WO2022123243A1 - Method and apparatus for making a filter element - Google Patents
Method and apparatus for making a filter element Download PDFInfo
- Publication number
- WO2022123243A1 WO2022123243A1 PCT/GB2021/053211 GB2021053211W WO2022123243A1 WO 2022123243 A1 WO2022123243 A1 WO 2022123243A1 GB 2021053211 W GB2021053211 W GB 2021053211W WO 2022123243 A1 WO2022123243 A1 WO 2022123243A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- filtering material
- sheets
- longitudinally
- gathering
- chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0225—Applying additives to filter materials with solid additives, e.g. incorporation of a granular product
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0229—Filter rod forming processes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0229—Filter rod forming processes
- A24D3/0233—Filter rod forming processes by means of a garniture
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/025—Final operations, i.e. after the filter rod forming process
- A24D3/0254—Cutting means
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
Definitions
- the present invention relates filter elements and filters, methods for making filter elements, and an apparatus for making filter elements.
- Tobacco filter elements or filters which include a frangible capsule are known in the art.
- the frangible capsule typically contains a liquid additive which may modify the properties of the tobacco smoke which passes through the filter or filter element.
- the capsule may contain a flavourant such as menthol that modifies the flavour and other sensory properties of the tobacco smoke.
- the capsule is broken by the user prior to smoking such that the contents of the capsule is released into the surrounding filtering material.
- Tobacco filter elements or filters typically include a core comprising cellulose acetate filtering material.
- Cellulose acetate filtering material can be slow to degrade under normal environmental conditions.
- Filtering material made from paper or other non-woven materials can have improved degradability and other properties.
- Methods for making a filter element containing a capsule in which the filter element is formed from cellulose acetate tow are known in the art. Inserting a capsule into a filter element formed from sheet filtering material such as paper or a nonwoven material is more challenging, and problems relating to capsule placement and filtering material homogeneity are common.
- a method for making a filter element comprising the steps of: advancing two or more sheets of filtering material in a longitudinal direction; separating the two or more sheets of longitudinally advancing filtering material; gathering the separated sheets of longitudinally advancing filtering material to form a partially gathered rod of filtering material having a longitudinally extending recess; inserting an additive release vessel into the longitudinally extending recess; gathering the filtering material around the additive release vessel to close the recess and thereby forming a rod comprising a longitudinally extending core of filtering material and one or more additive release vessels.
- the applicant has found that using two or more sheets of filtering material and separating the two or more sheets before these are gathered leads to a partially gathered rod of filtering material which has a longitudinally extending recess, into which one or more capsules can be inserted.
- the formation of the recess leads to improved capsule positioning in filter elements made from sheet filtering material, such as paper or a nonwoven material.
- the applicant has also found that the process of the invention leads to a filter element formed from sheet filtering material having improved homogeneity.
- the two or more sheets of filtering material advancing longitudinally may be continuously advancing longitudinally.
- the two or more sheets of longitudinally advancing filtering material may be separated such that there is a gap between the two or more sheets of longitudinally advancing filtering material, and the size of the gap may reduce as the two or more sheets are partially gathered.
- the two or more sheets of filtering material Prior to capsule insertion, the two or more sheets of filtering material are not completely gathered, and the size of the gap between the two sheets reduces to form a recess in the rod of partially gathered filtering material.
- the two or more sheets may remain substantially vertically aligned.
- vertically aligned means aligned in the plane perpendicular to the plane in which the sheets of filtering material longitudinally advance and perpendicular to the plane that is transverse to plane in which the sheets of filtering material longitudinally advance.
- the two or more sheets of longitudinally advancing filtering material are separated by a separator.
- the step of gathering the separated two or more sheets of longitudinally advancing filtering material comprises drawing the separated two or more sheets of longitudinally advancing filtering material into a gathering chamber.
- the separator keeps the folds of the sheet material apart such that the capsule can be placed into the centre of the partially gathered filtering material, so leading to improved capsule positioning.
- the gathering chamber is a hollow element configured to gather or condense filtering material.
- the separator is coupled to the gathering chamber such that the two or more sheets of longitudinally advancing filtering material are separated before entering the gathering chamber, and the separator prevents complete gathering of the two or more sheets of longitudinally advancing filtering material to thereby form a longitudinally extending recess in the partially gathered filtering material.
- the gathering chamber may comprise an inlet for receiving the separated sheets of filtering material and an outlet for the gathered or partially gathered filtering material to exit.
- the gathering chamber is tapered longitudinally from the inlet, such that the inlet has a larger internal diameter than the outlet.
- the gathering chamber acts to gather (for example condense) the two or more sheets of filtering material into a partially gathered rod of filtering material having a longitudinally extending recess.
- the gathering chamber may comprise an aperture for receiving an inserter for inserting one or more additive release vessels into the longitudinally extending recess.
- the aperture may be positioned between the inlet and the outlet.
- the gathering chamber may further gather the partially gathered filtering material around the additive release vessel to close the recess and thereby form a rod comprising a longitudinally extending core of filtering material and one or more additive release vessels.
- the gathering chamber may be tapered after or from the aperture to thereby further gather the partially gathered filtering material.
- the further gathering may alternatively be performed by a further gathering chamber joined to the first gathering chamber.
- a further step of applying an outer wrapper may help to complete the gathering of the partially gathered rod of filtering material and complete the closing of the longitudinally extending recess.
- the separator is longitudinally tapered.
- the separator may have a first end having a first diameter, and a second end having a second diameter, wherein the second diameter is smaller than the first diameter.
- the separator may extend into and along at least part of the length of the gathering chamber.
- the first end of the separator may protrude from the gathering chamber and the second end of the separator may be positioned inside the gathering chamber.
- the separator may be tapered in the same direction as the gathering chamber.
- the separator may be substantially conical or frustroconical. The tapered shape of the separator separates the two or more sheets of filtering material while also facilitating the partial gathering of the sheets of filtering material.
- the gathering chamber may be tapered in the same direction as the separator so thereby partially gathering the two or more sheets of filtering material.
- the configuration of the separator and the gathering chamber maintains alignment of the two or more sheets of filtering material.
- vertical alignment means alignment in the plane perpendicular to the plane in which the sheets of filtering material longitudinally advance and perpendicular to the plane that is transverse to plane in which the sheets of filtering material longitudinally advance.
- maintaining the alignment of the two or more sheets of filtering material whilst the filtering material is gathered leads to a core of filtering material having improved homogeneity and assists with capsule placement.
- the separated two or more longitudinally advancing sheets of filtering material may be drawn into a preliminary chamber before entering the gathering chamber.
- the preliminary chamber may comprise an inlet and an outlet.
- the preliminary chamber may be tapered longitudinally away from the inlet.
- the inlet may have a larger internal diameter than the outlet.
- the outlet of the preliminary chamber may be joined to the inlet of the gathering chamber, and the separator may extend into and along at least part of the length of the preliminary chamber.
- the first end of the separator may protrude from the preliminary chamber and the second end of the separator may be positioned inside the preliminary chamber.
- the preliminary chamber and the separator may be configured such that the two or more sheets of longitudinally advancing filtering material are separated before entering the preliminary chamber, and the separator prevents complete gathering of the two or more sheets of longitudinally advancing filtering material to thereby form a longitudinally extending recess in the partially gathered filtering material.
- the gathering chamber comprises an inlet joined to the outlet of the preliminary chamber and, the gathering chamber comprises an aperture for receiving the inserter.
- the gathering chamber may taper longitudinally from or after the aperture to thereby gather the two or more sheets of filtering material around the additive release vessel to close the recess and thereby form a continuous rod comprising a longitudinally extending core of filtering material and one or more additive release vessels.
- the additive release vessel inserter may comprise a rotating drum or wheel that rotates to thereby insert an additive release vessel into the recess at regular intervals.
- the method may comprise a step of cutting the rod to form a filter element comprising a longitudinally extending core of filtering material and one or more additive release vessels.
- the method may comprise a step of advancing a sheet of filtering material in the longitudinal direction; and cutting the sheet longitudinally to thereby form two or more sheets of longitudinally extending filtering material.
- the two or more sheets of filtering material continue to advance longitudinally following the cutting.
- the sheet of longitudinally advancing filtering material may be cut to form two, three four or more sheets of longitudinally extending filtering material.
- the filtering material may be cut by a separate process and wound on to a reel for use in the methods of the invention.
- the two or more sheets of filtering material may be embossed.
- the method may comprise a step of embossing the two or more sheets of longitudinally extending filtering material.
- the embossing imparts an embossed profile onto the two or more sheets of filtering material.
- the embossing may be carried out by an embosser.
- the embosser may comprise a rotating drum (for example an embossing roller) comprising projections (e.g. spikes) extending away from the surface of the drum (for example the surface of the embossing roller).
- the applicant has found that the step of embossing the two or more sheets leads to a filter element having a desired pressure drop and a compact or dense end visual appearance.
- the two or more sheets of filtering material may comprise 2, 3 or 4 sheets of filtering material.
- the two or more sheets of filtering material may each have a width of 50 to 200mm, for example 75 to 175mm, for example 80 to 150mm, for example 90 to 125mm, for example 100 to 120mm, for example 110mm.
- the two or more sheets of filtering material may have a thickness of from 50 pm to 100 pm, for example 60 pm to 90 pm, for example, 70 pm to 90 pm, for example 80 pm to 90 pm, for example 82 pm to 88 pm, for example 83 pm to 87 pm, for example 84 pm to 86 pm, for example 85 pm.
- the filtering material may be tobacco filtering material.
- the filtering material may comprise paper or a non-woven material such as an air laid non-woven materials such as McAirlaid material, a melt-spun non-woven material, and/or a melt-blown non-woven material.
- the filtering material comprises or is paper.
- the paper may have a basis weight of from 25 g/m 2 to 65 g/m 2 , for example 30 to 60 g/m 2 , for example 30 to 50 g/m 2 , for example 30 to 40 g/m 2 , for example 32 to 38 g/m 2 , for example 33 to 37 g/m 2 , for example 36 g/m 2 .
- the additive release vessel may be a capsule, for example a frangible capsule.
- the additive release vessel such as a capsule, such as a frangible capsule, may comprise an additive.
- the additive may comprise a smoke modifying agent such as a flavourant and/or a liquid, solid or other material e.g. to aid smoke filtration.
- the flavourant may, for example, be menthol, spearmint, peppermint, nutmeg, cinnamon, clove, lemon, chocolate, peach, strawberry, vanilla or the like.
- the method may comprise a step of wrapping the continuous rod comprising a longitudinally extending core of filtering material and one or more additive release vessels before the continuous rod is cut.
- the step of wrapping may comprise applying an outer wrapper, for example a plug wrap, which surrounds the continuous rod.
- the method may comprise a step of applying an additive material to the two or more sheets of filtering material.
- the additive may be applied following the step of embossing.
- the additive may be a taste modifying agent and/or a flavourant.
- the flavourant may, for example, be menthol, spearmint, peppermint, nutmeg, cinnamon, clove, lemon, chocolate, peach, strawberry, vanilla or the like.
- a filter element obtained according to the method of the present invention, for example according to the method of any statement set out above.
- a filter element comprising a longitudinally extending core of filtering material and an additive release vessel within the longitudinally extending core of filtering material; wherein the longitudinally extending core of filtering material is formed from two or more sheets of filtering material.
- the additive release vessel may be a capsule such as a frangible capsule.
- the additive release vessel such as a capsule, such as a frangible capsule, may comprise an additive.
- the additive may comprise a smoke modifying agent such as a flavourant and/or a liquid, solid or other material e.g. to aid smoke filtration.
- the flavourant may, for example, be menthol, spearmint, peppermint, nutmeg, cinnamon, clove, lemon, chocolate, peach, strawberry, vanilla or the like.
- the amount of additive, for example flavourant may be less than 35 mg per filter element.
- the additive release vessel such as a capsule or frangible capsule, may be spherical.
- the additive release vessel (such as a capsule or frangible capsule) may have a width at its broadest point of 2.0 to 4mm, for example 2.8 to 3.5 mm.
- the filter element may be formed from 2, 3, 4 or more sheets of filtering material.
- the two or more sheets of filtering material may each have a width of 50 to 200mm, for example 75 to 175mm, for example 80 to 150mm, for example 90 to 125mm, for example 100 to 120mm, for example 1 10mm.
- the two or more sheets of filtering material may have a thickness of from 50 pm to 100 pm, for example 60 pm to 90 pm, for example, 70 pm to 90 pm, for example 80 pm to 90 pm, for example 82 pm to 88 pm, for example 83 pm to 87 pm, for example 84 pm to 86 pm, for example 85 pm.
- the filtering material may comprise a paper or non-woven material.
- the non-woven material may be an air laid non-woven material, such as McAirlaid material, a melt-spun non-woven material, and/or a melt-blown non-woven material.
- the paper may have a basis weight of from 25 g/m 2 to 65 g/m 2 , for example 30 to 60 g/m 2 , for example 30 to 50 g/m 2 , for example 30 to 40 g/m 2 , for example 32 to 38 g/m 2 , for example 33 to 37 g/m 2 , for example 36 g/m 2 .
- the two or more sheets of filtering material may be embossed.
- the outer circumference of the filter element may be between 14 and 26 mm, for example between 16 and 26 mm.
- the length of the filter element may be between 4.0 mm and 50 mm, for example between 5mm and 32mm.
- the filter element may be for use as part of a tobacco smoke filter or filter for a non-tobacco smokable material, for example marijuana.
- the filter element of the present invention may be incorporated into a multi-segment filter as a single segment. This would allow for an increase in the number of features that could be incorporated into the filter. For example, a filter element according to any statement set out above may be joined with a further filter element.
- the filter element of the present invention may be incorporated into a smoking article, such as a cigarette, cigarillo, cigar and the like.
- the filter element of the present invention may be incorporated into a tobacco heating product or an e-cigarette.
- the filter element may also be used alone or as part of a filter which is assembled by a user to form a smoking article, for example a roll-your-own smoking article.
- a filter for example a tobacco smoke filter, comprising a filter element according to any statement set out above.
- the filter for example a tobacco smoke filter, may further comprise one or more further filter element(s).
- Such a filter which comprises more than one filter element may be referred to as a multi segment filter.
- the filter may comprise an outer wrapper, for example plugwrap, which surrounds the filter element or one or more filter elements.
- the wrapper may be paper, for example an air permeable paper.
- the wrapper may have a basis weight from 20 to 100 grams per square metre, for example from 20 to 50 grams per square metre.
- the wrapper may be coated.
- the further filter element may be wrapped by an outer wrapper, for example a plugwrap, which surrounds the further filter element.
- the filter element as defined according to any statement set out above and a further filter element may together be wrapped by an outer wrapper, such as a plug wrap.
- the outer wrapper may function to join the filter elements and secure them in place.
- a smoking article comprising a filter or filter element as described above.
- the smoking article may include a filter as set out above that is joined to a wrapped rod of smoking material such as tobacco smoking material.
- the smoking article may further comprise a tipping wrapper, for example a tipping paper.
- the tipping wrapper joins the wrapped rod of smoking material to the filter by engaging around the adjacent ends of the filter and the wrapped rod of smoking material.
- the tipping wrapper may be configured to leave some of the outer surface of the filter or filter wrapper exposed.
- the filter may be joined to the wrapped rod of smoking material by a full tipping wrapper which engages around the full filter or mouthpiece length and the adjacent end of the rod of smoking material.
- the filter element, filter or smoking article according to the invention may be unventilated, or may be ventilated by methods well known in the art, e.g. by use of a pre-perforated or air-permeable filter wrapper (plugwrap) or tipping wrapper (tipping paper), and/or laser perforation of the filter wrapper and/or tipping wrapper.
- the mouthpiece, filter, filter element or smoking article according to the invention may be ventilated by laser perforation of the longitudinally extending core of filtering material (as well as wrapper(s) (plugwrap) and tipping wrapper (tipping paper) if present).
- a ventilating full tipping wrapper may likewise be inherently air-permeable or may be provided with ventilation holes, and for ventilated products where both filter wrapper (plugwrap) and tipping wrapper (tipping paper) are present, ventilation through the tipping wrapper (tipping paper) will usually be in register with that through the filter wrapper (plug wrap). Ventilation holes through a filter wrapper (plugwrap), or through a tipping wrapper (tipping paper), or through both simultaneously, may be made by laser perforation during mouthpiece, filter or filter element production.
- a multiple rod comprising a plurality of filter elements according to the invention arranged end-to-end in a mirror image relationship.
- an apparatus for making a filter element comprising: a separator for separating two or more longitudinally advancing sheets of filtering material; a gathering chamber configured to gather the separated longitudinally advancing sheets of filtering material and form a rod of partially gathered filtering material; wherein the separator is coupled to the gathering chamber, such that the separator and the gathering chamber are configured to form a longitudinally extending recess in the rod of partially gathered filtering material; and an inserter configured to insert one or more additive release vessels into the longitudinally extending recess.
- the gathering chamber is a hollow section configured to gather or condense filtering material to form a longitudinally extending rod of filtering material.
- the separator and gathering chamber are coupled such that the two or more sheets of longitudinally advancing filtering material are separated before entering the gathering chamber, and the separator prevents complete gathering of the two or more sheets of longitudinally advancing filtering material to thereby form a longitudinally extending recess in the partially gathered filtering material.
- the gathering chamber may comprise an inlet for receiving the separated sheets of filtering material and an outlet for the gathered or partially gathered filtering material to exit.
- the gathering chamber is tapered longitudinally away from the inlet, such that the inlet has a larger internal diameter than the outlet.
- the gathering chamber acts to gather (for example condense) the two or more sheets of filtering material into a partially gathered rod of filtering material having a longitudinally extending recess.
- the separator may be longitudinally tapered.
- the separator may have a first end having a first diameter, and a second end having a second diameter, wherein the second diameter is smaller than the first diameter.
- the separator may extend into and along at least part of the length of the gathering chamber.
- the first end of the separator may protrude from the gathering chamber and the second end of the separator may be positioned inside the gathering chamber.
- the separator may be tapered in the same direction as the gathering chamber.
- the separator may be substantially conical or frustroconical.
- the tapered shape of the separator is configured to separate the two or more sheets of filtering material while also facilitating the partial gathering of the sheets of filtering material.
- the gathering chamber may be tapered in the same direction as the separator so thereby partially gathering the two or more sheets of filtering material.
- the configuration of the separator and the gathering chamber maintains alignment of the two or more sheets of filtering material.
- vertical alignment means alignment in the plane perpendicular to the plane in which the sheets of filtering material longitudinally advance and perpendicular to the plane that is transverse to plane in which the sheets of filtering material longitudinally advance.
- maintaining the alignment of the two or more sheets of filtering material whilst the filtering material is gathered leads to a core of filtering material having improved homogeneity and also assists with capsule placement.
- the separator keeps the folds of the sheet material apart such that the capsule can be placed into the centre of the partially gathered filtering material, so leading to improved capsule positioning.
- the gathering chamber may comprise an aperture, for example a longitudinally extending aperture, for receiving the inserter. This configuration enables the inserter to insert one or more additive release vessels into the recess formed in the partially gathered rod of filtering material.
- the gathering chamber may be tapered from or after the aperture to facilitate further gathering of the partially gathered rod of filtering material around the additive release vessel to close the recess and thereby form a continuous rod comprising a longitudinally extending core of filtering material and one or more additive release vessels.
- the separator may extend into and along at least part of the length of the gathering chamber, but the separator does not extend as far as the longitudinally extending aperture. This configuration allows for the one or more additive release vessels to be inserted into the recess.
- the apparatus may comprise a preliminary chamber comprising: an inlet and an outlet; wherein the preliminary chamber is tapered longitudinally away from the inlet.
- the inlet may have a larger internal diameter than the outlet.
- the separator may be longitudinally tapered and extends into and along at least part of the length of the preliminary chamber.
- the first end of the separator may protrude from the preliminary chamber and the second end of the separator may be positioned inside the preliminary chamber.
- the separator may be tapered in the same direction as the preliminary chamber.
- the separator being tapered in the same direction as the preliminary chamber means that the separator is able to be positioned partially inside of the preliminary chamber.
- the preliminary chamber helps to partially gather the filtering material before it enters the gathering chamber.
- the gathering chamber comprises an inlet joined to the outlet of the preliminary chamber, and the gathering chamber comprises an aperture for receiving the inserter.
- the gathering chamber may taper longitudinally from the end of the aperture to thereby gather the two or more sheets of filtering material around the additive release vessel to close the recess and thereby form a continuous rod comprising a longitudinally extending core of filtering material and one or more additive release vessels.
- the apparatus may comprise a cutter configured to cut a single sheet of filtering material into two or more longitudinally extending sheets of filtering material.
- the cutter may be configured to cut the single sheet of filtering material into two, three, four or more longitudinally extending sheets of filtering material.
- the inserter may comprise a rotating drum or wheel configured to insert the or each additive release vessel into the longitudinally extending recess.
- the apparatus may comprise a rod cutter configured to cut a rod comprising a longitudinally extending core of filtering material and one or more additive release vessels to form a filter element.
- the apparatus may comprise an embosser.
- the embosser may comprise a rotating drum (for example an embossing roller) comprising projections (e.g. spikes) extending away from the surface of the drum (for example the surface of the embossing roller).
- the embosser may emboss the two or more sheets of filtering material. The applicant has found that embossing the two or more sheets leads to a filter element having a desired pressure drop and a compact or dense end visual appearance.
- the apparatus may comprise a wrapping element for wrapping the advancing rod before it is cut.
- the apparatus may comprise an additive applicator for applying an additive to the two or more sheets of filtering material.
- the additive may be a taste modifying agent and/or a flavourant.
- the flavourant may, for example, be menthol, spearmint, peppermint, nutmeg, cinnamon, clove, lemon, chocolate, peach, strawberry, vanilla or the like.
- an apparatus for separating and gathering two or more sheets of filtering material comprising: a gathering chamber comprising an inlet and an outlet, wherein the inlet has a larger diameter than the outlet such that the gathering chamber is longitudinally tapered; a separator extending at least part of the way into the gathering chamber and protruding from the inlet of the gathering chamber; wherein the separator and the gathering chamber are configured to separate and partially gather two or more sheets of filtering material to thereby form a partially gathered longitudinally extending rod of filtering material comprising a longitudinally extending recess.
- the gathering chamber may comprise an inlet for receiving the separated sheets of filtering material and an outlet for the partially gathered filtering material to exit.
- the gathering chamber acts to gather (for example condense) the two or more sheets of filtering material into a partially gathered rod of filtering material having a longitudinally extending recess.
- the separator may be tapered in the same direction as the gathering chamber.
- the separator may be substantially conical or frustroconical.
- the tapered shape of the separator separates the two or more sheets of filtering material while also facilitating the partial gathering of the sheets of filtering material.
- the gathering chamber may be tapered in the same direction as the separator so thereby partially gathering the two or more sheets of filtering material. The applicant has found that even at the point at which the separator is narrowest, the two or more sheets of filtering material remain separated, and after the sheets of filtering material advance beyond the separator, a recess remains in the partially gathered rod, and the recess can receive the or each additive release vessel.
- the configuration of the separator and the gathering chamber maintains alignment of the two or more sheets of filtering material.
- vertical alignment means alignment in the plane perpendicular to the plane in which the sheets of filtering material longitudinally advance and perpendicular to the plane that is transverse to plane in which the sheets of filtering material longitudinally advance.
- maintaining the alignment of the two or more sheets of filtering material whilst the filtering material is gathered leads to a core of filtering material having improved homogeneity and also assists with capsule placement.
- the separator keeps the folds of the sheet material apart such that the capsule can be placed into the centre of the partially gathered filtering material, so leading to improved capsule positioning.
- the gathering chamber may comprise an aperture, for example a longitudinally extending aperture, for receiving an inserter for inserting one or more additive release vessels. This configuration enables the inserter to insert one or more additive release vessels into the recess formed in the partially gathered rod of filtering material.
- the gathering chamber may be tapered from or after the aperture to facilitate further gathering of the partially gathered rod of filtering material around the additive release vessel to close the recess and thereby form a continuous rod comprising a longitudinally extending core of filtering material and one or more additive release vessels.
- the separator may extend into and along at least part of the length of the gathering chamber, but the separator does not extend as far as the longitudinally extending aperture. This configuration allows for the one or more additive release vessels to be inserted into the recess.
- the apparatus may comprise a preliminary chamber comprising: an inlet and an outlet; wherein the preliminary chamber is tapered longitudinally away from the inlet.
- the inlet may have a larger internal diameter than the outlet.
- the separator may be longitudinally tapered and extends into and along at least part of the length of the preliminary chamber.
- the first end of the separator may protrude from the preliminary chamber and the second end of the separator may be positioned inside the preliminary chamber.
- the separator may be tapered in the same direction as the preliminary chamber.
- the separator being tapered in the same direction as the preliminary chamber means that the separator is able to be positioned partially inside of the preliminary chamber.
- the preliminary chamber helps to partially gather the filtering material before it enters the gathering chamber.
- the gathering chamber comprises an inlet joined to the outlet of the preliminary chamber, and the gathering chamber comprises an aperture for receiving the inserter.
- the gathering chamber may taper longitudinally from or after the end of the aperture to thereby gather the two or more sheets of filtering material around the additive release vessel to close the recess and thereby form a continuous rod comprising a longitudinally extending core of filtering material and one or more additive release vessels.
- the apparatus for separating and gathering two or more sheets of filtering material may be included as part of an apparatus for making a filter element.
- the gathering chamber may also be referred to as a gathering shoe.
- the preliminary chamber may also be referred to as a supporting shoe.
- Figure 1 is a schematic overview of the method of the present invention
- Figure 2 is a perspective view of part of the apparatus according to the present invention.
- Figure 3 is a side view of part of the apparatus according to the present invention in use
- Figure 4 is a rear view of part of the apparatus according to the present invention in use
- Figure 5 is a side view of the separator according to the present invention.
- Figure 6 is a perspective view of a filter element according to the present invention.
- Figure 7 is a sectional view of a filter element according to the present invention.
- Figure 8 is a perspective view of an apparatus for separating and gathering two or more sheets of filtering material.
- Figure 1 shows a schematic overview of the process of the present invention.
- Filtering material 104 is unwound from a reel 102 and advanced in a longitudinal direction L.
- the filtering material is a pre-cut sheet of paper filtering material comprising two individual sheets of paper filtering material wound onto the same reel 102. Each sheet has a width of 110mm, a thickness of 85 pm and a basis weight of 36 g/m 2 .
- the two sheets 104 advance together longitudinally in parallel. The longitudinal edge of one sheet abuts the longitudinal edge of the other sheet. It will be appreciated that more than two sheets of filtering material could be used, for example 3 or 4 or more sheets of longitudinally advancing filtering material. It will be appreciated that the two or more sheets of filtering material may be formed as part of the method of the invention. For example, a single sheet of filtering material could be advanced longitudinally and cut longitudinally into multiple sheets. It will be appreciated that a non-woven sheet material could also be used.
- the advancing sheets of filtering material 104 are embossed by an embosser 106.
- the embosser 106 comprises a rotating roller comprising spikes which protrude from the outer surface of the roller.
- the advancing sheets of filtering material are drawn between the roller and a flat surface or between the roller and a second smooth roller (as shown in figure 1 ) and the embossing roller embosses the sheets of filtering material.
- the applicant has found that embossing the sheets of filtering material leads to a desired pressure drop and leads to a dense or compact visual end appearance.
- the embossed sheets of filtering material are then advanced and flattened by a wire 108.
- the flattened sheets of filtering material are then separated by a separator in the form of a separator cone 110.
- the separated sheets of filtering material pass into a preliminary chamber 116, and the sheets remain separated as the two sheets are gathered together such that a recess is formed in the partially gathered rod of filtering material.
- the partially gathered rod of filtering material then passes into the gathering chamber 122 and one or more capsules are inserted into the recess in the partially gathered rod of filtering material by means of a capsule inserter 130 comprising a rotating wheel.
- the rod is then further gathered and condensed by the gathering chamber 122 to thereby close the recess and form a rod comprising a longitudinally extending core of filtering material and one or more additive release vessel within the core of filtering material.
- the rod is advanced in the longitudinal direction and is wrapped with an outer wrapper, such as a plug wrap to form a wrapped rod.
- the rod is wrapped with an outer wrapper using techniques known in the art.
- the wrapped rod is cut by a rod cutter 140 to form a filter element comprising a longitudinally extending core of filtering material comprising one or more additive release vessels located within the core of filtering material.
- the rod cutter is a standard rod cutter known in the art.
- the flattened tow 104 is advanced and before it enters the preliminary chamber 116 the two sheets are separated by the cone 110.
- the cone 110 comprises a first end 112 and a second end 114.
- the first end has a wider diameter than the second end such that the cone tapers longitudinally from the first end to the second end.
- the cone is formed from a metal.
- the cone 110 separates the two sheets of filtering material as these enter the preliminary chamber 116.
- the preliminary chamber 116 comprises an inlet 118 and an outlet 120.
- the inlet 118 has a larger diameter than the outlet 120 such that the preliminary chamber 116 tapers longitudinally from the inlet 118 to the outlet 120.
- the cone 110 is positioned partially within the preliminary chamber 116 such that part of the cone 110 protrudes out of and away from the inlet 118 of the preliminary chamber 116.
- the preliminary chamber 116 is formed from a metal.
- the cone 110 is fixed within the preliminary chamber 116 by a mechanical support. Before the sheets of filtering material are drawn into the preliminary chamber 116, the sheets are separated by the cone 110. As the sheets of filtering material are drawn into the preliminary chamber 116, the sheets remain separated by the cone 110, but as the filtering material advances longitudinally, the gap between the sheets reduces as the diameter of the cone 110 reduces. At the same time, the filtering material is partially gathered by the inner surfaces of the preliminary chamber 116. As the diameter of the preliminary chamber 116 decreases, the filtering material is gathered and condensed to form a partially gathered rod of filtering material. The cone 110 prevents complete gathering of the filtering material and leads to the formation of a recess in the partially gathered rod off filtering material. The applicant has found that the cone 110 keeps the folds of the sheet material apart such that the capsule can be placed into the centre of the partially gathered filtering material, so leading to improved capsule positioning.
- the partially gathered rod of filtering material is drawn into the gathering chamber in the form of gathering shoe 122.
- Gathering shoe 122 comprises an inlet 124 and an outlet (not shown.
- the inlet of the gathering shoe has a larger diameter than the outlet of the gathering shoe.
- the cross sectional diameter of the gathering shoe initially remains constant in a first section 126.
- the cross sectional diameter decreases such that the second section 127 is longitudinally tapered.
- a third section 128 has a constant cross sectional diameter. It will be appreciated that the gathering shoe may not include a third section 128.
- Positioned in a top surface of the gathering shoe is a longitudinally extending aperture which extends partially along the first section 126 and second section 127 of the gathering shoe. The aperture is configured to receive the capsule inserter wheel 130.
- the capsule inserter wheel 130 is fed by a hopper (not shown).
- the capsule inserter wheel is one known in the art.
- the capsule inserter wheel utilises a vacuum and air jet system to collect and insert the capsules into the longitudinally extending recess.
- a first wheel (not shown) comprises a plurality of grooves spaced equidistantly around its cylindrical surface.
- a hopper which contains the capsules, releases the capsules and the capsules are collected by the grooves in the first wheel.
- a vacuum pump applies suction to the grooves such that each groove collects a single capsule.
- a second smaller wheel 130 is positioned beneath the first wheel.
- the second wheel 130 comprises a plurality of grooves spaced equidistantly around its cylindrical surface.
- the capsules collected by the first wheel are transferred to the second wheel 130.
- the suction applied to that groove stops, and the capsule is transferred by gravity to a corresponding groove on the second wheel.
- the capsules are retained in the grooves of the second wheel 130 by suction applied by a vacuum pump.
- the bottom part of the second wheel 130 is positioned within the aperture of the gathering shoe 122. At the bottom of the travel path of a given groove, the suction applied to that particular groove is stopped and is replaced by a jet of air directed at the capsule to thereby release the capsule into the longitudinally extending recess.
- the capsule inserter wheel has radially extending cylindrical recesses spaced equidistantly around its cylindrical surface.
- the base of each recess is formed by the free end of a plunger or piston.
- Each piston is resiliently biased by a spring radially towards the centre of the wheel, but is movable radially outwards against this spring bias to sweep through the recess and so positively eject its contents.
- Sequential operation of the pistons or plungers as the wheel rotates clockwise is effected by means of stationary cam surface which engages with the radially inner end of the pistons or plungers over a portion of their travel path.
- each recess is filled with an individual frangible capsule from a hopper as the recesses pass around the top of their travel path.
- the pistons or plungers are operated by a cam surface to empty the capsules from the inserter wheel recesses, into the longitudinally extending recess of the advancing rod of partially gathered filtering material, at the bottom of the travel path of the recesses.
- the aperture in the gathering shoe 122 enables the capsule inserter wheel to extend into the gathering shoe 122 and thereby insert one or more capsule into the recess within the rod of partially gathered filtering material.
- the rotational speed of the capsule inserter 130 and the longitudinal speed of the advancing rod of partially gathered filtering material is constant so the capsules are inserted into the rod of partially gathered filtering material at regular intervals and so are positioned at regular intervals within the core of filtering material.
- the presence of a recess in the partially gathered rod of filtering material aids the placement of the one of more capsules and improves the capsule positioning within the finished filter element.
- the partially gathered rod continues to advance longitudinally and is further gathered by the walls of the gathering shoe.
- the partially gathered rod is further gathered and condensed such that the recess is closed and a longitudinally advancing rod comprising a longitudinally extending core of filtering material and one or more capsules is provided.
- Figure 8 shows an apparatus for separating and gathering two or more sheets of filtering material.
- the apparatus includes the same structure and components as described above with reference to figures 2 to 4, but the apparatus does not include a capsule inserter.
- Figure 5 shows a side view of the cone 1 10.
- the cone has a first end 112 which has a larger diameter than the second end 114.
- a first section of the cone extending from the first end 112 of the cone has a constant diameter.
- a second section of the cone extends from the first section and has a diameter that decreases from the first end of the second section to the second end of the second section, such that the second section is tapered.
- a final third section extends from the second end of the second section and includes a narrower and constant diameter.
- Figure 6 is a perspective view of a filter element according to the invention.
- the filter element 200 shown in figure 6 comprises a longitudinally extending core of filtering material 202 formed from two sheets of paper filtering material having a basis weight of 36 g/m 2 , a thickness of 85 pm and each sheet having a width of 110mm.
- the core 202 comprises a capsule 204 positioned centrally within the core.
- the capsule is a frangible capsule containing 2.5g of menthol in an oil carrier.
- the capsule has a diameter 3.35mm.
- the filter element 200 also includes a paper plug wrap 206 which surrounds the core and is secured by a lapped and stuck seam as is known in the art.
- the filter element has a circumference of 24mm and a length of 27mm.
- Figure 6 shows a perspective sectional view of the filter element 200 shown in figure 5.
- Figure 6 illustrates the structure of the capsule 204 which includes a capsule shell 208 comprising gelatine, and a liquid menthol flavourant solution 210 within the capsule shell. It will be appreciated that other flavourants may be contained in the capsule 204.
- the filter element shown in figures 5 and 6 may be made according to the method described above with reference to figures 1 to 4.
- the filter element 200 shown in figures 5 and 6 may be joined to a wrapped tobacco rod (not shown) to form a filtered smoking article, such as a filtered cigarette.
- the filter element 200 may be joined to the wrapped tobacco rod by ring tipping paper, in which the tipping paper engages around only the adjacent ends of the filter element and wrapped tobacco rod to thereby leave some of the plug wrap 206 exposed.
- the filter may joined by a full tipping overwrap which engages around the entire length of the filter element and the adjacent end of the wrapped tobacco rod.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
- Filtering Materials (AREA)
- Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)
Abstract
Description
Claims
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2021397869A AU2021397869A1 (en) | 2020-12-09 | 2021-12-08 | Method and apparatus for making a filter element |
| MX2023006771A MX2023006771A (en) | 2020-12-09 | 2021-12-08 | Method and apparatus for making a filter element. |
| JP2023559174A JP2023554199A (en) | 2020-12-09 | 2021-12-08 | Method and apparatus for manufacturing filter elements |
| KR1020237022438A KR20230125218A (en) | 2020-12-09 | 2021-12-08 | Method and Apparatus for Manufacturing Filter Elements |
| CA3201708A CA3201708A1 (en) | 2020-12-09 | 2021-12-08 | Method and apparatus for making a filter element |
| US18/256,833 US20240041103A1 (en) | 2020-12-09 | 2021-12-08 | Method and apparatus for making a filter element |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2019408.0 | 2020-12-09 | ||
| GBGB2019408.0A GB202019408D0 (en) | 2020-12-09 | 2020-12-09 | Method and apparatus for making a filter element |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2022123243A1 true WO2022123243A1 (en) | 2022-06-16 |
Family
ID=74166004
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/GB2021/053211 Ceased WO2022123243A1 (en) | 2020-12-09 | 2021-12-08 | Method and apparatus for making a filter element |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20240041103A1 (en) |
| EP (1) | EP4011221A1 (en) |
| JP (1) | JP2023554199A (en) |
| KR (1) | KR20230125218A (en) |
| CN (2) | CN114601196A (en) |
| AU (1) | AU2021397869A1 (en) |
| CA (1) | CA3201708A1 (en) |
| GB (1) | GB202019408D0 (en) |
| MX (1) | MX2023006771A (en) |
| TW (1) | TW202235012A (en) |
| WO (1) | WO2022123243A1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120065042A1 (en) * | 2009-03-09 | 2012-03-15 | Gerhard Malan Le Roux | Apparatus for Introducing Objects into Filter Rod Material |
| US20120080043A1 (en) * | 2009-04-09 | 2012-04-05 | Rene Naenen | Introducing Objects Into Elongate Smoking Articles |
| US20150018187A1 (en) * | 2012-03-05 | 2015-01-15 | Montrade S.R.L. | Method and device for supplying filter material to a filter rod forming machine |
| EP2868215A2 (en) * | 2013-10-30 | 2015-05-06 | HAUNI Maschinenbau AG | Device and method for making a filter rod free of wrapping material and format unit and guide mandrel for use in this device |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1592952A (en) * | 1976-11-02 | 1981-07-15 | Cigarette Components Ltd | Smoke filter and process |
| JPH11243939A (en) * | 1998-02-27 | 1999-09-14 | Japan Tobacco Inc | Filter for tobacco product |
| JP5164217B2 (en) * | 2006-04-20 | 2013-03-21 | 日本たばこ産業株式会社 | Menthol delivery system for charcoal filter cigarette |
| ZA200905994B (en) * | 2009-08-28 | 2014-05-28 | Tobacco Res And Dev Inst (Pty) Ltd | Filter rod maker |
| US20110180084A1 (en) * | 2010-01-27 | 2011-07-28 | R.J. Reynolds Tobacco Company | Apparatus and associated method for forming a filter component of a smoking article |
| US9049887B2 (en) * | 2010-03-26 | 2015-06-09 | Philip Morris Usa Inc. | Apparatus and method for loading cavities of plug space plug filter rod |
| IT1408375B1 (en) * | 2010-10-20 | 2014-06-20 | Gd Spa | UNIT AND METHOD OF FEEDING ELEMENTS OF ADDITIVES OF FIBER MATERIAL IN A MACHINE FOR THE PRODUCTION OF SMOKE ITEMS |
| RU2672941C1 (en) * | 2015-09-29 | 2018-11-21 | Бритиш Американ Тобакко Мексико, С.А. Де С.В. | Tipping paper web |
| CN106942788B (en) * | 2017-04-26 | 2023-06-20 | 云南中烟工业有限责任公司 | Composite filter rod with through-type conical cavity structure and manufacturing method thereof |
| IT201800009608A1 (en) * | 2018-10-19 | 2020-04-19 | Gd Spa | Line and method of production of bar-shaped items from the tobacco industry |
| CN111329107A (en) * | 2020-03-13 | 2020-06-26 | 南通烟滤嘴有限责任公司 | Filter stick without wrapping paper and with continuous closed cavity, forming equipment and forming process |
-
2020
- 2020-12-09 GB GBGB2019408.0A patent/GB202019408D0/en not_active Ceased
-
2021
- 2021-05-28 CN CN202110591693.6A patent/CN114601196A/en active Pending
- 2021-06-24 EP EP21181456.1A patent/EP4011221A1/en active Pending
- 2021-10-12 CN CN202122449842.3U patent/CN217407771U/en active Active
- 2021-12-03 TW TW110145226A patent/TW202235012A/en unknown
- 2021-12-08 CA CA3201708A patent/CA3201708A1/en active Pending
- 2021-12-08 US US18/256,833 patent/US20240041103A1/en active Pending
- 2021-12-08 MX MX2023006771A patent/MX2023006771A/en unknown
- 2021-12-08 KR KR1020237022438A patent/KR20230125218A/en active Pending
- 2021-12-08 JP JP2023559174A patent/JP2023554199A/en active Pending
- 2021-12-08 AU AU2021397869A patent/AU2021397869A1/en not_active Abandoned
- 2021-12-08 WO PCT/GB2021/053211 patent/WO2022123243A1/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120065042A1 (en) * | 2009-03-09 | 2012-03-15 | Gerhard Malan Le Roux | Apparatus for Introducing Objects into Filter Rod Material |
| US20120080043A1 (en) * | 2009-04-09 | 2012-04-05 | Rene Naenen | Introducing Objects Into Elongate Smoking Articles |
| US20150018187A1 (en) * | 2012-03-05 | 2015-01-15 | Montrade S.R.L. | Method and device for supplying filter material to a filter rod forming machine |
| EP2868215A2 (en) * | 2013-10-30 | 2015-05-06 | HAUNI Maschinenbau AG | Device and method for making a filter rod free of wrapping material and format unit and guide mandrel for use in this device |
Also Published As
| Publication number | Publication date |
|---|---|
| TW202235012A (en) | 2022-09-16 |
| AU2021397869A1 (en) | 2023-07-06 |
| CN217407771U (en) | 2022-09-13 |
| JP2023554199A (en) | 2023-12-26 |
| KR20230125218A (en) | 2023-08-29 |
| CN114601196A (en) | 2022-06-10 |
| GB202019408D0 (en) | 2021-01-20 |
| CA3201708A1 (en) | 2022-06-16 |
| EP4011221A1 (en) | 2022-06-15 |
| US20240041103A1 (en) | 2024-02-08 |
| MX2023006771A (en) | 2023-08-14 |
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