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WO2023059155A1 - Composition cosmétique de type gel ayant d'excellentes capacités de rafraîchissement et d'hydratation de la peau, et son procédé de fabrication - Google Patents

Composition cosmétique de type gel ayant d'excellentes capacités de rafraîchissement et d'hydratation de la peau, et son procédé de fabrication Download PDF

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Publication number
WO2023059155A1
WO2023059155A1 PCT/KR2022/015197 KR2022015197W WO2023059155A1 WO 2023059155 A1 WO2023059155 A1 WO 2023059155A1 KR 2022015197 W KR2022015197 W KR 2022015197W WO 2023059155 A1 WO2023059155 A1 WO 2023059155A1
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WO
WIPO (PCT)
Prior art keywords
cosmetic composition
gel
skin
polyol
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2022/015197
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English (en)
Korean (ko)
Inventor
김나경
지진구
박명삼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cosmax Inc
Original Assignee
Cosmax Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cosmax Inc filed Critical Cosmax Inc
Publication of WO2023059155A1 publication Critical patent/WO2023059155A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention relates to a gel cosmetic composition with excellent skin cooling and moisturizing power and a manufacturing method thereof.
  • menthol or menthol derivatives have a strong odor and are relatively volatile, so their use is limited. In the case of general volatile components, especially highly volatile ethanol, you can feel an immediate cooling sensation, but the duration is short and can cause skin irritation and skin dryness.
  • the primer is a makeup cosmetic composition that refines the texture of the skin before proceeding with the main makeup.
  • a conventional primer it is stuffy by covering the skin thickly to fill the unevenness of the skin, or it is heavy with very high adhesion to increase the durability of makeup, or it is dry by adding an excessive amount of powder to absorb excessive sebum of the skin. There was a feeling of use.
  • moisture or ethanol may be blown away, causing skin dryness.
  • the present invention provides a cooling effect by adjusting the moisture condition of the fundamental skin while providing cooling with high-moisture and low-oil moisture care for skin that needs skin moisturizing but is burdened with excessive oil, while providing moisturizing power so that the skin does not dry out Through this, in particular, it is intended to provide a gel cosmetic composition with excellent makeup durability and a feeling of use.
  • the present invention provides a gel cosmetic composition comprising a water absorbent polymer and a polyol.
  • the water absorbent polymer may be included in 4.5 to 5.3% by weight based on the total weight of the cosmetic composition.
  • the polyol may be glycerols, glycols, or a combination thereof.
  • the polyol may be included in 5 to 25% by weight based on the total weight of the cosmetic composition.
  • the polyol may include glycerols and glycols in a weight ratio of 1:0.6 to 2.
  • the cosmetic composition may be an oil-free formulation.
  • the cosmetic composition may be a sherbet-shaped formulation.
  • a method for preparing a gel cosmetic composition comprising a water absorbent polymer and a polyol, S1) dispersing the water absorbent polymer in a portion of the polyol, and S2) mixing the remaining portion of the polyol component. It provides a method for producing a gel cosmetic composition comprising the step of.
  • the polyol of step S1) may be glycols.
  • the weight ratio of the polyol of step S1) to the polyol of step S2) may be 1:0.5 to 2.
  • the weight ratio of the polyol and the absorbent polymer mixed in step S1) may be 1:0.4 to 2.
  • the cosmetic composition of the present invention provides moisturizing power so that the skin does not dry out while providing a cooling effect to the skin, and has excellent makeup durability and feeling of use.
  • the cosmetic composition of the present invention can realize an appearance like ice sorbet, maximizes the feeling of moisture and cooling, and provides a light, non-sticky, silky finish compared to conventional primer compositions, thereby eliminating the stuffiness, stickiness, and lack of moisturizing feeling of existing primers. Significantly improved.
  • Figure 1 is an experimental result of the skin cooling effect of the present invention example (test product).
  • Figure 1a is a picture of the entire skin temperature measurement
  • Figure 1b is an enlarged picture of the skin temperature analysis site of an embodiment (test product) of the present invention
  • Figure 1c is a large enlargement of only the area after application of the embodiment (test product) of the present invention
  • Figure 1d is the skin temperature (left) and change rate (right) before and after application of the embodiment (test product) of the present invention.
  • Figure 2 is the result of measuring the skin moisture level of the present invention.
  • Figure 2a is a photograph of skin moisture color change
  • Figure 2b is a skin moisture change rate graph.
  • Figure 3 is the result of testing the skin moisturizing lasting effect of the embodiment of the present invention.
  • Figure 4 is the result of testing the makeup adhesion of the embodiment of the present invention.
  • the present invention for achieving the above-mentioned object is characterized by a gel-like cosmetic composition comprising a water absorbent polymer and a polyol and a manufacturing method thereof.
  • a gel-like cosmetic composition comprising a water absorbent polymer and a polyol and a manufacturing method thereof.
  • the present invention provides a gel-like cosmetic composition comprising an absorbent polymer and a polyol.
  • absorbent polymer is understood herein to mean a polymer capable of spontaneously absorbing aqueous fluids, in particular water and in particular distilled water. These polymers have a high capacity for absorption and retention of water and aqueous fluids. After absorption of the aqueous liquid, the particles of the polymer thus impregnated with the aqueous fluid remain insoluble in the aqueous fluid and thus retain their discrete particulate state.
  • the water absorbent polymer is, for example, 10 times to 2000 times its own weight (ie, absorption of 10 g to 2000 g of water per 1 g of the absorbent polymer), specifically in the range of 10 to 1500 times, more specifically 20 to 1000 times , and even more specifically 20 to 24 times the water-absorbing capacity.
  • These water-absorbing properties are defined under standard temperature (25° C.) and pressure (101 kPa (760 mmHg), i.e. 100,000 Pa) conditions and for distilled water.
  • the value of the water-absorbent capacity of the polymer was obtained by dispersing 0.5 g of the polymer(s) in 150 g of aqueous solution, by waiting 20 minutes, by filtering the unabsorbed solution through a 150 ⁇ m filter for 20 minutes, and by It can be determined by weighing
  • the absorbent polymer used in the composition of the present invention is specifically provided in the form of swollen particles, once hydrated, to form soft beads having a number average diameter of 10 ⁇ m to 1000 ⁇ m.
  • the absorbent polymer used in the composition of the present invention is preferably neutralized and provided in particulate form.
  • Absorbent polymers used in the compositions of the present invention are commercially available.
  • As cross-linked sodium polyacrylate Octacare X100, X110 and RM100 from Avecia, Flocare GB300 and Flosorb 500 from SNF; Luquasorb 1003, Luquasorb 1010, Luquasorb 1280 and Luquasorb 1100 from BASF, Water Lock G400 and G430 from Grain Processing (INCI Name: acrylamide/sodium acrylate copolymer), as sodium acrylate crosspolymer-2, Sumitomo Seika's Aqua Keep 10 SH NF, Aqua Keep 10 SH NFC, Sanyo Chemical Industries ) acrylic polymers (homopolymers or copolymers), such as Sanfresh ST-100C, ST100MC and IM-300MC (INCI name: sodium polyacrylate starch), and in particular starch grafted with sodium polyacrylate , such as Water Rock A-240, A-180, B-204, D-223, A-100, C-200 and D-223 (INCI
  • the absorbent polymer has, in the non-swollen state, no more than 100 ⁇ m, preferably no more than 50 ⁇ m, for example in the range of 2 ⁇ m to 100 ⁇ m, with a median particle size of 25, or preferably about 2 ⁇ m. It represents a number average size ranging from ⁇ m to about 40 ⁇ m, where the median particle size is 12.
  • the viscosity of the solution in 1% water preferably ranges from 20 to 30 Pas, even more preferably from 22 to 29 Pas at a pH of 4, and from 23 to 28 Pas at a pH of 7.
  • the absorbent polymer may be at least one selected from sodium acrylate crosspolymer-2, sodium acrylate, and sodium polyacrylate starch. Specifically, it may be sodium acrylate crosspolymer-2.
  • the water absorbent polymer may be included in 4.5 to 5.3% by weight based on the total weight of the cosmetic composition.
  • the water absorbent polymer may be 4.5 to 5.1% by weight, 4.6 to 5.1% by weight, 4.6 to 4.9% by weight, or 4.7 to 4.9% by weight based on the total weight of the cosmetic composition. If the content of the absorbent polymer is less than 4.5% by weight relative to the total weight of the cosmetic composition, the sherbet appearance is not formed, and the soft feeling and wrinkle hiding effect may be weak, and if it exceeds 5.3% by weight, the sherbet appearance is formed, but uniformity in the formulation If not thoroughly stirred, agglomeration may occur. In addition, the skin cooling and moisturizing effect may be weak.
  • the polyol may be glycerols, glycols, or a combination thereof, but is not limited thereto.
  • the glycerol may be glycerin, diglycerin, polyglycerin, glycerol, glycyl alcohol, or a combination of two or more thereof, but is not limited thereto. Specifically, it may be glycerin.
  • the glycerin may be used interchangeably with other commonly used names such as rislin, propane-1,2,3-triol, 1,2,3-propenetriol, and trihydroxypropane.
  • the glycols include propylene glycol, dipropylene glycol, butylene glycol, diethylene glycol, triethylene glycol, hexylene glycol, pentylene glycol, polyethylene glycol, or It may be a combination of two or more thereof. Specifically, it may be any one or more of butylene glycol, hexylene glycol, and pentylene glycol. More specifically, it may be butylene glycol, hexylene glycol, and pentylene glycol.
  • the polyol may be included in 5 to 25% by weight, specifically 10 to 22% by weight, more specifically 12 to 22% by weight based on the total weight of the makeup cosmetic composition.
  • the polyol may include glycerols and glycols.
  • the glycerol may be included in 3 to 17% by weight, specifically 5 to 15% by weight, more specifically 6 to 12% by weight.
  • the glycols may be included in an amount of 3 to 17% by weight, specifically 5 to 15% by weight, and more specifically 6 to 10% by weight.
  • the glycerols and glycols may be included in a weight ratio of 1: 0.6 to 2, specifically 1: a weight ratio of 0.7 to 1.5, more specifically a weight ratio of 1: 1 to 1.3 can be included as
  • the cosmetic composition of the present invention can be applied in various forms that can be applied to the skin, and specifically, it may be in a gel-cream form with a particle feeling such as sherbet or slush. According to one embodiment, the cosmetic composition may be a sherbet-shaped formulation.
  • composition of the formulation may be prepared according to a conventional method in the art.
  • the composition may further include at least one selected from the group consisting of purified water, a hydrophilic gelling agent, sugars, dyes, sweeteners, vitamins, flavors, and preservatives.
  • the compounding amount of the components can be easily selected by those skilled in the art within a range that does not impair the objects and effects of the present invention.
  • the hydrophilic gelling agent may include linear polysaccharides of glucuronic acid and glucosamine, gelatin, natural polysaccharide biopolymers, etc., for example, sodium hyaluronate, pectin, gelatin, agar, alginic acid, carrageenan, xanthine , xanthan gum, or a combination of two or more thereof, but is not limited thereto.
  • the sugars function as humectants, and include sorbitol, xylitol, erythritol, mannitol, maltitol, glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, and maltose.
  • sorbitol xylitol
  • erythritol erythritol
  • mannitol mannitol
  • maltitol glucose
  • fructose galactose
  • mannose mannose
  • threose xylose
  • arabinose fucose
  • fucose fucose
  • ribose deoxyribose
  • maltose may be one or more selected from the group consisting of trehalose, lactose and raffinose.
  • the sugar may be included in 1 to 10% by weight, specifically 1 to 5% by weight, more specifically 1 to 3% by weight, based on the total weight of the cosmetic composition. If the content of the saccharide is excessively high, the solvency of the water phase part is lowered, resulting in a problem in that the viscosifying power is lowered. . Therefore, it is preferable to satisfy the content of saccharides within the above range.
  • the cosmetic composition of the present invention is oil-free, oil-in-water (O/W), water-in-oil (W/O), water-in-silicone (W/S), water-in-oil (O/W/O) or water-in-oil-in-water ( W/O/W) formulation, and may specifically be an oil-free formulation.
  • O/W oil-in-water
  • W/O water-in-oil
  • W/S water-in-silicone
  • W/W/O water-in-oil
  • W/O/W water-in-oil-in-water
  • 'oil-free' means that oils are not included in the composition.
  • the cosmetic composition of the present invention is lotion (skin lotion), skin softener, skin toner, astringent, lotion, milk lotion, moisture lotion, nutrient lotion, massage cream, nutrient cream, moisture cream, eye Cream, hand cream, foundation, essence, nourishing essence, eye essence, pack, soap, cleansing foam, cleansing lotion, cleansing cream, body lotion, body cream, body cleanser, suspension, gel, powder, paste, mask pack or sheet, or It can be made into a dosage form comprising an aerosol composition.
  • it can be applied in various properties suitable for providing a refreshing feeling of moisture to the skin, such as gel or cream, paste, and solid, and specifically, it may be a gel cream with a particle feeling such as sherbet or slush.
  • Compositions of such formulations may be prepared according to conventional methods in the art.
  • the cosmetic composition may be a makeup cosmetic composition, but is not limited thereto, and is specifically any one selected from the group consisting of foundation, makeup base, BB cream, CC cream, makeup primer and concealer.
  • the cosmetic composition may be used for one or more selected from improving skin moisturizing power, controlling skin oil-moisture balance, soothing skin, cooling skin, improving makeup feeling, improving makeup adhesion, and improving makeup durability.
  • skin moisturizing refers to any action that maintains skin moisture or prevents moisture loss.
  • cooling refers to an effect of reducing skin temperature raised by heat, and may be used interchangeably with the terms skin cooling or refreshing feeling.
  • cooling may mean a temperature of 28 to 30 °C, but is not necessarily limited thereto.
  • the term “improving the feeling of use of makeup” means improving other satisfactions including stickiness and spreadability felt on the skin after application of the makeup composition to the skin after application to the skin.
  • the term "improving makeup adhesion” means improving the degree and time of adhesion of a makeup composition to the skin.
  • the term “enhancement of makeup durability” means to increase the duration of makeup after applying the makeup composition to the skin.
  • the cosmetic composition of the present invention provides a cooling effect by adjusting the fundamental moisture condition of the skin while providing cooling with high-moisture and low-oil moisture care for skin that requires skin moisturization but is burdened with excessive oil, while providing moisturizing power so that the skin does not dry out. provides, and through this, the makeup lasting power and feeling of use are particularly excellent.
  • the cosmetic composition according to the present invention can be used coolly on hot skin under a high temperature and dry environment, cares for excess sebum by replenishing moisture rather than controlling oil, and unlike existing makeup compositions, especially primer compositions, replenishes moisture and improves texture. It fills the skin to balance the oil and moisture of the skin, significantly improving the stuffiness, stickiness, and lack of moisturizing feeling of the existing primer.
  • the cosmetic composition according to the present invention prevents fine wrinkles by maintaining a moisturizing feeling, and prevents makeup applied after application of the present invention from being caught between skin wrinkles, thereby increasing makeup adhesion and durability and improving the feeling of use.
  • the present invention enables the implementation of an ice sherbet-like appearance and maximizes the moisture/cooling feeling through adjusting the content of a specific polymer that strongly captures moisture, providing a lighter, non-sticky, silky finish compared to conventional primer compositions.
  • the present invention also provides a method for preparing a gel cosmetic composition comprising a water absorbent polymer and a polyol.
  • a cosmetic composition in the form of a gel it is prepared by first dispersing a water absorbent polymer in a portion of polyol and then mixing the remaining components.
  • a method for preparing a gel cosmetic composition comprising a water absorbent polymer and a polyol, S1) dispersing the water absorbent polymer in a portion of the polyol and S2) mixing the remaining portion of the polyol component.
  • a method for preparing a cosmetic composition is provided. As such, it is preferable to implement a stable gel phase by first dispersing the absorbent polymer in a portion of the polyol and then mixing the remaining amount of the polyol.
  • the absorbent polymer and polyol are as detailed above.
  • the polyol dispersing the water absorbent polymer in step S1) may be glycols, specifically, glycols include propylene glycol, dipropylene glycol, butylene glycol, It may be diethylene glycol, triethylene glycol, hexylene glycol, pentylene glycol, polyethylene glycol, or a combination of two or more thereof. Specifically, it may be any one or more of butylene glycol, hexylene glycol, and pentylene glycol. More specifically, it may be butylene glycol.
  • the polyol of step S2) may be glycerol, glycol, or a combination thereof, but is not limited thereto.
  • the glycerol may be glycerin, diglycerin, polyglycerin, glycerol, glycyl alcohol, or a combination of two or more thereof, but is not limited thereto. Specifically, it may be glycerin.
  • the glycols include propylene glycol, dipropylene glycol, butylene glycol, diethylene glycol, triethylene glycol, hexylene glycol, pentylene glycol, polyethylene glycol, or It may be a combination of two or more thereof.
  • the weight ratio of the S1) step polyol and the S2) step polyol may be 1: 0.5 to 2, specifically a weight ratio of 1: 0.7 to 1.7, more specifically 1: It may be a weight ratio of 1 to 1.3.
  • the weight ratio of the polyol and the absorbent polymer mixed in step S1) in the cosmetic composition manufacturing method may be 1: 0.4 to 2, specifically 1: 0.4 to 1.5, and more specifically 1: 0.4 to 1.5. : may be 0.4 to 1.
  • step S2 in the cosmetic composition manufacturing method, in step S2), the remaining components of the cosmetic composition, except for the purified water, are further mixed with the remaining polyol, and then the purified water is mixed in step S3). In this way, if purified water is mixed in the last step, stability of the gel phase can be promoted.
  • the increase may be increased for an appropriate time, for example, 10 to 60 minutes.
  • composition of the present invention and the comparative example composition were prepared as follows with the composition shown in Table 1 below.
  • Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Purified water to 100 to 100 to 100 to 100 to 100 to 100 to 100 glycerin 6.20 6.20 6.20 3.00 8.00 - 11.00 Sodium Acrylate Crosspolymer-2 4.80 4.00 5.50 4.80 4.80 4.80 4.80 Butylene Glycol 4.80 4.80 4.80 8.00 3.00 11.00 - xylitol 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 pentylene glycol 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1,2-Hexanediol 1.00 1.00 1.00 1.00 1.00 1.00 Ethylhexylglycerin 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
  • Comparative Example 1 the viscosity was too low and thin, and the sherbet shape did not appear. Reduced makeup entrapment and decreased skin adhesion. In the case of Comparative Example 2, uniform mixing was not possible during manufacture, the formulation was opaque, and the skin moisturizing effect was insignificant. When this composition was applied to the skin, it was absorbed and looked white as it did not spread and clumped together.
  • Examples and Comparative Examples 3 to 6 compared the transparency and hardness (immediately after the experiment) of the formulation according to the content ratio of glycol and glycerin. The experimental results are shown in Table 2.
  • Comparative Example 3 had the highest hardness and lowest transparency among the other examples. In addition, Comparative Example 5 had the best transparency, but obtained a slurry appearance because the hardness was not high. Comparative Examples 4 and 6 had low transparency or low hardness compared to Examples, resulting in a muddy appearance.
  • the product was applied to the test site (inner side of the lower arm, 3cm * 3cm) in an amount of 18um, spread evenly, and then the skin temperature (before and after) of the test site was photographed with an infrared camera.
  • the skin temperature before and after of the test site was photographed with an infrared camera.
  • the test site was washed with lukewarm water, and after waiting in a constant temperature and humidity room (22 ⁇ 2°C, 40-60% RH) for 10 minutes, the skin moisture level (before) of the test site was measured.
  • 8um of the product was applied to the test site (inner side of the lower arm, 2cm * 2cm), spread evenly, washed with lukewarm water, waited in a constant temperature and humidity room for 10 minutes, and then the skin moisture level (after) was measured. After calculating the change rate of skin moisture using the average of the three measured values, it was compared and evaluated with the value before use.
  • the skin adhesion of the present invention was measured by applying the present invention to half of the subject's face, then applying the foundation to the entire face, and then taking pictures of the skin surface immediately after application and after 3 hours.
  • the present invention is applicable to cosmetics.

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Abstract

La présente invention concerne une composition cosmétique de type gel ayant d'excellentes capacités de rafraîchissement et d'hydratation de la peau. Spécifiquement, la présente invention concerne une composition cosmétique comprenant un polymère absorbant et un polyol qui fournit d'excellentes capacités de rafraîchissement ainsi que d'hydratation de la peau, et en particulier, présente une durée et une texture améliorées au maquillage en apportant des améliorations significatives à l'épaisseur, au collant, et au manque de propriétés hydratantes des compositions cosmétiques classiques.
PCT/KR2022/015197 2021-10-08 2022-10-07 Composition cosmétique de type gel ayant d'excellentes capacités de rafraîchissement et d'hydratation de la peau, et son procédé de fabrication Ceased WO2023059155A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20210134406 2021-10-08
KR10-2021-0134406 2021-10-08

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WO2023059155A1 true WO2023059155A1 (fr) 2023-04-13

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PCT/KR2022/015197 Ceased WO2023059155A1 (fr) 2021-10-08 2022-10-07 Composition cosmétique de type gel ayant d'excellentes capacités de rafraîchissement et d'hydratation de la peau, et son procédé de fabrication

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190099342A1 (en) * 2010-06-14 2019-04-04 Symrise Ag Cooling product
KR20200054681A (ko) * 2018-11-12 2020-05-20 코스맥스 주식회사 청량감을 갖는 세라마이드 함유 보습용 화장료 조성물
KR20200056925A (ko) * 2018-11-15 2020-05-25 주식회사 엘지생활건강 상전이 물질을 가시사이즈의 입자 형태로 포함하는 피부 외용 화장료 조성물
WO2020138424A1 (fr) * 2018-12-28 2020-07-02 株式会社 資生堂 Produit cosmétique sous forme de gel
US11033480B2 (en) * 2017-03-31 2021-06-15 The Procter & Gamble Company Skin care composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190099342A1 (en) * 2010-06-14 2019-04-04 Symrise Ag Cooling product
US11033480B2 (en) * 2017-03-31 2021-06-15 The Procter & Gamble Company Skin care composition
KR20200054681A (ko) * 2018-11-12 2020-05-20 코스맥스 주식회사 청량감을 갖는 세라마이드 함유 보습용 화장료 조성물
KR20200056925A (ko) * 2018-11-15 2020-05-25 주식회사 엘지생활건강 상전이 물질을 가시사이즈의 입자 형태로 포함하는 피부 외용 화장료 조성물
WO2020138424A1 (fr) * 2018-12-28 2020-07-02 株式会社 資生堂 Produit cosmétique sous forme de gel

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