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WO2021182943A1 - Electrolytic battery - Google Patents

Electrolytic battery Download PDF

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Publication number
WO2021182943A1
WO2021182943A1 PCT/MX2020/000010 MX2020000010W WO2021182943A1 WO 2021182943 A1 WO2021182943 A1 WO 2021182943A1 MX 2020000010 W MX2020000010 W MX 2020000010W WO 2021182943 A1 WO2021182943 A1 WO 2021182943A1
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WO
WIPO (PCT)
Prior art keywords
battery
cavity
container
insulator
bar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/MX2020/000010
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Spanish (es)
French (fr)
Inventor
Andrés Abelino CHOZA ROMERO
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bioactivos Y Nutraceuticos De Mexico SA de CV
Original Assignee
Bioactivos Y Nutraceuticos De Mexico SA de CV
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Filing date
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Publication of WO2021182943A1 publication Critical patent/WO2021182943A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/96Carbon-based electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention is related to the technical field of electricity, renewable energy and electrochemical, since it provides an electrolytic battery.
  • a battery, accumulator or cell is a device that consists of one or more electrochemical cells that can convert stored chemical energy into electrical current.
  • Each cell consists of a positive electrode, or anode, a negative electrode, or cathode, and electrolytes that allow ions to move between the electrodes, allowing current to flow out of the battery to carry out its function, powering a circuit electric.
  • Batteries have been fully incorporated into our daily lives since their invention in the 19th century and their massive commercialization in the 20th century, hand in hand with electronics. Vehicles, watches, computers, lamps, cell phones, as well as many devices that have existed since the creation of the battery, which use electricity for their operation, so they are manufactured in various powers and sizes.
  • Batteries have a charge capacity determined by the nature of their composition, and which is measured in amperes / hour (Ah), which means that the battery can deliver one ampere of current over a continuous hour of life.
  • Ah amperes / hour
  • the working principle of an accumulator is essentially based on a reversible chemical process called reduction-oxidation (also known as redox), in which one of the components is oxidized (loses electrons) and the other is reduced (gains electrons); that is, a process whose components are neither consumed nor lost, but merely change their oxidation state and, which in turn can return to their original state under the appropriate circumstances.
  • redox reduction-oxidation
  • an accumulator is a device in which the polarization is brought to its achievable limits, and generally consists of two electrodes, made of the same or different material, immersed in an electrolyte.
  • battery and cell come from the invention of the device capable of generating electrical energy and were not as confusing as today, since everything depended on the way in which the components were placed either in a battery one on top of the other, or in battery shape next to each other. It could be said that in batteries the two poles are on the same face, while in batteries we find them at different ends.
  • Primary cells are those that, once the reaction has occurred, cannot return to their original state, thus depleting their ability to store electrical current.
  • Secondary cells are those that can receive an injection of electrical energy to restore their original chemical composition, thus being able to be used numerous times before being completely exhausted.
  • Zinc-carbon batteries these are the oldest and cheapest, consequently they store less energy and as a result last less than alkaline ones, they can be used in practically any electronic device such as toys, radios, controls, watches, etc.
  • Alkaline batteries Commonly disposable, they use potassium hydroxide as the electrolyte, along with zinc and magnesium dioxide to elicit the chemical reaction that produces energy. They are extremely stable, but short-lived.
  • Lead-acid batteries common in vehicles and motorcycles, they are rechargeable batteries that have two lead electrodes. During charging, the lead sulfate inside is reduced and becomes lead metal at the anode, while lead oxide is formed at the cathode. The process is reversed during the download.
  • Nickel batteries Very low cost, but low performance, they are some of the first to be manufactured in history and gave rise to different combinations of elements:
  • Nickel-iron Easy and inexpensive to manufacture, they consisted of thin tubes wound by sheets of nickel-plated steel. Nickel hydroxide and caustic potash and distilled water were used inside the tubes. However, its performance did not exceed 65%.
  • Nickel-cadmium (NI-CD). With cadmium anode and nickel hydroxide cathode, and potassium hydroxide as electrolyte, these batteries are perfectly rechargeable, but have low energy density.
  • Nickel-hydride Ni-MH. They use nickel hydroxide for the anode and a metal hydride alloy as the cathode, they were the pioneers in being used for electric vehicles, since they are perfectly rechargeable.
  • Li-ION Lithium-ion batteries
  • Lithium polymer (Li-Po) batteries a variation of ordinary lithium batteries, they have better energy density and better discharge rate, but have the disadvantage of being unusable if they lose their charge below 3 volts.
  • Button batteries within these we can find silver oxide and mercury oxide batteries. With regard Mercury oxide must be treated with great caution since they are the most toxic due to their 30% mercury content. Its applications are based on precision instruments, calculators, watches, hearing aids etc.
  • Graphene batteries these types of batteries are the promise of the near future since they promise a longer duration, be cheaper and have much greater durability. It is worth mentioning that this type of battery is still under development.
  • At least one embodiment provides a negative electrode active material that includes V, Nb (niobium) doped TiO 2 (B) (titanium oxide) At least one embodiment provides a wet chemistry process to prepare V, Nb (niobium) doped TiO 2 (B) (titanium oxide).
  • JP2019003946 A
  • the positive electrode includes a positive electrode current collector, and a layer of positive electrode material formed on the positive electrode current collector.
  • the layer of positive electrode material includes: an active positive electrode material; and a first conducting agent.
  • the first conductive agent has a D band appearing at 1350 ⁇ 10 c and a G band appearing at 1590 ⁇ 10 c min in a Raman graph obtained according to Raman spectroscopy of the layer of positive electrode material; the ratio of an integrated intensity of the D band to an integrated intensity of the G band is in a range of more than 0.6 to 10.
  • the ratio of an occupied area of the first conductive agent to an occupied area of the positive electrode active material is 1.5 or more and 5 or less.
  • aqueous electrolyte and aqueous electrolyte capacitor on the one hand, ultr flexible graphite paper rolled material is used I tune for preparing the current collector, so that the continuous production of electrode plates can be realized;
  • a conductive polymer on the surface of the ultra-thin flexible graphite paper is modified, so that the problem that the electrode material is in a uniform coating caused by the fact that the hydrophilicity of the graphite paper is solved poor.
  • the method can be used in the fields of aqueous electrolyte batteries and aqueous electrolyte capacitors.
  • the aforementioned documents refer to improvements in electrodes for the generation of electrical energy, but do not show evidence of having integrated graphite bars that, due to their characteristics, have a greater contact surface with an electrolytic solution, improving efficiency. of the battery, there is also no reference to having two power generating banks that, due to their type of connection, add the voltages obtaining a greater electrical current.
  • Figure 1 shows a rear perspective view without a cover of the electrolytic battery.
  • Figure 2 shows a side perspective view without a cap of the electrolytic battery.
  • Figure 3 shows a front perspective view without a cover of the electrolytic battery.
  • Figure 4 shows a rear perspective view of the electrolytic battery wiring.
  • Figure 5 shows a top perspective view of the electrolytic battery.
  • Figure 6 shows a side view of the electrolytic battery.
  • the electrolytic battery is made up of a container (1) that is preferably cylindrical in shape, which is configured to install an insulator (2) inside, in the middle part, an insulator (2), which is preferably made of polymer, and is installed longitudinally, allowing the container (1) to be divided into a first cavity (3) and a second cavity (4), configured to store an electrolyte solution.
  • Some rails (20) can be placed in the middle part of the interior of the container (1), so that the insulator (2) is placed on them in such a way that it can be removable, to be changed if necessary.
  • At least one bar (5) is installed on the internal periphery of each of the cavities of the container (1), this configuration allows to have two electric power generators in said container (1).
  • the bar (5) is in a form in which carbon is presented, which is non-metal and has electrical conductivity, and which can be graphite or graphene; said bar (5) is preferably porous.
  • At least one hole (6) is located in the center of the bases of the bar (5), and a plurality of grooves (7), which preferably they are longitudinally, they are on the outer periphery of each bar (5), this configuration makes it possible to expand the contact surface of the graphite with the electrolyte solution to generate greater electrical energy.
  • the high reliefs of the grooves (7) have a positive valence metal plating, such as copper, silver, gold or aluminum or a combination of the above; This configuration makes it possible to increase the voltage of the electrolytic battery, improving the efficiency of electric power generation.
  • Fastening means (8) which are preferably made of stainless steel and which can be screws, studs, studs and / or a combination of the above, are installed in the middle part of the outer periphery of the container (1), in alignment with the bars (5), and are configured to hold said bars (5) in the container (1), and to channel the electrical current generated in said bars (5) to the outside.
  • a positive conductor (11) is installed on the outer periphery of the container (1) connected to each of the fastening means (8) by means of terminals (not illustrated) of the second cavity (4), configured to conduct the electric current generated in the bars (5) to a positive terminal (12) that is installed at one of the ends of said positive conductor (11), this configuration allows the positive charge to be transmitted.
  • a negative conductor (13) is installed on the outer periphery of the container (1) connected to each of the clamping means (8) by means of the terminals (not illustrated) of the first cavity (3), configured to conduct the electric current generated in the bars (5); the negative conductor (13) is connected by means of the oppressor (10) to the plate (9) of the second cavity (4); A negative terminal (14) is connected to the oppressor (10) of the plate (9) of the first cavity (3), configured to transmit the negative charge.
  • Both the positive conductor (11) and the negative conductor (14) are metal wires, such as copper, silver, gold or aluminum or the combination of the above, which allows conducting the electric current generated in the electrolytic battery.
  • a lid (15) that is preferably removable, is Installed on the upper part of the container (1) under pressure or by a threaded means; At least one filling hole (16) is installed in the upper part of the lid (15), configured to allow the electrolyte solution to be poured into the container (1), said filling hole (16) is preferably aligned with the first cavity (3) or second cavity (4).
  • a hole (17) is located in the upper part of the insulator (2), this configuration allows the circulation of the electrolyte solution from one cavity to another.
  • a plug (18) is installed in the upper part of the filling tube (16), configured for the hermetic closure of the electrolytic battery.
  • a cover (19) that preferably is made of an insulating material, is installed in the middle part of the outer periphery of the container (1), configured to cover and isolate from the outside the fastening means (8), the positive conductor (11) and the negative conductor (13).
  • Example 1 Generation of electrical energy by means of the electrolytic battery.
  • the cap (18) is removed from the filling hole (16) and the container (1) is filled with an electrolyte solution; Once the first cavity (3) and the second cavity (4) are completely filled, the cap (18) is placed again to close the electrolytic battery.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The present invention discloses an electrolytic battery having the advantage of generating electrical power by using an electrolytic solution, which can be seawater, eliminating the components that pollute the environment; furthermore, once the electrolytes in the solution are spent, said battery can be re-used by refilling it once again with more electrolytic solution, thereby making it a type of rechargeable battery. Another of the advantages of the battery which is the object of the present invention is that, as its container is divided into two sections, two banks of graphite rods are installed, thus forming two independent generators of electrical energy, and by means of the connection in series thereof the voltages are increased, thus obtaining a greater output from the electrolytic battery; in addition to this, the rods feature a plating which enables an even greater increase in the power obtained.

Description

BATERÍA ELECTROLÍTICA C AMPO TECNICO DE LA INVENCIÓN La presente invención se relaciona con el campo técnico de la eléctrica, energía renovable y electroquímica, ya que aporta una batería electrolítica. ELECTROLYTIC BATTERY TECHNICAL FIELD OF THE INVENTION The present invention is related to the technical field of electricity, renewable energy and electrochemical, since it provides an electrolytic battery.

ANTECEDENTES DE LA INVENCIÓN BACKGROUND OF THE INVENTION

Una batería, acumulador o pila, es un dispositivo que consiste en una o más celdas electroquímicas que pueden convertir la energía química almacenada en corriente eléctrica. Cada celda consta de un electrodo positivo, o ánodo, un electrodo negativo, o cátodo, y electrolitos que permiten que los iones se muevan entre los electrodos, permitiendo que la corriente fluya fuera de la batería para llevar a cabo su función, alimentar un circuito eléctrico. Las baterías están plenamente incorporadas a nuestra vida cotidiana desde su invención en el siglo XIX y su comercialización masiva en el siglo XX, de la mano de la electrónica. Vehículos, relojes, computadoras, lámparas, celulares, así como muchos aparatos que existen desde la creación de la batería, que utilizan electricidad para su funcionamiento, por lo que son fabricadas en diversas potencias y tamaños. A battery, accumulator or cell, is a device that consists of one or more electrochemical cells that can convert stored chemical energy into electrical current. Each cell consists of a positive electrode, or anode, a negative electrode, or cathode, and electrolytes that allow ions to move between the electrodes, allowing current to flow out of the battery to carry out its function, powering a circuit electric. Batteries have been fully incorporated into our daily lives since their invention in the 19th century and their massive commercialization in the 20th century, hand in hand with electronics. Vehicles, watches, computers, lamps, cell phones, as well as many devices that have existed since the creation of the battery, which use electricity for their operation, so they are manufactured in various powers and sizes.

Las baterías poseen una capacidad de carga determinada por la naturaleza de su composición, y que se mide en amperios/hora (Ah), lo cual significa que la pila puede dar un amperio de corriente a lo largo de una hora continua de vida. Mientras mayor sea su capacidad de carga, más corriente podrá almacenar en su interior. El principio de funcionamiento de un acumulador está basado esencialmente en un proceso químico reversible llamado reducción-oxidación (también conocida como redox), en el que uno de los componentes se oxida (pierde electrones) y el otro se reduce (gana electrones); es decir, un proceso cuyos componentes no resulten consumidos ni se pierdan, sino que meramente cambian su estado de oxidación y, que a su vez pueden retornar a su estado original en las circunstancias adecuadas. Estas circunstancias son, en el caso de las baterías y pilas recargables, el cierre del circuito externo durante el proceso de descarga y la aplicación de una corriente externa durante la carga. Batteries have a charge capacity determined by the nature of their composition, and which is measured in amperes / hour (Ah), which means that the battery can deliver one ampere of current over a continuous hour of life. The higher its charging capacity, the more current it can store inside. The working principle of an accumulator is essentially based on a reversible chemical process called reduction-oxidation (also known as redox), in which one of the components is oxidized (loses electrons) and the other is reduced (gains electrons); that is, a process whose components are neither consumed nor lost, but merely change their oxidation state and, which in turn can return to their original state under the appropriate circumstances. These circumstances are, in the case of batteries and rechargeable cells, the closure of the external circuit during the discharge process and the application of an external current during charging.

Estos procesos son comunes en las relaciones entre los elementos químicos y la electricidad durante el proceso denominado electrólisis y en los generadores voltaicos o pilas. Los investigadores del siglo XIX dedicaron numerosos esfuerzos a observar y a esclarecer este fenómeno, que recibió el nombre de polarización. Un acumulador es, así, un dispositivo en el que la polarización se lleva a sus limites alcanzables, y consta, en general, de dos electrodos, del mismo o de distinto material, sumergidos en un electrolito. These processes are common in the relationships between chemical elements and electricity during the process called electrolysis and in voltaic generators or batteries. Researchers in the 19th century devoted many efforts to observe and clarify this phenomenon, which was called polarization. Thus, an accumulator is a device in which the polarization is brought to its achievable limits, and generally consists of two electrodes, made of the same or different material, immersed in an electrolyte.

Los términos batería y pila provienen desde la invención del dispositivo capaz de generar energía eléctrica y no eran tan confusos como hoy en día, ya que todo dependía de la forma en que se colocaban los componentes ya sea en una pila uno sobre otro, o en forma de batería uno junto al otro. Se podría decir que en las baterías los dos polos se encuentran en la misma cara, mientras que en las pilas los encontramos en diferentes extremos. The terms battery and cell come from the invention of the device capable of generating electrical energy and were not as confusing as today, since everything depended on the way in which the components were placed either in a battery one on top of the other, or in battery shape next to each other. It could be said that in batteries the two poles are on the same face, while in batteries we find them at different ends.

Muchas veces se confunden estos dos términos, llamando así pilas a los dispositivos que no son recargables y baterías a lo que, sí lo son, pero en realidad esta forma de clasificarla está dada en celdas primarias y celdas secundarias. These two terms are often confused, thus calling non-rechargeable devices and batteries batteries. to what, yes they are, but in reality this way of classifying it is given in primary cells and secondary cells.

• Las celdas primarias son las que, una vez producida la reacción, no pueden volver a su estado original, agotando así su capacidad de almacenar corriente eléctrica. • Primary cells are those that, once the reaction has occurred, cannot return to their original state, thus depleting their ability to store electrical current.

• Las celdas secundarias son las que pueden recibir una inyección de energía eléctrica para restaurar su composición química original, pudiendo así ser empleadas numerosas veces antes de agotarse del todo. • Secondary cells are those that can receive an injection of electrical energy to restore their original chemical composition, thus being able to be used numerous times before being completely exhausted.

Existen muchos tipos de baterías, dependiendo de los elementos utilizados en su fabricación. There are many types of batteries, depending on the elements used in their manufacture.

Baterías de zinc-carbono: estas son las más antiguas y baratas, por consecuencia almacenan una menor cantidad de energía y como resultado duran menos que las alcalinas, se pueden utilizar prácticamente en cualquier aparato electrónico como juguetes, radios, controles, relojes, etc. Zinc-carbon batteries: these are the oldest and cheapest, consequently they store less energy and as a result last less than alkaline ones, they can be used in practically any electronic device such as toys, radios, controls, watches, etc.

Baterías alcalinas: comúnmente desechables, emplean hidróxido de potasio como electrolito, junto con zinc y dióxido de magnesio para suscitar la reacción química que produce energía. Son sumamente estables, pero de corta vida. Baterías de ácido-plomo: comunes en vehículos y motocicletas, son pilas recargables que poseen dos electrodos de plomo. Durante la carga, el sulfato de plomo en su interior se reduce y deviene plomo metal en el ánodo, mientras en el cátodo se forma óxido de plomo. El proceso se invierte durante la descarga. Baterías de níquel: De muy bajo costo, pero bajo rendimiento, son algunas de las primeras en manufacturarse en la historia y dieron origen a diferentes combinaciones de elementos: Alkaline batteries - Commonly disposable, they use potassium hydroxide as the electrolyte, along with zinc and magnesium dioxide to elicit the chemical reaction that produces energy. They are extremely stable, but short-lived. Lead-acid batteries: common in vehicles and motorcycles, they are rechargeable batteries that have two lead electrodes. During charging, the lead sulfate inside is reduced and becomes lead metal at the anode, while lead oxide is formed at the cathode. The process is reversed during the download. Nickel batteries: Very low cost, but low performance, they are some of the first to be manufactured in history and gave rise to different combinations of elements:

• Níquel-hierro (NI-FE). Fáciles y económicos de fabricar, consistían en tubos finos enrollados por láminas de acero niquelado. En el interior de los tubos se usaba hidróxido de níquel y como electrolito potasa cáustica y agua destilada. Sin embargo, su rendimiento no superaba el 65%. • Nickel-iron (NI-FE). Easy and inexpensive to manufacture, they consisted of thin tubes wound by sheets of nickel-plated steel. Nickel hydroxide and caustic potash and distilled water were used inside the tubes. However, its performance did not exceed 65%.

• Níquel-cadmio (NI-CD). Con ánodo de cadmio y cátodo de hidróxido de níquel, e hidróxido de potasio como electrolito, estos acumuladores son perfectamente recargables, pero presentan baja densidad energética. • Nickel-cadmium (NI-CD). With cadmium anode and nickel hydroxide cathode, and potassium hydroxide as electrolyte, these batteries are perfectly rechargeable, but have low energy density.

• Níquel-hidruro (Ni-MH). Emplean hidróxido de níquel para el ánodo y una aleación de hidruro metálico como cátodo, fueron las pioneras en usarse para vehículos eléctricos, dado que son perfectamente recargables. • Nickel-hydride (Ni-MH). They use nickel hydroxide for the anode and a metal hydride alloy as the cathode, they were the pioneers in being used for electric vehicles, since they are perfectly rechargeable.

Baterías de iones de litio (Li-ION): Las baterías más empleadas en la electrónica de pequeño tamaño, como celulares y otros artefactos portátiles. Destacan por su enorme densidad energética, sumados a su bajo peso, pequeño tamaño y buen rendimiento, pero poseen una vida máxima de tres años, además, al sobrecalentarse pueden explotar, ya que sus elementos son inflamables. Lithium-ion batteries (Li-ION): The batteries most used in small electronics, such as cell phones and other portable devices. They stand out for their enormous energy density, added to their low weight, small size and good performance, but they have a maximum life of three years, in addition, when overheated they can explode, since their elements are flammable.

Baterías de polímero de litio (Li-Po): variación de las ordinarias baterías de litio, presentan mejor densidad de energía y mejor tasa de descarga, pero presentan el inconveniente de quedar inutilizadas si pierden su carga por debajo de 3 voltios. Lithium polymer (Li-Po) batteries: a variation of ordinary lithium batteries, they have better energy density and better discharge rate, but have the disadvantage of being unusable if they lose their charge below 3 volts.

Baterías de botón: dentro de estas podemos encontrar las de óxido de plata y las de óxido de mercurio. Con respecto a la de óxido de mercurio se deben tratar con mucha precaución ya que son las más tóxicas por su contenido de 30% de mercurio. Sus aplicaciones se basan en instrumentos de precisión, calculadoras, relojes, aparatos para la sordera etc. Button batteries: within these we can find silver oxide and mercury oxide batteries. With regard Mercury oxide must be treated with great caution since they are the most toxic due to their 30% mercury content. Its applications are based on precision instruments, calculators, watches, hearing aids etc.

Baterías de Grafeno: este tipo de baterías son la promesa de un futuro cercano ya que prometen una mayor duración, ser más baratas y tener mucho mayor durabilidad. Cabe mencionar que este tipo de baterías aún se encuentra en desarrollo. Graphene batteries: these types of batteries are the promise of the near future since they promise a longer duration, be cheaper and have much greater durability. It is worth mentioning that this type of battery is still under development.

Se realizó una búsqueda del estado de la técnica de batería electrolítica, donde se encontró que se han desarrollado diferentes baterías con ese fin, como se menciona en el documento de solicitud de patente internacional número W02015138019 (Al), publicado el 17 de septiembre de 2015 con el titulo “MATERIAL ACTIVO DE ELECTRODO NEGATIVO PARA DISPOSITIVOS DE ALMACENAMIENTO DE ENERGÍA Y MÉTODO PARA FABRICARLO" el cual describe un dispositivo de almacenamiento de energía que incluye un electrodo positivo que incluye un material activo que puede almacenar y liberar iones, un electrodo negativo que incluye un V, Nb (niobio) dopado TiO2(B) (óxido de titanio) y un electrolito no acuoso que incluye iones de litio. Al menos una realización proporciona un material activo de electrodo negativo que incluye V, Nb (niobio) dopado TiO2(B) (óxido de titanio). Al menos una realización proporciona un proceso de química en húmedo para preparar V, Nb (niobio) dopado TiO2(B) (óxido de titanio). A search was carried out on the state of the electrolytic battery technique, where it was found that different batteries have been developed for this purpose, as mentioned in the international patent application document number W02015138019 (Al), published on September 17, 2015 with the title "ACTIVE NEGATIVE ELECTRODE MATERIAL FOR ENERGY STORAGE DEVICES AND METHOD OF MANUFACTURING IT" which describes an energy storage device that includes a positive electrode that includes an active material that can store and release ions, a negative electrode that includes a V, Nb (niobium) doped TiO 2 (B) (titanium oxide) and a non-aqueous electrolyte that includes lithium ions. At least one embodiment provides a negative electrode active material that includes V, Nb (niobium) doped TiO 2 (B) (titanium oxide) At least one embodiment provides a wet chemistry process to prepare V, Nb (niobium) doped TiO 2 (B) (titanium oxide).

Otro documento que se encontró es la solicitud de patente de Japón número JP2019003946 (A), publicada el 10 de enero de 2019, con el título “ELECTRODO POSITIVO" la cual describe una batería de electrolito no acuosa que comprende: un electrodo positivo; un electrodo negativo; y un electrolito no acuoso. El electrodo positivo incluye un colector de corriente de electrodo positivo, y una capa de material de electrodo positivo formada en el colector de corriente de electrodo positivo. La capa de material de electrodo positivo incluye: un material activo de electrodo positivo; y un primer agente conductor. El primer agente conductor tiene una banda D que aparece a 1350 ± 10 c y una banda G que aparece a 1590 ± 10 c min en un gráfico Raman obtenido según la espectroscopia Raman de la capa de material de electrodo positivo; la relación de una intensidad integrada de la banda D a una intensidad integrada de la banda G está en un rango de más de 0.6 a 10. En una imagen de mapeo de material constituyente de la capa de material de electrodo positivo obtenida por espectroscopia Raman, la relación de un área ocupada del primer agente conductor a un área ocupada del material activo de electrodo positivo es 1,5 o más y 5 o menos. Por último, se encontró el documento de solicitud de patente de China número CN104882615 (A), publicada el 02 d septiembre de 2015 con el titulo “MÉTODO PARA MEJORAR LA ESTABILIDAD DEL ELECTRODO DE LA BATERÍA DE ELECTROLITO ACUOSO Y EL CONDENSADOR DE ELECTROLITO ACUOSO", dicho documento describe un método para mejorar la estabilidad del electrodo de una batería de electrolito acuoso y un condensador de electrolito acuoso, se refiere a métodos para la estabilidad de baterías y condensadores, y tiene como objetivo resolver el problema de que un colector de corriente de electrodo existente es pobre en estabilidad y corto en vida de servicio. De acuerdo con el método, se usa papel de grafito flexible ultrafino o un material de grafito modificado con polímero conductor corno material colector de corriente de electrodo positivo y negativo de la batería de electrolito acuoso y el condensador de electrolito acuoso; por un lado, se utiliza un material enrollado de papel de grafito flexible ultrafino para preparar el colector de corriente, de modo que se pueda realizar la producción continua de placas de electrodos; por otro lado, se modifica un polímero conductor en la superficie del papel de grafito flexible ultrafino, de modo que se resuelve el problema de que el material del electrodo esté en un recubrimiento uniforme causado por el hecho de que la hidrofilia del papel de grafito es pobre. El método puede usarse en los campos de las baterías de electrolitos acuosos y los condensadores de electrolitos acuosos. Another document that was found is the Japanese patent application number JP2019003946 (A), published on January 10, 2019, with the title "POSITIVE ELECTRODE" which describes a non-aqueous electrolyte battery comprising: a positive electrode; a negative electrode; and a non-aqueous electrolyte. The positive electrode includes a positive electrode current collector, and a layer of positive electrode material formed on the positive electrode current collector. The layer of positive electrode material includes: an active positive electrode material; and a first conducting agent. The first conductive agent has a D band appearing at 1350 ± 10 c and a G band appearing at 1590 ± 10 c min in a Raman graph obtained according to Raman spectroscopy of the layer of positive electrode material; the ratio of an integrated intensity of the D band to an integrated intensity of the G band is in a range of more than 0.6 to 10. In a mapping image of constituent material of the layer of positive electrode material obtained by Raman spectroscopy, the ratio of an occupied area of the first conductive agent to an occupied area of the positive electrode active material is 1.5 or more and 5 or less. Finally, we found the Chinese patent application document number CN104882615 (A), published on September 2, 2015 with the title "METHOD TO IMPROVE THE STABILITY OF THE ELECTRODE OF THE AQUEOUS ELECTROLYTE BATTERY AND THE AQUEOUS ELECTROLYTE CONDENSER" , said document describes a method to improve the stability of the electrode of an aqueous electrolyte battery and an aqueous electrolyte capacitor, refers to methods for the stability of batteries and capacitors, and aims to solve the problem that a current collector The existing electrode is poor in stability and short in service life.According to the method, ultra-thin flexible graphite paper or a conductive polymer modified graphite material is used as the positive and negative electrode current collector material of the battery. aqueous electrolyte and aqueous electrolyte capacitor; on the one hand, ultr flexible graphite paper rolled material is used I tune for preparing the current collector, so that the continuous production of electrode plates can be realized; On the other hand, a conductive polymer on the surface of the ultra-thin flexible graphite paper is modified, so that the problem that the electrode material is in a uniform coating caused by the fact that the hydrophilicity of the graphite paper is solved poor. The method can be used in the fields of aqueous electrolyte batteries and aqueous electrolyte capacitors.

Como se puede observar, los documentos anteriormente citados hacen referencia a mejoras en electrodos para la generación de energía eléctrica, pero no muestran evidencia de tener integradas barras de grafito que, por sus características tienen una mayor superficie de contacto con una solución electrolítica mejorando la eficiencia de la batería, tampoco hay referencia de tener dos bancos generadores de energía que por su el tipo de conexión se suman los voltajes obteniendo una mayor corriente eléctrica. As can be seen, the aforementioned documents refer to improvements in electrodes for the generation of electrical energy, but do not show evidence of having integrated graphite bars that, due to their characteristics, have a greater contact surface with an electrolytic solution, improving efficiency. of the battery, there is also no reference to having two power generating banks that, due to their type of connection, add the voltages obtaining a greater electrical current.

Otra de las características no descritas en los documentos anteriores, es que cuenten con una aleación de metales que incrementan la atracción de electrones para aumentar el voltaje generado. Another of the characteristics not described in the previous documents is that they have an alloy of metals that increase the attraction of electrons to increase the voltage generated.

25 OBJETO DE LA INVENCIÓN 25 OBJECT OF THE INVENTION

Es, por lo tanto, objeto de la presente invención, proporcionar una batería electrolítica, que resuelve los problemas anteriormente mencionados. It is therefore an object of the present invention to provide an electrolytic battery, which solves the aforementioned problems.

BREVE DESCRIPCIÓN DE LAS FIGURAS BRIEF DESCRIPTION OF THE FIGURES

Los detalles característicos de esta novedosa batería electrolítica se muestran claramente en la siguiente descripción y en las figuras que se acompañan, así como una ilustración de aquella, y siguiendo los mismos signos de referencia para indicar las partes mostradas. Sin embargo, dichas figuras se muestran a manera de ejemplo y no deben de ser consideradas como limitativas para la presente invención. The characteristic details of this novel electrolytic battery are clearly shown in the following description and in the accompanying figures, as well as a illustration of that one, and following the same reference signs to indicate the parts shown. However, these figures are shown by way of example and should not be considered as limiting for the present invention.

La figura 1 muestra una vista en perspectiva posterior sin tapa de la batería electrolítica. Figure 1 shows a rear perspective view without a cover of the electrolytic battery.

La figura 2 muestra una vista en perspectiva lateral sin tapa de la batería electrolítica. Figure 2 shows a side perspective view without a cap of the electrolytic battery.

La figura 3 muestra una vista en perspectiva frontal sin tapa de la batería electrolítica. Figure 3 shows a front perspective view without a cover of the electrolytic battery.

La figura 4 muestra una vista en perspectiva posterior del cableado de la batería electrolítica. Figure 4 shows a rear perspective view of the electrolytic battery wiring.

La figura 5 muestra una vista en perspectiva superior de la batería electrolítica. Figure 5 shows a top perspective view of the electrolytic battery.

La figura 6 muestra una vista lateral de la batería electrolítica. Figure 6 shows a side view of the electrolytic battery.

20 DESCRIPCIÓN DETALLADA DE LA INVENCIÓN 20 DETAILED DESCRIPTION OF THE INVENTION

Para una mejor comprensión de la invención, a continuación, se enlistan las partes que componen la batería electrolítica: For a better understanding of the invention, the parts that make up the electrolytic battery are listed below:

1. Contenedor 1. Container

2 . Aislador 2 . Insulator

3 . Primera cavidad 3 . First cavity

4. Segunda cavidad 4. Second cavity

5. Barra 5. Bar

6. Barreno 6. Hole

7. Ranuras 7. Slots

8. Medios de sujeción 8. Fastening means

9. Placa 9. Plate

10. Opresores 10. Oppressors

11. Conductor positivo 12. Terminal positiva 11. Positive driver 12. Positive terminal

13. Conductor negativo 13. Negative conductor

14. Terminal negativa 14. Negative terminal

15. Tapa 15. Lid

16. Orificio de llenado 16. Fill hole

17. Barreno 17. Auger

18. Tapón 18. Plug

19. Cubierta 19. Cover

20. Rieles 20. Rails

Con referencia a las figuras, la batería electrolítica, está conformada por, un contenedor (1) que preferentemente es de forma cilindrica, el cual está configurado para instalar en su interior en la parte media, un aislador (2), el cual preferentemente es de polímero, y se instala de manera longitudinal, permitiendo dividir el contenedor (1) en una primera cavidad (3) y una segunda cavidad (4), configurados para almacenar una solución electrolítica. With reference to the figures, the electrolytic battery is made up of a container (1) that is preferably cylindrical in shape, which is configured to install an insulator (2) inside, in the middle part, an insulator (2), which is preferably made of polymer, and is installed longitudinally, allowing the container (1) to be divided into a first cavity (3) and a second cavity (4), configured to store an electrolyte solution.

Unos rieles (20) se pueden colocar en la parte media del interior del contenedor (1), para que sobre ellos se coloque el aislador (2) de tal manera que este pueda ser removible, para cambiarse en caso de ser necesario. Some rails (20) can be placed in the middle part of the interior of the container (1), so that the insulator (2) is placed on them in such a way that it can be removable, to be changed if necessary.

Al menos, una barra (5) se instalan en la periferia interna de cada una de las cavidades del contenedor (1), esta configuración permite tener dos generadores de energía eléctrica en dicho contenedor (1). La barra (5) es de una forma en que se presenta el carbono, que es no metal y presenta conductividad eléctrica, y que puede ser de grafito o grafeno; dicha barra (5) preferentemente es porosa. At least one bar (5) is installed on the internal periphery of each of the cavities of the container (1), this configuration allows to have two electric power generators in said container (1). The bar (5) is in a form in which carbon is presented, which is non-metal and has electrical conductivity, and which can be graphite or graphene; said bar (5) is preferably porous.

Al menos, un barreno (6) se encuentra en el centro de las bases de la barra (5), y una pluralidad de ranuras (7), que preferentemente están de manera longitudinal, están en la periferia exterior de cada barra (5), esta configuración permite ampliar la superficie de contacto del grafito con la solución electrolítica para generar una mayor energía eléctrica. At least one hole (6) is located in the center of the bases of the bar (5), and a plurality of grooves (7), which preferably they are longitudinally, they are on the outer periphery of each bar (5), this configuration makes it possible to expand the contact surface of the graphite with the electrolyte solution to generate greater electrical energy.

Los altos relieves de las ranuras (7) tienen un chapeado de metal de valencia positiva, como lo puede ser cobre, plata, oro o aluminio o la combinación de los anteriores; esta configuración permite aumentar el voltaje de la batería electrolítica mejorando la eficiencia de generación de energía eléctrica. The high reliefs of the grooves (7) have a positive valence metal plating, such as copper, silver, gold or aluminum or a combination of the above; This configuration makes it possible to increase the voltage of the electrolytic battery, improving the efficiency of electric power generation.

Unos medios de sujeción (8), que preferentemente son de acero inoxidable y que pueden ser tornillos, espárragos, birlos y/o la combinación de los anteriores, se instalan en la parte media de la periferia exterior del contenedor (1), en alineación con las barras (5), y están configurados para sujetar dichas barras (5) en el contenedor (1), y para canalizar al exterior la corriente eléctrica generada en dichas barras (5). Fastening means (8), which are preferably made of stainless steel and which can be screws, studs, studs and / or a combination of the above, are installed in the middle part of the outer periphery of the container (1), in alignment with the bars (5), and are configured to hold said bars (5) in the container (1), and to channel the electrical current generated in said bars (5) to the outside.

Al menos, una placa (9), que es de un metal de transición, como pueden ser Escandio, Titanio, Vanadio, Cromo, Manganeso, Hierro, Cobalto, Níquel, Cobre, Zinc, Itrio, Circonio, Niobio, Molibdeno, Tecnecio, Rutenio, Rodio, Paladio, Plata, Cadmio, Lutecio, Hafnio, Tantalio, Wolframio, Renio, Osmio, Iridio, Platino, Oro, Lawrencio, Rutherfordio, Dubnio, Seaborgio, Bohrio, Hassio, Meitnerio, Darmstadtio, Roentgenio, Copernicio y/o la combinación de los anteriores, preferentemente es de zinc, se instala en cada pared del aislador (2) por medio de unos opresores (10), quedando una placa en la primera cavidad (3) y otra en la segunda cavidad (4); dicha placas (9) están configuradas para ceder electrones a las barras (5) por la reacción electroquímica que se lleva a cabo por la solución electrolítica. Un conductor positivo (11) se encuentra instalado en la periferia exterior del contenedor (1) conectado a cada uno de los medios de sujeción (8) por medio de unos bornes (no ilustrados) de la segunda cavidad (4), configurado para conducir la corriente eléctrica generada en las barras (5) a una terminal positiva (12) que está instalada a uno de los extremos de dicho conductor positivo (11), esta configuración permite transmitir la carga positiva. At least one plate (9), which is made of a transition metal, such as Scandium, Titanium, Vanadium, Chromium, Manganese, Iron, Cobalt, Nickel, Copper, Zinc, Yttrium, Zirconium, Niobium, Molybdenum, Technetium, Ruthenium, Rhodium, Palladium, Silver, Cadmium, Lutetium, Hafnium, Tantalum, Tungsten, Rhenium, Osmium, Iridium, Platinum, Gold, Lawrence, Rutherfordium, Dubnium, Seaborgium, Bohrio, Hassium, Meitnerium, Darmstadtium, Roentgenium, Copernicium and / or the combination of the above, preferably zinc, is installed on each wall of the insulator (2) by means of oppressors (10), leaving a plate in the first cavity (3) and another in the second cavity (4); said plates (9) are configured to give electrons to the bars (5) by the electrochemical reaction that is carried out by the electrolytic solution. A positive conductor (11) is installed on the outer periphery of the container (1) connected to each of the fastening means (8) by means of terminals (not illustrated) of the second cavity (4), configured to conduct the electric current generated in the bars (5) to a positive terminal (12) that is installed at one of the ends of said positive conductor (11), this configuration allows the positive charge to be transmitted.

Un conductor negativo (13) se encuentra instalado en la periferia exterior del contenedor (1) conectado a cada uno de los medios de sujeción (8) por medio de los bornes (no ilustrados) de la primera cavidad (3), configurado para conducir la corriente eléctrica generada en las barras (5); el conductor negativo (13) se conecta por medio del opresor (10) a la placa (9) de la segunda cavidad (4); una terminal negativa (14) se conecta al opresor (10) de la placa (9) de la primer cavidad (3), configurada para transmitir la carga negativa. Tanto el conductor positivo (11) como el conductor negativo (14) son hilos de metal, como puede ser cobre, plata, oro o aluminio o la combinación de los anteriores, lo que permite conducir la corriente eléctrica generada en la batería electrolítica. A negative conductor (13) is installed on the outer periphery of the container (1) connected to each of the clamping means (8) by means of the terminals (not illustrated) of the first cavity (3), configured to conduct the electric current generated in the bars (5); the negative conductor (13) is connected by means of the oppressor (10) to the plate (9) of the second cavity (4); A negative terminal (14) is connected to the oppressor (10) of the plate (9) of the first cavity (3), configured to transmit the negative charge. Both the positive conductor (11) and the negative conductor (14) are metal wires, such as copper, silver, gold or aluminum or the combination of the above, which allows conducting the electric current generated in the electrolytic battery.

La interconexión de polos opuestos entre la primera cavidad (3) y la segunda cavidad (4) permite realizar una conexión en serie de dos fuentes de energía independientes y mejorar la eficiencia de la batería electrolítica. Una tapa (15) que preferentemente es removlble, se Instala en la parte superior del contenedor (1) a presión o por un medio roscado; al menos, un orificio de llenado (16) se encuentra instalado en la parte superior de la tapa (15), configurado para permitir verter la solución electrolítica dentro del contenedor (1), dicho orificio de llenado (16) queda preferentemente alineado con la primera cavidad (3) o la segunda cavidad (4). Un barreno (17) se encuentra en la parte superior del aislador (2), esta configuración permite la circulación de la solución electrolítica de una cavidad a otra. The interconnection of opposite poles between the first cavity (3) and the second cavity (4) makes it possible to make a series connection of two independent energy sources and improve the efficiency of the electrolytic battery. A lid (15) that is preferably removable, is Installed on the upper part of the container (1) under pressure or by a threaded means; At least one filling hole (16) is installed in the upper part of the lid (15), configured to allow the electrolyte solution to be poured into the container (1), said filling hole (16) is preferably aligned with the first cavity (3) or second cavity (4). A hole (17) is located in the upper part of the insulator (2), this configuration allows the circulation of the electrolyte solution from one cavity to another.

Un tapón (18) se instala en la parte superior del tubo de llenado (16), configurado para el cierre hermético de la batería electrolítica. A plug (18) is installed in the upper part of the filling tube (16), configured for the hermetic closure of the electrolytic battery.

Una cubierta (19) que preferentemente es de un material aislante, está instalada en la parte media de la periferia exterior del contenedor (1), configurada para cubrir y aislar del exterior los medios de sujeción (8), el conductor positivo (11) y el conductor negativo (13). A cover (19) that preferably is made of an insulating material, is installed in the middle part of the outer periphery of the container (1), configured to cover and isolate from the outside the fastening means (8), the positive conductor (11) and the negative conductor (13).

REALIZACIÓN PREFERENTE DE LA INVENCIÓN PREFERRED EMBODIMENT OF THE INVENTION

Ejemplos Examples

Los siguientes ejemplos ilustran una manera preferente, de cómo llevar a cabo la realización de la presente invención, por lo que no deben ser considerados como limitativos de la misma. The following examples illustrate a preferred way of carrying out the embodiment of the present invention, so they should not be considered as limiting it.

Ejemplo 1. Generación de energía eléctrica por medio de la batería electrolítica. Con referencia a las figuras antes mencionadas, se retira el tapón (18) del orificio de llenado (16) y se llena el contenedor (1) con una solución electrolítica; una vez que la primera cavidad (3) y la segunda cavidad (4) se encuentran totalmente llenas se coloca nuevamente el tapón (18) para cerrar la batería electrolítica. Seguido de esto, se lleva a cabo en el interior de la batería electrolítica una reacción electroquímica, donde las placas (9) empiezan a ceder iones negativos los cuales son atraídos por las barras de grafito (5), y con ayuda del chapado de cobre se amplifica la energía eléctrica generada, el conector positivo de la segunda cavidad (4) conduce la carga positiva a la terminal positiva (12), y por otra parte, la energía eléctrica generada en las barras de grafito (5) de la primera cavidad (3) es canalizada por medio del conector negativo (13) para ser depositada en la placa (9) de la segunda cavidad (4), logrando una conexión en serie para aumentar la energía eléctrica generada; la placa (9) de la primera cavidad (3) manda la carga negativa a la terminal negativa (14), de esta manera se obtiene la energía eléctrica para conectar un amplificador de corriente como puede ser un balastro. Example 1. Generation of electrical energy by means of the electrolytic battery. With reference to the aforementioned figures, the cap (18) is removed from the filling hole (16) and the container (1) is filled with an electrolyte solution; Once the first cavity (3) and the second cavity (4) are completely filled, the cap (18) is placed again to close the electrolytic battery. Following this, an electrochemical reaction is carried out inside the electrolytic battery, where the plates (9) begin to give up negative ions which are attracted by the graphite bars (5), and with the help of the copper plating The electrical energy generated is amplified, the positive connector of the second cavity (4) conducts the positive charge to the positive terminal (12), and on the other hand, the electrical energy generated in the graphite bars (5) of the first cavity (3) is channeled through the negative connector (13) to be deposited on the plate (9) of the second cavity (4), achieving a series connection to increase the electrical energy generated; the plate (9) of the first cavity (3) sends the negative charge to the negative terminal (14), in this way the electrical energy is obtained to connect a current amplifier such as a ballast.

El invento ha sido descrito suficientemente como para que una persona con conocimientos medios en la materia pueda reproducir y obtener los resultados que mencionamos en la presente invención. Sin embargo, cualquier persona hábil en el campo de la técnica que compete el presente invento puede ser capaz de hacer modificaciones no descritas en la presente solicitud, sin embargo, si para la aplicación de estas modificaciones en una estructura determinada o en el proceso de manufactura de este, se requiere de la materia reclamada en las siguientes reivindicaciones, dichas estructuras deberán ser comprendidas dentro del alcance de la invención. The invention has been described sufficiently so that a person of ordinary skill in the art can reproduce and obtain the results mentioned in the present invention. However, any person skilled in the field of art that is the subject of the present invention may be able to make modifications not described in the present application, however, if for the application of these modifications in a certain structure or in the manufacturing process of this, the matter claimed in the following claims is required, said structures should be included within the scope of the invention.

Claims

REIVINDICACIONES 1.Una batería electrolítica, caracterizada porque comprende: un contenedor (1); un aislador (2) se instala en el interior del contenedor (1) en la parte media de manera longitudinal, permitiendo dividir el contenedor1. An electrolytic battery, characterized in that it comprises: a container (1); an insulator (2) is installed inside the container (1) in the middle longitudinally, allowing the container to be divided (1) en dos cavidades denominadas primera cavidad (3) y segunda cavidad (4); al menos, una barra (5) se instalan en la periferia interna de cada una de las cavidades del contenedor (1), dicha barra (5) es de una forma en que se presenta el carbono; una pluralidad de ranuras (7) están en la periferia exterior de cada barra (5); los altos relieves de las ranuras (7) tienen un chapeado de metal de valencia positiva; unos medios de sujeción (8) se instalan en la parte media de la periferia exterior del contenedor (1), en alineación con las barras (5); al menos, una placa (9) se instala en cada pared del aislador(1) in two cavities called first cavity (3) and second cavity (4); at least one bar (5) is installed in the inner periphery of each of the cavities of the container (1), said bar (5) is in a form in which carbon is presented; a plurality of grooves (7) are on the outer periphery of each bar (5); the high reliefs of the grooves (7) have a positive valence metal plating; clamping means (8) are installed in the middle part of the outer periphery of the container (1), in alignment with the bars (5); at least one plate (9) is installed on each wall of the insulator (2) por medio de unos opresores (10) quedando una placa en la primera cavidad (3) y otra en la segunda cavidad (4); un conductor positivo (11) se encuentra instalado en la periferia exterior del contenedor (1) conectado a cada uno de los medios de sujeción (8) por medio de unos bornes (no ilustrados) de la segunda cavidad (4); una terminal positiva (12) está instalada a uno de los extremos de dicho conductor positivo (11); un conductor negativo (13) se encuentra instalado en la periferia exterior del contenedor (1) conectado a cada uno de los medios de sujeción (8) por medio de los bornes (no ilustrados) de la primera cavidad (3), dicho conductor negativo (13) se conecta por medio del opresor (10) a la placa (9) de la segunda cavidad (4); una terminal negativa (14) se conecta al opresor (10) de la placa (9) de la primer cavidad (3); una tapa (15) se instala en la parte superior del contenedor (1); un orificio de llenado (16) se encuentra instalado en la parte superior de la tapa (15); un barreno (17) se encuentra en la parte superior del aislador (2); un tapón (18) se instala en la parte superior del tubo de llenado (16); y, una cubierta (19) está instalada en la parte media de la periferia exterior del contenedor (1). (2) by means of oppressors (10) leaving a plate in the first cavity (3) and another in the second cavity (4); a positive conductor (11) is installed on the outer periphery of the container (1) connected to each of the clamping means (8) by means of terminals (not illustrated) of the second cavity (4); a positive terminal (12) is installed at one of the ends of said positive conductor (11); A negative conductor (13) is installed on the outer periphery of the container (1) connected to each of the clamping means (8) by means of the terminals (not illustrated) of the first cavity (3), said negative conductor (13) is connected by means of the oppressor (10) to the plate (9) of the second cavity (4); a negative terminal (14) is connected to the oppressor (10) of the plate (9) of the first cavity (3); a lid (15) is installed in the upper part of the container (1); a filling hole (16) is located installed on the top of the lid (15); a hole (17) is in the upper part of the insulator (2); a plug (18) is installed on top of the fill tube (16); and, a cover (19) is installed in the middle part of the outer periphery of the container (1). 2.La batería de la reivindicación 1 caracterizada porque, el contenedor (1) preferentemente es de forma cilindrica. The battery of claim 1 characterized in that the container (1) is preferably cylindrical in shape. 3.La batería de la reivindicación 1 caracterizada porque, el aislador (2) preferentemente es removible. The battery of claim 1 characterized in that the insulator (2) is preferably removable. 4.La batería de la reivindicaciones 1 y 3 caracterizada porque, el aislador (2) preferentemente es de polímero. 4. The battery of claims 1 and 3, characterized in that the insulator (2) is preferably made of polymer. 5.La batería de la reivindicación 1 caracterizada porque, la barra (5) preferentemente es porosa. The battery of claim 1 characterized in that the bar (5) is preferably porous. 6.La batería de las reivindicaciones 1 y 5 caracterizada porque, la barra (5) es de grafito o grafeno. 6. The battery of claims 1 and 5, characterized in that the bar (5) is made of graphite or graphene. 7.La batería de la reivindicación 1 caracterizada porque, la barra (5) cuenta con, al menos, un barreno (6) en el centro de sus bases. 7. The battery of claim 1 characterized in that the bar (5) has at least one hole (6) in the center of its bases. 8.La batería de la reivindicación 1 caracterizada porque, las ranuras (7) preferentemente están de manera longitudinal. 8. The battery of claim 1 characterized in that the grooves (7) are preferably longitudinally. 9.La batería de la reivindicación 1 caracterizada porque, el metal del chapeado de los altos relieves es de cobre, plata, oro o aluminio o la combinación de los anteriores. The battery of claim 1 characterized in that the metal of the plating of the high reliefs is copper, silver, gold or aluminum or a combination of the above. 10. La batería de la reivindicación 1 caracterizada porque, los medios de sujeción (8) preferentemente son de acero inoxidable. 10. The battery of claim 1 characterized in that the fastening means (8) are preferably made of stainless steel. 11. La batería de las reivindicaciones 1 y 10 caracterizada porque, los medios de sujeción (8) pueden ser tornillos, espárragos, birlos y/o la combinación de los anteriores. 11. The battery of claims 1 and 10 characterized in that the fastening means (8) can be screws, studs, studs and / or a combination of the above. 12. La batería de la reivindicación 1 caracterizada porque, la placa (9) es de un metal de transición. 12. The battery of claim 1 characterized in that the plate (9) is made of a transition metal. 13. La batería de las reivindicaciones 1 y 12 caracterizada porque, el metal de transición es Escandio, Titanio, Vanadio, Cromo, Manganeso, Hierro, Cobalto, Níquel, Cobre, Zinc, Itrio, Circonio, Niobio, Molibdeno, Tecnecio, Rutenio, Rodio, Paladio, Plata, Cadmio, Lutecio, Hafnio, Tantalio, Wolframio, Renio, Osmio, Iridio, Platino, Oro, Lawrencio, Rutherfordio, Dubnio, Seaborgio, Bohrio, Hassio, Meitnerio, Darmstadtio, Roentgenio, Copernicio y/o la combinación de los anteriores. 13. The battery of claims 1 and 12 characterized in that the transition metal is Scandium, Titanium, Vanadium, Chromium, Manganese, Iron, Cobalt, Nickel, Copper, Zinc, Yttrium, Zirconium, Niobium, Molybdenum, Technetium, Ruthenium, Rhodium, Palladium, Silver, Cadmium, Lutetium, Hafnium, Tantalum, Wolfram, Rhenium, Osmium, Iridium, Platinum, Gold, Lawrence, Rutherfordium, Dubnium, Seaborgium, Bohrio, Hassium, Meitnerium, Darmstadtium, Roentgenium, Copernicium and / or the combination of the above. 14. La batería de las reivindicaciones 1, 12 y 13 caracterizada porque, la placa (9) preferentemente es de zinc. 14. The battery of claims 1, 12 and 13 characterized in that the plate (9) is preferably made of zinc. 15. La batería de la reivindicación 1 caracterizada porque, tanto el conductor positivo (11) como el conductor negativo (14) son hilos de metal. 15. The battery of claim 1 characterized in that both the positive conductor (11) and the negative conductor (14) are metal wires. 16. La batería de las reivindicaciones 1 y 15 caracterizada porque, el metal de los hilos es de cobre, plata, oro o aluminio o la combinación de los anteriores. 16. The battery of claims 1 and 15 characterized in that the metal of the wires is copper, silver, gold or aluminum or a combination of the above. 17. La batería de la reivindicación 1 caracterizada porque, la tapa (15) preferentemente es removible. 17. The battery of claim 1 characterized in that the cover (15) is preferably removable. 18. La batería de las reivindicaciones 1 y 17 caracterizada porque, la tapa puede tener un medio roscado. 18. The battery of claims 1 and 17 characterized in that the cover can have a threaded means. 19. La batería de la reivindicación 1 caracterizada porque, el orificio de llenado (16) queda preferentemente alineado con la primera cavidad (3) o la segunda cavidad (4). 19. The battery of claim 1 characterized in that the filling hole (16) is preferably aligned with the first cavity (3) or the second cavity (4). 20. La batería de la reivindicación 1 caracterizada porque, la cubierta (19) preferentemente es de un material aislante. 20. The battery of claim 1 characterized in that the cover (19) is preferably made of an insulating material. 21. La batería electrolítica de las reivindicaciones anteriores caracterizada porque, unos rieles (20) se pueden colocar en la parte media del interior del contenedor (1), para que sobre ellos se coloque el aislador (2). 21. The electrolytic battery of the preceding claims, characterized in that rails (20) can be placed in the middle part of the interior of the container (1), so that the insulator (2) is placed on them. 22. La batería electrolítica de las reivindicaciones anteriores caracterizada porque, la interconexión de polos opuestos entre la primera cavidad (3) y la segunda cavidad (4) permite realizar una conexión en serie de dos fuentes de energía independientes. 22. The electrolytic battery of the preceding claims, characterized in that the interconnection of opposite poles between the first cavity (3) and the second cavity (4) allows a series connection of two independent energy sources.
PCT/MX2020/000010 2020-03-10 2020-03-13 Electrolytic battery Ceased WO2021182943A1 (en)

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Citations (5)

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JP2011040318A (en) * 2009-08-17 2011-02-24 Hitachi Vehicle Energy Ltd Lithium secondary battery
JP2014222569A (en) * 2013-05-13 2014-11-27 一徳 清家 Secondary battery of silicon catalyst positive electrode and manufacturing method thereof
US20160013484A1 (en) * 2014-07-08 2016-01-14 Hitachi, Ltd. Lithium ion secondary battery
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011040318A (en) * 2009-08-17 2011-02-24 Hitachi Vehicle Energy Ltd Lithium secondary battery
JP2014222569A (en) * 2013-05-13 2014-11-27 一徳 清家 Secondary battery of silicon catalyst positive electrode and manufacturing method thereof
US20160013484A1 (en) * 2014-07-08 2016-01-14 Hitachi, Ltd. Lithium ion secondary battery
US20170317383A1 (en) * 2014-10-29 2017-11-02 Hitachi Maxell, Ltd. Lithium-ion secondary battery
WO2019087683A1 (en) * 2017-10-31 2019-05-09 株式会社Gsユアサ Lead storage battery

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