WO2024041685A1 - Plaque bipolaire, électrolyseur et procédé de fabrication de plaque bipolaire - Google Patents
Plaque bipolaire, électrolyseur et procédé de fabrication de plaque bipolaire Download PDFInfo
- Publication number
- WO2024041685A1 WO2024041685A1 PCT/DE2023/100422 DE2023100422W WO2024041685A1 WO 2024041685 A1 WO2024041685 A1 WO 2024041685A1 DE 2023100422 W DE2023100422 W DE 2023100422W WO 2024041685 A1 WO2024041685 A1 WO 2024041685A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- base body
- bipolar plate
- stilt
- stilts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0232—Metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/861—Porous electrodes with a gradient in the porosity
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0241—Composites
- H01M8/0245—Composites in the form of layered or coated products
Definitions
- the invention relates to a bipolar plate at least partially designed as a 3D printed part according to the preamble of claim 1.
- the invention further relates to an electrochemical cell, in particular in the form of an electrolyzer for producing hydrogen, which has such a bipolar plate.
- the invention further relates to a method for producing a bipolar plate.
- a generic bipolar plate is known, for example, from DE 10 2020 203 398 A1.
- the production of the well-known bipolar plate involves the additive manufacturing of a metal support.
- the metal support should be built up by applying a metal layer to a base structure, which remains as part of the metal support after completion.
- the metal layer can be applied in the form of several partial metal layers lying one on top of the other.
- one of the partial metal layers can have a first porosity and another of the partial metal layers can have a second porosity that deviates from this.
- an additively manufactured structure is called a media distribution structure.
- the media distribution structure can, for example, be in the form of columns with an approximately teardrop-shaped cross section. It is possible to apply a media distribution structure to both sides of a flat base body.
- the additive manufacturing process i.e. 3D printing process, can be a se- lective melting of a powder by a laser beam or by an electron beam.
- porous layers should be produced additively.
- a starting material is used that contains metal and other components.
- the desired porosity should be achieved by removing the other components after the layer has been built up. The removal of the other components should be possible using a solvent or by increasing the temperature.
- a slip intended for use in additive manufacturing processes is described, for example, in WO 2017/081160 A1.
- the slip contains, among other things, a polymerizable substance and metal precursors present as particles.
- Possible manufacturing steps mentioned in WO 2017/081160 A1 include indirect stereolithography (SLA) and digital light processing (DLP).
- SLA indirect stereolithography
- DLP digital light processing
- the invention is based on the object of achieving progress compared to the stated prior art in the production of at least partially porous components of electrochemical cells, in particular electrolysis cells, with a particularly favorable relationship between manufacturing effort on the one hand and space requirements and robustness of the end product, i.e. the electrochemical cell , on the other hand, is aimed for.
- bipolar plate with the features of claim 1.
- the bipolar plate is particularly suitable for use in an electrochemical cell, in particular an electrolyzer, according to claim 9.
- the object is achieved by a method for producing a bipolar plate according to claim 10.
- the embodiments and advantages of the invention explained below in connection with the manufacturing method apply accordingly also for the devices, i.e. the bipolar plate and the electrochemical cell, here in particular an electrolyzer, and vice versa.
- the bipolar plate comprises a metallic base body and a perforated, open-pored 3D printing structure located on its surface, the porosity of which in different volume areas depends on the distance of the respective volume area from the surface of the base body.
- a gradient of porosity which can also be expressed in a single or multiple step change in porosity, starting from the surface of the base body in the normal direction of this surface.
- the porosity decreases with increasing distance from the base body and the pore diameters become smaller.
- the 3D printing structure comprises a first layer bordering the base body, which is designed as a coarse-pored stilt structure, i.e. column structure, comprising stilts arranged at a distance from one another on the base body.
- a second layer which can also be attributed to the 3D printing structure, which is designed as a lattice structure and has finer porosity and thinner compared to the first layer.
- the second layer is continuous parallel to the surface of the base body and covers the stilts.
- a distance between two stilts of the first layer is chosen in the range of 120pm ⁇ 20pm. Furthermore, it has proven to be advantageous if the lattice structure of the second layer has openings with an opening length and/or an opening width of ⁇ 80 pm.
- the 3D printed structure acts as a transport control layer within an electrochemical cell.
- the first layer of the 3D printing structure is materially connected to both the base body and the second, denser layer, which results in a very stable structure of the entire bipolar plate, which by definition includes the transport control layer in the present case.
- the bipolar plate In the normal direction of the three mutually parallel layers, i.e. the layer present as the base body and the two layers of the 3D printed structure, the bipolar plate is practically incompressible. This also applies to cases in which 3D printed structures of the type described are located on both sides of the base body, i.e. there are a total of five layers.
- the mutually parallel stilts of the first layer or of the two similar layers of the first type can have a targeted elastic compliance with respect to bending loads acting on the stilts, so that forces acting in the planes in which the different layers lie result in slight displacements between the flat base body and the at least one external, grid-shaped structured second layer, that is to say layer of the second type.
- the entire bipolar plate can be given a defined elastic flexibility under defined stresses, in this case shear stresses.
- the fine-pored, grid-like outer second layer i.e. cover layer, is suitable for uniform, large-area force introduction into the bipolar plate.
- the process for producing the bipolar plate is generally based on the production of a flat base body made of sheet metal, that is to say the bipolar plate in the narrower sense.
- a multilayer 3D printing structure is then built up on the base body, in particular by selective laser beam melting, with a first layer, which is generated directly on the surface of the base body, being produced in the form of a coarse-pored stilt structure comprising stilts arranged at a distance from one another on the base body and a second layer, which is generated on the first layer, is generated in the form of a relatively fine-pored lattice structure, which is thinner compared to the first layer, which is provided continuously parallel to the surface of the base body and covering the stilts.
- Titanium is particularly suitable as a material for producing the base body.
- the transport control layers which are available as 3D printed layers, can have titanium as the main component.
- various main components of the base body on the one hand and the transport control layers on the other hand can be provided.
- the integral production of the bipolar plate and at least one transport control layer reduces both the manufacturing and testing effort compared to conventional manufacturing concepts.
- the one-piece design of the bipolar plate including the transport control layer also minimizes electrical resistance and thus increases efficiency.
- the cavity volume in the first layer of the 3D printing structure is more than 50% of the total volume of the same layer, that is, the layer designed as a stilt structure.
- the first layer primarily with regard to low-resistance flowability.
- the stilt structure can be formed by leaf-shaped or blade-shaped stilts, whereby, according to various possible design variants, for example, the length of a cut surface of the stilt to be measured in a cutting plane parallel to the surface of the base body in the flow direction of the operating medium is at least twice and at most five times the length orthogonal thereto
- the thickness of the leaf-shaped or blade-shaped stilt to be measured in the same cutting plane is.
- the height of the stilt given as the distance between the surface of the flat base body and the continuous second layer can, for example, be twice the length of the stilt to be measured in the mentioned cutting plane or more.
- the second, outer layer of the 3D printing structure is not only finer-pored, but also denser than the first layer adjacent to the base body.
- the void volume is less than 25% of the total volume of this layer.
- the smaller thickness of the second layer can be at least partially compensated for by its higher density.
- configurations can be realized in which the second layer has the same mass or a higher mass than the first layer.
- the lattice structure of the second layer is, for example, in the form of openings arranged in a regular pattern, in particular with a rectangular cross section.
- the thickness of the second layer is, for example, at least 5% and at most 30% of the thickness of the first layer.
- the entire 3D layer structure provided by the two layers has, for example, a thickness which does not deviate upwards or downwards from the thickness of the base body by more than 50%.
- the free surface of the second layer facing away from the base body is reworked, with smoothing and leveling of surface roughness that occurs as a result of the process in a 3D printing process. It has proven useful if the free surface of the second layer is smoothed by rolling and/or rolling and/or grinding and/or honing and/or eroding and/or chemical removal.
- the smoothing of the free surface of the second layer reduces the risk of damage to a membrane electrode assembly (MEA) attached to it in an electrochemical cell.
- MEA membrane electrode assembly
- the bipolar plate is aligned and/or heat treated.
- the straightening in particular straightening rolling, is intended to improve the flatness of the bipolar plate and the heat treatment is intended to reduce existing internal stresses in the component, which could lead to the bipolar plate warping during use.
- An electrochemical cell in particular an electrolyzer for producing hydrogen, comprises at least one bipolar plate according to the invention.
- electrochemically Mix cell can also be a fuel cell or a redox flow cell.
- the basic structure of such cells is known from WO 2022 127 976 A1.
- Bipolar plates can also be used, the base bodies of which are assembled from two half-sheets and which form a cavity between the half-sheets for the passage of a fluid, in particular a coolant. At least one of the surfaces facing away from the cavity then has the 3D printed structure.
- FIG. 2 shows a detail of the arrangement according to FIG. 1 in a schematic sectional view from the base body in the direction of the second layer
- FIG. 3 shows a stilt structure of the arrangement according to FIG. 1 in a top view
- FIG. 5 shows a fine-pored second layer with a lattice structure of the arrangement according to FIG. 1.
- a bipolar plate 1, shown incompletely in the figures, is intended for use in an electrochemical cell, here an electrolyzer 10 for producing hydrogen.
- the bipolar plate 1 shown in detail according to FIG. 1 is shown in a three-dimensional view and separates a half cell of a first electrochemical cell, here an electrolysis cell, from a half cell of a second electrochemical cell.
- a plate-shaped base body 2 of the bipolar plate 1 is made of titanium in the present case.
- the base body 2 is also referred to as a bipolar plate in the narrower sense.
- iron-based or nickel-based materials come into consideration for producing the base body 2 and/or the porous layer structure 3.
- a porous layer structure 3 of the same type is also located on the underside of the base body 2.
- top and bottom refer exclusively to the orientation of the bipolar plate 1 that can be seen in the figures.
- bipolar plates 1 of the type shown can be in a vertical installation position in a cell stack, which is the main component of an electrochemical cell, here the electrolyzer 10 , forms, is located.
- the bipolar plate 1 including the porous layer structure 3 is also referred to as a bipolar plate in the broader sense.
- the porous layer structure 3 functions as a porous transport layer (PTL) within the completed electrolyzer 10 and is produced additively, that is, by 3D printing.
- PTL porous transport layer
- powdery or pasty precursors can be used to generate the layer structure 3.
- powdered starting materials are used to build the 3D printing structure 3 directly on the base body 2, that is, the titanium sheet.
- the 3D printing structure 3 is composed of a first layer 4, which is built directly on the base body 2 and is cohesively connected to it, and a second, comparatively fine-pored continuous layer 5, which borders directly on the first layer 4 and is cohesively connected to it and forms the outer surface of the bipolar plate 1, which also serves as a fluid conduit. Both layers 4, 5 are open-pored and have a geometrically defined shape.
- the thickness of the first layer 4 is designated Ü4
- the thickness of the second layer 5 is designated Ds.
- the sum of the thickness Ü4 and the thickness Ds results in the thickness Ds of the entire 3D printing structure 3.
- D2 denotes the thickness of the base body 2.
- the coarse-pored shape of the first layer 4 is given by a large number of individual, spaced apart and mutually parallel stilts 6, which overall represent a stilt structure 7. Each stilt 6 extends over the full height Ü4 of layer 4.
- Each stilt 6 has the shape of a narrow, elongated cuboid that is rounded on its longitudinal edges, which means that the stilt 6 has an approximate blade shape.
- the stilt 6 In cross section ( Figure 3), the stilt 6 has a length Le and a width Be.
- the stilts 6 are arranged in the manner of aerodynamically positioned strips, between which an operating medium of the electrolyzer 10 can flow.
- the length Le must be measured in the flow direction ST of the operating medium.
- the division of the stilt structure 7 given in the flow direction ST is T? specified and is more than 1.1 times, but less than twice the length Le.
- transverse division TQ? Across the direction of flow ST is a transverse division TQ? given to the stilt structure 7.
- the transverse division TQ? corresponds to more than 1.5 times but less than twice the width Be.
- the continuous second layer 5 has a lattice structure 8, which is formed by openings 9 arranged in a regular pattern, each with a square cross section.
- the second layer 4 is continuous parallel to the surface of the base body 2 and covers the stilts 6.
- the pitch of the grid structure 8 is both in the flow direction ST and in the transverse direction Ts. This is more than twice that indicated by Bg. ben edge length of the openings 9.
- the lattice structure 8 is significantly finer-pored than the stilt structure 7.
- the cavities present in the form of the openings 9 in the case of the lattice structure 8 take up significantly less than half of the total volume of the lattice structure 8 a.
- the free surface of the second layer 5, which faces away from the base body 2 can be smoothed, for example by grinding or rolling. But other smoothing processes can also be used.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Composite Materials (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
Une plaque bipolaire (1), en particulier destinée à une cellule électrochimique sous la forme d'un électrolyseur (10), comprend un corps de base métallique (2) et une structure d'impression 3D perforée (3) située sur sa surface, dont la porosité dépend de la distance par rapport à la surface du corps de base (2). Une première couche (4) de la structure d'impression 3D (3) adjacente au corps de base (2) se présente sous la forme d'une structure de pilotis à pores grossiers (7) comprenant des pilotis (6) disposés à distance les uns des autres sur le corps de base (2), une seconde couche (5) de la structure d'impression 3D (3) située sur la première couche (4) étant constituée d'une structure en treillis à pores fins (8) qui est plus fine que la première couche (4) et est disposée parallèlement à la surface du corps de base (2) de manière continue et recouvrant les pilotis (6).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102022121615.2 | 2022-08-26 | ||
| DE102022121615.2A DE102022121615A1 (de) | 2022-08-26 | 2022-08-26 | Bipolarplatte, Elektrolyseur und Verfahren zur Herstellung einer Bipolarplatte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2024041685A1 true WO2024041685A1 (fr) | 2024-02-29 |
Family
ID=86851388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/DE2023/100422 Ceased WO2024041685A1 (fr) | 2022-08-26 | 2023-06-05 | Plaque bipolaire, électrolyseur et procédé de fabrication de plaque bipolaire |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE102022121615A1 (fr) |
| WO (1) | WO2024041685A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025223598A1 (fr) | 2024-04-22 | 2025-10-30 | Schaeffler Technologies AG & Co. KG | Ensemble composé d'une membrane électrolytique polymère rainurée et d'une plaque bipolaire pour un système électrochimique, et procédé de fabrication de l'ensemble plaque |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102024202286A1 (de) | 2024-03-12 | 2025-09-18 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur Herstellung einer elektrochemischen Zelle, elektrochemische Zelle |
| DE102024112692A1 (de) * | 2024-05-06 | 2025-11-06 | Schaeffler Technologies AG & Co. KG | Plattenanordnung, Elektrolyseur und Verfahren zur Herstellung einer Plattenanordnung |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017081160A1 (fr) | 2015-11-10 | 2017-05-18 | Stichting Energieonderzoek Centrum Nederland | Fabrication additive d'objets métalliques |
| DE102017107422A1 (de) * | 2016-04-06 | 2017-10-12 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Verfahren zur Herstellung einer Bipolarplatte-Stromkollektor-Einheit, Bipolarplatte-Stromkollektor-Einheit und deren Verwendung |
| DE102016213057A1 (de) | 2016-07-18 | 2018-01-18 | Robert Bosch Gmbh | Verfahren zur Herstellung einer Bipolarplatte für eine Brennstoffzelle und Brennstoffzelle |
| US20190372133A1 (en) * | 2016-12-22 | 2019-12-05 | Robert Bosch Gmbh | Flow field plate for a fuel cell, and fuel cell |
| US20210164109A1 (en) * | 2018-07-27 | 2021-06-03 | Hoeller Electrolyzer Gmbh | Method for producing a porous transport layer for an electrochemical cell |
| WO2021138465A1 (fr) | 2019-12-31 | 2021-07-08 | The Regents Of The University Of California | Procédé de fabrication additive au laser pour la production de couches poreuses |
| DE102020203398A1 (de) | 2020-03-17 | 2021-09-23 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur additiven Herstellung eines Metallträgers einer Brennstoffzelle |
| DE102020109430A1 (de) * | 2020-04-03 | 2021-10-07 | Forschungszentrum Jülich GmbH | Bipolarplattenanordnung, Verwendung einer Bipolarplattenanordnung und Elektrolyse- oder Brennstoffzellenstapel mit einer Vielzahl von Bipolarplattenanordnungen |
| WO2022127976A1 (fr) | 2020-12-16 | 2022-06-23 | Schaeffler Technologies AG & Co. KG | Couche, système de couche, plaque électroconductrice et cellule électrochimique |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102071905B1 (ko) * | 2016-10-13 | 2020-01-31 | 주식회사 엘지화학 | 분리판, 이의 제조방법 및 이를 포함하는 연료전지 스택 |
-
2022
- 2022-08-26 DE DE102022121615.2A patent/DE102022121615A1/de not_active Ceased
-
2023
- 2023-06-05 WO PCT/DE2023/100422 patent/WO2024041685A1/fr not_active Ceased
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017081160A1 (fr) | 2015-11-10 | 2017-05-18 | Stichting Energieonderzoek Centrum Nederland | Fabrication additive d'objets métalliques |
| DE102017107422A1 (de) * | 2016-04-06 | 2017-10-12 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Verfahren zur Herstellung einer Bipolarplatte-Stromkollektor-Einheit, Bipolarplatte-Stromkollektor-Einheit und deren Verwendung |
| DE102016213057A1 (de) | 2016-07-18 | 2018-01-18 | Robert Bosch Gmbh | Verfahren zur Herstellung einer Bipolarplatte für eine Brennstoffzelle und Brennstoffzelle |
| US20190372133A1 (en) * | 2016-12-22 | 2019-12-05 | Robert Bosch Gmbh | Flow field plate for a fuel cell, and fuel cell |
| US20210164109A1 (en) * | 2018-07-27 | 2021-06-03 | Hoeller Electrolyzer Gmbh | Method for producing a porous transport layer for an electrochemical cell |
| WO2021138465A1 (fr) | 2019-12-31 | 2021-07-08 | The Regents Of The University Of California | Procédé de fabrication additive au laser pour la production de couches poreuses |
| DE102020203398A1 (de) | 2020-03-17 | 2021-09-23 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verfahren zur additiven Herstellung eines Metallträgers einer Brennstoffzelle |
| DE102020109430A1 (de) * | 2020-04-03 | 2021-10-07 | Forschungszentrum Jülich GmbH | Bipolarplattenanordnung, Verwendung einer Bipolarplattenanordnung und Elektrolyse- oder Brennstoffzellenstapel mit einer Vielzahl von Bipolarplattenanordnungen |
| WO2022127976A1 (fr) | 2020-12-16 | 2022-06-23 | Schaeffler Technologies AG & Co. KG | Couche, système de couche, plaque électroconductrice et cellule électrochimique |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025223598A1 (fr) | 2024-04-22 | 2025-10-30 | Schaeffler Technologies AG & Co. KG | Ensemble composé d'une membrane électrolytique polymère rainurée et d'une plaque bipolaire pour un système électrochimique, et procédé de fabrication de l'ensemble plaque |
Also Published As
| Publication number | Publication date |
|---|---|
| DE102022121615A1 (de) | 2024-02-29 |
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