WO2020171486A1 - Method for manufacturing eco-friendly paper straw and eco-friendly paper straw manufactured thereby - Google Patents
Method for manufacturing eco-friendly paper straw and eco-friendly paper straw manufactured thereby Download PDFInfo
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- WO2020171486A1 WO2020171486A1 PCT/KR2020/002130 KR2020002130W WO2020171486A1 WO 2020171486 A1 WO2020171486 A1 WO 2020171486A1 KR 2020002130 W KR2020002130 W KR 2020002130W WO 2020171486 A1 WO2020171486 A1 WO 2020171486A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31D—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER, NOT PROVIDED FOR IN SUBCLASSES B31B OR B31C
- B31D5/00—Multiple-step processes for making three-dimensional articles ; Making three-dimensional articles
- B31D5/0095—Making drinking straws
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31C—MAKING WOUND ARTICLES, e.g. WOUND TUBES, OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31C5/00—Making tubes or pipes without using mandrels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
- B31D—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER, NOT PROVIDED FOR IN SUBCLASSES B31B OR B31C
- B31D5/00—Multiple-step processes for making three-dimensional articles ; Making three-dimensional articles
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Definitions
- the present invention relates to a method of manufacturing an eco-friendly paper straw and an eco-friendly paper straw manufactured thereby, and more specifically, to a method of manufacturing an eco-friendly paper straw that does not contain an adhesive, and an eco-friendly paper straw manufactured thereby.
- Plastics are cheap and durable, so they are often used as a material for straws that suck food and beverages.
- Plastic is known to be a recyclable raw material.
- it is often made difficult to recycle from the manufacturing stage, or is discarded as it is due to contamination or damage in the discharge or collection stage.
- a video of removing a plastic straw from a turtle's nose, or a plastic island of plastic garbage shows this reality clearly.
- the inventor of the present invention came to complete the present invention after long research and trial and error in order to solve these problems.
- An embodiment of the present invention provides a method for manufacturing an eco-friendly paper straw that does not contain an adhesive, and an eco-friendly paper straw manufactured thereby.
- An eco-friendly paper straw manufacturing method comprises the steps of: providing a coated paper coated with an acrylic-based water-dispersible coating agent for papermaking on at least one side of both sides of a substrate; Bending one end and the other end of the coated paper to overlap each other to form an overlap section; And sealing the overlap section.
- the coated paper includes a first coating layer disposed under the substrate and a second coating layer disposed on the substrate, and in the overlap section, the first coating layer of one end of the coated paper may be fused with the second coating layer of the other end of the coated paper. have.
- the paper straw extends in a first direction, and the coated paper has a length in the first direction and a width in a second direction orthogonal to the first direction, and the overlap section is 1/of the width of the coated paper. It may be formed over a range of 10 to 1/2.
- the sealing may be performed by a heat sealing method.
- the sealing may be performed by pressing the overlap section at a predetermined pressure and temperature for a preset time.
- an ultrasonic irradiator or an iron may be used.
- the coated paper may have a basis weight of 33 to 162 g/m 2 .
- a method of manufacturing an eco-friendly paper straw includes: providing two or more fabrics including at least one coated paper coated with an acrylic-based water-dispersible coating liquid for papermaking on at least one side of both sides of a substrate; Stacking the fabrics with each other and winding them in a paper tube method; And bonding the wound fabrics to each other in an overlapping section overlapping each other.
- the bonding may include heating the wound fabrics.
- the heating may use a hot air.
- the first fabric and the second fabric are overlapped and wound, and the first and second fabrics may be wound by overlapping each other so that the coated surface faces the outside of the joint.
- the coated paper may have a basis weight of 33 to 162 g/m 2 .
- the eco-friendly paper straw includes one or more coated papers coated with an acrylic-based water-dispersible coating liquid for papermaking on at least one surface of a substrate, wherein the one or more coated papers form the shape of the straw. It has an overlap section that is bonded to each other, and the overlap section may not include a separate adhesive.
- This technology can provide eco-friendly paper straws that can be manufactured without adhesives.
- the present technology can manufacture a paper straw without an adhesive, the straw manufacturing cost can be drastically reduced.
- FIG. 1 is a flowchart illustrating a method of manufacturing an eco-friendly paper straw according to an embodiment of the present invention over time.
- FIG. 2 is a diagram showing a cross-sectional view of a coated paper used in a method of manufacturing an eco-friendly paper straw according to an embodiment of the present invention.
- 3A is a view showing a cross-sectional view of a coated paper bent in a step according to an embodiment of the present invention.
- 3B is a view showing a cross-sectional view of a state in which sealing is performed on a section that is bent and overlapped in a step according to an embodiment of the present invention.
- FIG. 4 is a view showing a cross-sectional view taken along line AA′ and a paper straw manufactured according to an embodiment of the present invention.
- FIG. 5 is a flowchart illustrating a method of manufacturing an eco-friendly paper straw according to another embodiment of the present invention over time.
- FIG. 6 is a diagram schematically showing coated papers wound in a paper tube manner in a step according to another embodiment of the present invention.
- FIG. 7 is a view showing a cross-sectional view taken along line AA′ and a paper straw manufactured according to an embodiment of the present invention.
- FIG. 8 is a diagram schematically showing coated papers wound in a paper tube method according to another embodiment of the present invention.
- FIG. 9 is a view showing a cross-sectional view of a single-sided coated coated paper according to another embodiment of the present invention.
- FIG. 10 is a diagram schematically showing coated papers wound in a paper tube manner using three coated papers according to an embodiment of the present invention.
- FIG. 1 is a flowchart illustrating a method of manufacturing an eco-friendly paper straw according to an embodiment of the present invention over time.
- Figure 2 is a view showing a cross-sectional view of the coated paper used in the eco-friendly paper straw manufacturing method according to an embodiment of the present invention.
- the method of manufacturing an eco-friendly paper straw (hereinafter, referred to as a'paper straw manufacturing method' for convenience of explanation) is a step of providing a coated paper (S110), a step of bending so that an overlap section is formed. (S129) and sealing (S130).
- the coated paper 100 used in the paper straw manufacturing method includes a substrate 102 and coating layers 110 and 120 coated on both sides of the substrate.
- a coated paper 100 is provided.
- Coated paper may be referred to as coated paper.
- the coated paper 100 is formed by forming the coating layers 110 and 120 on the substrate 102. That is, the substrate is coated with a water-dispersible coating agent for papermaking.
- an uncoated substrate may be referred to as the base paper. Both the original and coated paper can be referred to as fabric.
- the substrate 102 is made of paper.
- the substrate may be coated paper, uncoated paper, or kraft paper.
- Uncoated paper is paper that has not been coated with chemicals or fine stone powder. Since a paper straw is a part that directly contacts a person's mouth and food, it is preferable to be made of raw materials that are harmless to the human body.
- the substrate 102 may have a basis weight of 30 to 150 g/m 2 . If it is less than 30 g/m 2 , the tension becomes too weak, which is disadvantageous for continuous processing. In the process of coating with an aqueous solution, if the speed is not very slow, the problem of breaking may occur. If it is larger than 150 g/m 2 , it may not be easily bent, and thus a contact area (ie, an overlap section) to be described later may be lifted. When bending, as the contact area becomes thicker, it becomes difficult to derive the smooth surface of the straw. Poor compatibility.
- the coating layers 110 and 120 are for improving moisture-proof properties and heat sealability.
- the coating layers 110 and 120 include an upper coating layer 110 disposed above and a lower coating layer 120 disposed below the substrate.
- the coating liquid for making the coating layers 110 and 120 is a water-dispersible coating agent for papermaking (hereinafter, also referred to as a'coating agent' for convenience of explanation).
- the coating agent is an acrylic-based water-dispersible coating agent.
- the acrylic-based water-dispersible coating agent may include a copolymer emulsion in which an acrylic polymer and a silicone polymer are copolymerized, and an aqueous polyvinyl alcohol colloid solution gelatinized therein.
- the acrylic polymer resin has heat sealability in some sections of the polymerization degree of the acrylic monomer. Therefore, when the substrate is coated with a coating agent that satisfies the degree of polymerization, the basis for adhering the coated paper without an adhesive is provided.
- the coating amount of the coating agent may be 3 to 12 g/m 2 based on solid content. In the case of a coating of less than 3 g/m 2 , there is a problem in that the moisture-proof performance is poor and the sealing is not performed well. In the case of coatings exceeding 12 g/m 2 , blocking problems arise.
- the coated paper 100 including the coating layer on the substrate may have a basis weight of 33 to 162 g/m 2 .
- the lower limit corresponds to a value obtained by adding the lower limit of the substrate and the lower limit of the coating agent for the same reason as described above
- the upper limit may correspond to a value obtained by adding the upper limit of the substrate and the upper limit of the coating agent for the same reason as described above.
- Acrylic monomers that can be used in the present invention are methyl acrylate, ethyl acrylate, 2-hydroxyethyl acrylate propyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, cyclohexyl acrylate, methyl methacrylate, ethyl In the group consisting of methacrylate, hydroxyethyl methacrylate, propyl methacrylate, n-butyl methacrylate, cyclohexyl methacrylate, isobutyl methacrylate, acrylonitrile, methacrylic acid and combinations thereof It may consist of one or more selected compounds.
- the acrylic monomer may be made of a combination of butyl acrylate, methyl methacrylate, hydroxyethyl methacrylate, and methacrylic acid.
- step S120 one end and the other end of the coated paper are bent so as to overlap each other to form an overlap section OS.
- step S120 may be referred to as a pre-work for bonding.
- step S130 a sealing process for the overlap section OS is performed.
- the sealing process may be performed by a heat sealing method.
- Steps S120 and S130 may be performed in one process. That is, sealing may be performed immediately after bending in a device that performs bending and sealing at the same time.
- sealing may be performed immediately after bending in a device that performs bending and sealing at the same time.
- an embodiment that is a process that is separate from each other will be described.
- steps S120 and S130 will be described in more detail with reference to FIG. 3.
- FIG. 3A is a diagram showing a cross-sectional view of a coated paper bent in a step S120 according to an embodiment of the present invention.
- FIG. 3B is a view showing a cross-sectional view of a state in which sealing is performed for a section that is bent and overlapped in step S130 according to an embodiment of the present invention.
- one end E1 and the other end E2 of the coated paper 100 overlap each other to form an overlap section OS. It may be bent once so that both ends overlap each other.
- the coated paper 100 may have a width in the x-axis direction in the xyz coordinate system and a length in the z-axis direction.
- a sufficiently long length for example, 5 to 25 cm
- the straw that mediates the user's mouth and food can perform its original function.
- it has a width of a predetermined length in the x-axis direction (for example, 1 to 2.5 cm), forming an overlapping section that overlaps each other when bending, and at the same time forming a hollow (H) inside the food. You can create this flowing passage.
- the coated paper has a thickness in the y-axis direction. The thickness may be, for example, 0.3 ⁇ 1.5mm.
- the overlap section OS may be formed over a range of approximately 1/10 to 1/2 with respect to the width of the coated paper 100. That is, when the coated paper is bent, the section where one end and the other end overlap to occupy 1/10 to 1/2 of the width of the coated paper.
- the overlap section may be formed with a width of 0.1 to 1.25 cm.
- the overlap section is formed smaller than 1/10, it is difficult to secure sufficient adhesive strength for sealing because the bonding area is narrow (that is, it may be released during manufacturing and use).
- the peel strength which represents the adhesive strength, is very low. As such, the contact area can be easily torn off. If it is formed larger than 1/2, it is not economical because loss of material is expected due to unnecessary increase in bonding area. Therefore, it is preferable that the overlap section has a range of 1/10 to 1/2 with respect to the width of the coated paper.
- the upper coating layer 110 of the other end portion (indicated by E1 in the drawing) overlapping upward is disposed to face the lower coating layer 120 of the one end portion (indicated by E2 in the drawing) overlapping downward.
- an overlap section is formed in a section where they face each other.
- step S130 as shown in FIG. 3B, the overlap section is sealed.
- the sealing site is referred to as SP in the figure.
- the sealing portion (SP) is shown as a thick solid line for convenience of explanation, but is not limited thereto, and actually corresponds to a shape in which the upper and lower coating layers of the overlap section are melted and adhered to each other (as if the coating layers are fused together. Like the way it was).
- the sealing process may be performed by a heat sealing method.
- step S130 may be performed in consideration of this. That is, according to an embodiment of the present invention, since the acrylic-based water-dispersible coating agent T m is in the range of 300 to 340 °C, step 130 may apply heat so that the overlap section has a temperature of 300 to 340 °C. .
- the process of applying heat can be performed using an ultrasonic irradiator or an iron.
- the overlapping section may be heat-sealed by introducing the coated paper passed through the step S120 into a sealing device (not shown) having an ultrasonic irradiator or an iron.
- a process of pressing the objects to be joined ie, one end and the other end of the coated paper disposed in the overlap section
- a process of pressing the objects to be joined ie, one end and the other end of the coated paper disposed in the overlap section
- the peel strength has a tendency to be proportional to the pressure applied to the bonding portion, a predetermined pressure can be applied to secure the peel strength required for the overlap section.
- the basis weight of the above-described coated paper is 33 ⁇ 162 g/m 2 , it is suitable for the bonding areas of the coated paper to remain in contact, and a pre-contact state that allows the bonding areas to be immediately bonded when heat is applied.
- Appropriate pressure can be applied to ensure that it remains stable. For example, a pressure of 0.2kg/cm2 or more may be applied.
- Pressurization may use a pressurizing device (press, etc.) that pressurizes from top to bottom and from bottom to top around the overlap section.
- the sealing device may include a pressing portion (not shown), and the pressing portion can be pressed in the vertical direction during the heat sealing process of the overlap section.
- the pressure applied to the overlap section can be maintained for a predetermined time or longer.
- the basis weight of the coated paper is 33 to 162 g/m 2
- the pressure is applied for an appropriate time to ensure sufficient peel strength for the joints of the coated paper and to reduce unnecessary process duration.
- control variables such as temperature, pressure, and time
- the pressure application time When the temperature is relatively high, the pressure application time may be shortened, and when the temperature is relatively low, the pressure application time may be lengthened.
- the pressure application time when the pressure application time is relatively long, the applied pressure may be lowered, and conversely, when the pressure application time is short, the applied pressure may increase.
- FIG. 4 shows a paper straw manufactured according to an embodiment of the present invention.
- a cross-sectional view taken along line AA′ is shown together.
- the paper straw ST1 manufactured by the above-described steps S110 to S130 is composed of a coating layer CL coated on both sides of the substrate P.
- the coating layer has an inner coating layer CLi and an outer coating layer CLo.
- the substrate P corresponds to the above-described substrate 102
- the coating layers CLi and CLo correspond to the above-described coating layers 110 and 120.
- the overlap section which is a part in which heat sealing is performed, is clearly shown thicker than other parts, but in fact, the coated paper itself has a very thin thickness compared to the full scale of the paper straw (for example, 0.3 ⁇ 1.5mm, see the description of Fig. 2), as shown in the cross-sectional view of Fig. 4, the paper straw can have a long cylindrical shape without a large thickness change in the overlap section.
- the coated paper is a double-sided coating
- the present invention is not limited thereto, and the same description as in FIGS. 1 to 4 may be applied even in the case of single-sided coating.
- bonding may be made between the upper coating layer of the other end overlapped above and the substrate of one end overlapped downward, and thus, the sealing region as described above is Can be defined.
- the moisture-proof properties of the straw it is more preferable to use double-sided coating.
- FIG. 5 is a flowchart illustrating a method of manufacturing an eco-friendly paper straw according to another embodiment of the present invention over time.
- FIG. 6 is a diagram schematically showing coated papers wound in a paper tube method in step S220 according to another embodiment of the present invention.
- a method of manufacturing an eco-friendly paper straw includes providing coated papers (S210), winding up (S220), and bonding ( S230).
- the provided two coated papers 200 and 300 overlap each other and are wound in a paper tube manner.
- the paper tube method means that several fabrics are stacked on top of each other and wound on a winding pipe in a spiral manner. At this time, the coated papers may be completely overlapped over the entire area, but are disposed so as to overlap each other and are wound.
- the overlapping section is indicated by reference numeral OS1, which is referred to as the first overlap section. If necessary, the first overlapping section may be wider than that shown in the drawings, but in the present invention, for convenience of explanation, it is assumed that only the areas shown in the drawings are overlapped.
- ID the direction injected into the winding pipe for winding.
- the first overlap section (OS1) may be formed over a range of approximately 1/5 to 4/5 of the width of the coated paper, considering the basis weight of the coated paper of 33 to 162 g/m 2 . have. That is, the section where the first coated paper and the second coated paper overlap may occupy 1/5 to 4/5 of the width of each coated paper. For example, when the width of the coated paper is 1 to 2.5 cm, the overlap section may be formed with a width of 0.2 to 2.0 cm. If the overlap section is formed smaller than 1/5, the overlap tolerance becomes too narrow, making the spiral winding operation difficult, and when it is formed larger than 4/5, it is difficult to control the formation of the thickness of the branch pipe.
- step 210 two or more coated papers 200 and 300 are provided.
- the coated paper 100 described above in FIGS. 1 to 4 may be used. That is, the coated papers 200 and 300 may have the same structure as the coated paper 100 described above. Accordingly, a more detailed description will be omitted.
- the first coated paper 200 includes a substrate 202 and coating layers 210 and 220 coated on the upper and lower portions of the substrate. It is referred to as the upper coating layer 210 and the lower coating layer 220, respectively.
- the second coated paper 300 includes a substrate 302 and coating layers 310 and 320 coated on the upper and lower portions of the substrate. It is referred to as an upper coating layer 310 and a lower coating layer 320, respectively.
- step S220 the coated papers 200 and 300 are overlapped with each other and wound in a paper tube method.
- the first coated paper 200 and the second coated paper 300 overlap each other and are wound.
- the first and second coated papers 200 and 300 are overlapped with each other so that the coated surface faces outward.
- the upper coating layer 210 of the first coated paper and the lower coating layer 320 of the second coated paper are overlapped and wound toward the outside (ie, the outer side of the bonding area). That is, the upper coating layer 210 of the first coated paper faces upward and the lower coating layer 320 of the second coated paper faces downward, so that it is overlapped and wound.
- the lower coating layer 220 of the first coated paper and the upper coating layer 310 of the second coated paper are arranged to face the inside (that is, the inner side of the bonding area).
- the coated papers 200 and 300 are wound in a spiral manner based on a winding pipe (not shown), and in the drawing, the second coated paper 300 is disposed closer to the winding pipe than the first coated paper 200. Accordingly, the second coated paper 300 forms the inner side of the straw, and the outer side of the first coated paper 200 is formed.
- the first coated paper 200 is disposed on the second coated paper 300. That is, the upper coating layer 310 of the second coated paper 300 is disposed to face the lower coating layer 220 of the first coated paper 200.
- the portions arranged to face each other may be defined by the above-described primary overlap section OS1.
- first coated paper and the second coated paper may be disposed opposite to each other.
- portions of the first coated paper 200 and the second coated paper 300 facing each other are added from the point of time after being wound on the winding pipe. That is, before winding, the facing portion is the first overlap section, and after winding, the facing portion is the second overlap section.
- the added overlap section is referred to as the second overlap section OS2 in the drawing.
- the second overlap section may be a section other than the first overlap section OS1 with respect to the width of the coated paper.
- the secondary overlap section may be flexible depending on the winding angle, but may have a secondary overlap section as shown in the drawing in consideration of the thickness of the branch pipe that increases during winding.
- the first coated paper 200 is disposed on the second coated paper 300 in the second overlapping section OS2 as well. That is, the upper coating layer 310 of the second coated paper 300 is disposed to face the lower coating layer 220 of the first coated paper 200.
- the first overlapping section OS1 and the second overlapping section OS2 described above provide a space in which the coated papers 200 and 300 can be bonded to each other. As described later, the coated papers are joined in the first overlap section and the second overlap section.
- coated papers wound in step S230 are bonded to each other in an overlapping section overlapping each other.
- a process of heating the wound coated papers 200 and 300 may be performed.
- a process of passing the wound coated papers through a heating device (not shown) equipped with a heating unit may be performed.
- the heating unit may be a hot air fan (such as a chamber). For example, it may be exposed to hot air while passing through the hot air of the heating device.
- the heating process in step S230 is not limited thereto, and various methods for applying heat to the overlap sections OS1 and OS2 may be applied.
- step S230 may be performed in consideration of this. That is, according to an embodiment of the present invention, since the acrylic-based water-dispersible coating agent T m is in the range of 300 to 340 °C, step 230 may apply heat so that the overlap sections have a temperature of 300 to 340 °C. .
- step S220 the coated papers are already wound on the winding pipe with a predetermined tension. Therefore, since the coated papers are in a state of being pressed toward each other, if heat is applied in step S230, the coated papers may melt and adhere to each other even if there is no external pressure. It is placed in a state where it can be fused when heat is applied as it is wound. Unlike the process described above in FIGS. 1 to 4, it has the advantage of not requiring a separate pressing process.
- the heating process of step S230 considers that the basis weight of the coated paper is 33 to 162 g/m 2 It can be carried out for an appropriate time to ensure that the joint portions can secure sufficient peel strength and also reduce unnecessary process duration.
- the exposure time in the chamber may be 0.5 seconds or more.
- 7 shows a paper straw manufactured according to an embodiment of the present invention. 7 is a cross-sectional view taken along line AA′.
- the paper straws ST2 manufactured by the steps S210 to S230 described above include a first coated paper 200 forming an outer surface of the straw and a second coated paper forming an inner surface of the straw ( 300). Specifically, the upper coating layer 210 of the first coated paper forms the outer side of the straw, and the lower coating layer 320 of the second coated paper forms the inner side of the straw.
- the overlap section (especially OS1), which is the portion where the bonding is made, is clearly shown thicker than the other portions, but in fact, the coated paper itself has a very thin thickness compared to the full scale of the paper straw (example As shown in the cross-sectional view of FIG. 7, the paper straw may have a long cylindrical shape without a large change in thickness in the overlap section.
- FIG. 8 is a diagram schematically showing coated papers wound in a paper tube method according to another embodiment of the present invention. It corresponds to the above-described step (S220).
- Figure 9 is a view showing a cross-sectional view of a single-sided coated coated paper according to another embodiment of the present invention.
- first coated paper 400 and the second coated paper 500 overlap each other and are wound.
- first coated paper 400 is a single-sided coating
- second coated paper 500 is a double-sided coating. It is not limited thereto, and conversely, the first coated paper may be a double-sided coating, and the second coated paper may be a single-sided coating.
- the first coated paper 400 includes a substrate 402 and a coating layer 410 coated over the substrate. It is referred to as the upper coating layer 410.
- the second coated paper 50 includes a substrate 502 and coating layers 510 and 520 coated on the upper and lower portions of the substrate. It is referred to as an upper coating layer 510 and a lower coating layer 520, respectively.
- the first coated paper is a single-sided coating in which only the upper portion of the substrate is coated, the above descriptions may be applied in the same manner.
- the first and second coated papers 400 and 500 are overlapped and wound with the coated surface facing outward.
- the upper coating layer 410 of the first coated paper and the lower coating layer 520 of the second coated paper are overlapped and wound toward the outside (ie, the outer side of the bonding area). That is, the upper coating layer 410 of the first coated paper faces upward and the lower coating layer 520 of the second coated paper faces downward.
- the substrate 402 of the first coated paper and the upper coating layer 310 of the second coated paper are arranged to face the inside (ie, the inside of the bonding area).
- the portion in which the upper coating layer 510 of the second coated paper 500 is disposed to face the substrate 402 of the first coated paper 400 before being wound with a winding pipe is defined by the first overlap section OS1.
- a portion in which the upper coating layer 510 of the second coated paper 500 is disposed to face the substrate 402 of the first coated paper 400 may be defined by the second overlap section OS2. .
- the overlap sections OS1 and OS2 provide a space in which the coated papers 400 and 500 can be bonded to each other.
- the coating layers disposed between the substrates become sticky and can be bonded to each other without a separate adhesive.
- 10 is a diagram schematically showing coated papers wound in a paper tube manner using three coated papers according to an embodiment of the present invention. It corresponds to the above-described step (S220).
- FIGS. 5 to 9 can be applied in the same manner, except that three coated papers instead of two coated papers are applied, the differences will be mainly looked at.
- first coated paper 600 As shown in Fig. 10, three coated papers are wound by overlapping each other.
- the first coated paper 600, the second coated paper 700, and the third coated paper 800 overlap each other and are wound.
- all of the first to third coated papers are shown to be double-sided coating.
- the present invention is not limited thereto.
- the first coated paper 600 includes a substrate 602 and coating layers 610 and 620 coated on the upper and lower portions of the substrate. It is referred to as an upper coating layer 610 and a lower coating layer 620, respectively.
- the second coated paper 700 includes a substrate 702 and coating layers 710 and 720 coated on the upper and lower portions of the substrate. It is referred to as an upper coating layer 710 and a lower coating layer 720, respectively.
- the third coated paper 800 includes a substrate 802 and coating layers 810 and 820 coated on the upper and lower portions of the substrate. It is referred to as an upper coating layer 810 and a lower coating layer 820, respectively.
- the first and third coated papers 600 and 800 are overlapped and wound with the coated surfaces facing outward.
- the upper coating layer 610 of the first coated paper and the lower coating layer 820 of the third coated paper are overlapped and wound toward the outside (ie, the outer side of the bonding area). That is, the upper coating layer 610 of the first coated paper faces upward and the lower coating layer 820 of the third coated paper faces downward, so that the overlapping is wound.
- the lower coating layer 620 of the first coated paper and the upper coating layer 810 of the third coated paper are arranged to face the inside (ie, the inside of the bonding area).
- the second coated paper 700 is overlapped and wound between them. That is, the upper coating layer 710 of the second coated paper faces upward and the lower coating layer 720 of the third coated paper faces downward, so that the first and third coated papers are overlapped and wound.
- the first overlapping section (OS1) between coated papers before being wound with a winding pipe is formed as follows.
- An overlap section OS1 is formed between the first coated paper and the second coated paper.
- an overlap section OS1 is formed between the second coated paper and the third coated paper.
- the portion in which the upper coating layer 710 of the second coated paper 700 faces the lower coating layer 620 of the first coated paper 600 before being wound with a winding pipe is defined by the first overlap section OS1 Can be.
- the portion in which the upper coating layer 810 of the third coated paper 800 faces the lower coating layer 720 of the second coated paper 700 before being wound with a winding pipe is defined by the first overlap section OS1 Can be.
- a secondary overlap section (OS2) between coated papers is formed as follows.
- the portion in which the upper coating layer 710 of the second coated paper 700 faces the lower coating layer 620 of the first coated paper 600 after being wound with a winding pipe, and the upper coating layer of the third coated paper 800 A portion in which 810 is disposed so as to face the lower coating layer 720 of the second coated paper 700 may be defined by the second overlap section OS2.
- the overlap sections OS1 and OS2 provide a space in which the coated papers 600 to 800 can be bonded to each other.
- the coating layers disposed between the substrates become sticky and can be bonded to each other without a separate adhesive.
- the three coated papers are all double-sided coating, but it is not limited thereto, and even when at least one of them is single-sided coating, the same description as in FIGS. 8 to 9 may be applied.
- the first coated paper is a single-sided coating, and may include only a substrate and an upper coating layer.
- the third coated paper is a single-sided coating, and may include only a substrate and a lower coating layer.
- the three fabrics i.e., the uppermost fabric, the lowermost fabric, and the fabric between them
- the present invention is not limited thereto, and the fabric disposed in the center does not include a coating layer.
- the same description as in FIGS. 8 to 9 above can be applied. This is because the upper coating layer of the middle fabric can be replaced by the lower coating layer of the uppermost fabric, and the lower coating layer of the middle fabric can be replaced by the upper coating layer of the lowermost fabric.
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Abstract
Description
본 발명은 친환경 종이 빨대의 제조방법 및 이에 의해 제조된 친환경 종이 빨대에 관한 것으로, 보다 구체적으로는 접착제를 포함하지 않는 친환경 종이 빨대의 제조방법 및 이에 의해 제조된 친환경 종이 빨대에 관한 것이다.The present invention relates to a method of manufacturing an eco-friendly paper straw and an eco-friendly paper straw manufactured thereby, and more specifically, to a method of manufacturing an eco-friendly paper straw that does not contain an adhesive, and an eco-friendly paper straw manufactured thereby.
플라스틱은 값싸고 내구성이 좋아 식음료를 빨이들이는 빨대(straw)의 재질로도 많이 이용된다. Plastics are cheap and durable, so they are often used as a material for straws that suck food and beverages.
플라스틱은 재활용이 가능한 원료로 알려져 있기는 하다. 그러나, 일반적으로 플라스틱 제품 제조 과정에서는 그 제조단계부터 재활용하기 어렵게 만들어지거나, 배출이나 수거 단계에서 오염, 파손 등으로 그대로 버려지는 경우가 많다. 최근 플라스틱 빨대를 바다거북이의 코에서 빼내는 동영상이나, 플라스틱 쓰레기 더미 플라스틱 아일랜드는 이런 현실을 극명히 보여준다. Plastic is known to be a recyclable raw material. However, in general, in the manufacturing process of plastic products, it is often made difficult to recycle from the manufacturing stage, or is discarded as it is due to contamination or damage in the discharge or collection stage. Recently, a video of removing a plastic straw from a turtle's nose, or a plastic island of plastic garbage shows this reality clearly.
이에 스타벅스, 맥도날드와 같은 세계 유수 기업들과 벤쿠버와 같은 대도시에서는 플라스틱 빨대의 사용을 금지하려는 움직임을 보이고 있다. 스타벅스는 2020년까지 전 세계 2만8천여 개 매장에서 플라스틱 빨대를 없애겠다는 발표를 했다. As a result, world-renowned companies such as Starbucks and McDonald's and large cities such as Vancouver are making moves to ban plastic straws. Starbucks has announced that it will eliminate plastic straws at 28,000 stores worldwide by 2020.
종이 빨대가 플라스틱 빨대 대체제 역할을 하기 충분하다. Paper straws are enough to replace plastic straws.
기존에도 종이 빨대가 사용되고는 있었으나, 제조 단가 문제 때문에 그 판매량은 플라스틱 빨대의 0.1%에 불과한 것으로 알려져 있다. Paper straws have been used in the past, but because of the manufacturing cost problem, their sales are known to account for only 0.1% of plastic straws.
또한, 기존의 종이 빨대는 그 구조상 필연적으로 접착제를 필요로 하는데, 이는 사용자의 음용 과정에서 접착제가 이탈(마이그레이션)되는 문제를 유발시킨다. PLA(Polylactic Acid)나 PVAc(Polyvinyl acetate)와 같은 접착제가 고온의 음용수에 풀어져 사용자의 입안으로 들어오게 되는 것이다. 이는 결국 인체에 무해한 접착제를 사용해야 하는 등 제조비용 증가의 문제로 이어진다. In addition, conventional paper straws inevitably require an adhesive due to their structure, which causes a problem in which the adhesive is separated (migrated) during the user's drinking process. An adhesive such as PLA (Polylactic Acid) or PVAc (Polyvinyl acetate) is dissolved in hot drinking water and enters the user's mouth. This leads to a problem of increasing manufacturing cost, such as the need to use an adhesive that is harmless to the human body.
본 발명의 발명자는 이러한 문제점들을 해결하기 위하여 오랫동안 연구하고 시행착오를 거친 끝에 본 발명을 완성하기에 이르렀다.The inventor of the present invention came to complete the present invention after long research and trial and error in order to solve these problems.
본 발명의 실시예는 접착제를 포함하지 않는 친환경 종이 빨대의 제조방법 및 이에 의해 제조된 친환경 종이 빨대를 제공한다.An embodiment of the present invention provides a method for manufacturing an eco-friendly paper straw that does not contain an adhesive, and an eco-friendly paper straw manufactured thereby.
한편, 본 발명의 명시되지 않은 또 다른 목적들은 하기의 상세한 설명 및 그 효과로부터 용이하게 추론할 수 있는 범위 내에서 추가적으로 고려될 것이다.Meanwhile, other objects not specified of the present invention will be additionally considered within a range that can be easily deduced from the following detailed description and effects thereof.
본 발명의 실시예에 따른 친환경 종이 빨대 제조방법은, 기재의 양면 중 적어도 일면에 아크릴 베이스의 제지용 수분산성 코팅제가 코팅된 코팅지를 제공하는 단계; 상기 코팅지의 일단과 타단이 서로 겹쳐져 오버랩 구간이 형성되도록 벤딩하는 단계; 및 상기 오버랩 구간을 실링하는 단계;를 포함할 수 있다. An eco-friendly paper straw manufacturing method according to an embodiment of the present invention comprises the steps of: providing a coated paper coated with an acrylic-based water-dispersible coating agent for papermaking on at least one side of both sides of a substrate; Bending one end and the other end of the coated paper to overlap each other to form an overlap section; And sealing the overlap section.
상기 코팅지는 기재의 아래에 배치되는 제1 코팅층 및 기재의 위에 배치되는 제2 코팅층을 포함하고, 상기 오버랩 구간에서 상기 코팅지의 일단의 제1 코팅층은 상기 코팅지의 타단의 제2 코팅층과 융착될 수 있다. The coated paper includes a first coating layer disposed under the substrate and a second coating layer disposed on the substrate, and in the overlap section, the first coating layer of one end of the coated paper may be fused with the second coating layer of the other end of the coated paper. have.
상기 종이 빨대는 제1 방향으로 연장하고, 상기 코팅지는 상기 제1 방향으로의 길이와 상기 제1 방향에 직교하는 제2 방향으로의 폭을 가지며, 상기 오버랩 구간은 상기 코팅지의 폭에 대해 1/10~1/2 범위에 걸쳐서 형성될 수 있다. The paper straw extends in a first direction, and the coated paper has a length in the first direction and a width in a second direction orthogonal to the first direction, and the overlap section is 1/of the width of the coated paper. It may be formed over a range of 10 to 1/2.
상기 실링하는 단계는, 열봉합 방식에 의해 수행될 수 있다. The sealing may be performed by a heat sealing method.
상기 실링하는 단계는, 상기 오버랩 구간을 소정의 압력과 온도로 기설정된 시간동안 가압하는 방식에 의해 수행될 수 있다. The sealing may be performed by pressing the overlap section at a predetermined pressure and temperature for a preset time.
상기 실링하는 단계는, 초음파 조사기나 인두기를 이용할 수 있다. In the sealing step, an ultrasonic irradiator or an iron may be used.
상기 코팅지는 평량이 33~162 g/m 2 일 수 있다. The coated paper may have a basis weight of 33 to 162 g/m 2 .
또한 본 발명의 실시예에 따른 친환경 종이 빨대 제조방법은, 기재의 양면 중 적어도 일면에 아크릴 베이스의 제지용 수분산성 코팅액이 코팅된 코팅지를 하나 이상 포함하는 2 이상의 원단들을 제공하는 단계; 상기 원단들을 서로 겹쳐서 지관 방식으로 권취하는 단계; 및 상기 권취된 원단들을 서로 겹쳐진 오버랩 구간에서 상호간에 접합하는 단계;를 포함할 수 있다. In addition, a method of manufacturing an eco-friendly paper straw according to an embodiment of the present invention includes: providing two or more fabrics including at least one coated paper coated with an acrylic-based water-dispersible coating liquid for papermaking on at least one side of both sides of a substrate; Stacking the fabrics with each other and winding them in a paper tube method; And bonding the wound fabrics to each other in an overlapping section overlapping each other.
상기 접합하는 단계는, 상기 권취된 원단들을 가열하는 과정을 포함할 수 있다. The bonding may include heating the wound fabrics.
상기 가열은 열풍기를 이용할 수 있다. The heating may use a hot air.
상기 권취하는 단계에서, 제1 원단과 제2 원단이 서로 겹쳐서 권취되고, 상기 제1 및 제2 원단들은 서로 코팅면이 접합부위의 바깥쪽을 향하도록 하여 겹쳐서 권취될 수 있다. In the winding step, the first fabric and the second fabric are overlapped and wound, and the first and second fabrics may be wound by overlapping each other so that the coated surface faces the outside of the joint.
상기 코팅지는 평량이 33~162 g/m 2 일 수 있다.The coated paper may have a basis weight of 33 to 162 g/m 2 .
또한 본 발명의 실시예에 따른 친환경 종이 빨대는, 기재의 적어도 일면에 아크릴 베이스의 제지용 수분산성 코팅액이 코팅된 하나 이상의 코팅지들;을 포함하되, 상기 하나 이상의 코팅지들은 상기 빨대의 형상을 형성하기 위해 접합되는 오버랩 구간을 가지며, 상기 오버랩 구간은 별도의 접착제를 포함하지 않을 수 있다. In addition, the eco-friendly paper straw according to an embodiment of the present invention includes one or more coated papers coated with an acrylic-based water-dispersible coating liquid for papermaking on at least one surface of a substrate, wherein the one or more coated papers form the shape of the straw. It has an overlap section that is bonded to each other, and the overlap section may not include a separate adhesive.
본 기술은 접착제 없이 제조할 수 있는 친환경 종이 빨대를 제공할 수 있다.This technology can provide eco-friendly paper straws that can be manufactured without adhesives.
또한 본 기술은 접착제 없이 종이 빨대를 제조할 수 있으므로, 기존에 접착제인 PLA나 PVAC와 같이 고온의 음용수 내에서 녹아나오는 우려가 없다. In addition, since this technology can manufacture paper straws without adhesives, there is no fear of melting in hot drinking water such as PLA or PVAC, which are conventional adhesives.
또한 본 기술은 접착제 없이 종이 빨대를 제조할 수 있으므로, 빨대 제조 비용을 획기적으로 절감할 수 있다. In addition, since the present technology can manufacture a paper straw without an adhesive, the straw manufacturing cost can be drastically reduced.
도 1은 본 발명의 실시예에 따른 친환경 종이 빨대 제조방법을 시간의 흐름에 따라 도시하는 순서도이다. 1 is a flowchart illustrating a method of manufacturing an eco-friendly paper straw according to an embodiment of the present invention over time.
도 2는 본 발명의 실시예에 따른 친환경 종이 빨대 제조방법에 사용되는 코팅지의 단면도를 도시하는 도면이다.2 is a diagram showing a cross-sectional view of a coated paper used in a method of manufacturing an eco-friendly paper straw according to an embodiment of the present invention.
도 3a는 본 발명의 실시예에 따른 단계에서 벤딩된 상태의 코팅지의 단면도를 도시하는 도면이다. 3A is a view showing a cross-sectional view of a coated paper bent in a step according to an embodiment of the present invention.
도 3b는 본 발명의 실시예에 따른 단계에서 벤딩되어 오버랩된 구간에 대해 실링이 이루어진 상태의 단면도를 도시하는 도면이다.3B is a view showing a cross-sectional view of a state in which sealing is performed on a section that is bent and overlapped in a step according to an embodiment of the present invention.
도 4는 본 발명의 실시예에 따라 제조된 종이 빨대와 AA'선에 따른 단면도를 도시하는 도면이다. 4 is a view showing a cross-sectional view taken along line AA′ and a paper straw manufactured according to an embodiment of the present invention.
도 5는 본 발명의 다른 실시예에 따른 친환경 종이 빨대 제조방법을 시간의 흐름에 따라 도시하는 순서도이다. 5 is a flowchart illustrating a method of manufacturing an eco-friendly paper straw according to another embodiment of the present invention over time.
도 6은 본 발명의 다른 실시예에 따른 단계에서 지관 방식으로 권취되는 코팅지들을 개략적으로 도시하는 도면이다.6 is a diagram schematically showing coated papers wound in a paper tube manner in a step according to another embodiment of the present invention.
도 7은 본 발명의 실시예에 따라 제조된 종이 빨대와 AA'선에 따른 단면도를 도시하는 도면이다. 7 is a view showing a cross-sectional view taken along line AA′ and a paper straw manufactured according to an embodiment of the present invention.
도 8은 본 발명의 또 다른 실시예에 따라, 지관 방식으로 권취되는 코팅지들을 개략적으로 도시하는 도면이다. 8 is a diagram schematically showing coated papers wound in a paper tube method according to another embodiment of the present invention.
도 9는 본 발명의 다른 실시예에 따라 단면 코팅의 코팅지의 단면도를 도시하는 도면이다. 9 is a view showing a cross-sectional view of a single-sided coated coated paper according to another embodiment of the present invention.
도 10은 본 발명의 실시예에 따라, 3개의 코팅지들을 이용하여 지관 방식으로 권취되는 코팅지들을 개략적으로 도시하는 도면이다.10 is a diagram schematically showing coated papers wound in a paper tube manner using three coated papers according to an embodiment of the present invention.
첨부된 도면은 본 발명의 기술사상에 대한 이해를 위하여 참조로서 예시된 것임을 밝히며, 그것에 의해 본 발명의 권리범위가 제한되지는 아니한다.The accompanying drawings are exemplified by reference for an understanding of the technical idea of the present invention, and the scope of the present invention is not limited thereto.
이하에서는, 본 발명의 가장 바람직한 실시예가 설명된다. 도면에 있어서, 두께와 간격은 설명의 편의를 위하여 표현된 것이며, 실제 물리적 두께에 비해 과장되어 도시될 수 있다. 본 발명을 설명함에 있어서, 본 발명의 요지와 무관한 공지의 구성은 생략될 수 있다. 각 도면의 구성요소들에 참조 번호를 부가함에 있어서, 동일한 구성 요소들에 한해서는 비록 다른 도면상에 표시되더라도 가능한 한 동일한 번호를 가지도록 하고 있음에 유의하여야 한다.In the following, the most preferred embodiment of the present invention will be described. In the drawings, thickness and spacing are expressed for convenience of description, and may be exaggerated compared to actual physical thickness. In describing the present invention, known configurations irrelevant to the gist of the present invention may be omitted. In adding reference numerals to elements of each drawing, it should be noted that only the same elements have the same number as possible, even if they are indicated on different drawings.
도 1은 본 발명의 실시예에 따른 친환경 종이 빨대 제조방법을 시간의 흐름에 따라 도시하는 순서도이다. 1 is a flowchart illustrating a method of manufacturing an eco-friendly paper straw according to an embodiment of the present invention over time.
그리고 도 2는 본 발명의 실시예에 따른 친환경 종이 빨대 제조방법에 사용되는 코팅지의 단면도를 도시하는 도면이다. And Figure 2 is a view showing a cross-sectional view of the coated paper used in the eco-friendly paper straw manufacturing method according to an embodiment of the present invention.
먼저 도 1에 도시된 바와 같이, 친환경 종이 빨대 제조방법(이하, 설명의 편의를 위해, '종이 빨대 제조방법'이라 함)은 코팅지를 제공하는 단계(S110), 오버랩 구간이 형성되도록 벤딩하는 단계(S129) 및 실링하는 단계(S130)를 포함한다. First, as shown in FIG. 1, the method of manufacturing an eco-friendly paper straw (hereinafter, referred to as a'paper straw manufacturing method' for convenience of explanation) is a step of providing a coated paper (S110), a step of bending so that an overlap section is formed. (S129) and sealing (S130).
그리고, 도 2에 도시된 바와 같이, 종이 빨대 제조방법에 사용되는 코팅지(100)는 기재(102)와 기재의 양면으로 코팅된 코팅층들(110, 120)을 포함한다. And, as shown in Figure 2, the coated
먼저, 단계(S110)에서는 코팅지(100)를 제공한다. 코팅지는 코팅지로 참조될 수 있다. First, in step S110, a coated
코팅지(100)는 기재(102)에 코팅층(110, 120)을 형성시킨 것이다. 즉, 기재를 제지용 수분산성 코팅제로 코팅한 것이다. 이와 대비하여, 본 발명에서는 코팅되지 않은 기재를 원지로 참조할 수 있다. 원지와 코팅지를 모두 가리켜 원단으로 참조할 수 있다. The coated
기재(102)는 종이 재질이다. 기재는 도공지, 비도공지 또는 크래프트지 등일 수 있다. 본 발명에서는 설명의 편의를 위해 기재가 비도공지인 것으로 가정한다. 비도공지는 종이에 화학약품, 미세돌가루 등 도공처리를 하지 않은 용지이다. 종이 빨대는 사람의 입과 식품에 직접 닿는 부분이므로 인체에 무해한 원료로 제조되는 것이 바람직하다. The
기재(102)는 평량 30 내지 150 g/m
2의 무게를 가질 수 있다. 30 g/m
2 보다 작은 경우 장력이 너무 약해져서 연속 공정에 불리하다. 수용액으로 코팅하는 과정에서 그 속도를 매우 천천히 하지 않으면 끊어지는 문제가 발생할 수 있다. 150 g/m
2 보다 큰 경우에는 쉽게 벤딩되지 않아 후술하는 접촉 영역(즉, 오버랩 구간)이 들뜨는 문제점을 초래할 수 있다. 벤딩시 접점부위는 더욱 두꺼워짐에 따라 빨대의 매끈한 표면을 도출하기 어려워진다. 상용성이 떨어진다. The
코팅층(110, 120)은 방습성 및 열봉합성을 높이기 위한 것이다. 코팅층(110, 120)은 기재를 기준으로 위에 배치되는 상부 코팅층(110) 및 그 아래에 배치되는 하부 코팅층(120)을 포함한다. The coating layers 110 and 120 are for improving moisture-proof properties and heat sealability. The coating layers 110 and 120 include an
본 발명의 실시예에 따르면, 코팅층(110, 120)을 만드는 코팅액은 제지용 수분산성 코팅제(이하, 설명의 편의를 위해 '코팅제'라고도 함)이다. According to an embodiment of the present invention, the coating liquid for making the coating layers 110 and 120 is a water-dispersible coating agent for papermaking (hereinafter, also referred to as a'coating agent' for convenience of explanation).
일례로, 코팅제는 아크릴 베이스의 수분산성 코팅제이다. 예를 들어, 아크릴 베이스의 수분산성 코팅제는 아크릴계 중합체와 실리콘계 중합체가 공중합된 공중합 에멀젼, 및 이에 호화된 폴리비닐알코올 콜로이드 수용액을 포함할 수 있다. In one example, the coating agent is an acrylic-based water-dispersible coating agent. For example, the acrylic-based water-dispersible coating agent may include a copolymer emulsion in which an acrylic polymer and a silicone polymer are copolymerized, and an aqueous polyvinyl alcohol colloid solution gelatinized therein.
아크릴계 고분자 수지는 아크릴 모노머의 중합도 중 일부 구간에서 열봉합성을 갖는다. 따라서, 해당 중합도를 만족하는 코팅제로 기재를 코팅하는 경우 접착제 없이도 코팅지를 접착할 수 있는 근간을 마련한다. The acrylic polymer resin has heat sealability in some sections of the polymerization degree of the acrylic monomer. Therefore, when the substrate is coated with a coating agent that satisfies the degree of polymerization, the basis for adhering the coated paper without an adhesive is provided.
상기 코팅제의 코팅량은 고형분 기준으로 3~12 g/m 2 일 수 있다. 3 g/m 2 미만의 코팅인 경우 방습성 성능발현이 떨어지고 실링이 잘 이루어지지 않는 문제가 있다. 12 g/m 2 초과하는 코팅의 경우 블로킹 문제가 발생된다.The coating amount of the coating agent may be 3 to 12 g/m 2 based on solid content. In the case of a coating of less than 3 g/m 2 , there is a problem in that the moisture-proof performance is poor and the sealing is not performed well. In the case of coatings exceeding 12 g/m 2 , blocking problems arise.
따라서, 기재에 코팅층을 포함하는 코팅지(100)는 평량이 33~162 g/m
2 일 수 있다. 이때 하한은 상술한 바와 같은 이유로 기재의 하한과 코팅제의 하한을 더한 값에 해당하고, 상한은 상술한 바와 같은 이유로 기재의 상한과 코팅제의 상한을 더한 값에 해당할 수 있다. Accordingly, the
본 발명에서 사용될 수 있는 아크릴계 단량체는 메틸 아크릴레이트, 에틸 아크릴레이트, 2-히드록시에틸아크릴레이트 프로필 아크릴레이트, 부틸 아크릴레이트, 2-에틸헥실아크릴레이트, 시클로헥실 아크릴레이트, 메틸 메타크릴레이트, 에틸 메타크릴레이트, 하이드록시에틸 메타크릴레이트, 프로필 메타크릴레이트, n-부틸 메타크릴레이트, 시클로헥실 메타크릴레이트, 이소부틸 메타크릴레이트, 아크릴로니트릴, 메타크릴산 및 이들의 조합으로 이루어진 그룹에서 선택된 하나 이상의 화합물로 이루어질 수 있다. 바람직하게는, 아크릴계 단량체는, 부틸 아크릴레이트, 메틸 메타크릴레이트, 하이드록시에틸 메타크릴레이트, 및 메타크릴산의 조합으로 이루어질 수 있다.Acrylic monomers that can be used in the present invention are methyl acrylate, ethyl acrylate, 2-hydroxyethyl acrylate propyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, cyclohexyl acrylate, methyl methacrylate, ethyl In the group consisting of methacrylate, hydroxyethyl methacrylate, propyl methacrylate, n-butyl methacrylate, cyclohexyl methacrylate, isobutyl methacrylate, acrylonitrile, methacrylic acid and combinations thereof It may consist of one or more selected compounds. Preferably, the acrylic monomer may be made of a combination of butyl acrylate, methyl methacrylate, hydroxyethyl methacrylate, and methacrylic acid.
또한, 본 발명에서 사용될 수 있는 실리콘계 단량체는 헥사메틸시클로트리실록산, 옥타메틸시클로테트라실록산, 데카메틸시클로펜타실록산, 도데카메틸시클로헥사실록산, 트리메틸트리페닐시클로트리실록산, 테트라메틸테트라페닐시클로테트라실록산, 옥타페닐시클로테트라실록산 및 이들의 조합으로 이루어진 그룹에서 선택된 시클로실록산 화합물로 이루어질 수 있다.In addition, the silicone-based monomers that can be used in the present invention include hexamethylcyclotrisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, trimethyltriphenylcyclotrisiloxane, tetramethyltetraphenylcyclotetrasiloxane , Octaphenylcyclotetrasiloxane, and a cyclosiloxane compound selected from the group consisting of combinations thereof.
아크릴계 중합체의 중합도, 실리콘계 중합체의 중합도, 아크릴계 중합체 및 실리콘계 중합체의 비율, 공중합 에멀젼에 포함된 입자의 중량평균 분자량과 평균지름, 공중합 에멀젼의 고형분 비율, 농도, 폴리비닐알코올의 검화도(degree of saponification), 공중합 에멀젼과 폴리비닐알코올 콜로이드 수용액의 중량비, 기타 첨가되는 물, 개시제, 유화제, 완충제 등에 관한 정보는 본 출원인이 출원한 특허출원번호 제PCT-KR2017-010598호의 특허문헌에 개시된 내용을 참조할 수 있다. The degree of polymerization of the acrylic polymer, the degree of polymerization of the silicone polymer, the ratio of the acrylic polymer and the silicone polymer, the weight average molecular weight and average diameter of the particles contained in the copolymer emulsion, the solid content ratio of the copolymer emulsion, the concentration, the degree of saponification of polyvinyl alcohol ), for information on the weight ratio of the copolymer emulsion and the polyvinyl alcohol colloidal aqueous solution, other added water, initiator, emulsifier, buffer, etc., refer to the contents disclosed in the patent document of Patent Application No. PCT-KR2017-010598 filed by the present applicant. I can.
단계(S120)에서는 코팅지의 일단과 타단이 서로 겹쳐져 오버랩 구간(OS)이 형성되도록 벤딩한다. In step S120, one end and the other end of the coated paper are bent so as to overlap each other to form an overlap section OS.
오버랩 구간에서 후술하는 바와 같이 코팅지의 일단과 타단이 서로 접합되므로, 단계(S120)는 접합을 위한 사전 작업이라 할 수 있다. Since one end and the other end of the coated paper are bonded to each other as described later in the overlap section, step S120 may be referred to as a pre-work for bonding.
그리고, 단계(S130)에서 오버랩 구간(OS)에 대한 실링 과정이 수행된다. Then, in step S130, a sealing process for the overlap section OS is performed.
실링 과정은 열봉합 방식에 의해 수행될 수 있다. The sealing process may be performed by a heat sealing method.
단계(S120)와 단계(S130)는 하나의 과정에서 수행될 수도 있다. 즉, 벤딩과 실링을 동시에 수행하는 장치에서 벤딩 직후 바로 실링이 수행될 수 있다. 다만 본 발명에서는 설명의 편의를 위해, 서로 별개의 프로세스인 실시예를 중심으로 설명하기로 한다. Steps S120 and S130 may be performed in one process. That is, sealing may be performed immediately after bending in a device that performs bending and sealing at the same time. However, in the present invention, for convenience of description, an embodiment that is a process that is separate from each other will be described.
이하 도 3을 함께 참조하여 보다 단계(S120)와 단계(S130)를 보다 상세히 설명한다. Hereinafter, steps S120 and S130 will be described in more detail with reference to FIG. 3.
도 3a는 본 발명의 실시예에 따른 단계(S120)에서 벤딩된 상태의 코팅지의 단면도를 도시하는 도면이다. 그리고, 도 3b는 본 발명의 실시예에 따른 단계(S130)에서 벤딩되어 오버랩된 구간에 대해 실링이 이루어진 상태의 단면도를 도시하는 도면이다. 3A is a diagram showing a cross-sectional view of a coated paper bent in a step S120 according to an embodiment of the present invention. In addition, FIG. 3B is a view showing a cross-sectional view of a state in which sealing is performed for a section that is bent and overlapped in step S130 according to an embodiment of the present invention.
먼저, 도 3a를 참조하면, 코팅지(100)의 일단(E1)과 타단(E2)이 서로 겹쳐져 오버랩 구간(OS)이 형성된다. 양 쪽 끝이 서로 겹쳐지도록 한 번 구부려준 상태일 수 있다. First, referring to FIG. 3A, one end E1 and the other end E2 of the
보다 상세히 살펴보기 앞서 상술한 도 2를 참조하면, 도면에 도시된 바와 같이, 코팅지(100)는 xyz좌표계상 x축방향으로 폭을 갖고, z축방향으로 길이를 가질 수 있다. 도면에 표현되지는 않았으나, z축방향으로 충분히 긴 길이(일례로, 5~25cm)를 가짐으로써, 사용자의 입과 식품(음용수)을 매개하는 빨대본연의 기능을 수행할 수 있다. 또한, 이보다는 짧지만, x축방향으로 소정의 길이의 폭(일례로, 1~2.5cm)을 가짐으로써 벤딩하였을 때 서로 겹쳐진 오버랩 구간을 형성함과 동시에 내부에 중공(H)을 형성하여 식품이 흘러가는 통로를 만들어낼 수 있다. 또한, 코팅지는 y축방향으로 두께를 갖는다. 두께는 일례로, 0.3~1.5mm일 수 있다. Referring to FIG. 2 described above in more detail, as shown in the drawings, the
본 발명의 실시예에 따르면, 오버랩 구간(OS)은 코팅지(100)의 폭에 대해 대략 1/10~1/2의 범위에 걸쳐서 형성될 수 있다. 즉, 코팅지를 벤딩했을 때 일단과 타단이 겹져지는 구간이 코팅지의 폭의 1/10~1/2을 차지하도록 벤딩할 수 있다. According to an embodiment of the present invention, the overlap section OS may be formed over a range of approximately 1/10 to 1/2 with respect to the width of the
예를 들어, 코팅지의 폭이 1~2.5cm인 경우, 오버랩 구간은 0.1~1.25cm의 폭으로 형성될 수 있다. For example, when the width of the coated paper is 1 to 2.5 cm, the overlap section may be formed with a width of 0.1 to 1.25 cm.
오버랩 구간이 1/10보다 작게 형성되면 접합 면적이 좁아 실링을 위한 충분한 접착 강도를 확보하기 어렵다(즉, 제조과정 및 사용과정에서 풀어질 수 있다). 접착강도를 나타내는 필(peel) 강도가 매우 낮게 나타난다. 그만큼 접학 부위가 쉽게 뜯어질 수 있다. 1/2보다 크게 형성되면 불필요한 접합 면적 증가로 재료의 손실이 예상되므로 경제적이지 못하다. 따라서, 오버랩 구간은 코팅지의 폭에 대해 1/10~1/2의 범위를 갖는 것이 바람직하다. If the overlap section is formed smaller than 1/10, it is difficult to secure sufficient adhesive strength for sealing because the bonding area is narrow (that is, it may be released during manufacturing and use). The peel strength, which represents the adhesive strength, is very low. As such, the contact area can be easily torn off. If it is formed larger than 1/2, it is not economical because loss of material is expected due to unnecessary increase in bonding area. Therefore, it is preferable that the overlap section has a range of 1/10 to 1/2 with respect to the width of the coated paper.
도 3a에 도시된 바와 같이, 위로 겹쳐진 타단 부분(도면에서 E1으로 표시됨)의 상부 코팅층(110)이 아래로 겹쳐진 일단 부분(도면에서 E2로 표시됨)의 하부 코팅층(120)과 마주보도록 배치된다. 그리고, 이들이 마주보는 구간에서 오버랩 구간이 형성된다. As shown in FIG. 3A, the
단계(S130)에서 도 3b에 도시된 바와 같이, 오버랩 구간이 실링된다. In step S130, as shown in FIG. 3B, the overlap section is sealed.
실링 부위가 도면에서 SP로 참조된다. 도면에서 실링 부위(SP)는 설명의 편의를 위해 두꺼운 실선으로 도시되었을 뿐, 이에 한정되지 않으며, 실제로는 오버랩 구간의 상부 코팅층과 하부 코팅층이 녹아서 서로 들러붙은 형상에 해당한다(마치 코팅층들이 서로 융착된 모습과 같이). The sealing site is referred to as SP in the figure. In the drawings, the sealing portion (SP) is shown as a thick solid line for convenience of explanation, but is not limited thereto, and actually corresponds to a shape in which the upper and lower coating layers of the overlap section are melted and adhered to each other (as if the coating layers are fused together. Like the way it was).
실링 과정은 열봉합 방식에 의해 수행될 수 있다. The sealing process may be performed by a heat sealing method.
본 발명의 실시예에 따른 코팅지(100)는 그 코팅제가 본연의 멜팅템퍼레쳐(melting temperature, T
m)를 가지므로, 단계(S130)는 이를 고려하여 수행될 수 있다. 즉, 본 발명의 실시예에 따라, 아크릴 베이스의 수분산성 코팅제는 T
m 이 300~340℃ 범위 내에 존재하므로, 단계(130)는 오버랩 구간이 300~340℃의 온도를 갖도록 열을 가할 수 있다. In the
열을 가하는 과정은 초음파 조사기나 인두기를 이용할 수 잇다. 예를 들어, 초음파 조사기나 인두기를 구비하는 실링 장치(미도시)에 단계(S120)를 거친 코팅지가 도입됨으로써 오버랩 구간이 열봉합될 수 있다. The process of applying heat can be performed using an ultrasonic irradiator or an iron. For example, the overlapping section may be heat-sealed by introducing the coated paper passed through the step S120 into a sealing device (not shown) having an ultrasonic irradiator or an iron.
또한, 실링을 위해서는 열을 인가하는 과정에서 피접합대상물들(즉, 오버랩 구간에 배치된 코팅지의 일단과 타단)을 서로 가압하는 과정이 함께 수행될 수 있다. In addition, for sealing, a process of pressing the objects to be joined (ie, one end and the other end of the coated paper disposed in the overlap section) to each other in the process of applying heat may be performed together.
대체로, 필 강도는 접착 부위에 대해 가해지는 압력에 대해 비례하는 경향을 가지므로, 오버랩 구간에 대해 요구되는 필 강도를 확보할 수 있는 소정의 압력이 가해질 수 있다. 상술한 코팅지의 평량이 33~162 g/m 2 인 점을 고려하여, 코팅지의 접합 부위들이 접촉 상태를 유지하기에 적합하고, 또한 열이 가해질 경우 접합 부위들이 즉시 접합될 수 있도록 하는 사전 접촉 상태를 안정적으로 유지되도록 하는 적절한 압력이 가해질 수 있다. 일례로, 0.2kg/㎠ 이상의 압력이 가해질 수 있다. In general, since the peel strength has a tendency to be proportional to the pressure applied to the bonding portion, a predetermined pressure can be applied to secure the peel strength required for the overlap section. Considering that the basis weight of the above-described coated paper is 33~162 g/m 2 , it is suitable for the bonding areas of the coated paper to remain in contact, and a pre-contact state that allows the bonding areas to be immediately bonded when heat is applied. Appropriate pressure can be applied to ensure that it remains stable. For example, a pressure of 0.2kg/cm2 or more may be applied.
가압은 오버랩 구간을 중심으로 위에서 아래로 그리고 아래에서 위로 가압하는 가압 장치(프레스 등)를 이용할 수 있다. 예를 들어, 실링 장치는 가압부(미도시)를 구비할 수 있고, 이 가압부가 오버랩 구간의 열봉합 과정에서 상하방향으로 가압할 수 있다. Pressurization may use a pressurizing device (press, etc.) that pressurizes from top to bottom and from bottom to top around the overlap section. For example, the sealing device may include a pressing portion (not shown), and the pressing portion can be pressed in the vertical direction during the heat sealing process of the overlap section.
대체로, 필 강도는 시간에 대해 비례하다가 일정값으로 수렴하는 경향을 가지므로, 오버랩 구간에 대해 가해지는 압력을 일정 시간 이상 유지하도록 할 수 있다. 상술한 코팅지의 평량이 33~162 g/m 2 인 점을 고려하여, 코팅지의 접합 부위들이 충분한 필 강도를 확보할 수 있도록 하고, 또한 불필요한 공정 지속 시간을 줄일 수 있는 적절한 시간동안 상기 압력이 가해지도록 제어할 수 있다. 일례로, 상기 온도와 압력으로 0.5초 이상 가압할 수 있다. In general, since the peel strength is proportional to time and tends to converge to a predetermined value, the pressure applied to the overlap section can be maintained for a predetermined time or longer. Considering that the basis weight of the coated paper is 33 to 162 g/m 2 , the pressure is applied for an appropriate time to ensure sufficient peel strength for the joints of the coated paper and to reduce unnecessary process duration. Can be controlled to lose. For example, it may be pressurized for 0.5 seconds or more at the temperature and pressure.
한편, 상술한 제어변수들인 온도, 압력 및 시간은 서로 밀접하게 관계된 것들로서, 상대적으로 온도가 높은 경우 압력 인가 시간이 짧아질 수 있고, 상대적으로 온도가 낮은 경우 압력 인가 시간이 길어질 수 있다. 또한, 압력 인가 시간이 상대적으로 긴 경우 인가 압력이 낮아질 수 있고, 반대로 압력 인가 시간이 짧은 경우 인가 압력이 높아질 수 있다. Meanwhile, the above-described control variables, such as temperature, pressure, and time, are closely related to each other. When the temperature is relatively high, the pressure application time may be shortened, and when the temperature is relatively low, the pressure application time may be lengthened. In addition, when the pressure application time is relatively long, the applied pressure may be lowered, and conversely, when the pressure application time is short, the applied pressure may increase.
도 4는 본 발명의 실시예에 따라 제조된 종이 빨대를 도시한다. 도 4에서 AA'선에 따른 단면도가 함께 도시된다. 4 shows a paper straw manufactured according to an embodiment of the present invention. In FIG. 4, a cross-sectional view taken along line AA′ is shown together.
도 4를 참조하면, 상술한 단계들(S110 내지 S130)에 의해 제조된 종이 빨대(ST1)는 기재(P)의 양면으로 코팅된 코팅층(CL)으로 구성됨을 확인할 수 있다. 코팅층은 내부의 코팅층(CLi)과 외부의 코팅층(CLo)을 갖는다. Referring to FIG. 4, it can be seen that the paper straw ST1 manufactured by the above-described steps S110 to S130 is composed of a coating layer CL coated on both sides of the substrate P. The coating layer has an inner coating layer CLi and an outer coating layer CLo.
기재와 코팅층에 대해서는 상술한 도 1 내지 도 3에서의 설명이 동일하게 적용될 수 있다. 기재(P)는 상술한 기재(102)에 상응하고, 코팅층(CLi, CLo)은 상술한 코팅층(110, 120)에 상응한다. For the substrate and the coating layer, the description in FIGS. 1 to 3 described above may be equally applied. The substrate P corresponds to the above-described
상술한 도 3에서는 열봉합 과정을 상세하게 설명하기 위해 그 열봉합이 이루어지는 부분인 오버랩 구간을 다른 부분들보다 두껍게 명확히 도시하였지만, 실제로 코팅지 자체는 종이 빨대의 전체 스케일 대비 매우 얇은 두께(일례로, 0.3~1.5mm, 도 2 설명 부분 참조)를 가지므로, 도 4의 단면도에 도시된 바와 같이 종이 빨대는 오버랩 구간에서의 큰 두께 변화없이 전체적으로 매끈한 긴 원기둥 형상을 가질 수 있다. In FIG. 3 described above, in order to describe the heat sealing process in detail, the overlap section, which is a part in which heat sealing is performed, is clearly shown thicker than other parts, but in fact, the coated paper itself has a very thin thickness compared to the full scale of the paper straw (for example, 0.3 ~ 1.5mm, see the description of Fig. 2), as shown in the cross-sectional view of Fig. 4, the paper straw can have a long cylindrical shape without a large thickness change in the overlap section.
한편, 상기에서는 코팅지가 양면코팅인 실시예를 중심으로 살펴보았으나, 이에 한정되지 않으며, 단면코팅인 경우에도 상술한 도 1 내지 도 4에서와 같은 설명이 적용 가능하다. 예를 들어, 코팅지가 단면 코팅으로서, 기재와 상부 코팅층만을 포함하는 경우에도 위로 겹쳐진 타단 부분의 상부 코팅층과 아래로 겹쳐진 일단 부분의 기재 사이에 접합이 이루어질 수 있고, 따라서 상술한 바와 같은 실링 부위가 정의될 수 있다. 다만, 빨대의 방습성을 고려하면 양면코팅인 것이 더욱 바람직하다. Meanwhile, in the above, an embodiment in which the coated paper is a double-sided coating has been mainly examined, but the present invention is not limited thereto, and the same description as in FIGS. 1 to 4 may be applied even in the case of single-sided coating. For example, even when the coated paper is a single-sided coating and includes only a substrate and an upper coating layer, bonding may be made between the upper coating layer of the other end overlapped above and the substrate of one end overlapped downward, and thus, the sealing region as described above is Can be defined. However, considering the moisture-proof properties of the straw, it is more preferable to use double-sided coating.
도 5는 본 발명의 다른 실시예에 따른 친환경 종이 빨대 제조방법을 시간의 흐름에 따라 도시하는 순서도이다. 5 is a flowchart illustrating a method of manufacturing an eco-friendly paper straw according to another embodiment of the present invention over time.
그리고 도 6은 본 발명의 다른 실시예에 따른 단계(S220)에서 지관 방식으로 권취되는 코팅지들을 개략적으로 도시하는 도면이다. And FIG. 6 is a diagram schematically showing coated papers wound in a paper tube method in step S220 according to another embodiment of the present invention.
먼저 도 5를 참조하면, 친환경 종이 빨대 제조방법(이하, 설명의 편의를 위해 '종이 빨대 제조방법'이라 함)은 코팅지들을 제공하는 단계(S210), 권취하는 단계(S220) 및 접합하는 단계(S230)를 포함한다. First, referring to FIG. 5, a method of manufacturing an eco-friendly paper straw (hereinafter, referred to as a'paper straw manufacturing method' for convenience of explanation) includes providing coated papers (S210), winding up (S220), and bonding ( S230).
그리고 도 6을 참조하면, 제공된 2개의 코팅지들(200, 300)이 서로 겹쳐져 지관 방식으로 권취된다. And referring to FIG. 6, the provided two
지관(paper tube) 방식은 여러 개의 원단들을 서로 겹쳐서 스파이럴 방식으로 권취파이프에 말아주는 것(spiral winding)을 의미한다. 이때, 코팅지들이 전체 면적에 걸쳐 완전히 겹쳐질 수도 있지만, 대체로 일부만 서로 겹쳐지도록 배치되어 권취된다. 도면에서도 그 겹친 구간이 도면부호 OS1로 표시되어 있으며, 이를 1차 오버랩 구간으로 참조한다. 1차 오버랩 구간은 필요에 따라 도면에 도시된 것 보다 더 넓게 겹쳐질 수도 있지만, 본 발명에서는 설명의 편의를 위해 도면에 도시된 영역만큼만 겹쳐진 것으로 가정한다. 또한 와인딩을 위해 권취파이프로 주입되는 방향이 도면에서 ID로 참조된다. The paper tube method means that several fabrics are stacked on top of each other and wound on a winding pipe in a spiral manner. At this time, the coated papers may be completely overlapped over the entire area, but are disposed so as to overlap each other and are wound. In the drawing, the overlapping section is indicated by reference numeral OS1, which is referred to as the first overlap section. If necessary, the first overlapping section may be wider than that shown in the drawings, but in the present invention, for convenience of explanation, it is assumed that only the areas shown in the drawings are overlapped. In addition, the direction injected into the winding pipe for winding is referred to as ID in the drawing.
본 발명의 실시예에 따르면, 1차 오버랩 구간(OS1)은 코팅지의 평량 33~162 g/m 2을 고려할 때, 코팅지의 폭에 대해 대략 1/5~4/5의 범위에 걸쳐서 형성될 수 있다. 즉, 제1 코팅지와 제2 코팅지가 겹쳐지는 구간은 각 코팅지의 폭의 1/5~4/5를 차지할 수 있다. 예를 들어, 코팅지의 폭이 1~2.5cm인 경우, 오버랩 구간은 0.2~2.0cm의 폭으로 형성될 수 있다. 오버랩 구간이 1/5보다 작게 형성되면 오버랩 공차가 지나치게 좁아져 스파이럴 권취 작업이 난해해지며, 4/5보다 크게 형성되면 지관 두께 형성을 제어하기 어렵다.According to an embodiment of the present invention, the first overlap section (OS1) may be formed over a range of approximately 1/5 to 4/5 of the width of the coated paper, considering the basis weight of the coated paper of 33 to 162 g/m 2 . have. That is, the section where the first coated paper and the second coated paper overlap may occupy 1/5 to 4/5 of the width of each coated paper. For example, when the width of the coated paper is 1 to 2.5 cm, the overlap section may be formed with a width of 0.2 to 2.0 cm. If the overlap section is formed smaller than 1/5, the overlap tolerance becomes too narrow, making the spiral winding operation difficult, and when it is formed larger than 4/5, it is difficult to control the formation of the thickness of the branch pipe.
다시 도 5를 참조하여 본 발명의 실시예에 따른 종이 빨대 제조방법을 순서대로 살펴본다. Referring again to FIG. 5, a method of manufacturing a paper straw according to an embodiment of the present invention will be sequentially described.
먼저, 단계(210)에서 2 이상의 코팅지들(200, 300)을 제공한다. First, in
코팅지들(200, 300)로는 상기 도 1 내지 도 4에서 상술한 코팅지(100)를 이용할 수 있다. 즉, 코팅지들(200, 300)은 상술한 코팅지(100)와 동일한 구조를 가질 수 있다. 이에 보다 상세한 설명은 생략하기로 한다. As the
제1 코팅지(200)는 기재(202)와 기재의 상하부로 코팅되는 코팅층들(210, 220)을 포함한다. 각각 상부 코팅층(210) 및 하부 코팅층(220)이라 한다. The first
제2 코팅지(300)는 기재(302)와 기재의 상하부로 코팅되는 코팅층들(310, 320)을 포함한다. 각각 상부 코팅층(310) 및 하부 코팅층(320)이라 한다.The second
본 발명에서는 2개의 코팅지들로 빨대를 제조하는 실시예를 중심으로 설명하기로 하나, 본 발명이 이에 한정되지 않으며, 3개의 코팅지들로 제조하는 경우에도 동일한 설명의 적용이 가능하다. In the present invention, an embodiment of manufacturing a straw with two coated papers will be mainly described, but the present invention is not limited thereto, and the same description can be applied even when manufacturing a straw with three coated papers.
단계(S220)에서 코팅지들(200, 300)을 서로 겹쳐서 지관 방식으로 권취한다. In step S220, the
제1 코팅지(200)와 제2 코팅지(300)가 서로 겹쳐서 권취된다. 제1 및 제2 코팅지들(200, 300)은 서로 코팅면이 바깥쪽을 향하도록 하여 겹쳐서 권취된다. 도면에서는 제1 코팅지의 상부 코팅층(210)과 제2 코팅지의 하부 코팅층(320)이 바깥쪽(즉, 접합부위의 바깥쪽)을 향하도록 하여 겹쳐서 권취된다. 즉, 제1 코팅지의 상부 코팅층(210)이 위쪽을 향하고 제2 코팅지의 하부 코팅층(320)이 아래쪽을 향하도록 하여 겹쳐서 권취된다. 한편, 반대로, 제1 코팅지의 하부 코팅층(220)과 제2 코팅지의 상부 코팅층(310)은 안쪽(즉, 접합부위의 인쪽)을 향하도록 배치되어 있다. The first
권취파이프(미도시)를 기준으로 코팅지들(200, 300)이 스파이럴 방식으로 권취되며, 도면에서는 제2 코팅지(300)가 권취파이프에 제1 코팅지(200) 보다 가까이 배치되어 있다. 이에 따라, 제2 코팅지(300)가 빨대의 내측면을 형성하고, 제1 코팅지(200)의 빨대의 외측면을 형성한다.The
따라서, 도 6에서 코팅지들이 겹쳐진 부분에 대한 확대도(도면에서 A로 표시된 부분)를 참조하면, 제2 코팅지(300) 위에 제1 코팅지(200)가 배치된다. 즉, 제2 코팅지(300)의 상부 코팅층(310)이 제1 코팅지(200)의 하부 코팅층(220)과 마주하도록 배치된다. 이 마주하도록 배치된 부분은 상술한 1차 오버랩 구간(OS1)에 의해 정의될 수 있다. Therefore, referring to an enlarged view of a portion where the coated papers are overlapped in FIG. 6 (a portion indicated by A in the drawing), the first
한편, 상기의 배치는 설명의 편의를 위한 것일 뿐, 제1 코팅지와 제2 코팅지가 서로 반대로 배치되어도 무방하다. Meanwhile, the above arrangement is only for convenience of description, and the first coated paper and the second coated paper may be disposed opposite to each other.
스파이럴 방식으로 권취됨에 따라, 권취파이프에 권취된 이후의 시점부터는 제1 코팅지(200)와 제2 코팅지(300)가 서로 마주하는 부분이 추가된다. 즉, 권취 전에는 마주하는 부분이 제1 오버랩 구간이고, 권취 후에는 마주하는 부분이 제2 오버랩 구간이 추가된다. 추가된 오버랩 구간이 도면에서 2차 오버랩 구간(OS2)으로 참조된다. 2차 오버랩 구간은 코팅지의 폭에 대해 1차 오버랩 구간(OS1)을 제외한 나머지 구간일 수 있다. 권취 각도에 따라 2차 오버랩 구간은 유동적일 수 있지만, 권취시 증가하는 지관의 두께를 고려하여 대체로 도면에 도시된 바와 같은 2차 오버랩 구간을 가질 수 있다. As it is wound in a spiral manner, portions of the first
2차 오버랩 구간(OS2)에서도 제2 코팅지(300) 위에 제1 코팅지(200)가 배치된다. 즉, 제2 코팅지(300)의 상부 코팅층(310)이 제1 코팅지(200)의 하부 코팅층(220)과 마주하도록 배치된다. The first
상술한 1차 오버랩 구간(OS1)과 2차 오버랩 구간(OS2)은 코팅지들(200, 300)이 서로 접합될 수 있는 공간을 제공한다. 후술하는 바와 같이, 1차 오버랩 구간 및 2차 오버랩 구간에서 코팅지들의 접합이 이루어진다. The first overlapping section OS1 and the second overlapping section OS2 described above provide a space in which the coated
본 발명의 실시예에 따른 단계(S230)에서 권취된 코팅지들은 서로 겹쳐진 오버랩 구간에서 상호간에 접합된다. The coated papers wound in step S230 according to an embodiment of the present invention are bonded to each other in an overlapping section overlapping each other.
접합을 위해, 권취된 코팅지들(200, 300)을 가열하는 과정이 수행될 수 있다. 예를 들어, 권취된 코팅지들이 가열부가 구비된 가열 장치(미도시)를 통과하는 과정이 수행될 수 있다. 가열부는 열풍기(챔버와 같은)일 수 있다. 일례로, 가열 장치의 열풍기를 통과하면서 열풍에 노출될 수 있다. 단계(S230)의 가열하는 과정은 이에 한정되지 오버랩 구간들(OS1, OS2)에 열을 가할 수 있는 다양한 방식들이 적용될 수 있다. For bonding, a process of heating the wound coated
본 발명의 실시예에 따른 코팅지들(200, 300)은 그 코팅제가 본연의 멜팅템퍼레쳐를 가지므로, 단계(S230)는 이를 고려하여 수행될 수 있다. 즉, 본 발명의 실시예에 따라, 아크릴 베이스의 수분산성 코팅제는 T
m 이 300~340℃ 범위 내에 존재하므로, 단계(230)는 오버랩 구간들이 300~340℃의 온도를 갖도록 열을 가할 수 있다. In the
한편, 단계(S220)의 권취 과정에서는 코팅지들이 이미 소정의 텐션을 갖고서 권취파이프에 권취되어 있다. 따라서, 코팅지들은 서로를 향해 가압되고 있는 상태이므로, 단계(S230)에서 열이 가해지면 별도의 외부 가압이 없더라도 코팅지들이 녹아서 서로 들러붙을 수 있다. 권취 상태 그대로 열이 가해지면 융착될 수 있는 상태에 놓여져 있다. 도 1 내지 도 4에서 상술한 과정과 다르게 별도의 가압 과정을 필요로 하지 않는 장점을 갖는다. On the other hand, in the winding process of step S220, the coated papers are already wound on the winding pipe with a predetermined tension. Therefore, since the coated papers are in a state of being pressed toward each other, if heat is applied in step S230, the coated papers may melt and adhere to each other even if there is no external pressure. It is placed in a state where it can be fused when heat is applied as it is wound. Unlike the process described above in FIGS. 1 to 4, it has the advantage of not requiring a separate pressing process.
대체로, 필 강도는 시간에 대해 비례하다가 일정값으로 수렴하는 경향을 가지므로, 단계(S230)의 가열하는 과정은 상술한 코팅지의 평량이 33~162 g/m 2 인 점을 고려하여, 코팅지의 접합 부위들이 충분한 필 강도를 확보할 수 있도록 하고, 또한 불필요한 공정 지속 시간을 줄일 수 있도록 하는 적절한 시간동안 수행될 수 있다. 일례로, 챔버 내 노출 시간이 0.5초 이상이 되도록 할 수 있다. In general, since the peel strength is proportional to time and tends to converge to a certain value, the heating process of step S230 considers that the basis weight of the coated paper is 33 to 162 g/m 2 It can be carried out for an appropriate time to ensure that the joint portions can secure sufficient peel strength and also reduce unnecessary process duration. For example, the exposure time in the chamber may be 0.5 seconds or more.
도 7은 본 발명의 실시예에 따라 제조된 종이 빨대를 도시한다. 도 7에서 AA'선에 따른 단면도가 함께 도시된다. 7 shows a paper straw manufactured according to an embodiment of the present invention. 7 is a cross-sectional view taken along line AA′.
도 7을 참조하면, 상술한 단계들(S210 내지 S230)에 의해 제조된 종이 빨대(ST2)는 빨대의 외측면을 형성하는 제1 코팅지(200)와 빨대의 내측면을 형성하는 제2 코팅지(300)로 구성됨을 확인할 수 있다. 구체적으로, 제1 코팅지의 상부 코팅층(210)이 빨대의 외측면을 형성하고, 제2 코팅지의 하부 코팅층이(320)이 빨대의 내측면을 형성한다. Referring to FIG. 7, the paper straws ST2 manufactured by the steps S210 to S230 described above include a first
상술한 도 6에서는 접합 과정을 상세하게 설명하기 위해 그 접합이 이루어지는 부분인 오버랩 구간(특히 OS1)을 다른 부분들보다 두껍게 명확히 도시하였지만, 실제로 코팅지 자체는 종이 빨대의 전체 스케일 대비 매우 얇은 두께(일례로, 0.3~1.5mm, 도 2 설명 부분 참조)를 가지므로, 도 7의 단면도에 도시된 바와 같이 종이 빨대는 오버랩 구간에서의 큰 두께 변화없이 전체적으로 매끈한 긴 원기둥 형상을 가질 수 있다. In FIG. 6 described above, in order to describe the bonding process in detail, the overlap section (especially OS1), which is the portion where the bonding is made, is clearly shown thicker than the other portions, but in fact, the coated paper itself has a very thin thickness compared to the full scale of the paper straw (example As shown in the cross-sectional view of FIG. 7, the paper straw may have a long cylindrical shape without a large change in thickness in the overlap section.
한편, 2 이상의 코팅지들 중 하나는 단면 코팅인 경우에도 종이 빨대를 제조할 수 있다. 이하 도 8 내지 도 9를 참조한다. On the other hand, even when one of the two or more coated papers is single-sided coating, a paper straw can be manufactured. Hereinafter, refer to FIGS. 8 to 9.
도 8은 본 발명의 또 다른 실시예에 따라, 지관 방식으로 권취되는 코팅지들을 개략적으로 도시하는 도면이다. 상술한 단계(S220)에 대응한다. 8 is a diagram schematically showing coated papers wound in a paper tube method according to another embodiment of the present invention. It corresponds to the above-described step (S220).
2 이상의 코팅지들로서, 그들 중 하나가 양면 코팅이 아닌 단면 코팅이라는 점을 제외하고는 도 5 및 도 6에서 상술한 설명이 동일하게 적용될 수 있으므로, 차이점을 위주로 살펴본다. As two or more coated papers, since the description described above in FIGS. 5 and 6 can be applied in the same manner, except that one of them is a single-sided coating rather than a double-sided coating, the differences will be mainly looked at.
그리고 도 9는 본 발명의 다른 실시예에 따라 단면 코팅의 코팅지의 단면도를 도시하는 도면이다. And Figure 9 is a view showing a cross-sectional view of a single-sided coated coated paper according to another embodiment of the present invention.
도 8 및 도 9에 도시된 바와 같이, 2 이상의 코팅지들이 서로 겹쳐서 권취된다. 제1 코팅지(400)와 제2 코팅지(500)가 서로 겹쳐서 권취된다. 도면에서는 제1 코팅지(400)가 단면 코팅이고, 제2 코팅지(500)가 양면 코팅인 것으로 도시된다. 이에 한정되지 않고, 반대로, 제1 코팅지가 양면코팅이고, 제2 코팅지가 단면코팅일 수도 있다. 8 and 9, two or more coated papers are wound by overlapping each other. The first
제1 코팅지(400)는 기재(402)와 기재의 상부로 코팅되는 코팅층(410)을 포함한다. 상부 코팅층(410)이라 한다. The first
제2 코팅지(50)는 기재(502)와 기재의 상하부로 코팅되는 코팅층들(510, 520)을 포함한다. 각각 상부 코팅층(510) 및 하부 코팅층(520)이라 한다.The second coated paper 50 includes a
제1 코팅지가 기재의 상부만 코팅된 단면 코팅이라는 점을 제외하고는 앞서 설명한 내용들이 동일하게 적용될 수 있다. Except that the first coated paper is a single-sided coating in which only the upper portion of the substrate is coated, the above descriptions may be applied in the same manner.
제1 및 제2 코팅지들(400, 500)은 서로 코팅면이 바깥쪽을 향하도록 하여 겹쳐서 권취된다. 도면에서는 제1 코팅지의 상부 코팅층(410)과 제2 코팅지의 하부 코팅층(520)이 바깥쪽(즉, 접합부위의 바깥쪽)을 향하도록 하여 겹쳐서 권취된다. 즉, 제1 코팅지의 상부 코팅층(410)이 위쪽을 향하고 제2 코팅지의 하부 코팅층(520)이 아래쪽을 향하도록 하여 겹쳐서 권취된다. 한편, 반대로, 제1 코팅지의 기재(402)와 제2 코팅지의 상부 코팅층(310)은 안쪽(즉, 접합부위의 안쪽)을 향하도록 배치되어 있다. The first and second
이러한 배치 관계에서도 오버랩 구간들(OS1, OS2)이 형성된다. Even in this arrangement relationship, overlapping sections OS1 and OS2 are formed.
즉, 권취파이프로 권취되기 전 제2 코팅지(500)의 상부 코팅층(510)이 제1 코팅지(400)의 기재(402)와 마주하도록 배치된 부분이 1차 오버랩 구간(OS1)에 의해 정의될 수 있다. 권취파이프에 권취된 이후 제2 코팅지(500)의 상부 코팅층(510)이 제1 코팅지(400)의 기재(402)와 마주하도록 배치된 부분이 2차 오버랩 구간(OS2)에 의해 정의될 수 있다. That is, the portion in which the
그리고, 상술한 바와 같이, 오버랩 구간들(OS1 및 OS2)은 코팅지들(400, 500)이 서로 접합될 수 있는 공간을 제공한다. And, as described above, the overlap sections OS1 and OS2 provide a space in which the coated
이 오버랩 구간들(OS1 및 OS2)에 코팅층의 멜팅템퍼레쳐에 상응하는 열이 가해지면, 기재들 사이에 배치된 코팅층들이 끈적끈적해지면서 별도의 접착제 없이도 서로 접합될 수 있다. When heat corresponding to the melting temper of the coating layer is applied to the overlapping sections OS1 and OS2, the coating layers disposed between the substrates become sticky and can be bonded to each other without a separate adhesive.
도 10은 본 발명의 실시예에 따라, 3개의 코팅지들을 이용하여 지관 방식으로 권취되는 코팅지들을 개략적으로 도시하는 도면이다. 상술한 단계(S220)에 대응한다. 10 is a diagram schematically showing coated papers wound in a paper tube manner using three coated papers according to an embodiment of the present invention. It corresponds to the above-described step (S220).
2개의 코팅지들이 아닌 3개의 코팅지들이 적용되었다는 점을 제외하고는 도 5 내지 도 9에서 상술한 설명이 동일하게 적용될 수 있으므로, 차이점을 위주로 살펴본다. Since the above description in FIGS. 5 to 9 can be applied in the same manner, except that three coated papers instead of two coated papers are applied, the differences will be mainly looked at.
도 10에 도시된 바와 같이, 3개의 코팅지들이 서로 겹쳐서 권취된다. 제1 코팅지(600), 제2 코팅지(700) 및 제3 코팅지(800)가 서로 겹쳐서 권취된다. 도면에서는 제1 내지 제3 코팅지들이 모두 양면 코팅인 것으로 도시된다. 그러나 본 발명이 이에 한정되지 않는다. As shown in Fig. 10, three coated papers are wound by overlapping each other. The first
제1 코팅지(600)는 기재(602)와 기재의 상하부로 코팅되는 코팅층들(610, 620)을 포함한다. 각각 상부 코팅층(610) 및 하부 코팅층(620)이라 한다.The first
제2 코팅지(700)는 기재(702)와 기재의 상하부로 코팅되는 코팅층들(710, 720)을 포함한다. 각각 상부 코팅층(710) 및 하부 코팅층(720)이라 한다.The second
제3 코팅지(800)는 기재(802)와 기재의 상하부로 코팅되는 코팅층들(810, 820)을 포함한다. 각각 상부 코팅층(810) 및 하부 코팅층(820)이라 한다.The third
제1 및 제3 코팅지들(600, 800)은 서로 코팅면이 바깥쪽을 향하도록 하여 겹쳐서 권취된다. 도면에서는 제1 코팅지의 상부 코팅층(610)과 제3 코팅지의 하부 코팅층(820)이 바깥쪽(즉, 접합부위의 바깥쪽)을 향하도록 하여 겹쳐서 권취된다. 즉, 제1 코팅지의 상부 코팅층(610)이 위쪽을 향하고 제3 코팅지의 하부 코팅층(820)이 아래쪽을 향하도록 하여 겹쳐서 권취된다. 한편, 반대로, 제1 코팅지의 하부 코팅층(620)와 제3 코팅지의 상부 코팅층(810)은 안쪽(즉, 접합부위의 안쪽)을 향하도록 배치되어 있다. The first and third
이들 사이에 제2 코팅지(700)가 함께 겹쳐서 권취된다. 즉, 제2 코팅지의 상부 코팅층(710)이 위쪽을 향하고 제3 코팅지의 하부 코팅층(720)이 아래쪽을 향하도록 하여 제1 및 제3 코팅지들과 함께 겹쳐서 권취된다. The second
권취파이프로 권취되기 전 코팅지들간 1차 오버랩 구간(OS1)이 다음과 같이 형성된다. The first overlapping section (OS1) between coated papers before being wound with a winding pipe is formed as follows.
제1 코팅지와 제2 코팅지 간에 오버랩 구간(OS1)이 형성된다. 또한, 제2 코팅지와 제3 코팅지 간에 오버랩 구간(OS1)이 형성된다. An overlap section OS1 is formed between the first coated paper and the second coated paper. In addition, an overlap section OS1 is formed between the second coated paper and the third coated paper.
즉, 권취파이프로 권취되기 전 제2 코팅지(700)의 상부 코팅층(710)이 제1 코팅지(600)의 하부 코팅층(620)과 마주하도록 배치된 부분이 1차 오버랩 구간(OS1)에 의해 정의될 수 있다. 또한, 권취파이프로 권취되기 전 제3 코팅지(800)의 상부 코팅층(810)이 제2 코팅지(700)의 하부 코팅층(720)과 마주하도록 배치된 부분이 1차 오버랩 구간(OS1)에 의해 정의될 수 있다.That is, the portion in which the
권취파이프로 권취된 이후 코팅지들간 2차 오버랩 구간(OS2)이 다음과 같이 형성된다. After being wound with a winding pipe, a secondary overlap section (OS2) between coated papers is formed as follows.
즉, 권취파이프로 권치된 이후 제2 코팅지(700)의 상부 코팅층(710)이 제1 코팅지(600)의 하부 코팅층(620)과 마주하도록 배치된 부분, 및 제3 코팅지(800)의 상부 코팅층(810)이 제2 코팅지(700)의 하부 코팅층(720)과 마주하도록 배치된 부분이 2차 오버랩 구간(OS2)에 의해 정의될 수 있다. That is, the portion in which the
상술한 바와 같이, 오버랩 구간들(OS1 및 OS2)은 코팅지들(600 내지 800)이 서로 접합될 수 있는 공간을 제공한다. As described above, the overlap sections OS1 and OS2 provide a space in which the coated
이 오버랩 구간들(OS1 및 OS2)에 코팅층의 멜팅템퍼레쳐에 상응하는 열이 가해지면, 기재들 사이에 배치된 코팅층들이 끈적끈적해지면서 별도의 접착제 없이도 서로 접합될 수 있다.When heat corresponding to the melting temper of the coating layer is applied to the overlapping sections OS1 and OS2, the coating layers disposed between the substrates become sticky and can be bonded to each other without a separate adhesive.
한편, 상기에서는 3개의 코팅지들이 모두 양면코팅인 실시예를 중심으로 살펴보았으나, 이에 한정되지 않으며, 이들 중 적어도 하나가 단면코팅인 경우에도 상술한 도 8 내지 도 9에서와 같은 설명이 적용 가능하다. 예를 들어, 제1 코팅지가 단면 코팅으로서, 기재와 상부 코팅층만을 포함할 수 있다. 또는 제3 코팅지가 단면 코팅으로서, 기재와 하부 코팅층만을 포함할 수 있다. On the other hand, in the above, the three coated papers are all double-sided coating, but it is not limited thereto, and even when at least one of them is single-sided coating, the same description as in FIGS. 8 to 9 may be applied. Do. For example, the first coated paper is a single-sided coating, and may include only a substrate and an upper coating layer. Alternatively, the third coated paper is a single-sided coating, and may include only a substrate and a lower coating layer.
또한 상기에서는 3개의 원단들(즉, 최상위 원단, 최하위 원단 및 이들 사이에 원단)이 모두 코팅지인 실시예를 중심으로 살펴보았으나, 이에 한정되지 않으며, 가운데에 배치되는 원단이 코팅층을 포함하지 않은 원지인 경우에도 상술한 도 8 내지 도 9에서와 같은 설명이 적용 가능하다. 가운데 원단의 상부 코팅층을 최상위 원단의 하부 코팅층이 대신할 수 있고, 가운데 원단의 하부 코팅층을 최하위 원단의 상부 코팅층이 대신할 수 있기 때문이다. In addition, in the above, the three fabrics (i.e., the uppermost fabric, the lowermost fabric, and the fabric between them) were all coated on the embodiment, but the present invention is not limited thereto, and the fabric disposed in the center does not include a coating layer. Even in the case of the original paper, the same description as in FIGS. 8 to 9 above can be applied. This is because the upper coating layer of the middle fabric can be replaced by the lower coating layer of the uppermost fabric, and the lower coating layer of the middle fabric can be replaced by the upper coating layer of the lowermost fabric.
이와 같이 본 발명의 실시예에 따르면, 접착제 없이 코팅지만으로 종이 빨대를 제조할 수 있다. 기존에 PLA나 PVAC와 같은 접착제를 사용하지 않아도 되므로 접착제로부터 유래한 인체에 유해한 물질이 고온의 음용수 내에서 녹아나오는 우려가 없다. 또한, 별도의 접착제를 필요로 하지 않으므로, 제조 비용 또한 줄일 수 있는 장점을 갖는다. Thus, according to the embodiment of the present invention, it is possible to manufacture a paper straw with only coating without an adhesive. Since it is not necessary to use existing adhesives such as PLA or PVAC, there is no concern that substances harmful to the human body derived from the adhesive will melt in the hot drinking water. In addition, since it does not require a separate adhesive, it has the advantage of reducing manufacturing cost.
본 발명의 기술 사상은 상기 바람직한 실시예들에 따라 구체적으로 기록되었으나, 상기한 실시예는 그 설명을 위한 것이며 그 제한을 위한 것이 아님을 주의하여야 한다. 또한, 본 발명의 기술 분야의 통상의 전문가라면 본 발명의 기술 사상 범위내에서 다양한 실시예가 가능함을 이해할 수 있을 것이다.Although the technical idea of the present invention has been specifically recorded according to the above preferred embodiments, it should be noted that the above embodiments are for the purpose of explanation and not for the limitation thereof. In addition, those of ordinary skill in the technical field of the present invention will understand that various embodiments are possible within the scope of the technical spirit of the present invention.
[부호의 설명][Explanation of code]
100, 200, 300, 400, 500, 600, 700, 800 : 코팅지100, 200, 300, 400, 500, 600, 700, 800: coated paper
102, 202, 302, 402, 502, 602, 702, 802 : 기재102, 202, 302, 402, 502, 602, 702, 802: description
110, 210, 310, 410, 510, 610, 710, 810 : 상부 코팅층110, 210, 310, 410, 510, 610, 710, 810: upper coating layer
120, 220, 320, 420, 520, 620, 720, 820 : 하부 코팅층120, 220, 320, 420, 520, 620, 720, 820: lower coating layer
ST1, ST2 : 친환경 종이 빨대ST1, ST2: Eco-friendly paper straws
Claims (13)
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| Application Number | Priority Date | Filing Date | Title |
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| KR1020190018790A KR102176032B1 (en) | 2019-02-18 | 2019-02-18 | Method of manufacturing an environmentally friendly paper straw and environmentally friendly paper straw produced thereby |
| KR10-2019-0018790 | 2019-02-18 |
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| WO2020171486A1 true WO2020171486A1 (en) | 2020-08-27 |
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| PCT/KR2020/002130 Ceased WO2020171486A1 (en) | 2019-02-18 | 2020-02-14 | Method for manufacturing eco-friendly paper straw and eco-friendly paper straw manufactured thereby |
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| WO (1) | WO2020171486A1 (en) |
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| CN113152147A (en) * | 2021-04-22 | 2021-07-23 | 叶子包装(美国)有限公司 | Environment-friendly straw paper, preparation method thereof and paper straw processing technology |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR102259702B1 (en) * | 2020-11-11 | 2021-06-02 | (주)태양아이엔티 | Manufacturing method of eco-friendly sheets used wood for straw and eco-friendly straw |
| CN113829452B (en) * | 2020-12-17 | 2023-04-14 | 龙竹科技集团股份有限公司 | Bamboo straw processing method |
| KR102416131B1 (en) * | 2022-02-09 | 2022-07-01 | 황복남 | The manufacturing method of eco-friendly paper cups |
| KR102669284B1 (en) | 2023-07-27 | 2024-06-20 | 윤지환 | Intelligent paper straw manufacturing facility and paper straw manufacturing method using the same |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06133840A (en) * | 1992-10-26 | 1994-05-17 | Shigeru Nakagawa | Paper tube |
| JP2004210884A (en) * | 2002-12-27 | 2004-07-29 | Konishi Co Ltd | Aqueous adhesive composition |
| US20060169791A1 (en) * | 2005-01-31 | 2006-08-03 | Taylor Eve F | Sip straw with consumable component |
| JP3216663U (en) * | 2018-04-03 | 2018-06-14 | ▲ユ▼▲ティン▼ 許 | Drinking paper straws |
| KR20180089880A (en) * | 2018-07-22 | 2018-08-09 | 서규선 | Length Adjustable Paper Straw |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3203964B2 (en) * | 1994-07-18 | 2001-09-04 | ダイキン工業株式会社 | Pipe manufacturing method and pipe manufacturing apparatus |
-
2019
- 2019-02-18 KR KR1020190018790A patent/KR102176032B1/en active Active
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2020
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06133840A (en) * | 1992-10-26 | 1994-05-17 | Shigeru Nakagawa | Paper tube |
| JP2004210884A (en) * | 2002-12-27 | 2004-07-29 | Konishi Co Ltd | Aqueous adhesive composition |
| US20060169791A1 (en) * | 2005-01-31 | 2006-08-03 | Taylor Eve F | Sip straw with consumable component |
| JP3216663U (en) * | 2018-04-03 | 2018-06-14 | ▲ユ▼▲ティン▼ 許 | Drinking paper straws |
| KR20180089880A (en) * | 2018-07-22 | 2018-08-09 | 서규선 | Length Adjustable Paper Straw |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113152147A (en) * | 2021-04-22 | 2021-07-23 | 叶子包装(美国)有限公司 | Environment-friendly straw paper, preparation method thereof and paper straw processing technology |
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| KR20200100465A (en) | 2020-08-26 |
| KR102176032B1 (en) | 2020-11-06 |
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