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WO2023195584A1 - Method for manufacturing marine-derived biomass film - Google Patents

Method for manufacturing marine-derived biomass film Download PDF

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Publication number
WO2023195584A1
WO2023195584A1 PCT/KR2022/012417 KR2022012417W WO2023195584A1 WO 2023195584 A1 WO2023195584 A1 WO 2023195584A1 KR 2022012417 W KR2022012417 W KR 2022012417W WO 2023195584 A1 WO2023195584 A1 WO 2023195584A1
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WO
WIPO (PCT)
Prior art keywords
film
marine
derived biomass
manufacturing
forming
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2022/012417
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French (fr)
Korean (ko)
Inventor
이주봉
유승현
김영진
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Theday1lab
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Theday1lab
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Publication of WO2023195584A1 publication Critical patent/WO2023195584A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/04Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using liquids, gas or steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/24Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length
    • B29C41/28Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length by depositing flowable material on an endless belt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/34Component parts, details or accessories; Auxiliary operations
    • B29C41/36Feeding the material on to the mould, core or other substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/34Component parts, details or accessories; Auxiliary operations
    • B29C41/46Heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/34Component parts, details or accessories; Auxiliary operations
    • B29C41/52Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/24Calendering
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating

Definitions

  • Alginic acid is a marine-derived biomass (natural copolymer) that easily reacts with metal ions in salts to form various types of alginates for commercial use.
  • the purpose of the present invention is to provide a method for manufacturing a marine-derived biomass film that can precisely control the thickness of the marine-derived biomass film.
  • Another object of the present invention is to provide a method for manufacturing a marine-derived biomass film that can reduce production costs and shorten the process time by manufacturing in a continuous roll-to-roll process.
  • Another object of the present invention is to provide a film manufacturing apparatus capable of implementing the method for manufacturing the marine-derived biomass film.
  • One embodiment of the present invention for achieving the above object is the production of a marine-derived biomass film using a film manufacturing apparatus including a film forming unit, a thickness adjusting unit connected to the film forming unit, and a drying unit connected to the thickness adjusting unit. in a way,
  • the film forming unit provides a method of manufacturing a marine-derived biomass film containing the composition for forming the marine-derived biomass film therein.
  • the film forming unit includes a first adjusting unit that adjusts the thickness of the first film; a second control unit that adjusts the width of the first film; and a dam opposite to the first adjustment unit.
  • the method of applying the first and second curing agents may be a spray method.
  • the method for producing a marine-derived biomass film of the present invention may further include (S4) adjusting the thickness of the second film in the thickness adjustment unit.
  • the thickness adjusting unit includes a calendering roll (gap roll) that applies pressure to the surface of the second film, and the thickness of the second film whose thickness is adjusted is 0.01 to 1.00 cm. You can.
  • a calendering roll gap roll
  • the moving speeds of the first and second transfer felts may each independently be 10 cm/min to 500 m/min.
  • the method for producing a marine-derived biomass film of the present invention may further include (S5) drying the second film whose thickness is adjusted in the drying unit.
  • step (S5) may be a step using any one selected from the group consisting of an infrared drying method, a hot air drying method, and a combination thereof.
  • the drying unit may include a tunnel through which the second film passes.
  • the method for producing a marine-derived biomass film of the present invention further includes the step of (S6) rewinding the dried second film in a rewinding unit connected to the drying unit, , the rewinding unit may include a profile controller attached to the front end of the roll on which the dried second film is wound.
  • a manufacturing method in which the production cost of the product is reduced and the process time is shortened by drying a composition for forming a high-viscosity marine-derived biomass film and continuously producing it in the form of a film wound on a roll. You can.
  • the thickness of the marine-derived biomass film can be uniformly adjusted. This method of manufacturing marine-derived biomass films can be easily applied to large-scale mass production processes.
  • Figure 1 is a cross-sectional view of a film manufacturing apparatus for implementing a method for manufacturing a marine-derived biomass film according to an embodiment of the present invention.
  • Figure 2 is an enlarged cross-sectional view of the film forming part of Figure 1.
  • Figure 3 is a flow chart showing a method of manufacturing a marine-derived biomass film according to another embodiment of the present invention.
  • first or second may be used to describe various components, but these terms should be interpreted only for the purpose of distinguishing one component from other components.
  • a first component may be named a second component, and similarly, the second component may also be named a first component.
  • One embodiment of the present invention is a method of producing a marine-derived biomass film using a film manufacturing device including a film forming unit, a thickness adjusting unit connected to the film forming unit, and a drying unit connected to the thickness adjusting unit,
  • the film forming unit provides a method of manufacturing a marine-derived biomass film containing the composition for forming the marine-derived biomass film therein.
  • a manufacturing method in which the production cost of the product is reduced and the process time is shortened by drying a composition for forming a high-viscosity marine-derived biomass film and continuously producing it in the form of a film wound on a roll. You can. Additionally, according to an embodiment of the present invention, the thickness of the marine-derived biomass film can be uniformly adjusted.
  • Figure 1 is a cross-sectional view of a film manufacturing apparatus for implementing a method for manufacturing a marine-derived biomass film according to an embodiment of the present invention.
  • Figure 2 is an enlarged cross-sectional view of the film forming part of Figure 1.
  • the film manufacturing apparatus 100 for implementing the method for manufacturing a marine-derived biomass film according to the present invention includes a film forming part (FH) and a thickness adjusting part connected to the film forming part (FH). (20) and may include a drying unit (DR) connected to the thickness adjusting unit.
  • FH film forming part
  • DR drying unit
  • the meaning of 'connected' is defined to encompass not only the meaning of directly connecting one member to another member, but also the meaning of indirectly connecting one member.
  • the film forming part (FH) according to the present invention may be a member in which a film is formed by curing a composition for forming a marine-derived biomass film, which is a liquid sample in the form of a slurry.
  • the film manufacturing apparatus 100 has a first transfer felt supply unit (SF1) that supplies the first transfer felt (F1) to the film forming unit (FH) and a second transfer felt to the film forming unit (FH). It may include a second transfer felt supply unit (SF2) that supplies (F2).
  • the first transfer felt (F1) and the second transfer felt (F2) may be made of, for example, polyester-based resin, polyamide-based resin, fluorine-based resin, or polycarbonate-based resin.
  • the polyester-based resin may be, for example, polyethylene terephthalate (PET)
  • the fluorine-based resin may be, for example, polytetrafluoroethylene (PTFE).
  • the method for producing a marine-derived biomass film according to the present invention includes the step of (S1) applying a first curing agent to the first transfer felt (F1) entering the film forming portion (FH). Specifically, by applying the first curing agent on the surface of the first transfer felt, the slurry-type composition for forming a marine-derived biomass film can be well attached to the first transfer felt, and as a result, the reaction of forming a passive layer of the film proceeds.
  • the first film can be well formed.
  • the first curing agent is sucrose, lactose, maltose, MgCl 2 , CaCl 2 , sodium dodecyl sulfate, amine-based compound, and ethoxyl. It may be a solution containing one or more components selected from the group consisting of ethoxylate-based compounds.
  • the method for producing a marine-derived biomass film according to the present invention does not perform the step of applying a first curing agent (S1), but uses a composition for forming a marine-derived biomass film.
  • the first film can be formed by immediately applying it on the first transfer felt (F1).
  • the method for producing a marine-derived biomass film according to the present invention is (S2) forming a first film by applying a composition for forming a marine-derived biomass film on the first transfer felt (F1) to which the first curing agent is applied. It includes steps to: The composition for forming a marine-derived biomass film can be well attached to the first transfer felt (F1) due to the first curing agent applied to the surface of the first transfer felt.
  • the method for producing a marine-derived biomass film according to the present invention includes the step of (S3) forming a second film by applying a second curing agent that is the same as or different from the first curing agent on the first film.
  • the method of applying the first and second curing agents may be a spray method, and the spray device for implementing the spray method may be used at a point where the first and second transfer felt supply units and the film forming unit are connected or at the film forming unit depending on the purpose. Can be placed appropriately.
  • the second curing agent when the second curing agent is applied by a spray device, the second curing agent may be kept/stored in a dam structure, and the dam has a hole of a certain size so that the second curing agent is injected by spraying through the hole. It can be configured to be possible.
  • the method for producing a marine-derived biomass film according to the present invention includes the step of (S3) forming a second film by applying a second curing agent that is the same as or different from the first curing agent on the first film.
  • the method of applying the first and second curing agents may be a spray method, and the spray device for implementing the spray method may be used at a point where the first and second transfer felt supply units and the film forming unit are connected or at the film forming unit depending on the purpose. Can be placed appropriately.
  • the second curing agent when the second curing agent is applied by a spray device, the second curing agent may be kept/stored in a dam structure, and the dam has a hole of a certain size so that the second curing agent is injected by spraying through the hole. It can be configured to be possible.
  • the film forming part (FH) according to the present invention includes the composition (L) for forming the marine-derived biomass film therein.
  • the composition (L) for forming the marine-derived biomass film there was.
  • a manufacturing method in which the production cost of the product is reduced and the process time is shortened by drying a composition for forming a high-viscosity marine-derived biomass film and continuously producing it in the form of a film wound on a roll. You can. Additionally, according to an embodiment of the present invention, the thickness of the marine-derived biomass film can be uniformly adjusted.
  • the film forming part (FH) may include a passive layer forming part (CP) in which the composition for forming a marine-derived biomass film is cured.
  • the passive layer forming part (CP) may include a slurry-type composition for forming a marine-derived biomass film therein and a liquid first and second curing agent applied by a spray method.
  • the composition for forming a marine-derived biomass film may include a seafood-derived polymer compound derived from seafood.
  • the seafood may be any one selected from the group consisting of brown algae, red algae, green algae, and combinations thereof, and preferably brown algae.
  • the brown algae may be, for example, seaweed, kelp, kelp, etc.
  • the seafood-derived polymer compound according to the present invention may be a polysaccharide extracted from seafood.
  • the seafood-derived polymer compound may be alginate, and more specifically, the alginate may be sodium alginate or potassium alginate.
  • the weight average molecular weight of the alginate may be 10,000 to 100,000 g/mol, preferably 10,000 to 50,000 g/mol, and more preferably 10,000 to 30,000 g/mol. If the weight average molecular weight of the alginate is less than the above numerical range, the problem of lowering the strength of the marine-derived biomass film may occur, and if it exceeds the above numerical range, the viscosity of the composition for forming the marine-derived biomass film may become excessively high. .
  • the composition for forming a marine-derived biomass film according to the present invention may contain a plasticizer that lowers the viscosity of the composition and reduces deformation of the film due to external force.
  • the plasticizer may include an alcohol-type compound.
  • the alcohol compound may be any one selected from the group consisting of glycerin, xylitol, mannitol, sorbitol, and combinations thereof.
  • a composition for forming a marine-derived biomass film according to another embodiment of the present invention may further include 1 to 20 parts by weight of filler based on 100 parts by weight of the alginate.
  • the filler can be added to increase the strength and rigidity of the marine-derived biomass film.
  • the filler may be any one selected from the group consisting of protein-based additives, polysaccharide-based additives, and combinations thereof, and preferably may be a mixture of protein-based additives and polysaccharide-based additives. In this way, when two types of fillers are used, the strength and rigidity of the film can be further increased.
  • the protein-based additive may be, for example, any one selected from the group consisting of whey protein, gelatin, soy protein, keratin, and combinations thereof.
  • the molecular weight of the protein-based additive may be, for example, 15 to 75 kDa.
  • the polysaccharide-based additive may include any one selected from the group consisting of ⁇ -cellulose, ⁇ -cellulose, nanocellulose, starch, and combinations thereof.
  • the molecular weight of the polysaccharide-based additive may be, for example, 15 to 75 kDa.
  • the polysaccharide-based additive may be starch containing a large amount of starch.
  • the starch may be, for example, common corn starch, potato starch, cassava starch, etc.
  • the content of the filler may be preferably 2 to 10 parts by weight, more preferably 2 to 5 parts by weight, based on 100 parts by weight of the alginate. Only when the content of the filler satisfies the above numerical range can the strength and rigidity of the marine-derived biomass film be improved.
  • the composition for forming a marine-derived biomass film according to another embodiment of the present invention may further include 1 to 5 parts by weight of a moisture barrier additive based on 100 parts by weight of the alginate.
  • the moisture barrier additive may be added as needed to provide barrier properties against moisture.
  • the content of the moisture barrier additive can be adjusted appropriately.
  • the moisture barrier additive may be mica with a particle size of 1 to 10 ⁇ m (micrometer).
  • the film forming part (FH) includes a first adjusting part 12 that adjusts the thickness of the first film, adjusts the width of the first film, and marine-derived biomass. It may include a second control unit that prevents external leakage of the film forming composition (L) and a dam 14 opposite the first control unit 12.
  • the first adjusting part 12 may be, for example, a doctor blade, and the second adjusting part may be, for example, a side guard. Due to the first control unit and the second control unit, the width and thickness of the film can be precisely adjusted.
  • the dam 14 is a structure that has a volume capable of storing a certain amount of sample, and serves as a structure that assists injection while maintaining a constant input of a certain volume of sample to stably form a film.
  • the film forming unit (FH) uses a comma coater composed of several rolls to form the first film to a certain thickness.
  • a casting method can be adopted (not shown).
  • the film manufacturing apparatus 100 may include a first roll for supplying a film forming composition to the film forming unit (FH) and a second roll for supplying a substrate to the film forming unit (FH).
  • the first roll and the second roll may include, for example, tungsten carbide (WC) in consideration of wear resistance and oxidation resistance.
  • the method of manufacturing a marine-derived biomass film according to the present invention may further include (S4) adjusting the thickness of the second film in the thickness adjustment unit 20.
  • the thickness adjusting unit 20 may include a calendering roll (gap roll) that applies pressure to the surface of the second film, and the thickness of the second film whose thickness is adjusted may be 0.01 to 1.00 cm. there is. Calendering rolls can be used to apply pressure to both surfaces of the laminate passing between two rolls.
  • the laminate may be composed of a first transfer felt, a second transfer felt, and a second film interposed between the first transfer felt and the second transfer felt. By applying pressure to both surfaces of the laminate, the thickness of the second film can be precisely adjusted according to the purpose.
  • the second film may be interposed between the first transfer felt and a second transfer felt that is different from the first transfer felt.
  • the moving speed of the first and second transfer felts may each independently be 10 cm/min to 500 m/min, specifically 10 m/min to 200 m/min, and more specifically 50 m/min to 150 m/min. It can be. For example, it may be desirable in the process that the moving speeds of the first and second transfer felts are the same.
  • the first and second transfer felts may each independently include pores of 150 to 250 mesh. Specifically, because the first and second transfer felts include pores in the above size range, the solvent contained in the film can be effectively vaporized.
  • the method for producing a marine-derived biomass film according to the present invention may further include (S5) drying the second film whose thickness is adjusted in the drying unit (DR).
  • the step (S5) may be a step using any one selected from the group consisting of an infrared drying method, a hot air drying method, and a combination thereof, and preferably a step using a combination thereof.
  • the solvent remaining in the second film can be effectively removed, and as a result, the thickness of the marine-derived biomass film can be precisely controlled.
  • the drying unit (DR) may include a tunnel (TN) through which the second film passes.
  • the tunnel TN may be a profile that defines a space through which the laminate passes.
  • the internal temperature of the tunnel TN may be adjusted to, for example, 60 to 200°C.
  • the drying unit DR may additionally include piping to help hot air reflux.
  • the method for producing a marine-derived biomass film according to the present invention may further include (S6) the step of rewinding the dried second film in a rewinding unit (RW) connected to the drying unit (DR).
  • the rewinding unit (RW) may include a profile controller attached to the front end of the roll on which the dried second film is wound. The profile control unit can facilitate rewinding.
  • the first transfer felt (F1) according to the present invention can be wound in a roll form on the first air shaft (AS1), and the second transfer felt (F2) is wrapped around the second air shaft (AS2). It can be wound in a roll shape, and the second film can be wound in a roll shape on the third air shaft (AS3).
  • the first to third air shafts (AS1, AS2, AS3) may be cylindrical, which allows the transfer felt and film to be easily wound into a roll shape.
  • the rewinding unit (RW) of the present invention separates the dried second film, the first transfer felt (F1), and the second transfer felt (F2), and then separates the first transfer felt (F1) from the dried second film to create a new film. It may have a structure that circulates the second transfer felt (F2) back to the front end (not shown). In this way, by having a structure in which the first transfer felt (F1) and the second transfer felt (F2) are circulated to the front end, a continuous process is possible and the productivity of the marine-derived biomass film can be increased.
  • Figure 3 is a flow chart showing a method of manufacturing a marine-derived biomass film according to another embodiment of the present invention.
  • the method for manufacturing a marine-derived biomass film includes the steps of (a) applying a first curing agent to a first transfer felt entering the film forming unit by spraying; (b) forming a first film by applying a composition for forming a marine-derived biomass film on a first transfer felt coated with a first curing agent; (c) forming a second film by applying a second curing agent on the first film by spraying; (d) adjusting the thickness of the second film with a calendering roll; (e) drying the second film whose thickness is adjusted while passing it through an infrared and hot air tunnel; and (f) rewinding the dried second film.
  • the present invention provides the film forming portion (FH), a thickness adjusting portion 20 connected to the film forming portion (FH), and a drying portion connected to the thickness adjusting portion 20 (A method of manufacturing an eco-friendly film using a film manufacturing device including DR),
  • the first circulating felt may circulate in an endless orbit.
  • the step of forming the fourth film may be performed in a dam 14 in the form of a water reservoir containing the first curing agent.

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Abstract

Provided is a method for manufacturing a marine-derived biomass film capable of precisely adjusting the thickness of a marine-derived biomass film. According to an embodiment of the present invention, provided is a method for manufacturing a marine-derived biomass film using a film manufacturing device comprising a film forming part, a thickness adjusting part connected to the film forming part, and a drying part connected to the thickness adjusting part, the method for manufacturing a marine-derived biomass film comprising the steps of: (S1) applying a first curing agent to a first transfer felt that enters the film forming part; (S2) forming a first film by applying a composition for forming a marine-derived biomass film on the first transfer felt to which the first curing agent has been applied; and (S3) forming a second film by applying a second curing agent identical to or different from the first curing agent on the first film, wherein the film forming part comprises therein the composition for forming a marine-derived biomass film.

Description

해양유래 바이오매스 필름의 제조방법Manufacturing method of marine-derived biomass film

본 발명은 해양유래 바이오매스 필름의 제조방법에 관한 것으로, 보다 구체적으로 제품의 생산비용이 절감되고 공정시간이 단축될 수 있는 해양유래 바이오매스 필름의 제조방법에 관한 것이다. The present invention relates to a method of manufacturing a marine-derived biomass film, and more specifically, to a method of manufacturing a marine-derived biomass film that can reduce product production costs and shorten the process time.

알긴산은 염의 금속 이온과 쉽게 반응하여 상업적 용도로 다양한 종류의 알지네이트를 형성하는 해양유래 바이오매스(천연 공중합체)이다. Alginic acid is a marine-derived biomass (natural copolymer) that easily reacts with metal ions in salts to form various types of alginates for commercial use.

알긴산 염 중 하나인 알긴산나트륨(sodium alginate; SA)은 다량의 물을 쉽게 흡수하여 고점도의 용액을 형성하는 특성을 가지기 때문에 기존의 고분자 필름 생산 공정이나 제지 공정을 적용하더라도 얇고 균일한 알지네이트 필름을 연속적으로 생산하는 것은 쉽지 않은 문제점을 갖고 있었다. Sodium alginate (SA), one of the alginate salts, has the property of easily absorbing a large amount of water and forming a high viscosity solution, so even if the existing polymer film production process or papermaking process is applied, a thin and uniform alginate film can be continuously produced. There were problems with producing it.

알긴산나트륨을 활용하여 필름을 제조하는 선행문헌들은 랩스케일 (Lab-scale) 수준의 간이 필름을 생산하는 내용만을 제시하고 있고, 설사 전체 공정을 제시하였더라도 최초의 시료 용액에서부터 필름의 두께를 정교하게 조절할 수 있는 공정 및 설비에 관한 내용에 관한 연구는 미흡한 실정이다. Prior literature on producing films using sodium alginate only presents the production of simple films at the lab-scale level, and even if the entire process was presented, the thickness of the film could not be precisely controlled from the first sample solution. Research on possible processes and equipment is insufficient.

예를 들어, 대한민국 공개특허공보 제10-2016-0055973호 (2012.11.15. 국제공개)는 알지네이트막 층을 보유하는 필름 및 그 제조 방법에 관한 발명으로, 액체를 흡수하기 위해 필름 캐리어를 사용하며 2회의 별도의 연속 코팅 공정에 의해 처리되는 알제네이트막을 보유하는 필름의 제조방법을 개시하고 있지만, 최초의 시료 용액에서부터 알지네이트막 필름의 두께를 정교하게 조절하거나 얇은 알지네이트막을 제조하는 방법에 대해서는 개시하고 있지 않다.For example, Republic of Korea Patent Publication No. 10-2016-0055973 (International Publication on November 15, 2012) is an invention regarding a film having an alginate film layer and a method for manufacturing the same, using a film carrier to absorb liquid. Although a method of manufacturing a film having an algenate film processed by two separate continuous coating processes is disclosed, a method of precisely controlling the thickness of the algenate film from the first sample solution or manufacturing a thin algenate film is disclosed. There is not.

본 발명의 목적은, 해양유래 바이오매스 필름의 두께를 정교하게 조절할 수 있는 해양유래 바이오매스 필름의 제조방법을 제공하는 것이다.The purpose of the present invention is to provide a method for manufacturing a marine-derived biomass film that can precisely control the thickness of the marine-derived biomass film.

본 발명의 다른 목적은, 연속식 롤투롤 공정으로 제조하여 생산비용이 절감되고 공정시간이 단축될 수 있는 해양유래 바이오매스 필름의 제조방법을 제공하는 것이다.Another object of the present invention is to provide a method for manufacturing a marine-derived biomass film that can reduce production costs and shorten the process time by manufacturing in a continuous roll-to-roll process.

본 발명의 또 다른 목적은 상기 해양유래 바이오매스 필름의 제조방법을 구현할 수 있는 필름 제조장치를 제공하는 것이다.Another object of the present invention is to provide a film manufacturing apparatus capable of implementing the method for manufacturing the marine-derived biomass film.

본 발명의 목적들은 이상에서 언급한 목적으로 제한되지 않으며, 언급되지 않은 본 발명의 다른 목적 및 장점들은 하기의 설명에 의해서 이해될 수 있고, 본 발명의 실시예에 의해 보다 분명하게 이해될 것이다. 또한, 본 발명의 목적 및 장점들은 청구범위에 나타낸 수단 및 그 조합에 의해 실현될 수 있음을 쉽게 알 수 있을 것이다.The objects of the present invention are not limited to the objects mentioned above, and other objects and advantages of the present invention that are not mentioned can be understood by the following description and will be more clearly understood by the examples of the present invention. Additionally, it will be readily apparent that the objects and advantages of the present invention can be realized by means and combinations thereof as set forth in the claims.

상기 목적을 달성하기 위한 본 발명의 일 실시예는, 필름 형성부, 상기 필름 형성부와 연결된 두께조절부 및 상기 두께조절부와 연결된 건조부를 포함하는 필름 제조장치를 이용하는 해양유래 바이오매스 필름의 제조방법으로, One embodiment of the present invention for achieving the above object is the production of a marine-derived biomass film using a film manufacturing apparatus including a film forming unit, a thickness adjusting unit connected to the film forming unit, and a drying unit connected to the thickness adjusting unit. in a way,

(S1) 상기 필름 형성부에 들어가는 제1 이송펠트에 제1 경화제를 도포하는 단계; (S1) applying a first curing agent to the first transfer felt entering the film forming unit;

(S2) 상기 제1 경화제가 도포된 제1 이송펠트 상에, 해양유래 바이오매스 필름 형성용 조성물을 도포하여 제1 필름을 형성하는 단계; 및 (S2) forming a first film by applying a composition for forming a marine-derived biomass film on the first transfer felt to which the first curing agent is applied; and

(S3) 상기 제1 필름 상에, 상기 제1 경화제와 동일하거나 상이한 제2 경화제를 도포하여 제2 필름을 형성하는 단계를 포함하고, (S3) comprising forming a second film by applying a second curing agent that is the same as or different from the first curing agent on the first film,

상기 필름 형성부는, 그 내부에 상기 해양유래 바이오매스 필름 형성용 조성물을 포함하는 해양유래 바이오매스 필름의 제조방법을 제공한다.The film forming unit provides a method of manufacturing a marine-derived biomass film containing the composition for forming the marine-derived biomass film therein.

본 발명의 일 실시예에 따르면, 상기 필름 형성부는 상기 제1 필름의 두께를 조절하는 제1 조절부; 상기 제1 필름의 폭을 조절하는 제2 조절부; 및 상기 제1 조절부와 대향되는 댐을 포함한다.According to one embodiment of the present invention, the film forming unit includes a first adjusting unit that adjusts the thickness of the first film; a second control unit that adjusts the width of the first film; and a dam opposite to the first adjustment unit.

본 발명의 일 실시예에 따르면, 상기 제1 및 제2 경화제를 도포하는 방법은 스프레이 방법일 수 있다.According to one embodiment of the present invention, the method of applying the first and second curing agents may be a spray method.

본 발명의 일 실시예에 따르면, 본 발명의 해양유래 바이오매스 필름의 제조방법은 (S4) 상기 두께조절부에서 상기 제2 필름의 두께를 조절하는 단계를 더 포함할 수 있다.According to one embodiment of the present invention, the method for producing a marine-derived biomass film of the present invention may further include (S4) adjusting the thickness of the second film in the thickness adjustment unit.

본 발명의 일 실시예에 따르면, 상기 두께조절부는 상기 제2 필름의 표면에 압력을 가하는 캘린더링 롤(gap roll)을 포함하고, 상기 두께가 조절된 제2 필름의 두께는 0.01 내지 1.00cm일 수 있다.According to one embodiment of the present invention, the thickness adjusting unit includes a calendering roll (gap roll) that applies pressure to the surface of the second film, and the thickness of the second film whose thickness is adjusted is 0.01 to 1.00 cm. You can.

본 발명의 일 실시예에 따르면, 상기 제1 및 제2 이송펠트의 이동속도는 각각 독립적으로 10 cm/min 내지 500m/min일 수 있다.According to one embodiment of the present invention, the moving speeds of the first and second transfer felts may each independently be 10 cm/min to 500 m/min.

본 발명의 일 실시예에 따르면, 본 발명의 해양유래 바이오매스 필름의 제조방법은 (S5) 상기 건조부에서 상기 두께가 조절된 제2 필름을 건조하는 단계를 더 포함할 수 있다.According to one embodiment of the present invention, the method for producing a marine-derived biomass film of the present invention may further include (S5) drying the second film whose thickness is adjusted in the drying unit.

본 발명의 일 실시예에 따르면, 상기 (S5) 단계는 적외선 건조방법, 열풍 건조방법 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나를 이용하는 단계일 수 있다.According to one embodiment of the present invention, step (S5) may be a step using any one selected from the group consisting of an infrared drying method, a hot air drying method, and a combination thereof.

본 발명의 일 실시예에 따르면, 상기 건조부는 내부에 상기 제2 필름이 통과하는 터널을 포함할 수 있다.According to one embodiment of the present invention, the drying unit may include a tunnel through which the second film passes.

본 발명의 일 실시예에 따르면, 본 발명의 해양유래 바이오매스 필름의 제조방법은 (S6) 상기 건조부와 연결된 리와인딩부에서 상기 건조된 제2 필름을 리와인드(rewind)하는 단계를 더 포함하고, 상기 리와인딩부는 상기 건조된 제2 필름이 권취되는 롤의 전단에 부착된 프로파일 제어부(profile controller)를 포함할 수 있다.According to one embodiment of the present invention, the method for producing a marine-derived biomass film of the present invention further includes the step of (S6) rewinding the dried second film in a rewinding unit connected to the drying unit, , the rewinding unit may include a profile controller attached to the front end of the roll on which the dried second film is wound.

상기 과제의 해결수단은, 본 발명의 특징을 모두 열거한 것은 아니다. 본 발명의 다양한 특징과 그에 따른 장점과 효과는 아래의 구체적인 실시예를 참조하여 보다 상세하게 이해될 수 있을 것이다.The solution to the above problem does not enumerate all the features of the present invention. The various features of the present invention and its advantages and effects can be understood in more detail by referring to the specific examples below.

본 발명의 일 실시예에 따르면, 고점도의 해양유래 바이오매스 필름 형성용 조성물을 건조하여 롤에 권취된 필름 형태로 연속적으로 생산함으로써 제품의 생산비용이 절감되고 공정시간이 단축된 제조방법을 제공할 수 있다. According to one embodiment of the present invention, a manufacturing method is provided in which the production cost of the product is reduced and the process time is shortened by drying a composition for forming a high-viscosity marine-derived biomass film and continuously producing it in the form of a film wound on a roll. You can.

또한, 본 발명의 일 실시예에 따르면 해양유래 바이오매스 필름의 두께를 균일하게 조절할 수 있다. 이러한 해양유래 바이오매스 필름의 제조방법은 대규모 스케일의 대량생산 공정에도 쉽게 적용될 수 있다. Additionally, according to an embodiment of the present invention, the thickness of the marine-derived biomass film can be uniformly adjusted. This method of manufacturing marine-derived biomass films can be easily applied to large-scale mass production processes.

상술한 효과와 더불어 본 발명의 구체적인 효과는 이하 발명을 실시하기 위한 구체적인 내용을 설명하면서 함께 기술한다.In addition to the above-described effects, specific effects of the present invention are described below while explaining specific details for carrying out the invention.

도 1은 본 발명의 일 실시예에 따른 해양유래 바이오매스 필름의 제조방법을 구현하기 위한 필름 제조장치의 단면도이다. Figure 1 is a cross-sectional view of a film manufacturing apparatus for implementing a method for manufacturing a marine-derived biomass film according to an embodiment of the present invention.

도 2는 도 1의 필름 형성부를 확대한 단면도이다.Figure 2 is an enlarged cross-sectional view of the film forming part of Figure 1.

도 3은 본 발명의 다른 실시예에 따른 해양유래 바이오매스 필름의 제조방법을 나타낸 플로우 차트이다.Figure 3 is a flow chart showing a method of manufacturing a marine-derived biomass film according to another embodiment of the present invention.

이하, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 본 발명의 각 구성을 보다 상세히 설명하나, 이는 하나의 예시에 불과할 뿐, 본 발명의 권리범위가 다음 내용에 의해 제한되지 아니한다.Hereinafter, each configuration of the present invention will be described in more detail so that those skilled in the art can easily implement it. However, this is only an example, and the scope of rights of the present invention is determined by the following contents. Not limited.

한편, 제1 또는 제2 등의 용어를 다양한 구성요소들을 설명하는데 사용될 수 있지만, 이런 용어들은 하나의 구성요소를 다른 구성요소로부터 구별하는 목적으로만 해석되어야 한다. 예를 들어, 제1 구성요소는 제2 구성요소로 명명될 수 있고, 유사하게 제2 구성요소는 제1 구성요소로도 명명될 수 있다.Meanwhile, terms such as first or second may be used to describe various components, but these terms should be interpreted only for the purpose of distinguishing one component from other components. For example, a first component may be named a second component, and similarly, the second component may also be named a first component.

단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다. 본 명세서에서, "포함하다" 또는 "가지다" 등의 용어는 설명된 특징, 숫자, 단계, 동작, 구성요소, 부분품 또는 이들을 조합한 것이 존재함으로 지정하려는 것이지, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 동작, 구성요소, 부분품 또는 이들을 조합한 것들의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다.Singular expressions include plural expressions unless the context clearly dictates otherwise. In this specification, terms such as “comprise” or “have” are intended to designate the presence of the described features, numbers, steps, operations, components, parts, or combinations thereof, and are intended to indicate the presence of one or more other features or numbers, It should be understood that this does not exclude in advance the possibility of the presence or addition of steps, operations, components, parts, or combinations thereof.

다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 해당 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가진다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥상 가지는 의미와 일치하는 의미를 갖는 것으로 해석되어야 하며, 본 명세서에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다.Unless otherwise defined, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by a person of ordinary skill in the art. Terms as defined in commonly used dictionaries should be interpreted as having meanings consistent with the meanings they have in the context of the related technology, and unless clearly defined in this specification, should not be interpreted in an idealized or overly formal sense. No.

본 발명의 일 실시예는 필름 형성부, 상기 필름 형성부와 연결된 두께조절부 및 상기 두께조절부와 연결된 건조부를 포함하는 필름 제조장치를 이용하는 해양유래 바이오매스 필름의 제조방법으로, One embodiment of the present invention is a method of producing a marine-derived biomass film using a film manufacturing device including a film forming unit, a thickness adjusting unit connected to the film forming unit, and a drying unit connected to the thickness adjusting unit,

(S1) 상기 필름 형성부에 들어가는 제1 이송펠트에 제1 경화제를 도포하는 단계; (S1) applying a first curing agent to the first transfer felt entering the film forming unit;

(S2) 상기 제1 경화제가 도포된 제1 이송펠트 상에, 해양유래 바이오매스 필름 형성용 조성물을 도포하여 제1 필름을 형성하는 단계; 및 (S2) forming a first film by applying a composition for forming a marine-derived biomass film on the first transfer felt to which the first curing agent is applied; and

(S3) 상기 제1 필름 상에, 상기 제1 경화제와 동일하거나 상이한 제2 경화제를 도포하여 제2 필름을 형성하는 단계를 포함하고, (S3) comprising forming a second film by applying a second curing agent that is the same as or different from the first curing agent on the first film,

상기 필름 형성부는, 그 내부에 상기 해양유래 바이오매스 필름 형성용 조성물을 포함하는 해양유래 바이오매스 필름의 제조방법을 제공한다. The film forming unit provides a method of manufacturing a marine-derived biomass film containing the composition for forming the marine-derived biomass film therein.

본 발명의 일 실시예에 따르면, 고점도의 해양유래 바이오매스 필름 형성용 조성물을 건조하여 롤에 권취된 필름 형태로 연속적으로 생산함으로써 제품의 생산비용이 절감되고 공정시간이 단축된 제조방법을 제공할 수 있다. 또한, 본 발명의 일 실시예에 따르면 해양유래 바이오매스 필름의 두께를 균일하게 조절할 수 있다.According to one embodiment of the present invention, a manufacturing method is provided in which the production cost of the product is reduced and the process time is shortened by drying a composition for forming a high-viscosity marine-derived biomass film and continuously producing it in the form of a film wound on a roll. You can. Additionally, according to an embodiment of the present invention, the thickness of the marine-derived biomass film can be uniformly adjusted.

이하에서는, 도면을 참고하여 본 발명의 구성을 보다 상세히 설명한다.Hereinafter, the configuration of the present invention will be described in more detail with reference to the drawings.

도 1은 본 발명의 일 실시예에 따른 해양유래 바이오매스 필름의 제조방법을 구현하기 위한 필름 제조장치의 단면도이다. Figure 1 is a cross-sectional view of a film manufacturing apparatus for implementing a method for manufacturing a marine-derived biomass film according to an embodiment of the present invention.

도 2는 도 1의 필름 형성부를 확대한 단면도이다.Figure 2 is an enlarged cross-sectional view of the film forming part of Figure 1.

도 1 및 2를 참고하면, 본 발명에 따른 해양유래 바이오매스 필름의 제조방법을 구현하기 위한 필름 제조장치(100)는 필름 형성부(FH), 상기 필름 형성부(FH)와 연결된 두께조절부(20) 및 상기 두께조절부와 연결된 건조부(DR)를 포함할 수 있다. 본 명세서에서 '연결된다'의 의미는 일 부재와 다른 부재가 직접적으로 연결되는 의미뿐만 아니라 간접적으로 연결되는 의미도 포괄할 수 있는 것으로 정의된다.Referring to Figures 1 and 2, the film manufacturing apparatus 100 for implementing the method for manufacturing a marine-derived biomass film according to the present invention includes a film forming part (FH) and a thickness adjusting part connected to the film forming part (FH). (20) and may include a drying unit (DR) connected to the thickness adjusting unit. In this specification, the meaning of 'connected' is defined to encompass not only the meaning of directly connecting one member to another member, but also the meaning of indirectly connecting one member.

본 발명에 따른 필름 형성부(FH)는 슬러리 형태의 액상 시료인 해양유래 바이오매스 필름 형성용 조성물을 경화시켜 필름이 형성되는 부재일 수 있다.The film forming part (FH) according to the present invention may be a member in which a film is formed by curing a composition for forming a marine-derived biomass film, which is a liquid sample in the form of a slurry.

본 발명에 따른 필름 제조장치(100)는 상기 필름 형성부(FH)에 제1 이송펠트(F1)를 공급하는 제1 이송펠트 공급부(SF1) 및 상기 필름 형성부(FH)에 제2 이송펠트(F2)를 공급하는 제2 이송펠트 공급부(SF2)를 포함할 수 있다. 상기 제1 이송펠트(F1) 및 제2 이송펠트(F2)는 예를 들어, 폴리에스테르계 수지, 폴리아마이드계 수지, , 불소계 수지, 또는 폴리카보네이트계 수지로 이루어진 것일 수 있다. 상기 폴리에스테르계 수지는 예를 들어, 폴리에틸렌 테레프탈레이트(polyethylene terephthalate; PET)일 수 있고, 상기 불소계 수지는 예를 들어, 폴리테트라플루오로에틸렌(polytetrafluoroethylene; PTFE)일 수 있다. The film manufacturing apparatus 100 according to the present invention has a first transfer felt supply unit (SF1) that supplies the first transfer felt (F1) to the film forming unit (FH) and a second transfer felt to the film forming unit (FH). It may include a second transfer felt supply unit (SF2) that supplies (F2). The first transfer felt (F1) and the second transfer felt (F2) may be made of, for example, polyester-based resin, polyamide-based resin, fluorine-based resin, or polycarbonate-based resin. The polyester-based resin may be, for example, polyethylene terephthalate (PET), and the fluorine-based resin may be, for example, polytetrafluoroethylene (PTFE).

본 발명에 따른 해양유래 바이오매스 필름의 제조방법은, (S1) 상기 필름 형성부(FH)에 들어가는 제1 이송펠트(F1)에 제1 경화제를 도포하는 단계를 포함한다. 구체적으로, 상기 제1 이송펠트의 표면 위에 제1 경화제가 도포됨으로써 슬러리 형태의 해양유래 바이오매스 필름 형성용 조성물이 제1 이송펠트에 잘 부착될 수 있고, 결과적으로 필름의 부동층 형성 반응이 진행되어 제1 필름이 잘 형성될 수 있다. 상기 제1 경화제는 수크로스(sucrose), 락토스(lactose), 말토스(maltose), MgCl2, CaCl2, 도데실 황산 나트륨(sodium dodecyl sulfate), 아민계 화합물(amine-based compound) 및 에톡실레이트계 화합물(ethoxylate-based compound)로 이루어진 군에서 선택된 1개 이상의 성분을 포함하는 용액일 수 있다.The method for producing a marine-derived biomass film according to the present invention includes the step of (S1) applying a first curing agent to the first transfer felt (F1) entering the film forming portion (FH). Specifically, by applying the first curing agent on the surface of the first transfer felt, the slurry-type composition for forming a marine-derived biomass film can be well attached to the first transfer felt, and as a result, the reaction of forming a passive layer of the film proceeds. The first film can be well formed. The first curing agent is sucrose, lactose, maltose, MgCl 2 , CaCl 2 , sodium dodecyl sulfate, amine-based compound, and ethoxyl. It may be a solution containing one or more components selected from the group consisting of ethoxylate-based compounds.

한편, 본 발명에 따른 해양유래 바이오매스 필름의 제조방법은 목적하는 해양유래 바이오매스 필름의 성분에 따라, (S1) 제1 경화제를 도포하는 단계를 수행하지 않고, 해양유래 바이오매스 필름 형성용 조성물을 곧바로 제1 이송펠트(F1) 상에 도포하여 제1 필름을 형성할 수 있다.On the other hand, the method for producing a marine-derived biomass film according to the present invention, depending on the components of the desired marine-derived biomass film, does not perform the step of applying a first curing agent (S1), but uses a composition for forming a marine-derived biomass film. The first film can be formed by immediately applying it on the first transfer felt (F1).

본 발명에 따른 해양유래 바이오매스 필름의 제조방법은, (S2) 상기 제1 경화제가 도포된 제1 이송펠트(F1) 상에, 해양유래 바이오매스 필름 형성용 조성물을 도포하여 제1 필름을 형성하는 단계를 포함한다. 상기 해양유래 바이오매스 필름 형성용 조성물은 제1 이송펠트의 표면에 도포된 제1 경화제로 인해 제1 이송펠트(F1)와 잘 부착될 수 있다. The method for producing a marine-derived biomass film according to the present invention is (S2) forming a first film by applying a composition for forming a marine-derived biomass film on the first transfer felt (F1) to which the first curing agent is applied. It includes steps to: The composition for forming a marine-derived biomass film can be well attached to the first transfer felt (F1) due to the first curing agent applied to the surface of the first transfer felt.

본 발명에 따른 해양유래 바이오매스 필름의 제조방법은, (S3) 상기 제1 필름 상에, 상기 제1 경화제와 동일하거나 상이한 제2 경화제를 도포하여 제2 필름을 형성하는 단계를 포함한다. 상기 제1 및 제2 경화제를 도포하는 방법은, 스프레이 방법일 수 있고 상기 스프레이 방법을 구현하기 위한 스프레이 장치는 목적에 따라 제1 및 제2 이송펠트 공급부 및 필름 형성부가 연결된 지점 또는 필름 형성부에서 적절하게 배치될 수 있다. 구체적으로, 제2 경화제가 스프레이 장치에 의해 도포되는 경우, 제2 경화제는 댐 구조에 보관/저장될 수 있으며, 상기 댐은 일정 크기의 구멍을 가져 제2 경화제가 상기 구멍을 통해 스프레이 방식으로 사출될 수 있도록 구성될 수 있다. The method for producing a marine-derived biomass film according to the present invention includes the step of (S3) forming a second film by applying a second curing agent that is the same as or different from the first curing agent on the first film. The method of applying the first and second curing agents may be a spray method, and the spray device for implementing the spray method may be used at a point where the first and second transfer felt supply units and the film forming unit are connected or at the film forming unit depending on the purpose. Can be placed appropriately. Specifically, when the second curing agent is applied by a spray device, the second curing agent may be kept/stored in a dam structure, and the dam has a hole of a certain size so that the second curing agent is injected by spraying through the hole. It can be configured to be possible.

본 발명에 따른 해양유래 바이오매스 필름의 제조방법은, (S3) 상기 제1 필름 상에, 상기 제1 경화제와 동일하거나 상이한 제2 경화제를 도포하여 제2 필름을 형성하는 단계를 포함한다. 상기 제1 및 제2 경화제를 도포하는 방법은, 스프레이 방법일 수 있고 상기 스프레이 방법을 구현하기 위한 스프레이 장치는 목적에 따라 제1 및 제2 이송펠트 공급부 및 필름 형성부가 연결된 지점 또는 필름 형성부에서 적절하게 배치될 수 있다. 구체적으로, 제2 경화제가 스프레이 장치에 의해 도포되는 경우, 제2 경화제는 댐 구조에 보관/저장될 수 있으며, 상기 댐은 일정 크기의 구멍을 가져 제2 경화제가 상기 구멍을 통해 스프레이 방식으로 사출될 수 있도록 구성될 수 있다. The method for producing a marine-derived biomass film according to the present invention includes the step of (S3) forming a second film by applying a second curing agent that is the same as or different from the first curing agent on the first film. The method of applying the first and second curing agents may be a spray method, and the spray device for implementing the spray method may be used at a point where the first and second transfer felt supply units and the film forming unit are connected or at the film forming unit depending on the purpose. Can be placed appropriately. Specifically, when the second curing agent is applied by a spray device, the second curing agent may be kept/stored in a dam structure, and the dam has a hole of a certain size so that the second curing agent is injected by spraying through the hole. It can be configured to be possible.

본 발명에 따른 필름 형성부(FH)는 그 내부에 상기 해양유래 바이오매스 필름 형성용 조성물(L)을 포함한다. 종래 다량의 물을 쉽게 흡수하여 고점도의 용액을 형성하는 알긴산염의 특성으로 인해 슬러리 형태의 해양유래 바이오매스 필름 형성용 조성물로 고분자 필름의 생산 공정이나 제지 공정으로 얇은 필름을 연속적으로 생산하기 어려운 문제점이 있었다. The film forming part (FH) according to the present invention includes the composition (L) for forming the marine-derived biomass film therein. Conventionally, due to the characteristics of alginate, which easily absorbs large amounts of water and forms a high viscosity solution, it is difficult to continuously produce thin films through the polymer film production process or papermaking process with a slurry-type composition for forming marine-derived biomass films. there was.

본 발명의 일 실시예에 따르면, 고점도의 해양유래 바이오매스 필름 형성용 조성물을 건조하여 롤에 권취된 필름 형태로 연속적으로 생산함으로써 제품의 생산비용이 절감되고 공정시간이 단축된 제조방법을 제공할 수 있다. 또한, 본 발명의 일 실시예에 따르면 해양유래 바이오매스 필름의 두께를 균일하게 조절할 수 있다.According to one embodiment of the present invention, a manufacturing method is provided in which the production cost of the product is reduced and the process time is shortened by drying a composition for forming a high-viscosity marine-derived biomass film and continuously producing it in the form of a film wound on a roll. You can. Additionally, according to an embodiment of the present invention, the thickness of the marine-derived biomass film can be uniformly adjusted.

본 발명에 따른 필름 형성부(FH)는 해양유래 바이오매스 필름 형성용 조성물이 경화되는 부동층 형성부(CP)를 포함할 수 있다. 구체적으로, 상기 부동층 형성부(CP)는 그 내부에 슬러리 형태의 해양유래 바이오매스 필름 형성용 조성물 및 스프레이 방법으로 도포된 액상의 제1 및 제2 경화제를 포함할 수 있다. The film forming part (FH) according to the present invention may include a passive layer forming part (CP) in which the composition for forming a marine-derived biomass film is cured. Specifically, the passive layer forming part (CP) may include a slurry-type composition for forming a marine-derived biomass film therein and a liquid first and second curing agent applied by a spray method.

구체적으로, 상기 해양유래 바이오매스 필름 형성용 조성물은 해산물에서 유래된 해산물 유래 고분자 화합물을 포함할 수 있다. 상기 해산물은 갈조류, 홍조류, 녹조류 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나일 수 있고 바람직하게는 갈조류일 수 있다. 상기 갈조류는 예를 들어, 미역, 다시마, 켈프 등일 수 있다.Specifically, the composition for forming a marine-derived biomass film may include a seafood-derived polymer compound derived from seafood. The seafood may be any one selected from the group consisting of brown algae, red algae, green algae, and combinations thereof, and preferably brown algae. The brown algae may be, for example, seaweed, kelp, kelp, etc.

본 발명에 따른 해산물 유래 고분자 화합물은 해산물로부터 추출된 다당류일 수 있다. 구체적으로, 상기 해산물 유래 고분자 화합물은, 알긴산염일 수 있고, 더욱 구체적으로 상기 알긴산염은 알긴산나트륨 또는 알긴산칼륨일 수 있다.The seafood-derived polymer compound according to the present invention may be a polysaccharide extracted from seafood. Specifically, the seafood-derived polymer compound may be alginate, and more specifically, the alginate may be sodium alginate or potassium alginate.

상기 알긴산염의 중량평균분자량은 10,000 내지 100,000g/mol일 수 있고, 바람직하게는 10,000 내지 50,000g/mol일 수 있고, 더욱 바람직하게는 10,000 내지 30,000g/mol일 수 있다. 상기 알긴산염의 중량평균분자량이 상기 수치 범위 미만일 경우 해양유래 바이오매스 필름의 강도가 낮아지는 문제가 생길 수 있고, 상기 수치 범위를 초과할 경우 해양유래 바이오매스 필름 형성용 조성물의 점도가 지나치게 높아질 수 있다.The weight average molecular weight of the alginate may be 10,000 to 100,000 g/mol, preferably 10,000 to 50,000 g/mol, and more preferably 10,000 to 30,000 g/mol. If the weight average molecular weight of the alginate is less than the above numerical range, the problem of lowering the strength of the marine-derived biomass film may occur, and if it exceeds the above numerical range, the viscosity of the composition for forming the marine-derived biomass film may become excessively high. .

본 발명에 따른 알긴산염의 함량은 상기 해양유래 바이오매스 필름 형성용 조성물의 전체 중량을 기준으로 27 내지 43 중량%일 수 있고, 바람직하게는 35 내지 43 중량%, 더욱 바람직하게는 40 내지 42 중량%일 수 있다. 상기 알긴산염의 함량이 상기 수치 범위 내일 때, 해양유래 바이오매스 필름의 생분해성 및 물성이 최적화될 수 있다.The content of alginate according to the present invention may be 27 to 43% by weight, preferably 35 to 43% by weight, more preferably 40 to 42% by weight, based on the total weight of the composition for forming a marine-derived biomass film. It can be. When the alginate content is within the above numerical range, the biodegradability and physical properties of the marine-derived biomass film can be optimized.

본 발명에 따른 해양유래 바이오매스 필름 형성용 조성물은, 조성물의 점도를 낮추고 외력에 의한 필름의 변형을 줄이는 가소제를 포함할 수 있다. 상기 가소제는 알코올류 화합물을 포함할 수 있다. 상기 알코올류 화합물은 예를 들어, 글리세린, 자일리톨, 만니톨, 솔비톨 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나일 수 있다. The composition for forming a marine-derived biomass film according to the present invention may contain a plasticizer that lowers the viscosity of the composition and reduces deformation of the film due to external force. The plasticizer may include an alcohol-type compound. For example, the alcohol compound may be any one selected from the group consisting of glycerin, xylitol, mannitol, sorbitol, and combinations thereof.

상기 해양유래 바이오매스 필름 형성용 조성물은, 알긴산염 100 중량부 및 가소제 60 내지 200 중량부를 포함할 수 있다. 상기 가소제의 함량은 상기 알긴산염 100 중량부를 기준으로 바람직하게는 60 내지 100 중량부, 더욱 바람직하게는 60 내지 80 중량부일 수 있다. 상기 가소제의 함량이 상기 수치 범위 내를 만족해야 해양유래 바이오매스 필름의 높은 강성과 인장강도가 구현될 수 있다. The composition for forming a marine-derived biomass film may include 100 parts by weight of alginate and 60 to 200 parts by weight of a plasticizer. The content of the plasticizer may be preferably 60 to 100 parts by weight, more preferably 60 to 80 parts by weight, based on 100 parts by weight of the alginate. Only when the content of the plasticizer satisfies the above numerical range can the high rigidity and tensile strength of the marine-derived biomass film be realized.

본 발명의 다른 실시예에 따른 해양유래 바이오매스 필름 형성용 조성물은 상기 알긴산염 100 중량부를 기준으로 오일계 첨가제 40 내지 110 중량부를 더 포함할 수 있다. 상기 오일계 첨가제는 필름의 강성을 조절하기 위한 것일 수 있다. 상기 오일계 첨가제는, 올레산, 리놀레산(linoleic acid), 리놀렌산(linolenic acid), 스테아르산, 팔미트산, 미리스트산, 라우르산 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나를 포함할 수 있다. 예를 들어, 상기 오일계 첨가제는 해바라기씨유일 수 있다. 상기 오일계 첨가제의 함량은 바람직하게 상기 알긴산염 100 중량부를 기준으로 40 내지 90 중량부, 더욱 바람직하게는 40 내지 80 중량부일 수 있다. 상기 오일계 첨가제의 함량이 상기 수치 범위 내를 만족해야 해양유래 바이오매스 필름의 높은 강성을 구현할 수 있다. The composition for forming a marine-derived biomass film according to another embodiment of the present invention may further include 40 to 110 parts by weight of an oil-based additive based on 100 parts by weight of the alginate. The oil-based additive may be used to control the rigidity of the film. The oil-based additive may include any one selected from the group consisting of oleic acid, linoleic acid, linolenic acid, stearic acid, palmitic acid, myristic acid, lauric acid, and combinations thereof. . For example, the oil-based additive may be sunflower seed oil. The content of the oil-based additive may preferably be 40 to 90 parts by weight, more preferably 40 to 80 parts by weight, based on 100 parts by weight of the alginate. Only when the content of the oil-based additive satisfies the above numerical range can high rigidity of the marine-derived biomass film be realized.

본 발명의 또 다른 실시예에 따른 해양유래 바이오매스 필름 형성용 조성물은 상기 알긴산염 100 중량부를 기준으로 충전제 1 내지 20 중량부를 더 포함할 수 있다. 상기 충전제는 해양유래 바이오매스 필름의 강도 및 강성을 높이기 위해 첨가될 수 있다. 상기 충전제는 단백질계 첨가제, 폴리사카라이드계 첨가제 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나일 수 있고, 바람직하게는 단백질계 첨가제 및 폴리사카라이드계 첨가제의 혼합물일 수 있다. 이와 같이 충전제 2종을 사용할 경우 필름의 강도와 강성을 더욱 높일 수 있다. 단백질계 첨가제 및 폴리사카라이드계 첨가제 2종을 사용하는 본 발명의 일 실시예에 따르면, 상기 폴리사카라이드계 첨가제와 상기 단백질계 첨가제의 중량비(폴리사카라이드계 첨가제: 단백질계 첨가제)는 1:1 내지 1:9일 수 있고, 바람직하게는 1:2 내지 1:7일 수 있고, 더욱 바람직하게는 1:2 내지 1:3일 수 있다. 상기 폴리사카라이드계 첨가제와 상기 단백질계 첨가제의 중량비가 상기 수치 범위 내일 때, 해양유래 바이오매스 필름의 높은 강성, 인장강도 및 파단신율이 구현될 수 있다. A composition for forming a marine-derived biomass film according to another embodiment of the present invention may further include 1 to 20 parts by weight of filler based on 100 parts by weight of the alginate. The filler can be added to increase the strength and rigidity of the marine-derived biomass film. The filler may be any one selected from the group consisting of protein-based additives, polysaccharide-based additives, and combinations thereof, and preferably may be a mixture of protein-based additives and polysaccharide-based additives. In this way, when two types of fillers are used, the strength and rigidity of the film can be further increased. According to an embodiment of the present invention using two types of protein-based additives and polysaccharide-based additives, the weight ratio of the polysaccharide-based additive to the protein-based additive (polysaccharide-based additive: protein-based additive) is 1: It may be 1 to 1:9, preferably 1:2 to 1:7, and more preferably 1:2 to 1:3. When the weight ratio of the polysaccharide-based additive and the protein-based additive is within the above numerical range, high rigidity, tensile strength, and elongation at break of the marine-derived biomass film can be realized.

상기 단백질계 첨가제는 예를 들어, 유청 단백질, 젤라틴, 대두 단백질, 케라틴 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나일 수 있다. 상기 단백질계 첨가제의 분자량은 예를 들어, 15 내지 75kDa일 수 있다.The protein-based additive may be, for example, any one selected from the group consisting of whey protein, gelatin, soy protein, keratin, and combinations thereof. The molecular weight of the protein-based additive may be, for example, 15 to 75 kDa.

상기 폴리사카라이드계 첨가제는, α-셀룰로오스, β-셀룰로오스, 나노 셀룰로오스, 녹말 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나를 포함할 수 있다. 상기 폴리사카라이드계 첨가제의 분자량은 예를 들어, 15 내지 75kDa일 수 있다. 상기 폴리사카라이드계 첨가제는 녹말을 다량으로 함유하는 전분일 수 있다. 상기 전분은 예를 들어, 통상의 옥수수 전분, 감자 전분, 카사바 전분 등일 수 있다. The polysaccharide-based additive may include any one selected from the group consisting of α-cellulose, β-cellulose, nanocellulose, starch, and combinations thereof. The molecular weight of the polysaccharide-based additive may be, for example, 15 to 75 kDa. The polysaccharide-based additive may be starch containing a large amount of starch. The starch may be, for example, common corn starch, potato starch, cassava starch, etc.

상기 충전제의 함량은 바람직하게 상기 알긴산염 100 중량부를 기준으로 2 내지 10 중량부, 더욱 바람직하게는 2 내지 5 중량부일 수 있다. 상기 충전제의 함량이 상기 수치 범위 내를 만족해야 해양유래 바이오매스 필름의 강도와 강성이 개선될 수 있다.The content of the filler may be preferably 2 to 10 parts by weight, more preferably 2 to 5 parts by weight, based on 100 parts by weight of the alginate. Only when the content of the filler satisfies the above numerical range can the strength and rigidity of the marine-derived biomass film be improved.

본 발명의 또 다른 실시예에 따른 해양유래 바이오매스 필름 형성용 조성물은 상기 알긴산염 100 중량부를 기준으로 수분 차단 첨가제 1 내지 5 중량부를 더 포함할 수 있다. 상기 수분 차단 첨가제는 수분에 대한 차단성을 부여하기 위해 필요에 따라 첨가될 수 있다. 상기 수분 차단 첨가제의 함량은 적절히 조절될 수 있다. 상기 수분 차단 첨가제는 예를 들어, 입자크기가 1 내지 10 ㎛(마이크로미터)인 운모(mica)일 수 있다.The composition for forming a marine-derived biomass film according to another embodiment of the present invention may further include 1 to 5 parts by weight of a moisture barrier additive based on 100 parts by weight of the alginate. The moisture barrier additive may be added as needed to provide barrier properties against moisture. The content of the moisture barrier additive can be adjusted appropriately. For example, the moisture barrier additive may be mica with a particle size of 1 to 10 μm (micrometer).

도 2에 도시된 바와 같이, 본 발명에 따른 필름 형성부(FH)는 상기 제1 필름의 두께를 조절하는 제1 조절부(12), 상기 제1 필름의 폭을 조절하고, 해양유래 바이오매스 필름 형성용 조성물(L)의 외부 누수를 막는 제2 조절부 및 상기 제1 조절부(12)와 대향되는 댐(14)을 포함할 수 있다. 상기 제1 조절부(12)는 예를 들어, 닥터 블레이드(doctor blade)일 수 있고, 상기 제2 조절부는 예를 들어 사이드 가드일 수 있다. 상기 제1 조절부 및 제2 조절부로 인해 필름의 폭과 두께는 정교하게 조절될 수 있다. 상기 댐(14)은 일정량의 시료를 보관할 수 있는 부피를 가지는 구조물로, 안정적으로 필름을 형성할 수 있도록 일정 부피의 시료의 정량 투입을 유지함과 동시에 사출을 돕는 구조물 역할을 한다. As shown in Figure 2, the film forming part (FH) according to the present invention includes a first adjusting part 12 that adjusts the thickness of the first film, adjusts the width of the first film, and marine-derived biomass. It may include a second control unit that prevents external leakage of the film forming composition (L) and a dam 14 opposite the first control unit 12. The first adjusting part 12 may be, for example, a doctor blade, and the second adjusting part may be, for example, a side guard. Due to the first control unit and the second control unit, the width and thickness of the film can be precisely adjusted. The dam 14 is a structure that has a volume capable of storing a certain amount of sample, and serves as a structure that assists injection while maintaining a constant input of a certain volume of sample to stably form a film.

한편, 본 발명의 또 다른 실시예에 따르면, 상기 필름 형성부(FH)는 상술한 닥터 블레이드를 사용하는 방식 외에도, 수개의 롤(roll)로 구성된 콤마 코터를 사용하여 일정 두께로 제1 필름을 캐스팅하는 방식을 채용할 수 있다 (미도시).Meanwhile, according to another embodiment of the present invention, in addition to using the doctor blade described above, the film forming unit (FH) uses a comma coater composed of several rolls to form the first film to a certain thickness. A casting method can be adopted (not shown).

구체적으로, 본 발명에 따른 필름 제조장치(100)는 상기 필름 형성부(FH)에 필름 형성 조성물을 공급하는 제1 롤 및 상기 필름 형성부(FH)에 기재를 공급하는 제2 롤을 포함할 수 있다. 상기 제1 롤 및 제2 롤은 내마모성, 내산화성을 고려하여 예를 들어, 텅스텐 카비이드(WC)를 포함할 수 있다. Specifically, the film manufacturing apparatus 100 according to the present invention may include a first roll for supplying a film forming composition to the film forming unit (FH) and a second roll for supplying a substrate to the film forming unit (FH). You can. The first roll and the second roll may include, for example, tungsten carbide (WC) in consideration of wear resistance and oxidation resistance.

본 발명에 따른 해양유래 바이오매스 필름의 제조방법은, (S4) 상기 두께조절부(20)에서 상기 제2 필름의 두께를 조절하는 단계를 더 포함할 수 있다. 구체적으로, 상기 두께조절부(20)는 상기 제2 필름의 표면에 압력을 가하는 캘린더링 롤(gap roll)을 포함할 수 있고 상기 두께가 조절된 제2 필름의 두께는 0.01 내지 1.00cm일 수 있다. 캘린더링 롤을 이용하여 2개의 롤 사이로 지나가는 적층체의 양 표면에 압력을 가할 수 있다. 상기 적층체는 제1 이송펠트 및 제2 이송펠트, 상기 제1 이송펠트 및 상기 제2 이송펠트 사이에 개재되는 제2 필름으로 구성될 수 있다. 상기 적층체의 양 표면에 압력을 가함으로써, 제2 필름의 두께를 목적에 따라 정교하게 조절할 수 있다. The method of manufacturing a marine-derived biomass film according to the present invention may further include (S4) adjusting the thickness of the second film in the thickness adjustment unit 20. Specifically, the thickness adjusting unit 20 may include a calendering roll (gap roll) that applies pressure to the surface of the second film, and the thickness of the second film whose thickness is adjusted may be 0.01 to 1.00 cm. there is. Calendering rolls can be used to apply pressure to both surfaces of the laminate passing between two rolls. The laminate may be composed of a first transfer felt, a second transfer felt, and a second film interposed between the first transfer felt and the second transfer felt. By applying pressure to both surfaces of the laminate, the thickness of the second film can be precisely adjusted according to the purpose.

즉, 상기 제2 필름은 상기 제1 이송펠트 및 상기 제1 이송펠트와 상이한 제2 이송펠트 사이에 개재될 수 있다. 상기 제1 및 제2 이송펠트의 이동속도는 각각 독립적으로 10 cm/min 내지 500m/min일 수 있고, 구체적으로 10m/min 내지 200m/min일 수 있고, 더욱 구체적으로 50m/min 내지 150m/min일 수 있다. 예를 들어, 상기 제1 및 제2 이송펠트의 이동속도는 서로 동일한 것이 공정 상 바람직할 수 있다. That is, the second film may be interposed between the first transfer felt and a second transfer felt that is different from the first transfer felt. The moving speed of the first and second transfer felts may each independently be 10 cm/min to 500 m/min, specifically 10 m/min to 200 m/min, and more specifically 50 m/min to 150 m/min. It can be. For example, it may be desirable in the process that the moving speeds of the first and second transfer felts are the same.

본 발명의 또 다른 실시예에 따르면, 상기 제1 및 제2 이송펠트는 각각 독립적으로 150 내지 250 mesh의 공극을 포함할 수 있다. 구체적으로, 상기 제1 및 제2 이송펠트가 상기 크기 범위의 공극을 포함함으로써, 필름에 함유된 용매가 효과적으로 기화될 수 있다.According to another embodiment of the present invention, the first and second transfer felts may each independently include pores of 150 to 250 mesh. Specifically, because the first and second transfer felts include pores in the above size range, the solvent contained in the film can be effectively vaporized.

본 발명에 따른 해양유래 바이오매스 필름의 제조방법은, (S5) 상기 건조부(DR)에서 상기 두께가 조절된 제2 필름을 건조하는 단계를 더 포함할 수 있다. 구체적으로, 상기 (S5) 단계는, 적외선 건조방법, 열풍 건조방법 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나를 이용하는 단계일 수 있고, 바람직하게는 이들의 조합을 이용하는 단계일 수 있다. The method for producing a marine-derived biomass film according to the present invention may further include (S5) drying the second film whose thickness is adjusted in the drying unit (DR). Specifically, the step (S5) may be a step using any one selected from the group consisting of an infrared drying method, a hot air drying method, and a combination thereof, and preferably a step using a combination thereof.

적외선 건조방법과 열풍 건조방법을 동시에 사용함으로써 제2 필름에 잔류하는 용매를 효과적으로 제거할 수 있고 결과적으로 해양유래 바이오매스 필름의 두께를 정교하게 조절할 수 있다. By using the infrared drying method and the hot air drying method simultaneously, the solvent remaining in the second film can be effectively removed, and as a result, the thickness of the marine-derived biomass film can be precisely controlled.

본 발명에 따른 건조부(DR)는 내부에 상기 제2 필름이 통과하는 터널(TN) 을 포함할 수 있다. 상기 터널(TN)은 예를 들어, 내부에 상기 적층체가 통과하는 공간을 정의하는 프로파일일 수 있다. 상기 터널(TN)의 내부온도는 예를 들어 60 내지 200℃로 조절될 수 있다. 필요에 따라 상기 건조부(DR)는 열풍이 리플럭스(reflux)할 수 있도록 도와주는 배관을 추가로 포함할 수 있다.The drying unit (DR) according to the present invention may include a tunnel (TN) through which the second film passes. For example, the tunnel TN may be a profile that defines a space through which the laminate passes. The internal temperature of the tunnel TN may be adjusted to, for example, 60 to 200°C. If necessary, the drying unit DR may additionally include piping to help hot air reflux.

상기 적층체는 롤(R)로 인하여 터널(TN)을 통과할 수 있다.The laminate can pass through the tunnel (TN) due to the roll (R).

본 발명에 따른 건조유닛(DN)은 상기 터널(TN)의 내주면의 윗면과 아랫면에 일정 간격으로 배치될 수 있다. 구체적으로, 상기 건조유닛(DN)이 터널(TN)의 내주면에 배치됨으로써 제2 필름을 효과적으로 건조시킬 수 있다. The drying unit (DN) according to the present invention may be disposed at regular intervals on the upper and lower surfaces of the inner peripheral surface of the tunnel (TN). Specifically, the drying unit DN can effectively dry the second film by being disposed on the inner peripheral surface of the tunnel TN.

본 발명에 따른 해양유래 바이오매스 필름의 제조방법은 (S6) 상기 건조부(DR)와 연결된 리와인딩부(RW)에서 상기 건조된 제2 필름을 리와인드(rewind)하는 단계를 더 포함할 수 있다. 구체적으로, 상기 리와인딩부(RW)는, 상기 건조된 제2 필름이 권취되는 롤의 전단에 부착된 프로파일 제어부(profile controller)를 포함할 수 있다. 상기 프로파일 제어부는 리와인드가 용이하게 이루어지게 할 수 있다.The method for producing a marine-derived biomass film according to the present invention may further include (S6) the step of rewinding the dried second film in a rewinding unit (RW) connected to the drying unit (DR). . Specifically, the rewinding unit (RW) may include a profile controller attached to the front end of the roll on which the dried second film is wound. The profile control unit can facilitate rewinding.

도 1에 도시된 바와 같이, 본 발명에 따른 제1 이송펠트(F1)는 제1 에어샤프트(AS1)에 롤 형태로 권취될 수 있고 제2 이송펠트(F2)는 제2 에어샤프트(AS2)에 롤 형태로 권취될 수 있고, 제2 필름은 제3 에어샤프트(AS3)에 롤 형태로 권취될 수 있다. 예를 들어, 상기 제1 내지 제3 에어샤프트(AS1, AS2, AS3)는 원통형일 수 있고 이로 인해 이송 펠트와 필름이 롤 형태로 쉽게 권취될 수 있다.As shown in FIG. 1, the first transfer felt (F1) according to the present invention can be wound in a roll form on the first air shaft (AS1), and the second transfer felt (F2) is wrapped around the second air shaft (AS2). It can be wound in a roll shape, and the second film can be wound in a roll shape on the third air shaft (AS3). For example, the first to third air shafts (AS1, AS2, AS3) may be cylindrical, which allows the transfer felt and film to be easily wound into a roll shape.

한편, 본 발명의 리와인딩부(RW)는 건조된 제2 필름과 제1 이송펠트(F1), 제2 이송펠트(F2)를 분리한 뒤, 새로운 필름 생성을 위해 제1 이송펠트(F1)과 제2 이송펠트(F2)를 전단부로 다시 순환시키는 구조를 가질 수 있다 (미도시). 이와 같이, 제1 이송펠트(F1)과 제2 이송펠트(F2)를 전단부로 순환시키는 구조를 가짐으로써, 연속 공정이 가능하게 하여 해양유래 바이오매스 필름의 생산성을 높일 수 있다.Meanwhile, the rewinding unit (RW) of the present invention separates the dried second film, the first transfer felt (F1), and the second transfer felt (F2), and then separates the first transfer felt (F1) from the dried second film to create a new film. It may have a structure that circulates the second transfer felt (F2) back to the front end (not shown). In this way, by having a structure in which the first transfer felt (F1) and the second transfer felt (F2) are circulated to the front end, a continuous process is possible and the productivity of the marine-derived biomass film can be increased.

도 3은 본 발명의 다른 실시예에 따른 해양유래 바이오매스 필름의 제조방법을 나타낸 플로우 차트이다.Figure 3 is a flow chart showing a method of manufacturing a marine-derived biomass film according to another embodiment of the present invention.

도 3을 참고하면, 본 발명의 일 실시예에 따른 해양유래 바이오매스 필름의 제조방법은 (a) 필름 형성부에 들어가는 제1 이송펠트에 제1 경화제를 스프레이 방법으로 도포하는 단계; (b) 제1 경화제가 도포된 제1 이송펠트 상에 해양유래 바이오매스 필름 형성용 조성물을 도포하여 제1 필름을 형성하는 단계; (c) 제1 필름 상에 제2 경화제를 스프레이 방법으로 도포하여 제2 필름을 형성하는 단계; (d) 캘린더링 롤로 제2 필름의 두께를 조절하는 단계; (e) 두께가 조절된 제2 필름을 적외선 및 열풍 터널을 통과시키면서 건조하는 단계; 및 (f) 건조된 제2 필름을 리와인드하는 단계를 포함할 수 있다. Referring to Figure 3, the method for manufacturing a marine-derived biomass film according to an embodiment of the present invention includes the steps of (a) applying a first curing agent to a first transfer felt entering the film forming unit by spraying; (b) forming a first film by applying a composition for forming a marine-derived biomass film on a first transfer felt coated with a first curing agent; (c) forming a second film by applying a second curing agent on the first film by spraying; (d) adjusting the thickness of the second film with a calendering roll; (e) drying the second film whose thickness is adjusted while passing it through an infrared and hot air tunnel; and (f) rewinding the dried second film.

본 발명의 또 다른 일 실시예에 따르면, 본 발명은 상기 필름 형성부(FH), 상기 필름 형성부(FH)와 연결된 두께조절부(20) 및 상기 두께조절부(20)와 연결된 건조부(DR)를 포함하는 필름 제조장치를 이용하는 친환경 필름의 제조방법으로,According to another embodiment of the present invention, the present invention provides the film forming portion (FH), a thickness adjusting portion 20 connected to the film forming portion (FH), and a drying portion connected to the thickness adjusting portion 20 ( A method of manufacturing an eco-friendly film using a film manufacturing device including DR),

(Sa) 제1 순환펠트 상에, 해양유래 바이오매스 필름 형성용 조성물을 도포하여 제3 필름을 형성하는 단계; 및(Sa) forming a third film by applying a composition for forming a marine-derived biomass film on the first recycled felt; and

(Sb) 상기 제3 필름을 상기 제1 경화제로 침지시켜 제4 필름을 형성하는 단계를 포함하고,(Sb) immersing the third film in the first curing agent to form a fourth film,

상기 필름 형성부는, 그 내부에 상기 해양유래 바이오매스 필름 형성용 조성물을 포함하는 해양유래 바이오매스 필름의 제조방법을 제공할 수 있다.The film forming unit may provide a method of manufacturing a marine-derived biomass film containing the composition for forming the marine-derived biomass film therein.

여기서, 상기 제1 순환펠트는 무한궤도 형태로 순환할 수 있다.Here, the first circulating felt may circulate in an endless orbit.

상기 제4 필름을 형성하는 단계는 상기 제1 경화제를 포함하는 저수조 형태의 댐(14)에서 이루어질 수 있다.The step of forming the fourth film may be performed in a dam 14 in the form of a water reservoir containing the first curing agent.

그 외의 친환경 필름의 제조 방법에 대한 설명은 상기에서 설명한 바와 같다.Other descriptions of the manufacturing method of the eco-friendly film are the same as described above.

이상에서 본 발명의 바람직한 실시예들에 대하여 상세하게 설명하였지만 본 발명의 권리 범위는 이에 한정되는 것은 아니고 다음의 청구범위에서 정의하고 있는 본 발명의 기본 개념을 이용한 당업자의 여러 변형 및 개량 형태 또한 본 발명의 권리 범위에 속하는 것이다. Although the preferred embodiments of the present invention have been described in detail above, the scope of the present invention is not limited thereto, and various modifications and improvements can be made by those skilled in the art using the basic concept of the present invention defined in the following claims. It falls within the scope of invention rights.

Claims (10)

필름 형성부, 상기 필름 형성부와 연결된 두께조절부 및 상기 두께조절부와 연결된 건조부를 포함하는 필름 제조장치를 이용하는 해양유래 바이오매스 필름의 제조방법으로,A method for producing a marine-derived biomass film using a film manufacturing device including a film forming unit, a thickness adjusting unit connected to the film forming unit, and a drying unit connected to the thickness adjusting unit, (S1) 상기 필름 형성부에 들어가는 제1 이송펠트에 제1 경화제를 도포하는 단계; (S1) applying a first curing agent to the first transfer felt entering the film forming unit; (S2) 상기 제1 경화제가 도포된 제1 이송펠트 상에, 해양유래 바이오매스 필름 형성용 조성물을 도포하여 제1 필름을 형성하는 단계; 및 (S2) forming a first film by applying a composition for forming a marine-derived biomass film on the first transfer felt to which the first curing agent is applied; and (S3) 상기 제1 필름 상에, 상기 제1 경화제와 동일하거나 상이한 제2 경화제를 도포하여 제2 필름을 형성하는 단계; 를 포함하고,(S3) forming a second film by applying a second curing agent that is the same as or different from the first curing agent on the first film; Including, 상기 필름 형성부는,The film forming unit, 그 내부에 상기 해양유래 바이오매스 필름 형성용 조성물을 포함하는Containing the composition for forming the marine-derived biomass film therein 해양유래 바이오매스 필름의 제조방법.Manufacturing method of marine-derived biomass film. 제1항에 있어서,According to paragraph 1, 상기 필름 형성부는,The film forming unit, 상기 제1 필름의 두께를 조절하는 제1 조절부;a first control unit that adjusts the thickness of the first film; 상기 제1 필름의 폭을 조절하는 제2 조절부; 및a second control unit that adjusts the width of the first film; and 상기 제1 조절부와 대향되는 댐을 포함하는Comprising a dam opposite the first control unit 해양유래 바이오매스 필름의 제조방법. Manufacturing method of marine-derived biomass film. 제1항에 있어서,According to paragraph 1, 상기 제1 및 제2 경화제를 도포하는 방법은 스프레이 방법인, The method of applying the first and second curing agents is a spray method, 해양유래 바이오매스 필름의 제조방법. Manufacturing method of marine-derived biomass film. 제1항에 있어서,According to paragraph 1, (S4) 상기 두께조절부에서 상기 제2 필름의 두께를 조절하는 단계; 를 더 포함하고,(S4) adjusting the thickness of the second film in the thickness adjustment unit; It further includes, 상기 두께조절부는, The thickness control part, 상기 제2 필름의 표면에 압력을 가하는 캘린더링 롤을 포함하고,It includes a calendering roll that applies pressure to the surface of the second film, 상기 두께가 조절된 제2 필름의 두께는,The thickness of the second film whose thickness is adjusted is, 0.01 내지 1.00cm인0.01 to 1.00 cm 해양유래 바이오매스 필름의 제조방법.Manufacturing method of marine-derived biomass film. 제4항에 있어서,According to paragraph 4, 상기 제2 필름은, The second film is, 상기 제1 이송펠트 및 상기 제1 이송펠트와 상이한 제2 이송펠트 사이에 개재되는Interposed between the first transfer felt and a second transfer felt different from the first transfer felt 해양유래 바이오매스 필름의 제조방법.Manufacturing method of marine-derived biomass film. 제5항에 있어서,According to clause 5, 상기 제1 및 제2 이송펠트의 이동속도는, The moving speed of the first and second transfer felts is, 각각 독립적으로 10 cm/min 내지 1,000cm/min인Each independently 10 cm/min to 1,000 cm/min 해양유래 바이오매스 필름의 제조방법.Manufacturing method of marine-derived biomass film. 제4항에 있어서,According to paragraph 4, (S5) 상기 건조부에서 상기 두께가 조절된 제2 필름을 건조하는 단계; 를 더 포함하는(S5) drying the second film whose thickness is adjusted in the drying unit; containing more 해양유래 바이오매스 필름의 제조방법.Manufacturing method of marine-derived biomass film. 제7항에 있어서,In clause 7, 상기 (S5) 단계는,In the step (S5), 적외선 건조방법, 열풍 건조방법 및 이들의 조합으로 이루어진 군에서 선택된 어느 하나를 이용하는 단계인,A step of using any one selected from the group consisting of an infrared drying method, a hot air drying method, and a combination thereof, 해양유래 바이오매스 필름의 제조방법.Manufacturing method of marine-derived biomass film. 제7항에 있어서,In clause 7, 상기 건조부는,The drying part, 내부에 상기 제2 필름이 통과하는 터널을 포함하는 Comprising a tunnel through which the second film passes inside 해양유래 바이오매스 필름의 제조방법.Manufacturing method of marine-derived biomass film. 제7항에 있어서,In clause 7, (S6) 상기 건조부와 연결된 리와인딩부에서 상기 건조된 제2 필름을 리와인드(rewind)하는 단계; 를 더 포함하고,(S6) rewinding the dried second film in a rewinding unit connected to the drying unit; It further includes, 상기 리와인딩부는,The rewinding unit, 상기 건조된 제2 필름이 권취되는 롤의 전단에 부착된 프로파일 제어부(profile controller)를 포함하는Comprising a profile controller attached to the front end of the roll on which the dried second film is wound. 해양유래 바이오매스 필름의 제조방법. Manufacturing method of marine-derived biomass film.
PCT/KR2022/012417 2022-04-05 2022-08-19 Method for manufacturing marine-derived biomass film Ceased WO2023195584A1 (en)

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JP2003175522A (en) * 2001-12-11 2003-06-24 Fuji Photo Film Co Ltd Method for producing cellulose acetate film and cellulose acetate film, polarizing plate
KR100500304B1 (en) * 2003-07-01 2005-07-11 주식회사 엘지에스 Apparatus of manufacturing optical film and method thereof
JP2015205268A (en) * 2010-01-29 2015-11-19 スリーエム イノベイティブ プロパティズ カンパニー Continuous process for forming multilayer film and multilayer film prepared by same process
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