以上21質量%以下、さらにより好ましくは13質量%以上18質量%以下、より一層好ましくは13質量%以上16質量%以下である。
From the viewpoint of improving emulsion stability, the content of component (A) in the powdered oil composition is preferably 5% by mass or more, more preferably 8% by mass or more, even more preferably 11% by mass or more, and even more preferably 13% by mass or more, with the entire powdered oil composition being 100% by mass.
Furthermore, from the viewpoint of suppressing off-flavors, the content of component (A) in the powdered oil or fat composition is, relative to 100% by mass of the entire powdered oil or fat composition, preferably 23% by mass or less, more preferably 22% by mass or less, even more preferably 21% by mass or less, even more preferably 18% by mass or less, and even more preferably 16% by mass or less.
That is, from the viewpoint of improving emulsion stability and suppressing off-flavors, the content of component (A) in the powdered oil or fat composition is preferably 5% by mass or more and 23% by mass or less, more preferably 8% by mass or more and 22% by mass or less, even more preferably 11% by mass or more and 21% by mass or less, still more preferably 13% by mass or more and 18% by mass or less, and even more preferably 13% by mass or more and 16% by mass or less, taking the total powdered oil or fat composition as 100% by mass.
粉末油脂組成物中の成分(A)に対する食用油脂は、乳化安定性を向上させる観点から、質量比で1.3以上4.0以下であることが好ましく、質量比で1.5以上4.0以下であることがより好ましく、質量比で1.8以上4.0以下であることがさらに好ましく、質量比で1.8以上3.5以下であることがさらにより好ましく、質量比で1.9以上3.1以下であることがより一層好ましく、質量比で2.3以上2.8以下であることが特に好ましい。 From the viewpoint of improving emulsion stability, the ratio of edible oil to component (A) in the powdered oil composition is preferably 1.3 or more and 4.0 or less in mass ratio, more preferably 1.5 or more and 4.0 or less in mass ratio, even more preferably 1.8 or more and 4.0 or less in mass ratio, even more preferably 1.8 or more and 3.5 or less in mass ratio, even more preferably 1.9 or more and 3.1 or less in mass ratio, and particularly preferably 2.3 or more and 2.8 or less in mass ratio.
(成分(B))
成分(B)は植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上である。植物種子由来多糖類としては、タマリンドシードガム、グアーガム、ローカストビーンガム等が挙げられ、果実由来多糖類としては果実由来ペクチン、セルロース等が挙げられ、植物根由来多糖類としては、シュガービートペクチンやこんにゃくマンナン等が挙げられる。但し、成分(B)にはデンプンは含まない。本実施形態における成分(B)としては、好ましくはタマリンドシードガム、グアーガム、ローカストビーンガム、並びに、果実由来ペクチンおよびシュガービートペクチン等のペクチンからなる群から選択される1種又は2種以上であり、より好ましくはタマリンドシードガム及び果実由来ペクチンからなる群から選択される1種又は2種であり、さらに好ましくはタマリンドシードガムである。また、乳化安定性向上の観点からは、タマリンドシードガムおよび果実由来ペクチンを同時に含むことも好ましい。
(Component (B))
Component (B) is one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides. Examples of plant seed-derived polysaccharides include tamarind seed gum, guar gum, locust bean gum, etc., examples of fruit-derived polysaccharides include fruit-derived pectin, cellulose, etc., and examples of plant root-derived polysaccharides include sugar beet pectin and konjac mannan, etc. However, component (B) does not contain starch. Component (B) in this embodiment is preferably one or more selected from the group consisting of tamarind seed gum, guar gum, locust bean gum, and pectins such as fruit-derived pectin and sugar beet pectin, more preferably one or two selected from the group consisting of tamarind seed gum and fruit-derived pectin, and even more preferably tamarind seed gum. In addition, from the viewpoint of improving emulsion stability, it is also preferable to simultaneously contain tamarind seed gum and fruit-derived pectin.
粉末油脂組成物中の成分(B)の含有量は、乳化安定性を向上させる観点から、粉末油脂組成物全体を100質量%として、好ましくは0.1質量%以上であり、より好ましくは0.3質量%以上、さらに好ましくは0.4質量%以上である。
また、同様の観点から、粉末油脂組成物中の成分(B)の含有量は、粉末油脂組成物全体を100質量%として、好ましくは4質量%以下であり、より好ましくは2質量%以下であり、さらに好ましくは1.5質量%以下、さらにより好ましくは1.2質量%以下である。
すなわち、乳化安定性向上させる観点から、粉末油脂組成物中の成分(B)の含有量は、粉末油脂組成物全体を100質量%として、好ましくは0.1質量%以上4質量%以下であり、より好ましくは0.1質量%以上2質量%以下であり、さらに好ましくは0.3質量%以上1.5質量%以下、さらにより好ましくは0.4質量%以上1.2質量%以下である。
From the viewpoint of improving emulsion stability, the content of component (B) in the powdered oil composition is preferably 0.1 mass % or more, more preferably 0.3 mass % or more, and even more preferably 0.4 mass % or more, with the total powdered oil composition being 100 mass %.
From the same viewpoint, the content of component (B) in the powdered oil composition is preferably 4 mass% or less, more preferably 2 mass% or less, even more preferably 1.5 mass% or less, and even more preferably 1.2 mass% or less, taking the entire powdered oil composition as 100 mass%.
That is, from the viewpoint of improving emulsion stability, the content of component (B) in the powdered oil composition is preferably 0.1 mass % or more and 4 mass % or less, more preferably 0.1 mass % or more and 2 mass % or less, even more preferably 0.3 mass % or more and 1.5 mass % or less, and even more preferably 0.4 mass % or more and 1.2 mass % or less, taking the entire powdered oil composition as 100 mass %.
粉末油脂組成物中の成分(A)と成分(B)の合計に対する成分(B)[成分(B)/(成分(A)+成分(B))]は、乳化安定性を向上させる観点および異風味を抑制する観点から、質量比で0.010以上0.200以下であることが好ましく、質量比で0.010以上0.150以下であることがより好ましく、質量比で0.015以上0.130以下であることがさらに好ましく、質量比で0.020以上0.095以下であることがさらにより好ましく、質量比で0.025以上0.080以下であることがより一層好ましい。 The ratio of component (B) to the total of component (A) and component (B) in the powdered oil composition [component (B)/(component (A)+component (B))] is preferably from the viewpoint of improving emulsion stability and suppressing off-flavors a mass ratio of 0.010 to 0.200, more preferably from the viewpoint of 0.010 to 0.150, even more preferably from the viewpoint of 0.015 to 0.130, even more preferably from the viewpoint of 0.020 to 0.095, and even more preferably from the viewpoint of 0.025 to 0.080.
(食用油脂)
本発明の粉末油脂組成物は食用油脂を含む。本実施形態における食用油脂としては、制限はなく、適宜選択すればよい。例えば、菜種油、大豆油、パーム油、コーン油、アマニ油、えごま油、紅花油、ひまわり油、綿実油、こめ油、落花生油、シア脂、サル脂、カカオ脂、パーム核油、ヤシ油、グレープシード油、マカダミアナッツオイル、ココナッツオイル、月見草油などの植物油脂;牛脂、豚脂、乳脂、鶏油、魚油等の動物油脂;中鎖脂肪酸トリグリセリドなどの合成油脂などが挙げられる。また、これらに分別、水素添加、エステル交換等を施した加工油脂が挙げられる。
食用油脂は、菜種油、大豆油、パーム油、コーン油、パーム核油、及びヤシ油からなる群から選択される1種又は2種以上を含むことが好ましく、パーム油、パーム核油、及びヤシ油からなる群から選択される1種又は2種以上を含むことがより好ましく、パームオレインを含むことがさらに好ましい。
(Edible oils and fats)
The powdered oil and fat composition of the present invention contains edible oil and fat. The edible oil and fat in this embodiment is not limited and may be appropriately selected. For example, vegetable oils and fats such as rapeseed oil, soybean oil, palm oil, corn oil, linseed oil, perilla oil, safflower oil, sunflower oil, cottonseed oil, rice oil, peanut oil, shea fat, monkey fat, cacao butter, palm kernel oil, coconut oil, grape seed oil, macadamia nut oil, coconut oil, and evening primrose oil; animal oils and fats such as beef tallow, lard, milk fat, chicken oil, and fish oil; and synthetic oils and fats such as medium-chain fatty acid triglycerides. In addition, processed oils and fats obtained by fractionation, hydrogenation, transesterification, etc., may be mentioned.
The edible oils and fats preferably contain one or more selected from the group consisting of rapeseed oil, soybean oil, palm oil, corn oil, palm kernel oil, and coconut oil, more preferably contain one or more selected from the group consisting of palm oil, palm kernel oil, and coconut oil, and even more preferably contain palm olein.
本発明の粉末油脂組成物は、食用油脂に、調味油および風味向上油を含んでいても良い。本実施形態における調味油とは、油脂にスパイスや香料等で香りをつけたものや、何らかの成分を抽出することで風味をつけたものや、油脂に何らかの加工を施すことで、風味を付与したものも含まれ、また、ごま油のように食用油脂そのものが風味を持つものも含まれる。
また、風味向上油とは、食品に加えることで味や香り、うま味、コクや、その他の風味を向上又は異風味をマスキングするような機能性を有する食用油脂組成物を指す。
調味油の具体例としては、バターフレーバーオイル、レモンフレーバーオイル、アーモンドフレーバーオイル、バニラフレーバーオイル等のフレーバーオイル;ごま油、オリーブオイル、アーモンドオイル、ピーナッツオイル、焙煎菜種油等の搾油された油脂そのものが香りをもつ香味食用油脂;ラー油、ねぎ油、ショウガオイル、ガーリックオイル等、香味野菜やスパイスにより風味を付与した油脂;油脂に加熱や水素添加などの処理を施すことで風味を付与した風味油;焼き肉風味を付与したグリルオイル、炭火焼風味オイル等が挙げられ、風味向上油としては、後述のn-6系脂肪酸等を含有する油脂や、後述の酸化油脂を含む油脂等が挙げられる。
本発明の粉末油脂は、食用油脂に、調味油および風味向上油からなる群から選ばれる1種または2種以上を含むことが好ましく、フレーバーオイル、香味食用油脂、n-6系脂肪酸等を含有する油脂、および酸化油脂を含む油脂からなる群から選ばれる1種または2種以上を含むことがより好ましく、レモンフレーバーオイル、オリーブオイル、ゴマ油、n-6系脂肪酸等を含有する油脂、および酸化油脂を含む油脂からなる群から選ばれる1種または2種以上を含むことがさらに好ましく、オリーブオイル、ゴマ油、n-6系脂肪酸含有油脂および酸化油脂を含む油脂からなる群から選ばれる1種または2種以上を含むことがさらにより好ましく、オリーブオイル、n-6系脂肪酸含有油脂および酸化油脂を含む油脂からなる群から選ばれる1種または2種以上を含むことがより一層好ましく、n-6系脂肪酸含有油脂および酸化油脂を含む油脂から選ばれる1種または2種を含むことが特に好ましい。
The powdered oil-and-fat composition of the present invention may contain seasoning oil and flavor-improving oil in the edible oil-and-fat. The seasoning oil in this embodiment includes oil-and-fat that has been scented with spices, flavorings, etc., oil-and-fat that has been flavored by extracting some component, oil-and-fat that has been processed in some way, and also includes edible oil-and-fat that itself has a flavor, such as sesame oil.
Furthermore, the flavor-enhancing oil refers to an edible fat and oil composition that has the functionality of improving the taste, aroma, umami, richness, and other flavors or masking unusual flavors when added to food.
Specific examples of seasoning oils include flavor oils such as butter flavor oil, lemon flavor oil, almond flavor oil, and vanilla flavor oil; flavored edible oils and fats that have a fragrance themselves as extracted oils and fats, such as sesame oil, olive oil, almond oil, peanut oil, and roasted rapeseed oil; oils and fats flavored with aromatic vegetables or spices, such as chili oil, green onion oil, ginger oil, and garlic oil; flavored oils imparted with flavor by subjecting oils and fats to treatments such as heating and hydrogenation; grill oils and charcoal grilled flavor oils that impart a grilled meat flavor, and flavor-enhancing oils and fats include oils and fats containing n-6 fatty acids, which will be described later, and oils and fats containing oxidized oils, which will be described later.
The powdered oil and fat of the present invention preferably contains, in the edible oil and fat, one or more selected from the group consisting of seasoning oils and flavor-enhancing oils, more preferably one or more selected from the group consisting of flavor oils, flavored edible oils and fats, oils and fats containing n-6 fatty acids, and oils and fats containing oxidized oils and fats, even more preferably one or more selected from the group consisting of lemon flavor oil, olive oil, sesame oil, oils and fats containing n-6 fatty acids, and oils and fats containing oxidized oils and fats, even more preferably one or more selected from the group consisting of olive oil, sesame oil, oils and fats containing n-6 fatty acids, and oils and fats containing oxidized oils and fats, even more preferably one or more selected from the group consisting of olive oil, oils and fats containing n-6 fatty acids, and oils and fats containing oxidized oils and fats, and particularly preferably one or two selected from oils and fats containing n-6 fatty acids and oils and fats containing oxidized oils and fats.
前記食用油脂に調味油を含む場合、食用油脂中の調味油の含有量の下限は、食用油脂全体を100質量%として、好ましくは5質量%以上、より好ましくは10質量%以上、さらに好ましくは20質量%以上、さらにより好ましくは30質量%以上、より一層好ましくは50質量%以上、特に好ましくは80質量%以上である。
また、前記食用油脂に調味油を含む場合、食用油脂中の調味油の含有量の上限は、食用油脂全体を100質量%として、100質量%以下であり、99.5質量%以下、99質量%以下、98質量%以下等であってもよい。
すなわち、前記食用油脂に調味油を含む場合、食用油脂中の調味油の含有量は、食用油脂全体を100質量%として、好ましくは5質量%以上100質量%以下、より好ましくは10質量%以上99.5質量%以下、さらに好ましくは20質量%以上99質量%以下、さらにより好ましくは30質量%以上98質量%以下、より一層好ましくは50質量%以上98質量%以下、特に好ましくは80質量%以上98質量%以下である。
When the edible oil or fat contains a seasoning oil, the lower limit of the content of the seasoning oil in the edible oil or fat is preferably 5% by mass or more, more preferably 10% by mass or more, even more preferably 20% by mass or more, still more preferably 30% by mass or more, even more preferably 50% by mass or more, and particularly preferably 80% by mass or more, based on 100% by mass of the entire edible oil or fat.
Furthermore, when the edible oil or fat contains a seasoning oil, the upper limit of the content of the seasoning oil in the edible oil or fat is 100% by mass or less, and may be 99.5% by mass or less, 99% by mass or less, 98% by mass or less, etc., based on 100% by mass of the entire edible oil or fat.
In other words, when the edible oil contains seasoning oil, the content of the seasoning oil in the edible oil is, relative to 100% by mass of the entire edible oil, preferably 5% by mass or more and 100% by mass or less, more preferably 10% by mass or more and 99.5% by mass or less, even more preferably 20% by mass or more and 99% by mass or less, still more preferably 30% by mass or more and 98% by mass or less, even more preferably 50% by mass or more and 98% by mass or less, and particularly preferably 80% by mass or more and 98% by mass or less.
前記食用油脂に風味向上油を含む場合、食用油脂中の風味向上油の含有量の下限は、食用油脂全体を100質量%として、好ましくは0.1質量%以上、より好ましくは0.2質量%以上、さらに好ましくは0.4質量%以上、さらにより好ましくは1質量%以上、より一層好ましくは2質量%以上である。
また、前記食用油脂に風味向上油を含む場合、食用油脂中の風味向上油の含有量の上限は、食用油脂全体を100質量%として、好ましくは100質量%以下であり、より好ましくは60質量%以下、さらに好ましくは40質量%以下、さらにより好ましくは20質量%以下、より一層好ましくは10質量%以下、特に好ましくは6質量%以下である。
すなわち、前記食用油脂に風味向上油を含む場合、食用油脂中の風味向上油の含有量は、食用油脂全体を100質量%として、好ましくは0.1質量%以上100質量%以下、より好ましくは0.2質量%以上60質量%以下、さらに好ましくは0.4質量%以上40質量%以下、さらにより好ましくは1質量%以上20質量%以下、より一層好ましくは2質量%以上10質量%以下、特に好ましくは2質量%以上6質量%以下である。
When the edible oil or fat contains a flavor-enhancing oil, the lower limit of the content of the flavor-enhancing oil in the edible oil or fat is preferably 0.1 mass% or more, more preferably 0.2 mass% or more, even more preferably 0.4 mass% or more, still more preferably 1 mass% or more, and even more preferably 2 mass% or more, based on 100 mass% of the total edible oil or fat.
Furthermore, when the edible oil or fat contains a flavor-enhancing oil, the upper limit of the content of the flavor-enhancing oil in the edible oil or fat is preferably 100% by mass or less, more preferably 60% by mass or less, even more preferably 40% by mass or less, even more preferably 20% by mass or less, even more preferably 10% by mass or less, and particularly preferably 6% by mass or less, based on 100% by mass of the entire edible oil or fat.
In other words, when the edible oil contains a flavor-enhancing oil, the content of the flavor-enhancing oil in the edible oil is, relative to 100% by mass of the entire edible oil, preferably 0.1% by mass or more and 100% by mass or less, more preferably 0.2% by mass or more and 60% by mass or less, even more preferably 0.4% by mass or more and 40% by mass or less, still more preferably 1% by mass or more and 20% by mass or less, even more preferably 2% by mass or more and 10% by mass or less, and particularly preferably 2% by mass or more and 6% by mass or less.
粉末油脂組成物中の食用油脂の含有量は、乳化安定性向上させる観点から、粉末油脂組成物全体を100質量%として、好ましくは15質量%以上であり、より好ましくは20質量%以上であり、さらに好ましくは22質量%以上、さらにより好ましくは25質量%以上、より一層好ましくは28質量%以上である。
また、同様の観点から、粉末油脂組成物中の食用油脂の含有量は、粉末油脂組成物全体を100質量%として、好ましくは70質量%以下であり、より好ましくは65質量%以下、さらに好ましくは60質量%以下、さらにより好ましくは55質量%以下、より一層好ましくは50質量%以下、特に好ましくは45質量%以下である。
すなわち、粉末油脂組成物中の食用油脂の含有量は、乳化安定性向上させる観点から、粉末油脂組成物全体を100質量%として、好ましくは15質量%以上70質量%以下であり、より好ましくは20質量%以上65質量%以下であり、さらに好ましくは22質量%以上60質量%以下、さらにより好ましくは25質量%以上55質量%以下、より一層好ましくは28質量%以上50質量%以下、特に好ましくは28質量%以上45質量%以下である。
From the viewpoint of improving emulsion stability, the content of edible oils and fats in the powdered oil composition is preferably 15% by mass or more, more preferably 20% by mass or more, even more preferably 22% by mass or more, still more preferably 25% by mass or more, and even more preferably 28% by mass or more, taking the total powdered oil and fat composition as 100% by mass.
From the same viewpoint, the content of edible oils and fats in the powdered oil and fat composition is preferably 70% by mass or less, more preferably 65% by mass or less, even more preferably 60% by mass or less, still more preferably 55% by mass or less, even more preferably 50% by mass or less, and particularly preferably 45% by mass or less, taking the entire powdered oil and fat composition as 100% by mass.
That is, from the viewpoint of improving emulsion stability, the content of edible oils and fats in the powdered oil composition is, with the entire powdered oil and fat composition being 100% by mass, preferably 15% by mass or more and 70% by mass or less, more preferably 20% by mass or more and 65% by mass or less, even more preferably 22% by mass or more and 60% by mass or less, still more preferably 25% by mass or more and 55% by mass or less, even more preferably 28% by mass or more and 50% by mass or less, and particularly preferably 28% by mass or more and 45% by mass or less.
(n-6系脂肪酸等を含有する油脂)
前記食用油脂は、n-6系の長鎖高度不飽和脂肪酸及びそのエステル体からなる群から選択される少なくとも1種(以下「n-6系脂肪酸等」という場合がある。)を含有する油脂(以下「n-6系脂肪酸等を含有する油脂」という場合がある。)を含むことが好ましい。
(Oils and fats containing n-6 fatty acids, etc.)
The edible fats and oils preferably include fats and oils containing at least one selected from the group consisting of n-6 long-chain highly unsaturated fatty acids and esters thereof (hereinafter sometimes referred to as "n-6 fatty acids, etc.") (hereinafter sometimes referred to as "fat and oil containing n-6 fatty acids, etc.").
n-6系の長鎖高度不飽和脂肪酸とは、炭素数が18以上かつ二重結合を3以上有する脂肪酸を意味する。好ましくは、炭素数が20~24かつ二重結合を4~6有する長鎖高度不飽和脂肪酸である。
n-6系の長鎖高度不飽和脂肪酸として、例えば、アラキドン酸(AA)、ドコサテトラエン酸(DTA)等が挙げられ、好ましくはアラキドン酸である。
The n-6 long-chain highly unsaturated fatty acid means a fatty acid having 18 or more carbon atoms and 3 or more double bonds. A long-chain highly unsaturated fatty acid having 20 to 24 carbon atoms and 4 to 6 double bonds is preferred.
Examples of n-6 long-chain highly unsaturated fatty acids include arachidonic acid (AA) and docosatetraenoic acid (DTA), with arachidonic acid being preferred.
n-6系の長鎖高度不飽和脂肪酸のエステル体としては、n-6系の長鎖高度不飽和脂肪酸を含むグリセロール脂肪酸エステル、ショ糖脂肪酸エステル、有機酸脂肪酸エステル、脂肪酸アルコールエステル、スフィンゴ脂質、ソルビタン脂肪酸エステル、ポリプロピレン脂肪酸エステル、ステロールエステル等が挙げられる。なかでも、グリセロール脂肪酸エステルであることが好ましい。グリセロール脂肪酸エステルとは、グリセロールを構成成分として持つエステルであり、具体的には、トリアシルグリセロール(トリグリセリド)、ジアシルグリセロール(ジグリセリド)、モノアシルグリセロール(モノグリセリド)、グリセロリン脂質、グリセロ糖脂質等が挙げられる。上記エステル体は、好ましくはトリアシルグリセロールである。 Esters of n-6 long-chain highly unsaturated fatty acids include glycerol fatty acid esters, sucrose fatty acid esters, organic acid fatty acid esters, fatty acid alcohol esters, sphingolipids, sorbitan fatty acid esters, polypropylene fatty acid esters, sterol esters, etc., all of which contain n-6 long-chain highly unsaturated fatty acids. Of these, glycerol fatty acid esters are preferred. Glycerol fatty acid esters are esters that have glycerol as a constituent component, and specific examples include triacylglycerol (triglyceride), diacylglycerol (diglyceride), monoacylglycerol (monoglyceride), glycerophospholipid, and glyceroglycolipid. The above ester is preferably triacylglycerol.
n-6系脂肪酸等の由来に特に制限はなく、各種動植物、微生物、藻類等から得られたものが市販されており、当業者はこれら公知のものを適宜使用することができる。n-6系脂肪酸等は、1種類のものを単独で用いてもよく、あるいは複数種類を併用してもよい。 There are no particular limitations on the origin of n-6 fatty acids, etc., and those obtained from various animals and plants, microorganisms, algae, etc. are commercially available, and those skilled in the art can use these known ones as appropriate. One type of n-6 fatty acid, etc. may be used alone, or multiple types may be used in combination.
また、n-6系脂肪酸等を含有する油脂は、酸化処理されたもの(酸化処理物)でもよい。
酸化の程度としては、過酸化物価(Peroxidevalue;以下「POV」という場合がある。)を指標にするとき、一般に市場に流通している食用油脂の過酸化物価が0~10程度であるところ、その過酸化物価が15以上350以下程度に高められていることが好ましい。過酸化物価の範囲は、別の態様にあっては、20以上300以下であってよく、30以上270以下であってよく、40以上250以下であってよく、60以上200以下であってよい。過酸化物価(POV)は、「基準油脂分析試験法2.5.2過酸化物価」(日本油化学会)に則って測定できる。
Furthermore, the fats and oils containing n-6 fatty acids and the like may be those that have been subjected to an oxidation treatment (oxidation-treated product).
When the peroxide value (hereinafter sometimes referred to as "POV") is used as an index of the degree of oxidation, edible oils and fats generally available on the market have a peroxide value of about 0 to 10, and it is preferable that the peroxide value is increased to about 15 to 350. In another embodiment, the range of the peroxide value may be 20 to 300, 30 to 270, 40 to 250, or 60 to 200. The peroxide value (POV) can be measured in accordance with "Standard Methods for the Analysis of Fats, Oils and Related Materials 2.5.2 Peroxide Value" (Japan Oil Chemists' Society).
酸化処理の方法に特に制限はないが、好ましくは加熱処理する方法が挙げられる。例えば、工業的スケールで生産する観点からは、タンク等の適当な容器に原料油脂を収容したうえ、容器に備わる電熱式、直火バーナー式、マイクロ波式、蒸気式、熱風式などの加熱手段で行うことが好ましい。加熱処理の条件に特に制限はないが、40℃~200℃において0.1時間~240時間加熱することが好ましく、80℃~180℃において0.5時間~72時間加熱することがより好ましい。 There are no particular limitations on the oxidation method, but a preferred method is a heat treatment method. For example, from the perspective of industrial-scale production, it is preferable to place the raw oil or fat in a suitable container such as a tank, and use a heating means such as an electric heater, direct flame burner, microwave, steam, or hot air heater attached to the container. There are no particular limitations on the conditions for the heat treatment, but it is preferable to heat at 40°C to 200°C for 0.1 to 240 hours, and more preferably to heat at 80°C to 180°C for 0.5 to 72 hours.
加熱処理に際しては、撹拌により容器の開放スペースから酸素を取り入れたり、酸素を吹き込んだり(例えば、バブリング)して、酸素を供給してもよい。酸素源は空気などを用いてもよい。これにより上記n-6系脂肪酸等を含有する油脂の酸化が促進される。その場合、酸素の供給量としては、上記油脂1kgあたり0.001L/分以上2L/分以下となる範囲とすることが好ましい。例えば、空気の場合は、上記油脂1kgあたり0.005L/分以上10L/分以下となる範囲とすることが好ましく、0.01L/分以上5L/分以下となる範囲とすることがより好ましい。 During the heat treatment, oxygen may be supplied by introducing oxygen from the open space of the container by stirring or by blowing oxygen in (e.g., bubbling). Air may be used as the oxygen source. This promotes the oxidation of the oils and fats containing the n-6 fatty acids and the like. In this case, the amount of oxygen supplied is preferably in the range of 0.001 L/min to 2 L/min per 1 kg of the oil and fat. For example, in the case of air, the range is preferably 0.005 L/min to 10 L/min per 1 kg of the oil and fat, and more preferably 0.01 L/min to 5 L/min.
前記食用油脂中にn-6系脂肪酸等を含有する油脂を含む場合、粉末油脂組成物中のn-6系脂肪酸等を含有する油脂の含有量は、粉末油脂組成物全体を100質量%として、好ましくは0.05質量%以上、より好ましくは0.08質量%以上、さらに好ましくは0.1質量%以上、さらにより好ましくは0.13質量%以上である。
また、粉末油脂組成物中のn-6系脂肪酸等を含有する油脂の含有量は、粉末油脂組成物全体を100質量%として、好ましくは20質量%以下、より好ましくは10質量%以下、さらに好ましくは5質量%以下、さらにより好ましくは2質量%以下、より一層好ましくは1質量%以下、特に好ましくは0.6質量%以下、殊更好ましくは0.4質量%以下である。
すなわち、前記食用油脂中にn-6系脂肪酸等を含有する油脂を含む場合、粉末油脂組成物中のn-6系脂肪酸等を含有する油脂の含有量は、粉末油脂組成物全体を100質量%として、好ましくは0.05質量%以上20質量%以下、より好ましくは0.05質量%以上10質量%以下、さらに好ましくは0.08質量%以上5質量%以下、さらにより好ましくは0.08質量%以上2質量%以下、より一層好ましくは0.1質量%以上1質量%以下、特に好ましくは0.1質量%以上0.6質量%以下、殊更好ましくは0.13質量%以上0.4質量%以下である。
When the edible oil or fat contains an oil or fat containing n-6 fatty acids, the content of the oil or fat containing n-6 fatty acids, etc. in the powdered oil or fat composition is preferably 0.05% by mass or more, more preferably 0.08% by mass or more, even more preferably 0.1% by mass or more, and still more preferably 0.13% by mass or more, based on 100% by mass of the entire powdered oil or fat composition.
The content of the oil or fat containing n-6 fatty acids and the like in the powdered oil or fat composition is, relative to 100% by mass of the entire powdered oil or fat composition, preferably 20% by mass or less, more preferably 10% by mass or less, even more preferably 5% by mass or less, still more preferably 2% by mass or less, even more preferably 1% by mass or less, particularly preferably 0.6% by mass or less, and especially preferably 0.4% by mass or less.
That is, when the edible oil or fat contains an oil or fat containing n-6 fatty acids, etc., the content of the oil or fat containing n-6 fatty acids, etc. in the powdered oil or fat composition is, based on 100% by mass of the entire powdered oil or fat composition, preferably from 0.05% by mass to 20% by mass, more preferably from 0.05% by mass to 10% by mass, even more preferably from 0.08% by mass to 5% by mass, still more preferably from 0.08% by mass to 2% by mass, still more preferably from 0.1% by mass to 1% by mass, particularly preferably from 0.1% by mass to 0.6% by mass, and especially preferably from 0.13% by mass to 0.4% by mass.
(酸化油脂)
本発明の粉末油脂組成物は、食用油脂に、α-カロテンおよびβ-カロテンの合計含有量が50質量ppm以上2000質量ppm以下のパーム系油脂およびヒマワリ油からなる群から選ばれる1種以上の油脂の酸化処理物である酸化油脂を含んでいても良く、α-カロテンおよびβ-カロテンの合計含有量が50質量ppm以上2000質量ppm以下のパーム系油脂の酸化処理物である酸化油脂を含むことが好ましい。
(Oxidized oils and fats)
The powdered oil-and-fat composition of the present invention may contain, in the edible oil-and-fat, oxidized oil-and-fat which is an oxidation product of one or more kinds of oil-and-fat selected from the group consisting of palm-based oil-and-fat and sunflower oil having a total content of α-carotene and β-carotene of 50 ppm by mass or more and 2000 ppm by mass or less, and preferably contains oxidized oil-and-fat which is an oxidation product of palm-based oil-and-fat having a total content of α-carotene and β-carotene of 50 ppm by mass or more and 2000 ppm by mass or less.
酸化油脂に使用するパーム系油脂は、アブラヤシの果実から得られるパーム系油脂であればよく、分子蒸留、分別、脱ガム、脱酸、脱色、脱臭などの処理を施してなるものであってもよい。各処理の方法は、特に限定するものではなく、通常、油脂の加工・精製処理に用いられる方法を採用することができる。パーム系油脂のα-カロテンおよびβ-カロテンの合計含有量は、50質量ppm以上2000質量ppm以下であり、50質量ppm以上1500質量ppm以下であることが好ましく、50質量ppm以上1000質量ppm以下であることがより好ましく、50質量ppm以上800質量ppm以下であることがさらに好ましい。また、パーム系油脂は、α-カロテンおよびβ-カロテンの合計含有量が上記範囲となる1種類を用いてもよく、あるいは2種類以上を混合して上記合計含有量となるように調製して用いてもよい。
なお、油脂中のα-カロテンおよびβ-カロテンの含有量については、実施例の項に記載される方法又はこれと同等であることが当業者に理解される方法により測定することができる。
The palm-based oil used in the oxidized oil may be any palm-based oil obtained from the fruit of the oil palm, and may be one that has been subjected to treatments such as molecular distillation, fractionation, degumming, deacidification, bleaching, and deodorization. The method of each treatment is not particularly limited, and methods that are usually used in the processing and refining of oils and fats can be adopted. The total content of α-carotene and β-carotene in the palm-based oil is 50 ppm by mass or more and 2000 ppm by mass or less, preferably 50 ppm by mass or more and 1500 ppm by mass or less, more preferably 50 ppm by mass or more and 1000 ppm by mass or less, and even more preferably 50 ppm by mass or more and 800 ppm by mass or less. In addition, the palm-based oil may be one type having a total content of α-carotene and β-carotene in the above range, or two or more types may be mixed and used so as to obtain the total content.
The α-carotene and β-carotene contents in fats and oils can be measured by the method described in the Examples section or a method that will be understood by those skilled in the art to be equivalent thereto.
酸化油脂に使用するヒマワリ油は、特に限定するものではないが、構成脂肪酸総量に占めるオレイン酸の割合が70質量%以上100質量%以下であることが好ましく、75質量%以上95質量%以下であることがより好ましく、80質量%以上90質量%以下であることがさらに好ましい。また、ヒマワリ油は、精製処理を経ていることが好ましい。構成脂肪酸総量に占めるオレイン酸の含有量は、「基準油脂分析試験法2.5.23-2013脂肪酸組成(キャピラリーガスクロマトグラフ法」(日本油化学会)に記載の方法に準拠して測定することができる。 The sunflower oil used for the oxidized oil is not particularly limited, but the proportion of oleic acid in the total amount of constituent fatty acids is preferably 70% by mass or more and 100% by mass or less, more preferably 75% by mass or more and 95% by mass or less, and even more preferably 80% by mass or more and 90% by mass or less. In addition, it is preferable that the sunflower oil has been subjected to a refining process. The content of oleic acid in the total amount of constituent fatty acids can be measured in accordance with the method described in "Standard Methods for the Analysis of Fats, Oils and Related Materials 2.5.23-2013 Fatty Acid Composition (Capillary Gas Chromatography Method)" (Japan Oil Chemists' Society).
本発明における酸化油脂は、上記のパーム系油脂およびヒマワリ油からなる群から選ばれる1種以上の油脂を酸化処理してなる酸化処理物であることが重要であり、過酸化物価(以下、「POV」と称することがある。)が15以上300以下であることが好ましく、25以上290以下であることがより好ましく、40以上270以下であることがさらに好ましく、45以上250以下であることがさらにより好ましい。過酸化物価は、「基準油脂分析試験法2.5.2過酸化物価」(日本油化学会)に記載の方法に準拠して測定することができる。 It is important that the oxidized oil or fat in the present invention is an oxidation product obtained by oxidizing one or more oils or fats selected from the group consisting of palm-based oils and sunflower oils, and the peroxide value (hereinafter sometimes referred to as "POV") is preferably 15 to 300, more preferably 25 to 290, even more preferably 40 to 270, and even more preferably 45 to 250. The peroxide value can be measured in accordance with the method described in "Standard Methods for the Analysis of Fats, Oils, and Related Materials 2.5.2 Peroxide Value" (Japan Oil Chemists' Society).
酸化油脂を得る方法は、パーム系油脂およびヒマワリ油を酸化処理して過酸化物価が上記範囲内とすることができる方法であればよく、限定するものではないが、例えば、加熱処理が挙げられる。より具体的には、工業的スケールで生産する観点からは、タンク等の容器に原料となる油脂を収容した上で、容器に備えられた電熱式、直火バーナー式、マイクロ波式、蒸気式、熱風式等の加熱手段により加熱処理を行うことが好ましい。加熱処理の条件は、一概ではないが、例えば、加熱温度50℃以上220℃以下で加熱時間が0.1時間以上240時間以下で行うことが典型的であり、加熱温度60℃以上160℃以下で加熱時間が1時間以上100時間以下で行うことがより典型的である。加熱温度(℃)×加熱時間(時間)の積算量の条件としては、例えば、200以上20000以下の積算量で加熱処理を行うことが典型的であり、220以上18000以下の積算量で加熱処理を行うことがより典型的であり、240以上15000以下の積算量で加熱処理を行うことがさらに典型的である。なお、加熱温度を変化させた場合、加熱温度(℃)×加熱時間(時間)の積算量は、温度を変化させる前の加熱温度(℃)×温度を変化させる前の加熱時間(時間)+温度を変化させた後の加熱温度(℃)×温度を変化させた後の加熱時間(時間)、又は加熱時間(時間)にわたる加熱温度(℃)の積分値として算出することができる。 The method for obtaining oxidized fats and oils may be any method capable of oxidizing palm-based fats and sunflower oil to bring the peroxide value within the above range, and is not limited thereto, but examples thereof include heat treatment. More specifically, from the viewpoint of industrial-scale production, it is preferable to place the raw fats and oils in a container such as a tank, and then heat treat the raw fats and oils using a heating means such as an electric heater, direct flame burner, microwave, steam, or hot air heater provided in the container. The conditions for the heat treatment are not limited, but are typically performed at a heating temperature of 50°C to 220°C for a heating time of 0.1 to 240 hours, and more typically at a heating temperature of 60°C to 160°C for a heating time of 1 to 100 hours. As a condition for the integrated amount of heating temperature (°C) x heating time (hours), for example, heating treatment is typically performed with an integrated amount of 200 to 20,000, more typically with an integrated amount of 220 to 18,000, and even more typically with an integrated amount of 240 to 15,000. When the heating temperature is changed, the integrated amount of heating temperature (°C) x heating time (hours) can be calculated as heating temperature (°C) before the temperature change x heating time (hours) before the temperature change + heating temperature (°C) after the temperature change x heating time (hours) after the temperature change, or the integral value of the heating temperature (°C) over the heating time (hours).
また、酸化処理に際しては、加熱処理を施しながら撹拌により容器の開放スペースから酸素を取り入れたり、酸素を吹き込んだり(例えば、バブリング)して、酸素(空気)を供給してもよい。なお、酸素源は空気などを用いてもよい。これにより、原料となる油脂の酸化が促進される。その場合、酸素の供給量としては、原料油脂1kgあたり0.001~2L/分となるようにすることが好ましい。例えば、空気の場合は、原料油脂1kgあたり0.005~10L/分であることが好ましく、0.01~5L/分であることがよりに好ましい。 Furthermore, during the oxidation treatment, oxygen (air) may be supplied by introducing oxygen from the open space of the container while stirring or by blowing oxygen in (e.g., bubbling) while performing the heat treatment. The oxygen source may be air, etc. This promotes the oxidation of the raw material oils and fats. In this case, the oxygen supply rate is preferably 0.001 to 2 L/min per 1 kg of raw oils and fats. For example, in the case of air, it is preferable that the supply rate is 0.005 to 10 L/min per 1 kg of raw oils and fats, and 0.01 to 5 L/min is more preferable.
粉末油脂組成物中に酸化油脂を含む場合、粉末油脂組成物中の酸化油脂の含有量は、粉末油脂組成物全体を100質量%として、好ましくは0.1質量%以上であり、より好ましくは0.2質量%以上、さらに好ましくは0.5質量%以上、さらにより好ましくは0.7質量%以上、より一層好ましくは0.9質量%以上である。
また、粉末油脂組成物中の酸化油脂の含有量は、粉末油脂組成物全体を100質量%として、好ましくは5質量%以下であり、より好ましくは3質量%以下、さらに好ましくは2質量%以下、さらにより好ましくは1.5質量%以下、より一層好ましくは1.2質量%以下である。
すなわち、粉末油脂組成物中の酸化油脂を含む場合の含有量は、粉末油脂組成物全体を100質量%として、好ましくは0.1質量%以上5質量%以下であり、より好ましくは0.2質量%以上3質量%以下、さらに好ましくは0.5質量%以上2質量%以下、さらにより好ましくは0.7質量%以上1.5質量%以下、より一層好ましくは0.9質量%以上1.2質量%以下である。
When the powdered oil/fat composition contains oxidized oil/fat, the content of the oxidized oil/fat in the powdered oil/fat composition is preferably 0.1 mass% or more, more preferably 0.2 mass% or more, even more preferably 0.5 mass% or more, still more preferably 0.7 mass% or more, and even more preferably 0.9 mass% or more, based on 100 mass% of the entire powdered oil/fat composition.
Furthermore, the content of oxidized oils and fats in the powdered oil and fat composition is preferably 5 mass % or less, more preferably 3 mass % or less, even more preferably 2 mass % or less, even more preferably 1.5 mass % or less, and even more preferably 1.2 mass % or less, taking the entire powdered oil and fat composition as 100 mass %.
That is, when the powdered oil or fat composition contains oxidized oil or fats, the content thereof is, relative to 100 mass% of the entire powdered oil or fat composition, preferably from 0.1 mass% to 5 mass%, more preferably from 0.2 mass% to 3 mass%, even more preferably from 0.5 mass% to 2 mass%, still more preferably from 0.7 mass% to 1.5 mass%, and even more preferably from 0.9 mass% to 1.2 mass%.
(賦形剤)
本実施形態において、粉末油脂組成物は、賦形剤を含有することが好ましい。
賦形剤は、主として油性成分を被覆することにより粉末油脂を形成し、さらに、油性成分の滲み出しを防止するものである。このような賦形剤は、限定されず、通常、粉末油脂を製造する際に使用するものを使うことができる。例えば、デンプン(オクテニルコハク酸デンプン等)、水あめ、粉あめ、コーンシロップ、ショ糖(スクロース)、ブドウ糖(グルコース)、麦芽糖(マルトース)、乳糖(ラクトース)、果糖(フルクトース)、ガラクトース、トレハロース、デキストリン、アルギン酸ナトリウム、カラギーナン等の糖類;エリスリトール、ソルビトール、マンニトール、マルチトール、ラクチトール、パラチニット、還元水飴等の糖アルコール;小麦粉;ゼラチン、酸カゼイン、カゼインナトリウム等のタンパク質;キサンタンガム等の増粘剤(ただし成分(A)および成分(B)に含まれるものを除く)が挙げられる。賦形剤は、1種を単品で用いてもよく、2種以上を併用してもよい。
上記賦形剤は、好ましくはデンプン、糖類、増粘剤及びタンパク質からなる群から選択される1種又は2種以上であり、より好ましくはオクテニルコハク酸デンプン、コーンシロップ、デキストリンからなる群から選択される1種又は2種以上であり、さらに好ましくはデキストリン、オクテニルコハク酸デンプンからなる群から選択される1種又は2種であり、さらにより好ましくはデキストリンである。
また、本発明の粉末油脂組成物は、乳タンパク質、特にカゼイン及びその塩を含んでいても良いが、カゼインはアレルゲン性物質であるため、アレルゲンフリーの観点からは配合しないことが好ましい。本発明においては、カゼイン又はその塩を含まなくとも良好な乳化安定性を実現できる点で有利である。なお、本発明において、カゼイン又はその塩を含む態様は排除されない。
(Excipients)
In this embodiment, the powdered oil or fat composition preferably contains an excipient.
The excipient mainly coats the oily component to form the powdered oil and prevents the oily component from bleeding out. Such excipients are not limited, and those usually used in producing powdered oil can be used. For example, sugars such as starch (starch octenyl succinate, etc.), starch syrup, powdered syrup, sucrose, glucose, maltose, lactose, fructose, galactose, trehalose, dextrin, sodium alginate, and carrageenan; sugar alcohols such as erythritol, sorbitol, mannitol, maltitol, lactitol, palatinit, and reduced starch syrup; wheat flour; proteins such as gelatin, acid casein, and sodium caseinate; and thickeners such as xanthan gum (excluding those contained in components (A) and (B)). The excipients may be used alone or in combination of two or more.
The above-mentioned excipient is preferably one or more types selected from the group consisting of starch, sugars, thickeners and proteins, more preferably one or more types selected from the group consisting of starch octenyl succinate, corn syrup and dextrin, even more preferably one or two types selected from the group consisting of dextrin and starch octenyl succinate, and even more preferably dextrin.
The powdered oil and fat composition of the present invention may contain milk proteins, particularly casein and its salts, but casein is an allergenic substance, so it is preferable not to add it from the viewpoint of allergen-free. The present invention is advantageous in that good emulsion stability can be achieved without including casein or its salts. Note that the present invention does not exclude embodiments that contain casein or its salts.
上記糖類の平均分子量は、400以上20000以下であることが好ましく、500以上15000以下であることがより好ましい。
上記糖類のデキストロース当量(DE)は、5以上50以下であることが好ましく、7以上40以下であることがより好ましく、10以上35以下であることがさらに好ましく、10以上30以下であることがさらにより好ましく、11以上25以下であることがより一層好ましい。
The average molecular weight of the saccharide is preferably 400 or more and 20,000 or less, and more preferably 500 or more and 15,000 or less.
The dextrose equivalent (DE) of the above sugars is preferably 5 or more and 50 or less, more preferably 7 or more and 40 or less, even more preferably 10 or more and 35 or less, even more preferably 10 or more and 30 or less, and even more preferably 11 or more and 25 or less.
粉末油脂組成物中に賦形剤を含む場合、粉末油脂組成物中の賦形剤の含有量は、乳化安定性を向上させる観点及び異風味を抑制する観点から、粉末油脂組成物全体を100質量%として、好ましくは20質量%以上であり、より好ましくは25質量%以上、さらに好ましくは30質量%以上、さらにより好ましくは35質量%以上、より一層好ましくは43質量%以上である。
また、乳化安定性を向上させる観点から、粉末油脂組成物中の賦形剤の含有量は、粉末油脂組成物全体を100質量%として、好ましくは80質量%以下であり、より好ましくは75質量%以下、さらに好ましくは70質量%以下である。
すなわち、乳化安定性を向上させる観点及び異風味を抑制する観点から、粉末油脂組成物全体を100質量%として、好ましくは20質量%以上80質量%以下であり、より好ましくは25質量%以上80質量%以下、さらに好ましくは30質量%以上75質量%以下、さらにより好ましくは35質量%以上75質量%以下、より一層好ましくは43質量%以上70質量%以下である。
When the powdered oil or fat composition contains an excipient, the content of the excipient in the powdered oil or fat composition is, from the viewpoint of improving emulsion stability and suppressing off-flavors, preferably 20% by mass or more, more preferably 25% by mass or more, even more preferably 30% by mass or more, even more preferably 35% by mass or more, and even more preferably 43% by mass or more, with the entire powdered oil or fat composition being 100% by mass.
Furthermore, from the viewpoint of improving emulsion stability, the content of the excipient in the powdered oil/fat composition is preferably 80% by mass or less, more preferably 75% by mass or less, and even more preferably 70% by mass or less, with the entire powdered oil/fat composition being 100% by mass.
That is, from the viewpoint of improving emulsion stability and suppressing off-flavors, the content is preferably 20% by mass or more and 80% by mass or less, more preferably 25% by mass or more and 80% by mass or less, even more preferably 30% by mass or more and 75% by mass or less, still more preferably 35% by mass or more and 75% by mass or less, and even more preferably 43% by mass or more and 70% by mass or less, based on 100% by mass of the entire powdered oil or fat composition.
本実施形態において、粉末油脂組成物は、乳化剤を含有してもよいが、含有しないことが好ましい。ここで、乳化剤とは、食品衛生法上の表示基準で定められた、乳化剤を主要用途とする指定添加物及び既存添加物をいう。このような乳化剤は、食品用であれば特に限定されることなく、例えば、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、植物レシチン、卵黄レシチン等が挙げられる。 In this embodiment, the powdered oil composition may contain an emulsifier, but it is preferable that it does not contain one. Here, the emulsifier refers to designated additives and existing additives whose main use is as an emulsifier, as stipulated in the labeling standards under the Food Sanitation Act. Such emulsifiers are not particularly limited as long as they are food-grade, and examples include glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, propylene glycol fatty acid esters, vegetable lecithin, egg yolk lecithin, etc.
(上記以外の成分)
また、粉末油脂組成物は、上述の成分の他にも、発明の効果を損ねない範囲において、リン酸水素二カリウム、硫酸二カリウム、クエン酸三ナトリウム、水酸化ナトリウムなどのpH調整剤;トコフェロール等の抗酸化剤;上記賦形剤以外の甘味料;安定剤;香料;着色剤;炭酸カルシウム、二酸化チタン等を含んでもよい。
(Ingredients other than those listed above)
In addition to the above-mentioned components, the powdered oil or fat composition may contain, within the scope of the invention, pH adjusters such as dipotassium hydrogen phosphate, dipotassium sulfate, trisodium citrate, and sodium hydroxide; antioxidants such as tocopherol; sweeteners other than the above-mentioned excipients; stabilizers; flavorings; colorants; calcium carbonate, titanium dioxide, etc.
(抗酸化剤)
本発明の粉末油脂組成物は、異風味を抑制する観点から、抗酸化剤を含むことが好ましい。抗酸化剤としては、好ましくはトコフェロールであり、より好ましくはミックストコフェロールである。
粉末油脂組成物中に抗酸化剤を含む場合粉末油脂組成物中の抗酸化剤の含有量は、粉末油脂組成物全体を100質量%として、0.01質量%以上5質量%以下であることが好ましく、0.03質量%以上4質量%以下であることがより好ましく、0.05質量%以上3質量%以下であることがさらに好ましく、0.08質量%以上2.5質量%以下であることがさらにより好ましい。
(Antioxidant)
From the viewpoint of suppressing off-flavors, the powdered oil or fat composition of the present invention preferably contains an antioxidant. The antioxidant is preferably tocopherol, more preferably mixed tocopherol.
When the powdered oil or fat composition contains an antioxidant, the content of the antioxidant in the powdered oil or fat composition is, relative to 100% by mass of the entire powdered oil or fat composition, preferably from 0.01% by mass to 5% by mass, more preferably from 0.03% by mass to 4% by mass, even more preferably from 0.05% by mass to 3% by mass, and even more preferably from 0.08% by mass to 2.5% by mass.
本実施形態において、粉末油脂組成物は、水中油滴型ドライエマルジョン系粉末油脂組成物であることが好ましい。ここで、水中油滴型ドライエマルジョン系粉末油脂組成物とは、水中油滴型エマルジョンを乾燥させた粉末油脂組成物のことをいう。なお、全脂型粉末油脂組成物(高融点油脂を噴霧冷却または冷却粉砕により粉末化した粉末油脂組成物)は、上記水中油滴型ドライエマルジョン系粉末油脂組成物に含まれない。 In this embodiment, the powdered oil composition is preferably an oil-in-water dry emulsion type powdered oil composition. Here, the oil-in-water dry emulsion type powdered oil composition refers to a powdered oil composition obtained by drying an oil-in-water emulsion. Note that full-fat type powdered oil compositions (powdered oil compositions obtained by powdering high-melting-point oils and fats by spray cooling or cooling and pulverizing) are not included in the above-mentioned oil-in-water dry emulsion type powdered oil composition.
本実施形態において、粉末油脂組成物の製造直後の脂肪球(油滴球)のメディアン径は、乳化安定性を向上させる観点から、好ましくは8μm以下であり、より好ましくは6μm以下、さらに好ましくは4μm以下、さらにより好ましくは3μm以下、より一層好ましくは2.3μm以下、特に好ましくは1.7μm以下、殊更好ましくは1.3μm以下である。
また、同様の観点から、粉末油脂組成物の製造直後の脂肪球(油滴球)のメディアン径は、好ましくは0.1μm以上であり、0.2μm以上であってもよく、0.3μm以上であってもよく、0.5μm以上であってもよく、0.6μm以上であってもよい。
In this embodiment, the median diameter of the fat globules (oil droplet globules) immediately after the production of the powdered oil or fat composition is, from the viewpoint of improving emulsion stability, preferably 8 μm or less, more preferably 6 μm or less, even more preferably 4 μm or less, even more preferably 3 μm or less, still more preferably 2.3 μm or less, particularly preferably 1.7 μm or less, and especially preferably 1.3 μm or less.
From a similar viewpoint, the median diameter of the fat globules (oil droplet globules) immediately after production of the powdered oil or fat composition is preferably 0.1 μm or more, optionally 0.2 μm or more, optionally 0.3 μm or more, optionally 0.5 μm or more, or optionally 0.6 μm or more.
本実施形態において、粉末油脂組成物を60℃で一週間保存した場合の脂肪球(油滴球)のメディアン径は、乳化安定性を向上させる観点から、好ましくは10μm以下であり、より好ましくは8μm以下、さらに好ましくは6μm以下、さらにより好ましくは4μm以下、より一層好ましくは3.3μm以下、特に好ましくは2.8μm以下、殊更好ましくは2.0μm以下である。
また、同様の観点から、粉末油脂組成物を60℃で一週間保存した場合の脂肪球(油滴球)のメディアン径は、好ましくは0.1μm以上であり、0.2μm以上であってもよく、0.3μm以上であってもよく、0.4μm以上であってもよく、0.6μm以上であってもよく、0.9μm以上であってもよい。
In this embodiment, the median diameter of fat globules (oil droplet globules) when the powdered oil or fat composition is stored at 60°C for one week is, from the viewpoint of improving emulsion stability, preferably 10 µm or less, more preferably 8 µm or less, even more preferably 6 µm or less, even more preferably 4 µm or less, still more preferably 3.3 µm or less, particularly preferably 2.8 µm or less, and especially preferably 2.0 µm or less.
From a similar viewpoint, the median diameter of fat globules (oil droplet globules) when the powdered oil or fat composition is stored at 60°C for one week is preferably 0.1 µm or more, optionally 0.2 µm or more, optionally 0.3 µm or more, optionally 0.4 µm or more, optionally 0.6 µm or more, or optionally 0.9 µm or more.
本実施形態において、粉末油脂組成物の60℃で一週間保存した場合の脂肪球(油滴球)のメディアン径の変化倍率(60℃保存後変化倍率ともいう)は、乳化安定性を向上させる観点から、好ましくは2.00以下であり、より好ましくは1.80以下、さらに好ましくは1.60以下、さらにより好ましくは1.50以下、より一層好ましくは1.40以下である。
ここで、60℃保存後変化倍率は、製造直後の脂肪球(油滴球)のメディアン径に対する粉末油脂組成物を60℃で一週間保存した場合の脂肪球(油滴球)のメディアン径の比率で求めることができ、当該変化倍率が小さいほど保存後の乳化安定性が優れているといえる。よって60℃保存後変化倍率の下限は1.00以上であり、1.10以上であってもよい。
In this embodiment, the change ratio of the median diameter of fat globules (oil droplet globules) when the powdered oil or fat composition is stored at 60°C for one week (also referred to as the change ratio after storage at 60°C) is, from the viewpoint of improving emulsion stability, preferably 2.00 or less, more preferably 1.80 or less, even more preferably 1.60 or less, even more preferably 1.50 or less, and even more preferably 1.40 or less.
Here, the change ratio after storage at 60°C can be determined as the ratio of the median diameter of fat globules (oil droplet globules) when the powdered oil composition is stored at 60°C for one week to the median diameter of fat globules (oil droplet globules) immediately after production, and it can be said that the smaller the change ratio, the better the emulsion stability after storage. Therefore, the lower limit of the change ratio after storage at 60°C is 1.00 or more, and may be 1.10 or more.
粉末油脂組成物の脂肪球のメディアン径は、以下の手順にて測定することができる。
<脂肪球径の測定>
レーザ回折式粒度分布測定装置(製品名:LA-960、株式会社堀場製作所製)を用いて、以下の条件にて、粉末油脂組成物の脂肪球径(メディアン径)を測定する。なお、メディアン径は、横軸に粒子径、縦軸に積算%とした分布曲線において、50%の横軸と交差する粒子径を意味する。
(測定条件)
屈折率:1.60-0.5i
分散媒:水
The median diameter of fat globules in a powdered oil or fat composition can be measured by the following procedure.
<Measurement of fat globule diameter>
The fat globule size (median size) of the powdered oil composition is measured under the following conditions using a laser diffraction particle size analyzer (product name: LA-960, manufactured by Horiba, Ltd.) Note that the median size means the particle size that intersects with the 50% horizontal axis in a distribution curve with particle size on the horizontal axis and cumulative % on the vertical axis.
(Measurement conditions)
Refractive index: 1.60-0.5i
Dispersion medium: Water
(粉末油脂組成物を含む飲食品)
本発明の粉末油脂組成物は、コーヒー、紅茶、チョコレート飲料、ミルクセーキ等に使われるインスタントクリーミングパウダー; 粉末ホイップクリーム、粉末スープ等の粉末食品の成分;カレー・シチュー等のルウ;ジャム、クリーム、ソース等のフィリング類;シーズニングパウダー等の調味料類;冷菓、ゼリー、グミ、チョコレート等のデザート類;菓子、パン、麺、畜肉加工品等の食品用加工素材等の飲食品に用いることができる。
(Food and drink containing powdered oil and fat composition)
The powdered oil and fat composition of the present invention can be used in foods and beverages such as instant creaming powder used in coffee, tea, chocolate drinks, milkshakes, etc.; ingredients of powdered foods such as powdered whipped cream and powdered soup; roux for curry, stew, etc.; fillings such as jam, cream, sauce, etc.; condiments such as seasoning powder; desserts such as frozen desserts, jellies, gummies, chocolate, etc.; and processed food materials such as confectionery, bread, noodles, and processed meat products.
(粉末油脂組成物の製造方法)
本実施形態において、粉末油脂組成物の製造方法は、上述の粉末油脂組成物が以下の(a)乃至(c)の工程を経て製造される。各(a)乃至(c)の工程について詳しく説明する。
(a)食用油脂を含む油相原料と、成分(A)、成分(B)、水、及び賦形剤を含む水相原料との混合物を得る工程
(b)上記混合物を乳化させて水中油滴型エマルジョンを得る工程
(c)上記エマルジョンを乾燥する工程
(Method for producing powdered oil composition)
In the present embodiment, the powdered oil composition is produced through the following steps (a) to (c) in the method for producing the powdered oil composition. Each of the steps (a) to (c) will be described in detail.
(a) obtaining a mixture of an oil phase raw material containing an edible oil and fat and an aqueous phase raw material containing component (A), component (B), water, and an excipient; (b) emulsifying the mixture to obtain an oil-in-water emulsion; and (c) drying the emulsion.
(a)の工程においては、食用油脂、成分(A)、成分(B)及び賦形剤の合計100質量部に対して、通常、30質量部以上300質量部以下、好ましくは40質量部以上200質量部以下の水を混合して混合物を調製する。
また、(a)の工程は、以下の(a)-1乃至(a)-3の工程を含むことが好ましい。
(a)-1 成分(A)、成分(B)、賦形剤と水を混合して水相原料物を得る工程
(a)-2 食用油脂と任意で乳化剤を混合して油相原料物を得る工程
(a)-3 上記水相原料物及び上記油相原料物を混合して混合物を得る工程
In step (a), a mixture is prepared by mixing water in an amount of typically 30 parts by mass or more and 300 parts by mass or less, and preferably 40 parts by mass or more and 200 parts by mass or less, with respect to a total of 100 parts by mass of edible fats and oils, component (A), component (B), and excipients.
Moreover, the step (a) preferably includes the following steps (a)-1 to (a)-3.
(a)-1: A step of mixing component (A), component (B), an excipient and water to obtain an aqueous phase raw material; (a)-2: A step of mixing edible oils and fats and, optionally, an emulsifier to obtain an oil phase raw material; (a)-3: A step of mixing the aqueous phase raw material and the oil phase raw material to obtain a mixture.
(b)の工程においては、汎用の方法を用いることが可能であり、例えばホモジナイザー、ホモミキサー、高圧乳化機、高圧均質機、コロイドミル等により上記混合物に乳化処理を行い、水中油滴型エマルジョンを得る。 In step (b), a general-purpose method can be used, for example, a homogenizer, homomixer, high-pressure emulsifier, high-pressure homogenizer, colloid mill, etc. is used to emulsify the mixture to obtain an oil-in-water emulsion.
なお、粉末油脂組成物は、必要に応じて上記以外の他の成分を含んでもよい。その場合、他の成分は、(a)の工程及び(b)の工程のいずれの工程で混合してもよく、分散性の観点から、好ましくは(a)の工程で混合すればよく、より好ましくは他の成分の性質に応じて(a)-1の工程又は(a)-2の工程において混合すればよい。 The powdered oil composition may contain other components in addition to those described above, if necessary. In that case, the other components may be mixed in either step (a) or step (b). From the viewpoint of dispersibility, it is preferable to mix them in step (a), and more preferably, it is preferable to mix them in step (a)-1 or step (a)-2 depending on the properties of the other components.
(c)の工程においては、汎用の方法を用いることが可能であり、例えば、真空乾燥機、真空凍結乾燥機、真空ベルト乾燥機、真空ドラム乾燥機、スプレードライヤー等を用いてエマルジョンの乾燥を行う。 In step (c), a general-purpose method can be used, for example, a vacuum dryer, a vacuum freeze dryer, a vacuum belt dryer, a vacuum drum dryer, a spray dryer, etc. can be used to dry the emulsion.
(粉末油脂組成物の乳化安定性を向上させる方法)
本実施形態において、粉末油脂組成物の乳化安定性を向上させる方法は、食用油脂と、成分(A):樹液由来多糖類と、成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上、を含有させるものである。食用油脂、成分(A)、成分(B)についての詳しい説明は、(粉末油脂組成物)の項にて説明した内容と同じであるため割愛する。
ここで、粉末油脂組成物の乳化安定性は、脂肪球(油滴球)のメディアン径を指標とすることができ、具体的には[製造直後の脂肪球(油滴球)のメディアン径]に対する[粉末油脂組成物を60℃で一週間保存した場合の脂肪球(油滴球)のメディアン径]の比率で表すことができる。
(Method for improving emulsion stability of powdered oil composition)
In this embodiment, the method for improving the emulsion stability of a powdered oil-and-fat composition comprises containing an edible oil-and-fat, component (A): a sap-derived polysaccharide, and component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides. Detailed explanations of the edible oil-and-fat, component (A), and component (B) are omitted since they are the same as those explained in the section (Powdered oil-and-fat composition).
Here, the emulsion stability of the powdered oil composition can be indicated by the median diameter of the fat globules (oil droplet globules), and specifically, can be expressed as the ratio of the median diameter of the fat globules (oil droplet globules) when the powdered oil composition is stored at 60°C for one week to the median diameter of the fat globules (oil droplet globules) immediately after production.
本開示の例示的な実施形態及び例示的な実施形態の組み合わせの非限定的なリストを以下に開示する。
[1] 食用油脂と、以下の成分(A)および成分(B)を含有する、粉末油脂組成物。
成分(A):樹液由来多糖類
成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上
[2] 前記食用油脂の含有量が15質量%以上70質量%以下である、上記[1]に記載の粉末油脂組成物。
[3] 前記成分(A)に対する前記食用油脂が質量比で1.3以上4以下である、上記[1]または[2]に記載の粉末油脂組成物。
[4] 前記成分(A)がアラビアガムである、上記[1]~[3]のいずれかに記載の粉末油脂組成物。
[5] 前記成分(B)がタマリンドシードガム、グアーガム、ローカストビーンガムおよびペクチンからなる群から選択される1種または2種以上である、上記[1]~[4]のいずれかに記載の粉末油脂組成物。
[6] 前記成分(A)と前記成分(B)の合計に対する前記成分(B)が、質量比で0.01以上0.20以下である、上記[1]~[5]のいずれかに記載の粉末油脂組成物。
[7] 前記食用油脂に、n-6系の長鎖高度不飽和脂肪酸及びそのエステル体からなる群から選択される少なくとも1種を含有する油脂を含む、上記[1]~[6]のいずれかに記載の粉末油脂組成物。
[8] 前記食用油脂に、α-カロテンおよびβ-カロテンの合計含有量が50質量ppm以上2000質量ppm以下のパーム系油脂およびヒマワリ油からなる群から選ばれる1種以上の油脂の酸化処理物である酸化油脂を含む、上記[1]~[7]のいずれかに記載の粉末油脂組成物。
[9] 上記[1]~[8]のいずれかに記載の粉末油脂組成物を含む、飲食品。
[10] 食用油脂と、成分(A):樹液由来多糖類と、成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上、を含有する、粉末油脂組成物の製造方法であって、
前記粉末油脂組成物が、以下の(a)乃至(c)の工程を経て製造される、前記製造方法。
(a)食用油脂を含む油相原料と、成分(A)、成分(B)、水、及び賦形剤を含む水相原料との混合物を得る工程
(b)上記混合物を乳化させて水中油滴型エマルジョンを得る工程
(c)上記エマルジョンを乾燥する工程
[11] 食用油脂と、以下の(A)および成分(B)を含有させることを特徴とする、粉末油脂組成物の乳化安定性を向上させる方法。
成分(A):樹液由来多糖類
成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上
A non-limiting list of exemplary embodiments and combinations of exemplary embodiments of the present disclosure are disclosed below.
[1] A powdered fat or oil composition comprising an edible fat or oil and the following components (A) and (B):
Component (A): sap-derived polysaccharides Component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides [2] The powdered oil-and-fat composition described in [1] above, wherein the content of the edible oil-and-fat is 15% by mass or more and 70% by mass or less.
[3] The powdered oil/fat composition according to the above [1] or [2], wherein the mass ratio of the edible oil/fat to the component (A) is 1.3 or more and 4 or less.
[4] The powdered oil or fat composition according to any one of the above [1] to [3], wherein the component (A) is gum arabic.
[5] The powdered oil-and-fat composition according to any one of the above [1] to [4], wherein the component (B) is one or more selected from the group consisting of tamarind seed gum, guar gum, locust bean gum and pectin.
[6] The powdered oil or fat composition according to any one of the above [1] to [5], wherein the mass ratio of the component (B) to the total of the component (A) and the component (B) is 0.01 or more and 0.20 or less.
[7] The powdered oil-and-fat composition according to any one of the above [1] to [6], wherein the edible oil-and-fat contains at least one oil-and-fat selected from the group consisting of n-6 long-chain highly unsaturated fatty acids and esters thereof.
[8] The powdered oil-and-fat composition according to any one of the above [1] to [7], wherein the edible oil-and-fat contains oxidized oil-and-fat which is an oxidation product of one or more kinds of oil-and-fat selected from the group consisting of palm-based oils and sunflower oils, having a total content of α-carotene and β-carotene of 50 ppm by mass or more and 2000 ppm by mass or less.
[9] A food or drink comprising the powdered oil or fat composition according to any one of [1] to [8] above.
[10] A method for producing a powdered oil-and-fat composition comprising edible oil-and-fat, component (A): a sap-derived polysaccharide, and component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides, comprising:
The above-mentioned production method, in which the powdered oil or fat composition is produced through the following steps (a) to (c):
(a) obtaining a mixture of an oil phase raw material containing an edible oil or fat, and an aqueous phase raw material containing component (A), component (B), water, and an excipient; (b) emulsifying the mixture to obtain an oil-in-water emulsion; and (c) drying the emulsion. [11] A method for improving the emulsion stability of a powdered oil or fat composition, comprising comprising:
Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots
以上、本発明の実施形態について説明したが、各実施形態における各構成及びそれらの組み合わせ等は、一例であって、本発明の主旨から逸脱しない範囲内で、適宜、構成の付加、省略、置換、及びその他の変更が可能である。本発明は、実施形態によって限定されることはない。
本明細書に開示された各々の態様は、本明細書に開示された他のいかなる特徴とも組み合わせることができる。
Although the embodiments of the present invention have been described above, the configurations and combinations thereof in each embodiment are merely examples, and addition, omission, substitution, and other modifications of the configurations are possible as appropriate within the scope of the gist of the present invention. The present invention is not limited to the embodiments.
Each feature disclosed herein may be combined with any other feature disclosed herein.
以下に、実施例を示して本発明を更に詳細に説明するが、本発明の主旨はこれらに限定されるものではない。 The present invention will be explained in more detail below with reference to examples, but the scope of the present invention is not limited to these.
粉末油脂組成物の原材料として主に以下のものを使用した。
<原材料1(油相原料)>
(食用油脂)
・パームオレイン:パームオレインIV67(不二製油株式会社製)
・調味油1:オリーブ&レモンフレーバーオイル(AJINOMOTO オリーブ&レモンフレーバーオイル、株式会社J-オイルミルズ製)
・調味油2:ごま油(AJINOMOTO ごま油好きの純正ごま油、株式会社J-オイルミルズ製)
・風味向上油1:アラキドン酸含有油脂:下記の「アラキドン酸含有油脂の製造方法」で得られた油脂とパームオレインを質量比で1:3で混合した油脂
・風味向上油2:下記の「酸価油脂の製造方法」で得られた油脂
(抗酸化剤)
・ミックストコフェロール(トコフェロールAT-160(株式会社J-オイルミルズ製)
The following materials were mainly used as raw materials for the powdered oil composition.
<Raw material 1 (oil phase raw material)>
(Edible oils and fats)
Palm olein: Palm olein IV67 (manufactured by Fuji Oil Co., Ltd.)
Seasoning oil 1: Olive & Lemon Flavored Oil (AJINOMOTO Olive & Lemon Flavored Oil, manufactured by J-Oil Mills Co., Ltd.)
Seasoning oil 2: Sesame oil (AJINOMOTO Sesame Oil Lover's Pure Sesame Oil, manufactured by J-Oil Mills, Inc.)
Flavor-improving oil 1: Arachidonic acid-containing oil: Oil obtained by mixing palm olein with the oil obtained by the "Production method of arachidonic acid-containing oil" described below in a mass ratio of 1:3. Flavor-improving oil 2: Oil obtained by the "Production method of acid value oil" described below (antioxidant).
Mixed tocopherols (Tocopherol AT-160 (manufactured by J-Oil Mills Co., Ltd.)
<原材料2(水相原料)>
(成分(A)樹液由来多糖類)
・アラビアガム:アラビックコールSS(三栄薬品貿易株式会社製)
(成分(B)植物種子由来多糖類)
・タマリンドシードガム1:グリエイト(MP五協フード&ケミカル株式会社製)
・タマリンドシードガム2:グリロイド2A(MP五協フード&ケミカル株式会社製)
(成分(B)果実由来多糖類)
・ペクチン1:クラシックCM203(果実由来ペクチン、MP五協フード&ケミカル株式会社製)
(成分(B)植物根由来多糖類)
・ペクチン2:BETA BI-J(シュガービートペクチン、三晶株式会社製)
(賦形剤)
デキストリン:サンデック#150(三和澱粉工業株式会社製)、DE15~18、平均分子量10000
(水)
・市水(水道水)
<Raw material 2 (aqueous phase raw material)>
(Component (A) Polysaccharides derived from sap)
・Gum arabic: Arabic Coal SS (manufactured by San-ei Pharmaceutical Trading Co., Ltd.)
(Component (B) polysaccharide derived from plant seeds)
・Tamarind seed gum 1: Greate (MP Gokyo Food & Chemical Co., Ltd.)
・Tamarind seed gum 2: Glyloid 2A (MP Gokyo Food & Chemical Co., Ltd.)
(Component (B) Fruit-derived polysaccharides)
・Pectin 1: Classic CM203 (fruit-derived pectin, MP Gokyo Food & Chemical Co., Ltd.)
(Component (B) Plant root-derived polysaccharides)
Pectin 2: BETA BI-J (Sugar beet pectin, manufactured by Sansho Co., Ltd.)
(Excipients)
Dextrin: Sandec #150 (manufactured by Sanwa Starch Industries Co., Ltd.), DE 15-18, average molecular weight 10,000
(water)
・City water (tap water)
(酸化油脂の原料油脂のα-カロテンおよびβ-カロテンの定量)
α-カロテンおよびβ-カロテンの定量は、高速液体クロマトグラフィーによる分析(HPLC分析)にて行った。具体的には、パーム系油脂、又は酸化処理物を0.5g秤量し、アセトン及びテトラヒドロフランの混合液(質量比で1:1の溶液)で10mLにそれぞれメスアップし、HPLC分析に供し、検量線からα-カロテンおよびβ-カロテンの含有量を定量した。なお、検量線は定量標品としてα-カロテン(型番035-17981)およびβ-カロテン(型番035-05531)の試薬(富士フイルム和光純薬株式会社製)を使用して、所定濃度ごとにHPLC分析に供したときのピーク面積から作成した。以下には主な分析条件を示す。
(Quantitative Determination of α-Carotene and β-Carotene in Raw Material Oils and Fats for Oxidized Oils and Fats)
The α-carotene and β-carotene were quantified by high performance liquid chromatography (HPLC analysis). Specifically, 0.5 g of palm oil or oxidized product was weighed out, and then diluted to 10 mL with a mixture of acetone and tetrahydrofuran (a solution with a mass ratio of 1:1), and subjected to HPLC analysis, and the contents of α-carotene and β-carotene were quantified from the calibration curve. The calibration curve was created from the peak areas when α-carotene (model number 035-17981) and β-carotene (model number 035-05531) reagents (manufactured by Fujifilm Wako Pure Chemical Industries, Ltd.) were used as quantitative standards and subjected to HPLC analysis at each predetermined concentration. The main analysis conditions are shown below.
(HPLC条件)
・検出器:フォトダイオドアレイ検出器「2996 PHOTODIODE ARRAY DETECTOR」(Waters社)、300~600nmで検出
・カラム:Shim-pack VP-ODS, 4.6mmID×250mm, 4.6μm(株式会社島津製作所)
・カラム温度:50℃注入量:5μL
・流速:1.2mL/分
・移動相A:アセトニトリル
・移動相B:エタノール
・移動相C:アセトン
・グラジエント条件:表1に示す
(HPLC conditions)
Detector: Photodiode array detector "2996 PHOTODIODE ARRAY DETECTOR" (Waters), detection at 300 to 600 nm Column: Shim-pack VP-ODS, 4.6 mm ID x 250 mm, 4.6 μm (Shimadzu Corporation)
Column temperature: 50°C Injection volume: 5 μL
Flow rate: 1.2 mL/min. Mobile phase A: acetonitrile. Mobile phase B: ethanol. Mobile phase C: acetone. Gradient conditions: as shown in Table 1.
(過酸化物価(POV)の測定)
「基準油脂分析試験法2.5.2過酸化物価」(日本油化学会)に則って測定した。
(Measurement of Peroxide Value (POV))
The measurement was performed in accordance with "Standard Methods for the Analysis of Fats, Oils and Related Materials 2.5.2 Peroxide Value" (Japan Oil Chemists' Society).
(酸化油脂の製造方法)
レッドパーム油(カロチーノピュアオレイン、カロチーノ社製、分子蒸留、1回分別、α-カロテンおよびβ-カロテンの合計含有量411質量ppm)240gをビーカーに入れ、これに0.20L/分の量の空気をバブリングで供給しつつ、オイルバス中、撹拌速度200rpmで撹拌しながら、103℃で40時間加熱処理を施した。得られた酸化油脂の過酸化物価(POV)を、「基準油脂分析試験法2.5.2過酸化物価」に則って測定したところ、POVは115であった。
(Method for producing oxidized oils and fats)
240 g of red palm oil (Carotino Pure Olein, manufactured by Carotino Co., Ltd., molecular distillation, single fractionation, total content of α-carotene and β-carotene: 411 ppm by mass) was placed in a beaker and heat-treated at 103° C. for 40 hours while stirring at a stirring speed of 200 rpm in an oil bath and supplying air by bubbling at a rate of 0.20 L/min. The peroxide value (POV) of the obtained oxidized oil was measured according to "Standard Fats and Oils Analysis Test Method 2.5.2 Peroxide Value" and found to be 115.
(アラキドン酸含有油脂の製造方法)
アラキドン酸含有トリグリセリド(サントリー株式会社製SUNTGA40S(微生物由来アラキドン酸、アラキドン酸純度40~45質量%、トリグリセリド純度95質量%以上))25質量%と、パームオレイン(同上)75質量%からなる混合物250gをビーカーに入れ、これに0.25L/分の量の空気をバグリングで供給しつつ、オイルバス中、撹拌速度200rpmで撹拌しながら、95℃及び15時間の条件で加熱処理を施し、アラキドン酸含有油脂を得た。なお、当該油脂のPOVを「基準油脂分析試験法2.5.2過酸化物価」に則って測定したところ、POVは126であった。
(Method for producing arachidonic acid-containing oils and fats)
250 g of a mixture consisting of 25% by mass of arachidonic acid-containing triglyceride (SUNTGA 40S manufactured by Suntory Ltd. (microorganism-derived arachidonic acid, arachidonic acid purity 40-45% by mass, triglyceride purity 95% by mass or more)) and 75% by mass of palm olein (same as above) was placed in a beaker, and while supplying air at a rate of 0.25 L/min via a bag ring, the mixture was subjected to a heat treatment at 95°C for 15 hours while stirring at a stirring speed of 200 rpm in an oil bath to obtain an arachidonic acid-containing fat. The POV of the fat was measured according to "Standard Fats and Oils Analysis Test Method 2.5.2 Peroxide Value" and was found to be 126.
(粉末油脂組成物の製造)
表2、表3及び表4に示す配合に従い、以下の方法にて粉末油脂組成物を製造した。なお、各表において、配合組成は、水以外の水相原料と油相原料との配合比率を示しており、最終的に得られる粉末油脂組成物の組成比率(各成分の含有量)に対応する。
(Production of powdered oil composition)
Powdered oil compositions were produced by the following method according to the compositions shown in Tables 2, 3, and 4. In each table, the composition indicates the blend ratio of the aqueous phase raw materials other than water to the oil phase raw materials, and corresponds to the composition ratio (content of each component) of the powdered oil composition finally obtained.
1.水相原料の調製
水に、デキストリンと成分(A)、各実施例においては成分(B)も混合して、水相原料を得た。ここで、水の量は、得られる粉末油脂組成物100質量部に対し、150質量部となるように調製した。
2.高圧乳化と乾燥
上記1.で準備した水相原料と油相原料(食用油脂)を合一して撹拌することにより、混合液を得た。該混合液を、高圧乳化機(LAB-2000、SPX FLOW社製)にて500barで処理することにより、水中油滴型エマルジョンを得た。得られたエマルジョンをスプレードライヤー(B-290、日本ビュッヒ株式会社製、INLET175℃、ポンプ出力50%、噴霧空気流量600L/時間)を用いて乾燥粉末化することにより、各粉末油脂組成物を得た。
1. Preparation of aqueous phase raw material Dextrin and component (A), and in each example, component (B) were mixed with water to obtain an aqueous phase raw material. The amount of water was adjusted to 150 parts by mass per 100 parts by mass of the powdered oil composition to be obtained.
2. High-pressure emulsification and drying The aqueous phase raw material and the oil phase raw material (edible oil and fat) prepared in 1 above were combined and stirred to obtain a mixed liquid. The mixed liquid was treated at 500 bar with a high-pressure emulsifier (LAB-2000, manufactured by SPX FLOW) to obtain an oil-in-water emulsion. The obtained emulsion was dried and powdered using a spray dryer (B-290, manufactured by Nippon Buchi Co., Ltd., INLET 175°C, pump output 50%, spray air flow rate 600 L/hour) to obtain each powdered oil and fat composition.
(粉末油脂組成物の乳化安定性試験)
(粉末油脂組成物の製造)で得られた各粉末油脂組成物10gをアルミニウム製の袋(ラミジップAL-10、株式会社生産日本製)に量り取り、槽内温度60℃に設定した恒温槽(TVA360DB、アドバンテック東洋株式会社製)内で静置した。一週間静置後にアルミニウム製の袋を取り出し、以下の評価基準で評価した。
(Emulsion stability test of powdered oil composition)
10 g of each of the powdered oil compositions obtained in (Production of Powdered Oil Compositions) was weighed into an aluminum bag (Lamizip AL-10, manufactured by Advantec Co., Ltd., Japan) and allowed to stand in a thermostatic bath (TVA360DB, manufactured by Advantec Toyo Co., Ltd.) set at an internal temperature of 60° C. After standing for one week, the aluminum bag was taken out and evaluated according to the following evaluation criteria.
<脂肪球径の測定>
レーザ回折式粒度分布測定装置(LA-960、株式会社堀場製作所製)を用いて、以下の条件にて、製造直後および、60℃で一週間保存後の各粉末油脂組成物の脂肪球径(メディアン径)を測定した。なお、メディアン径は、横軸に粒子径、縦軸に積算%とした分布曲線において、50%の横軸と交差する粒子径を意味する。測定結果を表2~4にあわせて示す。
(測定条件)
屈折率:1.60-0.5i
分散媒:水
<Measurement of fat globule diameter>
The fat globule diameter (median diameter) of each powdered oil/fat composition was measured immediately after production and after one week of storage at 60°C under the following conditions using a laser diffraction particle size analyzer (LA-960, manufactured by Horiba, Ltd.). The median diameter means the particle diameter that intersects with the 50% horizontal axis in a distribution curve with particle diameter on the horizontal axis and cumulative % on the vertical axis. The measurement results are also shown in Tables 2 to 4.
(Measurement conditions)
Refractive index: 1.60-0.5i
Dispersion medium: Water
<風味評価>
得られた各粉末油脂組成物について、10質量%水溶液を作製し、風味評価を行った。得られた評価結果を表2~4に示す。なお、風味の評価は、特別な訓練を行った専門パネラー4名が以下の評価指標に従って行い、合議にて評価結果とした。
(評価指標) 3点以上を合格とする。
5:異風味が全くない
4:異風味がほとんどない
3:異風味があるが、弱い
2:異風味がある
1:異風味があり、強い
<Flavor evaluation>
A 10% by mass aqueous solution was prepared for each of the obtained powdered oil and fat compositions, and a flavor evaluation was performed. The obtained evaluation results are shown in Tables 2 to 4. The flavor evaluation was performed by four specially trained expert panelists according to the following evaluation indexes, and the evaluation results were determined by consensus.
(Evaluation criteria) A score of 3 or above is considered a pass.
5: No off-flavors at all 4: Almost no off-flavors 3: Off-flavors are present, but weak 2: Off-flavors are present 1: Off-flavors are present, but strong
<試験1>
表2に示す配合で粉末油脂組成物を作製し、製造直後および、60℃で一週間保存後の各粉末油脂組成物の脂肪球径(メディアン径)を測定し、10質量%水溶液の風味について評価を行った。結果を合わせて表2に示す。
<Test 1>
Powdered oil and fat compositions were prepared according to the formulations shown in Table 2, and the fat globule diameter (median diameter) of each powdered oil and fat composition was measured immediately after production and after storage at 60° C. for one week, and the flavor of a 10% by mass aqueous solution was evaluated. The results are also shown in Table 2.
その結果、表2に示されるように、食用油脂と、成分(A)としてアラビアガムと、成分(B)としてタマリンドシードガムとペクチンからなる1種または2種以上を使用した実施例1-1~1-10はいずれも、作製直後および保存後の脂肪球径の変化倍率が小さく、成分(A)の異風味が全くあるいはほとんどない、優れたものであった。
同じ食用油脂と成分(A)で比較した場合、成分(A)に対する食用油脂[食用油脂/成分(A)]の質量比が2.0~3.0の場合、保存後の脂肪球径の変化倍率が1.23~1.44と小さく、乳化安定性が優れていた(実施例1-1~1-5)。
また、異風味を抑制する観点では成分(A)の含有量が10~15質量%の場合、良好であった(実施例1-1~1-3、実施例1-9、1-10)。
さらに、成分(B)としてタマリンドシードガム1とペクチン1を併用した場合、保存後の脂肪球径の変化倍率が1.19と小さく、乳化安定性が優れていた(実施例1-10)。
製造直後の脂肪球径は小さい方が乳化安定性の観点で好ましいため、成分(A)アラビアガム1が20質量%で、成分(B)タマリンドシードガム1が0.5~1.0質量%の場合、異風味とのバランスの観点で優れていた(実施例1-5、1-6)。
一方、成分(B)を含まず、成分(A)に対する食用油脂[食用油脂/成分(A)]の質量比が1.0~1.7の場合、異風味があり、好ましいものではなかった(比較例1-1、1-2)。
As a result, as shown in Table 2, all of Examples 1-1 to 1-10, which used edible fats and oils, gum arabic as component (A), and one or more of tamarind seed gum and pectin as component (B), showed a small fold change in fat globule diameter immediately after preparation and after storage and were excellent in that they had no or almost no unusual flavor due to component (A).
When comparing the same edible oils and fats and component (A), when the mass ratio of edible oils and fats to component (A) [edible oils and fats/component (A)] was 2.0 to 3.0, the fold change in fat globule diameter after storage was small, at 1.23 to 1.44, and the emulsion stability was excellent (Examples 1-1 to 1-5).
From the viewpoint of suppressing off-flavors, a content of component (A) of 10 to 15 mass % was favorable (Examples 1-1 to 1-3, Examples 1-9, and 1-10).
Furthermore, when tamarind seed gum 1 and pectin 1 were used in combination as component (B), the fold change in fat globule diameter after storage was as small as 1.19, and the emulsion stability was excellent (Example 1-10).
Since a smaller fat globule diameter immediately after production is preferable from the viewpoint of emulsion stability, when the component (A) gum arabic 1 was 20% by mass and the component (B) tamarind seed gum 1 was 0.5 to 1.0% by mass, an excellent balance with off-flavors was obtained (Examples 1-5 and 1-6).
On the other hand, when component (B) was not included and the mass ratio of edible oil/component (A) [edible oil/component (A)] was 1.0 to 1.7, a strange flavor was observed and was not preferable (Comparative Examples 1-1 and 1-2).
<試験2>
表3に示す配合で粉末油脂組成物を作製し、製造直後および、60℃で一週間保存後の各粉末油脂組成物の脂肪球径(メディアン径)を測定し、10質量%水溶液の風味について評価を行った。結果を合わせて表3に示す。
<Test 2>
Powdered oil and fat compositions were prepared according to the formulations shown in Table 3, and the fat globule diameter (median diameter) of each powdered oil and fat composition was measured immediately after production and after storage at 60° C. for one week, and the flavor of a 10% by mass aqueous solution was evaluated. The results are also shown in Table 3.
その結果、表3に示されるように、食用油脂として特に風味を有しないパームオレインのみを使用した場合(実施例2-1)、風味向上油2をパームオレインに少量加えた場合(実施例2-2)、食用油脂を全て調味油3または4に置換した場合(実施例2-3、2-4)、いずれの場合でも成分(A)の異風味が感じられず、調味油を含有する場合は調味油の風味が感じられる、乳化安定性に優れた粉末油脂組成物が得られた。 As a result, as shown in Table 3, when only palm olein, which has no particular flavor, was used as the edible oil (Example 2-1), when a small amount of flavor-enhancing oil 2 was added to palm olein (Example 2-2), and when all edible oils and fats were replaced with seasoning oils 3 or 4 (Examples 2-3 and 2-4), the off-flavor of component (A) was not detected in any case, and when seasoning oil was contained, the flavor of the seasoning oil was detected, and a powdered oil composition with excellent emulsion stability was obtained.
<試験3>
表4に示す配合で粉末油脂組成物を作製し、製造直後および、60℃で一週間保存後の各粉末油脂組成物の脂肪球径(メディアン径)を測定し、10質量%水溶液の風味について評価を行った。結果を合わせて表4に示す。
<Test 3>
Powdered oil and fat compositions were prepared according to the formulations shown in Table 4. The fat globule diameter (median diameter) of each powdered oil and fat composition was measured immediately after production and after storage at 60° C. for one week, and the flavor of a 10% by mass aqueous solution was evaluated. The results are also shown in Table 4.
その結果、表4に示されるように、いずれの場合でも成分(A)の異風味が感じられず、調味油の風味が感じられる、乳化安定性に優れた粉末油脂組成物が得られた。
実施例3-4や3-5のように、食用油脂含有量が20質量%の場合、脂肪球径は作製直後および60℃で1週間保存後とも比較的小さく、脂肪球径の変化倍率も小さいことから乳化安定性に優れ、異風味が感じられず好ましかった。また、実施例3-4では成分(A)に対する食用油脂[食用油脂/成分(A)]の質量比が1.5であったが、上述のとおり優れた粉末油脂組成物であった。
またさらに、実施例3-3、3-5および3-8のように成分(A)と成分(B)の合計に対する成分(B)[成分(B)/(成分(A)+成分(B))]の質量比が0.091以上0.143以下の場合、脂肪球径の変化倍率が小さく、異風味は感じられず、好ましかった。
実施例3-6~3-8では、抗酸化剤としてミックストコフェロール1質量%を油相原料に添加して粉末油脂組成物を製造した場合も、異風味が抑制された、好ましい粉末油脂組成物が得られた。
As a result, as shown in Table 4, in all cases, no unusual flavor of component (A) was detected, and the flavor of the seasoning oil was detected, resulting in a powdered oil composition with excellent emulsion stability.
When the edible oil/fat content was 20% by mass as in Examples 3-4 and 3-5, the fat globule diameter was relatively small both immediately after preparation and after storage at 60°C for 1 week, and the rate of change in fat globule diameter was also small, so that the emulsion stability was excellent and no strange flavor was felt, which was preferable. In Example 3-4, the mass ratio of edible oil/fat to component (A) [edible oil/fat/component (A)] was 1.5, and as described above, it was an excellent powdered oil/fat composition.
Furthermore, when the mass ratio of component (B) [component (B)/(component (A)+component (B))] to the total of component (A) and component (B) was 0.091 or more and 0.143 or less as in Examples 3-3, 3-5 and 3-8, the rate of change in fat globule diameter was small and no unusual flavor was detected, which was preferable.
In Examples 3-6 to 3-8, even when powdered oil compositions were produced by adding 1% by mass of mixed tocopherol as an antioxidant to the oil phase raw material, preferable powdered oil compositions in which off-flavors were suppressed were obtained.
Claims (11)
成分(A):樹液由来多糖類
成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上 A powdered fat or oil composition comprising an edible fat or oil and the following components (A) and (B):
Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots
前記粉末油脂組成物が、以下の(a)乃至(c)の工程を経て製造される、前記製造方法。
(a)食用油脂を含む油相原料と、成分(A)、成分(B)、水、及び賦形剤を含む水相原料との混合物を得る工程
(b)上記混合物を乳化させて水中油滴型エマルジョンを得る工程
(c)上記エマルジョンを乾燥する工程 A method for producing a powdered oil-and-fat composition comprising edible oil-and-fat, component (A): a sap-derived polysaccharide, and component (B): one or more selected from the group consisting of plant seed-derived polysaccharides, fruit-derived polysaccharides, and plant root-derived polysaccharides, comprising:
The above-mentioned production method, in which the powdered oil or fat composition is produced through the following steps (a) to (c):
(a) obtaining a mixture of an oil phase raw material containing an edible oil and fat and an aqueous phase raw material containing component (A), component (B), water, and an excipient; (b) emulsifying the mixture to obtain an oil-in-water emulsion; and (c) drying the emulsion.
成分(A):樹液由来多糖類
成分(B):植物種子由来多糖類、果実由来多糖類および植物根由来多糖類からなる群から選択される1種または2種以上 A method for improving the emulsion stability of a powdered oil or fat composition, comprising comprising comprising an edible oil or fat and the following component (A) and component (B):
Component (A): Polysaccharides derived from tree sap Component (B): One or more selected from the group consisting of polysaccharides derived from plant seeds, polysaccharides derived from fruits, and polysaccharides derived from plant roots
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| PCT/JP2024/028858 Pending WO2025047405A1 (en) | 2023-08-29 | 2024-08-13 | Powdery oil or fat composition, food or beverage, method for producing powdery oil or fat composition, and method for improving emulsion stability of powdery oil or fat composition |
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