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WO2021182005A1 - Feuille stratifiée et son procédé de fabrication - Google Patents

Feuille stratifiée et son procédé de fabrication Download PDF

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Publication number
WO2021182005A1
WO2021182005A1 PCT/JP2021/005161 JP2021005161W WO2021182005A1 WO 2021182005 A1 WO2021182005 A1 WO 2021182005A1 JP 2021005161 W JP2021005161 W JP 2021005161W WO 2021182005 A1 WO2021182005 A1 WO 2021182005A1
Authority
WO
WIPO (PCT)
Prior art keywords
protective film
layer
laminated
film
adhesive layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2021/005161
Other languages
English (en)
Japanese (ja)
Inventor
載鎬 沈
大山 姜
東輝 金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2020192295A external-priority patent/JP2021144208A/ja
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to CN202180019939.0A priority Critical patent/CN115244439B/zh
Priority to KR1020227026244A priority patent/KR20220148805A/ko
Publication of WO2021182005A1 publication Critical patent/WO2021182005A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/263—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer having non-uniform thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00—Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36—Removing material
    • B23K26/38—Removing material by boring or cutting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/16—Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0008—Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B43/00—Operations specially adapted for layered products and not otherwise provided for, e.g. repairing; Apparatus therefor
    • B32B43/003—Cutting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/023—Optical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/06—Interconnection of layers permitting easy separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/42—Polarizing, birefringent, filtering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00—Treatment by energy or chemical effects
    • B32B2310/08—Treatment by energy or chemical effects by wave energy or particle radiation
    • B32B2310/0806—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
    • B32B2310/0843—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation using laser

Definitions

  • the present invention relates to a laminated sheet and a method for producing the same.
  • the front plate and the laminated sheet provided with the polarizing layer are attached to the display panel via the adhesive layer formed on the polarizing layer side to form a display device.
  • a separate film is laminated on the adhesive layer and a surface protective film is laminated on the front plate in order to prevent the surface of the laminated sheet from being contaminated or damaged until the laminated sheets are bonded.
  • the surface protective film side is first attracted to hold the laminated sheet.
  • the separate film is peeled off to expose the pressure-sensitive adhesive layer, and the laminate is attached to the display panel via the pressure-sensitive adhesive layer.
  • the laminated sheet provided with the front plate and the polarizing layer is manufactured by cutting from a long laminated body into a single-wafered body having a predetermined shape by a laser.
  • cutting with a laser causes minute cracks at the edges of the laminated sheet (for example, the length thereof is 200 ⁇ m or less) as compared with cutting with a cutting tool. It is excellent in that it is difficult to generate.
  • the laminated sheet may break due to the minute cracks at the time of bending, so it is desirable to cut with a laser. ..
  • An object of the present invention is to provide a laminated sheet whose suction force does not easily decrease when the laminated sheet is attached to a display panel.
  • the first protective film and the polarizing layer are laminated in this order.
  • the first protective film has a first pressure-sensitive adhesive layer on one surface of the first resin film.
  • the first protective film is laminated on the polarizing layer via the first pressure-sensitive adhesive layer.
  • the first protective film can be peeled off from the polarizing layer, and the first protective film can be peeled off from the polarizing layer.
  • the first protective film, the front plate, and the polarizing layer are laminated in this order.
  • the first protective film has a first pressure-sensitive adhesive layer on one surface of the first resin film.
  • the first protective film is laminated on the front plate via the first pressure-sensitive adhesive layer.
  • the first protective film can be peeled off from the front plate.
  • the second protective film, the first protective film, and the polarizing layer are laminated in this order.
  • the first protective film has a first pressure-sensitive adhesive layer on one surface of the first resin film.
  • the first protective film is laminated on the polarizing layer via the first pressure-sensitive adhesive layer.
  • the second protective film has a second pressure-sensitive adhesive layer on one surface of the second resin film.
  • the second protective film is laminated on the first protective film via the second adhesive layer.
  • the first protective film can be peeled off from the polarizing layer, and the first protective film can be peeled off from the polarizing layer.
  • the second protective film can be peeled off from the first protective film, a preparatory step for preparing a laminate, and A method for manufacturing a laminated sheet, which comprises a cutting step of cutting the laminated body into a predetermined shape by irradiating the laminated body with laser light from the polarizing layer side to obtain a laminated sheet.
  • the second protective film, the first protective film, the front plate, and the polarizing layer are laminated in this order.
  • the first protective film has a first pressure-sensitive adhesive layer on one surface of the first resin film.
  • the first protective film is laminated on the front plate via the first pressure-sensitive adhesive layer.
  • the second protective film has a second pressure-sensitive adhesive layer on one surface of the second resin film.
  • the second protective film is laminated on the first protective film via the second adhesive layer.
  • the first protective film can be peeled off from the front plate.
  • the second protective film can be peeled off from the first protective film, a preparatory step for preparing a laminate, and A method for manufacturing a laminated sheet, which comprises a cutting step of cutting the laminated body into a predetermined shape by irradiating the laminated body with laser light from the polarizing layer side to obtain a laminated sheet.
  • a method for manufacturing a laminated sheet which comprises a cutting step of cutting the laminated body into a predetermined shape by irradiating the laminated body with laser light from the polarizing layer side to obtain a laminated sheet.
  • the present invention it is possible to provide a laminated sheet in which the adsorption force does not easily decrease when the laminated sheet is attached to the display panel.
  • FIG. 1 is a schematic cross-sectional view showing an example of the laminated sheet of the present invention.
  • the first protective film 100, the front plate 1, and the polarizing layer 2 are laminated in this order.
  • the front plate 1 and the polarizing layer 2 are bonded by a bonding layer 3.
  • the polarizing layer 2 has a linear polarizing plate 20 and a retardation film 22 from the front plate 1 side.
  • the first protective film 100 corresponds to a so-called surface protective film, and has a first pressure-sensitive adhesive layer 102 on one surface of the first resin film 101.
  • the first protective film 100 is laminated on the front plate 1 via the first adhesive layer 102.
  • the adhesive strength of the first protective film 100 is adjusted so that the first protective film 100 can be peeled off from the front plate 1 and the first adhesive layer 102 can be peeled off from the front plate 1.
  • FIG. 4 is a schematic cross-sectional view showing an example of the laminated sheet of the present invention.
  • the first protective film 100 and the polarizing layer 2 are laminated in this order.
  • the polarizing layer 2 has a linear polarizing plate 20 and a retardation film 22 from the first protective film 100 side.
  • the first protective film 100 corresponds to a so-called surface protective film, and has a first pressure-sensitive adhesive layer 102 on one surface of the first resin film 101.
  • the first protective film 100 is laminated on the polarizing layer 2 via the first pressure-sensitive adhesive layer 102.
  • the adhesive strength of the first protective film 100 is adjusted so that it can be peeled off from the polarizing layer 2 and the first pressure-sensitive adhesive layer 102 can be peeled off from the polarizing layer 2.
  • the laminated sheet may be provided with a third pressure-sensitive adhesive layer and a third resin film on the side of the polarizing layer opposite to the front plate side (or the first protective film side).
  • 2 and 5 are schematic cross-sectional views showing an example of the laminated sheet of the present invention.
  • the first protective film 100, the front plate 1, the polarizing layer 2, the third adhesive layer 50, and the third resin film 51 are laminated in this order.
  • the front plate 1 and the polarizing layer 2 are bonded by a bonding layer 3.
  • the polarizing layer 2 has a linear polarizing plate 20 and a retardation film 22 from the front plate 1 side.
  • the third resin film 51 can correspond to a so-called separate film, and the third pressure-sensitive adhesive layer 50 can be a pressure-sensitive adhesive layer for adhering the laminated sheet to the display panel.
  • the surface of the third resin film 51 can be released from the third pressure-sensitive adhesive layer 50 so that the third resin film 51 can be peeled off from the third pressure-sensitive adhesive layer 50.
  • the first protective film 100, the polarizing layer 2, the third adhesive layer 50, and the third resin film 51 are laminated in this order.
  • the polarizing layer 2 has a linear polarizing plate 20 and a retardation film 22 from the first protective film 100 side.
  • the third resin film 51 can correspond to a so-called separate film, and the third pressure-sensitive adhesive layer 50 can be a pressure-sensitive adhesive layer for adhering the laminated sheet to the display panel. The surface of the third resin film 51 can be released from the third pressure-sensitive adhesive layer 50 so that the third resin film 51 can be peeled off from the third pressure-sensitive adhesive layer 50.
  • the laminated sheet can include layers other than the layers shown in FIGS. 1 to 2 and 4 to 5.
  • the laminated sheet is, for example, a touch sensor layer, a colored layer formed in a plan view between the front plate 1 and the polarizing layer 2, and an impact resistant film arranged between the front plate 1 and the polarizing layer 2. , And a resin film or the like may be provided.
  • the height of burrs on the outer peripheral edge of the first protective film is 6.0 ⁇ m or less.
  • the burrs are the outer residues of the geometry at the corner edges of the laminate and can be residues on the laminate after undergoing a machining or molding process.
  • the burr is a surface of the first protective film on the side opposite to the first adhesive layer side, and is present on the outer peripheral edge thereof, and is a material constituting the laminated sheet (particularly, a material of the first protective film). ) Can be melted and solidified.
  • the burrs can be those produced by laser processing.
  • the burr may be present on at least a part of the entire outer peripheral edge portion of the first protective film in a plan view, and may be present on the entire outer peripheral edge portion.
  • the burr 40 is a surface of the first protective film 100 opposite to the surface of the first adhesive layer 102, and is present on the outer peripheral edge thereof in a plan view.
  • the height of the burr corresponds to the height represented by reference numeral 41.
  • the height of the burr on the outer peripheral edge of the first protective film is 6.0 ⁇ m or less, the gap between the laminated sheet and the suction device can be reduced. Therefore, it is presumed that the force for adsorbing the laminated sheet is less likely to decrease. Therefore, the height of the burr is preferably 2.0 ⁇ m or less, more preferably 1.5 ⁇ m or less, further preferably 1.0 ⁇ m or less, and may be 0.7 ⁇ m or less.
  • the lower limit of the burr height is not particularly limited, but the burr height can be 0.01 ⁇ m or more, 0.1 ⁇ m or more, and may be 0.3 ⁇ m or more. If the height of the burr is within the above range, there is also a problem (multiple removal) in which a plurality of laminated sheets are taken out when the uppermost laminated sheet is taken out from the laminated body of the laminated sheets in which a plurality of laminated sheets are overlapped. Easy to prevent.
  • the height of the burr can be measured using a stylus type film thickness meter.
  • the stylus type film thickness meter include DEKTAK32 (manufactured by VEECO).
  • the laminated sheet can also have burrs on the surface opposite to the first protective film side.
  • the burr is the surface of the third resin film on the side opposite to the third pressure-sensitive adhesive layer side, and can be present on the outer peripheral edge portion thereof.
  • the burr can be a material obtained by melting and solidifying a material (particularly, a material of the third resin film) constituting the laminated sheet.
  • the height of burrs that can exist on the surface opposite to the first protective film side can be more than 0 ⁇ m and 100 ⁇ m or less, and may be larger than the height of burrs on the outer peripheral edge of the first protective film.
  • the laminated film including the front plate 1 and the polarizing layer 2 constituting the laminated sheet can be bent at least in the direction in which the front plate 1 is on the inside and the polarizing layer 2 is on the outside (so-called In-folding method). preferable. Bendable means that the front plate 1 can be bent in the direction in which the polarizing layer 2 is on the outside without cracking.
  • the laminated film including the polarizing layer 2 constituting the laminated sheet can be bent in a direction in which at least the linear polarizing plate 20 is on the inside and the retardation film 22 is on the outside (so-called In-folding method). It is preferable to have. Bendable means that the linear polarizing plate 20 can be bent in the direction in which the linear polarizing plate 20 is on the inside and the retardation film 22 is on the outside without cracking.
  • the shape of the laminated sheet in the plane direction may be, for example, a square shape, preferably a square shape having a long side and a short side, and more preferably a rectangle.
  • the length of the long side may be, for example, 10 mm to 1400 mm, preferably 50 mm to 600 mm.
  • the length of the short side is, for example, 5 mm to 800 mm, preferably 30 mm to 500 mm, and more preferably 50 mm to 300 mm.
  • Each layer constituting the laminated sheet may have a corner portion R-processed, an end portion notched, or a perforated process.
  • the thickness of the laminated sheet is not particularly limited because it varies depending on the function required for the laminated sheet, the application of the laminated sheet, etc., but is, for example, 20 ⁇ m to 1,000 ⁇ m, preferably 50 ⁇ m to 500 ⁇ m.
  • the first protective film corresponds to a so-called surface protective film, and has a first pressure-sensitive adhesive layer on one surface of the first resin film.
  • the first protective film is laminated on the front plate via the first pressure-sensitive adhesive layer.
  • the first protective film is peeled off together with the first adhesive layer contained therein. Therefore, the adhesive strength of the first protective film is adjusted so that the first protective film can be peeled off from the front plate and the first adhesive layer can be peeled off from the front plate.
  • the first protective film is laminated on the polarizing layer via the first pressure-sensitive adhesive layer.
  • the first protective film is peeled off together with the first adhesive layer contained therein. Therefore, the adhesive strength of the first protective film is adjusted so that it can be peeled off from the polarizing layer and the first pressure-sensitive adhesive layer can be peeled off from the polarizing layer.
  • the thickness of the first protective film can be, for example, 30 ⁇ m or more and 200 ⁇ m or less, and 50 ⁇ m or more and 150 ⁇ m or less.
  • the thickness of the first protective film refers to the thickness of the central portion (not the outer peripheral edge portion) of the laminated sheet.
  • the resin constituting the first resin film is, for example, a polyethylene resin such as polyethylene, a polypropylene resin such as polypropylene, a polyester resin such as polyethylene terephthalate or polyethylene naphthalate, or a thermoplastic resin such as a polycarbonate resin. There can be.
  • a polyester resin such as polyethylene terephthalate is preferable.
  • the first resin film may have a single-layer structure or a multi-layer structure, but is preferably a single-layer structure from the viewpoint of ease of manufacture, production cost, and the like.
  • the thickness of the first resin film can be, for example, 20 ⁇ m or more and 200 ⁇ m or less, and 30 ⁇ m or more and 150 ⁇ m or less.
  • the thickness of the first resin film refers to the thickness of the central portion (not the outer peripheral edge portion) of the laminated sheet.
  • the first pressure-sensitive adhesive layer can be composed of a pressure-sensitive adhesive composition containing a resin as a main component, such as (meth) acrylic-based, rubber-based, urethane-based, ester-based, silicone-based, and polyvinyl ether-based. Among them, a pressure-sensitive adhesive composition using a (meth) acrylic resin having excellent transparency, weather resistance, heat resistance and the like as a base polymer is preferable.
  • the pressure-sensitive adhesive composition may be an active energy ray-curable type or a thermosetting type.
  • Examples of the (meth) acrylic resin (base polymer) used in the pressure-sensitive adhesive composition include butyl (meth) acrylate, ethyl (meth) acrylate, isooctyl (meth) acrylate, and 2- (meth) acrylate.
  • a polymer or copolymer having one or more (meth) acrylic acid esters such as ethylhexyl as a monomer is preferably used.
  • the base polymer may be copolymerized with a polar monomer.
  • Examples of the polar monomer include (meth) acrylic acid, 2-hydroxypropyl (meth) acrylate, hydroxyethyl (meth) acrylate, (meth) acrylamide, N, N-dimethylaminoethyl (meth) acrylate, and glycidyl ().
  • Examples thereof include monomers having a carboxyl group, a hydroxyl group, an amide group, an amino group, an epoxy group and the like, such as meta) acrylate.
  • the pressure-sensitive adhesive composition can contain a cross-linking agent.
  • a cross-linking agent a metal ion having a valence of 2 or more that forms a carboxylic acid metal salt with a carboxyl group; a polyamine compound that forms an amide bond with a carboxyl group; poly.
  • examples include epoxy compounds and polyols that form an ester bond with a carboxyl group; polyisocyanate compounds that form an amide bond with a carboxyl group. Of these, polyisocyanate compounds are preferable.
  • the pressure-sensitive adhesive composition includes fine particles for imparting light scattering, beads (resin beads, glass beads, etc.), glass fibers, resins other than the base polymer, pressure-sensitive adhesives, fillers (metal powders and other inorganic powders). Etc.), antioxidants, UV absorbers, dyes, pigments, colorants, antifoaming agents, corrosion inhibitors, photopolymerization initiators and other additives may be included.
  • It can be formed by applying an organic solvent diluent of the above pressure-sensitive adhesive composition on a substrate and drying it.
  • the thickness of the first pressure-sensitive adhesive layer is preferably 5 ⁇ m or more, and more preferably 10 ⁇ m or more.
  • the upper limit of the thickness of the first pressure-sensitive adhesive layer is not particularly limited, but may be 50 ⁇ m or less, or 40 ⁇ m or less.
  • the front plate 1 can be a layer constituting the outermost surface of the display device when viewed from the visual side.
  • the material and thickness of the front plate 1 are not limited as long as it is a plate-like body capable of transmitting light, and the front plate 1 may be composed of only one layer or may be composed of two or more layers. Examples thereof include resin films and glass films.
  • the front plate preferably has a resin film.
  • the front plate 1 may be a laminate of a resin film and a glass film.
  • the thickness of the front plate 1 may be, for example, 30 to 200 ⁇ m, preferably 50 to 150 ⁇ m, and more preferably 50 to 100 ⁇ m.
  • the material thereof is, for example, an acrylic resin such as polymethyl (meth) acrylate and polyethyl (meth) acrylate; a polyolefin resin such as polyethylene, polypropylene, polymethylpentene and polystyrene; Cellular resins such as acetyl cellulose, acetyl cellulose butyrate, propionyl cellulose, butyryl cellulose and acetyl propionyl cellulose; polyvinyl chloride resins such as ethylene-vinyl acetate copolymer, polyvinyl chloride, polyvinylidene chloride, polyvinyl alcohol and polyvinyl acetal.
  • an acrylic resin such as polymethyl (meth) acrylate and polyethyl (meth) acrylate
  • a polyolefin resin such as polyethylene, polypropylene, polymethylpentene and polystyrene
  • Cellular resins such as acetyl cellulose, acetyl
  • Pulmonate resins such as polysulfone and polyether sulfone; ketone resins such as polyether ketone and polyether ether ketone; polyetherimide; polycarbonate resin; polyester resin; polyimide resin; polyamideimide resin; and polyamide resin Examples include resin. These polymers can be used alone or in combination of two or more. Above all, from the viewpoint of improving strength and transparency, it is preferable to use a polycarbonate resin, a polyester resin, a polyimide resin, a polyamide-imide resin, or a polyamide resin.
  • the thickness of the resin film may be, for example, 10 to 100 ⁇ m, preferably 20 to 70 ⁇ m, and more preferably 30 to 60 ⁇ m.
  • the front plate 1 may be a film in which a hard coat layer is provided on at least one surface of the resin film to further improve the hardness.
  • the hard coat layer may be formed on one surface of the resin film or may be formed on both surfaces. By providing the hard coat layer, it is possible to obtain a front plate having improved hardness and scratchability.
  • the hard coat layer is, for example, a cured layer of an ultraviolet curable resin. Examples of the ultraviolet curable resin include acrylic resin, silicone resin, polyester resin, urethane resin, amide resin, epoxy resin and the like.
  • the hard coat layer may contain additives to improve hardness. Additives are not limited, and examples thereof include inorganic fine particles, organic fine particles, and mixtures thereof.
  • a wear-resistant layer is formed on the visible side of the hard coat layer in order to improve wear resistance and prevent contamination by sebum and the like.
  • the front plate can have an abrasion resistant layer, and the abrasion resistant layer can be a layer constituting the visible side surface of the front plate.
  • the wear-resistant layer contains a structure derived from a fluorine compound.
  • a fluorine compound a compound having a silicon atom and having a hydrolyzable group such as an alkoxy group or a halogen in the silicon atom is preferable.
  • a coating film can be formed by the dehydration condensation reaction of the hydrolyzable groups, and the adhesion of the wear-resistant layer can be improved by reacting with the active hydrogen on the surface of the base material.
  • the fluorine compound has a perfluoroalkyl group or a perfluoropolyether structure because it can impart water repellency.
  • a fluorine-containing polyorganosiloxane compound having a perfluoropolyether structure and a long-chain alkyl group having 4 or more carbon atoms is also preferable to use two or more kinds of compounds as the fluorine compound.
  • the fluorine compound preferably contained is a fluorine-containing organosiloxane compound containing an alkylene group having 2 or more carbon atoms and a perfluoroalkylene group.
  • the thickness of the wear-resistant layer is, for example, 1 to 20 nm.
  • the abrasion resistant layer has water repellency, and the water contact angle is, for example, about 110 to 125 °.
  • the contact angle hysteresis and the sliding angle measured by the sliding method are about 3 to 20 ° and about 2 to 55 °, respectively.
  • the wear-resistant layer is a silanol condensation catalyst, an antioxidant, a rust preventive, an ultraviolet absorber, a light stabilizer, a fungicide, an antibacterial agent, an antibiotic agent, and an extinguishing agent, as long as the effect of the present invention is not impaired. It may contain various additives such as odorants, pigments, flame retardants, and antistatic agents.
  • a primer layer may be provided between the abrasion resistant layer and the hard coat layer.
  • the primer agent include a primer agent such as an ultraviolet curable type, a thermosetting type, a moisture curable type, or a two-component curable type epoxy compound.
  • a polyamic acid may be used as the primer agent, and it is also preferable to use a silane coupling agent.
  • the thickness of the primer layer is, for example, 0.001 to 2 ⁇ m.
  • a primer agent is applied, dried, and cured as necessary on the hard coat layer to form a primer layer, and then a fluorine compound is applied. It can be formed by applying and drying the containing composition (composition for coating an abrasion-resistant layer).
  • the coating method include a dip coating method, a roll coating method, a bar coating method, a spin coating method, a spray coating method, a die coating method, and a gravure coater method. It is also preferable that the coated surface is subjected to a hydrophilic treatment such as plasma treatment, corona treatment, or ultraviolet treatment before applying the primer agent or the composition for coating the abrasion resistant layer.
  • This laminate can be laminated directly on the front plate, or it can be laminated on another transparent base material and bonded to the front plate using an adhesive or an adhesive.
  • the front plate 1 has a glass film
  • tempered glass for a display is preferably used as the glass film.
  • the thickness of the glass film may be, for example, 10 ⁇ m or more and 500 ⁇ m or less, and may be 20 ⁇ m or more and 100 ⁇ m or less.
  • the front plate 1 may have a function as a window film in the display device.
  • the front plate 1 may further have a function as a touch sensor, a blue light cut function, a viewing angle adjusting function, and the like.
  • the polarizing layer can have a linear polarizing plate and a retardation film from the side closer to the front plate.
  • the polarizing layer may be a circular polarizing plate (including an elliptical polarizing plate). Since the circularly polarizing plate can absorb the external light reflected in the display device, it is possible to impart a function as an antireflection film to the laminated sheet.
  • the polarizing layer preferably has a layer in which the polymerizable liquid crystal compound is cured. According to the present invention, the height of burrs can be reduced and the flexibility can be improved while the polymerizable liquid crystal compound has a cured layer.
  • the linear polarizing plate has a function of selectively transmitting unidirectional linearly polarized light composed of unpolarized light rays such as natural light.
  • the linearly polarizing plate contains a stretched film or stretched layer on which a dichroic dye is adsorbed, a cured product of a polymerizable liquid crystal compound, and a dichroic dye, and the dichroic dye is dispersed in the layer on which the polymerizable liquid crystal compound is cured.
  • an oriented liquid crystal layer or the like can be provided as a polarizer.
  • a linear polarizing plate using a liquid crystal layer as a polarizer is preferable because there is no limitation in the bending direction as compared with a stretched film or a stretched layer on which a dichroic dye is adsorbed.
  • the polarizer which is a stretched film on which a dichroic dye is adsorbed, is usually obtained by uniaxially stretching the polyvinyl alcohol-based resin film and dyeing the polyvinyl alcohol-based resin film with a dichroic dye such as iodine. It can be produced through a step of adsorbing a dichroic dye, a step of treating a polyvinyl alcohol-based resin film on which a dichroic dye is adsorbed with an aqueous boric acid solution, and a step of washing with water after the treatment with the aqueous boric acid solution.
  • the thickness of the polarizer is usually 30 ⁇ m or less, preferably 18 ⁇ m or less, and more preferably 15 ⁇ m or less. Reducing the thickness of the polarizer is advantageous for thinning the laminated sheet.
  • the thickness of the polarizer is usually 1 ⁇ m or more, and may be, for example, 5 ⁇ m or more.
  • the polyvinyl alcohol-based resin is obtained by saponifying the polyvinyl acetate-based resin.
  • the polyvinyl acetate-based resin in addition to polyvinyl acetate which is a homopolymer of vinyl acetate, a copolymer of vinyl acetate and another monomer copolymerizable therewith is used.
  • examples of other monomers copolymerizable with vinyl acetate include unsaturated carboxylic acid compounds, olefin compounds, vinyl ether compounds, unsaturated sulfone compounds, and (meth) acrylamide compounds having an ammonium group. ..
  • the degree of saponification of the polyvinyl alcohol-based resin is usually about 85 mol% or more and 100 mol% or less, preferably 98 mol% or more.
  • the polyvinyl alcohol-based resin may be modified, and polyvinyl formal, polyvinyl acetal, and the like modified with aldehydes can also be used.
  • the degree of polymerization of the polyvinyl alcohol-based resin is usually 1000 or more and 10000 or less, preferably 1500 or more and 5000 or less.
  • the polarizer which is a stretched layer on which a dichroic dye is adsorbed, is usually a step of applying a coating liquid containing the polyvinyl alcohol-based resin on a base film, a step of uniaxially stretching the obtained laminated film, and a uniaxial stretching.
  • a dichroic dye By dyeing the polyvinyl alcohol-based resin layer of the laminated film with a dichroic dye, the dichroic dye is adsorbed to form a polarizer, and the film on which the dichroic dye is adsorbed is treated with a boric acid aqueous solution. It can be produced through a step of treating and a step of washing with water after treatment with an aqueous boric acid solution.
  • the base film used for forming the polarizer may be used as a protective layer for the polarizer. If necessary, the base film may be peeled off from the polarizer.
  • the material and thickness of the base film may be the same as the material and thickness of the resin film described later.
  • the stretched film or the polarizing element which is the stretched layer on which the dichroic dye is adsorbed may be used as it is as a linear polarizing plate, or a resin film may be attached to one or both sides thereof and used as a linear polarizing plate.
  • the thickness of the linearly polarizing plate is preferably 2 ⁇ m or more and 40 ⁇ m or less.
  • the resin film is, for example, a cyclopolyolefin resin film; a cellulose acetate resin film made of a resin such as triacetyl cellulose or diacetyl cellulose; a polyester resin film made of a resin such as polyethylene terephthalate, polyethylene naphthalate, or polybutylene terephthalate; a polycarbonate resin film.
  • films known in the art such as resin films; (meth) acrylic resin films; polypropylene-based resin films can be mentioned.
  • the polarizer and the protective layer can be laminated via a bonding layer described later.
  • the thickness of the resin film is, for example, 100 ⁇ m or less, preferably 80 ⁇ m or less, more preferably 60 ⁇ m or less, further preferably 40 ⁇ m or less, still more preferably 30 ⁇ m or less, and usually 10 ⁇ m or more. From the viewpoint of increasing the absorption rate of the laser, it is preferably 15 ⁇ m or more.
  • a hard coat layer may be formed on the resin film.
  • the hard coat layer may be formed on one surface of the resin film or may be formed on both sides.
  • a thermoplastic resin film having improved hardness and scratchability can be obtained.
  • the hard coat layer can be formed in the same manner as the hard coat layer formed on the resin film described above.
  • the polymerizable liquid crystal compound used for forming the liquid crystal layer is a compound having a polymerizable reactive group and exhibiting liquid crystallinity.
  • the polymerizable reactive group is a group involved in the polymerization reaction, and is preferably a photopolymerizable reactive group.
  • the photopolymerizable reactive group refers to a group that can participate in the polymerization reaction by an active radical, an acid, or the like generated from the photopolymerization initiator.
  • Examples of the photopolymerizable functional group include a vinyl group, a vinyloxy group, a 1-chlorovinyl group, an isopropenyl group, a 4-vinylphenyl group, an acryloyloxy group, a methacryloyloxy group, an oxylanyl group, an oxetanyl group and the like.
  • an acryloyloxy group, a methacryloyloxy group, a vinyloxy group, an oxylanyl group and an oxetanyl group are preferable, and an acryloyloxy group is more preferable.
  • the type of the polymerizable liquid crystal compound is not particularly limited, and a rod-shaped liquid crystal compound, a disk-shaped liquid crystal compound, and a mixture thereof can be used.
  • the liquid crystal property of the polymerizable liquid crystal compound may be a thermotropic liquid crystal or a lyotropic liquid crystal, and the phase-ordered structure may be a nematic liquid crystal or a smectic liquid crystal.
  • the dichroic dye used for the polarizing element which is a liquid crystal layer, preferably has an absorption maximum wavelength ( ⁇ MAX) in the range of 300 to 700 nm.
  • a dichroic dye include an acridine dye, an oxazine dye, a cyanine dye, a naphthalene dye, an azo dye, an anthraquinone dye and the like, and among them, the azo dye is preferable.
  • the azo dye include a monoazo dye, a bisazo dye, a trisazo dye, a tetrakisazo dye, a stillbenazo dye and the like, and a bisazo dye and a trisazo dye are preferable.
  • the dichroic dye may be used alone or in combination of two or more, but it is preferable to combine three or more. In particular, it is more preferable to combine three or more kinds of azo compounds.
  • a part of the dichroic dye may have a reactive group or may have a liquid crystal property.
  • the polarizing element which is a liquid crystal layer
  • a composition for forming a polarizing element containing a polymerizable liquid crystal compound and a dichroic dye is applied onto an alignment film formed on a base film, and the polymerizable liquid crystal compound is polymerized. It can be formed by curing.
  • the base film used for forming the polarizer may be used as a protective layer for the polarizer.
  • the material and thickness of the base film may be the same as the material and thickness of the resin film described above.
  • compositions for forming a polarizer containing a polymerizable liquid crystal compound and a dichroic dye examples include JP2013-37353A, JP2013-33249, and Japanese Patent Publication No. 2013-33249. Examples thereof include those described in Japanese Patent Publication No. 2017-83843.
  • the composition for forming a polarizer further contains additives such as a solvent, a polymerization initiator, a cross-linking agent, a leveling agent, an antioxidant, a plasticizer, and a sensitizer, in addition to the polymerizable liquid crystal compound and the dichroic dye. You may be. Only one of these components may be used, or two or more of these components may be used in combination.
  • the polymerization initiator that may be contained in the polarizer-forming composition is a compound that can initiate the polymerization reaction of the polymerizable liquid crystal compound, and is photopolymerizable in that the polymerization reaction can be initiated under lower temperature conditions. Initiators are preferred. Specific examples thereof include photopolymerization initiators capable of generating active radicals or acids by the action of light, and among them, photopolymerization initiators that generate radicals by the action of light are preferable.
  • the content of the polymerization initiator is preferably 1 part by mass or more and 10 parts by mass or less, and more preferably 3 parts by mass or more and 8 parts by mass or less, based on 100 parts by mass of the total amount of the polymerizable liquid crystal compound. Within this range, the reaction of the polymerizable group proceeds sufficiently, and the orientation state of the liquid crystal compound is likely to be stabilized.
  • the thickness of the polarizing element which is the liquid crystal layer, is usually 10 ⁇ m or less, preferably 0.5 ⁇ m or more and 8 ⁇ m or less, and more preferably 1 ⁇ m or more and 5 ⁇ m or less.
  • the polarizer which is a liquid crystal layer
  • the polarizer may be used as a linear polarizing plate without peeling and removing the base film, or may be used as a linear polarizing plate by peeling and removing the base film from the polarizer.
  • the polarizing element which is a liquid crystal layer, may be used as a linear polarizing plate by forming a protective layer on one side or both sides thereof.
  • the protective layer the above-mentioned resin film can be used.
  • the polarizer which is a liquid crystal layer, may have an overcoat layer on one side or both sides of the polarizer for the purpose of protecting the polarizer and the like.
  • the overcoat layer can be formed, for example, by applying a material (composition) for forming the overcoat layer on the polarizer.
  • the material constituting the overcoat layer include a photocurable resin and a water-soluble polymer.
  • a (meth) acrylic resin, a polyvinyl alcohol-based resin, or the like can be used as a material constituting the overcoat layer.
  • the retardation film included in the polarizing layer may be composed of one retardation layer or may be a laminate of two or more retardation layers.
  • the retardation film preferably includes a retardation layer including a layer on which the polymerizable liquid crystal compound is cured.
  • each retardation layer is a retardation layer including a layer in which a polymerizable liquid crystal compound is cured.
  • the retardation film is laminated on the side opposite to the front plate side (or the first protective film side) of the polarizer.
  • the retardation film may have an overcoat layer that protects the surface thereof, a base film that supports the retardation film, and the like.
  • the retardation film preferably includes a ⁇ / 4 layer as the retardation layer, and may further include at least one of a ⁇ / 2 layer and a positive C layer.
  • the retardation layer may have an alignment film.
  • the retardation film has a retardation layer having a ⁇ / 2 layer
  • the ⁇ / 2 layer and the ⁇ / 4 layer can be laminated in this order from the polarizer side.
  • the retardation film contains a retardation layer which is a positive C layer
  • the ⁇ / 4 layer and the positive C layer may be laminated in order from the polarizer side
  • the positive C layer and the ⁇ / 4 layer may be laminated in order from the polarizer side. It may be laminated.
  • the thickness of the retardation layer is, for example, 0.1 ⁇ m or more and 10 ⁇ m or less, preferably 0.5 ⁇ m or more and 8 ⁇ m or less, and more preferably 1 ⁇ m or more and 6 ⁇ m or less.
  • the retardation layer may be formed from the resin film exemplified as the material of the protective layer, or may be formed from a layer in which the polymerizable liquid crystal compound is cured.
  • the retardation layer may further include an alignment film.
  • the retardation film may have a bonding layer for bonding the ⁇ / 4 layer, the ⁇ / 2 layer, and the positive C layer.
  • the bonding layer can be formed from an adhesive layer or an adhesive layer, as will be described later.
  • the retardation layer can be formed by applying a composition containing the polymerizable liquid crystal compound to a base film and curing it.
  • An alignment film may be formed between the base film and the coating layer.
  • the material and thickness of the base film may be the same as the material and thickness of the resin film.
  • the retardation layer may be incorporated into a laminated sheet in the form of having an alignment film and a base film. The retardation layer can be bonded to the linear polarizing plate via the bonding layer.
  • the touch sensor layer may have at least a transparent conductive layer and may further have a resin film.
  • the touch sensor layer may include a transparent conductive layer and a resin film in this order from the front plate side (or the first protective film side).
  • the touch sensor layer may be provided with a resin film and a transparent conductive layer in this order from the front plate side (or the first protective film side).
  • the touch sensor layer does not have to have a resin film.
  • the touch sensor layer may include a separation layer, a bonding layer, and a protective layer in addition to the transparent conductive layer and the resin film.
  • the touch sensor layer is a sensor that can detect the touched position on the surface of the display device, and the detection method is not limited as long as it has a transparent conductive layer.
  • Examples of the touch sensor layer detection method include a resistive film method, a capacitance method, an optical sensor method, an ultrasonic method, an electromagnetic induction coupling method, and a surface acoustic wave method.
  • the capacitance type touch sensor layer is preferably used in terms of low cost, fast reaction speed, and thin film formation.
  • the transparent conductive layer may be a transparent conductive layer made of a metal oxide such as ITO, or may be a metal layer made of a metal such as aluminum, copper, silver, gold, or an alloy thereof.
  • the separation layer can be a layer formed on a substrate such as glass and for separating the transparent conductive layer formed on the separation layer from the substrate together with the separation layer.
  • the separation layer is preferably an inorganic layer or an organic layer. Examples of the material forming the inorganic layer include silicon oxide.
  • a (meth) acrylic resin composition, an epoxy resin composition, a polyimide resin composition, or the like can be used as the material for forming the organic material layer.
  • the third pressure-sensitive adhesive layer can be a pressure-sensitive adhesive layer for adhering the laminated sheet to a display panel or the like.
  • the third pressure-sensitive adhesive layer can be composed of the same pressure-sensitive adhesive composition as the first pressure-sensitive adhesive layer.
  • the thickness of the third pressure-sensitive adhesive layer is preferably 10 ⁇ m or more, and more preferably 20 ⁇ m or more.
  • the upper limit of the thickness of the first pressure-sensitive adhesive layer is not particularly limited, but may be 50 ⁇ m or less, or 40 ⁇ m or less.
  • the third resin film is a film that is temporarily attached to protect the surface of the third adhesive layer until it is attached to the display panel or other optical member.
  • the third resin film can be a so-called separate film.
  • the third resin film is usually composed of a resin film having one surface subjected to a mold release treatment such as a silicone-based or fluorine-based mold release agent, and the mold release-treated surface is bonded to the third pressure-sensitive adhesive layer.
  • the resin constituting the third resin film examples include the same resin as the resin constituting the first resin film.
  • the resin constituting the third resin film is preferably a polyester resin such as polyethylene terephthalate.
  • the third resin film may have a single-layer structure or a multi-layer structure, but is preferably a single-layer structure from the viewpoint of ease of manufacture, production cost, and the like.
  • the thickness of the third resin film can be, for example, 20 ⁇ m or more and 100 ⁇ m or less, and 30 ⁇ m or more and 80 ⁇ m or less.
  • the bonding layer can be a layer for bonding each layer, and can be a layer composed of an adhesive or an adhesive. Each laminating layer may be made of the same material or different materials.
  • the retardation films may be bonded to each other with an adhesive layer or may be bonded with an adhesive layer.
  • the linearly polarizing plate and the retardation film are preferably bonded with an adhesive layer.
  • the same pressure-sensitive adhesive layer as the above-mentioned first pressure-sensitive adhesive layer or third pressure-sensitive adhesive layer can be used.
  • the adhesive for example, one or a combination of two or more of water-based adhesives, active energy ray-curable adhesives, and the like can be formed.
  • the water-based adhesive include a polyvinyl alcohol-based resin aqueous solution, a water-based two-component urethane-based emulsion adhesive, and the like.
  • the active energy ray-curable adhesive is an adhesive that cures by irradiating with active energy rays such as ultraviolet rays, and is, for example, an adhesive containing a polymerizable compound and a photopolymerizable initiator, and an adhesive containing a photoreactive resin.
  • Adhesives containing a binder resin and a photoreactive cross-linking agent Adhesives containing a binder resin and a photoreactive cross-linking agent, and the like.
  • the polymerizable compound include photopolymerizable monomers such as a photocurable epoxy monomer, a photocurable acrylic monomer, and a photocurable urethane monomer, and oligomers derived from these monomers.
  • the photopolymerization initiator include compounds containing substances that generate active species such as neutral radicals, anion radicals, and cationic radicals by irradiating them with active energy rays such as ultraviolet rays.
  • the thickness of the pressure-sensitive adhesive layer is preferably 1 ⁇ m or more and 30 ⁇ m or less, more preferably 2 ⁇ m or more and 20 ⁇ m, and 3 ⁇ m or more and 10 ⁇ m or less.
  • the thickness of the adhesive layer is preferably 0.01 ⁇ m or more and 5 ⁇ m or less, and more preferably 0.1 ⁇ m or more and 3 ⁇ m or less.
  • the method for manufacturing a laminated sheet includes a preparatory step for preparing the laminated body and a cutting step for obtaining the laminated sheet from the laminated body.
  • the method for producing the laminated sheet may include a peeling step of peeling the second protective film.
  • the laminate prepared in the preparation step is a laminate in which the second protective film, the first protective film, the front plate, and the polarizing layer are laminated in this order.
  • the first protective film has a first pressure-sensitive adhesive layer on one surface of the first resin film, and the first protective film is laminated on the front plate via the first pressure-sensitive adhesive layer.
  • the second protective film has a second pressure-sensitive adhesive layer on one surface of the second resin film, and the second protective film is laminated on the first protective film via the second pressure-sensitive adhesive layer.
  • the first protective film can be peeled off from the front plate, and the second protective film can be peeled off from the first protective film.
  • the laminated body can have a layer (third pressure-sensitive adhesive layer, third resin film, touch sensor layer, colored layer, impact-resistant film, resin film, etc.) that the laminated sheet may include.
  • the laminate may be long or single frond of a predetermined size.
  • the first protective film, the front plate, and the polarizing layer those described above can be used.
  • the laminate prepared in the preparation step is a laminate in which a second protective film, a first protective film, and a polarizing layer are laminated in this order.
  • the first protective film has a first pressure-sensitive adhesive layer on one surface of the first resin film, and the first protective film is laminated on the polarizing layer via the first pressure-sensitive adhesive layer.
  • the second protective film has a second pressure-sensitive adhesive layer on one surface of the second resin film, and the second protective film is laminated on the first protective film via the second pressure-sensitive adhesive layer.
  • the first protective film can be peeled off from the polarizing layer, and the second protective film can be peeled off from the first protective film.
  • the laminated body can have a layer (third pressure-sensitive adhesive layer, third resin film, touch sensor layer, colored layer, impact-resistant film, resin film, etc.) that the laminated sheet may include.
  • the laminate may be long or single frond of a predetermined size.
  • the first protective film and the polarizing layer those described above can be used.
  • the second protective film 200, the first protective film 100, the front plate 1, and the polarizing layer 2 are laminated in this order.
  • the first protective film 100 has a first pressure-sensitive adhesive layer 102 on one surface of the first resin film 101.
  • the first protective film 100 is laminated on the front plate 1 via the first adhesive layer 102.
  • the second protective film 200 has a second pressure-sensitive adhesive layer 202 on one surface of the second resin film 201.
  • the second protective film 200 is laminated on the first protective film 100 via the second adhesive layer 202.
  • the first protective film 100 can be peeled off from the front plate 1, and the second protective film 200 can be peeled off from the first protective film 100.
  • the second protective film corresponds to a so-called surface protective film, and has a second adhesive layer on one surface of the second resin film.
  • the second protective film is laminated on the first protective film via the second pressure-sensitive adhesive layer. After finishing the cutting step of obtaining the laminated sheet from the laminated body, the second protective film is peeled off together with the second adhesive layer contained therein. Therefore, the adhesive strength of the second protective film is adjusted so that it can be peeled off from the first protective film and the second adhesive layer can be peeled off from the first protective film.
  • the adhesion of the second protective film to the first protective film is preferably smaller than the adhesion of the first protective film to the front plate. In another embodiment, the adhesion of the second protective film to the first protective film is preferably smaller than the adhesion of the first protective film to the polarizing layer. When the second protective film is peeled off, the problem of unintentionally peeling off the first protective film is unlikely to occur.
  • the thickness of the second protective film can be, for example, 30 ⁇ m or more and 200 ⁇ m or less, and 40 ⁇ m or more and 150 ⁇ m or less.
  • Examples of the resin constituting the second resin film include resins similar to the resin constituting the first resin film.
  • the resin constituting the second resin film is preferably a polyester resin such as polyethylene terephthalate.
  • the second resin film may have a single-layer structure or a multi-layer structure, but is preferably a single-layer structure from the viewpoint of ease of manufacture, production cost, and the like.
  • the thickness of the second resin film can be, for example, 20 ⁇ m or more and 100 ⁇ m or less, 30 ⁇ m or more and 80 ⁇ m or less, and may be 40 ⁇ m or more.
  • the second pressure-sensitive adhesive layer can be composed of the same pressure-sensitive adhesive composition as the first pressure-sensitive adhesive layer.
  • the thickness of the second pressure-sensitive adhesive layer is preferably 3 ⁇ m or more, and more preferably 5 ⁇ m or more.
  • the upper limit of the thickness of the first pressure-sensitive adhesive layer is not particularly limited, but may be 50 ⁇ m or less, or 40 ⁇ m or less.
  • the laminated body is produced by laminating each layer on each other, and the order in which each layer is laminated is not particularly limited.
  • the laminated body is obtained by, for example, a manufacturing method including a step of laminating a front plate and a polarizing layer, a step of laminating a first protective film on the front plate, and a step of laminating a second protective film on the first protective film. Be done.
  • the laminate is obtained by a manufacturing method including, for example, a step of laminating a first protective film on a polarizing layer and a step of laminating a second protective film on the first protective film.
  • the cutting step of obtaining the laminated sheet from the laminated body is performed by irradiating the laminated body with laser light from the polarizing layer side (from the anti-visual side) to cut the laminated body into a predetermined shape. That is, the surface on the emission side of the laser beam is formed of the second protective film.
  • the first protective film is not a layer constituting the outermost surface of the laminate, but a layer existing inside the laminate.
  • the outer peripheral edge of the surface on the emission side of the laser beam relatively large burrs are likely to be formed as compared with the outer peripheral edge of the layer existing inside the laminate. Therefore, when the laminated body includes the second protective film, the height of burrs on the outer peripheral edge of the first protective film can be easily reduced to 6.0 ⁇ m or less.
  • the laser for example, a laser that emits light having a wavelength included in the range of 200 nm to 11 ⁇ m is used.
  • the laser may be a continuous wave (CW) laser or a pulsed laser.
  • Examples of the laser include a gas laser such as a CO 2 laser, a solid-state laser such as a YAG laser, and a semiconductor laser.
  • a CO 2 laser is preferable because it can be easily adapted to the absorption region of the laminated sheet.
  • the output of the laser is preferably 50 W or more, more preferably 60 W or more, and further preferably 100 W or more.
  • the upper limit of the laser output is not particularly limited, but can be, for example, 200 W or less.
  • the energy of the laser beam irradiated by scanning a unit length (hereinafter, may be referred to as irradiation energy) is preferably 100 mJ / mm or more, and more preferably 200 mJ / mm or more. It is preferably 250 mJ / mm or more, and more preferably 250 mJ / mm or more.
  • the upper limit of the irradiation energy is not particularly limited, but may be, for example, 1000 mJ / mm or less, and may be 500 mJ / mm or less.
  • the speed at which the laser beam moves on the surface of the laminate (hereinafter, may be referred to as the moving speed) is preferably 50 mm / sec or more and 2000 mm / sec or less, more preferably 100 mm / sec or more and 1000 mm / sec or less, and further preferably. Is 150 mm / sec or more and 700 mm / sec or less, and may be 300 mm / sec or more.
  • the focus of the laser light may be aligned with the surface of the laminated body on the polarizing layer side, may be aligned with the surface of the second protective film side, or inside the laminated body. You may match.
  • the spot size of the laser beam can be 5 ⁇ m or more and 100 ⁇ m or less, and can be 10 ⁇ m or more and 70 ⁇ m or less.
  • the depth of focus (depth of Focus, DOF) of the lens can be 10 ⁇ m or more and 500 ⁇ m or less, and 100 ⁇ m or more and 300 ⁇ m or less.
  • the cutting step may be performed by full cutting, or once a cut is made to a depth that does not cut the laminated body by half cutting, and the laminated body is completely cut by irradiating the laser beam once or multiple times again. You may.
  • Full cut means that all the layers extending in the stacking direction are cut by a single laser irradiation. It is desirable to perform the cutting step in full cut from the viewpoint of reducing the height of burrs on the outer peripheral edge of the first protective film.
  • the method for manufacturing the laminated sheet may include a peeling step for peeling the second protective film.
  • a peeling step for peeling the second protective film By peeling off the second protective film, it is possible to obtain a laminated sheet in which the first protective film, the front plate, and the polarizing layer are laminated in this order.
  • a laminated sheet in which the first protective film and the polarizing layer are laminated in this order can be obtained.
  • the display device is obtained by adsorbing the first protective film to hold the laminated sheet, peeling off the third resin film to expose the pressure-sensitive adhesive layer, and bonding the laminated body to the panel via the pressure-sensitive adhesive layer. Be done.
  • Laminated sheets are particularly preferred for applications where they are applied to the display surface of flexible display panels.
  • the display panel may be configured to be foldable with the viewing side surface inside, or may be configured to be rotatable. Specific examples of the display panel include a liquid crystal display element, an organic EL display element, an inorganic EL display element, a plasma display element, and a field emission type display element.
  • the display device can be used as a mobile device such as a smartphone or tablet, a television, a digital photo frame, an electronic signboard, a measuring instrument or an instrument, an office device, a medical device, a computer device, or the like.
  • a mobile device such as a smartphone or tablet, a television, a digital photo frame, an electronic signboard, a measuring instrument or an instrument, an office device, a medical device, a computer device, or the like.
  • the unit "part" of the ratio of blending substances is based on weight unless otherwise specified.
  • a polyimide (PI) film having a hard coat layer formed on one surface was used as the front plate.
  • the thickness of the polyimide film was 50 ⁇ m, and the thickness of the hard coat layer was 10 ⁇ m.
  • [Circular polarizing plate] An alignment film was formed on one surface of the triacetyl cellulose (TAC) film. A composition having a polymerizable liquid crystal compound and a dichroic dye was applied onto the alignment film. The coating film was oriented and cured to obtain a polarizer. An ultraviolet curable resin was applied onto the polarizer. The coating film was cured to form an overcoat layer. In this way, a linear polarizing plate was obtained. The thickness of the TAC film was 25 ⁇ m, the thickness of the polarizer was 2.5 ⁇ m, and the thickness of the overcoat layer was 1.0 ⁇ m. The polarizer was such that the dichroic dye was dispersed and oriented in the layer on which the polymerizable liquid crystal compound was cured.
  • a ⁇ / 4 layer having a layer on which the polymerizable liquid crystal compound was cured and a positive C layer having a layer on which the polymerizable liquid crystal compound was cured were prepared. Both were bonded together with an ultraviolet curable adhesive to prepare a retardation film.
  • a linearly polarizing plate and a retardation film were bonded together with an acrylic pressure-sensitive adhesive layer to obtain a circularly polarizing plate.
  • the retardation film was laminated on the overcoat layer side of the linearly polarizing plate.
  • the angle formed by the absorption axis of the polarizer and the slow axis of the ⁇ / 4 layer was 45 °.
  • Examples 1 to 4, Comparative Example 2 The front plate and the circularly polarizing plate were laminated with each other via an acrylic pressure-sensitive adhesive layer. The thickness of this acrylic pressure-sensitive adhesive layer was 25 ⁇ m.
  • the front plate was laminated on the TAC film side of the circularly polarizing plate.
  • An acrylic pressure-sensitive adhesive layer was laminated on the retardation film provided in the circularly polarizing plate, and a third resin film was further laminated.
  • the first protective film was laminated on the front plate via the adhesive layer provided in the first protective film.
  • the second protective film was laminated on the first protective film via the adhesive layer provided in the second protective film. In this way, a laminate in which the second protective film, the first protective film, the front plate, the circularly polarizing plate, the third pressure-sensitive adhesive layer, and the third resin film were laminated in this order was produced.
  • the first protective film was peelable from the front plate, and the second protective film was peelable from the first protective film.
  • the laminate was cut into a predetermined shape (length 20 mm ⁇ width 100 mm) to obtain a laminate sheet.
  • the second protective film was peeled off, and the height of burrs was measured at the outer peripheral edge of the first protective film. The results are shown in Table 1.
  • Example 5 to 6 An acrylic pressure-sensitive adhesive layer was laminated on the retardation film provided in the circularly polarizing plate, and a third resin film was further laminated.
  • the first protective film was laminated on the circularly polarizing plate via the adhesive layer provided in the first protective film.
  • the pressure-sensitive adhesive layer included in the first protective film was laminated on the TAC film side of the circularly polarizing plate.
  • the second protective film was laminated on the first protective film via the adhesive layer provided in the second protective film. In this way, a laminate in which the second protective film, the first protective film, the circularly polarizing plate, the third pressure-sensitive adhesive layer, and the third resin film were laminated in this order was produced.
  • the first protective film was peelable from the circularly polarizing plate, and the second protective film was peelable from the first protective film.
  • the laminated body was cut into a predetermined shape (length 20 mm ⁇ width 100 mm) to obtain a laminated sheet.
  • the second protective film was peeled off, and the height of burrs was measured at the outer peripheral edge of the first protective film. The results are shown in Table 2.
  • the front plate and the circularly polarizing plate were laminated with each other via an acrylic pressure-sensitive adhesive layer.
  • the thickness of this acrylic pressure-sensitive adhesive layer was 25 ⁇ m.
  • the front plate was laminated on the TAC film side of the circularly polarizing plate.
  • An acrylic pressure-sensitive adhesive layer was laminated on the retardation film provided in the circularly polarizing plate, and a third resin film was further laminated.
  • the first protective film was laminated on the front plate via the adhesive layer provided in the first protective film. In this way, a laminate in which the first protective film, the front plate, the circularly polarizing plate, the third pressure-sensitive adhesive layer, and the third resin film were laminated in this order was produced.
  • the first protective film could be peeled off from the front plate.
  • the laminate was cut into a predetermined shape (length 20 mm ⁇ width 100 mm) to obtain a laminate sheet.
  • the height of burrs was measured at the outer peripheral edge of the first protective film. The results are shown in Table 1.
  • the laminated body was cut into a predetermined shape (length 20 mm ⁇ width 100 mm) to obtain a laminated sheet.
  • the height of burrs was measured at the outer peripheral edge of the first protective film. The results are shown in Table 2.
  • 1 time of laser light irradiation means that the laminated body was cut by full cut, and 10 times of laser light irradiation means that all layers extending in the stacking direction were completely cut by the 10th irradiation. It means that you did.
  • "from the visible side” means, for example, irradiating the laser in the direction from the second protective film 200 toward the polarizing layer 2 in FIG. 3, and "from the non-visual side” means, for example, the polarizing layer in FIG. It means irradiating the laser in the direction from 2 toward the second protective film 200.
  • the height of burrs on the outer peripheral edge of the first protective film is 6.0 ⁇ m or less, and the adsorption force is unlikely to decrease when the laminated sheet is attached to the display panel.

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Mathematical Physics (AREA)
  • Plasma & Fusion (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Polarising Elements (AREA)
  • Liquid Crystal (AREA)
  • Laminated Bodies (AREA)

Abstract

L'objet de la présente invention est de fournir une feuille stratifiée dont la force d'aspiration est difficilement altérée lorsque la feuille stratifiée est collée à un panneau d'affichage. Un premier film protecteur, une plaque de surface avant et une couche de polarisation sont stratifiés dans cet ordre, le premier film protecteur a une première couche adhésive sur une surface d'un premier film de résine, le premier film protecteur est stratifié sur la plaque de surface avant, la première couche adhésive disposée entre eux, le film protecteur peut être détaché de la plaque de surface avant et les hauteurs de bavures dans la section de bord périphérique externe du premier film protecteur ne dépassent pas 6,0 µm.
PCT/JP2021/005161 2020-03-10 2021-02-12 Feuille stratifiée et son procédé de fabrication Ceased WO2021182005A1 (fr)

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