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WO2024123591A1 - Compositions sans silicone pour applications de soins automobiles - Google Patents

Compositions sans silicone pour applications de soins automobiles Download PDF

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Publication number
WO2024123591A1
WO2024123591A1 PCT/US2023/081760 US2023081760W WO2024123591A1 WO 2024123591 A1 WO2024123591 A1 WO 2024123591A1 US 2023081760 W US2023081760 W US 2023081760W WO 2024123591 A1 WO2024123591 A1 WO 2024123591A1
Authority
WO
WIPO (PCT)
Prior art keywords
aqueous composition
composition
water insoluble
ethoxylates
silicone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2023/081760
Other languages
English (en)
Inventor
Scott A. Walters
Simone R. Bright
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
BASF Corp
Original Assignee
BASF SE
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, BASF Corp filed Critical BASF SE
Priority to CN202380083449.6A priority Critical patent/CN120303357A/zh
Priority to EP23837058.9A priority patent/EP4630494A1/fr
Publication of WO2024123591A1 publication Critical patent/WO2024123591A1/fr
Priority to MX2025006495A priority patent/MX2025006495A/es
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes

Definitions

  • the present disclosure relates to compositions comprising water insoluble surfactants that provide appearance enhancing and protectant properties when applied to various substrate surfaces, and methods of use thereof. More specifically, the present disclosure relates to non-silicone compositions comprising water insoluble surfactants, such as fatty alcohol ethoxylates, polyoxyethylene-polyoxypropylene block polymers, and combinations thereof, that provide appearance enhancing and protectant properties when applied to various substrate surfaces, and methods of use thereof.
  • water insoluble surfactants such as fatty alcohol ethoxylates, polyoxyethylene-polyoxypropylene block polymers, and combinations thereof.
  • Silicone-based compounds such as polydimethylsiloxane, are traditionally used in dispersions and emulsions to provide or impart an aesthetically desired shiny and/or darkening of the surface of rubber (tires), vinyl, and leather in auto care applications.
  • silicone fluids have been difficult to procure due to issues with imports and plant shutdowns, as well as price increases.
  • Non-silicone materials such as glycerin or polyalkylene glycol based dressings and protectants, are also available as alternatives to silicone-based materials when such materials are undesirable. However, lower cost and more readily -available non- silicone-based options are needed.
  • compositions such as protective coating compositions, comprising an effective amount of a water insoluble surfactant and a suitable carrier.
  • the water insoluble surfactant may be selected from fatty alcohol ethoxylates, polyoxyethylene-polyoxypropylene block polymers, and mixtures thereof.
  • the composition may be free of silicone.
  • the composition may be aqueous or non-aqueous.
  • compositions comprising an effective amount of a water insoluble surfactant and a suitable carrier as a coating or polish for a substrate.
  • compositions comprising an effective amount of a water insoluble surfactant and a suitable carrier to a substrate.
  • the composition may be applied to a substrate comprising a material selected from the group consisting of rubber, vinyl, leather, and combinations thereof.
  • Approximating language may be applied to modify any quantitative representation that could permissibly vary without resulting in a change in the basic function to which it is related. Accordingly, a value modified by a term or terms, such as ‘'about”, is not limited to the precise value specified. In at least some instances, the approximating language may correspond to the precision of an instrument for measuring the value. Range limitations may be combined and/or interchanged, and such ranges are identified and include all the sub-ranges stated herein unless context or language indicates otherwise. Other than in the operating examples or where otherwise indicated, all numbers or expressions referring to quantities of ingredients, reaction conditions and the like, used in the specification and the claims, are to be understood as modified in all instances by the term “about”.
  • “Optional” or “optionally” means that the subsequently described event or circumstance may or may not occur, or that the subsequently identified material may or may not be present, and that the description includes instances where the event or circumstance occurs or where the material is present, and instances where the event or circumstance does not occur or the material is not present.
  • the term “consisting of’ excludes any element, step, or ingredient not specified. If in the claim, such would close the claim to the inclusion of materials other than those recited except for impurities ordinarily associated therewith. When the phrase “consisting of’ appears in a clause of the body of a claim, rather than immediately following the preamble, it limits only the element set forth in that clause; other elements are not excluded from the claim as a whole.
  • wt% refers to a percent by weight of the recited component relative to a total weight of the recited composition.
  • compositions comprising water insoluble surfactants that provide appearance enhancing and protectant properties when applied to various substrate surfaces, and methods of use thereof.
  • compositions and methods disclosed herein may provide a lower cost and more readily available alternative or replacement for silicone fluids for application as appearance enhancing (shine, gloss, wet look) dressings and protectants for various surfaces in, for example, auto care applications. More specifically, the compositions and methods disclosed herein may provide a non-silicone-based compound having gloss enhancing and surface protecting properties, as well as longevity and water and/or detergent resistance.
  • an effective amount refers to any amount of a water insoluble surfactant that is effective in imparting appearance enhancing and protective properties to a substrate surface.
  • co-surfactant refers to a surfactant that may be used in compositions of the present disclosure, in combination with, for example, the primary’ water insoluble surfactant to improve the emulsification of the ingredients.
  • compositions for providing appearance enhancing and protectant properties to a surface or substrate may include an effective amount of one or more water insoluble surfactants and a suitable carrier.
  • the composition may be in the form of a coating composition.
  • the composition may include any amount of a water insoluble surfactant that is effective in providing appearance enhancing and protectant properties to a surface.
  • the water insoluble surfactant may be present in an amount of between about 5% to about 60% by weight of the composition, or about 5%, 10%. 15%, 20%, 25%. 30%, 35%, 40%. 45%, 50%, 55%. or 60% by weight of the composition, or any amount that falls between any of these percentages.
  • suitable water insoluble surfactants may include any water insoluble surfactant compounds that are effective in imparting appearance enhancing and protectant properties to the composition of the disclosure.
  • suitable water insoluble surfactants may be cationic, anionic, zwitterionic or nonionic.
  • suitable water insoluble surfactants may include, but are not limited to, nonionic surfactant compounds, such as low-foaming nonionic surfactants, including surfactants selected from fatty alcohol ethoxylates, such as C16-C18 alkoxylates, C13-C15 alkoxylates, C12-C15 alkoxylates, C4 alkoxylates, or mixtures thereof, polyoxyethylenepolyoxypropylene block polymers, such as alkyl and alkenyl alkoxylates of the type R- EOn/POm in which R are generally linear or branched C6-C30 alkyl radicals, or C8-C20 alkyl radicals, EO is an ethylene oxide unit and PO is a propylene oxide unit, the sequential arrangement of EO and PO being arbitrary, and n and m independently of one another being >1 and ⁇ 100, or >3 and ⁇ 50, or alkylphenol ethoxylates, EO/PO block copoly
  • suitable water insoluble surfactants may be characterized by a hydrophilic-lipophilic balance (HLB) of less than about 6.0, or less than about 6.0, about 5.0, about 4.0, about 3.0, about 2.0 or about 1.0, or any HLB between any of these values.
  • HLB hydrophilic-lipophilic balance
  • compositions of the disclosure may be aqueous or non-aqueous.
  • the compositions of the disclosure may include a suitable earner, such as an aqueous or non-aqueous solvent carrier.
  • compositions of the disclosure may be in the form of an aqueous mixture comprising the water insoluble surfactant and an aqueous carrier.
  • the aqueous mixture may include a co-surfactant to emulsify and/or couple the water insoluble surfactant to form an aqueous emulsion.
  • suitable co-surfactants may include any surfactant effective in emulsifying and/or coupling the water insoluble surfactant to form an aqueous emulsion.
  • suitable co-surfactants may include an HLB in a range of from about 8.0 to about 14.0.
  • suitable co-surfactants may be characterized by an HLB of at least about 8.0, about 9.0, about 10.0, about 11.0, about 12.0, or about 13.0. In various aspects, suitable co-surfactants may be characterized by an HLB of at most about 9.0, about 10.0, about 11.0, about 12.0, about 13.0, or about 14.0.
  • suitable co-surfactants are selected from castor oil ethoxylates, hydrogenated castor oil ethoxylates, oleyl alcohol (fatty alcohol) ethoxylates, tridecyl alcohol ethoxylates, nonyl phenol ethoxylates, tallow amine ethoxylates, linear alcohol ethoxylates, lauryl alcohol ethoxylates, C IO Guerbet alcohol alkoxylates, decyl alcohol ethoxylates, dodecyl alcohol ethoxylates, ethylhexyl alkoxylates, octyl phenol ethoxylates, polyoxyethylene-polyoxypropylene block co-polymers, alkoxylated fatty alcohols, polyethylene glycol (PEG) esters, fatty amine ethoxylates, ethoxylated glyceryl esters, fatty alcohol ethoxylates,
  • compositions may be in the form of a non-aqueous dispersion or emulsion comprising the water insoluble surfactant and a non-aqueous solvent carrier.
  • Suitable non-aqueous solvent carriers may include, but are not limited to, glycol ethers, alcohols, mineral spirits and mixtures thereof.
  • compositions of the present disclosure may include limited amounts of silicone.
  • silicone refers to silicone-based compounds, such as poly dimethyl siloxane and the like.
  • the compositions include silicone. In some aspects, the compositions include silicone in an amount in a range of from about 0 wt% to about 50 wt%. In some aspects, the compositions include silicone in an amount in a range of from about 0 wt% to about 30 wt%.
  • compositions include silicone in an amount of at least about 0 wt%, about 0.1 wt%, about 0.2 wt%, about 0.3 wt%, about 0.4 wt%, about 0.5 wt%, about 0.6 wt%, about 0.7 wt%, about 0.8 wt%, about 0.9 wt%.
  • the compositions include silicone in an amount of at most about 0.1 wt%, about 0.2 wt%, about 0.3 wt%, about 0.4 wt%, about 0.5 wt%, about 0.6 wt%, about 0.7 wt%, about 0.8 wt%, about 0.9 wt%, about 1.0 wt%, about 1.1 wt%, about 1.2 wt%, about 1.3 wt%, about 1.4 wt%, about 1.5 wt%, about 1.6 wt%, about 1.7 wt%, about 1.8 wt%, about 1.9 wt%, about 2.0 wt%, about 2.5 wt%, about 3.0 wt%, about 3.5 wt%, about 4.0 wt%, about 4.5 wt%, about 5.0 wt%, about 5.5 wt%, about 6.0 wt%, about 6.5 wt%, about 7.0 wt%, about 7.5
  • compositions of the present disclosure may be free of silicone.
  • the present disclosure may include a method for using a composition, the method comprising applying a composition comprising an effective amount of a water insoluble surfactant to a surface or substrate.
  • the present disclosure may include a method for forming a protective coating on a surface or substrate comprising applying a composition comprising an effective amount of a water insoluble surfactant to the surface or substrate.
  • suitable surfaces and substrates for application of the composition of the disclosure may include any surface or substrate that would benefit from the appearance enhancement and protectant properties of the composition of the disclosure.
  • suitable surfaces or substrates for application of the composition of the disclosure may include one or more materials selected from rubber, vinyl, leather, and combinations thereof.
  • suitable surfaces or substrates for application of the composition of the disclosure may include one or more of rubber-based substrates, vinyl substrates, leather substrates, and the like.
  • compositions of the present disclosure may be in the form of a formulation selected from coating compositions, tire shine formulations, vinyl polish formulations, and combinations thereof.
  • a tire shine formulation is a formulation applied to rubber tires, such as rubber automotive tires.
  • Tire shine formulations may protect tire sidewalls from harmful UV rays, dry rotting, and cracking, and make rubber surfaces appear like a wet and shiny tire.
  • Tire shine formulations may also serve to provide tire dressing, waxing, and/or sealing.
  • a vinyl polish formulation is a formulation applied to a vinyl.
  • the vinyl may be an automotive vinyl, such as in an automotive interior component, like a dashboard, seats, door panels, or a center console.
  • Vinyl polish formulations can help to protect these surfaces from fading, cracking, and other types of damage that can occur over time due to exposure to sunlight, heat, and other environmental factors.
  • the method may include applying a composition comprising any amount of a water insoluble surfactant that is effective in providing appearance enhancing and protectant properties to the surface or substrate.
  • the water insoluble surfactant may be present in an amount of between about 5% to about 60% by weight of the composition, or about 5%. 10%. 15%. 20%, 25%, 30%, 35%, 40%, 45%. 50%. 55%. or 60% by weight of the composition, or any amount that falls between any of these percentages.
  • suitable water insoluble surfactants may include any water insoluble surfactant compounds that are effective in imparting appearance enhancing and protectant properties to the composition of the disclosure.
  • suitable water insoluble surfactants may be cationic, anionic, zwitterionic or nonionic.
  • suitable water insoluble surfactants may include nonionic surfactant compounds, such as low-foaming nonionic surfactants, including surfactants selected from fatty alcohol ethoxylates, such as C16-C18 alkoxylates, C13-C15 alkoxylates, C12-C15 alkoxylates, C4 alkoxylates, or mixtures thereof, polyoxyethylene-polyoxypropylene block polymers, such as alkyl and alkenyl alkoxylates of the ty pe R-EO n /PO m in which R are generally linear or branched C6-C30 alkyd radicals, or C8-C20 alkyl radicals, EO is an ethylene oxide unit and PO is a propylene oxide unit, the sequential arrangement of EO and PO being arbitrary, and n and m independently of one another being >1 and ⁇ 100, or >3 and ⁇ 50, or alkylphenol ethoxylates, EO/PO block copoly
  • suitable water insoluble surfactants may be characterized by an HLB of less than about 6.0, or less than about 6.0, about 5.0, about 4.0, about 3.0, about 2.0 or about 1.0, or any HLB between any of these values.
  • the compositions may be aqueous or non-aqueous.
  • the compositions may include a suitable carrier, such as an aqueous or non-aqueous solvent carrier.
  • the compositions may be in the form of an aqueous mixture comprising the water insoluble surfactant and an aqueous carrier.
  • the aqueous mixture may include a co-surfactant to emulsify and/or couple the water insoluble surfactant to form an aqueous emulsion.
  • suitable co-surfactants may include any surfactant effective in emulsifying and/or coupling the water insoluble surfactant to form an aqueous emulsion.
  • suitable co-surfactants may include an HLB in a range of from about 8.0 to about 14.0. In some aspects, suitable co-surfactants may be characterized by an HLB of at least about 8.0, about 9.0, about 10.0, about 11.0, about 12.0, or about 13.0. In various aspects, suitable co-surfactants may be characterized by an HLB of at most about 9.0, about 10.0, about 1 1.0, about 12.0, about 13.0, or about 14.0.
  • suitable co-surfactants are selected from castor oil ethoxylates, hydrogenated castor oil ethoxylates, oleyl alcohol (fatty alcohol) ethoxylates, tridecyl alcohol ethoxylates, nonyl phenol ethoxylates, tallow amine ethoxylates, linear alcohol ethoxylates, lauryl alcohol ethoxylates, CIO Guerbet alcohol alkoxylates, decyl alcohol ethoxylates, dodecyl alcohol ethoxylates, ethylhexyl alkoxylates, octyl phenol ethoxylates, polyoxyethylene-polyoxypropylene block co-polymers, alkoxylated fatty alcohols, polyethylene glycol (PEG) esters, fatty amine ethoxylates, ethoxylated glyceryl esters, fatty alcohol ethoxylates, e
  • PEG polyethylene glyco
  • compositions may be in the form of a non-aqueous dispersion or emulsion comprising the water insoluble surfactant and a non-aqueous solvent carrier.
  • Suitable non-aqueous solvent carriers may include glycol ethers, alcohols, mineral spirits and mixtures thereof.
  • compositions may be free of silicone-based compounds, such as poly dimethylsiloxane and the like.
  • Benchmark 1 60% Water-Based Emulsion
  • a benchmark 1 emulsion was prepared by mixing a silicone compound (Silicone 350 cst) with an emulsifier and water to form a silicone fluid emulsion.
  • Benchmark 2 60% Water-Based Emulsion
  • a benchmark 2 emulsion was prepared by mixing a silicone compound (Silicone 1000 cst) with an emulsifier and water to form a silicone fluid emulsion.
  • Emulsion 1 60% Water-Based Emulsion
  • Emulsion 1 was prepared by mixing an alcohol alkoxy late with an alkyl polyethylene glycol ether (Guerbet Alcohol Ethoxylate. 9 mol EO) and water.
  • alkyl polyethylene glycol ether Guerbet Alcohol Ethoxylate. 9 mol EO
  • Emulsion 2 60% Water-Based Emulsion
  • Emulsion 2 was prepared by mixing an ethylene oxide and propylene oxide block copolymer (Ethylene Oxide/Propylene Oxide Block Copolymer, 20% EO) with an alk l polyethylene glycol ether (Guerbet Alcohol Ethoxylate, 7 mol EO) and water.
  • an ethylene oxide and propylene oxide block copolymer Ethylene Oxide/Propylene Oxide Block Copolymer, 20% EO
  • alk l polyethylene glycol ether Guerbet Alcohol Ethoxylate, 7 mol EO
  • compositions of the benchmark 1 emulsion, benchmark 2 emulsion, and Emulsions 1 and 2 are shown in Table 1 below.
  • the benchmark 1 emulsion and Emulsions 1 and 2 were also diluted to 20% and 10% concentrations, respectively, for comparative testing.
  • Example 1 The water based emulsions of Example 1 were applied to a tire wall, and the ease of rub, tackiness, shine, and darkening effects of each emulsion were evaluated. The results are shown below in Table 2.
  • Tire shine formulations [0078] Other co-surfactants suitable for tire shine formulations include castor oil ethoxylates, hydrogenated castor oil ethoxylates, oleyl alcohol (fatty alcohol) ethoxylates, tridecyl alcohol ethoxylates, nonyl phenol ethoxylates, tallow amine ethoxylates, methyl oxirane copolymers (e.g., Meroxapol® 174), lauryl alcohol ethoxylates, C12-C14 and C10- Ci6 alcohol ethoxylates, C13-C15 alcohol ethoxylates, C10 Guerbet alcohol alkoxylates, decyl alcohol ethoxylates, dodecyl alcohol ethoxylates, ethylhexyl alkoxylates, C9-C11 alcohol ethoxylates, octyl phenol ethoxylates, polyoxyethylene-polylene-poly
  • co-surfactants suitable for vinyl formulations include castor oil ethoxylates, hydrogenated castor oil ethoxylates, oleyl alcohol (fatty alcohol) ethoxylates, tridecyl alcohol ethoxylates, nonyl phenol ethoxylates, tallow amine ethoxylates, methyl oxirane copolymers (e.g., Meroxapol® 174), lauryl alcohol ethoxylates, C12-C14 and C10- Ci6 alcohol ethoxylates, C13-C15 alcohol ethoxylates, C10 Guerbet alcohol alkoxylates, decyl alcohol ethoxylates, dodecyl alcohol ethoxylates, ethylhexyl alkoxylates, C9-C11 alcohol ethoxylates, octyl phenol ethoxylates, polyoxyethylene-polyoxypropylene block copolymers,
  • the panelists rated the samples in four intervals after application: initial, 24 hours, 48 hours, and 1 week. The panelists were unaware of identity of products in each set.
  • the below table includes the averages and standard deviations of gloss values for each time point across all comparisons.
  • Benchmark 3 20% silicone emulsion
  • Benchmark 4 20% glycerin
  • a 1 ” thick heavy-duty styrene butadiene rubber sheeting of 60A durometer was cut and cleaned with acetone to remove any surface film.
  • the sheet was divided into three sections and onto each section a product was applied using a foam brush.
  • three gloss measurements were taken with a gloss meter (BYK Gardner micro- TRI-gloss glossmeter) at four intervals after application: initial, 24 hours, 48 hours, and 1 week.
  • the below table includes the averages of gloss values, measured in gloss units (GU), for each time point across all measurements.
  • compositions and methods in accordance with the present disclosure may provide a non-silicone-based compound having gloss enhancing and surface protecting properties, as well as longevity and water and/or detergent resistance.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des compositions aqueuses et non aqueuses et des procédés d'utilisation de celles-ci, les compositions étant exemptes de silicones, et comprenant une quantité efficace d'un tensioactif insoluble dans l'eau, tel qu'un éthoxylate d'alcool gras, un polymère séquencé de polyoxyéthylène-polyoxypropylène, ou des mélanges de ceux-ci, et un support approprié.
PCT/US2023/081760 2022-12-05 2023-11-30 Compositions sans silicone pour applications de soins automobiles Ceased WO2024123591A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN202380083449.6A CN120303357A (zh) 2022-12-05 2023-11-30 用于汽车护理应用的非硅酮组合物
EP23837058.9A EP4630494A1 (fr) 2022-12-05 2023-11-30 Compositions sans silicone pour applications de soins automobiles
MX2025006495A MX2025006495A (es) 2022-12-05 2025-06-04 Composiciones libres de silicona para aplicaciones de cuidado automotriz

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US202263386043P 2022-12-05 2022-12-05
US63/386,043 2022-12-05

Publications (1)

Publication Number Publication Date
WO2024123591A1 true WO2024123591A1 (fr) 2024-06-13

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ID=89507407

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2023/081760 Ceased WO2024123591A1 (fr) 2022-12-05 2023-11-30 Compositions sans silicone pour applications de soins automobiles

Country Status (4)

Country Link
EP (1) EP4630494A1 (fr)
CN (1) CN120303357A (fr)
MX (1) MX2025006495A (fr)
WO (1) WO2024123591A1 (fr)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5759988A (en) * 1993-12-30 1998-06-02 Ecolab Inc. Stable hygroscopic detergent article
WO1999028392A2 (fr) * 1997-12-03 1999-06-10 Milliken Research Corporation Composition d'encre essuyable a sec
US20020094939A1 (en) * 2001-01-17 2002-07-18 International Business Machines Corporation Aqueous cleaning of polymer apply equipment
US20080060551A1 (en) * 2004-02-18 2008-03-13 Everett Crews Method for producing bitumen compositions
WO2012154917A2 (fr) * 2011-05-10 2012-11-15 Archer Daniels Midland Company Dispersants ayant des composés d'origine biologique
WO2023014851A1 (fr) * 2021-08-05 2023-02-09 Stepan Company Compositions tensioactives

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5759988A (en) * 1993-12-30 1998-06-02 Ecolab Inc. Stable hygroscopic detergent article
WO1999028392A2 (fr) * 1997-12-03 1999-06-10 Milliken Research Corporation Composition d'encre essuyable a sec
US20020094939A1 (en) * 2001-01-17 2002-07-18 International Business Machines Corporation Aqueous cleaning of polymer apply equipment
US20080060551A1 (en) * 2004-02-18 2008-03-13 Everett Crews Method for producing bitumen compositions
WO2012154917A2 (fr) * 2011-05-10 2012-11-15 Archer Daniels Midland Company Dispersants ayant des composés d'origine biologique
WO2023014851A1 (fr) * 2021-08-05 2023-02-09 Stepan Company Compositions tensioactives

Also Published As

Publication number Publication date
MX2025006495A (es) 2025-07-01
CN120303357A (zh) 2025-07-11
EP4630494A1 (fr) 2025-10-15

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