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WO2024225959A1 - A fat composition comprising a vegetable fat phase originating from at least two different vegetable fat sources which is free from palm oil and/or fractions thereof - Google Patents

A fat composition comprising a vegetable fat phase originating from at least two different vegetable fat sources which is free from palm oil and/or fractions thereof Download PDF

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Publication number
WO2024225959A1
WO2024225959A1 PCT/SE2024/050396 SE2024050396W WO2024225959A1 WO 2024225959 A1 WO2024225959 A1 WO 2024225959A1 SE 2024050396 W SE2024050396 W SE 2024050396W WO 2024225959 A1 WO2024225959 A1 WO 2024225959A1
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Prior art keywords
weight
vegetable fat
triglycerides
fat
vegetable
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French (fr)
Inventor
Morten Daugaard Andersen
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AAK AB
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AAK AB
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Priority to AU2024261749A priority Critical patent/AU2024261749A1/en
Publication of WO2024225959A1 publication Critical patent/WO2024225959A1/en
Anticipated expiration legal-status Critical
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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/305Products for covering, coating, finishing or decorating
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings or cooking oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/36Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/06Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/062Products for covering, coating, finishing, decorating
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/06Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/066Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the fat used
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings or cooking oils
    • A23D9/02Other edible oils or fats, e.g. shortenings or cooking oils characterised by the production or working-up

Definitions

  • a fat composition comprising a vegetable fat phase originating from at least two different vegetable fat sources which is free from palm oil and/or fractions thereof
  • the present invention relates to a fat composition
  • a fat composition comprising a vegetable fat phase originating from at least two different vegetable fat sources, wherein the vegetable fat phase is free from palm oil and/or fractions thereof and also relates to the use of the fat composition.
  • the invention further relates to a confectionary or chocolate or chocolate-like product comprising the fat composition.
  • Palm oil is an extremely versatile oil that has many different properties and functions that makes it so useful and so widely used. It is semi-solid at room temperature so can keep spreads spreadable; it is resistant to oxidation so can give products a longer shelf-life; it’s stable at high temperatures so helps to give fried products a crispy and crunchy texture; and it’s also odourless and colourless so doesn’t alter the look or smell of food products.
  • the oil palm is a very efficient crop, able to produce high quantities of oil over small areas of land, almost all year round. This makes it an attractive crop for growers and smallholders, who can rely on the steady income that palm oil provides.
  • Palm oil is also found as an important component in cocoa butter equivalents (CBEs) and cocoa butter improvers (CBIs), both used in the chocolate industry today.
  • CBE and CBI components palm mid fractions is used as one of the more important components.
  • palm oil has been and continues to be a major driver of deforestation of some of the world’s most biodiverse forests, destroying the habitat of already endangered species like the Orangutan, pygmy elephant, and Sumatran rhino. This forest loss coupled with conversion of carbon rich peat soils are throwing out millions of tonnes of greenhouse gases into the atmosphere and contributing to climate changes. There also remains some exploitation of workers and child labour. These are serious issues that the whole palm oil sector needs to address.
  • the present invention relates to a fat composition
  • a fat composition comprising a vegetable fat phase, wherein the vegetable fat phase comprises: from 85.0% to 100.0% by weight of triglycerides compared to the total weight of the vegetable fat phase; from 50.0% to 85.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 35.0 to 55.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase;
  • the fat composition as disclosed herein shows the possibility to produce chocolate-like compounds without the use of a palm-based vegetable fat phase without compromising the quality.
  • a chocolate comprising CBI based on a combination of at least two non-palm oil sources as the predominant vegetable fat components in the fat phase, where the resulting chocolate or chocolate-like products is as bloom stable and has as good a sensory felling as a product made with cocoa butter.
  • the present invention is low or absent of asymmetric (SatSatO) TAGs in the CBI as compared to a CBE comprising Palm mid fraction, as the present invention has a ratio of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides of 0.08 or less.
  • This has an added advantage, since the presence of asymmetric TAG’S generally result in lower temperature settings in the crystallization and outlet zone of a temper unit, which can have a negative impact to crystallization in the cooling tunnel.
  • a minor impact to texture towards a softer product can also be a consequence of the presence of asymmetric mono-saturated TAGs in the fat composition.
  • the present invention also relates to use of the fat composition according to the present invention for bakery, dairy, or confectionary applications or in coating or enrobing for nuts, bakery or confectionary applications, such as bakery or confectionary application, selected from biscuit, cake, muffin, donut, pastry, or bread applications; or for chocolate and chocolate-like applications, such as chocolate-like coatings, or chocolate and chocolate-like moulding, such as tablet moulding.
  • a confectionary or chocolate or chocolate-like product having a fat content from 20% to 60% by weight, wherein the fat content comprises from 5% to 60% by weight of a fat composition according to the present invention compared to the total weight of the fat content.
  • vegetable shall be understood as originating from a plant or a single cell organism.
  • vegetable fat or vegetable triglycerides are still to be understood as vegetable fat or vegetable triglycerides if all the fatty acids used to obtain said triglyceride or fat is of plant origin or single cell organism origin.
  • triglycerides may be used interchangeably with the term “triacylglycerides” and should be understood as an ester derived from glycerol and three fatty acids. “Triglycerides” may be abbreviated TG or TAG.
  • Saturated fatty acids are chains of carbon atoms joined by single bonds, with the maximum number of hydrogen atoms attached to each carbon atom in the chain.
  • Unsaturated fatty acids are chains of carbon atoms joined by single bonds and varying numbers of double bonds, which do not have their full quota of hydrogen atoms attached.
  • An unsaturated fatty acid can exist in two forms, the cis form and the trans form.
  • a double bond may exhibit one of two possible configurations: trans or cis. In trans configuration (a trans fatty acid) the carbon chain extends from opposite sides of the double bond, whereas, in cis configuration (a cis fatty acid) the carbon chain extends from the same side of the double bond.
  • CX means that the fatty acid comprises X carbon atoms, e.g. a C14 fatty acid has 14 carbon atoms while a C8 fatty acid has 8 carbon atoms.
  • CX:Y means that the fatty acid comprises X carbon atoms and Y double bonds, e.g. a C14:0 fatty acid has 14 carbon atoms and 0 double bonds while a C18:1 fatty acid has 18 carbon atoms and 1 double bond.
  • triglycerides use a "sn” notation, which stands for stereospecific numbering.
  • the secondary hydroxyl group is shown to the left of C- 2; the carbon atom above this then becomes C-1 and that below becomes C-3.
  • the prefix ‘sn’ is placed before the stem name of the compound.
  • randomly distributed is meant that the fatty acids are randomly distributed to the three sn- positions.
  • a randomly distributed composition may be obtained by means of esterification, chemical transesterification or enzymatic transesterification. All naturally occurring fat compositions, e.g. virgin olive oil, palm kernel oil, coconut oil or rapeseed oil all have a non-randomly distribution of the fatty acids on the glycerol backbone.
  • vegetable fat phase is meant a combination of at least two different vegetable fat sources originating from a plant or a single cell organism.
  • the vegetable fat phase can e.g. be selected from the group of lllipe oil, Shea oil, or Sal oil, or a blend thereof, and/or fractions thereof. It can also be selected from an interesterified, fractionated, and/or hydrogenated version of Shea, lllipe, and/or Sal oil, or a blend thereof, and/or fractions thereof.
  • % or “percentage” relates to weight percentage i.e. wt.% or wt.-% if nothing else is indicated.
  • the sum of a given component in the fat composition or in the vegetable fat phase can never be more than 100% by weight, e.g. the sum of all the fatty acid in the vegetable fat composition can never be more than 100% by weight.
  • oil and “fat” are used interchangeably, unless otherwise specified.
  • vegetable oil and “vegetable fat” are used interchangeably, unless otherwise specified.
  • single cell oil shall mean oil from oleaginous microorganisms which are species of yeasts, molds (fungal), bacteria and microalgae. These single cell oils are produced intracellular and in most cases during the stationary growth phase under specific growth conditions (e.g. under nitrogen limitation with simultaneous excess of a carbon source).
  • oleaginous microorganisms are, but not limited to, Mortierella alpineea, Yarrowia lipolytica, Schizochytrium, Nannochloropsis, Chlorella, Crypthecodinium cohnii, Shewanella.
  • cocoa butter equivalent or CBE is intended to mean an edible fat having very similar chemical and physical properties and being compatible with cocoa butter.
  • the main fatty acids are typically palmitic, stearic, and oleic acids.
  • the triglycerides are typically 2-oleo di-saturated (SatOSat (Sat2O)).
  • SatOSat St2O
  • cocoa butter equivalents can be detected in chocolate by their triglyceride ratios, which are appreciably different from those in cocoa butter.
  • cocoa butter improver or CBI is intended to mean a harder version (i.e. has a higher solid fat content) of cocoa butter equivalent due to a higher content of high melting SatOSat triglycerides such as StOSt triglycerides and/or StOA triglycerides. It is usually used in chocolate formulations having a high content of milk fat or those meant for tropical climates. It improves the heat stability of soft cocoa butter varieties, adds more solid fat and thereby increases hardness in chocolate products.
  • edible is something that is suitable for use as food or as part of a food product, such as a dairy chocolate, or confectionary product.
  • a food product is a product for human consumption.
  • a chocolate or chocolate-like product is meant a product, which at least is experienced by the consumer as chocolate or as a confectionery product having sensorial attributes common with chocolate, such as e.g. melting profile, taste etc.
  • Some chocolate comprises cocoa butter, typically in substantial amounts, where some chocolate-like product may be produced with a low amount of or even without cocoa butter, e.g. by replacing the cocoa butter with a cocoa butter equivalent, cocoa butter substitute, etc.
  • many chocolate or chocolate-like products comprise cocoa powder or cocoa mass, although some chocolate or chocolate-like products, such as typical white chocolates, may be produced without cocoa powder, but e.g. drawing its chocolate taste from cocoa butter.
  • compound By compound is meant a product made from a combination of cocoa butter and (vegetable) fats.
  • a compound may also comprise milk fat in various amounts. It is used as a lower-cost alternative to true chocolate, as it uses less-expensive hard (vegetable) fats in place of the more expensive cocoa butter. It may also be known as “compound coating” or “chocolatey coating” when used as a coating for confectionary or candy.
  • the invention relates to a fat composition
  • a fat composition comprising a vegetable fat phase, wherein the vegetable fat phase comprises: from 85.0% to 100.0% by weight of triglycerides compared to the total weight of the vegetable fat phase; from 50.0% to 85.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 35.0 to 55.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; 8.0% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 12.0% to 28.0% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 0.9% to 6.0% by weight of StLiSt + StStLi triglycer
  • the fat composition as disclosed herein can be used to produce chocolate-like compounds which are as bloom stable as compounds based on cocoa butter only. Further, the produced chocolatelike compounds show a similar sensory feeling, as those made with cocoa butter.
  • compositions also referred to as blends
  • SFC profiles for the compositions disclosed herein are similar to the SFC profile for cocoa butter, strongly indicating the potential of the fat compositions as a partial substitute for cocoa butter in a chocolate application.
  • the vegetable fat phase is free from enzymatic intereste rifled components. Hence, this means that in one or more embodiments the vegetable fat phase is made without the use of 1-3 specific enzymatic interesterification.
  • the fat composition as disclosed herein therefore also shows the possibility to produce chocolate-like compounds without the use of a 1-3 specific enzymatic interesterification without compromising the quality.
  • the vegetable fat phase comprises from 95.0% to 99.0% by weight of triglycerides compared to the total weight of the vegetable fat phase.
  • the vegetable fat phase comprises from 55.0% to 83.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 58.0% to 81 .0% by weight, or such as from 60.0% to 80.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
  • the vegetable fat phase comprises from 37.0% to 52.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 39.0% to 50.0% by weight, such as from 40.0% to 47.0% by weight, or such as from 41.0% to 46.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
  • the vegetable fat phase comprises 7.0% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as 6.0% or less by weight, such as 5.0% or less by weight, or such as 4.5% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
  • the vegetable fat phase comprises from 13.0% to 26.0% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 14.0% to 24.0% by weight, such as from 14.5% to 23.0% by weight, or such as from 14.5% to 22.5% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
  • the vegetable fat phase further comprises from 2.5% to 10.0% by weight of StOA + StAO + AStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 2.8% to 9.5% by weight, or such as from 3.0% to 9.0% by weight of StOA+ StAO + AStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, wherein A is arachidic acid (C20:0).
  • the vegetable fat phase comprises from 1 .0% to 5.0% by weight of StLiSt + StStLi triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 1.1% to 4.0% by weight, or such as from 1 .1 % to 3.5% by weight of StLiSt triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
  • the ratio in the vegetable fat phase of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides is 0.06 or less, such as 0.04 or less, such as 0.02 or less, or such as 0.01 or less.
  • the ratio in the vegetable fat phase of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides is from 0.00 to 0.08, such as from 0.00 to 0.06, such as from 0.00 to 0.04, such as from 0.00 to 0.02, or such as from 0.00 to 0.01 .
  • the at least two different vegetable fat sources are composed of at least a first vegetable fat source and a second vegetable fat source; wherein the first vegetable fat source is originating from lllipe oil and/or fractions thereof; and wherein the second vegetable fat source is originating from Shea oil and/or fractions thereof, Sal oil and/or fractions thereof, or a combination of Shea oil and/or fractions thereof and Sal oil and/or fractions thereof.
  • the first vegetable fat source is originating from lllipe oil and/or fractions thereof; and wherein the second vegetable fat source is originating from Shea oil and/or fractions thereof or Sal oil and/or fractions thereof. In one or more embodiments, the first vegetable fat source is originating from lllipe oil; and wherein the second vegetable fat source is originating from Shea oil or Sal oil.
  • first vegetable fat source is in an amount from 30% to 70% by weight of the sum of the first vegetable fat source and the second vegetable fat source.
  • the second vegetable fat source is in an amount from 30% to 70% by weight of the sum of the first vegetable fat source and the second vegetable fat source.
  • the vegetable fat phase originates from and consist of two different vegetable fat sources.
  • the fat composition is a cocoa butter improver (CBI) composition.
  • CBI cocoa butter improver
  • Cocoa butter equivalents and cocoa butter improvers are e.g. normally made from a mix of palm mid fraction and a fractionated part of shea stearin or another oil fraction rich in SatOSat triglycerides, where Sat is a saturated fatty acid having a chain length of C16 or longer, such as C16 and C18.
  • Sat is a saturated fatty acid having a chain length of C16 or longer, such as C16 and C18.
  • the CBI’s disclosed herein shows an increase in heat related bloom stability (better shelf life at 25 °C in the examples).
  • fat composition according to the present invention for bakery, dairy, or confectionary applications, or in coating or enrobing for nuts, bakery or confectionary applications, such as bakery or confectionary application, selected from biscuit, cake, muffin, donut, pastry, or bread applications; or for chocolate and chocolate-like applications, such as chocolate-like coatings, or chocolate and chocolate-like moulding, such as tablet moulding is also disclosed.
  • a confectionary or chocolate or chocolate-like product having a fat content from 20% to 60% by weight, wherein the fat content comprises from 5% to 60% by weight of a fat composition according to the present invention compared to the total weight of the fat content.
  • the fat content comprises from 10% to 50% by weight of the fat composition, such as from 15% to 40% by weight of the fat composition compared to the total weight of the fat content.
  • a process for the preparation of a fat composition according to the present invention wherein the first vegetable fat source is blended with the second vegetable fat source to obtain the fat composition.
  • Table 1 displays a typical selected triglyceride composition for a lllipe, Shea oil, Sal oil and West Africa cocoa butter measured by AOCS method Ce 5b-89.
  • the asymmetric isomers are included in the amount specified under each TAGs in the examples since the method used (AOCS Ce 5b-89) does not measure the difference in isomeric state of a TAG.
  • POSt when there is written POSt in the table it also includes its isomers; PStO and StPO.
  • the content of SatSatO was determined using a well-known method by a commercial laboratory.
  • the amount of the asymmetric SatSatO isomer is measured using an absolute method. Thereafter, the triglyceride ratio SatSatO/SatOSat was calculated.
  • the solid fat content was measured by IUPAC 2.150b and is also displayed in Table 1.
  • Table 2 shows the selected triglyceride composition of West African cocoa butter compared to four CBIs made of blends of lllipe and Shea oil.
  • Example 2 Recipes and manufacture of dark chocolate applications with CBI compositions The procedure of the dark chocolate productions were all done following the below procedure:
  • the dark chocolates are deposited into 50 g preheated moulds and placed in a three-zone cooling tunnel for 30 minutes. Temperatures are adjusted to 15 °C in zone 1 and 3 and 12 °C in zone 2.
  • the demoulded chocolate tablets are kept at 20 °C for one week and then moved to 20 °C and 25 °C cabinets for isothermal storage. Once a week the tablets are evaluated by a trained panel of experts for visible bloom. The number of weeks until the appearance of strong bloom on the surface of the chocolate tablets are noted as the shelf life result (see table 7 below).
  • the shelf life results are given in table 7 below.
  • the shelf life results demonstrate that it is possible to make a chocolate comprising CBI based on blends of either Shea Stearin and Sal oil or Shea oil and Sal Stearin with a shelf life performance at least as good as cocoa butter-based chocolate when stored at 20 °C.
  • the higher content of the sum of StOSt and StOA for the CBI’s as compared to cocoa butter results in more heat stable chocolates with respect to shelf life when stored at 25 °C.

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Abstract

Disclosed is a fat composition comprising a vegetable fat phase, wherein the vegetable fat phase originates from at least two different vegetable fat sources and is free from palm oil and/or fractions thereof. Disclosed is further the use of the fat composition. Further disclosed is a confectionary or chocolate or chocolate-like product comprising the fat composition. A fat composition as disclosed shows the possibility to produce chocolate-like compounds without the use of a palm based vegetable fat phase without compromising the quality.

Description

A fat composition comprising a vegetable fat phase originating from at least two different vegetable fat sources which is free from palm oil and/or fractions thereof
Technical field of the invention
The present invention relates to a fat composition comprising a vegetable fat phase originating from at least two different vegetable fat sources, wherein the vegetable fat phase is free from palm oil and/or fractions thereof and also relates to the use of the fat composition. The invention further relates to a confectionary or chocolate or chocolate-like product comprising the fat composition.
Background of the invention
Palm oil is an extremely versatile oil that has many different properties and functions that makes it so useful and so widely used. It is semi-solid at room temperature so can keep spreads spreadable; it is resistant to oxidation so can give products a longer shelf-life; it’s stable at high temperatures so helps to give fried products a crispy and crunchy texture; and it’s also odourless and colourless so doesn’t alter the look or smell of food products.
As well as being versatile, compared to other vegetable oils the oil palm is a very efficient crop, able to produce high quantities of oil over small areas of land, almost all year round. This makes it an attractive crop for growers and smallholders, who can rely on the steady income that palm oil provides.
Palm oil is also found as an important component in cocoa butter equivalents (CBEs) and cocoa butter improvers (CBIs), both used in the chocolate industry today. In CBE and CBI components palm mid fractions is used as one of the more important components.
Unfortunately, palm oil has been and continues to be a major driver of deforestation of some of the world’s most biodiverse forests, destroying the habitat of already endangered species like the Orangutan, pygmy elephant, and Sumatran rhino. This forest loss coupled with conversion of carbon rich peat soils are throwing out millions of tonnes of greenhouse gases into the atmosphere and contributing to climate changes. There also remains some exploitation of workers and child labour. These are serious issues that the whole palm oil sector needs to address.
Therefore, non-palm oil sources in the vegetable oils and fats industry have become an important subject as an alternative to oil palms. Thus, there is a need in the art for such alternatives.
Accordingly, the main object of the invention is to provide such alternatives. Summary of the invention
The present invention relates to a fat composition comprising a vegetable fat phase, wherein the vegetable fat phase comprises: from 85.0% to 100.0% by weight of triglycerides compared to the total weight of the vegetable fat phase; from 50.0% to 85.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 35.0 to 55.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase;
8.0% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 12.0% to 28.0% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 0.9% to 6.0% by weight of StLiSt + StStLi triglycerides compared to the total weight of triglycerides in the vegetable fat phase; and a ratio of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides of 0.08 or less; and wherein the vegetable fat phase is free from palm oil and fractions thereof; wherein the vegetable fat phase originates from at least two different vegetable fat sources; and wherein Sat is saturated fatty acids selected from C16-, C18-, C20-, C22-, and/or C24-fatty acids, P is palmitic acid (C16:0), St is steric acid (C18:0), O is oleic acid (C18:1), and Li is linoleic acid (C18:2).
The fat composition as disclosed herein shows the possibility to produce chocolate-like compounds without the use of a palm-based vegetable fat phase without compromising the quality. As can be seen by the examples provided herein, it is possible to make a chocolate comprising CBI based on a combination of at least two non-palm oil sources as the predominant vegetable fat components in the fat phase, where the resulting chocolate or chocolate-like products is as bloom stable and has as good a sensory felling as a product made with cocoa butter.
This also means that the present invention as disclosed herein can be used to produce chocolatelike compounds, which are as bloom stable and has as good a sensory felling as traditional chocolate or chocolate-like compounds.
Further, the present invention is low or absent of asymmetric (SatSatO) TAGs in the CBI as compared to a CBE comprising Palm mid fraction, as the present invention has a ratio of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides of 0.08 or less. This has an added advantage, since the presence of asymmetric TAG’S generally result in lower temperature settings in the crystallization and outlet zone of a temper unit, which can have a negative impact to crystallization in the cooling tunnel. Furthermore, a minor impact to texture towards a softer product can also be a consequence of the presence of asymmetric mono-saturated TAGs in the fat composition.
The present invention also relates to use of the fat composition according to the present invention for bakery, dairy, or confectionary applications or in coating or enrobing for nuts, bakery or confectionary applications, such as bakery or confectionary application, selected from biscuit, cake, muffin, donut, pastry, or bread applications; or for chocolate and chocolate-like applications, such as chocolate-like coatings, or chocolate and chocolate-like moulding, such as tablet moulding.
Further disclosed is also a confectionary or chocolate or chocolate-like product having a fat content from 20% to 60% by weight, wherein the fat content comprises from 5% to 60% by weight of a fat composition according to the present invention compared to the total weight of the fat content.
Even further disclosed is a process for the preparation of a fat composition according to the present invention, wherein a first vegetable fat source is blended with a second vegetable fat source to obtain the fat composition as disclosed herein.
Definitions
In the context of the present invention, the following terms are meant to comprise the following, unless defined elsewhere in the description.
As used herein, the term “vegetable” shall be understood as originating from a plant or a single cell organism. Thus, vegetable fat or vegetable triglycerides are still to be understood as vegetable fat or vegetable triglycerides if all the fatty acids used to obtain said triglyceride or fat is of plant origin or single cell organism origin.
As used herein, the term “triglycerides” may be used interchangeably with the term “triacylglycerides” and should be understood as an ester derived from glycerol and three fatty acids. “Triglycerides” may be abbreviated TG or TAG.
Saturated fatty acids (SAFA) are chains of carbon atoms joined by single bonds, with the maximum number of hydrogen atoms attached to each carbon atom in the chain. Unsaturated fatty acids are chains of carbon atoms joined by single bonds and varying numbers of double bonds, which do not have their full quota of hydrogen atoms attached. An unsaturated fatty acid can exist in two forms, the cis form and the trans form. A double bond may exhibit one of two possible configurations: trans or cis. In trans configuration (a trans fatty acid) the carbon chain extends from opposite sides of the double bond, whereas, in cis configuration (a cis fatty acid) the carbon chain extends from the same side of the double bond. By using the nomenclature CX means that the fatty acid comprises X carbon atoms, e.g. a C14 fatty acid has 14 carbon atoms while a C8 fatty acid has 8 carbon atoms.
By using the nomenclature CX:Y means that the fatty acid comprises X carbon atoms and Y double bonds, e.g. a C14:0 fatty acid has 14 carbon atoms and 0 double bonds while a C18:1 fatty acid has 18 carbon atoms and 1 double bond.
In general, triglycerides use a "sn" notation, which stands for stereospecific numbering. In a Fischer projection of a natural L-glycerol derivative, the secondary hydroxyl group is shown to the left of C- 2; the carbon atom above this then becomes C-1 and that below becomes C-3. The prefix ‘sn’ is placed before the stem name of the compound.
Sn1/sn2/sn3:
H
H-C-OOCR’ position 5^1
R"COO-C-H position sn-2
H - C - OOCR*" position so-3
H
Fischer projection of a natural L-glycerol derivative.
By randomly distributed is meant that the fatty acids are randomly distributed to the three sn- positions. A randomly distributed composition may be obtained by means of esterification, chemical transesterification or enzymatic transesterification. All naturally occurring fat compositions, e.g. virgin olive oil, palm kernel oil, coconut oil or rapeseed oil all have a non-randomly distribution of the fatty acids on the glycerol backbone.
By vegetable fat phase is meant a combination of at least two different vegetable fat sources originating from a plant or a single cell organism. The vegetable fat phase can e.g. be selected from the group of lllipe oil, Shea oil, or Sal oil, or a blend thereof, and/or fractions thereof. It can also be selected from an interesterified, fractionated, and/or hydrogenated version of Shea, lllipe, and/or Sal oil, or a blend thereof, and/or fractions thereof.
As used herein, “%” or “percentage” relates to weight percentage i.e. wt.% or wt.-% if nothing else is indicated.
The sum of a given component in the fat composition or in the vegetable fat phase can never be more than 100% by weight, e.g. the sum of all the fatty acid in the vegetable fat composition can never be more than 100% by weight.
As used herein, “oil” and “fat” are used interchangeably, unless otherwise specified. As used herein, “vegetable oil” and “vegetable fat” are used interchangeably, unless otherwise specified.
As used herein the term “single cell oil” shall mean oil from oleaginous microorganisms which are species of yeasts, molds (fungal), bacteria and microalgae. These single cell oils are produced intracellular and in most cases during the stationary growth phase under specific growth conditions (e.g. under nitrogen limitation with simultaneous excess of a carbon source). Examples of oleaginous microorganisms are, but not limited to, Mortierella alpineea, Yarrowia lipolytica, Schizochytrium, Nannochloropsis, Chlorella, Crypthecodinium cohnii, Shewanella.
As used herein “cocoa butter equivalent” or CBE is intended to mean an edible fat having very similar chemical and physical properties and being compatible with cocoa butter. In both cocoa butter and cocoa butter equivalent, the main fatty acids are typically palmitic, stearic, and oleic acids. The triglycerides are typically 2-oleo di-saturated (SatOSat (Sat2O)). Despite their similarity to cocoa butter, cocoa butter equivalents can be detected in chocolate by their triglyceride ratios, which are appreciably different from those in cocoa butter.
As used herein “cocoa butter improver” or CBI is intended to mean a harder version (i.e. has a higher solid fat content) of cocoa butter equivalent due to a higher content of high melting SatOSat triglycerides such as StOSt triglycerides and/or StOA triglycerides. It is usually used in chocolate formulations having a high content of milk fat or those meant for tropical climates. It improves the heat stability of soft cocoa butter varieties, adds more solid fat and thereby increases hardness in chocolate products.
As used herein “edible” is something that is suitable for use as food or as part of a food product, such as a dairy chocolate, or confectionary product.
For products and methods in the confectionery areas, reference is made to “Chocolate, Cocoa and Confectionery”, B. W. Minifie, Aspen Publishers Inc., 3. Edition 1999.
A food product is a product for human consumption.
By a chocolate or chocolate-like product is meant a product, which at least is experienced by the consumer as chocolate or as a confectionery product having sensorial attributes common with chocolate, such as e.g. melting profile, taste etc. Some chocolate comprises cocoa butter, typically in substantial amounts, where some chocolate-like product may be produced with a low amount of or even without cocoa butter, e.g. by replacing the cocoa butter with a cocoa butter equivalent, cocoa butter substitute, etc. In addition, many chocolate or chocolate-like products comprise cocoa powder or cocoa mass, although some chocolate or chocolate-like products, such as typical white chocolates, may be produced without cocoa powder, but e.g. drawing its chocolate taste from cocoa butter. Depending on the country and/or region there may be various restrictions on which products may be marketed as chocolate.
By compound is meant a product made from a combination of cocoa butter and (vegetable) fats. A compound may also comprise milk fat in various amounts. It is used as a lower-cost alternative to true chocolate, as it uses less-expensive hard (vegetable) fats in place of the more expensive cocoa butter. It may also be known as "compound coating" or "chocolatey coating" when used as a coating for confectionary or candy.
The term “comprising” or “to comprise” is to be interpreted as specifying the presence of the stated parts, steps, features, or components, but does not exclude the presence of one of more additional parts, steps, features, or components.
As used herein, the term “and/or” is intended to mean the combined (“and”) and the exclusive (“or”) use, i.e. “A and/or B” is intended to mean “A alone, or B alone, or A and B together”.
Detailed description of the invention
When describing the below embodiments, the present invention envisages all possible combinations and permutations of the below described embodiments with the above disclosed aspects.
The invention relates to a fat composition comprising a vegetable fat phase, wherein the vegetable fat phase comprises: from 85.0% to 100.0% by weight of triglycerides compared to the total weight of the vegetable fat phase; from 50.0% to 85.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 35.0 to 55.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; 8.0% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 12.0% to 28.0% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase; from 0.9% to 6.0% by weight of StLiSt + StStLi triglycerides compared to the total weight of triglycerides in the vegetable fat phase; and a ratio of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides of 0.08 or less; and wherein the vegetable fat phase is free from palm oil and fractions thereof; wherein the vegetable fat phase originates from at least two different vegetable fat sources ; and wherein Sat is saturated fatty acids selected from C16-, C18-, C20-, C22-, and/or C24-fatty acids, P is palmitic acid (C16:0), St is steric acid (C18:0), O is oleic acid (C18:1), and Li is linoleic acid (C18:2). The fat composition as disclosed herein shows the possibility to produce chocolate-like compounds without the use of a palm-based vegetable fat phase without compromising the quality.
The fat composition as disclosed herein can be used to produce chocolate-like compounds which are as bloom stable as compounds based on cocoa butter only. Further, the produced chocolatelike compounds show a similar sensory feeling, as those made with cocoa butter.
Furthermore, some of the SFC profiles for the compositions (also referred to as blends) disclosed herein are similar to the SFC profile for cocoa butter, strongly indicating the potential of the fat compositions as a partial substitute for cocoa butter in a chocolate application.
In one or more embodiments, the vegetable fat phase is free from enzymatic intereste rifled components. Hence, this means that in one or more embodiments the vegetable fat phase is made without the use of 1-3 specific enzymatic interesterification. The fat composition as disclosed herein therefore also shows the possibility to produce chocolate-like compounds without the use of a 1-3 specific enzymatic interesterification without compromising the quality.
In one or more embodiments, the vegetable fat phase comprises from 95.0% to 99.0% by weight of triglycerides compared to the total weight of the vegetable fat phase.
In one or more embodiments, the vegetable fat phase comprises from 55.0% to 83.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 58.0% to 81 .0% by weight, or such as from 60.0% to 80.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
In one or more embodiments, the vegetable fat phase comprises from 37.0% to 52.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 39.0% to 50.0% by weight, such as from 40.0% to 47.0% by weight, or such as from 41.0% to 46.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
In one or more embodiments, the vegetable fat phase comprises 7.0% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as 6.0% or less by weight, such as 5.0% or less by weight, or such as 4.5% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase. In one or more embodiments, the vegetable fat phase comprises from 13.0% to 26.0% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 14.0% to 24.0% by weight, such as from 14.5% to 23.0% by weight, or such as from 14.5% to 22.5% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
In one or more embodiments, the vegetable fat phase further comprises from 2.5% to 10.0% by weight of StOA + StAO + AStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 2.8% to 9.5% by weight, or such as from 3.0% to 9.0% by weight of StOA+ StAO + AStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, wherein A is arachidic acid (C20:0).
In one or more embodiments, the vegetable fat phase comprises from 1 .0% to 5.0% by weight of StLiSt + StStLi triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 1.1% to 4.0% by weight, or such as from 1 .1 % to 3.5% by weight of StLiSt triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
In one or more embodiments, the ratio in the vegetable fat phase of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides is 0.06 or less, such as 0.04 or less, such as 0.02 or less, or such as 0.01 or less.
In one or more embodiments, the ratio in the vegetable fat phase of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides is from 0.00 to 0.08, such as from 0.00 to 0.06, such as from 0.00 to 0.04, such as from 0.00 to 0.02, or such as from 0.00 to 0.01 .
In one or more embodiments, the at least two different vegetable fat sources are composed of at least a first vegetable fat source and a second vegetable fat source; wherein the first vegetable fat source is originating from lllipe oil and/or fractions thereof; and wherein the second vegetable fat source is originating from Shea oil and/or fractions thereof, Sal oil and/or fractions thereof, or a combination of Shea oil and/or fractions thereof and Sal oil and/or fractions thereof.
The examples clearly demonstrate that a combination of lllipe oil and Shea and/or Sal oil can be used as an alternative to palm fractions to make non-palm CBI compositions.
In one or more embodiments, the first vegetable fat source is originating from lllipe oil and/or fractions thereof; and wherein the second vegetable fat source is originating from Shea oil and/or fractions thereof or Sal oil and/or fractions thereof. In one or more embodiments, the first vegetable fat source is originating from lllipe oil; and wherein the second vegetable fat source is originating from Shea oil or Sal oil.
In one or more embodiments, first vegetable fat source is in an amount from 30% to 70% by weight of the sum of the first vegetable fat source and the second vegetable fat source.
In one or more embodiments, the second vegetable fat source is in an amount from 30% to 70% by weight of the sum of the first vegetable fat source and the second vegetable fat source.
In one or more embodiments, the vegetable fat phase originates from and consist of two different vegetable fat sources.
In one or more embodiments, the fat composition is a cocoa butter improver (CBI) composition.
Cocoa butter equivalents and cocoa butter improvers are e.g. normally made from a mix of palm mid fraction and a fractionated part of shea stearin or another oil fraction rich in SatOSat triglycerides, where Sat is a saturated fatty acid having a chain length of C16 or longer, such as C16 and C18. However, by the present invention, it has shown to be possible to make non-palm cocoa butter improvers.
The CBI’s disclosed herein shows an increase in heat related bloom stability (better shelf life at 25 °C in the examples).
Use of the fat composition according to the present invention for bakery, dairy, or confectionary applications, or in coating or enrobing for nuts, bakery or confectionary applications, such as bakery or confectionary application, selected from biscuit, cake, muffin, donut, pastry, or bread applications; or for chocolate and chocolate-like applications, such as chocolate-like coatings, or chocolate and chocolate-like moulding, such as tablet moulding is also disclosed.
Further disclosed is also a confectionary or chocolate or chocolate-like product having a fat content from 20% to 60% by weight, wherein the fat content comprises from 5% to 60% by weight of a fat composition according to the present invention compared to the total weight of the fat content.
In one or more embodiments, the fat content comprises from 10% to 50% by weight of the fat composition, such as from 15% to 40% by weight of the fat composition compared to the total weight of the fat content. Even further disclosed is also a process for the preparation of a fat composition according to the present invention, wherein the first vegetable fat source is blended with the second vegetable fat source to obtain the fat composition.
The present invention is further illustrated by the following examples, which are not to be construed as limiting the scope of protection.
Examples
Example 1 - CBI compositions
Table 1 displays a typical selected triglyceride composition for a lllipe, Shea oil, Sal oil and West Africa cocoa butter measured by AOCS method Ce 5b-89. The asymmetric isomers are included in the amount specified under each TAGs in the examples since the method used (AOCS Ce 5b-89) does not measure the difference in isomeric state of a TAG. Hence, for example, when there is written POSt in the table it also includes its isomers; PStO and StPO.
The content of SatSatO was determined using a well-known method by a commercial laboratory. The amount of the asymmetric SatSatO isomer is measured using an absolute method. Thereafter, the triglyceride ratio SatSatO/SatOSat was calculated.
The solid fat content was measured by IUPAC 2.150b and is also displayed in Table 1.
Figure imgf000011_0001
Figure imgf000012_0002
*Measured using AOCS Ce5b-89
Table 2 shows the selected triglyceride composition of West African cocoa butter compared to four CBIs made of blends of lllipe and Shea oil.
Figure imgf000012_0001
*Measured using AOCS Ce5b-89
There are differences in the SatOSat composition between cocoa butter and the CBI I to IV. The POP and POSt content is significantly lower for the CBI’s whereas the StOSt content is higher for the CBI’s compared to cocoa butter. This is the main reason for the differences in the SFC melting profiles between the CBI’s and cocoa butter as well. The CBI’s have significantly higher SFC at 35°C, while they are lower at 20 °C and 25 °C as a result of reduced total SatOSat content as compared to cocoa butter. Table 3 shows the selected triglyceride composition of West African cocoa butter compared to four CBIs made of blends of lllipe and Sal oil.
Figure imgf000013_0001
*Measured using AOCS Ce5b-89
As were the case for CBI I to IV compared to cocoa butter (Table 2) there are differences in the SatOSat composition between cocoa butter and the CBI V to VIII. The POP and POSt content is significantly lower for the CBI’s whereas the StOSt and StOA contents are higher for the CBI’s compared to cocoa butter. This is the main reason for the differences in the SFC melting profiles between the CBI’s and cocoa butter as well. The CBI’s have significantly higher SFC at 35°C, while they are lower at 20 °C and 25 °C as a result of reduced total SatOSat content as compared to cocoa butter.
Several fat blends of cocoa butter and CBI I to VIII were made. Table 4 shows the SFC profiles for blends of 15.0 and 30.0% CBI with Cocoa butter for a CBI I to VIII. Cocoa butter is shortened CB in the table.
Figure imgf000014_0001
Figure imgf000015_0001
A comparison of the SFC profiles for the CBI I to VIII and for the blends of CBI I to VIII with cocoa butter makes it clear that the SFC at 35 °C is decreased significantly in the CBI and cocoa butter blends. Furthermore, the SFC profiles for the blends based on 15% CBI and 85% cocoa butter are similar to the SFC profile for cocoa butter, strongly indicating the potential of CBI I to VIII as a partial substitute for cocoa butter in a chocolate application.
The increase in SFC at 35 °C for the blends with 30% CBI and 70% cocoa butter indicate that the sensory perception for such a fat composition in a chocolate application may be perceived as slightly waxier as compared to a cocoa butter based analogue application.
Example 2 - Recipes and manufacture of dark chocolate applications with CBI compositions The procedure of the dark chocolate productions were all done following the below procedure:
All ingredients, except lecithin and some of the fat, are mixed on a teddy mixer with heat jacket to a consistency of marzipan. Afterwards, the mixture is refined on a three-roller Buhler refiner to an average particle size of 20 micron. The mass is then dry-conched at 65 °C for three hours before the remaining fat is added and then followed by wet-couching for three hours. Half an hour before conching is complete lecithin is added. The chocolates are then transferred to an Aasted AMC 50 three zone tempering machine to be optimally tempered.
The dark chocolates are deposited into 50 g preheated moulds and placed in a three-zone cooling tunnel for 30 minutes. Temperatures are adjusted to 15 °C in zone 1 and 3 and 12 °C in zone 2. The demoulded chocolate tablets are kept at 20 °C for one week and then moved to 20 °C and 25 °C cabinets for isothermal storage. Once a week the tablets are evaluated by a trained panel of experts for visible bloom. The number of weeks until the appearance of strong bloom on the surface of the chocolate tablets are noted as the shelf life result (see table 7 below).
Dark chocolate recipe and fat composition are given in Table 5.
Figure imgf000015_0002
Figure imgf000016_0001
Example 3 - Sensory evaluation
The 50g tablets (of table 5) were tasted by a trained sensory panel and evaluated for meltdown using the scale below: A = Good and clean meltdown. Comparable to cocoa butter-based chocolate
B = Acceptable meltdown. Slightly waxy meltdown but close to cocoa-butter based chocolate
C = Inferior meltdown. Waxy meltdown not comparable to cocoa butter-based chocolate
Figure imgf000016_0002
The sensory evaluation in table 6 clearly demonstrates that good or at least acceptable meltdown is achievable in chocolates with 15% and 30% substitution of cocoa butter with CBI in the fat phase of the dark chocolates. Example 4 - Shelf life evaluation
The shelf life results are given in table 7 below. The shelf life results demonstrate that it is possible to make a chocolate comprising CBI based on blends of either Shea Stearin and Sal oil or Shea oil and Sal Stearin with a shelf life performance at least as good as cocoa butter-based chocolate when stored at 20 °C. However, the higher content of the sum of StOSt and StOA for the CBI’s as compared to cocoa butter results in more heat stable chocolates with respect to shelf life when stored at 25 °C.
Figure imgf000017_0001

Claims

Claims
1 . A fat composition comprising a vegetable fat phase, wherein the vegetable fat phase comprises:
- from 85.0% to 100.0% by weight of triglycerides compared to the total weight of the vegetable fat phase;
- from 50.0% to 85.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase;
- from 35.0 to 55.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase;
- 8.0% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase;
- from 12.0% to 28.0% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase;
- from 0.9% to 6.0% by weight of StLiSt + StStLi triglycerides compared to the total weight of triglycerides in the vegetable fat phase; and
- a ratio of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides of 0.08 or less; and wherein the vegetable fat phase is free from palm oil and fractions thereof; wherein the vegetable fat phase originates from at least two different vegetable fat sources; and wherein Sat is saturated fatty acids selected from C16-, C18-, C20-, C22-, and/or C24-fatty acids, P is palmitic acid (C16:0), St is steric acid (C18:0), O is oleic acid (C18:1), and Li is linoleic acid (C18:2).
2. The fat composition according to claim 1 , wherein the vegetable fat phase is free from enzymatic interesterified components.
3. The fat composition according to any of the preceding claims, wherein the vegetable fat phase comprises from 95.0% to 99.0% by weight of triglycerides compared to the total weight of the vegetable fat phase.
4. The fat composition according to any of the preceding claims, wherein the vegetable fat phase comprises from 55.0% to 83.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 58.0% to 81 .0% by weight, or such as from 60.0% to 80.0% by weight of SatOSat + SatSatO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
5. The fat composition according to any of the preceding claims, wherein the vegetable fat phase comprises from 37.0% to 52.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 39.0% to 50.0% by weight, such as from 40.0% to 47.0% by weight, or such as from 41 .0% to 46.0% by weight of StOSt + StStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
6. The fat composition according to any of the preceding claims, wherein the vegetable fat phase comprises 7.0% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as 6.0% or less by weight, such as 5.0% or less by weight, or such as 4.5% or less by weight of POP + PPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
7. The fat composition according to any of the preceding claims, wherein the vegetable fat phase comprises from 13.0% to 26.0% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 14.0% to 24.0% by weight, such as from 14.5% to 23.0% by weight, or such as from 14.5% to 22.5% by weight of POSt + PStO + StPO triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
8. The fat composition according to any of the preceding claims, wherein the vegetable fat phase further comprises from 2.5% to 10.0% by weight of StOA + StAO + AStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 2.8% to 9.5% by weight, or such as from 3.0% to 9.0% by weight of StOA+ StAO + AStO triglycerides compared to the total weight of triglycerides in the vegetable fat phase, wherein A is arachidic acid (C20:0).
9. The fat composition according to any of the preceding claims, wherein the vegetable fat phase comprises from 1 .0% to 5.0% by weight of StLiSt + StStLi triglycerides compared to the total weight of triglycerides in the vegetable fat phase, such as from 1.1% to 4.0% by weight, or such as from 1.1 % to 3.5% by weight of StLiSt triglycerides compared to the total weight of triglycerides in the vegetable fat phase.
10. The fat composition according to any of the preceding claims, wherein the ratio in the vegetable fat phase of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides is 0.06 or less, such as 0.04 or less, such as 0.02 or less, or such as 0.01 or less.
11. The fat composition according to any of the preceding claims, wherein the ratio in the vegetable fat phase of the weight of SatSatO triglycerides to the weight of SatOSat triglycerides is from 0.00 to 0.08, such as from 0.00 to 0.06, such as from 0.00 to 0.04, such as from 0.00 to 0.02, or such as from 0.00 to 0.01 .
12. The fat composition according to any of the preceding claims, wherein the at least two different vegetable fat sources are composed of at least a first vegetable fat source and a second vegetable fat source; wherein the first vegetable fat source is originating from lllipe oil and/or fractions thereof; and wherein the second vegetable fat source is originating from Shea oil and/or fractions thereof, Sal oil and/or fractions thereof, or a combination of Shea oil and/or fractions thereof and Sal oil and/or fractions thereof.
13. The fat composition according to claim 12, wherein the first vegetable fat source is originating from lllipe oil and/or fractions thereof; and wherein the second vegetable fat source is originating from Shea oil and/or fractions thereof or Sal oil and/or fractions thereof.
14. The fat composition according to claim 13, wherein the first vegetable fat source is originating from lllipe oil; and wherein the second vegetable fat source is originating from Shea oil or Sal oil.
15. The fat composition according to any of claim 12-14, wherein first vegetable fat source is in an amount from 30% to 70% by weight of the sum of the first vegetable fat source and the second vegetable fat source.
16. The fat composition according to any of claim 12-15, wherein the second vegetable fat source is in an amount from 30% to 70% by weight of the sum of the first vegetable fat source and the second vegetable fat source.
17. The fat composition according to any of the preceding claims, wherein the vegetable fat phase originates from and consist of two different vegetable fat sources.
18. The fat composition according to any of the preceding claims, wherein the fat composition is a cocoa butter improver (CBI) composition.
19. Use of the fat composition according to any of the claims 1 -18 for bakery, dairy, or confectionary applications, or in coating or enrobing for nuts, bakery or confectionary applications, such as bakery or confectionary application, selected from biscuit, cake, muffin, donut, pastry, or bread applications; or for chocolate and chocolate-like applications, such as chocolate-like coatings, or chocolate and chocolate-like moulding, such as tablet moulding.
20. A confectionary or chocolate or chocolate-like product having a fat content from 20% to 60% by weight, wherein the fat content comprises from 5% to 60% by weight of a fat composition according to any of claims 1-17 compared to the total weight of the fat content.
21. The confectionary or chocolate or chocolate-like product according to claim 20, wherein the fat content comprises from 10% to 50% by weight of the fat composition, such as from 15% to 40% by weight of the fat composition compared to the total weight of the fat content.
22. Process for the preparation of a fat composition according to claims 1-18, wherein the first vegetable fat source is blended with the second vegetable fat source to obtain the fat composition.
PCT/SE2024/050396 2023-04-28 2024-04-25 A fat composition comprising a vegetable fat phase originating from at least two different vegetable fat sources which is free from palm oil and/or fractions thereof Pending WO2024225959A1 (en)

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