WO2024089072A1 - Detergent and/or cleaning compositions for malodor reduction and fragrance boost - Google Patents
Detergent and/or cleaning compositions for malodor reduction and fragrance boost Download PDFInfo
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- WO2024089072A1 WO2024089072A1 PCT/EP2023/079720 EP2023079720W WO2024089072A1 WO 2024089072 A1 WO2024089072 A1 WO 2024089072A1 EP 2023079720 W EP2023079720 W EP 2023079720W WO 2024089072 A1 WO2024089072 A1 WO 2024089072A1
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- alkanediol
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- heptanediol
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Definitions
- the present invention refers generally to the field of detergent and/or cleaning compositions used in the field of homecare.
- it relates to detergent and/or cleaning compositions comprising specific combinations of hydroxyl compounds and having an improved fragrance performance as well as improved malodor reduction/coverage/masking properties.
- the present invention relates to detergent and/or cleaning compositions that comprise a surfactant, an odorous substance, an effective amount of a mixture of 1 ,2-heptanediol and/or 2,3-heptanediol or at least one other alkanediol having a carbon chain of 5 to 14 carbon atoms and glyceryl caprylate, 4-hydroxyacetophenone, and/or ethyl hexyl glycerin as fragrance boosters, and optionally an antimicrobial component, and the use of said detergent and/or cleaning compositions for the preparation of a detergent and/or cleaning preparation/product for household, institutional and industrial application.
- a surfactant an odorous substance
- the present invention relates to the use of a mixture of 1 ,2-heptanediol and/or 2,3- heptanediol or at least one other alkanediol having a carbon chain of 5 to 14 carbon atoms as defined herein with glyceryl caprylate, 4-hydroxyacetophenone, and/or ethyl hexyl glycerin for boosting the cleaning efficiency of a detergent and/or cleaning composition and/or boosting the olfactory properties of odorous substances and/or for boosting the adherence of odorous substances and/or for malodor reduction and/or for malodor coverage and/or for malodor prevention.
- the present invention relates to a method for boosting the cleaning efficiency of a detergent and/or cleaning composition and/or for boosting the olfactory properties of odorous substances and/or for boosting the adherence of odorous substances and/or for malodor reduction/coverage/prevention by adding an effective amount of a mixture of 1 ,2-heptanediol and/or 2,3-heptanediol or of other alkanediols having a carbon chain of 5 to 14 carbon atoms as defined herein with glyceryl caprylate, 4-hydroxyacetophenone, and/or ethyl hexyl glycerin as (fragrance) boosting agents to said (perfumed) detergent and/or cleaning composition.
- Detergent and/or cleaning compositions must remove a wide variety of stains and soils form different substrate types under a broad range of cleaning conditions.
- Detergents and cleaning compositions in particular for laundry and textile cleaning, dishwashing and the like are composed predominantly of surfactants or a mixture of surfactants, whose main task is to remove water-insoluble substances like dirt and grease from surfaces such as fabric, clothes, dishes, wares, etc., and hard surfaces such as metals, plastics, glass, ceramics, etc.
- surfactants modern detergent and/or cleaning formulations consist of builders, chelating agents, co-builders and other polymer additives used for specific washing or cleaning effects such as soil release and anti-redeposition, dye transfer inhibition and rheology modification.
- one or more bleaching agents as a further active substance are usually added to the detergents and cleaning compositions.
- many consumer products such as detergents, fabric softeners, washing powders, liquid detergents, shower gels, shampoos, deodorants, lotions, etc. are perfumed with fragrance materials or contain cosmetic ingredients to deliver a specific effect.
- the detergent and/or cleaning composition should amongst others provide for a fresh scent in order to not only visually but also olfactory perceive the freshness and cleanness after cleaning or washing.
- the detergent and/or cleaning compositions should also provide for an efficient malodor coverage / masking or removal, i.e.
- the cleaned item should smell fresh and clean without malodors adhered to the item or alternatively impart a certain desirable fragrance or a sensation of freshness. This sensation of cleanness or freshness is particularly desired for example for laundry detergents, toilet cleaners and the like.
- homecare products such as laundry detergents (in powdered or liquid form), fabric conditioner, dishwashing detergents, floor and surface cleaners, glass cleaners, air freshers and the like should be able to efficiently reduce the malodor or unpleasant smell such as from human sweats or from animal sweats on home furnishings and textiles such as pillows, sofa covers etc., clothes, carpets, and the like. Additionally, an efficient detergent and/or cleaning composition should prevent the formation of malodor.
- Substrates treated with the detergent and/or cleaning compositions according to the present invention show a considerably increased fragrance impression with prolonged adhesion compared to formulations not comprising the mixtures containing 1 ,2-heptanediol or 2,3-heptanediol or a mixture comprising 1 ,2-heptanediol and 2,3-heptanediol or of the at least one alkanediol as specified herein with glyceryl caprylate, 4-hydroxyacetophenone, and/or ethyl hexyl glycerin as fragrance boosters.
- mixtures of alkanediols with glyceryl caprylate, 4- hydroxyacetophenone, and/or ethyl hexyl glycerin show excellent fragrance boosting properties, i.e. the intensity and the adherence of the fragrances contained in the detergent and/or cleaning compositions is improved even when using small amounts of the fragrance component without requiring the addition of fixatives and the like thereby reducing the overall amount of ingredients in the final formulation and reducing the allergic potential and environmental impact of the final product formulation.
- compositions disclosed herein can efficiently reduce malodor or at least efficiently cover malodor. Moreover, it was surprisingly found that the compositions disclosed herein can efficiently prevent the formation of malodor.
- the fragrance boosting component simultaneously improves the cleaning performance so that in total less ingredients are required in order to provide for an efficient detergent and/or cleaning formulation providing for a clean and fresh result and impression.
- the perfumed detergent and/or cleaning compositions which contain a fragrance component in combination with 1 ,2-heptanediol or 2,3-heptanediol or a mixture comprising 1 ,2-heptanediol and 2,3-heptanediol or at least one alkanediol having a carbon chain of 5 to 14 carbon atoms, or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol in combination with glyceryl caprylate, 4-hydroxyacetophenone, and/or ethyl hexyl glyceryl, as defined herein, provide for an improved overall performance in terms of cleaning and scent impression over detergent and/or cleaning compositions without such a fragrance boosting composition.
- the present invention was made in view of the disadvantages described above. To solve the above-mentioned drawbacks, the present invention provides a detergent and/or cleaning composition, that noticeably minimizes or removes malodor or prevents the formation of malodor and simultaneously shows an intense and long-lasting odor performance along with an improved cleaning performance.
- the present invention thus provides in an aspect a detergent and/or cleaning composition, comprising or consisting of:
- (c1.2) at least one (fragrance) boosting agent selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, ethyl hexyl glycerin, and any mixtures thereof; and
- (d3) optionally at least one antimicrobial compound, preferably for boosting the cleaning efficiency of a detergent and/or cleaning composition and/or for boosting the olfactory properties of odorous substances and/or for boosting the adherence of odorous substances and/or for malodor reduction and/or for malodor coverage and/or for malodor prevention.
- the present invention provides a detergent and/or cleaning composition, comprising or consisting of:
- the at least one linear alkanediol, the at least one first linear alkanediol and/or the one or more second linear alkanediol have a carbon chain length of 7 to 14 carbon atoms, and further preferred a carbon chain length from 7 to 12 carbon atoms, more preferred a carbon chain length of 7 to 10 carbon atoms, and most preferred a carbon chain length from 7 to 9 carbon atoms.
- these alkanediols particularly pronounced boosting effects were observed, especially in terms of fragrance boosting.
- the present invention provides for the use of the detergent and/or cleaning composition as a detergent and/or cleaning product, or for the preparation of a detergent and/or cleaning product.
- the present invention provides for a detergent and/or cleaning product as such comprising or consisting of the detergent and/or cleaning compositions according to the present invention.
- compositions according to the invention can efficiently be used for boosting the cleaning efficiency of a detergent and/or cleaning composition and/or for boosting the olfactory properties of odorous substances contained therein and/or for boosting the adherence of odorous substances and/or for malodor reduction and/or for malodor coverage and/or for malodor prevention.
- the present invention provides for the use of a mixture of 1 ,2- heptanediol or 2,3-heptanediol or a mixture comprising 1 ,2-heptanediol and 2,3-heptanediol or a mixture (c) comprising or consisting of
- At least one boosting agent selected from the group consisting of at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol; and at least one further boosting agent selected from the group consisting of
- the present invention relates to the use of a mixture (c) comprising or consisting of
- At least one boosting agent selected from the group consisting of at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol; and at least one further boosting agent selected from the group consisting of
- the at least one linear alkanediol, the at least one first linear alkanediol and/or the one or more second linear alkanediol have a carbon chain length of 7 to 14 carbon atoms, and further preferred a carbon chain length from 7 to 12 carbon atoms, more preferred a carbon chain length from 7 to 10 carbon atoms, and most preferred a carbon chain length from 7 to 9 carbon atoms.
- these alkanediols particularly pronounced boosting effects were observed, especially in terms of fragrance boosting.
- the present invention provides for a method of boosting or improving the cleaning efficiency of a detergent and/or cleaning composition and/or for boosting the olfactory properties of odorous substances and/or for boosting the adherence of odorous substances and/or for malodor reduction and/or for malodor prevention, comprising the steps of:
- At least one boosting agent selected from the group consisting of at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol; and at least one further boosting agent selected from the group consisting of
- the present invention provides for a method of boosting or improving the cleaning efficiency of a detergent and/or cleaning composition and/or for boosting the olfactory properties of odorous substances and/or for boosting the adherence of odorous substances and/or for malodor reduction and/or for malodor prevention, comprising the steps of:
- At least one boosting agent selected from the group consisting of at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol; and at least one further boosting agent selected from the group consisting of
- the at least one linear alkanediol, the at least one first linear alkanediol and/or the one or more second linear alkanediol have a carbon chain length of 7 to 14 carbon atoms, and further preferred a carbon chain length from 7 to 12 carbon atoms, more preferred a carbon chain length from 7 to 10 carbon atoms, and most preferred a carbon chain length from 7 to 9 carbon atoms.
- these alkanediols particularly pronounced boosting effects were observed, especially in terms of fragrance boosting.
- Numeric ranges recited within the specification and given in the form “x to y” include the values defining the range and include each integer within the defined range. When multiple preferred numeric ranges are specified in this format, all ranges created by combining the various endpoints are also included.
- the term “consisting of’ as used according to the present invention means that the total amount of components (a) to (c) (and (a) to (d) respectively) adds up to 100 % by weight, based on the total weight of the detergent and/or cleaning composition, and signifies that the subject matter is closed-ended and can only include the limitations that are expressly recited.
- the term “at least one ...” or “one or more ...” means that the detergent and/or cleaning composition according to the present invention can comprise either one or a mixture of two, three, four, five, six or even more different of the respective components following said term.
- alkyl refers to saturated hydrocarbons having one or more carbon atoms, including straight-chain alkyl groups (such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, etc.), cyclic alkyl groups (or cycloalkyl or alicyclic or carbocyclic groups) (such as cyclopropyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, etc.), branched-chain alkyl groups (such as isopropyl, tert-butyl,
- alkyl includes both unsubstituted alkyls and substituted alkyls.
- substituted alkyls refers to alkyl groups having substituents, replacing one or more hydrogens on one or more carbons of the hydrocarbon backbone.
- substituents may include, for example, alkenyl, alkynyl, halogen, hydroxyl, alkylcarbonyloxy, arylcarbonyloxy, alkoxycarbonyloxy, aryloxy, aryloxycarbonyloxy, carboxylate, alkylcarbonyl, arylcarbonyl, alkoxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylthiocarbonyl, alkoxyl, phosphate, phosphonate, cyano, amino, imino, sulfhydryl, alkylthio, arylthiol, thiocarboxylate, sulfates, alkylsulfinyl, sulfonates, nitro, etc.
- boosting in the context of the present invention means “improving”, “enhancing”, “increasing”.
- a “boosting agent” or a “boosting composition” is an agent or mixture of substances (composition) capable of “improving”, “enhancing”, “increasing” certain features or properties as defined herein, and in particular the fragrance performance in terms of fragrance intensity and/or fragrance adhesion of an odorous substance in a detergent and/or cleaning composition.
- the boosting agents as specified herein improve the cleaning properties and the malodor coverage/reduction/prevention properties of the detergent and/or cleaning compositions disclosed herein. Accordingly, the term “boosting” is not restricted to the fragrance boosting properties of the corresponding composition.
- fragrance refers to the reminiscence of a fragrance compound (odorous substance) on the substrate it is applied to (also referred to as fixation or tenacity).
- fixation also referred to as fixation or tenacity.
- fragment substance “fragrance compound”, “odorous substance” and “odorous compound” and the like are used synonymously.
- compositions according to the present invention are efficient detergent and/or cleaning compositions simultaneously showing improved fixation/tenacity allowing for long-lasting and intense fragrance impressions.
- the odor neutralizing agents function to interact with the malodors and chemically neutralize them.
- these neutralizing agents such as oxidizing agents such as oxygen bleaches, chlorine; chlorinated materials such as sodium hypochlorite, chlorine dioxide; potassium permanganate; reducing agents such as sodium bisulfite
- oxidizing agents such as oxygen bleaches, chlorine
- chlorinated materials such as sodium hypochlorite, chlorine dioxide
- potassium permanganate reducing agents such as sodium bisulfite
- the odor masking agents function to intentionally conceal odors by the addition of another. Odor masking has been accomplished by using perfumes, fragrances, colognes, etc.
- both the deodorizing agents and neutralizing agents might cause allergic reactions or interact with the other components of the final product.
- masking agents suppress the malodor by: (i) providing a more pleasing scent using large quantities of a fragrance; or (ii) providing a fragrance that blends with the malodor to provide a different and more desirable scent.
- a large amount of fragrance must be utilized, which in itself often proves to be offensive.
- the malodor is usually still detectable at the levels of masking fragrances that are reasonably tolerable. Additionally, high levels of odorous components are expensive and might cause allergic reactions.
- compositions disclosed herein are efficient in masking malodor (“malodor coverage”).
- malodor coverage In order to achieve an efficient coverage only low levels of odorous components are required based on the boosting effect of the (fragrance) boosting agents as specified herein.
- compositions disclosed herein are efficient in reducing malodor or even preventing the formation of malodor without requiring the addition of harmful or dangerous neutralizing agents. Accordingly, the compositions according to the present invention are not only able to cover or mask malodor but also efficiently prevent the formation of malodor.
- the present invention relates to a detergent and/or cleaning composition, comprising or consisting of:
- (c1 .2) at least one (fragrance) boosting agent selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, ethyl hexyl glycerin, and any mixtures thereof; and
- (d1) optionally at least one antimicrobial compound.
- the present invention relates in one aspect to a detergent and/or cleaning composition, comprising or consisting of:
- the present invention relates in one aspect to a detergent and/or cleaning composition, comprising or consisting of:
- (d3) optionally at least one antimicrobial compound.
- said composition is used for boosting or improving the cleaning efficiency of a detergent and/or cleaning composition and/or for boosting the olfactory properties of odorous substances and/or for boosting the adherence of odorous substances and/or for malodor reduction and/or for malodor coverage and/or for malodor prevention.
- the present invention relates to a detergent and/or cleaning composition, comprising or consisting of:
- the at least one linear alkanediol, the at least one first linear alkanediol and/or the one or more second linear alkanediol have a carbon chain length of 7 to 14 carbon atoms, and further preferred a carbon chain length from 7 to 12 carbon atoms, more preferred a carbon chain length from 7 to 10 carbon atoms, and most preferred a carbon chain length from 7 to 9 carbon atoms.
- these alkanediols particularly pronounced boosting effects were observed.
- the detergent and/or cleaning composition according to the present invention comprises a (first) boosting component (c) that is based on a boosting mixture (c) of at least one first alkanediol component ((first) boosting agent / component) as specified above and at least one further or second component (further or second boosting agent / component) selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, ethyl hexyl glycerin, or any mixture of these further boosting agents.
- a boosting component that is based on a boosting mixture (c) of at least one first alkanediol component ((first) boosting agent / component) as specified above and at least one further or second component (further or second boosting agent / component) selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, ethyl hexyl glycerin, or any mixture of these further boosting agents.
- detergent and/or cleaning composition as contemplated herein, is understood to mean all products that are suitable and commonly used for washing or cleaning.
- Detergent and/or cleaning compositions are composed predominantly of surfactants or a mixture of surfactants.
- the detergent and/or cleaning compositions normally consist of builders and chelating agents, co-builders and other polymeric additives used for specific effects such as anti-redeposition, dye transfer inhibition, or rheology modification.
- Detergent and/or cleaning compositions refer to compositions that find use in the removal of undesired compounds from items to be cleaned, such as textiles (such as fabrics, clothes), dishes, floors, hard surfaces (such as metals, plastics and ceramics).
- Detergents are the most commonly used cleaning compositions for textiles.
- the detergent and/or cleaning compositions may be used for household cleaning, institutional cleaning, and industrial cleaning.
- the detergent and/or cleaning compositions also include disinfectants that kill all vegetative cells including recognized pathogenic microorganisms.
- the detergent and/or cleaning compositions can be used by the detergent composition itself or by a detergent product or by a use solution thereof.
- the detergent and/or cleaning compositions according to the present invention are preferably used for removing stains and/or soils from textile, fabrics, laundry, dishes, ware, medical and dental instruments, hard surfaces, etc. while simultaneously boosting or improving the olfactory impression and/or for boosting the adherence of odorous substances and/or malodor reduction/coverage/prevention.
- the detergent and/or cleaning compositions according to the present invention provide for both improved cleaning performances and improved olfactory properties along with a reduction of malodor and/or malodor coverage and/or malodor prevention.
- cleaning and “washing” are used synonymously and refer to the reduction and/or removal of deposits, i.e. the removal of undesired compounds from items/substrates to be cleaned such as textiles and surfaces, on tableware/dishes and other kitchen utensils such as cutlery/silverware, pots, pans, bakeware and the like as well as other substrates.
- deposits might be formed by stains caused by sweat, grease, tea, chocolate, coffee, grass, red wine, grass/mud, fruit juice, blood, tomato puree, unused motor oil, salad dressing balsamic, cooked beef fat, French squez mustard, make-up, and the like, or by soils caused by grease, starch based soils such as rice, pasta, protein based soils such as egg yolk, mayonnaise, lipstick, starch based soils, and the like and other remaining on the corresponding surfaces. Deposits are thus any form of unwanted residues of impureness, of dirt, food, grease etc.
- substrate in the context of the present invention includes fabrics, textiles, laundry, dishes, ware, carpets, any hard surfaces (such as tiles, floors or furniture), medical and dental instruments, and the like which can be contaminated with stains and/or soils and can be treated by a washing or cleaning processes.
- the term “dish” or “ware” as used herein is intended to mean any form of kitchen utensil, dinner set or tableware such as but not limited to pots, cutlery, pans, plates, cops, knives, forks, spoons, glassware such as glasses, cutting boards, porcelain etc.
- hard surface refers to a solid, substantially non-flexible surface such as a countertop, tile, floor, wall, panel, window, plumbing fixture, kitchen and bathroom furniture, appliance, engine, circuit board, and dish. Hard surfaces may include for example, health care surfaces and food/plant/animal processing surfaces.
- compositions according to the present invention are suitable as, or, for use in malodor management, or for modulating fragrance notes, or for the modification of fragrance notes.
- the compositions according to the present invention provide excellent effects for modulating, modifying or suppressing undesired fragrance notes.
- malodor coverage means that the unpleasant smell of one or more substances or a composition is entirely suppressed or reduced, but the coverage is not achieved by a beneficial intrinsic odor of an added compound.
- an unpleasant smell of a substance or a composition is improved by adding a compound exhibiting a malodor coverage effect, however the added compound does not improve the unpleasant smell of the substance or composition due to a beneficial intrinsic odor of the added compound.
- the added compound is an odor neutral molecule without a beneficial intrinsic odor. Therefore, in the context of the present invention the term “malodor coverage” does not relate to fragrance compounds or compositions which only cover an unpleasant smell due to a strong beneficial intrinsic odor.
- malodor management means that the formation of an unpleasant smell is entirely suppressed or inhibited (prevention of the formation of malodor) and/or an already existing unpleasant smell is entirely suppressed or at least reduced (“malodor reduction”).
- malodor reduction means that the suppression or inhibition of the formation of an unpleasant smell may be achieved by the suppression or inhibition of microbial activity. Therefore, “malodor management” may be achieved by inhibiting malodor development and/or malodor reduction.
- the malodor reducing/covering/preventing effect in the context of the present invention means that the offensive or to most people unpleasant olfactory perception which is usually caused by particularly odorous substances, is perceivably reduced, covered or even inhibited. Thereby, the reduction is not merely based on masking with a strong fragrance.
- the detergent and/or cleaning composition according to the present invention includes at least one surfactant (a1 , a2, a3, a) typically used in the field of homecare.
- Surfactants are added for a number of reasons, the main purposes being their washing-active properties. They remove soils from the clothing and surfaces in the washing and cleaning process and keep it suspended in the washing solution. Some surfactants perform other functions such as foam inhibition.
- the detergent and/or cleaning composition according to the present invention may comprise any kind of surfactant, namely anionic surfactants, cationic surfactants, non-ionic surfactants, amphoteric / zwitterionic surfactant, and any mixture thereof.
- Suitable surfactants which can be incorporated into the detergent and/or cleaning compositions according to the present invention are:
- Suitable anionic surfactants for the detergent and/or cleaning compositions according to the present invention may include any conventional anionic surfactants.
- Typical examples for anionic surfactants encompass:
- the anionic surfactant is selected from the group consisting of:
- C8 to C18 alkyl carboxylates ethoxylated with 3 to 10 moles ethylene oxide, and preferably ethoxylated with 3 to 6 moles ethylene oxide; and any mixture thereof.
- the anionic surfactant is selected from the group consisting of: dodecyl benzene sulfonate; dodecyl sulfate; dodecyl sulfate, ethoxylated with 2 moles ethylene oxide;
- the at least one surfactant is an anionic surfactant, and preferably one that is typically used in the field of homecare.
- the at least one surfactant is a non-ionic surfactant, and preferably one that is typically used in the field of homecare.
- the detergent and/or cleaning composition according to the present invention comprises a combined mixture of two or even more of anionic and nonionic surfactants as specified herein.
- the anionic surfactant is most preferred selected from the group consisting of dodecyl benzene sulfonate, dodecyl sulfate, dodecyl sulfate, ethoxylated with 2 moles ethylene oxide, and any mixture thereof.
- the anionic surfactant is most preferred selected from the group consisting of dodecyl sulfate, dodecyl sulfate, ethoxylated with 2 moles ethylene oxide, and any mixture thereof.
- the anionic surfactant is most preferred selected from the group consisting of dodecyl sulfate, dodecyl sulfate, ethoxylated with 2 moles ethylene oxide, and any mixture thereof.
- Suitable cationic surfactants for the detergent and/or cleaning compositions according to the present invention may include any conventional cationic surfactants.
- Typical examples for cationic surfactants encompass: quaternary C8 to C18 alkyl ethanolamines; quaternary C8 to C18 alkyl ammonium compounds;
- the cationic surfactant is selected from the group consisting of: quaternary C12 to C18 alkyl ethanolamines; quaternary C12 to C18 alkyl ammonium compounds;
- the cationic surfactant is selected from the group consisting of: quaternary C16 to C18 alkyl ethanolamines; quaternary C16 to C18 alkyl ammonium compounds;
- the cationic surfactant is most preferred selected form the group consisting of quaternary C16 to C18 alkyl ammonium compounds, and any mixture thereof.
- the cationic surfactant is most preferred selected form the group consisting of C14 to C18 alkyl ammonium methosulfates, and any mixture thereof.
- Suitable non-ionic surfactants for the detergent and/or cleaning compositions according to the present invention may include any conventional non-ionic surfactants.
- Typical examples for non-ionic surfactants encompass:
- C6 to C18 fatty alcohols ethoxylated with 1 to 12 moles ethylene oxide; alkoxylated C6 to C18 fatty alcohols such as
- the non-ionic surfactant is selected from the group consisting of:
- the non-ionic surfactant is selected from the group consisting of:
- the non-ionic surfactant is selected from the group consisting of:
- Said non-ionic surfactants are particularly beneficial for preparing “green” detergent and/or cleaning compositions.
- the non-ionic surfactant is most preferred selected from the group consisting of C10 to C18 sophorolipids, C10 to C18 rhamnolipids, C8 to C14 alkyl polyglycosides, and any mixture thereof.
- the non-ionic surfactant is selected from the group consisting of C12 to C14 fatty alcohols, ethoxylated with 7 moles ethylene oxide, C13 to C15 fatty alcohols, ethoxylated with 7 moles ethylene oxide, and any mixture thereof.
- the non-ionic surfactant is selected from the group consisting of C9 to C11 fatty alcohols, ethoxylated with 3 to 8 moles ethylene oxide, C10 fatty alcohol, ethoxylated with 3 to 8 moles ethylene oxide, and any mixture thereof.
- the non-ionic surfactant is selected from the group consisting of C12 to C14 fatty alcohols, ethoxylated with 5 mol ethylene oxide and/or propoxylated with 4 mol propylene oxide.
- Suitable amphoteric / zwitterionic surfactants for the detergent and/or cleaning compositions according to the present invention may include any conventional amphoteric/zwitterionic surfactants.
- Typical examples for amphoteric/zwitterionic surfactants encompass:
- amphoteric/zwitterionic surfactant is selected from the group consisting of:
- amphoteric/zwitterionic surfactant is selected from the group consisting of:
- amphoteric/zwitterionic surfactant is most preferred selected from the group consisting of C12 to C14 alkylbetaines, and any mixture thereof.
- the above numeric ranges recited with respect of the number of C atoms of the surfactants, given in the form “Cx to Cy” include the values defining the range and include each integer within the defined range, the range C10 to C18 includes C10, C11 , C12, C13, C14, C15, C16, C17 and C18.
- the term “C10 to C18 alkyl” includes decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl and octadecyl.
- C12 to C14 alkyl includes dodecyl, tridecyl and tetradecyl.
- C6 to C18 fatty alcohols includes fatty alcohols having a carbon chain with 6, 7, 8, 9, 10, 11 ,
- C6 to C18 rhamnolipids includes structures comprising a rhamnolipid and a carbon chain having 6, 7, 8, 9, 10, 11 , 12,
- surfactants can be used either singular or in the form of mixtures of two, three, or even more surfactants, either from the same surfactant category (anionic, cationic, non-ionic, amphoteric/zwitterionic) or as mixture of surfactants of different surfactant categories.
- the detergent and/or cleaning composition according to the present invention further includes at least one odorous substance as component (b1), (b2), (b3), (b).
- odorous substance as used herein relates to a single substance. These substances are also referred to as “fragrant substances”, “perfume substances” or “fragrance substances” as well as “fragrances”.
- perfume oil refers to mixtures of two or more of the aforementioned single odorous substances (also called “perfume mixture” or “fragrance mixture” or “fragrance compositions” etc.).
- the at least one odorous substance is a compound which is used for the primary purpose of conferring or modifying an odor.
- these substances or mixtures of substances are able to impart or modify the odor of a composition or formulation in a positive or pleasant way.
- the composition according to the present invention preferably includes one or more perfume oils and/or fragrances.
- perfume oils are mixtures of natural and synthetic fragrances.
- Natural fragrances are extracts from flowers, stems and leaves, fruits, fruit peels, roots, woods, herbs and grasses, needles and branches, and resins and balsams.
- animal products such as, for example, civet and castoreum.
- Natural fragrances include for example the extracts of blossoms (lily, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), fruit peel (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calmus), woods (pinewood, sandalwood, guaiac wood, cedarwood, rosewood), herbs and grasses (tarragon, lemon grass, sage, thyme), needles and branches (spruce, fir, pine, dwarf pine), resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax).
- Typical (synthetic) fragrance compounds are usually products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type.
- fragrance compounds of the ester type are benzyl acetate, phenoxyethyl isobutyrate, p-tert. butyl cyclohexylacetate, linalyl acetate, dimethyl benzyl carbinyl acetate, phenyl ethyl acetate, linalyl benzoate, benzyl formate, ethylmethyl phenyl glycinate, allyl cyclohexyl propionate, styrallyl propionate and benzyl salicylate.
- Ethers include, for example, benzyl ethyl ether while aldehydes include, for example, the linear alkanals containing 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal.
- ketones are the ionones, beta-isomethylionone and methyl cedryl ketone.
- Suitable alcohols are anethol, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol.
- the hydrocarbons mainly include the terpenes and balsams.
- perfume oils are essential oils of relatively low volatility which are mostly used as aroma components. Examples are sage oil, chamomile oil, clove oil, melissa oil, mint oil, cinnamon leaf oil, lime-blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, ladanum oil and lavendin oil.
- Fragrance substances which are advantageously suitable for combining are the following examples of known odorous / odorant substances: extracts of natural raw materials such as essential oils, concretes, absolutes, resins, resinoids, balsams, tinctures such as for example: ambergris tincture; amyris oil; angelica seed oil; angelica root oil; anise oil; valerian oil; basil oil; tree moss absolute; bay oil; artemisia oil; benzoin resin; bergamot oil; beeswax absolute; birch tar oil; bitter almond oil; savory oil; buchu leaf oil; cabreuva oil; cade oil; calamus oil; camphor oil; cananga oil; cardamom oil; cascarilla oil; cassia oil; cassie absolute; castoreum absolute cedar leaf oil; cedarwood oil; cistus oil; citronella oil; lemon oil; copaiba balsam; copaiba balsam oil; coriander oil; costus
- the above specified odorous substances can be used either singular or in the form of mixtures of two, three, or even more odorous substances, either from the same type (natural, synthetic, ether, ester etc.) or as mixture of odorous substances of different types.
- the fragrance substances specified above can be used, either as individual substances or in mixtures with at least one, two, three or even more fragrance substances, in a large number of fragrance mixtures, selected from an extensive range of natural and synthetic substances.
- the list of odorous substances (b1 , b2, b3, b) specified herein can be arbitrary combined with the list of surfactants specified herein as well as the list of (fragrance) boosting agents as specified herein.
- the amount of the odorous substance or mixture of odorous substances is preferably comprised in amounts of around 0.00001 % to 10 % by weight, preferably 0.0001 % to 5 % by weight and particularly preferably 0.001 % to 2 % by weight, relative to the total amount of the detergent and/or cleaning compositions.
- Fragrance compositions which contain the at least one odorous substance may be used in liquid form, undiluted or diluted with a solvent.
- Solvents suitable for this purpose are for example ethanol, isopropanol, diethylene glycol monoethyl ether, glycerol, propylene glycol, 1 ,2-butylene glycol, dipropylene glycol, diethyl phthalate, triethyl citrate, isopropyl myristate, triacetin, vegetable oils, etc.
- fragrance compositions which contain one or more odorous substances may be adsorbed on a carrier which ensures both a fine distribution of the fragrance substances in the product and controlled release upon use.
- a carrier may be porous inorganic materials such as sodium sulphate, silica gels, zeolites, gypsums, clays, clay granules, aerated concrete etc., or organic materials such as woods, cellulose-based substances, sugars, dextrins (for example maltodextrin), or plastics such as PVC, polyvinyl acetates or polyurethanes.
- the one or more odorous substances may be provided in microencapsulated form, in spray-dried form or as inclusion complexes or as extrusion products.
- the odorous substances may be encapsulated, for example, by coacervation methods with the assistance of capsule materials made for example from polyurethane-type substances or soft gelatin.
- Spray-dried fragrance compositions may be produced for example by spray-drying an emulsion or dispersion containing the fragrance substance composition, wherein modified starches, proteins, dextrin and vegetable gums may be used as carriers.
- Inclusion complexes may be produced for example by introducing dispersions of the fragrance substance composition and cyclodextrins or urea derivatives into a suitable solvent, for example water.
- Extrusion products may be produced by melting the fragrance substance compositions with a suitable waxy substance and extruding with subsequent solidification, optionally in a suitable solvent, for example isopropanol.
- the detergent and/or cleaning composition according to the present invention further includes at least one boosting component / mixture / composition (c). These are also referred to as fragrance boosting agent / component or fragrance booster / boosting component or mixture or composition.
- Boosting agent mixtures or boosting compositions (c) within the meaning of the present invention are mixtures of (c1.1) 1 ,2-heptanediol, (c2.1) 2,3-heptanediol, (c3.1) a mixture of 1 ,2-heptanediol and 2,3-heptanediol, (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol with (c") glyceryl caprylate and/or (c IH ) 4-hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin.
- boosting compositions (c) within the meaning of the present invention are mixtures of (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol with (c") glyceryl caprylate and/or (c IH ) 4- hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin.
- the first boosting component of the boosting component or mixture (c) in the composition [alkanediol component] according to the present invention is preferably either 1 ,2- heptanediol (c1.1) or 2,3-heptanediol (c2.1), or a mixture comprising both heptanediols, i.e. 1 ,2-heptanediol plus 2,3-heptanediol (c3.1).
- the boosting component (c) is based on a mixture of at least one (first) alkanediol boosting component ((first) boosting agent / component) as specified herein and at least one further or second boosting component (further or second boosting agent / component) selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, ethyl hexyl glycerin or any mixture of these further boosting agents.
- mixtures of at least one alkanediol with at least one of glyceryl caprylate, 4-hydroxyacetophenone, and/or ethyl hexyl glycerin show excellent fragrance boosting properties, i.e. the intensity and the adherence of the fragrances contained in the detergent and/or cleaning compositions is improved even when using small amounts of the fragrance component without requiring the addition of fixatives and the like.
- these boosters provide for an improved reduction of malodour and efficiently prevent the formation of malodor and result in an improved cleaning performance.
- the overall amount of ingredients such as fragrances and other additives can be considerable reduced, thereby advantageously reducing the allergic potential of the final product formulation and its environmental impact.
- This improvement in the properties is based on a synergistical interaction between the at least one alkanediol (boosting agent) and the at least one further boosting agent. Additionally, this improvement in the properties is based on a synergistical interaction between the boosting component (c) and the components (a) and (b).
- mixtures of these boosting agents as specified above were found to efficiently boost or improve the cleaning efficiency and simultaneously enhance the olfactory properties of odorous substances in a synergistical manner. Additionally, these substances were found to efficiently improve the adherence of odorous substances on substrates such as laundry, fabrics, textiles, dishes, ware, surfaces, and the like, treated with the corresponding detergent and/or cleaning composition while simultaneously providing for an improved malodor reduction and/or malodor coverage and/or malodor prevention.
- the first component of the boosting component or mixture (c) [i.e. the alkanediol component] in the detergent and/or cleaning composition according to the present invention is preferably either 1 ,2-heptanediol (c1.1) or 2,3-heptanediol (c2.1), or a mixture comprising both heptanediols, i.e. 1 ,2-heptanediol plus 2,3-heptanediol (c3.1).
- 1 ,2-Heptanediol belongs to the category of alkanediols and is a straight chain alkanediol with the general formula:
- 2,3-Heptanediol likewise belongs to the category of alkanediols and is a straight chain alkanediol with the general formula:
- the first component of the fragrance boosting component (c) in the detergent and/or cleaning composition according to the present invention i.e. the alkanediol component] is selected from the group consisting of:
- (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol.
- the at least one linear alkanediol, the at least one first linear alkanediol and/or the one or more second linear alkanediol have a carbon chain length of 7 to 14 carbon atoms, and further preferred a carbon chain length from 7 to 12 carbon atoms, more preferred a carbon chain length from 7 to 10 carbon atoms, and most preferred a carbon chain length from 7 to 9 carbon atoms.
- Most preferred the at least one linear alkanediol has a carbon chain of 7 or 8 carbon atoms.
- these alkanediols were found to exhibit the best fragrance boosting properties, i.e. enhancing the olfactory properties of odorous substances and their adherence to substrates while simultaneously providing for an improvement in malodor reduction / coverage / prevention compared to shorter chained alkanediols. For these alkanediols particularly pronounced boosting effects were observed.
- Alkanediols are glycols, i.e. any of a class of organic compounds belonging to the alcohol family; in the molecule of a glycol, two hydroxyl (-OH) groups are attached to different carbon atoms of a carbon chain.
- Straight chain 1 ,2-alkanediols have been used for more than 15 years as multifunctional actives.
- Short chain 1 ,2-alkanediols are amphiphilic compounds and thus, like 1 ,2-pentanediol, 1 ,2-hexanediol and 1 ,2-heptanediol, are soluble both in water and oils.
- 1 ,2-octanediol is a solid and tends to precipitate or recrystallize in oily solutions as well as in water at > 0.5 %.
- 1 ,2-decanediol is a solid and soluble only in oils. Apart from moisturizing, some 1 ,2-alkanediols are used as viscosity modifiers.
- the boosting agent (c 1 ) of the detergent and/or cleaning composition according to the present invention is in a first alternative at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms, and preferably a carbon chain of 7 to 14 carbon atoms, and even more preferred a carbon chain of 7 to 12 carbon atoms and more preferred of 7 to 10 carbon atoms.
- Most preferred the at least one linear alkanediol has a carbon chain of 7 to 9 carbon atoms and further preferred a carbon chain of 7 or 8 carbon atoms. For these alkanediols particularly pronounced boosting effects were observed.
- the boosting component (c 1 ) may include at least one first linear alkanediol in combination with one or more second linear alkanediol, preferably wherein the at least one first linear alkanediol has a carbon chain of 5 to 14 carbon atoms (and preferably a carbon chain of 7 to 14 carbon atoms, further preferred a carbon chain of 7 to 12 carbon atoms, and even more preferred a carbon chain of 7 to 10 carbon atoms, and most preferred 7 to 9 carbon atoms and further preferred a carbon chain of 7 or 8 carbon atoms) and the at least one second linear alkanediol has a carbon chain of 5 to 14 carbon atoms (and preferably a carbon chain of 7 to 14 carbon atoms, further preferred a carbon chain of 7 to 12 carbon atoms, and even more preferred a carbon chain of 7 to 10 carbon atoms, and most preferred 7 to 9 carbon atoms and further preferred a carbon chain of 7 or 8 carbon atoms) and the at least one second linear al
- first linear alkanediol of the invention can be selected from the same lists and types of compounds as the linear alkanediol according to the first alternative, in the following, reference is made to the linear alkanediol in general, which can also be the first linear alkanediol.
- first and second linear alkanediols where these are specifically different, the specific terms “first” and “second” will be used to distinguish the two alkanediol components.
- the phrase “at least one linear alkanediol” or “at least one first linear alkanediol” means that the composition can comprise one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or can comprise one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms or can comprise more than one linear alkanediol or can comprise more than one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms, i.e. two, three, four or more different linear alkanediols or first linear alkanediols having a carbon chain of 5 to 14 carbon atoms.
- the at least one linear alkanediol or the at least one first linear alkanediol according to the present invention consists of a chain of 5 to 14 carbon atoms (and preferably a carbon chain of 7 to 14 carbon atoms, further preferred a carbon chain of 7 to 12 carbon atoms, and even more preferred a carbon chain of 7 to 10 carbon atoms, and most preferred 7 to 9 carbon atoms and further preferred a carbon chain of 7 or 8 carbon atoms) joined to each other by single covalent bonds with two OH-functional groups attached to two different carbon atoms in the chain.
- the at least one linear alkanediol or the at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms in the detergent and/or cleaning composition according to the present invention is selected from the group consisting of pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol, and tetradecanediol.
- the at least one linear alkanediol or the at least one first linear alkanediol has a carbon chain of 7 to 14 carbon atoms and is selected from the group consisting of heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol tridecanediol, and tetradecanediol.
- the at least one linear alkanediol or the at least one first linear alkanediol has a carbon chain of 7 to 12 carbon atoms and is selected from the group consisting of heptanediol, octanediol, nonanediol, decanediol, undecanediol, and dodecanediol.
- the at least one linear alkanediol or the at least one first linear alkanediol has a carbon chain of 7 to 10 carbon atoms and is selected from the group consisting of heptanediol, octanediol, nonanediol, and decanediol.
- the at least one linear alkanediol or the at least one first linear alkanediol has a carbon chain of 7 to 9 carbon atoms and is selected from the group consisting of heptanediol, octanediol, and nonanediol.
- the at least one linear or the at least one first linear alkanediol has a carbon chain of 7 or 8 carbon atoms in the detergent and cleaning composition according to the present invention and is selected from the group consisting of heptanediol, octanediol, and nonanediol.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of alkanediols having a number of carbon atoms of 7 and 8, i.e. heptanediol, octanediol, and any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of alkanediols having a higher number of carbon atoms of 9 to 14, i.e. nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol, tetradecanediol and any mixture thereof, or is selected from the group consisting of alkanediols having a number of carbon atoms of 9 to 13, i.e.
- nonanediol decanediol, undecanediol, dodecanediol, tridecanediol, and any mixture thereof, or is selected from the group consisting of alkanediols having a number of carbon atoms of 9 to 12, i.e. nonanediol, decanediol, undecanediol, dodecanediol, and any mixture thereof, or is selected from the group consisting of alkanediols having a number of carbon atoms of 9 to 11 , i.e.
- nonanediol decanediol, undecanediol, and any mixture thereof, or is selected from the group consisting of alkanediols having a number of carbon atoms of 9 and 10, i.e. nonanediol, decanediol, and any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is either nonanediol, decanediol, undecanediol, or dodecanediol, or any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of heptanediol, octanediol and nonanediol.
- the at least one linear alkanediol or the at least first linear alkanediol is heptanediol.
- the detergent and/or cleaning composition according to the present invention comprises as a first boosting agent a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms (and preferably a carbon chain of 7 to 14 carbon atoms, further preferred a carbon chain of 7 to 12 carbon atoms, and even more preferred a carbon chain of 7 to 10 carbon atoms, and most preferred 7 to 9 carbon atoms and further preferred a carbon chain of 7 or 8 carbon atoms) and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms (and preferably a carbon chain of 7 to 14 carbon atoms, further preferred a carbon chain of 7 to 12 carbon atoms, and even more preferred a carbon chain of 7 to 10 carbon atoms, and most preferred 7 to 9 carbon atoms and further preferred a carbon chain of 7 or 8 carbon atoms) which is/are different from the first linear alkanediol.
- the (first) fragrance boosting agent / component is an alkanediol mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more, i.e. two, three, four or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms.
- the first linear alkanediol can be any of the alkanediols as described herein for the linear alkanediol in general and in particular for the first alternative.
- the mixture can include one first linear alkanediol and one, two, three or more second linear alkanediols; or the mixture can include two first linear alkanediols and one, two, three or more second linear alkanediols, etc. with the proviso, that in each mixture, the first linear alkanediols and the second linear alkanediols are different from each other.
- the second linear alkanediol preferably consists of a chain of 5 to 14 carbon atoms joined to each other by single covalent bonds with two OH-functional groups attached to two different carbon atoms in the chain.
- the at least one second linear alkanediol having a carbon chain of 5 to 14 carbon atoms in the detergent and/or cleaning composition according to the present invention is selected from the group consisting of pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol and tetradecanediol.
- the at least one second linear alkanediol has a carbon chain of 7 to 14 carbon atoms and is selected from the group consisting of heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol and tetradecanediol.
- the at least one second linear alkanediol has a carbon chain of 7 to 12 carbon atoms and is selected from the group consisting of heptanediol, octanediol, nonanediol, decanediol, undecanediol, and dodecanediol.
- the at least one second linear alkanediol has a carbon chain of 7 to 10 carbon atoms and is selected from the group consisting of heptanediol, octanediol, nonanediol, and decanediol.
- the at least one second linear alkanediol has a carbon chain of 7 to 9 carbon atoms and is selected from the group consisting of heptanediol, octanediol, and nonanediol.
- the at least one second linear alkanediol has a carbon chain of 7 or 8 carbon atoms in the detergent and cleaning composition according to the first aspect of the present invention and is selected from the group consisting of heptanediol and octanediol.
- the at least one second linear alkanediol is selected from the group consisting of heptanediol, octanediol and nonanediol.
- first linear alkanediols and the second linear alkanediols in the mixture are either different with regard to the length of their carbon chain, i.e. number of the carbon atoms, or with regard to their constitutional isomerism.
- the number of the carbon atoms of the first linear alkanediols and the second linear alkanediols in the mixture can also be same.
- the first linear alkanediol and the second linear alkanediol have a carbon chain of 7 carbon atoms, but the first linear alkanediol and the second linear alkanediol are different with regard to their constitutional isomerism or with regard to their stereoisomerism.
- both the first and the second alkanediol is for example heptanediol
- the second linear alkanediol heptanediol is a different constitutional isomer or stereoisomer from the first linear alkanediol, according to the second alternative.
- the detergent and/or cleaning composition according to the present invention comprises a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms wherein the number of the carbon atoms of the first and the second alkanediol is either same or different.
- first and the second alkanediol have the same number of carbon atoms, such an alkanediol combination is herein also referred to as “homo alkanediol mixture” or “homo combination”.
- the first linear alkanediol and the second linear alkanediol have a carbon chain of 7 carbon atoms, but the first linear alkanediol and the second linear alkanediol are different with regard to their constitutional isomerism or with regard to their stereoisomerism.
- first and the second alkanediol have a different number of carbon atoms
- such an alkanediol combination is herein also referred to as “hetero alkanediol mixture” or “hetero combination”.
- the first linear alkanediol has a carbon chain of 7 carbon atoms and the second linear alkanediol has a carbon chain of 8 carbon atoms.
- the first linear alkanediol and the second linear alkanediol can be different with regard to their constitutional isomerism or with regard to their stereoisomerism.
- the present invention relates to a detergent and/or cleaning composition, wherein the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol, and tetradecanediol; and/or the one or more second linear alkanediol is selected from the group consisting of pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol; and/or
- Particular preferred is a (fragrance) boosting agent mixture, wherein the at least one first linear alkanediol is selected from an alkanediol having a lower number of carbon atoms from 5 to 8 and wherein the one or more second alkanediol is selected from an alkanediol having a higher number of carbon atoms from 9 to 14.
- a (fragrance) boosting agent mixture wherein the at least one first linear alkanediol is selected from the group consisting of pentanediol, hexanediol, heptanediol, octanediol, and any mixture thereof, and the one or more second alkanediol is selected from the group consisting of nonanediol, decanediol, undecanediol, dodecanediol, tridecanediol, and any mixture thereof.
- alkanediol within the context of the present invention also includes its constitutional isomers or position isomers.
- Constitutional isomers are compounds that have the same molecular formula and different connectivity.
- Position isomers a particular form of constitutional isomerism, are structural isomers that can be viewed as differing only in the position of a functional group on a parent structure, which in this case, in particular, is the position of the two alcohol functions.
- the two OH-groups of the alkanediol are chemically bonded to the C1 and C2 carbon atoms in the alkanediol chain; if x is 2, the two OH-groups of the alkanediol are chemically bonded to the C2 and 03 carbon atoms in the alkanediol chain, etc.
- the two OH functional groups are vicinal attached to two different adjacent carbon atoms in the chain.
- the two OH functional groups are attached to two different carbon atoms in the chain where the two carbon atoms are separated by one carbon atom.
- the two OH functional groups are attached to two different carbon atoms in the chain where the two carbon atoms are separated by two carbon atoms.
- the two functional groups are attached to the first carbon atom and to the terminal carbon atom.
- the linear alkanediol having a carbon chain of 5 to 14 carbon atoms is preferably a vicinal (x,x+1)-diol, selected from the group consisting of a 1 ,2-diol, 2,3-diol, 3,4- diol, 4,5-diol, further (x,x+1)-diols, and mixtures thereof, preferably an alpha, beta- 1 ,2- constitutional isomer.
- the at least one first linear alkanediol and/or the one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms is a vicinal (x,x+1)-diol, selected from the group consisting of a 1 ,2-diol, 2,3-diol, 3,4-diol, 4,5-diol, further (x,x+1)-diols, and mixtures thereof, preferably an alpha, beta-1 , 2-constitutional isomer, and preferably the first linear alkanediol and/or the second linear alkanediol having a carbon chain of 5 to 14 carbon atoms is selected from 1 ,2-diols and/or 2, 3-diols.
- the at least one linear alkanediol, the at least one first linear alkanediol and/or the one or more second linear alkanediol is an (x,x+1) constitutional isomer, wherein x stands for the number of the carbon atom in the alkanediol chain, to which the OH groups of the alkanediol are chemically bonded, in particular a 1 ,2-alkanediol, a 2,3-alkanediol, a 3,4-alkanediol, or mixtures thereof, preferably a 1 ,2-alkanediol or a 2,3-alkanediol.
- vicinal (x,x+1)-diols are most preferred, such as alpha, beta or beta, gamma or gamma, delta etc.
- the linear alkanediol and in particular the first linear alkanediol and/or the second linear alkanediol is a 1 ,2-alkanediol, a 2,3-alkanediol, a 3,4-alkanediol, or mixtures thereof, more preferred a 2,3-alkanediol.
- the 1 ,2-alkanediols of the linear alkanediol in particular the first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and/or the second linear alkanediol having a carbon chain of 5 to 14 carbon atoms, can preferably be those as represented by the following formulae:
- the 1 ,2-alkanediols of the linear alkanediol in particular the first linear alkanediol and/or the second linear alkanediol have a carbon chain of 7 to 14 carbon atoms, and further preferred a carbon chain length from 7 to 12 carbon atoms, more preferred a carbon chain length of 7 to 10 carbon atoms, and most preferred a carbon chain length from 7 to 9 carbon atoms.
- the 1,2-alkanediols of the linear alkanediol, in particular the first linear alkanediol and/or the second linear alkanediol have a carbon chain of 7 or 8 carbon atoms. For these alkanediols particularly pronounced boosting effects were observed.
- the 2,3-alkanediols of the linear alkanediol of the invention can preferably be those as represented by the following formulae:
- the 2,3-alkanediols of the linear alkanediol in particular the first linear alkanediol and/or the second linear alkanediol have a carbon chain of 7 to 14 carbon atoms, and further preferred a carbon chain length from 7 to 12 carbon atoms, more preferred a carbon chain length of 7 to 10 carbon atoms, and most preferred a carbon chain length from 7 to 9 carbon atoms.
- the 2,3-alkanediols of the linear alkanediol, in particular the first linear alkanediol and/or the second linear alkanediol have a carbon chain of 7 or 8 carbon atoms. For these alkanediols particularly pronounced boosting effects were observed.
- the 3,4-alkanediols of the linear alkanediol can preferably be those as represented by the following formulae:
- the 3,4-alkanediols of the linear alkanediol, in particular the first linear alkanediol and/or the second linear alkanediol have a carbon chain of 7 to 14 carbon atoms, and further preferred a carbon chain length from 7 to 12 carbon atoms, more preferred a carbon chain length of 7 to 10 carbon atoms, and most preferred a carbon chain length from 7 to 9 carbon atoms.
- the 3,4-alkanediols of the linear alkanediol, in particular the first linear alkanediol and/or the second linear alkanediol have a carbon chain of 7 or 8 carbon atoms. For these alkanediols particularly pronounced boosting effects were observed.
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of:
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of:
- linear alkanediol or the first linear alkanediol is selected from the group consisting of:
- linear alkanediol or the first linear alkanediol is selected from the group consisting of:
- linear alkanediol or the first linear alkanediol is selected from the group consisting of:
- linear alkanediol or the first linear alkanediol is selected from the group consisting of:
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1,2-pentanediol, 2,3-pentanediol, 1,2-hexanediol, 2,3-hexanediol,
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1,2-heptanediol, 2,3-heptanediol, 1 ,2-octanediol, 2,3-octanediol,
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1 ,2-heptanediol, 2,3-heptanediol, 1 ,2-octanediol, 2,3-octanediol,
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1 ,2-heptanediol, 2,3-heptanediol, 1 ,2-octanediol,
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1 ,2-heptanediol, 2,3-heptanediol, 1 ,2-octanediol, 2,3-octanediol,
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1 ,2-heptanediol, 2,3-heptanediol, 1 ,2-octanediol,
- alkanediols are liquid at a purity of 90 % to 99 %.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of:
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of:
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of:
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1 ,2-pentanediol, 2,3-pentanediol, and mixtures thereof, or is selected from the group consisting of 1 ,2-heptanediol, 2,3-heptanediol, and mixtures thereof.
- the linear alkanediol or the first linear alkanediol can also preferably be selected from the group consisting of 1 ,2-octanediol, 2,3-octanediol, and mixtures thereof.
- the linear alkanediol or the first linear alkanediol is an alpha, beta- or a beta, gamma-diol as either 1 ,2-heptanediol or 2,3-heptanediol or a mixture thereof.
- the linear alkanediol or the first linear alkanediol can also preferably be an alpha, beta- or a beta, gamma-diol as either 1 ,2-octanediol or 2,3-octanediol or a mixture thereof.
- a mixture comprising 1 ,2-heptanediol and 2,3-octanediol or a mixture comprising 1 ,2-octanediol and 2,3- heptanediol is also possible.
- the linear alkanediol or the first linear alkanediol is 2,3-pentanediol or
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1 ,2-nonanediol, 2,3-nonanediol, 1 ,2-decanediol, 2,3-decanediol, 1 ,2-undecanediol, 2,3-undecanediol, 1 ,2-dodecanediol, 2,3-dodecanediol, and any mixture thereof.
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 1 ,2-nonanediol, 2,3-nonanediol, and mixtures thereof, or can also be preferably selected from the group consisting of 1 ,2-decanediol, 2,3-decanediol, and mixtures thereof, or can also be preferably selected from the group consisting of 1 ,2-undecanediol, 2,3-undecanediol, and mixtures thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 7 to 14, i.e. 1 ,2-heptanediol, 1 ,2-octanediol, 1 ,2-nonanediol, 1 ,2-decanediol,
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a lower number of carbon atoms of 5 to 8, i.e. 1 ,2-pentanediol, 1 ,2-hexanediol, 1 ,2-heptanediol, 1 ,2- octanediol, and any mixture thereof, or is selected from the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 6 to 8, i.e.
- the at least one linear alkanediol or the at least one first linear alkanediol is either 1 ,2-pentanediol or 1 ,2-hexanediol or 1 ,2-heptanediol or 1 ,2- octanediol or any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is either 1 ,2-heptanediol or 1 ,2-octanediol or any mixture thereof.
- the at least one linear alkanediol or the at least first linear alkanediol is 1 ,2-heptanediol.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a higher number of carbon atoms of 9 to 14, i.e.
- 1.2-nonanediol 1 ,2-decanediol, 1 ,2-undecanediol, 1 ,2-dodecanediol, 1 ,2-tridecanediol, and any mixture thereof, or is selected from the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 9 to 12, i.e.
- 1.2-undecanediol and any mixture thereof, or is selected from the group consisting of 1 ,2- alkanediols having a number of carbon atoms of 9 and 10, i.e. 1 ,2-nonanediol, 1 ,2-decanediol, and any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is either 1 ,2-nonanediol or 1 ,2-decanediol or 1 ,2-undecanediol or 1 ,2- dodecanediol or any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a higher number of carbon atoms, and more specifically more than 10 carbon atoms, i.e. 11 , 12, 13, or 14 carbon atoms, i.e. 1 ,2-undecanediol, 1 ,2-dodecanediol, 1 ,2-tridecanediol, or 1 ,2- tetradecanediol.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 7 to 14, i.e. 2,3-heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol,
- 2,3-heptanediol, 2,3-octanediol, 2,3-nonanediol, and any mixture thereof or is selected form the group consisting of 2,3-alkanediols having a number of carbon atoms of 7 and 8, i.e. 2,3-heptanediol, 2,3-octanediol, and any mixture thereof.
- the linear alkanediol or the first linear alkanediol is selected from the group consisting of 2,3-alkanediols having a lower number of carbon atoms of 5 to 8, i.e. 2,3-pentanediol, 2,3-hexanediol, 2,3-heptanediol, 2,3-octanediol, and any mixture thereof, or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 6 to 8, i.e.
- 2,3-hexanediol, 2,3-heptanediol, 2,3-octanediol, and any mixture thereof or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 7 and 8, i.e. 2,3-heptanediol, 2,3-octanediol, and any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is either 2,3-pentanediol or 2,3-hexanediol or 2,3-heptanediol or 2,3- octanediol or any mixture thereof.
- the at least one linear alkanediol or the at least first linear alkanediol is 2,3-heptanediol.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of 2,3-alkanediols having a higher number of carbon atoms of 9 to 14, i.e. 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3- dodecanediol, 2,3-tridecanediol, 2,3-tetradecanediol, and any mixture thereof, or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 9 to 13, i.e.
- 2.3-nonanediol 2,3-decanediol, 2,3-undecanediol, 2,3-dodecanediol, 2,3-tetradecanediol, and any mixture thereof, or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 9 to 12, i.e.
- 2.3-nonanediol 2,3-decanediol, 2,3-undecanediol, 2,3- dodecanediol, and any mixture thereof, or is selected from the group consisting of 2,3- alkanediols having a number of carbon atoms of 9 to 11 , i.e. 2,3-nonanediol, 2,3-decanediol,
- 2.3-undecanediol and any mixture thereof, or is selected from the group consisting of 2,3- alkanediols having a number of carbon atoms of 9 and 10, i.e. 2,3-nonanediol, 2,3-decanediol, and any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is either 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol or 2,3- dodecanediol, or any mixture thereof.
- the at least one linear alkanediol or the at least one first linear alkanediol is selected from the group consisting of 2,3-alkanediols having a higher number of carbon atoms, and more specifically more than 10 carbon atoms, i.e. 11 , 12, 13 or 14 carbon atoms, i.e. 2,3-undecanediol, 2,3-dodecanediol, 2,3-tridecanediol, or 2,3- tetradecanediol.
- the one or more second linear alkanediol is selected from the group consisting of:
- the second linear alkanediol is selected from the group consisting of:
- the second linear alkanediol is selected from the group consisting of: 1.2-heptanediol, 2,3-heptanediol, 3,4-heptanediol,
- the second linear alkanediol is selected from the group consisting of:
- the second linear alkanediol is selected from the group consisting of:
- the second linear alkanediol is selected from the group consisting of:
- the second linear alkanediol is selected from the group consisting of 1,2-pentanediol, 2,3-pentanediol, 1 ,2-hexanediol, 2,3-hexanediol,
- the second linear alkanediol is selected from the group consisting of 1,2-heptanediol, 2,3-heptanediol, 1,2-octanediol, 2,3-octanediol, 1 ,2-nonanediol,
- the second linear alkanediol is selected from the group consisting of 1,2-heptanediol, 2,3-heptanediol, 1,2-octanediol, 2,3-octanediol, 1 ,2-nonanediol,
- the second linear alkanediol is selected from the group consisting of 1 ,2-heptanediol, 2,3-heptanediol, 1 ,2-octanediol, 2,3-octanediol, 1 ,2-nonanediol,
- the second linear alkanediol is selected from the group consisting of 1 ,2-heptanediol, 2,3-heptanediol, 1 ,2-octanediol, 2,3-octanediol, 1 ,2-nonanediol,
- the second linear alkanediol is selected from the group consisting of 1 ,2-heptanediol, 2,3-heptanediol,
- the second linear alkanediol is selected from the group consisting of:
- the second linear alkanediol is selected from the group consisting of:
- the second linear alkanediol is selected from the group consisting of 1 ,2- pentanediol, 2,3-pentanediol, and mixtures thereof, or is selected from the group consisting of
- the second linear alkanediol can also preferably be selected from the group consisting of 1 ,2-octanediol, 2,3-octanediol, and mixtures thereof.
- the second linear alkanediol is an alpha, beta- or a beta, gamma-diol as either 1.2-pentanediol or 2,3-pentanediol or a mixture thereof.
- the second linear alkanediol can also preferably be an alpha, beta- or a beta, gamma-diol as either 1 ,2-hexanediol or 2,3- hexanediol or a mixture thereof.
- a mixture comprising 1 ,2-pentanediol and 2,3-hexanediol or a mixture comprising 2,3-pentanediol and 1 ,2-hexanediol is also possible.
- the second linear alkanediol is 2,3-pentanediol or 2,3-hexanediol or
- the second linear alkanediol is selected from the group consisting of 1 ,2-nonanediol, 2,3-nonanediol, 1 ,2-decanediol, 2,3-decanediol, 1 ,2- undecanediol, 2,3-undecanediol, 1 ,2-dodecanediol, 2,3-dodecanediol, and any mixture thereof.
- the second linear alkanediol is selected from the group consisting of 1 ,2-nonanediol,
- 2.3-nonanediol, and mixtures thereof or can also be preferably selected form the group consisting of 1 ,2-decanediol, 2,3-decanediol, and mixtures thereof, or can also be preferably selected from the group consisting of 1 ,2-undecanediol, 2,3-undecanediol, and mixtures thereof.
- the at least one second linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 7 to 14, i.e. 1 ,2- heptanediol, 1 ,2-octanediol, 1 ,2-nonanediol, 1 ,2-decanediol, 1 ,2-undecanediol, 1 ,2- dodecanediol, 1 ,2-tridecanediol, 1 ,2-tetradecanediol, and any mixture thereof, or is selected from the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 7 to 12, i.e.
- 1 .2-nonanediol, 1 ,2-decanediol, 1 ,2-undecanediol, and any mixture thereof or is selected from the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 7 to 10, i.e. 1 ,2- heptanediol, 1 ,2-octanediol, 1 ,2-nonanediol, 1 ,2-decanediol, and any mixture thereof, or is selected form the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 7 to 9, i.e.
- the second linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a lower number of carbon atoms of 5 to 8, i.e. 1 ,2- pentanediol, 1 ,2-hexanediol, 1 ,2-heptanediol, 1 ,2-octanediol, and any mixture thereof, or is selected from the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 6 to 8, i.e.
- the second linear alkanediol is either 1 ,2-pentanediol or 1 ,2-hexanediol or 1 ,2-heptanediol or 1 ,2-octanediol or any mixture thereof.
- the second linear alkanediol is either 1 ,2-heptanediol or 1 ,2-octanediol or any mixture thereof.
- the second linear alkanediol is 1 ,2-heptanediol.
- the second linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a higher number of carbon atoms of 9 to 14, i.e. 1 ,2- nonanediol, 1 ,2-decanediol, 1 ,2-undecanediol, 1 ,2-dodecanediol, 1 ,2-tridecanediol, 1 ,2- tetradecanediol, and any mixture thereof, or is selected from the group consisting of 1 ,2- alkanediols having a number of carbon atoms of 9 to 13, i.e. 1 ,2-nonanediol, 1 ,2-decanediol,
- 1.2-undecanediol 1 ,2-dodecanediol, 1 ,2-tridecanediol, and any mixture thereof, or is selected from the group consisting of 1 ,2-alkanediols having a number of carbon atoms of 9 to 12, i.e.
- the second linear alkanediol is either 1 ,2-nonanediol or 1 ,2-decanediol or 1 ,2-undecanediol or 1 ,2-dodecanediol or any mixture thereof.
- the second linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a higher number of carbon atoms, and more specifically more than 10 carbon atoms, i.e. 11 , 12, 13 or 14 carbon atoms, i.e. 1 ,2- undecanediol, 1 ,2-dodecanediol, 1 ,2-tridecanediol, or 1 ,2-tetradecanediol.
- the at least one second linear alkanediol is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 7 to 14, i.e. 2,3- heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3- dodecanediol, 2,3-tridecanediol, 2,3-tetradecanediol, and any mixture thereof, or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 7 to 12, i.e.
- 2,3-alkanediols having a number of carbon atoms of 7 to 10 i.e. 2,3- heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, and any mixture thereof, or is selected form the group consisting of 2,3-alkanediols having a number of carbon atoms of 7 to 9, i.e.
- the second linear alkanediol is selected from the group consisting of 2,3-alkanediols having a lower number of carbon atoms of 5 to 8, i.e. 2,3- pentanediol, 2,3-hexanediol, 2,3-heptanediol, 2,3-octanediol, and any mixture thereof, or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 6 to 8, i.e.
- 2,3-hexanediol, 2,3-heptanediol, 2,3-octanediol, and any mixture thereof or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 7 and 8, i.e. 1 ,2-heptanediol, 1 ,2-octanediol, and any mixture thereof.
- the second linear alkanediol is either 2,3-pentanediol or 2,3-hexanediol or 2,3-heptanediol or 2,3-octanediol or any mixture thereof.
- the second linear alkanediol is either 2,3-heptanediol or 2,3-octanediol or any mixture thereof.
- the second linear alkanediol is 2,3-heptanediol.
- the second linear alkanediol is selected from the group consisting of 2,3-alkanediols having a higher number of carbon atoms of 9 to 14, i.e. 2,3- nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3-dodecanediol, 2,3-tridecanediol, 2,3- tetradecanediol, and any mixture thereof, or is selected from the group consisting of 2,3- alkanediols having a number of carbon atoms of 9 to 13, i.e. 2.3-nonanediol, 2,3-decanediol,
- 2.3-undecanediol 2,3-dodecanediol, 2,3-tridecanediol, and any mixture thereof, or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 9 to 12, i.e.
- 2,3-decanediol, 2,3-undecanediol, 2,3-dodecanediol, and any mixture thereof or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 9 to 11 , i.e. 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, and any mixture thereof, or is selected from the group consisting of 2,3-alkanediols having a number of carbon atoms of 9 and 10, i.e. 2,3-nonanediol, 2,3-decanediol, and any mixture thereof.
- the second linear alkanediol is either 2,3-nonanediol or 2,3-decanediol or 2,3-undecanediol or 2,3-dodecanediol or any mixture thereof.
- the second linear alkanediol is selected from the group consisting of 2,3-alkanediols having a higher number of carbon atoms, and more specifically more than 10 carbon atoms, i.e. 11 , 12, 13 or 14 carbon atoms, i.e. 2,3- undecanediol, 2,3-dodecanediol, 2,3-tridecanediol, or 2,3-tetradecanediol.
- the linear alkanediol is selected from the group consisting of 1 ,2-pentanediol, 1 ,2-hexanediol, 1 ,2-heptanediol, 1 ,2-octanediol, 1 ,2-nonanediol, 1 ,2- decanediol, 1 ,2-undecanediol, 1 ,2-dodecanediol, 1 ,2-tridecanediol, 1 ,2-tetradecanediol, and any mixture thereof.
- the detergent and/or cleaning composition according to the present invention which comprises a mixture or a combination comprising at least one first linear alkanediol and one or more second linear alkanediol includes any one of the following mixtures/combinations:
- ⁇ a mixture comprising 1 ,2-heptanediol and 2,3-heptanediol; or ⁇ a mixture comprising 1 ,2-octanediol and 2,3-octanediol; or
- the first linear alkanediol and the second linear alkanediol have the same number of carbon atoms.
- Particularly favorable is a mixture including 1 ,2-pentanediol in combination with 2,3- pentanediol, or a mixture including 1 ,2-heptanediol in combination with 2,3-heptanediol, or a mixture including 1 ,2-octanediol in combination with 2,3-octanediol and/or 3,4-octanediol.
- a homo alkanediol mixture comprising 1 ,2-nonanediol and 2,3- nonanediol or a homo alkanediol mixture comprising 1 ,2-decanediol and 2,3-decanediol or a homo alkanediol mixture comprising 1 ,2-undecanediol and 2,3-undecanediol are most preferred.
- the malodor coverage and/or reduction properties are enhanced in a synergistical manner.
- the above specified homo alkanediol mixtures according to the present invention comprising a 1 ,2-alkanediol and a 2,3-alkanediol are characterized by a synergistically intensified action, i.e. the alkanediol mixtures show increased cleaning performances along with remarkable fragrance boosting properties in terms of intensity and adherence in a synergistic way compared to their respective single 1 ,2-alkanediol or 2,3-alkanediol substances.
- the malodor coverage and/or reduction properties are enhanced in a synergistical manner.
- the homo mixture including 1 ,2-heptanediol and 2,3-heptanediol is particularly beneficial since it has a particularly pronounced synergistic boosting effect on the fragrance performance and its adhesion properties in a detergent and/or cleaning composition. In addition, the malodor coverage and/or reduction properties are enhanced in a synergistical manner.
- the alkanediol mixture comprising 1 ,2-octanediol and 2,3-octanediol or the alkanediol mixture comprising 1 ,2-nonanediol and 2,3-nonanediol are particularly advantageous, since the mixtures are effective in synergistically boosting an odorous substance when used in a detergent and/or cleaning composition. In addition, the malodor coverage and/or reduction properties are enhanced in a synergistical manner.
- the alkanediol mixture comprising 1 ,2-decanediol and 2,3-decanediol or the alkanediol mixture comprising 1 ,2-undecanediol and 2,3-undecanediol synergistically enhance the fragrance performance of an odorous substance in a detergent and/or cleaning composition.
- the malodor coverage and/or reduction properties are enhanced in a synergistical manner.
- a fragrance boosting effect is also observed for an alkanediol mixture including 1 ,2- dodecanediol and 2,3-dodecanediol or an alkanediol mixture including 1 ,2-tridecanediol and 2,3-tridecanediol.
- the malodor coverage and/or reduction properties are enhanced in a synergistical manner.
- the afore-mentioned synergistically improving effect towards the performance of a fragrance component in a cleaning performance is particularly pronounced for the homo mixture including 1 ,2-heptanediol and 2,3-heptanediol or the homo mixture including 1 ,2- octanediol and 2,3-octanediol or the homo mixture including 1 ,2-nonanediol and 2,3- nonanediol.
- the malodor coverage and/or reduction properties are enhanced in a synergistical manner.
- the afore specified homo alkanediol mixtures including a 1 ,2-alkanediol and the corresponding 2,3-alkanediol display a remarkably synergistic boosting effect and are clearly superior to the individually corresponding 1 ,2-alkanediols or 2,3-alkanediols and having the same concentration.
- the detergent and/or cleaning composition according to the present invention which comprises a mixture or a combination comprising at least one first linear alkanediol and one or more second linear alkanediol thus includes any one of the following mixtures/combinations:
- 1.2-decanediol in combination with one of 1 ,2-pentanediol, 1 ,2-hexanediol, 1 ,2- heptanediol, 1,2-octanediol, 1,2-nonanediol, 1,2-undecanediol, 1,2-dodecanediol, 1,2- tridecanediol, or 1,2-tetradecanediol; or
- 1.2-undecanediol in combination with one of 1,2-pentanediol, 1,2-hexanediol, 1 ,2- heptanediol, 1,2-octanediol, 1,2-nonanediol, 1,2-decanediol, 1,2-dodecanediol, 1 ,2- tridecanediol, or 1,2-tetradecanediol; or
- 1.2-dodecanediol in combination with one of 1,2-pentanediol, 1,2-hexanediol, 1 ,2- heptanediol, 1,2-octanediol, 1,2-nonanediol, 1,2-decanediol, 1,2-undecanediol, 1 ,2- tridecanediol, or 1,2-tetradecanediol; or
- 1.2-tridecanediol in combination with one of 1,2-pentanediol, 1,2-hexanediol, 1,2- heptanediol, 1,2-octanediol, 1,2-nonanediol, 1,2-decanediol, 1,2-undecanediol, 1 ,2- dodecanediol, or 1,2-tetradecanediol; or
- 1.2-tetradecanediol in combination with one of 1,2-pentanediol, 1 ,2-hexanediol, 1,2- heptanediol, 1,2-octanediol, 1,2-nonanediol, 1,2-decanediol, 1,2-undecanediol, 1 ,2- dodecanediol, or 1,2-tridecanediol; or
- 1.2-octanediol in combination with one of 2,3-pentanediol, 2,3-hexanediol, 2,3- heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3- dodecanediol, 2,3-tridecanediol, 2,3-tetradecanediol; or
- 1.2-dodecanediol in combination with one of 2,3-pentanediol, 2,3-hexanediol, 2,3- heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3- dodecanediol, 2,3-tridecanediol, 2,3-tetradecanediol; or
- 1.2-tridecanediol in combination with one of 2,3-pentanediol, 2,3-hexanediol, 2,3- heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-dodecanediol, 2,3-undecanediol, 2,3- dodecanediol, 2,3-tridecanediol, 2,3-tetradecanediol; or
- 2.3-pentanediol in combination with one of 1,2-hexanediol, 1,2-heptanediol, 1,2- octanediol, 1,2-nonanediol, 1 ,2-decanediol, 1,2-undecanediol, 1,2-dodecanediol, 1,2- tridecanediol, or 1,2-tetradecanediol; or
- 2.3-heptanediol in combination with one of 1,2-pentanediol, 1,2-hexanediol, 1,2- octanediol, 1,2-nonanediol, 1 ,2-decanediol, 1,2-undecanediol, 1,2-dodecanediol, 1,2- tridecanediol, or 1,2-tetradecanediol; or
- 2.3-octanediol in combination with one of 1,2-pentanediol, 1 ,2-hexanediol, 1 ,2- heptanediol, 1,2-nonanediol, 1,2-decanediol, 1 ,2-undecanediol, 1,2-dodecanediol, 1 ,2- tridecanediol, or 1,2-tetradecanediol; or
- 2.3-undecanediol in combination with one of 1,2-pentanediol, 1,2-hexanediol, 1 ,2- heptanediol, 1,2-octanediol, 1,2-nonanediol, 1,2-decanediol, 1,2-dodecanediol, 1 ,2- tridecanediol, or 1,2-tetradecanediol; or
- 2.3-dodecanediol in combination with one of 1,2-pentanediol, 1,2-hexanediol, 1 ,2- heptanediol, 1,2-octanediol, 1,2-nonanediol, 1,2-decanediol, 1,2-undecanediol, 1 ,2- tridecanediol, or 1,2-tetradecanediol; or
- 2.3-tridecanediol in combination with one of 1,2-pentanediol, 1,2-hexanediol, 1,2- heptanediol, 1,2-octanediol, 1,2-nonanediol, 1,2-decanediol, 1,2-undecanediol, 1 ,2- dodecanediol, or 1,2-tetradecanediol; or
- 2.3-octanediol in combination with one of 2,3-pentanediol, 2,3-hexanediol, 2,3- heptanediol, 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3-dodecanediol, 2,3- tridecanediol, or 2,3-tetradecanediol; or
- 2,3-dodecanediol in combination with one of 2,3-pentanediol, 2,3-hexanediol, 2,3- heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3- tridecanediol, or 2,3-tetradecanediol; or
- 2,3-tridecanediol in combination with one of 2,3-pentanediol, 2,3-hexanediol, 2,3- heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3- dodecanediol, or 2,3-tetradecanediol; or
- 2,3-tetradecanediol in combination with one of 2,3-pentanediol, 2,3-hexanediol, 2,3- heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3- dodecanediol or 2,3-tridecanediol.
- the detergent and/or cleaning composition according to the present invention which comprises a mixture or a combination comprising at least one first linear alkanediol and one or more second linear alkanediol thus may include any of the following mixtures/combinations:
- the first linear alkanediol and the second linear alkanediol have a different number of carbon atoms.
- the afore specified alkanediol mixtures according to the present invention comprising at least one first linear alkanediol and one or more second linear alkanediol, are characterized by synergistically intensified action, i.e. the alkanediol mixtures enhance the fragrance performance of an odorous substance in a detergent and/or cleaning composition in a synergistic way compared to the corresponding individual 1 ,2-alkanediol and/or 2,3-alkanediol substances. Additionally, the cleaning performance of the detergent and/or cleaning composition is improved and improvements in the malodor reduction and/or coverage are observed. Surprisingly, said composition are even efficient in preventing the formation of malodor.
- the detergent and/or cleaning composition according to the present invention which comprises a mixture or a combination comprising at least one first linear alkanediol and one or more second linear alkanediol thus may include the following mixture/combination:
- hetero alkanediol mixtures have a particularly pronounced cleaning performance and remarkably improved fragrance performance along with an improved adherence. Additionally, the mixtures provide for an efficient malodor coverage and/or reduction and/or prevention.
- the afore specified hetero mixtures or combinations comprising at least one first linear alkanediol and one or more second linear alkanediol simultaneously have also a synergistic malodor coverage and/or reduction effect, compared to the corresponding individual 1 ,2-alkanediol and/or 2, 3-alkanediol substances.
- the above specified alkanediol mixtures according to the present invention comprising a first linear alkanediol and a second linear alkanediol, are characterized by synergistically intensified action, i.e. the alkanediol mixtures boost the fragrance performance of a detergent and/or cleaning composition in terms of intensity and adherence in a synergistic way compared to the corresponding individual 1 ,2-alkanediol or 2, 3-alkanediol substances. Additionally, improvements in the malodor reduction and/or coverage are observed.
- Still more preferred is a (fragrance) boosting agent mixture, wherein the at least first linear alkanediol is selected from a 1 ,2-alkanediol having a lower number of carbon atoms from 5 to 8 and the one or more second alkanediol is selected from a 1 ,2-alkanediol having a higher number of carbon atoms from 9 to 14.
- a (fragrance) boosting agent mixture wherein the at least one first linear alkanediol is selected from the group consisting of 1 ,2-pentanediol, 1 ,2-hexanediol, 1 ,2- heptanediol, 1 ,2-octanediol, and any mixture thereof, and the one or more second alkanediol is selected from the group consisting of 1 ,2-nonanediol, 1 ,2-decanediol, 1 ,2-undecanediol, 1 ,2- dodecanediol, 1 ,2-tridecanediol, 1 ,2-tetradecanediol, and any mixture thereof.
- a (fragrance) boosting agent blend wherein the at least one first linear alkanediol is selected from the group consisting of 1 ,2-alkanediols having a lower number of carbon atoms of 5 to 8, i.e. 1 ,2-pentanediol, 1 ,2-hexanediol, 1 ,2-heptanediol, 1 ,2- octanediol, and any mixture thereof, and the one or more second alkanediol is selected from the group consisting of 1 ,2-alkanediols having a higher number of carbon atoms of 9 to 13, i.e.
- alkanediol mixtures wherein the difference between the number of carbon atoms of the at least one first linear alkanediol and the number of carbon atoms of the one or more second alkanediol is at least 2 carbon atoms.
- short-chained and long-chained alkanediols are combined with each other resulting in improved fragrance performances in terms of intensity and adherence as well as improved malodor reduction/coverage effects.
- a (fragrance) boosting agent mixture wherein the difference between the number of carbon atoms of the at least one first linear alkanediol and the number of carbon atoms of the one or more second alkanediol is at least 3 carbon atoms.
- the (fragrance) boosting as well as the malodor reduction/coverage effect is particularly pronounced.
- Such combinations may include any of the following mixtures/combinations:
- 1,2-hexanediol in combination with one of 1,2-nonanediol, 1,2-decanediol, 1,2- undecanediol, 1 ,2-dodecanediol, 1 ,2-tridecanediol, or 1 ,2-tetradecanediol; or
- 1,2-heptanediol in combination with one of 1 ,2-decanediol, 1,2-undecanediol, 1 ,2- dodecanediol, or 1,2-tridecanediol, or 1,2-tetradecanediol;
- 1,2-octanediol in combination with one of 1,2-undecanediol, 1,2-dodecanediol, 1,2- tridecanediol, or 1,2-tetradecanediol.
- the linear alkanediol is selected from the group consisting of 2,3- pentanediol, 2,3-hexanediol, 2,3-heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol,
- the linear alkanediol is selected from the group consisting of 2,3- pentanediol, 2,3-hexanediol, 2,3-heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol,
- the linear alkanediol is selected from the group consisting of 2,3-heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, 2,3-undecanediol, 2,3- dodecanediol, 2,3-tridecanediol, 2,3-tetradecanediol, and mixtures thereof.
- the detergent and/or cleaning composition according to the present invention comprises at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 5 to 8 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 5 to 8 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 5 to 8 carbon atoms, which is different from the first linear 1 ,2-alkanediol.
- fragment fragment boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 5 to 8 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 5 to 8 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 5 to 8 carbon atoms, which
- the detergent and/or cleaning composition according to the present invention comprises at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 6 to 7 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 6 to 7 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 6 to 7 carbon atoms, which is different from the first linear 1 ,2-alkanediol.
- fragment fragment boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 6 to 7 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 6 to 7 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 6 to 7 carbon atoms, which
- the detergent and/or cleaning composition according to the present invention comprises at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 7 to 9 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 7 to 9 carbon atoms and one or more second linear 1 ,2-alkanediol having a carbon chain of 7 to 9 carbon atoms, which is different from the first linear 1 ,2-alkanediol.
- fragment fragment boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 7 to 9 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 7 to 9 carbon atoms and one or more second linear 1 ,2-alkanediol having a carbon chain of 7 to 9 carbon atoms, which is different
- these 1 ,2-alkanediols are particularly suitable (fragrance) boosting agents in terms of intensity and adhesion, which can also efficiently be incorporated into detergent and/or cleaning compositions. It was found that these substances show better cleaning results and outstanding fragrance performances. These improved properties were for example found for laundry detergents: even after long term storage of the treated textiles, the textiles show high fragrance intensities. Such detergent and/or cleaning compositions show improved cleaning and fragrance performances compared to detergent and/or cleaning composition without the addition of such substances. Additionally, improvements in view of malodor were observed.
- the detergent and/or cleaning composition according to the present invention comprises at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 7 to 14 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 7 to 14 carbon atoms and one or more second linear 1 ,2-alkanediol having a carbon chain of 7 to 14 carbon atoms, which is different from the first linear 1 ,2-alkanediol.
- fragment fragment boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 7 to 14 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 7 to 14 carbon atoms and one or more second linear 1 ,2-alkanediol having a carbon chain of 7 to 14 carbon atoms, which is different
- the detergent and/or cleaning composition according to the present invention comprises at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 9 to 14 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 9 to 14 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 9 to 14 carbon atoms, which is different from the first linear 1 ,2-alkanediol.
- fragment fragment boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 9 to 14 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 9 to 14 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 9 to 14 carbon atoms, which
- the detergent and/or cleaning composition according to the present invention comprises at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 10 to 13 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 10 to 13 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 10 to 13 carbon atoms, which is different from the first linear 1 ,2-alkanediol.
- fragment fragment boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 10 to 13 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 10 to 13 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 10 to 13 carbon atoms, which
- the detergent and/or cleaning composition according to the present invention comprises at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 11 to 12 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 11 to 12 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 11 to 12 carbon atoms, which is different from the first linear 1 ,2-alkanediol.
- fragment fragment boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a carbon chain of 11 to 12 atoms, or a mixture comprising at least one first linear 1 ,2-alkanediol having a carbon chain of 11 to 12 carbon atoms and one or more second linear 1 ,2-alkanediols having a carbon chain of 11 to 12 carbon atoms, which
- the detergent and/or cleaning compositions according to the present invention comprise at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a log Pow value of ⁇ 1 , or a mixture comprising at least one first linear 1 ,2-alkanediol having a log Pow value of ⁇ 1 and one or more second linear 1 ,2-alkanediol having a log Pow value of ⁇ 1 , which is different from the first linear 1 ,2-alkanediol.
- the Pow value is the partition coefficient of a chemical compound for the two-phase system consisting of the two immiscible solvents n-octanol and water at equilibrium. This value is therefore a comparison of the solubility of the solute in these two liquids. Hence the partition coefficient measures how hydrophilic or hydrophobic a chemical substance is.
- the log Pow value is a constant defined in the following manner:
- Partition Coefficient, P [n-octanol]/[water] where [ ] indicates the concentration of solute in the organic and/or aqueous partition.
- the log Pow value is determined at a standard temperature of 25 °C.
- the log Pow value ⁇ 1 means the compound has a higher affinity for the aqueous phase (it is more hydrophilic) and, thus, more soluble in water; a log Pow value > 1 denotes a higher concentration in the lipid phase (i.e. , the compound is more lipophilic) and, thus, more soluble in fat-like solvents.
- 1 ,2-alkanediols having a Pow value of ⁇ 1 are particularly suitable (fragrance) boosting agents within the meaning of the present invention, which can also efficiently be incorporated into a broad range of detergent and/or cleaning compositions.
- the aforesaid 1 ,2-alkanediols exhibit outstanding improved cleaning properties in a detergent and/or cleaning composition and provide for improved malodor reduction and/or coverage.
- detergent and/or cleaning compositions comprising 1 ,2-alkanediols having a Pow value of ⁇ 1 show improved olfactory properties compared to detergent and/or cleaning composition without the addition of such 1 ,2- alkanediols.
- the detergent and/or cleaning composition according to the present invention comprises at least one (fragrance) boosting agent selected from the group consisting of at least one linear 1 ,2-alkanediol having a log Pow value of > 1 , or a mixture comprising at least one first linear 1 ,2-alkanediol having a log Pow value of > 1 and one or more second linear 1 ,2-alkanediol having a log Pow value of > 1 , which is different from the first linear 1 ,2-alkanediol.
- fragment fragment
- Said 1 ,2-alkanediols are more soluble in soluble in fat-like solvents, for example n- octanol.
- 1 ,2-alkanediols having a Pow value of > 1 are suitable (fragrance) boosting agents, which can also efficiently be incorporated into a broad range of detergent and/or cleaning compositions and provide for improved malodor reduction and/or coverage.
- the aforesaid 1 ,2-alkanediols exhibit outstanding improved cleaning and fragrance properties in a detergent and/or cleaning composition.
- detergent and/or cleaning compositions comprising 1 ,2-alkanediols having a Pow value of > 1 show improved olfactory properties compared to detergent and/or cleaning composition without the addition of such 1 ,2-alkanediols.
- alkanediol within the context of the present invention also includes its stereoisomers. Stereoisomers are molecules that have the same molecular formula and differ only in how their atoms are arranged in three-dimensional space.
- the linear alkanediol of the invention or the first linear alkanediol having a carbon chain of 5 to 14 carbon atoms or the second linear alkanediol having a carbon chain of 5 to 14 carbon atoms as described above in detail encompass the following stereoisomers:
- the terms “1 ,2-diol”, “2,3-diol” or “3,4-diol” includes both the corresponding S-configured enantiomers and also the R-enantiomer as well as arbitrary mixtures of these S- and R-configured enantiomers, i.e. mixtures of racemates of the respective diols.
- the alkanediol mixture of the detergent and/or cleaning composition according to the present invention comprises the 1 ,2-heptanediol and the 2,3-heptanediol in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2 or still more preferred in a ratio in a range of 90 : 10 to 95 : 5.
- 1 ,2- heptanediol and 2,3-heptanediol are comprised in the mixture preferably in a ratio in a range of 98 : 2 to 99.9 : 0.1.
- 1 ,2- heptanediol and 2,3-heptanediol are comprised in the alkanediol mixture preferably in a ratio in a range of 95 : 5 to 99.9 : 0.1.
- 1 ,2-heptanediol and 2,3-heptanediol are comprised in the mixture of the detergent and/or cleaning composition according to the present invention in a ratio of > 95 : ⁇ 5, more preferred in a ratio of > 96 : ⁇ 4; still more preferred in a ratio of > 97 : ⁇ 3, and most preferred in a ratio of > 98 : ⁇ 2.
- mixtures of the detergent and/or cleaning composition according to the present invention comprise 1 ,2-heptanediol and 2,3-heptanediol in a ratio of > 95 : ⁇ 5, including the ratios > 95.5 : ⁇ 4.5; > 96 : ⁇ 4; > 96.5 : ⁇ 3.5; > 97 : ⁇ 3; > 97.5 : 2,5 and > 98.0 : ⁇ 2.0.
- the alkanediol mixture of the detergent and/or cleaning composition according to the present invention comprises 1 ,2-heptanediol and 2,3-heptanediol in a ratio of > 98 : ⁇ 2, including the ratios of > 98.1 : ⁇ 1.9; > 98.2 : ⁇ 1.8; > 98.3 : ⁇ 1.7; > 98.4 : ⁇ 1.6; > 98.5 : ⁇ 1.5; > 98.6 : ⁇ 1.4; > 98.7 : ⁇ 1.3; > 98.8 : ⁇ 1.2; > 98.9 : ⁇ 1.1 ; > 99 : ⁇ 1.0; > 99.1 : ⁇ 0.9; > 99.2 : ⁇ 0.8; > 99.3 : ⁇ 0.7; > 99.4 : ⁇ 0.6; > 99.5 : ⁇ 0.5; > 99.6 : ⁇ 0.4; > 99.7
- the at least one first linear alkanediol and the one or more second linear alkanediol as defined in detail above, are present in the alkanediol mixture according to the present invention in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2, still more preferred in a ratio in a range of 90 : 10 to 95 : 5.
- the first linear alkanediol and the second linear alkanediol are comprised in the mixture preferably in a ratio in a range of 98 : 2 to 99.9 : 0.1
- the first linear alkanediol and the second alkanediol are comprised in the alkanediol mixture preferably in a ratio in a range of 95 : 5 to 99.9 : 0.1 .
- the first linear alkanediol and the second alkanediol are comprised in the mixture of the detergent and/or cleaning composition according to the present invention in a ratio of > 95 : ⁇ 5, more preferred in a ratio of > 96 : ⁇ 4; still more preferred in a ratio of > 97 :
- Most of all the mixtures of the detergent and/or cleaning composition according to the present invention comprises the first linear alkanediol and the second linear alkanediol in a ratio of > 95 : ⁇ 5, including the ratios > 95.5 : ⁇ 4.5; > 96 : ⁇ 4; > 96.5 : ⁇ 3.5; > 97 : ⁇ 3; > 97.5 : 2,5 and > 98.0 : ⁇ 2.0.
- the alkanediol mixture of the detergent and/or cleaning composition according to the present invention comprises the first linear alkanediol and the second alkanediol in a ratio of > 98 : ⁇ 2, including the ratios of > 98.1 : ⁇ 1.9; > 98.2 : ⁇ 1.8; >
- said ratio ranges for the first and second alkanediol are switched, such that the one or more second alkanediol is the main component and the at least one first alkanediol is the secondary component.
- the alkanediol mixture comprises as first linear alkanediol an 1 ,2-alkanediol, such as 1 ,2-pentanediol, 1 ,2-hexanediol,
- the alkanediol mixture comprises as first linear alkanediol an 1 ,2-alkanediol, such as 1 ,2-heptanediol, 1 ,2-octanediol, 1 ,2-nonanediol, 1 ,2-decanediol,
- 2.3-nonanediol 2,3-decanediol, 2,3-undecanediol, 2,3-dodecanediol, 2,3-tridecanediol, or 2,3- tetradecanediol, in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2, still more preferred in a ratio in a range of 90 : 10 to 95 : 5.
- the alkanediol mixture comprises as first linear alkanediol an 2,3-alkanediol, such as 2,3-pentanediol, 2,3- hexanediol, 2,3-heptanediol, 2,3-octanediol, 2,3-nonanediol, 2,3-decanediol, 2,3- undecanediol, 2,3-dodecanediol, 2,3-tridecanediol, or 2,3-tetradecanediol, and as second linear alkanediol the corresponding 1 ,2-alkanediols, such as 1 ,2-pentanediol, 1 ,2-hexanediol,
- the alkanediol mixture comprises as first linear alkanediol an 2,3-alkanediol, such as 2,3-heptanediol, 2,3-octanediol, 2,3-nonanediol,
- 1.2-octanediol 1 ,2-nonanediol, 1 ,2-decanediol, 1 ,2-undecanediol, 1 ,2-dodecanediol, 1 ,2- tridecanediol, or 1 ,2-tetradecanediol, in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2, still more preferred in a ratio in a range of 90 : 10 to 95 : 5.
- alkanediol mixtures comprising a combination of a 1 ,2-alkanediol as first linear alkanediol and the corresponding 2,3-alkanediol as second linear alkanediol, such as
- the first linear alkanediol and the second linear alkanediol are present in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2 or still more preferred in ratio in a range of 90 : 10 to 95 : 5.
- a preferred variant according to the present invention also encompasses a mixture including as first linear alkanediol 1 ,2-hexanediol and as second linear alkanediol 1 ,2- octanediol either in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2 or still more preferred in a ratio in a range of 90 : 10 to 95 : 5.
- the present invention relates to a detergent and/or cleaning composition as specified herein,
- the mixture comprising 1 ,2-heptanediol and 2,3-heptanediol comprises the 1 ,2- heptanediol and the 2,3-heptanediol in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2, still more preferred in a ratio of 90 : 10 to 95 : 5; or
- the mixture comprising at least one first linear alkanediol and one or more second linear alkanediol, as defined herein, comprises the first linear alkanediol and the second alkanediol in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2, still more preferred in a ratio of 90 : 10 to 95 : 5.
- the present invention relates to a detergent and/or cleaning composition as specified herein, wherein the mixture comprising at least one first linear alkanediol and one or more second linear alkanediol, as defined herein, comprises the first linear alkanediol and the second alkanediol in a ratio in a range of 50 : 50 to 99.9 : 0.1 , preferably in a ratio in a range of 75 : 25 to 99 : 1 , more preferred in a ratio in a range of 80 : 20 to 98 : 2, still more preferred in a ratio of 90 : 10 to 95 : 5.
- the alkanediols are obtained either by synthesis from petrochemical or other fossil fuel sources by known methods such as olefin bis-hydroxylation, hydrolysis from epoxide or various chemical transformations or from bioderived feedstock by fermentation or from biobased natural and renewable feedstock such as biomass by catalytic synthesis as it is described in US 2019/0241491 A1 and US 2020/0189995 A1.
- the alkanediols used according to the present invention comprise either petrochemically derived and biobased natural and renewable feedstock derived alkanediols.
- the alkanediols are from bio-based sources and are thus bio-alkanediols.
- the further or second additional (fragrance) boosting agent of the boosting mixture (c) of the detergent and/or cleaning composition according to the present invention is either (c") glyceryl caprylate, or (c IH ) 4- hydroxyacetophenone, or (c lv ) ethyl hexyl glycerin, or any mixture of the aforementioned further boosting agents.
- Glyceryl caprylate, (c") is a natural emollient derived from glycerin and plant fatty acids, usually appearing as a white waxy solid. This ingredient is used in many skincare products for its emollient and moisturizing properties, to help maintain the balance of moisture in the skin. In additional, glyceryl caprylate (c 11 ) is used as antimicrobial active component in cosmetic preparations.
- oily, surface-active co-emulsifier glyceryl caprylate is a further suitable (fragrance) boosting agent within the meaning of the present invention.
- the 4-HAP is a further suitable a (fragrance) boosting agent within the meaning of the present invention.
- Ethyl hexyl glycerin (EHG), (c lv ): is a relatively new cosmetic ingredient that is used for its surfactant, dispersant, emollient, skinconditioning and antimicrobial properties.
- Ethyl hexyl glycerin (EHG or octoxyglycerin) is a glyceryl ether and a vicinal diol.
- EHG is suitable to provide a fragrance boosting effect in detergent and/or cleaning compositions within the meaning of the present invention.
- the above specified further (fragrance) boosting agents (c"), (c IH ), and (c lv ) can be used either individually or in the form of mixtures of two, or even more of said (fragrance) boosting agents. Accordingly, in the boosting mixture / composition (c) at least one of the further (or second) (fragrance) boosting agents (c"), (c IH ), and (c lv ) is comprised as a second boosting component in addition to the at least one alkanediol component.
- fragment boosting agents (c"), (c IH ), and (c lv ) or mixtures or two or three (fragrance) boosting agents (c"), (c IH ), and (c lv ) can also be used in admixture with one or two alkanediol boosting agents (c 1 ) as defined herein.
- such mixtures contain two, or even more boosting agents as defined herein.
- the boosting component (c) is based on a mixture of at least one first alkanediol boosting component (first boosting agent / component) as specified above in combination with at least one further or second boosting component (further or second boosting agent / component) selected from the group consisting of glyceryl caprylate, 4- hydroxyacetophenone, ethyl hexyl glycerin or any mixture of these further boosting agents.
- the detergent and/or cleaning composition according to the present invention includes any of the following mixtures/combinations:
- a mixture comprising (c 11 ) glyceryl caprylate and (c 111 ) 4-hydroxyacetophenone and (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above;
- a mixture comprising (c") glyceryl caprylate and (c lv ) ethyl hexyl glycerin and (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above;
- a mixture comprising (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above, and (c") glyceryl caprylate; a mixture comprising (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above, and (c IH ) 4-hydroxyacetophenone; a mixture comprising
- the detergent and/or cleaning composition according to the present invention includes any of the following boosting agent mixtures/combinations selected from the group consisting of:
- the list of boosting agents ((c1.1), (c1.2), (c2.1), (c2.2), (c3.1), (c3.2), (c 1 ), (c 11 ), (c 111 ), (c lv ), (c)) specified herein can be arbitrary combined with the list of surfactants (a) as specified herein.
- the list of boosting agents ((c1.1), (c1.2), (c2.1), (c2.2), (c3.1), (c3.2), (c 1 ), (c 11 ), (c 111 ), (c lv ), (c)) specified herein can be arbitrary combined with the list of odorous substances as specified herein.
- the list of surfactants (a) as specified herein can be arbitrary combined with the list of odorous substances as specified herein.
- the detergent and/or cleaning composition according to the present invention comprises one of the following combinations of components (b) and (c):
- extracts of natural raw fragrance materials plus the following (fragrance) boosting agents (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c") glyceryl caprylate; (c IH ) 4-hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin; or
- hydrocarbons plus the following (fragrance) boosting agents at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c") glyceryl caprylate; (c IH ) 4- hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin; or
- aliphatic alcohols plus the following (fragrance) boosting agents (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c") glyceryl caprylate; (c IH ) 4- hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin; or aliphatic aldehydes and the acetals thereof plus the following (fragrance) boosting agents: (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear al
- lactones plus the following (fragrance) boosting agents at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c") glyceryl caprylate; (c IH ) 4-hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin.
- the detergent and/or cleaning composition according to the present invention comprises one of the following combinations of components (b) and (c):
- ester type fragrance substances plus the following (fragrance) boosting agents: (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c") glyceryl caprylate; (c IH ) 4- hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin; or
- ⁇ ether type fragrance substances plus the following (fragrance) boosting agents: ( cl ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c") glyceryl caprylate; (c IH ) 4- hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin; or
- aldehyde type fragrance substances plus the following (fragrance) boosting agents: (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c 11 ) glyceryl caprylate; (c 111 ) 4- hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin; or
- ⁇ ketone type fragrance substances plus the following (fragrance) boosting agents: (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c") glyceryl caprylate; (c IH ) 4- hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin; or
- hydrocarbon type fragrance substances plus the following (fragrance) boosting agents: (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediol having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol, as defined above; in combination with at least one of the following further boosting agents: (c") glyceryl caprylate; (c IH ) 4-hydroxyacetophenone; or (c lv ) ethyl hexyl glycerin.
- said combinations comprising an odorous component and a (fragrance) boosting agent mixture do not only have a remarkable fragrance performance, but are simultaneously beneficial in laundry detergents, detergents for manual and automatic dishwash, hard surface cleaners, cleaners for medical and dental instruments, stain removers and the like, since they exhibit an enhanced cleaning activity combined with an improved malodor reduction and/or coverage and efficiently allow for the prevention malodor formation, resulting in an improved performance upon application, in comparison to a detergent and/or cleaning composition without the addition of said mixtures of (fragrance) boosting agents.
- the list of a boosting agents and their mixtures specified herein can be arbitrary combined with the list of surfactants specified herein.
- the detergent and/or cleaning compositions can further include one or more antimicrobial agents.
- antimicrobial component in the context of the present invention refers to a group of substances, in particular to agents that kills microorganisms, such as bacteria, yeast and/or fungi, or stops or inhibits their growth, which prevents products from microbial contamination. Without the addition of such agents the products spoil, which may manifest changes in smell, discoloration, mould growth, gas formation, the separation of emulsions or changes in viscosity, rendering the product unacceptable to the consumer.
- Suitable antimicrobial agents include, but are not limited to, the antimicrobial classes such as phenolics, quaternary ammonium compounds, metal derivatives, amines, alkanol amines, nitro derivatives, analides, organosulfur and sulfur-nitrogen compounds and miscellaneous compounds.
- phenolic agents include pentachlorophenol, orthophenylphenol, phenoxyethanol.
- Exemplary quaternary antimicrobial agents include benzalkonium chloride, cetylpyridiniumchloride, amine and nitro containing antimicrobial compositions such as hexahydro-1 , 3, 5-tris(2-hydroxyethyl)-s-triazine, dithiocarbamates such as sodium dimethyldithiocarbamate, and a variety of other materials known in the art for their antimicrobial properties.
- antimicrobial agents include gluteraldehyde, Bronopol (2-bromo-2-nitropropane-1 ,3-diol), silver, and isothiazolones such as methylisothiazolinone, ethyl lauroyl arginate HCI, sold under the tradename NeoIoneTM, sodium benzoate, benzyl alcohol, or methylbenzyl alcohol.
- the detergent and/or cleaning compositions are further combined with benzyl alcohol, methylbenzyl alcohol, phenoxyethanol, and any mixture thereof.
- Said substances have a broad-spectrum activity against microorganisms and are added to the detergent and/or cleaning compositions to inhibit microbial spoilage, and, thus, for stabilizing purposes.
- the antimicrobial agents are added to liquid detergent and/or cleaning due to their higher water content, which makes such compositions susceptible against microbial infestation and growth.
- an antimicrobial agent is included in the inventive detergent and/or cleaning compositions, it is preferably added in an amount between about 0.001 % by weight and about 5 % by weight, based on the total weight of the composition.
- the antimicrobial component is present in the composition according to the present invention in an amount of 0.0001 % to 15.0 % by weight, based on the total weight of the composition.
- the composition comprises the antimicrobial component in an amount of 0.001 % to 10.0 % by weight, based on the total weight of the composition.
- the antimicrobial component is advantageously used in the composition in an amount of at 0.001 % to 5.0 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition according to the present invention thus preferably comprises the at least one antimicrobial compound in an amount of 0.0001 % to 15.0 % by weight, particularly in an amount of 0.001 % to 10.0 % by weight, most particularly in an amount of 0.001 % to 5.0 % by weight, based on the total weight of the composition.
- compositions according to the present invention The activity of these antimicrobial compounds is synergistically improved based on the formulation of the compositions according to the present invention, and is particularly improved in a synergistical manner based on component (c) as specified herein.
- the detergent and/or cleaning composition according to the present invention can additionally comprise at least one enzyme or an enzyme formulation, comprising at least one enzyme as further component that provides additional cleaning benefits.
- Enzymes are known as effective chemicals for use with detergents and other cleaning agents to break down soils. Enzymes break down soils, make them more soluble, and enable surfactants to remove them from a surface to provide enhanced cleaning of a substrate. Specifically, enzymes can provide desirable activity for removal of, for example, protein-based, carbohydrate-based, or triglyceride-based stains from substrates. In addition, enzymes also help to improve wash results at lower temperatures. As a result, enzymes have been used for various cleaning applications in order to digest or degrade soils such as grease, oils (e.g. vegetable oils or animal fat), protein, carbohydrate, or the like. For example, enzymes may be added as a component of a composition for laundry, textiles, ware washing, cleaning-in-place, cleaning drains, floors, carpets, medical or dental instruments, meat cutting tools, hard surfaces, personal care, or the like.
- oils e.g. vegetable oils or animal fat
- enzymes may be added as a component of a composition for laundry,
- Enzymes suitable for the detergent and/or cleaning compositions can act by degrading or altering one or more types of soil residues encountered on a fabric or textile thus removing the soil or making the soil more removable by a surfactant or other component of the cleaning composition. Both degradation and alteration of soil residues can improve detergency by reducing the physicochemical forces that bind the soil to the instrument or device being cleaned, e.g., the soil becomes more water soluble.
- one or more proteases can cleave complex, macro molecular protein structures present in soil residues into simpler short chain molecules which are, of themselves, more readily desorbed from surfaces, solubilized or otherwise more easily removed by detersive solutions containing said proteases.
- Detersive enzymes according to the present invention have a cleaning, destaining or otherwise beneficial effect as a component of a detergent and/or cleaning composition for instruments, devices, or equipment, such as medical or dental instruments, devices, or equipment; or for laundry, textiles, ware-washing, cleaning-in-place, drains, carpets, meat cutting tools, hard surfaces, personal care, or the like.
- Enzymes that can be used according to the present invention include enzymes that provide desirable activity for removal of protein-based, carbohydrate-based, or triglyceride- based stains from substrates; for cleaning, destaining, and sanitizing presoaks, such as presoaks for medical and dental instruments, devices, and equipment; presoaks for flatware, cooking ware, and table ware; or presoaks for meat cutting equipment; for machine ware washing; for laundry and textile cleaning and destaining; for carpet cleaning and destaining; for cleaning-in-place (CIP) and destaining-in-place; for cleaning and destaining food processing surfaces and equipment; for drain cleaning; presoaks for cleaning; and the like.
- presoaks for medical and dental instruments, devices, and equipment
- presoaks for flatware, cooking ware, and table ware
- presoaks for meat cutting equipment
- machine ware washing for laundry and textile cleaning and destaining
- Suitable enzymes used according to the present invention are selected from the group consisting of proteases, amylases, lipases, cellulases, cutinases, gluconases, peroxidases, pectinases, mannanases, esterases, hemicellulases, xylanases, phospholipases, pectate lyases, keratinases, reductases, nucleases (including Dnase and/or Rnase), phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases, malanases, B-glucanases, arabinosidases, hyaluronidases, chondroitinase, oxidoreductase, and any mixture thereof.
- the enzymes used according to the present invention are of any suitable origin, such as vegetable, animal, bacterial, fungal or yeast origin.
- protease or mixture of proteases can be used in the detergent and/or cleaning compositions, provided that the selected enzyme is stable in the desired pH range (between about 6 and about 9).
- the protease enzymes can be derived from a plant, an animal, or a microorganism such as a yeast, a mold, or a bacterium.
- Preferred protease enzymes include, but are not limited to, the enzymes derived from Bacillus subtilis, Bacillus licheniformis and Streptomyces griseus.
- Protease enzymes derived from B. subtilis are most preferred.
- protease can be purified or a component of a microbial extract, and either wild type or variant (either chemical or recombinant).
- exemplary proteases are commercially available under the following trade names Alcalase®, Blaze®, Savinase®, Esperase®, and Progress UNOTM, Liquanase® and Pristine®, each available from Novozymes; and Preferenz® P and Excellenz® P, each available from DUPONT/IFF.
- Amylases Any amylase or mixture of amylases, from any source, can be used in the detergent and/or cleaning compositions, provided that the selected enzyme is stable in the desired pH range (between about 6 and about 9).
- the amylase enzymes can be derived from a plant, an animal, or a microorganism such as a yeast, a mold, or a bacterium.
- Preferred amylase enzymes include, but are not limited to, those derived from a Bacillus, such as B. licheniformis, B. amyloliquefaciens, B. subtilis, or B. stearothermophilus. Amylase enzymes derived from B. subtilis are most preferred.
- amylase can be purified or a component of a microbial extract, and either wild type or variant (either chemical or recombinant).
- Preferred amylases are commercially available under the trade names Stainzyme® and Amplify®, each available from Novozymes; and Preferenz® S, available from DUPONT/IFF.
- Lipases Any lipase or mixture of lipases, from any source, can be used in the detergent and/or cleaning compositions, provided that the selected enzyme is stable in the desired pH range (between about 6 and about 9).
- the lipase enzymes can be derived from a plant, an animal, or a microorganism such as a fungus or a bacterium.
- Preferred protease enzymes include, but are not limited to, the enzymes derived from a Pseudomonas, such as Pseudomonas stutzeri ATCC 19.154, or from a Humicola, such as Humicola lanuginosa (typically produced recombinantly in Aspergillus oryzae).
- the lipase can be purified or a component of a microbial extract, and either wild type or variant (either chemical or recombinant).
- Preferred lipases are commercially available under the trade names Lipex®, available from Novozymes, and Preferenz® L, available from DUPONT/IFF.
- Cellulases Any cellulase or mixture of cellulases, from any source, can be used in the detergent and/or cleaning compositions, provided that the selected enzyme is stable in the desired pH range (between about 6 and about 9).
- the cellulase enzymes can be derived from a plant, an animal, or a microorganism such as a fungus or a bacterium.
- Preferred cellulase enzymes include, but are not limited to, those derived from Humicola insolens, Humicola strain DSM1800, or a cellulase 212-producing fungus belonging to the genus Aeromonas and those extracted from the hepatopancreas of a marine mollusc, Dolabella Auricula Solander.
- the cellulase can be purified or a component of a microbial extract, and either wild type or variant (either chemical or recombinant).
- Preferred cellulases are commercially available under the trade names Celluclean® and Carezyme®, each available from Novozymes; and Revitalenz®, available from DUPONT/IFF.
- Preferred enzyme selections depend upon the conditions of final utility, including the physical product form, use pH, use temperature, and soil types to be degraded or altered and are influenced by factors such as pH-activity and/or stability optima, thermostability, and stability to active detergents, builders and the like.
- the enzyme can be chosen to provide optimum activity and stability for any given set of utility conditions. In this respect, bacterial or fungal enzymes are preferred.
- protease enzymes are particularly advantageous for cleaning soils containing protein, e.g. egg, milk, meat residue, or the like.
- the amylase enzymes are particularly advantageous for removing starch-based soils, such as pasta and rice.
- the lipase enzymes are particularly advantageous for cleaning soils including fat/grease.
- ware wash applications may use a protease enzyme as it is effective at the high temperatures of the ware wash machines and is effective in reducing protein-based soils.
- Protease enzymes are particularly advantageous for cleaning soils containing protein, such as blood, cutaneous scales, mucus, grass, food (e.g. egg, milk, spinach, meat residue, tomato sauce), or the like.
- the enzyme contained in detergent and/or cleaning composition may be varied based on the particular cleaning application and the types of soils in need of cleaning.
- the temperature of a particular cleaning application will impact the enzymes selected for an enzyme composition according to the invention.
- Ware wash applications for example, clean substrates at temperatures in excess of approximately 60 °C, or in excess of approximately 70 °C, or between approximately 65 °C to 80 °C, and enzymes such as proteases are desirable due to their ability to retain enzymatic activity at such elevated temperatures.
- Laundry applications for example, clean laundry at temperatures in excess of approximately 40 °C, or in excess of approximately 50 °C, or between approximately 65 °C to 95 °C, and enzymes such as proteases are desirable due to their ability to retain enzymatic activity at such elevated temperatures.
- the enzyme in the detergent and/or cleaning composition is a single enzyme.
- the enzyme in the detergent and/or cleaning composition is preferably an enzyme cocktail of two, three, four or even more different enzymes.
- laundry detergents contain from two (preferably protease and amylase) to five or even to six enzymes.
- the at least one enzyme is selected from the group consisting of a protease, an amylase, a lipase, a gluconase, a cellulase, a peroxidase, or a mixture thereof.
- the enzyme in the composition is a protease, an amylase, a lipase, a cellulase, a gluconase, a peroxidase, a mannanase, or any mixture thereof.
- the enzyme is a mixture of protease, an amylase, a lipase, a cellulase and/or pectate lyase.
- Preferred detersive enzymes include a hydrolase such as a protease, an amylase, a lipase, or a combination thereof.
- the enzyme is a protease, amylase, lipase, cellulose, peroxidase, gluconase, or any mixture thereof.
- the enzyme in the detergent and/or cleaning compositions disclosed here is a protease, amylase, lipase, or any mixture thereof.
- the enzyme is a protease, an amylase, or a mixture thereof.
- the enzyme is a protease, a lipase, or a mixture thereof.
- the enzyme is selected from an amylase, a lipase, or a mixture thereof.
- the enzyme is a protease.
- the enzyme is an amylase.
- the enzyme is a lipase.
- the enzyme is a cellulase.
- Preferred enzymes in solid detergent and/or cleaning compositions according to the present invention include a protease, an amylase, a lipase, a cellulase, or a combination thereof.
- Preferred enzymes in detergent and/or cleaning compositions according to the present invention for cleaning medical or dental devices or instruments include a protease, an amylase, a cellulase, a lipase, or a combination thereof.
- Preferred enzymes in detergent and/or cleaning compositions according to the present invention for food processing surfaces and equipment include a protease, a lipase, an amylase, a gluconase, or a combination thereof.
- Preferred enzymes in detergent and/or cleaning compositions according to the present invention for laundry or textiles include a protease, a cellulase, a lipase, a peroxidase, or a combination thereof.
- Preferred enzymes in detergent and/or cleaning compositions for carpets include a protease, an amylase, or a combination thereof.
- Preferred enzymes in detergent and/or cleaning compositions according to the present invention for meat cutting tools include a protease, a lipase, or a combination thereof.
- Preferred enzymes in detergent and/or cleaning compositions according to the present invention for hard surfaces include a protease, an amylase, a lipase, or a combination thereof.
- Preferred enzymes in detergent and/or cleaning compositions according to the present invention for drains include a protease, an amylase, a lipase, or a combination thereof.
- the enzymes are preferably selected from the group consisting of protease, amylase, lipase, mannanase, pectate lyase, and any mixture thereof.
- the enzyme is preferably cellulase.
- oxidoreductases are added to the detergent and/or cleaning composition according to the present invention.
- the oxidoreductases are selected from the group consisting of oxidases, oxygenases, catalases, peroxidases, such as halo-, chloro-, bromo-, lignin-, glucose- or manganeseperoxidases, dioxygenases or laccases, such as phenoloxidases and polyphenoloxidases, and any mixture thereof.
- Enzymes are typically not used in combination with bleaching agents in liquid detergent and/or cleaning compositions as they are not stable (enzyme denaturation) but in powdered compositions percarbonate and enzymes are typically added.
- the enzyme(s) are added to the detergent and/or cleaning compositions either as single enzyme formulation, as enzyme cocktail formulation comprising a mixture of different enzymes or still more preferred as formulation in admixture with stabilizers, preferably with one or more enzyme stabilizers, buffers, and the like.
- the enzymes can be encapsulated both for the solid and for the liquid administration form, for example by spray drying or extrusion of the enzyme solution together with a preferably natural polymer, or in the form of capsules, for example those in which the enzymes are enclosed, such as in a solidified gel, or in those of the core-shell type, in which an enzyme-containing core is coated with a protective layer that is impermeable to water, air, and/or chemicals.
- Further active substances for example stabilizers, emulsifiers, pigments, bleaches or dyes, can additionally be applied in superimposed layers.
- Such capsules are applied using methods known per se, for example by vibratory or roll granulation or in fluidized bed processes.
- Such granulates are low in dust, for example as a result of the application of polymeric film formers and are storage-stable on account of the coating.
- the enzyme is added to the detergent and/or cleaning composition as a single enzyme.
- the enzyme added to the detergent and/or cleaning composition is preferably an enzyme cocktail of two, three, four or even more different enzymes.
- an enzyme cocktail typically contains from two (preferably protease and amylase) to six enzymes.
- the enzyme(s) is/are normally incorporated into the detergent and/or cleaning composition according to the disclosure in an amount sufficient to yield effective cleaning during a washing procedure.
- An amount effective for cleaning refers to an amount that produces a clean, sanitary, and, preferably, corrosion free appearance to the material cleaned, particularly for medical or dental devices or instruments.
- An amount effective for cleaning also can refer to an amount that produces a cleaning, stain removal, soil removal, whitening deodorizing, or freshness improving effect on substrates such as medical or dental devices or instruments and the like. Such a cleaning effect can be achieved with amounts of enzyme as low as about 0.02 % by weight of the detergent and/or cleaning composition.
- suitable cleaning can typically be achieved when an enzyme is present at about 0.0001 % to about 35 % by weight; preferably about 2 % to about 15 % by weight; preferably about 3 % to about 10 % by weight; preferably about 4 % to about 8 % by weight; preferably about 4 %, about 5 %, about 6 %, about 7 %, or about 8 % by weight, based on the total weight of the composition.
- the higher enzyme levels are typically desirable in highly concentrated cleaning formulations.
- suitable cleaning can typically be achieved when an enzyme is present in an amount of 0.0001 % to 5 % by weight, based on the total weight of the composition.
- the enzyme is present in an amount of 0.0001 % to 4 % weight, based on the total weight of the composition.
- the detergent and/or cleaning composition according to the present invention comprises the enzyme in an amount of 0.001 % to 3 % by weight, based on the total weight of the composition.
- the enzyme is present in the detergent and/or cleaning composition in an amount of 0.01 % to 2 % by weight, based on the total weight of the composition.
- the enzyme is present in the detergent and/or cleaning composition in an amount of 0.05 % to 2 % by weight, based on the total weight of the composition.
- the enzyme is present in the detergent and/or cleaning composition according to the present invention in an amount of 0.05 % to 2.0 % by weight.
- proteases and amylase are used in higher concentrations in the detergent and/or cleaning compositions, namely proteases in an amount of 0.4 % to 1.5 % by weight, amylases in an amount of 0.05 % to 0.6 % by weight, based on the total weight of the composition.
- the above amounts relate to the total content of the enzymes in the mixture, i.e. the amount is the sum of the content of all enzymes in the mixture.
- the detergent and/or cleaning composition according to the present invention optionally comprises at least one enzyme stabilizer, to further stabilize the enzyme in the detergent and/or cleaning composition from loss of activity (i.e. retain proteolytic activity or enzymatic retention).
- the enzymes are stabilized by the further enzyme stabilizer through a physical protection by means of a protective layer.
- the at least one enzyme is added to the detergent and/or cleaning composition according to the present invention as enzyme formulation in mixture with one or more stabilizer(s), preferably with one or more enzyme stabilizers, and optionally buffers, additives, and the like.
- Suitable enzyme stabilizers are known to the person skilled in the art.
- the enzyme formulation with the enzyme stabilizer is added to the detergent and/or cleaning composition in such amounts, that the enzyme stabilizer is present in the detergent and/or cleaning composition in an amount of 0.0001 % to 5 % by weight, based on the total weight of the detergent and/or cleaning composition.
- the enzyme stabilizer is present in an amount of 0.001 % to 4 % by weight, based on the total weight of the detergent and/or cleaning composition.
- the detergent and/or cleaning composition includes the enzyme stabilizer in an amount of 0.01 % to 3 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning compositions according to the present invention with other active substances and/or additives, depending on the purpose of the composition, in order to obtain a ready-for-use composition or formulation.
- the active ingredients provide the desired properties and functionalities to the detergent and/or cleaning compositions according to the present invention.
- the term “functional ingredient” or “functional additive” includes an ingredient that provides a beneficial property in a particular use. Some particular examples of functional ingredients are discussed in more detail below. However, a broad variety of other functional ingredients may be used.
- the detergent and/or cleaning compositions according to the present invention may comprise any of the ingredients customarily found in such compositions, such as, for example organic solvents, builders, and additional auxiliaries such as soil repellents, thickeners, colorants and fragrances or the like.
- the detergent and/or cleaning composition according to the present invention can advantageously be combined or varied with at least one active substance and/or at least one (functional) additive, such as for example anti-static agents, anti-wrinkling agents, antimicrobial agents, dye transfer inhibition agents (dye transfer inhibiting agents or dye transfer inhibitors) / color protection agents, dye scavengers, dyes / coloring agents, greying inhibitors, odor removal / odor capturing agents, soil shielding / soil releasing agents, antiredeposition agents, ultraviolet light protection agents, sanitizing agents, disinfecting agents, water repellency agents, insect repellency agents, anti-pilling agents, souring agents, mildew removing agents, allergicide agents, solubility modifiers, rheology modifiers / viscosity modifiers or thickeners, dispersing agents, water softeners, buffers, (organic) solvents, defoamers / foam inhibitors / suds suppressor, foam stabilizers, fabric soft
- Boosting agents (c) within the meaning of the present invention are mixtures of (c1.1) 1 ,2-heptanediol, (c2.1) 2,3-heptanediol, (c3.1) a mixture of 1 ,2-heptanediol and 2,3- heptanediol, or (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol with (c") glyceryl caprylate and/or (c IH ) 4-hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin.
- boosting agents (c) within the meaning of the present invention are mixtures of (c 1 ) at least one linear alkanediol having a carbon chain of 5 to 14 carbon atoms or a mixture comprising at least one first linear alkanediol having a carbon chain of 5 to 14 carbon atoms and one or more second linear alkanediols having a carbon chain of 5 to 14 carbon atoms which is different from the first linear alkanediol with (c") glyceryl caprylate and/or (c IH ) 4-hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin.
- the boosting component (c) is based on a mixture of a first alkanediol boosting component as specified herein and at least one second boosting component selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, ethyl hexyl glycerin or any mixture thereof.
- the 1 ,2-heptanediol (c1.1) or the 2,3-heptanediol (c2.1) or the mixture comprising 1 ,2- heptanediol and 2,3-heptanediol (c3.1) according to the present invention is present in the detergent and/or cleaning composition in an amount of 0.001 % to 15.0 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition comprises the 1 ,2-heptanediol (c1.1) or the 2,3-heptanediol (c2.1) or the mixture comprising 1 ,2-heptanediol and 2,3-heptanediol (c3.1) in an amount of 0.01 % to 10.0 % by weight, based on the total weight of the composition.
- the 1 ,2- heptanediol (c1.1) or 2,3-heptanediol (c2.1) or the mixture comprising 1 ,2-heptanediol and 2,3- heptanediol (c3.1) is advantageously used in the detergent and/or cleaning composition in an amount of at 0.1 % to 5.0 % by weight, based on the total weight of the composition.
- the 1 ,2-heptanediol (c1.1) or 2,3-heptanediol (c2.1) or the mixture comprising 1 ,2-heptanediol and 2,3-heptanediol (c3.1) is advantageously used in the detergent and/or cleaning composition in an amount of at 0.3 % to 3.0 % by weight, based on the total weight of the composition.
- the 1 ,2-heptanediol (c1.1) or 2,3- heptanediol (c2.1) or the mixture comprising 1 ,2-heptanediol and 2,3-heptanediol (c3.1) is advantageously used in the detergent and/or cleaning composition in an amount of at 0.5 % to 1.0 % by weight, based on the total weight of the composition.
- the above amounts relate to the total content of the 1 ,2-heptanediol and the 2,3-heptanediol in the mixture, i.e. the amount is the sum of the content of 1 ,2-heptanediol and 2,3-heptanediol in the mixture.
- the at least one first component of the boosting component or mixture (c), i.e. the alkanediol component (c 1 ) according to the present invention is present in the detergent and/or cleaning composition in an amount of 0.001 % to 15.0 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition comprises the at least one alkanediol boosting component (c 1 ) in an amount of 0.01 % to 10.0 % by weight, based on the total weight of the composition.
- the at least one alkanediol boosting component (c 1 ) is advantageously used in the detergent and/or cleaning composition in an amount of at 0.1 % to 5.0 % by weight, based on the total weight of the composition. In a still more preferred variant, the at least one alkanediol boosting component (c 1 ) is advantageously used in the detergent and/or cleaning composition in an amount of at 0.3 % to 3.0 % by weight, based on the total weight of the composition.
- the at least one alkanediol boosting component (c 1 ) is advantageously used in the detergent and/or cleaning composition in an amount of at 0.5 % to 1 .0 % by weight, based on the total weight of the composition.
- the above amounts relate to the total content of the first linear alkanediol and the second linear alkanediol(s) in the mixture, i.e. the amount is the sum of the content of the first linear alkanediol and the second linear alkanediol in the mixture.
- the detergent and/or cleaning composition comprises the 2,3-heptanediol or the 2,3-heptanediol of the mixture comprising 1 ,2-heptanediol and 2,3-heptanediol (c3.1) in an amount of 0.001 % to 15.0 % by weight, preferred in an amount of 0.01 to 10.0 % by weight, more preferred in an amount of 0.1 % to 5.0 % by weight, still more preferred in an amount of 0.3 % to 3.0 % by weight, and most preferred in an amount of 0.5 % to 1.0 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition comprises the 2,3- heptanediol or the 2,3-heptanediol of the mixture comprising 1 ,2-heptanediol and 2,3- heptanediol (c3.1) in an amount of 0.001 % to 0.5 % weight, preferably in an amount of 0.005 % to 0.1 % by weight and most preferably in an amount of 0.01 % to 0.075 % by weight, based on the total weight of the composition or detergent and/or cleaning product.
- the detergent and/or cleaning composition comprises the 2,3-alkanediol as the at least one linear alkanediol or of the mixture comprising at least one first linear alkanediol and one or more second linear alkanediol in an amount of 0.001 % to 15.0 % by weight, preferably in an amount of 0.01 % to 10.0 % by weight, more preferred in an amount of 0.1 % to 5.0 % by weight, still more preferred in an amount of 0.3 % to 3.0 % by weight, and most preferred in an amount of 0.5 to 1 .0 % by weight, based on the total weight of the composition or detergent and/or cleaning product.
- the detergent and/or cleaning composition comprises the 2,3- alkanediol as the at least one linear alkanediol or of the mixture comprising at least one first linear alkanediol and one or more second linear alkanediol in an amount of 0.001 % to 0.5 % weight, preferably in an amount of 0.005 % to 0.1 % by weight and most preferably in an amount of 0.01 % to 0.075 % by weight, based on the total weight of the composition or detergent and/or cleaning product.
- the at least one second component of the boosting component or mixture (c), i.e. the (c") glyceryl caprylate and/or (c IH ) 4-hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin (also referred to as (c1.2), (c2.2), (c3.2)) according to the present invention is/are present in the detergent and/or cleaning composition in an amount of 0.001 % to 15.0 %by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition comprises the (c 11 ) glyceryl caprylate and/or (c 111 ) 4-hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin in an amount of 0.01 % to 10.0 %by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition comprises the (c") glyceryl caprylate and/or (c IH ) 4-hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin in an amount of 0.1 % to 5.0 % by weight, based on the total weight of the composition.
- the (c") glyceryl caprylate and/or (c IH ) 4- hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin is advantageously used in the detergent and/or cleaning composition in an amount of at 0.3 % to 3.0 % by weight, based on the total weight of the composition.
- the (c") glyceryl caprylate and/or (c IH ) 4- hydroxyacetophenone and/or (c lv ) ethyl hexyl glycerin is advantageously used in the detergent and/or cleaning composition in an amount of at 0.5 % to 1.0 % by weight, based on the total weight of the composition.
- the above amounts relate to the total content of further boosting agents in the mixture, i.e. the amount is the sum of the content of the single further boosting agents in the mixture.
- the detergent and/or cleaning composition comprises the boosting component (c), i.e. a mixture of at least one (first) alkanediol boosting component (at least one boosting agent) as specified herein and at least one second boosting component (at least one further boosting agent) selected from the group consisting of glyceryl caprylate, 4- hydroxyacetophenone, ethyl hexyl glycerin or any mixture thereof in an amount of 0.001 % to 15.0 % by weight, based on the total weight of the composition, and further preferred in an amount of 0.01 % to 10.0 %by weight, based on the total weight of the composition, and even more preferred in an amount of 0.1 % to 5.0 % by weight, based on the total weight of the composition.
- boosting component c
- the boosting component (c) is advantageously used in the detergent and/or cleaning composition in an amount of at 0.3 % to 3.0 % by weight, based on the total weight of the composition. In a most preferred variant, the boosting component (c) is advantageously used in the detergent and/or cleaning composition in an amount of at 0.5 % to 1.0 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition according to the present invention thus preferably comprises a mixture of the at least one boosting agent (c 1 ) and the at least one further boosting agent selected from the group consisting of (c 11 ), (c 111 ), (c lv ), and any mixtures of these further boosting agents, in an amount of 0.001 % to 15.0 % by weight, preferred in an amount of 0.01 % to 10.0 % by weight, more preferred in an amount of 0.1 % to 5.0 % by weight, still more preferred in an amount of 0.3 to 3.0 % by weight, most preferred in an amount of 0.5 % to 1 .0 % by weight, based on the total weight of the composition.
- the above amounts relate to the total content of the boosting agents in the composition, i.e. the amount is the sum of the content of all boosting agents in the composition (alkanediol boosting agents plus further boosting agents).
- the at least one surfactant (a), (a1), (a2), (a3) is present in the detergent and/or cleaning composition according to the present invention in an amount of 0.001 % to 90 % by weight, based on the total weight of the composition.
- the surfactant is present in an amount of 0.001 % to 60 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition according to the present invention comprises the surfactant in an amount of 0.01 % to 50 % by weight and most preferred in an amount of 0.1 % to 40 % by weight, based on the total weight of the composition.
- light-duty compositions according to the present invention comprise the at least one surfactant in an amount of 0.001 % to 40 % by weight, based on the total weight of the composition.
- the at least one surfactant is present in an amount of 0.005 % to 30 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition according to the present invention preferably comprises the surfactant in an amount of 0.01 % to 25 % by weight and preferred in an amount of 0.1 % to 20 % by weight, based on the total weight of the composition.
- the above amounts relate to the total content of the surfactants in the mixture, i.e. the amount is the sum of the content of all surfactants in the mixture.
- the at least one odorous substance or mixture of odorous substances is preferably comprised in amounts of around 0.00001 % to 10 % by weight, preferably 0.0001 % to 5 % by weight and particularly preferably 0.001 % to 2 % by weight, relative to the total amount of the detergent and/or cleaning compositions.
- the at least one antimicrobial compound (component (d), (d 1 ) , (d2), (d3)) is preferably present in the composition according to the present invention in an amount of 0.0001 % to 15.0 % by weight, based on the total weight of the composition.
- the composition comprises the antimicrobial component in an amount of 0.001 % to 10.0 % by weight, based on the total weight of the composition.
- the antimicrobial component is advantageously used in the composition in an amount of at 0.001 % to 5.0 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition according to the present invention thus preferably comprises the at least one antimicrobial compound in an amount of 0.0001 % to 15.0 % by weight, particularly in an amount of 0.001 % to 10.0 % by weight, most particularly in an amount of 0.001 % to 5.0 % by weight, based on the total weight of the composition.
- the detergent and/or cleaning composition according to the present invention is used as such (i.e. as a detergent and/or cleaning product) or for the preparation of a detergent and/or cleaning product or a detergent and/or cleaning formulation.
- the detergent and/or cleaning compositions of the current disclosure are found, surprisingly, to have a superior cleaning performance and simultaneously show efficient malodor coverage and/or malodor reduction properties, compared to compositions without the addition of an inventive boosting agent mixture.
- the compositions according to the present invention are efficient in preventing the formation of malodor.
- the detergent and/or cleaning compositions according to the present invention boost the olfactory properties of odorous substances and/or the adherence of odorous substances comprised in said detergent and/or cleaning compositions, compared to compositions without the addition of an inventive boosting agent mixture. This results in improved intensities even when using small amounts of the odorous component.
- the malodor reduction and/or malodor coverage performance of the detergent and/or cleaning compositions is further improved based on the combination of at least one boosting composition based on the combination of at least one alkanediol boosting agent and at least one further boosting agent selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, ethyl hexyl glycerin, or any mixture of these further boosting agents as specified herein, a surfactant component, an odorous fragrance component as well as an optional additional antimicrobial component in a synergistical manner.
- at least one boosting composition based on the combination of at least one alkanediol boosting agent and at least one further boosting agent selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, ethyl hexyl glycerin, or any mixture of these further boosting agents as specified herein, a surfactant component, an odorous fragrance component as well as an optional
- the fragrance substance(s) in these detergent and/or cleaning compositions show(s) a superior olfactory performance in terms of intensity and adhesion, compared to detergent and/or cleaning compositions without such a boosting composition.
- an alkanediol component as a first boosting component
- a second / further boosting component selected from the group consisting of glyceryl caprylate, 4-hydroxyacetophenone, or ethyl hexyl glycerin, or any mixture thereof synergistically boost (or improve) the malodor reduction and/or malodor coverage performance of the detergent and/or cleaning compositions.
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202380073421.4A CN119998432A (en) | 2022-10-25 | 2023-10-25 | Detergent and/or cleaning composition for malodor reduction and fragrance enhancement |
| EP23798371.3A EP4608952A1 (en) | 2022-10-25 | 2023-10-25 | Detergent and/or cleaning compositions for malodor reduction and fragrance boost |
| MX2025004486A MX2025004486A (en) | 2022-10-25 | 2025-04-15 | Detergent and/or cleaning compositions for malodor reduction and fragrance boost |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EPPCT/EP2022/079776 | 2022-10-25 | ||
| EP2022079776 | 2022-10-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2024089072A1 true WO2024089072A1 (en) | 2024-05-02 |
Family
ID=84361578
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2023/079720 Ceased WO2024089072A1 (en) | 2022-10-25 | 2023-10-25 | Detergent and/or cleaning compositions for malodor reduction and fragrance boost |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP4608952A1 (en) |
| CN (1) | CN119998432A (en) |
| MX (1) | MX2025004486A (en) |
| WO (1) | WO2024089072A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3162983A1 (en) * | 2024-06-05 | 2025-12-12 | Expressions Parfumees | A mixture comprising beta ionone, alpha ionone, cedrol, hexanal, and C10 aldehyde, and its use in masking unpleasant odors. |
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|---|---|---|---|---|
| US20100130624A1 (en) * | 2008-11-27 | 2010-05-27 | Symrise Gmbh & Co. Kg | 4-alkyl substituted pyridines as odiferous substances |
| CN106893645A (en) * | 2016-12-27 | 2017-06-27 | 广州舒泰生物技术有限公司 | A kind of method of electrolysis production small-micelle water and in household detergent application |
| US20190241491A1 (en) | 2018-01-30 | 2019-08-08 | Inolex Investment Corporation | Natural 1,2-Alkanediols, Compositions Having Natural 1,2-Alkanediols and Processes for Making the Same |
| US20200056118A1 (en) * | 2017-05-05 | 2020-02-20 | Symrise Ag | Composition for odour improvement |
| US10638755B2 (en) * | 2013-03-08 | 2020-05-05 | Symrise Ag | Antimicrobial compositions |
| US20210403830A1 (en) * | 2018-11-19 | 2021-12-30 | Symrise Ag | Jasmol |
| WO2022199790A1 (en) * | 2021-03-22 | 2022-09-29 | Symrise Ag | A liquid detergent composition |
-
2023
- 2023-10-25 EP EP23798371.3A patent/EP4608952A1/en active Pending
- 2023-10-25 WO PCT/EP2023/079720 patent/WO2024089072A1/en not_active Ceased
- 2023-10-25 CN CN202380073421.4A patent/CN119998432A/en active Pending
-
2025
- 2025-04-15 MX MX2025004486A patent/MX2025004486A/en unknown
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100130624A1 (en) * | 2008-11-27 | 2010-05-27 | Symrise Gmbh & Co. Kg | 4-alkyl substituted pyridines as odiferous substances |
| US10638755B2 (en) * | 2013-03-08 | 2020-05-05 | Symrise Ag | Antimicrobial compositions |
| CN106893645A (en) * | 2016-12-27 | 2017-06-27 | 广州舒泰生物技术有限公司 | A kind of method of electrolysis production small-micelle water and in household detergent application |
| US20200056118A1 (en) * | 2017-05-05 | 2020-02-20 | Symrise Ag | Composition for odour improvement |
| US20190241491A1 (en) | 2018-01-30 | 2019-08-08 | Inolex Investment Corporation | Natural 1,2-Alkanediols, Compositions Having Natural 1,2-Alkanediols and Processes for Making the Same |
| US20200189995A1 (en) | 2018-01-30 | 2020-06-18 | Inolex Investment Corporation | Natural 1,2-Alkanediols, Compositions Having Natural 1,2-Alkanediols and Processes for Making the Same |
| US20210403830A1 (en) * | 2018-11-19 | 2021-12-30 | Symrise Ag | Jasmol |
| WO2022199790A1 (en) * | 2021-03-22 | 2022-09-29 | Symrise Ag | A liquid detergent composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3162983A1 (en) * | 2024-06-05 | 2025-12-12 | Expressions Parfumees | A mixture comprising beta ionone, alpha ionone, cedrol, hexanal, and C10 aldehyde, and its use in masking unpleasant odors. |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2025004486A (en) | 2025-05-02 |
| CN119998432A (en) | 2025-05-13 |
| EP4608952A1 (en) | 2025-09-03 |
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