WO2024157572A1 - Sintered ore production method - Google Patents
Sintered ore production method Download PDFInfo
- Publication number
- WO2024157572A1 WO2024157572A1 PCT/JP2023/040356 JP2023040356W WO2024157572A1 WO 2024157572 A1 WO2024157572 A1 WO 2024157572A1 JP 2023040356 W JP2023040356 W JP 2023040356W WO 2024157572 A1 WO2024157572 A1 WO 2024157572A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ore
- mass
- content
- raw material
- sintering raw
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
Definitions
- the present invention relates to a method for producing sintered ore from sintered raw materials containing iron ore.
- Sintered ore the raw material used in the blast furnace iron-making process, is produced by sintering raw materials that include powdered iron ore, auxiliary materials such as limestone, and carbonaceous materials such as coke.
- auxiliary materials such as limestone
- carbonaceous materials such as coke.
- the iron ore used in Japan is broadly divided into hematite ore and magnetite ore from South America, and hematite ore, pisolite ore, and Marra Mamba ore from Australia.
- South American ore is high in Fe content and high quality, but its origin is remote, which creates a problem in terms of transportation costs.
- the production of Australian ore has increased significantly since the 1980s, and it has been used as the main raw material for iron ore in Japan. Since the 2000s, as Australian hematite ore has been depleted, the use of Australian pisolite ore has expanded. Since then, Australian pisolite ore has been widely used as iron ore in Japan.
- Marra Mamba ore has a higher content of fines with diameters of 0.15 mm or less than pisolite ore.
- Marra Mamba ore has a higher alumina content ( Al2O3 content) and a lower silica content ( SiO2 content) than pisolite ore.
- Al2O3 content alumina content
- SiO2 content silica content
- Patent Document 1 discloses a method for preventing problems caused by the particle size of Marra Mamba ore by limiting the blending rate of Marra Mamba ore to 70% or less of the total iron ore. According to Patent Document 1, by limiting the blending rate of Marra Mamba ore, the proportion of fine ore with a particle size of 0.25 mm or less can be restricted, thereby suppressing the impact on productivity.
- Patent Document 2 discloses a method for producing sintered ore in which the blending ratio of Brazilian pellet feed is reduced by 30% or more relative to the increase in the blending ratio of Marra Mamba ore relative to the blending ratio of the standard sintered raw materials when Marra Mamba ore is not used, based on the blending ratio of sintered raw materials. According to Patent Document 2, when using Marra Mamba ore, reducing the blending ratio of Brazilian pellet feed, which has poor granulation properties, improves granulation properties and maintains good product yield, sintered ore quality, and productivity.
- Patent Document 3 discloses a method for producing sintered ore by adding pisolite ore to Marra Mamba ore, mixing and granulating the mixture with 3.0 to 5.0% by mass of SiO2 and less than 30% by mass of fine powder of 0.5 mm or less, adding 5 to 10% by mass of water, and adding solid fuel and other ores, mixing and granulating again, and then sintering.
- porous pisolite ore to Marra Mamba ore, adding an appropriate amount of water, and mixing and granulating with a high-speed stirring mixer, some of the fine powder of Marra Mamba ore adheres to the open pores of the pisolite ore, and a mixed granulated product with less fine powder is obtained. It is disclosed that as a result, the pseudo particle size and pseudo particle strength are improved, and the air permeability during the sintering process is improved, thereby improving the production rate and product yield.
- Marra Mamba ore has a lower SiO 2 content, a higher Al 2 O 3 content, and a higher fine powder content than pisolite ore.
- the basicity of the sintered ore in a blast furnace process in which sintered ore is used, so the basicity of the sintered ore must also be kept within a certain range.
- the CaO content in the sintering raw material, the CaO content also decreases with a decrease in SiO 2 content. Therefore, as the replacement of pisolite ore with Marra Mamba ore progresses, the SiO 2 content and CaO content in the sintering raw material decrease, and the Al 2 O 3 content and fine powder content increase.
- Patent Documents 1 to 3 methods have been developed to obtain good air permeability and productivity using Marra Mamba ore by strengthening granulation and limiting the amount of Marra Mamba ore used.
- Patent Documents 1 to 3 do not consider the influence of the difference in chemical composition between Marra Mamba ore and pisolite ore on the sintering process and sintered ore.
- Marra Mamba ore there is no consideration of what the SiO2 content, CaO content, and Al2O3 content should be to obtain high-strength sintered ore with good productivity.
- the present invention was made in consideration of these circumstances, and aims to provide a method for producing sintered ore that can maintain the productivity rate in sintered ore production even when Marra Mamba ore is included in the sintering raw material as a substitute for pisolite ore.
- a method for producing sintered ore which comprises making the total iron ore contain 30.0% by mass or more of iron ore having an iron content of 58.0% by mass or more, a crystal water content of 4.00% by mass or more but less than 9.00% by mass, an Al 2 O 3 content of 2.00% by mass or more, and a SiO 2 content of less than 5.0% by mass, and producing sintered ore from a sintering raw material containing the total iron ore, and adjusting the composition of the sintering raw material so that the SiO 2 content of the sintered ore is 5.50 to 6.00% by mass and the CaO content is 11.0 to 12.0% by mass.
- the iron ore having an iron content of 60.0 mass% or more, a crystal water content of less than 4.00 mass%, an Al2O3 content of less than 1.50 mass%, and a SiO2 content of 4.5 mass% or more and less than 5.0 mass% is adjusted so that the total iron ore contains 55.0 mass% or more of iron ore.
- the productivity rate in the production of sintered ore can be maintained even when Marra Mamba ore is included in the sintering raw material as a substitute for pisolite ore.
- FIG. 1 shows the results of productivity, yield and sintering rate in Tests 1 and 2.
- FIG. 2 shows the results of productivity, yield and sintering rate in Tests 3 and 4.
- FIG. 3 shows the results of productivity, yield and sintering rate in Tests 5 and 6.
- FIG. 4 shows the results of productivity, yield, sintering rate and strength in Tests 3, 4, 7 and 8.
- Marra Mamba ore is used as a substitute for pisolite ore, which has traditionally been used as the iron ore contained in the sintering raw material used to manufacture sintered ore.
- the amount of Marra Mamba ore contained in the sintering raw material is 30.0% by mass or more, which is sufficient to replace pisolite ore.
- Table 2 explains the content of each component, fine powder content, and water of crystallization for Marra Mamba ore used in the production of sintered ore. Table 2 also shows the content of each component, fine powder content, and water of crystallization content for various iron ores used in the production of sintered ore.
- Marra Mamba ore has a composition with an iron content (T.Fe) of 58.0 mass% or more, an Al2O3 content of 2.00 mass% or more, and a SiO2 content of less than 5.0 mass%.
- the water of crystallization (LOI) content of Marra Mamba ore is 4.00 mass% or more and less than 9.00 mass%.
- the sintering raw material is adjusted so that the total iron ore containing 30.0% or more by mass of Marra Mamba ore is included in the sintering raw material, and the composition of the sintered ore after sintering is such that the SiO2 content is 5.50 to 6.00% by mass and the CaO content is 11.0 to 12.0% by mass.
- the sintering raw material is adjusted so that an auxiliary material with a high SiO2 content is included in the sintering raw material, or an auxiliary material with a high SiO2 content is included in the sintering raw material and iron ore with a higher SiO2 content than Marra Mamba ore or pisolite ore is used in combination with Marra Mamba ore.
- iron ore having a higher SiO2 content than Marra Mamba ore or pisolite ore for example, ore F having a higher SiO2 content may be used among the various iron ores shown in Table 2.
- an auxiliary material having a higher SiO2 content for example, silica stone or the like may be used.
- silica stone or the like having a higher SiO2 content may be included as an auxiliary material in the sintering raw material, or an auxiliary material having a higher SiO2 content may be included in the sintering raw material and an ore having a higher SiO2 content than Marra Mamba ore or pisolite ore may be used in combination with the Marra Mamba ore.
- the sintering raw material may be adjusted so that the SiO 2 content is 5.50 to 6.00 mass% and the CaO content is 11.0 to 12.0 mass%, and then the composition of the sintering raw material may be further adjusted so that the Al 2 O 3 content is 1.9 mass% or less.
- iron ore having a lower Al2O3 content than Marra Mamba ore or pisolite ore may be used in combination with Marra Mamba ore.
- the iron ore having a lower Al2O3 content than Marra Mamba ore or pisolite ore may be further adjusted so that it contains 5.0 mass% or more of the iron ore in total.
- low alumina fine ore G having a lower Al 2 O 3 content may be used among various iron ores shown in Table 2. That is, in adjusting the sintering raw material, low alumina fine ore G having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be used in combination with Marra Mamba ore.
- low alumina fine ore G having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be further adjusted so that it contains 5.0 mass% or more of low alumina fine ore G in the total iron ore.
- the composition of low alumina fine ore G is 64.0 mass% or more of iron, less than 1.00 mass% of water of crystallization, and less than 0.50 mass% of Al 2 O 3 .
- the blending ratio of iron ore having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore in the total iron ore may be increased.
- the iron ore having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be adjusted to contain 55.0 mass% or more of the iron ore in the total iron ore.
- ore E having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore and capable of increasing the blending ratio in the total iron ore for example, among various iron ores shown in Table 2, ore E having a lower Al 2 O 3 content may be used. That is, in adjusting the sintering raw material, ore E having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be increased in the blending ratio in the total iron ore. And, ore E having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be further adjusted to contain 55.0 mass% or more in the total iron ore.
- the composition of ore E is 60.0 mass% or more of iron, less than 4.00 mass% of crystal water, less than 1.50 mass% of Al 2 O 3 , and 4.5 mass% or more and less than 5.0 mass% of SiO 2 .
- the increase in Al2O3 content of the sintering raw material due to the use of Marra Mamba ore can be suppressed.
- the increase in the melting point of the molten liquid generated in the sintering raw material during sintering is suppressed, the fluidity of the sintering raw material is increased, the coalescence of solid particles is promoted, and the strength of the sintered ore is improved.
- the shutter strength of the sintered ore can be increased to 75% or more.
- the composition of the sintered ore may be adjusted so that the SiO2 content is 5.50 to 6.00 mass%, the CaO content is 11.0 to 12.0 mass%, and the Al2O3 content is 1.9 mass% or less, and the total iron ore in the sintered raw material may be adjusted so that the proportion of particles smaller than 0.5 mm in the total iron ore is 40.0 mass% or less.
- the productivity of sintered ore can be increased to 1.7 t/(h ⁇ m 2 ) or more.
- sintering raw material which included various iron ores, auxiliary materials including limestone or silica, and carbonaceous materials such as coke, and the sintering raw material was mixed and granulated to obtain pseudo-granulated sintering raw material.
- a sintering test was conducted on the pseudo-granulated sintering raw material using a cylindrical sintering test pot with a diameter of 300 mm and a height of 400 mm. 20 mm of sintered ore was packed as a floor on the fire grate inside the cylindrical sintering test pot, and the pseudo-granulated sintering raw material was packed on top of that as a sintering raw material layer.
- the carbonaceous material contained in the top of the packed sintering raw material layer was ignited, and the combustion of the carbonaceous material progressed downward while air was sucked downward, and the sintering raw material layer was sintered by the combustion heat of the carbonaceous material to obtain a sintered cake.
- the time required from the start of sintering until the temperature of the combustion exhaust gas reached its maximum value was taken as the sintering time.
- the height of the cylindrical sintering test pot was divided by the sintering time to obtain the sintering speed (mm/min).
- the sintered cake was taken out of the cylindrical sintering test pot and dropped four times from a height of 2 m, after which the weight of the sintered cake on the 5 mm sieve was weighed, and the ratio of the weight of the sintered cake on the 5 mm sieve to the weight of the sintered cake before dropping was taken as the yield (mass%).
- the weight of the sintered cake on the 5 mm sieve obtained was divided by the sintering time and the bottom area of the test pot to obtain the productivity (t/(h ⁇ m 2 )).
- the strength (%) of the sintered ore was measured based on the drop strength index (SI) of "JIS M8711 Iron ore sinter - Drop strength test method".
- the sintered raw materials subjected to the sintering test are shown in Table 3.
- the sintering tests were conducted using a total of eight sintering raw materials, as shown in Table 3, for Tests 1 to 3 and Test 5, which are comparative examples, and Tests 4, 6 to 8, which are invention examples.
- the sintering raw materials were adjusted based on the raw material blending ratios shown in Table 3 so that the sintered ore composition after sintering would be as shown in Table 3.
- the sintering raw materials were then mixed, humidified, and granulated to form pseudo-granules, which were then filled into the sintering raw material layer and sintered using the heat of combustion of the carbonaceous material to produce sintered ore.
- the sintering raw materials for Tests 1 to 8 were sintered by sucking air from below the sintering raw material layer based on the suction pressure (kPa) shown in Table 3.
- Test 1 is a comparative example in which pisolite ore was used as the iron ore in the sintering raw material.
- Test 2 Marra Mamba ore was used as the iron ore in the sintering raw material.
- Test 2 is a comparative example in which Marra Mamba ore was used as a substitute for the pisolite ore in Test 1.
- the SiO 2 content in Test 2 was 5.27% by mass compared to the SiO 2 content (5.99% by mass) in Test 1.
- the CaO content in Test 2 was 9.9% by mass compared to the CaO content (11.4% by mass) in Test 1. Accordingly, as shown in FIG. 1, the yield and productivity in Test 2 were lower than those in Test 1. Specifically, the productivity in Test 2 was 1.28 t/(h ⁇ m 2 ) compared to the productivity in Test 1 (1.36 t/(h ⁇ m 2 )). This is because the yield was lowered due to the reduced SiO 2 and CaO contents in the sintering raw material, and the amount of molten liquid generated during sintering was reduced.
- Test 3 shows the results of using pisolite ore as the iron ore in the sintering raw material.
- Test 4 shows the results of using Marra Mamba ore as the iron ore in the sintering raw material.
- silica stone with a high SiO 2 content was further included in the sintering raw material as an auxiliary material.
- Test 4 is an example of the invention in which Marra Mamba ore was used as the iron ore in the sintering raw material, and the sintering raw material was adjusted so that the composition of the sintered ore after sintering was 5.80 mass% SiO 2 and 11.0 mass% CaO.
- Test 3 was conducted under the same conditions as Test 4, except for the adjustment regarding the use of Marra Mamba ore and silica stone in Test 4.
- the SiO2 content in Test 4 was 5.80 mass% compared to the SiO2 content (5.80 mass%) in Test 3.
- the CaO content in Test 4 was 11.0 mass% compared to the CaO content (11.0 mass%) in Test 3.
- a good productivity of 1.62 t/(h ⁇ m2 ) was obtained without causing a decrease in yield as confirmed in the implementation result of Test 2, compared to Test 3.
- Test 5 shows the results of using pisolite ore as the iron ore in the sintering raw material.
- Test 6 shows the results of using Marra Mamba ore as the iron ore in the sintering raw material.
- Test 6 shows the results of using silica stone with a high SiO 2 content as an auxiliary raw material in the sintering raw material in order to suppress the decrease in SiO 2 content in the sintering raw material due to the use of Marra Mamba ore, and also shows the results of using ore F with a high SiO 2 content (see Table 2) in combination with Marra Mamba ore.
- Test 6 is an example of the invention in which Marra Mamba ore is used as the iron ore in the sintering raw material, and the sintering raw material is adjusted so that SiO 2 is 5.59 mass% and CaO is 11.2 mass% in the composition of the sintered ore after sintering.
- Test 5 shows the results of a test conducted under the same conditions as Test 6, except for the adjustments regarding the use of Marra Mamba ore, silica stone, and ore F in Test 6.
- Test 6 achieved a good productivity of 1.54 t/(h ⁇ m2 ) without causing a decrease in yield compared to Test 5.
- Figure 4 shows the results of Test 3, Test 4, and Tests 7 and 8, which are examples of the invention, regarding the strength of sintered ore (shutter strength, hereafter simply referred to as "strength").
- Tests 3 and 4 were conducted using the same sintered raw materials as Tests 3 and 4 shown in Figure 2.
- the strength of the sintered ore in Test 4 was 71.2%, which was lower than the strength of the sintered ore in Test 3 (74.4%) in which pisolite ore was used as the iron ore.
- the Al2O3 content in Test 4 2.06% by mass
- the Al2O3 content in Test 3 1.91% by mass.
- the melting point of the molten liquid generated in the sintering process increased, the fluidity decreased, and the coalescence of solid particles was inhibited, resulting in a decrease in strength.
- Test 7 in order to suppress an increase in the Al2O3 content in the sintering raw material due to the use of Marra Mamba ore, low- alumina fine ore G (see Table 2) with a low Al2O3 content was used in combination with Marra Mamba ore.
- Test 7 is an example of the invention in which Marra Mamba ore was used as the iron ore in the sintering raw material, silica was also used as an auxiliary raw material, and the sintering raw material was adjusted so that the composition of the sintered ore after sintering was 5.80 mass% SiO2 , 11.0 mass% CaO, and 1.90 mass% Al2O3 .
- Test 8 in order to suppress the increase in the Al2O3 content in the sintering raw material due to the use of Marra Mamba ore, the amount of Ore E (see Table 2), which has a low Al2O3 content , mixed in the sintering raw material was increased. That is, Test 8 is an example of the invention in which Marra Mamba ore was used as the iron ore in the sintering raw material, and silica was also used as an auxiliary raw material, and the sintering raw material was adjusted so that the composition of the sintered ore after sintering was 5.80 mass% SiO2 , 11.0 mass% CaO, and 1.88 mass% Al2O3 .
- Tests 7 and 8 show the results of tests conducted under the same conditions as Tests 3 and 4, except for the use of low alumina fine ore G in Test 7 and the adjustment of the increased amount of ore E in Test 8. As shown in Figure 4, Tests 7 and 8 produced good results, with the strength of the sintered ore at 75% or more. Tests 7 and 8 also produced good results, with the yield at 75% or more.
- the sintering speed in Test 7 was slower than in Tests 3 and 4, which were conducted under similar conditions. This is because the proportion of particles smaller than 0.5 mm (hereinafter also referred to as "fine powder") in the iron ore in Test 7 was high, at 40 mass% or more (see Table 3). In other words, when the proportion of fine powder in the total iron ore in the sintering raw material is 40 mass% or more, the air permeability during sintering is significantly reduced, and the sintering speed is reduced. From this result, it can be seen that it is preferable to adjust the proportion of fine powder in the total iron ore in the sintering raw material to less than 40 mass%. This improves air permeability during sintering, and high-strength sintered ore can be obtained at a high productivity rate.
- the ratio of fine powder to the total iron ore in the sintering raw material was adjusted to be less than 40 mass%.
- the sintering speed in Test 8 was faster than that in Test 7.
- the Al 2 O 3 content was 1.90 mass% or less, so the strength of the sintered ore was also good.
- the SiO 2 content was 5.80 mass% and the CaO content was 11.0 mass%, so the yield was also good.
- the amount of melt in the sintering raw material layer increased during sintering, and strong bonding of solid particles was obtained.
- the amount of fine powder in the total iron ore was reduced, and the sintering speed was increased.
- high-strength sintered ore could be obtained at a good sintering speed, and the productivity was greatly improved.
- high-strength sintered ore of 75% or more could be obtained at a high productivity of 1.7 t/(h ⁇ m 2 ) or more.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
本発明は、鉄鉱石を含む焼結原料から焼結鉱を製造する焼結鉱の製造方法に関する。 The present invention relates to a method for producing sintered ore from sintered raw materials containing iron ore.
高炉製銑法の原料である焼結鉱は、粉体を含む鉄鉱石、石灰石等の副原料、コークス等の炭材等を含む焼結原料を焼結することにより製造される。原料である鉄鉱石には、成分や粒度の異なる多様な銘柄が存在し、複数の銘柄の鉄鉱石を配合して焼結原料とする。 Sintered ore, the raw material used in the blast furnace iron-making process, is produced by sintering raw materials that include powdered iron ore, auxiliary materials such as limestone, and carbonaceous materials such as coke. There are many different brands of iron ore with different compositions and particle sizes, and multiple brands of iron ore are blended together to produce the sintered raw material.
我が国で使用されている鉄鉱石は、南米産のヘマタイト鉱石及びマグネタイト鉱石、豪州産のヘマタイト鉱石、ピソライト鉱石及びマラマンバ鉱石に大別される。南米産の鉱石はFe含有量が多く高品位であるが、産地が遠隔地であり輸送費の面で問題がある。豪州産の鉱石は1980年代から生産量が大幅に増加しており、我が国の鉄鉱石の主原料として利用されてきた。2000年代以降、豪州産ヘマタイト鉱石が枯渇に向かうに伴い、豪州産ピソライト鉱石の使用が拡大した。以来、我が国では豪州産ピソライト鉱石が広く鉄鉱石として使用されている。近年、豪州産ピソライト鉱石も枯渇に向かっており、将来の主要な鉄鉱石としてマラマンバ鉱石が注目されている。今後、我が国で使用される豪州産ピソライト鉱石は、マラマンバ鉱石に代替されていくことが予想される。各種の鉄鉱石の性状及び組成について、表1に示す。 The iron ore used in Japan is broadly divided into hematite ore and magnetite ore from South America, and hematite ore, pisolite ore, and Marra Mamba ore from Australia. South American ore is high in Fe content and high quality, but its origin is remote, which creates a problem in terms of transportation costs. The production of Australian ore has increased significantly since the 1980s, and it has been used as the main raw material for iron ore in Japan. Since the 2000s, as Australian hematite ore has been depleted, the use of Australian pisolite ore has expanded. Since then, Australian pisolite ore has been widely used as iron ore in Japan. In recent years, Australian pisolite ore has also been depleted, and Marra Mamba ore has been attracting attention as the main iron ore of the future. It is expected that Australian pisolite ore used in Japan will be replaced by Marra Mamba ore in the future. The properties and compositions of various iron ores are shown in Table 1.
表1に示す通り、マラマンバ鉱石は、ピソライト鉱石に比べて、直径が0.15mm以下の微粉の含有量が多い。マラマンバ鉱石は、ピソライト鉱石に比べて、アルミナ含有量(Al2O3含有量)が多く、シリカ含有量(SiO2含有量)が少ない。これを踏まえ、マラマンバ鉱石の使用による微粉含有量の増加に対応するため、マラマンバ鉱石を使用した焼結原料の焼結においては、焼結プロセスにおける焼結原料の通気性向上を指向した開発が行われてきた。 As shown in Table 1, Marra Mamba ore has a higher content of fines with diameters of 0.15 mm or less than pisolite ore. Marra Mamba ore has a higher alumina content ( Al2O3 content) and a lower silica content ( SiO2 content) than pisolite ore. In light of this, in order to deal with the increase in fine content caused by the use of Marra Mamba ore, development has been carried out to improve the permeability of the sintering raw material during the sintering process when using Marra Mamba ore as the sintering raw material.
特許文献1には、全鉄鉱石に占めるマラマンバ鉱石の配合率を70%以下とすることで、マラマンバ鉱石の粒度に起因した問題を防止する方法が開示されている。特許文献1によれば、マラマンバ鉱石の配合率を制限することで、粒径0.25mm以下の細粒の鉱石の割合を制限し、生産性への影響を抑制できるとしている。 Patent Document 1 discloses a method for preventing problems caused by the particle size of Marra Mamba ore by limiting the blending rate of Marra Mamba ore to 70% or less of the total iron ore. According to Patent Document 1, by limiting the blending rate of Marra Mamba ore, the proportion of fine ore with a particle size of 0.25 mm or less can be restricted, thereby suppressing the impact on productivity.
特許文献2には、マラマンバ鉱石を用いない場合の焼結原料の配合を基準とし、ブラジル産ペレットフィードの配合率を、基準の焼結原料の配合に対するマラマンバ鉱石の配合率の増加率に対して30%以上減少させる焼結鉱の製造方法が開示されている。特許文献2によれば、マラマンバ鉱石を使用する際に、造粒性に乏しいブラジル産ペレットフィードの配合率を減じることで、造粒性を改善し、良好な成品歩留まり、焼結鉱品質、生産性を維持できるとしている。 Patent Document 2 discloses a method for producing sintered ore in which the blending ratio of Brazilian pellet feed is reduced by 30% or more relative to the increase in the blending ratio of Marra Mamba ore relative to the blending ratio of the standard sintered raw materials when Marra Mamba ore is not used, based on the blending ratio of sintered raw materials. According to Patent Document 2, when using Marra Mamba ore, reducing the blending ratio of Brazilian pellet feed, which has poor granulation properties, improves granulation properties and maintains good product yield, sintered ore quality, and productivity.
特許文献3には、マラマンバ鉱石にピソライト鉱石を添加して、SiO2が3.0~5.0質量%、0.5mm以下の微粉含有量が30質量%未満とした配合物に、水分を5~10質量%添加して高速撹拌混合機で混合造粒し、固体燃料とその他鉱石を添加し、再度混合造粒したのち焼結する焼結鉱の製造方法が開示されている。マラマンバ鉱石に多孔質なピソライト鉱石を添加し、適量の水分を加えて高速撹拌混合機で混合造粒することで、ピソライト鉱石の開気孔内にマラマンバ鉱石の微粉の一部が付着し、微粉の少ない混合造粒物が得られる。その結果、擬似粒子径や擬似粒子強度が改善し、焼結過程での通気性が向上して生産率や成品歩留が向上することが開示されている。 Patent Document 3 discloses a method for producing sintered ore by adding pisolite ore to Marra Mamba ore, mixing and granulating the mixture with 3.0 to 5.0% by mass of SiO2 and less than 30% by mass of fine powder of 0.5 mm or less, adding 5 to 10% by mass of water, and adding solid fuel and other ores, mixing and granulating again, and then sintering. By adding porous pisolite ore to Marra Mamba ore, adding an appropriate amount of water, and mixing and granulating with a high-speed stirring mixer, some of the fine powder of Marra Mamba ore adheres to the open pores of the pisolite ore, and a mixed granulated product with less fine powder is obtained. It is disclosed that as a result, the pseudo particle size and pseudo particle strength are improved, and the air permeability during the sintering process is improved, thereby improving the production rate and product yield.
マラマンバ鉱石は、ピソライト鉱石と比べてSiO2含有量が少なく、Al2O3含有量が多く、微粉含有量が多い。また、焼結鉱が用いられる高炉プロセスにおいては、生成されるスラグの塩基度を制御する必要があるため、焼結鉱の塩基度も一定の範囲内に保つ必要がある。このため、焼結原料においては、SiO2含有量の減少に伴い、CaO含有量も減少する。従って、マラマンバ鉱石によるピソライト鉱石の代替が進むにつれ、焼結原料におけるSiO2含有量及びCaO含有量の減少、Al2O3含有量の増加及び微粉含有量の増加が進む。また、微粉含有量が増加した場合、焼結プロセスにおける焼結原料の通気性が低下し、焼結速度の低下や生産率の低下を招く。そのため、特許文献1~3に開示される通り、造粒の強化やマラマンバ鉱石の使用量を制限することで、マラマンバ鉱石を使用して良好な通気性や生産性を得る方法が開発されてきた。 Marra Mamba ore has a lower SiO 2 content, a higher Al 2 O 3 content, and a higher fine powder content than pisolite ore. In addition, in a blast furnace process in which sintered ore is used, it is necessary to control the basicity of the slag produced, so the basicity of the sintered ore must also be kept within a certain range. For this reason, in the sintering raw material, the CaO content also decreases with a decrease in SiO 2 content. Therefore, as the replacement of pisolite ore with Marra Mamba ore progresses, the SiO 2 content and CaO content in the sintering raw material decrease, and the Al 2 O 3 content and fine powder content increase. In addition, if the fine powder content increases, the air permeability of the sintering raw material in the sintering process decreases, leading to a decrease in the sintering speed and a decrease in the productivity. For this reason, as disclosed in Patent Documents 1 to 3, methods have been developed to obtain good air permeability and productivity using Marra Mamba ore by strengthening granulation and limiting the amount of Marra Mamba ore used.
他方、特許文献1~3において、マラマンバ鉱石とピソライト鉱石との化学組成の相違による焼結プロセス及び焼結鉱への影響については考慮されていない。特に、マラマンバ鉱石を使用する際に、SiO2含有量やCaO含有量、Al2O3含有量をどの程度にすれば、高強度な焼結鉱を良好な生産性にて得られるか、検討がなされていない。 On the other hand, Patent Documents 1 to 3 do not consider the influence of the difference in chemical composition between Marra Mamba ore and pisolite ore on the sintering process and sintered ore. In particular, when using Marra Mamba ore, there is no consideration of what the SiO2 content, CaO content, and Al2O3 content should be to obtain high-strength sintered ore with good productivity.
本発明は、かかる事情を鑑みてなされたもので、ピソライト鉱石の代替としてマラマンバ鉱石を焼結原料に含めた場合であっても、焼結鉱の製造における生産率を維持できる焼結鉱の製造方法を提供することを目的とする。 The present invention was made in consideration of these circumstances, and aims to provide a method for producing sintered ore that can maintain the productivity rate in sintered ore production even when Marra Mamba ore is included in the sintering raw material as a substitute for pisolite ore.
上記課題を解決する本発明の要旨構成は以下のとおりである。
[1]鉄含有量が58.0質量%以上、結晶水含有量が4.00質量%以上9.00質量%未満、Al2O3含有量が2.00質量%以上、SiO2含有量が5.0質量%未満である鉄鉱石を全鉄鉱石において30.0質量%以上含ませると共に、当該全鉄鉱石を含む焼結原料から焼結鉱を製造する焼結鉱の製造方法であって、前記焼結鉱のSiO2含有量が5.50~6.00質量%、CaO含有量が11.0~12.0質量%となるように、前記焼結原料の配合を調整する、焼結鉱の製造方法。
[2]前記焼結原料の配合の調整では、珪石を前記焼結原料に含むように調整する、[1]に記載の焼結鉱の製造方法。
[3]前記焼結原料の配合の調整では、前記焼結鉱のAl2O3含有量が1.9質量%以下となるように調整する、[1]または[2]に記載の焼結鉱の製造方法。
[4]前記焼結原料の配合の調整では、鉄含有量が64.0質量%以上、結晶水含有量が1.00質量%未満、Al2O3含有量が0.50質量%未満である鉄鉱石を、前記全鉄鉱石において5.0質量%以上含むように調整する、[3]に記載の焼結鉱の製造方法。
[5]前記焼結原料の配合の調整では、鉄含有量が60.0質量%以上、結晶水含有量が4.00質量%未満、Al2O3含有量が1.50質量%未満、SiO2含有量が4.5質量%以上5.0質量%未満である鉄鉱石を、前記全鉄鉱石において55.0質量%以上含むように調整する、[3]に記載の焼結鉱の製造方法。
[6]前記焼結原料の配合の調整では、前記全鉄鉱石における0.5mm未満の粒子の割合が40.0質量%以下となるように調整する、[5]に記載の焼結鉱の製造方法。
The gist and configuration of the present invention to solve the above problems are as follows.
[1] A method for producing sintered ore, which comprises making the total iron ore contain 30.0% by mass or more of iron ore having an iron content of 58.0% by mass or more, a crystal water content of 4.00% by mass or more but less than 9.00% by mass, an Al 2 O 3 content of 2.00% by mass or more, and a SiO 2 content of less than 5.0% by mass, and producing sintered ore from a sintering raw material containing the total iron ore, and adjusting the composition of the sintering raw material so that the SiO 2 content of the sintered ore is 5.50 to 6.00% by mass and the CaO content is 11.0 to 12.0% by mass.
[2] The method for producing sintered ore described in [1], wherein the composition of the sintering raw materials is adjusted so that silica stone is contained in the sintering raw materials.
[3] The method for producing sintered ore according to [1] or [2], wherein the composition of the sintering raw materials is adjusted so that the Al 2 O 3 content of the sintered ore is 1.9 mass% or less.
[4] The method for producing sintered ore according to [3], wherein the composition of the sintering raw materials is adjusted so that the iron ore contains 5.0 mass% or more of iron ore having an iron content of 64.0 mass% or more, a crystal water content of less than 1.00 mass%, and an Al2O3 content of less than 0.50 mass% in the total iron ore.
[5] In the adjustment of the composition of the sintering raw materials, the iron ore having an iron content of 60.0 mass% or more, a crystal water content of less than 4.00 mass%, an Al2O3 content of less than 1.50 mass%, and a SiO2 content of 4.5 mass% or more and less than 5.0 mass% is adjusted so that the total iron ore contains 55.0 mass% or more of iron ore.
[6] The method for producing sintered ore described in [5], wherein the composition of the sintering raw material is adjusted so that the proportion of particles smaller than 0.5 mm in the total iron ore is 40.0 mass% or less.
本発明によれば、ピソライト鉱石の代替としてマラマンバ鉱石を焼結原料に含めた場合であっても、焼結鉱の製造における生産率を維持できる。 According to the present invention, the productivity rate in the production of sintered ore can be maintained even when Marra Mamba ore is included in the sintering raw material as a substitute for pisolite ore.
以下、本発明の実施形態を通じて本発明を説明する。 The present invention will be explained below through an embodiment of the present invention.
本実施形態では、焼結鉱の製造に使用される焼結原料に関し、焼結原料に含める鉄鉱石として従来から使用されていたピソライト鉱石の代替として、マラマンバ鉱石を使用する。マラマンバ鉱石は、ピソライト鉱石を代替するのに十分な量として、焼結原料に含まれる全鉄鉱石において30.0質量%以上含める。 In this embodiment, Marra Mamba ore is used as a substitute for pisolite ore, which has traditionally been used as the iron ore contained in the sintering raw material used to manufacture sintered ore. The amount of Marra Mamba ore contained in the sintering raw material is 30.0% by mass or more, which is sufficient to replace pisolite ore.
焼結鉱の製造に使用されるマラマンバ鉱石について、表2を用いて、各組成の含有量、微粉含有量、結晶水含有量を説明する。表2は、焼結鉱の製造に使用される各種の鉄鉱石における各成分の含有量、微粉含有量、結晶水含有量も示す。 Table 2 explains the content of each component, fine powder content, and water of crystallization for Marra Mamba ore used in the production of sintered ore. Table 2 also shows the content of each component, fine powder content, and water of crystallization content for various iron ores used in the production of sintered ore.
マラマンバ鉱石は、表2に示す通り、鉄含有量(T.Fe)が58.0質量%以上、Al2O3含有量が2.00質量%以上、SiO2含有量が5.0質量%未満の組成を有する。マラマンバ鉱石の結晶水含有量(LOI)は、4.00質量%以上9.00質量%未満である。 As shown in Table 2, Marra Mamba ore has a composition with an iron content (T.Fe) of 58.0 mass% or more, an Al2O3 content of 2.00 mass% or more, and a SiO2 content of less than 5.0 mass%. The water of crystallization (LOI) content of Marra Mamba ore is 4.00 mass% or more and less than 9.00 mass%.
そして、マラマンバ鉱石を30.0質量%以上含む全鉄鉱石を焼結原料に含ませると共に、焼結後の焼結鉱の組成について、SiO2含有量が5.50~6.00質量%、CaO含有量が11.0~12.0質量%となるように、焼結原料の調整を行う。具体的に、焼結原料の調整では、SiO2含有量の多い副原料を焼結原料に含める、又は、SiO2含有量の多い副原料を焼結原料に含めると共にマラマンバ鉱石やピソライト鉱石よりもSiO2含有量の多い鉄鉱石をマラマンバ鉱石と併用するように焼結原料の配合を調整する。 The sintering raw material is adjusted so that the total iron ore containing 30.0% or more by mass of Marra Mamba ore is included in the sintering raw material, and the composition of the sintered ore after sintering is such that the SiO2 content is 5.50 to 6.00% by mass and the CaO content is 11.0 to 12.0% by mass. Specifically, the sintering raw material is adjusted so that an auxiliary material with a high SiO2 content is included in the sintering raw material, or an auxiliary material with a high SiO2 content is included in the sintering raw material and iron ore with a higher SiO2 content than Marra Mamba ore or pisolite ore is used in combination with Marra Mamba ore.
マラマンバ鉱石やピソライト鉱石よりもSiO2含有量の多い鉄鉱石として、例えば、表2に示す各種の鉄鉱石のうち、SiO2含有量の多い鉱石Fを用いてもよい。また、SiO2含有量の多い副原料として、例えば、珪石等を用いてもよい。即ち、焼結原料の調整では、SiO2含有量の多い珪石等を副原料として焼結原料に含める、又は、SiO2含有量の多い副原料を焼結原料に含めると共にマラマンバ鉱石やピソライト鉱石よりもSiO2含有量の多い鉱石をマラマンバ鉱石と併用するように焼結原料の配合を調整してもよい。 As iron ore having a higher SiO2 content than Marra Mamba ore or pisolite ore, for example, ore F having a higher SiO2 content may be used among the various iron ores shown in Table 2. Also, as an auxiliary material having a higher SiO2 content, for example, silica stone or the like may be used. That is, in adjusting the sintering raw material, silica stone or the like having a higher SiO2 content may be included as an auxiliary material in the sintering raw material, or an auxiliary material having a higher SiO2 content may be included in the sintering raw material and an ore having a higher SiO2 content than Marra Mamba ore or pisolite ore may be used in combination with the Marra Mamba ore.
これにより、マラマンバ鉱石の使用に伴う焼結原料のSiO2含有量の減少を補填できるので、CaO含有量を低下させずとも塩基度を一定に保つことができ、CaO含有量の低下が抑制される。この結果、焼結時において焼結原料内に十分な融液が生成され、焼結鉱の歩留の低下が抑制されて、1.5t/h・m2以上の良い生産率が得られる。 This makes it possible to compensate for the decrease in the SiO2 content of the sintering raw material caused by the use of Marra Mamba ore, so that the basicity can be kept constant without decreasing the CaO content, and the decrease in the CaO content is suppressed. As a result, sufficient molten liquid is generated in the sintering raw material during sintering, the decrease in the sintered ore yield is suppressed, and a good productivity of 1.5 t/h m2 or more can be obtained.
また、焼結鉱の組成について、SiO2含有量が5.50~6.00質量%、CaO含有量が11.0~12.0質量%となるように焼結原料の調整を行った後、Al2O3が1.9質量%以下となるように、焼結原料の配合の調整を更に行ってもよい。 In addition, regarding the composition of the sintered ore, the sintering raw material may be adjusted so that the SiO 2 content is 5.50 to 6.00 mass% and the CaO content is 11.0 to 12.0 mass%, and then the composition of the sintering raw material may be further adjusted so that the Al 2 O 3 content is 1.9 mass% or less.
具体的に、焼結原料の調整では、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量の少ない鉄鉱石をマラマンバ鉱石と併用してもよい。この場合、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量の少ない鉄鉱石を、全鉄鉱石において5.0質量%以上含むように更に調整してもよい。 Specifically, in adjusting the sintering raw material, iron ore having a lower Al2O3 content than Marra Mamba ore or pisolite ore may be used in combination with Marra Mamba ore. In this case, the iron ore having a lower Al2O3 content than Marra Mamba ore or pisolite ore may be further adjusted so that it contains 5.0 mass% or more of the iron ore in total.
マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量が少なく、マラマンバ鉱石と併用し得る鉄鉱石として、例えば、表2に示す各種の鉄鉱石のうち、Al2O3含有量が少ない低アルミナ微粉鉱石Gを用いてもよい。つまり、焼結原料の調整では、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量の少ない低アルミナ微粉鉱石Gをマラマンバ鉱石と併用してもよい。そして、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量の少ない低アルミナ微粉鉱石Gを、全鉄鉱石において5.0質量%以上含むように更に調整してもよい。低アルミナ微粉鉱石Gの組成は、表2に示す通り、鉄含有量が64.0質量%以上、結晶水含有量が1.00質量%未満、Al2O3含有量が0.50質量%未満である。 As iron ore having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore and usable in combination with Marra Mamba ore, for example, low alumina fine ore G having a lower Al 2 O 3 content may be used among various iron ores shown in Table 2. That is, in adjusting the sintering raw material, low alumina fine ore G having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be used in combination with Marra Mamba ore. And, low alumina fine ore G having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be further adjusted so that it contains 5.0 mass% or more of low alumina fine ore G in the total iron ore. As shown in Table 2, the composition of low alumina fine ore G is 64.0 mass% or more of iron, less than 1.00 mass% of water of crystallization, and less than 0.50 mass% of Al 2 O 3 .
また、焼結原料の調整では、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量の少ない鉄鉱石について、全鉄鉱石における配合率を増加する増配をしてもよい。この場合、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量の少ない鉄鉱石を、全鉄鉱石において55.0質量%以上含むように調整してもよい。 In addition, in adjusting the sintering raw material, the blending ratio of iron ore having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore in the total iron ore may be increased. In this case, the iron ore having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be adjusted to contain 55.0 mass% or more of the iron ore in the total iron ore.
マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量が少なく、全鉄鉱石における配合率を増配し得る鉄鉱石として、例えば、表2に示す各種の鉄鉱石のうち、Al2O3含有量が少ない鉱石Eを用いてもよい。つまり、焼結原料の調整では、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量の少ない鉱石Eを、全鉄鉱石における配合率を増加する増配をしてもよい。そして、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量の少ない鉱石Eを、全鉄鉱石において55.0質量%以上含むように更に調整してもよい。鉱石Eの組成は、表2に示す通り、鉄含有量が60.0質量%以上、結晶水含有量が4.00質量%未満、Al2O3含有量が1.50質量%未満、SiO2含有量が4.5質量%以上5.0質量%未満である。 As an iron ore having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore and capable of increasing the blending ratio in the total iron ore, for example, among various iron ores shown in Table 2, ore E having a lower Al 2 O 3 content may be used. That is, in adjusting the sintering raw material, ore E having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be increased in the blending ratio in the total iron ore. And, ore E having a lower Al 2 O 3 content than Marra Mamba ore or pisolite ore may be further adjusted to contain 55.0 mass% or more in the total iron ore. As shown in Table 2, the composition of ore E is 60.0 mass% or more of iron, less than 4.00 mass% of crystal water, less than 1.50 mass% of Al 2 O 3 , and 4.5 mass% or more and less than 5.0 mass% of SiO 2 .
このように、マラマンバ鉱石やピソライト鉱石よりもAl2O3含有量が少ない鉄鉱石の併用又は増配により、マラマンバ鉱石の使用に伴う焼結原料のAl2O3含有量の増加を抑制できる。その結果、焼結時において焼結原料内に生成される融液の融点の上昇が抑制されて、焼結原料の流動性が増して固体粒子の合体が促進され、焼結鉱の強度が向上する。具体的に、焼結鉱のシャッター強度を75%以上とすることができる。 In this way, by using or increasing the amount of iron ore with a lower Al2O3 content than Marra Mamba ore or pisolite ore, the increase in Al2O3 content of the sintering raw material due to the use of Marra Mamba ore can be suppressed. As a result, the increase in the melting point of the molten liquid generated in the sintering raw material during sintering is suppressed, the fluidity of the sintering raw material is increased, the coalescence of solid particles is promoted, and the strength of the sintered ore is improved. Specifically, the shutter strength of the sintered ore can be increased to 75% or more.
また、焼結鉱の組成について、SiO2含有量が5.50~6.00質量%、CaO含有量が11.0~12.0質量%、Al2O3が1.9質量%以下となるように焼結原料の調整を行うと共に、全鉄鉱石において0.5mm未満の粒子の割合が40.0質量%以下となるように、焼結原料における全鉄鉱石を調整してもよい。 In addition, the composition of the sintered ore may be adjusted so that the SiO2 content is 5.50 to 6.00 mass%, the CaO content is 11.0 to 12.0 mass%, and the Al2O3 content is 1.9 mass% or less, and the total iron ore in the sintered raw material may be adjusted so that the proportion of particles smaller than 0.5 mm in the total iron ore is 40.0 mass% or less.
このように、焼結原料において、全鉄鉱石における0.5mm未満の粒子の割合が40.0質量%以下となるように調整することで、焼結時における焼結原料層の通気性が向上し、焼結プロセスの促進の効果により、焼結鉱の生産率が更に向上する。具体的に、焼結鉱の生産率を1.7t/(h・m2)以上とすることができる。 In this way, by adjusting the ratio of particles smaller than 0.5 mm in the total iron ore in the sintering raw material to 40.0 mass % or less, the air permeability of the sintering raw material layer during sintering is improved, and the sintering process is accelerated, thereby further improving the productivity of sintered ore. Specifically, the productivity of sintered ore can be increased to 1.7 t/(h·m 2 ) or more.
以下、本実施形態に係る焼結鉱の製造方法を用いて行った実施例を説明する。 Below, we will explain examples that were carried out using the sintered ore manufacturing method according to this embodiment.
各種の鉄鉱石と、石灰石又は珪石等を含む副原料と、コークス等の炭材とを含む焼結原料に、数パーセントの水分を添加し、混合及び造粒して擬似粒化した焼結原料を得た。擬似粒化した焼結原料について、直径が300mm、高さが400mmである円筒型焼結試験鍋を用いて焼結試験を行った。円筒型焼結試験鍋の内部の火格子上に、床敷として焼結鉱を20mm充填し、その上に擬似粒化した焼結原料を焼結原料層として充填した。充填した焼結原料層について、上方に含まれる炭材に着火させると共に、下方に向けて空気を吸引しながら、炭材の燃焼を下方に進行させ、炭材の燃焼熱により焼結原料層を焼結させて焼結ケーキを得た。 Several percent of water was added to the sintering raw material, which included various iron ores, auxiliary materials including limestone or silica, and carbonaceous materials such as coke, and the sintering raw material was mixed and granulated to obtain pseudo-granulated sintering raw material. A sintering test was conducted on the pseudo-granulated sintering raw material using a cylindrical sintering test pot with a diameter of 300 mm and a height of 400 mm. 20 mm of sintered ore was packed as a floor on the fire grate inside the cylindrical sintering test pot, and the pseudo-granulated sintering raw material was packed on top of that as a sintering raw material layer. The carbonaceous material contained in the top of the packed sintering raw material layer was ignited, and the combustion of the carbonaceous material progressed downward while air was sucked downward, and the sintering raw material layer was sintered by the combustion heat of the carbonaceous material to obtain a sintered cake.
実施例においては、焼結の開始から燃焼排ガスの温度が最大値を示すまでに要した時間を焼結時間とした。また、円筒型焼結試験鍋の高さを焼結時間で除した値を焼結速度(mm/min)とした。そして、焼結の完了後に、焼結ケーキを円筒型焼結試験鍋から取り出して、2mの高さより4回落下させた後に、5mm篩上の焼結ケーキの重量を秤量し、落下前の焼結ケーキの重量に占める5mm篩上の焼結ケーキの重量の割合を歩留(質量%)とした。更に、得られた5mm篩上の焼結ケーキの重量について、焼結時間および試験鍋底面積で除した値を生産率(t/(h・m2))とした。焼結鉱の強度(%)は、「JIS M8711 鉄鉱石焼結鉱-落下強度試験方法」の落下強度指数(SI)に基づいて測定した。焼結試験を行った焼結原料を表3に示す。 In the examples, the time required from the start of sintering until the temperature of the combustion exhaust gas reached its maximum value was taken as the sintering time. The height of the cylindrical sintering test pot was divided by the sintering time to obtain the sintering speed (mm/min). After the completion of sintering, the sintered cake was taken out of the cylindrical sintering test pot and dropped four times from a height of 2 m, after which the weight of the sintered cake on the 5 mm sieve was weighed, and the ratio of the weight of the sintered cake on the 5 mm sieve to the weight of the sintered cake before dropping was taken as the yield (mass%). The weight of the sintered cake on the 5 mm sieve obtained was divided by the sintering time and the bottom area of the test pot to obtain the productivity (t/(h·m 2 )). The strength (%) of the sintered ore was measured based on the drop strength index (SI) of "JIS M8711 Iron ore sinter - Drop strength test method". The sintered raw materials subjected to the sintering test are shown in Table 3.
焼結試験を行った焼結原料は、表3に示す通り、比較例である試験1~3及び試験5、発明例である試験4、6~8についての合計8つの焼結原料を用いて実施した。焼結原料は、焼結後に表3に示す焼結鉱組成として示す値となるように、表3に示す原料配合率に基づいて調整した。そして、混合、調湿、造粒することで擬似粒化した焼結原料を焼結原料層として充填し、炭材の燃焼熱により焼結して焼結鉱とした。なお、試験1~試験8の焼結原料は、表3に示す吸引圧力(kPa)に基づいて焼結原料層の下方から空気を吸引して焼結を行った。 The sintering tests were conducted using a total of eight sintering raw materials, as shown in Table 3, for Tests 1 to 3 and Test 5, which are comparative examples, and Tests 4, 6 to 8, which are invention examples. The sintering raw materials were adjusted based on the raw material blending ratios shown in Table 3 so that the sintered ore composition after sintering would be as shown in Table 3. The sintering raw materials were then mixed, humidified, and granulated to form pseudo-granules, which were then filled into the sintering raw material layer and sintered using the heat of combustion of the carbonaceous material to produce sintered ore. The sintering raw materials for Tests 1 to 8 were sintered by sucking air from below the sintering raw material layer based on the suction pressure (kPa) shown in Table 3.
<実施例1>比較例である試験1及び試験2の実施結果を図1に示す。試験1は、焼結原料における鉄鉱石にピソライト鉱石を用いた比較例である。試験2では、焼結原料における鉄鉱石にマラマンバ鉱石を用いた。即ち、試験2は、試験1におけるピソライト鉱石の代替として、マラマンバ鉱石を用いた比較例である。 <Example 1> Figure 1 shows the results of Test 1 and Test 2, which are comparative examples. Test 1 is a comparative example in which pisolite ore was used as the iron ore in the sintering raw material. In Test 2, Marra Mamba ore was used as the iron ore in the sintering raw material. In other words, Test 2 is a comparative example in which Marra Mamba ore was used as a substitute for the pisolite ore in Test 1.
表3に示す通り、試験1におけるSiO2含有量(5.99質量%)に比べて、試験2におけるSiO2含有量は、5.27質量%となった。また、試験1におけるCaO含有量(11.4質量%)に比べて、試験2におけるCaO含有量は、9.9質量%となった。これに伴い、図1に示す通り、試験2は、試験1に比べて歩留が低下すると共に生産率も低下した。具体的に、試験1における生産率(1.36t/(h・m2))に比べて、試験2における生産率は、1.28t/(h・m2)となった。これは、焼結原料中のSiO2含有量及びCaO含有量が減少し、焼結時に生成する融液が減少することで、歩留が低下したことによる。 As shown in Table 3, the SiO 2 content in Test 2 was 5.27% by mass compared to the SiO 2 content (5.99% by mass) in Test 1. Also, the CaO content in Test 2 was 9.9% by mass compared to the CaO content (11.4% by mass) in Test 1. Accordingly, as shown in FIG. 1, the yield and productivity in Test 2 were lower than those in Test 1. Specifically, the productivity in Test 2 was 1.28 t/(h·m 2 ) compared to the productivity in Test 1 (1.36 t/(h·m 2 )). This is because the yield was lowered due to the reduced SiO 2 and CaO contents in the sintering raw material, and the amount of molten liquid generated during sintering was reduced.
<実施例2>次に、比較例である試験3及び発明例である試験4の実施結果を図2に示す。試験3は、焼結原料における鉄鉱石にピソライト鉱石を用いた実施結果を示す。試験4は、焼結原料における鉄鉱石にマラマンバ鉱石を用いた実施結果を示す。試験4では、マラマンバ鉱石を用いることに伴う焼結原料中のSiO2含有量の低下を抑制するため、更に副原料としてSiO2含有量の多い珪石を焼結原料に含めた。即ち、試験4は、焼結原料における鉄鉱石にマラマンバ鉱石を使用し、焼結後の焼結鉱の組成のうち、SiO2が5.80質量%、CaOが11.0質量%となるように、焼結原料の調整を行った発明例である。試験3は、試験4におけるマラマンバ鉱石及び珪石の使用に関する調整を除き、試験4と同様の条件にて試験を行った。 <Example 2> Next, the results of Test 3, which is a comparative example, and Test 4, which is an example of the invention, are shown in FIG. 2. Test 3 shows the results of using pisolite ore as the iron ore in the sintering raw material. Test 4 shows the results of using Marra Mamba ore as the iron ore in the sintering raw material. In Test 4, in order to suppress the decrease in the SiO 2 content in the sintering raw material due to the use of Marra Mamba ore, silica stone with a high SiO 2 content was further included in the sintering raw material as an auxiliary material. That is, Test 4 is an example of the invention in which Marra Mamba ore was used as the iron ore in the sintering raw material, and the sintering raw material was adjusted so that the composition of the sintered ore after sintering was 5.80 mass% SiO 2 and 11.0 mass% CaO. Test 3 was conducted under the same conditions as Test 4, except for the adjustment regarding the use of Marra Mamba ore and silica stone in Test 4.
表3に示す通り、試験3におけるSiO2含有量(5.80質量%)に比べて、試験4におけるSiO2含有量は、5.80質量%となった。また、試験3におけるCaO含有量(11.0質量%)に比べて、試験4におけるCaO含有量は、11.0質量%となった。この結果、図2に示す通り、試験4では、試験3に対して、試験2の実施結果で確認されたような歩留の低下を起こすことなく、1.62t/(h・m2)の良好な生産率を得られた。 As shown in Table 3, the SiO2 content in Test 4 was 5.80 mass% compared to the SiO2 content (5.80 mass%) in Test 3. Also, the CaO content in Test 4 was 11.0 mass% compared to the CaO content (11.0 mass%) in Test 3. As a result, as shown in FIG. 2, in Test 4, a good productivity of 1.62 t/(h· m2 ) was obtained without causing a decrease in yield as confirmed in the implementation result of Test 2, compared to Test 3.
<実施例3>次に、比較例である試験5及び発明例である試験6の実施結果を図3に示す。試験5は、焼結原料における鉄鉱石にピソライト鉱石を用いた実施結果を示す。試験6は、焼結原料における鉄鉱石にマラマンバ鉱石を用いた実施結果を示す。試験6は、マラマンバ鉱石を用いることに伴う焼結原料中のSiO2含有量の低下を抑制するため、更に副原料としてSiO2含有量の多い珪石を焼結原料に含めると共に、SiO2含有量の多い鉱石F(表2参照)をマラマンバ鉱石と併用した実施結果を示す。即ち、試験6は、焼結原料における鉄鉱石にマラマンバ鉱石を使用し、焼結後の焼結鉱の組成のうち、SiO2が5.59質量%、CaOが11.2質量%となるように、焼結原料の調整を行った発明例である。試験5は、試験6におけるマラマンバ鉱石、珪石及び鉱石Fの使用に関する調整を除き、試験6と同様の条件にて試験を行った実施結果を示す。 <Example 3> Next, the results of Test 5, which is a comparative example, and Test 6, which is an example of the invention, are shown in FIG. 3. Test 5 shows the results of using pisolite ore as the iron ore in the sintering raw material. Test 6 shows the results of using Marra Mamba ore as the iron ore in the sintering raw material. Test 6 shows the results of using silica stone with a high SiO 2 content as an auxiliary raw material in the sintering raw material in order to suppress the decrease in SiO 2 content in the sintering raw material due to the use of Marra Mamba ore, and also shows the results of using ore F with a high SiO 2 content (see Table 2) in combination with Marra Mamba ore. That is, Test 6 is an example of the invention in which Marra Mamba ore is used as the iron ore in the sintering raw material, and the sintering raw material is adjusted so that SiO 2 is 5.59 mass% and CaO is 11.2 mass% in the composition of the sintered ore after sintering. Test 5 shows the results of a test conducted under the same conditions as Test 6, except for the adjustments regarding the use of Marra Mamba ore, silica stone, and ore F in Test 6.
表3に示す通り、試験5におけるSiO2含有量(5.60質量%)に比べて、試験6におけるSiO2含有量は、5.59質量%となった。また、試験5におけるCaO含有量(11.2質量%)に比べて、試験6におけるCaO含有量は、11.2質量%となった。この結果、図3に示す通り、試験6では、試験5に対して、歩留の低下を起こすことなく、1.54t/(h・m2)の良好な生産率を得られた。 As shown in Table 3, the SiO2 content in Test 6 was 5.59 mass% compared to the SiO2 content (5.60 mass%) in Test 5. Also, the CaO content in Test 6 was 11.2 mass% compared to the CaO content (11.2 mass%) in Test 5. As a result, as shown in Figure 3, Test 6 achieved a good productivity of 1.54 t/(h· m2 ) without causing a decrease in yield compared to Test 5.
<実施例4>焼結鉱の強度(シャッター強度。以下、単に「強度」という。)に関し、試験3、試験4、発明例である試験7及び試験8の実施結果を図4に示す。図4において、試験3及び試験4は、図2に示した試験3及び試験4と同一の焼結原料を用いて行った試験である。 <Example 4> Figure 4 shows the results of Test 3, Test 4, and Tests 7 and 8, which are examples of the invention, regarding the strength of sintered ore (shutter strength, hereafter simply referred to as "strength"). In Figure 4, Tests 3 and 4 were conducted using the same sintered raw materials as Tests 3 and 4 shown in Figure 2.
図4に示す通り、試験4は、焼結鉱の強度が71.2%となっており、鉄鉱石にピソライト鉱石を用いた試験3における焼結鉱の強度(74.4%)よりも低かった。これは、試験4におけるAl2O3含有量(2.06質量%)が、試験3におけるAl2O3含有量(1.91質量%)よりも多いことが原因といえる。つまり、焼結原料中のAl2O3含有量が増加した結果、焼結過程において生成する融液の融点が上昇することで、流動性が低下し、固体粒子の合体が阻害されることで、強度の低下が生じたといえる。このため、焼結原料に含まれる鉄鉱石にマラマンバ鉱石を使用しつつ、高強度な焼結鉱を得るためには、Al2O3含有量を制限することが好ましいことがわかる。 As shown in Fig. 4, the strength of the sintered ore in Test 4 was 71.2%, which was lower than the strength of the sintered ore in Test 3 (74.4%) in which pisolite ore was used as the iron ore. This is because the Al2O3 content in Test 4 (2.06% by mass) was higher than the Al2O3 content in Test 3 (1.91% by mass). In other words, as a result of the increase in the Al2O3 content in the sintering raw material, the melting point of the molten liquid generated in the sintering process increased, the fluidity decreased, and the coalescence of solid particles was inhibited, resulting in a decrease in strength. For this reason, it can be seen that it is preferable to limit the Al2O3 content in order to obtain high-strength sintered ore while using Marra Mamba ore as the iron ore contained in the sintering raw material.
試験7では、マラマンバ鉱石を用いることに伴う焼結原料中のAl2O3含有量の増加を抑制するため、Al2O3含有量の少ない低アルミナ微粉鉱石G(表2参照)をマラマンバ鉱石と併用した。即ち、試験7は、焼結原料における鉄鉱石にマラマンバ鉱石を使用すると共に副原料として珪石を併用しつつ、焼結後の焼結鉱の組成のうち、SiO2が5.80質量%、CaOが11.0質量%、Al2O3が1.90質量%となるように、焼結原料の調整を行った発明例である。 In Test 7, in order to suppress an increase in the Al2O3 content in the sintering raw material due to the use of Marra Mamba ore, low- alumina fine ore G (see Table 2) with a low Al2O3 content was used in combination with Marra Mamba ore. In other words, Test 7 is an example of the invention in which Marra Mamba ore was used as the iron ore in the sintering raw material, silica was also used as an auxiliary raw material, and the sintering raw material was adjusted so that the composition of the sintered ore after sintering was 5.80 mass% SiO2 , 11.0 mass% CaO, and 1.90 mass% Al2O3 .
試験8では、マラマンバ鉱石を用いることに伴う焼結原料中のAl2O3含有量の増加を抑制するため、Al2O3含有量の少ない鉱石E(表2参照)を焼結原料中において配合量を増加させる増配をした。即ち、試験8は、焼結原料における鉄鉱石にマラマンバ鉱石を使用すると共に副原料として珪石を併用しつつ、焼結後の焼結鉱の組成のうち、SiO2が5.80質量%、CaOが11.0質量%、Al2O3が1.88質量%となるように、焼結原料の調整を行った発明例である。 In Test 8, in order to suppress the increase in the Al2O3 content in the sintering raw material due to the use of Marra Mamba ore, the amount of Ore E (see Table 2), which has a low Al2O3 content , mixed in the sintering raw material was increased. That is, Test 8 is an example of the invention in which Marra Mamba ore was used as the iron ore in the sintering raw material, and silica was also used as an auxiliary raw material, and the sintering raw material was adjusted so that the composition of the sintered ore after sintering was 5.80 mass% SiO2 , 11.0 mass% CaO, and 1.88 mass% Al2O3 .
図4において、試験7及び試験8は、試験7における低アルミナ微粉鉱石Gの使用及び試験8における鉱石Eの増配に関する調整を除き、試験3及び試験4と同様の条件にて試験を行った実施結果を示す。図4に示す通り、試験7及び試験8では、焼結鉱の強度が75%以上となる良好な結果が得られた。また、試験7及び試験8では、歩留が75%以上となる良好な結果も得られた。 In Figure 4, Tests 7 and 8 show the results of tests conducted under the same conditions as Tests 3 and 4, except for the use of low alumina fine ore G in Test 7 and the adjustment of the increased amount of ore E in Test 8. As shown in Figure 4, Tests 7 and 8 produced good results, with the strength of the sintered ore at 75% or more. Tests 7 and 8 also produced good results, with the yield at 75% or more.
特に試験7では、焼結鉱の強度が80%以上となる高い強度を得ることができた。これは、Al2O3量を制限したことに加え、微粉鉱石による焼結原料層における通気阻害の影響から、焼結速度が低下したためといえる。試験8では、焼結鉱の強度が75%以上となる良好な結果を得ることができた。これは、Al2O3含有量を制限することで、焼結時に生成する融液の融点の上昇を抑制し、強固な粒子結合を得られた結果、焼結鉱の強度が向上したためといえる。 In particular, in Test 7, a high strength of 80% or more was obtained. This is because the sintering rate decreased due to the influence of the air permeability inhibition in the sintering raw material layer caused by the fine ore powder, in addition to the restriction of the Al2O3 content. In Test 8, a good result of 75% or more strength was obtained. This is because the restriction of the Al2O3 content suppressed the rise in the melting point of the molten liquid generated during sintering, and strong particle bonding was obtained, resulting in improved strength of the sintered ore.
ここで、図4に示す通り、試験7においては、同様の条件にて試験を行った試験3及び試験4と比べて、焼結速度が遅い結果となった。これは、試験7において鉄鉱石中に占める0.5mm未満の粒子(以下、「微粉」ともいう。)の割合が、40質量%以上と多い(表3参照)ことが原因といえる。即ち、焼結原料における全鉄鉱石に占める微粉の割合が40質量%以上になると、焼結時の通気性が大きく低下し、焼結速度が低下することとなる。この結果から、焼結原料における全鉄鉱石に占める微粉の割合が40質量%未満となるように調整することが好ましいことがわかる。これにより、焼結時の通気性が向上し、高強度な焼結鉱を高い生産率にて得ることができる。 As shown in Figure 4, the sintering speed in Test 7 was slower than in Tests 3 and 4, which were conducted under similar conditions. This is because the proportion of particles smaller than 0.5 mm (hereinafter also referred to as "fine powder") in the iron ore in Test 7 was high, at 40 mass% or more (see Table 3). In other words, when the proportion of fine powder in the total iron ore in the sintering raw material is 40 mass% or more, the air permeability during sintering is significantly reduced, and the sintering speed is reduced. From this result, it can be seen that it is preferable to adjust the proportion of fine powder in the total iron ore in the sintering raw material to less than 40 mass%. This improves air permeability during sintering, and high-strength sintered ore can be obtained at a high productivity rate.
このため、表3に示す通り、試験8では、焼結原料における全鉄鉱石に占める微粉の割合が40質量%未満となるように調整した。この結果、試験8は、試験7に比べて焼結速度が速くなった。試験8は、Al2O3含有量が1.90質量%以下となっているため、焼結鉱の強度も良好な結果となった。また、試験8は、SiO2含有量が5.80質量%、CaO含有量が11.0質量%であるため、歩留も良好な結果となった。そして、焼結時において焼結原料層の融液量が増加し、固体粒子の強固な結合が得られたことに加え、全鉄鉱石中の微粉が減少して焼結速度が速くなった結果、高強度な焼結鉱を良好な焼結速度で得ることができ生産率が大きく向上した。具体的に、試験8では、75%以上の高強度な焼結鉱を1.7t/(h・m2)以上という高い生産率にて得ることができた。 Therefore, as shown in Table 3, in Test 8, the ratio of fine powder to the total iron ore in the sintering raw material was adjusted to be less than 40 mass%. As a result, the sintering speed in Test 8 was faster than that in Test 7. In Test 8, the Al 2 O 3 content was 1.90 mass% or less, so the strength of the sintered ore was also good. In addition, in Test 8, the SiO 2 content was 5.80 mass% and the CaO content was 11.0 mass%, so the yield was also good. Then, the amount of melt in the sintering raw material layer increased during sintering, and strong bonding of solid particles was obtained. In addition, the amount of fine powder in the total iron ore was reduced, and the sintering speed was increased. As a result, high-strength sintered ore could be obtained at a good sintering speed, and the productivity was greatly improved. Specifically, in Test 8, high-strength sintered ore of 75% or more could be obtained at a high productivity of 1.7 t/(h·m 2 ) or more.
Claims (6)
前記焼結鉱のSiO2含有量が5.50~6.00質量%、CaO含有量が11.0~12.0質量%となるように、前記焼結原料の配合を調整する、焼結鉱の製造方法。 A method for producing sintered ore, comprising the steps of: making the total iron ore contain 30.0% by mass or more of iron ore having an iron content of 58.0% by mass or more, a crystal water content of 4.00% by mass or more but less than 9.00% by mass, an Al2O3 content of 2.00% by mass or more, and a SiO2 content of less than 5.0% by mass; and producing sintered ore from a sintering raw material containing the total iron ore,
A method for producing sintered ore, comprising adjusting the composition of the sintering raw material so that the SiO2 content of the sintered ore is 5.50 to 6.00 mass% and the CaO content is 11.0 to 12.0 mass%.
The method for producing sintered ore according to claim 5, wherein the composition of the sintering raw material is adjusted so that a ratio of particles smaller than 0.5 mm in the total iron ore is 40.0 mass % or less.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020257023982A KR20250126081A (en) | 2023-01-26 | 2023-11-09 | Method for producing sintered ore |
| EP23918527.5A EP4624600A4 (en) | 2023-01-26 | 2023-11-09 | METHOD FOR THE PRODUCTION OF SINTERED ORE |
| JP2024501583A JP7460041B1 (en) | 2023-01-26 | 2023-11-09 | Sinter manufacturing method |
| CN202380091510.1A CN120530211A (en) | 2023-01-26 | 2023-11-09 | Method for producing sintered ore |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2023-009991 | 2023-01-26 | ||
| JP2023009991 | 2023-01-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2024157572A1 true WO2024157572A1 (en) | 2024-08-02 |
Family
ID=91970249
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2023/040356 Ceased WO2024157572A1 (en) | 2023-01-26 | 2023-11-09 | Sintered ore production method |
Country Status (2)
| Country | Link |
|---|---|
| TW (1) | TWI870118B (en) |
| WO (1) | WO2024157572A1 (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10502417A (en) * | 1994-07-06 | 1998-03-03 | ビーエイチピー・アイアン・オア・ピーティワイ・リミテッド | Sintering of iron ore containing porous ore |
| JP2001348623A (en) * | 2000-06-07 | 2001-12-18 | Nkk Corp | Method for producing high quality low SiO2 sintered ore for blast furnace |
| JP2004137575A (en) | 2002-10-18 | 2004-05-13 | Kobe Steel Ltd | Production method for sintered ore |
| JP2009019224A (en) * | 2007-07-10 | 2009-01-29 | Sumitomo Metal Ind Ltd | Method for producing sintered ore |
| JP4786022B2 (en) | 2000-10-25 | 2011-10-05 | 新日本製鐵株式会社 | Method for producing sintered ore |
| JP5004421B2 (en) | 2004-09-17 | 2012-08-22 | Jfeスチール株式会社 | Method for producing sintered ore |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5464317B2 (en) * | 2007-11-22 | 2014-04-09 | Jfeスチール株式会社 | Manufacturing method of forming raw material for sinter production |
| EP3550037B1 (en) * | 2017-02-16 | 2025-04-02 | JFE Steel Corporation | Method for manufacturing sintered ore |
| CN115261613B (en) * | 2022-05-26 | 2023-11-28 | 柳州钢铁股份有限公司 | Iron ore powder evaluation and comparison method, sinter raw material selection and sintering method |
-
2023
- 2023-11-09 WO PCT/JP2023/040356 patent/WO2024157572A1/en not_active Ceased
- 2023-11-22 TW TW112145059A patent/TWI870118B/en active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10502417A (en) * | 1994-07-06 | 1998-03-03 | ビーエイチピー・アイアン・オア・ピーティワイ・リミテッド | Sintering of iron ore containing porous ore |
| JP2001348623A (en) * | 2000-06-07 | 2001-12-18 | Nkk Corp | Method for producing high quality low SiO2 sintered ore for blast furnace |
| JP4786022B2 (en) | 2000-10-25 | 2011-10-05 | 新日本製鐵株式会社 | Method for producing sintered ore |
| JP2004137575A (en) | 2002-10-18 | 2004-05-13 | Kobe Steel Ltd | Production method for sintered ore |
| JP5004421B2 (en) | 2004-09-17 | 2012-08-22 | Jfeスチール株式会社 | Method for producing sintered ore |
| JP2009019224A (en) * | 2007-07-10 | 2009-01-29 | Sumitomo Metal Ind Ltd | Method for producing sintered ore |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP4624600A1 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW202430655A (en) | 2024-08-01 |
| TWI870118B (en) | 2025-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6686974B2 (en) | Sintered ore manufacturing method | |
| JP7460041B1 (en) | Sinter manufacturing method | |
| WO2024157572A1 (en) | Sintered ore production method | |
| JP2002129246A (en) | Sinter production method | |
| KR100787359B1 (en) | Method for producing sintered steel | |
| JP2009019224A (en) | Method for producing sintered ore | |
| JP2004137575A (en) | Production method for sintered ore | |
| JP2003096521A (en) | Sinter ore containing high alumina iron ore and production method thereof | |
| JP4767388B2 (en) | Method for producing sintered ore with excellent high-temperature properties | |
| JP7754374B1 (en) | Sinter manufacturing method | |
| JP4725230B2 (en) | Method for producing sintered ore | |
| JP4661077B2 (en) | Method for producing sintered ore | |
| JP5126580B2 (en) | Method for producing sintered ore | |
| JP6885164B2 (en) | Sintered ore manufacturing method | |
| JP2009114485A (en) | Method for manufacturing sintered ore | |
| JP2007327096A (en) | Method for producing sintered ore using brucite | |
| JP4982986B2 (en) | Method for producing sintered ore | |
| JP4412313B2 (en) | Manufacturing method of high quality low SiO2 sintered ore | |
| JP4501656B2 (en) | Method for producing sintered ore | |
| JPH073342A (en) | Method for producing sinter having excellent softening and melting properties | |
| JPH0827525A (en) | Method for producing sintered ore using highly crystallized water ore as raw material | |
| TW202540446A (en) | Sintered ore production method | |
| JP2002332526A (en) | Pre-processing method for sintering raw materials | |
| JP2548647B2 (en) | Manufacturing method of sintered ore for iron making from high goethite iron ore | |
| JP5074043B2 (en) | Method for producing sintered ore |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WWE | Wipo information: entry into national phase |
Ref document number: 2024501583 Country of ref document: JP |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 23918527 Country of ref document: EP Kind code of ref document: A1 |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 202517059262 Country of ref document: IN |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2023918527 Country of ref document: EP |
|
| WWP | Wipo information: published in national office |
Ref document number: 202517059262 Country of ref document: IN |
|
| ENP | Entry into the national phase |
Ref document number: 2023918527 Country of ref document: EP Effective date: 20250624 |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 202380091510.1 Country of ref document: CN |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 1020257023982 Country of ref document: KR |
|
| WWP | Wipo information: published in national office |
Ref document number: 1020257023982 Country of ref document: KR Ref document number: 202380091510.1 Country of ref document: CN |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| WWP | Wipo information: published in national office |
Ref document number: 2023918527 Country of ref document: EP |