[go: up one dir, main page]

WO2025045998A1 - Combinaisons herbicides - Google Patents

Combinaisons herbicides Download PDF

Info

Publication number
WO2025045998A1
WO2025045998A1 PCT/EP2024/074170 EP2024074170W WO2025045998A1 WO 2025045998 A1 WO2025045998 A1 WO 2025045998A1 EP 2024074170 W EP2024074170 W EP 2024074170W WO 2025045998 A1 WO2025045998 A1 WO 2025045998A1
Authority
WO
WIPO (PCT)
Prior art keywords
combination
spp
component
methyl
plants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/EP2024/074170
Other languages
English (en)
Inventor
Thomas Auler
Udo Bickers
Hervé TOSSENS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of WO2025045998A1 publication Critical patent/WO2025045998A1/fr
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Definitions

  • the present invention primarily relates to herbicide combinations comprising (i) aclonifen (ii) diflufenican and (iii) prosulfocarb and to compositions comprising said herbicide combinations.
  • the present invention further relates to a method for producing said herbicide combinations and compositions.
  • the present invention also relates to the use of said herbicide combinations and compositions in the field of agriculture and for controlling harmful plants.
  • Aclonifen is known as a selective herbicide from DE2831262 and is used both alone and in mixtures in many countries around the world. It is already known that diflufenican is a broad-spectrum pre- and early post-emergence herbicide for use in wheat and barley.
  • Prosulfocarb is known as a selective herbicide from US3836524 and is used both alone and in mixtures in many countries around the world.
  • herbicidal crop protection agents (herbicides) and combinations/compositions thereof known to date for controlling harmful plants or unwanted vegetation have some disadvantages, above all (a) that they have no or else insufficient herbicidal activity against specific harmful plants, (b) that the spectrum of harmful plants which can be controlled with the herbicides is not broad enough, (c) that the selectivity of herbicides in and the compatibility with crops is too low, thereby causing unwanted damage and/or unwanted reduced harvest yields of the crops, (d) that the initial herbicidal activity is not acceptable or not strong enough and/or (e) that the herbicidal activity does not last long enough.
  • the present invention relates to a combination of herbicides (herbicide combination) comprising or consisting of (i) aclonifen, (ii) diflufenican and (iii) prosulfocarb.
  • the present invention relates to a combination which comprises in addition to (i), (ii) and (iii) at least one additional herbicidal active ingredient, e.g: bromoxynil, bromoxynil-butyrate, -potassium, - heptanoate, and –octanoate, benzofenap, butachlor, 2,4-D, 2,4-D-butotyl, -butyl, -dimethylammonium, - diolamin, -ethyl, -2-ethylhexyl, -isobutyl, -isooctyl, -isopropylammonium, -potassium, - triisopropanolammonium, and –trolamine, broclozone, cinmethylin, dimethenamid, clomazone, cyclopyrimorate, propoxycarbazone, ethoxysulfuron,
  • the present invention relates to a combination comprising as sole herbicidally active constituents (i) aclonifen, (ii) diflufenican and (iii) prosulfocarb. Further, the present invention relates to a combination comprising as sole herbicidally active constituents (ii) aclonifen, (ii) diflufenican and (iii) prosulfocarb and in addition at least one safener. Further, the present invention relates to a combination which comprises in addition to (i), (ii) and (iii) at least one safener.
  • the present invention relates to a combination which comprises in addition to (i), (ii) and (iii) at least one additional herbicidal active ingredient and at least one safener.
  • the salts of compounds used in the context of the present invention may be used in the form of the respective agronomically acceptable salts, such as alkali metal salts, alkaline earth salts or ammonium salts.
  • S1 a Compounds of the type of dichlorophenylpyrazoline-3-carboxylic acid (S1 a ), preferably compounds such as 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylic acid, ethyl 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate (S1-1) ("mefenpyr(-diethyl)"), and related compounds, as described in WO-A-91/07874; S1 b ) Derivatives of dichlorophenylpyrazolecarboxylic acid (S1 b ), preferably compounds such as ethyl 1-(2,4-dichlorophenyl)-5-
  • S2 a Compounds of the group of 8-quinolinoxy derivatives (S2): S2 a ) Compounds of the type of 8-quinolinoxyacetic acid (S2 a ), preferably 1-methylhexyl (5-chloro-8-quinolinoxy)acetate (common name "cloquintocet-mexyl” (S2-1), 1,3-dimethyl-but-1-yl (5-chloro-8-quinolinoxy)acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolinoxy)acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy)acetate (S2-4), ethyl (5-chloro-8-quinolinoxy)acetate (S2-5), methyl (5-chloro-8-quinolinoxy)acetate (S2-6), allyl (5-chloro-8-quinolinoxy)acetate (S2-7), BCS231017 FC 17.06.2024
  • S3 Active compounds of the type of dichloroacetamides (S3) which are frequently used as pre- emergence safeners (soil-acting safeners), such as, for example, “dichlormid” (N,N-diallyl-2,2-dichloroacetamide) (S3-1), “R-29148” (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine) (S3-2), “R-28725" (3-dichloroacetyl-2,2-dimethyl-1,3-oxazolidine) (S3-3), "benoxacor” (4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine) (S3-4), "PPG-1292” (N-allyl-N-[(1,3-dioxolan-2-yl)methyl]dichloroacetamide) (S35), "DKA-24” (N-allyl-N-[
  • S4 a N-acylsulphonamides of the formula (S4 a ) and salts thereof, as described in WO-A-97/45016 H O H in which RA 1 is (C1-C6)-alkyl, (C3-C6)-cycloalkyl, where the 2 last-mentioned radicals are substituted by vA substituents from the group consisting of halogen, (C1-C4)-alkoxy, halo-(C1-C6)-alkoxy and (C1-C4)-alkylthio and, in the case of cyclic radicals, also (C1-C4)-alkyl and (C1-C4)- haloalkyl; BCS231017 FC 17.06.2024 - 5 - RA 2 is halogen, (C1-C4)-alkyl, (C1-C4)-alkoxy, CF3; mA
  • S5 Active compounds from the class of hydroxyaromatics and aromatic-aliphatic carboxylic acid derivatives (S5), for example ethyl 3,4,5-triacetoxybenzoate, 3,5-dimethoxy-4-hydroxybenzoic acid, 3,5-dihydroxybenzoic acid, 4-hydroxysalicylic acid, 4-fluorosalicyclic acid, 2-hydroxycinnamic acid, 2,4-dichlorocinnamic acid, as described in WO-A-2004/084631, WO-A-2005/015994, WO-A- 2005/016001.
  • S5 Active compounds from the class of hydroxyaromatics and aromatic-aliphatic carboxylic acid derivatives (S5), for example ethyl 3,4,5-triacetoxybenzoate, 3,5-dimethoxy-4-hydroxybenzoic acid, 3,5-dihydroxybenzoic acid, 4-hydroxysalicylic acid, 4-fluorosalicyclic acid, 2-hydroxycinnamic acid, 2,4-dichloro
  • S6 Active compounds from the class of 1,2-dihydroquinoxalin-2-ones (S6), for example 1-methyl-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one, 1-methyl-3-(2-thienyl)-1,2- dihydroquinoxaline-2-thione, 1-(2-aminoethyl)-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one hydrochloride, 1-(2-methylsulphonylaminoethyl)-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one, as described in WO-A-2005/112630.
  • S7 Compounds from the class of diphenylmethoxyacetic acid derivatives (S7), for example BCS231017 FC 17.06.2024 - 7 - methyl diphenylmethoxyacetate (CAS-Reg.Nr.41858-19-9) (S7-1), ethyl diphenylmethoxyacetate, or diphenylmethoxyacetic acid, as described in WO-A-98/38856.
  • S9 Active compounds from the class of 3-(5-tetrazolylcarbonyl)-2-quinolones (S9), for example 1,2-dihydro-4-hydroxy-1-ethyl-3-(5-tetrazolylcarbonyl)-2-quinolone (CAS Reg. No.: 219479-18-2), 1,2-dihydro-4-hydroxy-1-methyl-3-(5-tetrazolylcarbonyl)-2-quinolone (CAS Reg. No.: 95855-00- 8), as described in WO-A-1999/000020.
  • S9 3-(5-tetrazolylcarbonyl)-2-quinolones
  • S11 Active compounds of the type of oxyimino compounds (S11), which are known as seed dressings, such as, for example, “oxabetrinil” ((Z)-1,3-dioxolan-2-ylmethoxyimino(phenyl)acetonitrile) (S11-1), which is known as seed dressing safener for millet against metolachlor damage, "fluxofenim” (1-(4-chlorophenyl)-2,2,2-trifluoro-1-ethanone O-(1,3-dioxolan-2-ylmethyl)oxime) (S11-2), which is known as seed dressing safener for millet against metolachlor damage, and “cyometrinil” or “CGA-43089” ((Z)-cyanomethoxyimino(phenyl)acetonitrile) (S11-3), which is known as seed dressing safener for millet against metolachlor damage.
  • oxabetrinil
  • S12 Active compounds from the class of isothiochromanones (S12), such as, for example, methyl [(3- oxo-1H-2-benzothiopyran-4(3H)-ylidene)methoxy]acetate (CAS Reg. No.: 205121-04-6) (S12-1) and related compounds from WO-A-1998/13361.
  • S12 isothiochromanones
  • S13 One or more compounds from group (S13): “naphthalic anhydrid” (1,8-naphthalenedicarboxylic anhydride) (S13-1), which is known as seed dressing safener for corn against thiocarbamate herbicide damage, "fenclorim” (4,6-dichloro-2-phenylpyrimidine) (S13-2), which is known as safener for pretilachlor in sown rice, "flurazole” (benzyl 2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate) (S13-3), which is known as seed dressing safener for millet against alachlor and metolachlor damage, "CL 304415” (CAS Reg.
  • compositions within the context of the present invention comprise in addition to the combinations according to the invention one or more further component(s) selected from the group consisting of formulation auxiliaries, additives customary in crop protection, and further agrochemically active compounds.
  • fenchlorazole-ethyl S1
  • mefenpyr-diethyl S2
  • isoxadifen-ethyl S3
  • cyprosulfamide S4
  • cloquintocet-mexyl S5
  • fenclorim S6
  • dichlormid S7
  • benoxacor S8
  • furilazole S9
  • oxabetrinil S10
  • fluxofenim S11
  • flurazole S12
  • naphthalic anhydride S13
  • mefenpyr-diethyl (S2), isoxadifen-ethyl (S3), cyprosulfamide (S4) or cloquintocet-mexyl (S5) is the safener.
  • mefenpyr-diethyl (S2) or cloquintocet- mexyl (S5) is the safener.
  • the weight ratio of the combination according to the invention can be described by the weight of the total amount of component (i) to the total amount of component (ii) and the weight of the total amount of component (i) to the total amount of component (iii), which is as follows: (i) to (ii) in the range of from 125 : 1 to 1 : 125 and for (i) to (iii) in the range of from 60 : 1 to 1 : 60.
  • the ratio by weight of the total amount of component (i) to the total amount of component (ii) in a herbicide combination according to the present invention is in the range of from 25 : 1 to 1 : 25 and for (i) to (iii) in the range of from 10 : 1 to 1: 10.
  • the ratio by weight of the total amount of component (i) to the total amount of component (ii) in a herbicide combination according to the present invention is in the range of from 10 : 1 to 1 : 10 and for (i) to (iii) in the range of from 5 : 1 to 1: 5.
  • the synergistic effects allow a reduction in the amount expended the combating of a broader spectrum of weeds, a faster onset of the herbicidal action, a longer lasting action, better control of the harmful plants, with only one or a few applications, and a broadening of the possible application period.
  • the properties and advantages mentioned are of use for controlling harmful plants or unwanted vegetation and accordingly to safeguard and/or to increase the yields in terms of quality and quantity.
  • the technical standard is, with regard to the properties described, clearly exceeded by these new combinations.
  • the combination(s)/composition(s) according to the present invention can be employed for controlling harmful plants in genetically modified crops or crops obtained by mutation/selection.
  • crops are distinguished as a rule by particular, advantageous properties, such as resistances to herbicidal combinations/compositions or resistances to plant diseases or causative agents of plant diseases such as particular insects or microorganisms such as fungi, bacteria or viruses.
  • Other particular properties relate, for example, to the harvested material with regard to quantity, quality, storability, composition and specific constituents.
  • transgenic plants are known whose starch content is increased or whose starch quality is altered, or those where the harvested material has a different fatty acid composition.
  • the present invention also relates to a method for controlling harmful plants or unwanted vegetation, which comprises applying a herbicide combination/composition according to the present invention by pre- emergence, early post-emergence or post-emergence treatment to harmful plants or unwanted vegetation, parts of said harmful plants or unwanted vegetation, or the area where the harmful plants or unwanted vegetation grow, for example the area under cultivation.
  • a herbicide combination/composition according to the present invention by pre- emergence, early post-emergence or post-emergence treatment to harmful plants or unwanted vegetation, parts of said harmful plants or unwanted vegetation, or the area where the harmful plants or unwanted vegetation grow, for example the area under cultivation.
  • controlling denotes a significant reduction of the growth of the harmful plant(s) in comparison to the untreated harmful plants.
  • the growth of the harmful plant(s) is essentially diminished (60-79%), more preferably the growth of the harmful plant(s) is largely or fully suppressed (80-100%), and in particular the growth of the harmful plant(s) is almost fully or fully suppressed (90-100%).
  • the herbicide combination(s)/composition(s) according to the present invention is applied to the soil surface before or after germination of the crop plant but prior to emergence from the soil, the treatment is a pre-emergence treatment.
  • the herbicide combination(s)/composition(s) according to the present invention is applied to the soil surface after emergence of the crop plant, the treatment is a post-emergence treatment. Preferred is the use as pre-emergence herbicide and post-emergence herbicide.
  • the combination according to the invention can be used for many crop plants, preferably cereals (e.g. in wheat and barley). They are also very suitable for use in transgenic crops. Most preferred is the use as pre-emergence and early post-emergence herbicide in cereals.
  • the application rates (indicated as g/ha i.e.
  • grams of active ingredient per hectare), of the herbicide combination (i), (ii) and (iii)) used in the context of the present invention are as defined as follows: (i) in g/ha (ii) in g/ha (iii) in g/ha 2500 to 100 250 to 20 6000 to 1000 Preferably 1000 to 200 150 to 40 5000 to 1500 More preferably 600 to 300 120 to 60 4000 to 2400 Table 1
  • the herbicide combination(s)/composition(s) according to the present invention have an outstanding herbicidal activity against a broad spectrum of economically important harmful monocotyledonous and dicotyledonous harmful plants.
  • Examples of monocotyledonous harmful plants on which the herbicide combination/composition according to the present invention act efficiently are from amongst the genera Hordeum spp., Echinochloa spp., Poa spp., Bromus spp., Digitaria spp., Eriochloa spp., Setaria spp., Pennisetum spp., Phalaris sp., Eleusine spp., Eragrostis spp., Panicum spp., Lolium spp., Alopecurus sp., Apera sp.
  • Brachiaria spp. Leptochloa spp., Avena spp., Cyperus spp., Axonopris spp., Sorghum spp., and Melinus spp..
  • monocotyledonous harmful plants species on which the herbicide combination/composition according to the present invention act efficiently are selected from amongst the species Hordeum murinum, Echinochloa crus-galli, Poa annua, Bromus rubens L., Bromus rigidus, Bromus secalinus L., Digitaria insularis, Digitaria sanguinalis, Eriochloa gracilis, Setaria faberi, Setaria viridis, Pennisetum glaucum, Eleusine indica, Eragrostis pectinacea, Panicum miliaceum, Phalaris minor, Lolium multiflorum, Lolium rigidum, Lolium perenne, Brachiaria platyphylla
  • Examples of dicotyledonous harmful plants on which the herbicide combination/composition according to the present invention act efficiently are from amongst the genera Amaranthus spp., Polygonum spp., Medicago spp., Mollugo spp., Cyclospermum spp., Stellaria spp., Gnaphalium spp., Taraxacum spp., Oenothera spp., Amsinckia spp., Erodium spp., Erigeron spp., Senecio spp., Lamium spp., Kochia spp., Chenopodium spp., Lactuca spp., Malva spp., Ipomoea spp., Brassica spp., Sinapis spp., Urtica spp., Sida spp, Portulaca spp., Richardia spp., Ambrosia spp.,
  • Bidens spp. Veronica spp., and Hypochaeris spp..
  • dicotyledonous harmful plants species on which the herbicide combination/composition according to the present invention act efficiently are selected from amongst the species Amaranthus spinosus, Amaranthus palmer, Amaranthis rudis, Polygonum convolvulus, Medicago polymorpha, Mollugo verticillata, Cyclospermum leptophyllum, Stellaria media, Gnaphalium purpureum, Taraxacum offi cinale, Oenothera laciniata, Amsinckia intermedia, Erodium cicutarium, Erodium moschatum, Erigeron bonariensis, Senecio vulgaris, Lamium sp., Erigeron canadensis, Polygonum aviculare, Kochia scoparia, Chenopodium album, Lactuca serriola, Malva parviflora, Malva neglecta, I
  • the herbicide combination(s)/composition(s) according to the present invention are easily and readily obtained, by combining the components (i), (ii) and (iii) in the ratio by weight as defined in the context of the present invention, for example by mixing the appropriate amounts of components (i), (ii) and (iii).
  • the present invention relates to a method for producing combination(s) of herbicides according to the present invention and to a method of producing the composition(s) according to the present invention comprising the steps of (a) providing component (i), (b) providing component (ii), (c) providing component (iii), (c) combining component (i), component (ii) and component (iii), such that a combination of herbicides according to the present invention or a composition according to the present invention is obtained.
  • the herbicides (i), (ii) and (iii) used in the herbicide combination(s)/composition(s) according to the present invention are applied once, twice or three times per Gregorian calendar year, i.e.
  • the herbicides (i), (ii) and (iii) as defined herein can be used together with other agrochemically active compounds, for example from the group of safener, fungicides, insecticides, other herbicides and other plant growth regulators, or with formulation auxiliaries and additives customary in crop protection. Additives are, for example, fertilizers and colorants.
  • the herbicide combination(s)/composition(s) according to the present invention cannot only be used as mixed formulations which are then applied in the customary manner as a dilution with water, but also as so- called tank mixes by jointly diluting the separately formulated, or partially separately formulated, components with water.
  • the herbicide combination(s)/composition(s) according to the present invention can be formulated in various ways, depending on the prevailing biological and/or chemical-physical parameters.
  • Wettable powders are products which are uniformly dispersible in water and which, besides the active compound, also comprise ionic or nonionic surfactants (wetters, dispersants), for example polyoxethylated alkylphenols, polyethoxylated fatty alcohols or fatty amines, alkanesulfonates or alkylbenzenesulfonates, sodium lignosulfonate, sodium 2,2’-dinaphthylmethane-6,6’-disulfonate, sodium dibutylnaphthalenesulfonate or else sodium oleoylmethyltauride, in addition to a diluent or inert material.
  • ionic or nonionic surfactants for example polyoxethylated alkylphenols, polyethoxylated fatty alcohols or fatty amines, alkanesulfonates or alkylbenzenesulfonates, sodium lignosulfonate
  • Emulsifiable concentrates are prepared by dissolving the active compound in an organic solvent, for example butanol, cyclohexanone, dimethylformamide, xylene or else higher-boiling aromatics or hydrocarbons with addition of one or more ionic or nonionic surfactants (emulsifiers).
  • organic solvent for example butanol, cyclohexanone, dimethylformamide, xylene or else higher-boiling aromatics or hydrocarbons with addition of one or more ionic or nonionic surfactants (emulsifiers).
  • emulsifiers which may be used are: calcium salts of alkylarylsulfonic acids, such as calcium dodecylbenzene sulfonate, or nonionic emulsifiers such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide/ethylene oxide condensates, alkyl polyethers, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters or polyoxethylene sorbitol esters.
  • alkylarylsulfonic acids such as calcium dodecylbenzene sulfonate
  • nonionic emulsifiers such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide/ethylene oxide condensates, alkyl polyethers, sorbitan fatty acid esters, polyoxyethylene sorbitan
  • Dusts are obtained by grinding the active compound with finely divided solid materials, for example talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
  • BCS231017 FC 17.06.2024 - 16 - Suspension concentrates (SC) can be water- or oil-based. They can be prepared, for example, by wet grinding by means of commercially available bead mills and, if appropriate, addition of further surfactants as they have already been mentioned for example above in the case of the other formulation types.
  • Emulsions for example oil-in-water emulsions (EW) can be prepared for example by means of stirrers, colloid mills and/or static mixers using aqueous organic solvents and, if appropriate, further surfactants as have already been mentioned for example above in the case of the other formulation types.
  • Granules can be prepared either by spraying the active compound onto adsorptive, granulated inert material or by applying active compound concentrates to the surface of carriers such as sand, kaolinites or granulated inert material with the aid of binders, for example polyvinyl alcohol, sodium polyacrylate or else mineral oils.
  • Suitable active compounds may also be granulated in the manner conventionally used for the production of fertilizer granules, if desired in a mixture with fertilizers.
  • water-dispersible granules are prepared by customary processes such as spray drying, fluidized-bed granulation, disk granulation, mixing with high-speed mixers and extrusion without solid inert material.
  • disk granules fluidized-bed granules, extruder granules and spray granules, see, for example, the methods in "Spray-Drying Handbook" 3rd ed. 1979, G. Goodwin Ltd., London; J.E.
  • the agrochemical formulations comprise 1 to 95% by weight, of active compounds, the following concentrations being customary, depending on the type of formulation:
  • the active compound concentration in wettable powders is, for example, approximately 10 to 95% by weight, the remainder to 100% by weight being composed of customary formulation constituents.
  • the active compound concentration may amount to, for example, 5 to 80% by weight.
  • Formulations in the form of dusts comprise, in most cases, 5 to 20% by weight of active compound, sprayable solutions approximately 0.2 to 25% by weight of active compound.
  • the active compound content depends partly on whether the active compound is present in liquid or solid form and on which granulation auxiliaries and fillers are being used. As a rule, the content amounts to between 10 and 90% by weight in the case of the water-dispersible granules.
  • the abovementioned active compound formulations may comprise, if appropriate, the conventional adhesives, wetters, dispersants, emulsifiers, preservatives, antifreeze agents, solvents, fillers, colorants, carriers, antifoams, evaporation inhibitors, pH regulators or viscosity regulators.
  • the herbicidal action of the herbicide combinations according to the present invention can be improved, for example, by surfactants, preferably by wetters from the group of the fatty alcohol polyglycol ethers.
  • the fatty alcohol polyglycol ethers preferable contain 10 – 18 carbon atoms in the fatty alcohol radical and 2 – 20 ethylene oxide units in the polyglycol ether moiety.
  • the fatty alcohol polyglycol ethers can be nonionic or ionic, for example in the form of fatty alcohol polyglycol ethers sulfates, which can be used, for example, as alkali metal salts (e.g.
  • Nonionic fatty alcohol polyglycol ethers are, for example, (C 10 -C 18 )-, preferably (C 10 -C 14 )-fatty alkohol polyglycol ethers containing 2 – 20, preferably 3 – 15, ethylene oxide units (e.g. isotridecyl alcohol polyglycol ether), for example from the Genapol ® series, such as Genapol ® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).
  • Genapol ® series such as Genapol ® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).
  • the present invention furthermore embraces the combination of herbicides (i), (ii) and (iii) as defined above with the wetting agents mentioned above from the group of the fatty alcohol polyglycolethers which preferably contain 10 - 18 carbon atoms in the fatty alcohol radical and 2 - 20 ethylene oxide units in the polyglycol ether moiety and which can be present in nonionic or ionic form (for example as fatty alcohol polyglycol ether sulfates).
  • C 12 /C 14 -fatty alcohol diglycol ether sulfate sodium (Genapol ® LRO, Clariant); and isotridecyl alcohol polyglycol ether with 3 - 15 ethylene oxide units, for example from the Genapol ® X series, such as Genapol ® X-030, Genapol ® X-060, Genapol ® X-080 or Genapol ® X-150 (all from Clariant GmbH).
  • fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (for example fatty alcohol polyglycol ether sulfates) are also suitable for use as penetrants and activity enhancers for a number of other herbicides, inter alia also for herbicides from the group of the imidazolinones (see, for example, EP-A-0502014).
  • fatty alcohol polyglycol ethers such as nonionic or ionic fatty alcohol polyglycol ethers (for example fatty alcohol polyglycol ether sulfates) are also suitable as penetrants and synergists for a number of other herbicides, inter alia also herbicides from the group of the imidazolinones; (see, for example, EP-A-0502014).
  • the herbicidal effect of the herbicide combinations according to the present invention can also be increased using vegetable oils.
  • vegetable oils is to be understood as meaning oils from oil-plant species, such as soya oil, rapeseed oil, corn oil, sunflower oil, cottonseed oil, linseed oil, coconut oil, palm oil, safflower oil or castor oil, in particular rapeseed oil, and their transesterification products, for example alkyl esters, such as rapeseed oil methyl ester or rapeseed oil ethyl ester.
  • the vegetable oils are preferably esters of C10-C22-, preferably C12-C20-fatty acids.
  • the C10-C22-fatty acid esters are, for example, esters of unsaturated or saturated C10-C22-fatty acids, in particular those with an even BCS231017 FC 17.06.2024 - 18 - number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and, in particular, C18-fatty acids such as stearic acid, oleic acid, linoleic acid or linolenic acid.
  • Preferred C1-C20-alkyl-C10-C22-fatty acid esters are the methyl, ethyl, propyl, butyl, 2-ethylhexyl and dodecyl esters.
  • Preferred glycol- and glycerol-C10-C22-fatty acid esters are the uniform or mixed glycol esters and glycerol esters of C10-C22-fatty acids, in particular those fatty acids which have an even number of carbon atoms, for example erucic acid, lauric acid, palmitic acid and, in particular, C18-fatty acids such as stearic acid, oleic acid, linolic acid or linolenic acid.
  • the vegetable oils can be present in the herbicidal compositions according to the present invention for example in the form of commercially available oil-containing formulation additives, in particular those based on rapeseed oil such as Hasten ® (Victorian Chemical Company, Australia, hereinbelow termed Hasten, main constituent: rapeseed oil ethyl ester), Actirob ® B (Novance, France, hereinbelow termed ActirobB, main constituent: rapeseed oil methyl ester), Rako-Binol ® (Bayer AG, Germany, termed Rako- Binol hereinbelow, main constituent: rapeseed oil), Renol ® (Stefes, Germany, termed Renol hereinbelow, vegetable oil constituent: rapeseed oil methyl ester), or Stefes Mero ® (Stefes, Germany, hereinbelow termed Mero, main constituent: rapeseed oil methyl ester).
  • Hasten Vanictori
  • the formulations which are present in commercially available form, are optionally diluted in the customary manner, for example using water in the case of wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules.
  • Preparations in the form of dusts, soil granules, granules for broadcasting and sprayable solutions are usually not diluted further with other inert substances prior to use.
  • a herbicide combination according to the present invention and a composition comprising the herbicide combination as defined in the context of the present invention are preferably applied to the harmful plants or undesired plants or parts thereof, seeds of the plants or the area under cultivation (soil of a field), preferably to the green of the harmful plants or parts thereof, or to the green parts of the undesired plants or parts thereof.
  • a composition comprising a herbicide combination used in the context of the present invention has the advantage of being easier to apply since the quantities of the components are already presented in the correct ratio to each other. Moreover, the adjuvants in the formulation can be matched optimally to each other.
  • the present invention further relates to the use of combination of herbicides according to the present invention (preferably in one of the preferred embodiments defined herein) or a composition according to the present invention (preferably in one of the preferred embodiments defined herein) in the field of agriculture, in particular as plant growth regulators and/or for controlling harmful plants or undesired plant growth.
  • BCS231017 FC 17.06.2024 - 19 - Examples The following data are the results of a greenhouse investigation in which the herbicide combination according to the present invention was tested against various monocotyledonous and dicotyledonous weeds after an pre emergence application and an early-post emergence application (BBCH 10-11).
  • weeds were selected for testing: Target Bayer code Species Echinochloa crus-galli ECHCG Barnyardgrass, common Hordeum murinum HORMU Wall barley Lolium rigidum LOLRI Ryegrass, rigid Setaria viridis SETVI Foxtail, green Matricaria inodora MATIN Daisy, horse Polygonum convolvulus POLCO Buckwheat, wild Pharbitis purpurea PHBPU Morningglory, common Table 1
  • seeds of the above mentioned species were sown in 7 cm pots containing standard soil (14,7% sand, 19,9% clay, 65,4% silt and 1,8% organic matter) covered with 0,5 cm depth of sandy soil, lightly irrigated from above and used for the pre emergence trial.
  • the pots were placed in a glasshouse (with conditions of 16 hour day and 8 hour night, 21°C day and 12°C night and 60% relative humidity) and irrigated from above to allow the seeds to germinate and grow. Once they had reached the required growth stage BBCH 10-11 the propagated plants were used for the early post emergence trial.
  • the herbicide application was done with a track sprayer at a spray volume of 300 l water/ha using a flat fan nozzle XR 8001 at a pressure of 1.8 bar.
  • the formulations shown in the table 2 were used.
  • the methylated rape seed oil adjuvant Mero® was added to each application liquid with 1 l/ha.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne principalement des combinaisons herbicides comprenant (i) de l'aclonifène (ii) du diflufénican et (iii) du prosulfocarb et des compositions comprenant lesdites combinaisons herbicides. La présente invention concerne en outre un procédé de production desdites combinaisons et compositions herbicides. La présente invention concerne également l'utilisation desdites combinaisons et compositions herbicides dans le domaine de l'agriculture et pour lutter contre des plantes nuisibles.
PCT/EP2024/074170 2023-08-30 2024-08-29 Combinaisons herbicides Pending WO2025045998A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP23194234 2023-08-30
EP23194234.3 2023-08-30

Publications (1)

Publication Number Publication Date
WO2025045998A1 true WO2025045998A1 (fr) 2025-03-06

Family

ID=87863617

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2024/074170 Pending WO2025045998A1 (fr) 2023-08-30 2024-08-29 Combinaisons herbicides

Country Status (2)

Country Link
AR (1) AR133702A1 (fr)
WO (1) WO2025045998A1 (fr)

Citations (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3836524A (en) 1973-04-26 1974-09-17 Stauffer Chemical Co Preparation of esters of thiocarbamic acids
DE2831262A1 (de) 1978-07-15 1980-01-31 Celamerck Gmbh & Co Kg 2-chlor-6-nitroaniline
EP0048436A1 (fr) 1980-09-20 1982-03-31 Hoechst Aktiengesellschaft Agents herbicides
EP0086750A2 (fr) 1982-02-17 1983-08-24 Ciba-Geigy Ag Utilisation de dérivés de la quinoléine pour la protection de plantes cultivables
EP0094349A2 (fr) 1982-05-07 1983-11-16 Ciba-Geigy Ag Utilisation de dérivés de quinoléine pour protéger des plantes cultivées
JPS6087254A (ja) 1983-10-19 1985-05-16 Japan Carlit Co Ltd:The 新規尿素化合物及びそれを含有する除草剤
EP0174562A2 (fr) 1984-09-11 1986-03-19 Hoechst Aktiengesellschaft Agents pour la protection de plantes basés sur des dérivés de 1,2,4- briazole ainsi que dérivés 1,2,4-triazole
EP0191736A2 (fr) 1985-02-14 1986-08-20 Ciba-Geigy Ag Utilisation de dérivés de la quinoléine pour la protection de plantes cultivables
EP0268554A2 (fr) 1986-10-22 1988-05-25 Ciba-Geigy Ag Dérivés d'acide diphényl-1,5-pyrazol-3-carbonique pour la protection de plantes de culture
EP0269806A1 (fr) 1986-10-04 1988-06-08 Hoechst Aktiengesellschaft Dérivés d'acide phénylpyrazolcarbonique, leur préparation et leur utilisation comme agents régulateurs de croissance des plantes et antidote
EP0333131A1 (fr) 1988-03-17 1989-09-20 Hoechst Aktiengesellschaft Agent de protection des plantes à base de dérivés d'acide pyrazolcarboxylique
EP0336151A2 (fr) 1988-03-18 1989-10-11 Hoechst Aktiengesellschaft Agent herbicide liquide
EP0346620A1 (fr) 1988-05-20 1989-12-20 Hoechst Aktiengesellschaft Agents phytoprotecteurs contenant des dérivés du 1,2,4-triazole ainsi que dérivés du 1,2,4-triazole
EP0365484A1 (fr) 1988-10-20 1990-04-25 Ciba-Geigy Ag Sulfamoylphénylurées
WO1991007874A1 (fr) 1989-11-30 1991-06-13 Hoechst Aktiengesellschaft Pyrazoline pour la protection de plantes cultivees contre les herbicides
WO1991008202A1 (fr) 1989-11-25 1991-06-13 Hoechst Aktiengesellschaft Isoxazolines, procede de preparation et application comme produits phytosanitaires
EP0476555A2 (fr) 1990-09-15 1992-03-25 Hoechst Schering AgrEvo GmbH Agents herbicides synergiques
EP0492366A2 (fr) 1990-12-21 1992-07-01 Hoechst Schering AgrEvo GmbH Nouveaux dérivés de chloro-5-quinoline-8-acide oxyalkanecarboniques, procédé pour leur préparation et leur utilisation comme antidote d'herbicides
EP0502014A1 (fr) 1989-11-21 1992-09-09 Hoechst Ag Agents herbicides.
EP0531116A1 (fr) 1991-09-04 1993-03-10 Rhone-Poulenc Agriculture Ltd. Compositions herbicides
EP0582198A2 (fr) 1992-08-01 1994-02-09 Hoechst Schering AgrEvo GmbH Composés (hétéro-)aryliques substitués, procédé pour leur préparation, compositions les contenant et leur utilisation comme agents de protection
WO1995007897A1 (fr) 1993-09-16 1995-03-23 Hoechst Schering Agrevo Gmbh Isoxazolines substituees, leur procede de preparation, agents les contenant et leur utilisation comme reducteurs de phytotoxicite
US5674809A (en) 1993-05-19 1997-10-07 Rhone-Poulenc Agrochimie Herbicidal mixtures comprising diflufenican and a substituted 3-phenylpyrazole
WO1997045016A1 (fr) 1996-05-29 1997-12-04 Hoechst Schering Agrevo Gmbh Nouveaux n-acylsulfonamides, nouveaux melanges d'herbicides et d'antidotes et leur utilisation
WO1998013361A1 (fr) 1996-09-26 1998-04-02 Novartis Ag Composition herbicide
WO1998027049A1 (fr) 1996-12-19 1998-06-25 Hoechst Schering Agrevo Gmbh Nouveaux derives d'acide 2-fluoroacrylique, nouveaux melanges d'herbicides et d'antidotes et leur utilisation
WO1998038856A1 (fr) 1997-03-04 1998-09-11 Zeneca Limited Compositions pour proteger du riz contre l'acetochlore
WO1999000020A1 (fr) 1997-06-27 1999-01-07 Hoechst Schering Agrevo Gmbh 3-(5-tetrazolylcarbonyle)-2-quinolones et produits phytosanitaires pour plantes utiles les contenant
WO1999016744A1 (fr) 1997-09-29 1999-04-08 Aventis Cropscience Gmbh Amides d'acide benzoique d'acylsulfamoyle, agents phytosanitaires les contenant et procede permettant de les preparer
WO2002034048A1 (fr) 2000-10-23 2002-05-02 Syngenta Participations Ag Compositions agrochimiques avec des phytoprotecteurs a base de quinoline
WO2004084631A1 (fr) 2003-03-26 2004-10-07 Bayer Cropscience Gmbh Utilisation de composés aromatiques hydroxy comme phytoprotecteurs
WO2005015994A1 (fr) 2003-08-05 2005-02-24 Bayer Cropscience Gmbh Utilisation d'aromates hydroxy comme phytoprotecteurs
WO2005016001A1 (fr) 2003-08-05 2005-02-24 Bayer Cropscience Gmbh Agents phytoprotecteurs a base de derives d'acide carboxylique aromatiques-aliphatiques
WO2005112630A1 (fr) 2004-05-12 2005-12-01 Bayer Cropscience Gmbh Derives de quinoxalin-2-one, phytoprotecteurs pour plantes utiles contenant ces derives, procede de production et utilisation desdits derives
WO2007023764A1 (fr) 2005-08-26 2007-03-01 Kumiai Chemical Industry Co., Ltd. Agent servant à réduire les effets nocifs d’un herbicide et composition d’herbicide ayant des effets nocifs réduits
WO2007023719A1 (fr) 2005-08-22 2007-03-01 Kumiai Chemical Industry Co., Ltd. Agent servant à réduire l'attaque chimique et composition herbicide produisant une attaque chimique réduite
DE102006056207A1 (de) * 2006-11-29 2008-06-05 Bayer Cropscience Ag Herbizide Mittel enthaltend Diflufenican
WO2008131860A2 (fr) 2007-04-30 2008-11-06 Bayer Cropscience Ag Pyridone-carboxamides, phytoprotecteurs contenant ces composés, procédés pour leur production et leur utilisation
WO2008131861A1 (fr) 2007-04-30 2008-11-06 Bayer Cropscience Ag Utilisation de pyridin-2-oxy-3-carbonamides comme phytoprotecteurs
WO2009106259A1 (fr) 2008-02-27 2009-09-03 Bayer Cropscience Ag Combinaisons d'herbicides contenant du diflufenican
CN101838227A (zh) 2010-04-30 2010-09-22 孙德群 一种苯甲酰胺类除草剂的安全剂
WO2014095619A1 (fr) * 2012-12-18 2014-06-26 Bayer Cropscience Ag Agents herbicides contenant de l'aclonifène

Patent Citations (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3836524A (en) 1973-04-26 1974-09-17 Stauffer Chemical Co Preparation of esters of thiocarbamic acids
DE2831262A1 (de) 1978-07-15 1980-01-31 Celamerck Gmbh & Co Kg 2-chlor-6-nitroaniline
EP0048436A1 (fr) 1980-09-20 1982-03-31 Hoechst Aktiengesellschaft Agents herbicides
US4400196A (en) 1980-09-20 1983-08-23 Hoechst Aktiengesellschaft Herbicidal compositions
EP0086750A2 (fr) 1982-02-17 1983-08-24 Ciba-Geigy Ag Utilisation de dérivés de la quinoléine pour la protection de plantes cultivables
EP0094349A2 (fr) 1982-05-07 1983-11-16 Ciba-Geigy Ag Utilisation de dérivés de quinoléine pour protéger des plantes cultivées
JPS6087254A (ja) 1983-10-19 1985-05-16 Japan Carlit Co Ltd:The 新規尿素化合物及びそれを含有する除草剤
EP0174562A2 (fr) 1984-09-11 1986-03-19 Hoechst Aktiengesellschaft Agents pour la protection de plantes basés sur des dérivés de 1,2,4- briazole ainsi que dérivés 1,2,4-triazole
EP0191736A2 (fr) 1985-02-14 1986-08-20 Ciba-Geigy Ag Utilisation de dérivés de la quinoléine pour la protection de plantes cultivables
EP0269806A1 (fr) 1986-10-04 1988-06-08 Hoechst Aktiengesellschaft Dérivés d'acide phénylpyrazolcarbonique, leur préparation et leur utilisation comme agents régulateurs de croissance des plantes et antidote
EP0268554A2 (fr) 1986-10-22 1988-05-25 Ciba-Geigy Ag Dérivés d'acide diphényl-1,5-pyrazol-3-carbonique pour la protection de plantes de culture
EP0333131A1 (fr) 1988-03-17 1989-09-20 Hoechst Aktiengesellschaft Agent de protection des plantes à base de dérivés d'acide pyrazolcarboxylique
EP0336151A2 (fr) 1988-03-18 1989-10-11 Hoechst Aktiengesellschaft Agent herbicide liquide
EP0346620A1 (fr) 1988-05-20 1989-12-20 Hoechst Aktiengesellschaft Agents phytoprotecteurs contenant des dérivés du 1,2,4-triazole ainsi que dérivés du 1,2,4-triazole
EP0365484A1 (fr) 1988-10-20 1990-04-25 Ciba-Geigy Ag Sulfamoylphénylurées
EP0502014A1 (fr) 1989-11-21 1992-09-09 Hoechst Ag Agents herbicides.
WO1991008202A1 (fr) 1989-11-25 1991-06-13 Hoechst Aktiengesellschaft Isoxazolines, procede de preparation et application comme produits phytosanitaires
WO1991007874A1 (fr) 1989-11-30 1991-06-13 Hoechst Aktiengesellschaft Pyrazoline pour la protection de plantes cultivees contre les herbicides
EP0476555A2 (fr) 1990-09-15 1992-03-25 Hoechst Schering AgrEvo GmbH Agents herbicides synergiques
EP0492366A2 (fr) 1990-12-21 1992-07-01 Hoechst Schering AgrEvo GmbH Nouveaux dérivés de chloro-5-quinoline-8-acide oxyalkanecarboniques, procédé pour leur préparation et leur utilisation comme antidote d'herbicides
EP0531116A1 (fr) 1991-09-04 1993-03-10 Rhone-Poulenc Agriculture Ltd. Compositions herbicides
EP0582198A2 (fr) 1992-08-01 1994-02-09 Hoechst Schering AgrEvo GmbH Composés (hétéro-)aryliques substitués, procédé pour leur préparation, compositions les contenant et leur utilisation comme agents de protection
US5674809A (en) 1993-05-19 1997-10-07 Rhone-Poulenc Agrochimie Herbicidal mixtures comprising diflufenican and a substituted 3-phenylpyrazole
WO1995007897A1 (fr) 1993-09-16 1995-03-23 Hoechst Schering Agrevo Gmbh Isoxazolines substituees, leur procede de preparation, agents les contenant et leur utilisation comme reducteurs de phytotoxicite
WO1997045016A1 (fr) 1996-05-29 1997-12-04 Hoechst Schering Agrevo Gmbh Nouveaux n-acylsulfonamides, nouveaux melanges d'herbicides et d'antidotes et leur utilisation
WO1998013361A1 (fr) 1996-09-26 1998-04-02 Novartis Ag Composition herbicide
WO1998027049A1 (fr) 1996-12-19 1998-06-25 Hoechst Schering Agrevo Gmbh Nouveaux derives d'acide 2-fluoroacrylique, nouveaux melanges d'herbicides et d'antidotes et leur utilisation
WO1998038856A1 (fr) 1997-03-04 1998-09-11 Zeneca Limited Compositions pour proteger du riz contre l'acetochlore
WO1999000020A1 (fr) 1997-06-27 1999-01-07 Hoechst Schering Agrevo Gmbh 3-(5-tetrazolylcarbonyle)-2-quinolones et produits phytosanitaires pour plantes utiles les contenant
WO1999016744A1 (fr) 1997-09-29 1999-04-08 Aventis Cropscience Gmbh Amides d'acide benzoique d'acylsulfamoyle, agents phytosanitaires les contenant et procede permettant de les preparer
WO2002034048A1 (fr) 2000-10-23 2002-05-02 Syngenta Participations Ag Compositions agrochimiques avec des phytoprotecteurs a base de quinoline
WO2004084631A1 (fr) 2003-03-26 2004-10-07 Bayer Cropscience Gmbh Utilisation de composés aromatiques hydroxy comme phytoprotecteurs
WO2005015994A1 (fr) 2003-08-05 2005-02-24 Bayer Cropscience Gmbh Utilisation d'aromates hydroxy comme phytoprotecteurs
WO2005016001A1 (fr) 2003-08-05 2005-02-24 Bayer Cropscience Gmbh Agents phytoprotecteurs a base de derives d'acide carboxylique aromatiques-aliphatiques
WO2005112630A1 (fr) 2004-05-12 2005-12-01 Bayer Cropscience Gmbh Derives de quinoxalin-2-one, phytoprotecteurs pour plantes utiles contenant ces derives, procede de production et utilisation desdits derives
WO2007023719A1 (fr) 2005-08-22 2007-03-01 Kumiai Chemical Industry Co., Ltd. Agent servant à réduire l'attaque chimique et composition herbicide produisant une attaque chimique réduite
WO2007023764A1 (fr) 2005-08-26 2007-03-01 Kumiai Chemical Industry Co., Ltd. Agent servant à réduire les effets nocifs d’un herbicide et composition d’herbicide ayant des effets nocifs réduits
DE102006056207A1 (de) * 2006-11-29 2008-06-05 Bayer Cropscience Ag Herbizide Mittel enthaltend Diflufenican
WO2008131860A2 (fr) 2007-04-30 2008-11-06 Bayer Cropscience Ag Pyridone-carboxamides, phytoprotecteurs contenant ces composés, procédés pour leur production et leur utilisation
WO2008131861A1 (fr) 2007-04-30 2008-11-06 Bayer Cropscience Ag Utilisation de pyridin-2-oxy-3-carbonamides comme phytoprotecteurs
WO2009106259A1 (fr) 2008-02-27 2009-09-03 Bayer Cropscience Ag Combinaisons d'herbicides contenant du diflufenican
CN101838227A (zh) 2010-04-30 2010-09-22 孙德群 一种苯甲酰胺类除草剂的安全剂
WO2014095619A1 (fr) * 2012-12-18 2014-06-26 Bayer Cropscience Ag Agents herbicides contenant de l'aclonifène

Non-Patent Citations (12)

* Cited by examiner, † Cited by third party
Title
"Factors Affecting Herbicidal Activity and Selectivity", PROC. EWRS SYMP., 1988, pages 227 - 232
"Growth stages of mono-and dicotyledonous plants", 2001, FEDERAL BIOLOGICAL RESEARCH CENTRE FOR AGRICULTURE AND FORESTRY
"The Pesticide Manual", 2012, THE BRITISH CROP PROTECTION COUNCIL AND THE ROYAL SOC. OF CHEMISTRY
G.C. KLINGMAM: "Weed Control as a Science", 1961, JOHN WILEY AND SONS, pages: 81 - 96
H.V. OLPHEN: "Handbook of Insecticide Dust Diluents and Carriers", 1950, J. WILEY & SONS
J.D. FREYERS.A. EVANS: "Weed Control Handbook", 1968, BLACKWELL SCIENTIFIC PUBLICATIONS, pages: 101 - 103
J.E. BROWNING: "Agglomeration", 1967, CHEMICAL AND ENGINEERING, pages: 147
K. MARTENS: "Spray-Drying Handbook", 1979, G. GOODWIN LTD.
MCCUTCHEON'S: "Encyclopedia of Surface Active Agents", 1964, CHEM. PUBL. CO. INC.
SCHONFELDT: "Grenzflachenaktive Athylenoxidaddukte", 1976, WISS. VERLAGSGESELLSCHAFT
VALKENBURG: "Perry's Chemical Engineer's Handbook", 1973, MARCEL DEKKER, pages: 8 - 57
WINNACKER-KÜCHLER: "Chemische Technologie", vol. 7, 1986, C. HAUSER VERLAG MUNICH

Also Published As

Publication number Publication date
AR133702A1 (es) 2025-10-22

Similar Documents

Publication Publication Date Title
US10869478B2 (en) Uses of 2-(2,4-dichlorophenyl)methyl-4,4-dimethyl-3-isoxazolidone as foliar herbicide
EP3506747B1 (fr) Methode de reduction des dommages aux plantes cultivees
EP3866599B1 (fr) Combinaisons d'herbicides
EP3639664A1 (fr) Combinaisons d'herbicides
US11219209B2 (en) Method of reducing crop damage
US20240276986A1 (en) Compositions With Ethofumesate And A Safener
US10863742B2 (en) Herbicide combinations
WO2025045998A1 (fr) Combinaisons herbicides
WO2025162909A1 (fr) Combinaisons herbicides
AU2022323684A1 (en) Use of compositions with ethofumesate and bixlozone in wheat crops
EP3639665A1 (fr) Combinaisons d'herbicides
US20200404907A1 (en) Method of reducing crop damage
US20200404916A1 (en) Method of reducing crop damage
EA050490B1 (ru) Применение композиций с этофумезатом и бикслозоном в культурах пшеницы
US20210227824A1 (en) Method of reducing crop damage

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 24761662

Country of ref document: EP

Kind code of ref document: A1