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WO2022248460A3 - Catalyseur comprenant du cuivre et du gallium pour la conversion directe de co2 et de mélange co2/co en présence de h2 en mélanges de méthanol et de diméthyléther - Google Patents

Catalyseur comprenant du cuivre et du gallium pour la conversion directe de co2 et de mélange co2/co en présence de h2 en mélanges de méthanol et de diméthyléther Download PDF

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Publication number
WO2022248460A3
WO2022248460A3 PCT/EP2022/064028 EP2022064028W WO2022248460A3 WO 2022248460 A3 WO2022248460 A3 WO 2022248460A3 EP 2022064028 W EP2022064028 W EP 2022064028W WO 2022248460 A3 WO2022248460 A3 WO 2022248460A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
gallium
copper
dimethylether
methanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2022/064028
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English (en)
Other versions
WO2022248460A2 (fr
Inventor
Chiara BOSCAGLI
Stephan A Schunk
Hamideh AHI
Sandip DE
Elias Christopher FREI
Matthias Mueller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of WO2022248460A2 publication Critical patent/WO2022248460A2/fr
Publication of WO2022248460A3 publication Critical patent/WO2022248460A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/825—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne un catalyseur, ou un précurseur de catalyseur, pour la synthèse directe de mélanges de méthanol et de diméthyléther à partir d'un gaz comprenant du CO2, du CO et du H2, le catalyseur, ou le précurseur de catalyseur, comprenant du cuivre et du gallium, les éléments cuivre et gallium étant de préférence contenus dans un ou plusieurs oxydes binaires et/ou multinaires. La présente invention concerne également un procédé de préparation d'un catalyseur comprenant du cuivre élémentaire, et un ou plusieurs oxydes binaires et/ou multinaires contenant du cuivre et du gallium, et de préférence d'un catalyseur selon la présente invention. La présente invention concerne également l'utilisation du catalyseur, ou d'un précurseur de catalyseur, de l'invention dans la synthèse directe de diméthyléther et de méthanol à partir de CO2, de CO et de H2.
PCT/EP2022/064028 2021-05-25 2022-05-24 Catalyseur comprenant du cuivre et du gallium pour la conversion directe de co2 et de mélange co2/co en présence de h2 en mélanges de méthanol et de diméthyléther Ceased WO2022248460A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP21175683.8 2021-05-25
EP21175683 2021-05-25

Publications (2)

Publication Number Publication Date
WO2022248460A2 WO2022248460A2 (fr) 2022-12-01
WO2022248460A3 true WO2022248460A3 (fr) 2023-01-12

Family

ID=76098857

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2022/064028 Ceased WO2022248460A2 (fr) 2021-05-25 2022-05-24 Catalyseur comprenant du cuivre et du gallium pour la conversion directe de co2 et de mélange co2/co en présence de h2 en mélanges de méthanol et de diméthyléther

Country Status (1)

Country Link
WO (1) WO2022248460A2 (fr)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0864360A1 (fr) * 1997-03-11 1998-09-16 Agency of Industrial Science and Technology Catalyseur de synthèse du méthanol à base d'oxyde de cuivre et de zinc et procédé de preparation de ce dernier
US20030060355A1 (en) * 2001-09-26 2003-03-27 Jianhua Yao Catalyste for converting carbon dioxide to oxygenates and processes therefor and therewith
EP2399671A1 (fr) * 2009-02-23 2011-12-28 Mitsui Chemicals, Inc. Procédé de fabrication d'un catalyseur à base de cuivre, catalyseur à base de cuivre et procédé de prétraitement de celui-ci
US20120083539A1 (en) * 2008-12-18 2012-04-05 Research Instutute of Petroleum Procesing, Sinopec Process for Preparing Methanol, Dimethyl Ether, and Low Carbon Olefins from Syngas
US20170158588A1 (en) * 2015-12-02 2017-06-08 King Abdullah University Of Science And Technology Utilization and recycling of emitted carbon dioxide
WO2018162893A1 (fr) * 2017-03-06 2018-09-13 Oxford University Innovation Limited Précurseur d'hydroxyde double en couches, son procédé de préparation et catalyseurs préparés à partir de celui-ci
CN109126808A (zh) * 2018-10-24 2019-01-04 太原理工大学 一种助剂改性铜基催化剂及制备方法及其应用
CN106732616B (zh) * 2016-11-29 2019-07-30 西南化工研究设计院有限公司 一种适于大规模甲醇合成装置的催化剂及其制备方法
WO2020091298A1 (fr) * 2018-10-29 2020-05-07 한국가스공사 Catalyseur mixte pour la préparation d'éther diméthylique, son procédé de préparation et procédé de préparation d'éther diméthylique l'utilisant
CN110433864B (zh) * 2019-07-11 2020-11-27 厦门大学 一种mof负载双金属型催化剂的制备及其应用

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6004396B2 (ja) 2012-09-13 2016-10-05 国立大学法人静岡大学 ジメチルエーテル製造用触媒、基材担持触媒、及びジメチルエーテルの製造方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0864360A1 (fr) * 1997-03-11 1998-09-16 Agency of Industrial Science and Technology Catalyseur de synthèse du méthanol à base d'oxyde de cuivre et de zinc et procédé de preparation de ce dernier
US20030060355A1 (en) * 2001-09-26 2003-03-27 Jianhua Yao Catalyste for converting carbon dioxide to oxygenates and processes therefor and therewith
US20120083539A1 (en) * 2008-12-18 2012-04-05 Research Instutute of Petroleum Procesing, Sinopec Process for Preparing Methanol, Dimethyl Ether, and Low Carbon Olefins from Syngas
EP2399671A1 (fr) * 2009-02-23 2011-12-28 Mitsui Chemicals, Inc. Procédé de fabrication d'un catalyseur à base de cuivre, catalyseur à base de cuivre et procédé de prétraitement de celui-ci
US20170158588A1 (en) * 2015-12-02 2017-06-08 King Abdullah University Of Science And Technology Utilization and recycling of emitted carbon dioxide
CN106732616B (zh) * 2016-11-29 2019-07-30 西南化工研究设计院有限公司 一种适于大规模甲醇合成装置的催化剂及其制备方法
WO2018162893A1 (fr) * 2017-03-06 2018-09-13 Oxford University Innovation Limited Précurseur d'hydroxyde double en couches, son procédé de préparation et catalyseurs préparés à partir de celui-ci
CN109126808A (zh) * 2018-10-24 2019-01-04 太原理工大学 一种助剂改性铜基催化剂及制备方法及其应用
WO2020091298A1 (fr) * 2018-10-29 2020-05-07 한국가스공사 Catalyseur mixte pour la préparation d'éther diméthylique, son procédé de préparation et procédé de préparation d'éther diméthylique l'utilisant
CN110433864B (zh) * 2019-07-11 2020-11-27 厦门大学 一种mof负载双金属型催化剂的制备及其应用

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
FORNERO ESTEBAN L ET AL: "Performance of ternary Cu-Ga2O3-ZrO2catalysts in the synthesis of methanol using CO2-rich gas", CATALYSIS TODAY, ELSEVIER, AMSTERDAM, NL, vol. 213, 20 April 2013 (2013-04-20), pages 163 - 170, XP028674829, ISSN: 0920-5861, DOI: 10.1016/J.CATTOD.2013.03.012 *
HENGNE AMOL M. ET AL: "Preparation and Activity of Copper-Gallium Nanocomposite Catalysts for Carbon Dioxide Hydrogenation to Methanol", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, vol. 58, no. 47, 22 October 2019 (2019-10-22), pages 21331 - 21340, XP093005125, ISSN: 0888-5885, DOI: 10.1021/acs.iecr.9b04083 *

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WO2022248460A2 (fr) 2022-12-01

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