WO2024262547A1 - Blast furnace operation method - Google Patents
Blast furnace operation method Download PDFInfo
- Publication number
- WO2024262547A1 WO2024262547A1 PCT/JP2024/022266 JP2024022266W WO2024262547A1 WO 2024262547 A1 WO2024262547 A1 WO 2024262547A1 JP 2024022266 W JP2024022266 W JP 2024022266W WO 2024262547 A1 WO2024262547 A1 WO 2024262547A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- blast furnace
- gas
- temperature
- tuyere
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
Definitions
- the present invention relates to a method for operating a blast furnace.
- This application claims priority based on Japanese Patent Application No. 2023-101584, filed on June 21, 2023, the contents of which are incorporated herein by reference.
- the blast furnace process is the mainstream of pig iron manufacturing processes.
- ferrous raw materials raw materials containing iron oxide, mainly sintered ore, hereafter also referred to simply as "ferrous raw materials”
- coke are charged alternately and in layers into the blast furnace from the top of the furnace, while hot air is blown into the blast furnace from tuyere holes installed in the lower part of the blast furnace below the bosh.
- the hot air reacts with the pulverized coal blown in together with the hot air and the coke in the blast furnace to generate high-temperature reducing gas (mainly CO gas in this case).
- high-temperature reducing gas mainly CO gas in this case
- the reducing gas rises in the blast furnace, heating and reducing the ferrous raw materials.
- the ferrous raw materials descend in the blast furnace, while being heated and reduced by the reducing gas.
- the ferrous raw materials then melt and drip into the blast furnace while being further reduced by the coke.
- the iron-based raw materials are eventually stored in the hearth as molten pig iron (pig iron) containing just under 5% by mass of carbon.
- the molten pig iron in the hearth is removed from the tap hole and used in the next steelmaking process. Therefore, in the blast furnace process, carbonaceous materials such as coke and pulverized coal are used as reducing agents.
- CO2 gas carbon dioxide
- the blast furnace process uses carbonaceous materials as a reducing agent, which generates a large amount of CO2 gas. Therefore, the steel industry is one of the major industries in terms of CO2 gas emissions, and must respond to this social demand. Specifically, there is an urgent need to further reduce the reducing agent ratio (amount of reducing agent used per ton of molten iron) in blast furnace operation.
- the reducing agent has the role of raising the temperature of the charge by becoming heat in the furnace and the role of reducing the iron-based raw materials in the furnace, and in order to reduce the reducing agent ratio, it is necessary to increase the reduction efficiency in the furnace.
- the reduction reaction in the furnace can be expressed by various reaction formulas. Among these reduction reactions, the direct reduction reaction by coke (reaction formula: FeO + C ⁇ Fe + CO) is an endothermic reaction accompanied by a large heat absorption. Therefore, it is important to prevent this reaction from occurring as much as possible in reducing the reducing agent ratio.
- this direct reduction reaction occurs in the lower part of the blast furnace, if the iron-based raw materials can be sufficiently reduced by reducing gas such as CO and H2 before they reach the lower part of the furnace, the iron-based raw materials that are the subject of the direct reduction reaction can be reduced.
- Patent Document 1 As a conventional technique for solving the above problems, for example, as disclosed in Patent Document 1, a technique is known in which hydrogen gas is blown in together with hot air from the tuyere to improve the reducing gas potential inside the furnace. In this technique, hydrogen gas is used as a reducing gas for the iron-based raw material, thereby reducing the reducing agent ratio.
- the present inventors have defined a parameter called the reduction rate of carbon consumption intensity (Input ⁇ C) as a parameter serving as an index for reducing the reducing agent ratio.
- Carbon consumption intensity (Input C) is the carbon required to produce one ton of molten iron (i.e., the carbon consumption per ton of molten iron).
- the inventors of the present invention have studied the technology described in Patent Document 1 in detail, and have found that when trying to increase Input ⁇ C by the technology described in Patent Document 1, it is necessary to heat a large amount of hydrogen gas to a high temperature and inject it into the blast furnace. For example, when trying to make Input ⁇ C 40% or more, it is necessary to make the injection amount of hydrogen gas 650 Nm 3 /t or more and the temperature of the hydrogen gas 1200° C. or more. In this case, in addition to the need to prepare a large amount of hydrogen gas, it is necessary to prepare a heating device for heating the hydrogen gas to a high temperature and to construct the blast furnace equipment from a material that can withstand high-temperature hydrogen gas.
- Patent Document 1 had the problem that it required a great deal of effort to increase Input ⁇ C.
- the present invention has been made in consideration of the above problems, and the object of the present invention is to provide a method of operating a blast furnace that can increase Input ⁇ C even when the amount of hydrogen-based reducing gas (details of hydrogen-based reducing gas will be described later) injected is reduced and the heating temperature of the hydrogen-based reducing gas is lowered.
- the object of the present invention is to provide a method of operating a blast furnace that can increase Input ⁇ C even when the amount of hydrogen-based reducing gas (details of hydrogen-based reducing gas will be described later) injected is reduced and the heating temperature of the hydrogen-based reducing gas is lowered.
- the inventors have studied the technology described in Patent Document 1 in detail and found that a large amount of hydrogen gas is discharged as top exhaust gas during blast furnace operation.
- the inventors therefore attempted to separate reducing gas (this reducing gas includes hydrogen gas and CO gas) from the top exhaust gas and inject the separated reducing gas into the blast furnace.
- this reducing gas includes hydrogen gas and CO gas
- the inventors found that even when the amount of hydrogen gas injected was reduced compared to the technology described in Patent Document 1 and the heating temperature of the hydrogen gas was lowered, an Input ⁇ C equivalent to that of the technology described in Patent Document 1 could be obtained.
- the present invention was made based on this knowledge.
- the gist of the present invention is as follows. (1) a step of heating a hydrogen-based reducing gas supplied from outside a blast furnace system; injecting the heated hydrogen-based reducing gas into a blast furnace; separating the reducing gas from the top exhaust gas; heating the separated reducing gas; and injecting the reducing gas into the blast furnace. (2) The method for operating a blast furnace according to (1), characterized in that the reducing gas is injected into the blast furnace from a normal tuyere provided in a lower part of the blast furnace. (3) The method for operating a blast furnace according to (1) or (2), characterized in that the reducing gas is injected into a shaft portion of the blast furnace.
- the Input ⁇ C can be increased even if the amount of hydrogen-based reducing gas injected is reduced and the heating temperature of the hydrogen-based reducing gas is lowered.
- FIG. 1 is a flow diagram showing an overall configuration of a blast furnace system used in this embodiment.
- 6 is a graph verifying the effect of the first embodiment.
- 11 is a graph verifying the effect of the second embodiment.
- 11 is a graph verifying the effect of the second embodiment.
- 11 is a graph verifying the effect of the second embodiment.
- 11 is a graph verifying the effect of the second embodiment.
- 11 is a graph verifying the effect of the second embodiment.
- the blast furnace system 1 includes a blast furnace 10, a CO2 separation and capture device 20, a buffer tank 30, a compressor 40, a heater 50, and flow meters 61 and 62.
- the blast furnace 10 includes a blast furnace body 10a, a normal tuyere 11, and a shaft tuyere 12. Inside the blast furnace body 10a, a reduction reaction of the iron-based raw materials occurs by the blast furnace method. Specifically, the iron-based raw materials and coke are charged alternately and in layers into the blast furnace 10 from the top of the blast furnace 10, while hot air, pulverized coal, and enriched oxygen gas are blown into the blast furnace 10 from the normal tuyere 11.
- the "tuyere tip combustion temperature” means the temperature at the gas outlet of the normal tuyere 11.
- the hot air reacts with the pulverized coal blown in together with the hot air and the coke in the blast furnace 10 to generate high-temperature reducing gas (mainly CO gas in this case).
- high-temperature reducing gas mainly CO gas in this case.
- the hot air gas ifies the coke and pulverized coal.
- the reducing gas rises inside the blast furnace 10 and reduces the iron-based raw materials while heating them.
- the iron-based raw materials are heated and reduced by reducing gas while descending through the blast furnace 10.
- the iron-based raw materials then melt and drip through the blast furnace 10 while being further reduced by coke.
- the iron-based raw materials are ultimately stored in the hearth as molten pig iron (pig iron) containing just under 5% by mass of carbon.
- the molten pig iron in the hearth is removed from the tap hole and used in the next steelmaking process.
- the normal tuyere 11 is installed below the bosh of the blast furnace 10, and in addition to the hot air described above, as described below, heated hydrogen-based reducing gas and reducing gas separated from the top exhaust gas (blast furnace exhaust gas) are blown into the blast furnace 10. Note that while normal tuyere 11 is shown in two locations, one on the left and one on the right, in FIG. 1, three or more tuyere may be installed around the entire circumference of the blast furnace 10, spaced apart at a predetermined pitch.
- the shaft tuyere 12 is provided at a higher position than the normal tuyere 11 of the blast furnace 10, and injects the reducing gas separated from the top exhaust gas into the shaft 10b of the blast furnace 10.
- the shaft tuyere 12 is depicted in two places on the left and right of the shaft 10b in FIG. 1, three or more may be attached at a predetermined pitch around the entire circumference of the blast furnace 10.
- the shaft tuyere 12 is depicted in FIG. 1 on the shaft 10b, it may be attached to the belly, bosch, or lower position, which is lower than the shaft 10b, as long as it can inject the reducing gas separated from the top exhaust gas into the shaft 10b and is higher than the installation position of the normal tuyere 11.
- the CO2 separation and capture device 20 is a device that recovers the top flue gas and separates it into reducing gas (CO gas and hydrogen gas) and nitrogen gas, and CO2 gas and H2O gas.
- the separation method is not particularly limited, and examples thereof include chemical adsorption and physical adsorption (PSA).
- PSA chemical adsorption and physical adsorption
- the reducing gas and nitrogen gas separated from the top flue gas are also referred to as RBFG (Returned Blast Furnace Gas).
- RBFG Returned Blast Furnace Gas
- CO2 gas and H2O gas are discharged outside the system.
- the CO2 separation and capture device 20 does not necessarily recover the entire amount of the top flue gas.
- the CO2 separation and capture device 20 may recover only the amount of top flue gas corresponding to the flow rate of RBFG injected into the blast furnace.
- the buffer tank 30 is a tank that temporarily stores RBFG. A desired amount of RBFG is introduced from the buffer tank 30 to the compressor 40. The remaining RBFG is used, for example, as a heat source in a steelworks.
- the compressor 40 pressurizes the RBFG.
- the compressor 40 pressurizes the RBFG to, for example, the internal pressure of the blast furnace 10 (approximately 4.5 atmospheres).
- the pressurized RBFG is introduced into the heater 50.
- the heater 50 heats the RBFG.
- the heating temperature is set arbitrarily according to the operating conditions of the blast furnace 10, but for example, when the RBFG is blown into the shaft 10b of the blast furnace 10 from the shaft tuyere 12, it is preferable to set it to 800°C or higher.
- the heater 50 can be sufficiently realized by an electric heater or the like.
- the RBFG heated by the heater 50 is blown into the blast furnace 10, for example, from the normal tuyere 11, or blown into the shaft 10b of the blast furnace 10 from the shaft tuyere 12. In FIG.
- the RBFG is blown into the blast furnace 10 from the normal tuyere 11 and the shaft tuyere 12 on the left side, but the RBFG may also be blown into the blast furnace 10 from the normal tuyere 11 and the shaft tuyere 12 on the right side.
- the RBFG may be blown into the blast furnace 10 from both the normal tuyere 11 and the shaft tuyere 12.
- the flow meter 61 normally measures the flow rate of RBFG injected into the blast furnace 10 from the tuyere 11.
- the flow meter 62 measures the flow rate of RBFG injected into the shaft section 10b of the blast furnace 10 from the shaft section tuyere 12.
- by adjusting the flow rate of RBFG introduced from the buffer tank 30 to the compressor 40 it is possible to arbitrarily adjust the flow rate of RBFG injected into the blast furnace 10 from the tuyere 11 and the flow rate of RBFG injected into the shaft section 10b of the blast furnace 10 from the shaft section tuyere 12.
- the hydrogen-based reducing gas supply system 2 includes a hydrogen-based reducing gas tank 70, a heater 71, and a flow meter 72.
- the hydrogen-based reducing gas supply system 2 is a system that supplies hydrogen-based reducing gas to the blast furnace system 1 from outside the blast furnace system 1.
- the hydrogen-based reducing gas tank 70 is a tank for storing hydrogen-based reducing gas.
- the hydrogen-based reducing gas is a concept including hydrogen gas as well as a mixed gas of hydrogen gas and other gases (such as nitrogen gas) (which do not impair the effect of this embodiment).
- the heater 71 heats the hydrogen-based reducing gas supplied from the hydrogen-based reducing gas tank 70.
- the heater 71 can be sufficiently realized by an electric heater or the like.
- the heater 71 is normally connected to the tuyere 11, and the heated hydrogen-based reducing gas is normally blown into the blast furnace 10 from the tuyere 11.
- the heater 71 may be used in combination with the heater 50.
- the flowmeter 72 measures the flow rate of the hydrogen-based reducing gas blown into the blast furnace 10 from the tuyere 11.
- the Input ⁇ C can be increased.
- the hydrogen-based reducing gas is normally injected from the tuyere 11, but the hydrogen-based reducing gas may also be injected into the blast furnace 10 from the shaft tuyere 12.
- the operation method of the blast furnace 10 according to the first embodiment is generally as follows. That is, iron-based raw materials and coke are charged alternately and in layers into the blast furnace 10 from the top of the blast furnace 10, while heated hydrogen-based reducing gas is supplied from the hydrogen-based reducing gas supply system 2 to the normal tuyere 11. Then, hot air, pulverized coal, enriched oxygen gas, heated hydrogen-based reducing gas, and RBFG containing heated CO and H 2 are blown into the blast furnace 10 from the normal tuyere 11. The hot air reacts with the pulverized coal blown in together with the hot air and the coke in the blast furnace 10 to generate high-temperature reducing gas (mainly CO gas here).
- high-temperature reducing gas mainly CO gas here.
- the hot air gas ifies the coke and pulverized coal.
- the reducing gas rises in the blast furnace 10 and reduces the iron-based raw materials while heating them.
- the hydrogen-based reducing gas and RBFG rise in the blast furnace 10 and reduce the iron-based raw materials while heating them.
- the iron-based raw materials are heated and reduced by reducing gas, hydrogen-based reducing gas, and RBFG while descending through the blast furnace 10.
- the iron-based raw materials are then melted and dripped through the blast furnace 10 while being further reduced by coke.
- the iron-based raw materials are finally stored in the hearth as molten pig iron (pig iron) containing slightly less than 5% by mass of carbon.
- the molten pig iron in the hearth is removed from a tap hole and is used in the next steelmaking process.
- the CO2 separation and capture device 20 recovers the top flue gas and separates it into reducing gas (CO gas and hydrogen gas) and nitrogen gas (i.e., RBFG) and CO2 gas and H2O gas.
- the CO2 gas and H2O gas are discharged outside the system.
- RBFG is temporarily stored in the buffer tank 30.
- a desired amount of RBFG is introduced from the buffer tank 30 into the compressor 40.
- the remaining RBFG is discharged outside the system and used, for example, as a heat source in a steelworks.
- the RBFG is then pressurized by the compressor 40.
- the compressor 40 pressurizes the RBFG to, for example, the internal pressure of the blast furnace 10 (approximately 4.5 atmospheres).
- the pressurized RBFG is introduced into the heater 50.
- the RBFG is then heated by the heater 50.
- the heating temperature is set arbitrarily depending on the operating conditions of the blast furnace 10.
- the RBFG heated by the heater 50 is blown into the blast furnace 10 from the normal tuyere 11.
- the flowmeter 61 measures the flow rate of the RBFG blown into the blast furnace 10 from the normal tuyere 11.
- the RBFG is mainly blown into the blast furnace 10 from the normal tuyere 11, but may also be blown into the blast furnace 10 from the shaft tuyere 12 as an auxiliary. Details will be described later.
- the tuyere combustion temperature is preferably maintained at about 2000 to 2300°C
- the furnace top exhaust gas temperature is preferably maintained at about 105°C or higher
- the molten iron temperature is preferably maintained at about 1520°C or higher.
- the upper limit value of the tuyere combustion temperature is an upper limit value assuming normal operation (operation without injection of hydrogen-based reducing gas or RBFG).
- the tuyere combustion temperature exceeds the upper limit value, it is preferable to take measures such as strengthening the cooling capacity of the tuyere equipment to prevent wear and tear on the tuyere equipment and using materials with higher heat resistance. It is preferable to determine the specifications of the blast furnace operation so that the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within a specified range. As long as the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within the specified ranges, the blast furnace operation specifications can be freely designed. Also, although the tuyere combustion temperature may exceed the upper limit as a result of the design, it is preferable to take the above-mentioned measures separately.
- the blowing temperature of the hydrogen-based reducing gas (the temperature of the hydrogen-based reducing gas usually blown from the tuyere 11) is preferably about 800 to 1000°C, and the blowing amount of hydrogen gas in the hydrogen-based reducing gas is preferably about 300 to 600 Nm 3 /t. Both are in a range lower than that of Patent Document 1.
- the blowing temperature of the RBFG (the temperature of the RBFG usually blown from the tuyere 11, i.e., the heating temperature by the heater 50) is preferably about 800 to 1000°C, and the blowing amount of the RBFG is preferably about 400 to 800 Nm 3 /t.
- the blowing amount of the RBFG is preferably 600 Nm 3 /t or more.
- Input ⁇ C exceeds 40%.
- Other adjustable parameters include the blowing amount of hot air, the amount of oxygen contained in the hot air (the blowing amount of oxygen), etc.
- the molten pig iron temperature can also be adjusted by the amount of pulverized coal injected into the blast furnace 10 or the coke ratio (the amount of coke used per ton of molten pig iron). For example, the molten pig iron temperature is first adjusted by the amount of pulverized coal injected, and if the molten pig iron temperature exceeds a predetermined range even when the amount of pulverized coal injected becomes zero, the coke ratio is adjusted.
- the molten pig iron temperature is a value that reflects the total heat (furnace heat) in the blast furnace 10.
- the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature are monitored periodically (preferably all the time), and if any of the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature falls outside the above-mentioned range, the operating conditions (for example, as described above, at least one of the hydrogen-based reducing gas blowing temperature, the amount of hydrogen gas blown in the hydrogen-based reducing gas, the RBFG blowing temperature, the RBFG blowing amount, the hot blast blowing amount, and the amount of oxygen contained in the hot blast (the amount of enriched oxygen gas blown)) can be adjusted.
- the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature are prone to fluctuate when blowing hydrogen-based reducing gas or RBFG, it is preferable to monitor the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature when blowing these gases.
- This blast furnace mathematical model is, in outline, a plurality of meshes (small regions) defined by dividing the internal region of the blast furnace in the height direction, radial direction, and circumferential direction, and the behavior of each mesh is simulated.
- the prerequisites for the simulation are as follows. ⁇ Hydrogen gas is used as the hydrogen-based reducing gas.
- the CO2 separation and capture device 20 separates and removes 100% of the CO2 gas and H2O gas contained in the top flue gas. -
- the amount of molten iron produced and the temperature of molten iron will be constant at all levels (12,350 t/d, 1,535°C).
- the top exhaust gas temperature is set near the lower limit (105°C).
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted. The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
- Levels 1 to 5 correspond to the first embodiment.
- Level 1-1 No hydrogen gas blowing, hot air blowing temperature of 1200°C, RBFG blowing operation (blow temperature of 1200°C) (H2-0 BT1200°C in Figures 2 and 3.
- H2-0 BT1200°C indicates that no hydrogen gas blowing and hot air blowing temperature of 1200°C.
- Level 1-2 With hydrogen gas blowing (blowing temperature 1200°C, blowing rate 650 Nm 3 /t), hot air blowing temperature 1200°C, RBFG blowing operation (blowing temperature 1000°C) (H2-650 1200°C, BT 1200°C in Figures 2 and 3.
- H2-650 1200°C indicates that the hydrogen gas blowing rate is 650 Nm 3 /t and the blowing temperature is 1200°C
- BT 1200°C indicates that the hot air blowing temperature is 1200°C.
- Level 1-3 With hydrogen gas blowing (blowing temperature 1000°C, blowing rate 650 Nm 3 /t), hot air blowing temperature 1200°C, RBFG blowing operation (blowing temperature 1000°C) (H2-650 1000°C, BT 1200°C in Figures 2 and 3.
- H2-650 1000°C indicates that the hydrogen gas blowing rate is 650 Nm 3 /t and the blowing temperature is 1000°C
- BT 1200°C indicates that the hot air blowing temperature is 1200°C.
- Level 1-4 With hydrogen gas blowing (blowing temperature 1000°C, blowing rate 650 Nm 3 /t), hot air blowing temperature 1300°C, RBFG blowing operation (blowing temperature 1000°C) (H2-650 1000°C, BT 1300°C in Figures 2 and 3.
- H2-650 1000°C indicates that the hydrogen gas blowing rate is 650 Nm 3 /t and the blowing temperature is 1000°C
- BT 1300°C indicates that the hot air blowing temperature is 1300°C.
- Level 1-5 With hydrogen gas blowing (blowing temperature 1000°C, blowing rate 325 Nm 3 /t), hot air blowing temperature 1300°C, RBFG blowing operation (blowing temperature 1000°C) (H2-325 1000°C, BT 1300°C in Figures 2 and 3.
- H2-325 1000°C indicates that the hydrogen gas blowing rate is 325 Nm 3 /t and the blowing temperature is 1000°C
- BT 1300°C indicates that the hot air blowing temperature is 1300°C.
- the horizontal axis of Figure 2 indicates the amount of RBFG injected into the blast furnace 10 from the normal tuyere 11 ( Nm3 /t), and the vertical axis indicates Input ⁇ C (%).
- the horizontal axis of Figure 3 indicates the amount of RBFG injected into the blast furnace 10 from the normal tuyere 11 ( Nm3 /t), and the vertical axis (system-wide hydrogen gas utilization rate) indicates the utilization rate (%) of hydrogen gas in the entire system.
- the utilization rate of hydrogen gas in the entire system is expressed by the following formula.
- n H2 * 100 ⁇ a/(a+b)
- nH2 * Hydrogen gas utilization rate (%)
- a Amount of H 2 O gas discharged from the CO 2 separation and capture device 20 to the outside of the system (Nm 3 /t)
- b Amount of hydrogen gas discharged from the buffer tank 30 to the outside of the system (Nm 3 /t)
- the injection amount of hydrogen gas in level 1-5 is 325 Nm 3 /t, which is 50% less than levels 1-2 to 1-4, and the injection temperature of hydrogen gas is also low at 1000°C.
- the Input ⁇ C can be increased.
- Second embodiment (3-1. Blast furnace operation method according to the second embodiment) Next, a second embodiment of the present invention will be described.
- the RBFG is injected into the blast furnace 10 from the shaft tuyere 12.
- the flow meter 61 may be omitted.
- the operation method of the blast furnace 10 according to the second embodiment is generally as follows. That is, iron-based raw materials and coke are alternately and in layers charged into the blast furnace 10 from the top of the blast furnace 10, while heated hydrogen-based reducing gas is supplied from the hydrogen-based reducing gas supply system 2 to the normal tuyeres 11. Then, hot air, pulverized coal, enriched oxygen gas, and heated hydrogen-based reducing gas are blown into the blast furnace 10 from the normal tuyeres 11. Meanwhile, RBFG is blown into the shaft 10b of the blast furnace 10 from the shaft tuyeres 12.
- the hot air reacts with the pulverized coal blown in together with the hot air and the coke in the blast furnace 10 to generate high-temperature reducing gas (mainly CO gas in this case). That is, the hot air gasifies the coke and pulverized coal.
- the reducing gas rises inside the blast furnace 10 and reduces the iron-based raw materials while heating them.
- the hydrogen-based reducing gas and RBFG rise inside the blast furnace 10, heating and reducing the iron-based raw materials.
- the iron-based raw materials melt and drip inside the blast furnace 10 while being further reduced by coke.
- the iron-based raw materials are ultimately stored in the hearth as molten pig iron (pig iron) containing just under 5% by mass of carbon. The molten pig iron in the hearth is removed from the tap hole and used in the next steelmaking process.
- the CO2 separation and capture device 20 recovers the top flue gas and separates it into reducing gas (CO gas and hydrogen gas) and nitrogen gas (i.e., RBFG) and CO2 gas and H2O gas.
- the CO2 gas and H2O gas are discharged outside the system.
- RBFG is temporarily stored in the buffer tank 30.
- a desired amount of RBFG is introduced from the buffer tank 30 into the compressor 40.
- the remaining RBFG is discharged outside the system and used, for example, as a heat source in a steelworks.
- the RBFG is then pressurized by the compressor 40.
- the compressor 40 pressurizes the RBFG to, for example, the internal pressure of the blast furnace 10 (approximately 4.5 atmospheres).
- the pressurized RBFG is introduced into the heater 50.
- the RBFG is then heated by the heater 50.
- the heating temperature is set arbitrarily depending on the operating conditions of the blast furnace 10.
- the RBFG heated by the heater 50 is blown into the shaft section 10b of the blast furnace 10 from the shaft section tuyere 12.
- the flowmeter 62 measures the flow rate of the RBFG blown into the shaft section 10b of the blast furnace 10 from the shaft section tuyere 12.
- the RBFG is mainly blown into the shaft section 10b of the blast furnace 10 from the shaft section tuyere 12, but may also be blown into the blast furnace 10 from the normal tuyere 11 as an auxiliary.
- a specific example of the operating method is as described in the first embodiment.
- the tuyere combustion temperature is preferably maintained at about 2000 to 2300°C
- the furnace top exhaust gas temperature is preferably maintained at about 105°C or higher
- the molten iron temperature is preferably maintained at about 1520°C or higher.
- the upper limit value of the tuyere combustion temperature is an upper limit value assuming normal operation (operation without injection of hydrogen-based reducing gas or RBFG).
- the tuyere combustion temperature exceeds the upper limit value, it is preferable to take measures such as strengthening the cooling capacity of the tuyere equipment to prevent wear and tear on the tuyere equipment and using materials with higher heat resistance.
- the specifications of the blast furnace operation are determined so that the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within a specified range. As long as the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within the specified ranges, the blast furnace operation specifications can be freely designed. Also, although the tuyere combustion temperature may exceed the upper limit as a result of the design, it is preferable to take the above-mentioned measures separately.
- the blowing temperature of the hydrogen-based reducing gas (the temperature of the hydrogen-based reducing gas usually blown from the tuyere 11) is preferably about 600 to 1000°C, and the blowing amount of hydrogen gas in the hydrogen-based reducing gas is preferably about 400 to 600 Nm 3 /t. Both are in the range lower than that of Patent Document 1.
- the blowing temperature of the RBFG (the temperature of the RBFG blown from the shaft tuyere 12, i.e., the heating temperature by the heater 50) is preferably about 800 to 1000°C, and the blowing amount of the RBFG is preferably about 200 to 600 Nm 3 /t. This is because, as will be described later, in this case, Input ⁇ C exceeds 40%.
- the molten pig iron temperature can also be adjusted by the amount of pulverized coal injected into the blast furnace 10 or the coke ratio (the amount of coke used per ton of molten pig iron). For example, the molten pig iron temperature is first adjusted by the amount of pulverized coal injected, and if the molten pig iron temperature exceeds a predetermined range even when the amount of pulverized coal injected becomes zero, the coke ratio is adjusted.
- the molten pig iron temperature is a value that reflects the total heat (furnace heat) in the blast furnace 10.
- the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature are monitored periodically (preferably all the time), and if any of the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature falls outside the above-mentioned range, the operating conditions (for example, as described above, at least one of the hydrogen-based reducing gas blowing temperature, the amount of hydrogen gas blown in the hydrogen-based reducing gas, the RBFG blowing temperature, the RBFG blowing amount, the hot blast blowing amount, and the amount of oxygen contained in the hot blast (the amount of enriched oxygen gas blown)) can be adjusted.
- the operating conditions for example, as described above, at least one of the hydrogen-based reducing gas blowing temperature, the amount of hydrogen gas blown in the hydrogen-based reducing gas, the RBFG blowing temperature, the RBFG blowing amount, the hot blast blowing amount, and the amount of oxygen contained in the hot blast (the amount of enriched oxygen gas blown)
- the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature are prone to fluctuate when blowing hydrogen-based reducing gas or RBFG, it is preferable to monitor the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature when blowing these gases.
- the simulation model is the same as that of the first embodiment.
- the prerequisites for the simulation are as follows.
- ⁇ Hydrogen gas is used as the hydrogen-based reducing gas.
- the CO2 separation and capture device 20 separates and removes 100% of the CO2 gas and H2O gas contained in the top flue gas.
- the hydrogen gas injection temperature and RBFG injection temperature are 800°C for all levels. However, the hydrogen gas injection temperature for level 2-1 is 1200°C.
- the hot air blowing temperature (air supply temperature) is 1200°C for all levels.
- the amount of molten iron produced and the temperature of molten iron will be constant at all levels (12,350 t/d, 1,535°C).
- the top exhaust gas temperature shall be 135°C at all levels.
- Furnace heat adjustment is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted. The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
- Levels 2-2 to 2-4 correspond to the second embodiment.
- Level 2-1 Hydrogen gas blowing amount 650 Nm 3 /t, hot air blowing temperature 1200° C., no RBFG blowing (H2: 650 Nm 3 /t, BT 1200° C.).
- Level 2-2 Hydrogen gas injection amount 600 Nm 3 /t, hot air injection temperature 1200°C, RBFG injection operation (H2: 600 Nm 3 /t, BT 1200°C)
- Level 2-3 Hydrogen gas injection amount 500 Nm 3 /t, hot air injection temperature 1200°C, RBFG injection operation (H2: 500 Nm 3 /t, BT 1200°C)
- Level 2-4 Hydrogen gas injection amount 400 Nm 3 /t, hot air injection temperature 1200°C, RBFG injection operation (H2: 400 Nm 3 /t, BT 1200°C)
- the results are shown in Figures 4 and 5.
- the horizontal axis of Figure 4 shows the injection amount ( Nm3 /t) of RBFG injected from the shaft tuyere 12 into the shaft section 10b of the blast furnace 10, and the vertical axis shows Input ⁇ C (%).
- the horizontal axis of Figure 5 shows the injection amount ( Nm3 /t) of RBFG injected from the shaft tuyere 12 into the shaft section 10b of the blast furnace 10, and the vertical axis (total system hydrogen gas utilization rate) shows the hydrogen gas utilization rate (%) of the entire system.
- the method of calculating the hydrogen gas utilization rate of the entire system is as described above.
- the following findings can be obtained.
- the Input ⁇ C exceeds 40% (40.5%, the point surrounded by the dashed circle in Figure 4). This value is comparable to level 2-1, in which a large amount of hydrogen gas is injected, and levels 2-2 to 2-3, in which the hydrogen gas injection amount is slightly larger.
- the hydrogen gas injection amount in level 2-4 is 400 Nm 3 /t, which is smaller than levels 2-1 to 2-3, and the hydrogen gas injection temperature is also low at 800°C.
- the Input ⁇ C can be increased.
- Fig. 6 The inventors further studied the degree of freedom of operation. The results are shown in Fig. 6 and Fig. 7.
- the horizontal axis of Fig. 6 (shaft tuyere RBFG injection amount) indicates the injection amount (Nm 3 /t) of RBFG injected from the shaft tuyere 12 into the shaft section 10b of the blast furnace 10, and the vertical axis indicates the tuyere tip combustion temperature (°C).
- ⁇ C indicates Input ⁇ C.
- Fig. 6 a group of points where Input ⁇ C is 29% or more and less than 33%, a group where Input ⁇ C is 33% or more and less than 38%, and a group where Input ⁇ C is more than 40% are surrounded by dashed lines.
- the horizontal axis of Fig. 7 indicates the tuyere tip combustion temperature (°C), and the vertical axis indicates the furnace top exhaust gas temperature (°C).
- Figs. 6 and 7 also show, as a reference example, an example in which the blast temperature was 1300°C (BT 1300°C) and the hydrogen gas injection temperature was 1000°C in level 2-4.
- the following findings can be obtained.
- the tuyere combustion temperature increases.
- the top exhaust gas temperature depends greatly on the flow rate of gas supplied into the blast furnace, and the more the gas flow rate per pig iron output increases, the higher the top exhaust gas temperature.
- the tuyere combustion temperature depends greatly on the oxygen enrichment rate, which is the combustion condition at the tuyere, and the higher the oxygen enrichment rate, the higher the tuyere combustion temperature.
- increasing the oxygen enrichment rate reducing the amount of hot air blown and reducing the gas flow rate supplied from the tuyere, so if the oxygen enrichment rate is increased to increase the tuyere combustion temperature, the gas flow rate supplied into the furnace decreases and the top exhaust gas temperature decreases. Therefore, assuming that gas is normally blown from the tuyere 11, it is difficult to control the top exhaust gas temperature and the tuyere combustion temperature independently (because trying to move one of them will move the other in the opposite direction).
- gas at a temperature lower than the tuyere combustion temperature is supplied into the furnace, as in the first embodiment, but since RBFG is blown from the shaft 10b, not from the tuyere where the coke is burning (usually the end of the tuyere 11), the tuyere combustion temperature does not decrease even if the amount of RBFG blown is controlled. Therefore, it is possible to adjust the tuyere combustion temperature to an appropriate value by separately adjusting the oxygen enrichment rate at the tuyere while adjusting the furnace top exhaust gas temperature by increasing the amount of RBFG blown. This is one of the advantages of the second embodiment (the advantage is that gas is blown into a place other than the usual tuyere 11).
- the tuyere combustion temperature in level 2-4 is higher than those in levels 2-1 to 2-3.
- the tuyere combustion temperature in level 2-4 is sufficiently higher than the lower limit (2000°C).
- the furnace top exhaust gas temperature in level 2-4 is also sufficiently higher than the lower limit (105°C).
- the degree of freedom in operation is high (the range in which the operational parameters can be designed is wide). Note that if the Input ⁇ C of level 2-4 exceeds 40%, the tuyere tip combustion temperature will exceed the upper limit (2300°C) (point indicated by dashed circle A in Figure 6), but operation can be continued by taking the measures described above.
- the operation method of the blast furnace 10 according to the third embodiment is generally as follows. That is, iron-based raw materials and coke are alternately and layeredly charged into the blast furnace 10 from the top of the blast furnace 10, while heated hydrogen-based reducing gas is supplied from the hydrogen-based reducing gas supply system 2 to the normal tuyeres 11. Then, hot air, pulverized coal, enriched oxygen gas, and heated hydrogen-based reducing gas are blown into the blast furnace 10 from the normal tuyeres 11. Meanwhile, RBFG is blown into the blast furnace 10 from the normal tuyeres 11 and the shaft tuyeres 12.
- the hot air reacts with the pulverized coal blown in together with the hot air and the coke in the blast furnace 10 to generate high-temperature reducing gas (mainly CO gas in this case). That is, the hot air gasifies the coke and pulverized coal.
- the reducing gas rises inside the blast furnace 10 and reduces the iron-based raw materials while heating them.
- the hydrogen-based reducing gas and RBFG rise inside the blast furnace 10, heating and reducing the iron-based raw materials.
- the iron-based raw materials melt and drip inside the blast furnace 10 while being further reduced by coke.
- the iron-based raw materials are ultimately stored in the hearth as molten pig iron (pig iron) containing just under 5% by mass of carbon. The molten pig iron in the hearth is removed from the tap hole and used in the next steelmaking process.
- the CO2 separation and capture device 20 recovers the top flue gas and separates it into reducing gas (CO gas and hydrogen gas) and nitrogen gas (i.e., RBFG) and CO2 gas and H2O gas.
- the CO2 gas and H2O gas are discharged outside the system.
- RBFG is temporarily stored in the buffer tank 30.
- a desired amount of RBFG is introduced from the buffer tank 30 into the compressor 40.
- the remaining RBFG is discharged outside the system and used, for example, as a heat source in a steelworks.
- the RBFG is then pressurized by the compressor 40.
- the compressor 40 pressurizes the RBFG to, for example, the internal pressure of the blast furnace 10 (approximately 4.5 atmospheres).
- the pressurized RBFG is introduced into the heater 50.
- the RBFG is then heated by the heater 50.
- the heating temperature is set arbitrarily depending on the operating conditions of the blast furnace 10.
- the RBFG heated by the heater 50 is blown into the blast furnace 10 from the normal tuyere 11 and the shaft tuyere 12.
- the flowmeter 61 measures the flow rate of the RBFG blown into the blast furnace 10 from the normal tuyere 11.
- the flowmeter 62 measures the flow rate of the RBFG blown into the shaft 10b of the blast furnace 10 from the shaft tuyere 12.
- a specific example of the operating method is as described in the first embodiment.
- the tuyere combustion temperature is preferably maintained at about 2000 to 2300°C
- the furnace top exhaust gas temperature is preferably maintained at about 105°C or higher
- the molten iron temperature is preferably maintained at about 1520°C or higher.
- the upper limit value of the tuyere combustion temperature is an upper limit value assuming normal operation (operation without injection of hydrogen-based reducing gas or RBFG).
- the tuyere combustion temperature exceeds the upper limit value, it is preferable to take measures such as strengthening the cooling capacity of the tuyere equipment and using materials with higher heat resistance to prevent wear and tear on the tuyere equipment.
- the specifications of the blast furnace operation are determined so that the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within a specified range. As long as the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within the specified ranges, the blast furnace operation specifications can be freely designed. Also, although the tuyere combustion temperature may exceed the upper limit as a result of the design, it is preferable to take the above-mentioned measures separately.
- the blowing temperature of the hydrogen-based reducing gas (the temperature of the hydrogen-based reducing gas normally blown from the tuyere 11) is preferably about 800 to 1000°C, and the blowing amount of hydrogen gas in the hydrogen-based reducing gas is preferably about 300 to 600 Nm 3 /t. Both are in a range lower than that of Patent Document 1.
- the normal tuyere blowing temperature of the RBFG (the temperature of the RBFG normally blown from the tuyere 11, i.e., the heating temperature by the heater 50) is preferably about 800 to 1000°C, and the normal tuyere blowing amount of the RBFG is preferably about 100 to 300 Nm 3 /t.
- the shaft part tuyere blowing temperature of the RBFG (the temperature of the RBFG blown from the shaft part tuyere 12, i.e., the heating temperature by the heater 50) is preferably the same as the normal tuyere blowing temperature, and the shaft part tuyere blowing amount of the RBFG is preferably about 200 to 600 Nm 3 /t.
- the RBFG injection rate is preferably 600 Nm 3 /t or more in total of the normal tuyere injection rate and the shaft tuyere injection rate. This is because, as described later, in this case, the Input ⁇ C exceeds 40%.
- Other adjustable parameters include the hot air injection rate and the amount of oxygen contained in the hot air (oxygen injection rate).
- the molten pig iron temperature can also be adjusted by the amount of pulverized coal injected into the blast furnace 10 or the coke ratio (amount of coke used per ton of molten pig iron). For example, the molten pig iron temperature is first adjusted by the amount of pulverized coal injection, and if the molten pig iron temperature exceeds a predetermined range even when the amount of pulverized coal injection becomes zero, the coke ratio can be adjusted.
- the molten pig iron temperature is a value that reflects the total heat (furnace heat) in the blast furnace 10.
- the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature are monitored periodically (preferably all the time), and if any of the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature falls outside the above-mentioned range, the operating conditions (for example, as described above, at least one of the hydrogen-based reducing gas blowing temperature, the amount of hydrogen gas blown in the hydrogen-based reducing gas, the RBFG blowing temperature, the RBFG blowing amount, the hot blast blowing amount, and the amount of oxygen contained in the hot blast (the amount of enriched oxygen gas blown)) can be adjusted.
- the operating conditions for example, as described above, at least one of the hydrogen-based reducing gas blowing temperature, the amount of hydrogen gas blown in the hydrogen-based reducing gas, the RBFG blowing temperature, the RBFG blowing amount, the hot blast blowing amount, and the amount of oxygen contained in the hot blast (the amount of enriched oxygen gas blown)
- the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature are prone to fluctuate when blowing hydrogen-based reducing gas or RBFG, it is preferable to monitor the tuyere combustion temperature, the top exhaust gas temperature, and the hot metal temperature when blowing these gases.
- the simulation model is the same as that of the first embodiment.
- the prerequisites for the simulation are as follows. ⁇ Hydrogen gas is used as the hydrogen-based reducing gas.
- the CO2 separation and capture device 20 separates and removes 100% of the CO2 gas and H2O gas contained in the top flue gas.
- the hydrogen gas blowing temperature and the RBFG blowing temperature are set to 800°C.
- the hot air blowing temperature (air supply temperature) is 1200°C.
- the amount of molten iron produced and the temperature of the molten iron will be 12,350 t/d and 1,535°C.
- the top exhaust gas temperature is 132°C, and the tuyere combustion temperature is 2196°C.
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted. The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
- the hydrogen gas injection rate was 400 Nm3 /t
- the RBFG shaft tuyere injection rate was 400 Nm3 /t
- the normal tuyere injection rate was 200 Nm3 /t.
- the Input ⁇ C was 42.2%.
- the Input ⁇ C can be increased.
- Example 1 corresponds to the first embodiment
- Example 2 corresponds to the second embodiment
- Example 3 corresponds to the third embodiment.
- the CO2 separation and capture device 20 separates and removes 100% of the CO2 gas and H2O gas contained in the top flue gas.
- the amount of molten iron produced and the temperature of the molten iron will be 12,350 t/d and 1,535°C.
- the furnace top exhaust gas temperature is set near the lower limit (105°C) to maximize the carbon reduction effect.
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted.
- the amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites. Hydrogen gas was blown (blowing temperature 1000°C, blowing amount 325 Nm 3 /t), hot air blowing temperature 1300°C, RBFG blowing temperature 1000°C, blowing amount 600 Nm 3 /t
- Example 2> (2-1. Main specifications) Hydrogen gas was used as the hydrogen-based reducing gas.
- the CO2 separation and capture device 20 separates and removes 100% of the CO2 gas and H2O gas contained in the top flue gas.
- the hydrogen gas blowing temperature and the RBFG blowing temperature are 800°C.
- the hot air blowing temperature (air supply temperature) is 1200°C.
- the amount of molten iron produced and the temperature of the molten iron will be 12,350 t/d and 1,535°C.
- the top exhaust gas temperature is 135°C.
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected.
- Example 3> (3-1. Main specifications) ⁇ Hydrogen gas is used as the hydrogen-based reducing gas.
- the CO2 separation and capture device 20 separates and removes 100% of the CO2 gas and H2O gas contained in the top flue gas.
- the hydrogen gas blowing temperature and the RBFG blowing temperature are set to 800°C.
- the hot air blowing temperature (air supply temperature) is 1200°C.
- the amount of molten iron produced and the temperature of the molten iron will be 12,350 t/d and 1,535°C.
- the top exhaust gas temperature is 132°C, and the tuyere combustion temperature is 2196°C.
- - Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted. The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
- the hydrogen gas injection rate was 400 Nm 3 /t
- the RBFG shaft tuyere injection rate was 400 Nm 3 /t
- the normal tuyere injection rate was 200 Nm 3 /t.
- the Input ⁇ C can be increased.
- Blast furnace system 2 Hydrogen-based reducing gas supply system 10
- Blast furnace 10a Blast furnace body 10b Shaft section 11 Normal tuyere 12 Shaft section tuyere 20 CO2 separation and capture device 30
- Buffer tank 40 Compressor 50, 71 Heater 61, 62, 72 Flow meter 70 Hydrogen-based reducing gas tank
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
Abstract
Description
本発明は、高炉の操業方法に関する。
本願は、2023年6月21日に、日本に出願された特願2023-101584号に基づき優先権を主張し、その内容をここに援用する。
The present invention relates to a method for operating a blast furnace.
This application claims priority based on Japanese Patent Application No. 2023-101584, filed on June 21, 2023, the contents of which are incorporated herein by reference.
鉄鋼業においては、高炉法が銑鉄製造工程の主流を担っている。高炉法においては、高炉の炉頂から高炉用鉄系原料(酸化鉄を含む原料。主として、焼結鉱。以下、単に「鉄系原料」とも称する)及びコークスを高炉内に交互かつ層状に装入する一方で、ボッシュ部より下方にあたる高炉下部に設けられた羽口から熱風を高炉内に吹き込む。熱風は、熱風とともに吹き込まれる微粉炭、及び、高炉内のコークスと反応することで、高温の還元ガス(ここでは主としてCOガス)を発生させる。すなわち、熱風は、コークス及び微粉炭をガス化させる。還元ガスは、高炉内を上昇し、鉄系原料を加熱しながら還元する。鉄系原料は、高炉内を降下する一方で、還元ガスにより加熱及び還元される。その後、鉄系原料は溶融し、コークスによってさらに還元されながら高炉内を滴下する。鉄系原料は、最終的には炭素を5質量%弱含む溶銑(銑鉄)として炉床部に溜められる。炉床部の溶銑は、出銑口から取り出され、次の製鋼プロセスに供される。したがって、高炉法では、コークス及び微粉炭等の炭材を還元材として使用する。 In the steel industry, the blast furnace process is the mainstream of pig iron manufacturing processes. In the blast furnace process, ferrous raw materials (raw materials containing iron oxide, mainly sintered ore, hereafter also referred to simply as "ferrous raw materials") and coke are charged alternately and in layers into the blast furnace from the top of the furnace, while hot air is blown into the blast furnace from tuyere holes installed in the lower part of the blast furnace below the bosh. The hot air reacts with the pulverized coal blown in together with the hot air and the coke in the blast furnace to generate high-temperature reducing gas (mainly CO gas in this case). In other words, the hot air gasifies the coke and pulverized coal. The reducing gas rises in the blast furnace, heating and reducing the ferrous raw materials. The ferrous raw materials descend in the blast furnace, while being heated and reduced by the reducing gas. The ferrous raw materials then melt and drip into the blast furnace while being further reduced by the coke. The iron-based raw materials are eventually stored in the hearth as molten pig iron (pig iron) containing just under 5% by mass of carbon. The molten pig iron in the hearth is removed from the tap hole and used in the next steelmaking process. Therefore, in the blast furnace process, carbonaceous materials such as coke and pulverized coal are used as reducing agents.
ところで、近年、地球温暖化防止が叫ばれ、温室効果ガスの一つである二酸化炭素(CO2ガス)の排出量削減が社会問題になっている。上述したように、高炉法では、還元材として炭材を使用するので、大量のCO2ガスを発生する。したがって、鉄鋼業はCO2ガス排出量において主要な産業のひとつとなっており、その社会的要請に応えねばならない。具体的には、高炉操業での更なる還元材比(溶銑1トンあたりの還元材使用量)の削減が急務となっている。 Recently, the prevention of global warming has been called for, and the reduction of carbon dioxide ( CO2 gas) emissions, which is one of the greenhouse gases, has become a social issue. As described above, the blast furnace process uses carbonaceous materials as a reducing agent, which generates a large amount of CO2 gas. Therefore, the steel industry is one of the major industries in terms of CO2 gas emissions, and must respond to this social demand. Specifically, there is an urgent need to further reduce the reducing agent ratio (amount of reducing agent used per ton of molten iron) in blast furnace operation.
還元材は炉内で熱となって装入物を昇温させる役割と、炉内の鉄系原料を還元する役割があり、還元材比を低減させるためには炉内の還元効率を上げる必要がある。炉内の還元反応は様々な反応式で表記することができる。これらの還元反応のうち、コークスによる直接還元反応(反応式:FeO+C⇒Fe+CO)は大きな吸熱を伴う吸熱反応である。したがって、この反応を極力発生させないことが還元材比の低減において重要となる。この直接還元反応は高炉下部で生じる反応であるため、鉄系原料が炉下部に至るまでにCO、H2等の還元ガスで鉄系原料を十分に還元することができれば、直接還元反応の対象となる鉄系原料を減らすことができる。 The reducing agent has the role of raising the temperature of the charge by becoming heat in the furnace and the role of reducing the iron-based raw materials in the furnace, and in order to reduce the reducing agent ratio, it is necessary to increase the reduction efficiency in the furnace. The reduction reaction in the furnace can be expressed by various reaction formulas. Among these reduction reactions, the direct reduction reaction by coke (reaction formula: FeO + C ⇒ Fe + CO) is an endothermic reaction accompanied by a large heat absorption. Therefore, it is important to prevent this reaction from occurring as much as possible in reducing the reducing agent ratio. Since this direct reduction reaction occurs in the lower part of the blast furnace, if the iron-based raw materials can be sufficiently reduced by reducing gas such as CO and H2 before they reach the lower part of the furnace, the iron-based raw materials that are the subject of the direct reduction reaction can be reduced.
上記課題を解決するための従来技術として、例えば特許文献1に開示されるように、羽口から熱風と共に水素ガスを吹き込むことで、炉内の還元ガスポテンシャルを向上させる技術が知られている。この技術では、水素ガスを鉄系原料の還元ガスとして使用することで、還元材比を低減させる。
As a conventional technique for solving the above problems, for example, as disclosed in
特許文献1にも開示されているが、本発明者は、還元材比を低減するための指標となるパラメータとして、炭素消費原単位の削減割合(Input △C)というパラメータを定義した。「炭素消費原単位(Input C)」は、溶銑1トンを製造するのに要した炭素(すなわち溶銑1トンあたりの炭素消費量)である。「炭素消費原単位の削減割合Input △C」は、水素ガスを吹き込まない操業であるベース操業に対する炭素消費原単位の削減割合を意味する。単位kg/tでのベース操業のInput CをA、単位kg/tでのある操業時のInput CをBとすると、Input △Cは、以下の数式で示される。
Input △C=(A-B)/A×100(%)
炭素消費原単位の削減割合Input △Cが大きいほど、還元材比も削減され、ひいては、CO2排出量が削減される。
As disclosed in
Input △C=(AB)/A×100(%)
The larger the reduction rate Input ΔC of the carbon consumption intensity is, the more the reducing agent ratio is reduced, and thus the amount of CO 2 emissions is reduced.
本発明者が特許文献1に記載された技術を詳細に検討したところ、特許文献1に記載された技術によってInput △Cを高くしようとした場合、多量の水素ガスを高温に加熱して高炉に吹き込む必要があることが判明した。例えば、Input △Cを40%以上としようとした場合、水素ガスの吹込み量を650Nm3/t以上とし、かつ水素ガスの温度を1200℃以上とする必要があった。この場合、多量の水素ガスを準備する必要があることに加え、水素ガスを高温に加熱する加熱装置を準備し、さらに高炉設備を高温の水素ガスに耐えうる材料で構成する必要があった。
The inventors of the present invention have studied the technology described in
このように、特許文献1に開示された技術には、Input △Cを高くするために多大な手間を要するという問題があった。
As such, the technology disclosed in
そこで、本発明は、上記問題に鑑みてなされたものであり、本発明の目的とするところは、水素系還元ガス(水素系還元ガスの詳細は後述する)の吹込み量を減少させ、かつ水素系還元ガスの加熱温度を低下させた場合であっても、Input △Cを高くすることができる高炉の操業方法を提供することにある。 The present invention has been made in consideration of the above problems, and the object of the present invention is to provide a method of operating a blast furnace that can increase Input △C even when the amount of hydrogen-based reducing gas (details of hydrogen-based reducing gas will be described later) injected is reduced and the heating temperature of the hydrogen-based reducing gas is lowered.
本発明者は、特許文献1に記載された技術を詳細に検討したところ、高炉の操業中に多量の水素ガスが炉頂排ガスとして排出されることが判明した。そこで、本発明者は、炉頂排ガスから還元ガス(この還元ガスには、水素ガス及びCOガスが含まれる)を分離し、分離した還元ガスを高炉に吹き込むことを試みた。この結果、特許文献1に記載された技術よりも水素ガスの吹込み量を減少させ、かつ水素ガスの加熱温度を低下させた場合であっても、特許文献1に記載された技術と同程度のInput △Cが得られることが判明した。本発明は、当該知見に基づいてなされたものである。
The inventors have studied the technology described in
本発明の要旨は以下である。
(1)高炉系外から供給される水素系還元ガスを加熱する工程と、
加熱された前記水素系還元ガスを高炉に吹き込む工程と、
炉頂排ガスから還元ガスを分離する工程と、
分離した前記還元ガスを加熱する工程と、
前記還元ガスを前記高炉に吹き込む工程と、を含むことを特徴とする、高炉の操業方法。
(2)前記還元ガスを前記高炉の下部に設けられた通常羽口から前記高炉に吹き込むことを特徴とする、(1)に記載の高炉の操業方法。
(3)前記還元ガスを前記高炉のシャフト部に吹き込むことを特徴とする、(1)または(2)に記載の高炉の操業方法。
(4)羽口先燃焼温度及び炉頂排ガス温度に基づいて、操業条件を調整することを特徴とする、(1)~(3)の何れか1項に記載の高炉の操業方法。
(5)前記操業条件には、前記還元ガスの吹込み量、熱風の送風量、及び前記熱風に含まれる酸素量が含まれることを特徴とする、(4)に記載の高炉の操業方法。
(6)高炉系外から供給される水素系還元ガスを加熱する工程と、
加熱された前記水素系還元ガスを通常羽口及び、少なくとも前記通常羽口よりも高い位置に設けられたシャフト部羽口のうち少なくとも一方から高炉に吹き込む工程と、
炉頂排ガスから還元ガスを分離する工程と、
分離した前記還元ガスを加熱する工程と、
加熱された前記還元ガスを前記通常羽口及び前記シャフト部羽口のうち少なくとも一方から高炉に吹き込む工程と、
を含み、
加熱された前記水素系還元ガスを前記通常羽口及び前記シャフト部羽口のうち少なくとも一方から高炉に吹き込む際、及び加熱された前記還元ガスを前記通常羽口及び前記シャフト部羽口のうち少なくとも一方から高炉に吹き込む際のうち、少なくとも一方のタイミングで、羽口先燃焼温度及び炉頂排ガス温度に基づいて、前記還元ガスの吹込み量、熱風の送風量、及び前記熱風に含まれる酸素量のうち、少なくとも1種以上の操業条件を調整することを特徴とする、(1)~(5)の何れか1項に記載の高炉の操業方法。
(7)前記還元ガスは前記炉頂排ガスから分離したCOガスと、水素ガスとを含むことを特徴とする、(1)~(6)に記載の高炉の操業方法。
The gist of the present invention is as follows.
(1) a step of heating a hydrogen-based reducing gas supplied from outside a blast furnace system;
injecting the heated hydrogen-based reducing gas into a blast furnace;
separating the reducing gas from the top exhaust gas;
heating the separated reducing gas;
and injecting the reducing gas into the blast furnace.
(2) The method for operating a blast furnace according to (1), characterized in that the reducing gas is injected into the blast furnace from a normal tuyere provided in a lower part of the blast furnace.
(3) The method for operating a blast furnace according to (1) or (2), characterized in that the reducing gas is injected into a shaft portion of the blast furnace.
(4) A method for operating a blast furnace according to any one of (1) to (3), characterized in that the operating conditions are adjusted based on the tuyere combustion temperature and the furnace top exhaust gas temperature.
(5) The method for operating a blast furnace according to (4), characterized in that the operating conditions include the amount of reducing gas blown, the amount of hot air blown, and the amount of oxygen contained in the hot air.
(6) heating a hydrogen-based reducing gas supplied from outside the blast furnace;
Injecting the heated hydrogen-based reducing gas into the blast furnace from at least one of a normal tuyere and a shaft tuyere provided at a position higher than the normal tuyere;
separating the reducing gas from the top exhaust gas;
heating the separated reducing gas;
Injecting the heated reducing gas into a blast furnace from at least one of the normal tuyere and the shaft tuyere;
Including,
The method for operating a blast furnace according to any one of (1) to (5), characterized in that at least one of the operating conditions, among the amount of the reducing gas injected, the amount of hot air blown, and the amount of oxygen contained in the hot air, is adjusted based on the tuyere tip combustion temperature and the furnace top exhaust gas temperature at at least one of the timings when the heated hydrogen-based reducing gas is injected into the blast furnace from at least one of the normal tuyere and the shaft tuyere and when the heated reducing gas is injected into the blast furnace from at least one of the normal tuyere and the shaft tuyere.
(7) The method for operating a blast furnace according to any one of (1) to (6), characterized in that the reducing gas contains CO gas separated from the top exhaust gas and hydrogen gas.
本発明によれば、水素系還元ガスの吹込み量を減少させ、かつ水素系還元ガスの加熱温度を低下させた場合であっても、Input △Cを高くすることができる。 According to the present invention, the Input △C can be increased even if the amount of hydrogen-based reducing gas injected is reduced and the heating temperature of the hydrogen-based reducing gas is lowered.
以下に添付図面を参照しながら、本発明の好適な実施の形態について詳細に説明する。本明細書及び図面において、実質的に同一の機能構成を有する構成要素については、同一の符号を付することにより重複説明を省略する。 Below, a preferred embodiment of the present invention will be described in detail with reference to the attached drawings. In this specification and drawings, components having substantially the same functional configuration are designated by the same reference numerals to avoid redundant description.
<1.高炉システムの全体構成>
まず、図1に基づいて、本実施形態に係る高炉システム1及び高炉システム1に接続されている水素系還元ガス供給システム2の全体構成について説明する。高炉システム1は、高炉10と、CO2分離回収装置20と、バッファータンク30と、コンプレッサー40と、加熱器50と、流量計61、62とを備える。
<1. Overall configuration of the blast furnace system>
First, with reference to Fig. 1, a description will be given of the overall configuration of a
高炉10は、高炉本体10aと、通常羽口11と、シャフト部羽口12とを備える。高炉本体10aの内部では、高炉法による鉄系原料の還元反応が生じる。具体的には、高炉10の炉頂から鉄系原料及びコークスを高炉10内に交互かつ層状に装入する一方で、通常羽口11から熱風、微粉炭、及び富化酸素ガスを高炉10内に吹き込む。なお、以下の説明において、「羽口先燃焼温度」は、通常羽口11のガス噴出口における温度を意味するものとする。熱風は、熱風とともに吹き込まれる微粉炭、及び、高炉10内のコークスと反応することで、高温の還元ガス(ここでは主としてCOガス)を発生させる。すなわち、熱風は、コークス及び微粉炭をガス化させる。なお、詳細は後述するが、微粉炭が高炉10内に吹き込まれない場合もある。還元ガスは、高炉10内を上昇し、鉄系原料を加熱しながら還元する。鉄系原料は、高炉10内を降下する一方で、還元ガスにより加熱及び還元される。その後、鉄系原料は溶融し、コークスによってさらに還元されながら高炉10内を滴下する。鉄系原料は、最終的には炭素を5質量%弱含む溶銑(銑鉄)として炉床部に溜められる。炉床部の溶銑は、出銑口から取り出され、次の製鋼プロセスに供される。
The
通常羽口11は、高炉10のボッシュ部より下方に設けられ、上述した熱風の他、後述するように、加熱された水素系還元ガス、及び炉頂排ガス(高炉排ガス)から分離された還元ガスを高炉10内に吹き込む。なお、図1では高炉10の左右二個所に通常羽口11が描かれているが、高炉10の全周に亘って三つ以上所定ピッチで離間して取り付けられてもよい。
The
シャフト部羽口12は、高炉10の通常羽口11よりも高い位置に設けられ、炉頂排ガスから分離された還元ガスを高炉10のシャフト部10bに吹き込む。なお、図1ではシャフト部10bの左右二個所にシャフト部羽口12が描かれているが、高炉10の全周に亘って三つ以上所定ピッチで離間して取り付けられてもよい。また、図1ではシャフト部羽口12は、シャフト部10bに描かれているが、炉頂排ガスから分離された還元ガスをシャフト部10bに吹き込むことができ、且つ、通常羽口11の設置位置より高い位置であれば、シャフト部10bより低い位置である、ベリー部、ボッシュ部又はそれらより低い位置に取り付けられていてもよい。
The
CO2分離回収装置20は、炉頂排ガスを回収し、還元ガス(COガス及び水素ガス)及び窒素ガスと、CO2ガス及びH2Oガスとに分離する装置である。分離の方法は特に制限されないが、例えば化学吸着法及び物理吸着法(PSA)等が挙げられる。以下の説明において、炉頂排ガスから分離された還元ガス及び窒素ガスをRBFG(Returned Blast Furnace Gas)とも称する。CO2ガス及びH2Oガスは系外に排出される。なお、CO2分離回収装置20は、必ずしも炉頂排ガスの全量を回収しなくてもよい。例えば、CO2分離回収装置20は、高炉に吹き込むRBFGの流量に応じた分だけの炉頂排ガスを回収するようにしてもよい。
The CO2 separation and
バッファータンク30は、RBFGを一時的に貯留するタンクである。バッファータンク30から所望量のRBFGがコンプレッサー40に導入される。残りのRBFGは例えば製鉄所の熱源として使用される。
The
コンプレッサー40は、RBFGを加圧する。ここで、コンプレッサー40は、例えば高炉10の内圧(4.5気圧程度)程度までRBFGを加圧する。加圧されたRBFGは加熱器50に導入される。
The
加熱器50は、RBFGを加熱する。加熱温度は高炉10の操業条件に応じて任意に設定されるが、例えばRBFGをシャフト部羽口12から高炉10のシャフト部10bに吹き込む場合、800℃以上に設定されることが好ましい。加熱器50は電気ヒーター等で十分実現可能である。加熱器50で加熱されたRBFGは、例えば通常羽口11から高炉10内に吹き込まれるか、または、シャフト部羽口12から高炉10のシャフト部10bに吹き込まれる。図1では左側の通常羽口11及びシャフト部羽口12からRBFGを高炉10内に吹き込んでいるが、右側の通常羽口11及びシャフト部羽口12からもRBFGを高炉10内に吹き込んでもよい。RBFGは、通常羽口11及びシャフト部羽口12の双方から高炉10内に吹き込まれてもよい。
The
流量計61は、通常羽口11から高炉10内に吹き込まれるRBFGの流量を測定する。流量計62は、シャフト部羽口12から高炉10のシャフト部10bに吹き込まれるRBFGの流量を測定する。本実施形態では、バッファータンク30からコンプレッサー40に導入されるRBFGの流量を調整することで、通常羽口11から高炉10内に吹き込まれるRBFGの流量、及びシャフト部羽口12から高炉10のシャフト部10bに吹き込まれるRBFGの流量を任意に調整可能である。
The
水素系還元ガス供給システム2は水素系還元ガスタンク70と、加熱器71と、流量計72とを備える。水素系還元ガス供給システム2は、高炉システム1の系外から高炉システム1に水素系還元ガスを供給するシステムである。
The hydrogen-based reducing
水素系還元ガスタンク70は、水素系還元ガスを貯留するタンクである。ここで、水素系還元ガスは、水素ガスの他、水素ガスと(本実施形態の効果を損なわない)他のガス(例えば窒素ガス)との混合ガスを含む概念である。加熱器71は、水素系還元ガスタンク70から供給される水素系還元ガスを加熱する。加熱器71は電気ヒーター等で十分実現可能である。加熱器71は、通常羽口11と接続されており、加熱された水素系還元ガスは、通常羽口11から高炉10内に吹き込まれる。加熱器71は加熱器50と併用してもよい。流量計72は、通常羽口11から高炉10内に吹き込まれる水素系還元ガスの流量を測定する。また、後述するように、水素系還元ガスの吹込み量を減少させ、かつ水素系還元ガスの加熱温度を低下させた場合であっても、Input △Cを高くすることができる。また、本実施形態では、水素系還元ガスを通常羽口11から吹き込むこととしたが、シャフト部羽口12から水素系還元ガスを高炉10内に吹き込んでもよい。
The hydrogen-based reducing
<2.第1の実施形態>
(2-1.第1の実施形態に係る高炉の操業方法)
次に、本発明の第1の実施形態について説明する。第1の実施形態では、RBFGは通常羽口11から高炉10内に吹き込まれる。第1の実施形態では、シャフト部羽口12及び流量計62は省略されてもよい。
2. First embodiment
(2-1. Blast furnace operation method according to the first embodiment)
Next, a first embodiment of the present invention will be described. In the first embodiment, the RBFG is normally injected into the
第1の実施形態に係る高炉10の操業方法は概ね以下の通りである。すなわち、高炉10の炉頂から鉄系原料及びコークスを高炉10内に交互かつ層状に装入する一方で、水素系還元ガス供給システム2から加熱された水素系還元ガスを通常羽口11に供給する。そして、通常羽口11から熱風、微粉炭、富化酸素ガス、加熱された水素系還元ガス、及び加熱されたCOおよびH2を含むRBFGを高炉10内に吹き込む。熱風は、熱風とともに吹き込まれる微粉炭、及び、高炉10内のコークスと反応することで、高温の還元ガス(ここでは主としてCOガス)を発生させる。すなわち、熱風は、コークス及び微粉炭をガス化させる。還元ガスは、高炉10内を上昇し、鉄系原料を加熱しながら還元する。水素系還元ガス及びRBFGは、高炉10内を上昇し、鉄系原料を加熱しながら還元する。鉄系原料は、高炉10内を降下する一方で、還元ガス、水素系還元ガス、及びRBFGにより加熱及び還元される。その後、鉄系原料は溶融し、コークスによってさらに還元されながら高炉10内を滴下する。鉄系原料は、最終的には炭素を5質量%弱含む溶銑(銑鉄)として炉床部に溜められる。炉床部の溶銑は、出銑口から取り出され、次の製鋼プロセスに供される。
The operation method of the
一方、高炉10の炉頂排ガスが排出される。CO2分離回収装置20は、炉頂排ガスを回収し、還元ガス(COガス及び水素ガス)及び窒素ガス(すなわち、RBFG)と、CO2ガス及びH2Oガスとに分離する。CO2ガス及びH2Oガスは系外に排出される。
Meanwhile, the top flue gas of the
RBFGは、バッファータンク30に一時的に貯留される。バッファータンク30から所望量のRBFGがコンプレッサー40に導入される。残りのRBFGは系外に排出され、例えば製鉄所の熱源として使用される。
RBFG is temporarily stored in the
ついで、RBFGは、コンプレッサー40により加圧される。ここで、コンプレッサー40は、例えば高炉10の内圧(4.5気圧程度)程度までRBFGを加圧する。加圧されたRBFGは加熱器50に導入される。
The RBFG is then pressurized by the
ついで、RBFGは、加熱器50により加熱される。加熱温度は高炉10の操業条件に応じて任意に設定される。加熱器50で加熱されたRBFGは、通常羽口11から高炉10内に吹き込まれる。流量計61は、通常羽口11から高炉10内に吹き込まれるRBFGの流量を測定する。RBFGは、主に通常羽口11から高炉10内に吹き込まれるが、シャフト部羽口12から補助的に高炉10内に吹き込まれてもよい。詳細は後述する。
The RBFG is then heated by the
ここで、高炉操業においては、安定した操業を行う等の理由により、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度を所定範囲内に維持することが好ましい。例えば、羽口先燃焼温度は2000~2300℃程度に維持されることが好ましく、炉頂排ガス温度は、105℃程度以上に維持されることが好ましく、溶銑温度は1520℃程度以上に維持されることが好ましい。なお、羽口先燃焼温度の上限値は通常操業(水素系還元ガスの吹き込み、RBFGの吹き込みを行わない操業)を想定した上限値である。羽口先燃焼温度が上限値を超える場合には、羽口設備の損耗を防ぐために羽口設備の冷却能力を強化する、より耐熱性能の高い材料を使用する、等の対策を行うことが好ましい。高炉操業の諸元は、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が所定範囲内に維持されるように決定されることが好ましい。なお、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が所定範囲内に維持される限り、高炉操業の諸元を自由に設計することができる。また、設計の結果、羽口先燃焼温度が上限値を超えてもよいが、上述した対策を別途行うことが好ましい。 Here, in blast furnace operation, it is preferable to maintain the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature within a specified range for reasons such as stable operation. For example, the tuyere combustion temperature is preferably maintained at about 2000 to 2300°C, the furnace top exhaust gas temperature is preferably maintained at about 105°C or higher, and the molten iron temperature is preferably maintained at about 1520°C or higher. The upper limit value of the tuyere combustion temperature is an upper limit value assuming normal operation (operation without injection of hydrogen-based reducing gas or RBFG). If the tuyere combustion temperature exceeds the upper limit value, it is preferable to take measures such as strengthening the cooling capacity of the tuyere equipment to prevent wear and tear on the tuyere equipment and using materials with higher heat resistance. It is preferable to determine the specifications of the blast furnace operation so that the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within a specified range. As long as the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within the specified ranges, the blast furnace operation specifications can be freely designed. Also, although the tuyere combustion temperature may exceed the upper limit as a result of the design, it is preferable to take the above-mentioned measures separately.
例えば、水素系還元ガスの吹込み温度(通常羽口11から吹き込まれる水素系還元ガスの温度)は800~1000℃程度とすることが好ましく、水素系還元ガス中の水素ガスの吹込み量は300~600Nm3/t程度とすることが好ましい。いずれも特許文献1よりも低い範囲になる。RBFGの吹込み温度(通常羽口11から吹き込まれるRBFGの温度、すなわち加熱器50による加熱温度)は800~1000℃程度とすることが好ましく、RBFGの吹込み量は400~800Nm3/t程度とすることが好ましい。特に、RBFGの吹込み量は、600Nm3/t以上であることが好ましい。後述するように、この場合、Input △Cが40%を超えるからである。他に調整可能な諸元として、熱風の吹込み量、熱風に含まれる酸素量(酸素の吹込み量)等が挙げられる。また、溶銑温度は、高炉10に吹き込む微粉炭の吹込み量またはコークス比(溶銑1トンあたりに使用するコークス量)によっても調整することができる。たとえば、まず微粉炭の吹込み量で溶銑温度を調整し、微粉炭の吹込み量がゼロになっても溶銑温度が所定範囲を超える場合には、コークス比を調整するといった制御が可能である。なお、溶銑温度は高炉10内の総熱量(炉熱)を反映した値になる。なお、高炉操業中には、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度を定期的に(好ましくは常時)モニタリングし、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度の何れかが上述した範囲外の値となった場合には、操業条件(例えば上述したように水素系還元ガスの吹込み温度、水素系還元ガス中の水素ガスの吹込み量、RBFGの吹込み温度、RBFGの吹込み量、熱風の吹込み量、及び熱風に含まれる酸素量(富化酸素ガスの吹込み量)のうち少なくとも1種以上)を調整すればよい。なお、水素系還元ガスまたはRBFGの吹込みの際に羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が変動しやすいので、これらのガスの吹込みの際には、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度をモニタリングすることが好ましい。
For example, the blowing temperature of the hydrogen-based reducing gas (the temperature of the hydrogen-based reducing gas usually blown from the tuyere 11) is preferably about 800 to 1000°C, and the blowing amount of hydrogen gas in the hydrogen-based reducing gas is preferably about 300 to 600 Nm 3 /t. Both are in a range lower than that of
(2-2.操業方法の具体例)
以下、操業方法の具体例についていくつか説明する。なお、以下に列挙する具体例は、後述する第2の実施形態にも適用可能である。
(2-2. Specific examples of operation methods)
Some specific examples of the operation method will be described below. Note that the specific examples listed below are also applicable to the second embodiment described later.
(2-2-1.溶銑温度が低下した場合)
通常羽口11から高炉10内に吹き込むRBFGの吹込み量を増加させる。同時に富化酸素ガスの吹込み量を増加させ、熱風の吹込み量(送風量)を低下させて羽口先燃焼温度を維持する。また、これにより、炉頂排ガス温度が所定範囲を下回った場合は、更にシャフト部羽口12から吹き込むRBFGの吹込み量を増加させる。
(2-2-1. When the molten iron temperature drops)
The amount of RBFG blown into the
(2-2-2.羽口先燃焼温度が低下した場合)
富化酸素ガスの吹込み量を増加させ、熱風の吹込み量を低下させて羽口先燃焼温度を上昇させる。これにより、ボッシュガス量が低下して炉頂排ガス温度が所定範囲を下回る懸念が生じるが、その際は、同時にシャフト部羽口12から吹き込むRBFGの吹込み量を増加させて対応する。
(2-2-2. When the tuyere combustion temperature drops)
The amount of oxygen-enriched gas injected is increased and the amount of hot air injected is decreased to raise the tuyere combustion temperature. This may cause a concern that the amount of bosh gas will decrease and the top exhaust gas temperature will fall below a specified range, but in that case, the amount of RBFG injected from the
(2-2-3.炉頂排ガス温度が低下した場合)
シャフト部羽口12から吹き込むRBFGの吹込み量を増加させる。
(2-2-3. When the top exhaust gas temperature drops)
The amount of RBFG blown from the
(2-2-4.羽口先燃焼温度、炉頂排ガス温度の両方が低下した場合)
富化酸素ガスの吹込み量を増加させ、熱風の吹込み量を低下させて羽口先燃焼温度を上昇させつつ、同時にシャフト部羽口12から吹き込むRBFGの吹込み量を増加させる。
(2-2-4. When both the tuyere combustion temperature and the top exhaust gas temperature drop)
The amount of oxygen-enriched gas blown is increased and the amount of hot air blown is decreased to raise the tuyere tip combustion temperature, while at the same time increasing the amount of RBFG blown from the
(2-2-5.羽口先燃焼温度が低下し、炉頂排ガス温度が上昇した場合)
炉頂排ガス温度が高すぎると、炉内ガス流速が上がって操業変動を引き起こす可能性が高まるため、過度な炉頂排ガス温度の上昇は好ましくない。
富化酸素ガスの吹込み量を増加させ、熱風の吹込み量を低下させる。これによって羽口先燃焼温度は上昇傾向、炉頂排ガス温度は低下傾向となる。炉頂排ガス温度が所定範囲を下回った場合は、同時にシャフト部羽口12から吹き込むRBFGの吹込み量を増加させて炉頂排ガス温度を制御する。
(2-2-5. When the tuyere combustion temperature drops and the top exhaust gas temperature rises)
If the top exhaust gas temperature is too high, the gas flow rate in the furnace increases, which increases the possibility of causing operational fluctuations. Therefore, an excessive increase in the top exhaust gas temperature is undesirable.
The amount of oxygen-enriched gas blown in is increased and the amount of hot air blown in is decreased. This causes the combustion temperature at the tuyere tip to tend to rise and the top exhaust gas temperature to tend to fall. If the top exhaust gas temperature falls below a specified range, the amount of RBFG blown in from the
(2-2-6.羽口先燃焼温度が上昇し、炉頂排ガス温度が低下した場合)
富化酸素ガスの吹込み量を低下させ、熱風の吹込み量を増加させる。これによって羽口先燃焼温度は低下し、炉頂排ガス温度は上昇傾向となる。炉頂排ガス温度が所定範囲を上回った場合は、同時にシャフト部羽口12から吹き込むRBFGの吹込み量を低下させて炉頂排ガス温度を制御する。
(2-2-6. When the tuyere combustion temperature rises and the top exhaust gas temperature falls)
The amount of oxygen-enriched gas blown in is reduced and the amount of hot air blown in is increased. This reduces the combustion temperature at the tuyere tip and increases the top exhaust gas temperature. When the top exhaust gas temperature exceeds a predetermined range, the amount of RBFG blown in from the
(2-2-7.羽口先燃焼温度、炉頂排ガス温度の両方が上昇した場合)
富化酸素ガスの吹込み量を低下させ、熱風の吹込み量を増加させ、シャフト部羽口12から吹き込むRBFGの吹込み量を低下させる。
(2-2-7. When both the tuyere combustion temperature and the top exhaust gas temperature rise)
The amount of enriched oxygen gas blown is reduced, the amount of hot air blown is increased, and the amount of RBFG blown from the
(2-3.効果の検証)
つぎに、本発明者が行った効果の検証について説明する。本検証では、高炉操業のシミュレーションを行い、第1の実施形態に係る高炉の操業方法の効果を検証した。シミュレーションモデルは、Kouji TAKATANI、Takanobu INADA、Yutaka UJISAWA、「Three-dimensional Dynamic Simulator for Blast Furnace」、ISIJ International、Vol.39(1999)、No.1、p.15-22などに示される、所謂「高炉数学モデル」を用いた。この高炉数学モデルは、概略的には、高炉の内部領域を高さ方向、径方向、周方向に分割することで複数のメッシュ(小領域)を規定し、各メッシュの挙動をシミュレーションするものである。シミュレーションの前提条件は以下である。
・水素系還元ガスとして水素ガスを用いる。
・CO2分離回収装置20は、炉頂排ガスに含まれるCO2ガス及びH2Oガスを100%分離除去する。
・出銑量、溶銑温度は全水準で一定(12350t/d、1535℃)とする。
・炉頂排ガス温度は、下限値近傍(105℃)とする。
・炉熱調整(溶銑温度の調整)は、微粉炭の吹込み量を調整することで行う。微粉炭の吹込み量がゼロになっても溶銑温度が1535℃を超える場合には、コークス比を調整する。
・熱風の吹込み量、酸素の吹込み量は、上記前提条件が満たされるように調整した。
(2-3. Verification of Effects)
Next, the verification of the effects performed by the present inventor will be described. In this verification, a simulation of blast furnace operation was performed to verify the effects of the blast furnace operation method according to the first embodiment. The simulation model used was a so-called "blast furnace mathematical model" shown in Kouji TAKATANI, Takanobu INADA, Yutaka UJISAWA, "Three-dimensional Dynamic Simulator for Blast Furnace", ISIJ International, Vol. 39 (1999), No. 1, p. 15-22, etc. This blast furnace mathematical model is, in outline, a plurality of meshes (small regions) defined by dividing the internal region of the blast furnace in the height direction, radial direction, and circumferential direction, and the behavior of each mesh is simulated. The prerequisites for the simulation are as follows.
・Hydrogen gas is used as the hydrogen-based reducing gas.
The CO2 separation and
- The amount of molten iron produced and the temperature of molten iron will be constant at all levels (12,350 t/d, 1,535°C).
The top exhaust gas temperature is set near the lower limit (105°C).
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted.
The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
上記の前提条件の下、以下の各水準についてシミュレーションを行った。水準1-5が第1の実施形態に対応する。
(水準1-1)水素ガス吹込みなし、熱風の吹込み温度が1200℃、RBFG吹込み操業(吹込み温度が1200℃)(図2、3中H2-0 BT1200℃。なお、H2-0 BT1200℃は、水素ガス吹込みなし、熱風の吹込み温度が1200℃であることを示す。)
(水準1-2)水素ガス吹込みあり(吹込み温度が1200℃、吹込み量650Nm3/t)、熱風の吹込み温度が1200℃、RBFG吹込み操業(吹込み温度が1000℃)(図2、3中H2-650 1200℃、BT1200℃。なお、H2-650 1200℃は、水素ガスの吹込み量が650Nm3/t、吹込み温度が1200℃であることを示し、BT1200℃は熱風の吹込み温度が1200℃であることを示す。)
(水準1-3)水素ガス吹込みあり(吹込み温度が1000℃、吹込み量650Nm3/t)、熱風の吹込み温度が1200℃、RBFG吹込み操業(吹込み温度が1000℃)(図2、3中H2-650 1000℃、BT1200℃。なお、H2-650 1000℃は、水素ガスの吹込み量が650Nm3/t、吹込み温度が1000℃であることを示し、BT1200℃は熱風の吹込み温度が1200℃であることを示す。)
(水準1-4)水素ガス吹込みあり(吹込み温度が1000℃、吹込み量650Nm3/t)、熱風の吹込み温度が1300℃、RBFG吹込み操業(吹込み温度が1000℃)(図2、3中H2-650 1000℃、BT1300℃。なお、H2-650 1000℃は、水素ガスの吹込み量が650Nm3/t、吹込み温度が1000℃であることを示し、BT1300℃は熱風の吹込み温度が1300℃であることを示す。)
(水準1-5)水素ガス吹込みあり(吹込み温度1000℃、吹込み量325Nm3/t)、熱風の吹込み温度が1300℃、RBFG吹込み操業(吹込み温度が1000℃)(図2、3中H2-325 1000℃、BT1300℃。なお、H2-325 1000℃は、水素ガスの吹込み量が325Nm3/t、吹込み温度が1000℃であることを示し、BT1300℃は熱風の吹込み温度が1300℃であることを示す。)
Under the above preconditions, a simulation was performed for each of the following levels:
(Level 1-1) No hydrogen gas blowing, hot air blowing temperature of 1200°C, RBFG blowing operation (blow temperature of 1200°C) (H2-0 BT1200°C in Figures 2 and 3. H2-0 BT1200°C indicates that no hydrogen gas blowing and hot air blowing temperature of 1200°C.)
(Level 1-2) With hydrogen gas blowing (blowing temperature 1200°C, blowing rate 650 Nm 3 /t), hot air blowing temperature 1200°C, RBFG blowing operation (blowing
(Level 1-3) With hydrogen gas blowing (blowing
(Level 1-4) With hydrogen gas blowing (blowing
(Level 1-5) With hydrogen gas blowing (blowing
結果を図2及び図3に示す。図2の横軸(RBFG羽口吹込み量)は通常羽口11から高炉10内に吹き込まれるRBFGの吹込み量(Nm3/t)を示し、縦軸はInput △C(%)を示す。図3の横軸(RBFG羽口吹込み量)は通常羽口11から高炉10内に吹き込まれるRBFGの吹込み量(Nm3/t)を示し、縦軸(系全体水素ガス利用率)は系全体の水素ガスの利用率(%)を示す。ここで、系全体の水素ガスの利用率は、以下の数式で示される。
nH2
*=100×a/(a+b)
nH2
*:水素ガスの利用率(%)
a:CO2分離回収装置20から系外に排出されるH2Oガスの量(Nm3/t)
b:バッファータンク30から系外に排出される水素ガスの量(Nm3/t)
The results are shown in Figures 2 and 3. The horizontal axis of Figure 2 (RBFG tuyere injection amount) indicates the amount of RBFG injected into the
n H2 * =100×a/(a+b)
nH2 * : Hydrogen gas utilization rate (%)
a: Amount of H 2 O gas discharged from the CO 2 separation and
b: Amount of hydrogen gas discharged from the
図2及び図3によれば、以下の知見が得られる。
・水素系還元ガス供給システム2からの(すなわち、RBFGに含まれるものではない)水素ガスの吹込み量が多くなる程、Input △Cが大きくなる。しかし、多量の水素ガスを用意する必要があるため、上述した問題が生じる。
・RBFGの吹込み量が多くなる程、Input △Cが大きくなる。水準1-5では、RBFGの吹込み量を600Nm3/tとすることで、Input △Cが40%を超える(43.2%、図2中の破線円で囲んだ点)。この値は、水素ガスを大量に吹き込む水準1-2~1-4に匹敵するものである。さらに、水準1-5の水素ガスの吹込み量は325Nm3/tと水準1-2~1-4に比べて50%少なく、水素ガスの吹込み温度も1000℃と低い。なお、このときの水準1-5の水素ガスの利用率は77%(a=253Nm3/t、b=76Nm3/t)となる(図3中の破線円で囲んだ点)。
According to FIG. 2 and FIG. 3, the following findings can be obtained.
The more hydrogen gas (i.e., not contained in the RBFG) is blown in from the hydrogen-based reducing
The larger the RBFG injection amount, the larger the Input ΔC becomes. In level 1-5, by setting the RBFG injection amount to 600 Nm 3 /t, the Input ΔC exceeds 40% (43.2%, the point surrounded by the dashed circle in Figure 2). This value is comparable to levels 1-2 to 1-4, in which a large amount of hydrogen gas is injected. Furthermore, the injection amount of hydrogen gas in level 1-5 is 325 Nm 3 /t, which is 50% less than levels 1-2 to 1-4, and the injection temperature of hydrogen gas is also low at 1000°C. The hydrogen gas utilization rate in level 1-5 at this time is 77% (a = 253 Nm 3 /t, b = 76 Nm 3 /t) (the point surrounded by the dashed circle in Figure 3).
以上により、第1の実施形態によれば、水素系還元ガス供給システム2からの水素系還元ガスの吹込み量を減少させ、かつ水素系還元ガスの加熱温度を低下させた場合であっても、Input △Cを高くすることができる。
As described above, according to the first embodiment, even if the amount of hydrogen-based reducing gas injected from the hydrogen-based reducing
<3.第2の実施形態>
(3-1.第2の実施形態に係る高炉の操業方法)
次に、本発明の第2の実施形態について説明する。第2の実施形態では、RBFGはシャフト部羽口12から高炉10内に吹き込まれる。第2の実施形態では、流量計61は省略されてもよい。
3. Second embodiment
(3-1. Blast furnace operation method according to the second embodiment)
Next, a second embodiment of the present invention will be described. In the second embodiment, the RBFG is injected into the
第2の実施形態に係る高炉10の操業方法は概ね以下の通りである。すなわち、高炉10の炉頂から鉄系原料及びコークスを高炉10内に交互かつ層状に装入する一方で、水素系還元ガス供給システム2から加熱された水素系還元ガスを通常羽口11に供給する。そして、通常羽口11から熱風、微粉炭、富化酸素ガス、及び加熱された水素系還元ガスを高炉10内に吹き込む。一方で、シャフト部羽口12からRBFGを高炉10のシャフト部10bに吹き込む。熱風は、熱風とともに吹き込まれる微粉炭、及び、高炉10内のコークスと反応することで、高温の還元ガス(ここでは主としてCOガス)を発生させる。すなわち、熱風は、コークス及び微粉炭をガス化させる。還元ガスは、高炉10内を上昇し、鉄系原料を加熱しながら還元する。水素系還元ガス及びRBFGは、高炉10内を上昇し、鉄系原料を加熱しながら還元する。鉄系原料は、高炉10内を降下する一方で、還元ガス、水素系還元ガス、及びRBFGにより加熱及び還元される。その後、鉄系原料は溶融し、コークスによってさらに還元されながら高炉10内を滴下する。鉄系原料は、最終的には炭素を5質量%弱含む溶銑(銑鉄)として炉床部に溜められる。炉床部の溶銑は、出銑口から取り出され、次の製鋼プロセスに供される。
The operation method of the
一方、高炉10の炉頂排ガスが排出される。CO2分離回収装置20は、炉頂排ガスを回収し、還元ガス(COガス及び水素ガス)及び窒素ガス(すなわち、RBFG)と、CO2ガス及びH2Oガスとに分離する。CO2ガス及びH2Oガスは系外に排出される。
Meanwhile, the top flue gas of the
RBFGは、バッファータンク30に一時的に貯留される。バッファータンク30から所望量のRBFGがコンプレッサー40に導入される。残りのRBFGは系外に排出され、例えば製鉄所の熱源として使用される。
RBFG is temporarily stored in the
ついで、RBFGは、コンプレッサー40により加圧される。ここで、コンプレッサー40は、例えば高炉10の内圧(4.5気圧程度)程度までRBFGを加圧する。加圧されたRBFGは加熱器50に導入される。
The RBFG is then pressurized by the
ついで、RBFGは、加熱器50により加熱される。加熱温度は高炉10の操業条件に応じて任意に設定される。加熱器50で加熱されたRBFGは、シャフト部羽口12から高炉10のシャフト部10bに吹き込まれる。流量計62は、シャフト部羽口12から高炉10のシャフト部10bに吹き込まれるRBFGの流量を測定する。RBFGは、主にシャフト部羽口12から高炉10のシャフト部10bに吹き込まれるが、通常羽口11から補助的に高炉10内に吹き込まれてもよい。操業方法の具体例は第1の実施形態で説明した通りである。
The RBFG is then heated by the
ここで、高炉操業においては、安定した操業を行う等に理由により、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度を所定範囲内に維持することが好ましい。例えば、羽口先燃焼温度は2000~2300℃程度に維持されることが好ましく、炉頂排ガス温度は、105℃程度以上に維持されることが好ましく、溶銑温度は1520℃程度以上に維持されることが好ましい。なお、羽口先燃焼温度の上限値は通常操業(水素系還元ガスの吹き込み、RBFGの吹き込みを行わない操業)を想定した上限値である。羽口先燃焼温度が上限値を超える場合には、羽口設備の損耗を防ぐために羽口設備の冷却能力を強化する、より耐熱性能の高い材料を使用する、等の対策を行うことが好ましい。高炉操業の諸元は、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が所定範囲内に維持されるように決定される。なお、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が所定範囲内に維持される限り、高炉操業の諸元を自由に設計することができる。また、設計の結果、羽口先燃焼温度が上限値を超えてもよいが、上述した対策を別途行うことが好ましい。 Here, in blast furnace operation, it is preferable to maintain the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature within a specified range for reasons such as stable operation. For example, the tuyere combustion temperature is preferably maintained at about 2000 to 2300°C, the furnace top exhaust gas temperature is preferably maintained at about 105°C or higher, and the molten iron temperature is preferably maintained at about 1520°C or higher. The upper limit value of the tuyere combustion temperature is an upper limit value assuming normal operation (operation without injection of hydrogen-based reducing gas or RBFG). If the tuyere combustion temperature exceeds the upper limit value, it is preferable to take measures such as strengthening the cooling capacity of the tuyere equipment to prevent wear and tear on the tuyere equipment and using materials with higher heat resistance. The specifications of the blast furnace operation are determined so that the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within a specified range. As long as the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within the specified ranges, the blast furnace operation specifications can be freely designed. Also, although the tuyere combustion temperature may exceed the upper limit as a result of the design, it is preferable to take the above-mentioned measures separately.
例えば、水素系還元ガスの吹込み温度(通常羽口11から吹き込まれる水素系還元ガスの温度)は600~1000℃程度とすることが好ましく、水素系還元ガス中の水素ガスの吹込み量は400~600Nm3/t程度とすることが好ましい。いずれも特許文献1よりも低い範囲になる。RBFGの吹込み温度(シャフト部羽口12から吹き込まれるRBFGの温度、すなわち加熱器50による加熱温度)は800~1000℃程度とすることが好ましく、RBFGの吹込み量は200~600Nm3/t程度とすることが好ましい。後述するように、この場合、Input △Cが40%を超えるからである。他に調整可能な諸元として、熱風の吹込み量、熱風に含まれる酸素量(酸素の吹込み量)等が挙げられる。また、溶銑温度は、高炉10に吹き込む微粉炭の吹込み量またはコークス比(溶銑1トンあたりに使用するコークス量)によっても調整することができる。たとえば、まず微粉炭の吹込み量で溶銑温度を調整し、微粉炭の吹込み量がゼロになっても溶銑温度が所定範囲を超える場合には、コークス比を調整するといった制御が可能である。なお、溶銑温度は高炉10内の総熱量(炉熱)を反映した値になる。なお、高炉操業中には、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度を定期的に(好ましくは常時)モニタリングし、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度の何れかが上述した範囲外の値となった場合には、操業条件(例えば上述したように水素系還元ガスの吹込み温度、水素系還元ガス中の水素ガスの吹込み量、RBFGの吹込み温度、RBFGの吹込み量、熱風の吹込み量、及び熱風に含まれる酸素量(富化酸素ガスの吹込み量)のうち少なくとも1種以上)を調整すればよい。なお、水素系還元ガスまたはRBFGの吹込みの際に羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が変動しやすいので、これらのガスの吹込みの際には、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度をモニタリングすることが好ましい。
For example, the blowing temperature of the hydrogen-based reducing gas (the temperature of the hydrogen-based reducing gas usually blown from the tuyere 11) is preferably about 600 to 1000°C, and the blowing amount of hydrogen gas in the hydrogen-based reducing gas is preferably about 400 to 600 Nm 3 /t. Both are in the range lower than that of
(3-2.効果の検証)
つぎに、本発明者が行った効果の検証について説明する。本検証では、高炉操業のシミュレーションを行い、第2の実施形態に係る高炉の操業方法の効果を検証した。シミュレーションモデルは第1の実施形態と同様である。シミュレーションの前提条件は以下である。
・水素系還元ガスとして水素ガスを用いる。
・CO2分離回収装置20は、炉頂排ガスに含まれるCO2ガス及びH2Oガスを100%分離除去する。
・水素ガスの吹込み温度、RBFGの吹込み温度はいずれの水準でも800℃とする。ただし、水準2-1の水素ガスの吹込み温度は1200℃とする。
・熱風の吹込み温度(送風温度)はいずれの水準でも1200℃とする。
・出銑量、溶銑温度は全水準で一定(12350t/d、1535℃)とする。
・炉頂排ガス温度はいずれの水準でも135℃とする。
・炉熱調整(溶銑温度の調整)は、微粉炭の吹込み量を調整することで行う。微粉炭の吹込み量がゼロになっても溶銑温度が1535℃を超える場合には、コークス比を調整する。
・熱風の吹込み量、酸素の吹込み量は、上記前提条件が満たされるように調整した。
(3-2. Verification of Effects)
Next, the verification of the effects performed by the present inventor will be described. In this verification, a simulation of blast furnace operation was performed to verify the effects of the blast furnace operation method according to the second embodiment. The simulation model is the same as that of the first embodiment. The prerequisites for the simulation are as follows.
・Hydrogen gas is used as the hydrogen-based reducing gas.
The CO2 separation and
The hydrogen gas injection temperature and RBFG injection temperature are 800°C for all levels. However, the hydrogen gas injection temperature for level 2-1 is 1200°C.
The hot air blowing temperature (air supply temperature) is 1200°C for all levels.
- The amount of molten iron produced and the temperature of molten iron will be constant at all levels (12,350 t/d, 1,535°C).
- The top exhaust gas temperature shall be 135°C at all levels.
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted.
The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
上記の前提条件の下、以下の各水準についてシミュレーションを行った。水準2-2~2-4が第2の実施形態に対応する。
(水準2-1)水素ガス吹込み量650Nm3/t、熱風の吹込み温度1200℃、RBFG吹込みなし(H2:650Nm3/t、BT1200℃)。
(水準2-2)水素ガス吹込み量600Nm3/t、熱風の吹込み温度1200℃、RBFG吹込み操業(H2:600Nm3/t、BT1200℃)
(水準2-3)水素ガス吹込み量500Nm3/t、熱風の吹込み温度1200℃、RBFG吹込み操業(H2:500Nm3/t、BT1200℃)
(水準2-4)水素ガス吹込み量400Nm3/t、熱風の吹込み温度1200℃、RBFG吹込み操業(H2:400Nm3/t、BT1200℃)
Under the above preconditions, a simulation was performed for each of the following levels. Levels 2-2 to 2-4 correspond to the second embodiment.
(Level 2-1) Hydrogen gas blowing amount 650 Nm 3 /t, hot air blowing temperature 1200° C., no RBFG blowing (H2: 650 Nm 3 /t, BT 1200° C.).
(Level 2-2) Hydrogen gas injection amount 600 Nm 3 /t, hot air injection temperature 1200°C, RBFG injection operation (H2: 600 Nm 3 /t, BT 1200°C)
(Level 2-3) Hydrogen gas injection amount 500 Nm 3 /t, hot air injection temperature 1200°C, RBFG injection operation (H2: 500 Nm 3 /t, BT 1200°C)
(Level 2-4) Hydrogen gas injection amount 400 Nm 3 /t, hot air injection temperature 1200°C, RBFG injection operation (H2: 400 Nm 3 /t, BT 1200°C)
結果を図4及び図5に示す。図4の横軸(シャフト羽口RBFG吹込み量)はシャフト部羽口12から高炉10のシャフト部10bに吹き込まれるRBFGの吹込み量(Nm3/t)を示し、縦軸はInput △C(%)を示す。図5の横軸(シャフト羽口RBFG吹込み量)はシャフト部羽口12から高炉10のシャフト部10bに吹き込まれるRBFGの吹込み量(Nm3/t)を示し、縦軸(系全体水素ガス利用率)は系全体の水素ガスの利用率(%)を示す。系全体の水素ガスの利用率の算出方法は上述した通りである。
The results are shown in Figures 4 and 5. The horizontal axis of Figure 4 (shaft tuyere RBFG injection amount) shows the injection amount ( Nm3 /t) of RBFG injected from the
図4及び図5によれば、以下の知見が得られる。
・水素系還元ガス供給システム2からの(すなわち、RBFGに含まれるものではない)水素ガスの吹込み量が多くなる程、Input △Cが大きくなる。
・RBFGの吹込み量が多くなる程、Input △Cが大きくなる。水準2-4では、RBFGの吹込み量を600Nm3/tとすることで、Input △Cが40%を超える(40.5%、図4中の破線円で囲んだ点)。この値は、水素ガスを大量に吹き込む水準2-1、水素ガスの吹込み量がやや多い水準2-2~2-3に匹敵するものである。さらに、水準2-4の水素ガスの吹込み量は400Nm3/tと水準2-1~2-3に比べて少なく、水素ガスの吹込み温度も800℃と低い。なお、このときの水準2-4の水素ガスの利用率は63%(a=260Nm3/t、b=151Nm3/t)となる(図5中の破線円で囲んだ点)。
According to FIG. 4 and FIG. 5, the following findings can be obtained.
The greater the amount of hydrogen gas blown in from the hydrogen-based reducing gas supply system 2 (i.e., not contained in the RBFG), the greater the Input ΔC.
The larger the RBFG injection amount, the larger the Input ΔC becomes. In level 2-4, by setting the RBFG injection amount to 600 Nm 3 /t, the Input ΔC exceeds 40% (40.5%, the point surrounded by the dashed circle in Figure 4). This value is comparable to level 2-1, in which a large amount of hydrogen gas is injected, and levels 2-2 to 2-3, in which the hydrogen gas injection amount is slightly larger. Furthermore, the hydrogen gas injection amount in level 2-4 is 400 Nm 3 /t, which is smaller than levels 2-1 to 2-3, and the hydrogen gas injection temperature is also low at 800°C. The hydrogen gas utilization rate in level 2-4 at this time is 63% (a = 260 Nm 3 /t, b = 151 Nm 3 /t) (the point surrounded by the dashed circle in Figure 5).
以上により、第2の実施形態によれば、水素系還元ガスの吹込み量を減少させ、かつ水素系還元ガスの加熱温度を低下させた場合であっても、Input △Cを高くすることができる。 As described above, according to the second embodiment, even if the amount of hydrogen-based reducing gas injected is reduced and the heating temperature of the hydrogen-based reducing gas is lowered, the Input △C can be increased.
本発明者は、さらに操業の自由度についても検討した。結果を図6及び図7に示す。図6の横軸(シャフト羽口RBFG吹込み量)はシャフト部羽口12から高炉10のシャフト部10bに吹き込まれるRBFGの吹込み量(Nm3/t)を示し、縦軸は羽口先燃焼温度(℃)を示す。△CはInput △Cを示す。図6には、Input △Cが29%以上33%未満となる点のグループ、Input △Cが33%以上38%未満となるグループ、Input △Cが40%超となるグループを破線で囲んだ。図6中の羽口先燃焼温度の「通常上限」(=2300℃)は、通常操業(水素系還元ガスの吹き込み、RBFGの吹き込みを行わない操業)を想定した上限値である。図7の横軸は羽口先燃焼温度(℃)を示し、縦軸は炉頂排ガス温度(℃)を示す。図6、図7には、参考例として、水準2-4において、送風温度1300℃(BT1300℃)、水素ガスの吹込み温度1000℃とした例も示す。
The inventors further studied the degree of freedom of operation. The results are shown in Fig. 6 and Fig. 7. The horizontal axis of Fig. 6 (shaft tuyere RBFG injection amount) indicates the injection amount (Nm 3 /t) of RBFG injected from the
図6及び図7によれば、以下の知見が得られる。
・水素系還元ガス供給システム2からの(すなわち、RBFGに含まれるものではない)水素系還元ガスの吹込み量を低減させるか、またはRBFGの吹込み量を増加させることで、羽口先燃焼温度が上昇する。
高炉操業において、炉頂排ガス温度と羽口先燃焼温度とがどちらも適正範囲内となるように操業することが必要である。炉頂排ガス温度は高炉炉内に供給されるガスの流量に大きく依存し、出銑量あたりのガス流量を増やすほど炉頂排ガス温度は上昇する。一方で、羽口先燃焼温度は、羽口先での燃焼条件である酸素富化率に大きく依存し、酸素富化率を上げるほど羽口先燃焼温度は上昇する。高炉操業においては、酸素富化率を上げる=熱風の送風量が減って羽口から供給されるガス流量が低下する、こととなるので、酸素富化率を上げて羽口先燃焼温度を上げると、炉内供給ガス流量が減って炉頂排ガス温度は低下する。よって、通常羽口11からガスを吹き込む操業を前提とすると、炉頂排ガス温度と羽口先燃焼温度を独立して制御することは困難になる(どちらかを動かそうとすると、もう一方が逆方向に動いてしまうため)。なお、第1の実施形態のように通常羽口にRBFGを吹込む場合、RBFG吹込み量を調整することで炉内へ供給されるガスの吹込み量を調整することは可能であるが、羽口先燃焼温度より低温のガスを高炉炉内に供給することになるので、RBFG吹込み量を増やす=羽口先燃焼温度は低下してしまう、こととなり、炉頂排ガス温度と羽口先燃焼温度を独立制御することはできない。
第2の実施形態の場合、羽口先燃焼温度より低温のガスを炉内に供給する点は第1の実施形態と同様であるが、RBFGをコークスが燃焼している羽口部(通常羽口11の先)ではなく、シャフト部10bから吹き込むため、RBFGの吹込み量を操作しても、羽口先燃焼温度が低下することはない。このため、RBFGの吹込み量を増やして炉頂排ガス温度を調整しつつ、羽口部で酸素富化率を別個で調整して羽口先燃焼温度を適正値にすることが可能となる。これは、第2の実施形態の強みの1つである(ガスを通常羽口11とは別のところに吹き込むという点が良い)。
したがって、水準2-4の羽口先燃焼温度は水準2-1~2-3の羽口先燃焼温度よりも高くなる。水準2-4の羽口先燃焼温度は、下限値(2000℃)よりも十分に高くなる。さらに、水準2-4の炉頂排ガス温度も下限値(105℃)よりも十分に高くなる。
According to FIG. 6 and FIG. 7, the following findings can be obtained.
By reducing the amount of hydrogen-based reducing gas injected from the hydrogen-based reducing gas supply system 2 (i.e., not contained in the RBFG) or by increasing the amount of RBFG injected, the tuyere combustion temperature increases.
In blast furnace operation, it is necessary to operate so that both the top exhaust gas temperature and the tuyere combustion temperature are within the appropriate range. The top exhaust gas temperature depends greatly on the flow rate of gas supplied into the blast furnace, and the more the gas flow rate per pig iron output increases, the higher the top exhaust gas temperature. On the other hand, the tuyere combustion temperature depends greatly on the oxygen enrichment rate, which is the combustion condition at the tuyere, and the higher the oxygen enrichment rate, the higher the tuyere combustion temperature. In blast furnace operation, increasing the oxygen enrichment rate = reducing the amount of hot air blown and reducing the gas flow rate supplied from the tuyere, so if the oxygen enrichment rate is increased to increase the tuyere combustion temperature, the gas flow rate supplied into the furnace decreases and the top exhaust gas temperature decreases. Therefore, assuming that gas is normally blown from the
In the second embodiment, gas at a temperature lower than the tuyere combustion temperature is supplied into the furnace, as in the first embodiment, but since RBFG is blown from the
Therefore, the tuyere combustion temperature in level 2-4 is higher than those in levels 2-1 to 2-3. The tuyere combustion temperature in level 2-4 is sufficiently higher than the lower limit (2000°C). Furthermore, the furnace top exhaust gas temperature in level 2-4 is also sufficiently higher than the lower limit (105°C).
したがって、第2の実施形態では、操業の自由度が高くなる(操業の諸元を設計できる幅が広い)。なお、水準2-4のInput △Cが40%を超えると羽口先燃焼温度が上限値(2300℃)を超える(図6中破線円Aで示す点)が、上述した対策を行えば操業を継続することができる。 Therefore, in the second embodiment, the degree of freedom in operation is high (the range in which the operational parameters can be designed is wide). Note that if the Input △C of level 2-4 exceeds 40%, the tuyere tip combustion temperature will exceed the upper limit (2300°C) (point indicated by dashed circle A in Figure 6), but operation can be continued by taking the measures described above.
<4.第3の実施形態>
(4-1.第3の実施形態に係る高炉の操業方法)
次に、本発明の第3の実施形態について説明する。第3の実施形態では、RBFGは通常羽口11及びシャフト部羽口12の双方から高炉10内に吹き込まれる。
4. Third embodiment
(4-1. Blast furnace operation method according to the third embodiment)
Next, a third embodiment of the present invention will be described. In the third embodiment, RBFG is injected into a
第3の実施形態に係る高炉10の操業方法は概ね以下の通りである。すなわち、高炉10の炉頂から鉄系原料及びコークスを高炉10内に交互かつ層状に装入する一方で、水素系還元ガス供給システム2から加熱された水素系還元ガスを通常羽口11に供給する。そして、通常羽口11から熱風、微粉炭、富化酸素ガス、加熱された水素系還元ガスを高炉10内に吹き込む。一方で、通常羽口11及びシャフト部羽口12からRBFGを高炉10内に吹き込む。熱風は、熱風とともに吹き込まれる微粉炭、及び、高炉10内のコークスと反応することで、高温の還元ガス(ここでは主としてCOガス)を発生させる。すなわち、熱風は、コークス及び微粉炭をガス化させる。還元ガスは、高炉10内を上昇し、鉄系原料を加熱しながら還元する。水素系還元ガス及びRBFGは、高炉10内を上昇し、鉄系原料を加熱しながら還元する。鉄系原料は、高炉10内を降下する一方で、還元ガス、水素系還元ガス、及びRBFGにより加熱及び還元される。その後、鉄系原料は溶融し、コークスによってさらに還元されながら高炉10内を滴下する。鉄系原料は、最終的には炭素を5質量%弱含む溶銑(銑鉄)として炉床部に溜められる。炉床部の溶銑は、出銑口から取り出され、次の製鋼プロセスに供される。
The operation method of the
一方、高炉10の炉頂排ガスが排出される。CO2分離回収装置20は、炉頂排ガスを回収し、還元ガス(COガス及び水素ガス)及び窒素ガス(すなわち、RBFG)と、CO2ガス及びH2Oガスとに分離する。CO2ガス及びH2Oガスは系外に排出される。
Meanwhile, the top flue gas of the
RBFGは、バッファータンク30に一時的に貯留される。バッファータンク30から所望量のRBFGがコンプレッサー40に導入される。残りのRBFGは系外に排出され、例えば製鉄所の熱源として使用される。
RBFG is temporarily stored in the
ついで、RBFGは、コンプレッサー40により加圧される。ここで、コンプレッサー40は、例えば高炉10の内圧(4.5気圧程度)程度までRBFGを加圧する。加圧されたRBFGは加熱器50に導入される。
The RBFG is then pressurized by the
ついで、RBFGは、加熱器50により加熱される。加熱温度は高炉10の操業条件に応じて任意に設定される。加熱器50で加熱されたRBFGは、通常羽口11及びシャフト部羽口12から高炉10内に吹き込まれる。流量計61は、通常羽口11から高炉10内に吹き込まれるRBFGの流量を測定する。流量計62は、シャフト部羽口12から高炉10のシャフト部10bに吹き込まれるRBFGの流量を測定する。操業方法の具体例は第1の実施形態で説明した通りである。
The RBFG is then heated by the
ここで、高炉操業においては、安定した操業を行う等に理由により、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度を所定範囲内に維持することが好ましい。例えば、羽口先燃焼温度は2000~2300℃程度に維持されることが好ましく、炉頂排ガス温度は、105℃程度以上に維持されることが好ましく、溶銑温度は1520℃程度以上に維持されることが好ましい。なお、羽口先燃焼温度の上限値は通常操業(水素系還元ガスの吹き込み、RBFGの吹き込みを行わない操業)を想定した上限値である。羽口先燃焼温度が上限値を超える場合には、羽口設備の損耗を防ぐために羽口設備の冷却能力を強化する、より耐熱性能の高い材料を使用する等の対策を行うことが好ましい。高炉操業の諸元は、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が所定範囲内に維持されるように決定される。なお、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が所定範囲内に維持される限り、高炉操業の諸元を自由に設計することができる。また、設計の結果、羽口先燃焼温度が上限値を超えてもよいが、上述した対策を別途行うことが好ましい。 Here, in blast furnace operation, it is preferable to maintain the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature within a specified range for reasons such as stable operation. For example, the tuyere combustion temperature is preferably maintained at about 2000 to 2300°C, the furnace top exhaust gas temperature is preferably maintained at about 105°C or higher, and the molten iron temperature is preferably maintained at about 1520°C or higher. The upper limit value of the tuyere combustion temperature is an upper limit value assuming normal operation (operation without injection of hydrogen-based reducing gas or RBFG). If the tuyere combustion temperature exceeds the upper limit value, it is preferable to take measures such as strengthening the cooling capacity of the tuyere equipment and using materials with higher heat resistance to prevent wear and tear on the tuyere equipment. The specifications of the blast furnace operation are determined so that the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within a specified range. As long as the tuyere combustion temperature, furnace top exhaust gas temperature, and molten iron temperature are maintained within the specified ranges, the blast furnace operation specifications can be freely designed. Also, although the tuyere combustion temperature may exceed the upper limit as a result of the design, it is preferable to take the above-mentioned measures separately.
例えば、水素系還元ガスの吹込み温度(通常羽口11から吹き込まれる水素系還元ガスの温度)は800~1000℃程度とすることが好ましく、水素系還元ガス中の水素ガスの吹込み量は300~600Nm3/t程度とすることが好ましい。いずれも特許文献1よりも低い範囲になる。RBFGの通常羽口吹込み温度(通常羽口11から吹き込まれるRBFGの温度、すなわち加熱器50による加熱温度)は800~1000℃程度が好ましく、RBFGの通常羽口吹込み量は100~300Nm3/t程度とすることが好ましい。RBFGのシャフト部羽口吹込み温度(シャフト部羽口12から吹き込まれるRBFGの温度、すなわち加熱器50による加熱温度)は通常羽口吹込み温度と同様であり、RBFGのシャフト部羽口吹込み量は200~600Nm3/t程度とすることが好ましい。特に、RBFGの吹込み量は、通常羽口吹込み量とシャフト部羽口吹込み量の合計で600Nm3/t以上であることが好ましい。後述するように、この場合、Input △Cが40%を超えるからである。他に調整可能な諸元として、熱風の吹込み量、熱風に含まれる酸素量(酸素の吹込み量)等が挙げられる。また、溶銑温度は、高炉10に吹き込む微粉炭の吹込み量またはコークス比(溶銑1トンあたりに使用するコークス量)によっても調整することができる。たとえば、まず微粉炭の吹込み量で溶銑温度を調整し、微粉炭の吹込み量がゼロになっても溶銑温度が所定範囲を超える場合には、コークス比を調整するといった制御が可能である。なお、溶銑温度は高炉10内の総熱量(炉熱)を反映した値になる。なお、高炉操業中には、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度を定期的に(好ましくは常時)モニタリングし、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度の何れかが上述した範囲外の値となった場合には、操業条件(例えば上述したように水素系還元ガスの吹込み温度、水素系還元ガス中の水素ガスの吹込み量、RBFGの吹込み温度、RBFGの吹込み量、熱風の吹込み量、及び熱風に含まれる酸素量(富化酸素ガスの吹込み量)のうち少なくとも1種以上)を調整すればよい。なお、水素系還元ガスまたはRBFGの吹込みの際に羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度が変動しやすいので、これらのガスの吹込みの際には、羽口先燃焼温度、炉頂排ガス温度、及び溶銑温度をモニタリングすることが好ましい。
For example, the blowing temperature of the hydrogen-based reducing gas (the temperature of the hydrogen-based reducing gas normally blown from the tuyere 11) is preferably about 800 to 1000°C, and the blowing amount of hydrogen gas in the hydrogen-based reducing gas is preferably about 300 to 600 Nm 3 /t. Both are in a range lower than that of
(3-2.効果の検証)
つぎに、本発明者が行った効果の検証について説明する。本検証では、高炉操業のシミュレーションを行い、第3の実施形態に係る高炉の操業方法の効果を検証した。シミュレーションモデルは第1の実施形態と同様である。シミュレーションの前提条件は以下である。
・水素系還元ガスとして水素ガスを用いる。
・CO2分離回収装置20は、炉頂排ガスに含まれるCO2ガス及びH2Oガスを100%分離除去する。
・水素ガスの吹込み温度、RBFGの吹込み温度は800℃とする。
・熱風の吹込み温度(送風温度)は1200℃とする。
・出銑量、溶銑温度は12350t/d、1535℃とする。
・炉頂排ガス温度は132℃、羽口先燃焼温度は2196℃とする。
・炉熱調整(溶銑温度の調整)は、微粉炭の吹込み量を調整することで行う。微粉炭の吹込み量がゼロになっても溶銑温度が1535℃を超える場合には、コークス比を調整する。
・熱風の吹込み量、酸素の吹込み量は、上記前提条件が満たされるように調整した。
(3-2. Verification of Effects)
Next, the verification of the effects performed by the present inventor will be described. In this verification, a simulation of blast furnace operation was performed to verify the effects of the blast furnace operation method according to the third embodiment. The simulation model is the same as that of the first embodiment. The prerequisites for the simulation are as follows.
・Hydrogen gas is used as the hydrogen-based reducing gas.
The CO2 separation and
The hydrogen gas blowing temperature and the RBFG blowing temperature are set to 800°C.
The hot air blowing temperature (air supply temperature) is 1200°C.
The amount of molten iron produced and the temperature of the molten iron will be 12,350 t/d and 1,535°C.
- The top exhaust gas temperature is 132°C, and the tuyere combustion temperature is 2196°C.
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted.
The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
上記の前提条件の下、以下の水準についてシミュレーションを行った。本水準では、水素ガス吹込み量を400Nm3/t、RBFGのシャフト部羽口吹込み量は400Nm3/tとし、通常羽口吹込み量は200Nm3/tとした。この結果、Input △Cは42.2%であった。 Simulations were performed under the above preconditions for the following levels. In these levels, the hydrogen gas injection rate was 400 Nm3 /t, the RBFG shaft tuyere injection rate was 400 Nm3 /t, and the normal tuyere injection rate was 200 Nm3 /t. As a result, the Input ΔC was 42.2%.
以上により、第3の実施形態によれば、水素ガスの吹込み量を減少させ、かつ水素ガスの加熱温度を低下させた場合であっても、Input △Cを高くすることができる。 As described above, according to the third embodiment, even if the amount of hydrogen gas injected is reduced and the heating temperature of the hydrogen gas is lowered, the Input △C can be increased.
つぎに、本実施形態の実施例を説明する。本実施例では、高炉数学モデルを用いた高炉操業シミュレーションを行い、第1~第3の実施形態の効果を確認した。実施例1が第1の実施形態に対応し、実施例2が第2の実施形態に対応し、実施例3が第3の実施形態に対応する。 Next, an example of this embodiment will be described. In this example, a blast furnace operation simulation was performed using a blast furnace mathematical model, and the effects of the first to third embodiments were confirmed. Example 1 corresponds to the first embodiment, Example 2 corresponds to the second embodiment, and Example 3 corresponds to the third embodiment.
<1.実施例1>
(1-1.主要諸元)
・水素系還元ガスとして水素ガスを用いる。
・CO2分離回収装置20は、炉頂排ガスに含まれるCO2ガス及びH2Oガスを100%分離除去する。
・出銑量、溶銑温度は12350t/d、1535℃とする。
・炉頂排ガス温度は、炭素削減効果を最大限享受するため、下限値近傍(105℃)とする。
・炉熱調整(溶銑温度の調整)は、微粉炭の吹込み量を調整することで行う。微粉炭の吹込み量がゼロになっても溶銑温度が1535℃を超える場合には、コークス比を調整する。
・熱風の吹込み量、酸素の吹込み量は、上記前提条件が満たされるように調整した。
・水素ガス吹込みあり(吹込み温度1000℃、吹込み量325Nm3/t)、熱風の吹込み温度1300℃、RBFG吹込み温度1000℃、吹込み量600Nm3/t
<1. Example 1>
(1-1. Main specifications)
・Hydrogen gas is used as the hydrogen-based reducing gas.
The CO2 separation and
The amount of molten iron produced and the temperature of the molten iron will be 12,350 t/d and 1,535°C.
The furnace top exhaust gas temperature is set near the lower limit (105°C) to maximize the carbon reduction effect.
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted.
The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
Hydrogen gas was blown (
(1-2.シミュレーションの結果)
シミュレーションの結果、実施例1では、Input △Cが43.2%となった。
(1-2. Simulation results)
As a result of the simulation, in Example 1, Input ΔC was 43.2%.
<2.実施例2>
(2-1.主要諸元)
・水素系還元ガスとして水素ガスを用いた。
・CO2分離回収装置20は、炉頂排ガスに含まれるCO2ガス及びH2Oガスを100%分離除去する。
・水素ガスの吹込み温度、RBFGの吹込み温度は800℃とする。
・熱風の吹込み温度(送風温度)は1200℃とする。
・出銑量、溶銑温度は12350t/d、1535℃とする。
・炉頂排ガス温度は135℃とする。
・炉熱調整(溶銑温度の調整)は、微粉炭の吹込み量を調整することで行う。微粉炭の吹込み量がゼロになっても溶銑温度が1535℃を超える場合には、コークス比を調整する。
・熱風の吹込み量、酸素の吹込み量は、上記前提条件が満たされるように調整した。
・水素ガス吹込み量400Nm3/t、RBFG吹込み量600Nm3/t
<2. Example 2>
(2-1. Main specifications)
Hydrogen gas was used as the hydrogen-based reducing gas.
The CO2 separation and
The hydrogen gas blowing temperature and the RBFG blowing temperature are 800°C.
The hot air blowing temperature (air supply temperature) is 1200°C.
The amount of molten iron produced and the temperature of the molten iron will be 12,350 t/d and 1,535°C.
- The top exhaust gas temperature is 135°C.
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted.
The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
Hydrogen gas injection rate: 400 Nm 3 /t, RBFG injection rate: 600 Nm 3 /t
(2-2.シミュレーションの結果)
シミュレーションの結果、実施例2では、Input △Cが40.5%となった。
(2-2. Simulation results)
As a result of the simulation, in Example 2, Input ΔC was 40.5%.
<3.実施例3>
(3-1.主要諸元)
・水素系還元ガスとして水素ガスを用いる。
・CO2分離回収装置20は、炉頂排ガスに含まれるCO2ガス及びH2Oガスを100%分離除去する。
・水素ガスの吹込み温度、RBFGの吹込み温度は800℃とする。
・熱風の吹込み温度(送風温度)は1200℃とする。
・出銑量、溶銑温度は12350t/d、1535℃とする。
・炉頂排ガス温度は132℃、羽口先燃焼温度は2196℃とする。
・炉熱調整(溶銑温度の調整)は、微粉炭の吹込み量を調整することで行う。微粉炭の吹込み量がゼロになっても溶銑温度が1535℃を超える場合には、コークス比を調整する。
・熱風の吹込み量、酸素の吹込み量は、上記前提条件が満たされるように調整した。
・水素ガス吹込み量を400Nm3/t、RBFGのシャフト部羽口吹込み量は400Nm3/tとし、通常羽口吹込み量は200Nm3/tとした。
<3. Example 3>
(3-1. Main specifications)
・Hydrogen gas is used as the hydrogen-based reducing gas.
The CO2 separation and
The hydrogen gas blowing temperature and the RBFG blowing temperature are set to 800°C.
The hot air blowing temperature (air supply temperature) is 1200°C.
The amount of molten iron produced and the temperature of the molten iron will be 12,350 t/d and 1,535°C.
- The top exhaust gas temperature is 132°C, and the tuyere combustion temperature is 2196°C.
- Furnace heat adjustment (adjustment of molten iron temperature) is performed by adjusting the amount of pulverized coal injected. If the molten iron temperature exceeds 1535°C even when the amount of pulverized coal injected becomes zero, the coke rate is adjusted.
The amount of hot air and the amount of oxygen blown were adjusted so as to satisfy the above prerequisites.
The hydrogen gas injection rate was 400 Nm 3 /t, the RBFG shaft tuyere injection rate was 400 Nm 3 /t, and the normal tuyere injection rate was 200 Nm 3 /t.
(3-2.シミュレーションの結果)
シミュレーションの結果、実施例3では、Input △Cが42.2%となった。
(3-2. Simulation results)
As a result of the simulation, in Example 3, Input ΔC was 42.2%.
したがって、第1~第3の実施形態によれば、水素系還元ガスの吹込み量を減少させ、かつ水素系還元ガスの加熱温度を低下させた場合であっても、Input △Cを高くすることができる。 Therefore, according to the first to third embodiments, even if the amount of hydrogen-based reducing gas injected is reduced and the heating temperature of the hydrogen-based reducing gas is lowered, the Input △C can be increased.
以上、添付図面を参照しながら本発明の好適な実施形態について詳細に説明したが、本発明は係る例に限定されない。本発明の属する技術の分野における通常の知識を有する者であれば、特許請求の範囲に記載された技術的思想の範疇内において、各種の変更例または修正例に想到し得ることは明らかであり、これらについても、当然に本発明の技術的範囲に属するものと了解される。 A preferred embodiment of the present invention has been described in detail above with reference to the attached drawings, but the present invention is not limited to the examples. It is clear that a person with ordinary knowledge in the technical field to which the present invention pertains can conceive of various modified or revised examples within the scope of the technical ideas described in the claims, and it is understood that these also naturally fall within the technical scope of the present invention.
1 高炉システム
2 水素系還元ガス供給システム
10 高炉
10a 高炉本体
10b シャフト部
11 通常羽口
12 シャフト部羽口
20 CO2分離回収装置
30 バッファータンク
40 コンプレッサー
50、71 加熱器
61、62、72 流量計
70 水素系還元ガスタンク
Claims (7)
加熱された前記水素系還元ガスを高炉に吹き込む工程と、
炉頂排ガスから還元ガスを分離する工程と、
分離した前記還元ガスを加熱する工程と、
前記還元ガスを前記高炉に吹き込む工程と、を含むことを特徴とする、高炉の操業方法。 Heating a hydrogen-based reducing gas supplied from outside the blast furnace;
injecting the heated hydrogen-based reducing gas into a blast furnace;
separating the reducing gas from the top exhaust gas;
heating the separated reducing gas;
and injecting the reducing gas into the blast furnace.
加熱された前記水素系還元ガスを通常羽口及び、少なくとも前記通常羽口よりも高い位置に設置されたシャフト部羽口のうち少なくとも一方から高炉に吹き込む工程と、
炉頂排ガスから還元ガスを分離する工程と、
分離した前記還元ガスを加熱する工程と、
加熱された前記還元ガスを前記通常羽口及び前記シャフト部羽口のうち少なくとも一方から高炉に吹き込む工程と、
を含み、
加熱された前記水素系還元ガスを前記通常羽口及び前記シャフト部羽口のうち少なくとも一方から高炉に吹き込む際、及び加熱された前記還元ガスを前記通常羽口及び前記シャフト部羽口のうち少なくとも一方から高炉に吹き込む際のうち、少なくとも一方のタイミングで、羽口先燃焼温度及び炉頂排ガス温度に基づいて、前記還元ガスの吹込み量、熱風の送風量、及び前記熱風に含まれる酸素量のうち、少なくとも1種以上の操業条件を調整することを特徴とする、請求項1または2に記載の高炉の操業方法。 Heating a hydrogen-based reducing gas supplied from outside the blast furnace;
Injecting the heated hydrogen-based reducing gas into the blast furnace from at least one of a normal tuyere and a shaft tuyere installed at a position higher than the normal tuyere;
separating the reducing gas from the top exhaust gas;
heating the separated reducing gas;
Injecting the heated reducing gas into a blast furnace from at least one of the normal tuyere and the shaft tuyere;
Including,
3. The method for operating a blast furnace according to claim 1 or 2, characterized in that at least one of the operating conditions, among the amount of the reducing gas injected, the amount of hot air blown, and the amount of oxygen contained in the hot air, is adjusted based on the tuyere tip combustion temperature and the furnace top exhaust gas temperature at at least one of the timings when the heated hydrogen-based reducing gas is injected into the blast furnace from at least one of the normal tuyere and the shaft tuyere and when the heated reducing gas is injected into the blast furnace from at least one of the normal tuyere and the shaft tuyere.
3. The method for operating a blast furnace according to claim 1, wherein the reducing gas contains CO gas separated from the top exhaust gas and hydrogen gas.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2023101584 | 2023-06-21 | ||
| JP2023-101584 | 2023-06-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2024262547A1 true WO2024262547A1 (en) | 2024-12-26 |
Family
ID=93935464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2024/022266 Pending WO2024262547A1 (en) | 2023-06-21 | 2024-06-19 | Blast furnace operation method |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2024262547A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4979910A (en) * | 1972-11-25 | 1974-08-01 | ||
| JP2009221547A (en) * | 2008-03-17 | 2009-10-01 | Jfe Steel Corp | Method for operating blast furnace |
| JP2020045508A (en) * | 2018-09-14 | 2020-03-26 | 日本製鉄株式会社 | Operation method of blast furnace |
| JP2020132928A (en) * | 2019-02-18 | 2020-08-31 | 日本製鉄株式会社 | Determination method of blowing amount of reducing gas and operation method of blast furnace |
| WO2021107091A1 (en) * | 2019-11-29 | 2021-06-03 | 日本製鉄株式会社 | Blast furnace operation method |
-
2024
- 2024-06-19 WO PCT/JP2024/022266 patent/WO2024262547A1/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4979910A (en) * | 1972-11-25 | 1974-08-01 | ||
| JP2009221547A (en) * | 2008-03-17 | 2009-10-01 | Jfe Steel Corp | Method for operating blast furnace |
| JP2020045508A (en) * | 2018-09-14 | 2020-03-26 | 日本製鉄株式会社 | Operation method of blast furnace |
| JP2020132928A (en) * | 2019-02-18 | 2020-08-31 | 日本製鉄株式会社 | Determination method of blowing amount of reducing gas and operation method of blast furnace |
| WO2021107091A1 (en) * | 2019-11-29 | 2021-06-03 | 日本製鉄株式会社 | Blast furnace operation method |
Also Published As
| Publication number | Publication date |
|---|---|
| TW202500764A (en) | 2025-01-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP7297091B2 (en) | Blast furnace operation method | |
| CN113423845B (en) | Blast furnace operation method | |
| CN104412056A (en) | Blast furnace with top-gas recycle | |
| JP6354962B2 (en) | Oxygen blast furnace operation method | |
| CN101473048A (en) | Direct smelting plant with waste heat recovery unit | |
| US6478841B1 (en) | Integrated mini-mill for iron and steel making | |
| JP4743332B2 (en) | Blast furnace operation method | |
| CN119731344A (en) | Method for operating a smelting furnace installation | |
| JP7055082B2 (en) | How to operate the blast furnace | |
| JP7662417B2 (en) | Blast furnace operation method | |
| WO2024262547A1 (en) | Blast furnace operation method | |
| JP7651338B2 (en) | Blast furnace operation method | |
| JP7709109B1 (en) | Blast furnace operation method | |
| CA3154824A1 (en) | Method of operating blast furnace and blast furnace ancillary facility | |
| JP2023128470A (en) | How to operate a blast furnace | |
| EP4306660A1 (en) | Oxygen blast furnace and oxygen blast furnace operation method | |
| TWI906913B (en) | Blast furnace operating methods | |
| JP2025133638A (en) | Blast furnace operation method | |
| JP2023114182A (en) | Blast furnace operation method | |
| WO2025187271A1 (en) | Blast furnace operation method | |
| JP7791433B2 (en) | Blast furnace operation method | |
| JP2025148977A (en) | Blast furnace operation method | |
| KR101225116B1 (en) | Device and method for controlling by-product gas generated from steelwork | |
| WO2025187531A1 (en) | Blast furnace operation method | |
| KR102177047B1 (en) | Manufacturing apparatus of molten iron and manufacturing method of molten iron |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 24825948 Country of ref document: EP Kind code of ref document: A1 |
|
| DPE1 | Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101) | ||
| ENP | Entry into the national phase |
Ref document number: 2025528095 Country of ref document: JP Kind code of ref document: A |