WO2024178100A1

WO2024178100A1 - Method and apparatus for using pulsed neutron generators and dual-function detectors to obtain formation mineralogy

Info

Publication number: WO2024178100A1
Application number: PCT/US2024/016694
Authority: WO
Inventors: Sheng ZHAN; Jeremy Zhang; Zongqi Chen; Xianghua Liu
Original assignee: China Petroleum and Chemical Corp; Sinopec Tech Houston LLC
Current assignee: China Petroleum and Chemical Corp; Sinopec Tech Houston LLC
Priority date: 2023-02-21
Filing date: 2024-02-21
Publication date: 2024-08-29
Anticipated expiration: 2025-08-21
Also published as: CN120981714A

Abstract

A method for obtaining elemental concentration and determining the formation mineralogy uses a tool having multiple dual-function detectors that can detect both neutrons and gamma rays simultaneously. The method includes emitting neutrons into the formation, detecting neutron and gamma ray signals from the formation and discriminating the neutron signal and the gamma ray signal, obtaining the space, time and energy dependent fluence rates for fast neutrons and thermal neutrons, obtaining gamma ray energy spectra from inelastic scattering and neutron capture reactions from one or more detectors, obtaining the energy spectrum of inelastic gamma rays and/or capture gamma rays from a single element, calculating concentration of the element in the formation using its energy spectrum of inelastic gamma rays or capture gamma rays from one or more detectors and the space, time and energy dependent fluence rate of fast neutrons or thermal neutrons, and determining the formation mineralogy.

Description

Docket No.: PA173.0071PCT METHOD AND APPARATUS FOR USING PULSED NEUTRON GENERATORS AND DUAL-FUNCTION DETECTORS TO OBTAIN FORMATION MINERALOGY BACKGROUND 1. Field of Technology [0001] This disclosure provides methods and systems for nuclear well logging and formation evaluation, in particularly methods and systems for nuclear logging and data analysis to obtain real-time formation minerology using a nuclear logging tool having multiple dual-function detectors. 2. Description of Related Art [0002] In oil and gas exploration, porosity, mineralogy, density, and gas/oil saturation are important formation parameters for evaluating the total oil/gas reserves in a field. Various wireline and LWD (Logging-While-Drilling) logging tools and methods have been developed for the measurement of downhole formation parameters, including formation mineralogy. [0003] Formation mineralogy can be obtained by a pulsed neutron tool, employing a pulsed neutron source (e.g., a D-T neutron generator) and one, two, or three detectors that detect neutrons or neutron-induced gamma rays. The energy spectrum of neutron- induced gamma rays from each element is unique. By measuring the energy spectrum of gamma rays from fast neutron inelastic scattering and/or from thermal neutron capture reactions, one may identify elements and obtain the relative percentage of gamma rays from each of those elements in the formation, i.e., the elemental yields. The inelastic spectrum is the basis for detecting Mg, Fe, S, C, Al, Si, Ca, and O elements. The capture spectrum provides information on other elements, such as Mg, S, Ti, Al, K, Ca, Si, Gd, Fe, Cl, H elements. [0004] The energy spectrum of gamma rays induced by either fast neutron inelastic scattering during neutron pulses or thermal neutron capture reaction between the neutron pulses from an element is unique. Some elements have high cross sections of fast neutron inelastic scattering, such as C, O, etc., while other elements have high cross sections of thermal neutron capture reactions, such as H, Cl, etc. Still other elements, including Si and Fe, have high cross sections of both fast neutron inelastic scattering and thermal neutron capture reactions. By separately measuring the energy spectra of gamma rays from the fast neutron inelastic scattering and thermal neutron capture reactions, one can reduce the effects from other elements in determining target elements. Docket No.: PA173.0071PCT [0005] The inelastic energy spectrum and the capture energy spectrum can be deconvoluted according to a library of standard single element spectrum to obtain the energy spectrum from each element and its relative percentage of gamma rays from the element (relative yield from each element). By utilizing the relative yield of gamma rays from each element with its cross section of fast neutron inelastic scatter or thermal neutron capture reaction and other information, such as formation density, one can also calculate each element concentration (such as weight percentage) in the formation, which can be used to obtain formation mineralogy. [0006] Nowadays, most of the nuclear logging tools employ single function detectors configured to detect either neutrons or gamma rays. For example, He-3 gaseous detectors are used to detect thermal neutrons. He-3 isotope has high thermal neutron absorption cross sections. After fast neutrons emitted from a neutron source are slowed down by the formation and scattered back to the detectors, neutrons are absorbed, which produces other detectable ions, such as protons (p) and trilliums (T), which in turn ionize the gas. Ions and electrons are multiplied and drifted in an electric field to form electric signals. A variety of scintillation detectors, e.g., NaI, CsI, BGO, GSO, LaBr₃, YAP scintillators and photomultiplier tubes (PMTs), are employed to detect gamma rays. These scintillators convert the deposited energy of gamma rays into scintillation lights. The PMT converts the scintillation lights into electrons and amplifies them to form electronic signals. [0007] One or two gamma ray detectors are utilized in the mineralogy measurement in commercial pulsed neutron tools, such as the FLeX^TM tool (1 gamma ray detector) from Baker Hughes, the RMT-3D^TM tool (3 gamma ray detectors) from Halliburton, as well as the RST tool (2 gamma ray detectors) and PNX tool (3 gamma ray detectors but only 2 of them use for mineralogy) from Schlumberger. Evidently none of these tools measures the fluence rate of fast neutrons or the fluence rate of thermal neutrons in the surrounding formation simultaneously when measuring gamma rays, let alone measuring both at different locations in the formation. [0008] Without knowing the fluence rates of fast neutrons and thermal neutron at different time, energy, and locations, which can be expressed as

(fast neutron space distribution or thermal neutron space distribution with time and energy), the analysis and calculation of the elemental composition of the formation are not accurate. For example, there are more fast neutrons near the neutron source, as a result, more Docket No.: PA173.0071PCT gamma rays are produced from fast neutron inelastic scattering in a space near the neutron source. Moreover, gamma rays from an element close to a detector (such as inside wellbore) are more likely to be detected than those from the same element further away from the detector (such as in the formation). Furthermore, even the same fast neutron energy spectrum or thermal neutron energy spectrum in the formation would have different effects on different elements, as the different element not only have different cross-sections, but also have different thresholds for inelastic scattering or thermal neutron capture reactions. [0009] To further complicate the calculations and minerology estimation, different elements have different energy spectra of gamma rays, which means a same detector can have different detection ranges of gamma rays. Moreover, three detectors at different distances from the neutron source have three different depth-of-investigations (DOIs) even for the same element in the same formation, making the above calculation more problematic. [0010] Therefore, existing nuclear logging tools are not equipped to obtain gamma rays from inelastic scattering and neutron capture reactions, together with fast neutrons and thermal neutrons which initiate inelastic gamma rays and capture gamma rays and further to obtain the space, time and energy dependent fast neutron distribution and the space, time and energy dependent thermal neutron distribution. Hence, there is a need to develop a new method and system for an improved measurement of elemental concentrations to obtain minerology in the downhole formation. SUMMARY [0011] This summary is provided to introduce a selection of concepts in a simplified form that are further described below in the detailed description. It is not intended to identify key features or essential features of the claimed subject matter, nor is it intended to be used as an aid in determining the scope of the claimed subject matter. [0012] According to one of the embodiments in this disclosure, a method for evaluating a formation mineralogy of a subterranean formation includes a plurality of steps. First, a nuclear logging tool is deployed into the subterranean formation. The nuclear logging tool has one or more neutron source and two or more dual-function detectors configured to simultaneously detect both neutrons and gamma rays. Next, the one or more neutron sources emit neutrons into the subterranean formation; and neutrons and gamma rays from the subterranean formation are detected at the three or more detectors to form electric signals. Further, electric signals from neutrons and gamma Docket No.: PA173.0071PCT rays for each of the three or more detectors are separated; the detector count rates of total neutrons, fast neutrons and thermal neutrons at the three or more detectors are obtained and utilized to obtain space, time and energy dependent fluence rates for fast neutrons and thermal neutrons; and detector count rates of inelastic gamma rays and capture gamma rays, and the energy spectrum of inelastic gamma rays and the energy spectrum of capture gamma rays at the three or more detectors are obtained. After that, elemental concentrations of a plurality of elements in the formation are calculated using the space, time and energy dependent fluence rates of fast neutrons and thermal neutrons, energy spectra of inelastic gamma rays and capture gamma rays at the three or more detectors and other information. Finally, the formation mineralogy is determined based on the elemental concentration of the plurality of elements obtained at three or more detectors. [0013] In some of the embodiments, the neutron source is utilized to generate neutrons in either pulse mode or continuous mode. [0014] In other embodiments, the plurality of elements is selected from Mg, Fe, S, C, Al, Si, Ca, O, Ti, K, Gd, Cl, and H. [0015] In still other embodiments, single element gamma ray energy spectrum for each of a plurality of elements is obtained. [0016] In certain embodiments, the elemental concentration is calculated using a gamma ray count rate and a space, time and energy dependent neutron fluence rate obtained at one or more of the pluralities of dual-function detectors. [0017] In other embodiments, the neutron fluence rate is a fast neutron fluence rate or a thermal neutron fluence rate. [0018] In still other embodiments, the gamma ray count rate is a count rate of gamma rays generated by fast neutron inelastic scattering or by thermal neutron capture reactions. BRIEF DESCRIPTION OF THE DRAWINGS [0019] The teachings of the present invention can be readily understood by considering the following detailed description in conjunction with the accompanying drawings. [0020] FIG.1A, FIG.1B, FIG.1C, and FIG.1D illustrate four exemplary configurations of a nuclear logging tool having one neutron source (S1) and three detectors (D1, D2, and D3) disposed along the longitudinal direction of the housing of the tool. [0021] FIG.2A, FIG.2B, and FIG.2C show cross-sectional views of exemplary nuclear logging tools having S1, D1, D2, and D3. Docket No.: PA173.0071PCT [0022] FIG.3A and FIG.3B show cross-sectional views of exemplary nuclear logging tools having four (D1, D2, D31, and D32) and six detectors (D1, D21, D22, D31, D32, and D33), respectively. [0023] FIG.4A is an embodiment of the nuclear logging tool having two neutron sources (S1, S2) and two detectors (D1, D2); FIG.4B and FIG.4C provide cross- sectional views of exemplary configurations of this embodiment. [0024] FIG.5A is a further exemplary embodiment of the nuclear logging tool having two neutron sources (S1, S2) and four detectors (D11, D12, D21, D22); FIG.5B provides cross-sectional views of this embodiment. [0025] FIG.6 is a diagram of an exemplary drilling system that implements an embodiment of the current disclosure. [0026] FIG.7 is a schematic diagram illustrating measurement of neutron and gamma signals in a downhole formation using a nuclear logging tool of the current disclosure. [0027] FIG.8 shows schematics of neutron pulses, as well as neutron count rates, inelastic spectrum, capture spectrum of neutron-induced gamma rays in response to the ON and OFF of the neutron pulses. [0028] FIG.9 is a flow diagram showing exemplary methods to obtain formation mineralogy according to the current disclosure. [0029] FIG.10 is a block diagram showing exemplary methods to obtain formation mineralogy according to the current disclosure. [0030] Throughout the drawings and the detailed description, unless otherwise described, the same drawing reference numerals will be understood to refer to the same elements, features, and structures. The relative size and depiction of these elements may be exaggerated for clarity, illustration, and convenience. DETAILED DESCRIPTION [0031] The following detailed description is provided to assist the reader in gaining a comprehensive understanding of the methods, apparatuses, and/or systems described herein. References are made in detail to embodiments of the present disclosure, examples of which are illustrated in the accompanying drawings. Similar or like reference numbers may be used in the drawings and may indicate similar or like elements. [0032] The features described herein may be embodied in different forms and are not to be construed as being limited to the embodiments described herein. Rather, the embodiments described herein and depicted in the drawings have been provided so Docket No.: PA173.0071PCT that this disclosure will be thorough and complete and will convey the full scope of the disclosure to one of ordinary skill in the art, who may readily recognize from the following description that alternative embodiments exist without departing from the general principles of the disclosure. [0033] Therefore, the scope of the disclosure is defined not by the detailed description, but by the claims and their equivalents, and all variations within the scope of the claims and their equivalents are to be construed as being included in the disclosure. [0034] In this disclosure, unless otherwise noted, a detector refers to a dual-function detector that can detect both neutrons and gamma rays. Such a detector employs scintillation crystals such as Cs₂LiYCl₆ (CLYC) or Cs₂LiLaBr₆ (CLLB) and associated electronics, e.g., PMT. The detectors may be actively cooled or not actively cooled when deployed downhole. For example, a detector using CLLB and high-temperature PMT can be used at a high temperature without additional cooling. [0035] FIGs.1A to 1D are schematic illustrations (not to scale) of four exemplary configurations of a cylindrical nuclear logging tool having a neutron source (S1) and three dual-function detectors (D1, D2, D3) disposed along the housing of the logging tool suitable for logging-while-drilling (LWD) operations. A mud channel (MC) is disposed along the axis of the logging tool while the detectors are eccentrically disposed along the longitudinal direction of the tool. FIG.1A also shows a high voltage power supply (HV), an electronic instrument, e.g., a controller, for sending instructions, receiving, and processing data from the neutron source and the detectors, as well as a telemetry for transmitting data between the logging tool and surface. The high voltage power supply provides power to detectors (D1, D2, D3) and to the pulsed neutron source (S1). The power supply, the electronic instrument, and telemetry are required but not shown in FIGs.1B-1D for simplicity. [0036] As shown in the figures, D1 is the near detector that has the shortest distance in longitudinal direction to the neutron source, D3 is the far detector having the longest longitudinal distance to the neutron source, and D2 is the middle detector that has a longitudinal distance that is in the middle. [0037] In FIG.1A, all three detectors reside on one side of the neutron source along the logging tool. The one side can be either the proximal side or the distal side of the neutron source. The proximal side is the side of the nuclear logging tool that is closer to the surface when it is deployed downhole while the distal side is farther away from the surface. The high voltage power supply provides power to detectors (D1, D2, D3) and to Docket No.: PA173.0071PCT the pulsed neutron source (S1). The signals from detectors are processed by the electronic instruments and measurements/data are collected and transmitted by telemetry. In FIGs.1B, 1C, and 1D, both the distal side and the proximal side of the neutron source has at least one detector disposed thereto. [0038] In wireline logging, the tool can be installed in a sonde, which does not contain a mud channel. Detectors can be installed either along or off the axis of the tool body. Power and control signals can also be provided to the logging tool from the surface while data from the logging tool can be transmitted to the surface via the wireline cable. [0039] The neutron source S1 in each logging tool depicted in FIGs.1A to 1D is a pulsed neutron generator. The pulsed neutron source may be a Deuterium-Tritium (D-T) pulsed neutron generator, which can be operated in a variety of pulse schematics (e.g., frequency, duty time) in a pulse mode. For example, the frequency of neutron pulses may be about 10 kHz (the period is 100µs) and the neutron duty time may be about 20 µs. Depending on the methods and measurements, the D-T neutron generator may also be operated in a continuous mode. In that case, the neutron generator is activated frequent enough so that neutrons are emitted continuously. Neutrons from a D-T neutron generator has an initial energy of about 14.1 MeV. [0040] The neutron source S1 and detectors D1, D2, and D3 as depicted in FIGs.1A- 1D only show their relative positions along the longitudinal direction of the housing of the tool but not their positions in the radial direction in a cross-section of the tool housing. [0041] In certain embodiments, S1, D1, D2, and D3 can be disposed at the same radial or different radial directions, i.e., having the same or different toolface angles when deployed in the formation. FIGs.2A, 2B, and 2C show exemplary cross-sectional views in the directions of A-A, B-B, C-C, and D-D as shown in FIGs.1A to 1D. S1, D1, D2, and D3 in FIG.2A are disposed at same toolface angle. In FIG.2B, however, S1, D1, and D3 have the same toolface angle while D2 is at a different toolface angle. In FIG.2C, S1 and D1 have the same toolface angle while each of D2 and D3 has a different toolface angle. [0042] Other embodiments of the logging tool may have more than three detectors. For example, FIG.3A depicts a variation of the logging tool in FIG.1A that has four detectors -D1, D2, D31, and D32. D31 and D32 have approximately the same distance from S1 but are disposed at two different toolface angles. Likewise, FIG.3B depicts another variation of tool in FIG.1A, which has six detectors: D1, D21, D22, D31, D32, Docket No.: PA173.0071PCT and D33. In this embodiment, D21 and D22 are disposed opposite to each other on the cross-sectional area of the logging tool, i.e., the toolface angle of D21 and D22 is 0^o and 180^o, respectively. D31, D32, and D33 are disposed 120^o apart on the cross-sectional area of the logging tool, i.e., a difference in the toolface angles of any two among D31, D32, and D33 is 120^o. Having different toolface angles allows detectors to preferentially receive neutrons and gamma-rays at certain incident angles from the formation. It also increases the detection efficiency of neutrons and gamma rays by increasing the total count rate of all the detectors. [0043] Further, in FIG.3A, D31 and D32 have substantially the same distance from S1. In FIG.3B, middle detectors D21 and D22 have substantially the same distance from S1 while far detectors D31, D32, and D33 have substantially the same distance from S1. “Substantially the same distance” means the distances from S1 to the center of scintillators of the detectors (e.g., D31 and D32) is about the same. For example, the difference is less than ½” or ¼”. By this arrangement, the middle detectors as a whole and far detectors as a whole have higher count rates than when only one middle detector or only one far detector is used. Accordingly, the neutron generator S1 can be of a less powerful source, which may not be subject to stringent regulations as more powerful neutron sources are subject to. In addition, the count rate of individual detectors can separately be recorded and processed. The differences of various detectors in distance and in toolface angles can be used to obtain formation information in specific azimuthal directions. [0044] In some embodiments, the logging tool have multiple shields that can absorb neutrons and gamma-rays (not shown). The shields can be placed in the logging tool between the neutron source and the detectors so that the detectors receive neutrons and gamma-rays coming from the formation rather than traveling through the logging tool itself. Alternatively, the detectors can also be partially shielded by the shield material that absorb both neutrons and gamma rays from certain directions. [0045] The shield is made of or contains one or more materials that can effectively attenuate both neutrons and gamma rays. The shield material can contain light elements for fast neutrons, such as hydrogen (H) in polyethylene, and heavy elements having high thermal neutron absorption cross sections, including metals such as gadolinium (Gd), samarium (Sm), metal oxides such as Gd₂O₃, Sm₂O₃, B₂O₃, alloys containing Gd or Sm with other heavy metals Fe, Pb, or W, or materials containing boron, such as tungsten borides (WB, WB2, etc.). Docket No.: PA173.0071PCT [0046] The shield may be a stand-alone metal piece inserted in the logging tool, or an integral part of the detector casing. For example, the portion of the detector casing facing inward to the logging tool can be made of the shield material while the portion facing the formation is made of a material that is transparent to neutrons and gamma rays, forming a window that neutrons and gamma rays can travel through. As such, neutrons and gamma-rays from certain incident angles may be absorbed by the shield material while those travel through the window are received by the detector. Therefore, the detector can be more sensitive to certain incident angles by adjusting the size and orientation of the window in the detector casing. During operation, data collected by various detectors may produce direction-specific formation properties, which can be used to guide directional drilling. [0047] The nuclear logging tool may have more than one neutron sources. FIG.4A shows a further embodiment of the logging tool having two neutron sources (S1 and S2), one at the proximal end and the other at the distal end while two detectors (D1 and D2) are arranged between S1 and S2. Alternatively, S1 and S2 can be arranged in tandem and disposed near one end of the logging tool while D1 and D2 arranged in tandem near the other end, as the engineering considerations require. In both embodiments, the distance between S1 and D1 is d1, the distance between S1 and D2 is d₂, the distance between S2 and D2 is d₃, while the distance between S2 to D1 is d₄. When S1 and S2 are both pulsed neutron generators, they can be alternately turned ON or OFF, thereby inducing neutrons and gamma-rays from the formation alternately, which are received by D1 and D2. Since there are four different source-to-detector distances (d₁ to d₄), the data generated in D1 and D2 may be better compensated than tools with only two or three source-to-detector distances for near wellbore effects, such as borehole size, tool standoff, mud weight and/or salinity, casing size, cement thickness, etc. As a result, the obtained formation parameters could be more accurate. [0048] FIG.4B and FIG.4C illustrate two exemplary embodiments of the logging tool, where the two sources and two detectors can be arranged at same toolface angle or at different toolface angles. When, as in FIG.4B, the sources and detectors have the same toolface angle, the measurement covers the same sector in the formation at any given time. When, as in FIG.4A, the sources and detectors may have different toolface angles, the data generated in D1 and D2 reflect different sectors of the formation, which can reveal differences amongst various formation sectors at any given time by comparing the measurements from D1 and D2. Docket No.: PA173.0071PCT [0049] FIGs.5A and 5B illustrate a logging tool that has four detectors (D11, D12, D21, D22) and two neutron sources (S1 and S2). Note that the pair of detectors D11 and D12 (as well as D21 and D22) are disposed at substantially the same distance from S1 or S2. As indicated before, having more than one detector at a certain distance increase the count rate at that distance so that a less powerful neutron source may be viable. The count rate of one far detector may be too low to provide reliable measurement data. By using two or more far detectors, the count rate can be significantly increased so that reliable measurement results can be obtained by processing data from the multiple far detectors as a whole. [0050] In some embodiments, S1 and S2 can be turned ON or OFF simultaneously. Doing so increases the count rate of D1 and D2, thereby reducing the statistical measurement uncertainty. [0051] In still another embodiment, S1 and S2 can be same or different types of neutron generators. For example, Both S1 and S2 can be D-T neutron generators or D- D neutron generators, or S1 can be a D-T neutron generator while S2 can be a D-D neutron generator. [0052] The logging tool can be a part of a wireline logging tool or be included in a downhole assembly as a LWD logging tool in a drilling operation. FIG.6 is a diagram of an oil drilling system 10 used in the directional drilling of borehole 16. The oil drilling system 10 may be used for drilling on land as well as beneath the water. The borehole 16 is drilled into the earth formation using a rotary drilling rig that includes a derrick 12, drill floor 14, draw works 18, traveling block 20, hook 22, swivel joint 24, kelly joint 26 and rotary table 28. A drill string 100 includes a plurality of drill pipes that are serially connected and secured to the bottom of the kelly joint 26 at the surface. The rotary table 28 is used to rotate the entire drill string 100 while the draw works 18 is used to lower the drill string 100 into the bore hole 16 and apply controlled axial compressive loads. The bottom whole assembly 150 is disposed at the distal end of the drill string 100. [0053] The drilling fluid (also referred to as mud) is usually stored in mud pits or mud tanks 46, and is transferred using a mud pump 38, which forces the drilling fluid to flow through a surge suppressor 40, then through a kelly hose 42, and through the swivel joint 24 and into the top of the drill string 100. The drilling fluid flows through the drill string 100 at about 150 gallons per minute to about 600 gallons per minute and flows into the bottom whole assembly 150. The drilling fluid then returns to the surface by traveling through the annular space between the outer surface of the drill string 100 and Docket No.: PA173.0071PCT the bore hole 16. When the drilling fluid reaches the surface, it is diverted through a mud return line 44 back to the mud tanks 46. [0054] The pressure required to keep the drilling fluid in circulation is measured by a pressure sensitive transducer 48 on the kelly hose 42. The pressure sensitive transducer detects changes in pressure caused by the pressure pulses generated by a pulser. The magnitude of the pressure wave from the pulser may be up to 500 psi or more. The measured pressure is transmitted as electrical signals through transducer cable 50 to a surface computer 52, which decodes and displays the transmitted information. Alternatively, the measured pressure is transmitted as electrical signals through transducer cable 50 to a decoder that decodes the electrical signals and transmits the decoded signals to a surface computer 52, which displays the data on a display screen. [0055] As indicated above, the lower part (“distal part”) of the drill string 100 includes the bottom hole assembly (BHA) 150, which includes a non-magnetic drill collar with a MWD system (MWD assembly or MWD tool) 160 installed therein, logging-while drilling (LWD) instruments sub 165 containing LWD instruments, a downhole motor 170, a near- bit measurement sub 175, and the drill bit 180 having drilling nozzles (not shown). The drilling fluid flows through the drill string 100 and is output through the drilling nozzles of the drill bit 180. During the drilling operation, the drilling system 10 may operate in the rotary mode, in which the drill string 100 is rotated from the surface either by the rotary table 28 or a motor in the traveling block 20 (i.e., a top drive). The drilling system 10 may also operate in a sliding mode, in which the drill string 100 is not rotated from the surface but is driven by the downhole motor 170 rotating the drill bit 180. The drilling fluid is pumped from the surface through the drill string 100 to the drill bit 180, being injected into an annulus between the drill string 100 and the wall of the bore hole 16. The drilling fluid carries the cuttings up from the bore hole 16 to the surface. [0056] In one or more embodiments, the MWD system 160 may include a pulser sub, a pulser driver sub, a battery sub, a central storage unit, a master board, a power supply sub, a directional module sub, and other sensor boards. In some embodiments, some of these devices may be located in other areas of the BHA 150. One or more of the pulser sub and pulser driver sub may communicate with the pulser 300, which may be located below the MWD system 160. The MWD system 160 can transmit data to the pulser 300 so that the pulser 300 generates pressure pulses. [0057] The non-magnetic drill collar houses the MWD system 160, which includes a Docket No.: PA173.0071PCT package of instruments for measuring inclination, azimuth, well trajectory (bore hole trajectory), etc. The nuclear logging tool and associated electronic components may be located in LWD instrument sub 165. The nuclear logging tool and other well logging instruments may be electrically or wirelessly coupled together, powered by a battery pack or a power generator driven by the drilling fluid. All information gathered may be transmitted to the surface via in the form of pressure pulses generated by the pulser 300 through the mud column in the drill string. [0058] The near-bit measurement sub 175 may be disposed between the downhole motor 170 and drill bit 180. The nuclear logging tool may alternatively be installed in the near-bit measure sub 175 to provide more accurate real-time formation parameters to guide directional drilling. The data may be transmitted through the cable embedded in the downhole motor 170 to the MWD system 160 in the bottom whole assembly 150. [0059] In one embodiment of the current disclosure, a variety of formation parameters obtained using a logging tool having a D-T neutron generator and three dual-function detectors. FIG.7 illustrates such a logging tool 700 operating in a wellbore 709. In the logging tool 700, the D-T neutron pulse generator 701 is separated by a neutron shield 702 from the near detector 703, the middle detector 704, and the far detector 705. FIG.7 shows that the neutron pulse generator 701 generates neutron pulses into the formation 710. The neutrons reach a spot 706 in the formation having a small volume of dΩ. The spot 706 is defined by a vector of ^^ from the neutron pulse generator 701 and is at a distance of L from the middle detector as an example. The formation material at 706 reflects fast neutrons scattered inelastically to generate inelastic gamma rays or thermal neutrons captured and emit capture gamma rays. Some of the neutrons and gamma rays reach the detectors and are registered are count rates and energy spectra. [0060] FIG.8 shows schematics of neutron pulses, neutron count rates, as well as inelastic spectrum and capture spectrum of neutron-induced gamma rays. The frequency of neutron pulses is 10 kHz (the period is 100 µs) and the neutron duty time is 20 µs, as shown in FIG.8, panel (b). [0061] The neutron count rates measured from each of the three detectors, shown in FIG.8, panel (a), are utilized to obtain formation porosity. Neutrons from three detectors may be further separated according to whether the neutron pulse is ON or OFF, which serves as a coincident or anti-coincident signal to neutrons from the three detectors so Docket No.: PA173.0071PCT that during the neutron pulses (when neutron pulse is ON), neutrons are recorded mainly as fast neutrons. Between the neutron pulses (when neutron pulse is OFF), neutrons are recorded as thermal neutrons. Fast neutrons and thermal neutrons recorded at three detectors can be used to obtain fast neutron space, time and energy dependent distribution and thermal neutron space, time and energy dependent distribution. The neutrons from each detector may also be recorded together. In that case, all neutrons (from thermal neutrons to fast neutrons) are used to obtain the neutron space, time and energy dependent distribution. [0062] Gamma rays from three detectors may be further separated according to whether the neutron pulse is ON or OFF, which serves as a coincident or anti-coincident signal to gamma rays from the three detectors so that during the neutron pulses (neutron pulse is ON), gamma rays are mainly recorded as inelastic spectrum induced by inelastically scattered fast neutrons, shown in FIG.8, panel (c). Between the neutron pulses (neutron pulse is OFF), gamma rays are recorded as capture spectrum induced by thermal neutrons, shown in Figure 8, panel (d). Proper time windows are selected so that gamma rays measured in the capture time window are from thermal neutron capture reactions and most gamma rays measured in the inelastic time window are from fast neutron inelastic scattering. [0063] Background noises in various detectors may be measured while the neutron generator is OFF for a period of time and can be subtracted from the total signals of either neutrons or gamma rays. Neutron background measured during the neutron pulses may be further subtracted to get “pure” fast neutrons by using a small percentage of the measured neutrons between the neutron pulses. Similarly, the capture gamma rays measured during the neutron pulses may be further subtracted to get “pure” inelastic spectrum by using a small percentage of the measured capture spectrum between neutron pulses. [0064] Gamma rays detected by each detector can also be recorded in one energy spectrum (e.g., a total energy spectrum), whether they are initiated from neutron inelastic scattering or neutron capture reactions. Accordingly, several formation measurements are feasible, such as the formation porosity, elemental concentrations, and formation oil/gas saturation, but one may not be able to get formation density, as the spectrum of inelastic gamma rays, which are less dependent on the formation type, porosity and have smaller space distributions, are needed to obtain the formation density for a D-T pulsed neutron generator-based measurement system. Docket No.: PA173.0071PCT [0065] FIG.9 is an exemplary workflow showing the steps in the processing of data from the logging tool having one D-T neutron generator and three detectors (the near detector, the middle detector, and the far detector) to obtain real-time formation mineralogy. In Step 901, the D-T neutron generator emits neutron pulses into the formation surrounding the measurement tool. In Step 902, fast neutrons are slowed down to become thermal neutrons. Inelastic gamma rays and capture gamma rays are produced. [0066] In Step 903, neutrons and neutron-induced gamma rays are detected by the three detectors. In Step 904, signals from neutrons and neutron-induced gamma rays are distinguished from each other, e.g., using the pulse shape discrimination (PSD) technique. In Step 907, the neutron signals from the three detectors are then utilized to obtain the total count rates (CRN_n, CRN_m, CRN_f), fast neutron count rates (CRFN_n, CRFN_m, CRFN_f) thermal neutron count rates (CRTN_n, CRTN_m, CRTN_f). The space, time and energy dependent distributions are then obtained for fast neutrons and thermal neutrons in Step 1008. [0067] On the other hand, in Step 905, the total energy spectrum from inelastic gamma rays and the total energy spectrum from capture gamma rays are obtained after the separation in Step 904, e.g., according to the timing of the neutron pulses shown in FIG. 8. In Step 1006, the total energy spectrum from Step 905 can be stripped using standard energy spectrum for single elements, e.g., Mg, Fe, S, C, Al, Si, Ca, O, Ti, K, Gd, Cl, and H, etc. in Step 906. Then all element concentrations are obtained in Step 909 using single element gamma ray energy spectrum and space, time and energy dependent fast neutron and thermal neutron distributions from Step 908. Formation minerology is determined mainly by the concentrations of elements like C, O, Mg, Si, Ca in Step 910. [0068] FIG.10 presents the embodiment of this disclosure using mathematical symbols and equations, carried out using an exemplary logging tool having a D-T neutron generator and three dual-function detectors. [0069] Element concentrations (i.e., the atomic density of an element, the weight per unit volume of an element) in the formation can be obtained by measuring the energy spectrum of gamma rays from both neutron inelastic scattering and neutron capture reactions, using the same tool. Neutron pulses from the D-T neutron generator are timed as descried in relation to FIG.8. Neutron-induced gamma ray signals from the three detectors, after being separated from neutron signals according to the timing of Docket No.: PA173.0071PCT the pulses, are further separated into gamma ray signals from thermal neutron capture reactions and gamma ray signals from fast neutron inelastic scattering. The inelastic spectrum is the basis for detecting Mg, Fe, S, C, Al, Si, Ca, and O elements. The capture spectrum provides information on other elements, such as Mg, S, Ti, Al, K, Ca, Si, Gd, Fe, Cl, H elements. [0070] In some embodiments, gamma rays detected by each detector may be recorded either in two separate spectra (inelastic spectrum and capture spectrum). By separating the two spectra, the effect from the other spectrum can be eliminated. As a result, the elements can be identified and relative yields of characteristic gamma rays from those elements can be obtained more accurately, so as the element concentrations. [0071] Since the three detectors in the logging tool detect both neutrons and gamma rays simultaneously at three different locations while the logging tool as a whole is moving along the wellbore, the neutron count rates from three detectors (CRN, CRFN, CRTN at the near detector, the middle detector, or the far detector) can be used to derive the space, time and energy dependent distribution of the fast neutrons as well as the thermal neutrons, represented by ^^^ ^^^^, ^^, ^^_^^. [0072] Equation 1 shows the mathematical relation between a detector count rate of gamma rays from either fast neutron inelastic scattering or thermal neutron capture reaction with a target element in near wellbore region.

in which ^^_^൫ ^^, ^^_ఊ൯ is the detector count rate (1/s) of gamma rays at energy ^^_ఊ from element i; ^^_ௗ is detector’s effective area (cm²); ∑ is macroscopic absorption cross section (1/cm) of formation to gamma rays from element i; L is the distance from the detector to a small volume Ω; ^ ^^^ is the distance vector from the neutron source to a small volume Ω;

is the neutron fluence rate at time t, at energy En, at position ^ ^^^ , per unit energy bin, per unit time (1/(cm²∙MeV∙s)); ni (t) is atomic density of the target element i at time t, (1/cm³), which changes with time as the logging tool passing through different depth intervals; σ_୧^E_୬^ is cross section of fast neutron inelastic scattering or thermal neutron capture Docket No.: PA173.0071PCT reaction with the target element i when the neutron energy in En (cm²); is relative detection efficiency of detector to gamma rays at energy E_ஓ (unitless); and V is the total volume of near wellbore space (mainly wellbore and formation) where neutron-induced gamma rays can get to the detector. [0073] Note that the detector count rate ^^_^^ ^^, ^^_ఊ^ of gamma rays at each detector is known, as well as the neutron fluence rate ^^^ ^^^^, ^^, ^^_^^. Indeed, all parameters in Equation 1 except for the atomic density of target element ^^_^ are known or can be derived from measured. Accordingly, the atomic density,

elemental concentration of the target element, can be calculated according to Equation 2: ^^^ ^{^ ^௧,ாം^}

neutron fluence rate ^^^ ^^^^, ^^, ^^_^^ is used together with the capture gamma ray count rate to calculate the atomic density. Indeed, each detector may produce two atomic density values and the logging tool with three detectors may produce up to six atomic density values. One may arrive at a final atomic density value at each detector or for a logging interval or a datum output of the logging tool based on such information, e.g., by a weighted average or any other suitable means. [0075] While in the foregoing specification this disclosure has been described in relation to certain preferred embodiments thereof, and many details have been set forth for purpose of illustration, it will be apparent to those skilled in the art that the disclosure is susceptible to alteration and that certain other details described herein can vary considerably without departing from the basic principles of the disclosure. In addition, it should be appreciated that structural features or methodologies shown or described in any one embodiment herein can be used in other embodiments as well.

Claims

Docket No.: PA173.0071PCT WHAT IS CLAIMED IS: 1. A method for evaluating a formation mineralogy of a subterranean formation, comprising: S1: deploying a nuclear logging tool into the subterranean formation, wherein the nuclear logging tool comprises one or more neutron generators and two or more dual-function detectors configured to simultaneously detect neutrons and gamma rays S2: causing the one or more neutron generators to emit neutrons into the subterranean formation; S3: detecting neutrons and gamma rays from the subterranean formation at the three or more detectors to form electric signals; S4: separating electric signals from neutrons and gamma rays for each of the three or more detectors; S5: obtaining detector count rates of total neutrons, fast neutrons and thermal neutrons; obtaining space, time and energy dependent neutron fluence rates of fast neutrons and thermal neutrons; S6: obtaining detector count rates of inelastic gamma rays and capture gamma rays, and the energy spectrum of inelastic gamma rays and the energy spectrum of capture gamma rays; S8: calculating elemental concentrations of a plurality of elements in the formation using the energy spectrum of inelastic gamma rays and/or the energy spectrum of capture gamma rays, and the space, time and energy dependent neutron fluence rate of fast neutrons and/or the space, time and energy dependent neutron fluence rate of thermal neutrons; and S9: determining the formation mineralogy based on the elemental concentration of the plurality of elements in the formation. 2. The method of claim 1, wherein the neutron generators is utilized to generate neutrons in either pulse mode or continuous mode. 3. The method of claim 1, wherein the plurality of elements is selected from Mg, Fe, S, C, Al, Si, Ca, O, Ti, K, Gd, Cl, and H. 4. The method of claim 3, wherein single element gamma ray energy spectrum for each of a plurality of elements is obtained. Docket No.: PA173.0071PCT 5. The method of claim 4, further comprising obtaining space, time and energy dependent neutron fluence rate using neutrons detected at each dual-function detector. 6. The method of claim 5, wherein the elemental concentration is calculated using a gamma ray count rate and a space, time and energy dependent neutron fluence rate obtained at one or more of the pluralities of dual-function detectors. 7. The method of claim 6, wherein the neutron fluence rate is a fast neutron fluence rate or a thermal neutron fluence rate. 8. The method of claim 6, wherein the gamma ray count ray is a count rate of gamma rays generated by fast neutron inelastic scattering or by thermal neutron capture reactions. 9. The method of claim 6, wherein the elemental concentration is calculated according to

wherein: ^^_^൫ ^^, ^^_ఊ൯ is the detector count rate (1/s) of gamma rays at energy ^^_ఊ from element i; ^^_ௗ is detector’s effective area (cm²); ∑ is macroscopic absorption cross section (1/cm) of formation to gamma rays from element i; L is the distance from the detector to a small volume Ω; ^ ^^^ is the distance vector from the neutron source to a small volume Ω; ^^^{^} ^^^^, ^^, ^^_^ ^{^} is the neutron fluence rate, at time t, at energy En, at position ^ ^^^ , per unit energy bin, per unit time; ni (t) is atomic density of the target element i at time t, which changes with time as the logging tool passing through different depth intervals; σ_୧^E_୬^ is cross section of fast neutron inelastic scattering or thermal neutron capture reaction with the target element i when the neutron energy is En; ^^E_ஓ^ is relative detection efficiency of detector to gamma rays at energy E_ஓ (unitless); and V is the total volume of near wellbore space (mainly wellbore and formation) Docket No.: PA173.0071PCT where neutron-induced gamma rays can get to the detector. 10. The method of claim 1, wherein the nuclear logging tool has at least one neutron generator and at least two dual-function detectors at different locations configured to simultaneously detect both neutrons and gamma rays. 11. The method of claim 1, wherein the neutron source can be a D-T neutron generator or a D-D neutron generator. 12. The method of claim 1, wherein the inelastic gamma rays and the capture gamma rays can be recorded separately or together in the total energy spectrum without further discrimination.