WO2020116167A1 - Solar thermal power generation system - Google Patents
Solar thermal power generation system Download PDFInfo
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- WO2020116167A1 WO2020116167A1 PCT/JP2019/045446 JP2019045446W WO2020116167A1 WO 2020116167 A1 WO2020116167 A1 WO 2020116167A1 JP 2019045446 W JP2019045446 W JP 2019045446W WO 2020116167 A1 WO2020116167 A1 WO 2020116167A1
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- Prior art keywords
- heat
- storage device
- heat storage
- solar
- reactant
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K3/00—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
- F01K3/02—Use of accumulators and specific engine types; Control thereof
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F03—MACHINES OR ENGINES FOR LIQUIDS; WIND, SPRING, OR WEIGHT MOTORS; PRODUCING MECHANICAL POWER OR A REACTIVE PROPULSIVE THRUST, NOT OTHERWISE PROVIDED FOR
- F03G—SPRING, WEIGHT, INERTIA OR LIKE MOTORS; MECHANICAL-POWER PRODUCING DEVICES OR MECHANISMS, NOT OTHERWISE PROVIDED FOR OR USING ENERGY SOURCES NOT OTHERWISE PROVIDED FOR
- F03G6/00—Devices for producing mechanical power from solar energy
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S60/00—Arrangements for storing heat collected by solar heat collectors
- F24S60/20—Arrangements for storing heat collected by solar heat collectors using chemical reactions, e.g. thermochemical reactions or isomerisation reactions
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S90/00—Solar heat systems not otherwise provided for
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
- Y02E10/46—Conversion of thermal power into mechanical power, e.g. Rankine, Stirling or solar thermal engines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E70/00—Other energy conversion or management systems reducing GHG emissions
- Y02E70/30—Systems combining energy storage with energy generation of non-fossil origin
Definitions
- the present invention relates to a solar thermal power generation system.
- a solar thermal power generation system that uses the heat energy emitted from the sun to generate electricity.
- a solar thermal power generation system collects solar heat to heat water (water or steam) directly or indirectly through a heat medium to heat superheated steam or saturated steam (hereinafter collectively referred to as “collection of these” in a daytime with a lot of sunlight. "Heated steam”) is generated, the steam turbine is rotated by the steam, and power is generated by a generator connected to the steam turbine. Then, at night without sunlight, a part of the solar heat is stored in the heat storage device in the daytime, and heating steam is generated by heat radiation from the heat storage device to generate power in the same manner as described above. Many.
- a heat storage device capable of storing heat in the daytime and radiating heat at night to heat water directly or indirectly via a heat medium.
- oil or molten salt is used as the heat medium to exchange heat between the heat medium and water to generate heated steam
- the heat medium itself can be stored and used as a heat storage device.
- a pressure accumulator such as an accumulator may be used as a heat storage device for storing heated steam.
- a system using the DSG method using water as a heat medium is considered to be advantageous, and is excellent. It is desired to develop a heat storage device.
- Patent Document 1 As a solar thermal power generation system, for example, the one described in Patent Document 1 is considered, but there is a problem to be improved in this system.
- the technique of Patent Document 1 adopts the DSG method, and includes three types of heat storage tanks corresponding to water states, that is, superheated steam, saturated steam, and saturated water states, as a heat storage device. Is.
- the provision of the three types of heat storage devices complicates the piping configuration and the like, and increases the heat loss due to the long transport path of the heat medium, and further increases the equipment cost.
- the present invention has been made in view of such a background, and it is an object of the present invention to provide a simple solar thermal power generation system that adopts the DSG method and has a small heat loss in a path necessary for a heat storage device.
- a solar heat collector that directly heats a heat medium made of water by the collected solar heat to generate heated steam
- a heat storage device that performs heat exchange with the heat medium to store heat and radiate heat
- a steam turbine driven by heated steam
- a generator for generating power by the power of the steam turbine
- a condenser for condensing steam discharged from the steam turbine
- a water tank that stores the reconstituted water
- a water supply pump for pumping water from the water tank, A daytime operation mode of performing heat storage to the heat storage device and operation of the steam turbine by the heating steam supplied from the solar heat collector.
- the heat storage device contains a chemical heat storage material capable of storing heat and releasing heat by a chemical reaction, and is further connected to a reactant storage device, and a reaction material used in association with the chemical reaction of the chemical heat storage material,
- a solar thermal power generation system is configured to be able to supply from the reactant storage device to the heat storage device.
- the night operation mode is not limited to the night operation mode, and includes a case where the sunshine such as cloudy day is insufficient in the daytime.
- a chemical heat storage material is incorporated.
- the chemical heat storage material has a characteristic of receiving a heat transfer from a heat medium to cause a chemical reaction of releasing a reactant and storing the heat, and causing a chemical reaction of incorporating the reactant to radiate heat. Then, by utilizing the reversible reaction, it is possible to repeatedly store and radiate heat, and the heat storage energy density is high, so that stable radiative use for a long time is possible.
- the reactant stored in the reactant reservoir is used as the reactant released or introduced along with the reaction of the chemical heat storage material.
- FIG. 6 is an explanatory diagram showing a configuration of a solar thermal power generation system according to a second embodiment. Explanatory drawing which shows the structure of the solar thermal power generation system in Example 3.
- FIG. 6 is an explanatory diagram showing a configuration of a solar thermal power generation system according to a second embodiment. Explanatory drawing which shows the structure of the solar thermal power generation system in Example 3.
- various types of trough type, Fresnel type, tower type and the like can be adopted as the solar heat collector.
- the generator, the condenser, the water supply pump, the piping configuration and other components various known components can be adopted.
- the heat storage device as mentioned above, a device that incorporates a chemical heat storage material that stores and dissipates heat by a chemical reaction is adopted.
- this type of chemical heat storage material include oxides of alkaline earth metals such as calcium oxide (CaO), magnesium oxide (MgO), and barium oxide (BaO).
- the chemical heat storage material radiates heat in accordance with a hydration reaction that takes in water (H 2 O) or a carbonation reaction that takes in carbon dioxide (CO 2 ), and receives heat transfer from a heat medium to release water. Heat is stored by the reaction or the decarboxylation reaction that releases carbon dioxide, and is regenerated into an oxide. Then, the reversible reaction can be used to repeatedly store and radiate heat, and the heat storage energy density is high, so that stable radiative use for a long time is possible.
- a hydration reaction that takes in water (H 2 O) or a carbonation reaction that takes in carbon dioxide (CO 2 )
- Heat is stored by the reaction or the decarboxylation reaction that releases carbon dioxide, and is regenerated into an oxide. Then, the reversible reaction can be used to repeatedly store and radiate heat, and the heat storage energy density is high, so that stable radiative use for a long time is possible.
- the reactive substance used in association with the chemical reaction of the chemical heat storage material incorporated in the heat storage device in the solar thermal power generation system is either water or carbon dioxide.
- the reactant storage device is configured to be able to supply, to the heat storage device, the reactant used in association with the chemical reaction of the chemical heat storage material contained in the heat storage device.
- the reactant may be transferred between the reactant reservoir and the heat storage device. That is, not only can the reactant be supplied from the reactant storage device to the heat storage device, but the reactant released from the heat storage device can also be recovered and stored in the reaction device storage device.
- the solar thermal power generation system includes a plurality of the solar heat collectors, a plurality of the heat storage device, and a plurality of the reactant storage device, in the daytime operation mode, the heat medium, At least, after sequentially passing through the first solar heat collector, the first heat storage device, the second solar heat collector, the second heat storage device, and the third solar heat collector, the The heat medium is supplied to the steam turbine, and in the night operation mode, the flow paths of the heat medium are branched and supplied to the first and second heat storage devices respectively, and after being heated, they are merged and supplied to the steam turbine.
- the reactant may be supplied from the first and second reactant storage devices to the first and second heat storage devices, respectively.
- each solar heat collector can be miniaturized and reduced in capacity. Therefore, the equipment cost can be reduced and the energy efficiency in heat storage can be improved as compared with the case where the large-sized solar heat collector is provided.
- the number of the solar heat collector and the number of the heat storage device do not have to be the same, and the number and arrangement of specific devices may be appropriately adjusted, such as combining those having different capacities in series or in parallel. Good. The same applies hereinafter.
- the solar thermal power generation system includes a plurality of the solar heat collectors, and in the daytime operation mode, the flow path of the heat medium that has passed through the first solar heat collector is branched to form a daytime mainstream. And the daytime stream are formed, the heat medium of the daytime main stream is supplied to the steam turbine, and the heat medium of the daytime stream sequentially passes through the second solar heat collecting device and the heat storage device, and then again the second heat collecting device. Continuing the repeated circulation of sequentially passing through the solar heat collector and the heat storage device, in the night operation mode, the heat medium is supplied to the heat storage device, heated, and then supplied to the steam turbine.
- the reactant may be supplied from the reactant reservoir to the heat storage device.
- a circulation path is formed as a heat medium flow path, and the solar heat collector and the heat storage device are arranged in the circulation path.
- the solar thermal power generation system 101 heat-exchanges the solar heat collector 2 that directly heats a heat medium composed of water with the collected solar heat to generate heating steam, and the heat medium.
- the heat storage device 4 for performing heat storage and heat dissipation, a steam turbine 31 driven by heated steam, a generator 32 for generating power by the power of the steam turbine 31, and steam discharged from the steam turbine 31 to condensate water.
- the heat storage device 4 has a built-in chemical heat storage material capable of storing and releasing heat by a chemical reaction, and is further connected to a reactant storage device 6 to be used in association with the chemical reaction of the chemical heat storage material. Can be supplied from the reactant storage device 6 to the heat storage device 4. Further details will be given below.
- the solar thermal power generation system 101 has a configuration including the solar heat collector 2, the heat storage device 4, and the reactant storage device 6. Then, the pipe 7 for circulating the heat medium has a plurality of open/close valves 801, 802 so as to connect the solar heat collector 2, the heat storage device 4, the steam turbine 31, the condenser 51, the water tank 52, and the water supply pump 53. It is arranged while intervening.
- the heat storage device 4 of the present embodiment incorporates CaO/Ca(OH) 2 , CaO/CaCO 3 , MgO/Mg(OH) 2 , MgO/MgCO 3, etc. as the chemical heat storage material.
- CaO and Ca(OH) 2 , CaO and CaCO 3 , MgO and Mg(OH) 2 , and MgO and MgCO 3 have reversibly changeable characteristics. Specifically, CaO and Ca(OH) 2 cause the dehydration reaction of Equation 1 when heat is stored and the hydration reaction of Equation 2 when heat is released.
- CaO and CaCO 3 cause a reaction of releasing carbon dioxide of Formula 3 during heat storage, and CaO 3 reacts with carbon dioxide as in Formula 4 during heat release to cause a reaction of becoming CaCO 3 .
- MgO and Mg(OH) 2 and MgO and MgCO 3 .
- Formula 1 Ca(OH) 2 + heat ⁇ CaO + water (water or steam)
- Formula 2 CaO + water (water or water vapor) ⁇ Ca(OH) 2 + heat
- Formula 3 CaCO 3 + heat ⁇ CaO + CO 2 (carbon dioxide)
- Formula 4 CaO+CO 2 (carbon dioxide) ⁇ CaCO 3 + heat
- the heat storage device 4 includes a heat medium passage 43 in which a heat medium for exchanging heat with the chemical heat storage material is circulated, and a reaction material passage for releasing and introducing a reactant during a chemical reaction in the chemical heat storage material. 44, and the reactant flow path 44 is connected to the reactant storage device 6.
- the reactant storage device 6 of this embodiment supplies water or carbon dioxide to the heat storage device 4 as the above-mentioned reactant.
- the reaction substance is water (hereinafter, referred to as reaction water)
- the heat storage device 4 radiates heat
- the reaction water is accumulated from the reaction substance reservoir 6 by a pump or the like via the reaction substance flow path 44. It can be supplied to the device 4.
- the reaction water generated by the dehydration reaction of the chemical heat storage material contained in the heat storage device 4 is transferred from the heat storage device 4 to the reactant storage device 6 via the reactant flow path 44 by a pump or the like. Can be sent. That is, the reaction water can be transferred between the reactant storage device 6 and the heat storage device 4.
- the reactant when the reactant is carbon dioxide, when the heat storage device 4 radiates heat, the high-pressure tank filled with carbon dioxide serves as the reactant reservoir 6 and the valve of the high-pressure tank is opened. Carbon dioxide can be supplied to the heat storage device 4 via the flow path 44.
- carbon dioxide generated from the chemical heat storage material contained in the heat storage device 4 can be sent from the heat storage device 4 to the reactant storage device 6 via the reactant flow path 44 by a pump or the like. .. That is, carbon dioxide can be transferred between the reactant storage device 6 and the heat storage device 4.
- the flow path of the heat medium in the daytime operation mode in the solar thermal power generation system 101 is, as shown in FIG. 1, first, the heat medium in the water tank 52 is pressure-fed by the water supply pump 53, and the solar heat collector 2 is moved along the direction of arrow A. Sent to. In the solar heat collector 2, the heat medium at 30° C. is heated by the collected solar heat to become heated steam at 600° C., and is sent to the heat medium passage 43 of the heat storage device 4 along the direction of arrow A. .. In the heat storage device 4, heat of 100° C. is stored from the heat medium of 600° C. Then, the heated steam having a temperature of 500° C.
- the heated steam (heat medium) discharged from the steam turbine 31 is condensed by the condenser 51 and returned to the water tank 52 for storage.
- the heat storage device 4 stores 100° C. of heat.
- the chemical heat storage material contained in the heat storage device 4 causes a chemical reaction such as Equation 1 or Equation 3 illustrated above, and releases the reactant.
- This reactant may flow and be stored through the reactant channel 44 along the direction of arrow a1 toward the reactant reservoir 6.
- the flow path of the pipe 7 connected to the solar heat collector 2 is stopped by closing the opening/closing valve 801.
- the opening/closing valve 802 of the pipe 7 connected to the heat storage device 4 from the water supply pump 53 in the direction of the arrow B is opened.
- the heat medium in the water tank 52 is pressure-fed by the water supply pump 53 and heads for the heat storage device 4 along the direction of arrow B.
- the heat medium of 30° C. directed to the heat storage device 4 is supplied to the heat medium flow path 43 of the heat storage device 4, heated to 500° C. by heat exchange with the chemical heat storage material, and then supplied to the steam turbine 31 and the generator. Power is generated by 32.
- the heated steam (heat medium) discharged from the steam turbine 31 is condensed by the condenser 51 and returned to the water tank 52 for storage.
- the reactant is supplied from the reactant storage device 6 along the direction of the arrow a2 to the heat storage device 4 through the reactant flow path 44, and is used for the chemical reaction accompanying the heat dissipation of the chemical heat storage material.
- the heat medium is heated as described above by the heat generated by the chemical reaction between the reactant and the chemical heat storage material.
- the opening/closing valves in the pipe 7 through which the heat medium passes are opened, and the other opening/closing valves are closed.
- the reactant storage device 6 can be installed at a desired position, the path required for the heat storage device 4 is shortened and the structure can be further simplified. Further, along with this, it is possible to reduce the heat loss on the route and the energy required for transporting the reactant.
- the reactant stored in the reactant storage device 6 can be used as the reactant released or introduced along with the reaction of the chemical heat storage material.
- the reactant used for the chemical heat storage material is not limited to water, and carbon dioxide can also be used, so that the range of choices for the chemical heat storage material and the reaction material is expanded. Therefore, it is possible to generate power according to the location where the solar thermal power generation system 101 is installed, the usage conditions, and the like.
- the temperature required for heat storage and the temperature to be radiated differ depending on the difference between the chemical heat storage material and the reactant, power generation using a heat medium adjusted to a suitable temperature becomes possible.
- the reactant storage device 6 can supply the reactant to the heat storage device 4 and does not interfere with the heat medium path of the solar thermal power generation system 101, so that the control becomes easy. Furthermore, since the reactant used in the heat storage device 4 is not limited to water, the amount of water used can be reduced.
- the solar thermal power generation system 102 of the present embodiment is an example in which a solar heat collector, a heat storage device, and a reactant storage device are added based on the configuration of the first embodiment. That is, as shown in FIG. 2, a first heat storage device 41 is provided on the downstream side of the first solar heat collecting device 21, a second solar heat collecting device 22 is provided on the downstream side thereof, and a second solar heat collecting device 22 is provided on the downstream side thereof. The heat storage device 42 is provided, and the third solar heat collector 23 is further provided on the downstream side.
- each of the heat storage devices 41 and 42 it is connected to the reactant storage devices 61 and 62 via the reactant flow paths 414 and 424, and the reactant used for the chemical reaction of the chemical heat storage material can be supplied.
- the heat medium in the water tank 52 is pressure-fed by the water supply pump 53 and is fed to the first solar heat collector 21 in the direction of arrow A.
- the heat medium of 30° C. is heated by the collected solar heat into heated steam of 600° C., and then the heat medium of the first heat storage device 41 along the direction of arrow A. It is sent to the flow path 413.
- heat of 100° C. is stored from the heat medium of 600° C. and becomes heated steam of 500° C.
- the heated steam that has reached 500° C. is sent to the second solar heat collector 22 on the downstream side along the direction of arrow A, is heated to 600° C. again, and then the second heat storage on the downstream side. It is sent to the heat medium flow path 423 of the device 42, and heat of 100° C. is accumulated from the heat medium of 600° C., and the heat medium becomes 500° C. Then, along the direction of the arrow A, is sent to the third solar heat collector 23 further downstream and heated to 600° C. again, and then sent from the third solar heat collector 23 to the steam turbine 31, Power is generated in the same manner as described above.
- the heated steam (heat medium) discharged from the steam turbine 31 is condensed by the condenser 51 and returned to the water tank 52 for storage.
- heat of 100° C. is stored in each of the first and second heat storage devices 41 and 42.
- the reactant released from the first and second heat storage devices 41, 42 passes through the respective reactant passages 414, 424 along the direction of the arrow a1 to reach the reactant reservoirs 61, 62. It may be sent and stored.
- the flow path of the pipe 7 connected to the first to third solar heat collectors 21, 22, 23 is stopped by closing the opening/closing valves 801, 803, 804. .
- the on-off valves 805, 807 of the pipe 7 connected to the steam turbine 31 along the direction are opened.
- the heat medium in the water tank 52 is pressure-fed by the water supply pump 53, and goes toward the first and second heat storage devices 41 and 42 along the flow path indicated by the arrow B.
- the heat medium supplied to the heat medium flow paths 413 and 423 of the heat storage devices 41 and 42 is heated to 500° C. by heat exchange with the chemical heat storage material.
- each heat storage device 41, 42 merges along the direction of arrow B through the bypass 7 (b) without being sent to the solar heat collectors 22, 23, and the steam turbine 31 And is generated by the generator 32.
- the heated steam (heat medium) discharged from the steam turbine 31 is condensed by the condenser 51 and returned to the water tank 52 for storage.
- the reactants are supplied from the reactant reservoirs 61, 62 to the heat storage devices 41, 42 along the direction of arrow a2.
- the heat medium is heated as described above by the heat generated by the chemical reaction between the reactant and the chemical heat storage material.
- each heat storage device can be downsized and its capacity can be reduced, the facility cost can be reduced as compared with the case where the large heat storage device is provided.
- each solar heat collector can be miniaturized and reduced in capacity. Therefore, the equipment cost can be reduced and the energy efficiency in heat storage can be improved as compared with the case where the large-sized solar heat collector is provided.
- the solar thermal power generation system 103 of the present example enables repeated circulation flow in which the solar heat collector and the heat storage device are sequentially passed and then the solar heat collector and the heat storage device are sequentially passed again. That is, as shown in FIG. 3, the downstream side of the heat storage device 4 and the upstream side of the solar heat collector 22 are connected by the circulation path 7(c).
- the heat medium in the water tank 52 is pressure-fed by the water supply pump 53 and is fed to the first solar heat collector 21 along the direction of arrow A.
- the heat medium at 30° C. is heated to 500° C. by the collected solar heat and becomes heated steam.
- the flow path of the heat medium that has passed through the first solar heat collector 21 is branched to form a daytime main stream along the direction of arrow A1 and a daytime branch stream along the direction of arrow A2. Is supplied to the steam turbine 31 along the direction of arrow A1, and power generation is performed in the same manner as described above.
- the heated steam (heat medium) discharged from the steam turbine 31 is condensed by the condenser 51 and returned to the water tank 52 for storage.
- the heat medium of the daytime flow first passes through the second solar heat collector 22 along the direction of arrow A2 to be heated to 600° C., and then passes through the heat medium passage 43 of the heat storage device 4.
- the heat of 100° C. is accumulated to 500° C., and then the circulation path 7(c) is advanced along the direction of the arrow A2, and the repetitive circulation of sequentially passing through the second solar heat collecting device 22 and the heat storing device 4 again is performed. to continue.
- the reactant released from the chemical heat storage material in the heat storage device 4 during heat storage may be sent to the reactant storage device 6 and stored therein through the reactant flow path 44 along the direction of arrow a1.
- the flow path of the connected pipe 7 and the flow path of the circulation path 7(c) are stopped by closing the opening/closing valves 801, 808, 809.
- the on-off valve 802 of the pipe 7 connected to the heat storage device 4 from the water supply pump 53 along the direction of the arrow B and the on-off valve 810 of the pipe 7 connected to the steam turbine 31 from the heat storage device 4 along the direction of the arrow B are opened.
- the heat medium at 30° C. in the water tank 52 is pressure-fed by the water supply pump 53, is supplied to the heat medium passage 43 of the heat storage device 4 along the direction of the arrow B, and is 500° C. by heat exchange with the chemical heat storage material. After being heated to 1, it is supplied to the steam turbine 31 and is generated by the generator 32. The heated steam (heat medium) discharged from the steam turbine 31 is condensed by the condenser 51 and returned to the water tank 52 for storage.
- the reactant is sent from the reactant reservoir 6 through the reactant channel 44 in the direction of arrow a2 to the heat storage device 4 and supplied to the chemical heat storage material.
- the heat medium is heated as described above by the heat generated by the chemical reaction between the reactant and the chemical heat storage material.
- the solar heat collector 22 in the daytime operation mode, after repeatedly passing through the solar heat collector 22 and the heat storage device 4, it is possible to repeatedly circulate through the solar heat collector 22 and the heat storage device 4 again.
- the second solar heat collector 22 even if the capacity of the solar heat collector 22 in the circulation path is not high, the second solar heat collector 22 only needs to collect heat on the high-temperature heat medium that has passed through the heat storage device 4, and further the heat storage device.
- the solar heat collector 22 can be downsized and its capacity can be reduced, and the facility cost can be reduced, because the solar heat collector 22 can collect heat by the amount of heat stored by one heat exchange.
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Abstract
Description
本発明は、太陽熱発電システムに関する。 The present invention relates to a solar thermal power generation system.
自然エネルギーを利用した発電システムの一つとして、太陽から発せられる熱エネルギーを利用して発電を行う太陽熱発電システムがある。太陽熱発電システムは、日照量の多い昼間においては、太陽熱を集熱して直接又は熱媒体を介して間接的に水(水又は蒸気)を加熱して過熱蒸気または飽和蒸気(以下、これらを総称して、「加熱蒸気」という。)を生成し、当該蒸気により蒸気タービンを回し、蒸気タービンに接続された発電機により発電を行うよう構成されている。そして、日照のない夜間においては、昼間に太陽熱の一部を蓄熱装置に蓄熱しておき、当該蓄熱装置からの放熱により加熱蒸気を生成して前記と同様に発電を行うよう構成されることが多い。 As one of the power generation systems that use natural energy, there is a solar thermal power generation system that uses the heat energy emitted from the sun to generate electricity. A solar thermal power generation system collects solar heat to heat water (water or steam) directly or indirectly through a heat medium to heat superheated steam or saturated steam (hereinafter collectively referred to as “collection of these” in a daytime with a lot of sunlight. "Heated steam") is generated, the steam turbine is rotated by the steam, and power is generated by a generator connected to the steam turbine. Then, at night without sunlight, a part of the solar heat is stored in the heat storage device in the daytime, and heating steam is generated by heat radiation from the heat storage device to generate power in the same manner as described above. Many.
太陽熱発電システムを有効活用するには、夜間発電をこれまで以上に効率よく行う必要がある。夜間発電を行うには、昼間に蓄熱し、夜間に放熱して直接又は熱媒体を介して間接的に水を加熱できる蓄熱装置の利用が不可欠である。熱媒体として油や溶融塩等を用いて熱媒体と水との熱交換を行って加熱蒸気を生成する方式では、熱媒体そのものを貯蔵して蓄熱装置とすることができる。一方、熱媒体として水を用いるDSG(Direct Steam Generation)方式を利用したシステムでは、加熱蒸気を貯蔵する蓄熱装置としてアキュームレータなどの蓄圧器が利用される場合がある。それらは長時間貯蔵・利用には不向きであるにも関わらず、巨大な装置が必要になる。 To make effective use of the solar thermal power generation system, it is necessary to generate power at night more efficiently than ever before. In order to perform night-time power generation, it is essential to use a heat storage device capable of storing heat in the daytime and radiating heat at night to heat water directly or indirectly via a heat medium. In the system in which oil or molten salt is used as the heat medium to exchange heat between the heat medium and water to generate heated steam, the heat medium itself can be stored and used as a heat storage device. On the other hand, in a system using the DSG (Direct Steam Generation) method using water as a heat medium, a pressure accumulator such as an accumulator may be used as a heat storage device for storing heated steam. Although they are not suitable for long-term storage and use, they require huge equipment.
一方で、設備コスト、伝授した太陽熱からの発電効率、環境面及びシステム構成のシンプル化等の観点では、熱媒体として水を用いるDSG方式を利用したシステムが有利であると考えられており、優れた蓄熱装置の開発が望まれている。 On the other hand, from the viewpoint of equipment cost, power generation efficiency from transmitted solar heat, environmental aspects, and simplification of system configuration, a system using the DSG method using water as a heat medium is considered to be advantageous, and is excellent. It is desired to develop a heat storage device.
太陽熱発電システムとしては、例えば、特許文献1に記載のものが考えられているが、このシステムにおいては改善すべき課題がある。特許文献1の技術は、DSG方式を採用したものであって、蓄熱装置として、水の状態、つまり、過熱蒸気、飽和蒸気、及び飽和水の状態にそれぞれ対応する3種類の蓄熱タンクを備えるものである。しかし、3種類もの蓄熱装置を備えることは、配管構成等が複雑になると共に、熱媒体の輸送経路が長くなることで熱損失が増加し、さらに設備コストも高くなる。 As a solar thermal power generation system, for example, the one described in Patent Document 1 is considered, but there is a problem to be improved in this system. The technique of Patent Document 1 adopts the DSG method, and includes three types of heat storage tanks corresponding to water states, that is, superheated steam, saturated steam, and saturated water states, as a heat storage device. Is. However, the provision of the three types of heat storage devices complicates the piping configuration and the like, and increases the heat loss due to the long transport path of the heat medium, and further increases the equipment cost.
上記のように、太陽熱発電システムとしてDSG方式を採用した技術は従来より種々提案されているものの、蓄熱装置を設置するには配管を複雑に構成せざるを得ない場合が多く、その結果、熱損失の増大を招いている。 As described above, although various technologies that use the DSG method as a solar thermal power generation system have been proposed in the past, in many cases, piping must be configured in a complicated manner to install a heat storage device. This leads to an increase in loss.
本発明は、かかる背景に鑑みてなされたものであり、DSG方式を採用し、蓄熱装置に必要な経路での熱損失が少なく、かつシンプルな太陽熱発電システムを提供しようとするものである。 The present invention has been made in view of such a background, and it is an object of the present invention to provide a simple solar thermal power generation system that adopts the DSG method and has a small heat loss in a path necessary for a heat storage device.
本発明の一態様は、集熱した太陽熱により水からなる熱媒体を直接加熱して加熱蒸気を生成する太陽熱集熱装置と、
前記熱媒体との熱交換を行って蓄熱及び放熱を行う蓄熱装置と、
加熱蒸気により駆動する蒸気タービンと、
該蒸気タービンの動力により発電を行う発電機と、
前記蒸気タービンから排出される蒸気を復水する復水器と、
復水された水を貯留する水タンクと、
該水タンクから水を圧送する給水ポンプと、を有し、
前記太陽熱集熱装置から供給された加熱蒸気により前記蓄熱装置への蓄熱と前記蒸気タービンの運転とを行う昼運転モードと、
前記蓄熱装置の放熱を受けて加熱された加熱蒸気により前記蒸気タービンの運転を行う夜運転モードと、を切り替え可能に構成されており、
前記蓄熱装置は、化学反応により蓄熱及び放熱が可能な化学蓄熱材を内蔵し、さらに反応物質貯蔵器に連結されており、前記化学蓄熱材の前記化学反応に伴って利用される反応物質を、前記反応物質貯蔵器から前記蓄熱装置へ供給可能に構成されている、太陽熱発電システムにある。
なお、上記夜運転モードとは夜間に限らず、昼間で曇天等の日照が不十分な場合も含む。
One aspect of the present invention, a solar heat collector that directly heats a heat medium made of water by the collected solar heat to generate heated steam,
A heat storage device that performs heat exchange with the heat medium to store heat and radiate heat,
A steam turbine driven by heated steam,
A generator for generating power by the power of the steam turbine,
A condenser for condensing steam discharged from the steam turbine;
A water tank that stores the reconstituted water,
A water supply pump for pumping water from the water tank,
A daytime operation mode of performing heat storage to the heat storage device and operation of the steam turbine by the heating steam supplied from the solar heat collector.
It is configured to be able to switch between the night operation mode in which the steam turbine is operated by the heated steam that is heated by receiving the heat radiation of the heat storage device,
The heat storage device contains a chemical heat storage material capable of storing heat and releasing heat by a chemical reaction, and is further connected to a reactant storage device, and a reaction material used in association with the chemical reaction of the chemical heat storage material, A solar thermal power generation system is configured to be able to supply from the reactant storage device to the heat storage device.
The night operation mode is not limited to the night operation mode, and includes a case where the sunshine such as cloudy day is insufficient in the daytime.
前記太陽熱発電システムにおいては、上記のごとく、熱媒体として水(水、蒸気、水と蒸気の混合状態を含む。以下、同様。)を用いるDSG方式を採用した上で、化学蓄熱材を内蔵した蓄熱装置を採用している。前記化学蓄熱材は、熱媒体からの伝熱を受けて反応物質を放出する化学反応を起こして蓄熱し、前記反応物質を取り込む化学反応を起こして放熱する特性を有している。そして、その可逆反応を利用して、繰り返し蓄熱・放熱が可能であるとともに、蓄熱エネルギー密度も高く、長時間の安定した放熱利用が可能である。 In the solar thermal power generation system, as described above, after adopting the DSG method using water (including water, steam, and a mixed state of water and steam. The same applies hereinafter) as a heat medium, a chemical heat storage material is incorporated. Uses a heat storage device. The chemical heat storage material has a characteristic of receiving a heat transfer from a heat medium to cause a chemical reaction of releasing a reactant and storing the heat, and causing a chemical reaction of incorporating the reactant to radiate heat. Then, by utilizing the reversible reaction, it is possible to repeatedly store and radiate heat, and the heat storage energy density is high, so that stable radiative use for a long time is possible.
ここで、前記太陽熱発電システムにおいては、前記化学蓄熱材の反応に伴って放出又は導入する前記反応物質として、前記反応物質貯蔵器に貯蔵された前記反応物質を利用するよう構成されている。この構成を積極的に採用することによって、前記蓄熱装置に必要な経路をシンプルかつ短縮化でき、熱効率の向上を図ることができる。 Here, in the solar thermal power generation system, the reactant stored in the reactant reservoir is used as the reactant released or introduced along with the reaction of the chemical heat storage material. By positively adopting this configuration, the path required for the heat storage device can be simplified and shortened, and the thermal efficiency can be improved.
以上のごとく、上記態様によれば、DSG方式を採用し、蓄熱装置に必要な経路での熱損失が少なく、かつシンプルな太陽熱発電システムを提供することができる。 As described above, according to the above aspect, it is possible to provide a simple solar thermal power generation system that adopts the DSG method and has a small heat loss in the path required for the heat storage device.
前記太陽熱発電システムにおいて、前記太陽熱集熱装置としては、トラフ型、フレネル型、タワー型等の種々の形式を採用することができる。その他、蒸気タービン、発電機、復水器、給水ポンプ、配管構成その他の構成物についても、公知の種々のものを採用することができる。 In the solar thermal power generation system, various types of trough type, Fresnel type, tower type and the like can be adopted as the solar heat collector. In addition, as the steam turbine, the generator, the condenser, the water supply pump, the piping configuration and other components, various known components can be adopted.
また、前記蓄熱装置としては、上記のごとく、化学反応により蓄熱及び放熱を行う化学蓄熱材を内蔵したものを採用する。この種の化学蓄熱材としては、例えば、酸化カルシウム(CaO)や、酸化マグネシウム(MgO)、酸化バリウム(BaO)などのアルカリ土類金属の酸化物が挙げられる。 Also, as the heat storage device, as mentioned above, a device that incorporates a chemical heat storage material that stores and dissipates heat by a chemical reaction is adopted. Examples of this type of chemical heat storage material include oxides of alkaline earth metals such as calcium oxide (CaO), magnesium oxide (MgO), and barium oxide (BaO).
前記化学蓄熱材は、水(H2O)を取り込む水和反応、又は二酸化炭素(CO2)を取り込む炭酸化反応に伴って放熱し、熱媒体からの伝熱を受けて水を放出する脱水反応、又は二酸化炭素を放出する脱炭酸反応によって蓄熱し、酸化物へと再生される。そして、その可逆反応を利用して繰り返し蓄熱・放熱が可能であるとともに、蓄熱エネルギー密度も高く、長時間の安定した放熱利用が可能である。 The chemical heat storage material radiates heat in accordance with a hydration reaction that takes in water (H 2 O) or a carbonation reaction that takes in carbon dioxide (CO 2 ), and receives heat transfer from a heat medium to release water. Heat is stored by the reaction or the decarboxylation reaction that releases carbon dioxide, and is regenerated into an oxide. Then, the reversible reaction can be used to repeatedly store and radiate heat, and the heat storage energy density is high, so that stable radiative use for a long time is possible.
前記太陽熱発電システムにおける前記蓄熱装置に内蔵される前記化学蓄熱材の化学反応に伴って利用される反応物質は、水、又は二酸化炭素のうち、いずれか一種である。 The reactive substance used in association with the chemical reaction of the chemical heat storage material incorporated in the heat storage device in the solar thermal power generation system is either water or carbon dioxide.
また、前記反応物質貯蔵器は、前記蓄熱装置に内蔵された前記化学蓄熱材の化学反応に伴って利用される前記反応物質を、前記蓄熱装置へ供給可能となるよう構成されている。このとき、前記反応物質を、前記反応物質貯蔵器と前記蓄熱装置とで授受できるようにしてもよい。すなわち、前記反応物質を前記反応物質貯蔵器から前記蓄熱装置へ供給するだけでなく、前記蓄熱装置から放出される前記反応物質を前記反応物質貯蔵器に回収して貯蔵することが可能である。 Further, the reactant storage device is configured to be able to supply, to the heat storage device, the reactant used in association with the chemical reaction of the chemical heat storage material contained in the heat storage device. At this time, the reactant may be transferred between the reactant reservoir and the heat storage device. That is, not only can the reactant be supplied from the reactant storage device to the heat storage device, but the reactant released from the heat storage device can also be recovered and stored in the reaction device storage device.
また、前記太陽熱発電システムは、複数の前記太陽熱集熱装置と、複数の前記蓄熱装置と、複数の前記反応物質貯蔵器と、を備えており、前記昼運転モードにおいては、前記熱媒体が、少なくとも、第1の前記太陽熱集熱装置、第1の前記蓄熱装置、第2の前記太陽熱集熱装置、第2の前記蓄熱装置、及び第3の前記太陽熱集熱装置を順次通過した後、前記蒸気タービンに供給され、前記夜運転モードにおいては、前記熱媒体の流路が分岐して第1及び第2の前記蓄熱装置にそれぞれ供給され、加熱された後、合流して前記蒸気タービンに供給されると共に、第1及び第2の前記反応物質貯蔵器からそれぞれ第1及び第2の前記蓄熱装置へ前記反応物質が供給されるように構成されていてもよい。 Further, the solar thermal power generation system includes a plurality of the solar heat collectors, a plurality of the heat storage device, and a plurality of the reactant storage device, in the daytime operation mode, the heat medium, At least, after sequentially passing through the first solar heat collector, the first heat storage device, the second solar heat collector, the second heat storage device, and the third solar heat collector, the The heat medium is supplied to the steam turbine, and in the night operation mode, the flow paths of the heat medium are branched and supplied to the first and second heat storage devices respectively, and after being heated, they are merged and supplied to the steam turbine. In addition, the reactant may be supplied from the first and second reactant storage devices to the first and second heat storage devices, respectively.
この場合には、複数の太陽熱集熱装置と複数の蓄熱装置とを組み合わせることにより、個々の蓄熱装置の能力が高くなくても、蓄熱量を増やすことが可能となる。また、蓄熱装置の小型化及び低能力化を図ることができるため、大型の蓄熱装置を備える場合よりも、設備コストを低減させることができる。また、昼夜の発電量のバランスを最適化することが可能となり、昼夜を通じてタービン規模に合わせた蒸気供給が可能となるため、エネルギー効率を向上させることができる。 In this case, by combining a plurality of solar heat collectors and a plurality of heat storage devices, it is possible to increase the amount of heat storage even if the capacity of each heat storage device is not high. Further, since the heat storage device can be downsized and the capacity thereof can be reduced, the facility cost can be reduced as compared with the case where the large heat storage device is provided. In addition, it is possible to optimize the balance of the amount of power generation during the day and night, and it is possible to supply steam in accordance with the turbine scale throughout the day and night, thus improving energy efficiency.
また、個々の太陽熱集熱装置の能力が高くなくても、蓄熱装置が1回の熱交換によって蓄熱する熱量分だけ集熱すればよいため、太陽熱集熱装置を小型化及び低能力化することができ、大型の太陽熱集熱装置を備える場合よりも、設備コストの低減を図ることができるとともに、蓄熱におけるエネルギー効率を向上させることができる。 Further, even if the capacity of each solar heat collector is not high, it is sufficient to collect heat by the amount of heat stored by the heat storage device by one heat exchange, so that the solar heat collector can be miniaturized and reduced in capacity. Therefore, the equipment cost can be reduced and the energy efficiency in heat storage can be improved as compared with the case where the large-sized solar heat collector is provided.
なお、前記太陽熱集熱装置と前記蓄熱装置の数は同じである必要はなく、また、さらに能力の異なるものを直列又は並列に組み合わせるなど、具体的な装置の個数や配列は適宜調整してもよい。以下、同様である。 The number of the solar heat collector and the number of the heat storage device do not have to be the same, and the number and arrangement of specific devices may be appropriately adjusted, such as combining those having different capacities in series or in parallel. Good. The same applies hereinafter.
また、前記太陽熱発電システムは、複数の前記太陽熱集熱装置を備えており、前記昼運転モードにおいては、第1の前記太陽熱集熱装置を通過した前記熱媒体の流路が分岐して昼本流と昼分流とを形成し、昼本流の前記熱媒体が前記蒸気タービンに供給され、昼分流の前記熱媒体が第2の前記太陽熱集熱装置と前記蓄熱装置を順次通過した後、再び第2の前記太陽熱集熱装置及び前記蓄熱装置を順次通過する繰り返し循環を続け、前記夜運転モードにおいては、前記熱媒体が前記蓄熱装置に供給され、加熱された後、前記蒸気タービンに供給されると共に、前記反応物質貯蔵器から前記蓄熱装置へ前記反応物質が供給されるように構成されていてもよい。 Moreover, the solar thermal power generation system includes a plurality of the solar heat collectors, and in the daytime operation mode, the flow path of the heat medium that has passed through the first solar heat collector is branched to form a daytime mainstream. And the daytime stream are formed, the heat medium of the daytime main stream is supplied to the steam turbine, and the heat medium of the daytime stream sequentially passes through the second solar heat collecting device and the heat storage device, and then again the second heat collecting device. Continuing the repeated circulation of sequentially passing through the solar heat collector and the heat storage device, in the night operation mode, the heat medium is supplied to the heat storage device, heated, and then supplied to the steam turbine. The reactant may be supplied from the reactant reservoir to the heat storage device.
この場合には、熱媒体の流路として循環経路を形成し、その循環経路内に太陽熱集熱装置と蓄熱装置とを配置することとなる。この構成を採用することによって、昼夜の発電量のバランスを最適化することが可能となり、昼夜を通じてタービン規模に合わせた蒸気供給ができるため、エネルギー効率が向上するという効果を得ることができる。また、循環経路内の太陽熱集熱装置の能力が高くなくても、蓄熱装置が1回の熱交換によって蓄熱する熱量分だけ集熱すればよいため、その太陽熱集熱装置を小型化及び低能力化することができ、設備コストの低減を図ることができる。 In this case, a circulation path is formed as a heat medium flow path, and the solar heat collector and the heat storage device are arranged in the circulation path. By adopting this configuration, it is possible to optimize the balance of the amount of power generation during the day and night, and it is possible to supply steam in accordance with the scale of the turbine throughout the day and night, so that the effect of improving energy efficiency can be obtained. Further, even if the capacity of the solar heat collector in the circulation path is not high, it is sufficient to collect heat by the amount of heat stored by the heat storage device by one heat exchange, so that the solar heat collector can be downsized and have low capability. It is possible to reduce the equipment cost.
(実施例1)
本願の太陽熱発電システム101に係る実施例につき、図1を用いて説明する。
本実施例の太陽熱発電システム101は、図1に示すごとく、集熱した太陽熱により水からなる熱媒体を直接加熱して加熱蒸気を生成する太陽熱集熱装置2と、前記熱媒体との熱交換を行って蓄熱及び放熱を行う蓄熱装置4と、加熱蒸気により駆動する蒸気タービン31と、該蒸気タービン31の動力により発電を行う発電機32と、前記蒸気タービン31から排出される蒸気を復水する復水器51と、復水された水を貯留する水タンク52と、該水タンク52から水を圧送する給水ポンプ53と、を有する。そして、前記太陽熱集熱装置2から供給された加熱蒸気により前記蓄熱装置4への蓄熱と前記蒸気タービン31の運転とを行う昼運転モードと、前記蓄熱装置4の放熱を受けて加熱された加熱蒸気により前記蒸気タービン31の運転を行う夜運転モードと、を切り替え可能に構成されている。前記蓄熱装置4は、化学反応により蓄熱及び放熱が可能な化学蓄熱材を内蔵し、さらに反応物質貯蔵器6に連結されており、前記化学蓄熱材の前記化学反応に伴って利用される反応物質を、前記反応物質貯蔵器6から前記蓄熱装置4へ供給可能に構成されている。
以下、さらに詳説する。
(Example 1)
An example according to the solar thermal
As shown in FIG. 1, the solar thermal
Further details will be given below.
本実施例の太陽熱発電システム101は、上述したごとく、太陽熱集熱装置2、蓄熱装置4、及び反応物質貯蔵器6を備えた構成のものである。そして、太陽熱集熱装置2と、蓄熱装置4、蒸気タービン31、復水器51、水タンク52、給水ポンプ53をつなぐように、熱媒体を流通させる配管7が複数の開閉弁801、802を介在しながら配設されている。
As described above, the solar thermal
本実施例の蓄熱装置4は、化学蓄熱材としてCaO/Ca(OH)2、CaO/CaCO3、MgO/Mg(OH)2、MgO/MgCO3等を内蔵する。CaOとCa(OH)2、CaOとCaCO3、MgOとMg(OH)2、MgOとMgCO3は、それぞれ可逆的に変化可能な特性を有している。具体的には、CaOとCa(OH)2は、蓄熱時には式1の脱水反応を起こし、放熱時には式2の水和反応を起こす。また、CaOとCaCO3は、蓄熱時には式3の二酸化炭素を放出する反応を起こし、放熱時には式4のようにCaOと二酸化炭素とが反応し、CaCO3となる反応を起こす。また、MgOとMg(OH)2、MgOとMgCO3も同様である。
式1:Ca(OH)2+熱 → CaO+水(水又は水蒸気)
式2:CaO+水(水又は水蒸気) → Ca(OH)2+熱
式3:CaCO3+熱 → CaO+CO2(二酸化炭素)
式4:CaO+CO2(二酸化炭素) → CaCO3+熱
The
Formula 1: Ca(OH) 2 + heat → CaO + water (water or steam)
Formula 2: CaO + water (water or water vapor) → Ca(OH) 2 + heat Formula 3: CaCO 3 + heat → CaO + CO 2 (carbon dioxide)
Formula 4: CaO+CO 2 (carbon dioxide) → CaCO 3 + heat
そして、この蓄熱装置4は、化学蓄熱材との熱交換を行う熱媒体を内部において流通させる熱媒体流路43と、化学蓄熱材における化学反応時の反応物質を放出及び導入する反応物質流路44とを備えており、反応物質流路44は、反応物質貯蔵器6に連結されている。
The
本実施例の反応物質貯蔵器6は、上述した反応物質として、水又は二酸化炭素を蓄熱装置4へ供給する。例えば、反応物質を水(以下、反応水という。)とした場合、蓄熱装置4の放熱時においては、反応水を、反応物質貯蔵器6からポンプ等によって、反応物質流路44を介して蓄熱装置4へ供給できる。一方、蓄熱時においては、蓄熱装置4に内蔵された化学蓄熱材の脱水反応によって生成された反応水は、蓄熱装置4からポンプ等によって、反応物質流路44を介して反応物質貯蔵器6へ送ることができる。つまり、反応物質貯蔵器6と蓄熱装置4との間で反応水を授受可能とする。
The
また、例えば、反応物質を二酸化炭素とした場合、蓄熱装置4の放熱時においては、二酸化炭素が充填された高圧タンクを反応物質貯蔵器6として、高圧タンクのバルブを開放することで、反応物質流路44を介して蓄熱装置4へ二酸化炭素を供給できる。一方、蓄熱時においては、蓄熱装置4に内蔵された化学蓄熱材から発生した二酸化炭素は、蓄熱装置4からポンプ等によって、反応物質流路44を介して反応物質貯蔵器6へ送ることができる。つまり、反応物質貯蔵器6と蓄熱装置4との間で二酸化炭素を授受可能とする。
Further, for example, when the reactant is carbon dioxide, when the
本実施例の構成における熱媒体の流路の詳細については、太陽熱発電システム101の昼運転モードと夜運転モードにわけて、以下に説明する。また、本実施例1及び以降の他の実施例において、図を用いてシステムの構成を示し、以下の説明文においては、わかりやすくするために、熱媒体の温度も記載するが、これは例示であって、実際には、各機器の能力の設定等によって変更されうることは言うまでもない。
The details of the flow path of the heat medium in the configuration of this embodiment will be described below by dividing into the daytime operation mode and the nighttime operation mode of the solar thermal
太陽熱発電システム101における昼運転モードの熱媒体の流路は、図1に示すごとく、まず、水タンク52内の熱媒体が給水ポンプ53により圧送され矢印Aの方向に沿って太陽熱集熱装置2に送られる。太陽熱集熱装置2においては、集熱した太陽熱により、30℃の熱媒体が加熱され、600℃の加熱蒸気となり、矢印Aの方向に沿って、蓄熱装置4の熱媒体流路43に送られる。蓄熱装置4においては、600℃の熱媒体から100℃分の熱が蓄熱される。そして、500℃となった加熱蒸気が蓄熱装置4の熱媒体流路43から蒸気タービン31に送られ、蒸気タービン31が駆動することでその動力により発電機32が発電を行う。蒸気タービン31から排出された加熱蒸気(熱媒体)は、復水器51により復水されて水タンク52に戻されて貯留される。
The flow path of the heat medium in the daytime operation mode in the solar thermal
ここで、昼運転モードにおいては、上述したごとく、蓄熱装置4においては、100℃分の熱が蓄熱される。このとき、蓄熱装置4が内蔵する化学蓄熱材は上記で例示した式1や式3などの化学反応を起こし、反応物質を放出することとなる。この反応物質は、矢印a1の方向に沿って反応物質流路44を通って反応物質貯蔵器6に向かって流れ、貯蔵されてもよい。
Here, in the daytime operation mode, as described above, the
次に、太陽熱発電システム101の夜運転モードにおいては、太陽熱集熱装置2につながる配管7の流路は開閉弁801の閉鎖によって止められる。一方、給水ポンプ53から矢印Bの方向に沿って蓄熱装置4につながる配管7の開閉弁802は開放される。そして、水タンク52の熱媒体が給水ポンプ53により圧送され、矢印Bの方向に沿って蓄熱装置4に向かう。蓄熱装置4に向かった30℃の熱媒体は、蓄熱装置4の熱媒体流路43に供給され、化学蓄熱材との熱交換によって500℃に加熱された後、蒸気タービン31に供給され発電機32による発電がなされる。蒸気タービン31から排出された加熱蒸気(熱媒体)は復水器51により復水され、水タンク52に戻されて貯留される。
Next, in the night operation mode of the solar thermal
また、反応物質が反応物質貯蔵器6から矢印a2の方向に沿って、反応物質流路44を通って蓄熱装置4に供給され、化学蓄熱材の放熱に伴う化学反応に利用される。蓄熱装置4においては、この反応物質と化学蓄熱材との化学反応で生じた熱によって上記のごとく熱媒体が加熱される。
Further, the reactant is supplied from the
以上のような昼運転モード及び夜運転モードにおいて、熱媒体が通過した配管7における開閉弁は開となり、それ以外の開閉弁は閉となる。
In the daytime operation mode and nighttime operation mode as described above, the opening/closing valves in the
本実施例の太陽熱発電システム101は、所望の位置に反応物質貯蔵器6を設置できるため、蓄熱装置4に必要な経路が短くなり、さらにシンプルな構成とすることができる。また、それに伴って、経路上での熱損失や、反応物質の輸送に必要なエネルギーの低減を図ることができる。
In the solar thermal
また、本実施例の太陽熱発電システム101においては、化学蓄熱材の反応に伴って放出又は導入する反応物質として、反応物質貯蔵器6に貯蔵された反応物質を利用可能に構成されている。つまり、太陽熱発電システム101の熱媒体の経路とは独立した反応物質の輸送経路を有する。この構成を積極的に採用することによって、化学蓄熱材に利用される反応物質が水に限定されず、二酸化炭素も利用できるため、化学蓄熱材及び反応物質の選択可能な幅が広がる。そのため、前記太陽熱発電システム101が設けられる立地や利用条件等に合わせた発電が可能となる。また、前記化学蓄熱材と前記反応物質の違いによって蓄熱に必要な温度及び放熱される温度が異なるため、好適な温度に調整された熱媒体を利用した発電が可能となる。
Further, in the solar thermal
また、反応物質貯蔵器6は、蓄熱装置4に反応物質を供給可能としている他は、前記太陽熱発電システム101の熱媒体経路等と干渉しないため、制御が容易となる。さらに、前記蓄熱装置4に利用される反応物質は水に限定されないため、水の使用量の低減にもつながる。
In addition, the
(実施例2)
本実施例の太陽熱発電システム102は、実施例1の構成を基本として、太陽熱集熱装置、蓄熱装置及び反応物質貯蔵器を増やした例である。すなわち、図2に示すごとく、第1の太陽熱集熱装置21の下流側に第1の蓄熱装置41を設け、その下流側に第2の太陽熱集熱装置22を設け、その下流側に第2の蓄熱装置42を設け、さらに、その下流側に第3の太陽熱集熱装置23を設ける。また、それぞれの蓄熱装置41、42においては、反応物質流路414、424を介して反応物質貯蔵器61、62とつながっており、化学蓄熱材の化学反応に利用される反応物質が供給可能となっている。なお、説明の都合上、実施例1と同様の機能を有する構成要素については、実施例1と同じ符号を用いて説明する。以下、実施例3も同様とする。
(Example 2)
The solar thermal
本例における昼運転モードにおいては、水タンク52内の熱媒体が給水ポンプ53により圧送され、矢印Aの方向に沿って、第1の太陽熱集熱装置21に送られる。第1の太陽熱集熱装置21においては、集熱した太陽熱により、30℃の熱媒体が600℃の加熱蒸気に加熱され、次に矢印Aの方向に沿って第1の蓄熱装置41の熱媒体流路413に送られる。第1の蓄熱装置41においては、600℃の熱媒体から100℃分の熱が蓄熱され、500℃の加熱蒸気となる。
In the daytime operation mode in this example, the heat medium in the
次に、500℃となった加熱蒸気は、矢印Aの方向に沿ってその下流の第2の太陽熱集熱装置22に送られ、再度600℃まで加熱された後、その下流の第2の蓄熱装置42の熱媒体流路423に送られて、600℃の熱媒体から100℃分の熱が蓄熱され、熱媒体は500℃となる。そして、矢印Aの方向に沿って、さらに下流の第3の太陽熱集熱装置23に送られ、再度600℃まで加熱された後、第3の太陽熱集熱装置23から蒸気タービン31に送られ、前記と同様に発電が行われる。蒸気タービン31から排出された加熱蒸気(熱媒体)は、復水器51により復水されて水タンク52に戻されて貯留される。
Next, the heated steam that has reached 500° C. is sent to the second
また、昼運転モードにおいては、第1及び第2の蓄熱装置41、42において、それぞれ100℃分の熱が蓄熱される。このとき、第1及び第2の蓄熱装置41、42から放出される反応物質は、矢印a1の方向に沿ってそれぞれの反応物質流路414、424を通って反応物質貯蔵器61、62へと送られ、貯蔵されてもよい。
Also, in the daytime operation mode, heat of 100° C. is stored in each of the first and second
次に、太陽熱発電システム102の夜運転モードにおいては、第1~第3の太陽熱集熱装置21、22、23につながる配管7の流路は、開閉弁801、803、804の閉鎖によって止められる。一方、給水ポンプ53から矢印Bの方向に沿って第1及び第2の蓄熱装置41、42につながる配管7の開閉弁802、806、第1及び第2の蓄熱装置41、42から矢印Bの方向に沿って蒸気タービン31につながる配管7の開閉弁805、807は開放される。
Next, in the night operation mode of the solar thermal
そして、水タンク52内の熱媒体が給水ポンプ53により圧送され、矢印Bの流路に沿って、第1及び第2の蓄熱装置41、42に向かう。それぞれの蓄熱装置41、42の熱媒体流路413、423に供給された熱媒体は、化学蓄熱材との熱交換によって500℃に加熱される。
Then, the heat medium in the
それぞれの蓄熱装置41、42において加熱された熱媒体は、矢印Bの方向に沿って、太陽熱集熱装置22、23に送られることなくバイパス路7(b)を通って合流し、蒸気タービン31に供給され発電機32による発電がなされる。蒸気タービン31から排出された加熱蒸気(熱媒体)は、復水器51により復水されて水タンク52に戻されて貯留される。
The heat medium heated in each
また、反応物質が反応物質貯蔵器61、62から矢印a2の方向に沿って、蓄熱装置41、42に供給される。蓄熱装置41、42においては、この反応物質と化学蓄熱材との化学反応で生じた熱によって前記のごとく熱媒体が加熱される。
Further, the reactants are supplied from the
本実施例の場合は、複数の太陽熱集熱装置21、22、23を備え、かつ、これらの間に蓄熱装置41、42をさらに備えることにより、実施例1に示した作用効果に加え、昼夜の発電量のバランスを最適化できる。また、昼夜を通じてタービン規模に合わせた蒸気供給が可能となるため、エネルギー効率が向上するという効果を得ることができる。
In the case of the present embodiment, by providing a plurality of
また、個々の蓄熱装置の能力が高くなくても、複数あることで蓄熱量を増やすことが可能となる。また、蓄熱装置の小型化及び低能力化を図ることができるため、大型の蓄熱装置を備える場合よりも設備コストを低減させることができる。 Also, even if the capacity of each heat storage device is not high, it is possible to increase the amount of heat storage by having multiple heat storage devices. Further, since the heat storage device can be downsized and its capacity can be reduced, the facility cost can be reduced as compared with the case where the large heat storage device is provided.
また、個々の太陽熱集熱装置の能力が高くなくても、蓄熱装置が1回の熱交換によって蓄熱する熱量分だけ集熱すればよいため、太陽熱集熱装置を小型化及び低能力化することができ、大型の太陽熱集熱装置を備える場合よりも、設備コストの低減を図ることができるとともに、蓄熱におけるエネルギー効率を向上させることができる。 Further, even if the capacity of each solar heat collector is not high, it is sufficient to collect heat by the amount of heat stored by the heat storage device by one heat exchange, so that the solar heat collector can be miniaturized and reduced in capacity. Therefore, the equipment cost can be reduced and the energy efficiency in heat storage can be improved as compared with the case where the large-sized solar heat collector is provided.
(実施例3)
本例の太陽熱発電システム103は、昼運転モードにおいて、太陽熱集熱装置と蓄熱装置を順次通過した後、再び太陽熱集熱装置及び蓄熱装置を順次通過する繰り返し循環流動を可能としたものである。すなわち、図3に示すごとく、蓄熱装置4の下流側と太陽熱集熱装置22の上流側とが循環路7(c)により連結されている。
(Example 3)
In the daytime operation mode, the solar thermal
本例における昼運転モードにおいては、水タンク52内の熱媒体が給水ポンプ53により圧送され、矢印Aの方向に沿って第1の太陽熱集熱装置21に送られる。第1の太陽熱集熱装置21においては、集熱した太陽熱により、30℃の熱媒体が500℃まで加熱され、加熱蒸気となる。
In the daytime operation mode in this example, the heat medium in the
第1の太陽熱集熱装置21を通過した熱媒体の流路は分岐して、矢印A1の方向に沿った昼本流と矢印A2の方向に沿った昼分流とを形成し、昼本流の熱媒体が矢印A1の方向に沿って蒸気タービン31に供給され、前記と同様に発電が行われる。蒸気タービン31から排出された加熱蒸気(熱媒体)は、復水器51により復水されて水タンク52に戻されて貯留される。
The flow path of the heat medium that has passed through the first
また、昼分流の熱媒体は矢印A2の方向に沿ってまず第2の太陽熱集熱装置22を通過して600℃まで加熱され、次に、蓄熱装置4の熱媒体流路43を通過して100℃分の蓄熱がなされて500℃となり、その後、矢印A2の方向に沿って循環路7(c)を進み、再び第2の太陽熱集熱装置22及び蓄熱装置4を順次通過する繰り返し循環を続ける。
The heat medium of the daytime flow first passes through the second
また、蓄熱時の蓄熱装置4における化学蓄熱材から放出された反応物質は、矢印a1の方向に沿って反応物質流路44を通り、反応物質貯蔵器6へと送られ貯蔵されてもよい。
The reactant released from the chemical heat storage material in the
次に、本実施例の夜運転モードにおいては、第1の太陽熱集熱装置21につながる配管7の流路、第1の太陽熱集熱装置21から矢印A1の方向に沿って蒸気タービン31へとつながる配管7の流路、循環路7(c)の流路は、開閉弁801、808、809の閉鎖によって止められる。一方、給水ポンプ53から矢印Bの方向に沿って蓄熱装置4につながる配管7の開閉弁802、蓄熱装置4から矢印Bの方向に沿って蒸気タービン31につながる配管7の開閉弁810は開放される。
Next, in the night operation mode of the present embodiment, the flow path of the
そして、水タンク52内の30℃の熱媒体が給水ポンプ53により圧送され、矢印Bの方向に沿って蓄熱装置4の熱媒体流路43に供給され、化学蓄熱材との熱交換によって500℃に加熱された後、蒸気タービン31に供給され発電機32による発電がなされる。蒸気タービン31から排出された加熱蒸気(熱媒体)は、復水器51により復水されて水タンク52に戻されて貯留される。
Then, the heat medium at 30° C. in the
また、反応物質は、反応物質貯蔵器6から矢印a2の方向に沿って反応物質流路44を通って蓄熱装置4に送られ、化学蓄熱材に供給される。蓄熱装置4においては、この反応物質と化学蓄熱材による化学反応で生じた熱によって前記のごとく熱媒体が加熱される。
Further, the reactant is sent from the
本実施例の場合には、昼運転モードにおいて、太陽熱集熱装置22と蓄熱装置4を順次通過した後、再び太陽熱集熱装置22及び蓄熱装置4を順次通過する繰り返し循環流動を可能としたことにより、実施例1に示した作用効果に加え、昼夜の発電量のバランスを最適化することが可能となり、昼夜を通じてタービン規模に合わせた蒸気供給ができるため、エネルギー効率が向上するという効果を得ることができる。また、循環経路内の太陽熱集熱装置22の能力が高くなくても、第2の太陽熱集熱装置22は蓄熱装置4通過後の高温の熱媒体に対して集熱すればよく、さらに蓄熱装置4が1回の熱交換によって蓄熱する熱量分だけ集熱すればよいため、その太陽熱集熱装置22を小型化及び低能力化することができ、設備コストの低減を図ることができる。
In the case of the present embodiment, in the daytime operation mode, after repeatedly passing through the
以上のごとく、本実施例によれば、DSG方式を採用し、蓄熱装置に必要な経路での熱損失が少なく、かつシンプルな太陽熱発電システムを提供することができる。 As described above, according to the present embodiment, it is possible to provide a simple solar thermal power generation system that adopts the DSG method and has a small heat loss in the path required for the heat storage device.
Claims (3)
前記熱媒体との熱交換を行って蓄熱及び放熱を行う蓄熱装置と、
加熱蒸気により駆動する蒸気タービンと、
該蒸気タービンの動力により発電を行う発電機と、
前記蒸気タービンから排出される蒸気を復水する復水器と、
復水された水を貯留する水タンクと、
該水タンクから水を圧送する給水ポンプと、を有し、
前記太陽熱集熱装置から供給された加熱蒸気により前記蓄熱装置への蓄熱と前記蒸気タービンの運転とを行う昼運転モードと、
前記蓄熱装置の放熱を受けて加熱された加熱蒸気により前記蒸気タービンの運転を行う夜運転モードと、を切り替え可能に構成されており、
前記蓄熱装置は、化学反応により蓄熱及び放熱が可能な化学蓄熱材を内蔵し、さらに反応物質貯蔵器に連結されており、前記化学蓄熱材の前記化学反応に伴って利用される反応物質を、前記反応物質貯蔵器から前記蓄熱装置へ供給可能に構成されている、太陽熱発電システム。 A solar heat collector that directly heats a heat medium consisting of water by the collected solar heat to generate heated steam,
A heat storage device that performs heat exchange with the heat medium to store heat and radiate heat,
A steam turbine driven by heated steam,
A generator for generating power by the power of the steam turbine,
A condenser for condensing steam discharged from the steam turbine;
A water tank that stores the reconstituted water,
A water supply pump for pumping water from the water tank,
A daytime operation mode of performing heat storage to the heat storage device and operation of the steam turbine by the heating steam supplied from the solar heat collector.
It is configured to be able to switch between the night operation mode in which the steam turbine is operated by the heated steam that is heated by receiving the heat radiation of the heat storage device,
The heat storage device has a built-in chemical heat storage material capable of heat storage and heat dissipation by a chemical reaction, and is further connected to a reactant storage device, and a reaction material used in association with the chemical reaction of the chemical heat storage material, A solar thermal power generation system configured to be able to supply from the reactant storage device to the heat storage device.
前記昼運転モードにおいては、前記熱媒体が、少なくとも、第1の前記太陽熱集熱装置、第1の前記蓄熱装置、第2の前記太陽熱集熱装置、第2の前記蓄熱装置、及び第3の前記太陽熱集熱装置を順次通過した後、前記蒸気タービンに供給され、
前記夜運転モードにおいては、前記熱媒体の流路が分岐して第1及び第2の前記蓄熱装置にそれぞれ供給され、加熱された後、合流して前記蒸気タービンに供給されると共に、第1及び第2の前記反応物質貯蔵器からそれぞれ第1及び第2の前記蓄熱装置へ前記反応物質が供給されるように構成されている、請求項1に記載の太陽熱発電システム。 The solar thermal power generation system includes a plurality of the solar heat collectors, a plurality of the heat storage device, a plurality of the reactant storage device,
In the daytime operation mode, the heat medium includes at least a first solar heat collector, a first heat storage device, a second solar heat collector, a second heat storage device, and a third heat storage device. After sequentially passing through the solar heat collector, is supplied to the steam turbine,
In the night operation mode, the flow path of the heat medium is branched and supplied to the first and second heat storage devices, respectively, and after being heated, they are merged and supplied to the steam turbine, and The solar thermal power generation system according to claim 1, wherein the reactant is supplied from the second and second reactant storage devices to the first and second heat storage devices, respectively.
前記昼運転モードにおいては、第1の前記太陽熱集熱装置を通過した前記熱媒体の流路が分岐して昼本流と昼分流とを形成し、昼本流の前記熱媒体が前記蒸気タービンに供給され、昼分流の前記熱媒体が第2の前記太陽熱集熱装置と前記蓄熱装置を順次通過した後、再び第2の前記太陽熱集熱装置及び前記蓄熱装置を順次通過する繰り返し循環を続け、
前記夜運転モードにおいては、前記熱媒体が前記蓄熱装置に供給され、加熱された後、前記蒸気タービンに供給されると共に、前記反応物質貯蔵器から前記蓄熱装置へ前記反応物質が供給されるように構成されている、請求項1に記載の太陽熱発電システム。 The solar thermal power generation system includes a plurality of the solar heat collectors,
In the daytime operation mode, the flow path of the heat medium that has passed through the first solar heat collector is branched to form a daytime main stream and a daytime branch stream, and the heat medium of the daytime main stream is supplied to the steam turbine. The heat medium of the daytime stream sequentially passes through the second solar heat collector and the heat storage device, and then repeats repeated circulation through the second solar heat collector and the heat storage device.
In the night operation mode, the heat medium is supplied to the heat storage device, heated and then supplied to the steam turbine, and the reactant is supplied from the reactant storage device to the heat storage device. The solar thermal power generation system according to claim 1, which is configured to.
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