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WO2021110627A1 - Procédé pour l'élimination d'une impureté d'alcanol éther à partir d'un flux de carbonate organique - Google Patents

Procédé pour l'élimination d'une impureté d'alcanol éther à partir d'un flux de carbonate organique Download PDF

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Publication number
WO2021110627A1
WO2021110627A1 PCT/EP2020/084020 EP2020084020W WO2021110627A1 WO 2021110627 A1 WO2021110627 A1 WO 2021110627A1 EP 2020084020 W EP2020084020 W EP 2020084020W WO 2021110627 A1 WO2021110627 A1 WO 2021110627A1
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Prior art keywords
carbonate
alkanol
extraction solvent
alkanediol
unconverted
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Inventor
Evert Van Der Heide
Kai Jürgen FISCHER
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Shell Internationale Research Maatschappij BV
Shell USA Inc
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Shell Internationale Research Maatschappij BV
Shell Oil Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/08—Purification; Separation; Stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/86—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • C07C68/065—Preparation of esters of carbonic or haloformic acids from organic carbonates from alkylene carbonates

Definitions

  • the present invention relates to a process for removing an ether alkanol impurity from a stream containing an organic carbonate and the ether alkanol impurity.
  • organic carbonates are cyclic alkylene carbonates (such as ethylene carbonate) and non-cyclic dialkyl carbonates (such as diethyl carbonate). It is well known to make cyclic alkylene carbonate by reaction of alkylene oxide (such as ethylene oxide) with carbon dioxide in the presence of a suitable catalyst. Such processes have been described for example in US4508927 and US5508442.
  • Dialkyl carbonates can be produced by reaction of alkylene carbonate with alkanol. Where alkylene carbonate (such as ethylene carbonate) is reacted with alkanol (such as ethanol), the products are dialkyl carbonate (such as diethyl carbonate) and alkanediol (such as monoethylene glycol). Such process is well-known and an example thereof is disclosed in US5359118. This document discloses a process in which di(C 1 - C 4 alkyl) carbonates alkanediols are prepared by transesterification of an alkylene carbonate with a C 1 -C 4 alkanol.
  • organic carbonate streams containing one or more ether alkanol (i.e. alkoxy alkanol) impurities may be produced.
  • ether alkanol i.e. alkoxy alkanol
  • organic carbonate streams containing one or more ether alkanol impurities may be produced.
  • a side-reaction of ethanol with ethylene oxide formed by back- reaction of ethylene carbonate into ethylene oxide and carbon dioxide, into 2-ethoxyethanol (ethyl oxitol or ethylene glycol monoethyl ether) may take place.
  • ethyl oxitol may be formed by a side-reaction of ethanol with ethylene carbonate in such a way that carbon dioxide is released and ethyl oxitol is produced. Still further, a side-reaction between ethanol and monoethylene glycol may take place producing ethyl oxitol and water. Still even further, ethyl oxitol may be formed via decarboxylation of hydroxyethyl ethyl carbonate.
  • the product stream from a reactor where ethanol and ethylene carbonate are reacted into diethyl carbonate and monoethylene glycol may comprise unconverted ethanol, unconverted ethylene carbonate, diethyl carbonate, monoethylene glycol and the above-mentioned ethyl oxitol impurity.
  • the presence of said alkoxy alkanol impurity may be detrimental in any subsequent production process.
  • Said alkoxy alkanol impurity may for example end up in the dialkyl carbonate that is used as a starting material for the synthesis of diphenyl carbonate from said dialkyl carbonate and phenol.
  • dialkyl carbonate is diethyl carbonate and the alkoxy alkanol impurity is ethyl oxitol
  • said ethyl oxitol may react with the phenol starting material and/or with the diphenyl carbonate product.
  • Alkoxy alkanols (such as ethyl oxitol) are neither good leaving groups. Therefore, in case phenyl 2- ethoxyethyl carbonate is present in a diphenyl carbonate feed to be reacted with BPA, phenol will be released easily from said phenyl 2-ethoxyethyl carbonate but not ethyl oxitol which will consequently stop the polymerization process at one end of the chain. Consequently, phenyl 2-ethoxyethyl carbonate has to be removed from diphenyl carbonate before the latter is contacted with BPA.
  • the product stream also containing unconverted ethanol and ethylene carbonate and ethyl oxitol side-product may be separated by means of distillation.
  • the boiling points for the various components in said product stream are mentioned in the table below.
  • the distillation as referred to above may result in a top stream containing diethyl carbonate and unconverted ethanol and a bottom stream containing monoethylene glycol and unconverted ethylene carbonate. Most likely, all of the ethyl oxitol ends up in the top stream. However, depending on the specific conditions under which distillation is carried out, part of the ethyl oxitol may end up in the bottom stream. Subsequently, said top stream may be further separated by means of distillation into a top stream containing unconverted ethanol which can be recycled to the reactor where diethyl carbonate and monoethylene glycol are produced, and a bottom stream containing diethyl carbonate and the ethyl oxitol impurity.
  • the ether alkanol impurity has to be removed therefrom as that might interfere said subsequent process and/or any further processes.
  • ethyl oxitol and diethyl carbonate could be separated by means of a further distillation step.
  • such separation is very cumbersome requiring many distillation steps and stages.
  • ethyl proxitol may be formed as an ether alkanol impurity.
  • Ethyl proxitol (propylene glycol monoethyl ether) comprises l-ethoxy-2-propanol and/or 2- ethoxy-l-propanol.
  • W02010063694 discloses a process for removing an ether alkanol impurity from a stream containing an organic carbonate and the ether alkanol impurity, comprising contacting the stream with an extraction solvent and separating the extraction solvent phase from the organic carbonate phase.
  • extraction solvent may be selected from the group consisting of water, C 1 -C 4 aliphatic ketones, C 1 -C 4 aliphatic alcohols and C 1 -C 4 aliphatic carboxylic acids.
  • the extraction solvent is water.
  • a disadvantage of using water as extraction solvent is that water and the ether alkanol impurity, for example ethyl oxitol, may form an azeotrope complicating the further separation of the ether alkanol impurity from the water extraction solvent, after having extracted the ether alkanol impurity from an organic carbonate stream containing such ether alkanol impurity.
  • a further disadvantage of using water as extraction solvent is that water may react, also in the absence of a catalyst, with the organic carbonate, which may be a dialkyl carbonate and/or an alkylene carbonate, which results in the loss of valuable organic carbonate.
  • a dialkyl carbonate may be hydrolysed, upon adding water, into the corresponding alkanol and carbonic acid (H 2 CO 3 ) which is converted into water and carbon dioxide.
  • an alkylene carbonate may be hydrolysed into the corresponding alkanediol and said carbonic acid.
  • the density of water (1.00 g/ml at 25 °C) may be similar to the density of organic carbonates from which the ether alkanol impurity is to be extracted (e.g. diethyl carbonate has a density of 0.98 g/ml at 25 °C). This complicates the formation of separate extractant (water) and organic carbonate phases.
  • the resulting extractant (water) phase containing the ether alkanol impurity may need to be subjected to a distillation in order to remove the ether alkanol impurity therefrom, which may disadvantageously result in having to separate the water as an overhead stream rather than boiling off a relatively light ether alkanol impurity to separate it from the extractant.
  • the present invention relates to a process for removing an ether alkanol impurity from a stream containing an organic carbonate and the ether alkanol impurity, comprising contacting the stream with an extraction solvent and separating the extraction solvent phase comprising the ether alkanol impurity from the organic carbonate phase, said process involving liquid-liquid extraction, wherein the extraction solvent comprises an alkanol containing 2 or more hydroxyl groups.
  • the present invention also relates to a process for the preparation of a dialkyl carbonate and an alkanediol, wherein a stream containing the dialkyl carbonate and an ether alkanol impurity is subjected to the above-described extraction process.
  • the present invention relates to a process for making a diaryl carbonate, comprising reacting an aryl alcohol with a stream containing a dialkyl carbonate from which stream an ether alkanol impurity has been removed in accordance with the above-described extraction process.
  • Figures 1 and 2 show processes for the preparation of a dialkyl carbonate and an alkanediol involving the present extraction process as one of the steps.
  • said process may comprise one or more intermediate steps between subsequent steps. Further, said process may comprise one or more additional steps preceding the first step and/or following the last step.
  • a mixture or a stream or a catalyst comprises two or more components
  • these components are to be selected in an overall amount not to exceed 100%.
  • an ether alkanol impurity is removed from a stream containing an organic carbonate and the ether alkanol impurity.
  • An ether alkanol is identical to an alkoxy alkanol, and both terms are used interchangeably in the present specification.
  • the extraction process of the present invention is characterized by contacting a stream containing an organic carbonate and an ether alkanol impurity with an extraction solvent which is an alkanol containing 2 or more hydroxyl groups, resulting in an extraction solvent phase comprising the ether alkanol impurity and an organic carbonate phase, and separating the extraction solvent phase from the organic carbonate phase.
  • contacting the stream containing an organic carbonate and the ether alkanol impurity with an extraction solvent means that the former stream is contacted with another stream comprising extraction solvent.
  • the extraction process is a process involving liquid-liquid extraction.
  • the organic carbonate phase (or raffinate phase) may be the upper phase and the extraction solvent phase (or extract phase) may be the lower phase.
  • the organic carbonate may be a dialkyl carbonate, a diaryl carbonate, an alkyl aryl carbonate, an alkylene carbonate or a mixture of such organic carbonates, preferably a dialkyl carbonate and/or an alkylene carbonate.
  • Said diaryl carbonate may be diphenyl carbonate.
  • Said alkyl aryl carbonate may be an alkyl phenyl carbonate, wherein the alkyl group may be as defined below for a dialkyl carbonate.
  • Said alkylene carbonate may be a C 2 -C 6 alkylene carbonate, more suitably a C 2 -C 4 alkylene carbonate, most suitably a C 2 -C 3 alkylene carbonate.
  • said alkylene carbonate may be ethylene carbonate or propylene carbonate.
  • the above-mentioned organic carbonate is a dialkyl carbonate, which may be a di(C 1 -C 4 alkyl) carbonate, more suitably a di(C 1 -C 3 alkyl) carbonate, most suitably a di(C 2 -C 3 alkyl) carbonate.
  • dialkyl carbonate is dimethyl carbonate, diethyl carbonate or diisopropyl carbonate, more preferably diethyl carbonate or diisopropyl carbonate, most preferably diethyl carbonate.
  • the ether alkanol impurity is an alkoxy alkanol which is an alkanol of formula R 1 OH wherein R 1 is an alkoxyalkyl group.
  • the alkoxy part in said alkoxyalkyl group is preferably methoxy, ethoxy or isopropoxy, more preferably ethoxy or isopropoxy, most preferably ethoxy.
  • the alkyl part in said alkoxyalkyl group is preferably ethyl or propyl, most preferably ethyl.
  • the ether alkanol impurity may for example be 2-ethoxyethanol or 1-ethoxy-2-propanol and/or 2-ethoxy-1- propanol.
  • the amount of the ether alkanol impurity in the latter stream may be comprised in the range of from 10 parts per million by weight (ppmw) to 10 wt.%, specifically 100 ppmw to 9 wt.%, more specifically 0.1 to 8 wt.%, more specifically 0.3 to 7 wt.%, more specifically 0.5 to 6 wt.% and most specifically 0.5 to 5 wt.%.
  • the stream containing an organic carbonate and the ether alkanol impurity, to be treated in accordance with the extraction process of the present invention may comprise an alkanol containing 2 or more hydroxyl groups, for example an alkanediol such as monoethylene glycol. Such alkanediol may advantageously be used as additional extraction solvent.
  • alkanediol extraction solvent such as monoethylene glycol
  • alkanediol is a component that is already formed in the overall process so that less extraction solvent needs to be added to remove the ether alkanol impurity from a stream containing an organic carbonate, the ether alkanol impurity and said alkanediol.
  • the extraction solvent comprises an alkanol containing 2 or more hydroxyl groups, suitably 3 or more hydroxyl groups, preferably of from 2 to 5 hydroxyl groups, more preferably of from 2 to 4 hydroxyl groups, more preferably of from 2 to 3 hydroxyl groups, most preferably 3 hydroxyl groups.
  • said alkanol may contain 2 to 9 carbon atoms, suitably 2 to 7 carbon atoms, more suitably 2 to 5 carbon atoms, most suitably 2 to 3 carbon atoms.
  • said alkanol contains at least 2 carbon atoms and at least 2 hydroxyl groups, in which alkanol each hydroxyl group is bonded to a different carbon atom.
  • alkanol Suitable examples of said alkanol are monoethylene glycol, monopropylene glycol, glycerol, erythritol, xylitol and sorbitol, more suitably monoethylene glycol, monopropylene glycol and glycerol. More preferably, said alkanol is monoethylene glycol or glycerol, most preferably glycerol.
  • any mixture of two or more of the above-described extraction solvents may be used.
  • the weight ratio of said two or more extraction solvents may vary within a wide range. In the case of two extraction solvents, this weight ratio may be of from 0.1:10 to 10:1, suitably of from 0.5:1 to 5:1.
  • the stream containing an organic carbonate and the ether alkanol impurity, to be treated in accordance with the extraction process of the present invention comprises an alkanol containing 2 or more hydroxyl groups, for example an alkanediol such as monoethylene glycol, said alkanol is considered as an extraction solvent and should therefore be included in the above-mentioned weight ratio of said two or more extraction solvents.
  • a preferred mixture of extraction solvents is a mixture of an alkanol containing 2 hydroxyl groups, for example an alkanediol such as monoethylene glycol, with an alkanol containing 3 hydroxyl groups, for example glycerol.
  • the density of the lower phase is at least 0.05 g/ml, more preferably at least 0.10 g/ml, even more preferably at least 0.15 g/ml, most preferably at least 0.20 g/ml higher than the density of the upper phase.
  • density difference may also be achieved by adding additives that change the density of one of the phases, such additives including salts.
  • the contacting of the stream containing the organic carbonate and the ether alkanol impurity with the extraction solvent results in the formation of an extraction solvent phase comprising the ether alkanol impurity and an organic carbonate phase, thereby separating the ether alkanol impurity from the organic carbonate.
  • the time for contacting the stream containing the organic carbonate and the ether alkanol impurity with the extraction solvent in the present process should be sufficient to complete the extraction process.
  • Said contacting time may be in the order of 10 seconds to 5 hours, for example 10 seconds to 2 hours.
  • the temperature at which the present extraction process is performed may be comprised in the range of from 0 to 150 °C, for example 10 to 100 °C.
  • the feed to the present extraction process is a product mixture obtained by reacting an alkylene carbonate and an alkanol and containing unconverted alkylene carbonate, unconverted alkanol, dialkyl carbonate, alkanediol and an ether alkanol impurity, the feed does not have to be cooled before sending it to the present extraction process.
  • a suitable weight ratio of extraction solvent to the stream containing the organic carbonate and the ether alkanol impurity is comprised in the range of from 10:1 to 1:10, for example 5:1 to 1:5. If the stream containing an organic carbonate and the ether alkanol impurity, to be treated in accordance with the extraction process of the present invention, comprises an alkanol containing 2 or more hydroxyl groups, for example an alkanediol such as monoethylene glycol, said alkanol is considered as an extraction solvent and should therefore only be included as "extraction solvent" in the above-mentioned weight ratio of extraction solvent to the stream containing the organic carbonate and the ether alkanol impurity.
  • an alkanediol such as monoethylene glycol
  • the pressure at which the present extraction process is carried out may be subatmospheric, atmospheric or superatmospheric pressure, preferably atmospheric or superatmospheric pressure.
  • the extraction solvent phase should be separated from the organic carbonate phase, in accordance with the invention, so that a stream containing the organic carbonate from which stream the ether alkanol impurity has been removed, remains. Any skilled person can find a suitable method of separating the extraction solvent phase from the organic carbonate phase in the present process.
  • the stream containing the organic carbonate and the ether alkanol impurity is a stream containing a dialkyl carbonate that has been produced from reacting an alkanol with an alkylene carbonate
  • the stream usually contains unconverted alkanol reactant in addition to the ether alkanol impurity.
  • the stream containing the organic carbonate and the ether alkanol impurity is a stream containing dialkyl carbonate, unconverted alkanol and the ether alkanol impurity
  • contacting of said stream with an extraction solvent to extract and remove the ether alkanol impurity in accordance with the present invention may be performed after the step wherein dialkyl carbonate is separated from unconverted alkanol.
  • Separation of the dialkyl carbonate from unconverted alkanol may be effected by means of distillation. Such distillation results in a top stream containing the unconverted alkanol (such as ethanol) and a bottom stream containing the dialkyl carbonate (such as diethyl carbonate), in a case where the unconverted alkanol has been reacted in a preceding step with an alkylene carbonate to produce the dialkyl carbonate and an alkanediol.
  • the unconverted alkanol such as ethanol
  • dialkyl carbonate such as diethyl carbonate
  • the present invention advantageously results in the removal of an ether alkanol impurity in organic carbonate streams, which ether alkanol impurity might have interfered in any subsequent process using said organic carbonate if it would not have been removed.
  • the present invention also relates to a process for the preparation of a dialkyl carbonate and an alkanediol, comprising:
  • step (d) separating unconverted alkanol from the top stream obtained in step (b) to obtain a bottom stream containing dialkyl carbonate and the ether alkanol impurity; and (e) contacting the bottom stream obtained in step (d) with an extraction solvent and separating the extraction solvent phase comprising the ether alkanol impurity from the dialkyl carbonate phase, wherein the extraction solvent comprises an alkanol containing 2 or more hydroxyl groups;
  • step (f) removing the ether alkanol impurity from the extraction solvent phase obtained in step (e) and recycling the extraction solvent to step (e).
  • Step (a) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises reacting an alkylene carbonate and an alkanol to obtain a product mixture containing unconverted alkylene carbonate, unconverted alkanol, dialkyl carbonate, alkanediol and an ether alkanol impurity.
  • step (a) includes the reaction of an alkylene carbonate with an alkanol.
  • Said alkylene carbonate may be a C 2 -C 6 alkylene carbonate, more suitably a C 2 -C 4 alkylene carbonate, most suitably a C 2 -C 3 alkylene carbonate.
  • said alkylene carbonate is ethylene carbonate or propylene carbonate, most preferably ethylene carbonate.
  • the nature of the alkylene carbonate determines the nature of the alkanediol product: for example, reaction of ethylene carbonate with an alkanol results in monoethylene glycol, which is 1,2-ethanediol (the alkanediol).
  • said alkanol may be a C 1 -C 4 alkanol, more suitably a C 1 -C 3 alkanol, most suitably a C 2 -C 3 alkanol.
  • said alkanol contains 1 or 2 hydroxy groups, most preferably 1 hydroxy group.
  • said alkanol is methanol, ethanol or isopropanol, more preferably ethanol or isopropanol, most preferably ethanol.
  • the nature of the alkanol determines the nature of the dialkyl carbonate product: for example, reaction of an alkylene carbonate with ethanol results in diethyl carbonate (the dialkyl carbonate).
  • the product mixture obtained in step (a) contains an ether alkanol impurity.
  • an ether alkanol is identical to an alkoxy alkanol.
  • An alkoxy alkanol is an alkanol of formula R 1 OH wherein R 1 is an alkoxyalkyl group.
  • the alkoxy part in said alkoxyalkyl group is directly or indirectly derived from the alkanol used in step (a), whereas the alkyl part in said alkoxyalkyl group is directly or indirectly derived from the alkylene carbonate used in step (a). Therefore, the same preferences apply as discussed above with reference to the alkanol and alkylene carbonate used in step (a).
  • the alkoxy part in said alkoxyalkyl group is preferably methoxy, ethoxy or isopropoxy, more preferably ethoxy or isopropoxy, most preferably ethoxy.
  • the alkyl part in said alkoxyalkyl group is preferably ethyl or propyl, most preferably ethyl.
  • the ether alkanol impurity may for example be 2-ethoxyethanol or 1-ethoxy-2-propanol and/or 2-ethoxy-1-propanol.
  • the alkylene carbonate is ethylene carbonate
  • the alkanol is ethanol
  • the dialkyl carbonate is diethyl carbonate
  • the alkanediol is monoethylene glycol
  • the ether alkanol impurity is 2-ethoxyethanol.
  • 2- Ethoxyethanol may also be referred to as ethyl oxitol.
  • the alkylene carbonate is propylene carbonate
  • the alkanol is ethanol
  • the dialkyl carbonate is diethyl carbonate
  • the alkanediol is monopropylene glycol
  • the ether alkanol impurity is ethyl proxitol (propylene glycol monoethyl ether) which comprises 1-ethoxy-2-propanol and/or 2-ethoxy-1-propanol.
  • step (a) for the preparation of a dialkyl carbonate and an alkanediol a catalyst is used, more specificly a transesterification catalyst.
  • the transesterification catalyst that may be used in step (a) may be one of many suitable homogeneous and heterogeneous transesterification catalysts known from prior art.
  • suitable homogeneous transesterification catalysts have been described in US5359118 and include hydrides, oxides, hydroxides, alkanolates, amides, or salts of alkali metals, i.e., lithium, sodium, potassium, rubidium and cesium.
  • Preferred homogeneous transesterification catalysts are hydroxides or alkanolates of potassium or sodium.
  • Other suitable homogeneous transesterification catalysts are alkali metal salts, such as acetates, propionates, butyrates, or carbonates.
  • Suitable catalysts are described in US5359118 and the references mentioned therein, such as EP274953A, US3803201, EP1082A, and EP180387A.
  • Suitable heterogeneous catalysts include ion exchange resins that contain functional groups. Suitable functional groups include tertiary amine groups and quaternary ammonium groups, and also sulphonic acid and carboxylic acid groups. Further suitable catalysts include alkali metal and alkaline earth metal silicates. Suitable catalysts have been disclosed in US4062884 and US4691041.
  • the heterogeneous catalyst may be selected from ion exchange resins comprising a polystyrene matrix and tertiary amine functional groups.
  • a suitable heterogeneous transesterification catalyst may be a catalyst comprising an element from Group 4 (such as titanium), Group 5 (such as vanadium), Group 6 (such as chromium or molybdenum) or Group 12 (such as zinc) of the Periodic Table of the Elements, or tin or lead, or a combination of such elements, such as a combination of zinc with chromium (for example zinc chromite).
  • Said elements may be present in the catalyst as an oxide, such as zinc oxide.
  • a heterogeneous catalyst comprising zinc is used.
  • the conditions in step (a) include a temperature of from 10 to 200 °C, and a pressure of from 0.5 to 50 bara (5x10 4 to 5x10 6 N/m 2 ).
  • said pressure ranges from 1 to 20 bar, more preferably 1.5 to 20 bar, most preferably 2 to 15 bar
  • said temperature ranges from 30 to 200 °C, more preferably 40 to 170 °C, most preferably 50 to 150 °C.
  • step (a) preferably an excess of the alkanol over the alkylene carbonate is used in step (a).
  • the molar ratio of alkanol to alkylene carbonate in step (a) is suitably of from 1.01:1 to 25:1, preferably of from 2:1 to 20:1, more preferably of from 3:1 to 15:1, most preferably from 3:1 to 13:1.
  • the weight hourly space velocity (WHSV) in step (a) may suitably range of from 0.1 to 100 kg/kg cat .hr ("kg cat " refers to the catalyst amount), more suitably 0.5 to 50 kg/kg cat .hr, more suitably 1 to 20 kg/kg cat .hr, more suitably 1 to 10 kg/kg cat .hr.
  • Step (a) may be carried out in a reactive distillation column, as described in US5359118. This would entail that the reaction is carried out counter-currently.
  • the distillation column may contain trays with bubble caps, sieve trays, or Raschig rings. The skilled person will realise that several types of packings of catalyst and several tray configurations will be possible. Suitable columns have been described in, e.g., Ullmann's Encyclopedia of Industrial Chemistry, 5 th ed. Vol. B4, pp 321 ff, 1992.
  • the alkylene carbonate will generally have a higher boiling point than the alkanol. In the case of ethylene and propylene carbonate the atmospheric boiling points are above 240 °C. Therefore, in general, the alkylene carbonate will be fed at the upper part of a reactive distillation column and alkanol will be fed at the lower part of such column. The alkylene carbonate will flow downwardly, and the alkanol will flow upwardly.
  • step (a) is conducted in a co-current manner.
  • a suitable way to operate is to carry out the reaction in a trickle-flow manner wherein the reactants part in vapour phase and part in liquid phase drip down over the catalyst.
  • a more preferred way to operate step (a) is in a reactor with only liquids.
  • a suitable reaction zone of this type is a pipe-type reaction zone wherein the reaction is conducted in a plug flow manner.
  • step (a) may be carried out in one plug flow reactor or in a series of two or more plug flow reactors. This will enable the reaction to approach equilibrium.
  • step (a) is to conduct step (a) in a continuously stirred tank reactor (CSTR).
  • CSTR continuously stirred tank reactor
  • the effluent from the CSTR is preferably subjected to a post reaction in a plug flow reactor so that the reaction can approach equilibrium.
  • Step (a) is preferably carried out continuously.
  • unconverted alkylene carbonate and alkanol are preferably recycled.
  • Step (b) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises separating unconverted alkylene carbonate and alkanediol from the product mixture obtained in step (a) to obtain a top stream containing unconverted alkanol, dialkyl carbonate and the ether alkanol impurity.
  • Said step (b) may be effected by means of distillation.
  • the bottom stream obtained in step (b) comprises unconverted alkylene carbonate and alkanediol.
  • Step (c) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises recovering the alkanediol.
  • Said step (c) may be effected by means of distillation.
  • the alkanediol may be recovered by separating the bottom stream containing unconverted alkylene carbonate and alkanediol obtained in step (b) to obtain a top stream containing alkanediol and a bottom stream containing unconverted alkylene carbonate. Unconverted alkylene carbonate in said bottom stream may be recycled to step (a).
  • Step (d) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises separating unconverted alkanol from the top stream obtained in step (b) to obtain a bottom stream containing dialkyl carbonate and the ether alkanol impurity. Said step (d) may be effected by means of distillation. The top stream obtained in step (d) comprises unconverted alkanol. Unconverted alkanol in said top stream may be recycled to step (a).
  • steps (c), (d) and (f) may be effected in any known way.
  • steps (b), (c) and (d) they may be recovered by applying the process as disclosed in W02011039113, the disclosure of which is incorporated herein by reference.
  • the amount of the ether alkanol impurity in the bottom stream obtained in step (d) and containing dialkyl carbonate and said impurity may be comprised in the range of from 10 parts per million by weight (ppmw) to 10 wt.%, specifically 100 ppmw to 9 wt.%, more specifically 0.1 to 8 wt.%, more specifically 0.3 to 7 wt.%, more specifically 0.5 to 6 wt.% and most specifically 0.5 to 5 wt.%.
  • Step (e) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises contacting the bottom stream obtained in step (d) with an extraction solvent, resulting in an extraction solvent phase comprising the ether alkanol impurity and a dialkyl carbonate phase, and separating the extraction solvent phase from the dialkyl carbonate phase, wherein the extraction solvent comprises an alkanol containing 2 or more hydroxyl groups.
  • contacting the bottom stream obtained in step (d) with an extraction solvent means that the former stream is contacted with another stream comprising extraction solvent.
  • step (e) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol equally apply to step (e) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol.
  • Step (f) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises removing the ether alkanol impurity from the extraction solvent phase obtained in step (e) and recycling the extraction solvent to step (e).
  • Step (f) may be effected by separating the extraction solvent phase comprising the ether alkanol impurity obtained in step (e) to obtain a top stream comprising the ether alkanol impurity and a bottom stream comprising the extraction solvent. Said separation may be effected by means of distillation. At least a portion of the ether alkanol impurity may advantageously be recovered as a high purity ether alkanol product.
  • step (e) A portion of extraction solvent containing bottom stream(s) obtained in step (e) and/or step (f), preferably step (e), may be removed as a bleed to prevent a build-up of any heavies. In case of such bleed, an extraction solvent containing make-up stream needs to be fed to step (e).
  • the dialkyl carbonate phase obtained in step (e) additionally comprises extraction solvent.
  • the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol may comprise a step (g) which comprises removing extraction solvent from the dialkyl carbonate phase obtained in step (e) and recycling the extraction solvent to step (e).
  • step (g) may be effected by separating the dialkyl carbonate phase comprising extraction solvent obtained in step (e) to obtain a top stream comprising the dialkyl carbonate and a bottom stream comprising the extraction solvent. Said separation may be effected by means of distillation. The extraction solvent in said bottom stream is then recycled to step (e).
  • the present invention also relates to a process for the preparation of a dialkyl carbonate and an alkanediol, comprising:
  • step (ii) contacting the product mixture obtained in step (i) with an extraction solvent and separating the extraction solvent phase comprising unconverted alkanol, alkanediol and the ether alkanol impurity from the organic carbonate phase comprising unconverted alkylene carbonate and dialkyl carbonate, wherein the extraction solvent comprises an alkanol containing 2 or more hydroxyl groups;
  • step (iv) separating the extraction solvent phase obtained in step (ii) into a top stream comprising unconverted alkanol and the ether alkanol impurity and a bottom stream comprising extraction solvent and alkanediol;
  • step (v) recycling extraction solvent from the bottom stream obtained in step (iv) to step (ii).
  • An advantage of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol involving steps (i) to (v), as compared to the other process for the preparation of a dialkyl carbonate and an alkanediol involving steps (a) to (f) as described above, is that the formation of an azeotrope of the alkanediol (e.g. ethylene glycol) and the unconverted alkylene carbonate (e.g. ethylene carbonate) is avoided as in extraction step (ii) unconverted alkylene carbonate ends up in the organic carbonate phase and the alkanediol ends up in the extraction solvent phase.
  • the alkanediol e.g. ethylene glycol
  • unconverted alkylene carbonate e.g. ethylene carbonate
  • step (c) of the other process comprises recovering the alkanediol which may be effected by means of distillation, to obtain a top stream containing alkanediol and a bottom stream containing unconverted alkylene carbonate, in which distillation step the formation of such azeotrope may be problematic as this may result in a top stream containing alkanediol and additionally unconverted alkylene carbonate and a bottom stream containing unconverted alkylene carbonate.
  • W02008090108 addresses this by a further purification procedure which involves first converting the alkylene carbonate in the latter top stream by hydrolysis, upon adding water, into alkanediol and carbon dioxide and further separating the resulting stream to obtain purified alkanediol.
  • a disadvantage is that such additional purification procedure involving hydrolysis and further separation is cumbersome, and results in a lower amount of unconverted alkylene carbonate that is recycled to the reactor, thereby resulting in a lower overall yield of the desired dialkyl carbonate product.
  • An advantage of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol involving steps (i) to (v), is that a cumbersome additional purification procedure involving hydrolysis and further separation as disclosed in said WO2008090108, is advantageously avoided as already in extraction step (ii) alkanediol and alkylene carbonate are separated from each other by means of extraction.
  • a cumbersome additional purification procedure involving hydrolysis and further separation as disclosed in said WO2008090108 is advantageously avoided as already in extraction step (ii) alkanediol and alkylene carbonate are separated from each other by means of extraction.
  • An additional advantage of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol involving steps (i) to (v), as compared to the other process for the preparation of a dialkyl carbonate and an alkanediol involving steps (a) to (f) as described above, is that in case any polyalkylene glycols (polyglycols), for example diethylene glycol, are formed as a by-product, these end up in the bottom stream comprising extraction solvent and alkanediol obtained in step (iv) of the present process.
  • polyalkylene glycols polyglycols
  • a problem addressed in above-mentioned WO2008090108 is the potential formation of such polyglycols in the preparation of a dialkyl carbonate and an alkanediol from an alkylene carbonate and an alkanol.
  • such polyglycols end up in the above-mentioned bottom stream containing unconverted alkylene carbonate. By recycling the latter bottom stream to the reactor, these higher-boiling polyglycol by-products build up.
  • any unconverted alkylene carbonate from the bottom stream comprising extraction solvent and alkanediol obtained in step (iv), does not need to be recycled to reaction step (i), there is advantageously neither any recycle of any polyglycols to reaction step (i). Therefore, in the present invention, there is no need to split a stream comprising unconverted alkylene carbonate and polyglycols, as in the process of above-mentioned WO2008090108 wherein one part is recycled to the reactor and the other part is hydrolysed.
  • polyglycols if polyglycols are formed they may be sent, in step (v), to extraction step (ii) together with extraction solvent from the bottom stream obtained in step (iv), in which extraction step (ii) such polyglycols containing 2 hydroxyl groups may advantageously function as additional extraction solvent.
  • extraction step (ii) such polyglycols containing 2 hydroxyl groups may advantageously function as additional extraction solvent.
  • advantageously by not having to split a stream comprising unconverted alkylene carbonate and polyglycols and then hydrolysing one part as taught in said WO2008090108, even more alkylene carbonate can be recycled to the reaction step resulting in a higher overall yield of the desired dialkyl carbonate product.
  • Step (i) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises reacting an alkylene carbonate and an alkanol to obtain a product mixture containing unconverted alkylene carbonate, unconverted alkanol, dialkyl carbonate, alkanediol and an ether alkanol impurity.
  • step (i) may be carried out in the same way as above-described step (a).
  • the above-described features, preferences and embodiments in relation to step (a) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol equally apply to said step (i).
  • Step (ii) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises contacting the product mixture obtained in step (i) with an extraction solvent and separating the extraction solvent phase comprising unconverted alkanol, alkanediol and the ether alkanol impurity from the organic carbonate phase comprising unconverted alkylene carbonate and dialkyl carbonate, wherein the extraction solvent comprises an alkanol containing 2 or more hydroxyl groups.
  • contacting the product mixture obtained in step (i) with an extraction solvent means that a stream comprising the product mixture obtained in step (i) is contacted with another stream comprising extraction solvent.
  • step (ii) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol also contains alkanediol containing 2 hydroxyl groups, such as monoethylene glycol.
  • alkanediol may advantageously be used as additional extraction solvent.
  • reaction step (i) is a component that is already formed in the overall process, in reaction step (i), so that less extraction solvent needs to be added in extraction step
  • the total amount of unconverted alkanol and the ether alkanol impurity in the product mixture that is subjected to above-mentioned extraction step (ii) may be comprised in the range of from 10 parts per million by weight (ppmw) to 10 wt.%, specifically 100 ppmw to 9 wt.%, more specifically 0.1 to 8 wt.%, more specifically 0.3 to 7 wt.%, more specifically 0.5 to 6 wt.% and most specifically 0.5 to 5 wt.%.
  • step (i) it may be preferred, for example in a case where there is a relatively large amount of unconverted alkanol in the product mixture obtained in step (i), to first remove unconverted alkanol from that product mixture before subjecting it to above-mentioned extraction step (ii).
  • Preferably 10 to 80%, more preferably 20 to 70%, of unconverted alkanol may be removed in such case from the product mixture obtained in step (i).
  • Such removal of unconverted alkanol may be effected in any known way, for example by distillation including a vapour-liquid flash.
  • Step (iii) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises recovering the dialkyl carbonate.
  • Said step (iii) may be effected by means of distillation.
  • the dialkyl carbonate may be recovered by separating the organic carbonate phase comprising unconverted alkylene carbonate and dialkyl carbonate obtained in step (ii) to obtain a top stream containing dialkyl carbonate and a bottom stream containing unconverted alkylene carbonate. Unconverted alkylene carbonate in said bottom stream may be recycled to step (i).
  • said bottom stream additionally comprises alkanediol and/or extraction solvent.
  • said bottom stream comprises less than 15 wt.% of alkanediol.
  • the organic carbonate phase obtained in step (ii) additionally comprises alkanediol and/or extraction solvent as mentioned above and/or in a case wherein the above-mentioned bottom stream containing unconverted alkylene carbonate is combined with alkanediol and extraction solvent from a stream originating from the extraction solvent phase obtained in step (ii), said bottom stream or the combined stream, which comprises unconverted alkylene carbonate and additionally alkanediol and/or extraction solvent, may be separated into a top stream containing unconverted alkylene carbonate and a bottom stream containing alkanediol and/or extraction solvent. Unconverted alkylene carbonate in said top stream may be recycled to step (i).
  • Alkanediol and/or extraction solvent in said bottom stream may be recycled to step (ii).
  • step (iii) results in a bottom stream containing unconverted alkylene carbonate and additionally alkanediol and/or extraction solvent
  • said bottom stream may be split into two streams.
  • One split stream may then be recycled to step (ii).
  • the other split stream may be separated into a top stream containing unconverted alkylene carbonate and a bottom stream containing alkanediol and/or extraction solvent, optionally after first combining said other split stream with a split stream resulting from step (v) and comprising alkanediol and extraction solvent as described below. Said separations may be effected by means of distillation.
  • Step (iv) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises separating the extraction solvent phase obtained in step (ii) into a top stream comprising unconverted alkanol and the ether alkanol impurity and a bottom stream comprising extraction solvent and alkanediol.
  • said bottom stream additionally comprises unconverted alkylene carbonate.
  • said bottom stream comprises less than 50 wt.% of unconverted alkylene carbonate.
  • said top stream comprising unconverted alkanol and the ether alkanol impurity may be separated into a top stream comprising unconverted alkanol, which may be recycled to step (i), and a bottom stream comprising the ether alkanol impurity. Said separations may be effected by means of distillation.
  • Step (v) of the above-mentioned process for the preparation of a dialkyl carbonate and an alkanediol comprises recycling extraction solvent from the bottom stream obtained in step (iv), comprising extraction solvent and alkanediol, to step (ii).
  • Step (v) may comprise separating the bottom stream obtained in step (iv) into a top stream comprising alkanediol, thereby recovering alkanediol as one of the products, and a bottom stream comprising extraction solvent which may be recycled to step (ii).
  • the bottom stream obtained in step (iv) may be split into two streams. As described above, one split stream may then be separated into a top stream comprising alkanediol, thereby recovering alkanediol as one of the products, and a bottom stream comprising extraction solvent which may be recycled to step (ii).
  • the other split stream may be combined with a bottom stream obtained in step (iii) comprising unconverted alkylene carbonate and additionally alkanediol and/or extraction solvent, and then separated in a way as described above. Said separations may be effected by means of distillation.
  • steps (iii), (iv) and (v) may be effected in any known way.
  • the present invention relates to a process for making a diaryl carbonate, comprising reacting an aryl alcohol with a stream containing a dialkyl carbonate from which stream an ether alkanol impurity has been removed in accordance with any one of the above-described processes.
  • the present invention relates to a process for making a diaryl carbonate, comprising contacting, in the presence of a transesterification catalyst, an aryl alcohol with a stream containing a dialkyl carbonate from which stream an ether alkanol impurity has been removed in accordance with any one of the above-described processes.
  • the present invention also relates to a process for making a diaryl carbonate, comprising removing an ether alkanol impurity from a stream containing a dialkyl carbonate and the ether alkanol impurity in accordance with any one of the above-described processes, and then contacting, in the presence of a transesterification catalyst, an aryl alcohol with the stream containing the dialkyl carbonate.
  • the diaryl carbonate is diphenyl carbonate and the aryl alcohol is phenol.
  • the above-described transesterification catalyst and other transesterification conditions, as described for step (a), are equally applicable to said processes for making a diaryl carbonate.
  • ethanol is passed via line 1 into a reactor 2.
  • Reactor 2 can suitably be a continuously stirred tank reactor.
  • ethylene carbonate is also fed into reactor 2.
  • a transesterification catalyst may be present or may be fed continuously to the reactor. The catalyst may be mixed with one of the reactants or fed to the reactor via a separate line (not shown).
  • a product mixture containing unconverted ethylene carbonate, unconverted ethanol, diethyl carbonate, ethylene glycol (an alkanediol) and 2- ethoxyethanol (an ether alkanol impurity; ethyl oxitol) is withdrawn from reactor 2 via line 4.
  • the mixture is passed to a distillation column 5 where the product is separated into a top stream comprising diethyl carbonate, unconverted ethanol and ethyl oxitol that is withdrawn via line 7, and a bottom stream comprising ethylene glycol and unconverted ethylene carbonate that is withdrawn via line 6.
  • the bottom stream in line 6 is subjected to distillation in a distillation column 8, resulting in a top stream comprising ethylene glycol that is recovered via line 10 and a bottom stream comprising unconverted ethylene carbonate that is recycled via lines 9 and 3 to reactor 2.
  • the top stream comprising diethyl carbonate, unconverted ethanol and ethyl oxitol originating from distillation column 5 is subjected to distillation in a distillation column 11, resulting in a top stream comprising unconverted ethanol that is recycled via lines 13 and 1 to reactor 2 and a bottom stream comprising diethyl carbonate, ethyl oxitol and unconverted ethanol.
  • the latter bottom stream is fed via line 12 to an extraction column 14 at a lower part thereof.
  • the stream comprising diethyl carbonate, ethyl oxitol and unconverted ethanol is subjected to liquid-liquid extraction using glycerol as extraction solvent which is fed to the column at an upper part thereof.
  • the resulting top stream from extraction column 14 comprises diethyl carbonate.
  • the resulting bottom stream in line 15 comprises unconverted ethanol, ethyl oxitol and glycerol and is split into two substreams 15a and 15b.
  • Substream 15a ("fat” extractant stream) is recycled to extraction column 14 at an upper part thereof.
  • Substream 15b is sent to a distillation column 17, resulting in a top stream comprising unconverted ethanol and ethyl oxitol in line 19 and a bottom stream comprising glycerol in line 18.
  • the latter bottom stream 18 (“lean” extractant stream) may contain some ethyl oxitol and is recycled to extraction column 14 at a position which is above the position at which substream 15a is fed to that column.
  • the stream comprising unconverted ethanol and ethyl oxitol in line 19 is sent to a distillation column 20, resulting in a top stream comprising unconverted ethanol that is recycled via lines 22 and 1 to reactor 2 and a bottom stream comprising ethyl oxitol in line 21.
  • ethanol is passed via line 1 into a reactor 2.
  • Reactor 2 can suitably be a continuously stirred tank reactor.
  • ethylene carbonate is also fed into reactor 2.
  • a transesterification catalyst may be present or may be fed continuously to the reactor. The catalyst may be mixed with one of the reactants or fed to the reactor via a separate line (not shown).
  • a product mixture containing unconverted ethylene carbonate, unconverted ethanol, diethyl carbonate, ethylene glycol (an alkanediol) and 2- ethoxyethanol (an ether alkanol impurity; ethyl oxitol) is withdrawn from reactor 2 via line 4.
  • Via line 4 the mixture is passed to an extraction column 5 at a lower part thereof. In said column, said product mixture is subjected to liquid- liquid extraction using glycerol as extraction solvent which is fed to the column at an upper part thereof.
  • the resulting top stream from extraction column 5 in line 7 comprises diethyl carbonate, unconverted ethylene carbonate, ethylene glycol and glycerol, and is subjected to distillation in a distillation column 8, resulting in a top stream comprising diethyl carbonate that is recovered via line 9 and a bottom stream comprising unconverted ethylene carbonate, ethylene glycol and glycerol in line 10.
  • Stream 10 is split into two substreams 10a and 10b. Substream 10a is recycled to extraction column 5.
  • the resulting bottom stream from extraction column 5 in line 6 comprises unconverted ethanol, ethyl oxitol, ethylene glycol and glycerol.
  • said bottom stream may be split (not shown in Figure 2, but shown in Figure 1 in relation to stream 15), wherein one substream is recycled to extraction column 5 at an upper part thereof and the other substream is sent to a distillation column 11.
  • Stream 6 (without split) is subjected to distillation in distillation column 11, resulting in a top stream comprising unconverted ethanol and ethyl oxitol in line 12 and a bottom stream comprising ethylene glycol and glycerol in line 13.
  • the stream in line 12 is subjected to distillation in a distillation column 14, resulting in a top stream comprising unconverted ethanol that is recycled via lines 15 and 1 to reactor 2, and a bottom stream comprising ethyl oxitol in line 16.
  • the stream in line 13 is optionally split into two substreams 13a and 13b.
  • Substream 13b (with split) or stream 13 (without split) is subjected to distillation in a distillation column 17, resulting in a top stream comprising ethylene glycol that is recovered via line 18 and a bottom stream comprising glycerol that is sent via line 19 to extraction column 5.
  • Substream 10b comprising unconverted ethylene carbonate, ethylene glycol and glycerol, optionally in combination with substream 13a, is subjected to distillation in a distillation column 20, resulting in a top stream comprising unconverted ethylene carbonate that is recycled via lines 21 and 3 to reactor 2, and a bottom stream comprising ethylene glycol and glycerol that is sent via line 22 to extraction column 5.
  • Liquid-Liquid Equilibrium (LLE) data measurements were performed in a stirred and thermoregulated glass cell. After equilibration and phase settling samples were taken from both phases and analyzed by gas chromatography. The molar concentrations of each component in each of the two phases were determined.
  • the mole fraction in each of the two phases was determined.
  • the mole fraction of a component in the upper phase (raffinate phase) is referred to in Tables 1 and 2 below as x(component), for example x(DEC).
  • the mole fraction of a component in the lower phase (extract phase) is referred to in Tables 1 and 2 below as y(component), for example y(DEC).
  • K-values distribution coefficients
  • the relative selectivity alpha(component/oxitol or EtOH) can be defined as the ratio of the K-values of DEC and oxitol (EE) or ethanol (EtOH), for example K(DEC)/K(EE) in the oxitol containing quinary system and K(DEC)/K(EtOH) in the ethanol containing quinary system.
  • this relative selectivity is 1, there is no difference in selectivity between a component and oxitol or EtOH with respect to the two phases.
  • the efficiency of a solvent to enhance the separation of oxitol and/or EtOH from an organic carbonate, such DEC and EC can be assessed by monitoring the change of the relative selectivity alpha when adding such solvent.
  • Table 1 below shows for the oxitol containing quinary system the LLE data including the derived K-values and relative selectivities (as compared with oxitol).
  • Table 1 below shows for the ethanol containing quinary system the LLE data including the derived K-values and relative selectivities (as compared with ethanol).
  • An alpha value (relative selectivity) higher than 1 means that the first component will end up in the upper (raffinate) phase and the second component (oxitol or EtOH) will end up in the lower (extract) phase in a liquid-liquid extraction column.
  • Tables 1 and 2 show firstly that by adding monoethylene glycol and glycerol the relative selectivity of organic carbonates (such as DEC and EE) versus oxitol or EtOH is higher than 1 in the full range of compositions evaluated (with varying oxitol or EtOH concentrations in the feed), and that therefore there is a difference in selectivity between the organic carbonates and oxitol or EtOH with respect to the two phases, and secondly that the organic carbonates will move up in a liquid-liquid extraction column, and that oxitol or EtOH will move down together with the monoethylene glycol and glycerol.
  • organic carbonates such as DEC and EE
  • monoethylene glycol and glycerol are good extraction solvents for separating oxitol and/or EtOH from organic carbonates (such as DEC and EE) in a liquid-liquid extraction process.
  • monoethylene glycol and glycerol are solvents that preferably dissolve oxitol and/or EtOH and to a lesser extent organic carbonates, such as DEC and ethylene carbonate.
  • the oxitol and/or EtOH may easily be separated from monoethylene glycol and glycerol (e.g. by distillation) after which the monoethylene glycol and glycerol can advantageously be re used as extraction solvent in liquid-liquid extraction of mixtures containing organic carbonate and oxitol and/or EtOH.

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Abstract

L'invention concerne un procédé d'élimination d'une impureté d'alcanol éther à partir d'un flux contenant un carbonate organique et l'impureté d'alcanol éther, comprenant la mise en contact du flux avec un solvant d'extraction et la séparation de la phase de solvant d'extraction comprenant l'impureté d'alcanol éther de la phase de carbonate organique, le solvant d'extraction comprenant un alcanol contenant 2 groupes hydroxyle ou plus. L'invention concerne également des procédés de préparation d'un dialkylcarbonate et d'un alcanediol, un flux contenant le dialkylcarbonate et une impureté d'alcanol éther étant soumis au procédé d'extraction décrit ci-dessus. En outre, l'invention concerne un procédé de production d'un dialkylcarbonate, comprenant la réaction d'un alcool arylique avec un flux contenant un dialkylcarbonate à partir duquel une impureté d'alcanol éther a été éliminée selon le procédé d'extraction décrit ci-dessus.
PCT/EP2020/084020 2019-12-06 2020-12-01 Procédé pour l'élimination d'une impureté d'alcanol éther à partir d'un flux de carbonate organique Ceased WO2021110627A1 (fr)

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