WO2024228013A1 - Système électronique de fourniture d'aérosol et procédé de distribution de vapeur pour un système électronique de fourniture de vapeur - Google Patents
Système électronique de fourniture d'aérosol et procédé de distribution de vapeur pour un système électronique de fourniture de vapeur Download PDFInfo
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- WO2024228013A1 WO2024228013A1 PCT/GB2024/051135 GB2024051135W WO2024228013A1 WO 2024228013 A1 WO2024228013 A1 WO 2024228013A1 GB 2024051135 W GB2024051135 W GB 2024051135W WO 2024228013 A1 WO2024228013 A1 WO 2024228013A1
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- vapour
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/50—Control or monitoring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/50—Control or monitoring
- A24F40/53—Monitoring, e.g. fault detection
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/10—Devices using liquid inhalable precursors
Definitions
- the present disclosure relates to electronic aerosol provision systems such as nicotine delivery systems (e.g. electronic cigarettes and the like).
- nicotine delivery systems e.g. electronic cigarettes and the like.
- Electronic aerosol provision systems such as electronic cigarettes (e-cigarettes) generally contain a reservoir of a source liquid containing a formulation, typically including nicotine, from which an aerosol is generated, e.g. through heat vaporisation.
- An aerosol source for an aerosol provision system may thus comprise a heater having a heating element arranged to receive source liquid from the reservoir, for example through wicking / capillary action. While a user inhales on the device, electrical power is supplied to the heating element to vaporise source liquid in the vicinity of the heating element to generate an aerosol for inhalation by the user.
- Such devices are usually provided with one or more air inlet holes located away from a mouthpiece end of the system.
- an electric current is supplied to the heater when a user is drawing/ puffing on the device.
- the electric current is supplied to the heater, e.g. resistance heating element, in response to either the activation of an airflow sensor along the flow path as the user inhales/draw/puffs or in response to the activation of a button by the user.
- the heat generated by the heating element is used to vaporise a formulation.
- the released vapour mixes with air drawn through the device by the puffing consumer and forms an aerosol.
- the flow or pressure sensor deactivates the electric heater by cutting off the electric current. At that point of time the heater is still at an elevated temperature capable of vaporising a certain portion of liquid.
- the heat for this continued vaporisation originates from the heat capacity of the heater itself. Subsequently, the heater cools down. When the temperature of the heater falls below the boiling point of the higher volatile formulation components (e.g. water, propylene glycol), the vaporisation process stalls. The vapour released during the continued vaporisation phase after deactivation is not delivered to the consumer since there is no air flow through the device anymore. Instead the vapour condenses on internal walls of the device causing potential problems (e.g. clogging). The evaporation heat released by the heater during the continued vaporisation phase can also be considered as an energy loss. The energy is lost as condensation heat which in turn is heating up structural components of the device. This issue is exacerbated in devices with larger heater elements.
- the higher volatile formulation components e.g. water, propylene glycol
- Figure 1 is a schematic (exploded) diagram of an electronic vapour provision system such as an e-cigarette in accordance with some embodiments of the description.
- Figure 2 is a schematic diagram of the body of the e-cigarette of Figure 1 in accordance with some embodiments of the description.
- Figure 3 is a schematic diagram of the vaporiser portion of the e-cigarette of Figure 1 in accordance with some embodiments of the description.
- Figure 4 is a schematic diagram showing certain aspects of one end of the body portion of the e-cigarette of Figure 1 in accordance with some embodiments of the description.
- Figure 5 is a schematic flowchart which illustrates certain aspects of operation of the e- cigarette of Figure 1 in accordance with some embodiments of the description.
- Figure 6 is a schematic flowchart which illustrates certain aspects of operation of the e- cigarette of Figure 1 in accordance with some embodiments of the description.
- Figure 7 is a schematic flowchart which illustrates a method of operating an electronic vapour provision in accordance with some embodiments of the description.
- Figure 8A is a graph depicting vapour detection against power timing in accordance with some embodiments of the description.
- Figure 8B is a graph depicting accumulated vapour mass as a function of puff duration in accordance with some embodiments of the description.
- Figure 9 is a graph depicting wasted vapour as a function of puff duration in accordance with some embodiments of the description.
- Figure 10 is graph depicting accumulated vapour mass as a function of power in accordance with some embodiments of the description.
- FIG. 1 is a schematic diagram of an electronic vapour provision system such as an e-cigarette 10 in accordance with some embodiments of the invention (not to scale).
- the e-cigarette has a generally cylindrical shape, extending along a longitudinal axis indicated by dashed line LA, and comprises two main components, namely a body 20 and a cartomiser 30.
- the cartomiser includes an internal chamber containing a reservoir of a payload such as for example nicotine, a vaporiser (such as a heater), and a mouthpiece 35.
- a payload such as for example nicotine
- a vaporiser such as a heater
- References to 'nicotine' hereafter will be understood to be merely exemplary and can be substituted with any suitable payload.
- the reservoir may be a foam matrix or any other structure for retaining the nicotine until such time that it is required to be delivered to the vaporiser.
- the vaporiser is for vaporising the nicotine, and the cartomiser 30 may further include a wick or similar facility to transport a small amount of nicotine from the reservoir to a vaporising location on or adjacent the vaporiser.
- a heater is used as a specific example of a vaporiser.
- other forms of vaporiser for example, those which utilise ultrasonic waves could also be used.
- the body 20 includes a re-chargeable cell or battery to provide power to the e-cigarette 10 and a circuit board for generally controlling the e-cigarette.
- the heater receives power from the battery, as controlled by the circuit board, the heater vaporises the nicotine and this vapour is then inhaled by a user through the mouthpiece 35.
- the body is further provided with a manual activation device 265, e.g. a button, switch, or touch sensor located on the outside of the body.
- the body 20 and cartomiser 30 may be detachable from one another by separating in a direction parallel to the longitudinal axis LA, as shown in Figure 1, but are joined together when the device 10 is in use by a connection, indicated schematically in Figure 1 as 25A and 25B, to provide mechanical and electrical connectivity between the body 20 and the cartomiser 30.
- the electrical connector 25B on the body 20 that is used to connect to the cartomiser 30 also serves as a socket for connecting a charging device (not shown) when the body 20 is detached from the cartomiser 30.
- the other end of the charging device may be plugged into a USB socket to re-charge the cell in the body 20 of the e-cigarette 10.
- a cable may be provided for direct connection between the electrical connector 25B on the body 20 and a USB socket.
- the e-cigarette 10 is provided with one or more holes (not shown in Figure 1) for air inlets. These holes connect to an air passage through the e-cigarette 10 to the mouthpiece 35. When a user inhales through the mouthpiece 35, air is drawn into this air passage through the one or more air inlet holes, which are suitably located on the outside of the e-cigarette. When the heater is activated to vaporise the nicotine from the cartridge, the airflow passes through, and combines with, the nicotine vapour, and this combination of airflow and nicotine vapour then passes out of the mouthpiece 35 to be inhaled by a user. Except in single-use devices, the cartomiser 30 may be detached from the body 20 and disposed of when the supply of nicotine is exhausted (and replaced with another cartomiser if so desired).
- the e-cigarette 10 shown in Figure 1 is presented by way of example, and various other implementations can be adopted.
- the cartomiser 30 is provided as two separable components, namely a cartridge comprising the nicotine reservoir and mouthpiece (which can be replaced when the nicotine from the reservoir is exhausted), and a vaporiser comprising a heater (which is generally retained).
- the charging facility may connect to an additional or alternative power source, such as a car cigarette lighter.
- Figure 2 is a schematic (simplified) diagram of the body 20 of the e-cigarette 10 of Figure 1 in accordance with some embodiments of the invention.
- Figure 2 can generally be regarded as a crosssection in a plane through the longitudinal axis LA of the e-cigarette 10. Note that various components and details of the body, e.g. such as wiring and more complex shaping, have been omitted from Figure 2 for reasons of clarity.
- the body 20 includes a battery or cell 210 for powering the e-cigarette 10 in response to a user activation of the device. Additionally, the body 20 includes a control unit (not shown in Figure 2), for example a chip such as an application specific integrated circuit (ASIC) or microcontroller, for controlling the e-cigarette 10.
- the microcontroller or ASIC includes a CPU or micro-processor. The operations of the CPU and other electronic components are generally controlled at least in part by software programs running on the CPU (or other component). Such software programs may be stored in non-volatile memory, such as ROM, which can be integrated into the microcontroller itself, or provided as a separate component. The CPU may access the ROM to load and execute individual software programs as and when required.
- the microcontroller also contains appropriate communications interfaces (and control software) for communicating as appropriate with other devices in the body 10.
- the control unit is operable to estimate a user's usage timing.
- the usage timing may relate to the user's prior inhalation durations (puff durations) and/or the gaps between inhalations, either of which can be indicative of the duration of the next puff.
- the control unit is also operable to adjust the power supplied to the vaporiser based upon the estimate. This adjustment may comprise modifying the duration of power supply to the system during a user's puff, and/or modifying the amount / level of power supplied.
- control unit is operable to estimate a user's expected puff duration, and to cause power to be supplied to the vaporiser for a period of time shorter than the user's expected puff duration.
- control unit is operable to measure the length of time the user activates the device (i.e. the puff duration).
- control unit is able to store the length of time of successive puffs in the memory associated with the ASIC.
- the control unit may utilise the CPU to execute software programs to analyse the puff information.
- the CPU analyses the puff information to learn an average puff duration for a user, by calculating the cumulative total duration of all puffs and dividing it by the total number of puffs.
- the total number of puffs may be limited to a certain number of puffs N, for example up to the last 100 puffs or up to the last 10 puffs.
- the e-cigarette may be deemed responsive to changes in usage behaviour. It will be appreciated that for 'new' devices the user will have taken a limited number of puffs which may be less than the total number typically used to calculate an average. For such devices the total number of puffs taken will be used to calculate an average, while this number is less than the limit.
- the memory may be used in a first-in-first out configuration (i.e. a circular configuration) to store the last N puff durations
- the memory may be provided with N instances of an average puff duration pre-loaded at manufacture so that the system does not have to operate differently during initial use. Over time, these pre-loaded values are supplanted by measured values from the user.
- the control unit learns a user's expected puff duration by employing machine learning.
- the CPU may be operable to employ certain software to analyse puff information, and identify trends in the user's usage behaviour. This may also be more responsive to a user's changing demands.
- control unit is operable to cause power to be supplied to the vaporiser for a period of time shorter than the user's expected puff duration.
- the control unit is operable to cause power to be supplied to the vaporiser for a period of time shorter than the user's expected puff duration.
- the heater remains at a sufficient temperature to continue to vaporise liquid for a short period of time.
- the power to the heater is cut off after being active for a time slightly shorter than the learned user puff duration.
- the time power is supplied to the heater is between 0.05 to 0.5 seconds shorter than the expected user puff duration.
- the time power is supplied to the heater is 0.3 seconds shorter than the expected user puff duration.
- the time is a ratio, for example a value between 95% and 70% of the estimated duration, the ratio dropping as the estimated duration increases. This approach is discussed in more detail later herein.
- the manufacturer of a device may measure the time taken for a heating element to drop below the vapourisation temperature of the payload liquid, and use this time (or a suitable approximation thereto) as the advance cut-off time. Where different available payloads have different vapourisation temperatures, then optionally the lowest temperature (the longest advance time) may be chosen, or optionally the device may be adapted to recognise the payload type and select the appropriate cutoff time.
- the body 20 further includes a cap 225 to seal and protect the far (distal) end of the e-cigarette 10.
- a cap 225 to seal and protect the far (distal) end of the e-cigarette 10.
- the control unit or ASIC may be positioned alongside or at one end of the battery 210.
- the ASIC is attached to a sensor unit 215 to detect an inhalation on mouthpiece 35 (or alternatively the sensor unit 215 may be provided on the ASIC itself).
- An air path is provided from the air inlet through the e-cigarette, past the airflow sensor 215 and the heater (in the vaporiser or cartomiser 30), to the mouthpiece 35.
- the CPU detects such inhalation based on information from the airflow sensor 215.
- the connector 25B for joining the body 20 to the cartomiser 30.
- the connector 25B provides mechanical and electrical connectivity between the body 20 and the cartomiser 30.
- the connector 25B includes a body connector 240, which is metallic (silver-plated in some embodiments) to serve as one terminal for electrical connection (positive or negative) to the cartomiser 30.
- the connector 25B further includes an electrical contact 250 to provide a second terminal for electrical connection to the cartomiser 30 of opposite polarity to the first terminal, namely body connector 240.
- the electrical contact 250 is mounted on a coil spring 255.
- the connector 25A on the cartomiser 30 pushes against the electrical contact 250 in such a manner as to compress the coil spring in an axial direction, i.e. in a direction parallel to (co-aligned with) the longitudinal axis LA.
- this compression biases the spring 255 to expand, which has the effect of pushing the electrical contact 250 firmly against connector 25A of the cartomiser 30, thereby helping to ensure good electrical connectivity between the body 20 and the cartomiser 30.
- the body connector 240 and the electrical contact 250 are separated by a trestle 260, which is made of a nonconductor (such as plastic) to provide good insulation between the two electrical terminals.
- the trestle 260 is shaped to assist with the mutual mechanical engagement of connectors 25A and 25B.
- a button 265, which represents a form of manual activation device 265, may be located on the outer housing of the body 20.
- the button 265 may be implemented using any appropriate mechanism which is operable to be manually activated by the user - for example, as a mechanical button or switch, a capacitive or resistive touch sensor, and so on. It will also be appreciated that the manual activation device 265 may be located on the outer housing of the cartomiser 30, rather than the outer housing of the body 20, in which case, the manual activation device 265 may be attached to the ASIC via the connections 25A, 25B.
- the button 265 might also be located at the end of the body 20, in place of (or in addition to) cap 225.
- Figure 3 is a schematic diagram of the cartomiser 30 of the e-cigarette 10 of Figure 1 in accordance with some embodiments of the invention.
- Figure 3 can generally be regarded as a crosssection in a plane through the longitudinal axis LA of the e-cigarette 10. Note that various components and details of the cartomiser 30, such as wiring and more complex shaping, have been omitted from Figure 3 for reasons of clarity.
- the cartomiser 30 includes an air passage 355 extending along the central (longitudinal) axis of the cartomiser 30 from the mouthpiece 35 to the connector 25A for joining the cartomiser 30 to the body 20.
- a reservoir of nicotine 360 is provided around the air passage 335. This reservoir 360 may be implemented, for example, by providing cotton or foam soaked in nicotine.
- the cartomiser 30 also includes a heater 365 for heating nicotine from reservoir 360 to generate nicotine vapour to flow through air passage 355 and out through mouthpiece 35 in response to a user inhaling on the e- cigarette 10.
- the heater 365 is powered through lines 366 and 367, which are in turn connected to opposing polarities (positive and negative, or vice versa) of the battery 210 of the main body 20 via connector 25A (the details of the wiring between the power lines 366 and 367 and connector 25A are omitted from Figure 3).
- the connector 25A includes an inner electrode 375, which may be silver-plated or made of some other suitable metal or conducting material.
- the inner electrode 375 contacts the electrical contact 250 of the body 20 to provide a first electrical path between the cartomiser 30 and the body 20.
- the inner electrode 375 pushes against the electrical contact 250 so as to compress the coil spring 255, thereby helping to ensure good electrical contact between the inner electrode 375 and the electrical contact 250.
- the inner electrode 375 is surrounded by an insulating ring 372, which may be made of plastic, rubber, silicone, or any other suitable material.
- the insulating ring is surrounded by the cartomiser connector 370, which may be silver-plated or made of some other suitable metal or conducting material.
- the cartomiser connector 370 contacts the body connector 240 of the body 20 to provide a second electrical path between the cartomiser 30 and the body 20.
- the inner electrode 375 and the cartomiser connector 370 serve as positive and negative terminals (or vice versa) for supplying power from the battery 210 in the body 20 to the heater 365 in the cartomiser 30 via supply lines 366 and 367 as appropriate.
- the cartomiser connector 370 is provided with two lugs or tabs 380A, 380B, which extend in opposite directions away from the longitudinal axis of the e-cigarette 10. These tabs are used to provide a bayonet fitting in conjunction with the body connector 240 for connecting the cartomiser 30 to the body 20.
- This bayonet fitting provides a secure and robust connection between the cartomiser 30 and the body 20, so that the cartomiser and body are held in a fixed position relative to one another, with minimal wobble or flexing, and the likelihood of any accidental disconnection is very small.
- the bayonet fitting provides simple and rapid connection and disconnection by an insertion followed by a rotation for connection, and a rotation (in the reverse direction) followed by withdrawal for disconnection. It will be appreciated that other embodiments may use a different form of connection between the body 20 and the cartomiser 30, such as a snap fit or a screw connection.
- Figure 4 is a schematic diagram of certain details of the connector 25B at the end of the body 20 in accordance with some embodiments of the invention (but omitting for clarity most of the internal structure of the connector as shown in Figure 2, such as trestle 260).
- Figure 4 shows the external housing 201 of the body 20, which generally has the form of a cylindrical tube.
- This external housing 201 may comprise, for example, an inner tube of metal with an outer covering of paper or similar.
- the external housing 201 may also comprise the manual activation device 265 (not shown in Figure 4) so that the manual activation device 265 is easily accessible to the user.
- the body connector 240 extends from this external housing 201 of the body 20.
- the body connector 240 as shown in Figure 4 comprises two main portions, a shaft portion 241 in the shape of a hollow cylindrical tube, which is sized to fit just inside the external housing 201 of the body 20, and a lip portion 242 which is directed in a radially outward direction, away from the main longitudinal axis (LA) of the e-cigarette.
- a collar or sleeve 290 Surrounding the shaft portion 241 of the body connector 240, where the shaft portion does not overlap with the external housing 201, is a collar or sleeve 290, which is again in a shape of a cylindrical tube.
- the collar 290 is retained between the lip portion 242 of the body connector 240 and the external housing 201 of the body, which together prevent movement of the collar 290 in an axial direction (i.e. parallel to axis LA). However, collar 290 is free to rotate around the shaft portion 241 (and hence also axis LA).
- the cap 225 is provided with an air inlet hole to allow air to flow when a user inhales on the mouthpiece 35.
- the majority of air that enters the device when a user inhales flows through collar 290 and body connector 240 as indicated by the two arrows in Figure 4.
- Figure 5 shows a flow chart illustrating a process performed by the control unit for controlling operation of the electronic vapour provision system according to some embodiments of the present description.
- step 500 it is determined whether or not the device has been activated by the user. Activation may be by inhalation, button press or touch sensor interaction, for example. If the device has not been activated, then the process returns to the beginning of step 505. On the other hand, if the device has been activated, then the process moves onto step 510, and a timer is started to measure the total length of time the user activates the device.
- the control unit causes power to be supplied to the vaporiser (such as heater 365). This activates the vaporiser and causes the liquid of the cartomiser 30 to be vaporised for inhalation by the user.
- step 520 in which it is determined whether or not the device is still being activated by the user, i.e. if the user is still inhaling, pressing the button or interacting with the touch sensor, as applicable. If it is determined at step 520 that the device is still activated, then the process moves onto step 525.
- the control unit compares the current time against the first period of time (i.e. the period of time shorter than the expected puff duration, that the control unit powers the vaporiser). If the current time is less than the first period of time then the system returns to step 515 and continues to supply power to the vaporiser.
- a loop is formed by steps 515, 520, and 525 that can only be broken by the user deactivating the device at step 520 or if the period of activation exceeds the first period of time, at step 525. If the user deactivates the device, the system proceeds to step 530 and immediately stops supplying power to the vaporiser. Alternatively, if the period of activation exceeds the first period of time the system proceeds to step 540 and immediately stops supplying power to the vaporiser.
- step 530 the control unit can immediately stop the timer at step 535, so that the time measured corresponds to the length of time the device has been activated.
- step 540 power has stopped being supplied to the vaporiser but the user is still activating the device, e.g. still puffing.
- step 545 continuously queries whether the user has ceased to activate the device.
- the system proceeds to step 535 and the timer is stopped, so that the time measured corresponds to the length of time the device has been activated.
- the control unit incorporates the latest puff duration into the analysis of the expected puff duration, to estimate the user's next expected puff duration.
- the next step 560 ends the process and returns the device to step 500, ready for the next user activation.
- Figure 6 shows the steps of starting the timer 510 and supplying power to the vaporiser 515 being performed sequentially, in practice these may be performed in parallel.
- the first period of time is 0.3 seconds shorter than the expected puff duration of the user. It is expected that 0.3 seconds represents a threshold time at which a user cannot detect the heater has switched off prematurely. As an example, for an expected puff duration of 3 seconds the first period of time would be 2.7 seconds. If the user presses an activation button for 2.9 seconds then 0.2 seconds of energy have been saved. Given the short period of time and the thermal inertia of the heater, liquid vaporised in this time is inhaled while no power is wasted. Furthermore as less liquid is vaporised as the temperature of the heater drops, once the user stops inhaling there will be less additional vaporisation that subsequently condenses on the internal walls of the device. As noted previously herein, other timing strategies may also be considered.
- the same approach may be used to set power levels instead of or as well as power duration to modify the delivery of an active ingredient, and also that the gaps between inhalations may similarly be measured and characterised to identify a correlation between gap duration and active ingredient demand.
- This latter approach may be useful for example once the system starts to change either the power duration and/or level, as this may affect the inhalation duration due to the change in delivery (whether consciously or unconsciously on the part of the user), so making the inhalation durations atypical, but the gaps between durations are unaffected inasmuch as they are influenced by the user's wish to consumed further active ingredient.
- the embodiment detailed in Figure 5 has the potential, in some circumstances, to provide an unsatisfactory user experience, particularly in the case that the power duration is curtailed, but potentially also when less vapour is being generated due to a lower power level. If the actual user puff duration exceeds the estimated (expected) user puff duration greatly, then the user may detect a significant loss of performance in the final stage of the puff (and/or it is symptomatic of the user not experiencing the desired puff). To overcome this issue some embodiments of the device are further configured to resume supplying power to the vaporiser, in response to a longer than expected puff, for a second period of time.
- Figure 6 shows a flow chart illustrating a process performed by the control unit for controlling operation of the electronic vapour provision system according to some embodiments of the present description, wherein the system is further configured to resume supplying power to the vaporiser in response to a longer than expected puff.
- step 600 it is determined whether or not the device has been activated by the user (again for example by inhalation, button press or touch sensor interaction). If the device has not been activated, then the process returns to the beginning of step 605. On the other hand, if the device has been activated, then the process moves onto step 610, and a timer is started to measure the total length of time the user activates the device.
- the control unit causes power to be supplied to the vaporiser (such as heater 365). This activates the vaporiser and causes the liquid of the cartomiser 30 to be vaporised for inhalation by the user.
- step 620 in which it is determined whether or not the device is still being activated by the user. If it is determined at step 620 that the device is still activated, then the process moves onto step 625.
- the control unit compares the current time against the first period of time (i.e. the period of time shorter than the expected puff duration that the control unit powers the vaporiser). If the current time is less than the first period of time then the system returns to step 615 and continues to supply power to the vaporiser.
- a loop is formed by steps 615, 620, and 625 that can only be broken by the user deactivating the device at step 620 or the period of activation exceeding the first period of time, at step 625.
- step 630 If the user deactivates the device, the system proceeds to step 630 and immediately stops supplying power to the vaporiser. Alternatively, if the period of activation exceeds the first period of time the system proceeds to step 640 and immediately stops supplying power to the vaporiser.
- step 630 the control unit can immediately stop the timer at step 635, so that the time measured corresponds to the length of time the device has been activated.
- step 640 power has stopped being supplied to the vaporiser but the user is still activating the device, i.e. still puffing.
- step 645 queries whether the user has ceased to activate the device. If the user is not activating the device, the control unit proceeds to step 635 and the timer is stopped, so that the time measured corresponds to the length of time the device has been activated. If the user is still activating the device, the control unit proceeds to step 650 and the control unit queries whether the current time is greater than the expected puff duration. If the current time is not greater, the system loops back to step 645.
- step 655 the system continuously queries whether the user has ceased to activate the device. Once the answer is no the system proceeds to step 665 and the control unit stops supplying power to the vaporiser. Next the control unit proceeds to step 635 and the timer is stopped, so that the time measured corresponds to the length of time the device has been activated by the user. At step 670 the control unit incorporates the latest puff duration into the analysis of the expected puff duration, to estimate the next puff duration. The next step 680 ends the process and returns the device to step 600, ready for the next user activation.
- the above approach may equally supply power at a first level for the expected time, and if the user is still activating the device at that point, proceed to supply power at a higher level.
- the resumed power level may either be the same as before (since it is still more than nothing) or be at a higher level on the assumption that it was not sufficient beforehand.
- the embodiment of Figure 6 powers the heater for a first period of time, slightly shorter than the expected puff duration, and then resumes powering the heater for a second period of time if the user activation of the device exceeds the expected puff duration.
- the power may be pulsed repeatedly during the second period while the user continues to activate the device.
- the integrated energy supplied by the pulses will be significantly less than the integrated energy supplied by the power level of the first period of time.
- the energy usage is reduced, enhancing the number of puffs that can be achieved per battery, whilst also ensuring that the performance of the device is not noticeably reduced. Additionally by reducing the length of the continued vaporisation phase, there is less condensation of vapour on the internal walls of the device.
- the control unit may not completely stop powering the heater after the first period, and instead may immediately start pulsing power to the heater or may immediately power the heater at a lower power for the second period of time. The thermal inertia of the heater will be slowly reduced; however this will not occur as quickly as if the heater were powered off and therefore if the user activates the device for a larger than expected time they are less likely to notice a loss of performance.
- some embodiments may adopt implementations of a manual activation device 265 rather than, for example, airflow sensor 215.
- the manual activation device may be activated by the user to cause the control unit to supply power to the vaporiser to vaporise the liquid.
- the user activation of the manual activation device facilitates the user activation of the device, thereby starting the processes described above, for example in Figure 5 and Figure 6.
- the manual activation device 265 may be, for example, a physical button or switch or may be a touch sensor (such as a resistive or capacitive touch sensor) which is activated simply by being touched by the user.
- the method of activating and deactivating the manual activation device 265 may also take a range of different approaches.
- the manual activation device may be activated for a predetermined period of time after the button 265 is pressed or touched, after which the manual activation device is de-activated.
- Such an implementation helps to ensure that the manual activation device is de-activated by the user, although the user does not have full (direct) control over the supply of power to the vaporiser.
- the manual activation device 265 comprises a button which is activated by a first press of the button by the user, and then deactivated by a second (subsequent) press of the button by the user. In other words, alternate presses of the button activate and then deactivate the manual activation device. During the time period between the first and second press, the microcontroller regards the manual activation device 265 as activated. This method has the advantage of providing the user with direct control over the duration of activation, although the manual activation device may remain activated if the user forgets or neglects to make a second press. In another example, the manual activation device 265 is deemed activated for as long as the button is continuously pressed by the user.
- This method again gives the user control over how long the vaporiser is activated. Moreover, it is natural for a user to stop pressing the button 265 when they have finished using the e-cigarette, so it is unlikely that the manual activation device would remain in an activated state unintentionally.
- the manual activation device 265 comprises a touch sensor. That is, in one example, the manual activation device 265 is deemed to be activated following a first touch of the touch sensor by the user and then deemed to be deactivated following a second touch of the touch sensor by the user. During the time period between the first and second touch, the manual activation device 265 is deemed activated. In another example, the manual activation device 265 is deemed activated for as long as the touch sensor is continuously touched by the user.
- the manual activation device 265 comprises a manual switch, such as a slidable or rotatable switch
- the manual activation device 265 will be activated when the switch is put into an "on” position and deactivated when the switch is put into an “off” position.
- the switch may be biased towards the "off” position so that the user has to continually hold the switch in the "on” position in order for the manual activation device to be activated. In this case, when the user stops holding the switch in the "on” position, the switch will automatically return (under the influence of a spring or some other resilient bias mechanism, etc) to the "off" position.
- the manual activation device 265, be it a button, touch sensor, switch or any other suitable device, is generally positioned such that it is easily accessible to the user when the user holds the e- cigarette 10 so as to inhale on it.
- the manual activation device 265 may be located somewhat closer to the proximal (mouth) end of the e-cigarette than to the distal (cap) end of the e- cigarette, since the user is more likely to hold the e-cigarette closer at a position closer to its proximal end (as is the case for conventional combustible cigarettes).
- the button 265 is located on the body portion 25 (since the cartridge 30 is disposable), but at the end nearest to the mouthpiece.
- the button may be activated (pressed, moved or touched) conveniently while the e-cigarette is being held by a user. While the manual activation devices have been described in-depth with regard to the activation of the device and consequently the vaporiser, it will be appreciated that in many embodiments additional manual activation devices may serve ancillary functions, for example an on/off or lock switch.
- an air flow sensor may be implemented in the device so that the user may activate the device and cause the control unit to supply power to the vaporiser to vaporise the liquid by inhaling on the device.
- the user activation of the air flow sensor facilitates the user activation of the device, thereby starting the processes described above, for example in Figure 5 and Figure 6.
- the body 20 includes the sensor unit 215 located in or adjacent to the air path through the body 20 from the air inlet to the air outlet (to the vaporiser).
- the sensor unit 215 may include a pressure drop sensor and temperature sensor (also in or adjacent to this air path).
- the sensor unit 215 may include the pressure drop sensor without the temperature sensor or may include an airflow monitor to directly measure airflow (rather than pressure drop).
- the control unit detects such inhalation based on information from the pressure drop sensor.
- the CPU supplies power to the heater, which thereby heats and vaporises the nicotine from the wick for inhalation by the user.
- 'activation' and 'deactivation' may equally be considered separate actions (such as pushing a button or switch on and then off) or the commencement and cessation of a single action (such as inhalation, pressing a button or interacting with a touch sensor).
- the above described embodiments act to reduce the energy supplied to the heater during each puff. As such, this may increase the number of puffs for a given battery capacity or present an opportunity to reduce the battery capacity of the device.
- the reduced length of the continued vaporisation phase additionally reduces unwanted condensates on the internal walls of the device, improves puff count for a given volume of liquid, and may also help to alleviate carbonyl build up, which occurs when the heater is on but there is no airflow in the device.
- an electronic vapour provision system comprises a vaporiser for vaporising a payload for inhalation by a user of the electronic vapour provision system (as described elsewhere herein) and a power supply for supplying power to the vaporiser to vaporise the payload in response to a user activation of the device (as described elsewhere herein); and furthermore comprises a control unit configured to estimate a user's usage timing (whether activation duration and/or gaps, as described elsewhere herein); and adjust the power supplied to the vaporiser based upon the estimate (whether duration and/or level, as described elsewhere herein).
- control unit is configured to measure an actual usage timing of the user (whether the user's inhalation duration and/or the gap between inhalations) and compare the actual usage timing and the estimated usage timing, and adjust the power supplied to the vaporiser based upon a difference between the actual and estimated usage timings; e.g. whether the actual and estimated usage timings differ by more than a predetermined amount.
- control unit In relation to the usage timing being a user's vaporiser activation duration, as described elsewhere herein, then in one instance the control unit is configured to increase the power level to the vaporiser to supply more vapour, if the measured actual timing of the user exceeds the estimate by a predetermined amount. Conversely in another instance the control unit is configured to decrease the power level to the vaporiser to supply less vapour, if the measured actual timing of the user is less than the estimate by a predetermined amount.
- control unit may optionally also be configured to cause power to be supplied to the vaporiser for a period of time shorter than the estimated usage timing.
- control unit is configured to increase the power to the vaporiser to supply more vapour, if the measured actual timing of the user is less than the estimate by a predetermined amount.
- control unit is configured to decrease the power to the vaporiser to supply less vapour, if the measured actual timing of the user is more than the estimate by a predetermined amount.
- the usage timing is a period between vaporiser activations by the user within a predetermined range consistent with an ongoing usage session and not a period of cessation between sessions; in other words, the inter-activation timings are assumed to be whilst the user is actively consuming vapour from the system (e.g. as if smoking a single cigarette) and not, for example a period when the device has been put away or otherwise removed from ongoing use.
- the adjustment of the power to the vaporiser is implemented for the next user activation of the device, since the information about whether the actual timing is greater or smaller than the estimate can only be determined after the fact (at least when the actual timing is greater).
- the predetermined amount by which the timing exceeds or is less than the estimate may be selected based on calculating the standard deviation associated with the mean of the N prior events (previously measured timings, e.g. puffs or gaps) where as noted previously herein N is typically a number between 10 and 100. Then in embodiments of the description, optionally the predetermined amount is a certain number of standard deviations from the mean (whether fractional, e.g. % SD or % SD) or equal to or larger than 1 SD (e.g. 1 SD, 1% SDs or 2 SDs).
- This approach allows the system to effectively calibrate to the behaviour of the user and detect when that behaviour is out of the norm, indicating that the user is either experiencing sufficient desire for the active ingredient that it has altered their behaviour by this measureable extent, or conversely the user is sufficiently sated that it has altered their behaviour by this measureable extent.
- control unit may be configured to estimate the user's usage timing responsive to one or more contextual factors external to the electronic vapour provision system, in order to improve the estimate, since such factors may affect how the user uses the system.
- control unit may be configured to estimate the user's usage timing responsive to one or more selected from the list consisting of a current time of day or a current day of the week (either of which may result in, for example more relaxed or more urgent inhalation patterns of use), a current location (which for example may impose time limits on use or different types of behaviour), identities of one or more people nearby, and (for example as a proxy for those people, or for locations) identities of one or more devices nearby (for example using Bluetooth® identifiers), since a user may behave differently with family, friends, or strangers, or as noted above in different locations, including mobile locations such as a car.
- the control unit may employ machine learning software to learn a user's expected activation duration.
- control unit may be further configured to resume causing power to be supplied to the vaporiser for a second period of time, if the user activates the device for a duration exceeding the user's expected timing, the second period of time ending when the user ceases activation of the device.
- the power level may be the same as before, higher (to help sate the user) or lower (to help reduce condensation), depending on the relative significance of these considerations to the designer.
- the above techniques may set the power supply time as a ratio or proportion of the expected inhalation time; for example a value between 95% and 70% of the estimated duration, the ratio dropping as the estimated duration increases.
- a method of vapour delivery for an electronic vapour provision system comprises the following steps:
- a first step 710 detecting an inhalation action by a user; as note elsewhere herein, this may be done for example using an airflow sensor 215.
- a second step 720 activating a heater of an aerosol generator to deliver vapour to the user, as described elsewhere herein.
- a third step 730 predicting a duration of the inhalation action of the user, as described elsewhere herein.
- a proportion of the predicted duration (as non-limiting examples, between 70 and 95% of the predicted duration) as described elsewhere herein.
- a fifth step 750 deactivating the heater of the aerosol generator after the calculated proportion of the predicted duration has elapsed, as described elsewhere herein; and wherein the calculated proportion of the predicted duration is made smaller as the predicted duration becomes longer.
- the heater is then cut off after each of one, two, and three seconds from activation. It will be appreciated that in the case of a one second cut off, the heater had only just reached full output before being disabled whilst the two second and three second sessions each had at least some period of full output.
- this vapour overhead at the end of inhalation has a non-linear relationship with inhalation duration, representing a larger proportion of the vapour generated for short puffs than for long puffs.
- an electronic vapour provision system calculates a proportion of that predicted duration after which the heater is deactivated, wherein the calculated proportion of the predicted duration is made smaller as the predicted duration becomes longer.
- the proportion may be 95%, whereas for a long predicted inhalation (for example 6 seconds) the proportion may be 70%.
- the proportion may vary linearly or non-linearly with duration, and may be bracketed in that the proportion may reach a maximum value at a predetermined short period (as a non-limiting example 1 second), and may reach a minimum value at a predetermined long period (as a non-limiting example 6 seconds).
- the predetermined maximum proportion may be 95%, 90%, 85%, or 80%, or values in between, whilst the predetermined minimum proportion may be 70%, 65%, 60%, 55%, or 50%, or values in between.
- the maximum proportion is less than 100%; hence there is always an attempt to cut off the heater before the predicted duration has elapsed, in order to attempt to extract vapour generated during the highest residual temperature period after the heater has been deactivated, which will be when a disproportionate amount of the residual vapour is generated.
- the difference in time between the calculated proportion of the predicted duration and the predicted duration itself corresponds to no less than a time taken for the heater to drop below a vaporisation temperature for the delivered vapour; that is to say, the maximum proportion percentage may be calculated to provide enough time for the heater to drop to (or just below) the vaporisation temperature of the payload.
- the minimum proportion is significantly lower than the maximum; for example there may be a 20%, 25% or 30% gap between the minimum and maximum proportions in any one implementation of the technique.
- the minimum proportion provides improved battery efficiency and vapour efficiency in the latter part of an inhalation, and empirically it has been observed that users do not notice a tail-off in the production of vapour at the end of a longer inhalation, possibly because the mouth and potentially the airways are already thoroughly infused with the vapour.
- vapour delivery efficiency as a function of battery use is the power level supplied to the heater; referring now to figure 10, for an identical inhalation profile, the ratio of power to accumulated vapour mass ('ACM') improves (becomes more efficient) as power increases. This is essentially because a certain proportion of the power is raising the temperature of the heating element to the vaporisation temperature, whilst the remaining proportion of the power is raising the temperature further to create vapour; hence for example a power 1.5 W may result in no vapour at all as the heater does not reach the vaporisation temperature; meanwhile a 40% increase in power from 2.5 W to 3.5 W may result in a 100% increase in accumulated vapour mass. This disproportionate benefit reduces as the proportion of the deliver power accounting for preheat temperatures reduces, and by close to around 6 to 7 watts, the increase in power results in a closely corresponding increase in vapour.
- the heater optionally may be supplied with power at a level being one selected from the list consisting of within 30%, 20% or 10% of maximum, or at maximum power. If the battery is running low on power, then the effective maximum power may of course drop.
- the calculated proportion of the predicted duration may be modified responsive to the level of power supplied, with the capitated proportion being overall smaller as the power goes higher, or conversely being overall longer as the selected power drops below maximum. Of course, this may be subject to the caveat of an overall maximum proportion such as 95%.
- the predicted duration of the inhalation action of the user may be responsive to one or more selected from the list consisting of an average of a predetermined number of preceding inhalation actions, as described elsewhere herein; a duration of an inhalation action at a corresponding period within a prior sequence of inhalation actions (in other words a duration characteristic of a duration envelope for a particular sequence such as the consumption of a virtual cigarette); and a duration of a corresponding inhalation action within a predetermined pattern of inhalation actions (similar to the second example, but not necessarily time-based but rather pattern-based, for example where inhalation is a function of habit).
- the predicted duration of the inhalation action of the user may be responsive to an initial inhalation airflow gradient (for example during the first 0.1. 0.2, 0.3, 0.4, or 0.5 seconds after inhalation is detected).
- the rate at which airflow increases at the start of an inhalation is indicative of how rapidly the user's lungs will inflate. Since these have a finite capacity (and the user's maximum can be determined from an integral of the airflow among prior inhalations), then the initial gradient of the airflow is a strong indicator of both the type of inhalation being conducted (e.g. hard & fast or relaxed & slow) and hence also its duration (based on time to maximum capacity, or maximum typically inhaled amount).
- the gradient detection can also be combined with the other techniques to improve the estimate. For example, using one or more gradient thresholds, averages can be maintained for different classes of gradient so that each average is a more accurate estimate of the duration for that particular type of inhalation.
- the gradients can be used to characterise patterns or sequences within a puff session, and to estimate where the user is within a session (or identify the session type) for example using correlation between a current sequence of initial gradients (or their thresholded classification) and a stored sequence.
- the proportion of the predicted duration may be calculated using any of the techniques described herein, including one or optionally more selected from the list consisting of using a predetermined linear relationship between predicted duration and proportion, as described elsewhere herein, using a predetermined non-linear relationship between predicted duration and proportion, as described elsewhere herein, and using a look-up table providing proportion values for respective predicted durations based on the closest table entry to the predicted duration, which provides a piece-wise or quantised implementation of either the linear or non-linear relationship, but simplifies the calculation by storing the results in advance.
- the step of predicting the duration of the inhalation action of the user may use a machine learning algorithm, trained on a training set comprising one or more initial parameters of inhalation actions as inputs and the corresponding overall duration of the inhalation actions as the target output.
- the inputs may comprise for example one or more average values, pattern positions, initial airflow gradients, or other statistical information about the inhalation (e.g. current target power level set for the heater, and/or battery level, and/or a standard deviation associated with any averages provided).
- the target outputs are the actual inhalation durations observed.
- a machine learning system can be pretrained prior to use by a particular user (for example based on usage data acquired by a developer of the device) and optionally different models may be trained for different demographics (e.g. using gender and/or height as a proxy for lung capacity and any behavioural differences) so that the initial estimates are suited to the user. However optionally the system may then continue to learn for the actual user, based on the observed inhalation durations during use. Similarly, the step of calculating a proportion of the predicted duration may use a machine learning algorithm, trained on a training set comprising durations of inhalation actions as inputs and proportion values as the target output.
- the input durations may be the estimated durations of inhalation, as this will be the information available from the preceding step.
- the target output comprises the proportion value.
- the target output may include both the proportion value and the eventually observed inhalation duration, so that the machine learning system can learn to predict any patterns relating to systemic inaccuracies in estimation (for example the estimate may become less accurate in terms of absolute time for longer inhalations) when estimating the proportion of time.
- the target output may further include a user satisfaction/dissatisfaction value, indicating whether the user was satisfied with the inhalation when the heater was activated for the proportion of the estimated inhalation duration indicated by the proportion value.
- a user satisfaction/dissatisfaction value indicating whether the user was satisfied with the inhalation when the heater was activated for the proportion of the estimated inhalation duration indicated by the proportion value.
- this feedback approach of receiving a user input indicating dissatisfaction with the delivery of vapour may be used to calculate a modified proportion of subsequent predicted durations responsive to the input for any other techniques herein, for example modifying the linear, nonlinear, or tabulated relationship between the predicted duration and the proportion of saturation during which the heater is activated.
- machine learning systems may be trained for different user demographics.
- machine learning systems may alternatively or in addition be trained for different respective models of electronic vapour provision system, as these may have different heating profiles, different airflow pathways, and the like; and also for different payloads, as these may produce different qualities of vapour, have different vaporisation temperatures, and/or different concentrations of active ingredient, which may contrary to different inhalation behaviours and different acceptable heating proportions during an inhalation.
- an electronic vapour provision system 'EVPS' comprises the following. Firstly, a sensor (e.g. airflow sensor 215) configured to detect an inhalation action by a user, an aerosol generator comprising a heater (365). Secondly, a control unit (whose functionality may be provided by a processor within the EVPS, a processor within a mobile phone in short range wireless communication with the EVPS, or a combination of the two) configured to activate the heater to deliver vapour to the user. Thirdly a duration processor (typically the control unit operating under suitable software instruction) configured to predict a duration of the inhalation action of the user.
- a proportion processor (typically the control unit operating under suitable software instruction) configured to calculate a proportion of the predicted duration.
- the control unit is configured (e.g. under suitable software instruction) to deactivate the heater generator after the calculated proportion of the predicted duration has elapsed, and the proportion processor is configured (e.g. under suitable software instruction) to make the calculated proportion of the predicted duration smaller as the predicted duration becomes longer.
- calculated proportion corresponds to a value between a predetermined minimum percentage and a predetermined maximum percentage of the predicted duration of the inhalation action, as described elsewhere herein; in this case, the calculated proportion corresponds to no more than a maximum percentage of 95%, as described elsewhere herein; similarly in this case, the calculated proportion corresponds to no less than a minimum percentage of 70%, as described elsewhere herein; the difference in time between the calculated proportion of the predicted duration and the predicted duration itself corresponds to no less than a time taken for the heater to drop below a vaporisation temperature for the delivered vapour, as described elsewhere herein; during the calculated proportion of the predicted duration, the heater is supplied with power at a level being one selected from the list consisting of within 30% of maximum, within 20% of maximum, within 10% of maximum, and maximum, as described elsewhere herein; in this case, the calculated proportion of the predicted duration is modified responsive to the
- control unit and one or more of the processors may be implemented by a processor on the EVPS, a processor within a mobile phone or similar device in short range wireless communication with the EVPS, or a combination of the two, as described elsewhere herein.
- a system may comprise the EVPS and a mobile communication device operable to communicate with the EVPS by a sort range wireless protocol, wherein a functionality of at least one or the control unit, the duration processor, and the proportion processor is implemented at least in part by the mobile communication device.
Landscapes
- Medicinal Preparation (AREA)
- Control Of Resistance Heating (AREA)
Abstract
Un procédé de distribution de vapeur pour un système électronique de fourniture de vapeur comprend les étapes suivantes : détecter une action d'inhalation d'un utilisateur (710) ; activer un dispositif de chauffage d'un générateur d'aérosol pour distribuer de la vapeur à l'utilisateur (720) ; prédire une durée de l'action d'inhalation de l'utilisateur (730) ; calculer une proportion de la durée prédite (740) ; et désactiver le dispositif de chauffage du générateur d'aérosol après que la proportion calculée de la durée prédite s'est écoulée (750) ; la proportion calculée de la durée prédite diminuant à mesure que la durée prédite augmente.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202480029850.6A CN121127153A (zh) | 2023-05-03 | 2024-04-29 | 电子气溶胶供应系统及用于电子气雾供应系统的气雾输送方法 |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2306538.6 | 2023-05-03 | ||
| GBGB2306538.6A GB202306538D0 (en) | 2023-05-03 | 2023-05-03 | Electronic aerosol provision system |
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| Publication Number | Publication Date |
|---|---|
| WO2024228013A1 true WO2024228013A1 (fr) | 2024-11-07 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| PCT/GB2024/051135 Pending WO2024228013A1 (fr) | 2023-05-03 | 2024-04-29 | Système électronique de fourniture d'aérosol et procédé de distribution de vapeur pour un système électronique de fourniture de vapeur |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN121127153A (fr) |
| GB (1) | GB202306538D0 (fr) |
| WO (1) | WO2024228013A1 (fr) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130340750A1 (en) * | 2010-12-03 | 2013-12-26 | Philip Morris Products S.A. | Electrically Heated Aerosol Generating System Having Improved Heater Control |
| US20170318861A1 (en) * | 2014-12-11 | 2017-11-09 | Philip Morris Products S.A. | Inhaling device with user recognition based on inhalation behaviour |
| WO2021260343A1 (fr) * | 2020-06-22 | 2021-12-30 | Nicoventures Trading Limited | Système et procédé de retour d'utilisateur |
| CA3172032A1 (fr) * | 2020-07-10 | 2022-01-13 | Nicoventures Trading Limited | Systeme de fourniture d'aerosol |
| US20220361585A1 (en) * | 2019-10-16 | 2022-11-17 | Nicoventures Trading Limited | Electronic aerosol provision system and method |
-
2023
- 2023-05-03 GB GBGB2306538.6A patent/GB202306538D0/en not_active Ceased
-
2024
- 2024-04-29 CN CN202480029850.6A patent/CN121127153A/zh active Pending
- 2024-04-29 WO PCT/GB2024/051135 patent/WO2024228013A1/fr active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130340750A1 (en) * | 2010-12-03 | 2013-12-26 | Philip Morris Products S.A. | Electrically Heated Aerosol Generating System Having Improved Heater Control |
| US20170318861A1 (en) * | 2014-12-11 | 2017-11-09 | Philip Morris Products S.A. | Inhaling device with user recognition based on inhalation behaviour |
| US20220361585A1 (en) * | 2019-10-16 | 2022-11-17 | Nicoventures Trading Limited | Electronic aerosol provision system and method |
| WO2021260343A1 (fr) * | 2020-06-22 | 2021-12-30 | Nicoventures Trading Limited | Système et procédé de retour d'utilisateur |
| CA3172032A1 (fr) * | 2020-07-10 | 2022-01-13 | Nicoventures Trading Limited | Systeme de fourniture d'aerosol |
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| Publication number | Publication date |
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| GB202306538D0 (en) | 2023-06-14 |
| CN121127153A (zh) | 2025-12-12 |
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