WO2024227651A1 - Method and device for producing a flexible web-type composite material - Google Patents
Method and device for producing a flexible web-type composite material Download PDFInfo
- Publication number
- WO2024227651A1 WO2024227651A1 PCT/EP2024/061002 EP2024061002W WO2024227651A1 WO 2024227651 A1 WO2024227651 A1 WO 2024227651A1 EP 2024061002 W EP2024061002 W EP 2024061002W WO 2024227651 A1 WO2024227651 A1 WO 2024227651A1
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- substrate
- particles
- nonwoven material
- thermoplastic polymer
- web
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C53/00—Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
- B29C53/36—Bending and joining, e.g. for making hollow articles
- B29C53/38—Bending and joining, e.g. for making hollow articles by bending sheets or strips at right angles to the longitudinal axis of the article being formed and joining the edges
- B29C53/382—Bending and joining, e.g. for making hollow articles by bending sheets or strips at right angles to the longitudinal axis of the article being formed and joining the edges using laminated sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/04—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the partial melting of at least one layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
Definitions
- the invention relates to a method for producing a flexible web-shaped composite material, according to the preamble of claim 1.
- the invention further relates to a device for producing a flexible web-shaped composite material, according to the preamble of claim 17.
- Non-slip flexible packaging bags are also disclosed, the outer surface of which has roughening projections, as well as methods for their production and use. If such bags lie on top of one another, the roughening projections prevent mutual slipping, even if the material of the bags is not non-slip per se, because the projections interlock with one another.
- these projections produce an effective, non-slip mechanical lock with a fibrous engagement material, such as a commercially available fleece, which is placed between two bags, for example.
- a fibrous engagement material such as a commercially available fleece
- the fleece can be lifted vertically from the rough surface.
- the bag can consist of a film and/or a fabric and/or a nonwoven fabric.
- EP 3 463 805 B1 shows a tubular web of plastic film in which roughening projections are applied to one surface and a nonwoven strip is fixed to the opposite surface, either by a fiber-sprayed hot melt adhesive or by extrusion lamination, in which a continuous application of narrow strands of an extruded polyolefin polymer is carried out in order to encapsulate the fibers of the nonwoven and fix them to the film, and the sandwich arrangement of film/melt/nonwoven is pressed between a pair of metal rollers.
- the disadvantage of the film-nonwoven composite material produced in this way is that the mechanical properties of the fleece are changed by the hot melt adhesive or the extruded polyolefin polymer, as the hot melt adhesive or the extruded polyolefin polymer coats the fibers of the fleece and is then pressed against the film.
- the hot melt adhesive or the extruded polyolefin polymer penetrates the fleece to its surface facing away from the film, making it stiff and impairing the mechanical locking with the rough surface of the film.
- the described methods of fixing the fleece to the film also require a high material consumption of hot melt adhesive or polyolefin polymer, which is not necessary for the desired mechanical locking function of the fleece.
- the use of hot melt is also disadvantageous because hot melt adhesives are expensive and make it difficult to recycle objects made from the film-nonwoven composite material.
- a non-slip, heat-sealable plastic packaging bag and a method and a device for its production are known.
- the bag is made of a flexible plastic material, on the surface of which a large number of separate, anti-slip projections made of a thermoplastic polymer are applied.
- the material of the anti-slip projections should be different from the material of the bag.
- DE 40 33 499 A1 discloses a method for equipping a thermoplastic film web for further processing into sacks, wherein the sacks have perforated areas that are covered with fleece strips.
- the fleece strips are attached to the film web with a connecting means, wherein the film web, the fleece strip and the connecting means are made of the same thermoplastic.
- This method solves the problem that plastic bags coated with adhesives can no longer be recycled or can only be recycled for inferior applications.
- the melted connecting means is applied along the edge areas of the fleece strip between the fleece strip and the film web and connecting pressure is exerted on the fleece strip, connecting means and film web so that the thermoplastic of the connecting means at least partially penetrates the fleece strip and connects the fleece strip to the film web while the thermoplastic hardens.
- the method described in DE 40 33 499 A1 has the disadvantage described above that the partial or complete Penetration of plastic into the fleece impairs its mechanical locking with rough surfaces of adjacent bags.
- the fleece strip is only attached to its edges, so that the fleece is freely movable between its edges due to its elastic properties, which means that it is not suitable for preventing bags lying on top of one another from slipping.
- This problem is not addressed in DE 40 33 499 A1 because the fleece strips in the bags disclosed only serve to cover perforations in the bag body made from the film web. For this reason alone, it would not be possible to attach the fleece strip over the entire surface of the film web by applying the melted connecting agent and then applying connecting pressure, because this would close the perforations in the film web.
- a method for producing a sack is known from the document WO 2011/018318 A1, wherein the sack contains a plastic nonwoven material.
- the method comprises providing a flat sheet material with at least two layers, with a first layer of a plastic nonwoven material and a second layer of a plastic coating, forming a tube from the flat sheet material by laying the side regions of the flat sheet material on top of one another to form an overlap and connecting them to one another, wherein after the tube has been formed, the plastic coating faces outwards and the plastic nonwoven material layer faces inwards, separating the tube into tube pieces and forming a base on at least one end of a tube piece.
- the flat sheet material with at least two layers or the tube produced from it is perforated.
- the plastic nonwoven material layer is permeable to air, which is important when filling the sacks so that the air can escape from the inside of the sack, but the plastic coating prevents the air from escaping.
- the disadvantage of perforating the flat sheet material that includes the plastic fleece material layer and the plastic coating is that the plastic fleece material layer is also perforated.
- a fleece layer forms a labyrinth with its many fibers that allows air to pass through but holds back the filling material contained in the bag, usually granular or powdery, and thus prevents the filling material from escaping from the bag.
- the object of the present invention is to propose a method and a device for producing a flexible web-shaped composite material which overcomes or at least mitigates the above-mentioned disadvantages of the prior art.
- the flexible web-shaped composite material produced according to the invention is used to produce sacks.
- the invention solves the problem by providing a method for producing a flexible web-shaped composite material with the features of claim 1 and a device with the features of claim 17.
- Advantageous embodiments of the invention are set out in dependent claims, the description and the drawings.
- the method according to the invention for producing a flexible sheet-like composite material comprises providing a sheet-like substrate which at least partially contains a first thermoplastic polymer, providing a sheet-like nonwoven material which at least partially contains a second thermoplastic polymer, applying discrete particles containing a third thermoplastic polymer to the sheet-like substrate or to the sheet-like nonwoven material by providing a release surface, providing and arranging a plurality of the discrete particles on the release surface, wherein the release surface has a temperature which is above a softening temperature of the third thermoplastic polymer, heating the particles arranged on the release surface above the softening temperature of the third thermoplastic polymer, bringing a surface of the substrate or the nonwoven material into contact with the release surface and the softened particles arranged thereon so that the particles adhere to the surface of the substrate or the nonwoven material, then removing the surface of the substrate or the nonwoven material with the particles adhering thereto.
- Particles from the release surface and optionally cooling the particles adhering to the surface of the substrate or the nonwoven material below the softening temperature of the third thermoplastic polymer, bringing the substrate and the nonwoven material together, wherein the surface of the substrate or the nonwoven material with the particles adhering thereto faces a surface of the nonwoven material or the substrate, pressing the substrate and the nonwoven material together, whereby the particles bond the mutually facing surfaces of the substrate and the nonwoven material to one another, optionally before pressing the substrate and the Nonwoven material, heating of the particles adhering to the surface of the substrate or the nonwoven material above the softening temperature of the third thermoplastic polymer takes place, and optionally cooling the composite material thus produced from the substrate and the nonwoven material.
- This method connects the substrate and the nonwoven material to one another by means of a large number of discrete connection points made of particles containing the third thermoplastic polymer, with the connection points being distributed as evenly as possible over essentially the entire connection surface between the substrate and the nonwoven material, so that the overall effect of a "full-surface" connection with homogeneous connection properties is created.
- the cavities of the nonwoven material remain largely intact, so that they are retained both for the positive connection with a material made slip-resistant by the application of plastic particles and for the retention of powdery or granular material through the labyrinth channels formed by the cavities of the nonwoven.
- the method according to the invention makes it possible to dispense with expensive equipment such as extruders or hot melt melting devices.
- the material consumption of the connecting agent i.e. the particles, is significantly lower than when connecting a substrate to a fleece using hot melt adhesive or extruded polymer.
- Another positive effect of the invention is the possibility of recycling the substrate and fleece together.
- discrete particles containing a fourth thermoplastic polymer are applied to the surface of the substrate opposite the nonwoven material by providing a release surface, providing and arranging a plurality of the discrete particles on the release surface, wherein the release surface has a temperature which is above a softening temperature of the fourth thermoplastic polymer, heating the particles arranged on the release surface above the softening temperature of the fourth thermoplastic polymer, bringing the surface of the substrate opposite the nonwoven material into contact with the release surface and the softened particles arranged thereon so that the particles adhere to the surface of the substrate, and then removing the surface of the substrate with the particles adhering thereto from the Detachment surface, and optionally cooling the particles adhering to the surface of the substrate below the softening temperature of the fourth thermoplastic polymer.
- cooling is understood to mean active cooling using a cooling device or passive cooling by allowing it to cool, e.g. in the ambient air.
- the flexible web-shaped composite material produced in this way therefore meets all the requirements to be processed into bags that are characterized by high slip resistance when stacked on top of one another, in that the particles applied to a surface of the substrate that forms an outer surface of the bag engage in a form-fitting manner in the cavities of the nonwoven material of the composite material, which is arranged on an outer surface of the bag that is opposite the outer surface of the bag with the particles.
- the nonwoven material is connected to the substrate over the entire connection surface by a large number of connection points, it does not come loose when shear forces occur when a stack of bags lying on top of one another, in which one side with nonwoven fabric of a bag faces one side with particles on the substrate of an adjacent bag, is tilted. This means that high tilt angles, typically of 35° and more, are possible without the bags slipping; instead, the stack of bags will fall over first. This means that when stacking bags, there is no need for stretch film, shrink film or covers or other means of securing the load.
- the device on which the web-shaped composite material is produced according to the method according to the invention can be considerably simplified because a single release surface is used for applying the particles on both sides of the composite material.
- the web-shaped substrate may be tubular for the production of bags, whereby, depending on the type of bags to be produced from the composite material, the tubular substrate is optionally provided with side folds.
- the substrate has at least one layer of a plastic ribbon fabric, preferably made of PP, HDPE or PET.
- the plastic ribbon fabric can have an optionally printed coating or a have a laminated plastic film, which serves, for example, as a carrier for printing or as a barrier layer, e.g. as a moisture barrier layer.
- the substrate is a single- or multi-layer, optionally printed plastic film, preferably made of PP, LLDPE, LDPE, HDPE or PET.
- the composite material produced according to the invention must be permeable to air, for example when valve bags are made from the composite material which are filled with powdery or granular filling material by means of an air stream, whereby the air must be able to escape from the bag.
- the substrate is perforated before it is combined with the fleece material. It is important that only the substrate and not the fleece material is perforated, because otherwise the fleece material would lose its retention function for the filling material, for example very fine-grained/fine-dust cement.
- the nonwoven material is a spunbonded nonwoven or a carded nonwoven or a spunlace material or a meltblown material or a spunbond material or a composite material of the materials mentioned.
- first and/or the second thermoplastic polymer is selected from: PET, PP, PE, or a co- or terpolymer containing two or three of the following monomers: ethylene, propylene, vinyl acetate, alkyl acrylate, maleic anhydride, alpha-olefin.
- the first and the second thermoplastic polymer can be selected from the same material or from different materials.
- the third and/or fourth thermoplastic polymer are selected from: PET, PP, PE, or a co- or terpolymer containing two or three of the following monomers: ethylene, propylene, vinyl acetate, alkyl acrylate, maleic anhydride, alpha-olefin.
- the third and fourth thermoplastic polymers can be selected from the same material or from different materials.
- the particles containing the third thermoplastic polymer have an average particle size of less than or equal to 1000 pm.
- the particles containing the fourth thermoplastic polymer have an average particle size between 80 and 800 pm, preferably between 100 and 500 pm, whereby for largely homogeneous bonding and slip resistance properties, particle sizes that are as uniform as possible, in particular with size differences of less than a factor of 3, are particularly preferred.
- the particles containing the fourth thermoplastic polymer are selected by sieving with sieves of defined mesh width, which ensures good, uniform particle sizes.
- the particles are applied to the substrate and/or the nonwoven material with a basis weight of between 1 g and 20 g per m 2 , preferably between 3 g and 5 g per m 2 .
- basis weights are far below the basis weights of extrusion connections, but still ensure sufficient bonding strength, whereby the bonding strength can be adjusted by selecting an appropriate basis weight so that the nonwoven material does not detach from the substrate due to the action of shear forces, but can be pulled off the substrate by applying force perpendicular to the bonding surface, e.g. by hand. If the basis weight of the particles is in the specified range, this also ensures that the particles do not clog the cavities in the nonwoven material.
- the particles are set to a temperature above their softening temperature but below their melting temperature when bonding to the substrate or the nonwoven material. This means that the particles are embedded in the substrate or the nonwoven material, the nonwoven material or its fibers remain essentially non-destructive, but good adhesive properties are nevertheless created between the substrate and the nonwoven material (through positive locking). In this procedure, the particles do not form large, undefined areas that change the mechanical properties of the substrate or nonwoven material, as is the case when plastic extrudate or hot melt is applied over the entire surface. It should be mentioned that it has proven to be expedient if the heating of the particles on the release surface takes place to a higher temperature, which can also be above the melting temperature of the particles, than when the substrate and nonwoven are bonded using the particles.
- the web-shaped composite material is formed from the substrate and the nonwoven material into a tube by placing the side regions of the flat, web-shaped composite material on top of one another to form an overlap and connecting them to one another, the nonwoven material forming an inner layer of the tube.
- a tubular Composite material can be formed into bags in which the nonwoven material forms an inner layer that prevents the contents, such as fine-grained/dusty cement material, from escaping to the outside by separating the tube into tube pieces and forming a base at at least one end of the tube pieces. This is particularly advantageous if the substrate has been perforated before being connected to the nonwoven material.
- Fig. 1 shows schematically a first embodiment of an apparatus for producing a flexible web-shaped composite material according to the invention.
- Fig. 2 shows schematically a second embodiment of an apparatus for producing a flexible web-shaped composite material according to the invention.
- Fig. 3 shows a turning device of the device of Fig. 2.
- Fig. 4 shows schematically a simpler embodiment of the device shown in Fig. 1 for producing a flexible web-shaped composite material.
- Fig. 5 shows the production of a hose from a flat web-shaped composite material according to the invention.
- Fig. 1 shows a device 1 for producing a flexible web-shaped composite material 2.
- This device 1 is provided with a web-shaped substrate 3, which at least partially contains a first thermoplastic polymer, wound up on a roll.
- the web-shaped substrate 3 can be a flat material or a tubular material, optionally with side folds.
- the device 1 is also provided with a web-shaped nonwoven material 4, which at least partially contains a second thermoplastic polymer, wound up on a roll.
- the web-shaped substrate 3 is unwound from its roll by means of feed means (not shown), such as driven roller pairs, pulled through a perforation device 5 where it is perforated, and fed to a release surface 6.
- the release surface is designed as a heated endless conveyor belt circulating around rollers, which is preferably equipped with a surface made of polytetrafluoroethylene (PTFE), known under the brand name "Teflon", or a material with similar properties to PTFE.
- PTFE polytetrafluoroethylene
- Discrete particles 7 containing a third thermoplastic polymer are discharged from a container 8, for example by means of a spreading roller, applied in large numbers in as even a distribution as possible to the release surface 6.
- the heated release surface 6 has a temperature which is above a softening temperature of the third thermoplastic polymer.
- the particles 7 heat up on the release surface above the softening temperature of the third thermoplastic polymer and, in the softened state, adhere sufficiently to the release surface 6 that they do not fall off the release surface 6 even when they are transported on the rotating release surface 6.
- the substrate 3 and the release surface 6 run through a pair of rollers 9 so that the particles 7 on the release surface 6 face a surface 3a of the substrate 3.
- the pair of rollers 9 presses the particles 7 against the surface 3a of the substrate 3, whereby the softened particles 7 adhere to the surface 3a of the substrate 3.
- the surface 3a of the substrate 3 with the particles 7 transferred to it then moves away from the release surface 6, which is then ready for the renewed application of particles 7.
- the surface 3a of the substrate 3 is now cooled until the particles 7 have a temperature below the softening temperature of the third polymer.
- cooling is carried out actively by means of a cooling device 10.
- passive cooling e.g. by ambient air, can also be provided, in which the particles 7 are allowed to cool on the substrate 3. If the substrate 3 with the particles 7 adhering to it is processed directly, cooling below the softening temperature can be omitted.
- the web-shaped nonwoven material 4 is fed by unwinding it from its roll by means of feed means (not shown), such as driven rollers, and the nonwoven material 4 is brought together with the substrate 3 via a roller 21, wherein the surface 3a of the substrate 3 with the particles 7 adhering to it faces a surface 4a of the nonwoven material 4.
- feed means such as driven rollers
- the superimposed layers of substrate 3 and nonwoven material 4 are then heated by means of a heating device 11 above the softening temperature of the third thermoplastic polymer of the particles 7 adhering to the surface 3a of the substrate 3, followed by the pressing together of the substrate 3 and the nonwoven material 4 by means of a pair of rollers 12, whereby the softened particles 7 connect the mutually facing surfaces 3a, 4a of the substrate 3 and the nonwoven material 4 to one another.
- the flexible web-shaped composite material 2 produced in this way is finally cooled either actively by means of a cooling device 14 or passively by being allowed to cool in the ambient air during transport through the device 1, and can be wound onto a roll for further processing.
- An embodiment of the device 1 for producing the flexible web-shaped composite material 2, which comprises the parts described so far and in which the composite material 2 is wound onto a roll for further processing, is shown schematically in Fig. 4.
- the main advantage of the device 1 and the method carried out thereon is that the substrate 3 and the nonwoven material 4 are connected to one another by a large number of discrete connection points made of the particles 7 containing the third thermoplastic polymer, wherein the connection points are distributed as evenly as possible and extend essentially over the entire connection surface between the substrate 3 and the nonwoven material 4, so that the overall effect of a "full-surface” connection with homogeneous connection properties is created.
- the cavities of the nonwoven material 4 remain largely intact.
- the substrate 3 is first fed in and, after the particles 7 have been applied, is brought together and connected to the nonwoven material 4. It should be mentioned, however, that the device 1 is also suitable for first feeding the nonwoven material 4 and, after the particles 7 have been applied to the nonwoven material 4, bringing it together with the substrate 3 so that their surfaces 3a, 4a are connected to one another by a plurality of connection points consisting of the particles 7.
- the composite material is further treated immediately after its production by applying discrete particles 17 containing a fourth thermoplastic polymer to the surface 3b of the substrate 3 opposite the nonwoven material 4, i.e. facing away from it, after the substrate 3 and the nonwoven material 4 have been pressed together by the pair of rollers 12.
- the particles 17 are applied by applying the particles 17 from a container 18, for example by means of a spreading roller, in a large number in as even a distribution as possible to a heated release surface 16.
- the heated release surface 16 has a temperature which is above a softening temperature of the fourth thermoplastic polymer.
- the particles 17 heat up on the release surface 16 above the softening temperature of the fourth thermoplastic polymer and, in the softened state, adhere sufficiently to the release surface 16 that they do not fall off the release surface 16 even when they are transported on the rotating release surface 16.
- the release surface 16 is designed as a heated endless conveyor belt rotating around rollers, which is preferably covered with a surface made of PTFE or a material with similar properties to PTFE.
- the composite material 2 and the release surface 16 pass through a pair of rollers 19 so that the particles 17 on the release surface 16 face the surface 3b of the substrate 3.
- the pair of rollers 19 presses the particles 17 against the surface 3b of the substrate 3 of the composite material 2, whereby the softened particles 17 adhere to the surface 3b of the substrate 3.
- the surface 3b of the substrate 3 of the composite material 2 with the particles 17 transferred thereto then moves away from the release surface 16, which is thus ready for new application of particles 17.
- the composite material 2 is now cooled actively by means of a cooling device 14 or passively by being allowed to cool, e.g. in the ambient air, until the particles 17 have a temperature below the softening temperature of the fourth polymer.
- the web-shaped flexible composite material treated in this way is then wound onto a roll for further use, for example for the production of bags.
- thermoplastic polymers examples are given above in the text.
- Fig. 2 shows schematically a further embodiment of a device 20 for producing a flexible web-shaped composite material 2, which essentially carries out the same process steps as the device 1 of Fig. 1.
- the same or similar device parts as in the embodiment of Fig. 1 are provided with the same reference numerals in Fig. 2 and for their explanation reference is made to the description of the device of Fig. 1.
- the essential difference between the two devices 1, 20 is that in the device 20 of Fig. 2 only one release surface 6 is used, with which both surfaces 3a, 3b of the substrate 3 are provided one after the other with particles 7, 17.
- the substrate 3 is turned in a turning device 30 after the particles 7 have been applied to its first surface 3a.
- the nonwoven material 4 is then brought together with the first surface 3a of the substrate provided with the particles 7.
- the substrate 3 and the nonwoven material 4 are connected to one another at their mutually facing surfaces by a plurality of connection points, as described in detail above with reference to Fig. 1.
- the composite material 2 produced in this way is then fed again to the release surface 6, in such a way that the surface 3b of the substrate 3 opposite the nonwoven material 4, i.e. facing away, faces the release surface 6.
- Discrete particles 17 are applied to this surface 3b of the substrate 3 opposite the nonwoven material 4 and then in the cooling device 14.
- the composite material 2 treated in this way is then wound into a roll.
- Fig. 3 shows an embodiment of a turning device 30, as can be used in the device 20 of Fig. 2, in plan view. To make the drawing easier to understand, some device parts not necessary for the explanation have been omitted.
- the representation in Fig. 3 shows the substrate 3, which has already been subjected to the particles 7 containing the third thermoplastic polymer on the pair of rollers 9, the particles 7 being applied from the container 8 to the release surface 6.
- the substrate 3 provided with the particles 7 is turned by 180° on a first deflection roller 24, then fed to a first fixed deflection rod 22, where it is deflected by 90°, then fed to a second fixed deflection rod 23, where it is deflected again by 90°.
- the substrate 3 is then turned again by 180° around a second deflection roller 25 and is thereby guided in the direction of the heated release surface 6. Before the substrate 3 comes into contact with the release surface 6, it is brought together with the nonwoven material 4 on the roller 21, as described above. The substrate 3 is then exposed to the particles 17 containing the fourth thermoplastic polymer on the pair of rollers 19, the particles 17 being applied from the container 18 to the release surface 6.
- Fig. 5 shows schematically the forming of a tube 15 from the composite material 2, which is designed as a flat material.
- the side areas 2a, 2b of the flat, web-shaped composite material 2 are placed on top of one another by deflection means (not shown) to form an overlap 2c and connected to one another, so that the nonwoven material 4 forms an inner layer of the tube 15.
- the connection of the side areas 2a, 2b of the flat, web-shaped composite material 2 takes place by introducing a plastic extrudate into the overlap 2c by means of an extruder 26 and an extrusion nozzle 27 and then passing the overlap 2c through a pair of rollers 28 and thereby pressing it together.
- Bags can then be formed from the tube 15 by separating the tube 15 into tube pieces and forming a base at at least one end of the tube pieces.
- the composite material 2 if it has a tubular substrate 3, can also be separated into tubular pieces and a base can be formed at at least one end of the tubular pieces. This makes it possible to produce cross-bottom bags, valve bags, pouches or form-fill-and-seal bags, the shapes of which are well known to those skilled in the art.
- the composite material 2 used is preferably a material whose substrate 3 has been perforated before being connected to the nonwoven material 4.
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Abstract
Description
Verfahren und Vorrichtung zur Herstellung eines flexiblen bahnförmigen Verbundmaterials Method and device for producing a flexible web-shaped composite material
Die Erfindung betrifft ein Verfahren zur Herstellung eines flexiblen bahnförmigen Verbundmaterials, gemäß dem Oberbegriff des Anspruchs 1. The invention relates to a method for producing a flexible web-shaped composite material, according to the preamble of claim 1.
Die Erfindung betrifft weiters eine Vorrichtung zur Herstellung eines flexiblen bahnförmigen Verbundmaterials, gemäß dem Oberbegriff des Anspruchs 17. The invention further relates to a device for producing a flexible web-shaped composite material, according to the preamble of claim 17.
Das Dokument EP 3 463 805 Bl beschreibt rutschfeste, flexible Materialien und Verfahren zu deren Herstellung und Verwendung. Bei diesen Verfahren werden einzelne, in einen klebrigen Zustand erhitzte thermoplastische Teilchen auf einer Oberfläche eines thermoplastischen flexiblen Trägers aufgetragen, der als rutschhemmendes flexibles Verpackungsmaterial verwendet werden kann. Es werden auch rutschfeste flexible Verpackungsbeutel offenbart, deren äußere Oberfläche aufrauende Vorsprünge aufweist, sowie Verfahren zu deren Herstellung und Verwendung. Liegen solche Beutel aufeinander, so verhindern die aufrauenden Vorsprünge ein gegenseitiges Verrutschen, auch wenn das Material der Beutel an sich nicht rutschfest ist, weil sich die Vorsprünge gegenseitig verzahnen. Es ist auch erwähnt, dass diese Vorsprünge eine wirksame, rutschfeste mechanische Verriegelung mit einem faserigen Eingriffsmaterial, wie z. B. einem handelsüblichen Vlies, herstellen, das z.B. zwischen zwei Beutel gelegt wird. Das Vlies lässt sich senkrecht von der rauen Oberfläche abheben. Weiters ist in diesem Dokument beschrieben, dass der Beutel aus einer Folie und/oder einem Gewebe und/oder einem Vliesstoff bestehen kann. Fig. 12a von EP 3 463 805 Bl zeigt eine schlauchförmige Bahn aus Kunststofffolie, bei der auf einer Oberfläche aufrauende Vorsprünge angebracht sind und auf der gegenüberliegenden Oberfläche ein Vliesstreifen fixiert ist, entweder durch einen faser-aufgesprühten Hotmelt-Kleber oder durch Extrusionslaminierung, indem ein kontinuierlicher Auftrag von schmalen Strängen eines extrudierten Polyolefinpolymers erfolgt, um die Fasern des Vlieses einzukapseln und an der Folie zu fixieren, und die Sandwich- Anordnung aus Folie/Schmelze/Vlies zwischen einem Metallwalzenpaar gepresst wird. The document EP 3 463 805 B1 describes non-slip, flexible materials and methods for their production and use. In these methods, individual thermoplastic particles heated to a sticky state are applied to a surface of a thermoplastic flexible carrier which can be used as a non-slip flexible packaging material. Non-slip flexible packaging bags are also disclosed, the outer surface of which has roughening projections, as well as methods for their production and use. If such bags lie on top of one another, the roughening projections prevent mutual slipping, even if the material of the bags is not non-slip per se, because the projections interlock with one another. It is also mentioned that these projections produce an effective, non-slip mechanical lock with a fibrous engagement material, such as a commercially available fleece, which is placed between two bags, for example. The fleece can be lifted vertically from the rough surface. This document further describes that the bag can consist of a film and/or a fabric and/or a nonwoven fabric. Fig. 12a of EP 3 463 805 B1 shows a tubular web of plastic film in which roughening projections are applied to one surface and a nonwoven strip is fixed to the opposite surface, either by a fiber-sprayed hot melt adhesive or by extrusion lamination, in which a continuous application of narrow strands of an extruded polyolefin polymer is carried out in order to encapsulate the fibers of the nonwoven and fix them to the film, and the sandwich arrangement of film/melt/nonwoven is pressed between a pair of metal rollers.
Nachteilig an dem solcherart hergestellten Folien- Vlies-Verbundmaterial ist, dass durch den Hotmelt-Kleber oder das extrudierte Polyolefinpolymer die mechanischen Eigenschaften des Vlieses verändert werden, indem der Hotmelt-Kleber oder das extrudierte Polyolefinpolymer die Fasern des Vlieses ummantelt und dann gegen die Folie gedrückt werden. Dadurch durchdringt der Hotmelt-Kleber oder das extrudierte Polyolefinpolymer das Vlies bis zu seiner von der Folie abgewandten Oberfläche, wodurch es steif wird und die mechanische Verriegelung mit der rauen Oberfläche der Folie beeinträchtigt wird. Die beschriebenen Fixierungsarten des Vlieses an der Folie bedingen auch einen hohen Materialverbrauch an Hotmelt-Kleber oder Polyolefmpolymer, der für die erwünschte mechanische Verriegelungsfunktion des Vlieses nicht notwendig ist. Die Verwendung von Hotmelt ist darüber hinaus nachteilig, weil Hotmelt-Kleber teuer sind und das Recycling von aus dem Folien- Vlies-Verbundmaterial hergestellten Gegenständen erschweren. The disadvantage of the film-nonwoven composite material produced in this way is that the mechanical properties of the fleece are changed by the hot melt adhesive or the extruded polyolefin polymer, as the hot melt adhesive or the extruded polyolefin polymer coats the fibers of the fleece and is then pressed against the film. the hot melt adhesive or the extruded polyolefin polymer penetrates the fleece to its surface facing away from the film, making it stiff and impairing the mechanical locking with the rough surface of the film. The described methods of fixing the fleece to the film also require a high material consumption of hot melt adhesive or polyolefin polymer, which is not necessary for the desired mechanical locking function of the fleece. The use of hot melt is also disadvantageous because hot melt adhesives are expensive and make it difficult to recycle objects made from the film-nonwoven composite material.
In dem Dokument US 2015/0036952 Al ist die Herstellung eines Verpackungsbeutels mit einer rutschhemmenden Beschichtung beschrieben. Dabei wird ein leicht extrudierbares olefinisches Elastomer aus einem Extrusionskopf auf einen gewebten Polypropylen- Verpackungsbeutel aufgetragen und sofort mit Walzen in mehreren voneinander beabstandeten Streifen flachgedrückt, mit dem Ziel der Erhöhung des Reibungskoeffizienten der Oberfläche des Beutels. The document US 2015/0036952 A1 describes the production of a packaging bag with an anti-slip coating. An easily extrudable olefinic elastomer is applied from an extrusion head to a woven polypropylene packaging bag and immediately flattened with rollers in several spaced-apart strips with the aim of increasing the friction coefficient of the surface of the bag.
Aus dem Dokument US 2019/02913337 Al sind ein rutschfester, heißsiegelfähiger Kunststoffverpackungsbeutel sowie ein Verfahren und eine Vorrichtung zu seiner Herstellung bekannt. Der Beutel wird aus einem flexiblen Kunststoffmaterial hergestellt, auf dessen Oberfläche eine Vielzahl separater, rutschhemmender Vorsprünge aus einem thermoplastischen Polymer aufgebracht werden. Das Material der rutschhemmenden Vorsprünge soll sich vom Material des Beutels unterscheiden. From the document US 2019/02913337 Al, a non-slip, heat-sealable plastic packaging bag and a method and a device for its production are known. The bag is made of a flexible plastic material, on the surface of which a large number of separate, anti-slip projections made of a thermoplastic polymer are applied. The material of the anti-slip projections should be different from the material of the bag.
Aus der DE 40 33 499 Al ist ein Verfahren zum Ausrüsten einer thermoplastischen Kunststofffolienbahn für die Weiterverarbeitung zu Säcken, bekannt, wobei die Säcke gelochte Bereiche aufweisen, die mit Vliesstreifen abgedeckt sind. Die Vliesstreifen werden mit einem Verbindungsmittel an der Folienbahn befestigt, wobei die Folienbahn, der Vliesstreifen und das Verbindungsmittel aus dem gleichen thermoplastischen Kunststoff bestehen. Dieses Verfahren löst das Problem, dass mit Klebstoffen beschichtete Plastiksäcke sich nicht mehr oder nur für minderwertige Anwendungsfälle recyceln lassen. Bei der Herstellung der Säcke wird das aufgeschmolzene Verbindungsmittel entlang der Randbereiche des Vliesstreifens zwischen Vliesstreifen und Folienbahn aufgebracht und Verbindungsdruck auf Vliesstreifen, Verbindungsmittel und Folienbahn ausgeübt, so dass der thermoplastische Kunststoff des Verbindungsmittels zumindest teilweise in den Vliesstreifen eindringt und den Vliesstreifen mit der Folienbahn unter Erhärtung des thermoplastischen Kunststoffes verbindet. Das in der DE 40 33 499 Al beschriebene Verfahren hat den oben beschriebenen Nachteil, dass das teilweise oder vollständige Eindringen von Kunststoff in das Vlies dessen mechanische Verriegelung mit rauen Oberflächen anliegender Säcke beeinträchtigt. Außerdem erfolgt die Anbringung des Vliesstreifens nur an dessen Rändern, so dass das Vlies zwischen seinen Rändern aufgrund seiner elastischen Eigenschaften frei beweglich ist, wodurch es zur Verhinderung von Verrutschen aufeinanderliegender Säcke nicht tauglich ist. Dieses Problem wird in der DE 40 33 499 Al nicht angesprochen, weil die Vliesstreifen bei den offenbarten Säcken nur dazu dienen, Perforationen des aus der Folienbahn hergestellten Sackkörpers abzudecken. Schon allein aus diesem Grund wäre eine vollflächige Befestigung des Vliesstreifens auf der Folienbahn durch Aufträgen des aufgeschmolzenen Verbindungsmittels und nachfolgende Verbindungsdruckausübung nicht möglich, weil dadurch die Perforationen der Folienbahn verschlossen würden. DE 40 33 499 A1 discloses a method for equipping a thermoplastic film web for further processing into sacks, wherein the sacks have perforated areas that are covered with fleece strips. The fleece strips are attached to the film web with a connecting means, wherein the film web, the fleece strip and the connecting means are made of the same thermoplastic. This method solves the problem that plastic bags coated with adhesives can no longer be recycled or can only be recycled for inferior applications. When producing the sacks, the melted connecting means is applied along the edge areas of the fleece strip between the fleece strip and the film web and connecting pressure is exerted on the fleece strip, connecting means and film web so that the thermoplastic of the connecting means at least partially penetrates the fleece strip and connects the fleece strip to the film web while the thermoplastic hardens. The method described in DE 40 33 499 A1 has the disadvantage described above that the partial or complete Penetration of plastic into the fleece impairs its mechanical locking with rough surfaces of adjacent bags. In addition, the fleece strip is only attached to its edges, so that the fleece is freely movable between its edges due to its elastic properties, which means that it is not suitable for preventing bags lying on top of one another from slipping. This problem is not addressed in DE 40 33 499 A1 because the fleece strips in the bags disclosed only serve to cover perforations in the bag body made from the film web. For this reason alone, it would not be possible to attach the fleece strip over the entire surface of the film web by applying the melted connecting agent and then applying connecting pressure, because this would close the perforations in the film web.
Aus dem Dokument WO 2011/018318 Al ist ein Verfahren zur Herstellung eines Sacks bekannt, wobei das Sack ein Kunststoffvliesmaterial enthält. Das Verfahren umfasst das Bereitstellen eines zumindest zweischichtigen Flachbahnmaterials mit einer ersten Schicht aus einem Kunststoffvliesmaterial und einer zweiten Schicht aus einer Kunststoffbeschichtung, das Bilden eines Schlauches aus dem Flachbahnmaterial, indem die Seitenbereiche des Flachbahnmaterials unter Ausbildung einer Überlappung aufeinander gelegt und miteinander verbunden werden, wobei nach dem Bilden des Schlauches die Kunststoffbeschichtung nach außen und die Kunststoffvliesmaterialschicht nach innen gerichtet ist, das Vereinzeln des Schlauches zu Schlauchstücken und das Anformen eines Bodens an zumindest einem Ende eines Schlauchstücks. Vor dem Vereinzeln des Schlauches zu Schlauchstücken wird das zumindest zweischichtige Flachbahnmaterials oder der daraus hergestellte Schlauch perforiert. Dies ist notwendig, weil die Kunststoffvliesmaterialschicht zwar luftdurchlässig ist, was beim Befüllen der Säcke wichtig ist, damit die Luft aus dem Sackinneren entweichen kann, die Kunststoffbeschichtung jedoch das Entweichen der Luft verhindert. Nachteilig am Perforieren des die Kunststoffvliesmaterialschicht und die Kunststoffbeschichtung umfassenden Flachbahnmaterials ist jedoch, dass damit auch die Kunststoffvliesmaterialschicht perforiert wird. Eine Vliesschicht bildet durch seine vielen Fasern ein Labyrinth, das zwar Luft durchlässt, aber das im Sack enthaltene, meist körnige oder pulverige Füllmaterial zurückhält und dadurch verhindert, dass das Füllmaterial aus dem Sack austritt. Wird nun die Vliesschicht perforiert, so bildet die Perforierung einen geradlinigen Durchgang durch das gesamte Flachbahnmaterial, so dass die Vliesschicht das Füllmaterial nicht mehr vor dem Durchtritt durch das Flachbahnmaterial, das die Sackwand bildet, hindern kann. Die Aufgabe der vorliegenden Erfindung ist es, ein Verfahren und eine Vorrichtung zur Herstellung eines flexiblen bahnförmigen Verbundmaterials vorzuschlagen, die die oben genannten Nachteile des Standes der Technik überwinden oder zumindest mildern. In einem Aspekt der Erfindung dient das erfindungsgemäß hergestellte flexible bahnförmige Verbundmaterial zur Herstellung von Säcken. A method for producing a sack is known from the document WO 2011/018318 A1, wherein the sack contains a plastic nonwoven material. The method comprises providing a flat sheet material with at least two layers, with a first layer of a plastic nonwoven material and a second layer of a plastic coating, forming a tube from the flat sheet material by laying the side regions of the flat sheet material on top of one another to form an overlap and connecting them to one another, wherein after the tube has been formed, the plastic coating faces outwards and the plastic nonwoven material layer faces inwards, separating the tube into tube pieces and forming a base on at least one end of a tube piece. Before separating the tube into tube pieces, the flat sheet material with at least two layers or the tube produced from it is perforated. This is necessary because the plastic nonwoven material layer is permeable to air, which is important when filling the sacks so that the air can escape from the inside of the sack, but the plastic coating prevents the air from escaping. The disadvantage of perforating the flat sheet material that includes the plastic fleece material layer and the plastic coating is that the plastic fleece material layer is also perforated. A fleece layer forms a labyrinth with its many fibers that allows air to pass through but holds back the filling material contained in the bag, usually granular or powdery, and thus prevents the filling material from escaping from the bag. If the fleece layer is now perforated, the perforation forms a straight passage through the entire flat sheet material, so that the fleece layer can no longer prevent the filling material from passing through the flat sheet material that forms the bag wall. The object of the present invention is to propose a method and a device for producing a flexible web-shaped composite material which overcomes or at least mitigates the above-mentioned disadvantages of the prior art. In one aspect of the invention, the flexible web-shaped composite material produced according to the invention is used to produce sacks.
Die Erfindung löst die gestellte Aufgabe durch Bereitstellen eines Verfahrens zur Herstellung eines flexiblen bahnförmigen Verbundmaterials mit den Merkmalen des Anspruchs 1 und einer Vorrichtung mit den Merkmalen des Anspruchs 17. Vorteilhafte Ausgestaltungen der Erfindung sind in abhängigen Ansprüchen, der Beschreibung und den Zeichnungen dargelegt. The invention solves the problem by providing a method for producing a flexible web-shaped composite material with the features of claim 1 and a device with the features of claim 17. Advantageous embodiments of the invention are set out in dependent claims, the description and the drawings.
Das erfindungsgemäße Verfahren zur Herstellung eines flexiblen bahnförmigen Verbundmaterials umfasst das Bereitstellen eines bahnförmigen Substrats, das wenigstens zum Teil ein erstes thermoplastisches Polymer enthält, das Bereitstellen eines bahnförmigen Vliesmaterials, das wenigstens zum Teil ein zweites thermoplastisches Polymer enthält, das Aufbringen von diskreten Partikeln, die ein drittes thermoplastisches Polymer enthalten, an dem bahnförmigen Substrat oder an dem bahnförmigen Vliesmaterial, durch Bereitstellen einer Ablösefläche, Bereitstellen und Anordnen einer Vielzahl der diskreten Partikel auf der Ablösefläche, wobei die Ablösefläche eine Temperatur aufweist, die über einer Erweichungstemperatur des dritten thermoplastischen Polymers liegt, Erwärmen der auf der Ablösefläche angeordneten Partikel über der Erweichungstemperatur des dritten thermoplastischen Polymers, Inkontaktbringen einer Oberfläche des Substrats oder des Vliesmaterials mit der Ablösefläche und den darauf angeordneten erweichten Partikeln, so dass die Partikel an der Oberfläche des Substrats oder des Vliesmaterials anhaften, anschließend Entfernen der Oberfläche des Substrats oder des Vliesmaterials mit den daran anhaftenden Partikeln von der Ablösefläche, und optionalem Abkühlen der an der Oberfläche des Substrats oder des Vliesmaterials anhaftenden Partikel unter die Erweichungstemperatur des dritten thermoplastischen Polymers, das Zusammenführen des Substrats und des Vliesmaterials, wobei die Oberfläche des Substrats oder des Vliesmaterials mit den daran anhaftenden Partikeln einer Oberfläche des Vliesmaterials oder des Substrats zugewandt ist, das Zusammenpressen des Substrats und des Vliesmaterials, wodurch die Partikel die einander zugewandten Oberflächen des Substrats und des Vliesmaterials miteinander verbinden, wobei gegebenenfalls vor dem Zusammenpressen des Substrats und des Vliesmaterials ein Erwärmen der auf der Oberfläche des Substrats oder des Vliesmaterials anhaftenden Partikel über der Erweichungstemperatur des dritten thermoplastischen Polymers erfolgt, und das optionale Abkühlen des so erzeugten Verbundmaterials aus dem Substrat und dem Vliesmaterial. The method according to the invention for producing a flexible sheet-like composite material comprises providing a sheet-like substrate which at least partially contains a first thermoplastic polymer, providing a sheet-like nonwoven material which at least partially contains a second thermoplastic polymer, applying discrete particles containing a third thermoplastic polymer to the sheet-like substrate or to the sheet-like nonwoven material by providing a release surface, providing and arranging a plurality of the discrete particles on the release surface, wherein the release surface has a temperature which is above a softening temperature of the third thermoplastic polymer, heating the particles arranged on the release surface above the softening temperature of the third thermoplastic polymer, bringing a surface of the substrate or the nonwoven material into contact with the release surface and the softened particles arranged thereon so that the particles adhere to the surface of the substrate or the nonwoven material, then removing the surface of the substrate or the nonwoven material with the particles adhering thereto. Particles from the release surface, and optionally cooling the particles adhering to the surface of the substrate or the nonwoven material below the softening temperature of the third thermoplastic polymer, bringing the substrate and the nonwoven material together, wherein the surface of the substrate or the nonwoven material with the particles adhering thereto faces a surface of the nonwoven material or the substrate, pressing the substrate and the nonwoven material together, whereby the particles bond the mutually facing surfaces of the substrate and the nonwoven material to one another, optionally before pressing the substrate and the Nonwoven material, heating of the particles adhering to the surface of the substrate or the nonwoven material above the softening temperature of the third thermoplastic polymer takes place, and optionally cooling the composite material thus produced from the substrate and the nonwoven material.
Durch dieses Verfahren werden das Substrat und das Vliesmaterial durch eine Vielzahl von diskreten Verbindungspunkten aus den das dritte thermoplastische Polymer enthaltenden Partikeln miteinander verbunden, wobei sich die Verbindungspunkte möglichst gleich verteilt im Wesentlichen über die gesamte Verbindungsfläche zwischen dem Substrat und dem Vliesmaterial erstrecken, so dass insgesamt der Effekt einer „vollflächigen“ Verbindung mit homogenen Verbindungseigenschaften entsteht. Im Gegensatz zu den aus dem Stand der Technik bekannten Verbindungen eines Substrats und eines Vlieses mittels Extrusionslaminierung oder Verklebung bleiben gemäß der Erfindung die Hohlräume des Vliesmaterials weitgehend intakt, so dass sie sowohl zur formschlüssigen Verbindung mit einem durch das Aufbringen von Kunststoffpartikeln rutschhemmend gemachten Material als auch zur Rückhaltung von pulverigem oder körnigem Material durch die durch die Hohlräume des Vlieses gebildeten Labyrinthgänge erhalten bleiben. This method connects the substrate and the nonwoven material to one another by means of a large number of discrete connection points made of particles containing the third thermoplastic polymer, with the connection points being distributed as evenly as possible over essentially the entire connection surface between the substrate and the nonwoven material, so that the overall effect of a "full-surface" connection with homogeneous connection properties is created. In contrast to the connections of a substrate and a nonwoven by means of extrusion lamination or bonding known from the prior art, according to the invention the cavities of the nonwoven material remain largely intact, so that they are retained both for the positive connection with a material made slip-resistant by the application of plastic particles and for the retention of powdery or granular material through the labyrinth channels formed by the cavities of the nonwoven.
Vorteilhaft kann gemäß dem erfindungsgemäßen Verfahren auf teure Ausrüstung, wie Extruder oder Hotmelt-Schmelzeinrichtungen verzichtet werden. Zudem ist der Materialverbrauch des Verbindungsmittels, d.h. der Partikel, wesentlich geringer als beim Verbinden eines Substrats mit einem Vlies durch Hotmelt-Kleber oder extrudiertes Polymer. Ein weiterer positiver Effekt der Erfindung ist die Möglichkeit des gemeinsamen Recycelns von Substrat und Vlies. Advantageously, the method according to the invention makes it possible to dispense with expensive equipment such as extruders or hot melt melting devices. In addition, the material consumption of the connecting agent, i.e. the particles, is significantly lower than when connecting a substrate to a fleece using hot melt adhesive or extruded polymer. Another positive effect of the invention is the possibility of recycling the substrate and fleece together.
In einer Fortbildung der Erfindung werden nach dem Zusammenpressen des Substrats und des Vliesmaterials auf der dem Vliesmaterial gegenüberliegenden Oberfläche des Substrats diskrete Partikel aufgebracht, die ein viertes thermoplastisches Polymer enthalten, durch Bereitstellen einer Ablösefläche, Bereitstellen und Anordnen einer Vielzahl der diskreten Partikel auf der Ablösefläche, wobei die Ablösefläche eine Temperatur aufweist, die über einer Erweichungstemperatur des vierten thermoplastischen Polymers liegt, Erwärmen der auf der Ablösefläche angeordneten Partikel über der Erweichungstemperatur des vierten thermoplastischen Polymers, Inkontaktbringen der dem Vliesmaterial gegenüberliegenden Oberfläche des Substrats mit der Ablösefläche und den darauf angeordneten erweichten Partikeln, so dass die Partikel an der Oberfläche des Substrats anhaften, und anschließend Entfernen der Oberfläche des Substrats mit den daran anhaftenden Partikeln von der Ablösefläche, und optional Abkühlen der an der Oberfläche des Substrats anhaftenden Partikel unter die Erweichungstemperatur des vierten thermoplastischen Polymers. Unter „Abkühlen“ wird in diesem Text grundsätzlich aktives Abkühlen mittels einer Kühleinrichtung oder passives Ab kühl en durch Ab kühlenlassen, z.B. an der Umgebungsluft, verstanden. In a further development of the invention, after the substrate and the nonwoven material have been pressed together, discrete particles containing a fourth thermoplastic polymer are applied to the surface of the substrate opposite the nonwoven material by providing a release surface, providing and arranging a plurality of the discrete particles on the release surface, wherein the release surface has a temperature which is above a softening temperature of the fourth thermoplastic polymer, heating the particles arranged on the release surface above the softening temperature of the fourth thermoplastic polymer, bringing the surface of the substrate opposite the nonwoven material into contact with the release surface and the softened particles arranged thereon so that the particles adhere to the surface of the substrate, and then removing the surface of the substrate with the particles adhering thereto from the Detachment surface, and optionally cooling the particles adhering to the surface of the substrate below the softening temperature of the fourth thermoplastic polymer. In this text, "cooling" is understood to mean active cooling using a cooling device or passive cooling by allowing it to cool, e.g. in the ambient air.
Damit erfüllt das solcherart hergestellte flexible bahnförmige Verbundmaterial alle Voraussetzungen, um zu Säcken verarbeitet zu werden, die sich beim Stapeln übereinander durch hohe Rutschfestigkeit auszeichnen, indem die auf einer Oberfläche des Substrats, die eine Außenfläche des Sacks bildet, aufgebrachten Partikel formschlüssig in die Hohlräume des Vliesmaterials des Verbundmaterials eingreifen, das beim Sack auf einer Außenfläche angeordnet ist, die der Außenfläche des Sacks mit den Partikeln gegenüberliegt. Da das Vliesmaterial über die gesamte Verbindungsfläche mit dem Substrat durch eine Vielzahl von Verbindungspunkten verbunden ist, löst es sich auch nicht bei auftretenden Scherkräften, wenn ein Stapel aus aufeinander liegenden Säcken, bei denen jeweils eine Seite mit Vlies eines Sackes einer Seite mit Partikeln auf dem Substrat eines benachbarten Sackes zugewandt ist, gekippt wird. D.h. es sind hohe Kippwinkel, typischerweise von 35° und mehr möglich, ohne dass die Säcke verrutschen, sondern es wird zuvor der Sackstapel umfallen. Damit können bei gestapelten Säcken Stretchfolien, Schrumpffolien oder -hauben oder sonstige Mittel zur Ladungssicherung entfallen. The flexible web-shaped composite material produced in this way therefore meets all the requirements to be processed into bags that are characterized by high slip resistance when stacked on top of one another, in that the particles applied to a surface of the substrate that forms an outer surface of the bag engage in a form-fitting manner in the cavities of the nonwoven material of the composite material, which is arranged on an outer surface of the bag that is opposite the outer surface of the bag with the particles. Since the nonwoven material is connected to the substrate over the entire connection surface by a large number of connection points, it does not come loose when shear forces occur when a stack of bags lying on top of one another, in which one side with nonwoven fabric of a bag faces one side with particles on the substrate of an adjacent bag, is tilted. This means that high tilt angles, typically of 35° and more, are possible without the bags slipping; instead, the stack of bags will fall over first. This means that when stacking bags, there is no need for stretch film, shrink film or covers or other means of securing the load.
Wenn das Substrat oder der Verbund aus dem Substrat und dem Vliesmaterial vor dem Aufbringen der das vierte thermoplastische Polymer enthaltenden Partikel auf der dem Vliesmaterial gegenüberliegenden Oberfläche des Substrats gewendet und diese Oberfläche des Substrats der Ablösefläche zugewandt wird, die auch zum Aufbringen der Partikel, die ein drittes thermoplastisches Polymer enthalten, dient, kann die Vorrichtung, auf der das bahnförmige Verbundmaterial gemäß dem erfindungsgemäßen Verfahren hergestellt wird, erheblich vereinfacht werden, weil eine einzige Ablösefläche für das Aufbringen der Partikel auf beiden Seiten des Verbundmaterials verwendet wird. If the substrate or the composite of the substrate and the nonwoven material is turned over before the application of the particles containing the fourth thermoplastic polymer on the surface of the substrate opposite the nonwoven material and this surface of the substrate is turned towards the release surface which also serves for applying the particles containing a third thermoplastic polymer, the device on which the web-shaped composite material is produced according to the method according to the invention can be considerably simplified because a single release surface is used for applying the particles on both sides of the composite material.
Das bahnförmige Substrat kann zur Herstellung von Säcken schlauchförmig sein, wobei je nach Art der aus dem Verbundmaterial herzustellenden Säcke das schlauchförmige Substrat optional mit Seitenfalten versehen ist. The web-shaped substrate may be tubular for the production of bags, whereby, depending on the type of bags to be produced from the composite material, the tubular substrate is optionally provided with side folds.
In einer bevorzugten Ausführungsform der Erfindung weist das Substrat zumindest eine Lage aus einem Kunststoffbändchengewebe, vorzugsweise aus PP, HDPE oder PET, auf. Das Kunststoffbändchengewebe kann eine, optional bedruckte, Beschichtung oder eine auflaminierte Kunststofffolie aufweisen, die z.B. als Träger für eine Bedruckung oder als Barrierreschicht, z.B. als Feuchtigkeitssperrschicht, dient. In a preferred embodiment of the invention, the substrate has at least one layer of a plastic ribbon fabric, preferably made of PP, HDPE or PET. The plastic ribbon fabric can have an optionally printed coating or a have a laminated plastic film, which serves, for example, as a carrier for printing or as a barrier layer, e.g. as a moisture barrier layer.
In einer alternativen Ausführungsform der Erfindung ist das Substrat eine ein- oder mehrschichtige, optional bedruckte Kunststofffolie, vorzugsweise aus PP, LLDPE, LDPE, HDPE oder PET. In an alternative embodiment of the invention, the substrate is a single- or multi-layer, optionally printed plastic film, preferably made of PP, LLDPE, LDPE, HDPE or PET.
Für gewisse Anwendungen muss das gemäß der Erfindung hergestellte Verbundmaterial luftdurchlässig sein, beispielsweise wenn aus dem Verbundmaterial Ventilsäcke hergestellt werden, die mittels eines Luftstroms mit pulverigem oder körnigem Füllgut befüllt werden, wobei die Luft aus dem Sack austreten können muss. Für solche Anwendungen ist vorgesehen, dass das Substrat vor seinem Zusammenführen mit dem Vliesmaterial perforiert wird. Wesentlich ist dabei, dass nur das Substrat, nicht aber auch das Vliesmaterial perforiert wird, weil sonst das Vliesmaterial seine Rückhaltefunktion für das Füllgut, beispielsweise sehr feinkörniger/feinstaubiger Zement, verlieren würde. For certain applications, the composite material produced according to the invention must be permeable to air, for example when valve bags are made from the composite material which are filled with powdery or granular filling material by means of an air stream, whereby the air must be able to escape from the bag. For such applications, the substrate is perforated before it is combined with the fleece material. It is important that only the substrate and not the fleece material is perforated, because otherwise the fleece material would lose its retention function for the filling material, for example very fine-grained/fine-dust cement.
Bevorzugt ist das Vliesmaterial ein Spinnvlies oder ein kardiertes Vlies oder ein Spunlacematerial oder ein Meltblownmaterial oder ein Spunbondmaterial oder ein Verbundmaterial aus den genannten Materialien. Preferably, the nonwoven material is a spunbonded nonwoven or a carded nonwoven or a spunlace material or a meltblown material or a spunbond material or a composite material of the materials mentioned.
Es hat sich bewährt, wenn das erste und/oder das zweite thermoplastische Polymer ausgewählt wird aus: PET, PP, PE, oder einem Co- oder Terpolymer, das zwei bzw. drei der folgenden Monomere enthält: Ethylen, Propylen, Vinylacetat, Alkylacrylat, Maleinsäureanhydrid, Alpha-Olefin. Dabei können das erste und das zweite thermoplastische Polymer aus demselben Material oder aus verschiedenen Materialien ausgewählt werden. It has proven to be effective if the first and/or the second thermoplastic polymer is selected from: PET, PP, PE, or a co- or terpolymer containing two or three of the following monomers: ethylene, propylene, vinyl acetate, alkyl acrylate, maleic anhydride, alpha-olefin. The first and the second thermoplastic polymer can be selected from the same material or from different materials.
Bevorzugt werden das dritte und/oder das vierte thermoplastische Polymer ausgewählt aus: PET, PP, PE, oder einem Co- oder Terpolymer, das zwei bzw. drei der folgenden Monomere enthält: Ethylen, Propylen, Vinylacetat, Alkylacrylat, Maleinsäureanhydrid, Alpha-Olefin. Dabei können das dritte und das vierte thermoplastische Polymer aus demselben Material oder aus verschiedenen Materialien ausgewählt werden. Preferably, the third and/or fourth thermoplastic polymer are selected from: PET, PP, PE, or a co- or terpolymer containing two or three of the following monomers: ethylene, propylene, vinyl acetate, alkyl acrylate, maleic anhydride, alpha-olefin. The third and fourth thermoplastic polymers can be selected from the same material or from different materials.
In einer bevorzugten Ausführungsform der Erfindung haben die das dritte thermoplastische Polymer enthaltenden Partikel eine durchschnittliche Partikelgröße kleiner gleich 1000 pm. In einer weiteren bevorzugten Ausführungsform der Erfindung haben die das vierte thermoplastische Polymer enthaltenden Partikel eine durchschnittliche Partikelgröße zwischen 80 und 800 pm, vorzugsweise zwischen 100 und 500 pm, wobei für weitgehend homogene Verbindungs- und Rutschfestigkeitseigenschaften möglichst einheitliche Partikelgrößen, insbesondere mit Größenunterschieden von weniger als dem Faktor 3, besonders bevorzugt sind. Die das vierte thermoplastische Polymer enthaltenden Partikel werden durch Sieben mit Sieben definierter Meshweite ausgewählt, was für gute einheitliche Partikelgrößen sorgt. In a preferred embodiment of the invention, the particles containing the third thermoplastic polymer have an average particle size of less than or equal to 1000 pm. In a further preferred embodiment of the invention, the particles containing the fourth thermoplastic polymer have an average particle size between 80 and 800 pm, preferably between 100 and 500 pm, whereby for largely homogeneous bonding and slip resistance properties, particle sizes that are as uniform as possible, in particular with size differences of less than a factor of 3, are particularly preferred. The particles containing the fourth thermoplastic polymer are selected by sieving with sieves of defined mesh width, which ensures good, uniform particle sizes.
Gemäß der Erfindung ist es bevorzugt, wenn die Partikel mit einem Flächengewicht zwischen 1 g und 20 g pro m2, vorzugsweise zwischen 3 g und 5 g pro m2, auf das Substrat und/oder das Vliesmaterial aufgebracht werden. Diese Flächengewichte liegen weit unter den Flächengewichten von Extrusionsverbindungen, sorgen aber dennoch für eine ausreichende Verbindungsfestigkeit, wobei die Verbindungsfestigkeit durch Auswahl eines entsprechenden Flächengewichts so eingestellt werden kann, dass das Vliesmaterial durch Einwirken von Scherkräften sich nicht vom Substrat löst, aber durch, z.B. händische, Krafteinwirkung senkrecht zur Verbindungsfläche vom Substrat abgezogen werden kann. Liegt das Flächengewicht der Partikel in dem angegebenen Bereich, so ist dadurch auch sichergestellt, dass die Partikel die Hohlräume des Vliesmaterials nicht verstopfen. According to the invention, it is preferred if the particles are applied to the substrate and/or the nonwoven material with a basis weight of between 1 g and 20 g per m 2 , preferably between 3 g and 5 g per m 2 . These basis weights are far below the basis weights of extrusion connections, but still ensure sufficient bonding strength, whereby the bonding strength can be adjusted by selecting an appropriate basis weight so that the nonwoven material does not detach from the substrate due to the action of shear forces, but can be pulled off the substrate by applying force perpendicular to the bonding surface, e.g. by hand. If the basis weight of the particles is in the specified range, this also ensures that the particles do not clog the cavities in the nonwoven material.
Gemäß der Erfindung kann vorgesehen werden, dass die Partikel beim Verbinden mit dem Substrat oder dem Vliesmaterial auf eine Temperatur über ihrer Erweichungstemperatur, aber unter ihrer Schmelztemperatur eingestellt sind. Dadurch werden die Partikel in das Substrat oder das Vliesmaterial eingebettet, das Vliesmaterial bzw. dessen Fasern bleiben dabei im Wesentlichen zerstörungsfrei, es werden aber dennoch gute Hafteigenschaften zwischen dem Substrat und dem Vliesmaterial (durch Formschluss) hergestellt. Die Partikel bilden bei dieser Vorgangsweise keine großflächigen, Undefinierten Bereiche, die die mechanischen Eigenschaften von Substrat oder Vliesmaterial verändern, wie es beim vollflächigen Einbringen von Kunststoffextrudat oder Hotmelt der Fall ist. Es sei erwähnt, dass es sich als zweckmäßig herausgestellt hat, wenn die Erwärmung der Partikel an der Ablösefläche auf eine höhere Temperatur, die auch über der Schmelztemperatur der Partikel liegen kann, erfolgt, als bei der Verbindung von Substrat und Vlies mittels der Partikel. According to the invention, it can be provided that the particles are set to a temperature above their softening temperature but below their melting temperature when bonding to the substrate or the nonwoven material. This means that the particles are embedded in the substrate or the nonwoven material, the nonwoven material or its fibers remain essentially non-destructive, but good adhesive properties are nevertheless created between the substrate and the nonwoven material (through positive locking). In this procedure, the particles do not form large, undefined areas that change the mechanical properties of the substrate or nonwoven material, as is the case when plastic extrudate or hot melt is applied over the entire surface. It should be mentioned that it has proven to be expedient if the heating of the particles on the release surface takes place to a higher temperature, which can also be above the melting temperature of the particles, than when the substrate and nonwoven are bonded using the particles.
In einer weiteren Ausführungsform des erfindungsgemäßen Verfahrens, bei dem das bahnförmige Substrat als eine flache Bahn bereitgestellt wird, wird das bahnförmige Verbundmaterial aus dem Substrat und dem Vliesmaterial zu einem Schlauch geformt, indem die Seitenbereiche des flachliegenden, bahnförmigen Verbundmaterials unter Ausbildung einer Überlappung aufeinandergelegt und miteinander verbunden werden, wobei das Vliesmaterial eine Innenlage des Schlauchs bildet. Ein solches schlauchförmiges Verbundmaterial kann zu Säcken geformt werden, bei denen das Vliesmaterial eine Innenlage bildet, die ein Austreten des Füllguts, wie feinkörniges/-staubiges Zementmaterial, nach außen verhindert, indem der Schlauch zu Schlauchstücken vereinzelt und an zumindest einem Ende der Schlauchstücke ein Boden ausgebildet wird. Dies ist insbesondere vorteilhaft, wenn das Substrat vor dem Verbinden mit dem Vliesmaterial perforiert worden ist. In a further embodiment of the method according to the invention, in which the web-shaped substrate is provided as a flat web, the web-shaped composite material is formed from the substrate and the nonwoven material into a tube by placing the side regions of the flat, web-shaped composite material on top of one another to form an overlap and connecting them to one another, the nonwoven material forming an inner layer of the tube. Such a tubular Composite material can be formed into bags in which the nonwoven material forms an inner layer that prevents the contents, such as fine-grained/dusty cement material, from escaping to the outside by separating the tube into tube pieces and forming a base at at least one end of the tube pieces. This is particularly advantageous if the substrate has been perforated before being connected to the nonwoven material.
Die Erfindung wird nachfolgend anhand der Zeichnungen durch nicht einschränkende Ausführungsbeispiele näher erläutert. The invention is explained in more detail below with reference to the drawings by means of non-limiting embodiments.
Fig. 1 zeigt schematisch eine erste Ausführungsform einer Vorrichtung zur Herstellung eines flexiblen bahnförmigen Verbundmaterials gemäß der Erfindung. Fig. 1 shows schematically a first embodiment of an apparatus for producing a flexible web-shaped composite material according to the invention.
Fig. 2 zeigt schematisch eine zweite Ausführungsform einer Vorrichtung zur Herstellung eines flexiblen bahnförmigen Verbundmaterials gemäß der Erfindung. Fig. 2 shows schematically a second embodiment of an apparatus for producing a flexible web-shaped composite material according to the invention.
Fig. 3 zeigt eine Wendeeinrichtung der Vorrichtung von Fig. 2. Fig. 3 shows a turning device of the device of Fig. 2.
Fig. 4 zeigt schematisch eine einfachere Ausführungsform der in Fig. 1 dargestellten Vorrichtung zur Herstellung eines flexiblen bahnförmigen Verbundmaterials. Fig. 5 zeigt das Herstellen eines Schlauches aus einem flachen bahnförmigen Verbundmaterial gemäß der Erfindung. Fig. 4 shows schematically a simpler embodiment of the device shown in Fig. 1 for producing a flexible web-shaped composite material. Fig. 5 shows the production of a hose from a flat web-shaped composite material according to the invention.
Anhand der schematischen Darstellung von Fig. 1 wird nun eine erste Ausführungsform der Erfindung erläutert. Fig. 1 zeigt eine Vorrichtung 1 zur Herstellung eines flexiblen bahnförmigen Verbundmaterials 2. Dieser Vorrichtung 1 wird ein bahnförmiges Substrat 3, das wenigstens zum Teil ein erstes thermoplastisches Polymer enthält, auf einer Rolle aufgewickelt, bereitgestellt. Das bahnförmige Substrat 3 kann ein Flachmaterial oder ein Schlauchmaterial, optional mit Seitenfalten sein. Weiters wird der Vorrichtung 1 ein bahnförmiges Vliesmaterial 4, das wenigstens zum Teil ein zweites thermoplastisches Polymer enthält, auf einer Rolle aufgewickelt, bereitgestellt. Im Betrieb der Vorrichtung 1 wird das bahnförmige Substrat 3 mittels nicht dargestellter Zuführmittel, wie z.B. angetriebener Walzenpaare, von seiner Rolle abgewickelt, durch eine Perforationsvorrichtung 5 hindurchgezogen, wo es perforiert wird, und einer Ablösefläche 6 zugeführt. Die Ablösefläche ist als beheiztes, um Rollen umlaufendes Endlosförderband ausgeführt, das vorzugsweise mit einer Oberfläche aus Polytetrafluorethylen (PTFE), bekannt unter dem Markennamen „Teflon“, oder einem Material mit ähnlichen Eigenschaften wie PTFE ausgerüstet ist. PTFE hat eine hohe chemische und thermische Beständigkeit, einen niedrigen Reibungskoeffizienten und ist anti-adhäsiv. Diskrete Partikel 7, die ein drittes thermoplastisches Polymer enthalten, werden aus einem Behälter 8, beispielsweise mittels einer Streuwalze, in einer Vielzahl in möglichst gleichmäßiger Verteilung auf die Ablösefläche 6 aufgetragen. Die beheizte Ablösefläche 6 weist eine Temperatur auf, die über einer Erweichungstemperatur des dritten thermoplastischen Polymers liegt. Die Partikel 7 erwärmen sich auf der Ablösefläche über der Erweichungstemperatur des dritten thermoplastischen Polymers und haften im erweichten Zustand ausreichend an der Ablösefläche 6 an, dass sie auch bei ihrem Transport auf der umlaufenden Ablösefläche 6 nicht von der Ablösefläche 6 herabfallen. Das Substrat 3 und die Ablösefläche 6 laufen durch ein Walzenpaar 9 hindurch, so dass die Partikel 7 auf der Ablösefläche 6 einer Oberfläche 3a des Substrats 3 zugewandt sind. Das Walzenpaar 9 presst die Partikel 7 gegen die Oberfläche 3a des Substrats 3, wodurch die erweichten Partikel 7 an der Oberfläche 3a des Substrats 3 anhaften. Anschließend entfernt sich die Oberfläche 3a des Substrats 3 mit den darauf übertragenen Partikeln 7 von der Ablösefläche 6, die somit zum erneuten Aufträgen von Partikeln 7 bereit ist. Die Oberfläche 3a des Substrats 3 wird nun gekühlt, bis die Partikel 7 eine Temperatur unter der Erweichungstemperatur des dritten Polymers aufweisen. Das Kühlen erfolgt in diesem Ausführungsbeispiel aktiv mittels einer Kühlvorrichtung 10. Je nach Umgebungstemperatur, Transportgeschwindigkeit und Transportlänge des Substrats 3 kann aber auch eine passive Kühlung, z.B. durch Umgebungsluft, vorgesehen werden, bei der die Partikel 7 auf dem Substrat 3 erkalten gelassen werden. Bei direkter Weiterverarbeitung des Substrats 3 mit den darauf anhaftenden Partikeln 7 kann eine Kühlung unter der Erweichungstemperatur entfallen. A first embodiment of the invention will now be explained with reference to the schematic representation in Fig. 1. Fig. 1 shows a device 1 for producing a flexible web-shaped composite material 2. This device 1 is provided with a web-shaped substrate 3, which at least partially contains a first thermoplastic polymer, wound up on a roll. The web-shaped substrate 3 can be a flat material or a tubular material, optionally with side folds. The device 1 is also provided with a web-shaped nonwoven material 4, which at least partially contains a second thermoplastic polymer, wound up on a roll. During operation of the device 1, the web-shaped substrate 3 is unwound from its roll by means of feed means (not shown), such as driven roller pairs, pulled through a perforation device 5 where it is perforated, and fed to a release surface 6. The release surface is designed as a heated endless conveyor belt circulating around rollers, which is preferably equipped with a surface made of polytetrafluoroethylene (PTFE), known under the brand name "Teflon", or a material with similar properties to PTFE. PTFE has a high chemical and thermal resistance, a low coefficient of friction and is anti-adhesive. Discrete particles 7 containing a third thermoplastic polymer are discharged from a container 8, for example by means of a spreading roller, applied in large numbers in as even a distribution as possible to the release surface 6. The heated release surface 6 has a temperature which is above a softening temperature of the third thermoplastic polymer. The particles 7 heat up on the release surface above the softening temperature of the third thermoplastic polymer and, in the softened state, adhere sufficiently to the release surface 6 that they do not fall off the release surface 6 even when they are transported on the rotating release surface 6. The substrate 3 and the release surface 6 run through a pair of rollers 9 so that the particles 7 on the release surface 6 face a surface 3a of the substrate 3. The pair of rollers 9 presses the particles 7 against the surface 3a of the substrate 3, whereby the softened particles 7 adhere to the surface 3a of the substrate 3. The surface 3a of the substrate 3 with the particles 7 transferred to it then moves away from the release surface 6, which is then ready for the renewed application of particles 7. The surface 3a of the substrate 3 is now cooled until the particles 7 have a temperature below the softening temperature of the third polymer. In this embodiment, cooling is carried out actively by means of a cooling device 10. Depending on the ambient temperature, transport speed and transport length of the substrate 3, passive cooling, e.g. by ambient air, can also be provided, in which the particles 7 are allowed to cool on the substrate 3. If the substrate 3 with the particles 7 adhering to it is processed directly, cooling below the softening temperature can be omitted.
Im nächsten Schritt erfolgt das Zuführen des bahnförmigen Vliesmaterials 4 durch Abwi ekeln von seiner Rolle mittels nicht dargestellter Zuführmittel, wie z.B. angetriebener Walzen, und das Zusammenführen des Vliesmaterials 4 über eine Rolle 21 mit dem Substrat 3, wobei die Oberfläche 3a des Substrats 3 mit den daran anhaftenden Partikeln 7 einer Oberfläche 4a des Vliesmaterials 4 zugewandt ist. Die übereinanderliegenden Lagen aus Substrat 3 und Vliesmaterial 4 werden nun mittels einer Heizeinrichtung 11 über der Erweichungstemperatur des dritten thermoplastischen Polymers der auf der Oberfläche 3 a des Substrats 3 anhaftenden Partikel 7 erwärmt, gefolgt von dem Zusammenpressen des Substrats 3 und des Vliesmaterials 4 mittels eines Walzenpaars 12, wodurch die erweichten Partikel 7 die einander zugewandten Oberflächen 3a, 4a des Substrats 3und des Vliesmaterials 4 miteinander verbinden. Das solcherart hergestellte flexible bahnförmige Verbundmaterial 2 wird zum Schluss entweder aktiv mittels einer Kühleinrichtung 14 oder passiv durch Abkühlenlassen an der Umgebungsluft während des Transports durch die Vorrichtung 1, abgekühlt und kann auf eine Rolle zur weiteren Verarbeitung aufgewickelt werden. Eine Ausführungsform der Vorrichtung 1 zur Herstellung des flexiblen bahnförmigen Verbundmaterials 2, die die bisher beschriebenen Teile umfasst und bei der das Verbundmaterial 2 zur weiteren Bearbeitung auf eine Rolle aufgewickelt wird, ist in Fig. 4 schematisch dargestellt. In the next step, the web-shaped nonwoven material 4 is fed by unwinding it from its roll by means of feed means (not shown), such as driven rollers, and the nonwoven material 4 is brought together with the substrate 3 via a roller 21, wherein the surface 3a of the substrate 3 with the particles 7 adhering to it faces a surface 4a of the nonwoven material 4. The superimposed layers of substrate 3 and nonwoven material 4 are then heated by means of a heating device 11 above the softening temperature of the third thermoplastic polymer of the particles 7 adhering to the surface 3a of the substrate 3, followed by the pressing together of the substrate 3 and the nonwoven material 4 by means of a pair of rollers 12, whereby the softened particles 7 connect the mutually facing surfaces 3a, 4a of the substrate 3 and the nonwoven material 4 to one another. The flexible web-shaped composite material 2 produced in this way is finally cooled either actively by means of a cooling device 14 or passively by being allowed to cool in the ambient air during transport through the device 1, and can be wound onto a roll for further processing. An embodiment of the device 1 for producing the flexible web-shaped composite material 2, which comprises the parts described so far and in which the composite material 2 is wound onto a roll for further processing, is shown schematically in Fig. 4.
Der wesentliche Vorteil der Vorrichtung 1 und des darauf ausgeführten Verfahrens ist, dass das Substrat 3 und das Vliesmaterial 4 durch eine Vielzahl von diskreten Verbindungspunkten aus den das dritte thermoplastische Polymer enthaltenden Partikeln 7 miteinander verbunden werden, wobei sich die Verbindungspunkte möglichst gleich verteilt im Wesentlichen über die gesamte Verbindungsfläche zwischen dem Substrat 3 und dem Vliesmaterial 4 erstrecken, so dass insgesamt der Effekt einer „vollflächigen“ Verbindung mit homogenen Verbindungseigenschaften entsteht. Dabei bleiben die Hohlräume des Vliesmaterials 4 weitgehend intakt. The main advantage of the device 1 and the method carried out thereon is that the substrate 3 and the nonwoven material 4 are connected to one another by a large number of discrete connection points made of the particles 7 containing the third thermoplastic polymer, wherein the connection points are distributed as evenly as possible and extend essentially over the entire connection surface between the substrate 3 and the nonwoven material 4, so that the overall effect of a "full-surface" connection with homogeneous connection properties is created. The cavities of the nonwoven material 4 remain largely intact.
Bei der in Fig. 1 und Fig. 4 dargestellten Ausführungsform der Vorrichtung 1 wird zunächst das Substrat 3 zugeführt und nach Aufbringen der Partikel 7 mit dem Vliesmaterial 4 zusammengeführt und verbunden. Es sei aber erwähnt, dass die Vorrichtung 1 auch dazu geeignet ist, zunächst das Vliesmaterial 4 zuzuführen und nach Aufbringen der Partikel 7 auf das Vliesmaterial 4 es mit dem Substrat 3 zusammenzuführen, so dass ihre Oberflächen 3a, 4a durch eine Vielzahl von aus den Partikeln 7 bestehenden Verbindungspunkten miteinander verbunden werden. In the embodiment of the device 1 shown in Fig. 1 and Fig. 4, the substrate 3 is first fed in and, after the particles 7 have been applied, is brought together and connected to the nonwoven material 4. It should be mentioned, however, that the device 1 is also suitable for first feeding the nonwoven material 4 and, after the particles 7 have been applied to the nonwoven material 4, bringing it together with the substrate 3 so that their surfaces 3a, 4a are connected to one another by a plurality of connection points consisting of the particles 7.
In der in Fig. 1 dargestellten Ausführungsform der Vorrichtung 1 zur Herstellung des flexiblen bahnförmigen Verbundmaterials 2 wird das Verbundmaterial unmittelbar nach seiner Herstellung noch weiter behandelt, indem nach dem Zusammenpressen des Substrats 3 und des Vliesmaterials 4 durch das Walzenpaar 12 auf der dem Vliesmaterial 4 gegenüberliegenden, d.h. abgewandten Oberfläche 3b des Substrats 3 diskrete Partikel 17 aufgebracht werden, die ein viertes thermoplastisches Polymer enthalten. Das Aufbringen der Partikel 17 erfolgt, indem die Partikel 17 aus einem Behälter 18, beispielsweise mittels einer Streuwalze, in einer Vielzahl in möglichst gleichmäßiger Verteilung auf eine beheizte Ablösefläche 16 aufgetragen werden. Die beheizte Ablösefläche 16 weist eine Temperatur auf, die über einer Erweichungstemperatur des vierten thermoplastischen Polymers liegt. Die Partikel 17 erwärmen sich auf der Ablösefläche 16 über der Erweichungstemperatur des vierten thermoplastischen Polymers und haften im erweichten Zustand ausreichend an der Ablösefläche 16 an, dass sie auch bei ihrem Transport auf der umlaufenden Ablösefläche 16 nicht von der Ablösefläche 16 herabfallen. Die Ablösefläche 16 ist als beheiztes, um Rollen umlaufendes Endlosförderband ausgeführt, das vorzugsweise mit einer Oberfläche aus PTFE oder einem Material mit ähnlichen Eigenschaften wie PTFE ausgerüstet ist. Das Verbundmaterial 2 und die Ablösefläche 16 laufen durch ein Walzenpaar 19 hindurch, so dass die Partikel 17 auf der Ablösefläche 16 der Oberfläche 3b des Substrats 3 zugewandt sind. Das Walzenpaar 19 presst die Partikel 17 gegen die Oberfläche 3b des Substrats 3 des Verbundmaterials 2, wodurch die erweichten Partikel 17 an der Oberfläche 3b des Substrats 3 anhaften. Anschließend entfernt sich die Oberfläche 3b des Substrats 3 des Verbundmaterials 2 mit den darauf übertragenen Partikeln 17 von der Ablösefläche 16, die somit zum erneuten Aufträgen von Partikeln 17 bereit ist. Das Verbundmaterial 2 wird nun aktiv mittels einer Kühleinrichtung 14 oder passiv durch Abkühlenlassen, z.B. an der Umgebungsluft, gekühlt, bis die Partikel 17 eine Temperatur unter der Erweichungstemperatur des vierten Polymers aufweisen. Anschließend wird das solcherart behandelte bahnförmige flexible Verbundmaterial zur weiteren Verwendung, beispielsweise zur Herstellung von Säcken, auf eine Rolle aufgewickelt. In the embodiment of the device 1 for producing the flexible web-shaped composite material 2 shown in Fig. 1, the composite material is further treated immediately after its production by applying discrete particles 17 containing a fourth thermoplastic polymer to the surface 3b of the substrate 3 opposite the nonwoven material 4, i.e. facing away from it, after the substrate 3 and the nonwoven material 4 have been pressed together by the pair of rollers 12. The particles 17 are applied by applying the particles 17 from a container 18, for example by means of a spreading roller, in a large number in as even a distribution as possible to a heated release surface 16. The heated release surface 16 has a temperature which is above a softening temperature of the fourth thermoplastic polymer. The particles 17 heat up on the release surface 16 above the softening temperature of the fourth thermoplastic polymer and, in the softened state, adhere sufficiently to the release surface 16 that they do not fall off the release surface 16 even when they are transported on the rotating release surface 16. The release surface 16 is designed as a heated endless conveyor belt rotating around rollers, which is preferably covered with a surface made of PTFE or a material with similar properties to PTFE. The composite material 2 and the release surface 16 pass through a pair of rollers 19 so that the particles 17 on the release surface 16 face the surface 3b of the substrate 3. The pair of rollers 19 presses the particles 17 against the surface 3b of the substrate 3 of the composite material 2, whereby the softened particles 17 adhere to the surface 3b of the substrate 3. The surface 3b of the substrate 3 of the composite material 2 with the particles 17 transferred thereto then moves away from the release surface 16, which is thus ready for new application of particles 17. The composite material 2 is now cooled actively by means of a cooling device 14 or passively by being allowed to cool, e.g. in the ambient air, until the particles 17 have a temperature below the softening temperature of the fourth polymer. The web-shaped flexible composite material treated in this way is then wound onto a roll for further use, for example for the production of bags.
Beispiele für bevorzugte Materialien für das erste, das zweite, das dritte und das vierte thermoplastische Polymer sind weiter oben im Text angeführt worden. Examples of preferred materials for the first, second, third and fourth thermoplastic polymers are given above in the text.
Fig. 2 zeigt schematisch eine weitere Ausführungsform einer Vorrichtung 20 zur Herstellung eines flexiblen bahnförmigen Verbundmaterials 2, die im Wesentlichen dieselben Verfahrensschritte ausführt wie die Vorrichtung 1 von Fig. 1. Gleiche oder ähnliche Vorrichtungsteile wie bei der Ausführung von Fig. 1 sind in Fig. 2 mit den gleichen Bezugszeichen versehen und zu ihrer Erklärung wird auf die Beschreibung der Vorrichtung von Fig. 1 verwiesen. Der wesentliche Unterschied zwischen den beiden Vorrichtungen 1, 20 besteht darin, dass bei der Vorrichtung 20 von Fig. 2 nur eine Ablösefläche 6 verwendet wird, mit der beide Oberflächen 3a, 3b des Substrats 3 nacheinander mit Partikeln 7, 17 versehen werden. Dafür wird das Substrat 3 nach dem Aufbringen der Partikel 7 auf seiner ersten Oberfläche 3a in einer Wendeeinrichtung 30 gewendet. Anschließend wird das Vliesmaterial 4 mit der mit den Partikeln 7 versehenen ersten Oberfläche 3a des Substrats zusammengeführt. Durch Wärme- und Druckeinwirkung in der Heizeinrichtung 11 und dem Walzenpaar 12 werden das Substrat 3 und das Vliesmaterial 4 miteinander an ihren einander zugewandten Oberflächen durch eine Vielzahl von Verbindungspunkten verbunden, wie oben anhand der Fig. 1 detailliert beschrieben worden ist. Danach wird das solcherart hergestellte Verbundmaterial 2 erneut der Ablösefläche 6 zugeführt, und zwar so, dass die dem Vliesmaterial 4 gegenüberliegende, d.h. abgewandte Oberfläche 3b des Substrats 3 der Ablösefläche 6 zugewandt ist. Auf dieser dem Vliesmaterial 4 gegenüberliegenden Oberfläche 3b des Substrats 3 werden diskrete Partikel 17 aufgebracht und anschließend in der Kühleinrichtung 14 gekühlt. Danach wird das so behandelte Verbundmaterial 2 zu einer Rolle aufgewickelt. Fig. 2 shows schematically a further embodiment of a device 20 for producing a flexible web-shaped composite material 2, which essentially carries out the same process steps as the device 1 of Fig. 1. The same or similar device parts as in the embodiment of Fig. 1 are provided with the same reference numerals in Fig. 2 and for their explanation reference is made to the description of the device of Fig. 1. The essential difference between the two devices 1, 20 is that in the device 20 of Fig. 2 only one release surface 6 is used, with which both surfaces 3a, 3b of the substrate 3 are provided one after the other with particles 7, 17. For this purpose, the substrate 3 is turned in a turning device 30 after the particles 7 have been applied to its first surface 3a. The nonwoven material 4 is then brought together with the first surface 3a of the substrate provided with the particles 7. By applying heat and pressure in the heating device 11 and the pair of rollers 12, the substrate 3 and the nonwoven material 4 are connected to one another at their mutually facing surfaces by a plurality of connection points, as described in detail above with reference to Fig. 1. The composite material 2 produced in this way is then fed again to the release surface 6, in such a way that the surface 3b of the substrate 3 opposite the nonwoven material 4, i.e. facing away, faces the release surface 6. Discrete particles 17 are applied to this surface 3b of the substrate 3 opposite the nonwoven material 4 and then in the cooling device 14. The composite material 2 treated in this way is then wound into a roll.
Fig. 3 zeigt eine Ausführungsform einer Wendeeinrichtung 30, wie sie in der Vorrichtung 20 von Fig. 2 zum Einsatz kommen kann, in Draufsicht. Zum leichteren Verständnis der Zeichnung wurden einige für die Erläuterung nicht notwendige Vorrichtungsteile weggelassen. Man erkennt aus der Darstellung von Fig. 3 das Substrat 3, das bereits am Walzenpaar 9 mit den das dritte thermoplastische Polymer enthaltenden Partikeln 7 beaufschlagt worden ist, wobei die Partikel 7 aus dem Behälter 8 auf die Ablösefläche 6 aufgetragen werden. Das mit den Partikeln 7 versehene Substrat 3 wird an einer ersten Umlenkrolle 24 um 180° gewendet, dann einer ersten feststehenden Umlenkstange 22 zugeführt, wo es um 90° umgelenkt wird, danach einer zweiten feststehenden Umlenkstange 23 zugeführt, wo es wieder um 90° umgelenkt wird. Danach wird das Substrat 3 um eine zweite Umlenkrolle 25 erneut um 180° gewendet und wird dadurch in Richtung der beheizten Ablösefläche 6 geführt. Bevor das Substrat 3 mit der Ablösefläche 6 in Berührung kommt, wird es an der Rolle 21 mit dem Vliesmaterial 4 zusammengeführt, wie oben beschrieben worden ist. Anschließend wird das Substrat 3 am Walzenpaar 19 mit den das vierte thermoplastische Polymer enthaltenden Partikeln 17 beaufschlagt, wobei die Partikel 17 aus dem Behälter 18 auf die Ablösefläche 6 aufgetragen werden. Fig. 3 shows an embodiment of a turning device 30, as can be used in the device 20 of Fig. 2, in plan view. To make the drawing easier to understand, some device parts not necessary for the explanation have been omitted. The representation in Fig. 3 shows the substrate 3, which has already been subjected to the particles 7 containing the third thermoplastic polymer on the pair of rollers 9, the particles 7 being applied from the container 8 to the release surface 6. The substrate 3 provided with the particles 7 is turned by 180° on a first deflection roller 24, then fed to a first fixed deflection rod 22, where it is deflected by 90°, then fed to a second fixed deflection rod 23, where it is deflected again by 90°. The substrate 3 is then turned again by 180° around a second deflection roller 25 and is thereby guided in the direction of the heated release surface 6. Before the substrate 3 comes into contact with the release surface 6, it is brought together with the nonwoven material 4 on the roller 21, as described above. The substrate 3 is then exposed to the particles 17 containing the fourth thermoplastic polymer on the pair of rollers 19, the particles 17 being applied from the container 18 to the release surface 6.
Fig. 5 zeigt schematisch das Formen eines Schlauchs 15 aus dem Verbundmaterial 2, das als Flachmaterial ausgebildet ist. Dazu werden die Seitenbereiche 2a, 2b des flachliegenden, bahnförmigen Verbundmaterials 2 durch nicht dargestellte Umlenkmittel unter Ausbildung einer Überlappung 2c aufeinandergelegt und miteinander verbunden, so dass das Vliesmaterial 4 eine Innenlage des Schlauchs 15 bildet. Das Verbinden der Seitenbereiche 2a, 2b des flachliegenden, bahnförmigen Verbundmaterials 2 erfolgt, indem mittels eines Extruders 26 und einer Extrusionsdüse 27 ein Kunststoffextrudat in die Überlappung 2c eingebracht und die Überlappung 2c anschließend durch ein Walzenpaar 28 hindurchgeführt und dabei zusammengepresst wird. Aus dem Schlauch 15 können anschließend Säcke geformt werden, indem der Schlauch 15 zu Schlauchstücken vereinzelt und an zumindest einem Ende der Schlauchstücke ein Boden ausgebildet wird. Es kann aber auch das Verbundmaterial 2, wenn es ein schlauchförmiges Substrat 3 aufweist, zu Schlauchstücken vereinzelt und an zumindest einem Ende der Schlauchstücke ein Boden ausgebildet werden. Dadurch können Kreuzbodensäcke, Ventilsäcke, Beutel oder Form-Fill-and-Seal Säcke hergestellt werden, deren Gestalten dem Fachmann wohlbekannt sind. Bevorzugt handelt es sich bei dem verwendeten Verbundmaterial 2 um ein Material, dessen Substrat 3 vor dem Verbinden mit dem Vliesmaterial 4 perforiert worden ist. Fig. 5 shows schematically the forming of a tube 15 from the composite material 2, which is designed as a flat material. For this purpose, the side areas 2a, 2b of the flat, web-shaped composite material 2 are placed on top of one another by deflection means (not shown) to form an overlap 2c and connected to one another, so that the nonwoven material 4 forms an inner layer of the tube 15. The connection of the side areas 2a, 2b of the flat, web-shaped composite material 2 takes place by introducing a plastic extrudate into the overlap 2c by means of an extruder 26 and an extrusion nozzle 27 and then passing the overlap 2c through a pair of rollers 28 and thereby pressing it together. Bags can then be formed from the tube 15 by separating the tube 15 into tube pieces and forming a base at at least one end of the tube pieces. However, the composite material 2, if it has a tubular substrate 3, can also be separated into tubular pieces and a base can be formed at at least one end of the tubular pieces. This makes it possible to produce cross-bottom bags, valve bags, pouches or form-fill-and-seal bags, the shapes of which are well known to those skilled in the art. The composite material 2 used is preferably a material whose substrate 3 has been perforated before being connected to the nonwoven material 4.
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202480030162.1A CN121127367A (en) | 2023-05-03 | 2024-04-23 | Method and apparatus for producing flexible net-like composite material |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP23171429 | 2023-05-03 | ||
| EP23171429.6 | 2023-05-03 |
Publications (1)
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|---|---|
| WO2024227651A1 true WO2024227651A1 (en) | 2024-11-07 |
Family
ID=86328861
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2024/061002 Pending WO2024227651A1 (en) | 2023-05-03 | 2024-04-23 | Method and device for producing a flexible web-type composite material |
| PCT/EP2024/061003 Pending WO2024227652A1 (en) | 2023-05-03 | 2024-04-23 | Flexible web-type composite material and bags made from same |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2024/061003 Pending WO2024227652A1 (en) | 2023-05-03 | 2024-04-23 | Flexible web-type composite material and bags made from same |
Country Status (5)
| Country | Link |
|---|---|
| CN (2) | CN121127367A (en) |
| AR (1) | AR132568A1 (en) |
| MX (1) | MX2025012884A (en) |
| TW (1) | TW202448667A (en) |
| WO (2) | WO2024227651A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4033499A1 (en) | 1990-10-20 | 1992-04-23 | Silver Plastics Gmbh & Co Kg | Production of thermoplastic valve bags - overlapping perforated longitudinal edges of plastic film, strip of fibres and fused strip of same polymer and welding together by rollers |
| WO2011018318A1 (en) | 2009-08-10 | 2011-02-17 | Windmöller & Hölscher Kg | Method and device for producing a sack or a bag having plastic non-woven material, and sack or bag comprising plastic non-woven material |
| US20150036952A1 (en) | 2013-08-05 | 2015-02-05 | Standard Multiwall Bag Manufacturing Co., | Bulk Materials Bag Having Anti-Skid Treatment and Method of Applying Treatment |
| US20190291337A1 (en) | 2016-05-26 | 2019-09-26 | Flexinnova Kft | Antislip, heat sealable plastic flexible packaging bag and method and apparatus for its production |
| EP3463805B1 (en) | 2016-05-26 | 2021-12-22 | Flexinnova Kft | Antislip flexible materials and methods for their making and use |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5792513A (en) | 1997-03-07 | 1998-08-11 | Koslow Technologies Corporation | Continuous solid state web coating process |
| DE102020118734A1 (en) | 2020-07-15 | 2022-01-20 | Outlast Technologies Gmbh | Airgel-containing insulation layer |
-
2024
- 2024-04-23 CN CN202480030162.1A patent/CN121127367A/en active Pending
- 2024-04-23 WO PCT/EP2024/061002 patent/WO2024227651A1/en active Pending
- 2024-04-23 CN CN202480030143.9A patent/CN121038953A/en active Pending
- 2024-04-23 WO PCT/EP2024/061003 patent/WO2024227652A1/en active Pending
- 2024-04-30 TW TW113116240A patent/TW202448667A/en unknown
- 2024-05-02 AR ARP240101102A patent/AR132568A1/en unknown
-
2025
- 2025-10-28 MX MX2025012884A patent/MX2025012884A/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4033499A1 (en) | 1990-10-20 | 1992-04-23 | Silver Plastics Gmbh & Co Kg | Production of thermoplastic valve bags - overlapping perforated longitudinal edges of plastic film, strip of fibres and fused strip of same polymer and welding together by rollers |
| WO2011018318A1 (en) | 2009-08-10 | 2011-02-17 | Windmöller & Hölscher Kg | Method and device for producing a sack or a bag having plastic non-woven material, and sack or bag comprising plastic non-woven material |
| US20150036952A1 (en) | 2013-08-05 | 2015-02-05 | Standard Multiwall Bag Manufacturing Co., | Bulk Materials Bag Having Anti-Skid Treatment and Method of Applying Treatment |
| US20190291337A1 (en) | 2016-05-26 | 2019-09-26 | Flexinnova Kft | Antislip, heat sealable plastic flexible packaging bag and method and apparatus for its production |
| EP3463805B1 (en) | 2016-05-26 | 2021-12-22 | Flexinnova Kft | Antislip flexible materials and methods for their making and use |
Also Published As
| Publication number | Publication date |
|---|---|
| CN121127367A (en) | 2025-12-12 |
| MX2025012884A (en) | 2025-12-01 |
| AR132568A1 (en) | 2025-07-16 |
| TW202448667A (en) | 2024-12-16 |
| WO2024227652A1 (en) | 2024-11-07 |
| CN121038953A (en) | 2025-11-28 |
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