WO2024244191A1 - Spectrometer, spectral reconstruction method and computer device - Google Patents
Spectrometer, spectral reconstruction method and computer device Download PDFInfo
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- WO2024244191A1 WO2024244191A1 PCT/CN2023/116611 CN2023116611W WO2024244191A1 WO 2024244191 A1 WO2024244191 A1 WO 2024244191A1 CN 2023116611 W CN2023116611 W CN 2023116611W WO 2024244191 A1 WO2024244191 A1 WO 2024244191A1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
- G01J3/44—Raman spectrometry; Scattering spectrometry ; Fluorescence spectrometry
- G01J3/4412—Scattering spectrometry
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/28—Investigating the spectrum
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
Definitions
- the present invention relates to the technical field of spectrum detection, and in particular to a spectrometer, a spectrum reconstruction method, and a computer device.
- the spectral characteristics of a substance contain a large amount of information, which can be used to detect the composition of the substance in physics and chemistry, and to detect pathological information of the body in biology.
- the working principle of the swept laser detection method is that the laser outputs a single wavelength, obtains the scattering or absorption information of a single wavelength by irradiating the sample to be tested and collecting the scattered or transmitted light, and then scans each wavelength through the sweep function of the swept laser to obtain the characteristic information of the entire spectrum.
- This method requires scanning wavelength by wavelength.
- the number of required wavelength points is large, the working time will increase significantly.
- the time cost increases, and on the other hand, it is not suitable for some samples that change rapidly.
- the price of swept lasers is also relatively expensive, and the size and mass are large. If the wavelength range of the required spectral information is large, a single swept laser may not be able to meet the application requirements, which will further increase the cost, volume and mass.
- the working principle of the spectrometer detection method is to use a wide-spectrum light source to illuminate the sample, and the scattered or transmitted light is collected and enters the spectrometer.
- the intensity information of light of different wavelengths is obtained through the spectrometer, so as to infer the scattering and absorption characteristics of the sample.
- a spectrometer using this structure will have certain losses in the process of collecting scattered or transmitted light entering the spectrometer.
- its wide-spectrum light source is mostly independently powered. Even if there is a large loss in the optical link transmission, it can be compensated by increasing the power of the light source, and it will not affect the detection.
- computational reconstruction spectrometers can be set up in some miniaturized, portable or wearable devices To reduce the size, but in some cases the same problem mentioned above still exists. Limited by the size of the device and the battery capacity, it is an urgent problem for technicians in this field to ensure the reliability of the detection results and reduce the power consumption of the light source and improve the battery life of the device.
- the present invention aims to solve one of the technical problems in the related art to a certain extent.
- the present invention provides a spectrometer, a spectrum reconstruction method, and a computer device, which can reduce the loss of the light source in the link transmission, thereby reducing the power consumption of the light source and improving the endurance of the device.
- the present invention adopts the following technical solutions in the first aspect:
- a computational reconstruction spectrometer comprising:
- At least one wide spectrum response filter the wide spectrum response filter having an input end and an output end, wherein the input end receives the light source; the wide spectrum response filter responds to the spectrum of the light source and outputs different modulated spectra at its output end according to a pre-made response rule to irradiate the sample to be tested; and
- At least one photodetector is used to collect scattered or transmitted light intensity information of the sample to be tested after being irradiated with different modulated spectra.
- the computational reconstruction spectrometer of the present invention when in use, because the light source is relatively orderly and has a small optical expansion, it can enter the wide spectrum response filter through the optical waveguide almost losslessly, either directly or after being modulated (through some optical elements).
- the wide spectrum response filter outputs different modulated spectra according to pre-made response rules and irradiates the sample to be tested. Although the light beam will be scattered when passing through the sample to be tested, and its disorder and optical expansion increase, it can still be received by the photodetector.
- Each photodetector can measure light signals of different wavelengths and convert them into electrical signals.
- By setting up multiple photodetectors for two A 3D array or a one-dimensional array (such as a ring or a parabola) can increase the coverage area and range, so that scattered light at different angles passing through the sample (or samples) to be tested can be detected as much as possible. Therefore, this solution can reduce the loss of light in the transmission link, so that more light can enter the wide-spectrum response filter and be fully received by the photodetector after being scattered by the sample to be tested.
- the utilization rate of light in the whole process is improved, and the endurance of the equipment is also improved due to the reduction of light source energy consumption.
- the present invention is further preferably provided with an optical window for placing the sample to be tested between the output end of the wide spectrum response filter and the photodetector; the output end of the wide spectrum response filter faces the optical window at an illumination angle to generate scattered light on the surface of the sample to be tested; the photodetector is arranged around the illumination center of the output end of the wide spectrum response filter on the optical window to receive scattered light intensity information; the angle between the direction of the photodetector to the illumination center and the optical window is the receiving angle, and the receiving angle is (0°, 90°].
- the illumination angle is further preferably 90°, and the photodetector surrounds the periphery of the wide spectrum response filter.
- a space for placing the sample to be tested is provided between the output end of the wide spectrum response filter and the photodetector, and the output end of the wide spectrum response filter generates transmitted light through the sample to be tested in the space.
- the wide spectrum response filter is a tunable filter, and only one wide spectrum response filter is provided; when in use, the tunable filter can form multiple optical channels in time sequence through multiple tunings to output different modulation spectra to establish the spectral response matrix.
- the wide spectrum response filter is a filter with an optical waveguide structure.
- the filter of the optical waveguide structure is a Fabry-Perot filter.
- the filter of the optical waveguide structure is a Bragg grating filter.
- the present invention is further preferably that the filter of the optical waveguide structure is a Mach-Zehnder interference filter Wave device.
- the present invention is further preferably configured on a miniaturized, portable or wearable device when in use.
- the filter of the optical waveguide structure is a filter of a single-mode waveguide structure.
- the filter of the optical waveguide structure is a filter of a multimode waveguide structure.
- optical etendue of waveguide filters is lower, and the orderliness of photons coupled into the waveguide is higher, so the coupling efficiency is more significantly improved.
- their relationship is: single-mode waveguide ⁇ multi-mode waveguide ⁇ slit.
- the photodetector is a planar photodetector, and the photodetector is only provided with one.
- a planar photodetector is a special type of photodetector, also known as a planar array photodetector. It is composed of a plurality of photodetector units, which are arranged on a two-dimensional plane to form an array structure. Each unit can independently measure the optical signal and convert it into an electrical signal.
- surface photodetectors Compared with photodetector arrays, surface photodetectors have the advantages of high spatial resolution, real-time imaging, easy integration and high sensitivity.
- the surface photodetectors are arranged in two dimensions, they can provide higher spatial resolution; surface photodetectors can acquire two-dimensional image data in real time, and they can simultaneously capture the entire image in a short time; surface photodetectors usually integrate multiple photodetector units on a chip, and this integrated structure makes them more compact and convenient to use, and can be easily integrated with other electronic devices and systems; surface photodetectors improve sensitivity by measuring multiple light signals at the same time. These light signals can enter the photodetector unit from different angles or positions, thereby enhancing the ability to receive light. Therefore, surface photodetectors can also be set on a hemispherical surface with the irradiation center of the sample to be tested as the sphere center to receive light at different angles. of scattered light.
- planar photodetector can be regarded as a special case of a photodetector array, that is, photodetectors arranged on a two-dimensional plane.
- the spectral width of the light source is above 200 nm, 500 nm or 1000 nm.
- the light sources are all SLED light sources, and all the SLED light sources cover the range of the spectrum width when working simultaneously.
- the present invention is further preferably provided with a first lens at the output end of the wide spectrum response filter to increase the light intensity of the modulated spectrum on the sample to be measured; or, provided with a second lens before the photodetector to enable the photodetector to collect light in a larger spatial range.
- the present invention also provides a spectral calculation and reconstruction method in the second aspect, including constructing a spectral response matrix, establishing an underdetermined set of equations, solving the underdetermined set of equations and spectral reconstruction; wherein the spectral response matrix and the underdetermined set of equations are respectively established by the spectrometer described in the first aspect.
- the spectrum calculation and reconstruction method provided by the present invention is similar to the beneficial effect reasoning process of the aforementioned spectrometer, and will not be repeated here.
- the present invention further provides a computer device in a third aspect, comprising a memory and a processor, wherein the memory stores a computer program, and the processor implements the spectral calculation and reconstruction method as described in the second aspect when executing the computer program.
- FIG1 is a schematic diagram of the principle of the spectrometer described in the present invention.
- FIG. 2 is a schematic diagram of the structure of a spectrometer according to an exemplary embodiment, showing a multi-light source and multi-filter structure.
- FIG. 3 is a schematic diagram of the structure of a spectrometer according to an exemplary embodiment, showing an adjustable broadband filter and a planar photodetector.
- FIG4 is a schematic structural diagram of a spectrometer in an exemplary embodiment, showing a spectrometer applied to a smart watch or a wristband.
- FIG5 is a schematic diagram of the structure of the spectrometer in an exemplary embodiment, showing how to implement time-division multiplexing of a broadband light source and a photodetector by switching filters.
- references in this specification to "one embodiment” or “an example” or “an example” mean that a particular feature, structure, or characteristic described in conjunction with the embodiment itself may be included in at least one embodiment of the present patent disclosure.
- the appearance of the phrase “in one embodiment” in various places in the specification does not necessarily refer to the same embodiment.
- the light source of the existing spectrometer has a large loss during the link transmission process.
- the inventor found that the principle of the spectrometer determines that the light beam must enter the spectrometer from a very small size in order to effectively distinguish the spectral information.
- the input end of the commonly used spectrometer is usually made into a slit or optical fiber.
- the light beam will be scattered after passing through the sample, and its disorder and optical expansion will increase, resulting in a large loss of coupling into the slit or optical fiber.
- Energy which means that the detector array at the receiving end must have very high sensitivity and responsiveness. On the one hand, this places extremely high demands on the detector array, which will increase the cost.
- due to link loss the resolution of weak transmitted or scattered light is very poor.
- the general spectrometer solution requires the light source to illuminate the sample to be tested, which will produce scattered light. Due to the disorder and increased optical expansion of the scattered light, it cannot be concentrated and directed through the slit or optical fiber to enter the filter, resulting in link loss. The loss is usually between 10% and 99.9%. The smaller the slit or the smaller the optical fiber aperture, the higher the resolution, and the greater the loss. For the application of photonic chip spectrometers, especially computational reconstruction spectrometers, it is necessary to couple the spatial diffraction light into a single-mode optical fiber or waveguide, and its loss can be above 99%. If the above-mentioned computational reconstruction spectrometer is integrated into a miniaturized, portable or wearable device, it will also be a serious test for battery life, which will seriously hinder its application in miniaturized, portable or wearable devices.
- this embodiment proposes a computational reconstruction spectrometer, including a light source, at least one wide-spectrum response filter, at least one photodetector, and a working area for placing a sample to be tested.
- the working area is arranged at the output end of the wide spectrum response filter, which can also be said to be the case that the wide spectrum response filter is placed before the sample to be tested.
- the light generated by the wide spectrum light source directly or after being modulated (through some optical elements) first enters the wide spectrum response filter through an optical waveguide, then irradiates the sample to be tested and is scattered, and finally is received by a photodetector.
- the order of light in the original link transmission process is changed.
- the light source produces relatively orderly light with small optical expansion, which passes through the optical waveguide almost losslessly into the wide spectrum response filter.
- the coverage area or range can be increased, so that as much scattered light passing through the sample to be tested can be detected as much as possible.
- the loss of light in the transmission link can be reduced, allowing more light to enter the wide-spectrum response filter and be fully received by the photodetector after being scattered by the sample to be tested.
- the utilization rate of light in the whole process is improved, and the battery life is also improved due to the reduction in light source energy consumption.
- the wide spectrum response filter used is a spatial coupling filter
- its loss can be ignored.
- the wide spectrum response filter adopts an integrated photonic chip its coupling loss is less than 30%.
- the huge difference in loss leads to different tolerance to noise.
- the noise introduced by the photodetector and circuit is 20dB on the filter pre-structure spectrometer, and the noise introduced in the general spectrometer may be 2dB (1:70 signal intensity), which is a great degradation of the spectrometer indicators.
- the traditional solution is to improve the light source, PD (photodetector), or circuit, which requires the light source optical power to increase 70 times or the PD and circuit noise to reduce 70 times to achieve the same effect.
- the invention can solve the above problems by only changing the position of the filter.
- the scheme of the present invention greatly improves the performance of the spectrometer, and will have a beneficial effect in any field where the spectrometer can be applied, especially in the field of weak spectrum detection.
- Specific fields may include spectral analysis in the field of communications, spectral monitoring of harmful gases, spectral monitoring of water quality, spectral monitoring of various substances in the human body (blood oxygen, blood lactate, blood sugar, blood lipids, etc.), and spectral monitoring of soil.
- the light source adopts a broad spectrum light source, and its spectrum width can be designed to be above 60nm, above 200nm, or above 500nm, or above 1000nm.
- the broad spectrum light source includes a plurality of light sources located in different wavelength ranges and capable of working independently of each other. According to the needs of the actual application scenario, several of them can be selectively combined to work.
- the light source can also adopt a single light source with a narrow spectrum width, which can also be selected according to the actual situation for the specific application.
- the wide spectrum light source is preferably a plurality of SLED light sources, and all the SLED light sources cover the range of the spectrum width when working simultaneously.
- SLED is the abbreviation of Superluminescent Light Emitting Diode, which is a special type of light emitting diode. Compared with traditional light emitting diodes (LEDs), SLEDs have a wider spectrum bandwidth and higher brightness.
- SLED The working principle of SLED is similar to that of LED, but it is different in structure. It is usually composed of a series of semiconductor material layers, including a light-emitting layer and a light-reflecting layer. This structure generates light by stimulated radiation when an excitation current passes through it. Due to the optical enhancement mechanism in SLED, it can provide a wider spectral bandwidth and higher output power than ordinary LEDs.
- the wavelength range of SLED depends on its specific design and manufacturing. Common SLED wavelength ranges include visible light, near infrared light, and mid-infrared light. In the visible light range, the wavelength of SLED is usually between 400 nanometers and 700 nanometers. In the near infrared range, the wavelength can extend from 800 nanometers to thousands of nanometers. For the mid-infrared range, the wavelength can extend from a few micrometers to more than ten micrometers.
- SLED wavelength range depends on factors such as material selection, device structure and manufacturing process. Different SLED products may have different wavelength ranges and output power characteristics, so the present invention needs to make appropriate selections according to application requirements when selecting and using them.
- the spectrometer is configured on a miniaturized, portable or wearable device
- the wide spectrum response filter has an input end and an output end, and its input end is connected to the wide spectrum light source through an optical waveguide.
- the wide spectrum response filter is configured to receive and respond to the spectrum of the wide spectrum light source through the optical waveguide, and output different modulated spectra at its output end according to a pre-made response rule.
- the wide spectrum response filter is a tunable filter, and only one wide spectrum response filter may be provided.
- the tunable filter can form multiple optical channels in time sequence through multiple tunings to output different modulation spectra to establish the spectrum response matrix.
- Tunable filters can use liquid crystal filters (Liquid Crystal Filters), which use the electro-optical effect of liquid crystal materials to adjust the spectral range passing through the filter. By controlling the applied voltage, the wavelength range can be adjusted. Liquid crystal filters can be adjusted within a wide wavelength range and have high optical transmittance and modulation speed.
- Liquid Crystal Filters Liquid Crystal Filters
- Tunable filters can also use acousto-optic tunable filters (AOTF), which use the acousto-optic effect to adjust the transmission characteristics of light. It changes the refractive index of light by applying acoustic vibrations, thereby achieving wavelength selection. AOTF can be quickly and accurately adjusted over a wide range of wavelengths.
- AOTF acousto-optic tunable filters
- Tunable filters can also use thermal tunable filters, which are devices that use thermal effects to change the optical properties of the filter. They usually use heat sources and temperature control systems to change the operating temperature of the filter, thereby adjusting its transmission or reflection characteristics.
- the wide spectrum response filter is a filter of an optical waveguide structure.
- the filter of the optical waveguide structure is a Fabry-Perot filter.
- the Fabry-Perot filter uses the interference effect between optical waveguides to achieve filtering function. It is composed of an air cavity between two reflectors, at least one of which is translucent. By adjusting the cavity length or changing the transmittance of the reflector, light of a specific wavelength can be selectively transmitted or reflected.
- the filter of the optical waveguide structure can also be a Bragg grating filter.
- the Bragg grating filter uses a periodic refractive index modulation structure to selectively reflect or transmit light of a specific wavelength through the Bragg reflection effect.
- This filter is usually composed of a periodic refractive index modulation area on an optical waveguide, and different filtering characteristics can be achieved by changing the period and depth of the refractive index modulation area.
- the filter of the optical waveguide structure can also be a Mach-Zehnder interference filter.
- the Mach-Zehnder interference filter uses the interference effect in the optical waveguide to achieve the filtering function. It consists of a beam splitter, two optical waveguide transmission paths and a recoupler. By adjusting the path length or phase difference, light of a specific wavelength can be selectively transmitted or reflected.
- the wide spectrum response filter here refers to a filter having a wide spectral width range of the response spectrum.
- the wide spectrum response filter includes a plurality of filters arranged in space or a filter that is adjustable in time sequence. If the spectral width of the spectrum is X, and the corresponding spectral width of n spatially arranged wide spectrum response filters is X 1 -X n , then X 1 ⁇ X 2 ⁇ ... ⁇ X n ⁇ X; if the spectral width of the spectrum is X, an adjustable filter can modulate n filters with corresponding spectral widths of X 1 -X n in time sequence, then X 1 ⁇ X 2 ⁇ ... ⁇ X n ⁇ X is also satisfied.
- the photodetector is used to collect the scattered or transmitted light intensity information of the sample to be tested after being irradiated with different modulated spectra.
- multiple photodetectors are arranged in a two-dimensional array or a one-dimensional array (such as a ring or a parabola), which can increase the coverage area (range) so that as much scattered light as possible passing through the sample to be tested (or sample) can be detected.
- the photodetector is a surface photodetector, see Figures 3 and 4, the surface photodetector can be regarded as a special case of a photodetector array, that is, a photodetector arranged on a two-dimensional plane, so there can be only one photodetector.
- the wide-spectrum filters when only one surface photodetector is used, it may correspond to multiple channels or multiple wide-spectrum filters.
- time-sharing multiplexing of the wide-spectrum light source and the photodetector can be achieved. This can not only improve the signal strength, but also ensure that the spectral distribution of the light source and the response distribution of the photodetector are completely consistent, further increasing the signal-to-noise ratio and obtaining better spectral recovery results.
- a channel space can be set at the output end of the wide spectrum response filter and the photodetector to form the working area so that the sample to be tested can enter. This is mainly used to detect transparent or translucent samples, such as gases and liquids.
- another method is to set an optical window between the output end of the wide spectrum response filter and the photodetector.
- transparent glass can be used as the optical window.
- the working area is used to place the sample to be tested. This situation is mainly used when the sample to be tested cannot be destroyed or divided.
- the spectrometer is configured on a smart watch to detect the composition of a substance in the subcutaneous blood vessels of the human body.
- the sample to be tested can only be used as an inhomogeneous medium or particle. When the light encounters the microstructure, particles or other scattering centers inside the material, the light deviates or changes the propagation direction in all directions. These scattered lights can be collected by photodetectors.
- a first lens may be provided between the output end of the wide spectrum response filter and the sample to be tested to focus or collimate the light, so that the light irradiated to the sample to be tested is stronger, and the area will be more concentrated when scattered, which is helpful to obtain a scattering spectrum with better uniformity.
- a second lens may be provided between the sample to be tested and the photodetector to focus the light, so as to collect light in a larger spatial range onto the photodetector, thereby increasing the signal-to-noise ratio.
- the light source will be used to irradiate the human skin. Since the adaptability of the human skin has a threshold, there will be a small amount of loss of the light source after passing through the filter.
- the spectrometer with the filter in front can not only reduce the intensity of the light source, but also make full use of the loss of the filter to reduce the stimulation of the light source to the human skin.
- the existing spectrometer that uses the light source to pass through the sample to be tested first will undoubtedly increase the intensity of irradiation on the human skin because it requires a high-power light source. Excessive irradiation will cause discomfort to people with sensitive skin, and even cause a burning sensation.
- a working surface for attaching a sample to be tested is provided on one side of the transparent glass, and the working area is located on the side where the working surface is located.
- the output end of the wide spectrum response filter faces the working surface at an illumination angle, and the photodetector is arranged around the illumination center of the output end of the wide spectrum response filter on the working surface.
- the illumination angle is the angle between the direction from the output end of the wide spectrum response filter to the illumination center and the working surface.
- the angle between the direction from the photodetector to the illumination center and the working surface is the receiving angle, which is (0°, 90°).
- the illumination angle is 90°
- the photodetector surrounds the periphery of the wide spectrum response filter.
- the photodetector is a surface photodetector, which is an annular surface and is on a hemispherical surface with the illumination center of the sample to be tested as the sphere center.
- the illumination angle is 45°
- the photodetector is half-surrounded on one side of the wide spectrum response filter.
- the photodetector in which the illumination angle and the receiving angle are on the same plane is used as an example for explanation, and the receiving angle in the figure is taken as 45° as an example.
- This embodiment also provides a spectrum calculation and reconstruction method, including constructing a spectrum response matrix, establishing an underdetermined equation group, solving the underdetermined equation group and spectrum reconstruction, wherein the spectrum response matrix and the underdetermined equation group are respectively established by the above-mentioned spectrometer.
- spectral response matrix Constructing the spectral response matrix: First, a set of samples of known input spectra need to be obtained through experiments or simulations, and the corresponding output signals need to be measured. These input spectra can be a series of samples of known wavelengths and light intensities. By simulating or experimentally measuring the input spectra through the optical system of the computational reconstruction spectrometer, the corresponding output signals can be obtained. These input spectra and the corresponding output signals are used as data to construct a spectral response matrix.
- an underdetermined system of equations Based on the principle of computational reconstruction spectrometer and the spectral response matrix, an underdetermined system of equations can be established.
- the unknown quantity of the system of equations is the spectrum of the sample to be measured, and the equations of the system of equations come from the relationship between the input spectrum and the output signal, which is mapped through the spectral response matrix.
- Spectral reconstruction By solving the underdetermined equations, the spectrum estimation result of the sample to be tested can be obtained. This estimation result can represent the spectrum information of the sample to be tested under the computational reconstruction spectrometer.
- the spectrometer includes a broadband light source (non-laser light source, 3dB bandwidth>1nm), multiple broadband filters, samples to be tested, and multiple photodetectors.
- the broadband light source passes through different broadband filters, and the spectrum is modulated. Different modulated spectra are absorbed or scattered by the sample after irradiating the sample, and the light intensity signal is collected by a photodetector, i.e., PD.
- the spectral range to be detected is decomposed into multiple segments, corresponding to ( ⁇ 1, ⁇ 2, ⁇ 3, ... ⁇ n).
- the intensity distribution of a broadband light source on the spectrum is represented by a vector (A ⁇ 1 ,A ⁇ 2 ,A ⁇ 3 ,...A ⁇ n );
- the filtering curve of the wide spectrum filter is represented by the vector (f ⁇ 1 ,f ⁇ 2 ,f ⁇ 3 ,...f ⁇ n );
- the spectral characteristics of the sample to be tested are represented by the vector (X ⁇ 1 ,X ⁇ 2 ,X ⁇ 3 ,...X ⁇ n );
- the response curve of the photodetector is represented by the vector (D ⁇ 1 , D ⁇ 2 , D ⁇ 3 , ... D ⁇ n ).
- the light emitted by the broadband light source passes through the broadband filter and its intensity is modulated to (A ⁇ 1 f ⁇ 1 ,A ⁇ 2 f ⁇ 2 ,A ⁇ 3 f ⁇ 3 ,...A ⁇ n f ⁇ n ),
- a ⁇ n D ⁇ n f ⁇ n is determined by the device selected by the system and is a known item. To simplify the description, this parameter is subsequently expressed by Sn .
- X ⁇ n is the spectral characteristic of the property to be measured and is an unknown item.
- this embodiment also provides a computer device, including a memory and a processor, wherein the memory stores a computer program, and the processor implements the steps of the above-mentioned spectrum calculation and reconstruction method when executing the computer program.
- the computer device can be a wearable device such as a smart watch, a smart bracelet, a smart helmet, etc.
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Abstract
Description
本发明涉及光谱检测技术领域,具体涉及一种光谱仪、光谱重构方法、及计算机设备。The present invention relates to the technical field of spectrum detection, and in particular to a spectrometer, a spectrum reconstruction method, and a computer device.
物质的光谱特性包含了大量的信息,在物理和化学上可以用于检测物质的成分,在生物学上可以用于检测机体的病变信息等。The spectral characteristics of a substance contain a large amount of information, which can be used to detect the composition of the substance in physics and chemistry, and to detect pathological information of the body in biology.
传统的光谱特性检测方法通常是通过扫频激光器或者光谱仪来实现的。Traditional spectral characteristic detection methods are usually achieved through swept lasers or spectrometers.
扫频激光器检测方法的工作原理是激光器单波长输出,通过照射待测样品并收集散射或透射光获取单波长的散射或吸收信息,然后通过扫频激光器的扫频功能逐个波长进行扫描获得整个光谱的特性信息。这种方法需要逐个波长扫描,当所需波长点数较多时,会大量增加工作时间,一方面时间成本增加,另一方面对于某些快速发生变化的样品来说也不适合。扫频激光器的价格也比较昂贵,体积和质量都较大,如果所需光谱信息的波长范围较大,可能单个扫频激光器还无法满足应用需求,会进一步增加成本、体积和质量。The working principle of the swept laser detection method is that the laser outputs a single wavelength, obtains the scattering or absorption information of a single wavelength by irradiating the sample to be tested and collecting the scattered or transmitted light, and then scans each wavelength through the sweep function of the swept laser to obtain the characteristic information of the entire spectrum. This method requires scanning wavelength by wavelength. When the number of required wavelength points is large, the working time will increase significantly. On the one hand, the time cost increases, and on the other hand, it is not suitable for some samples that change rapidly. The price of swept lasers is also relatively expensive, and the size and mass are large. If the wavelength range of the required spectral information is large, a single swept laser may not be able to meet the application requirements, which will further increase the cost, volume and mass.
而光谱仪检测方法的工作原理是使用宽谱光源照射样品,散射或透射光被收集进入光谱仪,通过光谱仪获取不同波长光的强度信息,从而推算出样品的散射和吸收特性。使用这种结构的光谱仪在收集散射或透射光进入光谱仪的过程中会存在一定的损耗。对于这种光谱仪来说,其宽谱光源多为独立供电的,即使在光链路传输中存在很大的损耗,也可以通过增加光源的功率来弥补,并不会对检测产生影响。The working principle of the spectrometer detection method is to use a wide-spectrum light source to illuminate the sample, and the scattered or transmitted light is collected and enters the spectrometer. The intensity information of light of different wavelengths is obtained through the spectrometer, so as to infer the scattering and absorption characteristics of the sample. A spectrometer using this structure will have certain losses in the process of collecting scattered or transmitted light entering the spectrometer. For this type of spectrometer, its wide-spectrum light source is mostly independently powered. Even if there is a large loss in the optical link transmission, it can be compensated by increasing the power of the light source, and it will not affect the detection.
虽然在一些小型化、便携式或可穿戴的设备中可以设置计算重构式光谱仪 来减小体积,但是某些情况下依然会存在上述同样的问题,受限于设备的体积和电池容量,既要保证检测结果可靠,又要降低光源的功耗,提高设备的续航是本领域技术人员急需解决的问题。Although computational reconstruction spectrometers can be set up in some miniaturized, portable or wearable devices To reduce the size, but in some cases the same problem mentioned above still exists. Limited by the size of the device and the battery capacity, it is an urgent problem for technicians in this field to ensure the reliability of the detection results and reduce the power consumption of the light source and improve the battery life of the device.
发明内容Summary of the invention
本发明旨在一定程度上解决相关技术中的技术问题之一。为此,本发明提供了一种光谱仪、光谱重构方法、及计算机设备,能够降低对光源在链路传输中的损耗,从而降低光源的功耗,提高设备续航。The present invention aims to solve one of the technical problems in the related art to a certain extent. To this end, the present invention provides a spectrometer, a spectrum reconstruction method, and a computer device, which can reduce the loss of the light source in the link transmission, thereby reducing the power consumption of the light source and improving the endurance of the device.
为了达到上述目的,本发明在第一方面采用如下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions in the first aspect:
一种计算重构式光谱仪,包括:A computational reconstruction spectrometer, comprising:
光源;light source;
至少一个宽谱响应滤波器,所述宽谱响应滤波器具有输入端和输出端,其输入端接收与所述光源;所述宽谱响应滤波器响应于所述光源的光谱,按照预制的响应规则在其输出端输出不同的调制光谱,用以照射待测样品;以及,At least one wide spectrum response filter, the wide spectrum response filter having an input end and an output end, wherein the input end receives the light source; the wide spectrum response filter responds to the spectrum of the light source and outputs different modulated spectra at its output end according to a pre-made response rule to irradiate the sample to be tested; and
至少一个光电探测器,用于收集待测样品在经不同的调制光谱照射后的散射或者透射光强度信息。At least one photodetector is used to collect scattered or transmitted light intensity information of the sample to be tested after being irradiated with different modulated spectra.
现有技术中,光源先经过待测样品后,散射光由于无序性和光学扩展量增加,导致不能够集中定向的通过狭缝或光纤进入滤波器,存在链路损耗。相比于现有技术,本发明的计算重构式光谱仪,其在使用时光源因其比较有序且光学扩展量小,可以直接或在被调制(通过一些光学元件)后,几乎无损的通过光波导进入宽谱响应滤波器,宽谱响应滤波器按照预制的响应规则输出不同的调制光谱照射到待测样品上,光束在经过待测样品时虽然会被散射,其无序性和光学扩展量增加,但依然能够被光电探测器接收。每个光电探测器都可以测量不同波长的光信号,并将其转换为电信号。通过设置多个光电探测器进行二 维阵列或一维阵列(例如环形或抛物线),能增加覆盖面积和范围,让经过待测样品(或样品)的不同角度的散射光能够尽可能多的检测到。故本方案能够让光在传输链路上降低了损耗,使得更多的光能够进入宽谱响应滤波器并在被待测样品散射后,能够被光电探测器充分接收,整个过程光的利用率得到了提高,设备的续航也因光源能耗的降低而得到了提高。In the prior art, after the light source passes through the sample to be tested, the scattered light cannot enter the filter through the slit or optical fiber in a concentrated and directed manner due to the disorder and increased optical expansion, resulting in link loss. Compared with the prior art, the computational reconstruction spectrometer of the present invention, when in use, because the light source is relatively orderly and has a small optical expansion, it can enter the wide spectrum response filter through the optical waveguide almost losslessly, either directly or after being modulated (through some optical elements). The wide spectrum response filter outputs different modulated spectra according to pre-made response rules and irradiates the sample to be tested. Although the light beam will be scattered when passing through the sample to be tested, and its disorder and optical expansion increase, it can still be received by the photodetector. Each photodetector can measure light signals of different wavelengths and convert them into electrical signals. By setting up multiple photodetectors for two A 3D array or a one-dimensional array (such as a ring or a parabola) can increase the coverage area and range, so that scattered light at different angles passing through the sample (or samples) to be tested can be detected as much as possible. Therefore, this solution can reduce the loss of light in the transmission link, so that more light can enter the wide-spectrum response filter and be fully received by the photodetector after being scattered by the sample to be tested. The utilization rate of light in the whole process is improved, and the endurance of the equipment is also improved due to the reduction of light source energy consumption.
本发明进一步优选为,在所述宽谱响应滤波器的输出端和所述光电探测器之间设有用于放置待测样品的光学窗口;所述宽谱响应滤波器的输出端以一个照射角对着所述光学窗口,用以在待测样品表面产生散射光;所述光电探测器围绕所述宽谱响应滤波器的输出端在光学窗口上的照射中心设置以接收散射光强度信息;所述光电探测器到照射中心的方向与光学窗口之间的夹角为接收角,所述接收角为(0°,90°]。The present invention is further preferably provided with an optical window for placing the sample to be tested between the output end of the wide spectrum response filter and the photodetector; the output end of the wide spectrum response filter faces the optical window at an illumination angle to generate scattered light on the surface of the sample to be tested; the photodetector is arranged around the illumination center of the output end of the wide spectrum response filter on the optical window to receive scattered light intensity information; the angle between the direction of the photodetector to the illumination center and the optical window is the receiving angle, and the receiving angle is (0°, 90°].
本发明进一步优选为,所述照射角为90°,所述光电探测器环绕在所述宽谱响应滤波器的周边。In the present invention, the illumination angle is further preferably 90°, and the photodetector surrounds the periphery of the wide spectrum response filter.
本发明进一步优选为,在所述宽谱响应滤波器的输出端和所述光电探测器之间设有用于放置待测样品的空间,所述宽谱响应滤波器的输出端透过该空间中的待测样品产生透射光。In the present invention, it is further preferred that a space for placing the sample to be tested is provided between the output end of the wide spectrum response filter and the photodetector, and the output end of the wide spectrum response filter generates transmitted light through the sample to be tested in the space.
本发明进一步优选为,所述宽谱响应滤波器为可调谐滤波器,所述宽谱响应滤波器仅设有一个;所述可调谐滤波器在使用时通过多次调谐可在时序上形成多路光通道以输出的不同调制光谱来建立所述光谱响应矩阵。The present invention is further preferably that the wide spectrum response filter is a tunable filter, and only one wide spectrum response filter is provided; when in use, the tunable filter can form multiple optical channels in time sequence through multiple tunings to output different modulation spectra to establish the spectral response matrix.
本发明进一步优选为,所述宽谱响应滤波器为光波导结构的滤波器。In the present invention, it is further preferred that the wide spectrum response filter is a filter with an optical waveguide structure.
本发明进一步优选为,所述光波导结构的滤波器为Fabry-Perot滤波器。In the present invention, it is further preferred that the filter of the optical waveguide structure is a Fabry-Perot filter.
本发明进一步优选为,所述光波导结构的滤波器为Bragg光栅滤波器。In the present invention, it is further preferred that the filter of the optical waveguide structure is a Bragg grating filter.
本发明进一步优选为,所述光波导结构的滤波器为Mach-Zehnder干涉滤 波器。The present invention is further preferably that the filter of the optical waveguide structure is a Mach-Zehnder interference filter Wave device.
本发明进一步优选为,其在使用时被配置于小型化、便携式或可穿戴设备的上。The present invention is further preferably configured on a miniaturized, portable or wearable device when in use.
本发明进一步优选为,所述光波导结构的滤波器为单模波导结构的滤波器。It is further preferred that the filter of the optical waveguide structure is a filter of a single-mode waveguide structure.
本发明进一步优选为,所述光波导结构的滤波器为多模波导结构的滤波器。It is further preferred that the filter of the optical waveguide structure is a filter of a multimode waveguide structure.
波导滤波器的光学扩展量更低,对耦合进入波导内的光子的有序性要求更高,耦合效率提升更为明显。用光学扩展量衡量,则它们的关系是为:单模波导<多模波导<狭缝。The optical etendue of waveguide filters is lower, and the orderliness of photons coupled into the waveguide is higher, so the coupling efficiency is more significantly improved. Measured by optical etendue, their relationship is: single-mode waveguide < multi-mode waveguide < slit.
本发明进一步优选为,所述光电探测器为面光电探测器,所述光电探测器仅设有一个。面光电探测器是一种特殊类型的光电探测器,也称为面阵列光电探测器。它由多个光电探测器单元组成,这些单元排列在二维平面上形成阵列结构。每个单元都可以独立地测量光信号并转换为电信号。The present invention is further preferably that the photodetector is a planar photodetector, and the photodetector is only provided with one. A planar photodetector is a special type of photodetector, also known as a planar array photodetector. It is composed of a plurality of photodetector units, which are arranged on a two-dimensional plane to form an array structure. Each unit can independently measure the optical signal and convert it into an electrical signal.
面光电探测器相比于光电探测器阵列具有高空间分辨率、实时成像、方便集成和高灵敏度等优势。Compared with photodetector arrays, surface photodetectors have the advantages of high spatial resolution, real-time imaging, easy integration and high sensitivity.
由于面光电探测器是二维排列的,可以提供更高的空间分辨率;面光电探测器能够以实时的方式获取二维图像数据,它们可以在短时间内同时采集整个图像;面光电探测器通常在一个芯片上集成了多个光电探测器单元,这种集成结构使得它们更加紧凑和方便使用,可以轻松地与其他电子设备和系统集成;面光电探测器通过同时测量多个光信号来提高灵敏度。这些光信号可以从不同的角度或位置进入光电探测器单元,从而增强了对光的接收能力,故还可以在以待测样品的照射中心为球心的半球面上,设置面光电探测器,接收不同角度 的散射光。Since the surface photodetectors are arranged in two dimensions, they can provide higher spatial resolution; surface photodetectors can acquire two-dimensional image data in real time, and they can simultaneously capture the entire image in a short time; surface photodetectors usually integrate multiple photodetector units on a chip, and this integrated structure makes them more compact and convenient to use, and can be easily integrated with other electronic devices and systems; surface photodetectors improve sensitivity by measuring multiple light signals at the same time. These light signals can enter the photodetector unit from different angles or positions, thereby enhancing the ability to receive light. Therefore, surface photodetectors can also be set on a hemispherical surface with the irradiation center of the sample to be tested as the sphere center to receive light at different angles. of scattered light.
需要注意的是,实际上,面光电探测器可以看作是一种光电探测器阵列的特例,即在二维平面上排列的光电探测器。It should be noted that, in fact, a planar photodetector can be regarded as a special case of a photodetector array, that is, photodetectors arranged on a two-dimensional plane.
本发明进一步优选为,所述光源的谱宽在200nm或500nm或1000nm以上。It is further preferred that the spectral width of the light source is above 200 nm, 500 nm or 1000 nm.
本发明进一步优选为,所述光源均为SLED光源,所有的SLED光源同时工作时覆盖所述谱宽的范围。It is further preferred that the light sources are all SLED light sources, and all the SLED light sources cover the range of the spectrum width when working simultaneously.
本发明进一步优选为,在所述宽谱响应滤波器的输出端设有第一透镜,以增加调制光谱在待测样品上的光强;或者,在所述光电探测器之前设有第二透镜,以使光电探测器能收集更大空间范围的光。The present invention is further preferably provided with a first lens at the output end of the wide spectrum response filter to increase the light intensity of the modulated spectrum on the sample to be measured; or, provided with a second lens before the photodetector to enable the photodetector to collect light in a larger spatial range.
此外,本发明在第二方面还提供了一种光谱计算重构方法,包括构建光谱响应矩阵、建立欠定方程组、求解欠定方程组和光谱重构;其中光谱响应矩阵和欠定方程组分别是通过第一方面中所述的光谱仪建立。In addition, the present invention also provides a spectral calculation and reconstruction method in the second aspect, including constructing a spectral response matrix, establishing an underdetermined set of equations, solving the underdetermined set of equations and spectral reconstruction; wherein the spectral response matrix and the underdetermined set of equations are respectively established by the spectrometer described in the first aspect.
本发明所提供的光谱计算重构方法与前述光谱仪的有益效果推理过程相似,在此不再赘述。The spectrum calculation and reconstruction method provided by the present invention is similar to the beneficial effect reasoning process of the aforementioned spectrometer, and will not be repeated here.
并且,本发明在第三方面还提供了一种计算机设备,包括存储器和处理器,所述存储器存储有计算机程序,所述处理器执行所述计算机程序时实现如第二方面所述的光谱计算重构方法。Furthermore, the present invention further provides a computer device in a third aspect, comprising a memory and a processor, wherein the memory stores a computer program, and the processor implements the spectral calculation and reconstruction method as described in the second aspect when executing the computer program.
本发明的这些特点和优点将会在下面的具体实施方式以及附图中进行详细的揭露。本发明最佳的实施方式或手段将结合附图来详尽表现,但并非是对本发明技术方案的限制。另外,在每个下文和附图中出现的这些特征、要素和组件是具有多个,并且为了表示方便而标记了不同的符号或数字,但均表示相同或相似构造或功能的部件。These features and advantages of the present invention will be disclosed in detail in the following specific embodiments and drawings. The best embodiments or means of the present invention will be described in detail in conjunction with the drawings, but they are not intended to limit the technical solutions of the present invention. In addition, there are multiple features, elements, and components that appear in each of the following texts and drawings, and different symbols or numbers are marked for convenience, but they all represent components with the same or similar structures or functions.
下面结合附图对本发明作进一步说明:The present invention will be further described below in conjunction with the accompanying drawings:
图1是本发明中所述光谱仪的原理示意图。FIG1 is a schematic diagram of the principle of the spectrometer described in the present invention.
图2是一示范性实施例中所述的光谱仪的结构示意图,示出了多光源多滤波器结构。FIG. 2 is a schematic diagram of the structure of a spectrometer according to an exemplary embodiment, showing a multi-light source and multi-filter structure.
图3是一示范性实施例中所述的光谱仪的结构示意图,示出了可调宽普滤波器和面光电探测器。FIG. 3 is a schematic diagram of the structure of a spectrometer according to an exemplary embodiment, showing an adjustable broadband filter and a planar photodetector.
图4是一示范性实施例中所述光谱仪的结构示意图,示出了一种应用在智能手表或手环上的光谱仪。FIG4 is a schematic structural diagram of a spectrometer in an exemplary embodiment, showing a spectrometer applied to a smart watch or a wristband.
图5是一示范性实施例中所述光谱仪的结构示意图,示出了切换滤波器的方式实现对宽谱光源和光电探测器分时复用。FIG5 is a schematic diagram of the structure of the spectrometer in an exemplary embodiment, showing how to implement time-division multiplexing of a broadband light source and a photodetector by switching filters.
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。基于实施方式中的实施例,旨在用于解释本发明,而不能理解为对本发明的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements with the same or similar functions. The embodiments in the implementation manner are intended to be used to explain the present invention and should not be construed as limiting the present invention.
在本说明书中引用的“一个实施例”或“实例”或“例子”意指结合实施例本身描述的特定特征、结构或特性可被包括在本专利公开的至少一个实施例中。短语“在一个实施例中”在说明书中的各位置的出现不必都是指同一个实施例。References in this specification to "one embodiment" or "an example" or "an example" mean that a particular feature, structure, or characteristic described in conjunction with the embodiment itself may be included in at least one embodiment of the present patent disclosure. The appearance of the phrase "in one embodiment" in various places in the specification does not necessarily refer to the same embodiment.
现有光谱仪的光源在链路传输过程中损耗较大,发明人发现是由于光谱仪的原理决定了光束必须从一个很小的尺寸进入光谱仪才可以有效地分辨光谱信息,常用的光谱仪输入端通常会做成狭缝或者光纤,经过样品后的光束会被散射,其无序性和光学扩展量会增加,导致耦合进入狭缝或者光纤会损耗大量 能量,这就代表接收端的探测器阵列必须有非常高的灵敏度和响应度。一方面这对探测器阵列要求极高,会提升成本,另一方面由于链路损耗导致对于微弱的透射或者散射光的分辨能力非常差。The light source of the existing spectrometer has a large loss during the link transmission process. The inventor found that the principle of the spectrometer determines that the light beam must enter the spectrometer from a very small size in order to effectively distinguish the spectral information. The input end of the commonly used spectrometer is usually made into a slit or optical fiber. The light beam will be scattered after passing through the sample, and its disorder and optical expansion will increase, resulting in a large loss of coupling into the slit or optical fiber. Energy, which means that the detector array at the receiving end must have very high sensitivity and responsiveness. On the one hand, this places extremely high demands on the detector array, which will increase the cost. On the other hand, due to link loss, the resolution of weak transmitted or scattered light is very poor.
一般光谱仪方案需要将光源照射待测样品,会产生散射光,散射光由于无序性和光学扩展量增加,导致不能够集中定向的通过狭缝或光纤进入滤波器,存在链路损耗,损耗通常在10%-99.9%之间,狭缝越小或光纤通光孔径越小,分辨率就越高,同时损耗增大。对于光子芯片光谱仪的应用,尤其是计算重构式光谱仪,需要将空间衍射光耦合进入单模光纤或波导,其损耗可在99%以上。若在小型化、便携式或可穿戴设备集成上述的计算重构式光谱仪时,对于续航也是个严重的考验,将严重阻碍了其在小型化、便携式或可穿戴设备上应用。The general spectrometer solution requires the light source to illuminate the sample to be tested, which will produce scattered light. Due to the disorder and increased optical expansion of the scattered light, it cannot be concentrated and directed through the slit or optical fiber to enter the filter, resulting in link loss. The loss is usually between 10% and 99.9%. The smaller the slit or the smaller the optical fiber aperture, the higher the resolution, and the greater the loss. For the application of photonic chip spectrometers, especially computational reconstruction spectrometers, it is necessary to couple the spatial diffraction light into a single-mode optical fiber or waveguide, and its loss can be above 99%. If the above-mentioned computational reconstruction spectrometer is integrated into a miniaturized, portable or wearable device, it will also be a serious test for battery life, which will seriously hinder its application in miniaturized, portable or wearable devices.
如图1所示,本实施例提出了一种计算重构式光谱仪,包括光源、至少一个宽谱响应滤波器、至少一个光电探测器和用于放置待测样品工作区。As shown in FIG. 1 , this embodiment proposes a computational reconstruction spectrometer, including a light source, at least one wide-spectrum response filter, at least one photodetector, and a working area for placing a sample to be tested.
所述工作区设置在所述宽谱响应滤波器的输出端,也可以说是将宽谱响应滤波器前置到待测样品之前,由宽谱光源产生的光直接或在被调制(通过一些光学元件)后,先通过光波导进入宽谱响应滤波器,再照射到待测样品上散射,最后被光电探测器接收。The working area is arranged at the output end of the wide spectrum response filter, which can also be said to be the case that the wide spectrum response filter is placed before the sample to be tested. The light generated by the wide spectrum light source directly or after being modulated (through some optical elements) first enters the wide spectrum response filter through an optical waveguide, then irradiates the sample to be tested and is scattered, and finally is received by a photodetector.
此过程中,改变了光在原有链路传输过程中的顺序,光源产生比较有序性且光学扩展量小的光,几乎无损的通过光波导进入宽谱响应滤波器,而后又通过设置多个光电探测器进行二维阵列或一维阵列(例如环形或抛物线),能增加覆盖面积或范围,让经过待测样品的散射光能够尽可能多的检测到。In this process, the order of light in the original link transmission process is changed. The light source produces relatively orderly light with small optical expansion, which passes through the optical waveguide almost losslessly into the wide spectrum response filter. Then, by setting up multiple photodetectors in a two-dimensional array or one-dimensional array (such as a ring or parabola), the coverage area or range can be increased, so that as much scattered light passing through the sample to be tested can be detected as much as possible.
所以能够让光在传输链路上降低了损耗,使得更多的光能够进入宽谱响应滤波器并在被待测样品散射后,能够被光电探测器充分接收,整个过程光的利用率得到了提高,续航也因光源能耗的降低而得到了提高。 Therefore, the loss of light in the transmission link can be reduced, allowing more light to enter the wide-spectrum response filter and be fully received by the photodetector after being scattered by the sample to be tested. The utilization rate of light in the whole process is improved, and the battery life is also improved due to the reduction in light source energy consumption.
在一些实施例中,如果所用宽谱响应滤波器为空间耦合滤波器,其损耗可以忽略不计。在另一些实施例中,如果宽谱响应滤波器采用集成光子芯片,其耦合损耗<30%。巨大的损耗差异带来对噪声的容忍度不同,如光电探测器和电路引入的噪声在滤波器前置结构光谱仪上为20dB,在一般光谱仪引入的噪声可能为2dB(1:70信号强度),这是光谱仪指标的极大劣化。传统的解决方案是对光源、PD(光电探测器),或者电路进行提升,需要光源光功率增加70倍或PD和电路噪声降低70倍才可以达到同样的效果。而发明仅改变滤波器位置即可解决上述问题。In some embodiments, if the wide spectrum response filter used is a spatial coupling filter, its loss can be ignored. In other embodiments, if the wide spectrum response filter adopts an integrated photonic chip, its coupling loss is less than 30%. The huge difference in loss leads to different tolerance to noise. For example, the noise introduced by the photodetector and circuit is 20dB on the filter pre-structure spectrometer, and the noise introduced in the general spectrometer may be 2dB (1:70 signal intensity), which is a great degradation of the spectrometer indicators. The traditional solution is to improve the light source, PD (photodetector), or circuit, which requires the light source optical power to increase 70 times or the PD and circuit noise to reduce 70 times to achieve the same effect. The invention can solve the above problems by only changing the position of the filter.
故本发明的方案对光谱仪性能的极大提高,在任何光谱仪可以应用的领域都会产生有益的作用,尤其是微弱光谱探测方面。具体领域可能包含通信领域的光谱分析、有害气体光谱监测、水质光谱监测、人体多种物质(血氧、血乳酸、血糖、血脂等)光谱监测、土壤光谱监测等。Therefore, the scheme of the present invention greatly improves the performance of the spectrometer, and will have a beneficial effect in any field where the spectrometer can be applied, especially in the field of weak spectrum detection. Specific fields may include spectral analysis in the field of communications, spectral monitoring of harmful gases, spectral monitoring of water quality, spectral monitoring of various substances in the human body (blood oxygen, blood lactate, blood sugar, blood lipids, etc.), and spectral monitoring of soil.
以下针对光源、宽谱响应滤波器和光电探测器的具体实施方式进行详细说明。The specific implementations of the light source, the wide spectrum response filter and the photodetector are described in detail below.
在具体的实施方式中,光源采用宽谱光源,其谱宽可以被设计在60nm以上,200nm以上,或500nm以上,或1000nm以上。宽谱光源包括多个位于不同波段范围且可相互独立工作的光源,根据实际应用场景的需要,可以选择性的组合其中几个进行工作。在一些实施例中,光源还可以采用谱宽较窄的单个光源,亦可,具体应用根据实际情况选择。In a specific embodiment, the light source adopts a broad spectrum light source, and its spectrum width can be designed to be above 60nm, above 200nm, or above 500nm, or above 1000nm. The broad spectrum light source includes a plurality of light sources located in different wavelength ranges and capable of working independently of each other. According to the needs of the actual application scenario, several of them can be selectively combined to work. In some embodiments, the light source can also adopt a single light source with a narrow spectrum width, which can also be selected according to the actual situation for the specific application.
如图2所示,宽谱光源均优选为多个SLED光源,所有的SLED光源同时工作时覆盖所述谱宽的范围。SLED是Superluminescent Light Emitting Diode(超亮发光二极管)的缩写,它是一种特殊类型的发光二极管。与传统的发光二极管(LED)相比,SLED具有更宽的光谱带宽和较高的亮度。 As shown in FIG2 , the wide spectrum light source is preferably a plurality of SLED light sources, and all the SLED light sources cover the range of the spectrum width when working simultaneously. SLED is the abbreviation of Superluminescent Light Emitting Diode, which is a special type of light emitting diode. Compared with traditional light emitting diodes (LEDs), SLEDs have a wider spectrum bandwidth and higher brightness.
SLED的工作原理类似于LED,但在结构上有所不同。它通常由一系列的半导体材料层组成,包括发光层和光反射层。这种结构在激发电流通过时,通过受激辐射的方式产生光。由于在SLED中存在光学增强机制,它可以提供比普通LED更宽的光谱带宽和较高的输出功率。The working principle of SLED is similar to that of LED, but it is different in structure. It is usually composed of a series of semiconductor material layers, including a light-emitting layer and a light-reflecting layer. This structure generates light by stimulated radiation when an excitation current passes through it. Due to the optical enhancement mechanism in SLED, it can provide a wider spectral bandwidth and higher output power than ordinary LEDs.
SLED的波长范围取决于其具体设计和制造。常见的SLED波长范围包括可见光、近红外光和中红外光。在可见光范围内,SLED的波长通常在400纳米到700纳米之间。而在近红外光范围内,波长可以从800纳米延伸到数千纳米。对于中红外光范围,波长可以从几微米延伸到十几微米。The wavelength range of SLED depends on its specific design and manufacturing. Common SLED wavelength ranges include visible light, near infrared light, and mid-infrared light. In the visible light range, the wavelength of SLED is usually between 400 nanometers and 700 nanometers. In the near infrared range, the wavelength can extend from 800 nanometers to thousands of nanometers. For the mid-infrared range, the wavelength can extend from a few micrometers to more than ten micrometers.
需要注意的是,具体的SLED波长范围取决于材料选择、器件结构和制造工艺等因素。不同的SLED产品可能有不同的波长范围和输出功率特性,因此本发明中在选择和使用时需要根据应用需求进行合适的选择。It should be noted that the specific SLED wavelength range depends on factors such as material selection, device structure and manufacturing process. Different SLED products may have different wavelength ranges and output power characteristics, so the present invention needs to make appropriate selections according to application requirements when selecting and using them.
在一些实施例中,所述光谱仪被配置于小型化、便携式或可穿戴设备上,所述宽谱响应滤波器具有输入端和输出端,其输入端与所述宽谱光源通过光波导相连。所述宽谱响应滤波器被配置为通过所述光波导接收并响应于所述宽谱光源的光谱,在其输出端按照预制的响应规则输出不同的调制光谱。In some embodiments, the spectrometer is configured on a miniaturized, portable or wearable device, the wide spectrum response filter has an input end and an output end, and its input end is connected to the wide spectrum light source through an optical waveguide. The wide spectrum response filter is configured to receive and respond to the spectrum of the wide spectrum light source through the optical waveguide, and output different modulated spectra at its output end according to a pre-made response rule.
为了减少宽谱响应滤波器的数量和在芯片中的占用空间,如图3所示,在一些实施例中,所述宽谱响应滤波器为可调谐滤波器,所述宽谱响应滤波器可以仅设有一个。所述可调谐滤波器在使用时通过多次调谐可在时序上形成多路光通道以输出的不同调制光谱来建立所述光谱响应矩阵。In order to reduce the number of wide spectrum response filters and the space occupied in the chip, as shown in Figure 3, in some embodiments, the wide spectrum response filter is a tunable filter, and only one wide spectrum response filter may be provided. When in use, the tunable filter can form multiple optical channels in time sequence through multiple tunings to output different modulation spectra to establish the spectrum response matrix.
可调谐滤波器可以选用液晶滤波器(Liquid Crystal Filter),利用液晶材料的电光效应来调节通过滤波器的光谱范围。通过控制施加的电压,可以实现波长范围的调整。液晶滤波器可以在较宽的波长范围内进行调节,并具有较高的光学透过率和调制速度。 Tunable filters can use liquid crystal filters (Liquid Crystal Filters), which use the electro-optical effect of liquid crystal materials to adjust the spectral range passing through the filter. By controlling the applied voltage, the wavelength range can be adjusted. Liquid crystal filters can be adjusted within a wide wavelength range and have high optical transmittance and modulation speed.
可调谐滤波器也可以选用声光可调滤波器(Acousto-Optic Tunable Filter,AOTF),利用声光效应来调节光的传输特性。它通过施加声波振动以改变光的折射率,从而实现波长选择。声光可调滤波器可以在广泛的波长范围内进行快速和精确的调节。Tunable filters can also use acousto-optic tunable filters (AOTF), which use the acousto-optic effect to adjust the transmission characteristics of light. It changes the refractive index of light by applying acoustic vibrations, thereby achieving wavelength selection. AOTF can be quickly and accurately adjusted over a wide range of wavelengths.
可调谐滤波器还可以选用热调滤波器,热调滤波器是一种利用热效应来改变滤波器的光学特性的器件。它通常使用热源和温度控制系统来改变滤波器的工作温度,从而调节其透过或反射特性。Tunable filters can also use thermal tunable filters, which are devices that use thermal effects to change the optical properties of the filter. They usually use heat sources and temperature control systems to change the operating temperature of the filter, thereby adjusting its transmission or reflection characteristics.
在一些示范性的实施例中,所述宽谱响应滤波器为光波导结构的滤波器。所述光波导结构的滤波器为Fabry-Perot滤波器。Fabry-Perot滤波器利用光波导之间的干涉效应实现滤波功能。它由两个反射镜之间的空气腔构成,其中至少一个镜面是半透明的。通过调节腔长或改变反射镜的透过率,可以选择性地传输或反射特定波长的光。In some exemplary embodiments, the wide spectrum response filter is a filter of an optical waveguide structure. The filter of the optical waveguide structure is a Fabry-Perot filter. The Fabry-Perot filter uses the interference effect between optical waveguides to achieve filtering function. It is composed of an air cavity between two reflectors, at least one of which is translucent. By adjusting the cavity length or changing the transmittance of the reflector, light of a specific wavelength can be selectively transmitted or reflected.
作为上述替代实施例之一,所述光波导结构的滤波器还可以为Bragg光栅滤波器。Bragg光栅滤波器利用周期性的折射率调制结构,通过布拉格反射效应选择性地反射或透射特定波长的光。这种滤波器通常由光波导上的周期性折射率调制区域构成,通过改变折射率调制区域的周期和深度,可以实现不同的滤波特性。As one of the above alternative embodiments, the filter of the optical waveguide structure can also be a Bragg grating filter. The Bragg grating filter uses a periodic refractive index modulation structure to selectively reflect or transmit light of a specific wavelength through the Bragg reflection effect. This filter is usually composed of a periodic refractive index modulation area on an optical waveguide, and different filtering characteristics can be achieved by changing the period and depth of the refractive index modulation area.
作为上述替代实施例之一,所述光波导结构的滤波器还可以为Mach-Zehnder干涉滤波器。Mach-Zehnder干涉滤波器利用光波导中的干涉效应实现滤波功能。它由分束器、两个光波导传输路径和再耦合器组成。通过调节路径长度或相位差,可以选择性地传输或反射特定波长的光。As one of the above alternative embodiments, the filter of the optical waveguide structure can also be a Mach-Zehnder interference filter. The Mach-Zehnder interference filter uses the interference effect in the optical waveguide to achieve the filtering function. It consists of a beam splitter, two optical waveguide transmission paths and a recoupler. By adjusting the path length or phase difference, light of a specific wavelength can be selectively transmitted or reflected.
需要说明的是,这里宽谱响应滤波器是指响应光谱的谱宽范围较宽,宽谱响应滤波器包括多个在空间上排布的滤波器或是一个在时序上可调的滤波器。 若光谱的谱宽为X,空间上排布的n个宽谱响应滤波器的对应谱宽为X1-Xn,则X1∪X2∪…∪Xn≥X;若光谱的谱宽为X,一个可调的滤波器可以在时序上分别调制出对应谱宽为X1-Xn的n个滤波器,则也满足X1∪X2∪…∪Xn≥X。It should be noted that the wide spectrum response filter here refers to a filter having a wide spectral width range of the response spectrum. The wide spectrum response filter includes a plurality of filters arranged in space or a filter that is adjustable in time sequence. If the spectral width of the spectrum is X, and the corresponding spectral width of n spatially arranged wide spectrum response filters is X 1 -X n , then X 1 ∪X 2 ∪…∪X n ≥X; if the spectral width of the spectrum is X, an adjustable filter can modulate n filters with corresponding spectral widths of X 1 -X n in time sequence, then X 1 ∪X 2 ∪…∪X n ≥X is also satisfied.
所述光电探测器用于收集所述待测样品在经不同的调制光谱照射后的散射或者透射光强度信息。为了让散射光能够在不同角度都被收集,通过设置多个光电探测器进行二维阵列或一维阵列(例如环形或抛物线),能增加覆盖面积(范围),让经过待测样品(或样品)的散射光能够尽可能多的检测到。在一些实施例中,所述光电探测器为面光电探测器,参见图3和图4,面光电探测器可以看作是一种光电探测器阵列的特例,即在二维平面上排列的光电探测器,故光电探测器可以仅设有一个。The photodetector is used to collect the scattered or transmitted light intensity information of the sample to be tested after being irradiated with different modulated spectra. In order to collect the scattered light at different angles, multiple photodetectors are arranged in a two-dimensional array or a one-dimensional array (such as a ring or a parabola), which can increase the coverage area (range) so that as much scattered light as possible passing through the sample to be tested (or sample) can be detected. In some embodiments, the photodetector is a surface photodetector, see Figures 3 and 4, the surface photodetector can be regarded as a special case of a photodetector array, that is, a photodetector arranged on a two-dimensional plane, so there can be only one photodetector.
需要说明的是,如图5所示,在仅采用一个面光电探测器,其可能对应多个通道或多个宽谱滤波器,通过切换宽谱滤波器的方式实现对宽谱光源和光电探测器分时复用,不仅可以提升信号强度,而且可以保证光源的光谱分布和光电探测器的响应分布完全一致,进一步增加了信噪比,获得更好的光谱恢复结果。It should be noted that, as shown in FIG5 , when only one surface photodetector is used, it may correspond to multiple channels or multiple wide-spectrum filters. By switching the wide-spectrum filters, time-sharing multiplexing of the wide-spectrum light source and the photodetector can be achieved. This can not only improve the signal strength, but also ensure that the spectral distribution of the light source and the response distribution of the photodetector are completely consistent, further increasing the signal-to-noise ratio and obtaining better spectral recovery results.
需要说明的是,宽谱响应滤波器、工作区,还有光电探测器的空间排布,存在两种实施方式。参见图1-3,一种是将工作区设置在宽谱响应滤波器的输出端和光电探测器的中间,从宽谱响应滤波器出来的光谱,可以直接穿过待测样品并产生透射光被光电探测器。在具体实施时,可以在宽谱响应滤波器的输出端和光电探测器设置一个通道空间来形成所述工作区,以便让待测样品进入。这种主要是用于检测透明或半透明样品,如气体,液体。It should be noted that there are two implementation methods for the spatial arrangement of the wide spectrum response filter, the working area, and the photodetector. Referring to Figures 1-3, one is to set the working area between the output end of the wide spectrum response filter and the photodetector, and the spectrum coming out of the wide spectrum response filter can directly pass through the sample to be tested and generate transmitted light to be detected by the photodetector. In the specific implementation, a channel space can be set at the output end of the wide spectrum response filter and the photodetector to form the working area so that the sample to be tested can enter. This is mainly used to detect transparent or translucent samples, such as gases and liquids.
参见图4,另一种是在宽谱响应滤波器的输出端和光电探测器之间设置光学窗口。具体实施时,可设置以透明玻璃作为光学窗口,透明玻璃表面即为可 以放置待测样品的工作区。这种情况主要用于待测样品不可被破坏、分割的情形下,例如光谱仪被配置在智能手表上用于检测人体皮下血管中某物质成分,只能利用待测样品为不均匀介质或微粒的特制,在光线遇到物质内部的微观结构、颗粒或其他散射中心时,光线在各个方向上发生偏离或改变传播方向。这些散射光可以被光电探测器收集。Referring to FIG4 , another method is to set an optical window between the output end of the wide spectrum response filter and the photodetector. In specific implementation, transparent glass can be used as the optical window. The working area is used to place the sample to be tested. This situation is mainly used when the sample to be tested cannot be destroyed or divided. For example, the spectrometer is configured on a smart watch to detect the composition of a substance in the subcutaneous blood vessels of the human body. The sample to be tested can only be used as an inhomogeneous medium or particle. When the light encounters the microstructure, particles or other scattering centers inside the material, the light deviates or changes the propagation direction in all directions. These scattered lights can be collected by photodetectors.
需要说明的是,在一些示范性实施例中,在宽谱响应滤波器的输出端和待测样品之间可以设置第一透镜进行聚光或准直,使得照射到待测样品的光更强,则在散射时区域会更集中,有助于获取均匀性较好的散射光谱。另外,也可以在待测样品和光电探测器之间设置第二透镜进行聚光,收集更大空间范围的光到光电探测器上,从而增加信噪比。It should be noted that, in some exemplary embodiments, a first lens may be provided between the output end of the wide spectrum response filter and the sample to be tested to focus or collimate the light, so that the light irradiated to the sample to be tested is stronger, and the area will be more concentrated when scattered, which is helpful to obtain a scattering spectrum with better uniformity. In addition, a second lens may be provided between the sample to be tested and the photodetector to focus the light, so as to collect light in a larger spatial range onto the photodetector, thereby increasing the signal-to-noise ratio.
此外,在光谱仪的使用过程中会用光源照射人体皮肤,由于人体皮肤的适应性存在一个阈值,光源经过滤波器也会存在少量的损耗,滤波器前置的光谱仪不仅能减少光源强度,还能够充分利用滤波器的损耗来减少光源对人体皮肤的刺激。而现有采用光源先经过待测样品的光谱仪,无疑会因需要高功耗的光源,增加了对人体皮肤的照射强度,过高强度的照射会对皮肤敏感的人带来不适,甚至会产生灼烧感。In addition, during the use of the spectrometer, the light source will be used to irradiate the human skin. Since the adaptability of the human skin has a threshold, there will be a small amount of loss of the light source after passing through the filter. The spectrometer with the filter in front can not only reduce the intensity of the light source, but also make full use of the loss of the filter to reduce the stimulation of the light source to the human skin. The existing spectrometer that uses the light source to pass through the sample to be tested first will undoubtedly increase the intensity of irradiation on the human skin because it requires a high-power light source. Excessive irradiation will cause discomfort to people with sensitive skin, and even cause a burning sensation.
在一些示范性的实施例中,在透明玻璃的一侧设有用于贴合待测样品的工作面,所述工作区位于所述工作面所在的一侧。所述宽谱响应滤波器的输出端以一个照射角对着所述工作面,所述光电探测器围绕所述宽谱响应滤波器的输出端在工作面上的照射中心设置。In some exemplary embodiments, a working surface for attaching a sample to be tested is provided on one side of the transparent glass, and the working area is located on the side where the working surface is located. The output end of the wide spectrum response filter faces the working surface at an illumination angle, and the photodetector is arranged around the illumination center of the output end of the wide spectrum response filter on the working surface.
其中,所述照射角是所述宽谱响应滤波器的输出端到照射中心的这个方向与工作面之间的夹角。所述光电探测器到照射中心的方向与工作面之间的夹角为接收角,所述接收角为(0°,90°]。 The illumination angle is the angle between the direction from the output end of the wide spectrum response filter to the illumination center and the working surface. The angle between the direction from the photodetector to the illumination center and the working surface is the receiving angle, which is (0°, 90°).
更具体地,所述照射角为90°,所述光电探测器环绕在所述宽谱响应滤波器的周边。所述光电探测器为面光电探测器,面光电探测器为环形面且在以待测样品的照射中心为球心的半球面上。More specifically, the illumination angle is 90°, and the photodetector surrounds the periphery of the wide spectrum response filter. The photodetector is a surface photodetector, which is an annular surface and is on a hemispherical surface with the illumination center of the sample to be tested as the sphere center.
作为替代实施例,所述照射角为45°,所述光电探测器半环绕在所述宽谱响应滤波器一侧的周边。如图所4,仅以其中照射角和接收角同在一个平面上的光电探测器为例进行说明,图中接收角以45°为例。As an alternative embodiment, the illumination angle is 45°, and the photodetector is half-surrounded on one side of the wide spectrum response filter. As shown in FIG4 , only the photodetector in which the illumination angle and the receiving angle are on the same plane is used as an example for explanation, and the receiving angle in the figure is taken as 45° as an example.
本实施例在还提供了一种光谱计算重构方法,包括构建光谱响应矩阵、建立欠定方程组、求解欠定方程组和光谱重构。其中光谱响应矩阵和欠定方程组分别是通过上述的光谱仪建立。This embodiment also provides a spectrum calculation and reconstruction method, including constructing a spectrum response matrix, establishing an underdetermined equation group, solving the underdetermined equation group and spectrum reconstruction, wherein the spectrum response matrix and the underdetermined equation group are respectively established by the above-mentioned spectrometer.
构建光谱响应矩阵:首先,需要通过实验或模拟获得一组已知输入光谱的样本,并测量对应的输出信号。这些输入光谱可以是一系列已知波长和光强度的样本。通过将输入光谱经过计算重构式光谱仪的光学系统进行模拟或实验测量,可以得到相应的输出信号。将这些输入光谱和对应的输出信号作为数据,构建一个光谱响应矩阵。Constructing the spectral response matrix: First, a set of samples of known input spectra need to be obtained through experiments or simulations, and the corresponding output signals need to be measured. These input spectra can be a series of samples of known wavelengths and light intensities. By simulating or experimentally measuring the input spectra through the optical system of the computational reconstruction spectrometer, the corresponding output signals can be obtained. These input spectra and the corresponding output signals are used as data to construct a spectral response matrix.
建立欠定方程组:根据计算重构式光谱仪的原理和光谱响应矩阵,可以建立一个欠定方程组。该方程组的未知量是待测样品的光谱,而方程组的等式来自于输入光谱与输出信号之间的关系,通过光谱响应矩阵进行映射。Establishing an underdetermined system of equations: Based on the principle of computational reconstruction spectrometer and the spectral response matrix, an underdetermined system of equations can be established. The unknown quantity of the system of equations is the spectrum of the sample to be measured, and the equations of the system of equations come from the relationship between the input spectrum and the output signal, which is mapped through the spectral response matrix.
求解欠定方程组:由于方程组是欠定的,即未知量(待测样品的光谱)多于等式的数量,因此无法直接求解。在这种情况下,需要使用适当的数学方法来求解方程组。常见的求解方法包括最小二乘法(Least Squares)、正则化方法(Regularization)等。Solving underdetermined equations: Since the equations are underdetermined, that is, the unknowns (the spectra of the samples to be measured) are more than the number of equations, they cannot be solved directly. In this case, appropriate mathematical methods are needed to solve the equations. Common solution methods include least squares method, regularization method, etc.
光谱重构:通过求解欠定方程组,可以得到待测样品的光谱估计结果。这个估计结果可以代表待测样品在计算重构式光谱仪下的光谱信息。 Spectral reconstruction: By solving the underdetermined equations, the spectrum estimation result of the sample to be tested can be obtained. This estimation result can represent the spectrum information of the sample to be tested under the computational reconstruction spectrometer.
以下结合具体实施例来详细说明其工作原理。如图1所示,该光谱仪包括一个宽谱光源(非激光光源,3dB带宽>1nm)、多个宽谱滤波器、待测样品和多个光电探测器。宽谱光源通过不同宽谱滤波器,光谱被调制,不同的调制光谱照射样品后被样品吸收或散射,用光电探测器,即PD收集光强信号。The working principle is described in detail below in conjunction with a specific embodiment. As shown in Figure 1, the spectrometer includes a broadband light source (non-laser light source, 3dB bandwidth>1nm), multiple broadband filters, samples to be tested, and multiple photodetectors. The broadband light source passes through different broadband filters, and the spectrum is modulated. Different modulated spectra are absorbed or scattered by the sample after irradiating the sample, and the light intensity signal is collected by a photodetector, i.e., PD.
数学上,将所需探测的光谱范围分解为多段,分别对应(λ1,λ2,λ3,...λn)。Mathematically, the spectral range to be detected is decomposed into multiple segments, corresponding to (λ1, λ2, λ3, ... λn).
宽谱光源在光谱上的强度分布用向量(Aλ1,Aλ2,Aλ3,...Aλn)表示;The intensity distribution of a broadband light source on the spectrum is represented by a vector (A λ1 ,A λ2 ,A λ3 ,...A λn );
宽谱滤波器的滤波曲线用向量(fλ1,fλ2,fλ3,...fλn)来表示;The filtering curve of the wide spectrum filter is represented by the vector (f λ1 ,f λ2 ,f λ3 ,...f λn );
待测样品的光谱特性通过向量(Xλ1,Xλ2,Xλ3,...Xλn)来表示;The spectral characteristics of the sample to be tested are represented by the vector (X λ1 ,X λ2 ,X λ3 ,...X λn );
光电探测器的响应曲线通过向量(Dλ1,Dλ2,Dλ3,...Dλn)表示。The response curve of the photodetector is represented by the vector (D λ1 , D λ2 , D λ3 , ... D λn ).
宽谱光源发出的光通过宽谱滤波器后光强被调制为(Aλ1fλ1,Aλ2fλ2,Aλ3fλ3,...Aλnfλn),The light emitted by the broadband light source passes through the broadband filter and its intensity is modulated to (A λ1 f λ1 ,A λ2 f λ2 ,A λ3 f λ3 ,...A λn f λn ),
待测光谱曲线通过待测样品后光谱信息再次改变,用(Aλ1fλ1Xλ1,Aλ2fλ2Xλ2,Aλ3fλ3Xλ3,...AλnfλnXλn)表示;After the spectrum curve to be measured passes through the sample to be measured, the spectrum information changes again, which is expressed by (A λ1 f λ1 X λ1 ,A λ2 f λ2 X λ2 ,A λ3 f λ3 X λ3 ,...A λn f λn X λn );
这些信息被光电探测器收集,反映为一个电信号强度为其中AλnDλnfλn由系统选择的器件决定,为已知项,为描述简化,后续该参数用Sn表达,Xλn为待测性质光谱特性,为未知项。This information is collected by the photodetector and reflected as an electrical signal with a strength of Among them, A λn D λn f λn is determined by the device selected by the system and is a known item. To simplify the description, this parameter is subsequently expressed by Sn . X λn is the spectral characteristic of the property to be measured and is an unknown item.
如果有m组宽谱滤波器分别收集每组宽谱滤波器的探测光强,可以得到一个方程组用如下矩阵表示
If there are m groups of wide spectrum filters that collect the detection light intensity of each group of wide spectrum filters, we can get a set of equations represented by the following matrix:
其中为由系统决定的参数,除系统器件的特性外,其主要由每个滤波器的设计决定,为待测的光谱特性,为探测器探测到的数值。in It is a parameter determined by the system. In addition to the characteristics of the system components, it is mainly determined by the design of each filter. is the spectral characteristic to be measured, The value detected by the detector.
研究表明,当m<<n时,通过构造矩阵使他们具有好的不相关性,可以解出的数值。很明显m代表需要的滤波器或通道的数量,n代表获取光谱特性的分辨率,这表明通过设计每个滤波器的滤波特性只需要非常少量的滤波器或通道,就可以获取非常高分辨率的光谱特性。Studies have shown that when m<<n, by constructing the matrix Make them have good uncorrelation, and solve It is obvious that m represents the number of filters or channels required, and n represents the resolution of the spectral characteristics. This shows that by designing the filtering characteristics of each filter, only a very small number of filters or channels are needed to obtain very high-resolution spectral characteristics.
与此同时,本实施例在还提供了一种计算机设备,包括存储器和处理器,所述存储器存储有计算机程序,所述处理器执行所述计算机程序时实现上述的光谱计算重构方法的步骤。这里计算机设备可以是智能手表、智能手环,智能头盔等可穿戴设备。At the same time, this embodiment also provides a computer device, including a memory and a processor, wherein the memory stores a computer program, and the processor implements the steps of the above-mentioned spectrum calculation and reconstruction method when executing the computer program. Here, the computer device can be a wearable device such as a smart watch, a smart bracelet, a smart helmet, etc.
本领域普通技术人员可以理解,实现上述实施例方法中的全部或部分流程,是可以通过计算机程序来指令相关的硬件来完成。据此,所述的计算机程序可存储于一非易失性计算机可读取存储介质中,该计算机程序在执行时,可实现上述任意一项实施例的方法。 Those skilled in the art can understand that all or part of the processes in the above-mentioned embodiments can be implemented by instructing the relevant hardware through a computer program. Accordingly, the computer program can be stored in a non-volatile computer-readable storage medium, and when the computer program is executed, the method of any of the above-mentioned embodiments can be implemented.
以上,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,熟悉该本领域的技术人员应该明白本发明包括但不限于附图和上面具体实施方式中描述的内容。任何不偏离本发明的功能和结构原理的修改都将包括在权利要求书的范围中。 The above are only specific embodiments of the present invention, but the protection scope of the present invention is not limited thereto. Those skilled in the art should understand that the present invention includes but is not limited to the contents described in the drawings and the above specific embodiments. Any modification that does not deviate from the functional and structural principles of the present invention will be included in the scope of the claims.
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