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WO2021208060A1 - Gas supply device, use thereof for lightening hair color and method - Google Patents

Gas supply device, use thereof for lightening hair color and method Download PDF

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Publication number
WO2021208060A1
WO2021208060A1 PCT/CN2020/085297 CN2020085297W WO2021208060A1 WO 2021208060 A1 WO2021208060 A1 WO 2021208060A1 CN 2020085297 W CN2020085297 W CN 2020085297W WO 2021208060 A1 WO2021208060 A1 WO 2021208060A1
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Prior art keywords
gas supply
supply device
hair
peroxide
metal
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PCT/CN2020/085297
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French (fr)
Chinese (zh)
Inventor
曹荣华
王婷嬅
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TO2M Corp
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TO2M Corp
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Priority to PCT/CN2020/085297 priority Critical patent/WO2021208060A1/en
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition

Definitions

  • the invention relates to a gas supply device for lightening hair color, and the use of the device.
  • the primary hair color of the hair is mainly related to the melanin produced in the hair follicles of the scalp.
  • Melanin can be divided into eumelanin and pheomelanin, which is processed by tyrosinase through tyrosinase.
  • Asian scalp hair follicles mainly produce eumelanin, so their hair color appears black; while for Westerners with reddish brown hair, their scalp hair follicles mainly produce dark brown pigment, making their hair red. brown.
  • hydrogen peroxide will gradually accumulate in the hair follicles.
  • Hair color can be effectively changed by dyeing hair.
  • the dyes currently used in hair dyeing are all in liquid or gel state, which can easily touch the scalp and cause discomfort.
  • the operation steps are lengthy, complicated, and even costly.
  • hair coloring agents often involve the use of chemicals that can remove, replace, and hide the pigments in natural hair.
  • the use of these chemicals can cause a series of adverse effects, including skin irritation and allergies, hair breakage, and poor hair quality.
  • IARC International Agency for Research on Cancer
  • an object of the present invention is to provide a method of lightening hair color that is easy to operate, low-cost, and does not use liquid or colloidal chemical dyes, so as to prevent chemical dyes from causing damage to hair and skin. Damage, but also has the effect of changing hair color.
  • the present invention provides a gas supply device for lightening hair color, which includes a separation layer and a functional unit wrapped in the separation layer, wherein the functional unit includes a metal peroxide, an activator, and catalyst.
  • the separation layer can be a single layer or a composite layer; the material of the separation layer can be a gas-permeable material or a gas-impermeable material; the materials on both sides of the separation layer can be inconsistent.
  • the metal peroxide in the functional unit includes calcium peroxide, magnesium peroxide, sodium peroxide, or potassium peroxide.
  • the activator in the functional unit is an acyl compound selected from the group consisting of tetraacetyl ethylene diamine (TAED), sodium nonanoyloxybenzene sulfonate (NOBS), tetraacetyl glycoluril, The group consisting of pentaacetyl glucose, N-acetyl phthalimide, 1-acetyl ethyl benzoate, triacetyl ethanolamine and nonanoyl acetophenone sulfonate.
  • TAED tetraacetyl ethylene diamine
  • NOBS sodium nonanoyloxybenzene sulfonate
  • tetraacetyl glycoluril The group consisting of pentaacetyl glucose, N-acetyl phthalimide, 1-acetyl ethyl benzoate, triacetyl ethanolamine and nonanoyl acetophenone sulfonate.
  • the catalyst in the functional unit is catalase.
  • the gas supply device is a device for the head.
  • the gas supply device is a device for the trunk or limbs.
  • the gas supply device provided by the present invention may further include a component that generates carbon dioxide or/and a component that generates nitric oxide, so as to improve the efficiency of lightening the hair color.
  • the carbon dioxide generating component includes solid acid and solid sodium bicarbonate or metal carbonate; the solid acid is lactic acid or/and citric acid; and the metal carbonate includes magnesium carbonate, calcium carbonate, sodium carbonate or potassium carbonate.
  • the nitric oxide generating component includes a metal unit and a nitric acid wrapping unit; wherein the nitric acid wrapping unit seals the nitric acid in it, and the nitric acid wrapping unit can be destroyed to release the nitric acid, and the nitric acid is dilute nitric acid; wherein ,
  • the metal unit is selected from the group consisting of sodium, magnesium, aluminum, zinc, iron, tin, lead, copper, silver and combinations thereof; wherein the nitric acid coating unit is a metal composite film with a high gas and water barrier ,
  • the inner layer is a polymer film, and the outer layer is a metal film.
  • the nitric oxide generating component may further include a deoxidizer, a super absorbent polymer, an activator, or a catalyst; the deoxidizer includes an iron-based deoxidizer, a sulfite-based deoxidizer, or a hydrogenation catalyst type Deoxidizer.
  • the polymer film is selected from polyethylene, polypropylene, polyethylene terephthalate (PET), PET aluminized film, PET coated polysilazane, cast polypropylene film ( CPP), CPP aluminized film, Al2O3 composite PET/CPP, copolyester plastics and combinations thereof.
  • the material of the metal film is selected from the group consisting of sodium, magnesium, aluminum, zinc, iron, tin, lead, copper, silver, and combinations thereof.
  • the gas supply device provided by the present invention may further include a component for generating hydrogen.
  • the hydrogen generating component includes (1) metal hydroxide or metal peroxide and aluminum powder, (2) hydride, or (3) a combination of the two.
  • the weight ratio of functional unit: carbon dioxide generating component is 1:10-10:1; wherein, the weight ratio of functional unit: nitric oxide generating component is 1:10-10:1; Among them, the weight ratio of functional unit: hydrogen-generating component is 1:10-10:1.
  • the gas supply device as described above may further include at least one pipe connected to the separation layer.
  • Step 1 Place the gas supply device in the head wear device
  • the provided gas supply device supplies active oxygen to the scalp and hair, which reduces the color of black hair and achieves the effect of changing the color of the hair.
  • Another object of the present invention is to provide a method for eliminating hair dyes that is simple to operate, low-cost, and relatively free of side effects.
  • the method for lightening hair color provided by the present invention does not irritate hair and skin, and does not cause allergic reactions, and the cost is lower than the chemical dyes used in the past, the operation is relatively simple, and the hair color can be effectively changed.
  • the present invention also discloses a head wear device or hairdressing equipment that can be used to lighten hair color.
  • the head wear device can put the scalp or hair in an oxygen and other gas environment, and be close to the skin, so that the oxygen or other gas can be easily absorbed by the hair follicles, and has the advantage of being portable.
  • the hairdressing equipment allows the user's hair and scalp to be in an oxygen and other gas environment during the hairdressing process, so as to perform hairdressing and lighten hair color at the same time, and the gas environment also has the effect of promoting the growth of hair follicles.
  • Fig. 1 is a schematic diagram of the gas supply device of the present invention.
  • Figure 2 is an exploded view of the gas supply device of the present invention.
  • Fig. 3 is a cross-sectional view of the gas supply device of the present invention.
  • Fig. 4 is a schematic diagram of a hood including a gas supply device.
  • Fig. 6 is a cross-sectional view of the gas supply device of the third embodiment.
  • Fig. 7 is a cross-sectional view of another gas supply device of the third embodiment.
  • Fig. 8 is a cross-sectional view of the gas supply device of the fourth embodiment.
  • Fig. 9 is a schematic diagram of the gas supply device of the present invention being equipped with a duct.
  • Fig. 10 is a schematic diagram of the gas supply device of the present invention installed in a hairdressing equipment.
  • Fig. 11 is a view of the use state of the hood actually worn on the gas supply device.
  • Figure 12 is a photograph of the hair color of the subject of Example 1 before use.
  • Figure 13 is a photograph of the hair color of the subject of Example 1 after use.
  • 1-gas supply device 11-separation layer; 111-permeable structure; 12-functional unit; 13-carbon dioxide-generating component; 14-metal unit; 141-nitric acid wrapping unit; 15-hydrogen-generating component; 16-pipe.
  • primary hair color in this manual refers to the color of the hair grown from healthy, undamaged, and aging hair follicles after mature individual development. Hair color can vary depending on the ability of each individual's healthy hair follicle to produce pigment different.
  • diluted hair color in this specification refers to changing the hair color to a lighter color system than the original hair color. For example, black hair turns into brown hair, and the color change varies depending on the original hair color or the degree of use.
  • the present invention provides a gas supply device 1 for lightening hair color, as shown in FIGS. 1-3, which includes a separation layer 11 and a functional unit 12 wrapped in the separation layer 11.
  • the separation layer 11 may be a single layer or a composite layer.
  • the material of the separation layer 11 may be a gas-permeable material or a gas-impermeable material.
  • the side of the separation layer 11 close to the user is a gas-permeable structure 111 to allow gas to enter and exit, and the materials on both sides of the separation layer 11 may be inconsistent.
  • the functional unit 12 includes a metal peroxide, an activator, and a catalyst. Metal peroxides include calcium peroxide, magnesium peroxide, sodium peroxide, or potassium peroxide.
  • the activator in the functional unit 12 is an acyl compound selected from the group consisting of tetraacetylethylenediamine (TAED), sodium nonanoyloxybenzene sulfonate (NOBS), tetraacetylglycoluril, five Acetyl glucose, N-acetyl phthalimide, 1-acetyl ethyl benzoate, triacetyl ethanolamine and nonanoyl acetophenone sulfonate.
  • the catalyst in the functional unit 12 is catalase.
  • the present invention provides a use for lightening hair color, using a gas supply device 1 to supply active oxygen to the scalp and hair, wherein the active oxygen has the effect of promoting the lightening of the hair color and can promote the growth of the hair.
  • the functional unit 12 can interact with the water vapor in the environment or the water vapor emitted by the human body to generate active oxygen. It can also prepare an aqueous liquid for its effect.
  • the reaction equation is as follows:
  • Hydrogen peroxide anion is a nucleophile, which can cause hydrogen peroxide to form free radicals:
  • the nitric acid coating unit 141 when needed, can be destroyed to release the dilute nitric acid.
  • the dilute nitric acid meets the metal unit 14, it can react to produce nitric oxide, and the reaction is as follows:
  • X is magnesium, aluminum, zinc, iron, tin, lead, or copper
  • Y is aluminum, iron, or copper
  • Z is sodium or silver
  • nitric acid is dilute nitric acid
  • the weight ratio of nitric acid to water is 1:3-1:20, preferably 1:4-1:6, most preferably 1:5.
  • nitric oxide has the functions of expanding capillaries and accelerating blood flow, so as to accelerate the gas (oxygen) exchange rate. Therefore, this embodiment uses nitric oxide to work together to accelerate the reaction to obtain Better fade hair color effect.
  • the metal hydroxide can react with the aluminum powder to generate hydrogen, as in the following reactions:
  • Embodiment 6 Gas supply device including conduit
  • Step 2 Wear the head wear device for 1-4 hours in the position where you want to lighten your hair color
  • this method can spray a little water on the gas supply device before use to speed up the reaction.
  • the method for lightening hair color provided by the present invention can be used with a head wear device or hairdressing equipment.
  • the head wear device provided by the present invention has the advantage of being portable, allowing users to dye hair at any time; while the hairdressing equipment provided by the present invention allows users to dye hair at the same time during the hairdressing process, saving The advantage of time.

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Abstract

Provided is a gas supply device (1) for lightening hair color, comprising a separating layer (11) and a functional unit (12) encased in the separating layer (11), wherein the functional unit (12) comprises a metal peroxide, an activator and a catalyst. The gas supply device (1) further comprises components for generating carbon dioxide, nitric oxide or/and hydrogen. Also provided are a use of the gas supply device (1) for lightening hair color and a method, comprising supplying oxygen to the scalp and hair and further reacting to produce activated oxygen. Further provided is a method for eliminating dye from hair by using the gas supply device (1).

Description

气体供应装置、用于淡化发色的用途及方法Gas supply device, use and method for lightening hair color 技术领域Technical field

本发明涉及淡化发色的气体供应装置,以及该装置的用途。The invention relates to a gas supply device for lightening hair color, and the use of the device.

背景技术Background technique

头发颜色是现代人很在意的问题,时下越来越多年轻人会进行染发,以改变原有发色,其视为一种时尚、流行,而年纪稍长之人则因发色变白会影响到外观与自信,亦会寻求染发方式,以改善白头发的问题。Hair color is a problem that modern people are very concerned about. Nowadays, more and more young people will dye their hair to change the original hair color. Affect the appearance and self-confidence, will also look for ways to dye hair to improve the problem of gray hair.

头发的原生发色主要与头皮毛囊中所制造的黑色素有关,黑色素可分为真黑色素(eumelanin)及黑褐色素(pheomelanin),其通过酪胺酸酶(tyrosinase)将酪胺酸(tyrosine)进行一连串的反应所生成,亚洲人的头皮毛囊主要制造真黑色素,因此发色呈现黑色;而红褐发色的西方人,其头皮毛囊则是以制造黑褐色素为主,使其头发颜色呈现红褐色。随着年纪的增长,毛囊中会逐渐累积过氧化氢,过氧化氢会抑制参与黑色素形成的酪胺酸酶活性,造成毛囊中的黑色素产量下降,进而导致新生成的头发以白色呈现,亦即所谓的白发。The primary hair color of the hair is mainly related to the melanin produced in the hair follicles of the scalp. Melanin can be divided into eumelanin and pheomelanin, which is processed by tyrosinase through tyrosinase. As a result of a series of reactions, Asian scalp hair follicles mainly produce eumelanin, so their hair color appears black; while for Westerners with reddish brown hair, their scalp hair follicles mainly produce dark brown pigment, making their hair red. brown. As the age grows, hydrogen peroxide will gradually accumulate in the hair follicles. Hydrogen peroxide inhibits the activity of tyrosinase involved in the formation of melanin, causing the melanin production in the hair follicles to decrease, which in turn causes the newly formed hair to appear white, that is, The so-called gray hair.

通过染发可以有效改变头发的发色,然而目前于染发时所使用的染剂皆为液体或胶体状态,使用上易接触到头皮造成不舒适感,且操作步骤冗长、复杂,甚至成本也较高。另一方面,毛发染色剂经常涉及使用能够去除、替换、遮掩天然毛发内色素的化学物质,而这些化学物质的使用可导致一系列的不良影响,包括皮肤刺激和过敏、头发断裂、发质变差及皮肤变色等问题,且根据国际癌症研究机构(IARC)研究数据表明,在毛发染色过程中使用的一些染料和化学物质被认为会提高细胞突变和致癌的风险。Hair color can be effectively changed by dyeing hair. However, the dyes currently used in hair dyeing are all in liquid or gel state, which can easily touch the scalp and cause discomfort. The operation steps are lengthy, complicated, and even costly. . On the other hand, hair coloring agents often involve the use of chemicals that can remove, replace, and hide the pigments in natural hair. The use of these chemicals can cause a series of adverse effects, including skin irritation and allergies, hair breakage, and poor hair quality. According to research data from the International Agency for Research on Cancer (IARC), some dyes and chemicals used in the hair dyeing process are believed to increase the risk of cell mutation and carcinogenesis.

因此,本领域亟需寻找一种操作简便、成本较低且相对无不良副作用的染发方式,以改善化学物质染剂对人体造成伤害的风险。Therefore, there is an urgent need in the art to find a hair dyeing method that is easy to operate, low cost, and relatively free of adverse side effects, so as to improve the risk of harm to the human body caused by chemical dyes.

另外,在毛发染色后,时常会有人不满意染色后的结果,此时需等待头发重新长出,以变回原生的发色,因此需花费较长时间,且等待新头发长出的期间皆需维持该不满意的发色;若想在短时间内修改染发结果,则需进行漂白、重新染色等,该方式则需花费较大的额外费用,且对头发及皮肤易造 成再度的伤害。In addition, after the hair is dyed, people are often dissatisfied with the result of the dyeing. At this time, it is necessary to wait for the hair to grow back to return to the original hair color. Therefore, it takes a long time and waits for the new hair to grow out. It is necessary to maintain the unsatisfactory hair color; if you want to modify the hair coloring result in a short time, you need to perform bleaching, re-dyeing, etc. This method requires a large additional cost and is likely to cause further damage to the hair and skin.

因此,如何花费较少的成本,且使用对人体较无副作用的方式修改染发结果,以去除染剂,使头发变回原生的发色,是本技术领域亟欲解决的另一重要问题。Therefore, how to modify the hair dyeing results in a way that costs less cost and has less side effects on the human body to remove the dye and return the hair to its original hair color is another important problem that the technical field urgently wants to solve.

发明内容Summary of the invention

有鉴于先前技术的不足与缺失,本发明的一个目的在于提供一种操作简便、低成本且不使用液态或胶态化学染剂的淡化发色方式,以防止化学物质染剂对头发及皮肤造成伤害,同时亦具有改变发色的功效。In view of the shortcomings and deficiencies of the prior art, an object of the present invention is to provide a method of lightening hair color that is easy to operate, low-cost, and does not use liquid or colloidal chemical dyes, so as to prevent chemical dyes from causing damage to hair and skin. Damage, but also has the effect of changing hair color.

为达前述发明目的,本发明提供一种用于淡化发色的气体供应装置,其包括分隔层及包裹于该分隔层中的功能单元,其中,该功能单元包含金属过氧化物、活化剂和催化剂。In order to achieve the aforementioned object of the invention, the present invention provides a gas supply device for lightening hair color, which includes a separation layer and a functional unit wrapped in the separation layer, wherein the functional unit includes a metal peroxide, an activator, and catalyst.

可选地,该分隔层可以是单层或复合层;该分隔层的材料可以是透气材料或不透气材料;该分隔层两面的材料可以不一致。Optionally, the separation layer can be a single layer or a composite layer; the material of the separation layer can be a gas-permeable material or a gas-impermeable material; the materials on both sides of the separation layer can be inconsistent.

可选地,该功能单元中的金属过氧化物包含过氧化钙、过氧化镁、过氧化钠或过氧化钾。Optionally, the metal peroxide in the functional unit includes calcium peroxide, magnesium peroxide, sodium peroxide, or potassium peroxide.

可选地,该功能单元中的活化剂为酰基化合物,所述酰基化合物选自于由四乙酰基乙二胺(TAED)、壬酰氧基苯磺酸钠(NOBS)、四乙酰甘脲、五乙酰葡萄糖、N-乙酰基邻苯二甲酰亚胺、1-乙酰乙基苯甲酸酯、三乙酰基乙醇胺和壬酰乙酰苯酯磺酸盐所组成的群组。Optionally, the activator in the functional unit is an acyl compound selected from the group consisting of tetraacetyl ethylene diamine (TAED), sodium nonanoyloxybenzene sulfonate (NOBS), tetraacetyl glycoluril, The group consisting of pentaacetyl glucose, N-acetyl phthalimide, 1-acetyl ethyl benzoate, triacetyl ethanolamine and nonanoyl acetophenone sulfonate.

可选地,该功能单元中的催化剂为过氧化氢酶。Optionally, the catalyst in the functional unit is catalase.

可选地,该气体供应装置是用于头部的装置。Optionally, the gas supply device is a device for the head.

可选地,该气体供应装置是用于躯干或四肢的装置。Optionally, the gas supply device is a device for the trunk or limbs.

为达前述发明目的,本发明提供的气体供应装置可进一步包括产生二氧化碳的组件或/和产生一氧化氮的组件,以提高淡化头发发色的效率。In order to achieve the aforementioned object of the invention, the gas supply device provided by the present invention may further include a component that generates carbon dioxide or/and a component that generates nitric oxide, so as to improve the efficiency of lightening the hair color.

可选地,该产生二氧化碳的组件包含固体酸与固体碳酸氢钠或碳酸金属;该固体酸是乳酸或/和柠檬酸;该碳酸金属包含碳酸镁、碳酸钙、碳酸钠或碳酸钾。Optionally, the carbon dioxide generating component includes solid acid and solid sodium bicarbonate or metal carbonate; the solid acid is lactic acid or/and citric acid; and the metal carbonate includes magnesium carbonate, calcium carbonate, sodium carbonate or potassium carbonate.

可选地,该产生一氧化氮的组件包括金属单元及硝酸包裹单元;其中, 该硝酸包裹单元将硝酸封存于其内,可通过破坏硝酸包裹单元以释出硝酸,该硝酸为稀硝酸;其中,该金属单元选自于由钠、镁、铝、锌、铁、锡、铅、铜、银及其组合所组成的群组;其中,该硝酸包裹单元为高度阻气阻水的金属复合膜,其内层为高分子膜,外层为金属膜。Optionally, the nitric oxide generating component includes a metal unit and a nitric acid wrapping unit; wherein the nitric acid wrapping unit seals the nitric acid in it, and the nitric acid wrapping unit can be destroyed to release the nitric acid, and the nitric acid is dilute nitric acid; wherein , The metal unit is selected from the group consisting of sodium, magnesium, aluminum, zinc, iron, tin, lead, copper, silver and combinations thereof; wherein the nitric acid coating unit is a metal composite film with a high gas and water barrier , The inner layer is a polymer film, and the outer layer is a metal film.

可选地,该产生一氧化氮的组件可进一步包含脱氧剂、高吸水性聚合物、活化剂、或催化剂;该脱氧剂包含铁系脱氧剂、亚硫酸盐系脱氧剂、或加氢催化剂型脱氧剂。Optionally, the nitric oxide generating component may further include a deoxidizer, a super absorbent polymer, an activator, or a catalyst; the deoxidizer includes an iron-based deoxidizer, a sulfite-based deoxidizer, or a hydrogenation catalyst type Deoxidizer.

可选地,该高分子膜选自于由聚乙烯、聚丙烯、聚对苯二甲酸乙二醇酯(PET)、PET镀铝薄膜、PET涂布聚硅氮烷、流延聚丙烯薄膜(CPP)、CPP镀铝薄膜、三氧化二铝复合PET/CPP、共聚酯塑料及其组合所组成的群组。Optionally, the polymer film is selected from polyethylene, polypropylene, polyethylene terephthalate (PET), PET aluminized film, PET coated polysilazane, cast polypropylene film ( CPP), CPP aluminized film, Al2O3 composite PET/CPP, copolyester plastics and combinations thereof.

可选地,该金属膜的材质选自于由钠、镁、铝、锌、铁、锡、铅、铜、银及其组合所组成的群组。Optionally, the material of the metal film is selected from the group consisting of sodium, magnesium, aluminum, zinc, iron, tin, lead, copper, silver, and combinations thereof.

为达前述发明目的,本发明提供的气体供应装置可进一步包括产生氢气的组件。In order to achieve the aforementioned object of the invention, the gas supply device provided by the present invention may further include a component for generating hydrogen.

可选地,该产生氢气的组件包含(1)金属氢氧化物或金属过氧化物及铝粉、(2)氢化物或(3)上述两者的组合。Optionally, the hydrogen generating component includes (1) metal hydroxide or metal peroxide and aluminum powder, (2) hydride, or (3) a combination of the two.

可选地,该产生氢气的组件中的金属氢氧化物包含氢氧化钙、氢氧化镁、氢氧化钠或氢氧化钾;该金属过氧化物包含过氧化钙、过氧化镁、过氧化钠或过氧化钾;该氢化物包含可与水反应生成氢气的氢化物。Optionally, the metal hydroxide in the hydrogen generating component includes calcium hydroxide, magnesium hydroxide, sodium hydroxide or potassium hydroxide; the metal peroxide includes calcium peroxide, magnesium peroxide, sodium peroxide or Potassium peroxide; this hydride contains a hydride that can react with water to form hydrogen.

如上所述的气体供应装置,其中,功能单元:产生二氧化碳的组件的重量比例为1:100-100:1;其中,功能单元:产生一氧化氮的组件的重量比例为1:100-100:1;其中,功能单元:产生氢气的组件的重量比例为1:100-100:1。。In the gas supply device as described above, the weight ratio of the functional unit: carbon dioxide generating component is 1:100-100:1; wherein, the weight ratio of the functional unit: nitric oxide generating component is 1:100-100: 1; Among them, the weight ratio of functional unit: hydrogen-generating components is 1:100-100:1. .

如上所述的气体供应装置,其中,功能单元:产生二氧化碳的组件的重量比例为1:10-10:1;其中,功能单元:产生一氧化氮的重量比例为1:10-10:1;其中,功能单元:产生氢气的组件的重量比例为1:10-10:1。In the gas supply device as described above, the weight ratio of functional unit: carbon dioxide generating component is 1:10-10:1; wherein, the weight ratio of functional unit: nitric oxide generating component is 1:10-10:1; Among them, the weight ratio of functional unit: hydrogen-generating component is 1:10-10:1.

如上所述的气体供应装置可进一步包括至少一条导管,该导管与该分隔层连接。The gas supply device as described above may further include at least one pipe connected to the separation layer.

如上所述的气体供应装置可以用于头部穿戴装置或美发设备;其中,该头部穿戴装置包括头罩、安全帽、帽子、浴帽或泳帽;该美发设备包括吹风 机、头发烘干机或烫发机。The gas supply device as described above can be used in a head wear device or hairdressing equipment; wherein, the head wear device includes a hood, a safety helmet, a hat, a shower cap or a swimming cap; the hairdressing equipment includes a hair dryer, a hair dryer Or a perm machine.

为达前述发明目的,本发明提供一种如上所述的气体供应装置用于淡化发色的用途,其提供气体于头皮及头发,其中该气体为氧气,并可进一步反应生成活性氧,其具有促使头发颜色转淡的功效,且可促进头发的生长,其中,该气体可进一步包含二氧化碳、一氧化氮及/或氢气。In order to achieve the aforementioned object of the invention, the present invention provides a gas supply device as described above for lightening hair color, which provides gas to the scalp and hair, wherein the gas is oxygen and can be further reacted to generate active oxygen, which has The effect of promoting the lightening of hair color and promoting the growth of hair, wherein the gas may further include carbon dioxide, nitric oxide and/or hydrogen.

一种如上所述的气体供应装置用于淡化发色的方法,其包括以下步骤:A method for lightening hair color with the gas supply device as described above, which includes the following steps:

步骤1:将该气体供应装置放置于头部穿戴装置中;Step 1: Place the gas supply device in the head wear device;

步骤2:穿戴该头部穿戴装置于欲淡化发色的位置1-4小时;Step 2: Wear the head wear device for 1-4 hours at the position where you want to lighten your hair color;

步骤3:持续使用4-5次,每次间隔1-3天。Step 3: Use it continuously for 4-5 times with an interval of 1-3 days.

过去研究中曾揭露氢气可用于将白发改善成黑发,因此于白发的使用者,可于上述步骤1之前先施用氢气于头皮及头发,以将头发先改为黑色,再施用本发明提供的气体供应装置供给活性氧于头皮及头发,将黑发颜色转淡,达到改变头发颜色的功效。Past studies have revealed that hydrogen can be used to transform white hair into black hair. Therefore, users with white hair can apply hydrogen to the scalp and hair before step 1 above to change the hair to black before applying the present invention The provided gas supply device supplies active oxygen to the scalp and hair, which reduces the color of black hair and achieves the effect of changing the color of the hair.

可选地,该方法可于使用前先喷洒少许水于该气体供应装置,以加快反应进行。Optionally, the method can spray a little water on the gas supply device before use to speed up the reaction.

本发明的另一个目的在于提供一种操作简便、低成本且相对无副作用的消除头发染剂的方式。Another object of the present invention is to provide a method for eliminating hair dyes that is simple to operate, low-cost, and relatively free of side effects.

为达前述发明目的,本发明提供一种如上所述的气体供应装置用于消除头发上的染剂的用途,其中,该消除头发上的染剂,使发色变回原生发色。In order to achieve the above-mentioned object of the invention, the present invention provides a use of the gas supply device as described above for removing the dye on the hair, wherein the removing the dye on the hair turns the hair color back to the original hair color.

本发明所提供的淡化发色的方法,不会刺激头发与皮肤,亦不会引发过敏反应,且成本低于过去使用的化学染剂,操作上相对简便,并可有效改变头发颜色。The method for lightening hair color provided by the present invention does not irritate hair and skin, and does not cause allergic reactions, and the cost is lower than the chemical dyes used in the past, the operation is relatively simple, and the hair color can be effectively changed.

本发明亦揭示可用于淡化发色的头部穿戴装置或美发设备。该头部穿戴装置可让头皮或头发处于氧气及其他气体环境中,并且贴近皮肤,使氧气或其他气体易于被毛囊吸收,更具有可随身携带的优势。该美发设备可让使用者的头发及头皮在进行美发过程中处于氧气及其他气体的环境中,以同时进行美发及淡化发色,并且该气体环境亦具有促进毛囊生长的效果。The present invention also discloses a head wear device or hairdressing equipment that can be used to lighten hair color. The head wear device can put the scalp or hair in an oxygen and other gas environment, and be close to the skin, so that the oxygen or other gas can be easily absorbed by the hair follicles, and has the advantage of being portable. The hairdressing equipment allows the user's hair and scalp to be in an oxygen and other gas environment during the hairdressing process, so as to perform hairdressing and lighten hair color at the same time, and the gas environment also has the effect of promoting the growth of hair follicles.

附图说明Description of the drawings

图1为本发明的气体供应装置的示意图。Fig. 1 is a schematic diagram of the gas supply device of the present invention.

图2为本发明的气体供应装置的分解图。Figure 2 is an exploded view of the gas supply device of the present invention.

图3为本发明的气体供应装置的剖面图。Fig. 3 is a cross-sectional view of the gas supply device of the present invention.

图4为包含气体供应装置的头罩示意图。Fig. 4 is a schematic diagram of a hood including a gas supply device.

图5为实施例2的气体供应装置的剖面图。Fig. 5 is a cross-sectional view of the gas supply device of the second embodiment.

图6为实施例3的气体供应装置的剖面图。Fig. 6 is a cross-sectional view of the gas supply device of the third embodiment.

图7为实施例3的另一气体供应装置的剖面图。Fig. 7 is a cross-sectional view of another gas supply device of the third embodiment.

图8为实施例4的气体供应装置的剖面图。Fig. 8 is a cross-sectional view of the gas supply device of the fourth embodiment.

图9为本发明的气体供应装置加装导管的示意图。Fig. 9 is a schematic diagram of the gas supply device of the present invention being equipped with a duct.

图10为本发明的气体供应装置安置于美发设备的示意图。Fig. 10 is a schematic diagram of the gas supply device of the present invention installed in a hairdressing equipment.

图11为实际穿戴该气体供应装置的头罩的使用态样图。Fig. 11 is a view of the use state of the hood actually worn on the gas supply device.

图12为实施例1的受试者于使用前的头发颜色照片图。Figure 12 is a photograph of the hair color of the subject of Example 1 before use.

图13为实施例1的受试者于使用后的头发颜色照片图。Figure 13 is a photograph of the hair color of the subject of Example 1 after use.

图14为实施例4的受试者于使用前(第1天)及使用后(第5天)的头发颜色照片图。Figure 14 is a photograph of the hair color of the subjects of Example 4 before use (day 1) and after use (day 5).

附图标记说明Description of Reference Signs

1-气体供应装置;11-分隔层;111-透气结构;12-功能单元;13-产生二氧化碳的组件;14-金属单元;141-硝酸包裹单元;15-产生氢气的组件;16-导管。1-gas supply device; 11-separation layer; 111-permeable structure; 12-functional unit; 13-carbon dioxide-generating component; 14-metal unit; 141-nitric acid wrapping unit; 15-hydrogen-generating component; 16-pipe.

具体实施方式Detailed ways

本发明说明书中所述的所有技术性及科学术语,除非另外有所定义,皆为该所属专业人士领域可共同了解的意义。All technical and scientific terms described in the specification of the present invention, unless otherwise defined, are meanings commonly understood by the professionals in the field.

本说明书术语“原生发色”是指成人个体发育成熟后的健康、未受损及老化的毛囊所生长出的头发颜色,头发颜色可因每一个个体的健康毛囊产生色素能力的差异而有所不同。The term "primary hair color" in this manual refers to the color of the hair grown from healthy, undamaged, and aging hair follicles after mature individual development. Hair color can vary depending on the ability of each individual's healthy hair follicle to produce pigment different.

本说明书术语“淡化发色”是指将头发颜色改变为相较原生发色浅的色系,例如:黑色头发转变成褐色头发,颜色改变因原生发色或使用程度而有所差异。The term "diluted hair color" in this specification refers to changing the hair color to a lighter color system than the original hair color. For example, black hair turns into brown hair, and the color change varies depending on the original hair color or the degree of use.

本发明提供一种淡化发色的气体供应装置1,如图1-3所示,其包含分隔层11及包裹于分隔层11中的功能单元12。分隔层11可以是单层或复合层。分隔层11的材料可以是透气材料或不透气材料。本发明一较佳实施例中,分隔层11靠近用户一侧为透气结构111,使气体得以进出,分隔层11两面的材料可以不一致。功能单元12包含金属过氧化物、活化剂、催化剂。金属过氧化物包含过氧化钙、过氧化镁、过氧化钠或过氧化钾。The present invention provides a gas supply device 1 for lightening hair color, as shown in FIGS. 1-3, which includes a separation layer 11 and a functional unit 12 wrapped in the separation layer 11. The separation layer 11 may be a single layer or a composite layer. The material of the separation layer 11 may be a gas-permeable material or a gas-impermeable material. In a preferred embodiment of the present invention, the side of the separation layer 11 close to the user is a gas-permeable structure 111 to allow gas to enter and exit, and the materials on both sides of the separation layer 11 may be inconsistent. The functional unit 12 includes a metal peroxide, an activator, and a catalyst. Metal peroxides include calcium peroxide, magnesium peroxide, sodium peroxide, or potassium peroxide.

优选地,功能单元12中的活化剂为酰基化合物,所述酰基化合物选自于由四乙酰基乙二胺(TAED)、壬酰氧基苯磺酸钠(NOBS)、四乙酰甘脲、五乙酰葡萄糖、N-乙酰基邻苯二甲酰亚胺、1-乙酰乙基苯甲酸酯、三乙酰基乙醇胺和壬酰乙酰苯酯磺酸盐所组成的群组。功能单元12中的催化剂为过氧化氢酶。Preferably, the activator in the functional unit 12 is an acyl compound selected from the group consisting of tetraacetylethylenediamine (TAED), sodium nonanoyloxybenzene sulfonate (NOBS), tetraacetylglycoluril, five Acetyl glucose, N-acetyl phthalimide, 1-acetyl ethyl benzoate, triacetyl ethanolamine and nonanoyl acetophenone sulfonate. The catalyst in the functional unit 12 is catalase.

本发明提供一种淡化发色的用途,其施用气体供应装置1供给活性氧于头皮及头发,其中活性氧具有促使头发颜色转淡的功效,且可促进头发的生长。功能单元12可与环境中的水气或人体散发出的水气作用,以生成活性氧,亦可另备水性液体进行作用,其反应方程如下所示:The present invention provides a use for lightening hair color, using a gas supply device 1 to supply active oxygen to the scalp and hair, wherein the active oxygen has the effect of promoting the lightening of the hair color and can promote the growth of the hair. The functional unit 12 can interact with the water vapor in the environment or the water vapor emitted by the human body to generate active oxygen. It can also prepare an aqueous liquid for its effect. The reaction equation is as follows:

2XO 2+2H 2O→2X(OH) 2+O 2(X为钙、镁) 2XO 2 +2H 2 O→2X(OH) 2 +O 2 (X is calcium, magnesium)

2Y2O 2+2H 2O→4Y(OH)+O 2(Y为钠、钾) 2Y2O 2 +2H 2 O→4Y(OH)+O 2 (Y is sodium, potassium)

上述反应中间产物过氧化氢(H 2O 2)像弱酸一样,在碱性介质中离解为过氧化氢负离子: Hydrogen peroxide (H 2 O 2 ), the intermediate product of the above reaction, is like a weak acid and dissociates into anions of hydrogen peroxide in an alkaline medium:

H 2O 2+OH -→HOO -+H 2O H 2 O 2 + OH - → HOO - + H 2 O

过氧化氢负离子是一种亲核试剂,可引发过氧化氢形成游离基:Hydrogen peroxide anion is a nucleophile, which can cause hydrogen peroxide to form free radicals:

HOO -+H 2O 2→HOO ·+HO ·+OH - HOO - + H 2 O 2 → HOO · + HO · + OH -

两者皆有较高的活性,可使头发中的色素氧化分解而产生类似于漂白的作用,以淡化发色。Both have high activity, which can oxidize and decompose the pigment in the hair to produce a bleach-like effect to lighten the hair color.

其中,气体供应装置1是用于头部的装置。Among them, the gas supply device 1 is a device for the head.

其中,气体供应装置1是用于躯干或四肢的装置。Among them, the gas supply device 1 is a device for the trunk or limbs.

本发明进一步使用上述的原理施用于染色后的头发,发现其具有消除染剂的功效,因此提供一种消除头发上的染剂的方法,其施用如上所述的气体供应装置1供给活性氧于头皮及头发,其中,消除头发上的染剂,使发色变回原生发色。The present invention further uses the above-mentioned principle to apply to dyed hair and finds that it has the effect of eliminating dyes. Therefore, a method for eliminating dyes on hair is provided. The gas supply device 1 as described above is used to supply active oxygen to Scalp and hair, among them, remove the dye on the hair, and make the hair color return to the original hair color.

本发明以下面的实施例予以示范阐明,应当理解,所述的实施例仅为说明本发明的技术思想及特点,其目的使熟习此项技艺人士能够了解本发明的内容并据以实施,当不能以之限定本发明的专利范围,即凡依本发明所揭示的精神所作的均等变化或修饰,仍应涵盖在本案的专利范围内。The present invention is exemplified and illustrated by the following embodiments. It should be understood that the described embodiments are only to illustrate the technical ideas and features of the present invention, and their purpose is to enable those skilled in the art to understand the content of the present invention and implement them accordingly. It cannot be used to limit the patent scope of the present invention, that is, any equivalent changes or modifications made in accordance with the spirit of the present invention should still be covered by the patent scope of this case.

实施例1 气体淡化发色实验Example 1 Gas desalination and color development experiment

将100g固体氧源过氧化钙(CaO 2)、0.5g催化剂过氧化氢酶(CAT)、10g活化剂四乙酰基乙二胺(TAED)制作成前述气体供应装置1的功能单元12,并将其安置于头罩中,如图4所示,并进一步测试其淡化发色的效果。 100g solid oxygen source calcium peroxide (CaO 2 ), 0.5g catalyst catalase (CAT), 10g activator tetraacetyl ethylene diamine (TAED) are made into the functional unit 12 of the aforementioned gas supply device 1, and It was placed in the hood, as shown in Figure 4, and the effect of lightening hair color was further tested.

招募黑发的受试者数名,令受试者每次穿戴头罩1-4小时,持续使用4-5次,每次间隔1-3天。受试者实际穿戴头罩的态样如图11所示,观察并纪录其头皮状况及头发颜色的改变。Several subjects with black hair were recruited, and the subjects were asked to wear the hood for 1-4 hours at a time and use it continuously for 4-5 times, with an interval of 1-3 days between each time. The actual state of the subject wearing the hood is shown in Figure 11. Observe and record the changes in the condition of their scalp and hair color.

如图12所示,受试者于使用前头发颜色为黑色(PANTONE Black C),经过持续使用头罩4-5次后,受试者的头发颜色由黑色转变成红褐色。如图13所示,发色为PANTONE色标编号1675C(红褐色),发色有明显淡化的趋势,且颜色改变显著。As shown in Figure 12, the subject's hair color was black (PANTONE Black C) before use. After 4-5 times of continuous use of the hood, the subject's hair color changed from black to reddish brown. As shown in Figure 13, the hair color is PANTONE color code number 1675C (red-brown), the hair color has a tendency to fade obviously, and the color changes significantly.

另外,受试者于穿戴头罩时,并无不适的情况产生,且脱下头罩后,头皮亦无红肿或过敏的情形发生,显示本发明所提供的方法及装置不会对头皮产生刺激性或不良副作用。In addition, the subjects did not experience any discomfort when wearing the hood, and there was no redness or allergies on the scalp after taking off the hood, which shows that the method and device provided by the present invention will not cause irritation to the scalp. Or adverse side effects.

实施例2 气体淡化发色实验-搭配产生二氧化碳的组件Example 2 Gas desalination and color development experiment-with components that produce carbon dioxide

本实施例进一步将前述的气体供应装置1包括产生二氧化碳的组件13,该产生二氧化碳的组件13包含固体酸与固体碳酸氢钠或碳酸金属。In this embodiment, the aforementioned gas supply device 1 further includes a component 13 for generating carbon dioxide. The component 13 for generating carbon dioxide includes solid acid and solid sodium bicarbonate or metal carbonate.

优选地,产生二氧化碳的组件13中的固体酸是乳酸或/和柠檬酸。碳酸金属包含碳酸镁、碳酸钙、碳酸钠或碳酸钾。固体酸:固体碳酸氢钠或碳酸金属的重量比例为1:100-100:1,优选为1:10-10:1。Preferably, the solid acid in the carbon dioxide generating component 13 is lactic acid or/and citric acid. The metal carbonate includes magnesium carbonate, calcium carbonate, sodium carbonate, or potassium carbonate. The weight ratio of solid acid: solid sodium bicarbonate or metal carbonate is 1:100-100:1, preferably 1:10-10:1.

本实施例使用步骤如下:The steps used in this embodiment are as follows:

将10g固体氧源过氧化镁(MgO 2)、0.5g催化剂过氧化氢酶(CAT)、0.05g活化剂四乙酰基乙二胺(TAED)制作成功能单元12,并将0.7g柠檬酸与0.5g碳酸氢钠制作成产生二氧化碳的组件13。 10g solid oxygen source magnesium peroxide (MgO 2 ), 0.5g catalyst catalase (CAT), 0.05g activator tetraacetyl ethylenediamine (TAED) are made into functional unit 12, and 0.7g citric acid is combined with 0.5g of sodium bicarbonate is made into a component 13 that generates carbon dioxide.

将上述功能单元12与产生二氧化碳的组件13制成本发明所述的气体供 应装置1,如图11所示,并将其安置于头罩中,如图4所示。The above-mentioned functional unit 12 and the carbon dioxide generating component 13 are made into the gas supply device 1 of the present invention, as shown in Fig. 11, and placed in a hood, as shown in Fig. 4.

使用者每日穿戴头罩1-4小时,持续使用4-5次,每次间隔1-3天。The user wears the hood for 1-4 hours a day and uses it continuously for 4-5 times with an interval of 1-3 days.

本实施例的产生二氧化碳的组件13与环境中的水气或人体散发出的水气作用,可生成二氧化碳,其反应方程如下所示:The carbon dioxide generating component 13 of this embodiment interacts with water vapor in the environment or water vapor emitted by the human body to generate carbon dioxide. The reaction equation is as follows:

3NaHCO 3+C 3H 4(OH)(COOH) 3→C 3H 4(OH)(COONa) 3+3H 2O+3CO 2 3NaHCO 3 +C 3 H 4 (OH)(COOH) 3 →C 3 H 4 (OH)(COONa) 3 +3H 2 O+3CO 2

研究显示,二氧化碳具有扩张微血管的功能,以致于能加速气体(氧气)交换速率,因此本实施例使用二氧化碳共同进行作用,使其具有加速反应进行的功效,以得到更佳的淡化发色效果。Studies have shown that carbon dioxide has the function of expanding capillaries, so that it can accelerate the gas (oxygen) exchange rate. Therefore, this embodiment uses carbon dioxide to act together to accelerate the reaction, so as to obtain a better lightening effect.

实施例3 气体淡化发色实验-搭配产生一氧化氮的组件Example 3 Gas desalination and color development experiment-with a component that produces nitric oxide

本实施例进一步将前述的气体供应装置1包括产生一氧化氮的组件,该产生一氧化氮的组件包含金属单元14及硝酸包裹单元141。硝酸包裹单元141将硝酸封存于其内,可通过破坏硝酸包裹单元141以释出硝酸,该硝酸为稀硝酸。金属单元14选自于由钠、镁、铝、锌、铁、锡、铅、铜、银及其组合所组成的群组。硝酸包裹单元141为高度阻气阻水的金属复合膜,其内层为高分子膜,外层为金属膜。高分子膜选自于由聚乙烯、聚丙烯、聚对苯二甲酸乙二醇酯(PET)、PET镀铝薄膜、PET涂布聚硅氮烷、流延聚丙烯薄膜(CPP)、CPP镀铝薄膜、三氧化二铝复合PET/CPP、共聚酯塑料及其组合所组成的群组。其中,金属膜的材质选自于由钠、镁、铝、锌、铁、锡、铅、铜、银及其组合所组成的群组。In this embodiment, the aforementioned gas supply device 1 further includes a nitric oxide generating component, and the nitric oxide generating component includes a metal unit 14 and a nitric acid coating unit 141. The nitric acid coating unit 141 seals the nitric acid therein, and the nitric acid can be released by destroying the nitric acid coating unit 141, which is dilute nitric acid. The metal unit 14 is selected from the group consisting of sodium, magnesium, aluminum, zinc, iron, tin, lead, copper, silver, and combinations thereof. The nitric acid coating unit 141 is a metal composite film with a high gas and water barrier. The inner layer is a polymer film, and the outer layer is a metal film. The polymer film is selected from polyethylene, polypropylene, polyethylene terephthalate (PET), PET aluminized film, PET coated polysilazane, cast polypropylene film (CPP), CPP coated A group consisting of aluminum film, aluminum oxide composite PET/CPP, copolyester plastic and combinations thereof. Wherein, the material of the metal film is selected from the group consisting of sodium, magnesium, aluminum, zinc, iron, tin, lead, copper, silver and combinations thereof.

优选地,产生一氧化氮的组件可进一步包含脱氧剂、高吸水性聚合物、活化剂、或催化剂。脱氧剂包含铁系脱氧剂、亚硫酸盐系脱氧剂、或加氢催化剂型脱氧剂。Preferably, the nitric oxide generating component may further include a deoxidizer, a super absorbent polymer, an activator, or a catalyst. The deoxidizer includes an iron-based deoxidizer, a sulfite-based deoxidizer, or a hydrogenation catalyst type deoxidizer.

本发明的实施例,当需要使用时,可通过破坏硝酸包裹单元141以释出稀硝酸,当稀硝酸遇到金属单元14即可反应生成一氧化氮,其反应如下:In the embodiment of the present invention, when needed, the nitric acid coating unit 141 can be destroyed to release the dilute nitric acid. When the dilute nitric acid meets the metal unit 14, it can react to produce nitric oxide, and the reaction is as follows:

3X+8HNO 3→3X(NO 3) 2+2NO↑+4H 2O 3X+8HNO 3 →3X(NO 3 ) 2 +2NO↑+4H 2 O

Y+4HNO 3→Y(NO 3) 3+NO↑+2H 2O Y+4HNO 3 →Y(NO 3 ) 3 +NO↑+2H 2 O

3Z+4HNO 3→3ZNO 3+NO↑+2H 2O 3Z+4HNO 3 →3ZNO 3 +NO↑+2H 2 O

其中,X为镁、铝、锌、铁、锡、铅、或铜,Y为铝、铁、或铜,Z为钠或银;其中,硝酸为稀硝酸;其中,硝酸与水的重量比例为1:3-1:20,较佳 为1:4-1:6,最佳为1:5。Among them, X is magnesium, aluminum, zinc, iron, tin, lead, or copper, Y is aluminum, iron, or copper, and Z is sodium or silver; wherein, nitric acid is dilute nitric acid; wherein the weight ratio of nitric acid to water is 1:3-1:20, preferably 1:4-1:6, most preferably 1:5.

本实施例使用步骤如下:The steps used in this embodiment are as follows:

将50g固体氧源过氧化钾(K 2O 2)、1g催化剂过氧化氢酶(CAT)、0.3g壬酰氧基苯磺酸钠(NOBS)制作成功能单元12。 50 g of solid oxygen source potassium peroxide (K 2 O 2 ), 1 g of catalyst catalase (CAT), and 0.3 g of sodium nonanoyloxybenzene sulfonate (NOBS) were made into functional unit 12.

将硝酸包裹单元141与5g金属钠制成产生一氧化氮的组件。The nitric acid coating unit 141 and 5 g of metallic sodium are made into a component that generates nitric oxide.

将上述功能单元12与产生一氧化氮的组件制成本发明所述的气体供应装置1,如图6所示,并将其安置于头罩中,如图4所示。气体供应装置1亦可通过分隔层11,化分成不同区域,以分隔功能单元12与产生一氧化氮的组件的配方,如图7所示。The above-mentioned functional unit 12 and the nitric oxide generating component are made into the gas supply device 1 according to the present invention, as shown in FIG. 6, and placed in a hood, as shown in FIG. 4. The gas supply device 1 can also be divided into different regions by the separation layer 11 to separate the functional unit 12 and the formula of the nitric oxide generating component, as shown in FIG. 7.

使用者每日穿戴头罩1-4小时,持续使用4-5次,每次间隔1-3天。The user wears the hood for 1-4 hours a day and uses it continuously for 4-5 times with an interval of 1-3 days.

研究显示,一氧化氮具有扩张微血管、加快血液流动等功能,以致于能加速气体(氧气)交换速率,因此本实施例使用一氧化氮共同进行作用,使其具有加速反应进行的功效,以得到更佳的淡化发色效果。Studies have shown that nitric oxide has the functions of expanding capillaries and accelerating blood flow, so as to accelerate the gas (oxygen) exchange rate. Therefore, this embodiment uses nitric oxide to work together to accelerate the reaction to obtain Better fade hair color effect.

实施例4 气体淡化发色实验-搭配氢气使用Example 4 Gas desalination and color development experiment-use with hydrogen

本实施例进一步将前述的气体供应装置1搭配产生氢气的组件15使用,产生氢气的组件15包含(1)金属氢氧化物或金属过氧化物及铝粉、(2)氢化物或(3)上述两者的组合。This embodiment further uses the aforementioned gas supply device 1 with a hydrogen-generating component 15 which includes (1) metal hydroxide or metal peroxide and aluminum powder, (2) hydride, or (3) A combination of the above two.

优选地,产生氢气的组件15中的金属氢氧化物包含氢氧化钙、氢氧化镁、氢氧化钠或氢氧化钾。金属过氧化物包含过氧化钙、过氧化镁、过氧化钠或过氧化钾;氢化物包含可与水反应生成氢气的氢化物。Preferably, the metal hydroxide in the hydrogen generating component 15 contains calcium hydroxide, magnesium hydroxide, sodium hydroxide or potassium hydroxide. Metal peroxides include calcium peroxide, magnesium peroxide, sodium peroxide, or potassium peroxide; hydrides include hydrides that can react with water to generate hydrogen.

过去研究显示,氢气具有改善白发的功效,其利用氢气消除头发及毛囊内的过氧化氢,反应式如下:Past studies have shown that hydrogen has the effect of improving gray hair. It uses hydrogen to eliminate hydrogen peroxide in hair and hair follicles. The reaction formula is as follows:

H 2+H 2O 2→2H 2O H 2 +H 2 O 2 →2H 2 O

本实施例中,产生氢气的组件15包含金属氢氧化物及铝粉时,金属氢氧化物可与铝粉反应产生氢气,如下列反应:In this embodiment, when the hydrogen-generating component 15 includes metal hydroxide and aluminum powder, the metal hydroxide can react with the aluminum powder to generate hydrogen, as in the following reactions:

2Al+2H 2O+X(OH) 2→X(AlO 2) 2+3H 2(X为钙、镁) 2Al+2H 2 O+X(OH) 2 →X(AlO 2 ) 2 +3H 2 (X is calcium, magnesium)

2Al+2H 2O+2Y(OH)→2YAlO 2+3H 2(Y为钠、钾) 2Al+2H 2 O+2Y(OH)→2YAlO 2 +3H 2 (Y is sodium, potassium)

当产生氢气的组件15包含金属过氧化物及铝粉时,金属过氧化物可与环境中的水气反应生成金属氢氧化物,且可同时产生氧气,如下列反应式:When the hydrogen generating component 15 contains metal peroxide and aluminum powder, the metal peroxide can react with moisture in the environment to form metal hydroxide, and can simultaneously generate oxygen, as shown in the following reaction formula:

2XO 2+2H 2O→2X(OH) 2+O 2(X为钙、镁) 2XO 2 +2H 2 O→2X(OH) 2 +O 2 (X is calcium, magnesium)

2Y2O 2+2H 2O→4Y(OH)+O 2(Y为钠、钾) 2Y2O 2 +2H 2 O→4Y(OH)+O 2 (Y is sodium, potassium)

所生成的金属氢氧化物可再通过上述金属氢氧化物及铝粉的反应式生成氢气。The generated metal hydroxide can generate hydrogen gas through the reaction formula of the above-mentioned metal hydroxide and aluminum powder.

本实施例使用步骤如下:The steps used in this embodiment are as follows:

取2g固体氧源过氧化钠(Na 2O 2)、0.05g催化剂过氧化氢酶(CAT)及0.04g五乙酰葡萄糖制成前述气体供应装置1的功能单元12,并将1g过氧化钠、1g氢氧化钠,10g铝粉及适量草酸制作成产生氢气的组件15。 Take 2g of solid oxygen source sodium peroxide (Na 2 O 2 ), 0.05g of catalyst catalase (CAT) and 0.04g of pentaacetyl glucose to make the functional unit 12 of the aforementioned gas supply device 1, and add 1g of sodium peroxide, 1g of sodium hydroxide, 10g of aluminum powder and appropriate amount of oxalic acid are made into a hydrogen generating module 15.

将上述功能单元12与产生氢气的组件15制成本发明所述的气体供应装置1,如图8所示,并将其安置于头罩中,如图4所示。The above-mentioned functional unit 12 and the hydrogen generating component 15 are made into the gas supply device 1 according to the present invention, as shown in FIG. 8, and placed in a hood, as shown in FIG. 4.

使用者每日穿戴头罩1-4小时,持续使用4-5次,每次间隔1-3天。The user wears the hood for 1-4 hours a day and uses it continuously for 4-5 times with an interval of 1-3 days.

本实施例其中之一受试者的实验结果如图14所示,受试者于使用前(第1天)的头发颜色为白色,持续使用头罩5天后(第5天),受试者的头发颜色由白色转变成PANTONE色标编号160C(褐色),其因受氢气的影响改善白发,且受本发明的配方影响达到淡化发色的效果,其中,发色有明显淡化的趋势,且改变显著。本发明另一实施例亦可将产生氢气的组件15与功能单元12分别制成不同气体供应装置1,并先使用氢气供给装置将白发改善为黑发,再利用本发明的含有功能单元12的气体供应装置1将黑发颜色染淡,以达到改善白发又具有染发的功效。The experimental results of one of the subjects in this example are shown in Figure 14. The subject’s hair color was white before use (day 1), and after continuous use of the hood for 5 days (day 5), the subject The hair color of PANTONE changed from white to PANTONE color code 160C (brown), which is affected by hydrogen to improve gray hair, and is affected by the formula of the present invention to achieve the effect of lightening hair color. Among them, the hair color has a clear trend of lightening. And the change is significant. In another embodiment of the present invention, the hydrogen generating component 15 and the functional unit 12 can be made into different gas supply devices 1, and the hydrogen supply device is used to improve the white hair into black hair, and then the functional unit 12 of the present invention is used. The gas supply device 1 dyes the black hair lightly, so as to improve the white hair and have the effect of dyeing the hair.

实施例5 气体消除头发染剂实验Example 5 Experiment of Gas Elimination Hair Dye

将50g固体氧源过氧化钙(CaO 2)、0.5g催化剂过氧化氢酶(CAT)、10g活化剂三乙酰基乙醇胺制作成前述气体供应装置1的功能单元12,并将其安置于头罩中,如图4所示。 50g of solid oxygen source calcium peroxide (CaO 2 ), 0.5g of catalyst catalase (CAT), and 10g of activator triacetylethanolamine were made into the functional unit 12 of the aforementioned gas supply device 1 and placed on the hood , As shown in Figure 4.

本实施例用于具有不同发色的染发者,令使用者每日穿戴头罩1-4小时,持续使用4-5次,每次间隔1-3天,其可将使用者的原先头发上的染料逐渐消除,且头发的颜色变回原生发色,为具有消除头发染剂的功效。This embodiment is used for hair dyers with different hair colors. The user wears the hood for 1-4 hours a day and uses it continuously for 4-5 times with an interval of 1-3 days. It can put the user’s original hair on The dye is gradually eliminated, and the color of the hair returns to the original hair color, which has the effect of eliminating hair dye.

实施例6 包含导管的气体供应装置Embodiment 6 Gas supply device including conduit

本发明所提供的气体供应装置1可进一步包括至少一条导管16,如图9所示,导管16与分隔层11连接,可用于导出气体供应装置1所产生的气体。The gas supply device 1 provided by the present invention may further include at least one conduit 16, as shown in FIG.

实施例7 包含气体供应装置的美发设备Embodiment 7 Hairdressing equipment including gas supply device

本发明所提供的气体供应装置1可搭配美发设备使用,如图10所示,其将前述的气体供应装置1安置于美发设备上,在美发过程中,对头皮及头发供给活性氧,使头发中的色素氧化分解而产生类似于染发的效果,以淡化发色。The gas supply device 1 provided by the present invention can be used with hairdressing equipment. As shown in FIG. 10, it places the aforementioned gas supply device 1 on the hairdressing equipment. The pigments in oxidized and decomposed to produce an effect similar to hair dyeing to lighten hair color.

为了找出较佳的反应物比例,取0.01-100g上述各实施例反应物,测试其气体生成效率,结果发现功能单元12:产生二氧化碳的组件13的重量比例为1:100-100:1,最佳重量比为1:10-10:1;其中,功能单元12:产生一氧化氮的组件的重量比例为1:100-100:1,最佳重量比为1:10-10:1;其中,功能单元12:产生氢气的组件15的重量比例为1:100-100:1,最佳重量比为1:10-10:1。In order to find a better ratio of reactants, 0.01-100 g of the reactants in each of the above examples were taken to test the gas generation efficiency. As a result, it was found that the weight ratio of functional unit 12: carbon dioxide-generating component 13 was 1:100-100:1. The best weight ratio is 1:10-10:1; among them, the weight ratio of functional unit 12: nitric oxide generating components is 1:100-100:1, and the best weight ratio is 1:10-10:1; Among them, the weight ratio of the functional unit 12: the hydrogen generating component 15 is 1:100-100:1, and the optimal weight ratio is 1:10-10:1.

本发明的气体供应装置1可以用于头部穿戴装置或美发设备;其中,头部穿戴装置包含头罩、安全帽、帽子、浴帽或泳帽;其中,美发设备包含吹风机、头发烘干机或烫发机。The gas supply device 1 of the present invention can be used in a head wear device or hairdressing equipment; wherein, the head wear device includes a hood, a safety helmet, a hat, a shower cap or a swimming cap; wherein, the hairdressing equipment includes a hair dryer and a hair dryer Or a perm machine.

本发明提供一种如上所述的气体供应装置用于淡化发色的用途,其提供气体于头皮及头发,其中气体为氧气,并可进一步反应生成活性氧,所述活性氧具有促使头发颜色转淡的功效,且可促进头发的生长,其中,气体可进一步包含二氧化碳、一氧化氮及/或氢气。The present invention provides a use of the above-mentioned gas supply device for lightening hair color, which provides gas to the scalp and hair, wherein the gas is oxygen, and can be further reacted to generate active oxygen, which can promote hair color change It has a light effect and can promote hair growth. The gas may further include carbon dioxide, nitric oxide and/or hydrogen.

本发明提供一种如上所述的气体供应装置用于淡化发色的方法,其包括以下步骤:The present invention provides a method for lightening hair color using the gas supply device as described above, which includes the following steps:

步骤1:将气体供应装置放置于头部穿戴装置中;Step 1: Place the gas supply device in the head wear device;

步骤2:穿戴头部穿戴装置于欲淡化发色的位置1-4小时;Step 2: Wear the head wear device for 1-4 hours in the position where you want to lighten your hair color;

步骤3:持续使用4-5次,每次间隔1-3天。Step 3: Use it continuously for 4-5 times with an interval of 1-3 days.

其中,于白发的使用者,可于步骤1之前先施用氢气于头皮及头发,以将头发先染为黑色,再施用本发明提供的气体供应装置供给活性氧于头皮及头发,将黑发颜色转淡,达到改变头发颜色的功效。Among them, users with white hair can apply hydrogen to the scalp and hair before step 1 to dye the hair black first, and then use the gas supply device provided by the present invention to supply active oxygen to the scalp and hair to reduce the black hair. The color fades to achieve the effect of changing the color of the hair.

其中,该方法可于使用前先喷洒少许水于气体供应装置,以加快反应进行。Among them, this method can spray a little water on the gas supply device before use to speed up the reaction.

本发明另外提供一种如上所述的气体供应装置用于消除头发上的染剂的用途,其中,消除头发上的染剂,使发色变回原生发色。The present invention also provides a use of the gas supply device as described above for removing dye on hair, wherein the dye on hair is removed, and the hair color is changed back to the original hair color.

综合而言,本发明提供一种崭新的淡化头发的方法,亦可将其视为一种染发方式,其可促使头发的颜色改变,相较于传统方法,本发明所提供的方法具有成本便宜、操作简便及容易维护的优势。In summary, the present invention provides a new method of lightening hair, which can also be regarded as a hair dyeing method, which can promote the change of hair color. Compared with traditional methods, the method provided by the present invention has low cost. , The advantages of simple operation and easy maintenance.

本发明提供的方法可施用上述各实施例的气体供应装置供给活性氧及其他气体于头皮及头发,以达到促使头发颜色转淡的功效,其中,其他气体包含二氧化碳、一氧化氮及/或氢气。The method provided by the present invention can use the gas supply devices of the above embodiments to supply active oxygen and other gases to the scalp and hair to achieve the effect of promoting the color of the hair. The other gases include carbon dioxide, nitric oxide and/or hydrogen. .

本发明所提供的方法更可进一步用于染发问题,该染发不仅限于改变头发发色,亦可用于改变躯干及四肢的毛色,且其相较于传统用于染发的方法,本发明不使用化学染料,因此不具有细胞突变或致癌等的风险,甚至不刺激头皮或肌肤即能达到染发的效果。The method provided by the present invention can be further applied to the problem of hair dyeing. The hair dyeing is not limited to changing the hair color, but can also be used to change the hair color of the trunk and limbs. Compared with the traditional method for dyeing hair, the present invention does not use chemical The dye does not have the risk of cell mutation or carcinogenesis, and it can even achieve the effect of dyeing hair without irritating the scalp or skin.

此外,有研究指出,头皮于缺氧时会造成毛囊进入程序性细胞死亡(programmed cell death)状态,导致毛囊受损萎缩,产生不正常掉发情形,使发量减少,且有秃头的可能性。由此可知,本发明的包括功能单元12的气体供应装置1亦有助于头发的生长。In addition, studies have pointed out that when the scalp is hypoxia, the hair follicles will enter a programmed cell death (programmed cell death) state, leading to damage and shrinkage of the hair follicles, resulting in abnormal hair loss, reducing hair volume, and the possibility of baldness. . It can be seen that the gas supply device 1 including the functional unit 12 of the present invention also contributes to the growth of hair.

另外,本发明所提供的淡化发色的方法可搭配头部穿戴装置或美发设备一起使用。本发明所提供的头部穿戴装置具有可随身携带的轻便优势,可让使用者随时进行染发;而本发明所提供的美发设备则是可以让使用者在进行美发过程中同时进行染发,具节省时间的优势。In addition, the method for lightening hair color provided by the present invention can be used with a head wear device or hairdressing equipment. The head wear device provided by the present invention has the advantage of being portable, allowing users to dye hair at any time; while the hairdressing equipment provided by the present invention allows users to dye hair at the same time during the hairdressing process, saving The advantage of time.

上列详细说明是针对本发明的可行实施例的具体说明,惟实施例并非用以限制本发明的专利范围,凡未脱离本发明技艺精神所为的等效实施或变更,均应涵盖在本案的专利范围内。The above detailed description is a specific description of the feasible embodiments of the present invention, but the embodiments are not intended to limit the scope of the patent of the present invention. Any equivalent implementation or modification that does not deviate from the technical spirit of the present invention shall be covered in this case. Within the scope of the patent.

Claims (28)

一种用于淡化发色的气体供应装置,其包括:分隔层及包裹于所述分隔层中的功能单元,其中,所述功能单元包含金属过氧化物、活化剂和催化剂。A gas supply device for lightening hair color, comprising: a separation layer and a functional unit wrapped in the separation layer, wherein the functional unit includes a metal peroxide, an activator and a catalyst. 如权利要求1所述的气体供应装置,其中,所述分隔层是单层或复合层。The gas supply device according to claim 1, wherein the separation layer is a single layer or a composite layer. 如权利要求1所述的气体供应装置,其中,所述金属过氧化物包含过氧化钙、过氧化镁、过氧化钠或过氧化钾。The gas supply device according to claim 1, wherein the metal peroxide includes calcium peroxide, magnesium peroxide, sodium peroxide, or potassium peroxide. 如权利要求1所述的气体供应装置,其中,所述活化剂为酰基化合物,所述酰基化合物选自于由四乙酰基乙二胺(TAED)、壬酰氧基苯磺酸钠(NOBS)、四乙酰甘脲、五乙酰葡萄糖、N-乙酰基邻苯二甲酰亚胺、1-乙酰乙基苯甲酸酯、三乙酰基乙醇胺和壬酰乙酰苯酯磺酸盐所组成的群组。The gas supply device according to claim 1, wherein the activator is an acyl compound selected from the group consisting of tetraacetyl ethylene diamine (TAED), sodium nonanoyloxybenzene sulfonate (NOBS) , Tetraacetyl glycoluril, pentaacetyl glucose, N-acetyl phthalimide, 1-acetyl ethyl benzoate, triacetyl ethanolamine and nonanoyl acetophenone sulfonate . 如权利要求1所述的气体供应装置,其中,所述催化剂为过氧化氢酶。The gas supply device according to claim 1, wherein the catalyst is catalase. 如权利要求1所述的气体供应装置,其是用于头部的装置。The gas supply device according to claim 1, which is a device for a head. 如权利要求1所述的气体供应装置,其是用于躯干或四肢的装置。The gas supply device according to claim 1, which is a device for the trunk or limbs. 如权利要求1所述的气体供应装置,其中,所述气体供应装置进一步包括产生二氧化碳的组件或/和产生一氧化氮的组件。The gas supply device according to claim 1, wherein the gas supply device further comprises a component that generates carbon dioxide or/and a component that generates nitric oxide. 如权利要求8所述的气体供应装置,所述产生二氧化碳的组件包含固体酸与固体碳酸氢钠或碳酸金属。8. The gas supply device according to claim 8, wherein the carbon dioxide generating component comprises solid acid and solid sodium bicarbonate or metal carbonate. 如权利要求9所述的气体供应装置,其中,所述固体酸是乳酸或/和柠檬酸。The gas supply device according to claim 9, wherein the solid acid is lactic acid or/and citric acid. 如权利要求9所述的气体供应装置,其中,所述碳酸金属包含碳酸镁、碳酸钙、碳酸钠或碳酸钾。The gas supply device according to claim 9, wherein the metal carbonate contains magnesium carbonate, calcium carbonate, sodium carbonate, or potassium carbonate. 如权利要求8所述的气体供应装置,所述产生一氧化氮的组件包括金属单元及硝酸包裹单元;其中,所述硝酸包裹单元将硝酸封存于其内,通过破坏所述硝酸包裹单元以释出所述硝酸,所述硝酸为稀硝酸;其中,所述金属单元是选自于由钠、镁、铝、锌、铁、锡、铅、铜、银及其组合所组成的群组;其中,所述硝酸包裹单元为高度阻气阻水的金属复合膜,其内层为 高分子膜,外层为金属膜。The gas supply device of claim 8, wherein the nitric oxide generating component includes a metal unit and a nitric acid wrapping unit; wherein the nitric acid wrapping unit seals the nitric acid in it, and releases the nitric oxide by destroying the nitric oxide wrapping unit. The nitric acid is dilute nitric acid; wherein, the metal unit is selected from the group consisting of sodium, magnesium, aluminum, zinc, iron, tin, lead, copper, silver and combinations thereof; wherein The nitric acid wrapping unit is a metal composite film with a high gas and water barrier, and the inner layer is a polymer film, and the outer layer is a metal film. 如权利要求12所述的气体供应装置,其中,所述产生一氧化氮的组件进一步包含脱氧剂、高吸水性聚合物、活化剂、或催化剂;所述脱氧剂包含铁系脱氧剂、亚硫酸盐系脱氧剂、或加氢催化剂型脱氧剂。The gas supply device according to claim 12, wherein the nitric oxide generating component further includes a deoxidizer, a super absorbent polymer, an activator, or a catalyst; the deoxidizer includes an iron-based deoxidizer, sulfurous acid Salt-based deoxidizer, or hydrogenation catalyst type deoxidizer. 如权利要求12所述的气体供应装置,其中,所述高分子膜选自于由聚乙烯、聚丙烯、聚对苯二甲酸乙二醇酯(PET)、PET镀铝薄膜、PET涂布聚硅氮烷、流延聚丙烯薄膜(CPP)、CPP镀铝薄膜、三氧化二铝复合PET/CPP、共聚酯塑料及其组合所组成的群组。The gas supply device according to claim 12, wherein the polymer film is selected from polyethylene, polypropylene, polyethylene terephthalate (PET), PET aluminized film, PET coated poly Silazane, cast polypropylene film (CPP), CPP aluminized film, aluminum oxide composite PET/CPP, copolyester plastic, and combinations thereof. 如权利要求12所述的气体供应装置,其中,所述金属膜的材料选自于由钠、镁、铝、锌、铁、锡、铅、铜、银及其组合所组成的群组。The gas supply device of claim 12, wherein the material of the metal film is selected from the group consisting of sodium, magnesium, aluminum, zinc, iron, tin, lead, copper, silver, and combinations thereof. 如权利要求第1所述的气体供应装置,其中,所述气体供应装置进一步包括产生氢气的组件。The gas supply device according to claim 1, wherein the gas supply device further includes a component that generates hydrogen. 如权利要求第16所述的气体供应装置,其中,所述产生氢气的组件包含:The gas supply device of claim 16, wherein the hydrogen generating component comprises: (1)金属氢氧化物或金属过氧化物及铝粉、(1) Metal hydroxide or metal peroxide and aluminum powder, (2)氢化物或(2) Hydride or (3)上述两者的组合。(3) A combination of the above two. 如权利要求第17所述的气体供应装置,所述金属氢氧化物包含氢氧化钙、氢氧化镁、氢氧化钠或氢氧化钾;所述金属过氧化物包含过氧化钙、过氧化镁、过氧化钠或过氧化钾;所述氢化物包含与水反应生成氢气的氢化物。The gas supply device according to claim 17, wherein the metal hydroxide comprises calcium hydroxide, magnesium hydroxide, sodium hydroxide or potassium hydroxide; the metal peroxide comprises calcium peroxide, magnesium peroxide, Sodium peroxide or potassium peroxide; the hydride includes a hydride that reacts with water to generate hydrogen. 如权利要求1所述的气体供应装置,其中,所述气体供应装置进一步包括至少一条导管,所述导管与所述分隔层连接。The gas supply device according to claim 1, wherein the gas supply device further comprises at least one pipe connected to the separation layer. 如权利要求1所述的气体供应装置,所述装置用于头部穿戴装置或美发设备。The gas supply device according to claim 1, which is used in a head wear device or hairdressing equipment. 如权利要求20所述的气体供应装置,其中,所述头部穿戴装置包括头罩、安全帽、帽子、浴帽或泳帽。The gas supply device according to claim 20, wherein the head wear device comprises a hood, a safety helmet, a hat, a shower cap, or a swimming cap. 如权利要求20所述的气体供应装置,其中,所述美发设备包括吹风机、头发烘干机或烫发机。The gas supply device according to claim 20, wherein the hairdressing equipment includes a hair dryer, a hair dryer, or a hair iron. 一种如权利要求1所述的气体供应装置用于淡化发色的用途,其提供气体于头皮及头发,其中所述气体为氧气,并可进一步反应生成活性氧。A use of the gas supply device according to claim 1 for lightening hair color, which provides gas to the scalp and hair, wherein the gas is oxygen and can be further reacted to generate active oxygen. 如权利要求23所述的用途,其中所述气体进一步包含二氧化碳、一氧化氮及/或氢气。The use according to claim 23, wherein the gas further comprises carbon dioxide, nitric oxide and/or hydrogen. 一种如权利要求1所述的气体供应装置用于淡化发色的方法,其包括以下步骤:A method for lightening hair color with a gas supply device according to claim 1, which comprises the following steps: 步骤1:将所述气体供应装置放置于头部穿戴装置中;Step 1: Place the gas supply device in the head wear device; 步骤2:穿戴所述头部穿戴装置于欲淡化发色的位置1-4小时;Step 2: Wear the head wear device for 1-4 hours at the position where you want to lighten your hair color; 步骤3:持续使用4-5次,每次间隔1-3天。Step 3: Use it continuously for 4-5 times with an interval of 1-3 days. 如权利要求25所述的方法,其中,所述方法于步骤1之前先施用氢气于头皮及头发。26. The method of claim 25, wherein the method applies hydrogen to the scalp and hair before step 1. 如权利要求25所述的方法,其中,所述方法于使用前先喷洒少许水于所述气体供应装置。26. The method of claim 25, wherein the method first sprays a little water on the gas supply device before use. 一种如权利要求1所述的气体供应装置用于消除头发上的染剂的用途,其中,所述消除头发上的染剂,使发色变回原生发色。A use of the gas supply device as claimed in claim 1 for removing the dye on the hair, wherein the removing the dye on the hair changes the hair color back to the original hair color.
PCT/CN2020/085297 2020-04-17 2020-04-17 Gas supply device, use thereof for lightening hair color and method Ceased WO2021208060A1 (en)

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