WO2023158294A1 - Aluminium recycling process - Google Patents
Aluminium recycling process Download PDFInfo
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- WO2023158294A1 WO2023158294A1 PCT/MX2022/050008 MX2022050008W WO2023158294A1 WO 2023158294 A1 WO2023158294 A1 WO 2023158294A1 MX 2022050008 W MX2022050008 W MX 2022050008W WO 2023158294 A1 WO2023158294 A1 WO 2023158294A1
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- aluminum
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/04—Working-up slag
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the present invention is related to processes for recycling aluminum, and more particularly with a highly efficient process for recycling aluminum that has the capacity to recover a high percentage of aluminum present in the raw material that has a great diversity of materials of waste (scrap), with a minimum possible energy consumption and with very low carbon emissions, being friendly to the environment (sustainable).
- the aluminum recycling industry is mainly based on two main processes:
- the quality of the finished product that is obtained is not very good since many of the impurities present in the scrap that are not aluminum are incorporated into the aluminum alloy, so these alloys are used to produce products with low quality requirements.
- the applicant developed a process for aluminum recycling starting from aluminum scrap which is capable of recovering the maximum percentage of aluminum possible (up to 96% aluminum in the raw material), with a minimum possible energy consumption and with very low carbon emissions, being friendly to the environment (sustainable).
- the process for recycling aluminum of the present invention comprises the general steps of: submitting said waste material to a grinding and recovery process for aluminum scrap that can separate a high percentage of waste material from aluminum; subjecting the recovered aluminum to a delacquering and/or preheating process, where the generated (pyrolytic) gases are used as fuel; later they are fed to a fusion process with a Vortex system and finally to a continuous casting process.
- Some of the benefits of the aluminum recycling process of the present invention include:
- Each raw material has different characteristics that are associated with thickness, content of paints, fats or organic materials.
- Raw materials are divided into two groups, thick materials with thicknesses greater than 2 mm (numbers 1, 2, 8 and 9 of the table) and thin materials with thicknesses less than 2 mm (numbers 3, 4, 5, 6, and 7 of the table).
- the process can process feedstock comprising scrap or waste material with any amount of aluminum content.
- the first stage of the process for recycling aluminum of the present invention comprises the stage of grinding and removal of impurities, which is divided into the following substages:
- Secondary grinding in the secondary grinding substage, the pieces obtained in the primary grinding with sizes between 100mm and 300mm are fragmented into fragments smaller than 100mm in a grinding apparatus equipped with cutting blades with scissor effect known in the art, adjusted to produce fragments smaller than 100mm or by any other suitable grinding equipment or method.
- the thick materials and the thin materials are processed in the present stage a) separately or in different processing lines, in such a way that they enter stage b) to be processed separately or in different processing lines.
- the product of the grinding and removal of impurities stage comprises fragmented aluminum scrap in a uniform size in a range between 10mm to 100mm, up to 99% free of impurities such as iron, lead, copper, zinc, wood, plastic, paper etc
- the shredded aluminum scrap is transferred to the next stage of the process by any known means, such as conveyor belts, ideally continuously or until the next stage can process it.
- the size of raw material that enters substage I depends on the capacity of the grinding apparatus used (that is, it can have any size), as long as said grinding apparatus used in substage I can produce pieces between 100mm at 300mm. b) Deslacquering stage
- Much of the aluminum scrap contains 3% to 4% organic waste (paint, lacquer, etc.) such as beverage containers, construction profiles or sheets used for transport, so the aluminum scrap obtained in The stage of grinding and removal of impurities is subjected to a removal process called stripping, which consists of heating the fragmented aluminum scrap (subjecting it to a thermal process) in an oven until these materials are detached.
- organics in the form of gases typically at a temperature between 400 s C to 550 s C.
- the delacquering process is carried out using a system called IDEX® which is designed to subject aluminum scrap to a thermal process to eliminate volatile organic (paint, lacquer, oils) and inorganic (water) contaminants from a wide range of aluminum scrap through a continuous thermal process.
- IDEX® a system called IDEX® which is designed to subject aluminum scrap to a thermal process to eliminate volatile organic (paint, lacquer, oils) and inorganic (water) contaminants from a wide range of aluminum scrap through a continuous thermal process.
- step a) the thick materials and the thin materials that come out separately from step a) are also processed separately in the present step b) and can be processed in two separate processing lines.
- the temperature is adjusted between 500°C and 550°C at 30 rpm in the rotating kiln for the group of thick raw materials and for the group of thin raw materials the temperature it is set between 400°C and 500°C at 20 rpm on the rotating kiln.
- the material leaves the thermal process at a temperature between 400 s C to 550 s C. The reason for this is that the thickness of the raw material does not change after the primary and secondary grinding sub-stages.
- stripping can be carried out in any other oven or suitable stripping equipment that has a heating zone where the thermal process can be carried out at temperatures suitable for any type of raw material.
- the product of the stripping stage comprises aluminum scrap without any organic residue content (0%) which is transferred to the next stage of the process by any known means such as conveyor belts, ideally continuously or until the next stage stage is ready to process the aluminum scrap.
- c) Fusion stage The aluminum scrap obtained in the stripping stage is subjected to a continuous melting process in the absence of air. The melting process is carried out in a melting furnace that has a Vortex-type system that forms a whirlpool of molten aluminum (vortex well) at a temperature between 700°C and 750°C, where the aluminum scrap is immersed in the aluminum bath so that it melts, avoiding contact with the air, minimizing the oxidation of the metal.
- the Vortex-type melting furnace has a capacity of 125 tons and is maintained at a temperature between 720 s C and 750 s C.
- aluminum by-products are generated, which are mostly oxides in the surface of the liquid aluminum, said by-product is removed from the furnace for surface cleaning.
- the molten material in a liquid state is transferred by means of a graphite pump to the next stage of the process of the present invention by any known means, for example, by means of channels with flow control, maintaining a continuous flow of material, until the tank is filled. next stage holding furnace; d) Stage of adjustment of composition and refining.
- the molten aluminum produced in the melting stage is transferred, for example, by means of channels with flow control, maintaining a continuous flow of material to one or more aluminum holding furnaces where the aluminum is maintained at a temperature between 700 s C to 760s C.
- the process of adjusting the chemical composition is carried out according to any specification required by an end customer, which is achieved by adding addition elements to the molten aluminum. Additionally, aluminum refining is carried out.
- composition and refinement adjustment is done as follows:
- One or more samples of aluminum are taken from the one or more holding furnaces using any suitable means, such as by means of a spoon;
- Said one or more samples are analyzed for metal content using any known method to specifically determine which are the metals present in the one or more samples and the amount of addition elements to be added, which are selected from the group that includes, but is not limited to: silicon, copper, magnesium, manganese, zinc, titanium. Obviously during an initial taking of one or more samples, the aluminum content will be predominant:
- metal refining and cleaning processes are also carried out, removing any by-product present on the surface of the liquid aluminum and removing it from the furnace through the door.
- the product of the composition adjustment step comprises refined liquid molten aluminum with its chemical composition adjusted according to specifications predefined by a customer.
- Molten aluminum in a liquid state is transferred to the next filtering stage by tilting the furnace (tilting it) or by any known means, such as flow-controlled channels.
- Filter stage e) Filter stage
- the molten aluminum that comes out of the composition adjustment and refining stage is led to a filter box where filtering is carried out by means of a ceramic filter with between 20 to 50 PPI (pores per square inch), where said filtering retains either inclusion, intermetallic particles, or any additional material that was present in the molten aluminum.
- a ceramic filter with between 20 to 50 PPI (pores per square inch)
- the filtered aluminum exiting the lauter box is led to the next stage of continuous casting by any known means, such as flow-controlled channels, ideally continuously or until the next stage is ready to process the molten aluminum. . f) Continuous casting stage
- the filtered aluminum that leaves the previous stage is led and deposited continuously by any known method or means (for example, through channels with flow control), in a continuous ingot casting machine, which forms aluminum ingots of regular shape, preferably with a flat upper and lower surface, and cools them by means of pressurized water jets. Any known or available casting method or machine can be used.
- the liquid metal is solidified using pressurized water.
- a bar is formed, which passes to a section where it is identified and cut with a guillotine-type system to obtain an ingot of approximately 10 kg each, once the ingots are cut at a temperature between 350°C and 450°C is transported to a cooling tunnel where the ingots are cooled to 60°C
- the product of the continuous casting stage comprises refined aluminum ingots, with tight composition, free of oxides, of a regular size and shape that makes them easy to stow, ready for shipment.
- the apparatus used in the substages of I. primary grinding and II. Secondary milling have dust collection systems with thirteen commercially available collection points to avoid dust emissions into the atmosphere.
- said dust collection equipment comprises: a Pule Jef Type filter bag collector. ; the collector will have a configuration of 3 to 4 hoppers, with an air lock rotary valve for the discharge of material in each hopper; there are 2 cyclones for the separation of garbage and larger materials (that are not powders), this system has a nominal capacity of 870 bags, it has a direct coupling extractor, arrangement 8 with type C anti-spark construction, which is installed on the clean side of a manifold with BAU discharge, to connect a self-supported chimney on the floor.
- any other commercially available dust collection method or system may be used.
- stage b) delacquering it is very important that the process used (IDEX®) does not enter oxygen to avoid combustion inside the equipment where the process is carried out.
- gases are obtained that are released from the organics present in the raw material which, in a preferred modality of the process of the present invention, are conducted to equipment called "after burner” where these gases are used as fuel to heat the gases necessary for the heating system of the equipment where the stripping is carried out.
- the gas recovery system includes commercially available equipment.
- the gases produced in the stripping stage are used as fuel in the stripping equipment itself, which helps to have a self-sufficient process where natural gas consumption is reduced.
- the stripping equipment used in stage b) should have a high-temperature incinerator to ensure that no polluting or harmful elements will be emitted to the environment.
- stage b) of stripping Since the scrap that comes out of stage b) of stripping is at a temperature between 350 s C to 500 s C, less energy is consumed in stage c) of melting by feeding preheated material to the melting furnace. For this reason, it is important that the stripping equipment and the melting furnace are close to each other, so that the preheated scrap can be cooled considerably (for example, to less than 300 s C).
- stage c) of melting aluminum by-products are generated in the melting furnace, which are mostly oxides on the surface of the liquid aluminum. Said by-product is removed from the furnace for surface cleaning using known techniques and means. This practice is done to ensure the quality of the finished product.
- the following by-products are specifically generated:
- stages b), c) and d) additionally comprise sub-stages for collecting and filtering fumes and dust using known or commercially available methods and systems, since the stripping equipment, melting furnace and holding furnaces each one has anti-pollution systems for the collection and filtering of smoke. Additionally, the anti-pollution systems have filters that have additives (lime and activated carbon) to avoid any type of emission into the atmosphere.
- the melting furnace has an equipment for controlling emissions into the atmosphere that includes: a heat-insulated sleeve filter box with a cassette-type filter with flat bags and a low-pressure reverse flow cleaning system for suction and treatment of 100% of the gases generated, having 6 suction points during the fusion process.
- the filtering surface is 3,360/3,172 m 2 , with 2,240 filter bags, with an extraction fan that has a total flow of 165,000 Am3/hr and a 2 x 132 kW motor at 1,800 rpm and 440 V. It has a dosing system with storage silo, dosing and pneumatic transport of t mix additives of Ca (OH)2 and Activated Carbon from 7 to 14 l/h.
- All the by-products (1 to 10) that are generated by the process of the present invention can be subjected to a recovery stage in a recovery line using rotary kilns, by means of already known processes. Through these processes, between 30% and 40% of aluminum will be recovered from all by-products.
- the flow of material between one stage to another of the process for the recovery of aluminum of the present invention occurs continuously, however, the flow of material can be interrupted from one stage to another depending on the amount of material and the processing capacity of the equipment used in each stage, as long as the last stage f) of casting is carried out continuously. Experts in the field can suggest adjustments in each stage of the process of the present invention so that the last stage f) of casting is carried out continuously.
- the entire method can be performed simultaneously on two or more parallel processing lines.
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Abstract
Description
PROCESO PARA EL RECICLAJE DE ALUMINIO ALUMINUM RECYCLING PROCESS
ANTECEDENTES DE LA INVENCION BACKGROUND OF THE INVENTION
A. CAMPO DE LA INVENCION A. FIELD OF THE INVENTION
La presente invención está relacionada con procesos para el reciclaje de aluminio, y más particularmente con un proceso altamente eficiente para el reciclaje de aluminio que tiene la capacidad de recuperar un alto porcentaje de aluminio presente en la materia prima que tiene una gran diversidad de materiales de desecho (chatarra), con un mínimo consumo energético posible y con muy bajas emisiones de carbón, resultando amigable con el medio ambiente (sustentable). The present invention is related to processes for recycling aluminum, and more particularly with a highly efficient process for recycling aluminum that has the capacity to recover a high percentage of aluminum present in the raw material that has a great diversity of materials of waste (scrap), with a minimum possible energy consumption and with very low carbon emissions, being friendly to the environment (sustainable).
B, DESCRIPCION DEL ARTE RELACIONADO B, DESCRIPTION OF THE RELATED ART
La industria del reciclaje del aluminio se basa principalmente en dos procesos principales: The aluminum recycling industry is mainly based on two main processes:
1. Procesos de fusión utilizando Hornos Rotatorios donde no se trata previamente la chatarra de aluminio, en dicho proceso se genera una merma entre 5 y 10 % mayor al proceso más eficiente posible, generándose una mayor cantidad de escoria que tendrá que ser confinada lo que provoca muchos residuos, por otro lado durante el proceso de fusión se generan partículas volátiles que en su mayoría son orgánicos los cuales no se estabilizan y solo se diluyen en el mejor de los casos teniendo como consecuencia proceso poco limpios con altas emisiones de CO2 y otros gases a la atmosfera. 1. Melting processes using Rotary Furnaces where the aluminum scrap is not previously treated, in said process a reduction between 5 and 10% greater than the most efficient process possible is generated, generating a greater amount of slag that will have to be confined, which it causes a lot of waste, on the other hand, during the melting process, volatile particles are generated that are mostly organic, which are not stabilized and are only diluted in the best of cases, resulting in unclean processes with high CO2 emissions and others. gases into the atmosphere.
La calidad del producto terminado que se obtiene no es muy buena ya que muchas de las impurezas presentes en la chatarra que no son aluminio se incorporan a la aleación de aluminio por lo que dichas aleaciones se utilizan para producir productos de bajos requerimientos de calidad. The quality of the finished product that is obtained is not very good since many of the impurities present in the scrap that are not aluminum are incorporated into the aluminum alloy, so these alloys are used to produce products with low quality requirements.
2. Procesos de fusión utilizando un proceso previo de tratamiento de chatarra de aluminio que remueve una parte de impurezas, principalmente elementos magnéticos esto permite una recuperación un poco mayor, pero con mermas de entre 3 a 7 % mayor al proceso más eficiente posible. Durante el proceso de fusión también se generan partículas volátiles que en su mayoría son orgánicos, los cuales no se estabilizan y solo se diluyen en el mejor de los casos, teniendo como consecuencia proceso poco limpios con altas emisiones de CO2 a la atmosfera. La calidad del producto terminado que se obtiene es un poco mejor que la que se obtiene con el proceso del Horno rotatorio sin llegar a ser extraordinaria. 2. Fusion processes using a previous aluminum scrap treatment process that removes a part of impurities, mainly magnetic elements. This allows a slightly higher recovery, but with losses of between 3 to 7% greater than the most efficient process possible. During the melting process, volatile particles are also generated, which are mostly organic, which are not stabilized and are only diluted in the best of cases, resulting in an unclean process with high CO2 emissions into the atmosphere. The quality of the finished product obtained is slightly better than that obtained with the rotary kiln process, without being extraordinary.
Por lo tanto, existe la necesidad de contar con un proceso de reciclaje de aluminio que resulte altamente eficiente y que sea amigable con el medio ambiente. Therefore, there is a need for an aluminum recycling process that is highly efficient and environmentally friendly.
En vista de la necesidad anteriormente descrita, el solicitante desarrolló un proceso para reciclaje de aluminio partiendo de chatarra de aluminio el cual es capaz de recuperar el máximo porcentaje de aluminio posible (hasta un 96% de aluminio en la materia prima), con un mínimo consumo energético posible y con muy bajas emisiones de carbón, resultando amigable con el medio ambiente (sustentable). In view of the previously described need, the applicant developed a process for aluminum recycling starting from aluminum scrap which is capable of recovering the maximum percentage of aluminum possible (up to 96% aluminum in the raw material), with a minimum possible energy consumption and with very low carbon emissions, being friendly to the environment (sustainable).
El proceso para el reciclaje de aluminio de la presente invención comprende las etapas generales de: someter dicho material de desecho a un proceso de molienda y valorización de chatarra de aluminio que puede separar un alto porcentaje de material de desecho del aluminio; someter el aluminio recuperado a un proceso de deslacado y/o precalentado, en donde los gases (pirolíticos) generados se aprovechan como combustible; posteriormente se alimentan a un proceso de fusión con sistema Vortex y finalmente a un proceso de colada continua. The process for recycling aluminum of the present invention comprises the general steps of: submitting said waste material to a grinding and recovery process for aluminum scrap that can separate a high percentage of waste material from aluminum; subjecting the recovered aluminum to a delacquering and/or preheating process, where the generated (pyrolytic) gases are used as fuel; later they are fed to a fusion process with a Vortex system and finally to a continuous casting process.
Entre algunos de los beneficios del proceso para el reciclaje de aluminio de la presente invención, se encuentran: Some of the benefits of the aluminum recycling process of the present invention include:
• Incrementa el porcentaje de recuperación de aluminio hasta en un 10% al reducir las pérdidas de metal. • Increases the aluminum recovery percentage by up to 10% by reducing metal losses.
• Minimiza el uso de sales y fundentes porque al proceso de fusión entra la materia prima limpia y sin materiales orgánicos. • Minimizes the use of salts and fluxes because clean raw material without organic materials enters the melting process.
• Revaloriza la chatarra al incrementar el porcentaje de utilización de la misma en las aleaciones rediciendo el uso de aluminio primario como consecuencia de la remoción de impurezas. • Revalues scrap by increasing the percentage of its use in alloys, reducing the use of primary aluminum as a consequence of removing impurities.
• Reduce el consumo de energéticos al utilizar los materiales orgánicos presentes en la chatarra como combustibles durante la etapa de deslacado. • Reduces energy consumption by using the organic materials present in the scrap as fuel during the stripping stage.
SUMARIO DE LA INVENCION Es por lo tanto un objetivo principal de la presente invención, proporcionar un proceso para reciclaje de aluminio partiendo de chatarra de aluminio el cual es capaz de recuperar el máximo porcentaje de aluminio posible, con un mínimo consumo energético posible, con baja generación de escorias (materiales a confinar) y con muy bajas emisiones de carbón, resultando amigable con el medio ambiente (sustentable). SUMMARY OF THE INVENTION It is therefore a main objective of the present invention to provide a process for recycling aluminum starting from aluminum scrap which is capable of recovering the maximum percentage of aluminum possible, with the minimum possible energy consumption, with low slag generation ( materials to confine) and with very low carbon emissions, being friendly to the environment (sustainable).
Es aún otro objetivo principal de la presente invención, proporcionar un proceso para la recuperación de aluminio de la naturaleza anteriormente descrita, el cual comprende las etapas generales de: someter dicho material de desecho a un proceso de molienda y valorización de chatarra de aluminio que puede separar un alto porcentaje de material de impurezas (desecho) del aluminio; someter el aluminio recuperado a un proceso de deslacado, en donde los gases producidos se aprovechan como combustible; posteriormente a un proceso de fusión con sistema Vortex y finalmente a un proceso de colada continua. It is still another main objective of the present invention, to provide a process for the recovery of aluminum of the nature described above, which comprises the general steps of: submitting said waste material to a process of grinding and valorization of aluminum scrap that can separate a high percentage of impurity material (waste) from the aluminum; subjecting the recovered aluminum to a stripping process, where the gases produced are used as fuel; later to a fusion process with a Vortex system and finally to a continuous casting process.
Es un objetivo principal adicional de la presente invención, proporcionar un proceso para la recuperación de aluminio de la naturaleza anteriormente descrita, el cual cuenta con vahos beneficios, algunos de los cuales son: incrementa el porcentaje de recuperación de aluminio al reducir las pérdidas de metal; minimiza el uso de sales y fundentes porque al proceso de fusión entra la materia prima limpia y sin materiales orgánicos; revalorize la chatarra al incrementar el porcentaje de utilización de la misma en las aleaciones rediciendo el uso de aluminio primario como consecuencia de la remoción de impurezas; reduce el consumo de energéticos al utilizar los materiales orgánicos presentes en la chatarra como combustibles durante la etapa de deslacado. It is an additional main objective of the present invention, to provide a process for the recovery of aluminum of the nature described above, which has several benefits, some of which are: it increases the percentage of aluminum recovery by reducing metal losses ; it minimizes the use of salts and fluxes because clean raw material without organic materials enters the melting process; revalue scrap by increasing the percentage of its use in alloys, reducing the use of primary aluminum as a consequence of removing impurities; reduces energy consumption by using the organic materials present in the scrap as fuel during the stripping stage.
Estos y otros objetivos y ventajas de la presente invención se harán aparentes a las personas con conocimientos normales en el ramo, de la siguiente descripción detallada de la invención. These and other objects and advantages of the present invention will become apparent to those of ordinary skill in the art from the following detailed description of the invention.
DESCRIPCION DETALLADA DE LA INVENCION. DETAILED DESCRIPTION OF THE INVENTION.
El proceso para el reciclaje de aluminio de la presente invención será ahora descrito haciendo referencia a una modalidad preferida del mismo, Materia prima Antes de ser procesada, la materia prima es pesada, almacenada. Algunos de los tipos de materia prima que son aceptados por el proceso de la presente invención se resumen en la siguiente tabla: The process for recycling aluminum of the present invention will now be described with reference to a preferred embodiment thereof, Raw material Before being processed, the raw material is weighed, stored. Some of the types of raw material that are accepted by the process of the present invention are summarized in the following table:
★Descripción de materia prima de conformidad con la clasificación para materiales de aluminio descrita en el “Scrap Specifications Circular”; Enero 21, 2016; Institute of Scrap Recycling Industries, Inc. ★Description of raw material in accordance with the classification for aluminum materials described in the “Scrap Specifications Circular”; January 21, 2016; Institute of Scrap Recycling Industries, Inc.
Cada materia prima tiene características diferentes que están asociadas a espesores, contenido de pinturas, grasas o materiales orgánicos Each raw material has different characteristics that are associated with thickness, content of paints, fats or organic materials.
Las materias primas se dividen en dos grupos, materiales gruesos de espesores mayores a 2 mm ( números 1 , 2, 8 y 9 de la tabla ) y materiales delgados con espesores menores a 2 mm ( números 3, 4, 5, 6, y 7 de la tabla ). Raw materials are divided into two groups, thick materials with thicknesses greater than 2 mm (numbers 1, 2, 8 and 9 of the table) and thin materials with thicknesses less than 2 mm (numbers 3, 4, 5, 6, and 7 of the table).
No obstante, el proceso puede procesar materia prima que comprende chatarra o material de desecho con cualquier cantidad de contenido de aluminio. However, the process can process feedstock comprising scrap or waste material with any amount of aluminum content.
Deberá entenderse que estos tipos de materias primas no son exclusivos ni limitativos ya que se es posible utilizar otro tipo de chatarras o materias primas de aluminio, ya que los enumerados se mencionan como referencia solamente. a) Etapa de molienda y remoción de impurezas It should be understood that these types of raw materials are not exclusive or limiting since it is possible to use other types of aluminum scrap or raw materials, since those listed are mentioned for reference only. a) Stage of grinding and removal of impurities
La primera etapa del proceso para el reciclaje de aluminio de la presente invención comprende la etapa de molienda y remoción de impurezas, la cual está dividida en las siguientes subetapas: The first stage of the process for recycling aluminum of the present invention comprises the stage of grinding and removal of impurities, which is divided into the following substages:
I. Molienda primaria: en la subetapa de molienda primaria, se fragmenta la materia prima en trozos de entre 100mm a 300mm en un aparato de molienda equipado con cuchillas de corte con efecto tijera conocido en el arte ajustado para producir trozos de entre 100mm a 300mm, o mediante cualquier otro equipo o método de molienda adecuado;I. Primary grinding: in the primary grinding substage, the raw material is fragmented into pieces of between 100mm and 300mm in a grinding equipped with cutting blades with scissor effect known in the art adjusted to produce pieces of between 100mm to 300mm, or by any other suitable grinding equipment or method;
II. Molienda secundaria: en la subetapa de molienda secundaria son fragmentados los trozos obtenidos en la molienda primaria con tamaños de entre 100mm a 300mm en fragmentos menores a 100mm en un aparato de molienda equipado con cuchillas de corte con efecto tijera conocido en el arte, ajustado para producir fragmentos menores a 100mm o mediante cualquier otro equipo o método de molienda adecuado. II. Secondary grinding: in the secondary grinding substage, the pieces obtained in the primary grinding with sizes between 100mm and 300mm are fragmented into fragments smaller than 100mm in a grinding apparatus equipped with cutting blades with scissor effect known in the art, adjusted to produce fragments smaller than 100mm or by any other suitable grinding equipment or method.
III. Cribado: en la subetapa de cribado se retiran finos menores a 10mm de la materia prima fragmentada en la subetapa anterior mediante una criba con tamaño de malla de 10mm. Dichos finos comprenden principalmente impurezas adheridas a las diferentes materias primas además de fragmentos pequeños de aluminio con un tamaño menor a: 10mm. Gracias al cribado se garantiza un tamaño de fragmento uniforme de entre 10mm a 100mm. En una modalidad preferida, el aparato de molienda con cuchillas de corte de la molienda secundaria cuenta con una criba integrada al aparato en cada salida de los fragmentos, por lo que en dicha modalidad, la etapa de cribado se realiza en el mismo aparato de molienda de la molienda secundaria;III. Screening: in the screening substage, fines smaller than 10mm are removed from the raw material fragmented in the previous substage using a screen with a 10mm mesh size. Said fines mainly comprise impurities adhered to the different raw materials as well as small fragments of aluminum with a size of less than: 10mm. Thanks to the screening, a uniform fragment size between 10mm and 100mm is guaranteed. In a preferred modality, the grinding apparatus with cutting blades of the secondary grinding has a sieve integrated into the apparatus at each output of the fragments, so that in said modality, the screening stage is carried out in the same grinding apparatus. from secondary grinding;
IV. Retirar fragmentos de fierro. En esta subetapa, los fragmentos de fierro que quedaron después del cribado, con tamaños de entre 10mm a 100mm se retiran de la materia prima fragmentada mediante un tambor magnético (conocido en el arte) que atrae dichos fragmentos de fierro o cualquier otro método o aparato separador de fierro adecuado; IV. Remove iron fragments. In this substage, the iron fragments that remained after screening, with sizes between 10mm and 100mm, are removed from the fragmented raw material by means of a magnetic drum (known in the art) that attracts said iron fragments or any other method or device. adequate iron separator;
V. Retirar fragmentos de material inerte. En esta etapa los fragmentos de material inerte (todo aquel que no es metálico) con tamaños de entre 10mm a 10Omm, se retiran de los fragmentos de aluminio de la materia prima mediante el uso de un equipo separador de material inerte “Eddy current” conocido en el arte, o mediante cualquier otro equipo o método adecuado; VI. Retirar metales pesados. En esta etapa se retiran fragmentos de metales pesado con tamaños de entre 10mm a 100mm de los fragmentos de aluminio de la materia prima mediante un equipo de mesas por separación densimétrica en el cual el flujo de aire es ajustado para aluminio, por lo que otros elementos con densidades mayores (metales pesados) se separan y se retiran como impurezas, o bien mediante otro equipo o método de separación de metales pesados conocido en el arte; V. Remove fragments of inert material. In this stage, the fragments of inert material (everything that is not metallic) with sizes between 10mm to 10Omm, are removed from the aluminum fragments of the raw material by using a known “Eddy current” inert material separator equipment. in art, or by any other suitable equipment or method; SAW. Remove heavy metals. In this stage, heavy metal fragments with sizes between 10mm and 100mm are removed from the aluminum fragments of the raw material by means of a table equipment for densimetric separation in which the air flow is adjusted for aluminum, so that other elements with higher densities (heavy metals) they are separated and removed as impurities, or by other heavy metal separation equipment or method known in the art;
En una modalidad de la presente invención, los materiales gruesos y los materiales delgados son procesados en la presente etapa a) de manera separada o bien en líneas de procesamiento diferentes, de tal forma que entran a la etapa b) para ser procesados por separado o en líneas de procesamiento diferente. In an embodiment of the present invention, the thick materials and the thin materials are processed in the present stage a) separately or in different processing lines, in such a way that they enter stage b) to be processed separately or in different processing lines.
El producto de la etapa de molienda y remoción de impurezas comprende chatarra de aluminio fragmentada en un tamaño uniforme en un rango de entre 10mm a 100mm, hasta un 99% libre de impurezas tales como fierro, plomo, cobre, zinc, madera, plástico, papel, etc. The product of the grinding and removal of impurities stage comprises fragmented aluminum scrap in a uniform size in a range between 10mm to 100mm, up to 99% free of impurities such as iron, lead, copper, zinc, wood, plastic, paper etc
La chatarra de aluminio fragmentada se transfiere a la siguiente etapa del proceso por cualquier medio conocido, como por ejemplo bandas transportadoras, idealmente de manera continua o hasta que la siguiente etapa pueda procesarla. The shredded aluminum scrap is transferred to the next stage of the process by any known means, such as conveyor belts, ideally continuously or until the next stage can process it.
El tamaño de materia prima que entra a la subetapa I depende de la capacidad del aparato de molienda que se utilice (es decir, puede tener cualquier tamaño), siempre y cuando dicho aparato de molienda utilizado en la subetapa I pueda producir trozos de entre 100mm a 300mm. b) Etapa de deslacado The size of raw material that enters substage I depends on the capacity of the grinding apparatus used (that is, it can have any size), as long as said grinding apparatus used in substage I can produce pieces between 100mm at 300mm. b) Deslacquering stage
Mucha de la chatarra de aluminio contiene de 3% a 4% de residuos orgánicos (pintura, laca, etc.) como por ejemplo los envases de bebidas, perfiles para construcción o laminas utilizadas para transporte, por lo que la chatarra de aluminio obtenida en la etapa de molienda y remoción de impurezas se somete a un proceso de remoción que se denomina deslacado el cual consiste en calentar la chatarra de aluminio fragmentada (someterla a un proceso térmico) en un horno hasta que se desprendan estos materiales orgánicos en forma de gases, típicamente a una temperatura de entre 400sC a 550sC. Much of the aluminum scrap contains 3% to 4% organic waste (paint, lacquer, etc.) such as beverage containers, construction profiles or sheets used for transport, so the aluminum scrap obtained in The stage of grinding and removal of impurities is subjected to a removal process called stripping, which consists of heating the fragmented aluminum scrap (subjecting it to a thermal process) in an oven until these materials are detached. organics in the form of gases, typically at a temperature between 400 s C to 550 s C.
En una modalidad preferida, el proceso de deslacado se realiza utilizando un sistema denominado IDEX® el cual está diseñado para someter la chatarra de aluminio a un proceso térmico para eliminar los contaminantes orgánicos volátiles (pintura, lacas, aceites) e inorgánicos (agua) de una amplia gama de chatarras de aluminio mediante un proceso térmico continuo. In a preferred modality, the delacquering process is carried out using a system called IDEX® which is designed to subject aluminum scrap to a thermal process to eliminate volatile organic (paint, lacquer, oils) and inorganic (water) contaminants from a wide range of aluminum scrap through a continuous thermal process.
De conformidad con lo descrito en la etapa a), los materiales gruesos y los materiales delgados que salen por separado de la etapa a) se procesan también por separado en la presente etapa b) pudiendo procesarse en dos líneas de procesamiento por separado. According to what is described in step a), the thick materials and the thin materials that come out separately from step a) are also processed separately in the present step b) and can be processed in two separate processing lines.
De conformidad con lo anterior, utilizando el sistema IDEX® de deslacado, la temperatura se ajusta entre 500°C y 550°C a 30 rpm en el kiln giratorio para el grupo de materias primas gruesas y para el grupo de materias primas delgadas la temperatura se ajusta entre 400°C y 500°C a 20 rpm en el kiln giratorio. El material sale del proceso térmico a una temperatura de entre 400sC a 550sC. La razón de esto es que el grosor de la materia prima no se modifica después de las subetapas de molienda primaria y secundaria. In accordance with the above, using the IDEX® stripping system, the temperature is adjusted between 500°C and 550°C at 30 rpm in the rotating kiln for the group of thick raw materials and for the group of thin raw materials the temperature it is set between 400°C and 500°C at 20 rpm on the rotating kiln. The material leaves the thermal process at a temperature between 400 s C to 550 s C. The reason for this is that the thickness of the raw material does not change after the primary and secondary grinding sub-stages.
No obstante, el deslacado puede efectuarse en cualquier otro horno u equipo de deslacado adecuado que cuente con una zona de calentamiento en donde se pueda llevar a cabo el proceso térmico a temperaturas adecuadas para cualquier tipo de materia prima. However, stripping can be carried out in any other oven or suitable stripping equipment that has a heating zone where the thermal process can be carried out at temperatures suitable for any type of raw material.
Debido a que la siguiente etapa comprende fusión, ya no hay necesidad de separar los materiales gruesos y delgados, aunque en otras modalidades de la invención se pueden seguir procesando por separado en líneas de procesamiento diferentes. Because the next stage involves melting, there is no longer a need to separate the thick and thin materials, although in other embodiments of the invention they may still be processed separately on different processing lines.
El producto de la etapa de deslacado comprende chatarra de aluminio sin ningún contenido de residuos orgánicos (0%) la cual se transfiere a la siguiente etapa del proceso por cualquier medio conocido como por ejemplo bandas transportadoras, idealmente de manera continua o hasta que la siguiente etapa está lista para procesar la chatarra de aluminio. c) Etapa de fusión La chatarra de aluminio obtenida en la etapa de deslacado se somete a un proceso de fusión continuo en ausencia de aire. El proceso de fusión se lleva a cabo en un horno fusor que cuente con un sistema tipo Vortex que forma un remolino de aluminio fundido (vortex well) a una temperatura de entre 700°C y 750°C, en donde la chatarra de aluminio se sumerge en el baño de aluminio para que se funda, evitando el contacto con el aire, reduciéndose al máximo la oxidación del metal. En una modalidad preferida, el horno fusor tipo Vortex tiene una capacidad de 125 toneladas y se mantiene a una temperatura de entre 720sC y 750sC. Durante el proceso de fusión se generan subproductos de aluminio que en su mayoría son óxidos en la superficie del aluminio líquido, dicho subproducto se retira del horno para limpieza superficial. El material fundido en estado líquido se transfiere mediante una bomba de grafito a la siguiente etapa del proceso de la presente invención por cualquier medio conocido, por ejemplo, por medio de canales con control de flujo, manteniendo un flujo continuo de material, hasta llenar el horno holding de la siguiente etapa; d) Etapa de ajuste de composición y refinación. The product of the stripping stage comprises aluminum scrap without any organic residue content (0%) which is transferred to the next stage of the process by any known means such as conveyor belts, ideally continuously or until the next stage stage is ready to process the aluminum scrap. c) Fusion stage The aluminum scrap obtained in the stripping stage is subjected to a continuous melting process in the absence of air. The melting process is carried out in a melting furnace that has a Vortex-type system that forms a whirlpool of molten aluminum (vortex well) at a temperature between 700°C and 750°C, where the aluminum scrap is immersed in the aluminum bath so that it melts, avoiding contact with the air, minimizing the oxidation of the metal. In a preferred embodiment, the Vortex-type melting furnace has a capacity of 125 tons and is maintained at a temperature between 720 s C and 750 s C. During the smelting process, aluminum by-products are generated, which are mostly oxides in the surface of the liquid aluminum, said by-product is removed from the furnace for surface cleaning. The molten material in a liquid state is transferred by means of a graphite pump to the next stage of the process of the present invention by any known means, for example, by means of channels with flow control, maintaining a continuous flow of material, until the tank is filled. next stage holding furnace; d) Stage of adjustment of composition and refining.
El aluminio fundido producido en la etapa de fusión se transfiere por ejemplo por medio de canales con control de flujo, manteniendo un flujo continuo de material a uno o más hornos mantenedores de aluminio en donde el aluminio se mantiene una temperatura de entre 700sC a 760sC. The molten aluminum produced in the melting stage is transferred, for example, by means of channels with flow control, maintaining a continuous flow of material to one or more aluminum holding furnaces where the aluminum is maintained at a temperature between 700 s C to 760s C.
En dichos hornos mantenedores se realiza el proceso de ajuste de composición química (aleación) de acuerdo con cualquier especificación que requiera un cliente final, lo cual se logra agregando elementos de adición al aluminio fundido. Adicionalmente se realiza la refinación del aluminio. In these maintainer furnaces, the process of adjusting the chemical composition (alloy) is carried out according to any specification required by an end customer, which is achieved by adding addition elements to the molten aluminum. Additionally, aluminum refining is carried out.
El ajuste de composición y refinación se realiza de la siguiente manera:Composition and refinement adjustment is done as follows:
I. transferir el aluminio fundido a uno o más hornos mantenedores; y para cada horno mantenedor: I. transfer the molten aluminum to one or more holding furnaces; and for each holding furnace:
II. Se toma una o más muestras de aluminio del uno o más hornos mantenedores utilizando cualquier medio adecuado como por ejemplo mediante una cuchara; II. One or more samples of aluminum are taken from the one or more holding furnaces using any suitable means, such as by means of a spoon;
III. Se analiza el contenido de metal de dichas una o más muestras utilizando cualquier método conocido para determinar específicamente cuales son los metales presentes en la una o más muestras y la cantidad de elementos de adición a agregar, los cuales son seleccionados del grupo que comprende, pero sin limitarse a: silicio, cobre, magnesio, manganeso, zinc, titanio. Obviamente durante una toma inicial de la una o más muestras, el contenido de aluminio será preponderante: III. Said one or more samples are analyzed for metal content using any known method to specifically determine which are the metals present in the one or more samples and the amount of addition elements to be added, which are selected from the group that includes, but is not limited to: silicon, copper, magnesium, manganese, zinc, titanium. Obviously during an initial taking of one or more samples, the aluminum content will be predominant:
IV. Se agregan al aluminio fundido los elementos de adición que así se requieran de acuerdo con los resultados del análisis para el cumplimiento de la especificación de producto solicitada por el cliente.IV. The addition elements that are required according to the results of the analysis are added to the molten aluminum to comply with the product specification requested by the client.
V. Realizar la refinación y limpieza de metal mediante cualquier método conocido, lo cual comprende generalmente retirar cualquier subproducto presente en la superficie del aluminio líquido (que comprende material indeseable) y retirándolo del horno mantenedor utilizando cualquier instrumento adecuado para tal fin, como por ejemplo una cuchara. V. Carry out the refining and cleaning of metal by any known method, which generally includes removing any by-product present on the surface of the liquid aluminum (which includes undesirable material) and removing it from the holding furnace using any suitable instrument for that purpose, such as a spoon.
VI. Repetir las subetapas II a VI hasta obtener la especificación solicitada. Vil. Liberar el material fundido a la siguiente etapa del método. SAW. Repeat substages II to VI until obtaining the requested specification. Vile. Release the molten material to the next stage of the method.
VIII. Repetir las etapas i a VIII VIII. Repeat steps i to VIII
En dichos hornos mantenedores también se realizan los procesos de refinación y limpieza de metal retirando cualquier subproducto presente en la superficie del aluminio líquido y retirándolo del horno por la puerta. In these holding furnaces, metal refining and cleaning processes are also carried out, removing any by-product present on the surface of the liquid aluminum and removing it from the furnace through the door.
El producto de la etapa de ajuste de composición comprende aluminio fundido líquido refinado con su composición química ajustada de conformidad con especificaciones predefinidas por un cliente. The product of the composition adjustment step comprises refined liquid molten aluminum with its chemical composition adjusted according to specifications predefined by a customer.
En una modalidad preferida del proceso de la presente invención, se cuenta con cuatro hornos mantenedores con capacidad de 25 toneladas cada uno. In a preferred embodiment of the process of the present invention, there are four holding furnaces with a capacity of 25 tons each.
Así mismo, en dicha modalidad preferida, se cuenta con al menos dos hornos mantenedores para optimizar el vaciado de los hornos a las siguientes etapas del proceso, que comprende filtrado y colada continua ya que mientras un horno mantenedor está vaciando, otro está en proceso de refinación y ajuste de aleación. Por lo tanto, en otras modalidades preferentemente, se deben tener una cantidad de hornos mantenedores tal que permita en todo momento tener un horno mantenedor listo para ser vaciado a la siguiente etapa del proceso de tal manera que se tenga la capacidad de proporcionar de manera continua aluminio fundido refinado con su composición química ajustada. Likewise, in said preferred modality, there are at least two holding furnaces to optimize the emptying of the furnaces for the following stages of the process, which includes filtering and continuous casting, since while one holding furnace is emptying, another is in the process of refining and alloy setting. Therefore, in other modalities preferably, there must be a number of holding furnaces such that it allows in all time to have a holding furnace ready to be emptied to the next stage of the process in such a way that it has the capacity to continuously provide refined molten aluminum with its adjusted chemical composition.
El aluminio fundido en estado líquido se trasfiere a la siguiente etapa de filtrado inclinando el horno (basculándolo) o por cualquier medio conocido, como por ejemplo canales con control de flujo. e) Etapa de filtrado Molten aluminum in a liquid state is transferred to the next filtering stage by tilting the furnace (tilting it) or by any known means, such as flow-controlled channels. e) Filter stage
El aluminio fundido que sale de la etapa de ajuste de composición y refinación es conducido a una caja de filtración en donde se realiza un filtrado por medio de un filtro cerámico con entre 20 a 50 PPI (poros por pulgada cuadrada), en donde dicho filtrado retiene ya sea inclusión, partículas inter metálicas o cualquier material adicional que estuviera presente en el aluminio fundido. The molten aluminum that comes out of the composition adjustment and refining stage is led to a filter box where filtering is carried out by means of a ceramic filter with between 20 to 50 PPI (pores per square inch), where said filtering retains either inclusion, intermetallic particles, or any additional material that was present in the molten aluminum.
El aluminio filtrado que sale de la caja de filtración es conducido a la siguiente etapa de colado continuo mediante cualquier medio conocido, como por ejemplo canales con control de flujo, idealmente de manera continua o hasta que la siguiente etapa esté lista para procesar el aluminio fundido. f) Etapa de colada continua The filtered aluminum exiting the lauter box is led to the next stage of continuous casting by any known means, such as flow-controlled channels, ideally continuously or until the next stage is ready to process the molten aluminum. . f) Continuous casting stage
El aluminio filtrado que sale de la etapa anterior se conduce y deposita de manera continua mediante cualquier método o medios conocidos (por ejemplo, mediante canales con control de flujo), en una máquina de colado continuo de lingotes, la cual forma lingotes de aluminio de forma regular, preferentemente con superficie superior e inferior planas, y los enfría mediante chorros de agua a presión. Se puede utilizar cualquier método o máquina de colado conocida o disponible. The filtered aluminum that leaves the previous stage is led and deposited continuously by any known method or means (for example, through channels with flow control), in a continuous ingot casting machine, which forms aluminum ingots of regular shape, preferably with a flat upper and lower surface, and cools them by means of pressurized water jets. Any known or available casting method or machine can be used.
En una modalidad preferida, el metal líquido se solidifica utilizando agua a presión. Una vez solidificado el aluminio formado una barra la cual pasa a una sección donde se identifica y se corta con sistema tipo guillotina para obtener un lingote de 10 Kgs cada uno aproximadamente, una vez que los lingotes están cortados a una temperatura entre 350°C y 450°C se transporta hasta un túnel de enfriamiento donde se enfrían los lingotes hasta 60°C El producto de la etapa de colado continuo comprende lingotes de aluminio refinado, con composición ajustada, libres de óxido, de tamaño y forma regular que los hace fáciles de estibar, listos para su embarque. In a preferred embodiment, the liquid metal is solidified using pressurized water. Once the aluminum has solidified, a bar is formed, which passes to a section where it is identified and cut with a guillotine-type system to obtain an ingot of approximately 10 kg each, once the ingots are cut at a temperature between 350°C and 450°C is transported to a cooling tunnel where the ingots are cooled to 60°C The product of the continuous casting stage comprises refined aluminum ingots, with tight composition, free of oxides, of a regular size and shape that makes them easy to stow, ready for shipment.
Durante las subetapas de I. molienda primaria y II. molienda secundaria de la etapa de a) molienda y remoción de impurezas, se generan una señe de subproductos que son retirados en las subetapas II y III y los cuales se describen a continuación: During the substages of I. primary grinding and II. Secondary grinding of the stage of a) grinding and removal of impurities, a series of by-products are generated that are removed in substages II and III and which are described below:
En la modalidad preferida, los aparatos utilizados en las subetapas de I. molienda primaria y II. molienda secundaria cuentan con sistemas de captación de polvos con trece puntos de colección disponibles comercialmente, para evitar emisión de polvos a la atmósfera. In the preferred embodiment, the apparatus used in the substages of I. primary grinding and II. Secondary milling have dust collection systems with thirteen commercially available collection points to avoid dust emissions into the atmosphere.
En dicha modalidad preferida, dichos equipos de captación de polvos comprenden: un colector de bolsas filtro Tipo Pule Jef. ; el colector tendrá una configuración de 3 a 4 tolvas, con una válvula rotatoria tipo air lock para la descarga de material en cada tolva; se cuenta con 2 Ciclones para la separación de basura y materiales de mayor tamaño (que no son polvos), este sistema tiene una capacidad nominal de 870 bolsas, tiene un extractor de acoplamiento directo, arreglo 8 con construcción anti chispa tipo C, que es instalado en el lado limpio de un colector con descarga BAU, para conectar una chimenea soportada por sí misma en piso. In said preferred embodiment, said dust collection equipment comprises: a Pule Jef Type filter bag collector. ; the collector will have a configuration of 3 to 4 hoppers, with an air lock rotary valve for the discharge of material in each hopper; there are 2 cyclones for the separation of garbage and larger materials (that are not powders), this system has a nominal capacity of 870 bags, it has a direct coupling extractor, arrangement 8 with type C anti-spark construction, which is installed on the clean side of a manifold with BAU discharge, to connect a self-supported chimney on the floor.
En otras modalidades se puede utilizar cualquier otro método o sistema para la captación de polvo disponible comercialmente. In other embodiments, any other commercially available dust collection method or system may be used.
Gracias al uso de aparatos de molienda equipados con cuchillas de corte en las subetapas I y II, se reduce la generación de polvos y por lo tanto la merma de material, comparado con otros sistemas de molienda, como por ejemplo molinos de martillo. En la etapa de b) deslacado, es muy importante que en el proceso utilizado (IDEX®) no entre oxígeno para evitar combustión dentro del equipo en donde se lleve a cabo el proceso. Thanks to the use of grinding devices equipped with cutting blades in substages I and II, the generation of dust and therefore the loss of material is reduced, compared to other grinding systems, such as hammer mills. In stage b) delacquering, it is very important that the process used (IDEX®) does not enter oxygen to avoid combustion inside the equipment where the process is carried out.
Durante el proceso de deslacado se obtienen gases que se desprenden de los orgánicos presentes en la materia prima los cuales, en una modalidad preferida del proceso de la presente invención, se conducen a un equipo denominado “after burner” en donde se aprovechan estos gases como combustible para calentar los gases necesarios para el sistema de calentamiento del equipo en donde se realiza el deslacado. Cabe aclarar que el sistema de aprovechamiento de gases comprende equipos disponibles comercialmente. During the delacquering process, gases are obtained that are released from the organics present in the raw material which, in a preferred modality of the process of the present invention, are conducted to equipment called "after burner" where these gases are used as fuel to heat the gases necessary for the heating system of the equipment where the stripping is carried out. It should be noted that the gas recovery system includes commercially available equipment.
De esta manera, los gases producidos en la etapa de deslacado, se utilizan como combustibles en el mismo equipo de deslacado, lo que ayuda a tener un proceso autosuficiente en donde se reduce el consumo de gas natural. Idealmente, el equipo de deslacado utilizado en la etapa b) debe contar con un incinerador de alta temperatura para asegurar que no se emitirán elementos contaminantes o dañinos para el medio ambiente. In this way, the gases produced in the stripping stage are used as fuel in the stripping equipment itself, which helps to have a self-sufficient process where natural gas consumption is reduced. Ideally, the stripping equipment used in stage b) should have a high-temperature incinerator to ensure that no polluting or harmful elements will be emitted to the environment.
Durante la etapa de b) deslacado, se generan los siguientes subproductos: During stage b) lacquering, the following by-products are generated:
Como la chatarra que sale de la etapa b) de deslacado se encuentra a una temperatura de entre 350s C a 500s C, se logra que se consuma menos energía en la etapa c) de fusión al alimentarse material precalentado al horno fusor. Por ello, es importante que los equipos de deslacado y el horno fusor se encuentren cerca el uno del otro, para que la chatarra precalentada se enfríe de manera considerable (por ejemplo, a menos de 300s C). Since the scrap that comes out of stage b) of stripping is at a temperature between 350 s C to 500 s C, less energy is consumed in stage c) of melting by feeding preheated material to the melting furnace. For this reason, it is important that the stripping equipment and the melting furnace are close to each other, so that the preheated scrap can be cooled considerably (for example, to less than 300 s C).
Durante la etapa c) de fusión, en el horno fusor se generan subproductos de aluminio que en su mayoría son óxidos en la superficie del aluminio líquido, dicho subproducto se retira del horno para limpieza superficial utilizando técnicas y medios conocidos. Esta práctica se realiza para asegurar la calidad del producto terminado. Durante el proceso de c) fusión se generan específicamente los siguientes subproductos: During stage c) of melting, aluminum by-products are generated in the melting furnace, which are mostly oxides on the surface of the liquid aluminum. Said by-product is removed from the furnace for surface cleaning using known techniques and means. This practice is done to ensure the quality of the finished product. During the c) fusion process, the following by-products are specifically generated:
En la etapa d) composición y refinación, se generan los siguientes subproductos: In stage d) composition and refining, the following by-products are generated:
En la modalidad preferida de la invención, las etapas b), c) y d) comprenden adicionalmente subetapas de captación y filtrado de humos y polvos mediante métodos y sistemas conocidos o disponibles comercialmente, ya que los equipos de deslacado, horno fusor y hornos mantenedores cada uno cuenta con sistemas anticontaminantes para la captación y filtrado de humos. Adicionalmente los sistemas anticontaminantes cuentan con filtros que tienen aditivos (cal y carbón activo) para evitar cualquier tipo de emisión a la atmosfera. In the preferred embodiment of the invention, stages b), c) and d) additionally comprise sub-stages for collecting and filtering fumes and dust using known or commercially available methods and systems, since the stripping equipment, melting furnace and holding furnaces each one has anti-pollution systems for the collection and filtering of smoke. Additionally, the anti-pollution systems have filters that have additives (lime and activated carbon) to avoid any type of emission into the atmosphere.
En dicha modalidad preferida, el horno fusor cuenta con un equipo de control de emisiones a la atmósfera que comprende: una caja de filtro de mangas calorifugada con filtro tipo de cassette con bolsas planas y sistema de limpieza de flujo inverso de baja presión para aspiración y tratamiento del 100% de los gases generados, teniendo 6 puntos de succión durante el proceso de fusión. La superficie de filtrado es de 3360/3172 m2, con 2240 bolsas filtrantes, con un ventilador de extracción que tiene un caudal total de 165.000 Am3/hr y un motor de 2 x 132 kW a 1800 rpm y 440 V. Cuenta con un sistema de dosificación con silo almacén, dosificación y el transporte neumático de t aditivos mix de Ca (OH)2 y Carbón Activado de 7 a 14 l/h. In said preferred modality, the melting furnace has an equipment for controlling emissions into the atmosphere that includes: a heat-insulated sleeve filter box with a cassette-type filter with flat bags and a low-pressure reverse flow cleaning system for suction and treatment of 100% of the gases generated, having 6 suction points during the fusion process. The filtering surface is 3,360/3,172 m 2 , with 2,240 filter bags, with an extraction fan that has a total flow of 165,000 Am3/hr and a 2 x 132 kW motor at 1,800 rpm and 440 V. It has a dosing system with storage silo, dosing and pneumatic transport of t mix additives of Ca (OH)2 and Activated Carbon from 7 to 14 l/h.
Todos los subproductos (1 a 10) que se generan el proceso de la presente invención se pueden someter a una etapa recuperación en una línea de recuperación utilizando hornos rotatorios, mediante procesos ya conocidos. Mediante estos procesos se recuperarán entre un 30% y 40% de aluminio de todos los subproductos. Idealmente, el flujo de materia entre una etapa a otra del proceso para la recuperación de aluminio de la presente invención se da de manera continua, no obstante, el flujo de material se puede interrumpir entre una etapa a otra dependiendo de la cantidad de material y la capacidad de procesamiento del equipo que se utilice en cada etapa, siempre y cuando la última etapa f) de colada se lleve a cabo de manera continua. Los expertos en el ramo pueden sugerir ajustes en cada etapa del proceso de la presente invención con el fin de que la última etapa f) de colada se lleve de manera continua. All the by-products (1 to 10) that are generated by the process of the present invention can be subjected to a recovery stage in a recovery line using rotary kilns, by means of already known processes. Through these processes, between 30% and 40% of aluminum will be recovered from all by-products. Ideally, the flow of material between one stage to another of the process for the recovery of aluminum of the present invention occurs continuously, however, the flow of material can be interrupted from one stage to another depending on the amount of material and the processing capacity of the equipment used in each stage, as long as the last stage f) of casting is carried out continuously. Experts in the field can suggest adjustments in each stage of the process of the present invention so that the last stage f) of casting is carried out continuously.
En la etapa de fusión, se podría utilizar otro método de fusión, no obstante, dicho método de fusión debe estar preparado para fundir y proporcionar aluminio fundido de manera continua, contar con equipos anticontaminantes y garantizar un máximo aprovechamiento del aluminio: una merma de menos del 5%, es decir, Obtener un 95% de aluminio. In the smelting stage, another smelting method could be used, however, said smelting method must be prepared to melt and provide molten aluminum continuously, have anti-pollution equipment and guarantee maximum use of aluminum: less waste of 5%, that is, obtain 95% aluminum.
Finalmente, la totalidad del método puede realizarse de manera simultánea en dos o más líneas de procesamiento paralelas. Finally, the entire method can be performed simultaneously on two or more parallel processing lines.
Ventajas específicas del método de la presente invención respecto a métodos conocidos de reciclaje de aluminio. Specific advantages of the method of the present invention over known aluminum recycling methods.
• Se incrementa hasta un 10 % el aprovechamiento del aluminio. • The use of aluminum is increased by up to 10%.
• Se reduce el consumo de gas natural. • The consumption of natural gas is reduced.
• Se reduce la huella de carbón en general. • The overall carbon footprint is reduced.
• Se mantienen estándares de emisiones y control de contaminantes más reducidos. • Lower emission and pollutant control standards are maintained.
• Se evita la emisión de dioxinas y furanos gracias a los sistemas y equipos que están incorporados durante el proceso. • The emission of dioxins and furans is avoided thanks to the systems and equipment that are incorporated during the process.
• Se reduce el consumo de sales y fundentes que luego se convierten en residuos. • The consumption of salts and fluxes that later become waste is reduced.
• Se reduce la generación de residuos que se envían a centros de confinamiento. • The generation of waste that is sent to confinement centers is reduced.
Deberá finalmente entenderse que el proceso para el reciclaje de aluminio de la presente invención no se limita a la modalidad descrita anteriormente y que los expertos en el ramo quedarán capacitados, por las enseñanzas que aquí se establecen, para efectuar cambios en el proceso para el reciclaje de aluminio de la presente invención, cuyo alcance quedará establecido exclusivamente por las siguientes reivindicaciones. Finally, it should be understood that the aluminum recycling process of the present invention is not limited to the modality described above and that experts in the field will be enabled, by the teachings established herein, to make changes in the recycling process. aluminum stock the present invention, the scope of which will be established exclusively by the following claims.
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/MX2022/050008 WO2023158294A1 (en) | 2022-02-17 | 2022-02-17 | Aluminium recycling process |
| ARP220103337A AR127875A1 (en) | 2022-02-17 | 2022-12-05 | PROCESS FOR ALUMINUM RECYCLING |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/MX2022/050008 WO2023158294A1 (en) | 2022-02-17 | 2022-02-17 | Aluminium recycling process |
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| WO2023158294A1 true WO2023158294A1 (en) | 2023-08-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| PCT/MX2022/050008 Ceased WO2023158294A1 (en) | 2022-02-17 | 2022-02-17 | Aluminium recycling process |
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| Country | Link |
|---|---|
| AR (1) | AR127875A1 (en) |
| WO (1) | WO2023158294A1 (en) |
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2022
- 2022-02-17 WO PCT/MX2022/050008 patent/WO2023158294A1/en not_active Ceased
- 2022-12-05 AR ARP220103337A patent/AR127875A1/en unknown
Non-Patent Citations (9)
| Title |
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| "Light Metals", 30 November 2019, SPRINGER INTERNATIONAL PUBLISHING, Cham, ISBN: 978-3-030-36408-3, article EGGEN SIGVART, SANDAUNET KURT, KOLBEINSEN LEIV, KVITHYLD ANNE: "Recycling of Aluminium from Mixed Household Waste", pages: 1091 - 1100, XP009548319, DOI: 10.1007/978-3-030-36408-3_148 * |
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| STEFANO CAPUZZI ET AL.: "Preparation and Melting of Scrap in Aluminum Recycling: A Review", METALS, vol. 8, no. 4, 4 August 2018 (2018-08-04), pages 249, XP055755622, DOI: 10.3390/met8040249 * |
| Y YANG, Y XIAO, B ZHOU, MARKUS ANDREAS REUTER: "Aluminium recycling: scrap melting and process simulation", SUSTAINABLE DEVELOPMENTS IN METALS PROCESSING : PROCEEDINGS OF THE JOHN FLOYD INTERNATIONAL SYMPOSIUM, MELBOURNE, VIC., JULY 3-6, 2005, AUSIMM, AUSTRALIA, 1 January 2005 (2005-01-01) - 2005-07-06, Australia, pages 251 - 264, XP009549240, ISBN: 0-646-44868-4 * |
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| AR127875A1 (en) | 2024-03-06 |
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