WO2024065341A1 - Semiconductor device and manufacturing method therefor, and electronic device - Google Patents
Semiconductor device and manufacturing method therefor, and electronic device Download PDFInfo
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- WO2024065341A1 WO2024065341A1 PCT/CN2022/122368 CN2022122368W WO2024065341A1 WO 2024065341 A1 WO2024065341 A1 WO 2024065341A1 CN 2022122368 W CN2022122368 W CN 2022122368W WO 2024065341 A1 WO2024065341 A1 WO 2024065341A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
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- the present application relates to the field of semiconductor technology, and in particular to a semiconductor device and a manufacturing method thereof, and an electronic device.
- the embodiments of the present application provide a semiconductor device and a manufacturing method thereof, and an electronic device, which can reduce the resistance of a metal connection hole.
- the present application provides a semiconductor device, which may include a substrate, and a first conductive pattern (i.e., a lower conductive pattern), a second conductive pattern (i.e., an upper conductive pattern), a first dielectric layer, a second dielectric layer, and a metal connection hole arranged on the substrate.
- the second conductive pattern is located above the first conductive pattern (i.e., the second conductive pattern is located on the side of the first conductive pattern away from the substrate), the first dielectric layer and the second dielectric layer are located between the first conductive pattern and the second conductive pattern, and the first dielectric layer is located below the second dielectric layer (i.e., the first dielectric layer is close to the first conductive pattern relative to the second dielectric layer).
- the metal connection hole is located in the first dielectric layer and the second dielectric layer, and the first conductive pattern and the second conductive pattern are electrically connected through the metal connection hole.
- the metal connection hole includes a first metal column, and the bottom of the first metal column contacts the first conductive pattern.
- a first bonding layer is arranged between the first metal column and the second dielectric layer, and the first metal column contacts the first dielectric layer.
- a first metal column is used in the metal via, and the bottom of the first metal column is set to directly contact the first conductive pattern, so that the contact resistance between the first metal column and the first conductive pattern can be reduced.
- a first bonding layer is set between the side wall of the first metal column and the second dielectric layer, that is, the side wall of the first metal column and the second dielectric layer are filled with bonding material, so that the adhesion between the first metal column and the second dielectric layer located on the upper layer can be improved, so that defects caused by the gap between the side wall of the first metal column and the second dielectric layer can be avoided, thereby improving the reliability of the metal connection hole.
- the top of the first metal column contacts the second conductive pattern; that is, the top of the first metal column is directly connected to the second conductive pattern, ensuring a smaller contact resistance between the top of the first metal column and the second conductive pattern.
- the metal connection hole further includes a second metal column; the second metal column is located at the top of the first metal column, and a second bonding layer is provided between the second metal column and the top of the first metal column, and between the second metal column and the second dielectric layer; the top of the second metal column contacts the second conductive pattern.
- the second bonding layer at the bottom and sidewall of the second metal column, the probability of the polishing agent contacting the first conductive pattern when the surface of the second dielectric layer is subsequently polished can be further reduced.
- the surface of the first conductive pattern has a recessed portion, and the edge of the recessed portion is located outside the hole wall of the metal connection hole; the bottom of the first metal column extends and fills the recessed portion.
- the first metal column forms a rivet structure at the bottom, thereby generating a "rivet effect", further reducing the probability of the polishing agent contacting the first conductive pattern when the surface of the second dielectric layer is subsequently polished.
- the material used for the first bonding layer includes at least one of TiN, Ti, Ta or TaN.
- the material used for the second bonding layer includes at least one of TiN, Ti, Ta or TaN.
- the material used for the first dielectric layer includes SiN; and the material used for the second dielectric layer includes SiO 2 .
- the first metal pillar is manufactured using a selective deposition process.
- the second metal column is manufactured using a metal oxide chemical vapor deposition process.
- An embodiment of the present application also provides an electronic device, which includes a printed circuit board and a semiconductor device provided in any of the possible implementation methods described above; the semiconductor device is electrically connected to the printed circuit board.
- the embodiment of the present application also provides a method for manufacturing a semiconductor device, which may include: manufacturing a first conductive pattern on a substrate. Manufacturing a first dielectric layer and a second dielectric layer in sequence on the surface of the first conductive pattern. Forming a first via hole at a position of the second dielectric layer corresponding to the first conductive pattern, and forming a first bonding layer on the side wall of the first via hole. Etching the first dielectric layer at a position corresponding to the first via hole to form a second via hole, and leaking the first conductive pattern. Using a selective deposition process, forming a first metal column on the surface of the leaked first conductive pattern, and the first metal column extends into the second dielectric layer. Forming a second conductive pattern electrically connected to the first metal column on the surface of the second dielectric layer.
- the second conductive pattern electrically connected to the first metal pillar is formed on the surface of the second dielectric layer, and may include: forming the second conductive pattern connected to the surface of the first metal pillar on the surface of the second dielectric layer, that is, the top of the first metal pillar is in direct contact with the second conductive pattern, thereby ensuring a small contact resistance between the top of the first metal pillar and the second conductive pattern.
- the second conductive pattern electrically connected to the first metal pillar formed on the surface of the second dielectric layer may include: forming a second bonding layer on the surface of the substrate on which the first metal pillar is formed; forming a second metal pillar on the second bonding layer and in the first via hole by metal oxide chemical vapor deposition; and forming a second conductive pattern connected to the surface of the second metal pillar on the surface of the second dielectric layer.
- the above-mentioned etching of the first dielectric layer at a position corresponding to the first via hole to form a second via hole and leaking the first conductive pattern may include: etching the first dielectric layer at a position corresponding to the first via hole to form a second via hole, and etching the surface of the first conductive pattern to form a recessed portion; wherein the edge of the recessed portion is located on the outside of the hole wall of the second via hole.
- FIG1 is a schematic diagram of a metal connection hole in a semiconductor device provided in the prior art
- FIG2 is a schematic diagram of a metal connection hole in a semiconductor device provided in an embodiment of the present application.
- FIG3 is a schematic diagram of a metal connection hole in a semiconductor device provided in an embodiment of the present application.
- FIG4 is a schematic diagram of a metal connection hole in a semiconductor device provided in an embodiment of the present application.
- FIG5 is a schematic diagram of a metal connection hole in a semiconductor device provided in an embodiment of the present application.
- FIG6 is a flow chart of a method for manufacturing a semiconductor device provided in an embodiment of the present application.
- FIG7 is a schematic structural diagram of a semiconductor device during the manufacturing process provided by an embodiment of the present application.
- FIG8 is a schematic structural diagram of a semiconductor device during manufacturing provided by an embodiment of the present application.
- FIG9 is a schematic structural diagram of a semiconductor device during manufacturing provided by an embodiment of the present application.
- FIG10 is a schematic structural diagram of a semiconductor device during the manufacturing process provided by an embodiment of the present application.
- FIG11 is a schematic structural diagram of a semiconductor device during manufacturing process provided by an embodiment of the present application.
- FIG12 is a schematic structural diagram of a semiconductor device during the manufacturing process provided by an embodiment of the present application.
- FIG. 13 is a schematic structural diagram of a semiconductor device during the manufacturing process provided in an embodiment of the present application.
- An embodiment of the present application provides an electronic device, which includes a printed circuit board (PCB) and a semiconductor device connected to the printed circuit board.
- the semiconductor device includes conductive patterns located in different layers, and the conductive patterns in different layers are electrically connected through metal connecting holes.
- a new type of metal connecting hole with a lower resistance is used, thereby improving the performance of the semiconductor device.
- the electronic device may be a mobile phone, a tablet computer, a notebook, a car computer, a smart watch, a smart bracelet, or other electronic products.
- the semiconductor device may be a memory, a processor, a sensor, or the like.
- an embodiment of the present application provides a semiconductor device, which includes a substrate 10 and a first conductive pattern 1 and a second conductive pattern 2 disposed on the substrate 10 and located at different layers.
- the second conductive pattern 2 is located above the first conductive pattern 1 (i.e., on a side away from the substrate 10).
- a first dielectric layer 11 i.e., a lower dielectric layer
- a second dielectric layer 12 i.e., an upper dielectric layer
- the first dielectric layer 11 is located below the second dielectric layer 12 (i.e., the first dielectric layer 11 is closer to the substrate 10 relative to the second dielectric layer 12).
- the first conductive pattern 1 and the second conductive pattern 2 are electrically connected via metal connection holes 3 disposed in the first dielectric layer 11 and the second dielectric layer 12.
- the present application does not limit the specific configuration of the substrate 10 , the first conductive pattern 1 , and the second conductive pattern 2 , which can be determined in practice according to the specific structure of the semiconductor device.
- the substrate 10 may include a substrate and a transistor disposed on the substrate, the first conductive pattern 1 may be a source, a drain or a gate of the transistor, or may be a conductive pattern such as a signal line, and the second conductive pattern 2 may be a conductive pattern such as a signal line or a capacitor electrode; the present application does not limit this.
- the first conductive pattern 1 may be a source, a drain or a gate of a transistor
- the second conductive pattern 2 may be a signal line.
- the first conductive pattern 1 and the second conductive pattern 2 may both be signal lines.
- a through hole may be formed in the first dielectric layer 11 and the second dielectric layer 12, and one or more metal pillars may be formed in the through hole, thereby forming the metal connection hole 3; that is, the metal connection hole 3 may include one metal pillar, or may include two or more metal pillars.
- the metal connection hole 3 may also include other structures, and the present application does not impose any restrictions on this. For details, please refer to the description of the metal connection hole 3.
- the metal connection hole 3 includes a first metal column 31, and the bottom of the first metal column 31 is in direct contact with the first conductive pattern 1, thereby reducing the contact resistance between the first metal column 31 and the first conductive pattern 1.
- a first bonding layer a1 is provided between a portion of the first metal column 31 located in the second dielectric layer 12 and the second dielectric layer 12, and a portion of the first metal column 31 located in the first dielectric layer 11 is in direct contact with the first dielectric layer 11.
- top and bottom involved in this application are two relative positions of components, and the “top” is closer to the substrate 10 than the “bottom”; as mentioned above, the “bottom of the first metal column 31” refers to the end of the first metal column 31 close to the substrate 10, and the “top of the first metal column 31” refers to the end of the first metal column 31 away from the substrate 10.
- direct contact involved in this application means that there is no other component between the two components, and the two components are directly connected; such as the "bottom of the first metal column 31 is in direct contact with the first conductive pattern 1" in the above text, please refer to the corresponding relevant instructions below for details.
- the adhesion between the first metal column 31 and the second dielectric layer 12 located on the upper layer can be improved, thereby avoiding defects caused by the gap between the side wall of the first metal column 31 and the second dielectric layer 12 (see the description below for details), thereby improving the reliability of the metal connection hole 3.
- defects are caused by the gap between the side wall of the first metal pillar 31 and the second dielectric layer 12
- the adhesion between the metal material and the dielectric layer is poor.
- the first bonding layer a1 is not provided, a gap will be generated between the side wall of the first metal pillar 31 and the second dielectric layer 12 during the process of forming the first metal pillar 31 through the deposition process. Due to the existence of the gap, when the surface of the second dielectric layer 12 is ground (such as chemical mechanical grinding) in the subsequent manufacturing process, the grinding agent will move downward from the gap position, thereby causing missing (missing) on the side wall of the first metal pillar 31.
- the grinding agent contacts the first conductive pattern 1, which will cause damage (damage) to the first conductive pattern 1. Therefore, in the present application, by providing the first bonding layer a1 between the first metal pillar 31 and the second dielectric layer 12 located on the upper layer, the probability of the above-mentioned defects is reduced, thereby improving the reliability of the device.
- a selective deposition process can be used to manufacture the first metal pillar 31, that is, selectively depositing metal material on the surface of the first conductive pattern 1 to form the first metal pillar 31, so that the bottom of the first metal pillar 31 is in direct contact with the first conductive pattern 1, thereby avoiding the problem of high contact resistance between the bottom of the first metal pillar 31 and the first conductive pattern 1 due to the bonding layer in the prior art using MOCVD (refer to FIG. 1), and also avoiding the formation of a gap in the central area of the first metal pillar 31 (refer to S in FIG. 1); that is, reducing the resistance of the metal connection hole.
- the present application does not limit the conductive materials used by the first conductive pattern 1 and the second conductive pattern 2.
- the first conductive pattern 1 and the second conductive pattern 2 can be made of conductive materials such as Co, Cu, and W.
- the first conductive pattern 1 and the second conductive pattern 2 can be made of Co.
- the present application does not limit the metal material used for the first metal pillar 31.
- the first metal pillar 31 may be made of metal materials such as W, Cu, and Co.
- the first metal pillar 31 may be made of W.
- the present application does not limit the material used for the first bonding layer a1.
- the material used for the first bonding layer a1 may include at least one of TiN, Ti, Ta, and TaN.
- the first bonding layer a1 may be made of TiN.
- the present application does not limit the materials used for the first dielectric layer 11 and the second dielectric layer 12 and the number of layers.
- the first dielectric layer 11 can be one dielectric layer; for another example, in some possible implementations, as shown in FIG3 , the first dielectric layer 11 can include two dielectric layers (A1, A2).
- the second dielectric layer 12 can be one dielectric layer or multiple dielectric layers.
- the present application does not limit the insulating dielectric materials used in the first dielectric layer 11 and the second dielectric layer 12.
- the first dielectric layer 11 and the second dielectric layer 12 may be made of insulating dielectric materials such as oxides (such as SiO 2 ), nitrides (such as SiN), and oxynitrides (SiO y N x ).
- the first dielectric layer 11 includes two SiN layers (A1, A2)
- the second dielectric layer 12 is a SiO 2 layer.
- other film layer patterns may be provided between the two SiN layers (A1, A2).
- a recessed portion T may be provided on the surface of the first conductive pattern 1, and the edge of the recessed portion T is located outside the hole wall of the metal connection hole 3.
- the bottom of the first metal column 31 extends and fills into the groove portion T.
- the first metal column 31 forms a rivet structure at the bottom, thereby generating a "rivet effect", further reducing the probability of the grinding agent contacting the first conductive pattern 1 when the surface of the second dielectric layer 12 is subsequently ground (for details, refer to the following).
- the present application does not limit the electrical connection method between the first metal pillar 31 and the second conductive pattern 2 .
- the second conductive pattern 2 and the first metal pillar 31 may be directly connected or indirectly connected.
- the top of the first metal pillar 31 may be in direct contact with the second conductive pattern 2 to form an electrical connection.
- the metal connection hole 3 may further include a second metal column 32, the second metal column 32 is located at the top of the first metal column 31, and a second bonding layer a2 is provided between the bottom of the second metal column 32 and the first metal column 31, and between the side of the second metal column 32 and the second dielectric layer 12; that is, the second bonding layer a2 wraps around the side and bottom of the second metal column 32.
- the top of the second metal column 32 contacts the second conductive pattern 2, that is, the second conductive pattern 2 is electrically connected to the first metal column 31 through the second metal column 32.
- the material of the second bonding layer a2 may be the same as or different from that of the first bonding layer a1, and this application does not limit this.
- the material of the second bonding layer a2 may be at least one of TiN, Ti, Ta, and TaN.
- MOCVD metal oxide chemical vapor deposition
- the first bonding layer a1 located on the side of the first metal column 31 extends upward to the side of the second metal column 32, that is, the first bonding layer a1 and the second bonding layer a2 are provided between the side wall of the second metal column 32 and the second dielectric layer 12.
- the embodiment of the present application also provides a method for manufacturing a semiconductor device, as shown in FIG6 , the manufacturing method may include:
- Step 01 referring to FIG. 7 , a first conductive pattern 1 is manufactured on a substrate 10 , and a first dielectric layer 11 and a second dielectric layer 12 are sequentially manufactured on the surface of the first conductive pattern 1 .
- the substrate 10 may include a substrate and other structures disposed on the substrate.
- a Co conductive pattern (1) is formed on the surface of the substrate 10 through step 01.
- the Co conductive pattern (1) may be used as a source, a drain, a gate, etc. of a transistor.
- a first dielectric layer 11, such as two SiN layers (A1, A2), is formed on the surface of the Co conductive pattern (1); and a second dielectric layer 12, such as a SiO2 layer, is formed on the surface of the first dielectric layer 11.
- first conductive pattern 1, first dielectric layer 11, and second dielectric layer 12 are not necessarily manufactured in sequence and continuously, but depend on the structure of the entire device.
- other pattern film layers located in the area outside the first conductive pattern 1 may be manufactured between the two SiN layers (A1, A2) in the first dielectric layer 11; similarly, other film layers may be manufactured between the first dielectric layer 11 and the second dielectric layer 12 in the area outside the first conductive pattern 1.
- Step 02 referring to FIG. 8 , a first via hole V1 is formed at a position of the second dielectric layer 12 corresponding to the first conductive pattern 1, and a first adhesive layer a1 is formed on a side wall of the first via hole V1.
- step 02 first, at the position corresponding to the first conductive pattern 1, the second dielectric layer 12 is etched by dry etching to form a first via V1, and the etching stops on the first dielectric layer 11, that is, the first dielectric layer 11 serves as a contact etch stop layer (CESL).
- the etching of the first via V1 is completed, post-etching treatment is required, such as wet cleaning, removal of etching byproducts, etc.
- a first bonding layer a1 is deposited on the surface of the second dielectric layer 12, and the first bonding layer a1 located at the bottom of the first via V1 and the upper surface of the second dielectric layer 12 is removed, and only the first bonding layer a1 located on the side wall of the first via V1 is retained to protect the side wall of the first via V1.
- Step 03 referring to FIG. 9 , the first dielectric layer 11 is etched at a position corresponding to the first via hole V1 to form a second via hole V2, and the first conductive pattern 1 is exposed.
- the first dielectric layer 11 is dry-etched at a position corresponding to the first via hole V1 to form a second via hole V2, that is, a via hole V' is formed that penetrates the first dielectric layer 11 and the second dielectric layer 12.
- post-etching processing is required, such as wet cleaning, removal of etching byproducts, etc.
- the etching depth can be controlled, and the surface of the first conductive pattern 1 is etched to form a recessed portion T, and the edge of the recessed portion T is ensured to be located outside the hole wall of the second via hole V2.
- the bottom of the first metal column 31 formed subsequently can be extended and filled into the recessed portion T to form a rivet structure, thereby generating a "rivet effect".
- Step 04 referring to FIG. 11 , a selective deposition process is used to form a first metal column 31 on the surface of the leaked first conductive pattern 1 , and the first metal column 31 extends into the second dielectric layer 12 .
- a selective tungsten deposition process is used to grow W on the surface of the first conductive pattern 1 (such as a Co conductive pattern) located in the via hole V', thereby forming a first tungsten metal column (31).
- the surface of the first conductive pattern 1 can be pre-treated, such as removing surface dangling bonds, to increase selectivity.
- the first bonding layer a1 can be filled between the first tungsten metal column (31) and the second dielectric layer 12. Since the growth rate of the metal on the bonding layer (such as TiN) is greater than the growth rate directly on the dielectric layer (such as SiO 2 ), the bonding between tungsten (W) and the side wall can be increased by setting the first bonding layer a1. In this case, on the one hand, the process window is increased and the control difficulty of the process is reduced; on the other hand, the first bonding layer a1 can reduce the probability of the first tungsten metal column (31) and the second dielectric layer 12. The loss of the first tungsten metal column (31) (i.e., tungsten loss) and the damage of the Co conductive pattern (1) (i.e., cobalt damage) are reduced, thereby improving the reliability of the device.
- the loss of the first tungsten metal column (31) i.e., tungsten loss
- the damage of the Co conductive pattern (1) i.e., cobalt damage
- Step 05 referring to FIG. 3 , a second conductive pattern 2 electrically connected to the first metal pillar 31 is formed on the surface of the second dielectric layer 12 .
- the fabrication of the metal connection hole 3 does not require the use of metal oxide chemical vapor deposition (MOCVD), thereby reducing the process difficulty and cost.
- MOCVD metal oxide chemical vapor deposition
- a first via hole V1 with a certain depth is left unfilled above the first metal pillar 31; then, as shown in FIG. 12 (b), through step 05, a second bonding layer a2 is first deposited on the surface of the substrate on which the first metal pillar 31 is formed, so as to cover the bonding material on the upper surface of the second dielectric layer 12, the top of the first metal pillar 31, and the sidewall of the via hole. Then, as shown in FIG. 12 (c), a second metal pillar 32 is formed on the second bonding layer a2 and in the first via hole V1 by using metal oxide chemical vapor deposition (MOCVD).
- MOCVD metal oxide chemical vapor deposition
- the first bonding layer a1 and the second bonding layer a2 are provided between the sidewall of the second metal pillar 32 and the second dielectric layer 12.
- the second metal pillar 32 and the second bonding layer a2 can be completely removed as a grinding sacrificial layer to expose the top of the first metal pillar 31, and then the second conductive pattern 2 can be fabricated (refer to the structure of FIG. 3 ).
- the second conductive pattern 2 can be fabricated.
- FIG. 13 when the surface of the second dielectric layer 12 is ground, at least a portion of the second metal pillar 32 can be retained, and then the second conductive pattern 2 can be fabricated.
- the corresponding parts in the above-mentioned semiconductor device structure embodiment can be referred to, and no further details will be given here.
- the related structures in the above-mentioned semiconductor device structure embodiment they can be made correspondingly with reference to the above-mentioned semiconductor device manufacturing method embodiment, or they can be made by combining relevant technologies with appropriate adjustments, and this application does not limit this.
- the size of the serial numbers of the above-mentioned processes does not mean the order of execution.
- the execution order of each process should be determined by its function and internal logic, and should not constitute any limitation on the implementation process of the embodiments of the present application.
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Abstract
Description
本申请涉及半导体技术领域,尤其涉及一种半导体器件及其制作方法、电子设备。The present application relates to the field of semiconductor technology, and in particular to a semiconductor device and a manufacturing method thereof, and an electronic device.
在半导体器件中,通过需要将位于不同层的导电图案通过金属连接孔(via)进行电连接,然而随着半导体工艺的发展,金属连接孔的阻值越来越成为制约器件性能的关键。In semiconductor devices, conductive patterns located in different layers need to be electrically connected through metal vias. However, with the development of semiconductor technology, the resistance of the metal vias has become increasingly critical to device performance.
如图1所示,以采用钨(W)连接孔V连接下导电图案a1和上导电图案(图中未示出)为例,在采用金属氧化物化学气相沉积(metal oxide chemical vapor deposition,MOCVD)的传统钨沉积工艺中,需要在沉积钨之前先制作粘结层b(如TiN层)来改善钨与孔壁之间的粘接性,但是该工艺下的钨沉积会出现缝隙S,同时位于连接孔底部的粘接层b与下导电图案a1的接触电阻较高,从而导致金属连接孔的阻值很难降低。As shown in Figure 1, taking the use of tungsten (W) connecting holes V to connect the lower conductive pattern a1 and the upper conductive pattern (not shown in the figure) as an example, in the traditional tungsten deposition process using metal oxide chemical vapor deposition (MOCVD), it is necessary to first make an adhesive layer b (such as a TiN layer) before depositing tungsten to improve the adhesion between tungsten and the hole wall. However, the tungsten deposition under this process will appear a gap S, and at the same time, the contact resistance between the adhesive layer b at the bottom of the connecting hole and the lower conductive pattern a1 is high, which makes it difficult to reduce the resistance of the metal connecting hole.
发明内容Summary of the invention
本申请实施例提供一种半导体器件及其制作方法、电子设备,能够降低金属连接孔的阻值。The embodiments of the present application provide a semiconductor device and a manufacturing method thereof, and an electronic device, which can reduce the resistance of a metal connection hole.
本申请提供一种半导体器件,该半导体器件可以包括基板,以及设置于基板上的第一导电图案(也即下导电图案)、第二导电图案(也即上导电图案)、第一介质层、第二介质层、金属连接孔。其中,第二导电图案位于第一导电图案的上方(也即第二导电图案位于第一导电图案远离基板的一侧),第一介质层和二介质层位于第一导电图案和第二导电图案之间,且第一介质层位于第二介质层的下方(也即第一介质层相对于第二介质层靠近第一导电图案)。金属连接孔位于第一介质层和第二介质层中,且第一导电图案和第二导电图案通过金属连接孔电连接。金属连接孔包括第一金属柱,并且第一金属柱的底部与第一导电图案接触。第一金属柱与第二介质层之间设置有第一粘结层,且第一金属柱与第一介质层接触。The present application provides a semiconductor device, which may include a substrate, and a first conductive pattern (i.e., a lower conductive pattern), a second conductive pattern (i.e., an upper conductive pattern), a first dielectric layer, a second dielectric layer, and a metal connection hole arranged on the substrate. The second conductive pattern is located above the first conductive pattern (i.e., the second conductive pattern is located on the side of the first conductive pattern away from the substrate), the first dielectric layer and the second dielectric layer are located between the first conductive pattern and the second conductive pattern, and the first dielectric layer is located below the second dielectric layer (i.e., the first dielectric layer is close to the first conductive pattern relative to the second dielectric layer). The metal connection hole is located in the first dielectric layer and the second dielectric layer, and the first conductive pattern and the second conductive pattern are electrically connected through the metal connection hole. The metal connection hole includes a first metal column, and the bottom of the first metal column contacts the first conductive pattern. A first bonding layer is arranged between the first metal column and the second dielectric layer, and the first metal column contacts the first dielectric layer.
在本申请的半导体器件中,在金属过孔中采用第一金属柱,并设置该第一金属柱的底部与第一导电图案直接接触,从而能够降低第一金属柱与第一导电图案之间的接触电阻。同时还通过在第一金属柱的侧壁与第二介质层之间设置第一粘结层,也即在第一金属柱的侧壁与第二介质层之间填充有粘结材料,能够提高第一金属柱与位于上层的第二介质层之间粘附性,从而能够避免在第一金属柱的侧壁与第二介质层之间因间隙而产生缺陷问题,进而提高了金属连接孔的可靠性(reliability)。In the semiconductor device of the present application, a first metal column is used in the metal via, and the bottom of the first metal column is set to directly contact the first conductive pattern, so that the contact resistance between the first metal column and the first conductive pattern can be reduced. At the same time, a first bonding layer is set between the side wall of the first metal column and the second dielectric layer, that is, the side wall of the first metal column and the second dielectric layer are filled with bonding material, so that the adhesion between the first metal column and the second dielectric layer located on the upper layer can be improved, so that defects caused by the gap between the side wall of the first metal column and the second dielectric layer can be avoided, thereby improving the reliability of the metal connection hole.
在一些可能实现的方式中,第一金属柱的顶部与第二导电图案接触;也即第一金属柱的顶部与第二导电图案直接连接,保证第一金属柱的顶部与第二导电图案之间具有较小的接触电阻。In some possible implementations, the top of the first metal column contacts the second conductive pattern; that is, the top of the first metal column is directly connected to the second conductive pattern, ensuring a smaller contact resistance between the top of the first metal column and the second conductive pattern.
在一些可能实现的方式中,金属连接孔还包括第二金属柱;第二金属柱位于第一金属柱的顶部,且第二金属柱与第一金属柱的顶部之间,以及第二金属柱与第二介质层之间设 置有第二粘结层;第二金属柱的顶部与第二导电图案接触。在此情况下,通过在第二金属柱的底部以及侧壁形成第二粘结层,能够进一步降低在后续对第二介质层的表面进行研磨时,研磨试剂与第一导电图案接触的几率。In some possible implementations, the metal connection hole further includes a second metal column; the second metal column is located at the top of the first metal column, and a second bonding layer is provided between the second metal column and the top of the first metal column, and between the second metal column and the second dielectric layer; the top of the second metal column contacts the second conductive pattern. In this case, by forming the second bonding layer at the bottom and sidewall of the second metal column, the probability of the polishing agent contacting the first conductive pattern when the surface of the second dielectric layer is subsequently polished can be further reduced.
在一些可能实现的方式中,第一导电图案的表面具有凹陷部,且凹陷部的边缘位于金属连接孔的孔壁外侧;第一金属柱的底部延伸、并填充至凹陷部中。在此情况下,第一金属柱在底部形成铆钉结构,从而产生“铆钉效应”,进一步降低后续在对第二介质层的表面进行研磨时,研磨试剂与第一导电图案接触的几率。In some possible implementations, the surface of the first conductive pattern has a recessed portion, and the edge of the recessed portion is located outside the hole wall of the metal connection hole; the bottom of the first metal column extends and fills the recessed portion. In this case, the first metal column forms a rivet structure at the bottom, thereby generating a "rivet effect", further reducing the probability of the polishing agent contacting the first conductive pattern when the surface of the second dielectric layer is subsequently polished.
在一些可能实现的方式中,第一粘结层采用的材料包括TiN、Ti、Ta或TaN中的至少一种。In some possible implementations, the material used for the first bonding layer includes at least one of TiN, Ti, Ta or TaN.
在一些可能实现的方式中,第二粘结层采用的材料包括TiN、Ti、Ta或TaN中的至少一种。In some possible implementations, the material used for the second bonding layer includes at least one of TiN, Ti, Ta or TaN.
在一些可能实现的方式中,第一介质层采用的材料包括SiN;第二介质层采用的材料包括SiO 2。 In some possible implementations, the material used for the first dielectric layer includes SiN; and the material used for the second dielectric layer includes SiO 2 .
在一些可能实现的方式中,第一金属柱采用选择性沉积工艺制作而成。In some possible implementations, the first metal pillar is manufactured using a selective deposition process.
在一些可能实现的方式中,第二金属柱采用金属氧化物化学气相沉积工艺制作而成。In some possible implementations, the second metal column is manufactured using a metal oxide chemical vapor deposition process.
本申请实施例还提供一种电子设备,该电子设备包括印刷线路板以及如前述任一种可能实现的方式中提供的半导体器件;该半导体器件与印刷线路板电连接。An embodiment of the present application also provides an electronic device, which includes a printed circuit board and a semiconductor device provided in any of the possible implementation methods described above; the semiconductor device is electrically connected to the printed circuit board.
本申请实施例还提供一种半导体器件的制作方法,该制作方法可以包括:在基板上制作第一导电图案。在第一导电图案的表面依次制作第一介质层和第二介质层。在第二介质层对应第一导电图案的位置形成第一过孔,并在第一过孔的侧壁形成第一粘结层。在对应第一过孔的位置对第一介质层进行刻蚀形成第二过孔,并漏出第一导电图案。采用选择性沉积工艺,在漏出的第一导电图案的表面形成第一金属柱,且第一金属柱伸入至第二介质层中。在第二介质层表面形成与第一金属柱电连接的第二导电图案。The embodiment of the present application also provides a method for manufacturing a semiconductor device, which may include: manufacturing a first conductive pattern on a substrate. Manufacturing a first dielectric layer and a second dielectric layer in sequence on the surface of the first conductive pattern. Forming a first via hole at a position of the second dielectric layer corresponding to the first conductive pattern, and forming a first bonding layer on the side wall of the first via hole. Etching the first dielectric layer at a position corresponding to the first via hole to form a second via hole, and leaking the first conductive pattern. Using a selective deposition process, forming a first metal column on the surface of the leaked first conductive pattern, and the first metal column extends into the second dielectric layer. Forming a second conductive pattern electrically connected to the first metal column on the surface of the second dielectric layer.
在一些可能实现的方式中,上述在第二介质层表面形成与第一金属柱电连接的第二导电图案,可以包括:在第二介质层表面形成与第一金属柱的表面连接的第二导电图案。也即在第一金属柱的顶部与第二导电图案直接接触,从而保证第一金属柱的顶部与第二导电图案之间具有较小的接触电阻。In some possible implementations, the second conductive pattern electrically connected to the first metal pillar is formed on the surface of the second dielectric layer, and may include: forming the second conductive pattern connected to the surface of the first metal pillar on the surface of the second dielectric layer, that is, the top of the first metal pillar is in direct contact with the second conductive pattern, thereby ensuring a small contact resistance between the top of the first metal pillar and the second conductive pattern.
在一些可能实现的方式中,上述在第二介质层表面形成与第一金属柱电连接的第二导电图案,可以包括:在形成有第一金属柱的基板表面形成第二粘结层;采用金属氧化物化学气相沉积法,在第二粘结层上、位于第一过孔中形成第二金属柱;在第二介质层表面形成与第二金属柱的表面连接的第二导电图案。In some possible implementations, the second conductive pattern electrically connected to the first metal pillar formed on the surface of the second dielectric layer may include: forming a second bonding layer on the surface of the substrate on which the first metal pillar is formed; forming a second metal pillar on the second bonding layer and in the first via hole by metal oxide chemical vapor deposition; and forming a second conductive pattern connected to the surface of the second metal pillar on the surface of the second dielectric layer.
在一些可能实现的方式中,上述在对应第一过孔的位置对第一介质层进行刻蚀形成第二过孔,并漏出第一导电图案,可以包括:在对应第一过孔的位置对第一介质层进行刻蚀形成第二过孔,并对第一导电图案的表面进行刻蚀形成凹陷部;其中,凹陷部的边缘位于第二过孔的孔壁的外侧。In some possible implementations, the above-mentioned etching of the first dielectric layer at a position corresponding to the first via hole to form a second via hole and leaking the first conductive pattern may include: etching the first dielectric layer at a position corresponding to the first via hole to form a second via hole, and etching the surface of the first conductive pattern to form a recessed portion; wherein the edge of the recessed portion is located on the outside of the hole wall of the second via hole.
图1为现有技术中提供的一种半导体器件中金属连接孔的示意图;FIG1 is a schematic diagram of a metal connection hole in a semiconductor device provided in the prior art;
图2为本申请实施例提供的一种半导体器件中金属连接孔的示意图;FIG2 is a schematic diagram of a metal connection hole in a semiconductor device provided in an embodiment of the present application;
图3为本申请实施例提供的一种半导体器件中金属连接孔的示意图;FIG3 is a schematic diagram of a metal connection hole in a semiconductor device provided in an embodiment of the present application;
图4为本申请实施例提供的一种半导体器件中金属连接孔的示意图;FIG4 is a schematic diagram of a metal connection hole in a semiconductor device provided in an embodiment of the present application;
图5为本申请实施例提供的一种半导体器件中金属连接孔的示意图;FIG5 is a schematic diagram of a metal connection hole in a semiconductor device provided in an embodiment of the present application;
图6为本申请实施例提供的一种半导体器件的制作方法流程图;FIG6 is a flow chart of a method for manufacturing a semiconductor device provided in an embodiment of the present application;
图7为本申请实施例提供的一种半导体器件的制作过程中的结构示意图;FIG7 is a schematic structural diagram of a semiconductor device during the manufacturing process provided by an embodiment of the present application;
图8为本申请实施例提供的一种半导体器件的制作过程中的结构示意图;FIG8 is a schematic structural diagram of a semiconductor device during manufacturing provided by an embodiment of the present application;
图9为本申请实施例提供的一种半导体器件的制作过程中的结构示意图;FIG9 is a schematic structural diagram of a semiconductor device during manufacturing provided by an embodiment of the present application;
图10为本申请实施例提供的一种半导体器件的制作过程中的结构示意图;FIG10 is a schematic structural diagram of a semiconductor device during the manufacturing process provided by an embodiment of the present application;
图11为本申请实施例提供的一种半导体器件的制作过程中的结构示意图;FIG11 is a schematic structural diagram of a semiconductor device during manufacturing process provided by an embodiment of the present application;
图12为本申请实施例提供的一种半导体器件的制作过程中的结构示意图;FIG12 is a schematic structural diagram of a semiconductor device during the manufacturing process provided by an embodiment of the present application;
图13为本申请实施例提供的一种半导体器件的制作过程中的结构示意图。FIG. 13 is a schematic structural diagram of a semiconductor device during the manufacturing process provided in an embodiment of the present application.
为使本申请的目的、技术方案和优点更加清楚,下面将结合本申请中的附图,对本申请中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purpose, technical solutions and advantages of this application clearer, the technical solutions in this application will be clearly and completely described below in conjunction with the drawings in this application. Obviously, the described embodiments are part of the embodiments of this application, not all of the embodiments. Based on the embodiments in this application, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of this application.
本申请的说明书实施例和权利要求书及附图中的术语“第一”、“第二”等仅用于区分描述的目的,而不能理解为指示或暗示相对重要性,也不能理解为指示或暗示顺序。“以下至少一项(个)”或其类似表达,是指这些项中的任意组合,包括单项(个)或复数项(个)的任意组合。例如,a,b或c中的至少一项(个),可以表示:a,b,c,“a和b”,“a和c”,“b和c”,或“a和b和c”,其中a,b,c可以是单个,也可以是多个。“连接”、“相连”等类似的词语,用于表达不同组件之间的互通或互相作用,可以包括直接相连或通过其他组件间接相连。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元。方法、系统、产品或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。“上”、“下”、“左”、“右”、“顶”、“底”等仅用于相对于附图中的部件的方位而言的,这些方向性术语是相对的概念,它们用于相对于的描述和澄清,其可以根据附图中的部件所放置的方位的变化而相应地发生变化。The terms "first", "second", etc. in the specification embodiments, claims and drawings of the present application are only used for the purpose of distinguishing descriptions, and cannot be understood as indicating or implying relative importance, nor can they be understood as indicating or implying order. "At least one of the following" or similar expressions refers to any combination of these items, including any combination of single items or plural items. For example, at least one of a, b or c can represent: a, b, c, "a and b", "a and c", "b and c", or "a and b and c", where a, b, c can be single or multiple. "Connect", "connected" and similar words are used to express the intercommunication or interaction between different components, and may include direct connection or indirect connection through other components. In addition, the terms "including" and "having" and any of their variations are intended to cover non-exclusive inclusions, for example, including a series of steps or units. Methods, systems, products or devices are not necessarily limited to those steps or units clearly listed, but may include other steps or units that are not clearly listed or inherent to these processes, methods, products or devices. "Up", "down", "left", "right", "top", "bottom", etc. are only used relative to the orientation of the components in the drawings. These directional terms are relative concepts. They are used for relative description and clarification, and may change accordingly according to the changes in the orientation of the components in the drawings.
本申请实施例提供一种电子设备,该电子设备中包括印刷线路板(printed circuit board,PCB)以及与该印刷线路板连接的半导体器件,该半导体器件中包括位于不同层的导电图案,且不同层的导电图案之间通过金属连接孔电连接,本申请实施例中采用一种新型的金属连接孔具有较低的阻值,从而能够提升半导体器件的性能。An embodiment of the present application provides an electronic device, which includes a printed circuit board (PCB) and a semiconductor device connected to the printed circuit board. The semiconductor device includes conductive patterns located in different layers, and the conductive patterns in different layers are electrically connected through metal connecting holes. In the embodiment of the present application, a new type of metal connecting hole with a lower resistance is used, thereby improving the performance of the semiconductor device.
本申请对于上述电子设备的设置形式不做限制。示意的,该电子设备可以为手机、平板电脑、笔记本、车载电脑、智能手表、智能手环等电子产品。The present application does not limit the configuration of the above electronic device. For example, the electronic device may be a mobile phone, a tablet computer, a notebook, a car computer, a smart watch, a smart bracelet, or other electronic products.
本申请对于上述半导体器件的设置形式不做限制。示意的,该半导体器件可以是存储器、处理器、传感器等器件。The present application does not limit the configuration of the semiconductor device. For example, the semiconductor device may be a memory, a processor, a sensor, or the like.
以下对本申请实施例提供的半导体器件的具体结构进行示意的说明。The specific structure of the semiconductor device provided in the embodiment of the present application is schematically described below.
如图2所示,本申请实施例提供一种半导体器件,该半导体器件包括基板10以及设 置于基板10上、且位于不同层的第一导电图案1和第二导电图案2。其中,第二导电图案2位于第一导电图案1的上方(即远离基板10的一侧)。第一导电图案1和第二导电图案2之间设置有第一介质层11(也即下介质层)和第二介质层12(也即上介质层),第一介质层11位于第二介质层12的下方(也即第一介质层11相对于第二介质层12靠近基板10),第一导电图案1和第二导电图案2通过位于第一介质层11和第二介质层12中设置的金属连接孔3电连接。As shown in FIG2 , an embodiment of the present application provides a semiconductor device, which includes a
本申请对于上述基板10、第一导电图案1、第二导电图案2的具体设置形式不做限制,实际中可以根据半导体器件的具体结构而定。The present application does not limit the specific configuration of the
示意的,基板10可以包括衬底以及设置于衬底上的晶体管,第一导电图案1可以是晶体管的源极、漏极或栅极,还也可以是信号线等导电图案,第二导电图案2可以是信号线、电容电极等导电图案;本申请对此均不作限制。例如,在一些可能实现的方式中,第一导电图案1可以为晶体管的源极、漏极或栅极,第二导电图案2可以是信号线。又例如,在一些可能实现的方式中,第一导电图案1和第二导电图案2也可以均为信号线。Schematically, the
另外,对于上述位于第一介质层11和第二介质层12中的金属连接孔3而言,可以是在第一介质层11和第二介质层12中形成通孔,并在通孔中形成一个或多个金属柱,从而形成金属连接孔3;也就是说,该金属连接孔3可以包括一个金属柱,也可以包括两个或两个以上的金属柱,当然,根据实际的需要,该金属连接孔3还可以包括其他结构,本申请对此不作限制限制,具体可以参考关于金属连接孔3的说明。In addition, for the above-mentioned
示意的,参考图2所示,在一些可能实现的方式中,金属连接孔3包括第一金属柱31,第一金属柱31的底部与第一导电图案1直接接触,从而能够降低第一金属柱31与第一导电图案1之间的接触电阻。该第一金属柱31位于第二介质层12的部分与第二介质层12之间设置有第一粘结层a1,且该第一金属柱31位于第一介质层11的部分与第一介质层11直接接触。Schematically, referring to FIG. 2 , in some possible implementations, the
此处需要说明的是,本申请中所涉及的“顶”和“底”是部件的两个相对方位,“顶”相对于“底”更靠近基板10;如前述“第一金属柱31的底部”是指第一金属柱31靠近基板10的端部,“第一金属柱31的顶部”是指第一金属柱31远离基板10的端部。另外,本申请中所涉及的“直接接触”是指两个部件之间未间隔设置其他的部件,两个部件直接连接;如前文中“第一金属柱31的底部与第一导电图案1直接接触”,具体可以参考下文对应的相关说明。此外,可以理解的是,通过在第一金属柱31的侧壁与第二介质层12之间设置第一粘结层a1,也即在第一金属柱31的侧壁与第二介质层12之间填充有粘结材料,能够提高第一金属柱31与位于上层的第二介质层12之间粘附性,从而能够避免在第一金属柱31的侧壁与第二介质层12之间因间隙而产生缺陷问题(具体见下文的说明),进而提高了金属连接孔3的可靠性(reliability)。It should be noted here that the "top" and "bottom" involved in this application are two relative positions of components, and the "top" is closer to the
对于上述“第一金属柱31的侧壁与第二介质层12之间因间隙而产生缺陷”而言,可以理解的是,金属材料与介质层之间的粘结性较差,如果不设置第一粘结层a1的话,在通过沉积工艺形成第一金属柱31的过程中,会在第一金属柱31的侧壁与第二介质层12之间产生间隙,由于该间隙的存在,会导致后续制作过程中对第二介质层12的表面进行研磨(如化学机械研磨)时,研磨试剂会从间隙位置向下,从而会导致第一金属柱31的侧壁产生缺失(missing),同时研磨试剂与第一导电图案1接触,会对第一导电图案1造 成损伤(damage)。因此,本申请中通过在第一金属柱31与位于上层的第二介质层12之间设置第一粘结层a1,从而也就降低了上述缺陷产生的几率,从而提高了器件的可靠性。As for the above-mentioned “defects are caused by the gap between the side wall of the
另外,基于第一金属柱31的底部与第一导电图案1直接接触的设置方式,在实际的制作过程中,在一些可能实现的方式中,可以采用选择性沉积工艺来制作第一金属柱31,也即选择性的在第一导电图案1的表面沉积金属材料以形成第一金属柱31,使得第一金属柱31的底部与第一导电图案1直接接触,避免了现有技术中因采用MOCVD的方式中(参考图1),因第一金属柱31底部与第一导电图案1之间因具有粘结层导致的接触电阻高的问题,同时还避免了因在第一金属柱31的中心区域形成缝隙(参考图1中的S);也即减小了金属连接孔的阻值。In addition, based on the setting mode that the bottom of the
可以理解的是,不同的半导体器件对金属连接孔3的电阻的提升,具有不同的表现,通常金属连接孔3的电阻提升约50%左右,器件的性能会提升约5%。尤其是针对更加先进的半导体器件而言,金属连接孔3的阻值越来越成为制作器件性能的关键,通过采用本申请实施例中金属连接孔,能够对降低因为金属连接孔的阻值对器件造成的制约。It is understandable that different semiconductor devices have different performances on the improvement of the resistance of the
本申请对于第一导电图案1和第二导电图案2采用的导电材料不作限制。示意的,第一导电图案1和第二导电图案2可以采用Co、Cu、W等导电材料。例如,在一些可能实现的方式中,第一导电图案1和第二导电图案2可以采用Co。The present application does not limit the conductive materials used by the first
本申请对于第一金属柱31采用的金属材料不作限制。示意的,第一金属柱31可以采用W、Cu、Co等金属材料。例如,在一些可能实现的方式中,第一金属柱31可以采用W。The present application does not limit the metal material used for the
本申请对于第一粘结层a1采用的材料不作限制。示意的,第一粘结层a1采用的材料可以包括TiN、Ti、Ta、TaN中的至少一种。例如,在一些可能实现的方式中,第一粘结层a1可以采用TiN。The present application does not limit the material used for the first bonding layer a1. For example, the material used for the first bonding layer a1 may include at least one of TiN, Ti, Ta, and TaN. For example, in some possible implementations, the first bonding layer a1 may be made of TiN.
另外,本申请对于第一介质层11和第二介质层12采用的材料以及设置层数不作限制。例如,在一些可能实现的方式中,第一介质层11可以一个介质层;又例如,在一些可能实现的方式中,如图3所示,第一介质层11可以包括两个介质层(A1、A2)。类似的,如第二介质层12的设置,可以是一个介质层,也可以是多个介质层。In addition, the present application does not limit the materials used for the
另外,本申请对于第一介质层11、第二介质层12采用的绝缘介质材料不作限制。例如,第一介质层11、第二介质层12可以采用氧化物(如SiO
2)、氮化物(如SiN)、氮氧化物(SiO
yN
x)等绝缘介质材料。示意的,在一些可能实现的方式中,第一介质层11包括两个SiN层(A1、A2),第二介质层12为一个SiO
2层。当然,在位于金属连接孔3以外的区域,两个SiN层(A1、A2)之间可能设置有其他的膜层图案。
In addition, the present application does not limit the insulating dielectric materials used in the
此外,在一些可能实现的方式中,如图4所示,可以在第一导电图案1的表面设置凹陷部T,且凹陷部T的边缘位于金属连接孔3的孔壁外侧。第一金属柱31的底部延伸、并填充至凹槽部T中。在此情况下,第一金属柱31在底部形成铆钉结构,从而产生“铆钉效应”,进一步降低后续在对第二介质层12的表面进行研磨时(具体可以参考下文),研磨试剂与第一导电图案1接触的几率。In addition, in some possible implementations, as shown in FIG4 , a recessed portion T may be provided on the surface of the first
另外,本申请对于第一金属柱31与第二导电图案2的电连接方式不作限制,第二导电图案2与第一金属柱31可以直接连接,也可以间接连接。In addition, the present application does not limit the electrical connection method between the
例如,在一些可能实现的方式中,如图4所示,第一金属柱31的顶部可以与第二导 电图案2直接接触形成电连接。For example, in some possible implementations, as shown in FIG. 4 , the top of the
又例如,在一些可能实现的方式中,如图5所示,金属连接孔3还可以包括第二金属柱32,第二金属柱32位于第一金属柱31的顶部,且第二金属柱32的底部与第一金属柱31之间、以及第二金属柱32的侧面与第二介质层12之间设置有第二粘结层a2;也即第二粘结层a2包裹在第二金属柱32的侧面和底部。在此情况下,第二金属柱32的顶部与第二导电图案2接触,也即第二导电图案2通过第二金属柱32与第一金属柱31电连接。通过在第二金属柱的底部以及侧面设置第二粘结层a2,能够进一步降低在后续对第二介质层12的表面进行研磨时,研磨试剂与第一导电图案1接触的几率。For another example, in some possible implementations, as shown in FIG5 , the
上述第二粘结层a2采用的材料可以与前述第一粘结层a1的材料相同,也可以不同,本申请对此不作限制。示意的,第二粘结层a2采用的材料可以为TiN、Ti、Ta、TaN中的至少一种。The material of the second bonding layer a2 may be the same as or different from that of the first bonding layer a1, and this application does not limit this. Schematically, the material of the second bonding layer a2 may be at least one of TiN, Ti, Ta, and TaN.
对于上述第二金属柱32的制作而言,在一些可能实现的方式中,可以采用金属氧化物化学气相沉积(metal oxide chemical vapor deposition,MOCVD)的方式进行制作。应当理解的是,由于第二金属柱32位于整个金属连接孔3的顶部区域,在沉积过程中过孔的顶部被完全遮挡的几率较小,也即在第二金属柱32的中心区域出现缝隙的几率较小。For the production of the
此处需要说明的是,对于上述金属连接孔3同时包括第一金属柱31和第二金属柱32的情况下,在一些实施例中,参考图5所示,位于第一金属柱31侧面的第一粘结层a1向上延伸至第二金属柱32的侧面,也即第二金属柱32的侧壁与第二介质层12之间设置有第一粘结层a1和第二粘结层a2。本申请实施例还提供一种半导体器件的制作方法,如图6所示,该制作方法可以包括:It should be noted here that, in the case where the
步骤01、参考图7所示,在基板10上制作第一导电图案1,并在第一导电图案1的表面依次制作第一介质层11和第二介质层12。
示意的,在一些可能实现的方式中,基板10可以包括衬底以及设置于衬底上的其他结构,通过步骤01在基板10的表面形成Co导电图案(1),该Co导电图案(1)可以作为是晶体管的源极、漏极、栅极等。然后,在Co导电图案(1)的表面制作第一介质层11,如两个SiN层(A1、A2);并在第一介质层11的表面形成第二介质层12,如SiO
2层。
In some possible implementations, the
此处可以理解的是,上述第一导电图案1、第一介质层11、第二介质层12的制作并不必然是依次连续制作的,具体根据整个器件的结构而定,例如,在制作第一介质层11中的两个SiN层(A1、A2)之间可能制作有其他的图案膜层(位于第一导电图案1以外的区域);类似的,在第一介质层11与第二介质层12之间在位于第一导电图案1以外的区域也可能制作有其他的膜层。It can be understood here that the above-mentioned first
步骤02、参考图8所示,在第二介质层12对应第一导电图案1的位置形成第一过孔V1,并在第一过孔V1的侧壁形成第一粘结层a1。
示意的,在一些可能实现的方式中,参考图8中(a)所示,通过步骤02,先在对应第一导电图案1的位置,采用干法刻蚀对第二介质层12进行刻蚀形成第一过孔V1,并停止在第一介质层11上,也即第一介质层11作为接触刻蚀停止层(contact etch stop layer,CESL)。当然,在完成第一过孔V1的刻蚀后,需要进行刻蚀后处理,如湿法清洗、去除刻蚀副产物等。然后,参考图8中(b)、(c)所示,在第二介质层12的表面沉积第一 粘结层a1,并将位于第一过孔V1的底部以及第二介质层12的上表面的第一粘结层a1进行去除,仅保留位于第一过孔V1侧壁的第一粘结层a1,以对第一过孔V1的侧壁形成保护。Schematically, in some possible implementations, referring to FIG8 (a), through
步骤03、参考图9所示,在对应第一过孔V1的位置对第一介质层11进行刻蚀形成第二过孔V2,并漏出第一导电图案1。
示意的,在一些可能实现的方式中,参考图9所示,通过步骤03,在对应第一过孔V1的位置对第一介质层11进行干法刻蚀形成第二过孔V2,也即形成一个贯穿第一介质层11和第二介质层12的过孔V’。当然,在完成刻蚀后,需要进行刻蚀后处理,如湿法清洗、去除刻蚀副产物等。Schematically, in some possible implementations, referring to FIG9 , through
当然,在另一些可能实现的方式中,参考图10所示,通过步骤03在形成第二过孔V2时,可以控制刻蚀深度,对第一导电图案1的表面进行刻蚀形成凹陷部T,并且保证该凹陷部T的边缘位于第二过孔V2的孔壁的外侧。这样一来,参考图4所示,能够使得后续形成第一金属柱31的底部延伸、并填充至凹陷部T中形成铆钉结构,进而产生“铆钉效应”,相关说明可以参考前文,此处不再赘述。Of course, in other possible implementations, as shown in FIG10, when forming the second via hole V2 in
步骤04、参考图11所示,采用选择性沉积工艺,在漏出的第一导电图案1的表面形成第一金属柱31,且第一金属柱31伸入至第二介质层12中。
示意的,在一些可能实现的方式中,通过步骤04,采用选择性钨沉积工艺(selective tungsten deposition),在位于过孔V’中的第一导电图案1(如Co导电图案)表面生长W,从而形成第一钨金属柱(31)。在进行选择性钨沉积工艺之前,可以对第一导电图案1的表面进行前处理,如去除表面悬挂键,以增加选择性。As shown, in some possible implementations, through
此处可以理解的是,基于步骤02中形成的第一粘结层a1,在通过步骤04形成第一钨金属柱(31)时,能够使得第一钨金属柱(31)与第二介质层12之间填充第一粘结层a1,由于金属在粘结层(如TiN)上的生长速度要大于直接至介质层(如SiO
2)上的生长速度,因此通过设置第一粘结层a1能够增加钨(W)与侧壁之间的粘结性。在此情况下,一方面,增加了工艺窗口,降低了工艺过程的控制难度;另一方面,通过第一粘结层a1可以减小第一钨金属柱(31)与第二介质层12出现缝隙的几率,降低了第一钨金属柱(31)的缺失(即钨缺失)以及Co导电图案(1)的损伤(即钴损伤),进而提高了器件的可靠性。
It can be understood here that based on the first bonding layer a1 formed in
步骤05、参考图3所示,在第二介质层12表面形成与第一金属柱31电连接的第二导电图案2。
示意的,在一些可能实现的方式中,参考图3所示,在通过步骤04在完成第一金属柱31的制作后,直接对第二介质层12的表面进行研磨,如化学机械研磨(chemical mechanical polish,CMP)。然后,通过步骤05在第二介质层12的表面形成与第一金属柱31连接的第二导电图案2。在此情况下,该金属连接孔3的制作不需要采用金属氧化物化学气相沉积法(MOCVD),从而降低了工艺难度和成本。Schematically, in some possible implementations, as shown in FIG3 , after the
当然,作为另一种可能实现的方式中,参考图12中(a)所示,在通过步骤04中完成第一金属柱31的制作后,在第一金属柱31的上方留有一定的深度的第一过孔V1未填充;然后,参考图12中(b)所示,通过步骤05,在形成有第一金属柱31的基板表面先沉积第二粘结层a2,以在第二介质层12的上表面、第一金属柱31的顶部以及过孔的侧壁 覆盖粘结材料。然后,图12中(c)所示,采用金属氧化物化学气相沉积法(MOCVD),在第二粘结层a2上、位于第一过孔V1中形成第二金属柱32。在此情况下,第二金属柱32的侧壁与第二介质层12之间设置有第一粘结层a1和第二粘结层a2。在完成第二金属柱32的制作后,根据半导体器件的实际需求,在对第二介质层12的表面进行研磨时,可以将第二金属柱32以及第二粘结层a2作为研磨牺牲层全部去除,露出第一金属柱31的顶部,然后进行第二导电图案2的制作(参考图3的结构)。当然,作为另一种可能实现的方式,如图13所示,在对第二介质层12的表面进行研磨时,可以保留至少部分第二金属柱32,然后进行第二导电图案2的制作。Of course, as another possible implementation method, as shown in FIG. 12 (a), after the
关于上述半导体器件的制作方法实施例中其他相关的内容,可以对应参考前述半导体器件结构实施例中对应的部分,此处不再赘述。关于前述半导体器件结构实施例中相关的结构,可以对应参考上述半导体器件的制作方法实施例对应制作,也可以结合相关技术加以适当的调整进行制作,本申请对此不做限制。Regarding other related contents in the above-mentioned semiconductor device manufacturing method embodiment, the corresponding parts in the above-mentioned semiconductor device structure embodiment can be referred to, and no further details will be given here. Regarding the related structures in the above-mentioned semiconductor device structure embodiment, they can be made correspondingly with reference to the above-mentioned semiconductor device manufacturing method embodiment, or they can be made by combining relevant technologies with appropriate adjustments, and this application does not limit this.
应理解,在本申请的各种实施例中,上述各过程的序号的大小并不意味着执行顺序的先后,各过程的执行顺序应以其功能和内在逻辑确定,而不应对本申请实施例的实施过程构成任何限定。It should be understood that in the various embodiments of the present application, the size of the serial numbers of the above-mentioned processes does not mean the order of execution. The execution order of each process should be determined by its function and internal logic, and should not constitute any limitation on the implementation process of the embodiments of the present application.
以上所述,仅为本申请的具体实施方式,但本申请的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本申请揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本申请的保护范围之内。因此,本申请的保护范围应以所述权利要求的保护范围为准。The above is only a specific implementation of the present application, but the protection scope of the present application is not limited thereto. Any person skilled in the art who is familiar with the present technical field can easily think of changes or substitutions within the technical scope disclosed in the present application, which should be included in the protection scope of the present application. Therefore, the protection scope of the present application should be based on the protection scope of the claims.
Claims (13)
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| CN107946332A (en) * | 2017-11-22 | 2018-04-20 | 德淮半导体有限公司 | Semiconductor structure, CMOS image sensor and preparation method thereof |
-
2022
- 2022-09-29 WO PCT/CN2022/122368 patent/WO2024065341A1/en not_active Ceased
- 2022-09-29 CN CN202280097221.8A patent/CN119365975A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5686354A (en) * | 1995-06-07 | 1997-11-11 | Advanced Micro Devices, Inc. | Dual damascene with a protective mask for via etching |
| US6380065B1 (en) * | 1998-11-11 | 2002-04-30 | Sony Corporation | Interconnection structure and fabrication process therefor |
| US6040243A (en) * | 1999-09-20 | 2000-03-21 | Chartered Semiconductor Manufacturing Ltd. | Method to form copper damascene interconnects using a reverse barrier metal scheme to eliminate copper diffusion |
| US20060003577A1 (en) * | 2004-07-01 | 2006-01-05 | Semiconductor Leading Edge Technologies, Inc. | Method of manufacturing a semiconductor device |
| CN107946332A (en) * | 2017-11-22 | 2018-04-20 | 德淮半导体有限公司 | Semiconductor structure, CMOS image sensor and preparation method thereof |
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| CN119365975A (en) | 2025-01-24 |
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