WO2022146351A1

WO2022146351A1 - A package paper which is suitable for contact with food

Info

Publication number: WO2022146351A1
Application number: PCT/TR2021/051457
Authority: WO
Inventors: Duygu BAGBAKAR ORHAN; Nalan OZGUR SAGLAM
Original assignee: Modern Karton Sanayi Ve Ticaret AS
Current assignee: Modern Karton Sanayi Ve Ticaret AS
Priority date: 2020-12-28
Filing date: 2021-12-22
Publication date: 2022-07-07
Anticipated expiration: 2023-06-28
Also published as: EP4267795B1; EP4267795A1; TR202021876A2; EP4267795A4

Abstract

The present invention relates to a package paper produced from waste papers which are suitable for recycling, and the production process of package paper. The package paper has a barrier on its surface, said barrier is provided with a mixture comprising a starch aqueous solution which has dry starch at a proportion at least between 3% and 6% by weight of waste paper in a manner preventing oil permeability from one side to the other side, and a chemical material which has perfluoroalkyl group in cationic structure at a proportion between 0.2% and 0.6% by weight of paper.

Description

A PACKAGE PAPER WHICH IS SUITABLE FOR CONTACT WITH FOOD

TECHNICAL FIELD

The present invention relates to a package paper obtained from waste papers which are suitable for recycling, and the production process of package paper.

PRIOR ART

As a result of growth in population in Turkey and as well as, in the world, paper usage increases but forest areas decrease which are the primary fiber source. As the primary fiber source decreases, the usage and the importance of management of secondary fiber sources increase. Since the amount of waste paper collected in Turkey is not sufficient, waste paper is imported from abroad for sustaining paper production. The amount of collected waste paper in Turkey was 2.41 million tones between years 2014-2017, the amount of importation which has been 183 thousand tones in year 2014 has increased in time and it has been 753 thousand tones in year 2017. Because of hygiene, easy storage, low-cost, easy and rapid supply, corrugated cardboard package products are increasingly preferred. At the end of year 2017, corrugated cardboard has 56.9% of the paper-carton production capacity with the amount of corrugated cardboard equal to 2.94 million tones.

Corrugated cardboard is the general name given to papers formed by coating the under and/or top surfaces of one or more than one corrugated layer by means of a flat layer and used in production of package boxes and external parcels. Recycled paper is used in most of corrugated cardboard production. As the paper raw material in the world, waste papers are used with proportion of 70-75% and cellulose is used with proportion of 25-30%. It is estimated that half of the fibers used in paper production in the world is recycled and used again. In Turkey, the total of recycled paper used for paper production has reached 3.16 million tones in year 2017, and recycled paper has been used which is equal to 72.7% of paper production.

Recycled paper, which can be used as package material in almost every sector and which has a high share as mentioned above, cannot be used as package material which contacts with food within the scope of the Turkish Food Codex, Regulation of Substances and Materials Which Contact With Food. As a result, because of the abovementioned problems, an improvement is required in the related technical field.

BRIEF DESCRIPTION OF THE INVENTION

The present invention relates to a package paper which is suitable for contact with food and the production process of package paper, for eliminating the abovementioned disadvantages and for bringing new advantages to the related technical field.

An object of the present invention is to provide a process for producing a package paper by making waste papers, which are suitable for recycling, suitable for contact with food.

An object of the present invention is to provide a package paper which has been made suitable for contact with food from and produced from waste paper which is suitable for recycling and at the same time which does not allow oil permeability.

An object of the present invention is to provide a package paper for corrugated boxes used for short-duration carrying of fatty foods.

An object of the present invention is to provide a package paper which is suitable for contact with food and which has reduced cost and which is environment-friendly.

In order to realize the abovementioned objects and the objects which are to be deducted from the detailed description below, the present invention is a package paper obtained from waste papers which are suitable for recycling. Accordingly, the improvement of the present invention is that the package paper has a barrier on its surface, said barrier is provided with a mixture comprising a starch aqueous solution which has dry starch at a proportion at least between 3% and 6% by weight of waste paper in a manner preventing oil permeability from one side to the other side, and a chemical material which has perfluoroalkyl group in cationic structure at a proportion between 0.2% and 0.6% by weight of paper.

In a possible embodiment of the present invention, the chemical material is perfluorohexylethyl methacrylate, 2-N,N-diethylaminoethyl methacrylate, 2-hydroxyethyl methacrylate and 2,2’-ethylenedioxydiethyl dimethacrylate, malic acid salt copolymer.

In a possible embodiment of the present invention, the proportion of dry starch in starch aqueous solution is 12-15%. In a possible embodiment of the present invention, the viscosity of starch aqueous solution at speed of 100 rpm by means of rod with no 2 in Brookfield device is between 80 cp and 100 cp.

In another possible embodiment of the present invention, dry starch is provided at a proportion of 4% of the waste paper by weight in starch aqueous solution, and chemical material is provided at a proportion of 0.35% of waste paper by weight.

In another possible embodiment of the present invention, the mixture comprises adhesive such that there is water repellent characteristic for printing process.

The present invention is moreover a process for obtaining a package paper from waste papers which are suitable for recycling and comprising steps of making waste paper into fiber mixture form, diluting the fiber mixture and making into paper sheet form, and afterwards, drying in a first drying section. Accordingly, said improvement is that in order to provide a barrier on the surface of package paper in a manner preventing oil permeability from one side to the other side, a mixture, which comprises a starch aqueous solution including dry starch at a proportion between 3% and 6% by weight of waste paper and a chemical material which has perfluoroalkyl group in cationic structure at a proportion between 0.2% and 0.6% by weight of waste paper, is applied to the dried waste paper which is in paper sheet form having dry substance proportion between 85-90% by weight in a film press section.

In another possible embodiment of the present invention, the process is realized by coating the mixture to the paper sheet with the help of sizer rods.

In another possible embodiment of the present invention, natural corn starch, which is cooked by modifying with enzyme, is used as dry starch.

In another possible embodiment of the present invention, the fiber mixture is subjected to refiner press and fibrillation process, such that Schopper riegler value of waste paper is between 40 and 45, in a refiner unit in accordance with the refining level of waste paper.

In another possible embodiment of the present invention, adhesive is applied with the mixture to the waste paper which is in paper sheet form in order to provide water repellent characteristic for printing to the package paper. BRIEF DESCRIPTION OF THE FIGURES

In Figure 1 , a representative view of the production process of the subject matter package paper is given.

REFERENCE NUMBERS

10 Pulp unit

20 Refiner unit

30 Wire unit

40 Press unit

50 First drying section

60 Film press section

70 Second drying section

80 Reel unit

DETAILED DESCRIPTION OF THE INVENTION

In this detailed description, the subject matter package paper which is suitable for contact with food and the production process of package paper are explained with references to examples without forming any restrictive effect only in order to make the subject more understandable.

The subject matter package paper is obtained by subjecting the waste papers, which are suitable for recycling, to the process steps which shall be hereunder described.

In the first step, waste papers are disintegrated with water in a pulp unit (10) and are made into paper pulp form. Then, the paper pulp is cleaned by being passed through coarse screening and fine screening processes. The cleaned paper pulp is separated as long fiber and as short fiber in accordance with fiber lengths in pulp towers. Long fibers and short fibers are mixed with predetermined proportions and a fiber mixture is obtained. The fiber mixture is fibrillated in a refiner unit (20) and water retention and binding characteristics are increased. If the refining level of the waste paper is high during recycling, there may remain no need for the refiner press. If less amount of refined waste paper is used, refiner press is realized more. At the end of refiner press, the predetermined paper porosity must be reached. For white package paper, Schopper riegler value, which shows the freeness degree of the paper pulp and the drainage speed, is obtained as approximately 45 at the end of refiner press process. For brown package paper, Schopper riegler value is obtained approximately as 40. At the end of refining process realized in the refiner unit (20) for the waste paper, Schopper riegler value is provided between 40 and 45.

The diluted fiber mixture for forming wet paper sheet under a specific inner pressure in the pulp frame in the pulp unit (10) is sent onto long or short wire in a wire unit (30) by means of water jet method. Afterwards, the excessive water, which exists on the fiber mixture, is drained by vacuum. After paper sheet begins to be formed on the wire, it is carried on the felts, and the excessive water, which remains on the paper sheet, is removed by the pressure in a press unit (40). Thus, paper sheet is obtained where the dry weight thereof is between 50-55% by weight. In the preferred application, the proportion of dry weight of waste paper, which is in paper sheet form, is provided as 52%. The waste paper, where the dry weight proportion has reached a specific level, passes through drying cylinders at a first drying section (50) and the weight proportion of dry substance increases. The proportion of dry weight of waste paper has increased to between 85-90% by weight at the end of the first drying section (50).

In the next step, resistance and barrier characteristics are provided to the waste paper, which is in paper sheet form, in a film press section (60). In other words, characteristics are provided which shall prevent at least oil permeability from one side to the other side of the package paper. This process is realized by means of applying of starch onto the paper sheet surface with the help of sizer rods. Natural corn starch is used which has been cooked by modifying with enzyme. The proportion of starch in aqueous solution has been determined as 12-15%, and a starch aqueous solution with this concentration is used. In the preferred application, the concentration of starch aqueous solution is 14%. When the viscosity of starch aqueous solution is measured at speed of 100 rpm by means of rod with no 2 in Brookfield device, a value of 80-100 cp is obtained. Moreover, the proportion of dry starch, which exists in the starch aqueous solution, to the dry waste paper is determined as 3-6% by weight. In the preferred application, the starch aqueous solution is used such that its weight proportion to waste paper is 4%. Meanwhile, in order to be able to use waste paper as a package paper so as to be suitable for contact with food, the barrier chemical is applied to the paper sheet with the help of starch, and a barrier is formed on the surface of the produced package paper.

As the barrier chemical, polymeric barrier chemicals, based on fluorocarbon with 6 carbons and with cationic, anionic structure, and barrier chemicals, which do not include fluorine, have been tested. As the barrier chemical, a chemical comprising cationic perfluoroalkyl group is used. The barrier chemical used in the preferred application is perfluorohexylethyl methacrylate, 2-N,N-diethylaminoethyl methacrylate, 2-hydroxyethyl methacrylate and 2,2’- ethylenedioxydiethyl dimethacrylate, malic acid salt copolymer. CAS Registration number of the barrier chemical is 1225273-44-8 (copolymer of perfluorohexylethyl methacrylate, 2-N,N- diethylaminoethyl methacrylate, 2-hydroxyethyl methacrylate, and 2,2'-ethylenedioxydiethyl dimethacrylate, malic acid salt).

The weight proportion of the barrier chemical to the waste paper is provided between 0.2% and 0.6%. In the preferred application, the barrier chemical is used such that its weight proportion to the waste paper is 0.35%. A mixture is formed with starch and barrier chemical in the process detail, and said mixture is applied to the paper sheet. Such a mixture provides oil barrier characteristic to the package paper which is to be formed. Adhesive and water barrier can also be provided in the mixture accordingly. Since the adhesive and the water barrier are provided, the package paper can also have oil barrier characteristic and moreover, the water barrier can have water repellent characteristic for printing.

In the preferred application, since the waste paper, which is in paper sheet form and which enters the film press section (60), has 10% moisture, it has been determined that the applied mixture stays in the best manner on the paper sheet surface.

After application of the mixture on the paper sheet and after the paper sheet is brought to the desired characteristics, drying process is applied in a second drying section (70). At the end of the second drying section (70), the dry weight proportion of the paper sheet is increased to between 91% and 93% by weight. At the end of these steps, the waste paper is made into a package paper form which is suitable for contact with food. The package paper is finally wrapped in a reel unit (80) as buffer paper roll.

Staying of the mixture, comprising barrier chemical, on the surface of the package paper without penetrating into the package paper, is an important criterion for being suitable to contact with food and thus for not permeate oil, and as also mentioned above, this is produced by decreasing paper porosity by means of refiner press setting.

The tests of the package paper, which details are given above, have been made in laboratory scale and it has been detected whether it penetrates water and oil or not and whether the barrier is suitable or not. Accordingly, the recipe of the barrier mixture and the suitable process conditions have been determined. The tests have been realized in accordance with Tappi T559 - Grease Resistance Test for Paper and Paperboard test method. In Table 1 , the test results have been given in the case where the barrier chemical, with the details as given above, is used.

Table 1 - Laboratory Test Results for Package Paper

By means of the parameters given in Table 1 and given in process details, it has been determined that water does not penetrate for 15 seconds and warm oil does not penetrate for 15 seconds and hot oil at 55^eC does not penetrate for 20 minutes from one side to the other side of the package paper.

By means of a package paper provided in this manner, corrugated boxes are formed which are used for carrying fatty foods. During carrying of pizza, lahmacun, pita, etc, there is no oil permeability in the package paper. Moreover, in case adhesive is applied, the package paper does not permit water penetration.

Package papers are used in pizza box production and tester pizza boxes are produced and permeability has been observed by means of carrying with carrying bags during the pizza order delivery duration of approximately 30 minutes. Making comparison also with pizza boxes produced by means of original Craft facilitates optimization of the parameters.

Moreover, said package papers are also used in formation of the necessary corrugated boxes for carrying oily machine equipment besides the food sector.

The protection scope of the present invention is set forth in the annexed claims and cannot be restricted to the illustrative disclosures given above, under the detailed description. It is because a person skilled in the relevant art can obviously produce similar embodiments under the light of the foregoing disclosures, without departing from the main principles of the present invention.

Claims

CLAIMS A package paper produced from waste papers which are suitable for recycling, wherein the subject matter package paper has a barrier on its surface, said barrier is provided with a mixture comprising a starch aqueous solution which has dry starch at a proportion at least between 3% and 6% by weight of waste paper in a manner preventing oil permeability from one side to the other side, and a chemical material which has perfluoroalkyl group in cationic structure at a proportion between 0.2% and 0.6% by weight of waste paper. The package paper according to claim 1 , wherein the chemical material is perfluorohexylethyl methacrylate, 2-N,N-diethylaminoethyl methacrylate, 2- hydroxyethyl methacrylate and 2,2’-ethylenedioxydiethyl dimethacrylate, malic acid salt copolymer. The package paper according to claim 1 , wherein the proportion of dry starch in starch aqueous solution is 12-15%. The package paper according to claim 1 , wherein the viscosity of starch aqueous solution at speed of 100 rpm by means of rod with no 2 in Brookfield device is between 80 cp and 100 cp. The package paper according to claim 1 , wherein dry starch is provided at a proportion of 4% of the waste paper by weight in starch aqueous solution, and chemical material is provided at a proportion of 0.35% of waste paper by weight. The package paper according to claim 1 , wherein the mixture comprises adhesive such that there is water repellent characteristic for realizing press. A process for obtaining a package paper from waste papers which are suitable for recycling and comprising steps of making waste paper into fiber mixture form, diluting the fiber mixture and making into paper sheet form, and afterwards, drying in a first drying section (50), wherein in order to provide a barrier on the surface of package paper in a manner preventing oil permeability from one side to the other side, a mixture, which comprises a starch aqueous solution including dry starch at a proportion between 3% and 6% by weight of waste paper and a chemical material which has perfluoroalkyl group in cationic structure at a proportion between 0.2% and

0.6% by weight of waste paper, is applied to the dried waste paper which is in paper sheet form having dry weight proportion between 85-90% by weight in a film press section (60). 8. The process according to claim 7, wherein the process is realized by coating the mixture to the paper sheet with the help of sizer rods.

9. The process according to claim 7, wherein natural corn starch, which is cooked by modifying with enzyme, is used as dry starch.

10. The process according to claim 7, wherein the fiber mixture is subjected to refiner press and fibrillation process, such that Schopper riegler value of waste paper is between 40 and 45, in a refiner unit (20) in accordance with the refining level of waste paper.

11. The process according to claim 7, wherein adhesive is applied together with the mixture to the waste paper which is in paper sheet form in order to provide water repellent characteristic for printing to the package paper.