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WO2020158823A1 - H-shaped steel having protrusions, and manufacturing method for same - Google Patents

H-shaped steel having protrusions, and manufacturing method for same Download PDF

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Publication number
WO2020158823A1
WO2020158823A1 PCT/JP2020/003257 JP2020003257W WO2020158823A1 WO 2020158823 A1 WO2020158823 A1 WO 2020158823A1 JP 2020003257 W JP2020003257 W JP 2020003257W WO 2020158823 A1 WO2020158823 A1 WO 2020158823A1
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Prior art keywords
mass
less
steel
protrusions
content
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Ceased
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PCT/JP2020/003257
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French (fr)
Japanese (ja)
Inventor
佳祐 安藤
木村 達己
聡 伊木
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JFE Steel Corp
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JFE Steel Corp
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Priority to KR1020217027440A priority Critical patent/KR102602081B1/en
Priority to CN202080011533.3A priority patent/CN113396236B/en
Priority to JP2020533323A priority patent/JP6819830B2/en
Priority to SG11202108195WA priority patent/SG11202108195WA/en
Publication of WO2020158823A1 publication Critical patent/WO2020158823A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/08Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese

Definitions

  • the present invention relates to a H-section steel with protrusions and a method for manufacturing the same, and in addition to being excellent in mechanical properties such as tensile strength and elongation, which is a substitute for a reinforcing bar used as a reinforcing material for a large structure such as a bridge pier, it has excellent toughness. Also relates to a H-shaped steel with protrusions and a method for manufacturing the same.
  • reinforced concrete using reinforcing bars is widely used as a reinforcing material.
  • the construction of a reinforced concrete structure is performed by assembling the reinforcing bars, installing a formwork, and placing concrete in the formwork.
  • the reinforcing bars densely in terms of strength
  • the construction quality is deteriorated, but also the construction is prolonged, which is a major problem.
  • the number of skilled workers engaged in the construction is declining year by year, and there is a further demand for the development of structural steel that contributes to labor saving on site work and shortening the construction period.
  • H-section steel with a protrusion that has a greater cross-sectional rigidity than rebar and can reduce the number of necessary members in the same structure. It is known that this H-section steel with a projection has a projection on the outer surface of the flange and has a high concrete adhesion performance equal to or higher than that of a reinforcing bar. In order to guarantee the performance as a structure, the H-section steel with protrusions used for a large structure as a substitute for a reinforcing bar is required to have toughness in addition to mechanical properties such as tensile strength and elongation.
  • Patent Document 1 discloses a H-section steel with protrusions in which tensile strength and toughness are enhanced in a well-balanced manner by adjusting the addition amounts of Nb, V and Ni in the steel.
  • Patent Document 2 for the purpose of improving the toughness of the H-shaped steel with protrusions, there is a technique of setting an optimum cooling stop temperature according to the flange thickness and appropriately adjusting the amount of cooling water on the inner and outer surfaces of the flange. It is disclosed.
  • the H-section steel with protrusions described in Patent Documents 1 and 2 described above has both high tensile strength and toughness by adding Nb and V that form carbonitride, but it is a rolled material by continuous casting.
  • the present invention has been made in order to advantageously solve the above-mentioned problems.
  • the H-section with a projection that can dramatically improve the productivity while ensuring a tensile strength equal to or higher than that of the conventional H-section steel with a projection. It is an object to provide a shaped steel together with its manufacturing method.
  • the present inventors have made H-shaped steel with protrusions in which the contents of C, Si, Mn, P, S, Nb, V, Ti and N are changed, and have made earnest investigations on tensile properties and toughness. As a result, it was found that the rate of continuous casting cracking was high when Nb or V was contained in the steel. Furthermore, by optimizing the amounts of S, Ti, and N contained in the steel, continuous casting cracks can be stabilized and suppressed even when Nb and V are contained. It has been found that by promoting the ferrite transformation, excellent toughness can be obtained.
  • the present invention is based on the above findings of the present invention, and its gist is as follows.
  • 1. C: 0.05 to 0.20 mass%, Si: 0.05 to 0.60 mass%, Mn: 1.20 to 1.70 mass%, P: 0.035 mass% or less, S: 0.035 mass% or less, Nb: 0.005 to 0.050 mass%, V: 0.005 to 0.050% by mass, Ti: 0.005 to 0.030% by mass, and N: 0.0020 to 0.0100% by mass are contained within the range satisfying the following formula (1), and the balance has a steel composition of Fe and unavoidable impurities, and has a tensile strength.
  • H-shaped steel with protrusions having a strength of 490 MPa or more, a yield strength of 355 MPa or more, and an impact absorption energy vE0 of 27 J or more at 0°C.
  • [%S], [%Ti] and [%N] are the contents (mass %) of S, Ti and N in the steel, respectively.
  • the steel composition further comprises Cr: 1.0 mass% or less, Cu: 1.0 mass% or less, Ni: 1.0 mass% or less, Mo: 1.0 mass% or less, Al: 0.10 mass% or less, B: 0.010 mass% or less, Ca.
  • a method for producing a H-section steel with protrusions comprising hot rolling a steel material having the steel composition according to any one of 1 or 2 above to form H-section steel with protrusions, After the finish rolling of the hot rolling, protrusions are formed on the outer surface of the flange of the H-shaped steel, and after the finish rolling, the average cooling rate from the cooling start temperature of 750°C or higher to 500°C: 0.1 to 30°C/s.
  • a method for manufacturing an H-section steel with protrusions which is cooled under the conditions of.
  • the sectional view of H-section steel with a projection is shown. It is a figure which shows H-section steel with a protrusion, (a) is the side view seen from the opposing direction of a web, (b) is the top view seen from the opposing direction of a flange outer surface, (c) is the upper surface of a flange outer surface. The figures are respectively shown.
  • C 0.05 to 0.20% C is an element necessary to secure the strength of the base material and needs to be contained at least 0.05%. However, if the C content exceeds 0.20%, not only the toughness of the base material is lowered but also the weldability is lowered. Therefore, in the present invention, the C content is set to 0.05 to 0.20%.
  • the C content is preferably 0.10% or more. Further, the C content is preferably 0.15% or less.
  • Si 0.05 to 0.60% Si must be contained in the base metal at a strength of 0.05% or more as a deoxidizing agent, but if the Si content exceeds 0.60%, the toughness decreases and the high bond strength of Si with oxygen is high. Therefore, the weldability deteriorates. Therefore, in the present invention, the Si content is set to 0.05 to 0.60%.
  • the Si content is preferably 0.20% or more. Further, the Si content is preferably 0.40% or less.
  • Mn 1.20 ⁇ 1.70%
  • Mn is a relatively inexpensive element that has the effect of increasing the strength of steel, so it is an important element for increasing strength.
  • the Mn content is set to 1.20 to 1.70%.
  • the Mn content is preferably 1.40% or more. Further, the Mn content is preferably 1.60% or less.
  • the amount of P in steel is 0.035% or less. It is preferably 0.020% or less.
  • P is usually an element that is unavoidably contained in steel as an impurity, and excessive reduction in P causes an increase in refining time and an increase in cost, so the P content should be 0.005% or more. preferable.
  • S 0.035% or less
  • the S content in steel is 0.035% or less. It is preferably 0.020% or less.
  • the smaller the amount of S the more preferable. Therefore, the lower limit of the S content is not particularly limited and may be 0%.
  • S is an element that is unavoidably contained in steel as an impurity, and excessive reduction of S causes increase in refining time and cost, so the S content should be 0.002% or more. preferable.
  • Nb 0.005 to 0.050%
  • Nb is an element having the effect of improving tensile strength and yield point by precipitating as carbonitride. To obtain this effect, the Nb content needs to be 0.005% or more.
  • the Nb content is 0.005 to 0.050%.
  • the Nb content is preferably 0.010% or more. Further, the Nb content is preferably 0.030% or less.
  • V 0.005 to 0.050%
  • V is an element having the effect of improving tensile strength and yield point by precipitating as carbonitride. In order to obtain this effect, the V content needs to be 0.005% or more. On the other hand, when the V content exceeds 0.050%, precipitation embrittlement is promoted, and continuous casting cracks are likely to occur. Therefore, in the present invention, the V content is set to 0.005 to 0.050%.
  • the V content is preferably 0.010% or more. Further, the V content is preferably 0.030% or less.
  • Ti 0.005-0.030%
  • Ti is a useful element effective in preventing surface cracking during bending-unbending during continuous casting, and is positively added in the range of 0.005% or more. Further, Ti is an element effective in improving the toughness by forming TiN in the steel to refine the austenite grains and further promoting the intragranular ferrite transformation centered on TiN to refine the microstructure. On the other hand, if the Ti content exceeds 0.030%, coarse TiN is generated and the toughness of the steel is reduced, which is not preferable. Therefore, in the present invention, the Ti content is 0.005 to 0.030%. The Ti content is preferably 0.010% or more. Further, the Ti content is preferably 0.020% or less.
  • N 0.0020-0.0100%
  • N is a useful element that forms carbonitrides in steel and improves the strength of steel, and its content must be 0.0020% or more.
  • the N content exceeds 0.0100%, the carbonitrides formed become coarse and the toughness of the steel decreases. Further, when the N content exceeds 0.0100%, surface cracking of the cast piece occurs, and the cast piece quality deteriorates, which is not preferable. Therefore, in the present invention, the N content is set to 0.0020 to 0.0100%.
  • the N content is preferably 0.0030% or more. Further, the N content is preferably 0.0070% or less.
  • the value calculated by the left side of the above equation (1) which is a parameter based on the contents of S, Ti, and N, does not exceed 15.0, so that S is precipitated as Ti carbosulfide and N is precipitated as TiN.
  • the right side of the above formula (1) is 10.0 or less, that is, the following formula (1)′ is satisfied.
  • the balance other than the components described above is Fe and inevitable impurities.
  • Cr 1.0% or less
  • Cu 1.0% or less
  • Ni 1.0% or less for the purpose of improving strength, ductility, toughness, and weld property.
  • Mo 1.0% or less
  • Al 0.10% or less
  • B 0.010% or less
  • Ca 0.10% or less
  • Mg 0.10% or less
  • REM 0.10% or less. It may optionally contain.
  • Cr 1.0% or less Cr is an element that can further strengthen the steel by solid solution strengthening. However, if its content exceeds 1.0%, the upper bainite transformation is promoted and the toughness is lowered, which is not preferable. Therefore, when the chemical composition of steel contains Cr, the Cr content is 1.0% or less. It is more preferably 0.005% or more and 0.5% or less.
  • Cu 1.0% or less
  • Cu is an element that can further strengthen the steel by solid solution strengthening. However, if the content exceeds 1.0%, Cu cracking tends to occur. Therefore, if the composition of the steel contains Cu, the Cu content should be 1.0% or less. It is more preferably 0.005% or more and 0.5% or less.
  • Ni 1.0% or less
  • Ni is an element that can increase the strength of steel without deteriorating ductility.
  • Cu cracking can be suppressed by adding Cu together, it is desirable that Ni is also contained when the steel composition contains Cu.
  • the Ni content exceeds 1.0%, the hardenability of steel further increases and the toughness tends to decrease. Therefore, when the steel composition contains Ni, the Ni content is 1.0% or less. It is more preferably 0.005% or more and 0.5% or less.
  • Mo 1.0% or less Mo is an element that can further strengthen the steel by solid solution strengthening. However, if the content exceeds 1.0%, a large amount of upper bainite is generated in the steel, and the toughness tends to decrease. Therefore, when the component composition contains Mo, the Mo content is 1.0% or less. It is more preferably 0.005% or more and 0.5% or less.
  • Al 0.10% or less
  • Al is an element that can be added as a deoxidizing agent.
  • the Al content is preferably 0.10% or less.
  • the lower limit of the Al content is not particularly limited, but it is preferably 0.001% or more for deoxidation. More preferably, it is 0.001% or more and 0.03% or less.
  • B 0.010% or less
  • B is an element having the effect of segregating to the grain boundaries in steel and improving the grain boundary strength. It is also an element effective for improving toughness by forming a composite precipitate with TiN, which becomes the nucleation site of intragranular ferrite, and refining the microstructure.
  • the toughness decreases due to the precipitation of coarse carbonitrides at the grain boundaries. Therefore, when the steel composition contains B, the B content is 0.010% or less. It is more preferably 0.001% or more and 0.003% or less.
  • Ca 0.10% or less
  • Ca has a function of converting the oxides and sulfides in the sulfide-based inclusions into those having high stability at high temperatures, and granulating the sulfide-based inclusions.
  • the toughness and ductility of the steel can be improved by the effect of Ca to control the morphology of inclusions.
  • the Ca content exceeds 0.10%, the cleanliness tends to decrease and the toughness tends to decrease. Therefore, when the steel composition contains Ca, the Ca content is 0.10% or less. It is more preferably 0.0010% or more and 0.0050% or less.
  • Mg 0.10% or less
  • Mg has the function of transforming the oxides and sulfides in the sulfide-based inclusions into those having high stability at high temperatures and granulating them. Then, the toughness and ductility of the steel can be improved by the effect of controlling the morphology of inclusions by this Mg. However, if the Mg content exceeds 0.10%, the cleanliness tends to decrease and the toughness tends to decrease. Therefore, when the steel composition contains Mg, the Mg content is 0.10% or less. It is more preferably 0.0010% or more and 0.0050% or less.
  • REM 0.10% or less REM (rare earth metal) has the effect of transforming oxides and sulfides in sulfide-based inclusions into those with high stability at high temperatures, and granulating sulfide-based inclusions. .. Then, the toughness and ductility of the steel can be improved by the effect of controlling the morphology of inclusions by the REM. However, if the REM content exceeds 0.10%, the cleanliness tends to decrease and the toughness tends to decrease. Therefore, if the steel composition contains REM, the REM content should be 0.10% or less. It is more preferably 0.0010% or more and 0.0050% or less. The balance other than the elements described above is Fe and inevitable impurities.
  • the H-section steel with protrusions of the present invention will be described in detail. That is, as shown in FIG. 1, the H-section steel with protrusions is formed by connecting a pair of flanges 2 with a web 3 similarly to a general H-section steel.
  • the H-section steel with protrusions has protrusions 4 on the outer surface of the flange 2.
  • the projections 4 are provided to give concrete adhesion performance.
  • the location where the projection 4 is provided is the outer surface of the flange 2 as shown in FIG. In the illustrated example, the entire outer surface of the flange 2 is an enlarged view of a portion surrounded by a square in FIG. 2A.
  • the protrusions 4 are formed so as to be arranged in the longitudinal direction of the flange 2.
  • the shape, size, and number of protrusions can be set arbitrarily according to the specifications required for H-section steel with protrusions. Therefore, although not limited to the illustrated example, for example, the height h of the projection 4 is preferably 1.5 mm or more in consideration of the concrete adhesion performance. On the other hand, the upper limit of the height h is preferably 6 mm from the viewpoint of preventing roll breakage. Further, the distance d between the protrusions 4 preferably satisfies the relationship of h/d ⁇ 0.05 with the height h in consideration of the concrete adhesion performance.
  • the hot rolling conditions for forming the H-shaped steel are not particularly limited and may be carried out according to a conventional method.
  • the protrusion can be formed by using a roll having a groove corresponding to the protrusion to be formed on the surface of the roll as a roll for rolling down the portion (flange outer surface) where the protrusion is formed. After finish rolling, it is necessary to perform cooling satisfying the following conditions.
  • Flange temperature at the start of cooling 750°C or higher
  • the flange temperature at the start of cooling is set to 750°C or higher in order to prevent a decrease in production efficiency by starting cooling of the steel material immediately after finish rolling. To do.
  • the flange temperature at the start of cooling is less than the Ar 3 temperature, it becomes difficult to obtain sufficient strength, so it is preferable to further set the flange temperature at the start of cooling to the Ar 3 temperature or higher.
  • the Ar 3 transformation temperature is simply shown in relation to the steel composition by the following equation (2), for example.
  • Ar 3 910-310 ⁇ [%C]+25 ⁇ ([%Si]+2 ⁇ [%Al])-80 ⁇ [Mneq] ⁇ (2)
  • [Mneq] is a value calculated by the following equation (3).
  • [Mneq] [%Mn]+[%Cr]+[%Cu]+[%Mo]+[%Ni]/2+10 ⁇ ([%Nb]-0.02) ⁇ (3)
  • [%M] means the content (mass %) of the element M in the steel.
  • the content of the element M contained as an unavoidable impurity It should be calculated using the analysis value).
  • Average cooling rate from cooling start temperature to 500°C 0.1 ⁇ 30°C/s If the average cooling rate from the cooling start temperature to 500°C is less than 0.1°C/s, it is difficult to secure the predetermined tensile properties and toughness, so the cooling rate is 0.1°C/s or more. On the other hand, when the cooling rate becomes higher than 30°C/s, adverse effects such as decrease in toughness and excessive increase in tensile strength occur due to the formation of bainite or martensite.
  • the cooling rate is in the range of 0.1 to 30°C/s.
  • the preferable average cooling rate is in the range of 0.5 to 10°C/s.
  • the H-shaped steel with projections has a tensile strength of 490 MPa or more, a yield strength of 355 MPa or more, and an impact absorption energy vE0 of 27 J at 0°C.
  • excellent mechanical performance can be obtained.
  • the tensile strength is 640 MPa
  • the yield strength is 475 MPa
  • the impact absorption energy vE0 at 0° C. is about 350 J.
  • the flange thickness of the H-section steel with protrusions that is the subject of the present invention is not particularly limited.
  • the protrusion on the outer surface of the flange is formed by using a grooved roll in the finish rolling process. That is, it is necessary to increase the amount of reduction of the flange portion as much as possible in order to give a desired protrusion height. Therefore, a protruding H-section steel with a thick flange requires greater reduction.
  • the present invention by controlling the rolling temperature within an appropriate range, it is said that the formation efficiency of the projection height is lowered. Even in the case of a thick H-section steel with a flange thickness of 16 mm or more, a sufficient projection height can be obtained. Can be granted.
  • the finish rolling temperature is preferably 800°C or higher from the viewpoint of forming protrusions having a sufficient protrusion height. If the finishing rolling temperature is less than 800°C, it is difficult to stably form protrusions of sufficient height.
  • the upper limit of the finishing temperature is not particularly limited, but if it exceeds 1050° C., the austenite grain size becomes coarse and the toughness tends to decrease. Therefore, the finishing temperature is preferably 1050° C. or lower.
  • a steel blank having the composition shown in Table 1 was used as a beam blank having a cross section of 400 mm ⁇ 560 mm ⁇ length of 8000 mm by a continuous casting machine, and the presence or absence of cracks on the surface was examined. That is, the surface of the beam blank was observed in the longitudinal direction and examined for cracks having a length of 10 mm or more. Surface cracks obtains the number of cracks per 1 m 2, A: no cracks, B: 1 ⁇ 4 pieces / m 2, C: evaluated using an index of 5 or more / m 2, A or B in the index Those judged were accepted. Table 1 also shows the results of surface crack determination. In the steel having a steel composition satisfying the above formula (1), the surface cracking judgment result was A or B.
  • a H-section steel 1 with a protrusion having a cross-sectional shape that is, a shape having a web 3 and a pair of flanges 2 arranged at both ends of the web was manufactured.
  • the cross-sectional dimension is one of two types of 320 x 323 x 25 x 25 mm and 350 x 333 x 35 x 40 mm.
  • a rolling roll having a groove corresponding to the projection shape to be formed on the flange outer surface is used as a rolling roll for rolling down the flange outer surface, and the flange outer surface extends in the width direction of the flange 2 as shown in FIG.
  • the existing projections 6 were formed.
  • the finish rolling roll that rolls down the outer surface of the flange is provided with a groove capable of forming a protrusion having a protrusion width w of 15 mm and a protrusion height h of 1.5 mm or more.
  • the cooling rate after finish rolling is measured by measuring the temperature of the outer surface of the flange with a radiation thermometer and converting the temperature change from the start of cooling to the end of cooling per unit time (seconds) to obtain the cooling rate (°C/ s) was calculated.
  • the obtained H-section steel with protrusions was subjected to protrusion height evaluation, tensile test and toughness test. The details of each evaluation will be described below in detail.
  • the protrusion height h on the outer surface of the flange shown in FIG. 2 was measured. Such a value was measured at three points in the rolling direction of the H-section steel with protrusions after finish rolling in the rolling direction, the center portion and the tail end portion, and the average value was adopted.
  • the lower limit of the required performance of the protrusion height was set to 1.5 mm, and a value above this value was defined as a suitable range of the protrusion height h.
  • the manufacturing conditions under which the H-shaped steel with protrusions having the protrusion height h of not less than this value are obtained can be evaluated as particularly preferable conditions from the viewpoint of ease of forming the protrusions.
  • Table 2 also shows the results of the above survey.
  • Test results of the H-section steel with protrusions produced by the manufacturing method within the scope of the present invention (the average cooling rate of the outer surface of the flange is within the scope of the present invention) using a compatible steel satisfying the steel composition of the present invention (test No. in Table 2). .1 to 19, 31) all satisfied the desired properties (tensile strength: 490 MPa or more, yield strength: 355 MPa or more and impact absorption energy vE0: 27 J or more at 0° C.).
  • the protrusion height was 1.4 mm, which was less than the preferred range (1.5 mm or more).

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Abstract

Provided are an H-shaped steel having protrusions and a production method for same, the H-shaped steel ensuring tensile strength, being capable of suppressing the occurrence of surface cracking during continuous casting, and having dramatically improved manufacturability. A steel composition in which C: 0.05-0.20 mass%, Si: 0.05-0.60 mass%, Mn: 1.20-1.70 mass%, P: 0.035 mass% or less, S: 0.035 mass% or less, Nb: 0.005-0.050 mass%, V: 0.005-0.050 mass%, Ti: 0.005-0.030 mass% and N: 0.0020-0.0100 mass% are included in a range satisfying ([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≤15.0, the remainder being Fe and unavoidable impurities, the tensile strength being at least 490 MPa, the yield strength being at least 355 MPa, and the impact absorption energy vE0 at O°C being at least 27J.

Description

突起付きH形鋼およびその製造方法H-section steel with protrusion and method for manufacturing the same

 本発明は、突起付きH形鋼およびその製造方法に関し、橋脚等の大型構造物の補強材として用いられている鉄筋の代替となる、引張強度および伸びといった機械特性に優れることに加え、靭性にも優れた、突起付きH形鋼およびその製造方法に関する。 The present invention relates to a H-section steel with protrusions and a method for manufacturing the same, and in addition to being excellent in mechanical properties such as tensile strength and elongation, which is a substitute for a reinforcing bar used as a reinforcing material for a large structure such as a bridge pier, it has excellent toughness. Also relates to a H-shaped steel with protrusions and a method for manufacturing the same.

 橋脚等の大型構造物では、補強材として鉄筋を用いた鉄筋コンクリートが幅広く使用されている。一般的に鉄筋コンクリート構造物の工事は、鉄筋を組み立てた後に型枠を設置し、型枠内にコンクリートを打設することにより行われる。ここで、強度的に鉄筋の過密配設が必要となる場合、コンクリートの充填性が低下し、施工品質が悪化するだけでなく、工事が長期化する点が大きな課題となっている。加えて、当該工事に従事する技能労働者の数は年々減少傾向にあり、現場作業の省力化ならびに工期短縮に寄与する構造用鋼の開発がより一層求められている。  For large structures such as bridge piers, reinforced concrete using reinforcing bars is widely used as a reinforcing material. Generally, the construction of a reinforced concrete structure is performed by assembling the reinforcing bars, installing a formwork, and placing concrete in the formwork. Here, when it is necessary to dispose the reinforcing bars densely in terms of strength, not only the filling property of concrete is deteriorated, the construction quality is deteriorated, but also the construction is prolonged, which is a major problem. In addition, the number of skilled workers engaged in the construction is declining year by year, and there is a further demand for the development of structural steel that contributes to labor saving on site work and shortening the construction period.

 そのような要請を受け、鉄筋に比べて大きな断面剛性を有し、同一構造において必要な部材本数を減らすことが可能となる突起付きH形鋼に関して、様々な研究がおこなわれている。この突起付きH形鋼は、フランジ外面に突起が設けられており、鉄筋と同等以上の高いコンクリート付着性能を有することが知られている。鉄筋代替として大型構造物に使用される突起付きH形鋼に対しては、構造体としての性能を保証するため、引張強度、伸びといった機械特性に加えて、靭性の保証が要求されている。 In response to such a request, various studies have been conducted on H-section steel with a protrusion that has a greater cross-sectional rigidity than rebar and can reduce the number of necessary members in the same structure. It is known that this H-section steel with a projection has a projection on the outer surface of the flange and has a high concrete adhesion performance equal to or higher than that of a reinforcing bar. In order to guarantee the performance as a structure, the H-section steel with protrusions used for a large structure as a substitute for a reinforcing bar is required to have toughness in addition to mechanical properties such as tensile strength and elongation.

 これらの要求を満足するため、たとえば特許文献1には、鋼中のNb、VおよびNiの添加量を調整することで、引張強度と靭性をバランスよく高めた突起付きH形鋼が開示されている。また、特許文献2には、突起付きH形鋼の靭性を向上することを目的として、フランジ厚に応じて最適な冷却停止温度を設定すると共に、フランジ内外面の冷却水量を適宜調整する技術が開示されている。 In order to satisfy these requirements, for example, Patent Document 1 discloses a H-section steel with protrusions in which tensile strength and toughness are enhanced in a well-balanced manner by adjusting the addition amounts of Nb, V and Ni in the steel. There is. Further, in Patent Document 2, for the purpose of improving the toughness of the H-shaped steel with protrusions, there is a technique of setting an optimum cooling stop temperature according to the flange thickness and appropriately adjusting the amount of cooling water on the inner and outer surfaces of the flange. It is disclosed.

特許4045977号公報Japanese Patent No. 4045977 特開2006-75883号公報JP 2006-75883

 しかしながら、上述した特許文献1、2に記載の突起付きH形鋼は、炭窒化物を形成するNbやVを添加して高い引張強度と靭性の両立を図っているが、連続鋳造により圧延素材を製造する際に、連鋳割れと呼ばれる鋳片表面の欠陥が生じやすく、製造性を低下させるという問題があった。本発明は、上述した問題を有利に解決すべくなされたもので、従来の突起付きH形鋼に比べ、同等以上の引張強度を確保しつつ、製造性を飛躍的に向上し得る突起付きH形鋼をその製造方法と共に提供することを目的とする。 However, the H-section steel with protrusions described in Patent Documents 1 and 2 described above has both high tensile strength and toughness by adding Nb and V that form carbonitride, but it is a rolled material by continuous casting. When manufacturing the steel, there is a problem that defects on the surface of the slab called so-called continuous casting cracks are likely to occur and the manufacturability is reduced. The present invention has been made in order to advantageously solve the above-mentioned problems. As compared with the conventional H-section steel with a projection, the H-section with a projection that can dramatically improve the productivity while ensuring a tensile strength equal to or higher than that of the conventional H-section steel with a projection. It is an object to provide a shaped steel together with its manufacturing method.

 本発明者らは、C、Si、Mn、P、S、Nb、V、TiおよびNの含有量を変化させた突起付きH形鋼を作製し、引張特性および靭性を鋭意調査した。その結果、鋼中にNbやVを含有されている場合、連鋳割れの発生する率が高いことがわかった。さらに、鋼中に含まれるS、Ti、N量を適正化することで、NbおよびVが含まれる場合であっても連鋳割れを安定化して抑制でき、さらに、TiNを核とした粒内フェライト変態の促進により、優れた靭性が得られることを見出した。 The present inventors have made H-shaped steel with protrusions in which the contents of C, Si, Mn, P, S, Nb, V, Ti and N are changed, and have made earnest investigations on tensile properties and toughness. As a result, it was found that the rate of continuous casting cracking was high when Nb or V was contained in the steel. Furthermore, by optimizing the amounts of S, Ti, and N contained in the steel, continuous casting cracks can be stabilized and suppressed even when Nb and V are contained. It has been found that by promoting the ferrite transformation, excellent toughness can be obtained.

 本発明の、上記の知見に立脚するものであり、その要旨構成は次の通りである。
1.C:0.05~0.20質量%、Si:0.05~0.60質量%、Mn:1.20~1.70質量%、P:0.035質量%以下、S: 0.035質量%以下、Nb:0.005~0.050質量%、V:0.005~0.050質量%、Ti:0.005~0.030質量%およびN:0.0020~0.0100質量%を、下記(1)式を満足する範囲で含有し、残部がFeおよび不可避的不純物の鋼組成を有し、引張強さが490MPa以上、降伏強度が355MPa以上、かつ0℃における衝撃吸収エネルギーvE0が27J以上である、突起付きH形鋼。
                 記
 ([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≦15.0 ・・・(1)
  ここで、[%S]、[%Ti]および[%N]はそれぞれ、鋼中のS,TiおよびNの含有量(質量%)である。
The present invention is based on the above findings of the present invention, and its gist is as follows.
1. C: 0.05 to 0.20 mass%, Si: 0.05 to 0.60 mass%, Mn: 1.20 to 1.70 mass%, P: 0.035 mass% or less, S: 0.035 mass% or less, Nb: 0.005 to 0.050 mass%, V: 0.005 to 0.050% by mass, Ti: 0.005 to 0.030% by mass, and N: 0.0020 to 0.0100% by mass are contained within the range satisfying the following formula (1), and the balance has a steel composition of Fe and unavoidable impurities, and has a tensile strength. H-shaped steel with protrusions having a strength of 490 MPa or more, a yield strength of 355 MPa or more, and an impact absorption energy vE0 of 27 J or more at 0°C.
Note ([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≦15.0 ・・・(1)
Here, [%S], [%Ti] and [%N] are the contents (mass %) of S, Ti and N in the steel, respectively.

2.前記鋼組成は、さらに、Cr:1.0質量%以下、Cu:1.0質量%以下、Ni:1.0質量%以下、Mo:1.0質量%以下、Al:0.10質量%以下、B:0.010質量%以下、Ca:0.10質量%以下、Mg:0.10質量%以下およびREM:0.10質量%以下の中から選ばれる1種または2種以上を含有する上記1記載の突起付きH形鋼。 2. The steel composition further comprises Cr: 1.0 mass% or less, Cu: 1.0 mass% or less, Ni: 1.0 mass% or less, Mo: 1.0 mass% or less, Al: 0.10 mass% or less, B: 0.010 mass% or less, Ca. The protrusion H-shaped steel according to the above 1, containing one or more selected from the group consisting of: 0.10 mass% or less, Mg: 0.10 mass% or less, and REM: 0.10 mass% or less.

3.前記突起は、高さが1.5mm以上である上記1または2に記載の突起付きH形鋼。 3. The H-shaped steel with a protrusion according to 1 or 2 above, wherein the protrusion has a height of 1.5 mm or more.

4.上記1または2のいずれかに記載の鋼組成を有する鋼素材に、熱間圧延を施して突起付きH形鋼を成形する突起付きH形鋼の製造方法であって、
 前記熱間圧延の仕上圧延によりH形鋼のフランジ外面に突起を形成し、該仕上圧延の後に、750℃以上の冷却開始温度から500℃までの間を平均冷却速度:0.1~30℃/sの条件で冷却する突起付きH形鋼の製造方法。
4. A method for producing a H-section steel with protrusions, comprising hot rolling a steel material having the steel composition according to any one of 1 or 2 above to form H-section steel with protrusions,
After the finish rolling of the hot rolling, protrusions are formed on the outer surface of the flange of the H-shaped steel, and after the finish rolling, the average cooling rate from the cooling start temperature of 750°C or higher to 500°C: 0.1 to 30°C/s. A method for manufacturing an H-section steel with protrusions, which is cooled under the conditions of.

5.前記仕上圧延を800℃以上の温度で行う上記4に記載の突起付きH形鋼の製造方法。 5. 5. The method for producing a H-section steel with protrusions according to 4 above, wherein the finish rolling is performed at a temperature of 800° C. or higher.

 本発明によれば、優れた靭性を有する突起付きH形鋼を安定して製造することが可能となり、大型構造物の急速施工実現やコンクリート施工品の品質向上に寄与し、産業上有益な効果がもたらされる。 ADVANTAGE OF THE INVENTION According to this invention, it becomes possible to manufacture the H-section steel with a protrusion which has the outstanding toughness stably, it contributes to the rapid construction realization of a large-scale structure, and the quality improvement of a concrete construction product, and an industrially beneficial effect. Is brought about.

突起付きH形鋼の断面図を示す。The sectional view of H-section steel with a projection is shown. 突起付きH形鋼を示す図であり、(a)はウェブの対向方向から見た側面図を、(b)はフランジ外面の対向方向から見た平面図を、(c)はフランジ外面の上面図を、それぞれ示す。It is a figure which shows H-section steel with a protrusion, (a) is the side view seen from the opposing direction of a web, (b) is the top view seen from the opposing direction of a flange outer surface, (c) is the upper surface of a flange outer surface. The figures are respectively shown.

 以下、本発明を具体的に説明する。まず、本発明において、鋼組成を上記の範囲に限定した理由について説明する。なお、以下の説明における「%」は、特に断らない限り「質量%」を表すものとする。 The present invention will be specifically described below. First, in the present invention, the reason why the steel composition is limited to the above range will be described. In addition, "%" in the following description represents "mass %" unless otherwise specified.

C:0.05~0.20%
 Cは、母材強度を確保するために必要な元素であり、少なくとも0.05%含有されていることを必要とする。しかし、C含有量が0.20%を超えると、母材靭性を低下させるばかりか、溶接性を低下させる。そのため、本発明ではC含有量を0.05~0.20%とする。なお、C含有量は0.10%以上とすることが好ましい。また、C含有量は0.15%以下とすることが好ましい。
C: 0.05 to 0.20%
C is an element necessary to secure the strength of the base material and needs to be contained at least 0.05%. However, if the C content exceeds 0.20%, not only the toughness of the base material is lowered but also the weldability is lowered. Therefore, in the present invention, the C content is set to 0.05 to 0.20%. The C content is preferably 0.10% or more. Further, the C content is preferably 0.15% or less.

Si:0.05~0.60%
 Siは、母材強度の確保および脱酸剤として0.05%以上で含有される必要があるが、Si含有量が0.60%を超えると靭性の低下に加え、Siの有する高い酸素との結合力のため、溶接性が劣化する。そのため、本発明ではSi含有量を0.05~0.60%とする。なお、Si含有量は0.20%以上とすることが好ましい。また、Si含有量は0.40%以下とすることが好ましい。
Si: 0.05 to 0.60%
Si must be contained in the base metal at a strength of 0.05% or more as a deoxidizing agent, but if the Si content exceeds 0.60%, the toughness decreases and the high bond strength of Si with oxygen is high. Therefore, the weldability deteriorates. Therefore, in the present invention, the Si content is set to 0.05 to 0.60%. The Si content is preferably 0.20% or more. Further, the Si content is preferably 0.40% or less.

Mn:1.20~1.70%
 Mnは、Siと同様、鋼の強度を高める効果のある比較的安価な元素であるため、高強度化には重要な元素である。しかし、Mn含有量が1.20%未満では、その添加効果は小さく、一方、1.70%を超えると、上部ベイナイト変態を促進させ、靭性を低下させるので好ましくない。そのため、本発明ではMn含有量を1.20~1.70%とする。なお、Mn含有量は1.40%以上とすることが好ましい。また、Mn含有量は1.60%以下とすることが好ましい。
Mn: 1.20 ~ 1.70%
Like Si, Mn is a relatively inexpensive element that has the effect of increasing the strength of steel, so it is an important element for increasing strength. However, if the Mn content is less than 1.20%, the effect of addition is small, while if it exceeds 1.70%, the upper bainite transformation is promoted and the toughness is lowered, which is not preferable. Therefore, in the present invention, the Mn content is set to 1.20 to 1.70%. The Mn content is preferably 1.40% or more. Further, the Mn content is preferably 1.60% or less.

P:0.035%以下
 Pは、その含有量が0.035%を超えると、鋼の延性が劣化する。そのため、本発明では鋼中のP量を0.035%以下とする。好ましくは0.020%以下である。一方、Pは少ないほど好ましいため、P含有量の下限は特に限定されず、0%であってよい。しかし、通常、Pは不純物として鋼中に不可避的に含有される元素であり、過度の低P化は精錬時間の増加やコストの上昇を招くため、P含有量は0.005%以上とすることが好ましい。
P: 0.035% or less When the content of P exceeds 0.035%, the ductility of steel deteriorates. Therefore, in the present invention, the amount of P in steel is 0.035% or less. It is preferably 0.020% or less. On the other hand, the smaller the P content, the more preferable, so the lower limit of the P content is not particularly limited and may be 0%. However, P is usually an element that is unavoidably contained in steel as an impurity, and excessive reduction in P causes an increase in refining time and an increase in cost, so the P content should be 0.005% or more. preferable.

S:0.035%以下 
 Sは、鋼中に含有されると主にA系介在物の形態で鋼材中に存在する。S含有量が0.035%を超えると、この介在物量が著しく増加し、同時に粗大な介在物を生成するため、鋼の靭性を大きく低下させる。そのため、本発明では鋼中のS含有量を0.035%以下とする。好ましくは0.020%以下である。一方、Sは少ないほど好ましいため、S含有量の下限は特に限定されず、0%であってよい。なお、通常、Sは不純物として鋼中に不可避的に含有される元素であり、過度の低S化は精錬時間の増加やコストの上昇を招くため、S含有量は0.002%以上とすることが好ましい。
S: 0.035% or less
When S is contained in steel, it is mainly present in the steel material in the form of A-type inclusions. If the S content exceeds 0.035%, the amount of the inclusions increases remarkably, and at the same time, coarse inclusions are formed, which greatly reduces the toughness of the steel. Therefore, in the present invention, the S content in steel is 0.035% or less. It is preferably 0.020% or less. On the other hand, the smaller the amount of S, the more preferable. Therefore, the lower limit of the S content is not particularly limited and may be 0%. Usually, S is an element that is unavoidably contained in steel as an impurity, and excessive reduction of S causes increase in refining time and cost, so the S content should be 0.002% or more. preferable.

Nb:0.005~0.050%
 Nbは、炭窒化物として析出することで引張強度や降伏点を向上させる効果を有する元素である。この効果を得るためには、Nb含有量を0.005%以上とする必要がある。一方、Nb含有量が0.050%を超えると、析出脆化を助長することに加え、上部ベイナイト変態を促進させるため、連鋳割れが生じ易くなり、さらに靭性も低下する。そのため、本発明では、Nb含有量は0.005~0.050%とする。なお、Nb含有量は、0.010%以上とすることが好ましい。また、Nb含有量は、0.030%以下とすることが好ましい。
Nb: 0.005 to 0.050%
Nb is an element having the effect of improving tensile strength and yield point by precipitating as carbonitride. To obtain this effect, the Nb content needs to be 0.005% or more. On the other hand, if the Nb content exceeds 0.050%, in addition to promoting precipitation embrittlement, it also promotes upper bainite transformation, so continuous casting cracks are likely to occur, and toughness is also reduced. Therefore, in the present invention, the Nb content is 0.005 to 0.050%. The Nb content is preferably 0.010% or more. Further, the Nb content is preferably 0.030% or less.

V:0.005~0.050%
 Vは、炭窒化物として析出することで引張強度や降伏点を向上させる効果を有する元素である。この効果を得るためには、V含有量を0.005%以上とする必要がある。一方、V含有量が0.050%を超えると、析出脆化を助長するため、連鋳割れが生じ易くなる。そのため、本発明では、V含有量を0.005~0.050%とする。なお、V含有量は0.010%以上とすることが好ましい。また、V含有量は0.030%以下とすることが好ましい。
V: 0.005 to 0.050%
V is an element having the effect of improving tensile strength and yield point by precipitating as carbonitride. In order to obtain this effect, the V content needs to be 0.005% or more. On the other hand, when the V content exceeds 0.050%, precipitation embrittlement is promoted, and continuous casting cracks are likely to occur. Therefore, in the present invention, the V content is set to 0.005 to 0.050%. The V content is preferably 0.010% or more. Further, the V content is preferably 0.030% or less.

Ti:0.005~0.030%
 Tiは、連続鋳造時の曲げ-曲げ戻しの際の表面割れを防止するのに効果のある有用な元素であり、0.005%以上の範囲で積極的に添加する。また、Tiは鋼中でTiNを形成してオーステナイト粒を微細化し、さらに、TiNを核とした粒内フェライト変態の促進によってミクロ組織を微細化し、靭性向上にも有効な元素である。一方、Ti含有量が0.030%を超えることは、粗大なTiNが発生し鋼の靭性を低下させるので好ましくない。そのため、本発明では、Ti含有量は、0.005~0.030%とする。なお、Ti含有量は0.010%以上とすることが好ましい。また、Ti含有量は0.020%以下とすることが好ましい。
Ti: 0.005-0.030%
Ti is a useful element effective in preventing surface cracking during bending-unbending during continuous casting, and is positively added in the range of 0.005% or more. Further, Ti is an element effective in improving the toughness by forming TiN in the steel to refine the austenite grains and further promoting the intragranular ferrite transformation centered on TiN to refine the microstructure. On the other hand, if the Ti content exceeds 0.030%, coarse TiN is generated and the toughness of the steel is reduced, which is not preferable. Therefore, in the present invention, the Ti content is 0.005 to 0.030%. The Ti content is preferably 0.010% or more. Further, the Ti content is preferably 0.020% or less.

N:0.0020~0.0100%
 Nは、鋼中で炭窒化物を形成し、鋼の強度を向上させる有用な元素であり、その含有量は0.0020%以上である必要がある。しかし、N含有量が0.0100%を超えると形成される炭窒化物が粗大化して鋼の靭性を低下させる。また、N含有量が0.0100%を超えると、鋳片の表面割れが生じ、鋳片品質が低下するため好ましくない。そのため、本発明ではN含有量を0.0020~0.0100%とする。なお、N含有量は0.0030%以上とすることが好ましい。また、N含有量は0.0070%以下とすることが好ましい。
N: 0.0020-0.0100%
N is a useful element that forms carbonitrides in steel and improves the strength of steel, and its content must be 0.0020% or more. However, if the N content exceeds 0.0100%, the carbonitrides formed become coarse and the toughness of the steel decreases. Further, when the N content exceeds 0.0100%, surface cracking of the cast piece occurs, and the cast piece quality deteriorates, which is not preferable. Therefore, in the present invention, the N content is set to 0.0020 to 0.0100%. The N content is preferably 0.0030% or more. Further, the N content is preferably 0.0070% or less.

 さらに本発明では、各々の元素が単に上記の範囲を満足するだけでは不十分で、S、TiおよびNについては、[%S]、[%Ti]および[%N]をそれぞれ、鋼中のS,TiおよびNの含有量(質量%)としたときに、次の(1)式の関係を満足させることが重要である。
([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≦15.0・・・(1)
Further, in the present invention, it is not sufficient that each element simply satisfies the above range, and for S, Ti and N, [%S], [%Ti] and [%N] are respectively contained in the steel. When the contents of S, Ti and N (mass %) are set, it is important to satisfy the relationship of the following formula (1).
([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≦15.0・・・(1)

 発明者らは、連続鋳造時に鋼に割れが発生する原因について調査を行い、連続鋳造時にオーステナイト粒界に生成するフェライトへの粗大なMnSとVおよびNbの炭窒化物との析出が、割れの原因となっているとの知見を得た。そこで、該フェライトへのMnSとVおよびNb系炭窒化物との析出を抑制すべく検討を行ったところ、鋼中のS、TiおよびNの含有量を調整することによって、粒界フェライトへのMnSとVおよびNb系炭窒化物との析出を抑制して、連続鋳造時の割れを抑制できることが分かった。すなわち、S、TiおよびNの含有量に基づくパラメータである上記(1)式左辺で算出される値を、15.0を超えないようにすることで、SをTi炭硫化物、NをTiNとして析出させ、連続鋳造時にオーステナイト粒界に生成するフェライトへの粗大なMnSとVおよびNb系炭窒化物との析出を抑制し、連続鋳造割れを安定して抑制することができる。なお、上記(1)式における右辺は10.0以下とすること、すなわち、以下の(1)’式を満足させることがより好ましい。
([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≦10.0・・・(1)’
The inventors investigated the cause of cracking in steel during continuous casting, and found that coarse MnS and V and Nb carbonitride precipitates on ferrite formed in austenite grain boundaries during continuous casting. I got the knowledge that it was the cause. Therefore, a study was conducted to suppress the precipitation of MnS and V and Nb-based carbonitrides in the ferrite, and by adjusting the contents of S, Ti and N in the steel, it was found that It has been found that the precipitation of MnS with V and Nb-based carbonitrides can be suppressed to suppress cracking during continuous casting. That is, the value calculated by the left side of the above equation (1), which is a parameter based on the contents of S, Ti, and N, does not exceed 15.0, so that S is precipitated as Ti carbosulfide and N is precipitated as TiN. Thus, precipitation of coarse MnS and V and Nb-based carbonitrides on ferrite generated in the austenite grain boundaries during continuous casting can be suppressed, and continuous casting cracks can be stably suppressed. It is more preferable that the right side of the above formula (1) is 10.0 or less, that is, the following formula (1)′ is satisfied.
([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≦10.0・・・(1)'

 本発明で用いられる突起付きH形鋼の鋼組成は、以上説明した成分以外の残部は、Feおよび不可避的不純物である。
さらに、本発明の突起付きH形鋼では、以上説明した成分の他に、強度や延性、靱性、溶接部特性の向上を目的として、Cr:1.0%以下、Cu:1.0%以下、Ni:1.0%以下、Mo:1.0%以下、Al:0.10%以下、B:0.010%以下、Ca:0.10%以下、Mg:0.10%以下、REM: 0.10%以下の中から選ばれる1種または2種以上を任意に含有していてもよい。
以下、上記元素の含有量を特定した理由を説明する。
In the steel composition of the H-section steel with protrusions used in the present invention, the balance other than the components described above is Fe and inevitable impurities.
Further, in the H-section steel with protrusions of the present invention, in addition to the components described above, Cr: 1.0% or less, Cu: 1.0% or less, Ni: 1.0% or less for the purpose of improving strength, ductility, toughness, and weld property. % Or less, Mo: 1.0% or less, Al: 0.10% or less, B: 0.010% or less, Ca: 0.10% or less, Mg: 0.10% or less, REM: 0.10% or less. It may optionally contain.
Hereinafter, the reasons for specifying the contents of the above elements will be described.

Cr:1.0%以下
 Crは、固溶強化により鋼の更なる高強度化を図ることができる元素である。ただし、その含有量が1.0%を超えると上部ベイナイト変態を促進させ、靭性を低下させるので好ましくない。したがって、鋼の成分組成がCrを含有する場合は、Cr含有量は1.0%以下とする。より好ましくは0.005%以上であり、0.5%以下である。
Cr: 1.0% or less Cr is an element that can further strengthen the steel by solid solution strengthening. However, if its content exceeds 1.0%, the upper bainite transformation is promoted and the toughness is lowered, which is not preferable. Therefore, when the chemical composition of steel contains Cr, the Cr content is 1.0% or less. It is more preferably 0.005% or more and 0.5% or less.

Cu:1.0%以下
 Cuは、固溶強化により鋼の更なる高強度化を図ることができる元素である。ただし、その含有量が1.0%を超えると、Cu割れを生じやすくなる。したがって、鋼の成分組成がCuを含有する場合は、Cu含有量は1.0%以下とする。より好ましくは0.005%以上であり、0.5%以下である。
Cu: 1.0% or less Cu is an element that can further strengthen the steel by solid solution strengthening. However, if the content exceeds 1.0%, Cu cracking tends to occur. Therefore, if the composition of the steel contains Cu, the Cu content should be 1.0% or less. It is more preferably 0.005% or more and 0.5% or less.

Ni:1.0%以下
 Niは、延性を劣化することなく鋼の高強度化を図ることができる元素である。また、Cuと複合添加することによりCu割れを抑制することができるため、鋼組成がCuを含有する場合にはNiも含有することが望ましい。ただし、Ni含有量が1.0%を超えると、鋼の焼入れ性がより上昇し、靭性が低下する傾向がある。したがって、鋼組成がNiを含有する場合は、Ni量は1.0%以下とする。より好ましくは0.005%以上であり、0.5%以下である。
Ni: 1.0% or less Ni is an element that can increase the strength of steel without deteriorating ductility. Moreover, since Cu cracking can be suppressed by adding Cu together, it is desirable that Ni is also contained when the steel composition contains Cu. However, if the Ni content exceeds 1.0%, the hardenability of steel further increases and the toughness tends to decrease. Therefore, when the steel composition contains Ni, the Ni content is 1.0% or less. It is more preferably 0.005% or more and 0.5% or less.

Mo:1.0%以下
 Moは、固溶強化によってさらなる鋼の高強度化を図ることができる元素である。ただし、その含有量が1.0%を超えると、鋼中に上部ベイナイトが多量に生成するようになり、靭性が低下する傾向がある。したがって、成分組成がMoを含有する場合は、Mo含有量は1.0%以下とする。より好ましくは0.005%以上であり、0.5%以下である。
Mo: 1.0% or less Mo is an element that can further strengthen the steel by solid solution strengthening. However, if the content exceeds 1.0%, a large amount of upper bainite is generated in the steel, and the toughness tends to decrease. Therefore, when the component composition contains Mo, the Mo content is 1.0% or less. It is more preferably 0.005% or more and 0.5% or less.

Al:0.10%以下
 Alは、脱酸剤として添加することができる元素である。しかし、Al含有量が0.10%を超えると、Alの有する高い酸素との結合力のため、鋼中に酸化物系介在物が多量に生成し、その結果、鋼の延性が低下する。したがって、鋼組成がAlを含有する場合は、Al量は0.10%以下とすることが好ましい。一方、Al含有量の下限は特に限定されないが、脱酸のためには0.001%以上とすることが好ましい。より好ましくは0.001%以上であり、0.03%以下である。
Al: 0.10% or less Al is an element that can be added as a deoxidizing agent. However, when the Al content exceeds 0.10%, a large amount of oxide inclusions are generated in the steel due to the high binding force of Al with oxygen, and as a result, the ductility of the steel decreases. Therefore, when the steel composition contains Al, the Al content is preferably 0.10% or less. On the other hand, the lower limit of the Al content is not particularly limited, but it is preferably 0.001% or more for deoxidation. More preferably, it is 0.001% or more and 0.03% or less.

B:0.010%以下
 Bは、鋼中で粒界に偏析し粒界強度を向上させる効果を有する元素である。また、粒内フェライトの核生成サイトとなるTiNとの複合析出物を形成し、ミクロ組織を微細化することで靭性向上にも有効な元素である。一方、その含有量が0.010%を超えると、粗大な炭窒化物の粒界析出により靭性が低下する。したがって、鋼組成がBを含有する場合は、B含有量は0.010%以下とする。より好ましくは0.001%以上であり、0.003%以下である。
B: 0.010% or less B is an element having the effect of segregating to the grain boundaries in steel and improving the grain boundary strength. It is also an element effective for improving toughness by forming a composite precipitate with TiN, which becomes the nucleation site of intragranular ferrite, and refining the microstructure. On the other hand, if its content exceeds 0.010%, the toughness decreases due to the precipitation of coarse carbonitrides at the grain boundaries. Therefore, when the steel composition contains B, the B content is 0.010% or less. It is more preferably 0.001% or more and 0.003% or less.

Ca:0.10%以下
 Caは、硫化物系介在物中の酸化物および硫化物を、高温における安定性が高いものへ変質させて、硫化物系介在物を粒状化する作用を有する。そして、このCaによる介在物の形態制御効果により、鋼の靭性、延性の向上を図ることが出できる。但し、Ca含有量が0.10%を超えると、清浄度が低下して靭性が低下しがちとなる。したがって、鋼組成がCaを含有する場合は、Ca含有量は0.10%以下とする。より好ましくは0.0010%以上であり、0.0050%以下である。
Ca: 0.10% or less Ca has a function of converting the oxides and sulfides in the sulfide-based inclusions into those having high stability at high temperatures, and granulating the sulfide-based inclusions. The toughness and ductility of the steel can be improved by the effect of Ca to control the morphology of inclusions. However, if the Ca content exceeds 0.10%, the cleanliness tends to decrease and the toughness tends to decrease. Therefore, when the steel composition contains Ca, the Ca content is 0.10% or less. It is more preferably 0.0010% or more and 0.0050% or less.

Mg:0.10%以下
 Mgは、硫化物系介在物中の酸化物および硫化物を、高温における安定性が高いものへ変質させて粒状化する作用を有する。そして、このMgによる介在物の形態制御効果により、鋼の靭性、延性の向上を図ることが出できる。但し、Mg含有量が0.10%を超えると、清浄度が低下して靭性が低下しがちとなる。したがって、鋼組成がMgを含有する場合は、Mg含有量は0.10%以下とする。より好ましくは0.0010%以上であり、0.0050%以下である。
Mg: 0.10% or less Mg has the function of transforming the oxides and sulfides in the sulfide-based inclusions into those having high stability at high temperatures and granulating them. Then, the toughness and ductility of the steel can be improved by the effect of controlling the morphology of inclusions by this Mg. However, if the Mg content exceeds 0.10%, the cleanliness tends to decrease and the toughness tends to decrease. Therefore, when the steel composition contains Mg, the Mg content is 0.10% or less. It is more preferably 0.0010% or more and 0.0050% or less.

REM:0.10%以下
 REM(希土類金属)は、硫化物系介在物中の酸化物および硫化物を、高温における安定性が高いものへ変質させて、硫化物系介在物を粒状化する作用を有する。そして、このREMによる介在物の形態制御効果により、鋼の靭性、延性の向上を図ることが出できる。但し、REM含有量が0.10%を超えると、清浄度が低下して靭性が低下しがちとなる。したがって、鋼組成がREMを含有する場合は、REM含有量は0.10%以下とする。より好ましくは0.0010%以上であり、0.0050%以下である。
 以上説明した元素以外の残部はFeおよび不可避的不純物である。
REM: 0.10% or less REM (rare earth metal) has the effect of transforming oxides and sulfides in sulfide-based inclusions into those with high stability at high temperatures, and granulating sulfide-based inclusions. .. Then, the toughness and ductility of the steel can be improved by the effect of controlling the morphology of inclusions by the REM. However, if the REM content exceeds 0.10%, the cleanliness tends to decrease and the toughness tends to decrease. Therefore, if the steel composition contains REM, the REM content should be 0.10% or less. It is more preferably 0.0010% or more and 0.0050% or less.
The balance other than the elements described above is Fe and inevitable impurities.

 本発明の、突起付きH形鋼について詳しく説明する。すなわち、突起付きH形鋼は、図1に示すように、一般的なH形鋼と同様に、1対のフランジ2をウェブ3にて連結してなる。そして、突起付きH形鋼は、前記フランジ2の外面に突起4を有している。この突起4は、コンクリート付着性能を付与するために設けられるものである。この目的で突起4が設けられた突起付きH形鋼1において、突起4が設けられる箇所は、図2(a)に示すように、フランジ2の外面である。図示例では、フランジ2の外面全体に、図2(a)に四角で囲った部分の拡大図である、同図(b)に示す断面形状にてフランジ2の幅方向に延びる突条としての突起4がフランジ2の長手方向に配列して形成されている。 The H-shaped steel with protrusions of the present invention will be described in detail. That is, as shown in FIG. 1, the H-section steel with protrusions is formed by connecting a pair of flanges 2 with a web 3 similarly to a general H-section steel. The H-section steel with protrusions has protrusions 4 on the outer surface of the flange 2. The projections 4 are provided to give concrete adhesion performance. In the H-shaped steel with projection 1 provided with the projection 4 for this purpose, the location where the projection 4 is provided is the outer surface of the flange 2 as shown in FIG. In the illustrated example, the entire outer surface of the flange 2 is an enlarged view of a portion surrounded by a square in FIG. 2A. The protrusions 4 are formed so as to be arranged in the longitudinal direction of the flange 2.

 なお、突起の形状や寸法、個数などは突起付きH形鋼に要求される仕様に応じて任意に設定できる。従って、図示例に限定されないが、例えば突起4の高さhはコンクリート付着性能を考慮すると1.5mm以上とすることが好ましい。一方、高さhの上限は、ロール割損防止の観点から6mmとすることが好ましい。また、突起4相互の間隔dは、コンクリート付着性能を考慮すると、高さhとの間にh/d≧0.05の関係を満足することが好ましい。 Note that the shape, size, and number of protrusions can be set arbitrarily according to the specifications required for H-section steel with protrusions. Therefore, although not limited to the illustrated example, for example, the height h of the projection 4 is preferably 1.5 mm or more in consideration of the concrete adhesion performance. On the other hand, the upper limit of the height h is preferably 6 mm from the viewpoint of preventing roll breakage. Further, the distance d between the protrusions 4 preferably satisfies the relationship of h/d≧0.05 with the height h in consideration of the concrete adhesion performance.

 次に、本発明の突起付きH形鋼の製造方法について説明する。鋼(スラブまたはビームブランク)の溶製法および鋳造法については特に制限はなく、従来公知の方法いずれもが適合する。また、H形鋼に成形するための熱間圧延条件も特に制限されることはなく、常法に従って行えば良い。熱間圧延の仕上圧延において、突起を形成させる部分(フランジ外面)を圧下するロールとして、形成させる突起に対応した溝をロール表面に形成したものを用いることで、突起を形成することができる。仕上圧延の後は、以下の条件を満足させた冷却を行う必要がある。 Next, a method for manufacturing the H-section steel with protrusions of the present invention will be described. There is no particular limitation on the melting method and the casting method of steel (slab or beam blank), and any conventionally known method is suitable. Further, the hot rolling conditions for forming the H-shaped steel are not particularly limited and may be carried out according to a conventional method. In the finish rolling of the hot rolling, the protrusion can be formed by using a roll having a groove corresponding to the protrusion to be formed on the surface of the roll as a roll for rolling down the portion (flange outer surface) where the protrusion is formed. After finish rolling, it is necessary to perform cooling satisfying the following conditions.

冷却開始時のフランジ温度:750 ℃以上
 本発明では、仕上圧延直後に鋼材の冷却を開始することによって生産能率の低下を防止することを所期して、冷却開始時のフランジ温度は750℃以上とする。一方、冷却開始時のフランジ温度がAr温度未満になると、十分な強度を得難くなるため、さらに冷却開始時のフランジ温度をAr温度以上とすることが好ましい。なお、Ar変態温度は、例えば以下の(2)式により鋼成分との関係で簡易的に示される。
 Ar=910-310×[%C]+25×([%Si]+2×[%Al])-80×[Mneq] ・・・(2)
 ここで、[Mneq]は次の(3)式で算出される値である。
 [Mneq]=[%Mn]+[%Cr]+[%Cu]+[%Mo]+[%Ni]/2+10×([%Nb]-0.02)・・・(3)
 なお、上記(2)式、(3)式において、[%M]は鋼中の元素Mの含有量(質量%)を意味する。ここで、上記(2)式および(3)式でArを計算するにあたり、積極的に含有させていない元素Mの含有量については、不可避的不純物として含有されている元素Mの含有量(分析値)を用いて算出するものとする。
Flange temperature at the start of cooling: 750°C or higher In the present invention, the flange temperature at the start of cooling is set to 750°C or higher in order to prevent a decrease in production efficiency by starting cooling of the steel material immediately after finish rolling. To do. On the other hand, if the flange temperature at the start of cooling is less than the Ar 3 temperature, it becomes difficult to obtain sufficient strength, so it is preferable to further set the flange temperature at the start of cooling to the Ar 3 temperature or higher. The Ar 3 transformation temperature is simply shown in relation to the steel composition by the following equation (2), for example.
Ar 3 =910-310×[%C]+25×([%Si]+2×[%Al])-80×[Mneq] ・・・(2)
Here, [Mneq] is a value calculated by the following equation (3).
[Mneq]=[%Mn]+[%Cr]+[%Cu]+[%Mo]+[%Ni]/2+10×([%Nb]-0.02)・・・(3)
In the expressions (2) and (3), [%M] means the content (mass %) of the element M in the steel. Here, in calculating Ar 3 by the above formulas (2) and (3), regarding the content of the element M not positively contained, the content of the element M contained as an unavoidable impurity ( It should be calculated using the analysis value).

冷却開始温度から500℃までの平均冷却速度:0.1~30℃/s
 冷却開始温度から500℃までの平均冷却速度が0.1℃/sに満たないと、所定の引張特性および靭性を確保することが難しいため、冷却速度は0.1℃/s以上とする。一方、前記冷却速度が30℃/sを超えて大きくなると、ベイナイトあるいはマルテンサイトの生成により、靭性の低下や引張強さの過度な上昇といった弊害が生じるため、冷却開始温度から500℃までの平均冷却速度は0.1~30℃/sの範囲とする。好ましい平均冷却速度は、0.5~10℃/sの範囲とする。
Average cooling rate from cooling start temperature to 500℃: 0.1~30℃/s
If the average cooling rate from the cooling start temperature to 500°C is less than 0.1°C/s, it is difficult to secure the predetermined tensile properties and toughness, so the cooling rate is 0.1°C/s or more. On the other hand, when the cooling rate becomes higher than 30°C/s, adverse effects such as decrease in toughness and excessive increase in tensile strength occur due to the formation of bainite or martensite. The cooling rate is in the range of 0.1 to 30°C/s. The preferable average cooling rate is in the range of 0.5 to 10°C/s.

 上記した成分組成に調整し、上記した条件に従って圧延および冷却を行うことにより、突起付きH形鋼において、引張強さが490MPa 以上、降伏強度が355MPa以上、そして0℃における衝撃吸収エネルギーvE0が27J以上という、優れた機械的性能を得ることができる。いずれの特性も上限を規定する必要はないが、実用的には、引張強さが640MPa、降伏強度が475MPaおよび0℃における衝撃吸収エネルギーvE0が350J程度である。 By adjusting the above-mentioned composition and rolling and cooling according to the above conditions, the H-shaped steel with projections has a tensile strength of 490 MPa or more, a yield strength of 355 MPa or more, and an impact absorption energy vE0 of 27 J at 0°C. As described above, excellent mechanical performance can be obtained. Although it is not necessary to specify the upper limit for any of the characteristics, practically, the tensile strength is 640 MPa, the yield strength is 475 MPa, and the impact absorption energy vE0 at 0° C. is about 350 J.

 ここで、本発明で対象とする突起付きH形鋼は、そのフランジ厚が特に限定されることはない。フランジ外面の突起は、仕上げ圧延の工程において溝付きのロールを用いて形成する。すなわち、所望の突起高さを付与するためには、フランジ部の圧下量をできるだけ大きくする必要がある。従って、厚いフランジを有する突起付きH形鋼はより大きな圧下を必要とする。本発明では後述の通り、圧延温度を適正範囲にコントロールすることにより、突起高さの形成効率が低下するとされる、フランジ厚が16mm以上の厚肉のH形鋼においても十分な突起高さを付与することができる。 Here, the flange thickness of the H-section steel with protrusions that is the subject of the present invention is not particularly limited. The protrusion on the outer surface of the flange is formed by using a grooved roll in the finish rolling process. That is, it is necessary to increase the amount of reduction of the flange portion as much as possible in order to give a desired protrusion height. Therefore, a protruding H-section steel with a thick flange requires greater reduction. As will be described later, in the present invention, by controlling the rolling temperature within an appropriate range, it is said that the formation efficiency of the projection height is lowered. Even in the case of a thick H-section steel with a flange thickness of 16 mm or more, a sufficient projection height can be obtained. Can be granted.

 熱間圧延時に突起を形成する成形を行う仕上圧延では、十分な突起高さを有する突起を形成させる観点から、仕上圧延温度を800℃以上とすることが好ましい。仕上圧延温度が 800℃に満たないと、十分な高さの突起を安定して形成することが難しい。一方、前記仕上げ温度の上限は特に限定されないが、1050℃を超えると、オーステナイト粒径が粗大になるため、靭性が低下しがちとなる。そのため、前記仕上げ温度を1050℃以下とすることが好ましい。 In finish rolling for forming protrusions during hot rolling, the finish rolling temperature is preferably 800°C or higher from the viewpoint of forming protrusions having a sufficient protrusion height. If the finishing rolling temperature is less than 800°C, it is difficult to stably form protrusions of sufficient height. On the other hand, the upper limit of the finishing temperature is not particularly limited, but if it exceeds 1050° C., the austenite grain size becomes coarse and the toughness tends to decrease. Therefore, the finishing temperature is preferably 1050° C. or lower.

 以下、実施例に従って、本発明の構成および作用効果をより具体的に説明する。しかし、本発明は下記の実施例によって制限を受けるものではなく、本発明の趣旨に適合し得る範囲内にて適宜変更することも可能であり、これらは何れも本発明の技術的範囲に含まれる。 Hereinafter, the configuration and operational effects of the present invention will be described more specifically according to the examples. However, the present invention is not limited by the following examples, and can be appropriately modified within a range compatible with the spirit of the present invention, and these are all included in the technical scope of the present invention. Be done.

 表1に示す成分組成の鋼材を、連続鋳造機にて断面400mm×560mm×長さ8000mmのビームブランクとし、表面における割れの有無を調査した。すなわち、前記ビームブランクの表面を長手方向に観察し、長さ10mm以上の割れの有無を調査した。表面割れは1m当たりの割れの個数を求め、A:割れ無し、B:1~4個/m、C:5個以上/mの指標を用いて評価し、この指標においてAまたはB判定のものを合格とした。表1に、表面割れの判定結果を合わせて示す。鋼組成が、上記の(1)式を満足する鋼は、表面割れの判定結果がAまたはBであった。 A steel blank having the composition shown in Table 1 was used as a beam blank having a cross section of 400 mm×560 mm×length of 8000 mm by a continuous casting machine, and the presence or absence of cracks on the surface was examined. That is, the surface of the beam blank was observed in the longitudinal direction and examined for cracks having a length of 10 mm or more. Surface cracks obtains the number of cracks per 1 m 2, A: no cracks, B: 1 ~ 4 pieces / m 2, C: evaluated using an index of 5 or more / m 2, A or B in the index Those judged were accepted. Table 1 also shows the results of surface crack determination. In the steel having a steel composition satisfying the above formula (1), the surface cracking judgment result was A or B.

 次いで、これらのビームブランクのうち、表面割れの判定結果がAあるいはBであるものについて、1250℃で2時間加熱後、表2に示す条件で熱間圧延ならびに冷却を行って、図1に示す断面形状、すなわち、ウェブ3とウェブの両端に配置された1対のフランジ2を有する形状の突起付きH形鋼1を製造した。ここで、断面寸法(ウェブ高さ×フランジ幅×ウェブ厚×フランジ厚)は、320×323×25×25mmおよび350×333×35×40mmの2種のうちのいずれかとして、突起付きH形鋼を製造した。仕上圧延においては、フランジ外面を圧下する圧延ロールとして、フランジ外面に形成させる突起形状に対応した溝を設けたものを用い、フランジ外面に、図2に示すような、フランジ2の幅方向に延在する突起6を形成した。ここで、フランジ外面を圧下する仕上圧延ロールには、突起幅w:15mmおよび突起高さh:1.5mm以上の突起を形成し得る、溝を設けてある。仕上圧延後の冷却速度は、フランジ外面表面の温度を放射温度計で測定し、冷却開始から冷却停止までの間の温度変化を単位時間(秒)あたりに換算することで、冷却速度(℃/s)を算出した。 Next, among these beam blanks, those having a surface crack determination result of A or B were heated at 1250° C. for 2 hours, then hot-rolled and cooled under the conditions shown in Table 2, and shown in FIG. A H-section steel 1 with a protrusion having a cross-sectional shape, that is, a shape having a web 3 and a pair of flanges 2 arranged at both ends of the web was manufactured. Here, the cross-sectional dimension (web height x flange width x web thickness x flange thickness) is one of two types of 320 x 323 x 25 x 25 mm and 350 x 333 x 35 x 40 mm. Manufactured steel. In finish rolling, a rolling roll having a groove corresponding to the projection shape to be formed on the flange outer surface is used as a rolling roll for rolling down the flange outer surface, and the flange outer surface extends in the width direction of the flange 2 as shown in FIG. The existing projections 6 were formed. Here, the finish rolling roll that rolls down the outer surface of the flange is provided with a groove capable of forming a protrusion having a protrusion width w of 15 mm and a protrusion height h of 1.5 mm or more. The cooling rate after finish rolling is measured by measuring the temperature of the outer surface of the flange with a radiation thermometer and converting the temperature change from the start of cooling to the end of cooling per unit time (seconds) to obtain the cooling rate (°C/ s) was calculated.

Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001

 得られた突起付きH形鋼について、突起高さ評価、引張試験および靭性試験を実施した。以下にそれぞれの評価内容について詳細に説明する。 The obtained H-section steel with protrusions was subjected to protrusion height evaluation, tensile test and toughness test. The details of each evaluation will be described below in detail.

<突起高さ評価>
 得られた突起付きH形鋼について、図2に示したフランジ外面の突起高さhを測定した。かかる値の測定は、仕上圧延後の突起付きH形鋼の圧延方向における先端部、中央部および尾端部の3箇所について行い、その平均値を採用した。なお、突起高さの要求性能下限値を1.5mmに設定し、この値以上を突起高さhの好適範囲とした。また、突起高さhがこの値以上となる突起付きH形鋼が得られた製造条件は、突起形成のし易さの観点からも特に好ましい条件と評価できる。
<Evaluation of protrusion height>
With respect to the obtained H-section steel with protrusions, the protrusion height h on the outer surface of the flange shown in FIG. 2 was measured. Such a value was measured at three points in the rolling direction of the H-section steel with protrusions after finish rolling in the rolling direction, the center portion and the tail end portion, and the average value was adopted. The lower limit of the required performance of the protrusion height was set to 1.5 mm, and a value above this value was defined as a suitable range of the protrusion height h. Further, the manufacturing conditions under which the H-shaped steel with protrusions having the protrusion height h of not less than this value are obtained can be evaluated as particularly preferable conditions from the viewpoint of ease of forming the protrusions.

<引張試験>
 図1に符号5として示すフランジ1/6B部(1/6Bを挟むフランジ幅方向長さ60mm)より、引張方向がH形鋼のフランジ長手方向となるように、JIS Z2201に規定されたJIS1A試験片(フランジ全厚試験片)を採取し、JIS Z2241に準じて引張試験を行い、降伏強度(降伏応力YSまたは0.2%耐力)、引張強さを測定した。
<Tensile test>
JIS 1A test specified in JIS Z 2201 so that the tensile direction is the flange longitudinal direction of H-section steel from the flange 1/6B part (60 mm in the flange width direction sandwiching 1/6B) shown as reference numeral 5 in FIG. A piece (flange full-thickness test piece) was sampled, a tensile test was performed according to JIS Z2241, and the yield strength (yield stress YS or 0.2% proof stress) and the tensile strength were measured.

<靭性試験>
 図1に示したフランジ1/6B部5のフランジ裏面から1/4t(tはフランジ厚)の位置を中心として、JIS Z2202に規定された2mmVノッチシャルピー衝撃試験片を採取し、JISZ2242に準じてシャルピー衝撃試験を行い、0℃における吸収エネルギーを測定した。
<Toughness test>
A 2mmV notch Charpy impact test piece specified in JIS Z2202 was sampled from the back surface of the flange 1/6B portion 5 shown in FIG. A Charpy impact test was performed to measure the absorbed energy at 0°C.

 表2に上記調査の結果をあわせて示す。本発明の鋼組成を満足する適合鋼を用い、本発明範囲の製造方法(フランジ外面の平均冷却速度が本発明範囲内)で作製した突起付きH形鋼の試験結果(表2中の試験No.1~19、31)は、いずれも所望の特性(引張強さ:490MPa以上、降伏強度:355MPa以上および0℃における衝撃吸収エネルギーvE0:27J以上)を満足していた。なお、試験No. 33は、引張強さ、降伏強度、0℃における衝撃吸収エネルギーについては所望の特性を満足しているが、仕上圧延温度が好適下限である800℃を下回っていたため、突起高さが1.4mmであり、好適範囲(1.5mm以上)に満たなかった。 Table 2 also shows the results of the above survey. Test results of the H-section steel with protrusions produced by the manufacturing method within the scope of the present invention (the average cooling rate of the outer surface of the flange is within the scope of the present invention) using a compatible steel satisfying the steel composition of the present invention (test No. in Table 2). .1 to 19, 31) all satisfied the desired properties (tensile strength: 490 MPa or more, yield strength: 355 MPa or more and impact absorption energy vE0: 27 J or more at 0° C.). Although Test No. 33 satisfied the desired properties with respect to tensile strength, yield strength, and impact absorption energy at 0°C, since the finishing rolling temperature was below the suitable lower limit of 800°C, the protrusion height Was 1.4 mm, which was less than the preferred range (1.5 mm or more).

 一方、H形鋼の鋼組成が本発明の条件を満足しないか、あるいは、本発明範囲の製造方法を適用しなかった比較例(表2中の試験No.20~30、32~34)は、引張強さ、降伏強度および靭性のいずれかの値が要求特性を満足していない。 On the other hand, comparative examples (test Nos. 20 to 30, 32 to 34 in Table 2) in which the steel composition of the H-section steel did not satisfy the conditions of the present invention or the manufacturing method within the scope of the present invention was not applied , Tensile strength, yield strength, or toughness does not satisfy the required characteristics.

Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002

 1 突起付きH形鋼(圧延H形鋼)
 2 フランジ
 3 ウェブ
 4 突起
 5 フランジ1/6B部(試験片採取位置)
1 H-section steel with protrusions (rolled H-section steel)
2 Flange 3 Web 4 Protrusion 5 Flange 1/6B part (test piece sampling position)

Claims (5)

 C:0.05~0.20質量%、Si:0.05~0.60質量%、Mn:1.20~1.70質量%、P:0.035質量%以下、S:0.035質量%以下、Nb:0.005~0.050質量%、V:0.005~0.050質量%、Ti:0.005~0.030質量%およびN:0.0020~0.0100質量%を、下記(1)式を満足する範囲で含有し、残部がFeおよび不可避的不純物の鋼組成を有し、引張強さが490MPa以上、降伏強度が355MPa以上、かつ0℃における衝撃吸収エネルギーvE0が27J以上である、突起付きH形鋼。
                記
 ([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≦15.0  ・・・(1)
  ここで、[%S]、[%Ti]および[%N]はそれぞれ、鋼中のS,TiおよびNの含有量(質量%)である。
C: 0.05 to 0.20 mass%, Si: 0.05 to 0.60 mass%, Mn: 1.20 to 1.70 mass%, P: 0.035 mass% or less, S: 0.035 mass% or less, Nb: 0.005 to 0.050 mass%, V: 0.005 to 0.050% by mass, Ti: 0.005 to 0.030% by mass, and N: 0.0020 to 0.0100% by mass are contained within the range satisfying the following formula (1), and the balance has a steel composition of Fe and unavoidable impurities, and has a tensile strength. H-shaped steel with protrusions having a strength of 490 MPa or more, a yield strength of 355 MPa or more, and an impact absorption energy vE0 of 27 J or more at 0°C.
Note ([%S]/32)/([%Ti]/48)+4×([%N]/14)/([%Ti]/48)≦15.0 ・・・(1)
Here, [%S], [%Ti] and [%N] are the contents (mass %) of S, Ti and N in the steel, respectively.
 前記鋼組成は、さらに、Cr:1.0質量%以下、Cu:1.0質量%以下、Ni:1.0質量%以下、Mo:1.0質量%以下、Al:0.10質量%以下、B:0.010質量%以下、Ca:0.10質量%以下、Mg:0.10質量%以下およびREM:0.10質量%以下の中から選ばれる1種または2種以上を含有する請求項1に記載の突起付きH形鋼。 The steel composition further comprises Cr: 1.0 mass% or less, Cu: 1.0 mass% or less, Ni: 1.0 mass% or less, Mo: 1.0 mass% or less, Al: 0.10 mass% or less, B: 0.010 mass% or less, Ca. The protrusion H-shaped steel according to claim 1, containing one or more selected from the group consisting of: 0.10 mass% or less, Mg: 0.10 mass% or less, and REM: 0.10 mass% or less.  前記突起は、高さが1.5mm以上である請求項1または2に記載の突起付きH形鋼。 The H-shaped steel with protrusion according to claim 1 or 2, wherein the protrusion has a height of 1.5 mm or more.  請求項1または2のいずれかに記載の鋼組成を有する鋼素材に、熱間圧延を施して突起付きH形鋼を成形する突起付きH形鋼の製造方法であって、
前記熱間圧延の仕上圧延によりH形鋼のフランジ外面に突起を形成し、該仕上圧延の後に、750℃以上の冷却開始温度から500℃までの間を平均冷却速度:0.1~30℃/sの条件で冷却する突起付きH形鋼の製造方法。
A method for producing a H-section steel with protrusions, comprising hot rolling a steel material having the steel composition according to claim 1 or 2 to form H-section steel with protrusions,
After the finish rolling of the hot rolling, protrusions are formed on the outer surface of the flange of the H-shaped steel, and after the finish rolling, the average cooling rate from the cooling start temperature of 750°C or higher to 500°C: 0.1 to 30°C/s. A method for manufacturing an H-section steel with protrusions, which is cooled under the conditions of.
 前記仕上圧延を800℃以上の温度で行う請求項4に記載の突起付きH形鋼の製造方法。 The method for manufacturing a H-section steel with protrusions according to claim 4, wherein the finish rolling is performed at a temperature of 800°C or higher.
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