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WO2024157371A1 - Solar battery module and conversion device - Google Patents

Solar battery module and conversion device Download PDF

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Publication number
WO2024157371A1
WO2024157371A1 PCT/JP2023/002195 JP2023002195W WO2024157371A1 WO 2024157371 A1 WO2024157371 A1 WO 2024157371A1 JP 2023002195 W JP2023002195 W JP 2023002195W WO 2024157371 A1 WO2024157371 A1 WO 2024157371A1
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WO
WIPO (PCT)
Prior art keywords
solar cell
wavelength
light
cell module
transparent layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2023/002195
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French (fr)
Japanese (ja)
Inventor
将司 宮田
史英 小林
俊和 橋本
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NTT Inc
Original Assignee
Nippon Telegraph and Telephone Corp
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Publication date
Application filed by Nippon Telegraph and Telephone Corp filed Critical Nippon Telegraph and Telephone Corp
Priority to JP2024572582A priority Critical patent/JPWO2024157371A1/ja
Priority to PCT/JP2023/002195 priority patent/WO2024157371A1/en
Publication of WO2024157371A1 publication Critical patent/WO2024157371A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S40/00Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
    • H02S40/20Optical components
    • H02S40/22Light-reflecting or light-concentrating means

Definitions

  • the present invention relates to a solar cell module and a conversion device.
  • Non-Patent Document 1 a tandem solar cell has been proposed that uses a multi-junction compound semiconductor in which multiple materials with different bandgaps are stacked in the photoelectric conversion section, and that efficiently absorbs and photoelectrically converts sunlight with a wide spectrum.
  • tandem solar cells there is a problem with tandem solar cells in that there is a limit to the materials that can be bonded as multi-junction compound semiconductors, and there is a limit to how much improvement can be made in photoelectric conversion efficiency.
  • the present invention has been made in consideration of the above, and aims to provide a solar cell module and conversion device that can improve photoelectric conversion efficiency.
  • the solar cell module of the present invention is characterized by having a plurality of solar cells, each of which absorbs light in a respective predetermined wavelength band and converts it into electricity, a transparent layer covering the plurality of solar cells, and an optical element having a plurality of structures arranged on or within the transparent layer in the surface direction of the transparent layer at a period equal to or smaller than the wavelength of the incident light, the plurality of structures being arranged to separate the incident light into each of the predetermined wavelength bands and focus the light on the solar cell corresponding to each wavelength band.
  • the conversion device is characterized by having the above-mentioned solar cell module, a secondary battery that stores power, and a power conversion unit that boosts the input voltage from the solar cell module and supplies it to the secondary battery.
  • the present invention provides a solar cell module and conversion device that can improve photoelectric conversion efficiency.
  • FIG. 1 is a side view showing a schematic configuration of a conversion device according to an embodiment.
  • FIG. 2 is a diagram illustrating an example of a cross section of a main part of a solar cell module according to an embodiment.
  • FIG. 3 is a diagram showing a schematic arrangement of solar cells when the solar cell module according to the embodiment is viewed in plan.
  • FIG. 4 is a diagram showing an example of a cross section of the solar cell module when viewed from the side along the line aa' in FIG.
  • FIG. 5 is a diagram showing an example of a cross section of the solar cell module when viewed from the side along the line bb' in FIG.
  • FIG. 6 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG.
  • FIG. 1 is a side view showing a schematic configuration of a conversion device according to an embodiment.
  • FIG. 2 is a diagram illustrating an example of a cross section of a main part of a solar cell module according to an embodiment.
  • FIG. 7 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG.
  • FIG. 8 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG.
  • FIG. 9 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG.
  • FIG. 10 is a diagram showing a schematic arrangement of solar cells when the solar cell module according to the embodiment is viewed in plan.
  • FIG. 11 is a diagram showing an example of a cross section of the solar cell module when viewed from the side along the line cc' in FIG.
  • FIG. 12 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG. FIG.
  • FIG. 13 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG.
  • FIG. 14 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG.
  • FIG. 15 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 16 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 17 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 18 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 19 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 20 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 21 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 22 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 23 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 24 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. FIG. 20 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment.
  • FIG. 21 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the
  • FIG. 25 is a diagram showing an example of a schematic configuration of the structure shown in FIG.
  • FIG. 26 is a diagram showing an example of a schematic configuration of the structure shown in FIG.
  • FIG. 27 is a diagram showing an example of a schematic configuration of the structure shown in FIG.
  • FIG. 28 is a diagram showing an example of a schematic configuration of the structure shown in FIG.
  • FIG. 29 is a diagram showing an example of a schematic configuration of the structure shown in FIG.
  • FIG. 30 is a diagram showing an example of a schematic configuration of the structure shown in FIG.
  • FIG. 31 is a diagram showing an example of a cross-sectional shape of the structure shown in FIG.
  • FIG. 32 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 500 nm.
  • FIG. 32 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 500 nm.
  • FIG. 33 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 650 nm.
  • FIG. 34 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 800 nm.
  • FIG. 35 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 1000 nm.
  • FIG. 36 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 500 nm.
  • FIG. 37 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 650 nm.
  • FIG. 38 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 1000 nm.
  • FIG. 39 is a diagram illustrating an example of a cross section of a main part of a conventional solar cell module.
  • FIG. 40 is a diagram showing a schematic diagram of the wavelength dependency of the intensity of light radiated/absorbed by the solar cell module shown in FIG.
  • FIG. 41 is a diagram illustrating another example of a cross section of a main part of a conventional solar cell module.
  • FIG. 42 is a diagram showing a schematic diagram of the wavelength dependency of the intensity of light radiated/absorbed by the solar cell module shown in FIG. 41.
  • FIG. 43 is a diagram illustrating the wavelength dependency of the intensity of light radiated/absorbed by the solar cell module shown in FIG.
  • Fig. 1 is a block diagram showing an example of a schematic configuration of a conversion device according to an embodiment.
  • the conversion device 10 includes a solar cell module 1 having multiple solar cells that generate power, a power conversion unit 2 that, for example, boosts the input voltage from the solar cell module 1 and supplies it to a secondary battery, and a secondary battery 3 that stores the power generated by the solar cell module 1.
  • FIG. 2 is a diagram showing an example of a cross section of a main part of a solar cell module according to an embodiment.
  • a part of the solar cell module 1 will be described as a solar cell module 100.
  • an xyz coordinate system is shown in the subsequent figures.
  • the xy plane direction corresponds to the surface direction of the solar cell 110, the transparent layer 140, etc., which will be described later.
  • plane view refers to viewing in the z-axis direction (e.g., the z-axis negative direction).
  • ide view refers to viewing in the x-axis direction or the y-axis direction (e.g., the y-axis positive direction).
  • the solar cell module 100 has a plurality of solar cells 110-1 to 110-3 and a wavelength separation lens 120 (optical element) having a microscopic structure 150 integrated on the solar cells 110-1 to 110-3.
  • the solar cells 110-1 to 110-3 and the solar cell 110-4 described below are collectively referred to as solar cell 110.
  • Each of the solar cell units 110-1 to 110-3 absorbs light in a predetermined wavelength band and converts it into electricity.
  • the solar cell unit 110-1 absorbs light in wavelength band B1 and converts it into electricity.
  • the solar cell unit 110-2 absorbs light in wavelength band B2 and converts it into electricity.
  • the solar cell unit 110-3 absorbs light in wavelength band B3 and converts it into electricity.
  • the solar cells 110-1 to 110-3 each have a p-type semiconductor layer 160-1 to 160-3 and an n-type semiconductor layer 170-1 to 170-3 as a photoelectric conversion unit.
  • Each of the solar cells 110-1 to 110-3 has a material having a high light absorption rate in the corresponding wavelength bands B1 , B2 , and B3 as a photoelectric conversion unit.
  • An anti-reflection layer 180 is laminated on the n-type semiconductor layers 170-1 to 170-3.
  • the solar cells 110-1 to 110-3 each have a front electrode 190 connected to the n-type semiconductor layers 170-1 to 170-3 and a back electrode 200 connected to the p-type semiconductor layers 160-1 to 160-3.
  • Examples of materials constituting the photoelectric conversion unit include silicon-based materials such as x-Si and a-Si:H, compound semiconductors such as GaAs, InAs, GaInAs, Zn 3 P 2 , Cu 2 S, CuInSe 2 , CuIn 1-x GaxSe 2 , InP, CdTe, and CdS, organic semiconductors, photocatalytic materials (such as titanium oxide), and dye-sensitized materials consisting of dye molecules.
  • silicon-based materials such as x-Si and a-Si:H
  • compound semiconductors such as GaAs, InAs, GaInAs, Zn 3 P 2 , Cu 2 S, CuInSe 2 , CuIn 1-x GaxSe 2 , InP, CdTe, and CdS
  • organic semiconductors such as silicon oxide
  • photocatalytic materials such as titanium oxide
  • dye-sensitized materials consisting of dye molecules.
  • the wavelength separation lens 120 separates the incident light (for example, sunlight) into wavelength bands (for example, wavelength bands B 1 , B 2 , B 3 ) and focuses the light on each of the solar cell 110-1 to 110-3.
  • the wavelength separation lens 120 focuses the wavelength band B 1 of the incident light on the solar cell 110-1.
  • the wavelength separation lens 120 focuses the wavelength band B 2 of the incident light on the solar cell 110-2.
  • the wavelength separation lens 120 focuses the wavelength band B 3 of the incident light on the solar cell 110-3.
  • the wavelength bands (B k ) separated by the wavelength separation lens 120 correspond to bands obtained by arbitrarily dividing the spectral wavelength band of sunlight.
  • the wavelength separation lens 120 may be designed so that the wavelength bands separated by the wavelength separation lens 120 are adapted to the absorption spectrum of the existing solar cell 110.
  • the wavelength separation lens 120 has a transparent layer 140 that covers the multiple solar cells 110-1 to 110-3, and multiple columnar structures 150 arranged on the bottom surface of the transparent layer 140.
  • the structures 150 are supported by the transparent layer 140 above.
  • the multiple structures 150 are arranged so as to separate the incident light into each of the predetermined wavelength bands and focus the light on the solar cell 110-110-3 corresponding to each wavelength band.
  • the multiple structures 150 are arranged in the plane direction of the transparent layer 140 with a period equal to or less than the wavelength of the incident light.
  • the multiple structures 150 are made of columnar structures of constant height, and their in-plane shapes (upper and lower surfaces) have four-fold rotational symmetry. In the embodiment, the occurrence of polarization dependency is suppressed by making the shape of the structures 150 four-fold rotational symmetry.
  • Each of the plurality of structures 150 is formed from a material such as TiO2 or SiN having a refractive index higher than that of the transparent layers 130 and 140.
  • Each of the plurality of structures 150 is a columnar structure that imparts an optical phase delay amount to incident light according to the cross-sectional shape when the transparent layers 130 and 140 are viewed in plan.
  • the cross-sectional shape of the plurality of structures 150 is set according to an optical phase delay distribution for realizing light concentration on each of the solar cell arrays 110-1 to 110-3, and the structures 150 are arranged according to an optical phase delay distribution for realizing light concentration on each of the solar cell arrays 110-1 to 110-3.
  • the solar cell module 100 separates the incident light into a plurality of wavelength bands (e.g., wavelength bands B1 , B2 , B3 ) and receives the light with solar cell cells 110 (e.g., 110-1 to 110-3) having light absorption spectra suited to each wavelength band. Therefore, the solar cell module 100 maximizes the amount of photoelectric conversion in each wavelength band and increases efficiency compared to conventional solar cell modules.
  • wavelength bands B1 , B2 , B3 receives the light with solar cell cells 110 (e.g., 110-1 to 110-3) having light absorption spectra suited to each wavelength band. Therefore, the solar cell module 100 maximizes the amount of photoelectric conversion in each wavelength band and increases efficiency compared to conventional solar cell modules.
  • Each solar cell 110 (e.g., 110-1 to 110-3) may be a photoelectric conversion unit using a single material. Therefore, even if the solar cells 110 are made of materials that would be difficult to join together in a conventional tandem solar cell, each solar cell 110 having an optical absorption spectrum corresponding to each of the separated wavelength bands can be used simultaneously. Therefore, compared to conventional solar cells, the solar cell module 100 can efficiently absorb and photoelectrically convert light in multiple wavelength bands, and compared to conventional tandem solar cells, the difficulty of fabrication can be significantly reduced, and fabrication costs can also be reduced.
  • the wavelength separation lens 120 may also focus light of the same wavelength band on a plurality of solar cells 110.
  • the wavelength separation lens 120 focuses light of wavelength band B1 on the solar cell 110-1, but when a solar cell 110-3 is disposed at the position of the solar cell 110-1, the wavelength separation lens 120 may be designed to focus light of wavelength band B3 on the solar cell 110-3 instead of wavelength band B1 .
  • the wavelength separation lens 120 and the solar cell 110 may be arrayed, or may be composed of one wavelength separation lens 120 and a plurality of solar cells 110 as shown in FIG. 2.
  • FIG. 3 is a diagram showing a schematic arrangement of solar cell cells 110 when the solar cell module 100-1 according to the embodiment is viewed in plan.
  • FIG. 4 is a diagram showing an example of a cross section of the solar cell module 100-1 when viewed from the side along line a-a' in FIG. 3.
  • FIG. 5 is a diagram showing an example of a cross section of the solar cell module 100-1 when viewed from the side along line bb' in FIG. 3.
  • arrows typically indicate light incident on the solar cell module 100-1.
  • a wavelength separation lens 120-1 is arranged on the solar cells 110-1 to 110-4. Also, for example, one wavelength separation lens 120-1 may face the four solar cells 110-1 to 110-4 directly below it.
  • the solar cell 110-4 absorbs light in the wavelength band B4 and converts it into electricity.
  • the solar cell 110-4 has a p-type semiconductor layer 160-4 and an n-type semiconductor layer 170-4 as a photoelectric conversion unit, an anti-reflection layer 180 is laminated on the n-type semiconductor layer 170-4, and has a front electrode 190 connected to the n-type semiconductor layer 170-4 and a back electrode 200 connected to the p-type semiconductor layer 160-4.
  • the wavelength separation lens 120-1 separates the incident light into wavelength bands B 1 , B 2 , B 3 , and B 4 and focuses the separated light onto the solar cells 110-1 to 110-4 having optical absorption spectra suited to the respective wavelength bands B 1 , B 2 , B 3 , and B 4 .
  • the wavelength separation lens 120-1 focuses light in wavelength band B1 from the incident light onto the solar cell 110-1.
  • the wavelength separation lens 120-1 focuses light in wavelength band B2 from the incident light onto the solar cell 110-2.
  • the wavelength separation lens 120-1 focuses light in wavelength band B3 from the incident light onto the solar cell 110-3.
  • the wavelength separation lens 120-1 focuses light in wavelength band B4 from the incident light onto the solar cell 110-4.
  • the power generated by the solar cell cells 110-1 to 110-4 is output to the power conversion unit 2 via wiring connected to the back electrode 200 and the front electrode 190.
  • the wavelength separation lens 120-1 is provided so as to cover the solar cell 110-1 to 110-4.
  • An example of the wavelength separation lens 120-1 is a metasurface.
  • the metasurface is composed of multiple microstructures (corresponding to the structure 150) having a width equal to or less than the wavelength of light.
  • the metasurface may have a two-dimensional structure or a three-dimensional structure.
  • the wavelength separation lens 120-1 can control the phase and light intensity according to the characteristics of the light (wavelength, polarization, and angle of incidence) simply by changing the parameters of this structure 150. Furthermore, a three-dimensional structure provides greater design freedom than a two-dimensional structure.
  • the wavelength separation lens 120-1 has two functions: a wavelength separation function and a lens function.
  • the wavelength separation function is to separate the incident light into light of each wavelength band.
  • the lens function is to focus the light of each wavelength onto the corresponding pixel.
  • the wavelength separation function of the wavelength separation lens 120-1 separates the incident light into wavelength bands B1 , B2 , B3 , and B4 .
  • the light in the wavelength bands B1 , B2 , B3 , and B4 is focused on the solar cell 110-1 to 110-4 corresponding to the wavelength bands B1 , B2 , B3 , and B4 , respectively, by the lens function of the wavelength separation lens 120-1.
  • FIGS. 6 to 9 are schematic diagrams showing the concentration of light onto solar cells 110-1 to 110-4 in the solar cell module 100-1 shown in FIG. 3.
  • the wavelength separation function and lens function of the wavelength separation lens 120-1 allow light in wavelength band B1 to be concentrated on the solar cell 110-1 corresponding to the wavelength band B1 .
  • the multiple structures 150 are arranged so that light in wavelength band B1 that is incident outside the region facing the solar cell 110-1 is also concentrated on the solar cell 110-1.
  • the wavelength separation function and lens function of the wavelength separation lens 120-1 cause light in wavelength band B2 to be concentrated on the solar cell 110-2 corresponding to wavelength band B2 .
  • the multiple structures 150 are arranged so that light in wavelength band B2 that is incident outside the region facing the solar cell 110-2 is also concentrated on the solar cell 110-2.
  • the wavelength separation function and lens function of the wavelength separation lens 120-1 concentrate light in wavelength band B3 on the solar cell 110-3 corresponding to wavelength band B3 , as shown by the arrow in Fig. 8.
  • the multiple structures 150 are arranged so that light in wavelength band B3 that is incident outside the region facing the solar cell 110-3 is also concentrated on the solar cell 110-3.
  • the wavelength separation function and lens function of the wavelength separation lens 120-1 cause light in wavelength band B4 to be concentrated on the solar cell 110-4 corresponding to wavelength band B4 .
  • the multiple structures 150 are arranged so that light in wavelength band B4 that is incident outside the region facing the solar cell 110-4 is also concentrated on the solar cell 110-4.
  • the solar cell module 100-1 can receive a greater amount of light than when only light in the wavelength bands B1 , B2 , B3 , and B4 of the incident light in the opposing areas with the solar cells 110-1 to 110-4 is concentrated onto the solar cells 110-1 to 110-4.
  • the wavelength separation lens 120-1 may focus light of the same wavelength band on a plurality of solar cells 110.
  • the wavelength separation lens 120-1 focuses light of wavelength band B2 on the solar cell 110-2, but when the solar cell 110-4 is disposed at the position of the solar cell 110-2, the lens may be designed to focus light of wavelength band B4 on the solar cell 110-4 instead of wavelength band B2 .
  • Fig. 10 is a diagram showing a schematic arrangement of solar cells 110 when the solar cell module 100-2 according to the embodiment is viewed in plan.
  • Fig. 11 is a diagram showing an example of a cross section of the solar cell module 100-2 when viewed from the side along line c-c' in Fig. 10. In Fig. 11, arrows typically indicate light incident on the solar cell module 100-2.
  • a wavelength separation lens 120-2 is arranged above the solar cells 110-1 to 110-3.
  • one wavelength separation lens 120-2 may face the three solar cells 110-1 to 110-3 directly below it.
  • the wavelength separation lens 120-2 separates the incident light into wavelength bands B 1 , B 2 , and B 3 and focuses the separated light onto the solar cells 110-1 to 110-3 having optical absorption spectra suited to the respective wavelength bands B 1 , B 2 , and B 3 .
  • the wavelength separation lens 120-2 focuses light in wavelength band B1 from the incident light onto the solar cell 110-1.
  • the wavelength separation lens 120-2 focuses light in wavelength band B2 from the incident light onto the solar cell 110-2.
  • the wavelength separation lens 120-2 focuses light in wavelength band B3 from the incident light onto the solar cell 110-3.
  • the power generated by the solar cells 110-1 to 110-3 is output to the power conversion unit 2 via wiring connected to the back electrode 200 and the front electrode 190.
  • the wavelength separation lens 120-2 is provided to cover the solar cells 110-1 to 110-3.
  • An example of the wavelength separation lens 120-2 is a metasurface.
  • the wavelength separation lens 120-2 has two functions: a wavelength separation function and a lens function.
  • the wavelength separation function of the wavelength separation lens 120-2 separates the incident light into wavelength bands B1 , B2 , and B3 .
  • the light in the wavelength bands B1 , B2 , and B3 is focused on the solar cell 110-1 to 110-3 corresponding to the wavelength bands B1 , B2 , and B3 , respectively, by the lens function of the wavelength separation lens 120-2.
  • FIGS. 12 to 14 are schematic diagrams showing the concentration of light onto solar cells 110-1 to 110-3 in the solar cell module 100-2 shown in FIG. 10.
  • the solar cell module 100-2 As shown by the arrows in Fig. 12, light in wavelength band B1 is concentrated on the solar cell 110-1 corresponding to wavelength band B1 .
  • light in wavelength band B1 is concentrated on the solar cell 110-1 corresponding to wavelength band B1 .
  • the multiple structures 150 are arranged so that light in wavelength band B1 that is incident outside the region facing the solar cell 110-1 is also concentrated on the solar cell 110-1.
  • wavelength band B2 In the solar cell module 100-2, light in wavelength band B2 is concentrated on the solar cell 110-2 corresponding to wavelength band B2 , as shown by the arrows in Fig. 13.
  • the multiple structures 150 are arranged so that light in wavelength band B2 that is incident outside the region facing the solar cell 110-2 is also concentrated on the solar cell 110-2.
  • wavelength band B3 In the solar cell module 100-2, light in wavelength band B3 is concentrated on the solar cell 110-3 corresponding to wavelength band B3 , as shown by the arrows in Fig. 14.
  • the multiple structures 150 are arranged so that light in wavelength band B3 that is incident outside the region facing the solar cell 110-3 is also concentrated on the solar cell 110-3.
  • the solar cell module 100-2 can receive a greater amount of light than when only light in the wavelength bands B1 , B2 , and B3 of the incident light in the opposing areas with the solar cells 110-1 to 110-3 is concentrated onto the solar cells 110-1 to 110-3.
  • the wavelength separation lens 120-2 may focus light of the same wavelength band on a plurality of solar cells 110.
  • the wavelength separation lens 120-2 focuses light of wavelength band B1 on the solar cell 110-1, but when the solar cell 110-3 is disposed at the position of the solar cell 110-1, the lens may be designed to focus light of wavelength band B3 on the solar cell 110-3 instead of wavelength band B1 .
  • the wavelength separation lens 120 is formed on the bottom surface of the transparent layer 140, but this is not limited to this.
  • Figures 15 to 24 are diagrams each showing a schematic view of another example of a part of a cross section of the wavelength separation lens 120 according to the embodiment.
  • the structure 150 may be formed on the upper surface of the transparent layer 140.
  • the structure 150 is supported on the upper surface of the transparent layer 140.
  • the transparent layer above the structure 150 may be air or a protective layer such as a resin, and the transparent layer 140 may be made of a single material or may be made of multiple layers of materials.
  • structure 150 may be formed in multiple layers along the stacking direction of transparent layer 140.
  • the design parameters can be increased by the amount of the increase in layers compared to when it is a single layer, which increases the light control and allows for more efficient wavelength band separation.
  • structures 150-1 and 150-2 are formed on the upper surface of the transparent layer 140 and inside the transparent layer 140, respectively.
  • structures 150-1 to 150-3 are formed in a total of three layers, one layer on the upper surface of the transparent layer 140 and two layers inside the transparent layer 140. Structure 150-1 is supported on the upper surface of the lower transparent layer 140.
  • the material of structures 150-1 to 150-3 may be the same within a layer, or may be the same in all layers.
  • the material of structures 150-1 to 150-3 may be different for each location and/or for each layer.
  • the height, cross-sectional shape, and dimensions of structures 150-1 to 150-3 may be the same within a layer and/or in all layers, or may be different for each location and/or for each layer.
  • the structure 150 may be formed inside the transparent layer 140.
  • one layer of structure 150 is formed inside the transparent layer 140.
  • two layers of structures 150-1 and 150-2 are formed inside the transparent layer 140.
  • three layers of structures 150-1 to 150-3 are formed inside the transparent layer 140.
  • the structures 150 may be formed on the bottom surface of the transparent layer 140 and inside the transparent layer 140.
  • structures 150-1 and 150-2 are formed on the bottom surface of the transparent layer 140 and inside the transparent layer 140, respectively.
  • structures 150-1 to 150-3 are formed in a total of three layers, one layer on the bottom surface of the transparent layer 140 and two layers inside the transparent layer 140.
  • the structures 150-2 of the wavelength separation lens 120H and 150-3 of the wavelength separation lens 120I are supported by the transparent layer 140 above.
  • the structures 150 may be formed on the top and bottom surfaces of the transparent layer 140.
  • structures 150-1 and 150-2 are formed on the top surface and bottom surface of the transparent layer 140, respectively.
  • structures 150-1 to 150-3 are formed on the top surface of the transparent layer 140, the bottom surface of the transparent layer 140, and inside the transparent layer 140, respectively.
  • the structures 150-1 of the wavelength separation lens 120J and the wavelength separation lens 120K are supported by the transparent layer 140 below.
  • the structures 150-2 of the wavelength separation lens 120J and the structures 150-3 of the wavelength separation lens 120K are supported by the transparent layer 140 above.
  • the area between the wavelength separation lens 120 and the solar cell 110 may be filled with an air layer, or may be connected via a transparent layer.
  • the wavelength separation lens 120 is realized by utilizing the wavelength dispersion characteristics of the amount of optical phase delay that the fine columnar structure (structure 150) imparts to the incident light.
  • the structures 150 of each layer are formed from a material such as TiO2 or SiN having a refractive index n1 higher than the refractive index n0 of the transparent layers 130 and 140 surrounding the structure 150. From the viewpoint of the difficulty of fabrication, the structure 150 is preferably a structure having a constant height (length in the z-axis direction) hlayer within the plane. Note that the height of the structure 150 may differ for each layer.
  • the bottom and top surfaces of the structure 150 have a four-fold rotationally symmetric shape. This shape suppresses the occurrence of polarization dependency.
  • the structure 150 can be considered as an optical waveguide that confines and propagates light within the structure due to the refractive index difference between the transparent layers 130 and 140. Therefore, when light is incident on the top surface side of the structure 150, the light propagates while being strongly confined within the structure 150, and is output from the bottom surface side of the structure 150 after being subjected to a phase delay effect determined by the effective refractive index n eff of the optical waveguide.
  • the amount of optical phase delay ⁇ layer due to the structure 150 of each layer is expressed by equation (1), where ⁇ is the wavelength of light in a vacuum.
  • This optical phase delay amount ⁇ layer differs depending on the wavelength ⁇ of the light, so that the same structure 150 can impart different optical phase delay amounts ⁇ layer depending on the wavelength band of the light.
  • the effective refractive index neff of the optical waveguide is greatly dependent on the cross-sectional shape of the structure 150, and has a value of n0 ⁇ neff ⁇ n1 .
  • the effective refractive index n eff of the optical waveguide also differs depending on the wavelength ⁇ of the light, and the degree of this differs greatly depending on the cross-sectional shape of the structure 150 .
  • ⁇ min is the shortest central wavelength of the desired light receiving wavelength band.
  • n 0 is the refractive index of the transparent layer 140 located on the transmission side.
  • the height h1 of the single-layer structure 150 has an optical phase delay amount ⁇ layer of 2 ⁇ or more, so that it is preferable to set it as shown in formula (3) when the desired center wavelength in the wavelength range on the longest wavelength side of the wavelength range to be separated is ⁇ r .
  • n1 is the refractive index of the SiN of the structure 150 and n0 is the refractive index of the SiO2 of the transparent layers 130 and 140
  • the height h1 of the single-layer structure 150 be 1060 nm or more.
  • each structure 150 is set to be equal to or shorter than the shortest wavelength in the transparent material, for example, 280 nm or less when ⁇ is 410 nm and n0 is the refractive index of SiO2 , then it is necessary to set the aspect ratio of the structures 150 to 3.8 or more.
  • the cross-sectional dimension of the actual structure 150 is made smaller than the structural period P in order to reduce optical coupling with adjacent structures 150, and so if the maximum dimension is 200 nm, the aspect ratio will be 5.3 or more. Furthermore, some structures 150 having smaller cross-sectional dimensions are used in order to control the effective refractive index n eff of the optical waveguide, and if the minimum is 80 nm, the aspect ratio will be about 13.3.
  • the aspect ratio of the fine structure 150 can be suppressed while ensuring the required optical phase delay amount ⁇ layer in the sum of the layers.
  • the height h 1, 2 of the structure 150 of each layer can be about half that of a one-layer structure, for example, 530 nm or less. Therefore, the aspect ratio can be reduced to about half. Also, when a three-layer structure 150 is formed, the aspect ratio can be reduced to one-third in the same manner.
  • each structure 150 divided by layering do not need to be the same as before division, and may be different for each layer.
  • n eff and its wavelength dispersion can be arbitrarily changed by the cross-sectional dimensions for each layer of the structure 150. That is, when the structure 150 is formed into a plurality of layers, it becomes possible to set a wider variety of combinations of the optical phase delay amount ⁇ layer according to the wavelength ⁇ of light, compared with the case where the structure 150 is a single layer, and it becomes possible to improve the wavelength separation efficiency and the light collection efficiency.
  • FIGS. 25 to 30 are diagrams showing an example of the schematic configuration of the structure 150 shown in FIG. 2.
  • FIG. 25 is a side view of the structure 150, which has a square shape when viewed in a plane.
  • FIG. 26 is a bottom view of the structure 150 shown in FIG. 25. In this example, a case where the incident light is in the visible light region will be described.
  • the arrangement period of the structures 160 is denoted by P. It is desirable to set the arrangement period P as shown in formula (2) so that no diffracted light occurs on the transmission side.
  • the shortest wavelength ⁇ min of the light receiving wavelength band is set to 410 nm
  • n 0 is set to 1.45
  • the arrangement period P is set to 280 nm.
  • the height h layer (length in the z-axis direction) of the structure 150 is constant.
  • the height h layer is preferably such that the structure 150 has an optical phase delay (phase value) of 2 ⁇ or more with respect to the incident light, i.e., the light traveling along the z-axis direction. If the number of layers is L and the desired center wavelength in the wavelength range on the longest wavelength side of the wavelength range to be separated is ⁇ r , it is desirable to set the height h layer as shown in formula (4).
  • the effective refractive index neff and wavelength dispersion of the optical waveguide can be changed for each layer.
  • the structure 150 has multiple layers, considering the optical phase delay amount ⁇ layer as the sum of each layer makes it possible to have a wider variety of combinations of phase values, which leads to an increased degree of freedom in designing different lens functions for each wavelength range.
  • the cross-sectional shape of the structure 150 is preferably a four-fold rotationally symmetric shape in order to avoid polarization dependency.
  • FIG. 27 is a side view of the structure 150 which has an X-shape when viewed in a plane.
  • FIG. 28 is a plan view of the structure 150 shown in FIG. 27.
  • FIG. 29 is a side view of the structure 150 which has a hollow diamond shape when viewed in a plane.
  • FIG. 30 is a plan view of the structure 150 shown in FIG. 29.
  • the cross-sectional shape of the structure 150 may be an X-shape or a hollow diamond shape, which is formed by rotating a columnar structure having a square with a cross and square holes by 45° in-plane, as shown in FIGS. 27 to 30.
  • a columnar structure having a square with a cross-shaped and square hole is rotated by 45° in-plane as the cross-sectional shape of the structure 150, which has the effect of weakening the optical coupling with adjacent structures 150 compared to a structure that is not rotated. Even when various structures 150 are arranged periodically, the optical properties of each structure 150 are not affected by the adjacent structures 150, and the designed spatial phase distribution can be easily reproduced.
  • the distance between each layer can be set arbitrarily, but considering multiple reflections between layers and the dissipation and radiation of light after passing through a layer, it is desirable to set the distance to about the wavelength or less. Also, the structures 150 for each layer may be connected. In other words, the distance between layers may be zero.
  • the cross-sectional shape of the structure 150 is not limited to the shapes shown in Figures 26, 28, and 30.
  • Figure 31 is a diagram showing examples of the cross-sectional shape of the structure 150 shown in Figure 2.
  • the wavelength separation lens 120 may employ structures 160 of various cross-sectional shapes as exemplified in Figure 31.
  • the exemplified shapes are, for example, four-fold rotationally symmetric shapes obtained by combining and rotating various square, cross, and circular shapes.
  • the cross-sectional shape and arrangement of the structure 150 are designed to achieve an ideal optical phase delay distribution (phase distribution).
  • phase distribution phase distribution
  • a lens phase distribution with a different focal point for each wavelength band is designed and realized with a single or multiple layered columnar structure 150.
  • a structure 150 composed of SiN is used, and by utilizing the wavelength dispersion characteristics of the optical phase delay, a different phase distribution is designed for each central wavelength of each wavelength band from 400 nm to 1200 nm, resulting in the wavelength separation lens 120-1.
  • FIG. 32 is a diagram showing an ideal optical phase delay distribution when the central wavelength is 500 nm.
  • FIG. 33 is a diagram showing an ideal optical phase delay distribution when the central wavelength is 650 nm.
  • FIG. 34 is a diagram showing an ideal optical phase delay distribution when the central wavelength is 800 nm.
  • the parameters of the design example are as follows: Solar cell size: 15mm x 15mm Focal length: 15mm Central wavelengths of each wavelength band: Wavelength band B1 : 500 nm, Wavelength band B2 : 650 nm, Wavelength band B3 : 800 nm, Wavelength band B4 : 1000 nm
  • ⁇ d is the central wavelength (design wavelength)
  • x f , y f and z f are the focusing positions
  • n 2 is the refractive index of the lower transparent layers 130 and 140
  • C is an arbitrary constant.
  • is converted to fall within the range of 0 to 2 ⁇ .
  • -0.5 ⁇ and 2.5 ⁇ are converted to 1.5 ⁇ and 0.5 ⁇ , respectively.
  • the boundary region of the phase distribution is set so that the phase distribution of the lens at each central wavelength is symmetrical (together with adjacent lenses) in the left and right directions and up and down around the focusing position.
  • the constant C may be optimized for each wavelength so that the error in the phase distribution is minimized.
  • the structure that best matches the phase distribution of the above four wavelengths i.e., the structure 150 with the smallest phase error
  • the structural pattern on each cell has two-fold rotational symmetry due to the number of wavelength band divisions and the symmetry of the phase distribution.
  • the cross-sectional shape and arrangement of the structure 150 are designed to achieve an ideal optical phase delay distribution (phase distribution).
  • phase distribution phase distribution
  • a lens phase distribution with a different focal point for each wavelength band is designed and realized with a single or multiple layered columnar structure 150.
  • a structure 150 composed of SiN is used, and by utilizing the wavelength dispersion characteristics of the optical phase delay, a different phase distribution is designed for each central wavelength of each wavelength band from 400 nm to 1200 nm, and wavelength separation lens 120-2 is realized.
  • FIG. 36 is a diagram showing the ideal optical phase delay distribution when the central wavelength is 500 nm.
  • Figure 37 is a diagram showing the ideal optical phase delay distribution when the central wavelength is 650 nm.
  • the parameters of the design example are as follows: Solar cell size: 15mm x 15mm Focal length: 30mm Central wavelengths of each wavelength band: Wavelength band B1 : 500 nm, Wavelength band B2 : 650 nm, Wavelength band B3 : 1000 nm
  • ⁇ d is the central wavelength (design wavelength)
  • x f , y f and z f are the focusing positions
  • n 2 is the refractive index of the lower transparent layers 130 and 140
  • C is an arbitrary constant.
  • a phase distribution was set that provides the following light collection positions for wavelength bands B1 , B2 , and B3 in accordance with the positions of three solar cells 110-1 to 110-3.
  • is converted to fall within the range of 0 to 2 ⁇ .
  • -0.5 ⁇ and 2.5 ⁇ are converted to 1.5 ⁇ and 0.5 ⁇ , respectively.
  • the boundary region of the phase distribution is set so that the lens phase distribution at each central wavelength is symmetrical (together with adjacent lenses) in the left and right directions and up and down around the focusing position.
  • the constant C may be optimized for each wavelength so that the error in the phase distribution is minimized.
  • the structure that best matches the phase distribution of the above three wavelengths i.e., the structure 150 with the smallest phase error
  • the structural pattern on each cell is vertically symmetrical due to the number of wavelength band divisions and the symmetry of the phase distribution.
  • FIG. 39 is a diagram showing a schematic example of a cross section of a main part of a conventional solar cell module.
  • Fig. 39 shows a solar cell module having a photoelectric conversion part using only a single material (e.g., Si).
  • Fig. 40 is a diagram showing a schematic diagram of the wavelength dependency of the light intensity radiated/absorbed by the solar cell module shown in Fig. 39. Curve C1 in Fig. 40 shows the spectrum of sunlight.
  • the efficiency of the module is limited because only a portion of the wavelengths of incident sunlight are photoelectrically converted due to the light absorption spectrum resulting from the band gap of the material (see region R11).
  • Figure 41 is a diagram that shows a schematic diagram of another example of a cross section of a main part of a conventional solar cell module.
  • Figure 41 shows a tandem solar cell module having a photoelectric conversion section that uses a multi-junction compound semiconductor in which multiple materials with different bandgaps are stacked.
  • Figure 42 is a diagram that shows a schematic diagram of the wavelength dependence of the light intensity radiated/absorbed by the solar cell module shown in Figure 41.
  • Curve C1 in Figure 42 shows the spectrum of sunlight.
  • a tandem solar cell module can absorb and photoelectrically convert almost all wavelengths of incident sunlight (see regions R21 to R23), but the absorption rate of light in the long wavelength band, as in region R23, is low, and there is a limit to how much the photoelectric conversion efficiency can be improved.
  • the materials that can be bonded as multi-junction compound semiconductors are limited, and they are difficult to fabricate.
  • FIG 43 is a diagram showing the wavelength dependency of the light intensity radiated/absorbed by the solar cell module 100 shown in Figure 2.
  • the solar cell module 100 according to the embodiment can absorb and photoelectrically convert almost all wavelengths of incident sunlight (see regions R1 to R3).
  • the solar cell module 100 is expected to have improved photoelectric conversion efficiency because it has fewer material constraints than a tandem solar cell module.
  • the solar cell module 100 may be able to select a material for the photoelectric conversion section that has better absorption characteristics at long wavelengths, even though it is difficult to use this material in a tandem solar cell module. In this case, as shown in region R23, it is believed that the absorption rate of long wavelength band light is also higher than that of a tandem solar cell module, and high photoelectric conversion efficiency can be achieved.
  • the solar cell module 100 can increase the total photoelectric conversion amount compared to solar cell modules and tandem solar cell modules that have conventional photoelectric conversion parts made of a single material.
  • each solar cell 110 may have a photoelectric conversion section using a single material suited to each wavelength band. Therefore, with the solar cell module 100, solar cells 110 each made of materials that would be difficult to join together in a tandem solar cell can be used simultaneously, and it is expected that the photoelectric conversion efficiency can be maximized by using a material that can more efficiently absorb and convert sunlight into electricity in the photoelectric conversion section.
  • each solar cell 110 can be a photoelectric conversion unit using a single material that is suitable for each wavelength band, making it much easier to fabricate than a tandem solar cell, leading to reduced manufacturing costs.
  • the design parameters can be increased by the amount of the increase in layers compared to when the structure 150 has a single-layer structure, which increases the light control and allows for more efficient wavelength band separation.
  • the solar cell module 100 there is no limit to the number of wavelength bands that can be separated, and the effect can be achieved as long as there are multiple bands.
  • light of the same wavelength band may be concentrated on multiple solar cell cells 110, allowing for a high degree of freedom in design.
  • the conversion device 10 described with reference to FIG. 1 etc. is also one aspect of the present disclosure.
  • the conversion device 10 according to the embodiment has the solar cell module 100 described above, and therefore has improved photoelectric conversion efficiency and reduced manufacturing costs compared to the conventional technology.

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Abstract

A solar battery module (100) comprising a plurality of solar battery cells (110-1), (110-2), (110-3) each of which absorbs light in a set predetermined wavelength band and converts the light to electricity and a wavelength separation lens (120) which includes a transparent layer (140) which covers the plurality of solar battery cells (110-1), (110-2), (110-3) and a plurality of structures (150) which are arranged on the transparent layer (140) or in the transparent layer (140) in the surface direction of the transparent layer (140) at intervals equal to or shorter than the wavelength of the incident light and which are arranged such that the incident light is separated into the predetermined wavelength bands, the light separated into each predetermined wavelength band being focused onto the solar battery cell corresponding to each wavelength band.

Description

太陽電池モジュール及び変換装置Solar cell modules and conversion devices

 本発明は、太陽電池モジュール及び変換装置に関する。 The present invention relates to a solar cell module and a conversion device.

 カーボンニュートラル社会の実現に向け、太陽電池に対する研究開発が進んでいる。従来、太陽光の光電変換のために単一材料(例:Si)を用いた光電変換部を有する太陽電池セルをモジュール化・アレイ化する技術が提供されている。このような一般的なSiのみを用いた太陽電池では、材料のバンドギャップ由来の光吸収スペクトルにより、入射する光の内の一部の波長のみが電気に変換される。したがって、Siのみを用いた太陽電池では、材料のバンドギャップ由来の光吸収スペクトルにより、広域なスペクトルをもつ太陽光の全てを効率的に吸収・光電変換できず、モジュールの効率が制限されていた。  In order to realize a carbon-neutral society, research and development into solar cells is progressing. Conventionally, technology has been provided for modularizing and arraying solar cells with a photoelectric conversion section that uses a single material (e.g., Si) for the photoelectric conversion of sunlight. In such general solar cells that use only Si, only a portion of the wavelengths of incident light are converted into electricity due to the optical absorption spectrum resulting from the band gap of the material. Therefore, in solar cells that use only Si, the optical absorption spectrum resulting from the band gap of the material means that all of the sunlight, which has a wide spectrum, cannot be efficiently absorbed and photoelectrically converted, limiting the efficiency of the module.

 そこで、光電変換部にバンドギャップの異なる複数の材料を積み重ねた多接合型化合物半導体を用いることで、広域なスペクトルをもつ太陽光を効率的に吸収・光電変換するタンデム太陽電池が提案されている(非特許文献1)。 Therefore, a tandem solar cell has been proposed that uses a multi-junction compound semiconductor in which multiple materials with different bandgaps are stacked in the photoelectric conversion section, and that efficiently absorbs and photoelectrically converts sunlight with a wide spectrum (Non-Patent Document 1).

J. F. Geisz, R. M. France, K. L. Schulte, et al. “Six-junction III-V solar cells with 47.1% conversion efficiency under 143 Suns concentration”, Nat Energy 5, 326-335 (2020)., [令和4年12月20日検索],インターネット<URL:https://doi.org/10.1038/s41560-020-0598-5>J. F. Geisz, R. M. France, K. L. Schulte, et al. “Six-junction III-V solar cells with 47.1% conversion efficiency under 143 Suns concentration”, Nat Energy 5, 326-335 (2020 )., [Retrieved December 20, 2020], Internet <URL: https://doi.org/10.1038/s41560-020-0598-5>

 しかしながら、タンデム太陽電池は、多接合型化合物半導体として接合可能な材料が限られており、光電変換効率の向上には限界があるという課題があった。 However, there is a problem with tandem solar cells in that there is a limit to the materials that can be bonded as multi-junction compound semiconductors, and there is a limit to how much improvement can be made in photoelectric conversion efficiency.

 本発明は、上記に鑑みてなされたものであって、光電変換効率を向上することができる太陽電池モジュール及び変換装置を提供することを目的とする。 The present invention has been made in consideration of the above, and aims to provide a solar cell module and conversion device that can improve photoelectric conversion efficiency.

 上述した課題を解決し、目的を達成するために、本発明に係る太陽電池モジュールは、各々が、それぞれ設定された所定の波長帯域の光を吸収して電気に変換する複数の太陽電池セルと、前記複数の太陽電池セルを覆う透明層と、前記透明層上または前記透明層内において、前記透明層の面方向に、入射光の波長以下の周期で配置された複数の構造体であって、前記入射光を、各所定の波長帯域ごとに分離して、各波長帯域に対応する前記太陽電池セルにそれぞれ集光するように配置される複数の構造体と、を有する光学素子と、を有することを特徴とする。 In order to solve the above problems and achieve the object, the solar cell module of the present invention is characterized by having a plurality of solar cells, each of which absorbs light in a respective predetermined wavelength band and converts it into electricity, a transparent layer covering the plurality of solar cells, and an optical element having a plurality of structures arranged on or within the transparent layer in the surface direction of the transparent layer at a period equal to or smaller than the wavelength of the incident light, the plurality of structures being arranged to separate the incident light into each of the predetermined wavelength bands and focus the light on the solar cell corresponding to each wavelength band.

 また、本発明に係る変換装置は、上記の太陽電池モジュールと、電力を蓄積する二次電池と、前記太陽電池モジュールからの入力電圧を昇圧して前記二次電池に供給する電力変換部と、を有することを特徴とする。 The conversion device according to the present invention is characterized by having the above-mentioned solar cell module, a secondary battery that stores power, and a power conversion unit that boosts the input voltage from the solar cell module and supplies it to the secondary battery.

 本発明によれば、光電変換効率を向上することができる太陽電池モジュール及び変換装置を提供することができる。 The present invention provides a solar cell module and conversion device that can improve photoelectric conversion efficiency.

図1は、実施の形態に係る変換装置の概略構成を示した側面図である。FIG. 1 is a side view showing a schematic configuration of a conversion device according to an embodiment. 図2は、実施の形態に係る太陽電池モジュールの要部の断面の一例を模式的に示す図である。FIG. 2 is a diagram illustrating an example of a cross section of a main part of a solar cell module according to an embodiment. 図3は、実施の形態に係る太陽電池モジュールを平面視したときに太陽電池セルの配置を模式的に示す図である。FIG. 3 is a diagram showing a schematic arrangement of solar cells when the solar cell module according to the embodiment is viewed in plan. 図4は、図3のa-a´線に沿って側面視したときの太陽電池モジュールの断面の一例を示す図である。FIG. 4 is a diagram showing an example of a cross section of the solar cell module when viewed from the side along the line aa' in FIG. 図5は、図3のb-b´線に沿って側面視したときの太陽電池モジュールの断面の一例を示す図である。FIG. 5 is a diagram showing an example of a cross section of the solar cell module when viewed from the side along the line bb' in FIG. 図6は、図3に示す太陽電池モジュールにおける太陽電池セルへの集光を模式的に示す図である。FIG. 6 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG. 図7は、図3に示す太陽電池モジュールにおける太陽電池セルへの集光を模式的に示す図である。FIG. 7 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG. 図8は、図3に示す太陽電池モジュールにおける太陽電池セルへの集光を模式的に示す図である。FIG. 8 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG. 図9は、図3に示す太陽電池モジュールにおける太陽電池セルへの集光を模式的に示す図である。FIG. 9 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG. 図10は、実施の形態に係る太陽電池モジュールを平面視したときに太陽電池セルの配置を模式的に示す図である。FIG. 10 is a diagram showing a schematic arrangement of solar cells when the solar cell module according to the embodiment is viewed in plan. 図11は、図11は、図10のc-c´線に沿って側面視したときの太陽電池モジュールの断面の一例を示す図である。FIG. 11 is a diagram showing an example of a cross section of the solar cell module when viewed from the side along the line cc' in FIG. 図12は、図10に示す太陽電池モジュールにおける太陽電池セルへの集光を模式的に示す図である。FIG. 12 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG. 図13は、図10に示す太陽電池モジュールにおける太陽電池セルへの集光を模式的に示す図である。FIG. 13 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG. 図14は、図10に示す太陽電池モジュールにおける太陽電池セルへの集光を模式的に示す図である。FIG. 14 is a diagram illustrating the collection of light onto a solar cell in the solar cell module shown in FIG. 図15は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 15 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. 図16は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 16 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. 図17は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 17 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. 図18は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 18 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. 図19は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 19 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. 図20は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 20 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. 図21は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 21 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. In FIG. 図22は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 22 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. In FIG. 図23は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 23 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. In FIG. 図24は、実施の形態に係る波長分離レンズの断面の一部の他の例を模式的に示す図である。FIG. 24 is a diagram illustrating another example of a part of a cross section of the wavelength separation lens according to the embodiment. In FIG. 図25は、図2に示す構造体の概略構成の例を示す図である。FIG. 25 is a diagram showing an example of a schematic configuration of the structure shown in FIG. 図26は、図2に示す構造体の概略構成の例を示す図である。FIG. 26 is a diagram showing an example of a schematic configuration of the structure shown in FIG. 図27は、図2に示す構造体の概略構成の例を示す図である。FIG. 27 is a diagram showing an example of a schematic configuration of the structure shown in FIG. 図28は、図2に示す構造体の概略構成の例を示す図である。FIG. 28 is a diagram showing an example of a schematic configuration of the structure shown in FIG. 図29は、図2に示す構造体の概略構成の例を示す図である。FIG. 29 is a diagram showing an example of a schematic configuration of the structure shown in FIG. 図30は、図2に示す構造体の概略構成の例を示す図である。FIG. 30 is a diagram showing an example of a schematic configuration of the structure shown in FIG. 図31は、図2に示す構造体の断面形状の例を示す図である。FIG. 31 is a diagram showing an example of a cross-sectional shape of the structure shown in FIG. 図32は、中心波長が500nmの場合の理想的な光位相遅延量分布を示す図である。FIG. 32 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 500 nm. 図33は、中心波長が650nmの場合の理想的な光位相遅延量分布を示す図である。FIG. 33 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 650 nm. 図34は、中心波長が800nmの場合の理想的な光位相遅延量分布を示す図である。FIG. 34 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 800 nm. 図35は、中心波長が1000nmの場合の理想的な光位相遅延量分布を示す図である。FIG. 35 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 1000 nm. 図36は、中心波長が500nmの場合の理想的な光位相遅延量分布を示す図である。FIG. 36 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 500 nm. 図37は、中心波長が650nmの場合の理想的な光位相遅延量分布を示す図である。FIG. 37 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 650 nm. 図38は、中心波長が1000nmの場合の理想的な光位相遅延量分布を示す図である。FIG. 38 is a diagram showing an ideal distribution of the amount of optical phase delay when the center wavelength is 1000 nm. 図39は、従来の太陽電池モジュールの要部の断面の一例を模式的に示す図である。FIG. 39 is a diagram illustrating an example of a cross section of a main part of a conventional solar cell module. 図40は、図39に示す太陽電池モジュールが放射/吸収する光強度の波長依存性を模式的に示す図である。FIG. 40 is a diagram showing a schematic diagram of the wavelength dependency of the intensity of light radiated/absorbed by the solar cell module shown in FIG. 図41は、従来の太陽電池モジュールの要部の断面の他の例を模式的に示す図である。FIG. 41 is a diagram illustrating another example of a cross section of a main part of a conventional solar cell module. 図42は、図41に示す太陽電池モジュールが放射/吸収する光強度の波長依存性を模式的に示す図である。FIG. 42 is a diagram showing a schematic diagram of the wavelength dependency of the intensity of light radiated/absorbed by the solar cell module shown in FIG. 41. In FIG. 図43は、図2に示す太陽電池モジュールが放射/吸収する光強度の波長依存性を模式的に示す図である。FIG. 43 is a diagram illustrating the wavelength dependency of the intensity of light radiated/absorbed by the solar cell module shown in FIG.

 以下、本発明を実施するための最良の形態を図面とともに詳細に説明する。なお、以下の説明において、各図は本発明の内容を理解でき得る程度に形状、大きさ、及び位置関係を概略的に示してあるに過ぎず、したがって、本発明は各図で例示された形状、大きさ、及び位置関係のみに限定されるものではない。また、図面の記載において、同一部分には同一の符号を付して示している。 Below, the best mode for carrying out the present invention will be explained in detail with reference to the drawings. Note that in the following explanation, each figure merely shows a schematic representation of the shape, size, and positional relationship to the extent that the contents of the present invention can be understood, and therefore the present invention is not limited to only the shape, size, and positional relationship exemplified in each figure. In addition, in the description of the drawings, the same parts are denoted by the same reference numerals.

[実施の形態]
[変換装置]
 まず、本発明の実施の形態に係る変換装置について説明する。図1は、実施の形態に係る変換装置の概略構成を例示したブロック図である。
[Embodiment]
[Conversion device]
First, a conversion device according to an embodiment of the present invention will be described below. Fig. 1 is a block diagram showing an example of a schematic configuration of a conversion device according to an embodiment.

 例えば、図1に示すように、実施の形態に係る変換装置10は、電力を発電する複数の太陽電池セルを有する太陽電池モジュール1、太陽電池モジュール1からの入力電圧を、例えば昇圧して、二次電池に供給する電力変換部2、及び、太陽電池モジュール1で発電された電力を蓄積する二次電池3を有する。 For example, as shown in FIG. 1, the conversion device 10 according to the embodiment includes a solar cell module 1 having multiple solar cells that generate power, a power conversion unit 2 that, for example, boosts the input voltage from the solar cell module 1 and supplies it to a secondary battery, and a secondary battery 3 that stores the power generated by the solar cell module 1.

[太陽電池モジュール]
 次に、実施の形態に係る太陽電池モジュール1について説明する。図2は、実施の形態に係る太陽電池モジュールの要部の断面の一例を模式的に示す図である。図2以降では、太陽電池モジュール1の一部を、太陽電池モジュール100として説明する。また、以降の図において、xyz座標系が示される。xy平面方向は、後述する太陽電池セル110、透明層140等の面方向に相当する。以下、とくに説明がある場合を除き、「平面視」は、z軸方向に(例えばz軸負方向に)視ることを指し示す。「側面視」は、x軸方向またはy軸方向(例えばy軸正方向)に視ることを指し示す。
[Solar cell module]
Next, a solar cell module 1 according to an embodiment will be described. FIG. 2 is a diagram showing an example of a cross section of a main part of a solar cell module according to an embodiment. In FIG. 2 and subsequent figures, a part of the solar cell module 1 will be described as a solar cell module 100. In addition, an xyz coordinate system is shown in the subsequent figures. The xy plane direction corresponds to the surface direction of the solar cell 110, the transparent layer 140, etc., which will be described later. Hereinafter, unless otherwise specified, "planar view" refers to viewing in the z-axis direction (e.g., the z-axis negative direction). "Side view" refers to viewing in the x-axis direction or the y-axis direction (e.g., the y-axis positive direction).

 図2に示すように、太陽電池モジュール100は、複数の太陽電池セル110-1~110-3と、太陽電池セル110-1~110-3上に集積された、微細な構造体150を有する波長分離レンズ120(光学素子)とを有する。太陽電池セル110-1~110-3及び後述の太陽電池セル110-4を総称する場合には、太陽電池セル110とする。 As shown in FIG. 2, the solar cell module 100 has a plurality of solar cells 110-1 to 110-3 and a wavelength separation lens 120 (optical element) having a microscopic structure 150 integrated on the solar cells 110-1 to 110-3. The solar cells 110-1 to 110-3 and the solar cell 110-4 described below are collectively referred to as solar cell 110.

 太陽電池セル110-1~110-3は、各々が、それぞれ設定された所定の波長帯域の光を吸収して電気に変換するセルである。太陽電池セル110-1は、例えば、波長帯域Bの光を吸収して電気に変換する。太陽電池セル110-2は、例えば、波長帯域Bの光を吸収して電気に変換する。太陽電池セル110-3は、例えば、波長帯域Bの光を吸収して電気に変換する。 Each of the solar cell units 110-1 to 110-3 absorbs light in a predetermined wavelength band and converts it into electricity. For example, the solar cell unit 110-1 absorbs light in wavelength band B1 and converts it into electricity. For example, the solar cell unit 110-2 absorbs light in wavelength band B2 and converts it into electricity. For example, the solar cell unit 110-3 absorbs light in wavelength band B3 and converts it into electricity.

 太陽電池セル110-1~110-3は、それぞれ、p型半導体層160-1~160-3とn型半導体層170-1~170-3とを光電変換部として有する。各太陽電池セル110-1~110-3は、それぞれ対応する波長帯域B,B,Bにおいて高い光吸収率を有する材料を光電変換部として有する。n型半導体層170-1~170-3上には反射防止層180が積層される。そして、太陽電池セル110-1~110-3は、n型半導体層170-1~170-3に接続する表面電極190及び、p型半導体層160-1~160-3に接続する裏面電極200を有する。 The solar cells 110-1 to 110-3 each have a p-type semiconductor layer 160-1 to 160-3 and an n-type semiconductor layer 170-1 to 170-3 as a photoelectric conversion unit. Each of the solar cells 110-1 to 110-3 has a material having a high light absorption rate in the corresponding wavelength bands B1 , B2 , and B3 as a photoelectric conversion unit. An anti-reflection layer 180 is laminated on the n-type semiconductor layers 170-1 to 170-3. The solar cells 110-1 to 110-3 each have a front electrode 190 connected to the n-type semiconductor layers 170-1 to 170-3 and a back electrode 200 connected to the p-type semiconductor layers 160-1 to 160-3.

 光電変換部を構成する材料は、例えば、x-Si、a-Si:Hなどのシリコン系材料、GaAs、InAs、GaInAs,Zn、CuS、CuInSe、CuIn1-xGaxSe、InP、CdTe、CdSなどの化合物半導体、有機半導体、光触媒材料(酸化チタンなど)と色素分子から色素増感系材料が挙げられる。 Examples of materials constituting the photoelectric conversion unit include silicon-based materials such as x-Si and a-Si:H, compound semiconductors such as GaAs, InAs, GaInAs, Zn 3 P 2 , Cu 2 S, CuInSe 2 , CuIn 1-x GaxSe 2 , InP, CdTe, and CdS, organic semiconductors, photocatalytic materials (such as titanium oxide), and dye-sensitized materials consisting of dye molecules.

 波長分離レンズ120は、入射光(例えば、太陽光)を波長帯域(例えば、波長帯域B,B,B)毎に分離しながら各太陽電池セル110-1~110-3へそれぞれ集光する。波長分離レンズ120は、入射光のうち波長帯域Bを太陽電池セル110-1へ集光する。波長分離レンズ120は、入射光のうち波長帯域Bを太陽電池セル110-2へ集光する。波長分離レンズ120は、入射光のうち波長帯域Bを太陽電池セル110-3へ集光する。波長分離レンズ120が分離する波長帯域(B)は、太陽光のスペクトル波長帯域を任意に分割した帯域に対応する。または、波長分離レンズ120が分離する波長帯域を、既存の太陽電池セル110の吸収スペクトルに適合させるように波長分離レンズ120を設計してもよい。 The wavelength separation lens 120 separates the incident light (for example, sunlight) into wavelength bands (for example, wavelength bands B 1 , B 2 , B 3 ) and focuses the light on each of the solar cell 110-1 to 110-3. The wavelength separation lens 120 focuses the wavelength band B 1 of the incident light on the solar cell 110-1. The wavelength separation lens 120 focuses the wavelength band B 2 of the incident light on the solar cell 110-2. The wavelength separation lens 120 focuses the wavelength band B 3 of the incident light on the solar cell 110-3. The wavelength bands (B k ) separated by the wavelength separation lens 120 correspond to bands obtained by arbitrarily dividing the spectral wavelength band of sunlight. Alternatively, the wavelength separation lens 120 may be designed so that the wavelength bands separated by the wavelength separation lens 120 are adapted to the absorption spectrum of the existing solar cell 110.

 波長分離レンズ120は、複数の太陽電池セル110-1~110-3を覆う透明層140と、透明層140の底面に配置された複数の柱状の構造体150とを有する。構造体150は、上方の透明層140に支持されている。 The wavelength separation lens 120 has a transparent layer 140 that covers the multiple solar cells 110-1 to 110-3, and multiple columnar structures 150 arranged on the bottom surface of the transparent layer 140. The structures 150 are supported by the transparent layer 140 above.

 透明層140は、SiO(屈折率n=1.45)等の材料からなる低屈折率の透明層である。図2では、透明層130(例えば、空気層(屈折率n=1.00))を介して、波長分離レンズ120が太陽電池セル1110上に形成された例を示したが、太陽電池モジュール100は、波長分離レンズ120と太陽電池セル110との間を透明層140で覆う構成であってもよい。 The transparent layer 140 is a low-refractive index transparent layer made of a material such as SiO 2 (refractive index n=1.45). In Fig. 2, an example is shown in which the wavelength separation lens 120 is formed on the solar cell 1110 via the transparent layer 130 (e.g., an air layer (refractive index n=1.00)), but the solar cell module 100 may have a configuration in which the transparent layer 140 covers the space between the wavelength separation lens 120 and the solar cell 110.

 複数の構造体150は、入射光を、各所定の波長帯域ごとに分離して、各波長帯域に対応する太陽電池セル110-110-3に、それぞれ集光するように配置される。複数の構造体150は、透明層140の面方向に、入射光の波長以下の周期で配置される。複数の構造体150は、高さ一定の柱状構造からなり、その面内の形状(上面・下面)は4回回転対称の形状をもつ。実施の形態では、構造体150の形状を4回回転対称の形状とすることにより、偏光依存性の発生を抑制する。 The multiple structures 150 are arranged so as to separate the incident light into each of the predetermined wavelength bands and focus the light on the solar cell 110-110-3 corresponding to each wavelength band. The multiple structures 150 are arranged in the plane direction of the transparent layer 140 with a period equal to or less than the wavelength of the incident light. The multiple structures 150 are made of columnar structures of constant height, and their in-plane shapes (upper and lower surfaces) have four-fold rotational symmetry. In the embodiment, the occurrence of polarization dependency is suppressed by making the shape of the structures 150 four-fold rotational symmetry.

 複数の構造体150の各々は、透明層130,140の屈折率よりも高い屈折率を有するTiOやSiN等の材料から形成される。複数の構造体150の各々は、入射した光に対して透明層130,140を平面視したときの断面形状に応じた光位相遅延量を与える柱状構造体である。複数の構造体150は、各太陽電池セル110-1~110-3への集光を実現するための光位相量遅延分布に従って断面形状が設定され、各太陽電池セル110-1~110-3への集光を実現するための光位相量遅延分布に従って配置される。 Each of the plurality of structures 150 is formed from a material such as TiO2 or SiN having a refractive index higher than that of the transparent layers 130 and 140. Each of the plurality of structures 150 is a columnar structure that imparts an optical phase delay amount to incident light according to the cross-sectional shape when the transparent layers 130 and 140 are viewed in plan. The cross-sectional shape of the plurality of structures 150 is set according to an optical phase delay distribution for realizing light concentration on each of the solar cell arrays 110-1 to 110-3, and the structures 150 are arranged according to an optical phase delay distribution for realizing light concentration on each of the solar cell arrays 110-1 to 110-3.

 このように、太陽電池モジュール100は、入射光を複数の波長帯域(例えば、波長帯域B,B,B)に分離し、各波長帯域に適合した光吸収スペクトルを有する太陽電池セル110(例えば、110-1~110-3)で受光する。このため、太陽電池モジュール100は、従来の太陽電池モジュールと比して、いずれの波長帯域についても、光電変換量が最大化され、効率が増大する。 In this way, the solar cell module 100 separates the incident light into a plurality of wavelength bands (e.g., wavelength bands B1 , B2 , B3 ) and receives the light with solar cell cells 110 (e.g., 110-1 to 110-3) having light absorption spectra suited to each wavelength band. Therefore, the solar cell module 100 maximizes the amount of photoelectric conversion in each wavelength band and increases efficiency compared to conventional solar cell modules.

 各太陽電池セル110(例えば、110-1~110-3)は、それぞれ単一材料を用いた光電変換部でよい。このため、各太陽電池セル110は、従来のタンデム太陽電池では互いに接合が困難だった材料であっても、分離された波長帯域にそれぞれ対応した光吸収スペクトルを有する各太陽電池セル110を同時に使用できる。したがって、太陽電池モジュール100は、従来の太陽電池と比して、複数の波長帯域の光を効率的に吸収・光電変換できる上に、従来のタンデム太陽電池と比して、作製難易度を大幅に下げることができ、作製コスト低減を図ることもできる。 Each solar cell 110 (e.g., 110-1 to 110-3) may be a photoelectric conversion unit using a single material. Therefore, even if the solar cells 110 are made of materials that would be difficult to join together in a conventional tandem solar cell, each solar cell 110 having an optical absorption spectrum corresponding to each of the separated wavelength bands can be used simultaneously. Therefore, compared to conventional solar cells, the solar cell module 100 can efficiently absorb and photoelectrically convert light in multiple wavelength bands, and compared to conventional tandem solar cells, the difficulty of fabrication can be significantly reduced, and fabrication costs can also be reduced.

 波長分離レンズ120が分離する波長帯域の数に限定はなく、複数であればよい。また、波長分離レンズ120は、同じ波長帯域の光を複数の太陽電池セル110に集光してもよい。例えば、波長分離レンズ120は、波長帯域Bの光を太陽電池セル110-1に集光しているが、太陽電池セル110-1の位置に太陽電池セル110-3が配置される場合には、波長帯域Bに代えて、波長帯域Bのこの太陽電池セル110-3に集光するように設計されてもよい。また、波長分離レンズ120及び太陽電池セル110はアレイ化されていてもよく、また、図2のように1つの波長分離レンズ120と複数の太陽電池セル110から構成されてもよい。 There is no limitation on the number of wavelength bands separated by the wavelength separation lens 120, as long as there is more than one. The wavelength separation lens 120 may also focus light of the same wavelength band on a plurality of solar cells 110. For example, the wavelength separation lens 120 focuses light of wavelength band B1 on the solar cell 110-1, but when a solar cell 110-3 is disposed at the position of the solar cell 110-1, the wavelength separation lens 120 may be designed to focus light of wavelength band B3 on the solar cell 110-3 instead of wavelength band B1 . The wavelength separation lens 120 and the solar cell 110 may be arrayed, or may be composed of one wavelength separation lens 120 and a plurality of solar cells 110 as shown in FIG. 2.

[第1の構成例]
 次に、第1の構成例を有する太陽電池モジュール100-1について説明する。図3は、実施の形態に係る太陽電池モジュール100-1を平面視したときに太陽電池セル110の配置を模式的に示す図である。図4は、図3のa-a´線に沿って側面視したときの太陽電池モジュール100-1の断面の一例を示す図である。図5は、図3のb-b´線に沿って側面視したときの太陽電池モジュール100-1の断面の一例を示す図である。図4及び図5において、矢印は、太陽電池モジュール100-1に入射する光を模式的に示す。
[First Configuration Example]
Next, a solar cell module 100-1 having a first configuration example will be described. FIG. 3 is a diagram showing a schematic arrangement of solar cell cells 110 when the solar cell module 100-1 according to the embodiment is viewed in plan. FIG. 4 is a diagram showing an example of a cross section of the solar cell module 100-1 when viewed from the side along line a-a' in FIG. 3. FIG. 5 is a diagram showing an example of a cross section of the solar cell module 100-1 when viewed from the side along line bb' in FIG. 3. In FIG. 4 and FIG. 5, arrows typically indicate light incident on the solar cell module 100-1.

 太陽電池モジュール100-1では、波長帯域B,B,B,Bにそれぞれ対応した光吸収スペクトルを有する4つの太陽電池セルが、図3に示すように隣接して配置され、一つのユニット(単位パターン)U1-1を構成する。そして、図4及び図5に示すように、波長分離レンズ120-1は、太陽電池セル110-1~110-4上に配置される。また、例えば、1つの波長分離レンズ120-1につき直下の4つの太陽電池セル110-1~110-4が相対するようにしてもよい。 In the solar cell module 100-1, four solar cells having optical absorption spectra corresponding to the wavelength bands B1 , B2 , B3 , and B4 , respectively, are arranged adjacent to each other as shown in Fig. 3 to form one unit (unit pattern) U1-1. Then, as shown in Fig. 4 and Fig. 5, a wavelength separation lens 120-1 is arranged on the solar cells 110-1 to 110-4. Also, for example, one wavelength separation lens 120-1 may face the four solar cells 110-1 to 110-4 directly below it.

 太陽電池セル110-4は、波長帯域Bの光を吸収して電気に変換する。太陽電池セル110-4は、p型半導体層160-4とn型半導体層170-4とを光電変換部として有し、n型半導体層170-4上には反射防止層180が積層され、n型半導体層170-4に接続する表面電極190及び、p型半導体層160-4に接続する裏面電極200を有する。 The solar cell 110-4 absorbs light in the wavelength band B4 and converts it into electricity. The solar cell 110-4 has a p-type semiconductor layer 160-4 and an n-type semiconductor layer 170-4 as a photoelectric conversion unit, an anti-reflection layer 180 is laminated on the n-type semiconductor layer 170-4, and has a front electrode 190 connected to the n-type semiconductor layer 170-4 and a back electrode 200 connected to the p-type semiconductor layer 160-4.

 波長分離レンズ120-1は、入射光を波長帯域B,B,B,Bに分離し、分離した光を、各波長帯域B,B,B,Bに適合した光吸収スペクトルを有する太陽電池セル110-1~110-4に集光する。 The wavelength separation lens 120-1 separates the incident light into wavelength bands B 1 , B 2 , B 3 , and B 4 and focuses the separated light onto the solar cells 110-1 to 110-4 having optical absorption spectra suited to the respective wavelength bands B 1 , B 2 , B 3 , and B 4 .

 波長分離レンズ120-1は、入射した光のうち、波長帯域Bの光を、太陽電池セル110-1に集光する。波長分離レンズ120-1は、入射した光のうち、波長帯域Bの光を、太陽電池セル110-2に集光する。波長分離レンズ120-1は、入射した光のうち、波長帯域Bの光を、太陽電池セル110-3に集光する。波長分離レンズ120-1は、入射した光のうち、波長帯域Bの光を、太陽電池セル110-4に集光する。太陽電池セル110-1~110-4が発電した電力は、裏面電極200及び表面電極190に接続する配線を介して、電力変換部2に出力される。 The wavelength separation lens 120-1 focuses light in wavelength band B1 from the incident light onto the solar cell 110-1. The wavelength separation lens 120-1 focuses light in wavelength band B2 from the incident light onto the solar cell 110-2. The wavelength separation lens 120-1 focuses light in wavelength band B3 from the incident light onto the solar cell 110-3. The wavelength separation lens 120-1 focuses light in wavelength band B4 from the incident light onto the solar cell 110-4. The power generated by the solar cell cells 110-1 to 110-4 is output to the power conversion unit 2 via wiring connected to the back electrode 200 and the front electrode 190.

 波長分離レンズ120-1は、太陽電池セル110-1~110-4を覆うように設けられる。波長分離レンズ120-1の例は、メタサーフェスである。メタサーフェスは、光の波長以下の幅を有する複数の微細構造体(構造体150に相当)を含んで構成される。メタサーフェスは、2次元構造を有してもよいし、3次元構造を有してもよい。波長分離レンズ120-1は、この構造体150のパラメータを変えるだけで、光の特性(波長、偏波、入射角)に応じて、位相と光強度を制御することができる。また、3次元構造の場合、2次元構造よりも設計自由度が向上する。 The wavelength separation lens 120-1 is provided so as to cover the solar cell 110-1 to 110-4. An example of the wavelength separation lens 120-1 is a metasurface. The metasurface is composed of multiple microstructures (corresponding to the structure 150) having a width equal to or less than the wavelength of light. The metasurface may have a two-dimensional structure or a three-dimensional structure. The wavelength separation lens 120-1 can control the phase and light intensity according to the characteristics of the light (wavelength, polarization, and angle of incidence) simply by changing the parameters of this structure 150. Furthermore, a three-dimensional structure provides greater design freedom than a two-dimensional structure.

 波長分離レンズ120-1は、波長分離機能及びレンズ機能の2つの機能を有する。波長分離機能は、入射した光を各波長帯域の光に分離する機能である。レンズ機能は、各波長の光を、対応する画素に集光する機能である。 The wavelength separation lens 120-1 has two functions: a wavelength separation function and a lens function. The wavelength separation function is to separate the incident light into light of each wavelength band. The lens function is to focus the light of each wavelength onto the corresponding pixel.

 この例では、波長分離レンズ120-1の波長分離機能により、入射した光が波長帯域B,B,B,Bに分離される。波長帯域B,B,B,Bの光は、波長分離レンズ120-1のレンズ機能により、波長帯域B,B,B,Bに対応する太陽電池セル110-1~110-4にそれぞれ集光される。 In this example, the wavelength separation function of the wavelength separation lens 120-1 separates the incident light into wavelength bands B1 , B2 , B3 , and B4 . The light in the wavelength bands B1 , B2 , B3 , and B4 is focused on the solar cell 110-1 to 110-4 corresponding to the wavelength bands B1 , B2 , B3 , and B4 , respectively, by the lens function of the wavelength separation lens 120-1.

 図6~図9は、図3に示す太陽電池モジュール100-1における太陽電池セル110-1~110-4への集光を模式的に示す図である。 FIGS. 6 to 9 are schematic diagrams showing the concentration of light onto solar cells 110-1 to 110-4 in the solar cell module 100-1 shown in FIG. 3.

 太陽電池モジュール100-1では、図6の矢印で示されるように、波長分離レンズ120-1の波長分離機能及びレンズ機能によって、波長帯域Bの光が、波長帯域Bに対応する太陽電池セル110-1に集光される。この例では、太陽電池セル110-1の上方(z軸正方向)の光だけでなく、太陽電池セル110-1の周辺の光も太陽電池セル110-1に集光される。すなわち、複数の構造体150は、太陽電池セル110-1との対向領域外における入射光の波長帯域Bの光も、太陽電池セル110-1に集光するように配置される。 In the solar cell module 100-1, as shown by the arrows in Fig. 6, the wavelength separation function and lens function of the wavelength separation lens 120-1 allow light in wavelength band B1 to be concentrated on the solar cell 110-1 corresponding to the wavelength band B1 . In this example, not only light above the solar cell 110-1 (positive direction of the z-axis) but also light around the solar cell 110-1 is concentrated on the solar cell 110-1. That is, the multiple structures 150 are arranged so that light in wavelength band B1 that is incident outside the region facing the solar cell 110-1 is also concentrated on the solar cell 110-1.

 そして、太陽電池モジュール100-1では、図7の矢印で示されるように、波長分離レンズ120-1の波長分離機能及びレンズ機能によって、波長帯域Bの光が、波長帯域Bに対応する太陽電池セル110-2に集光される。複数の構造体150は、太陽電池セル110-2との対向領域外における入射光の波長帯域Bの光も、太陽電池セル110-2に集光するように配置される。 7, in the solar cell module 100-1, the wavelength separation function and lens function of the wavelength separation lens 120-1 cause light in wavelength band B2 to be concentrated on the solar cell 110-2 corresponding to wavelength band B2 . The multiple structures 150 are arranged so that light in wavelength band B2 that is incident outside the region facing the solar cell 110-2 is also concentrated on the solar cell 110-2.

 そして、太陽電池モジュール100-1では、図8の矢印で示されるように、波長分離レンズ120-1の波長分離機能及びレンズ機能によって、波長帯域Bの光が、波長帯域Bに対応する太陽電池セル110-3に集光される。複数の構造体150は、太陽電池セル110-3との対向領域外における入射光の波長帯域Bの光も、太陽電池セル110-3に集光するように配置される。 In the solar cell module 100-1, the wavelength separation function and lens function of the wavelength separation lens 120-1 concentrate light in wavelength band B3 on the solar cell 110-3 corresponding to wavelength band B3 , as shown by the arrow in Fig. 8. The multiple structures 150 are arranged so that light in wavelength band B3 that is incident outside the region facing the solar cell 110-3 is also concentrated on the solar cell 110-3.

 そして、太陽電池モジュール100-1では、図9の矢印で示されるように、波長分離レンズ120-1の波長分離機能及びレンズ機能によって、波長帯域Bの光が、波長帯域Bに対応する太陽電池セル110-4に集光される。複数の構造体150は、太陽電池セル110-4との対向領域外における入射光の波長帯域Bの光も、太陽電池セル110-4に集光するように配置される。 9, in the solar cell module 100-1, the wavelength separation function and lens function of the wavelength separation lens 120-1 cause light in wavelength band B4 to be concentrated on the solar cell 110-4 corresponding to wavelength band B4 . The multiple structures 150 are arranged so that light in wavelength band B4 that is incident outside the region facing the solar cell 110-4 is also concentrated on the solar cell 110-4.

 太陽電池モジュール100-1は、このように複数の構造体150が配置されることで、太陽電池セル110-1~110-4との対向領域における入射光の波長帯域B,B,B,Bの光だけを太陽電池セル110-1~110-4に集光する場合よりも、受光光量を増加させることができる。 By arranging multiple structures 150 in this manner, the solar cell module 100-1 can receive a greater amount of light than when only light in the wavelength bands B1 , B2 , B3 , and B4 of the incident light in the opposing areas with the solar cells 110-1 to 110-4 is concentrated onto the solar cells 110-1 to 110-4.

 なお、波長分離レンズ120-1は、同じ波長帯域の光を複数の太陽電池セル110に集光してもよい。波長分離レンズ120-1は、波長帯域Bの光を太陽電池セル110-2に集光しているが、太陽電池セル110-2の位置に太陽電池セル110-4が配置される場合には、波長帯域Bに代えて、波長帯域Bがこの太陽電池セル110-4に集光するように設計されてもよい。 The wavelength separation lens 120-1 may focus light of the same wavelength band on a plurality of solar cells 110. The wavelength separation lens 120-1 focuses light of wavelength band B2 on the solar cell 110-2, but when the solar cell 110-4 is disposed at the position of the solar cell 110-2, the lens may be designed to focus light of wavelength band B4 on the solar cell 110-4 instead of wavelength band B2 .

[第2の構成例]
 次に、第2の構成例を有する太陽電池モジュール100-2について説明する。図10は、実施の形態に係る太陽電池モジュール100-2を平面視したときに太陽電池セル110の配置を模式的に示す図である。図11は、図10のc-c´線に沿って側面視したときの太陽電池モジュール100-2の断面の一例を示す図である。図11において、矢印は、太陽電池モジュール100-2に入射する光を模式的に示す。
[Second Configuration Example]
Next, a solar cell module 100-2 having a second configuration example will be described. Fig. 10 is a diagram showing a schematic arrangement of solar cells 110 when the solar cell module 100-2 according to the embodiment is viewed in plan. Fig. 11 is a diagram showing an example of a cross section of the solar cell module 100-2 when viewed from the side along line c-c' in Fig. 10. In Fig. 11, arrows typically indicate light incident on the solar cell module 100-2.

 太陽電池モジュール100-2では、波長帯域B,B,Bにそれぞれ対応した光吸収スペクトルを有する3つの太陽電池セルが、図10に示すように並列に配置され、一つのユニットU1-2を構成する。そして、図11に示すように、波長分離レンズ120-2は、太陽電池セル110-1~110-3上に配置される。例えば、1つの波長分離レンズ120-2につき、直下の3つの太陽電池セル110-1~110-3が相対するようにしてもよい。 In the solar cell module 100-2, three solar cells having light absorption spectra corresponding to the wavelength bands B1 , B2 , and B3 , respectively, are arranged in parallel as shown in Fig. 10 to form one unit U1-2. Then, as shown in Fig. 11, a wavelength separation lens 120-2 is arranged above the solar cells 110-1 to 110-3. For example, one wavelength separation lens 120-2 may face the three solar cells 110-1 to 110-3 directly below it.

 波長分離レンズ120-2は、入射光を波長帯域B,B,Bに分離し、分離した光を、各波長帯域B,B,Bに適合した光吸収スペクトルを有する太陽電池セル110-1~110-3に集光する。 The wavelength separation lens 120-2 separates the incident light into wavelength bands B 1 , B 2 , and B 3 and focuses the separated light onto the solar cells 110-1 to 110-3 having optical absorption spectra suited to the respective wavelength bands B 1 , B 2 , and B 3 .

 波長分離レンズ120-2は、入射した光のうち、波長帯域Bの光を、太陽電池セル110-1に集光する。波長分離レンズ120-2は、入射した光のうち、波長帯域Bの光を、太陽電池セル110-2に集光する。波長分離レンズ120-2は、入射した光のうち、波長帯域Bの光を、太陽電池セル110-3に集光する。太陽電池セル110-1~110-3が発電した電力は、裏面電極200及び表面電極190に接続する配線を介して、電力変換部2に出力される。 The wavelength separation lens 120-2 focuses light in wavelength band B1 from the incident light onto the solar cell 110-1. The wavelength separation lens 120-2 focuses light in wavelength band B2 from the incident light onto the solar cell 110-2. The wavelength separation lens 120-2 focuses light in wavelength band B3 from the incident light onto the solar cell 110-3. The power generated by the solar cells 110-1 to 110-3 is output to the power conversion unit 2 via wiring connected to the back electrode 200 and the front electrode 190.

 波長分離レンズ120-2は、太陽電池セル110-1~110-3を覆うように設けられる。波長分離レンズ120-2の例は、メタサーフェスである。 The wavelength separation lens 120-2 is provided to cover the solar cells 110-1 to 110-3. An example of the wavelength separation lens 120-2 is a metasurface.

 波長分離レンズ120-2は、波長分離機能及びレンズ機能の2つの機能を有する。この例では、波長分離レンズ120-2の波長分離機能により、入射した光が波長帯域B,B,Bに分離される。波長帯域B,B,Bの光は、波長分離レンズ120-2のレンズ機能により、波長帯域B,B,Bに対応する太陽電池セル110-1~110-3にそれぞれ集光される。 The wavelength separation lens 120-2 has two functions: a wavelength separation function and a lens function. In this example, the wavelength separation function of the wavelength separation lens 120-2 separates the incident light into wavelength bands B1 , B2 , and B3 . The light in the wavelength bands B1 , B2 , and B3 is focused on the solar cell 110-1 to 110-3 corresponding to the wavelength bands B1 , B2 , and B3 , respectively, by the lens function of the wavelength separation lens 120-2.

 図12~図14は、図10に示す太陽電池モジュール100-2における太陽電池セル110-1~110-3への集光を模式的に示す図である。 FIGS. 12 to 14 are schematic diagrams showing the concentration of light onto solar cells 110-1 to 110-3 in the solar cell module 100-2 shown in FIG. 10.

 太陽電池モジュール100-2では、図12の矢印で示されるように、波長帯域Bの光が、波長帯域Bに対応する太陽電池セル110-1に集光される。この例では、太陽電池セル110-1の上方(z軸正方向)の光だけでなく、太陽電池セル110-1の周辺の光も太陽電池セル110-1に集光される。複数の構造体150は、太陽電池セル110-1との対向領域外における入射光の波長帯域Bの光も、太陽電池セル110-1に集光するように配置される。 In the solar cell module 100-2, as shown by the arrows in Fig. 12, light in wavelength band B1 is concentrated on the solar cell 110-1 corresponding to wavelength band B1 . In this example, not only light above the solar cell 110-1 (positive direction of the z-axis) but also light around the solar cell 110-1 is concentrated on the solar cell 110-1. The multiple structures 150 are arranged so that light in wavelength band B1 that is incident outside the region facing the solar cell 110-1 is also concentrated on the solar cell 110-1.

 そして、太陽電池モジュール100-2では、図13の矢印で示されるように、波長帯域Bの光が、波長帯域Bに対応する太陽電池セル110-2に集光される。複数の構造体150は、太陽電池セル110-2との対向領域外における入射光の波長帯域Bの光も、太陽電池セル110-2に集光するように配置される。 In the solar cell module 100-2, light in wavelength band B2 is concentrated on the solar cell 110-2 corresponding to wavelength band B2 , as shown by the arrows in Fig. 13. The multiple structures 150 are arranged so that light in wavelength band B2 that is incident outside the region facing the solar cell 110-2 is also concentrated on the solar cell 110-2.

 そして、太陽電池モジュール100-2では、図14の矢印で示されるように、波長帯域Bの光が、波長帯域Bに対応する太陽電池セル110-3に集光される。複数の構造体150は、太陽電池セル110-3との対向領域外における入射光の波長帯域Bの光も、太陽電池セル110-3に集光するように配置される。 In the solar cell module 100-2, light in wavelength band B3 is concentrated on the solar cell 110-3 corresponding to wavelength band B3 , as shown by the arrows in Fig. 14. The multiple structures 150 are arranged so that light in wavelength band B3 that is incident outside the region facing the solar cell 110-3 is also concentrated on the solar cell 110-3.

 太陽電池モジュール100-2は、このように複数の構造体150が配置されることで、太陽電池セル110-1~110-3との対向領域における入射光の波長帯域B,B,Bの光だけを太陽電池セル110-1~110-3に集光する場合よりも、受光光量を増加させることができる。 By arranging multiple structures 150 in this manner, the solar cell module 100-2 can receive a greater amount of light than when only light in the wavelength bands B1 , B2 , and B3 of the incident light in the opposing areas with the solar cells 110-1 to 110-3 is concentrated onto the solar cells 110-1 to 110-3.

 なお、波長分離レンズ120-2は、同じ波長帯域の光を複数の太陽電池セル110に集光してもよい。波長分離レンズ120-2は、波長帯域Bの光を太陽電池セル110-1に集光しているが、太陽電池セル110-1の位置に太陽電池セル110-3が配置される場合には、波長帯域Bに代えて、波長帯域Bがこの太陽電池セル110-3に集光するように設計されてもよい。 The wavelength separation lens 120-2 may focus light of the same wavelength band on a plurality of solar cells 110. The wavelength separation lens 120-2 focuses light of wavelength band B1 on the solar cell 110-1, but when the solar cell 110-3 is disposed at the position of the solar cell 110-1, the lens may be designed to focus light of wavelength band B3 on the solar cell 110-3 instead of wavelength band B1 .

[波長分離レンズの構造例]
 図2では、波長分離レンズ120が透明層140の底面に形成されているがこれに限らない。図15~図24は、実施の形態に係る波長分離レンズ120の断面の一部の他の例を模式的に示す図である。
[Structural example of wavelength separation lens]
2, the wavelength separation lens 120 is formed on the bottom surface of the transparent layer 140, but this is not limited to this. Figures 15 to 24 are diagrams each showing a schematic view of another example of a part of a cross section of the wavelength separation lens 120 according to the embodiment.

 図15の波長分離レンズ120Aに示すように、構造体150は、透明層140の上面に形成されてもよい。この場合、構造体150は、透明層140の上面に支持されている。構造体150の上方の透明層は、空気でも樹脂などの保護層でもよく、透明層140の材料は単一でよいし、複数の材料が層状になったものでもよい。 As shown in the wavelength separation lens 120A in FIG. 15, the structure 150 may be formed on the upper surface of the transparent layer 140. In this case, the structure 150 is supported on the upper surface of the transparent layer 140. The transparent layer above the structure 150 may be air or a protective layer such as a resin, and the transparent layer 140 may be made of a single material or may be made of multiple layers of materials.

 図16の波長分離レンズ120B及び図17の波長分離レンズ120Cに示すように、構造体150は、透明層140の積層方向に沿って複数層形成されてもよい。構造体150が複数層で構成される場合、単層である場合と比して、設計パラメータを層の増加分増やすことができ、これにより光制御制が増すため、より高効率な波長帯域分離を実現できる。 As shown in wavelength separation lens 120B in FIG. 16 and wavelength separation lens 120C in FIG. 17, structure 150 may be formed in multiple layers along the stacking direction of transparent layer 140. When structure 150 is composed of multiple layers, the design parameters can be increased by the amount of the increase in layers compared to when it is a single layer, which increases the light control and allows for more efficient wavelength band separation.

 波長分離レンズ120Bでは、透明層140の上面及び透明層140内部のそれぞれに1層ずつ、構造体150-1,150-2が形成される。また、波長分離レンズ120Cでは、透明層140の上面の1層及び透明層140内部の2層の合計3層の構造体150-1~150-3が形成される。構造体150-1は、下方の透明層140の上面に支持されている。構造体150-1~150-3の材料は、層内で同一であってもよく、全ての層で同一であってもよい。また、構造体150-1~150-3の材料は、場所毎及び/または層毎に異なっていてもよい。構造体150-1~150-3の高さ、断面の形状、寸法は、層内及び/または全ての層で同一であってもよいし、場所毎及び/または層毎に異なっていてもよい。 In the wavelength separation lens 120B, structures 150-1 and 150-2 are formed on the upper surface of the transparent layer 140 and inside the transparent layer 140, respectively. In the wavelength separation lens 120C, structures 150-1 to 150-3 are formed in a total of three layers, one layer on the upper surface of the transparent layer 140 and two layers inside the transparent layer 140. Structure 150-1 is supported on the upper surface of the lower transparent layer 140. The material of structures 150-1 to 150-3 may be the same within a layer, or may be the same in all layers. The material of structures 150-1 to 150-3 may be different for each location and/or for each layer. The height, cross-sectional shape, and dimensions of structures 150-1 to 150-3 may be the same within a layer and/or in all layers, or may be different for each location and/or for each layer.

 また、図18の波長分離レンズ120D、図19の波長分離レンズ120E、及び図20の波長分離レンズ120Gに示すように、構造体150は、透明層140内部に形成されてもよい。波長分離レンズ120Dでは、透明層140内部に1層の構造体150が形成される。また、波長分離レンズ120Eでは、透明層140内部に2層の構造体150-1,150-2が形成される。また、波長分離レンズ120Gでは、透明層140内部に3層の構造体150-1~150-3が形成される。 Also, as shown in wavelength separation lens 120D in FIG. 18, wavelength separation lens 120E in FIG. 19, and wavelength separation lens 120G in FIG. 20, the structure 150 may be formed inside the transparent layer 140. In wavelength separation lens 120D, one layer of structure 150 is formed inside the transparent layer 140. In wavelength separation lens 120E, two layers of structures 150-1 and 150-2 are formed inside the transparent layer 140. In wavelength separation lens 120G, three layers of structures 150-1 to 150-3 are formed inside the transparent layer 140.

 また、図21の波長分離レンズ120H、図22の波長分離レンズ120Iに示すように、構造体150は、透明層140の底面及び透明層140内部に形成されてもよい。波長分離レンズ120Hでは、透明層140の底面及び透明層140内部のそれぞれに1層ずつ、構造体150-1,150-2が形成される。また、波長分離レンズ120Iでは、透明層140の底面の1層及び透明層140内部の2層の合計3層の構造体150-1~150-3が形成される。波長分離レンズ120Hの構造体150-2、波長分離レンズ120Iの150-3は、上方の透明層140に支持されている。 Furthermore, as shown in the wavelength separation lens 120H in FIG. 21 and the wavelength separation lens 120I in FIG. 22, the structures 150 may be formed on the bottom surface of the transparent layer 140 and inside the transparent layer 140. In the wavelength separation lens 120H, structures 150-1 and 150-2 are formed on the bottom surface of the transparent layer 140 and inside the transparent layer 140, respectively. In the wavelength separation lens 120I, structures 150-1 to 150-3 are formed in a total of three layers, one layer on the bottom surface of the transparent layer 140 and two layers inside the transparent layer 140. The structures 150-2 of the wavelength separation lens 120H and 150-3 of the wavelength separation lens 120I are supported by the transparent layer 140 above.

 また、図23の波長分離レンズ120J、及び、図24の波長分離レンズ120Kに示すように、構造体150は、透明層140の上面及び底面に形成されてもよい。波長分離レンズ120Jでは、透明層140の上面及び透明層140の底面のそれぞれに1層ずつ、構造体150-1,150-2が形成される。また、波長分離レンズ120Kでは、透明層140の上面、透明層140底面、透明層140の内部に、それぞれ構造体150-1~150-3が形成される。波長分離レンズ120J及び波長分離レンズ120Kの構造体150-1は、下方の透明層140に支持されている。波長分離レンズ120Jの構造体150-2及び波長分離レンズ120Kの構造体150-3は、上方の透明層140に支持されている。 Also, as shown in the wavelength separation lens 120J of FIG. 23 and the wavelength separation lens 120K of FIG. 24, the structures 150 may be formed on the top and bottom surfaces of the transparent layer 140. In the wavelength separation lens 120J, structures 150-1 and 150-2 are formed on the top surface and bottom surface of the transparent layer 140, respectively. In the wavelength separation lens 120K, structures 150-1 to 150-3 are formed on the top surface of the transparent layer 140, the bottom surface of the transparent layer 140, and inside the transparent layer 140, respectively. The structures 150-1 of the wavelength separation lens 120J and the wavelength separation lens 120K are supported by the transparent layer 140 below. The structures 150-2 of the wavelength separation lens 120J and the structures 150-3 of the wavelength separation lens 120K are supported by the transparent layer 140 above.

 また、波長分離レンズ120と太陽電池セル110間の領域は、空気層で満たされていてもよいし、透明層を介して接続されていてもよい。 The area between the wavelength separation lens 120 and the solar cell 110 may be filled with an air layer, or may be connected via a transparent layer.

[波長分離レンズの実現方法]
 次に、第2の構成例における波長分離レンズ120-2であって、かつ、構造体150が2層である場合の波長分離レンズについて、実現方法を説明する。
[Method of realizing wavelength separation lens]
Next, a method for realizing the wavelength separation lens 120-2 in the second configuration example where the structure 150 has two layers will be described.

 入射光の波長帯域に応じて異なる集光位置をもつ波長分離レンズ120-2を実現するには、波長帯域毎に異なる光波面を与える構造を実現する必要がある。 To realize a wavelength separation lens 120-2 with different focusing positions depending on the wavelength band of the incident light, it is necessary to realize a structure that gives a different optical wavefront for each wavelength band.

 そこで、微細な柱状構造体(構造体150)が入射光に与える光位相遅延量の波長分散特性を利用することで、波長分離レンズ120を実現する。 The wavelength separation lens 120 is realized by utilizing the wavelength dispersion characteristics of the amount of optical phase delay that the fine columnar structure (structure 150) imparts to the incident light.

 各層の構造体150は、構造体150の周囲の透明層130,140の屈折率nよりも高い屈折率nを有するTiOやSiN等の材料から形成されている。構造体150は、作製難易度の観点から、高さ(z軸方向の長さ)hlayerが面内で一定の構造体が好適である。なお、構造体150は、層毎に高さが異なっていてよい。 The structures 150 of each layer are formed from a material such as TiO2 or SiN having a refractive index n1 higher than the refractive index n0 of the transparent layers 130 and 140 surrounding the structure 150. From the viewpoint of the difficulty of fabrication, the structure 150 is preferably a structure having a constant height (length in the z-axis direction) hlayer within the plane. Note that the height of the structure 150 may differ for each layer.

 構造体150の底面および上面は、4回回転対称の形状である。この形状によって、偏光依存性の発生を抑制する。 The bottom and top surfaces of the structure 150 have a four-fold rotationally symmetric shape. This shape suppresses the occurrence of polarization dependency.

 構造体150は、透明層130,140との屈折率差から、光を構造内に閉じ込めて伝搬させる光導波路として考えることができる。したがって、構造体150の上面側から光が入射すると、光は、構造体150内に強く閉じ込められながら伝搬し、光導波路の実効的な屈折率neffにより決定される位相遅延効果を受けて、構造体150底面側から出力される。 The structure 150 can be considered as an optical waveguide that confines and propagates light within the structure due to the refractive index difference between the transparent layers 130 and 140. Therefore, when light is incident on the top surface side of the structure 150, the light propagates while being strongly confined within the structure 150, and is output from the bottom surface side of the structure 150 after being subjected to a phase delay effect determined by the effective refractive index n eff of the optical waveguide.

 具体的に、透明層140を構造の厚み分の長さを伝搬した光の位相を基準した際、各層の構造体150による光位相遅延量φlayerは、光の真空中での波長をλとおくと、式(1)で表される。 Specifically, when the phase of light propagating through the transparent layer 140 a length equivalent to the thickness of the structure is used as a reference, the amount of optical phase delay φ layer due to the structure 150 of each layer is expressed by equation (1), where λ is the wavelength of light in a vacuum.

Figure JPOXMLDOC01-appb-M000001
Figure JPOXMLDOC01-appb-M000001

 この光位相遅延量φlayerは、光の波長λによって異なるため、同一の構造体150において、光の波長帯域に応じて異なる光位相遅延量φlayerを与えることができる。 This optical phase delay amount φ layer differs depending on the wavelength λ of the light, so that the same structure 150 can impart different optical phase delay amounts φ layer depending on the wavelength band of the light.

 さらに、光導波路の実効的な屈折率neffは、構造体150の断面形状に大きく依存することが知られており、n<neff<nの値をとる。 Furthermore, it is known that the effective refractive index neff of the optical waveguide is greatly dependent on the cross-sectional shape of the structure 150, and has a value of n0 < neff < n1 .

 また、光導波路の実効的な屈折率neffは、光の波長λによっても異なり、その度合いは、構造体150の断面形状に大きく依存する。 Moreover, the effective refractive index n eff of the optical waveguide also differs depending on the wavelength λ of the light, and the degree of this differs greatly depending on the cross-sectional shape of the structure 150 .

 したがって、多様な断面形状をもつ柱状の構造体150を用いることで、光の波長λに応じた位相遅延量φlayerの多彩な組み合わせを設定することが可能である。 Therefore, by using the columnar structures 150 having various cross-sectional shapes, it is possible to set various combinations of the phase delay amount φ layer according to the wavelength λ of light.

 これらの複数の構造体150を透明層140の面方向に適切に配置することで、波長毎に異なる空間位相分布(光位相遅延量分布)を形成することが可能となり、空間位相分布をレンズに対応した分布にすることで、波長帯域に応じて異なる集光位置を有する波長分離レンズ120を新たに設計及び実現することが可能となる。 By appropriately arranging these multiple structures 150 in the surface direction of the transparent layer 140, it is possible to form a spatial phase distribution (distribution of optical phase delay amount) that differs for each wavelength, and by making the spatial phase distribution a distribution corresponding to the lens, it is possible to newly design and realize a wavelength separation lens 120 that has different focusing positions depending on the wavelength band.

 構造体150を配置する配置周期Pは、効率低下の要因となる光の回折現象を防ぐため、所望の受光波長帯域の最短中心波長をλminとすると、式(2)のように設定することが望ましい。なお、nは、透過側に位置する透明層140の屈折率である。 In order to prevent the light diffraction phenomenon that causes a decrease in efficiency, it is desirable to set the arrangement period P of the structures 150 as shown in formula (2), where λ min is the shortest central wavelength of the desired light receiving wavelength band. Note that n 0 is the refractive index of the transparent layer 140 located on the transmission side.

Figure JPOXMLDOC01-appb-M000002
Figure JPOXMLDOC01-appb-M000002

 次に、構造体150の複数層化の利点について説明する。単層の構造体150の場合、単層の構造体150の高さhは、光位相遅延量φlayerを2π以上有していることが好ましいことから、分離する波長域の最も長波長側の波長域における所望の中心波長をλとすると、式(3)のように設定することが望ましい。 Next, we will explain the advantages of multi-layering the structure 150. In the case of a single-layer structure 150, it is preferable that the height h1 of the single-layer structure 150 has an optical phase delay amount φ layer of 2π or more, so that it is preferable to set it as shown in formula (3) when the desired center wavelength in the wavelength range on the longest wavelength side of the wavelength range to be separated is λr .

Figure JPOXMLDOC01-appb-M000003
Figure JPOXMLDOC01-appb-M000003

 可視光領域の場合であって、nを構造体150のSiNの屈折率、nを透明層130,140のSiOの屈折率とした場合、単層の構造体150の高さhは、1060nm以上とすることが望ましい。 In the case of the visible light region, when n1 is the refractive index of the SiN of the structure 150 and n0 is the refractive index of the SiO2 of the transparent layers 130 and 140, it is desirable that the height h1 of the single-layer structure 150 be 1060 nm or more.

 このとき、各構造体150の配置周期Pを透明材料内での最短波長以下、例えば、λが410nmであり、nをSiOの屈折率とした場合には、280nm以下とすると、構造体150のアスペクト比を3.8以上とすることが必要となる。 In this case, if the arrangement period P of each structure 150 is set to be equal to or shorter than the shortest wavelength in the transparent material, for example, 280 nm or less when λ is 410 nm and n0 is the refractive index of SiO2 , then it is necessary to set the aspect ratio of the structures 150 to 3.8 or more.

 実際の構造体150の断面寸法は、隣接する構造体150との光結合を緩和する目的で、構造周期Pより小さくするため、その最大寸法を200nmとすると、アスペクト比は5.3以上となる。さらに、光導波路の実効的な屈折率neffの制御のためにより小さな断面寸法を有する構造体150も一部用いられており、最小を80nmとするとアスペクト比は、約13.3となる。 The cross-sectional dimension of the actual structure 150 is made smaller than the structural period P in order to reduce optical coupling with adjacent structures 150, and so if the maximum dimension is 200 nm, the aspect ratio will be 5.3 or more. Furthermore, some structures 150 having smaller cross-sectional dimensions are used in order to control the effective refractive index n eff of the optical waveguide, and if the minimum is 80 nm, the aspect ratio will be about 13.3.

 このような高アスペクト比の微細構造を通常の半導体プロセスで作製するには、一般に高度な作製技術が必要とされる。  In order to fabricate such high aspect ratio microstructures using conventional semiconductor processes, advanced fabrication techniques are generally required.

 これに対し、構造体150を複数層化して高さ方向に分割することによって、各層の総和で必要な光位相遅延量φlayerを確保しながら、微細な構造体150のアスペクト比を抑えることができる。 In contrast, by dividing the structure 150 into a plurality of layers in the height direction, the aspect ratio of the fine structure 150 can be suppressed while ensuring the required optical phase delay amount φ layer in the sum of the layers.

 例えば、可視光領域の場合、nを構造体150のSiNの屈折率とし、nを透明層140のSiOの屈折率として、2層の構造体150を形成した場合、各層の構造体150の高さh1,2は、1層の場合の2分の1程度でよく、例えば、530nm以下となる。したがって、アスペクト比を約2分の1に低減することができる。また、3層の構造体150を形成した場合も、同様にアスペクト比を3分の1に低減することができる。 For example, in the case of the visible light region, when a two-layer structure 150 is formed with n 1 being the refractive index of the SiN of the structure 150 and n 0 being the refractive index of the SiO 2 of the transparent layer 140, the height h 1, 2 of the structure 150 of each layer can be about half that of a one-layer structure, for example, 530 nm or less. Therefore, the aspect ratio can be reduced to about half. Also, when a three-layer structure 150 is formed, the aspect ratio can be reduced to one-third in the same manner.

 さらに、複数層化により分割した各構造体150の断面寸法は、分割前と同一である必要はなく、層毎に異なっていてもよい。 Furthermore, the cross-sectional dimensions of each structure 150 divided by layering do not need to be the same as before division, and may be different for each layer.

 このとき、上記式から明らかなように、構造体150の複数層化によって、構造体150の層毎に、neffとその波長分散とを、断面寸法によって任意に変えることができる。すなわち、構造体150を複数層化した場合には、構造体150が1層である場合と比して、光の波長λに応じた光位相遅延量φlayerのより多彩な組み合わせを設定することが可能となり、波長分離効率の向上や集光効率の向上が可能となる。 At this time, as is clear from the above formula, by forming the structure 150 into a plurality of layers, n eff and its wavelength dispersion can be arbitrarily changed by the cross-sectional dimensions for each layer of the structure 150. That is, when the structure 150 is formed into a plurality of layers, it becomes possible to set a wider variety of combinations of the optical phase delay amount φ layer according to the wavelength λ of light, compared with the case where the structure 150 is a single layer, and it becomes possible to improve the wavelength separation efficiency and the light collection efficiency.

[構造体]
 第2の構成例における波長分離レンズ120であって、かつ、構造体150が2層である場合の構造体150の形状について説明する。なお、その他の構成例においても同様の設計指針で構成可能である。
[Structure]
The following describes the shape of the structure 150 in the wavelength separation lens 120 in the second configuration example when the structure 150 has two layers. Note that other configuration examples can also be configured with similar design guidelines.

 図25~図30は、図2に示す構造体150の概略構成の例を示す図である。図25は、平面視したときの形状が正方形形状である構造体150の側面図である。図26は、図25に示す構造体150の底面図である。本例では、入射光が可視光領域の場合について説明する。 FIGS. 25 to 30 are diagrams showing an example of the schematic configuration of the structure 150 shown in FIG. 2. FIG. 25 is a side view of the structure 150, which has a square shape when viewed in a plane. FIG. 26 is a bottom view of the structure 150 shown in FIG. 25. In this example, a case where the incident light is in the visible light region will be described.

 構造体160は、z軸方向に延在する柱状構造体であり、透明層140(例えばSiO(屈折率neff=1.45))の底面に形成される。構造体150の材料は、SiN(屈折率n=2.05)である。構造体150の側方及び下方は、空気(屈折率n=1.0)である。 The structure 160 is a columnar structure extending in the z-axis direction, and is formed on the bottom surface of the transparent layer 140 (e.g., SiO2 (refractive index neff = 1.45)). The material of the structure 150 is SiN (refractive index n1 = 2.05). The sides and bottom of the structure 150 are air (refractive index n0 = 1.0).

 それぞれの構造体160の配置周期をPとする。配置周期Pは、透過側で回折光が生じないように、式(2)のように設定することが望ましい。ここでは、受光波長帯域の最短波長λminを410nmとし、nを1.45とし、配置周期Pを280nmとする。 The arrangement period of the structures 160 is denoted by P. It is desirable to set the arrangement period P as shown in formula (2) so that no diffracted light occurs on the transmission side. Here, the shortest wavelength λ min of the light receiving wavelength band is set to 410 nm, n 0 is set to 1.45, and the arrangement period P is set to 280 nm.

 構造体150の高さhlayer(z軸方向の長さ)は、一定である。高さhlayerは、構造体150が、入射した光、すなわちz軸方向に沿って進む光に対して2π以上の光位相遅延量(位相値)を有していることが好ましい。層数をLとし、分離する波長域の最も長波長側の波長域における所望の中心波長をλとすると、高さhlayerは、式(4)のように設定することが望ましい。 The height h layer (length in the z-axis direction) of the structure 150 is constant. The height h layer is preferably such that the structure 150 has an optical phase delay (phase value) of 2π or more with respect to the incident light, i.e., the light traveling along the z-axis direction. If the number of layers is L and the desired center wavelength in the wavelength range on the longest wavelength side of the wavelength range to be separated is λ r , it is desirable to set the height h layer as shown in formula (4).

Figure JPOXMLDOC01-appb-M000004
Figure JPOXMLDOC01-appb-M000004

 ここではL=2とし、式(4)より、各層の高さh1,2=850nmとする。 Here, L=2, and from equation (4), the height of each layer is h 1,2 =850 nm.

 構造体160の断面形状とその寸法パラメータ(構造の幅)とを設計することで、複数波長において異なる位相値の様々な組み合わせを実現することができる。 By designing the cross-sectional shape of the structure 160 and its dimensional parameters (width of the structure), it is possible to realize various combinations of different phase values at multiple wavelengths.

 このとき、式(1)から明らかなように、層毎に断面形状と寸法パラメータとを変えることで、層毎に、光導波路の実効的な屈折率neffの値と波長分散とを変えることができる。 In this case, as is clear from formula (1), by changing the cross-sectional shape and dimensional parameters for each layer, the effective refractive index neff and wavelength dispersion of the optical waveguide can be changed for each layer.

 また、構造体150が複数層の場合、各層の総和として光位相遅延量φlayerを考えると、より様々な位相値の組み合わせが可能となり、波長域ごとに異なるレンズ機能を設計する上で自由度の増加につながる。 Furthermore, when the structure 150 has multiple layers, considering the optical phase delay amount φ layer as the sum of each layer makes it possible to have a wider variety of combinations of phase values, which leads to an increased degree of freedom in designing different lens functions for each wavelength range.

 構造体150の断面形状は、偏光依存性を生じさせないため、4回回転対称の形状が好適である。図27は、平面視したときの形状がX字形状である構造体150の側面図である。図28は、図27に示す構造体150の平面図である。図29は、平面視したときの形状が中空ひし形形状である構造体150の側面図である。図30は、図29に示す構造体150の平面図である。構造体150の断面形状は、図27~図30に示すように、十字形および正方形空孔を有する正方形を有する柱状構造を45°面内回転した、X字形状や中空ひし形形状であってもよい。 The cross-sectional shape of the structure 150 is preferably a four-fold rotationally symmetric shape in order to avoid polarization dependency. FIG. 27 is a side view of the structure 150 which has an X-shape when viewed in a plane. FIG. 28 is a plan view of the structure 150 shown in FIG. 27. FIG. 29 is a side view of the structure 150 which has a hollow diamond shape when viewed in a plane. FIG. 30 is a plan view of the structure 150 shown in FIG. 29. The cross-sectional shape of the structure 150 may be an X-shape or a hollow diamond shape, which is formed by rotating a columnar structure having a square with a cross and square holes by 45° in-plane, as shown in FIGS. 27 to 30.

 なお、図27~図30では、構造体150の断面形状として、十字形および正方形空孔を有する正方形を有する柱状構造を45°面内回転したものを採用しているが、これは回転しない構造と比較して、隣接する構造体150との光学的結合を弱める効果がある。様々な構造体150を周期的に配置した場合でも、各構造体150の光学特性が隣接する構造体150の影響を受けることなく、設計した空間位相分布を再現しやすいという効果がある。 In addition, in Figures 27 to 30, a columnar structure having a square with a cross-shaped and square hole is rotated by 45° in-plane as the cross-sectional shape of the structure 150, which has the effect of weakening the optical coupling with adjacent structures 150 compared to a structure that is not rotated. Even when various structures 150 are arranged periodically, the optical properties of each structure 150 are not affected by the adjacent structures 150, and the designed spatial phase distribution can be easily reproduced.

 構造体150を複数層とした場合、各層間の距離は任意に設定できるが、層間での多重反射や層透過後の光の散逸・放射を考慮すると、波長程度或いは波長以下にすることが望ましい。また、層毎の構造体150が接続されてもよい。すなわち、層間の距離0であってもよい。 When the structure 150 is made up of multiple layers, the distance between each layer can be set arbitrarily, but considering multiple reflections between layers and the dissipation and radiation of light after passing through a layer, it is desirable to set the distance to about the wavelength or less. Also, the structures 150 for each layer may be connected. In other words, the distance between layers may be zero.

 なお、構造体150の断面形状は、図26、図28、図30に示される形状に限られない。図31は、図2に示す構造体150の断面形状の例を示す図である。波長分離レンズ120は、図31に例示されるようなさまざまな断面形状の構造体160を採用してもよい。例示される形状は、例えば正方形形状、十字形状及び円形形状をさまざまに組み合わせ、回転することによって得られる4回回転対称形状である。 The cross-sectional shape of the structure 150 is not limited to the shapes shown in Figures 26, 28, and 30. Figure 31 is a diagram showing examples of the cross-sectional shape of the structure 150 shown in Figure 2. The wavelength separation lens 120 may employ structures 160 of various cross-sectional shapes as exemplified in Figure 31. The exemplified shapes are, for example, four-fold rotationally symmetric shapes obtained by combining and rotating various square, cross, and circular shapes.

[波長分離レンズの設計例1]
 次に、波長分離レンズの設計例について説明する。本例では、例えば、図3~図6に示す第1の構成例の太陽電池モジュール100-1の波長分離レンズ120-1を想定する。波長分離レンズ120-1の波長帯域分割数は4である。なお、その他の波長分割数に対しても、以下と同様の設計を適用できる。
[Design example 1 of wavelength separation lens]
Next, a design example of the wavelength separation lens will be described. In this example, for example, the wavelength separation lens 120-1 of the solar cell module 100-1 of the first configuration example shown in Figures 3 to 6 is assumed. The number of wavelength band divisions of the wavelength separation lens 120-1 is 4. Note that the same design as below can be applied to other numbers of wavelength divisions.

 レンズ設計では、理想的な光位相遅延量分布(位相分布)を実現するように、構造体150の断面形状及び配置を設計する。以下に説明する例では、波長帯域毎に集光点が異なるレンズの位相分布を設計し、1層または複数層の柱状の構造体150で実現する。本例では、SiNで組成される構造体150を用いて、光位相遅延量の波長分散特性を利用することで、400nm~1200nmの各波長帯域の中心波長毎に異なる位相分布を設計し、波長分離レンズ120-1を実現した。 In lens design, the cross-sectional shape and arrangement of the structure 150 are designed to achieve an ideal optical phase delay distribution (phase distribution). In the example described below, a lens phase distribution with a different focal point for each wavelength band is designed and realized with a single or multiple layered columnar structure 150. In this example, a structure 150 composed of SiN is used, and by utilizing the wavelength dispersion characteristics of the optical phase delay, a different phase distribution is designed for each central wavelength of each wavelength band from 400 nm to 1200 nm, resulting in the wavelength separation lens 120-1.

 ユニットU1-1(太陽電池セル110-1~110-4)の理想的な光位相遅延量分布を示す。図32は、中心波長が500nmの場合の理想的な光位相遅延量分布を示す図である。図33は、中心波長が650nmの場合の理想的な光位相遅延量分布を示す図である。図34は、中心波長が800nmの場合の理想的な光位相遅延量分布を示す図である。図35は、中心波長が1000nmの場合の理想的な光位相遅延量分布を示す図である。なお、図32~図35では、4つの太陽電池セル110-1~110-4(ユニットU1-1)の中心位置が、x=0、y=0に対応する。 The ideal optical phase delay distribution of unit U1-1 (solar cell 110-1 to 110-4) is shown. FIG. 32 is a diagram showing an ideal optical phase delay distribution when the central wavelength is 500 nm. FIG. 33 is a diagram showing an ideal optical phase delay distribution when the central wavelength is 650 nm. FIG. 34 is a diagram showing an ideal optical phase delay distribution when the central wavelength is 800 nm. FIG. 35 is a diagram showing an ideal optical phase delay distribution when the central wavelength is 1000 nm. Note that in FIG. 32 to FIG. 35, the central positions of the four solar cell 110-1 to 110-4 (unit U1-1) correspond to x=0, y=0.

 設計例のパラメータは、以下である。
太陽電池セルの大きさ:15mm×15mm
焦点距離:15mm
各波長帯域の中心波長:波長帯域B:500nm、波長帯域B:650nm、波長帯域B:800nm、波長帯域B:1000nm
The parameters of the design example are as follows:
Solar cell size: 15mm x 15mm
Focal length: 15mm
Central wavelengths of each wavelength band: Wavelength band B1 : 500 nm, Wavelength band B2 : 650 nm, Wavelength band B3 : 800 nm, Wavelength band B4 : 1000 nm

 理想的な光位相遅延量分布をφとすると、φは以下の式(5)で表される。 If the ideal optical phase delay distribution is φ, then φ is expressed by the following equation (5).

Figure JPOXMLDOC01-appb-M000005
Figure JPOXMLDOC01-appb-M000005

 上記の式(5)において、λは、中心波長(設計波長)である。x、y及びzは、集光位置である。nは、下方の透明層130,140の屈折率である。Cは、任意定数である。 In the above equation (5), λ d is the central wavelength (design wavelength), x f , y f and z f are the focusing positions, n 2 is the refractive index of the lower transparent layers 130 and 140, and C is an arbitrary constant.

 図32~図35の理想的な光位相遅延量分布を達成するように、4つの太陽電池セル110-1~110-4の位置に合わせて、波長帯域B、波長帯域B、波長帯域B、波長帯域Bそれぞれに以下の集光位置を与える位相分布とした。なお、4つの太陽電池セル110-1~110-4(ユニットU1-1)の中心位置が、x=0、y=0に対応する。
波長帯域B:x=+7.5mm, y=-7.5mm, z=15mm
波長帯域B:x=+7.5mm, y=+7.5mm, z=15mm
波長帯域B:x=-7.5mm, y=-7.5mm, z=15mm
波長帯域B:x=-7.5mm, y=+7.5mm, z=15mm
32 to 35, a phase distribution was set that provides the following light collection positions for wavelength bands B1 , B2 , B3 , and B4 in accordance with the positions of the four solar cells 110-1 to 110-4. Note that the central positions of the four solar cells 110-1 to 110-4 (unit U1-1) correspond to x=0, y=0.
Wavelength band B1 : xf = +7.5 mm, yf = -7.5 mm, zf = 15 mm
Wavelength band B2 : xf = +7.5 mm, yf = +7.5 mm, zf = 15 mm
Wavelength band B3 : xf = -7.5 mm, yf = -7.5 mm, zf = 15 mm
Wavelength band B4 : xf = -7.5 mm, yf = +7.5 mm, zf = 15 mm

 φは、0~2πの範囲に収まるように変換している。例えば、-0.5π及び2.5πは、1.5π及び0.5πにそれぞれに変換している。各中心波長におけるレンズの位相分布が集光位置を中心に(隣接レンズとあわせて)左右上下対称となるように位相分布の境界領域を設定した。定数Cは、各波長において、位相分布のエラーが最小になるようそれぞれ最適化してよい。 φ is converted to fall within the range of 0 to 2π. For example, -0.5π and 2.5π are converted to 1.5π and 0.5π, respectively. The boundary region of the phase distribution is set so that the phase distribution of the lens at each central wavelength is symmetrical (together with adjacent lenses) in the left and right directions and up and down around the focusing position. The constant C may be optimized for each wavelength so that the error in the phase distribution is minimized.

 そして、組成構造が有する各波長における光位相遅延量から、上記4波長の位相分布に最も適合する構造、すなわち、位相エラーが最小になる構造の構造体150を、位置毎に選んで配置すればよい。なお、この場合、各セル上の構造パターンは、波長帯域分割数と位相分布の対象性から、2回回転対称となる。 Then, from the amount of optical phase delay at each wavelength that the composition structure has, the structure that best matches the phase distribution of the above four wavelengths, i.e., the structure 150 with the smallest phase error, can be selected and placed for each position. In this case, the structural pattern on each cell has two-fold rotational symmetry due to the number of wavelength band divisions and the symmetry of the phase distribution.

[波長分離レンズの設計例2]
 次に、波長分離レンズの他の設計例について説明する。本例では、例えば、図10及び図11に示す第2の構成例の太陽電池モジュール100-2の波長分離レンズ120-2を想定する。波長分離レンズ120-2の波長帯域分割数は3である。なお、その他の波長分割数に対しても、以下と同様の設計を適用できる。
[Design example 2 of wavelength separation lens]
Next, another design example of the wavelength separation lens will be described. In this example, for example, the wavelength separation lens 120-2 of the solar cell module 100-2 of the second configuration example shown in Figures 10 and 11 is assumed. The number of wavelength band divisions of the wavelength separation lens 120-2 is 3. Note that the same design as below can be applied to other wavelength division numbers.

 レンズ設計では、理想的な光位相遅延量分布(位相分布)を実現するように、構造体150の断面形状及び配置を設計する。以下に説明する例では、波長帯域毎に集光点が異なるレンズの位相分布を設計し、1層または複数層の柱状の構造体150で実現する。本例では、SiNで組成される構造体150を用いて、光位相遅延量の波長分散特性を利用することで、400nm~1200nmの各波長帯域の中心波長毎に異なる位相分布を設計し、波長分離レンズ120-2を実現した。 In lens design, the cross-sectional shape and arrangement of the structure 150 are designed to achieve an ideal optical phase delay distribution (phase distribution). In the example described below, a lens phase distribution with a different focal point for each wavelength band is designed and realized with a single or multiple layered columnar structure 150. In this example, a structure 150 composed of SiN is used, and by utilizing the wavelength dispersion characteristics of the optical phase delay, a different phase distribution is designed for each central wavelength of each wavelength band from 400 nm to 1200 nm, and wavelength separation lens 120-2 is realized.

 ユニットU1-2(太陽電池セル110-1~110-3)の理想的な光位相遅延量分布を示す。図36は、中心波長が500nmの場合の理想的な光位相遅延量分布を示す図である。図37は、中心波長が650nmの場合の理想的な光位相遅延量分布を示す図である。図38は、中心波長が1000nmの場合の理想的な光位相遅延量分布を示す図である。なお、図36~図38では、3つの太陽電池セル110-1~110-3(ユニットU1-2)の中心位置が、x=0、y=0に対応する。 The ideal optical phase delay distribution of unit U1-2 (solar cell 110-1 to 110-3) is shown. Figure 36 is a diagram showing the ideal optical phase delay distribution when the central wavelength is 500 nm. Figure 37 is a diagram showing the ideal optical phase delay distribution when the central wavelength is 650 nm. Figure 38 is a diagram showing the ideal optical phase delay distribution when the central wavelength is 1000 nm. Note that in Figures 36 to 38, the central positions of the three solar cell 110-1 to 110-3 (unit U1-2) correspond to x=0, y=0.

 設計例のパラメータは、以下である。
太陽電池セルの大きさ:15mm×15mm
焦点距離:30mm
各波長帯域の中心波長:波長帯域B:500nm、波長帯域B:650nm、波長帯域B:1000nm
The parameters of the design example are as follows:
Solar cell size: 15mm x 15mm
Focal length: 30mm
Central wavelengths of each wavelength band: Wavelength band B1 : 500 nm, Wavelength band B2 : 650 nm, Wavelength band B3 : 1000 nm

 理想的な光位相遅延量分布をφとすると、φは以下の式(6)で表される。 If the ideal optical phase delay distribution is φ, then φ is expressed by the following equation (6).

Figure JPOXMLDOC01-appb-M000006
Figure JPOXMLDOC01-appb-M000006

 上記の式(6)において、λは、中心波長(設計波長)である。x、y及びzは、集光位置である。nは、下方の透明層130,140の屈折率である。Cは、任意定数である。 In the above equation (6), λ d is the central wavelength (design wavelength), x f , y f and z f are the focusing positions, n 2 is the refractive index of the lower transparent layers 130 and 140, and C is an arbitrary constant.

 図36~図38の理想的な光位相遅延量分布を達成するように、3つの太陽電池セル110-1~110-3の位置に合わせて、波長帯域B、波長帯域B、波長帯域Bそれぞれに以下の集光位置を与える位相分布とした。なお、4つの太陽電池セル110-1~110-3(ユニットU1-2)の中心位置が、x=0、y=0に対応する。
波長帯域B:x=-15mm, y=0mm, z=30mm
波長帯域B:x=0mm, y=0mm, z=30mm
波長帯域B:x=+15mm, y=0mm, z=30mm
36 to 38, a phase distribution was set that provides the following light collection positions for wavelength bands B1 , B2 , and B3 in accordance with the positions of three solar cells 110-1 to 110-3. Note that the central positions of the four solar cells 110-1 to 110-3 (unit U1-2) correspond to x=0, y=0.
Wavelength band B 1 : x f = -15 mm, y f = 0 mm, z f = 30 mm
Wavelength band B2 : xf = 0 mm, yf = 0 mm, zf = 30 mm
Wavelength band B3 : xf = +15 mm, yf = 0 mm, zf = 30 mm

 φは、0~2πの範囲に収まるように変換している。例えば、-0.5π及び2.5πは、1.5π及び0.5πにそれぞれに変換している。各中心波長におけるレンズ位相分布が集光位置を中心に(隣接レンズとあわせて)左右上下対称となるように位相分布の境界領域を設定した。定数Cは、各波長において、位相分布のエラーが最小になるようそれぞれ最適化してよい。 φ is converted to fall within the range of 0 to 2π. For example, -0.5π and 2.5π are converted to 1.5π and 0.5π, respectively. The boundary region of the phase distribution is set so that the lens phase distribution at each central wavelength is symmetrical (together with adjacent lenses) in the left and right directions and up and down around the focusing position. The constant C may be optimized for each wavelength so that the error in the phase distribution is minimized.

 そして、組成構造が有する各波長における位相遅延量から、上記3波長の位相分布に最も適合する構造、すなわち、位相エラーが最小になる構造の構造体150を、位置毎に選んで配置すればよい。なお、この場合、各セル上の構造パターンは、波長帯域分割数と位相分布の対象性とから、上下対称となる。 Then, from the amount of phase delay at each wavelength that the composition structure has, the structure that best matches the phase distribution of the above three wavelengths, i.e., the structure 150 with the smallest phase error, can be selected and placed for each position. In this case, the structural pattern on each cell is vertically symmetrical due to the number of wavelength band divisions and the symmetry of the phase distribution.

[実施の形態の効果]
 従来の太陽電池セルについて説明する。図39は、従来の太陽電池モジュールの要部の断面の一例を模式的に示す図である。図39では、単一材料(例:Si)のみを用いた光電変換部を有する太陽電池モジュールを示す。図40は、図39に示す太陽電池モジュールが放射/吸収する光強度の波長依存性を模式的に示す図である。図40の曲線C1は、太陽光のスペクトルを示す。
[Effects of the embodiment]
A conventional solar cell will be described. Fig. 39 is a diagram showing a schematic example of a cross section of a main part of a conventional solar cell module. Fig. 39 shows a solar cell module having a photoelectric conversion part using only a single material (e.g., Si). Fig. 40 is a diagram showing a schematic diagram of the wavelength dependency of the light intensity radiated/absorbed by the solar cell module shown in Fig. 39. Curve C1 in Fig. 40 shows the spectrum of sunlight.

 図40に示すように、単一材料のみを用いた光電変換部を有する太陽電池モジュールは、材料のバンドギャップ由来の光吸収スペクトルにより、入射する太陽光の一部の波長の光が光電変換されるのみであるため(領域R11参照)、モジュールの効率が制限されていた。 As shown in Figure 40, in a solar cell module having a photoelectric conversion section using only a single material, the efficiency of the module is limited because only a portion of the wavelengths of incident sunlight are photoelectrically converted due to the light absorption spectrum resulting from the band gap of the material (see region R11).

 図41は、従来の太陽電池モジュールの要部の断面の他の例を模式的に示す図である。図41では、バンドギャップの異なる複数の材料を積み重ねた多接合型化合物半導体を用いた光電変換部を有するタンデム太陽電池モジュールを示す。図42は、図41に示す太陽電池モジュールが放射/吸収する光強度の波長依存性を模式的に示す図である。図42の曲線C1は、太陽光のスペクトルを示す。 Figure 41 is a diagram that shows a schematic diagram of another example of a cross section of a main part of a conventional solar cell module. Figure 41 shows a tandem solar cell module having a photoelectric conversion section that uses a multi-junction compound semiconductor in which multiple materials with different bandgaps are stacked. Figure 42 is a diagram that shows a schematic diagram of the wavelength dependence of the light intensity radiated/absorbed by the solar cell module shown in Figure 41. Curve C1 in Figure 42 shows the spectrum of sunlight.

 図42に示すように、タンデム太陽電池モジュールでは、入射する太陽光のほぼ全ての波長の光を吸収・光電変換できるものの(領域R21~R23参照)、領域R23のように、長波長帯域の光の吸収率は低く、光電変換効率の向上には限界があった。また、タンデム太陽電池では、多接合型化合物半導体として接合可能な材料は限られている上、作製の難易度も高かった。 As shown in Figure 42, a tandem solar cell module can absorb and photoelectrically convert almost all wavelengths of incident sunlight (see regions R21 to R23), but the absorption rate of light in the long wavelength band, as in region R23, is low, and there is a limit to how much the photoelectric conversion efficiency can be improved. In addition, with tandem solar cells, the materials that can be bonded as multi-junction compound semiconductors are limited, and they are difficult to fabricate.

 図43は、図2に示す太陽電池モジュール100が放射/吸収する光強度の波長依存性を模式的に示す図である。図43に示すように、実施の形態に係る太陽電池モジュール100は、入射する太陽光のほぼ全ての波長の光を吸収・光電変換することができる(領域R1~R3参照)。さらに、太陽電池モジュール100は、タンデム太陽電池モジュールよりも、材料の制約が少ない分、光電変換効率が向上できる見込みがある。例えば、太陽電池モジュール100は、タンデム型太陽電池モジュールでは使用が困難だったものの長波長での吸収特性がよりよい材料を光電変換部に選択できる場合もあり、この場合には、領域R23に示すように、タンデム太陽電池モジュールよりも、長波長帯域光の吸収率も高く、高い光電変換効率を実現できると考えられる。 Figure 43 is a diagram showing the wavelength dependency of the light intensity radiated/absorbed by the solar cell module 100 shown in Figure 2. As shown in Figure 43, the solar cell module 100 according to the embodiment can absorb and photoelectrically convert almost all wavelengths of incident sunlight (see regions R1 to R3). Furthermore, the solar cell module 100 is expected to have improved photoelectric conversion efficiency because it has fewer material constraints than a tandem solar cell module. For example, the solar cell module 100 may be able to select a material for the photoelectric conversion section that has better absorption characteristics at long wavelengths, even though it is difficult to use this material in a tandem solar cell module. In this case, as shown in region R23, it is believed that the absorption rate of long wavelength band light is also higher than that of a tandem solar cell module, and high photoelectric conversion efficiency can be achieved.

 これは、波長分離レンズ120が、入射光のすべてを波長帯域毎に分離しながら、各波長帯域に対応する各太陽電池セル110-1~110-3へ集光することから、太陽光のスペクトルの広域に渡って吸収効率を増大できるためである。このため、太陽電池モジュール100は、従来の単一材料からなる光電変換部を有する太陽電池モジュールやタンデム太陽電池モジュールと比して、総光電変換量を増加させることが可能である。 This is because the wavelength separation lens 120 separates all of the incident light into wavelength bands while concentrating the light onto each of the solar cell cells 110-1 to 110-3 corresponding to each wavelength band, thereby increasing the absorption efficiency over a wide range of the sunlight spectrum. Therefore, the solar cell module 100 can increase the total photoelectric conversion amount compared to solar cell modules and tandem solar cell modules that have conventional photoelectric conversion parts made of a single material.

 また、太陽電池モジュール100では、各太陽電池セル110は、それぞれ各波長帯域に適合した単一材料を用いた光電変換部でよい。このため、太陽電池モジュール100によれば、タンデム太陽電池で互いに接合が困難だった材料からそれぞれ構成される太陽電池セル110を同時に使用でき、より効率的に太陽光を吸収及び光電変換できる材料を光電変換部に用いることで光電変換効率を最大化することが期待できる。 Furthermore, in the solar cell module 100, each solar cell 110 may have a photoelectric conversion section using a single material suited to each wavelength band. Therefore, with the solar cell module 100, solar cells 110 each made of materials that would be difficult to join together in a tandem solar cell can be used simultaneously, and it is expected that the photoelectric conversion efficiency can be maximized by using a material that can more efficiently absorb and convert sunlight into electricity in the photoelectric conversion section.

 また、太陽電池モジュール100では、各太陽電池セル110が、それぞれ各波長帯域に適合した単一材料を用いた光電変換部でよいため、タンデム太陽電池と比して、作製難易度を大幅に下げることができ、作製コスト低減につながる。 In addition, in the solar cell module 100, each solar cell 110 can be a photoelectric conversion unit using a single material that is suitable for each wavelength band, making it much easier to fabricate than a tandem solar cell, leading to reduced manufacturing costs.

 また、太陽電池モジュール100は、波長分離レンズ120の構造体150が複数層構造である場合、構造体150が単層構造である場合と比して、設計パラメータを層の増加分増やすことができ、これによって光制御制が増すため、より高効率な波長帯域分離を実現できる。 In addition, when the structure 150 of the wavelength separation lens 120 of the solar cell module 100 has a multi-layer structure, the design parameters can be increased by the amount of the increase in layers compared to when the structure 150 has a single-layer structure, which increases the light control and allows for more efficient wavelength band separation.

 太陽電池モジュール100において、分離する波長帯域の数に限定はなく、複数であれば効果を実現できる。また、太陽電池モジュール100では、同じ波長帯域の光を複数の太陽電池セル110に集光してもよいため、設計の自由度が高い。 In the solar cell module 100, there is no limit to the number of wavelength bands that can be separated, and the effect can be achieved as long as there are multiple bands. In addition, in the solar cell module 100, light of the same wavelength band may be concentrated on multiple solar cell cells 110, allowing for a high degree of freedom in design.

 図1等を参照して説明した変換装置10も、本開示の一態様である。実施の形態に係る変換装置10は、上述の太陽電池モジュール100を有するため、従来と比して、光電変換効率が向上するとともに、作製コストの低減を図ることができる。 The conversion device 10 described with reference to FIG. 1 etc. is also one aspect of the present disclosure. The conversion device 10 according to the embodiment has the solar cell module 100 described above, and therefore has improved photoelectric conversion efficiency and reduced manufacturing costs compared to the conventional technology.

 1,100,100-1,100-2 太陽電池モジュール
 2 電力変換部
 3 二次電池
 10 変換装置
 110,110-1~110-4 太陽電池セル
 120,120-1,120-2 波長分離レンズ
 130,140 透明層
 150,150-1~150-3 構造体
 160-1~160-4 p型半導体層
 170-1~170-4 n型半導体層
 180 反射防止層
 190 表面電極
 200 裏面電極
LIST OF SYMBOLS 1, 100, 100-1, 100-2 Solar cell module 2 Power conversion section 3 Secondary battery 10 Conversion device 110, 110-1 to 110-4 Solar cell 120, 120-1, 120-2 Wavelength separation lens 130, 140 Transparent layer 150, 150-1 to 150-3 Structure 160-1 to 160-4 P-type semiconductor layer 170-1 to 170-4 N-type semiconductor layer 180 Anti-reflection layer 190 Surface electrode 200 Back electrode

Claims (5)

 各々が、それぞれ設定された所定の波長帯域の光を吸収して電気に変換する複数の太陽電池セルと、
 前記複数の太陽電池セルを覆う透明層と、前記透明層上または前記透明層内において、前記透明層の面方向に、入射光の波長以下の周期で配置された複数の構造体であって、前記入射光を、各所定の波長帯域ごとに分離して、各波長帯域に対応する前記太陽電池セルにそれぞれ集光するように配置される複数の構造体と、を有する光学素子と、
 を有することを特徴とする太陽電池モジュール。
A plurality of solar cells, each of which absorbs light in a respective predetermined wavelength band and converts it into electricity;
an optical element including: a transparent layer covering the plurality of solar cells; and a plurality of structures arranged on or within the transparent layer in a plane direction of the transparent layer at a period equal to or shorter than the wavelength of incident light, the plurality of structures being arranged so as to separate the incident light into each of predetermined wavelength bands and concentrate the light on the solar cells corresponding to each wavelength band;
A solar cell module comprising:
 前記複数の構造体の各々は、前記透明層の屈折率よりも高い屈折率を有し、入射した光に対して前記透明層を平面視したときの断面形状に応じた光位相遅延量を与える柱状構造体であり、
 前記複数の構造体は、前記集光を実現するための光位相量遅延分布に従って断面形状が設定され、前記集光を実現するための光位相量遅延分布に従って配置されることを特徴とする請求項1に記載の太陽電池モジュール。
each of the plurality of structures is a columnar structure having a refractive index higher than a refractive index of the transparent layer and imparting an optical phase delay amount to incident light according to a cross-sectional shape of the transparent layer when viewed in a plan view;
The solar cell module according to claim 1 , wherein the plurality of structures have cross-sectional shapes set according to an optical phase delay distribution for achieving the light concentration, and are arranged according to the optical phase delay distribution for achieving the light concentration.
 前記複数の構造体の各々の断面形状は、4回回転対称形状であることを特徴とする請求項1に記載の太陽電池モジュール。 The solar cell module according to claim 1, characterized in that the cross-sectional shape of each of the plurality of structures is a four-fold rotationally symmetric shape.  前記複数の構造体は、前記透明層上または前記透明層内において、前記透明層の積層方向に沿って、複数層形成されることを特徴とする請求項1に記載の太陽電池モジュール。 The solar cell module according to claim 1, characterized in that the multiple structures are formed in multiple layers on or within the transparent layer along the stacking direction of the transparent layer.  請求項1~4のいずれか一つに記載の太陽電池モジュールと、
 電力を蓄積する二次電池と、
 前記太陽電池モジュールからの入力電圧を昇圧して前記二次電池に供給する電力変換部と、
 を有することを特徴とする変換装置。
A solar cell module according to any one of claims 1 to 4,
A secondary battery that stores power;
a power conversion unit that boosts an input voltage from the solar cell module and supplies the boosted voltage to the secondary battery;
A conversion device comprising:
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