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WO2024023568A1 - Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique - Google Patents

Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique Download PDF

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Publication number
WO2024023568A1
WO2024023568A1 PCT/IB2022/057047 IB2022057047W WO2024023568A1 WO 2024023568 A1 WO2024023568 A1 WO 2024023568A1 IB 2022057047 W IB2022057047 W IB 2022057047W WO 2024023568 A1 WO2024023568 A1 WO 2024023568A1
Authority
WO
WIPO (PCT)
Prior art keywords
pig iron
product
dri
scrap
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2022/057047
Other languages
English (en)
Inventor
Mathieu Sanchez
Jean-Christophe HUBER
Simon Pierre DEPLECHIN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ArcelorMittal SA
Original Assignee
ArcelorMittal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to PCT/IB2022/057047 priority Critical patent/WO2024023568A1/fr
Priority to AU2022471657A priority patent/AU2022471657A1/en
Priority to JP2025501801A priority patent/JP2025524807A/ja
Priority to MA71591A priority patent/MA71591A/fr
Priority to EP22754937.5A priority patent/EP4562198A1/fr
Priority to KR1020257001106A priority patent/KR20250024061A/ko
Application filed by ArcelorMittal SA filed Critical ArcelorMittal SA
Priority to CN202280097513.1A priority patent/CN119452105A/zh
Priority to CA3256513A priority patent/CA3256513A1/fr
Publication of WO2024023568A1 publication Critical patent/WO2024023568A1/fr
Priority to MX2025001163A priority patent/MX2025001163A/es
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B11/00—Making pig-iron other than in blast furnaces
    • C21B11/10—Making pig-iron other than in blast furnaces in electric furnaces
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/0073—Selection or treatment of the reducing gases
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/0086—Conditioning, transformation of reduced iron ores
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/12—Making spongy iron or liquid steel, by direct processes in electric furnaces
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/14—Multi-stage processes processes carried out in different vessels or furnaces
    • C21B13/143—Injection of partially reduced ore into a molten bath
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B3/00—General features in the manufacture of pig-iron
    • C21B3/04—Recovery of by-products, e.g. slag
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2200/00—Recycling of non-gaseous waste material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Definitions

  • the invention is related to a method of manufacturing pig iron, also called hot metal and to a method of producing steel out of such pig iron.
  • BF-BOF route consists in producing hot metal in a blast furnace, by use of a reducing agent, mainly coke, to reduce iron oxides and then transform hot metal into steel into a converter process or Basic Oxygen furnace (BOF).
  • a reducing agent mainly coke
  • BOF Basic Oxygen furnace
  • the second main route involves so-called “direct reduction methods”.
  • direct reduction methods are methods according to the brands MIDREX®, FINMET®, ENERGIRON®/HYL, COREX®, FINEX® etc., in which sponge iron is produced in the form of HDRI (hot direct reduced iron), CDRI (cold direct reduced iron), or HBI (hot briquetted iron) from the direct reduction of iron oxide carriers.
  • Sponge iron in the form of HDRI, CDRI, and HBI undergoes further processing in electric furnaces to produce steel.
  • the aim of the present invention is therefore to remedy the drawbacks of the pig iron and steelmaking manufacturing routes by providing a new route efficiently minimizing the environmental impact of such manufacturing without incurring heavy investments. [006] This problem is solved by a method for manufacturing pig iron as detailed in claim 1.
  • Such method may also comprise the optional characteristics of claims 2 to 7 considered separately or in any possible technical combinations.
  • the invention also deals with a method for manufacturing steel according to claim 8.
  • Such method may also comprise the optional characteristics of claim 9.
  • Figure 1 illustrates a pig iron and steelmaking process according to the smelting I BOF route
  • Figure 2 illustrates a smelting furnace
  • Figure 1 illustrates a steel production route according to the DRI route, from the reduction of iron to the casting of the steel into semi-products such as slabs, billets, blooms, or strips.
  • Iron ore 10 is first reduced in a direct reduction plant 11 .
  • This direct reduction plant 11 may be designed to implement any kind of direct reduction technology such as MIDREX® technology or Energiron®.
  • the direct reduction process may for example be a traditional natural-gas or a biogas-based process.
  • the DRI product used in the method according to the invention is manufactured using a reducing gas based on biogas coming from combustion of biomass.
  • Biomass is renewable organic material that comes from plants and animals.
  • Biomass sources include notably wood and wood processing wastes such as firewood, wood pellets, and wood chips, lumber and furniture mill sawdust and waste, and black liquor from pulp and paper mills, agricultural crops and waste materials such as corn, soybeans, sugar cane, switchgrass, woody plants, and algae, and crop and food processing residues, but also biogenic materials in municipal solid waste such as paper, cotton, and wool products, and food, yard, and wood wastes, animal manure and human sewage.
  • biomass may also encompass plastics residues, such as recycled waste plastics like Solid Refuse Fuels or SRF.
  • the carbon content of the DRI product can be set to a maximum of 3 % in weight and usually to a range of 2 to 3% in weight.
  • the DRI product used in the method according to the invention is manufactured through a so called H2-DRI process where the reducing gas comprises more than 50 % and preferably more than 60, 70, 80 or 90 % in volume of hydrogen or is even entirely made of hydrogen.
  • the H2- DRI product will contain a far lower level of carbon than the natural gas or biogas DRI, so typically below 1 % in weight or even lower.
  • the hydrogen used in the DRI reducing gas comes from the electrolysis of water, which is preferably powered in part or all by CO2 neutral electricity.
  • CO2 neutral electricity includes notably electricity from renewable source which is defined as energy that is collected from renewable resources, which are naturally replenished on a human timescale, including sources like sunlight, wind, rain, tides, waves, and geothermal heat.
  • renewable source which is defined as energy that is collected from renewable resources, which are naturally replenished on a human timescale, including sources like sunlight, wind, rain, tides, waves, and geothermal heat.
  • the use of electricity coming from nuclear sources can be used as it is not emitting CO2 to be produced.
  • the resulting Direct Reduced Iron (DRI) Product 12 is then charged into a smelting furnace 13 where the reduction of iron oxide is completed, and the product is melted to produce pig iron.
  • the DRI product can be transferred to the smelting furnace in various forms.
  • the directly reduced iron product (DRI product) is fed to the smelting furnace in a hot form as HDRI product (so-called Hot DRI), or in a cold form as CDRI product (so-called Cold DRI), or in hot briquette form as HBI product (so-called Hot Briquetted Iron) and/or in particulate form, preferably with an average particle diameter of at most 10.0 mm, more preferably with an average particle diameter of at most 5.0 mm.
  • It is preferably charged directly at the exit of the direct reduction plant 11 as a hot product with a temperature from 500°C to 700°C. This allows reducing the amount of energy needed to melt it.
  • hot charging is not possible, for example if the direct reduction plant 11 and the smelting furnace 13 are not on same location, or if the smelting furnace 13 is stopped for maintenance and thus DRI product must be stored, then the DRI product may be charged cold, or a preheating step may be performed.
  • the smelting furnace 13 uses electric energy provided by several electrodes to melt the DRI product 12 and produce a pig iron 14. In a preferred embodiment, part of or all the electricity needed comes from CO2 neutral electricity. Further detailed description of the smelting furnace will be given later, based on figure 2.
  • the pig iron 14 can be optionally sent to a desulphurization station 15 to perform a desulphurization step.
  • This desulphurization step may be performed in a dedicated vessel or preferentially directly in the pig iron ladle to avoid molten metal transfer and associated heat losses.
  • This desulphurization step is needed for production of steel grades requiring a low Sulphur content, which is, for example set at a maximum of 0.03 weight percent of Sulphur.
  • Desulfurization in oxidizing conditions is not effective and is thus preferentially performed either on pig iron before oxygen refining, or in steel ladle after steel deoxidizing. For very low sulfur contents, for example below 0.004 weight percent of sulfur, deoxidizing and desulphurization are combined for overall higher performance. Low sulfur grades thus benefit from performing pig iron desulfurization before the conversion step.
  • Desulphurization of the pig iron can be done by adding reagents, notably based on calcium or magnesium compounds, such as sodium carbonate, lime, calcium carbide, and/or magnesium into the pig iron. It may be done for example by injection of those reagents in the pig iron ladle.
  • the desulphurized pig iron 16 has preferentially a content of Sulphur lower than 0.03 % in weight and preferably lower than 0.004 % in weight.
  • the desulphurized pig iron 16 can then be transferred into a converter 17.
  • the converter basically turns the molten metal into liquid steel by blowing oxygen through molten metal to decarburize it. It is commonly named Basic Oxygen Furnace (BOF). Ferrous scraps 18, coming from recycling of steel, may also be charged into the converter 17 to take benefit of the heat released by the exothermic reactions resulting from the oxygen injection into pig iron.
  • BOF Basic Oxygen Furnace
  • Liquid steel 19 thus formed can then be transferred, whenever needed, to one or more secondary metallurgy tools 20A, 20B such as Ladle furnaces, RH (Ruhrstahl-Heareus) vacuum vessel, Vacuum Tank degasser, alloying and stirring stations, etc.... to be treated to reach the required steel composition according to the steel grades to be produced.
  • Liquid steel with the required composition 21 can then be transferred to a casting plant 22 where it can be turned into solid products, such as slabs, billets, blooms, or strips.
  • the smelting furnace 13 is composed of a vessel 20 able to contain hot metal.
  • the vessel 20 may have a circular or a rectangular shape, for example.
  • This vessel 20 is closed by a roof provided with some apertures to receive electrodes 22 to be inserted into the vessel 20 and with other apertures to allow charging of the raw materials into the vessel 20.
  • the smelting furnace 13 may be for example an open-slag bath furnace or OSBF.
  • the vessel 20 is also provided with at least one tap hole 25 to allow tapping of manufactured pig iron.
  • tap holes 25 are located in the lower part of the vessel 20. They may be located in the lateral walls of the vessel or in its bottom wall.
  • the electrodes 22 provide the required electric energy to melt the charged raw materials and form pig iron. They are preferably Soderberg-type electrodes.
  • a pig iron 14 layer which is the densest and is thus located at the bottom of the vessel 20 and a slag layer 23 located above the pig iron 14.
  • the slag layer 23 can be partially covered by piles of raw materials 24 waiting to be melted.
  • the smelting furnace 13 may be a SAF (Submerged-Arc Furnace) wherein the electrodes are immersed into the slag layer 23 or an OSBF (open-slag bath furnace) wherein the electrodes 22 are located above the slag layer 23. It is preferentially an OSBF as illustrated in the figures.
  • SAF Submerged-Arc Furnace
  • OSBF open-slag bath furnace
  • Another advantage is that thanks to the reducing conditions within the smelting furnace 13, oxidized iron present on scrap is reduced in the furnace and thus lower quality scrap may be used without specific pre-treatment besides size reduction.
  • the mass fraction of ferrous scrap is from 1 % to 20% by weight, based on the amount of DRI products fed in.
  • charged scrap is E40 specification scrap according to Ell-27 steel scrap specification, last update of May 2007.
  • a carbon-containing material is also added to the smelting furnace. Reaction of carbon with oxygen in the converter creates carbon monoxide gas, which provides intense and efficient stirring of the molten metal and thus improves the removal of impurities from the steel. This reaction is also exothermic and therefore provides additional energy for scrap melting. The more scrap is used, the smaller the environmental footprint of the process.
  • the carbon content of the pig iron 14 produced through the DRI route will generally be lower than 3 % in weight. However, to fulfil the requirements of the subsequent steelmaking process at the converter, the pig iron should preferentially have a carbon content as close as possible to 4.5% in weight, which is the level of saturation. In a preferred embodiment, the pig iron carbon content is set in the range of 4.0 to 4.5% in weight through the addition of carbon containing material.
  • the carbon containing material may come from different sources. It may be chosen, for example, among coke, anthracite, silicon carbide, calcium carbide, or a mixture of any of those sources, but can also advantageously come from renewable sources like biomass for part or all the carbon loads. In particular, biochar can be used. Adding calcium carbide is particularly advantageous as the calcium atoms can provide a desulphurizing effect.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Manufacture Of Iron (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

L'invention porte sur un procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique. Le procédé comprend les étapes successives suivantes consistant à : - fournir un produit de fer directement réduit (DRI) 12, - introduire le produit de DRI 12 dans l'unité de fusion 13, - introduire, conjointement avec le produit de DRI 13, des déchets ferreux ayant une taille inférieure à 80 mm, - faire fondre le produit de DRI (13) et les déchets ferreux pour produire de la fonte brute en fusion. L'invention porte également sur un procédé pour produire de l'acier liquide à partir de fonte brute fabriquée.
PCT/IB2022/057047 2022-07-29 2022-07-29 Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique Ceased WO2024023568A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
AU2022471657A AU2022471657A1 (en) 2022-07-29 2022-07-29 A method of manufacturing molten pig iron into an electrical smelting unit
JP2025501801A JP2025524807A (ja) 2022-07-29 2022-07-29 電気製錬ユニット内で溶銑鉄を製造するための方法
MA71591A MA71591A (fr) 2022-07-29 2022-07-29 Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique
EP22754937.5A EP4562198A1 (fr) 2022-07-29 2022-07-29 Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique
KR1020257001106A KR20250024061A (ko) 2022-07-29 2022-07-29 전기 제련 유닛 내로 용융 선철을 제조하는 방법
PCT/IB2022/057047 WO2024023568A1 (fr) 2022-07-29 2022-07-29 Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique
CN202280097513.1A CN119452105A (zh) 2022-07-29 2022-07-29 在电熔炼单元中制造液态生铁的方法
CA3256513A CA3256513A1 (fr) 2022-07-29 2022-07-29 Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique
MX2025001163A MX2025001163A (es) 2022-07-29 2025-01-28 Un metodo de fabricacion de arrabio fundido en una unidad de fundicion electrico

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2022/057047 WO2024023568A1 (fr) 2022-07-29 2022-07-29 Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique

Publications (1)

Publication Number Publication Date
WO2024023568A1 true WO2024023568A1 (fr) 2024-02-01

Family

ID=82932422

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2022/057047 Ceased WO2024023568A1 (fr) 2022-07-29 2022-07-29 Procédé pour la fabrication de fonte brute en fusion dans une unité de fusion électrique

Country Status (9)

Country Link
EP (1) EP4562198A1 (fr)
JP (1) JP2025524807A (fr)
KR (1) KR20250024061A (fr)
CN (1) CN119452105A (fr)
AU (1) AU2022471657A1 (fr)
CA (1) CA3256513A1 (fr)
MA (1) MA71591A (fr)
MX (1) MX2025001163A (fr)
WO (1) WO2024023568A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025222249A1 (fr) * 2024-04-23 2025-10-30 Carbelec Pty Ltd Production de métal à haute température associée à la récupération de carbone par électrolyse de dioxyde de carbone en carbone solide

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5882374A (en) * 1995-05-01 1999-03-16 Alabama Power Company Process for producing foundry iron with an insulated electrode
US6648942B2 (en) * 2001-01-26 2003-11-18 Midrex International B.V. Rotterdam, Zurich Branch Method of direct iron-making / steel-making via gas or coal-based direct reduction and apparatus
WO2022023187A1 (fr) * 2020-07-28 2022-02-03 Paul Wurth S.A. Procédé d'exploitation d'une usine métallurgique pour la production de produits sidérurgiques

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI2895630T3 (en) * 2012-09-14 2023-08-15 Voestalpine Stahl Gmbh METHOD FOR STORING DISCONTINUOUSLY OBTAINED ENERGY IN IRON ORE REDUCTION PROCESS
EP3954786A1 (fr) * 2020-08-12 2022-02-16 ThyssenKrupp Steel Europe AG Procédé de fabrication d'acier brut et agrégat destiné à la fabrication de celui-ci

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5882374A (en) * 1995-05-01 1999-03-16 Alabama Power Company Process for producing foundry iron with an insulated electrode
US6648942B2 (en) * 2001-01-26 2003-11-18 Midrex International B.V. Rotterdam, Zurich Branch Method of direct iron-making / steel-making via gas or coal-based direct reduction and apparatus
WO2022023187A1 (fr) * 2020-07-28 2022-02-03 Paul Wurth S.A. Procédé d'exploitation d'une usine métallurgique pour la production de produits sidérurgiques

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025222249A1 (fr) * 2024-04-23 2025-10-30 Carbelec Pty Ltd Production de métal à haute température associée à la récupération de carbone par électrolyse de dioxyde de carbone en carbone solide

Also Published As

Publication number Publication date
MA71591A (fr) 2025-05-30
JP2025524807A (ja) 2025-08-01
CA3256513A1 (fr) 2024-02-01
CN119452105A (zh) 2025-02-14
MX2025001163A (es) 2025-03-07
KR20250024061A (ko) 2025-02-18
AU2022471657A1 (en) 2024-11-28
EP4562198A1 (fr) 2025-06-04

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