WO2023065104A1 - Thermal interface material coating method for battery cell - Google Patents
Thermal interface material coating method for battery cell Download PDFInfo
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- WO2023065104A1 WO2023065104A1 PCT/CN2021/124599 CN2021124599W WO2023065104A1 WO 2023065104 A1 WO2023065104 A1 WO 2023065104A1 CN 2021124599 W CN2021124599 W CN 2021124599W WO 2023065104 A1 WO2023065104 A1 WO 2023065104A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C5/00—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
- B05C5/02—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- the thickness of the substrate is between 0.05 mm and 100 mm, and the mesh size of the mesh is between 10 and 200 mesh.
- FIG. 1 is a perspective view of a conventional first battery cell
- step S4a when the moving mechanism 11a is driven to drive the single battery B2 to move in a horizontal direction, the slit coating device 12 is operated to make the fluid 2 is coated on the substrate 13 through a slot nozzle 122 of the slot coating device 12. It is worth noting that, when the moving mechanism 11a is driven to drive the single battery B2 to move along the horizontal direction, the single battery B2 has a moving speed ranging from 1 cm/s to 30 cm/s .
- the fluid 2 will further flow through the plurality of mesh holes, and then be coated on the outer surface of the single battery B2.
- the substrate 13 may be coated with a smooth material layer, so that the fluid 2 does not stick to the substrate 13 and the mesh.
- the thermal interface material coating system 1 for a battery cell shown in FIG. 9 is capable of coating a layer of thermal interface material on the outer surface of the battery cell B2, and the film layer of the thermal interface material has a uniform lateral thickness. sex.
- the battery cell B2 is a square battery cell (Prismatic battery cell) or a pouch battery cell (Pouch battery cell).
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Abstract
Description
本发明系关于电动汽车用电池装置的技术领域,尤指一种用于电池单体之热界面材料涂覆方法。The invention relates to the technical field of battery devices for electric vehicles, in particular to a thermal interface material coating method for battery cells.
目前,电动汽车市场正在蓬勃发展,而电池是攸关电动汽车之性能和成本的重要部件。电动车电池(electric-vehicle battery)简称为EVB,用于供应纯电动车(BEV)或混合动力电动汽车(HEV)之电动机能量。更详细地说明,电动车电池又称为电池包(Battery pack),其包括复数个电池单体(Battery cell)以及一个电池管理电路模组。图1显示习知的第一种电池单体的立体图,图2显示习知的第二种电池单体的立体图,且图3显示习知的第三种电池单体的立体图。如图1、图2、与图3所示,依据封装方式的不同,目前习用的三种电池单体为:筒状电池单体(Cylindrical battery cell)B1a、方体电池单体(Prismatic battery cell)B2a以及软包电池单体(Pouch battery cell)B3a。At present, the electric vehicle market is booming, and the battery is an important component related to the performance and cost of electric vehicles. Electric-vehicle battery (electric-vehicle battery), referred to as EVB, is used to supply electric motor energy of pure electric vehicle (BEV) or hybrid electric vehicle (HEV). To explain in more detail, the electric vehicle battery is also called a battery pack, which includes a plurality of battery cells and a battery management circuit module. FIG. 1 shows a perspective view of a conventional first battery cell, FIG. 2 shows a conventional perspective view of a second battery cell, and FIG. 3 shows a conventional perspective view of a third battery cell. As shown in Figure 1, Figure 2, and Figure 3, according to the different packaging methods, the three commonly used battery cells are: cylindrical battery cell (Cylindrical battery cell) B1a, square battery cell (Prismatic battery cell) ) B2a and pouch battery cell (Pouch battery cell) B3a.
为了组装上的方便,电池制造厂会先将先将多个电池单体组成一个电池模组(Battery module),然后再将至少一个电池模组与所述电池管理电路模组组成一个电池包。举例而言,中国专利公开号CN111799405A揭示一种电池模组,其技术特征在于,在堆叠排列多个筒状电池单体时,采行列式排列及交错式排列,从而提高空间利用率,使多个筒状电池单体之间具有较大的间距,有助易于散热。为了进一步提升各所述筒状电池单体的散热,电池制造商通常会在进行电池模组之组装作业之前,先将各所述筒状电池单体浸泡在一高K值热界面材料(Thermal interface material,TIM)的溶液之中,以在各所述筒状电池单体的外表面形成一热界面层。然而,浸泡方式非常难以掌握TIM材料的膜层横向厚度的均匀性。For the convenience of assembly, the battery manufacturing factory will first form a plurality of battery cells into a battery module (Battery module), and then at least one battery module and the battery management circuit module into a battery pack. For example, Chinese Patent Publication No. CN111799405A discloses a battery module. Its technical feature is that when stacking and arranging a plurality of cylindrical battery cells, they adopt determinant arrangement and staggered arrangement, so as to improve space utilization and make multiple There is a large distance between the cylindrical battery cells, which helps to dissipate heat easily. In order to further improve the heat dissipation of each of the cylindrical battery cells, battery manufacturers usually soak each of the cylindrical battery cells in a high-K thermal interface material (Thermal Thermal Interface Material) before assembling the battery module. interface material (TIM) solution to form a thermal interface layer on the outer surface of each cylindrical battery cell. However, it is very difficult to control the uniformity of the lateral thickness of the film layer of the TIM material in the soaking method.
另一方面,中国专利公开号CN110915020A揭示一种电池模组,其中,该电池模组包括一电池架以及排列在该电池架内的多个方体电池单体。同样地,为了进一步提升各所述方体电池单体的散热,可在各所述方体电池单体的外表面覆上一层热界面材料。再者,中国专利公开号CN111653707A揭示一种电池模组,其中,该电池模组包括一塑胶框体以及排列在该塑胶框体内的多个软包电池单体。同样地,为了进一步提升各所述软包电池单体的散热,可在各所述软包电池单体的外表面覆上一层热界面材料。一般而言,可使用狭缝式涂布机(slot die coater)对软包电池单体或方体电池单体进行表面TIM材料之涂覆。On the other hand, Chinese Patent Publication No. CN110915020A discloses a battery module, wherein the battery module includes a battery frame and a plurality of square battery cells arranged in the battery frame. Likewise, in order to further improve the heat dissipation of each of the cubic battery cells, a layer of thermal interface material may be coated on the outer surface of each of the cubic battery cells. Furthermore, Chinese Patent Publication No. CN111653707A discloses a battery module, wherein the battery module includes a plastic frame and a plurality of pouch battery cells arranged in the plastic frame. Similarly, in order to further improve the heat dissipation of each of the pouch battery cells, a layer of thermal interface material can be coated on the outer surface of each of the pouch battery cells. Generally speaking, a slot die coater can be used to coat the surface of a pouch battery cell or a square battery cell with TIM material.
一般来说,狭缝式涂布机的内部流道设计会影响出液的均匀性,从而直接影响最后膜层 横向厚度的均匀性。因此,习知技术在完成软包电池单体或方体电池单体的狭缝式涂布制程(为slot die coating process)之后,会接着对其进行旋转制程(Spin process),从而保证TIM材料的膜层横向厚度的均匀性。然而,这样的方式却使得TIM材料之涂覆制成多了一道步骤,同时,也迫使狭缝式涂布机必须同时具有旋转基材之机构,导致狭缝式涂布机的设备成本提高。Generally speaking, the internal channel design of the slit coater will affect the uniformity of the liquid outlet, thus directly affecting the uniformity of the transverse thickness of the final film layer. Therefore, after the conventional technology completes the slit coating process (slot die coating process) of the pouch battery cell or square battery cell, it will then be subjected to a spin process (Spin process) to ensure that the TIM material The uniformity of the lateral thickness of the film layer. However, such a method adds an additional step to the coating of the TIM material, and at the same time forces the slit coater to have a mechanism for rotating the substrate, resulting in an increase in the equipment cost of the slit coater.
由前述说明可知,习知技术用于在筒状电池单体、方体电池单体及软包电池单体的外表面涂覆热界面材料之方法显然皆具有加以改善的空间。有鉴于此,本案之发明人系极力加以研究发明,而终于研发完成一种电池单体之热界面材料涂覆方法。It can be seen from the foregoing description that the conventional methods for coating thermal interface materials on the outer surfaces of cylindrical battery cells, cubic battery cells, and pouch battery cells obviously have room for improvement. In view of this, the inventor of this case made great efforts to research and invent, and finally developed a method for coating thermal interface materials of battery cells.
发明内容Contents of the invention
有鉴于先前技术所述不足之处,本发明之主要目的在于提供一种用于电池单体之热界面材料涂覆方法,其系利用包括一转动机构、一狭缝式涂覆装置以及一基板实现所组成之涂覆系统对至少一电池单体进行一热界面材料涂覆制程;其中,该基板具有复数个网格。依据本发明之设计,在适当地控制该狭缝式涂覆装置之狭缝喷嘴的流体喷出流量、该转动机构的转动速度、该基板的厚度、以及该基板的网孔大小的情况之下,所述涂覆系统系能够在电池单体的外表面涂上一层热界面材料,且该热界面材料的膜层横向厚度具均匀性。In view of the deficiencies described in the prior art, the main purpose of the present invention is to provide a thermal interface material coating method for battery cells, which utilizes a rotating mechanism, a slit coating device and a substrate The formed coating system performs a thermal interface material coating process on at least one battery cell; wherein, the substrate has a plurality of grids. According to the design of the present invention, under the condition of properly controlling the fluid ejection flow rate of the slit nozzle of the slit coating device, the rotational speed of the rotating mechanism, the thickness of the substrate, and the mesh size of the substrate , the coating system is capable of coating a layer of thermal interface material on the outer surface of the battery cell, and the lateral thickness of the film layer of the thermal interface material is uniform.
为达成上述目的,本发明提出所述用于电池单体之热界面材料涂覆方法的一第一实施例,其包括以下步骤:In order to achieve the above purpose, the present invention proposes a first embodiment of the thermal interface material coating method for battery cells, which includes the following steps:
(1)提供一转动机构与一狭缝式涂覆装置,且填入由一热界面材料制成的一流体至该狭缝式涂覆装置的一容器部之中;(1) providing a rotating mechanism and a slot coating device, and filling a fluid made of a thermal interface material into a container portion of the slot coating device;
(2)将至少一单体电池固定在该转动机构之上,使所述单体电池位于该狭缝式涂覆装置的下方处;(2) fixing at least one single battery on the rotating mechanism so that the single battery is located below the slit coating device;
(3)将具有复数个网孔的一基板置于所述单体电池与该狭缝式涂覆装置之间;(3) placing a substrate having a plurality of mesh holes between the single battery and the slot coating device;
(4)在驱动该转动机构转动所述单体电池的情况下,操作该狭缝式涂覆装置使该流体通过该狭缝式涂覆装置的一狭缝喷嘴而被涂覆在该基板之上;以及(4) In the case of driving the rotating mechanism to rotate the single battery, operate the slit coating device so that the fluid is coated on the substrate through a slit nozzle of the slit coating device on; and
(5)该流体进一步流过该复数个网孔,进而涂覆至所述所述单体电池的外表面。(5) The fluid further flows through the plurality of mesh holes, and then is coated on the outer surface of the unit battery.
在一实施例中,当驱动该转动机构转动所述单体电池之时,所述单体电池具有一转动速度与所述欲涂布的流体之黏稠度呈现负相关。In one embodiment, when the rotating mechanism is driven to rotate the unit battery, the unit battery has a rotation speed that is negatively correlated with the viscosity of the fluid to be coated.
在一实施例中,该基板为一弧形基板,且其一曲率半径系介于3毫米至50毫米之间。In one embodiment, the substrate is a curved substrate, and a radius of curvature thereof is between 3 mm and 50 mm.
在一实施例中,该基板的厚度介于0.05毫米至100毫米之间,且所述网孔的目数介于10至200目之间。In one embodiment, the thickness of the substrate is between 0.05 mm and 100 mm, and the mesh size of the mesh is between 10 and 200 mesh.
在可行的实施例中,该基板系镀覆有一光滑材料层,使该流体不沾黏于该基板及其所述网孔。In a possible embodiment, the substrate is coated with a layer of smooth material, so that the fluid does not stick to the substrate and the mesh.
在一实施例中,该单体电池为一筒状电池单体(Cylindrical battery cell),且该热界面材料包括一聚合物基体(Polymer matrix)和分布于该聚合物基体之中的复数个导热填料。In one embodiment, the single battery is a cylindrical battery cell, and the thermal interface material includes a polymer matrix and a plurality of thermal conductive elements distributed in the polymer matrix. filler.
在可行的实施例中,该狭缝喷嘴的口缘处系设有一刮板(Squeegee),使得执行该步骤(2)时,该流体2由该狭缝喷嘴喷出,且接着由该刮板刷涂于该基板之上。In a feasible embodiment, a scraper (Squeegee) is provided at the edge of the slit nozzle, so that when the step (2) is performed, the
在可行的实施例中,该狭缝式涂覆装置更包括与该容器部连通的一加压部,且一加压板设于该加压部内;其中,在一加压力提供装置提供一加压力至该加压板的情况下,该加压板依一移动速度向下移动,从而推挤该容器部的该流体。并且,该加压力提供装置为一气压式加压机或一机械式加压机。In a feasible embodiment, the slit coating device further includes a pressurizing part communicated with the container part, and a pressurizing plate is arranged in the pressurizing part; wherein, a pressurizing force providing device provides a pressurizing When pressure is applied to the pressure plate, the pressure plate moves downward at a moving speed, thereby pushing the fluid in the container portion. Moreover, the pressure providing device is a pneumatic pressure machine or a mechanical pressure machine.
在可行的实施例中,一加热装置系连接至该容器部的外表面,用以加热该容器部内的该流体。In a possible embodiment, a heating device is connected to the outer surface of the container part for heating the fluid in the container part.
并且,本发明还提出所述用于电池单体之热界面材料涂覆方法的一第二实施例,其包括以下步骤:Moreover, the present invention also proposes a second embodiment of the thermal interface material coating method for battery cells, which includes the following steps:
(1)提供一移动机构与一狭缝式涂覆装置,且填入由一热界面材料制成的一流体至该狭缝式涂覆装置的一容器部之中;(1) providing a moving mechanism and a slot coating device, and filling a fluid made of a thermal interface material into a container portion of the slot coating device;
(2)将至少一单体电池固定在该移动机构之上,使所述单体电池位于该狭缝式涂覆装置的下方处;(2) fixing at least one single battery on the moving mechanism so that the single battery is located below the slit coating device;
(3)将具有复数个网孔的一基板置于所述单体电池与该狭缝式涂覆装置之间;(3) placing a substrate having a plurality of mesh holes between the single battery and the slot coating device;
(4)在驱动该移动机构带动所述单体电池沿一水平方向移动的情况下,操作该狭缝式涂覆装置使该流体通过该狭缝式涂覆装置的一狭缝喷嘴而被涂覆在该基板之上;以及(4) When the moving mechanism is driven to drive the single battery to move in a horizontal direction, the slit coating device is operated so that the fluid is coated through a slit nozzle of the slit coating device overlies the substrate; and
(5)该流体进一步流过该复数个网孔,进而涂覆至所述所述单体电池的外表面。(5) The fluid further flows through the plurality of mesh holes, and then is coated on the outer surface of the unit battery.
在一实施例中,当驱动该移动机构带动所述单体电池沿该水平方向移动之时,所述单体电池具有范围介于1cm/s至30cm/s之间的一移动速度。In one embodiment, when the moving mechanism is driven to drive the single battery to move along the horizontal direction, the single battery has a moving speed ranging from 1 cm/s to 30 cm/s.
在一实施例中,该基板的厚度介于0.05毫米至100毫米之间,且所述网孔的目数介于10-200目之间。In one embodiment, the thickness of the substrate is between 0.05 mm and 100 mm, and the mesh size of the mesh is between 10-200 mesh.
在可行的实施例中,该基板系镀覆有一光滑材料层,使该流体不沾黏于该基板及其所述网孔。In a possible embodiment, the substrate is coated with a layer of smooth material, so that the fluid does not stick to the substrate and the mesh.
在一实施例中,该单体电池为一方体电池单体(Prismatic battery cell)或一软包电池单体(Pouch battery cell),且该热界面材料包括一聚合物基体(Polymer matrix)和分布于该聚合物基体之中的复数个导热填料。In one embodiment, the unit battery is a square battery unit (Prismatic battery cell) or a pouch battery unit (Pouch battery cell), and the thermal interface material includes a polymer matrix (Polymer matrix) and distributed A plurality of thermally conductive fillers in the polymer matrix.
在可行的实施例中,该狭缝喷嘴的口缘处系设有一刮板(Squeegee),使得执行该步骤(2)时,该流体2由该狭缝喷嘴喷出,且接着由该刮板刷涂于该基板之上。In a feasible embodiment, a scraper (Squeegee) is provided at the edge of the slit nozzle, so that when the step (2) is performed, the
在可行的实施例中,该狭缝式涂覆装置更包括与该容器部连通的一加压部,且一加压板设于该加压部内;其中,在一加压力提供装置提供一加压力至该加压板的情况下,该加压板依一移动速度向下移动,从而推挤该容器部的该流体。并且,该加压力提供装置为一气压式加压机或一机械式加压机。In a feasible embodiment, the slit coating device further includes a pressurizing part communicated with the container part, and a pressurizing plate is arranged in the pressurizing part; wherein, a pressurizing force providing device provides a pressurizing When pressure is applied to the pressure plate, the pressure plate moves downward at a moving speed, thereby pushing the fluid in the container portion. Moreover, the pressure providing device is a pneumatic pressure machine or a mechanical pressure machine.
在可行的实施例中,一加热装置系连接至该容器部的外表面,用以加热该容器部内的该流体。。In a possible embodiment, a heating device is connected to the outer surface of the container part for heating the fluid in the container part. .
如下之实施方式中详细叙述本发明之详细特征及优点,其内容足以使相关技术者了解本发明之技术内容并据以实施,且根据本发明之说明书所揭露之内容、申请专利范围及图式,可轻易地了解本发明相关之目的及优点。The detailed features and advantages of the present invention are described in detail in the following embodiments, the content of which is sufficient to enable those skilled in the art to understand the technical content of the present invention and implement it accordingly, and according to the content disclosed in the description of the present invention, the scope of the patent application and the drawings , the related objects and advantages of the present invention can be easily understood.
图1为习知的第一种电池单体的立体图;FIG. 1 is a perspective view of a conventional first battery cell;
图2为习知的第二种电池单体的立体图;FIG. 2 is a perspective view of a second conventional battery cell;
图3为习知的第三种电池单体的立体图;Fig. 3 is a perspective view of a third conventional battery cell;
图4为本发明之一种用于电池单体之热界面材料涂覆系统的第一立体图;4 is a first perspective view of a thermal interface material coating system for a battery cell of the present invention;
图5为本发明之用于电池单体之热界面材料涂覆系统的第二立体图;5 is a second perspective view of the thermal interface material coating system for battery cells of the present invention;
图6为本发明之用于电池单体之热界面材料涂覆系统的立体分解图;6 is an exploded perspective view of the thermal interface material coating system for battery cells of the present invention;
图7为本发明之用于电池单体之热界面材料涂覆系统的第一侧剖视图;7 is a first side sectional view of a thermal interface material coating system for a battery cell according to the present invention;
图8为本发明之一种用于电池单体之热界面材料涂覆方法的第一流程图;Fig. 8 is a first flowchart of a thermal interface material coating method for a battery cell according to the present invention;
图9为本发明之用于电池单体之热界面材料涂覆系统的第二侧剖视图;9 is a second side sectional view of the thermal interface material coating system for battery cells of the present invention;
图10为本发明之一种用于电池单体之热界面材料涂覆方法的第二流程图。FIG. 10 is a second flow chart of a thermal interface material coating method for a battery cell according to the present invention.
图例说明:illustration:
<本发明><this invention>
1:用于电池单体之热界面材料涂覆系统1: Thermal interface material coating system for battery cells
11:转动机构11: Turning mechanism
11a:移动机构11a: Mobile Mechanism
12:狭缝式涂覆装置12: Slot coating device
121:容器部121: Container Department
122:狭缝喷嘴122: Slit nozzle
123:刮板123: Scraper
124:加压部124: pressurized part
12P:加压板12P: Pressure plate
13:基板13: Substrate
14:加压力提供装置14: Pressure supply device
15:加热装置15: Heating device
B1:电池单体B1: battery cell
B2:电池单体B2: battery cell
S1-S5:方法步骤S1-S5: Method steps
S1a-S5a:方法步骤S1a-S5a: Method steps
<习知><knowledge>
B1a:筒状电池单体B1a: Cylindrical battery cell
B2a:方体电池单体B2a: Cube battery cell
B3a:软包电池单体B3a: Soft pack battery cell
有关本发明之前述及其他技术内容、特点与功效,以下配合图式及较佳实施例的详细说明,将可清楚的呈现。实施例中所提到的方向用语,例如:上、下、左、右、前或后等,仅是参考方位之用,因此所使用的方向用语系作为说明之用途,而非用来限制本发明。The foregoing and other technical contents, features and effects of the present invention will be clearly presented below in conjunction with the drawings and the detailed description of the preferred embodiments. The directional terms mentioned in the embodiments, such as: up, down, left, right, front or back, etc., are only used for reference orientation, so the directional terms used are for the purpose of illustration, not to limit the scope of the present invention. invention.
为了能够更清楚地描述本发明所提出之一种用于电池单体之热界面材料涂覆方法,以下将配合图式,详尽说明本发明之较佳实施例。In order to more clearly describe a thermal interface material coating method for battery cells proposed by the present invention, preferred embodiments of the present invention will be described in detail below with reference to the drawings.
第一实施例first embodiment
本发明提出一种用于电池单体之热界面材料涂覆方法。在第一实施例中,系利用一转动机构(Rotating mechanism)、一狭缝式涂覆装置(Slot die coater)以及一弧形基板实现所述用于电池单体之热界面材料涂覆方法。换句话说,亦可称该转动机构、该狭缝式涂覆装置及该弧形基板组成一个用于电池单体之热界面材料涂覆系统。The invention proposes a method for coating a thermal interface material of a battery cell. In the first embodiment, a rotating mechanism, a slot die coater and a curved substrate are used to implement the thermal interface material coating method for a battery cell. In other words, it can also be said that the rotating mechanism, the slit coating device and the curved base form a thermal interface material coating system for battery cells.
图4显示本发明之一种用于电池单体之热界面材料涂覆系统的第一立体图,且图5显示本发明之用于电池单体之热界面材料涂覆系统的第二立体图。并且,图6显示本发明之用于电池单体之热界面材料涂覆系统的立体分解图。进一步地,图7显示本发明之用于电池单体之热界面材料涂覆系统的第一侧剖视图。再者,图8显示本发明之一种用于电池单体之热界 面材料涂覆方法的第一流程图。FIG. 4 shows a first perspective view of a thermal interface material coating system for a battery cell of the present invention, and FIG. 5 shows a second perspective view of the thermal interface material coating system for a battery cell of the present invention. Moreover, FIG. 6 shows a three-dimensional exploded view of the thermal interface material coating system for battery cells of the present invention. Further, FIG. 7 shows a first side sectional view of the thermal interface material coating system for battery cells of the present invention. Furthermore, Fig. 8 shows a first flow chart of a thermal interface material coating method for battery cells according to the present invention.
如图4至图7以及图8所示,方法流程系首先执行步骤S1:提供一转动机构11与一狭缝式涂覆装置12,且填入由一热界面材料制成的一流体2至该狭缝式涂覆装置12的一容器部121之中。进一步地,方法流程系执行步骤S2:将至少一单体电池B1固定在该转动机构11之上,使所述单体电池B1位于该狭缝式涂覆装置12的下方处。接续地,方法流程系执行步骤S3:将具有复数个网孔的一基板13置于所述单体电池B1与该狭缝式涂覆装置12之间。值得注意的是,该狭缝喷嘴122的口缘处系设有一刮板(Squeegee)123,使得执行该步骤(2)时,该流体2由该狭缝喷嘴122喷出,且接着由该刮板123刷涂于该基板13之上。As shown in Fig. 4 to Fig. 7 and Fig. 8, the process of the method firstly executes step S1: provide a
如图4至图7所示,该基板13为一弧形基板,且其一曲率半径系介于3毫米至50毫米之间。应可理解,由于该单体电池B1为一筒状电池单体(Cylindrical battery cell),因此,曲率半径系依据该单体电池B1的直径(即,Φ值)而做调整。另一方面,该基板13的厚度介于0.05毫米至100毫米之间,且所述网孔的目数介于10至200目之间。在此所述的目数,是指(1英寸×1英寸)的面积内有多少个网孔数,当然,线径与孔径可以依照目数的需求而调整。As shown in FIG. 4 to FIG. 7 , the
如图4至图7以及图8所示,方法流程接着执行步骤S4:在驱动该转动机构11转动所述单体电池B1的情况下,操作该狭缝式涂覆装置12使该流体2通过该狭缝式涂覆装置12的一狭缝喷嘴122而被涂覆在该基板13之上。值得说明的是,在驱动该转动机构11转动所述单体电池B1的情况下,所述单体电池B1具有一转动速度与所述欲涂布的流体之黏稠度呈现负相关,亦即,可视欲涂布的热界面材料的黏稠度来调整单体电池B1的转动速度,如果黏稠度越高,则调整其转动速度越慢,反之,若热界面材料的黏稠度较低,则调整其转动速度越快。假设若转动机构11的转动角速度为ω,电池单体B1的半径为R,且若电池单体转动的切线速度与移动机构11a的移动速度V2相同,即ω*R=V2,则可由此关系式调整单体电池的转动角速度ω。As shown in FIG. 4 to FIG. 7 and FIG. 8, the method flow proceeds to step S4: in the case of driving the
如此设计,在接续的步骤S5之中,该流体2便会进一步流过该复数个网孔,进而涂覆至所述所述单体电池B1的外表面。补充说明的是,在可行的实施例中,可令该基板13被镀覆有一光滑材料层,使该流体2不沾黏于该基板13及其所述网孔,而在此所述的光滑材料层,较佳为包含高分子材料与无机材微粒所组成的复合材料,其中,高分子材料系选自于:聚甲基丙烯酸甲酯、聚酰胺、聚苯乙烯、聚乙烯、聚丙烯、聚亚酰胺、聚氨基甲酸脂、聚吡咯(Polypyrrole)、聚乳酸、氟碳树酯、环氧树脂等之一、其任意组合或其衍生物。无机材微粒系选自于:奈米石墨颗粒、氮化硼微粒、碳黑、活性碳、富勒烯、石墨烯等之一、其任意组合或其衍生物。而此复合材料中,高分子占光滑材料层之重量百分比范围系为1~68wt%,无 机材微粒占光滑材料层之之重量百分比范围系为5~40wt%之间。In such a design, in the subsequent step S5, the
应可理解,在适当地控制该狭缝喷嘴122喷出该流体2的流量、该单体电池B1的转动速度、该基板13的厚度、该基板13的网孔大小、以及该基板13的曲率半径的情况之下,如图4至图7所示之用于电池单体之热界面材料涂覆系统1系能够在筒状电池单体B1的外表面涂上一层热界面材料,且该热界面材料的膜层横向厚度具均匀性。并且,在完成复数个电池单体B1的热界面材料之表面涂覆之后,还可进一步地将多个电池单体B1组装成一电池模组(Battery module),并接着将至少一个电池模组与一个电池管理电路模组一同组装成一个电池包(Battery pack)。It should be understood that when properly controlling the flow rate of the
特别说明的是,本发明所揭示者为一种用于电池单体之热界面材料涂覆方法及系统,因此本发明之技术特征并非在于用以制成该流体2之热界面材料的组成。一般而言,如中国专利公开号CN101351755A所揭示者,该热界面材料包括一聚合物基体(Polymer matrix)和分布于该聚合物基体之中的复数个导热填料(fillers)。其中,该导热填料可为金属氧化物颗粒、氮化物颗粒、碳化物颗粒、二硼化物颗粒、石墨颗粒、金属颗粒等。当然,热界面材料可视需求弹性调整,如添加金属氧化物陶瓷填料,如氧化铝、氧化镁、氧化锌、氧化锆、等,或添加氮化物陶瓷填料如:氮化铝、氮化硼、氮化硅等,或添加碳系填料如:石墨,石墨烯等,以及,添加碳化物填料如:碳化硅、碳化钨、奈米碳管、石墨、碳黑等。In particular, what is disclosed in the present invention is a thermal interface material coating method and system for battery cells, so the technical feature of the present invention does not lie in the composition of the thermal interface material used to make the
如图4至图7所示,在可行的实施例中,该狭缝式涂覆装置12更包括与该容器部121连通的一加压部124,且一加压板12P设于该加压部124内;其中,在一加压力提供装置14提供一加压力至该加压板12P的情况下,该加压板12P依一移动速度向下移动,从而推挤该容器部121的该流体2。所述加压力提供装置14可为一气压式加压机或一机械式加压机,例如,图7绘示该加压力提供装置14为一气压式加压机。As shown in Figures 4 to 7, in a feasible embodiment, the
如图4至图7所示,在可行的实施例中,本发明之用于电池单体之热界面材料涂覆系统1更包括:一加热装置15,其系连接至该容器部121的外表面,用以加热该容器部121内的该流体2。As shown in Figures 4 to 7, in a feasible embodiment, the thermal interface
第二实施例second embodiment
在第二实施例中,系利用一移动机构(Translation mechanism)、一狭缝式涂覆装置(Slot die coater)以及一平面基板实现所述用于电池单体之热界面材料涂覆方法。换句话说,亦可称该移动机构、该狭缝式涂覆装置及该平面基板组成一个用于电池单体之热界面材料涂覆系统。In the second embodiment, a translation mechanism, a slot die coater and a flat substrate are used to implement the thermal interface material coating method for battery cells. In other words, it can also be said that the moving mechanism, the slit coating device and the planar substrate form a thermal interface material coating system for battery cells.
图9显示本发明之用于电池单体之热界面材料涂覆系统的第二侧剖视图。再者,图10显 示本发明之一种用于电池单体之热界面材料涂覆方法的第二流程图。FIG. 9 shows a second side cross-sectional view of the thermal interface material coating system for battery cells of the present invention. Furthermore, FIG. 10 shows a second flowchart of a thermal interface material coating method for a battery cell according to the present invention.
如图9及图10所示,方法流程系首先执行步骤S1a:提供一移动机构11a与一狭缝式涂覆装置12,且填入由一热界面材料制成的一流体2至该狭缝式涂覆装置12的一容器部121之中。进一步地,方法流程系执行步骤S2a:将至少一单体电池B2固定在该移动机构11a之上,使所述单体电池B2位于该狭缝式涂覆装置12的下方处。接续地,方法流程系执行步骤S3a:将具有复数个网孔的一基板13置于所述单体电池B2与该狭缝式涂覆装置12之间。值得注意的是,该狭缝喷嘴122的口缘处系设有一刮板(Squeegee)123,使得执行该步骤(2)时,该流体2由该狭缝喷嘴122喷出,且接着由该刮板123刷涂于该基板13之上。As shown in Figures 9 and 10, the method flow is to firstly execute step S1a: provide a moving
如图9及图10所示,该基板13为一平面基板。另一方面,该基板13的厚度介于0.05毫米至100豪之间,且所述网孔的目数介于10至200目之间。As shown in FIGS. 9 and 10 , the
如图9及图10所示,方法流程接着执行步骤S4a:在驱动该移动机构11a带动所述单体电池B2沿一水平方向移动的情况下,操作该狭缝式涂覆装置12使该流体2通过该狭缝式涂覆装置12的一狭缝喷嘴122而被涂覆在该基板13之上。值得说明的是,在驱动该移动机构11a带动所述单体电池B2沿该水平方向移动的情况下,所述单体电池B2具有范围介于1cm/s至30cm/s之间的一移动速度。更进一步说明,移动机构11a的移动速度V2,可以依据热界面材料单位时间涂布量Q、狭缝喷嘴122的截面积A、热界面材料的涂布速度V1、单体电池B2之涂布厚度t、单体电池B2之涂布宽度W等因素进行调整,亦即Q=A*V1=V2*t*W,据此根据A、V1、t、W,即可调整移动机构11a之移动速度V2。如此设计,在接续的步骤S5a之中,该流体2便会进一步流过该复数个网孔,进而涂覆至所述所述单体电池B2的外表面。补充说明的是,在可行的实施例中,可令该基板13被镀覆有一光滑材料层,使该流体2不沾黏于该基板13及其所述网孔。As shown in Figures 9 and 10, the method flow proceeds to step S4a: when the moving
应可理解,在适当地控制该狭缝喷嘴122喷出该流体2的流量、该单体电池B2的移动速度、该基板13的厚度、以及该基板13的网孔大小的情况之下,如图9所示之用于电池单体之热界面材料涂覆系统1系能够在所述电池单体B2的外表面涂上一层热界面材料,且该热界面材料的膜层横向厚度具均匀性。在可行的实施例中,该电池单体B2为一方体电池单体(Prismatic battery cell)或一软包电池单体(Pouch battery cell)。并且,在完成复数个电池单体B2的热界面材料之表面涂覆之后,还可进一步地将多个电池单体B2组装成一电池模组(Battery module),并接着将至少一个电池模组与一个电池管理电路模组一同组装成一个电池包(Battery pack)。It should be understood that under the conditions of properly controlling the flow rate of the
特别说明的是,本发明所揭示者为一种用于电池单体之热界面材料涂覆方法及系统,因此本发明之技术特征并非在于用以制成该流体2之热界面材料的组成。一般而言,如中国专 利公开号CN101351755A所揭示者,该热界面材料包括一聚合物基体(Polymer matrix)和分布于该聚合物基体之中的复数个导热填料。其中,该导热填料可为氧化物颗粒、氮化物颗粒、碳化物颗粒、二硼化物颗粒、石墨颗粒、金属颗粒等。In particular, what is disclosed in the present invention is a thermal interface material coating method and system for battery cells, so the technical feature of the present invention does not lie in the composition of the thermal interface material used to make the
如图9所示,在第二实施中,该狭缝式涂覆装置12同样可更包括与该容器部121连通的一加压部124,且一加压板12P设于该加压部124内;其中,在一加压力提供装置14提供一加压力至该加压板12P的情况下,该加压板12P依一移动速度向下移动,从而推挤该容器部121的该流体2。所述加压力提供装置14可为一气压式加压机或一机械式加压机,例如,图9绘示该加压力提供装置14为一气压式加压机。As shown in FIG. 9, in the second implementation, the
如图9所示,在第二实施中,本发明之用于电池单体之热界面材料涂覆系统1同样可更包括:一加热装置15,其系连接至该容器部121的外表面,用以加热该容器部121内的该流体2。As shown in FIG. 9, in the second implementation, the thermal interface
如此,上述系已完整且清楚地说明本发明之一种用于电池单体之热界面材料涂覆方法。必须加以强调的是,上述之详细说明系针对本发明可行实施例之具体说明,惟该实施例并非用以限制本发明之专利范围,凡未脱离本发明技艺精神所为之等效实施或变更,均应包含于本案之专利范围中。Thus, the above is a complete and clear description of a thermal interface material coating method for battery cells of the present invention. It must be emphasized that the above detailed description is a specific description of the feasible embodiment of the present invention, but the embodiment is not used to limit the patent scope of the present invention, and any equivalent implementation or modification without departing from the technical spirit of the present invention , should be included in the patent scope of this case.
又,本发明所揭示之具体实施态样,包含复数个共同描述且彼此间可协同提供一系列效益之特色;再者,以单数来指称所请求元件的任何参照,如「一」、「此」、或「所述」,亦不应视为将此元件限制为单数;即凡依本发明申请专利范围所作之均等变化与修饰者,皆为本发明专利范围所涵盖。In addition, the specific implementation forms disclosed in the present invention include a plurality of features that are commonly described and can cooperate with each other to provide a series of benefits; moreover, any reference to the requested element is referred to in the singular, such as "a", "here ", or "described", and should not be considered as limiting this element to a singular number; that is, all equivalent changes and modifications made according to the patent scope of the present invention are covered by the patent scope of the present invention.
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| CN209374415U (en) * | 2019-03-12 | 2019-09-10 | 天地科技股份有限公司上海分公司 | Thermal conductive silicone grease quantitative coating device |
| CN113275199A (en) * | 2021-06-01 | 2021-08-20 | 深圳市曼恩斯特科技股份有限公司 | Coating mechanism and coating method |
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