[go: up one dir, main page]

WO2020087425A1 - Hydrogen cycle-based solar hydrogen production, storage and application system - Google Patents

Hydrogen cycle-based solar hydrogen production, storage and application system Download PDF

Info

Publication number
WO2020087425A1
WO2020087425A1 PCT/CN2018/113246 CN2018113246W WO2020087425A1 WO 2020087425 A1 WO2020087425 A1 WO 2020087425A1 CN 2018113246 W CN2018113246 W CN 2018113246W WO 2020087425 A1 WO2020087425 A1 WO 2020087425A1
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
hydrate
solar
hydrate solution
storage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2018/113246
Other languages
French (fr)
Chinese (zh)
Inventor
顾士平
顾海涛
黄书慧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2020087425A1 publication Critical patent/WO2020087425A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0656—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by electrochemical means
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02N—ELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N11/00—Generators or motors not provided for elsewhere; Alleged perpetua mobilia obtained by electric or magnetic means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Definitions

  • the invention relates to a solar cycle hydrogen production, hydrogen storage and application system based on a hydrogen cycle, in particular to a hydrogen cycle solar energy storage and application system stored in a pipeline or a pressure tank of hydrogen hydrate.
  • Hydrogen is generated by sunlight decomposing water, and the solar energy is stored in the chemical energy of hydrogen; hydrogen is transported through pipelines or pressure tanks, or hydrogen dissolved in hydrogen hydrate is transported through pipelines or pressure tanks; hydrogen dissolved in hydrogen hydrates is reduced by Hydrogen evolution by pressurization, or hydrogen evolution by heating, or hydrogenation reaction of hydrogenated hydrate surfactants, referred to as reaction hydrogen evolution; hydrogen or hydrogen hydrate produces water by burning gas stoves with oxygen in the air, releasing heat for domestic or industrial use; hydrogen Or hydrogen hydrate is delivered to vehicles or factories through pipelines or pressure tanks for internal combustion engines to power cars or machines; hydrogen or hydrogen hydrate is delivered to vehicles through pipelines or pressure tanks or hydrogen fuel cells in factories are used to generate electricity , For life, or industry, or automotive power use; to form a solar energy storage based on hydrogen cycle, using a clean energy cycle system;
  • Hydrogen small cycle solar energy hydrogen production on home roof, hydrogen hydrate storage, pipeline or pressure delivery of hydrogen or hydrogen hydrate tank connected to gas stove to burn for heat, pipeline hydrogen transmission or connected fuel cell for power generation, for household use; or fuel cell and Generate electricity from the grid and sell it to a large power grid; or use it in a family car, or sell it to a hydrogen refueling station, or sell it to a tanker;
  • Hydrogen cycle solar hydrolyzed hydrogen generator, solar hydrolyzed hydrogen generator field, the generated hydrogen is transported to the hydrogen hydrate filling station through the hydrogen hydrate transportation network, or to the hydrogen hydrate pipeline system, or to the hydrogen hydration Mobile refueling vehicle; hydrogen hydrate transmission network is pipeline transportation; or hydrogen hydrate transmission network vehicle transportation; user terminal includes gas stove, fuel cell, hydrogen internal combustion engine;
  • the water in the solar hydrolyzed hydrogen generator (102) is photolyzed into hydrogen and oxygen, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (103) Storage (101), where hydrogen gas is dissolved into a hydrate solution of hydrogen gas to realize storage of hydrogen gas;
  • the circulation pump of the hydrogen combustion furnace (104) is started, the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (106), and the hydrogen hydrate solution storage (101)
  • the hydrogen hydrate solution in the hydrogen is sent to the hydrogen combustion furnace (104) to precipitate hydrogen.
  • the hydrogen burns with the oxygen in the air in the hydrogen combustion furnace (104) to generate heat for human use; the hydrate solution of the precipitated hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (101) through the hydrogen hydrate solution return pipe inlet pipe (105);
  • the water in the solar hydrogen hydrolysis generator (202) is photolyzed into hydrogen and oxygen under the irradiation of sunlight, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (203)
  • the storage (201), hydrogen gas is dissolved into the hydrogen hydrate solution to realize the storage of hydrogen gas;
  • the hydrogen fuel cell (204) needs hydrogen, start the circulation pump of the hydrogen fuel cell (204), the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (206), and the hydrogen hydrate solution storage (201) The hydrogen hydrate solution is sent to the hydrogen fuel cell (204) to precipitate hydrogen.
  • the hydrogen is burned in the hydrogen fuel cell (204) and the oxygen in the air burns to generate heat for human use; the hydrate solution storage of the hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (201) through the hydrogen hydrate solution return pipe inlet pipe (205);
  • the solar hydrolyzed hydrogen generator (401) is a small solar hydrolyzed hydrogen generator, which can be placed in a place where it can receive sunlight;
  • the solar hydrolyzed hydrogen generator field (402) is an array of large-scale solar hydrolyzed hydrogen generators, which can produce a large amount of Of hydrogen
  • the hydrogen produced by the solar hydrolyzed hydrogen generator (401) and the solar hydrolyzed hydrogen generator field (402) is transported to the hydrogen hydrate filling station (404) through the hydrogen hydrate transmission network (403) or to the hydrogen hydrate pipeline system (405), or transport to the mobile filling vehicle for hydrogen hydrate (406);
  • Hydrogen hydrate transmission network (403) is pipeline transportation; or hydrogen hydrate transmission network (403) vehicle transportation; or hydrogen pressure tank transportation; or hydrogen pipeline transportation;
  • Hydrogen cycle solar energy storage and hydrogen combustion system solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen hydrate combustion furnace unit, or hydrogen combustion furnace unit;
  • Hydrogen cycle solar energy storage and hydrogen fuel cell system solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen fuel cell unit; or hydrogen hydrate fuel cell unit;
  • Hydrogen cycle solar energy storage and hydrogen hydrate internal combustion engine solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen internal combustion engine unit; or hydrogen hydrate internal combustion engine unit;
  • the hydrogen hydrate solution uses an aqueous solution of a hydrogen surfactant
  • Hydrogen evolution of hydrogen hydrate hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution; the precipitated hydrogen enters the fuel cell, hydrogen reacts with air to realize hydrogen fuel cell power generation;
  • Hydrogen hydrate directly enters the fuel cell for power generation: Hydrogen hydrate solution (605), circulating hydrogen hydrate directly enters the fuel cell and oxygen in the air, reacts to generate electricity; or hydrogen hydrate solution (605) , Hydrate circulated into the hydrogen directly into the fuel cell and external oxygen, reaction power generation;
  • the solar energy storage and application system of the hydrogen cycle provide both a hydrogen combustion system and a fuel cell power generation system;
  • the solar energy storage and fuel cell power generation systems of the hydrogen cycle form grid-connected power generation and join the large power grid;
  • Excitation power supply the power generated by the hydrogen fuel cell is used to provide control power, or bias voltage, or configuration current for the system;
  • Hydrogen hydrate internal combustion engine use the existing diesel engine, hydrogen hydrate solution to replace diesel; or use the existing gasoline engine, hydrogen and hydrate solution to replace gasoline;
  • Hydrogen internal combustion engine either use the existing diesel engine to replace the hydrogen produced by diesel; or use the existing gasoline engine to replace the hydrogen produced by gasoline;
  • a hydrogen detection sensor to detect the hydrogen content of hydrogen hydrate: detect the hydrogen content in the hydrogen hydrate solution storage (001); or detect the hydrogen content in the hydrogen hydrate solution input pipe (206); or Detecting the hydrogen content in the inlet pipe (205) of the hydrate solution of the hydrogen gas; or detecting the hydrogen content in the solar hydrolyzed hydrogen generator (401); or detecting the hydrogen content in the solar hydrolyzed hydrogen generator field (402); or Detecting the hydrogen content in the hydrogen hydrate transmission network (403); or detecting the hydrogen content in the hydrogen hydrate filling station (404); or detecting the hydrogen content in the hydrogen hydrate piping system (405); or detecting the hydrogen hydrate
  • the structure of the solar hydrolyzed hydrogen generator includes: connecting an external water pipe (301), a water filtering unit (302), a deionized water unit (303), a water tank (304), connecting the water tank (304) and a solar hydrolytic hydrogen generator core unit (312) ) Connect water pipe (305), upper transparent electrode plate (306), upper transparent plate (307), aqueous solution (310), catalyst layer (311), lower electrode plate (309), lower support plate (308), lower end Board (313), upper end board (314), servo system (315);
  • the external water pipe (301) can be connected to tap water, well water, or other water tanks;
  • the water filtration unit (302) is connected to the external water source by connecting the external water pipe (301), and the water filtration unit (302) sends the filtered water to the deionized water unit (303); the water filtration unit (302) contains an activated carbon filter element, or molecular sieve The filter element, or the sponge filter element, or the cellulose filter element, filters out the particulate matter in the water, or the organism;
  • the deionized water unit (303) receives water from the water filtration unit (302), and after deionization, sends the deionized water to the water tank (304); the deionized water unit (303) contains ion exchange resin, or ion exchanger, or Ion exchange molecular sieve, or ion filter membrane; remove ions in water;
  • the water tank (304) uses gravity potential energy, or uses a water pump to send deionized water to the core unit (312) of the solar hydrogen hydrolysis generator;
  • the core unit (312) of the solar hydrolyzed hydrogen generator includes: an upper light-transmitting electrode plate (306), an upper light-transmitting plate (307), an aqueous solution (310), a catalyst layer (311), a lower electrode plate (309), and a lower support plate (308), lower end plate (313), upper end plate (314);
  • the upper transparent electrode plate (306) and the lower electrode plate (309) in the core unit (312) of the solar hydrogen hydrolysis hydrogen generator are connected to an external unit, and a voltage is applied to the core unit of the solar hydrogen hydrogen generator to promote water photolysis carry out;
  • the upper light-transmitting plate (307), the lower support plate (308), the lower end plate (313), and the upper end plate (314) provide support to the solar hydrolytic hydrogen generator core unit (312), forming a container to store the water to be photolyzed ; Provide support for the catalyst layer (311);
  • Upper transparent electrode plate (306), upper transparent plate (307) are two separate components; or upper transparent electrode plate (306), upper transparent plate (307) are the same component, ITO plate, or FTO plate , Or metal plated glass plate;
  • the lower electrode plate (309) and the lower support plate (308) are two independent components; or the lower electrode plate (309) and the lower support plate (308) are the same component, metal plate, or graphite plate, or the height of the conductive layer Molecular plate, or non-metallic material plated with conductive layer;
  • the upper light-transmitting electrode plate (306) constitutes an electrode, and the lower electrode plate (309) constitutes another electrode; applying voltage to the upper light-transmitting electrode plate (306) and the lower electrode plate (309) constitutes an electric field, which is a catalyst layer (311) Provide a bias voltage, or bias current, or electric field strength;
  • the catalyst layer (311) hydrolyzes water to hydrogen and oxygen under the combined action of sunlight and catalyst; or hydrolyzes water to hydrogen and oxygen under the combined action of sunlight, catalyst and electric field;
  • the servo system (315) controls the solar hydrolyzed hydrogen generator core unit (312), causes the solar hydrolyzed hydrogen generator core unit (312) to track sunlight, and enables the solar hydrolyzed hydrogen generator core unit (312) to vertically receive solar light, so that solar energy
  • the core unit (312) of the hydrolyzed hydrogen generator gets the most solar radiation
  • Hydrogen hydrate solution storage structure natural diffusion: For smaller solar hydrolyzed hydrogen systems, hydrogen can be naturally diffused in the hydrate;
  • the hydrogen inlet pipe (602) is connected to the hydrogen transmission pipe (203), and the hydrogen is input into the hydrogen hydrate solution storage tank (601), and the one-way valve (606) controls the hydrogen produced by the solar hydrolyzed hydrogen generator (202) to pass through Into the hydrogen hydrate solution storage tank (601), while preventing the hydrate solution in the hydrogen hydrate solution (605) from flowing back into the hydrogen hydrate solution storage tank (601); undissolved hydrogen (604) Input to the bottom of the hydrogen hydrate solution storage tank (601) through the diffusion pump (603), the undissolved hydrogen is continuously pumped unidirectionally through the diffusion pump (603) to continuously dissolve the hydrogen into the hydrogen hydrate solution;
  • Hydrogen evolution of hydrogen hydrate hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution;
  • Heating hydrogen evolution When the resistance wire (607) is energized, the hydrogen hydrate solution (605) is heated, and the solubility of hydrogen in the hydrogen hydrate solution (605) will be reduced, so that more hydrogen precipitates hydrogen hydrate solution (605) , Emit hydrogen;
  • Hydrogen hydrate solution (605) the hydrate circulating into the hydrogen directly flows into the hydrogen fuel cell and oxygen in the air to react to generate electricity; or the hydrogen hydrate solution (605), circulating into the hydrogen fuel cell to react with the added oxygen to generate electricity.
  • Excitation power supply The electricity generated by the hydrogen fuel cell provides control and bias voltage, or configuration current for the system; the control system of solar energy storage using the power generated by the hydrogen fuel cell for the hydrogen cycle, such as the servo system (315), The temperature sensor and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the electrode plate;
  • an external power source obtained from the rectification and stabilization of commercial power, or a battery, to provide control and bias voltage, or configure current for the system; use the power generated by the hydrogen fuel cell to control the solar energy storage system of the hydrogen cycle, such as servo The system (315), the temperature sensor, and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the electrode plate.
  • the hydrogen hydrate solution replaces the diesel, the hydrogen hydrate solution is injected into the third stroke, the hydrogen and the surfactant in the hydrate are mixed with the oxygen in the air to promote the piston to do work;
  • pipelines or pressure tanks to transport hydrogen or hydrogen hydration liquid
  • hydrogen combustion furnaces use existing fuel furnaces to burn naturally: pipelines or pressure tanks connect to gas stoves, and pipelines or pressure tanks connect to gas stoves to transport hydrogen or hydrogen hydration liquids;
  • Compressed hydrogen in the pipeline or compressed hydrogen in the pressure tank is connected to the gas stove through the pressure reducing valve. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use, while releasing pure water without pollution;
  • the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the gas stove through the pressure reducing valve.
  • the hydrogen hydrate precipitates hydrogen after decompression. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use and released at the same time. Pure water without pollution;
  • the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the heater.
  • the heater heats the hydrogen hydrate.
  • the hydrogen hydrate precipitates hydrogen after heating. After ignition, the hydrogen and the oxygen in the air burn to obtain thermal energy for human use. At the same time, release pure water without pollution;
  • the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the reactor, the hydrogen hydrate reactant is added to the hydrogen hydrate in the reactor, and the hydrogen hydrate precipitates hydrogen gas by adding the hydrogen surfactant reactant and is ignited. Hydrogen and oxygen in the air are burned to obtain heat energy for human use, while releasing pure water without pollution.
  • Hydrogen production for solar energy hydrolysis, storage of hydrogen, transportation of hydrogen, and application of hydrogen form a complete system, providing a perfect practical system for the practical application of solar hydrogen circulation.
  • Hydrogen is generated by sunlight decomposing water, and the solar energy is stored in the chemical energy of hydrogen; hydrogen is transported through pipelines or pressure tanks, or hydrogen dissolved in hydrogen hydrate is transported through pipelines or pressure tanks; hydrogen dissolved in hydrogen hydrates is reduced by Hydrogen evolution by pressurization, or hydrogen evolution by heating, or hydrogenation reaction of hydrogenated hydrate surfactants, referred to as reaction hydrogen evolution; hydrogen or hydrogen hydrate produces water by burning gas stoves with oxygen in the air, releasing heat for domestic or industrial use; hydrogen Or hydrogen hydrate is delivered to vehicles or factories through pipelines or pressure tanks for internal combustion engines to power cars or machines; hydrogen or hydrogen hydrate is delivered to vehicles through pipelines or pressure tanks or hydrogen fuel cells in factories are used to generate electricity , For life, or industry, or automotive power use; to form a solar energy storage based on hydrogen cycle, using a clean energy cycle system;
  • Hydrogen small cycle solar energy hydrogen production on home roof, hydrogen hydrate storage, pipeline or pressure delivery of hydrogen or hydrogen hydrate tank connected to gas stove to burn for heat, pipeline hydrogen transmission or connected fuel cell for power generation, for household use; or fuel cell and Generate electricity from the grid and sell it to a large power grid; or use it in a family car, or sell it to a hydrogen refueling station, or sell it to a tanker;
  • Hydrogen cycle solar hydrolyzed hydrogen generator, solar hydrolyzed hydrogen generator field, the generated hydrogen is transported to the hydrogen hydrate filling station through the hydrogen hydrate transportation network, or to the hydrogen hydrate pipeline system, or to the hydrogen hydration Mobile charging vehicle; hydrogen hydrate transmission network is pipeline transportation; or hydrogen hydrate transmission network vehicle transportation; user end includes gas stove, fuel cell, hydrogen internal combustion engine;
  • a solar hydrolysis and hydrogen hydrate storage unit a hydrogen hydrate solution storage (001), a solar hydrogen hydrolysis generator (003), a hydrogen transmission tube (002), a hydrate hydrogen content test unit (004) ; Realize hydrogen production by solar energy hydrolysis, hydrogen dissolved in hydrogen hydrate;
  • solar hydrolysis hydrogen production hydrogen storage, gas furnace small cycle; hydrogen hydrate solution storage (101), solar hydrogen hydrolysis generator (102), hydrogen transmission tube (103), hydrogen combustion furnace (104 ), Hydrogen hydrate solution input pipe (106), hydrogen hydrate solution return pipe input pipe (105);
  • the water in the solar hydrolyzed hydrogen generator (102) is photolyzed into hydrogen and oxygen, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (103) Storage (101), where hydrogen gas is dissolved into a hydrate solution of hydrogen gas to realize storage of hydrogen gas;
  • the circulation pump of the hydrogen combustion furnace (104) is started, the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (106), and the hydrogen hydrate solution storage (101)
  • the hydrogen hydrate solution in the hydrogen is sent to the hydrogen combustion furnace (104) to precipitate hydrogen.
  • the hydrogen burns with the oxygen in the air in the hydrogen combustion furnace (104) to generate heat for human use; the hydrate solution of the precipitated hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (101) through the hydrogen hydrate solution return pipe inlet pipe (105);
  • solar hydrolysis hydrogen production, energy storage, fuel cell small cycle As shown in Fig. 3, solar hydrolysis hydrogen production, energy storage, fuel cell small cycle; hydrogen hydrate solution storage (201), solar hydrogen hydrolysis generator (202), hydrogen transmission tube (203), hydrogen combustion battery (204 ), Hydrogen hydrate solution input pipe (206), hydrogen hydrate solution return pipe input pipe (205);
  • the water in the solar hydrogen hydrolysis generator (202) is photolyzed into hydrogen and oxygen under the irradiation of sunlight, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (203)
  • the storage (201), hydrogen gas is dissolved into the hydrogen hydrate solution to realize the storage of hydrogen gas;
  • the hydrogen fuel cell (204) needs hydrogen, start the circulation pump of the hydrogen fuel cell (204), the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (206), and the hydrogen hydrate solution storage (201) The hydrogen hydrate solution is sent to the hydrogen fuel cell (204) to precipitate hydrogen.
  • the hydrogen is burned in the hydrogen fuel cell (204) and the oxygen in the air burns to generate heat for human use; the hydrate solution storage of the hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (201) through the hydrogen hydrate solution return pipe inlet pipe (205);
  • solar hydrolysis hydrogen production hydrogen storage, transportation, application of large cycles; solar hydrogen hydrolysis generator (401), solar hydrogen hydrolysis generator field (402), hydrogen hydrate transmission network (403), hydrogen Hydrate filling station (404), hydrogen hydrate pipeline system (405), hydrogen hydrate mobile filling vehicle (406);
  • the solar hydrolyzed hydrogen generator (401) is a small solar hydrolyzed hydrogen generator, which can be placed in a place where it can get sunlight;
  • the solar hydrolyzed hydrogen generator field (402) is an array of large-scale solar hydrolyzed hydrogen generators, which can produce Of hydrogen
  • the hydrogen produced by the solar hydrolyzed hydrogen generator (401) and the solar hydrolyzed hydrogen generator field (402) is transported to the hydrogen hydrate filling station (404) through the hydrogen hydrate transmission network (403) or to the hydrogen hydrate pipeline system (405), or transport to the mobile filling vehicle for hydrogen hydrate (406);
  • Hydrogen hydrate transmission network (403) is pipeline transportation; or hydrogen hydrate transmission network (403) vehicle transportation; or hydrogen pressure tank transportation; or hydrogen pipeline transportation;
  • Hydrogen cycle solar energy storage and hydrogen combustion system solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen hydrate combustion furnace unit, or hydrogen combustion furnace unit;
  • Hydrogen cycle solar energy storage and hydrogen fuel cell system solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen fuel cell unit; or hydrogen hydrate fuel cell unit;
  • Hydrogen cycle solar energy storage and hydrogen hydrate internal combustion engine solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen internal combustion engine unit; or hydrogen hydrate internal combustion engine unit;
  • the hydrogen hydrate solution uses an aqueous solution of a hydrogen surfactant
  • Hydrogen evolution of hydrogen hydrate hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution; the precipitated hydrogen enters the fuel cell, hydrogen reacts with air to realize hydrogen fuel cell power generation;
  • Hydrogen hydrate directly enters the fuel cell for power generation: Hydrogen hydrate solution (605), circulating hydrogen hydrate directly enters the fuel cell and oxygen in the air, reacts to generate electricity; or hydrogen hydrate solution (605) , Hydrate circulated into hydrogen directly into the fuel cell and external oxygen, reaction power generation;
  • the solar energy storage and application system of the hydrogen cycle provide both a hydrogen combustion system and a fuel cell power generation system;
  • the solar energy storage and fuel cell power generation systems of the hydrogen cycle form grid-connected power generation and join the large power grid;
  • Excitation power supply the power generated by the hydrogen fuel cell is used to provide control power, or bias voltage, or configuration current for the system;
  • Hydrogen hydrate internal combustion engine use the existing diesel engine, hydrogen hydrate solution to replace diesel; or use the existing gasoline engine, hydrogen and hydrate solution to replace gasoline;
  • Hydrogen internal combustion engine Either use the existing diesel engine to replace the precipitated hydrogen with diesel; or use the existing gasoline engine to replace the precipitated hydrogen with gasoline;
  • a hydrogen detection sensor to detect the hydrogen content of hydrogen hydrate: detect the hydrogen content in the hydrogen hydrate solution storage (001); or detect the hydrogen content in the hydrogen hydrate solution input pipe (206); or Detecting the hydrogen content in the inlet pipe (205) of the hydrate solution of the hydrogen gas; or detecting the hydrogen content in the solar hydrolyzed hydrogen generator (401); or detecting the hydrogen content in the solar hydrolyzed hydrogen generator field (402); or Detecting the hydrogen content in the hydrogen hydrate transmission network (403); or detecting the hydrogen content in the hydrogen hydrate filling station (404); or detecting the hydrogen content in the hydrogen hydrate piping system (405); or detecting the hydrogen hydrate
  • the structure of the solar hydrolyzed hydrogen generator includes: connecting an external water pipe (301), a water filtering unit (302), a deionized water unit (303), a water tank (304), and connecting the water tank (304) to solar hydrolyzed hydrogen
  • the generator core unit (312) is connected to the water pipe (305), upper transparent electrode plate (306), upper transparent plate (307), aqueous solution (310), catalyst layer (311), lower electrode plate (309), lower support Board (308), lower end board (313), upper end board (314), servo system (315);
  • the external water pipe (301) can be connected to tap water, well water, or other water tanks;
  • the water filtration unit (302) is connected to the external water source by connecting the external water pipe (301), and the water filtration unit (302) sends the filtered water to the deionized water unit (303); the water filtration unit (302) contains an activated carbon filter element, or molecular sieve The filter element, or the sponge filter element, or the cellulose filter element, filters out the particulate matter in the water, or the organism;
  • the deionized water unit (303) receives water from the water filtration unit (302), and after deionization, sends the deionized water to the water tank (304); the deionized water unit (303) contains ion exchange resin, or ion exchanger, or Ion exchange molecular sieve, or ion filter membrane; remove ions in water;
  • the water tank (304) uses gravity potential energy, or uses a water pump to send deionized water to the core unit (312) of the solar hydrogen hydrolysis generator;
  • the core unit (312) of the solar hydrolyzed hydrogen generator includes: an upper light-transmitting electrode plate (306), an upper light-transmitting plate (307), an aqueous solution (310), a catalyst layer (311), a lower electrode plate (309), and a lower support plate (308), lower end plate (313), upper end plate (314);
  • the upper transparent electrode plate (306) and the lower electrode plate (309) in the core unit (312) of the solar hydrogen hydrolysis hydrogen generator are connected to an external unit, and a voltage is applied to the core unit of the solar hydrogen hydrogen generator to promote water photolysis carry out;
  • the upper light-transmitting plate (307), the lower support plate (308), the lower end plate (313), and the upper end plate (314) provide support to the solar hydrolytic hydrogen generator core unit (312), forming a container to store the water to be photolyzed ; Provide support for the catalyst layer (311);
  • Upper transparent electrode plate (306), upper transparent plate (307) are two separate components; or upper transparent electrode plate (306), upper transparent plate (307) are the same component, ITO plate, or FTO plate , Or metal plated glass plate;
  • the lower electrode plate (309) and the lower support plate (308) are two independent components; or the lower electrode plate (309) and the lower support plate (308) are the same component, metal plate, or graphite plate, or the height of the conductive layer Molecular plate, or non-metallic material plated with conductive layer;
  • the upper light-transmitting electrode plate (306) constitutes an electrode, and the lower electrode plate (309) constitutes another electrode; applying voltage to the upper light-transmitting electrode plate (306) and the lower electrode plate (309) constitutes an electric field, which is a catalyst layer (311) Provide a bias voltage, or bias current, or electric field strength;
  • the catalyst layer (311) hydrolyzes water to hydrogen and oxygen under the combined action of sunlight and catalyst; or hydrolyzes water to hydrogen and oxygen under the combined action of sunlight, catalyst and electric field;
  • the servo system (315) controls the solar hydrolyzed hydrogen generator core unit (312), causes the solar hydrolyzed hydrogen generator core unit (312) to track sunlight, and enables the solar hydrolyzed hydrogen generator core unit (312) to vertically receive solar light, so that solar energy
  • the core unit (312) of the hydrolyzed hydrogen generator gets the most solar radiation
  • Hydrogen hydrate solution storage structure natural diffusion: For smaller solar energy hydrolyzed hydrogen systems, hydrogen can be used to diffuse naturally in the hydrate;
  • the hydrogen inlet pipe (602) is connected to the hydrogen transmission pipe (203), and the hydrogen is input into the hydrogen hydrate solution storage tank (601), and the one-way valve (606) controls the hydrogen produced by the solar hydrolyzed hydrogen generator (202) to pass through Into the hydrogen hydrate solution storage tank (601), while preventing the hydrate solution in the hydrogen hydrate solution (605) from flowing back into the hydrogen hydrate solution storage tank (601); undissolved hydrogen (604) Input to the bottom of the hydrogen hydrate solution storage tank (601) through the diffusion pump (603), the undissolved hydrogen is continuously pumped unidirectionally through the diffusion pump (603) to continuously dissolve the hydrogen into the hydrogen hydrate solution;
  • Hydrogen evolution of hydrogen hydrate hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution;
  • decompression hydrogen evolution After part of the hydrogen is pumped out with a hydrogen aspirator (608), the solubility of hydrogen in the hydrogen hydrate solution (605) will decrease, so that more hydrogen will evolve out of the hydrogen hydrate solution ( 605), release hydrogen gas;
  • Heating hydrogen evolution When the resistance wire (607) is energized, the hydrogen hydrate solution (605) is heated, and the solubility of hydrogen in the hydrogen hydrate solution (605) will be reduced, so that more hydrogen precipitates hydrogen hydrate solution (605) , Emit hydrogen;
  • Hydrogen hydrate solution (605) the hydrate circulating into the hydrogen directly flows into the hydrogen fuel cell and oxygen in the air to react to generate electricity; or the hydrogen hydrate solution (605), circulating into the hydrogen fuel cell to react with the added oxygen to generate electricity.
  • Excitation power supply The electricity generated by the hydrogen fuel cell provides control and bias voltage, or configuration current for the system; the control system of solar energy storage using the power generated by the hydrogen fuel cell for the hydrogen cycle, such as the servo system (315), The temperature sensor and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the electrode plate;
  • an external power source obtained from the rectification and stabilization of commercial power, or a battery, to provide control and bias voltage, or configure current for the system; use the power generated by the hydrogen fuel cell to control the solar energy storage system of the hydrogen cycle, such as servo The system (315), the temperature sensor, and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the plate.
  • the hydrogen hydrate solution replaces the diesel, the hydrogen hydrate solution is injected into the third stroke, the hydrogen and the surfactant in the hydrate are mixed with the oxygen in the air to promote the piston to do work;
  • pipelines or pressure tanks to transport hydrogen or hydrogen hydration liquid
  • hydrogen combustion furnaces use existing fuel furnaces to burn naturally: pipelines or pressure tanks connect to gas stoves, and pipelines or pressure tanks connect to gas stoves to transport hydrogen or hydrogen hydration liquids;
  • Compressed hydrogen in the pipeline or compressed hydrogen in the pressure tank is connected to the gas stove through the pressure reducing valve. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use, while releasing pure water without pollution;
  • the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the gas stove through the pressure reducing valve.
  • the hydrogen hydrate precipitates hydrogen after decompression. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use and released at the same time. Pure water without pollution;
  • the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the heater.
  • the heater heats the hydrogen hydrate.
  • the hydrogen hydrate precipitates hydrogen after heating. After ignition, the hydrogen and the oxygen in the air burn to obtain thermal energy for human use. At the same time, release pure water without pollution;
  • the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the reactor, the hydrogen hydrate reactant is added to the hydrogen hydrate in the reactor, and the hydrogen hydrate precipitates hydrogen gas by adding the hydrogen surfactant reactant and is ignited. Hydrogen and oxygen in the air are burned to obtain heat energy for human use, while releasing pure water without pollution.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

Disclosed is a hydrogen cycle-based solar hydrogen production, storage and application system, the system involving: solar hydrolysis production of hydrogen, wherein a servo system uses a surfactant hydration liquid to achieve dissolution of hydrogen in a hydrogen hydrate, with the hydrogen being pressure-dissolved in the hydrogen hydrate; evolution of hydrogen from the hydrogen hydrate under a reduced pressure, evolution of hydrogen from the hydrogen hydrate by means of heating, and evolution of hydrogen by adding a reactant of the hydrogen surfactant to the hydrogen hydrate; transportation of hydrogen using a pipeline or pressure tank, or transportation of a hydrogen-containing hydrogen hydrate using a pipeline or pressure tank; connection of the pipeline or pressure tank to a gas stove for combustion to obtain heat energy; connection of the pipeline or pressure tank to a fuel cell for electricity generation; a small hydrogen cycle by means of the hydrogen cycle-based solar hydrogen production, storage and application system; and a large hydrogen cycle by means of the hydrogen cycle-based solar hydrogen production, storage and application system. A complete system is established for the solar hydrolysis production of hydrogen, hydrogen storage, hydrogen transport and hydrogen application, and a perfect practical system is provided for the implementation of a solar hydrogen cycle.

Description

基于氢循环的太阳能制氢、储氢与应用系统Solar hydrogen production, hydrogen storage and application system based on hydrogen cycle 技术领域Technical field

本发明涉及基于氢循环的太阳能制氢、储氢与应用系统，特别涉及氢水合物的管道或压力罐存储的氢循环的太阳能储能与应用系统。The invention relates to a solar cycle hydrogen production, hydrogen storage and application system based on a hydrogen cycle, in particular to a hydrogen cycle solar energy storage and application system stored in a pipeline or a pressure tank of hydrogen hydrate.

背景技术Background technique

专利申请号：201610991758.5光催化效应电池 申请日2016年11月5日 发明人：顾士平 顾海涛Patent application number: 201610991758.5 Photocatalytic effect battery Application date November 5, 2016 Inventor: Gu Shiping Gu Haitao

专利申请号：201810051597.0电光充电、充氢燃料电池 申请日2018年1月19日 发明人：顾士平 顾海涛Patent application number: 201810051597.0 Electro-optical charging, hydrogen-filled fuel cell Application date January 19, 2018 Inventor: Gu Shiping Gu Haitao

技术问题technical problem

解决基于氢循环的产生、存储、输运、应用问题。Solve the problems of generation, storage, transportation and application based on the hydrogen cycle.

技术解决方案Technical solution

太阳光解水生成氢气，将太阳能存储在氢气的化学能中；氢气通过管道或压力罐输送，或氢溶解于氢水合物中通过管道或压力罐输送；溶解于氢水合物中的氢通过减压析氢，或加热析氢，或加氢水合物表面活性剂的反应物析氢，简称反应析氢；氢气或氢水合物通过燃气灶与空气中的氧气燃烧生产水，放出热量供生 活或工业使用；氢气或氢水合物通过管道或压力罐输送到车辆上或工厂，供内燃机使用，为汽车或机器提供动力；氢气或氢水合物通过管道或压力罐输送到车辆上，或供工厂的氢燃料电池发电，供生活，或工业，或汽车动力使用；形成基于氢循环的太阳能储能，使用的清洁能源循环系统；Hydrogen is generated by sunlight decomposing water, and the solar energy is stored in the chemical energy of hydrogen; hydrogen is transported through pipelines or pressure tanks, or hydrogen dissolved in hydrogen hydrate is transported through pipelines or pressure tanks; hydrogen dissolved in hydrogen hydrates is reduced by Hydrogen evolution by pressurization, or hydrogen evolution by heating, or hydrogenation reaction of hydrogenated hydrate surfactants, referred to as reaction hydrogen evolution; hydrogen or hydrogen hydrate produces water by burning gas stoves with oxygen in the air, releasing heat for domestic or industrial use; hydrogen Or hydrogen hydrate is delivered to vehicles or factories through pipelines or pressure tanks for internal combustion engines to power cars or machines; hydrogen or hydrogen hydrate is delivered to vehicles through pipelines or pressure tanks or hydrogen fuel cells in factories are used to generate electricity , For life, or industry, or automotive power use; to form a solar energy storage based on hydrogen cycle, using a clean energy cycle system;

氢小循环：家庭屋顶太阳能制氢，氢水合物储氢，管道或压力输送氢气或氢水合物罐连接燃气灶燃烧取热，管道输氢或连接燃料电池发电，供家庭使用；或燃料电池并网发电，售电给大电网；或加入家用汽车使用，或售给加氢站，或售给收购槽车；Hydrogen small cycle: solar energy hydrogen production on home roof, hydrogen hydrate storage, pipeline or pressure delivery of hydrogen or hydrogen hydrate tank connected to gas stove to burn for heat, pipeline hydrogen transmission or connected fuel cell for power generation, for household use; or fuel cell and Generate electricity from the grid and sell it to a large power grid; or use it in a family car, or sell it to a hydrogen refueling station, or sell it to a tanker;

氢大循环：太阳能水解氢发生器，太阳能水解氢发生器场，产生的氢气通过氢水合物输运网络运输到氢气水合物加注站，或运输到氢气水合物管道系统，或运输到氢气水合物移动加注车；氢水合物传输网络是管道输送；或氢水合物传输网络车辆运输；用户端包括燃气灶，燃料电池，氢内燃机；Hydrogen cycle: solar hydrolyzed hydrogen generator, solar hydrolyzed hydrogen generator field, the generated hydrogen is transported to the hydrogen hydrate filling station through the hydrogen hydrate transportation network, or to the hydrogen hydrate pipeline system, or to the hydrogen hydration Mobile refueling vehicle; hydrogen hydrate transmission network is pipeline transportation; or hydrogen hydrate transmission network vehicle transportation; user terminal includes gas stove, fuel cell, hydrogen internal combustion engine;

太阳能水解及氢水合物存储单元；氢气的水合物溶液存储器(001)，太阳能水解氢发生器(003)，氢气传输管(002)，水合物氢含量测试单元(004)；实现太阳能水解制氢，氢溶解于氢水合物；Solar Hydrolysis and Hydrogen Hydrate Storage Unit; Hydrogen Hydrate Solution Storage (001), Solar Hydrogen Hydrogen Generator (003), Hydrogen Transmission Tube (002), Hydrate Hydrogen Content Test Unit (004); Realize Solar Hydrogen Production , Hydrogen dissolved in hydrogen hydrate;

太阳能水解制氢、氢存储、燃气炉小循环；氢气的水合物溶液存储器(101)，太阳能水解氢发生器(102)，氢气传输管(103)，氢气燃烧炉(104)，氢气的水合物溶液输入管(106)，氢气的水合物溶液回流管输入管(105)；Solar hydrolysis hydrogen production, hydrogen storage, gas furnace small cycle; hydrogen hydrate solution storage (101), solar hydrogen hydrolysis generator (102), hydrogen transmission tube (103), hydrogen combustion furnace (104), hydrogen hydrate Solution inlet pipe (106), hydrogen hydrate solution return pipe inlet pipe (105);

太阳能水解氢发生器(102)中的水在太阳光的照射下，光解为氢气和氧气，氧气直接排放到空气中；产生的氢气通过氢气传输管(103)，送到氢气的水合物溶液存储器(101)，氢气溶解到氢气的水合物溶液中，实现氢气的存储；Under the irradiation of sunlight, the water in the solar hydrolyzed hydrogen generator (102) is photolyzed into hydrogen and oxygen, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (103) Storage (101), where hydrogen gas is dissolved into a hydrate solution of hydrogen gas to realize storage of hydrogen gas;

当氢气燃烧炉(104)需要燃烧氢气时，启动氢气燃烧炉(104)的循环泵，氢气的水合物溶液通过氢气的水合物溶液输入管(106)，将氢气的水合物溶液存储器(101)中的氢气的水合物溶液，送到氢气燃烧炉(104)析出氢气，氢气在氢气燃烧炉(104)与空气中的氧气燃烧，产生热量，供人类使用；析出了氢气的水合物溶液存储器在循环泵的作用下，通过氢气的水合物溶液回流管输入管(105)回到氢气的水合物溶液存储器(101)；When the hydrogen combustion furnace (104) needs to burn hydrogen, the circulation pump of the hydrogen combustion furnace (104) is started, the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (106), and the hydrogen hydrate solution storage (101) The hydrogen hydrate solution in the hydrogen is sent to the hydrogen combustion furnace (104) to precipitate hydrogen. The hydrogen burns with the oxygen in the air in the hydrogen combustion furnace (104) to generate heat for human use; the hydrate solution of the precipitated hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (101) through the hydrogen hydrate solution return pipe inlet pipe (105);

太阳能水解制氢、储能、燃料电池小循环；氢气的水合物溶液存储器(201)，太阳能水解氢发生器(202)，氢气传输管(203)，氢气燃烧电池(204)，氢气的水合物溶液输入管(206)，氢气的水合物溶液回流管输入管(205)；Solar hydrolysis hydrogen production, energy storage, fuel cell small cycle; hydrogen hydrate solution storage (201), solar hydrogen hydrolysis generator (202), hydrogen transmission tube (203), hydrogen combustion cell (204), hydrogen hydrate Solution inlet pipe (206), hydrogen hydrate solution return pipe inlet pipe (205);

太阳能水解氢发生器(202)中的水在太阳光的照射下，光解为氢气和氧气，氧气直接排放到空气中；产生的氢气通过氢气传输管(203)，送到氢气的水合物溶液存储器(201)，氢气溶解到氢气的水合物溶液中，实现氢气的存储；The water in the solar hydrogen hydrolysis generator (202) is photolyzed into hydrogen and oxygen under the irradiation of sunlight, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (203) The storage (201), hydrogen gas is dissolved into the hydrogen hydrate solution to realize the storage of hydrogen gas;

当氢气燃料电池(204)需要氢气时，启动氢气燃料电池(204)的循环泵，氢气的水合物溶液通过氢气的水合物溶液输入管(206)，将氢气的水合物溶液存储器(201)中的氢气的水合物溶 液，送到氢气燃料电池(204)析出氢气，氢气燃烧在氢气燃料电池(204)与空气中的氧气燃烧，产生热量，供人类使用；析出了氢气的水合物溶液存储器在循环泵的作用下，通过氢气的水合物溶液回流管输入管(205)回到氢气的水合物溶液存储器(201)；When the hydrogen fuel cell (204) needs hydrogen, start the circulation pump of the hydrogen fuel cell (204), the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (206), and the hydrogen hydrate solution storage (201) The hydrogen hydrate solution is sent to the hydrogen fuel cell (204) to precipitate hydrogen. The hydrogen is burned in the hydrogen fuel cell (204) and the oxygen in the air burns to generate heat for human use; the hydrate solution storage of the hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (201) through the hydrogen hydrate solution return pipe inlet pipe (205);

太阳能水解制氢、储氢、输运、应用大循环；太阳能水解氢发生器(401)，太阳能水解氢发生器场(402)，氢水合物传输网络(403)，氢气水合物加注站(404)，氢气水合物管道系统(405)，氢气水合物移动加注车(406)；Solar hydrolysis hydrogen production, hydrogen storage, transportation, application of large cycles; solar hydrogen hydrolysis generator (401), solar hydrogen hydrolysis generator field (402), hydrogen hydrate transmission network (403), hydrogen hydrate filling station ( 404), hydrogen hydrate pipeline system (405), hydrogen hydrate mobile filling vehicle (406);

太阳能水解氢发生器(401)为小型的太阳能水解氢发生器，可以放在能得到阳光照射的地方；太阳能水解氢发生器场(402)为大型的太阳能水解氢发生器的阵列，能产生大量的氢气；The solar hydrolyzed hydrogen generator (401) is a small solar hydrolyzed hydrogen generator, which can be placed in a place where it can receive sunlight; the solar hydrolyzed hydrogen generator field (402) is an array of large-scale solar hydrolyzed hydrogen generators, which can produce a large amount of Of hydrogen

太阳能水解氢发生器(401)，太阳能水解氢发生器场(402)产生的氢气通过氢水合物传输网络(403)运输到氢气水合物加注站(404)，或运输到氢气水合物管道系统(405)，或运输到氢气水合物移动加注车(406)；The hydrogen produced by the solar hydrolyzed hydrogen generator (401) and the solar hydrolyzed hydrogen generator field (402) is transported to the hydrogen hydrate filling station (404) through the hydrogen hydrate transmission network (403) or to the hydrogen hydrate pipeline system (405), or transport to the mobile filling vehicle for hydrogen hydrate (406);

氢水合物传输网络(403)是管道输送；或氢水合物传输网络(403)车辆运输；或氢气的压力罐运输；或氢气的管道运输；Hydrogen hydrate transmission network (403) is pipeline transportation; or hydrogen hydrate transmission network (403) vehicle transportation; or hydrogen pressure tank transportation; or hydrogen pipeline transportation;

创新点：Innovation:

(1)氢循环的太阳能储能与氢气燃烧系统：太阳能水解氢单元，氢气溶入氢水合物，氢气水合物燃烧炉单元，或氢燃烧炉单元；(1) Hydrogen cycle solar energy storage and hydrogen combustion system: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen hydrate combustion furnace unit, or hydrogen combustion furnace unit;

(2)氢循环的太阳能储能与氢气燃料电池系统：太阳能水解 氢单元，氢气溶入氢水合物，氢气燃料电池单元；或氢水合物燃料电池单元；(2) Hydrogen cycle solar energy storage and hydrogen fuel cell system: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen fuel cell unit; or hydrogen hydrate fuel cell unit;

(3)氢循环的太阳能储能与氢气水合物内燃机：太阳能水解氢单元，氢气溶入氢水合物，氢气内燃机单元；或氢水合物内燃机单元；(3) Hydrogen cycle solar energy storage and hydrogen hydrate internal combustion engine: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen internal combustion engine unit; or hydrogen hydrate internal combustion engine unit;

(4)太阳能水解氢发生器结构：水净化单元，去离子净化单元，太阳能水解氢发生器核心单元，太阳能水解氢发生器的伺服系统；(4) Structure of solar hydrogen hydrolysis hydrogen generator: water purification unit, deionization purification unit, solar hydrogen hydrolysis hydrogen generator core unit, servo system of solar hydrogen hydrolysis hydrogen generator;

(5)氢气水合物溶液采用氢表面活性剂的水溶液；(5) The hydrogen hydrate solution uses an aqueous solution of a hydrogen surfactant;

(6)氢气的水合物溶液存储器的结构，自然扩散：产生的氢气由氢表面活性剂的水溶液底部通入，或氢气由氢气与氢气水合物的界面扩散，氢气通过自然扩散实现氢气溶解到氢表面活性剂的水溶液中；(6) The structure of hydrogen hydrate solution storage, natural diffusion: the generated hydrogen is introduced from the bottom of the aqueous solution of hydrogen surfactant, or the hydrogen diffuses from the interface of hydrogen and hydrogen hydrate, and hydrogen dissolves into hydrogen through natural diffusion Surfactant in aqueous solution;

(7)氢气的水合物溶液存储器的结构，泵驱动扩散：通过泵的循环推动，将氢气溶解到氢表面活性剂的水溶液中；(7) The structure of hydrogen hydrate solution storage, pump-driven diffusion: through the circulation of the pump, the hydrogen is dissolved into the aqueous solution of hydrogen surfactant;

(8)氢气的水合物析氢，氢气进入燃料电池发电：减压析氢；加温析氢；添加氢表面活性剂反应物析氢；析出的氢气进入燃料电池，氢气与空气反应实现氢燃料电池发电；(8) Hydrogen evolution of hydrogen hydrate, hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution; the precipitated hydrogen enters the fuel cell, hydrogen reacts with air to realize hydrogen fuel cell power generation;

(9)氢气的水合物直接进入燃料电池发电：氢气的水合物溶液(605)，循环流入氢气的水合物直接进入燃料电池与空气中的氧气，反应发电；或氢气的水合物溶液(605)，循环流入氢气的水合物直接进入燃料电池与外加氧气， 反应发电；(9) Hydrogen hydrate directly enters the fuel cell for power generation: Hydrogen hydrate solution (605), circulating hydrogen hydrate directly enters the fuel cell and oxygen in the air, reacts to generate electricity; or hydrogen hydrate solution (605) , Hydrate circulated into the hydrogen directly into the fuel cell and external oxygen, reaction power generation;

(10)氢循环的太阳能储能与应用系统同时提供氢气燃烧系统和燃料电池发电系统；(10) The solar energy storage and application system of the hydrogen cycle provide both a hydrogen combustion system and a fuel cell power generation system;

(11)氢循环的太阳能储能和燃料电池发电系统组成微网；(11) The solar energy storage and fuel cell power generation system of the hydrogen cycle form a microgrid;

(12)氢循环的太阳能储能和燃料电池发电系统组成并网发电，加入大电网；(12) The solar energy storage and fuel cell power generation systems of the hydrogen cycle form grid-connected power generation and join the large power grid;

(13)励电电源：用氢燃料电池产生的电，为系统提供控制电源，或偏置电压，或配置电流；(13) Excitation power supply: the power generated by the hydrogen fuel cell is used to provide control power, or bias voltage, or configuration current for the system;

(14)氢水合物内燃机：利用现有的柴油机，氢气的水合物溶液代替柴油；或者利用现有的汽油机，氢气及水合物溶液代替汽油；(14) Hydrogen hydrate internal combustion engine: use the existing diesel engine, hydrogen hydrate solution to replace diesel; or use the existing gasoline engine, hydrogen and hydrate solution to replace gasoline;

(15)氢气内燃机：或者利用现有的柴油机，将析出的氢气代替柴油；或者利用现有的汽油机，将析出的氢气代替汽油；(15) Hydrogen internal combustion engine: either use the existing diesel engine to replace the hydrogen produced by diesel; or use the existing gasoline engine to replace the hydrogen produced by gasoline;

(16)氢气燃烧炉的结构，自然燃烧：利用管道或压力罐输送氢气；氢气在燃烧炉中自然燃烧；利用管道或压力罐输送氢水合物；氢水合物在燃烧炉中自然燃烧；(16) The structure of a hydrogen combustion furnace, natural combustion: use pipelines or pressure tanks to transport hydrogen; hydrogen burns naturally in the furnace; use pipelines or pressure tanks to transport hydrogen hydrate; hydrogen hydrate naturally burns in the furnace;

(17)利用氢检测传感器，检测氢水合物的含氢量：检测氢气的水合物溶液存储器(001)中的氢含量；或检测氢气的水合物溶液输入管(206)中的氢含量；或检测氢气的水合物溶液回流管输入管(205)中的氢含量；或检测太阳能水解氢发生器(401)中的氢含量；或检测太阳能水解 氢发生器场(402)中的氢含量；或检测氢水合物传输网络(403)中的氢含量；或检测氢气水合物加注站(404)中的氢含量；或检测氢气水合物管道系统(405)中的氢含量；或检测氢气水合物移动加注车(406)中的氢含量；或检测氢气加注机中的氢气水合物中的氢含量；或检测车辆氢水合物中箱中的氢含量；或检测燃气中的氢含量。(17) Use a hydrogen detection sensor to detect the hydrogen content of hydrogen hydrate: detect the hydrogen content in the hydrogen hydrate solution storage (001); or detect the hydrogen content in the hydrogen hydrate solution input pipe (206); or Detecting the hydrogen content in the inlet pipe (205) of the hydrate solution of the hydrogen gas; or detecting the hydrogen content in the solar hydrolyzed hydrogen generator (401); or detecting the hydrogen content in the solar hydrolyzed hydrogen generator field (402); or Detecting the hydrogen content in the hydrogen hydrate transmission network (403); or detecting the hydrogen content in the hydrogen hydrate filling station (404); or detecting the hydrogen content in the hydrogen hydrate piping system (405); or detecting the hydrogen hydrate The hydrogen content in the mobile filling vehicle (406); or the hydrogen content in the hydrogen hydrate in the hydrogen filling machine; or the hydrogen content in the tank in the hydrogen hydrate of the vehicle; or the hydrogen content in the fuel gas.

太阳能水解氢发生器结构包括：连接外来水管(301)，水过滤单元(302)，去离子水单元(303)，水箱(304)，连接水箱(304)与太阳能水解氢发生器核心单元(312)连接水管(305)，上层透光电极板(306)，上层透光板(307)，水溶液(310)，催化剂层(311)，下层电极板(309)，下层支撑板(308)，下端板(313)，上端板(314)，伺服系统(315)；The structure of the solar hydrolyzed hydrogen generator includes: connecting an external water pipe (301), a water filtering unit (302), a deionized water unit (303), a water tank (304), connecting the water tank (304) and a solar hydrolytic hydrogen generator core unit (312) ) Connect water pipe (305), upper transparent electrode plate (306), upper transparent plate (307), aqueous solution (310), catalyst layer (311), lower electrode plate (309), lower support plate (308), lower end Board (313), upper end board (314), servo system (315);

连接外来水管(301)可连接自来水，或井水，或其它水箱的水；The external water pipe (301) can be connected to tap water, well water, or other water tanks;

水过滤单元(302)通过连接外来水管(301)连接外来水源，水过滤单元(302)将过滤的水连接送至去离子水单元(303)；水过滤单元(302)内装活性炭滤芯，或分子筛滤芯，或海绵滤芯，或纤维素滤芯，将水中的颗粒物，或生物滤去；The water filtration unit (302) is connected to the external water source by connecting the external water pipe (301), and the water filtration unit (302) sends the filtered water to the deionized water unit (303); the water filtration unit (302) contains an activated carbon filter element, or molecular sieve The filter element, or the sponge filter element, or the cellulose filter element, filters out the particulate matter in the water, or the organism;

去离子水单元(303)接收水过滤单元(302)的水，去离子后，将去离子水送到水箱(304)；去离子水单元(303)内装离子交换树脂，或离子交换剂，或离子交换分子筛，或离子过滤膜； 将水中的离子去掉；The deionized water unit (303) receives water from the water filtration unit (302), and after deionization, sends the deionized water to the water tank (304); the deionized water unit (303) contains ion exchange resin, or ion exchanger, or Ion exchange molecular sieve, or ion filter membrane; remove ions in water;

水箱(304)利用重力势能，或利用水泵将去离子水送至太阳能水解氢发生器核心单元(312)；The water tank (304) uses gravity potential energy, or uses a water pump to send deionized water to the core unit (312) of the solar hydrogen hydrolysis generator;

太阳能水解氢发生器核心单元(312)包括：上层透光电极板(306)，上层透光板(307)，水溶液(310)，催化剂层(311)，下层电极板(309)，下层支撑板(308)，下端板(313)，上端板(314)；The core unit (312) of the solar hydrolyzed hydrogen generator includes: an upper light-transmitting electrode plate (306), an upper light-transmitting plate (307), an aqueous solution (310), a catalyst layer (311), a lower electrode plate (309), and a lower support plate (308), lower end plate (313), upper end plate (314);

太阳能水解氢发生器核心单元(312)中的上层透光电极板(306)，下层电极板(309)，连接外接单元，对太阳能水解氢发生器核心单元加上一个电压，促进水光解的完成；The upper transparent electrode plate (306) and the lower electrode plate (309) in the core unit (312) of the solar hydrogen hydrolysis hydrogen generator are connected to an external unit, and a voltage is applied to the core unit of the solar hydrogen hydrogen generator to promote water photolysis carry out;

上层透光板(307)，下层支撑板(308)，下端板(313)，上端板(314)提供对太阳能水解氢发生器核心单元(312)支撑，形成一个容器，存储待光解的水；为催化剂层(311)提供支撑；The upper light-transmitting plate (307), the lower support plate (308), the lower end plate (313), and the upper end plate (314) provide support to the solar hydrolytic hydrogen generator core unit (312), forming a container to store the water to be photolyzed ; Provide support for the catalyst layer (311);

上层透光电极板(306)，上层透光板(307)是两个单独的部件；或上层透光电极板(306)，上层透光板(307)是同一部件，ITO板，或FTO板，或镀金属膜玻璃板；Upper transparent electrode plate (306), upper transparent plate (307) are two separate components; or upper transparent electrode plate (306), upper transparent plate (307) are the same component, ITO plate, or FTO plate , Or metal plated glass plate;

下层电极板(309)，下层支撑板(308)是两个独立部件；或下层电极板(309)，下层支撑板(308)是同一部件，金属板，或石墨板，或镀导电层的高分子板，或镀导电层非金属材料板；The lower electrode plate (309) and the lower support plate (308) are two independent components; or the lower electrode plate (309) and the lower support plate (308) are the same component, metal plate, or graphite plate, or the height of the conductive layer Molecular plate, or non-metallic material plated with conductive layer;

上层透光电极板(306)构成一个电极，下层电极板(309)构成另外一个电极；在上层透光电极板(306)和下层电极板(309)加上电压即构成一个电场，为催化剂层(311)提供一个偏置电压， 或偏置电流，或电场场强；The upper light-transmitting electrode plate (306) constitutes an electrode, and the lower electrode plate (309) constitutes another electrode; applying voltage to the upper light-transmitting electrode plate (306) and the lower electrode plate (309) constitutes an electric field, which is a catalyst layer (311) Provide a bias voltage, or bias current, or electric field strength;

催化剂层(311)将水在太阳光和催化剂共同作用下，将水水解为氢气和氧气；或在太阳光、催化剂和电场的共同作用下，将水水解为氢气和氧气；The catalyst layer (311) hydrolyzes water to hydrogen and oxygen under the combined action of sunlight and catalyst; or hydrolyzes water to hydrogen and oxygen under the combined action of sunlight, catalyst and electric field;

伺服系统(315)控制太阳能水解氢发生器核心单元(312)，使太阳能水解氢发生器核心单元(312)跟踪太阳光，使太阳能水解氢发生器核心单元(312)垂直接收太阳光线，使太阳能水解氢发生器核心单元(312)得到最多的太阳光辐射；The servo system (315) controls the solar hydrolyzed hydrogen generator core unit (312), causes the solar hydrolyzed hydrogen generator core unit (312) to track sunlight, and enables the solar hydrolyzed hydrogen generator core unit (312) to vertically receive solar light, so that solar energy The core unit (312) of the hydrolyzed hydrogen generator gets the most solar radiation;

氢气的水合物溶液存储器的结构，自然扩散：对较小的太阳能水解氢系统，可采用氢气在水合物中自然扩散；Hydrogen hydrate solution storage structure, natural diffusion: For smaller solar hydrolyzed hydrogen systems, hydrogen can be naturally diffused in the hydrate;

氢气的水合物溶液存储器的结构，泵驱动扩散：如图6所示，氢气的水合物溶液存储箱(601)，氢气输入管(602)，扩散泵(603)，未溶解的氢气(604)，氢气的水合物溶液(605)，单向阀(606)；电阻丝(607)；氢气抽气机(608)；Structure of hydrogen hydrate solution storage, pump-driven diffusion: As shown in Figure 6, hydrogen hydrate solution storage tank (601), hydrogen input pipe (602), diffusion pump (603), undissolved hydrogen (604) , Hydrogen hydrate solution (605), one-way valve (606); resistance wire (607); hydrogen aspirator (608);

氢气输入管(602)连接氢气传输管(203)，将氢气输入到氢气的水合物溶液存储箱(601)中，单向阀(606)控制太阳能水解氢发生器(202)产生的氢气可通入到氢气的水合物溶液存储箱(601)中，同时阻止氢气的水合物溶液(605)中的水合物溶液回流到氢气的水合物溶液存储箱(601)中；未溶解的氢气(604)经过扩散泵(603)输入到氢气的水合物溶液存储箱(601)的底部，未溶解的氢气经过扩散泵(603)不断的单向抽取，将氢气不断溶解到氢气水合物溶液中；The hydrogen inlet pipe (602) is connected to the hydrogen transmission pipe (203), and the hydrogen is input into the hydrogen hydrate solution storage tank (601), and the one-way valve (606) controls the hydrogen produced by the solar hydrolyzed hydrogen generator (202) to pass through Into the hydrogen hydrate solution storage tank (601), while preventing the hydrate solution in the hydrogen hydrate solution (605) from flowing back into the hydrogen hydrate solution storage tank (601); undissolved hydrogen (604) Input to the bottom of the hydrogen hydrate solution storage tank (601) through the diffusion pump (603), the undissolved hydrogen is continuously pumped unidirectionally through the diffusion pump (603) to continuously dissolve the hydrogen into the hydrogen hydrate solution;

对氢气的水合物溶液存储箱(601)加压强时增加氢气在氢气的水合物溶液(605)溶解度，从而实现更多的氢气溶解在氢气的水合物溶液(605)中。When the hydrogen hydrate solution storage tank (601) is pressurized, the solubility of hydrogen in the hydrogen hydrate solution (605) is increased, so that more hydrogen is dissolved in the hydrogen hydrate solution (605).

氢气的水合物析氢，氢气进入燃料电池发电：减压析氢；加温析氢；添加氢表面活性剂反应物析氢；Hydrogen evolution of hydrogen hydrate, hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution;

减压析氢：用氢气抽气机(608)抽去部分氢气后，氢气在氢气水合物溶液(605)溶解度将减少，从而有更多的氢气析出氢气的水合物溶液(605)，放出氢气；Hydrogen evolution under reduced pressure: After removing part of the hydrogen with a hydrogen aspirator (608), the solubility of hydrogen in the hydrogen hydrate solution (605) will be reduced, so that more hydrogen will evolve out of the hydrogen hydrate solution (605), releasing hydrogen;

加热析氢：电阻丝(607)通电时对氢气的水合物溶液(605)加热，氢气在氢气的水合物溶液(605)溶解度将减少，从而有更多的氢气析出氢气的水合物溶液(605)，放出氢气；Heating hydrogen evolution: When the resistance wire (607) is energized, the hydrogen hydrate solution (605) is heated, and the solubility of hydrogen in the hydrogen hydrate solution (605) will be reduced, so that more hydrogen precipitates hydrogen hydrate solution (605) , Emit hydrogen;

在氢气水合物溶液(605)中加入与氢表面活性剂功能团的反应物，减少氢表面活性剂的有效量，从而使氢气在氢气水合物溶液(605)中的氢气溶解度降低，放出氢气，实现析氢。Add the reactant with the hydrogen surfactant functional group to the hydrogen hydrate solution (605) to reduce the effective amount of the hydrogen surfactant, thereby reducing the solubility of hydrogen in the hydrogen hydrate solution (605) and releasing the hydrogen. Achieve hydrogen evolution.

氢气的水合物溶液(605)，循环流入氢气的水合物直接流入氢燃料电池与空气中的氧气，反应发电；或氢气水合物溶液(605)，循环流入氢气燃料电池与外加氧气反应发电。Hydrogen hydrate solution (605), the hydrate circulating into the hydrogen directly flows into the hydrogen fuel cell and oxygen in the air to react to generate electricity; or the hydrogen hydrate solution (605), circulating into the hydrogen fuel cell to react with the added oxygen to generate electricity.

励电电源：用氢燃料电池产生的电，为系统提供控制和偏置电压、或配置电流；利用氢燃料电池发出的电力为氢循环的太阳能储能的控制系统，如伺服系统(315)，温度传感器、氢气的水合物溶液存储箱(601)的电阻丝(607)提供电源；为氢燃料电池提供偏置电流、极板的加热提供电源；Excitation power supply: The electricity generated by the hydrogen fuel cell provides control and bias voltage, or configuration current for the system; the control system of solar energy storage using the power generated by the hydrogen fuel cell for the hydrogen cycle, such as the servo system (315), The temperature sensor and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the electrode plate;

或利用外加电源由市电整流稳压得到的电源，或电池，为系统提供控制和偏置电压、或配置电流；利用氢燃料电池发出的电力为氢循环的太阳能储能的控制系统，如伺服系统(315)，温度传感器、氢气的水合物溶液存储箱(601)的电阻丝(607)提供电源；为氢燃料电池提供偏置电流、极板的加热提供电源。Or use an external power source obtained from the rectification and stabilization of commercial power, or a battery, to provide control and bias voltage, or configure current for the system; use the power generated by the hydrogen fuel cell to control the solar energy storage system of the hydrogen cycle, such as servo The system (315), the temperature sensor, and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the electrode plate.

利用现有的柴油机，氢气的水合物溶液代替柴油，第三冲程喷入氢气的水合物溶液，氢气及水合物中的表面活性剂和空气中的氧气混合燃烧，推动活塞做功；Using the existing diesel engine, the hydrogen hydrate solution replaces the diesel, the hydrogen hydrate solution is injected into the third stroke, the hydrogen and the surfactant in the hydrate are mixed with the oxygen in the air to promote the piston to do work;

或者利用现有的汽油机，氢气及水合物溶液代替汽油，第一冲程吸入氢气的水合物溶液，第三冲程火花塞点火，氢气及水合物中的表面活性剂和空气的混合物燃烧，推动活塞做功；Or use the existing gasoline engine, hydrogen and hydrate solution to replace gasoline, inhale hydrogen hydrate solution in the first stroke, spark plug ignition in the third stroke, the mixture of surfactant and air in the hydrogen and hydrate burns, and push the piston to do work;

或者利用现有的柴油机，利用减压析出，或加温析氢，或反应析氢的氢气代替柴油，第三冲程喷入氢气，氢气和空气的混合物燃烧，推动活塞做功；Or use the existing diesel engine, use decompression precipitation, or heating hydrogen evolution, or reaction hydrogen evolution hydrogen instead of diesel, inject hydrogen in the third stroke, the mixture of hydrogen and air burns, and push the piston to do work;

或者利用现有的汽油机，将利用减压析出，或加温析氢，或反应析氢，析出的氢气代替汽油，第一冲程喷入氢气，第三冲程火花塞点火氢气和空气的混合物燃烧，推动活塞做功。Or use the existing gasoline engine, which will use vacuum decompression, hydrogenation by heating, or hydrogen evolution by reaction, and the precipitated hydrogen will replace gasoline. Hydrogen is injected in the first stroke, and the mixture of hydrogen and air is burned by the spark plug in the third stroke to promote the piston to work. .

利用管道或压力罐输送氢气或氢气水合液；氢气燃烧炉利用现有的燃料炉，自然燃烧：管道或压力罐连接燃气灶，利用管道或压力罐连接燃气灶输送氢气或氢气水合液；Use pipelines or pressure tanks to transport hydrogen or hydrogen hydration liquid; hydrogen combustion furnaces use existing fuel furnaces to burn naturally: pipelines or pressure tanks connect to gas stoves, and pipelines or pressure tanks connect to gas stoves to transport hydrogen or hydrogen hydration liquids;

管道内压缩氢气或压力罐的压缩氢气经过减压阀连接燃气灶，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用， 同时放出无污染的纯水；Compressed hydrogen in the pipeline or compressed hydrogen in the pressure tank is connected to the gas stove through the pressure reducing valve. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use, while releasing pure water without pollution;

或管道内压缩氢水合物或压力罐的氢水合物经过减压阀连接燃气灶，氢气水合物经过减压析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水；Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the gas stove through the pressure reducing valve. The hydrogen hydrate precipitates hydrogen after decompression. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use and released at the same time. Pure water without pollution;

或管道内压缩氢水合物或压力罐的氢水合物连接加热器，加热器加热氢水合物，氢气水合物经过加热析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水；Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the heater. The heater heats the hydrogen hydrate. The hydrogen hydrate precipitates hydrogen after heating. After ignition, the hydrogen and the oxygen in the air burn to obtain thermal energy for human use. At the same time, release pure water without pollution;

或管道内压缩氢水合物或压力罐的氢水合物连接反应器，反应器中氢水合物中加入氢表面活性剂反应物，氢气水合物经过添加氢表面活性剂反应物析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水。Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the reactor, the hydrogen hydrate reactant is added to the hydrogen hydrate in the reactor, and the hydrogen hydrate precipitates hydrogen gas by adding the hydrogen surfactant reactant and is ignited. Hydrogen and oxygen in the air are burned to obtain heat energy for human use, while releasing pure water without pollution.

有益效果Beneficial effect

为太阳能水解制氢，氢的存储，氢的输运，氢的应用构成一个完整系统，为太阳能氢循环的实用化提供完善的实用系统。Hydrogen production for solar energy hydrolysis, storage of hydrogen, transportation of hydrogen, and application of hydrogen form a complete system, providing a perfect practical system for the practical application of solar hydrogen circulation.

附图说明BRIEF DESCRIPTION

图1太阳能水解氢及水合物存储单元Figure 1 Solar Hydrogen Hydrogen and Hydrate Storage Unit

图2太阳能水解制氢、氢存储、燃气炉小循环Figure 2 Hydrogen production by solar energy hydrolysis, hydrogen storage, small cycle of gas furnace

图3太阳能水解制氢、储能、燃料电池小循环Figure 3 Small cycle of solar energy hydrogen production, energy storage and fuel cell

图4太阳能水解氢发生器结构Figure 4 Solar Hydrogen Hydrogen Generator Structure

图5太阳能水解制氢、储氢、输运、应用大循环Figure 5 Hydrogen production, storage, transportation and application of solar energy

图6所示，氢气的水合物溶液存储箱As shown in Figure 6, the hydrogen hydrate solution storage tank

本发明的实施方式Embodiments of the invention

优选实例1Preferred example 1

太阳光解水生成氢气，将太阳能存储在氢气的化学能中；氢气通过管道或压力罐输送，或氢溶解于氢水合物中通过管道或压力罐输送；溶解于氢水合物中的氢通过减压析氢，或加热析氢，或加氢水合物表面活性剂的反应物析氢，简称反应析氢；氢气或氢水合物通过燃气灶与空气中的氧气燃烧生产水，放出热量供生活或工业使用；氢气或氢水合物通过管道或压力罐输送到车辆上或工厂，供内燃机使用，为汽车或机器提供动力；氢气或氢水合物通过管道或压力罐输送到车辆上，或供工厂的氢燃料电池发电，供生活，或工业，或汽车动力使用；形成基于氢循环的太阳能储能，使用的清洁能源循环系统；Hydrogen is generated by sunlight decomposing water, and the solar energy is stored in the chemical energy of hydrogen; hydrogen is transported through pipelines or pressure tanks, or hydrogen dissolved in hydrogen hydrate is transported through pipelines or pressure tanks; hydrogen dissolved in hydrogen hydrates is reduced by Hydrogen evolution by pressurization, or hydrogen evolution by heating, or hydrogenation reaction of hydrogenated hydrate surfactants, referred to as reaction hydrogen evolution; hydrogen or hydrogen hydrate produces water by burning gas stoves with oxygen in the air, releasing heat for domestic or industrial use; hydrogen Or hydrogen hydrate is delivered to vehicles or factories through pipelines or pressure tanks for internal combustion engines to power cars or machines; hydrogen or hydrogen hydrate is delivered to vehicles through pipelines or pressure tanks or hydrogen fuel cells in factories are used to generate electricity , For life, or industry, or automotive power use; to form a solar energy storage based on hydrogen cycle, using a clean energy cycle system;

氢小循环：家庭屋顶太阳能制氢，氢水合物储氢，管道或压力输送氢气或氢水合物罐连接燃气灶燃烧取热，管道输氢或连接燃料电池发电，供家庭使用；或燃料电池并网发电，售电给大电网；或加入家用汽车使用，或售给加氢站，或售给收购槽车；Hydrogen small cycle: solar energy hydrogen production on home roof, hydrogen hydrate storage, pipeline or pressure delivery of hydrogen or hydrogen hydrate tank connected to gas stove to burn for heat, pipeline hydrogen transmission or connected fuel cell for power generation, for household use; or fuel cell and Generate electricity from the grid and sell it to a large power grid; or use it in a family car, or sell it to a hydrogen refueling station, or sell it to a tanker;

氢大循环：太阳能水解氢发生器，太阳能水解氢发生器场，产生的氢气通过氢水合物输运网络运输到氢气水合物加注站，或运输到氢气水合物管道系统，或运输到氢气水合物移动加注车； 氢水合物传输网络是管道输送；或氢水合物传输网络车辆运输；用户端包括燃气灶，燃料电池，氢内燃机；Hydrogen cycle: solar hydrolyzed hydrogen generator, solar hydrolyzed hydrogen generator field, the generated hydrogen is transported to the hydrogen hydrate filling station through the hydrogen hydrate transportation network, or to the hydrogen hydrate pipeline system, or to the hydrogen hydration Mobile charging vehicle; hydrogen hydrate transmission network is pipeline transportation; or hydrogen hydrate transmission network vehicle transportation; user end includes gas stove, fuel cell, hydrogen internal combustion engine;

如图1所示，太阳能水解及氢水合物存储单元；氢气的水合物溶液存储器(001)，太阳能水解氢发生器(003)，氢气传输管(002)，水合物氢含量测试单元(004)；实现太阳能水解制氢，氢溶解于氢水合物；As shown in Figure 1, a solar hydrolysis and hydrogen hydrate storage unit; a hydrogen hydrate solution storage (001), a solar hydrogen hydrolysis generator (003), a hydrogen transmission tube (002), a hydrate hydrogen content test unit (004) ; Realize hydrogen production by solar energy hydrolysis, hydrogen dissolved in hydrogen hydrate;

如图2所示，太阳能水解制氢、氢存储、燃气炉小循环；氢气的水合物溶液存储器(101)，太阳能水解氢发生器(102)，氢气传输管(103)，氢气燃烧炉(104)，氢气的水合物溶液输入管(106)，氢气的水合物溶液回流管输入管(105)；As shown in Fig. 2, solar hydrolysis hydrogen production, hydrogen storage, gas furnace small cycle; hydrogen hydrate solution storage (101), solar hydrogen hydrolysis generator (102), hydrogen transmission tube (103), hydrogen combustion furnace (104 ), Hydrogen hydrate solution input pipe (106), hydrogen hydrate solution return pipe input pipe (105);

太阳能水解氢发生器(102)中的水在太阳光的照射下，光解为氢气和氧气，氧气直接排放到空气中；产生的氢气通过氢气传输管(103)，送到氢气的水合物溶液存储器(101)，氢气溶解到氢气的水合物溶液中，实现氢气的存储；Under the irradiation of sunlight, the water in the solar hydrolyzed hydrogen generator (102) is photolyzed into hydrogen and oxygen, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (103) Storage (101), where hydrogen gas is dissolved into a hydrate solution of hydrogen gas to realize storage of hydrogen gas;

当氢气燃烧炉(104)需要燃烧氢气时，启动氢气燃烧炉(104)的循环泵，氢气的水合物溶液通过氢气的水合物溶液输入管(106)，将氢气的水合物溶液存储器(101)中的氢气的水合物溶液，送到氢气燃烧炉(104)析出氢气，氢气在氢气燃烧炉(104)与空气中的氧气燃烧，产生热量，供人类使用；析出了氢气的水合物溶液存储器在循环泵的作用下，通过氢气的水合物溶液回流管输入管(105)回到氢气的水合物溶液存储器(101)；When the hydrogen combustion furnace (104) needs to burn hydrogen, the circulation pump of the hydrogen combustion furnace (104) is started, the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (106), and the hydrogen hydrate solution storage (101) The hydrogen hydrate solution in the hydrogen is sent to the hydrogen combustion furnace (104) to precipitate hydrogen. The hydrogen burns with the oxygen in the air in the hydrogen combustion furnace (104) to generate heat for human use; the hydrate solution of the precipitated hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (101) through the hydrogen hydrate solution return pipe inlet pipe (105);

如图3所示，太阳能水解制氢、储能、燃料电池小循环；氢 气的水合物溶液存储器(201)，太阳能水解氢发生器(202)，氢气传输管(203)，氢气燃烧电池(204)，氢气的水合物溶液输入管(206)，氢气的水合物溶液回流管输入管(205)；As shown in Fig. 3, solar hydrolysis hydrogen production, energy storage, fuel cell small cycle; hydrogen hydrate solution storage (201), solar hydrogen hydrolysis generator (202), hydrogen transmission tube (203), hydrogen combustion battery (204 ), Hydrogen hydrate solution input pipe (206), hydrogen hydrate solution return pipe input pipe (205);

太阳能水解氢发生器(202)中的水在太阳光的照射下，光解为氢气和氧气，氧气直接排放到空气中；产生的氢气通过氢气传输管(203)，送到氢气的水合物溶液存储器(201)，氢气溶解到氢气的水合物溶液中，实现氢气的存储；The water in the solar hydrogen hydrolysis generator (202) is photolyzed into hydrogen and oxygen under the irradiation of sunlight, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (203) The storage (201), hydrogen gas is dissolved into the hydrogen hydrate solution to realize the storage of hydrogen gas;

当氢气燃料电池(204)需要氢气时，启动氢气燃料电池(204)的循环泵，氢气的水合物溶液通过氢气的水合物溶液输入管(206)，将氢气的水合物溶液存储器(201)中的氢气的水合物溶液，送到氢气燃料电池(204)析出氢气，氢气燃烧在氢气燃料电池(204)与空气中的氧气燃烧，产生热量，供人类使用；析出了氢气的水合物溶液存储器在循环泵的作用下，通过氢气的水合物溶液回流管输入管(205)回到氢气的水合物溶液存储器(201)；When the hydrogen fuel cell (204) needs hydrogen, start the circulation pump of the hydrogen fuel cell (204), the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (206), and the hydrogen hydrate solution storage (201) The hydrogen hydrate solution is sent to the hydrogen fuel cell (204) to precipitate hydrogen. The hydrogen is burned in the hydrogen fuel cell (204) and the oxygen in the air burns to generate heat for human use; the hydrate solution storage of the hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (201) through the hydrogen hydrate solution return pipe inlet pipe (205);

如图5所示，太阳能水解制氢、储氢、输运、应用大循环；太阳能水解氢发生器(401)，太阳能水解氢发生器场(402)，氢水合物传输网络(403)，氢气水合物加注站(404)，氢气水合物管道系统(405)，氢气水合物移动加注车(406)；As shown in Figure 5, solar hydrolysis hydrogen production, hydrogen storage, transportation, application of large cycles; solar hydrogen hydrolysis generator (401), solar hydrogen hydrolysis generator field (402), hydrogen hydrate transmission network (403), hydrogen Hydrate filling station (404), hydrogen hydrate pipeline system (405), hydrogen hydrate mobile filling vehicle (406);

太阳能水解氢发生器(401)为小型的太阳能水解氢发生器，可以放在能得到阳光照射的地方；太阳能水解氢发生器场(402)为大型的太阳能水解氢发生器的阵列，能产生大量的氢气；The solar hydrolyzed hydrogen generator (401) is a small solar hydrolyzed hydrogen generator, which can be placed in a place where it can get sunlight; the solar hydrolyzed hydrogen generator field (402) is an array of large-scale solar hydrolyzed hydrogen generators, which can produce Of hydrogen

太阳能水解氢发生器(401)，太阳能水解氢发生器场(402) 产生的氢气通过氢水合物传输网络(403)运输到氢气水合物加注站(404)，或运输到氢气水合物管道系统(405)，或运输到氢气水合物移动加注车(406)；The hydrogen produced by the solar hydrolyzed hydrogen generator (401) and the solar hydrolyzed hydrogen generator field (402) is transported to the hydrogen hydrate filling station (404) through the hydrogen hydrate transmission network (403) or to the hydrogen hydrate pipeline system (405), or transport to the mobile filling vehicle for hydrogen hydrate (406);

氢水合物传输网络(403)是管道输送；或氢水合物传输网络(403)车辆运输；或氢气的压力罐运输；或氢气的管道运输；Hydrogen hydrate transmission network (403) is pipeline transportation; or hydrogen hydrate transmission network (403) vehicle transportation; or hydrogen pressure tank transportation; or hydrogen pipeline transportation;

创新点：Innovation:

(1)氢循环的太阳能储能与氢气燃烧系统：太阳能水解氢单元，氢气溶入氢水合物，氢气水合物燃烧炉单元，或氢燃烧炉单元；(1) Hydrogen cycle solar energy storage and hydrogen combustion system: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen hydrate combustion furnace unit, or hydrogen combustion furnace unit;

(2)氢循环的太阳能储能与氢气燃料电池系统：太阳能水解氢单元，氢气溶入氢水合物，氢气燃料电池单元；或氢水合物燃料电池单元；(2) Hydrogen cycle solar energy storage and hydrogen fuel cell system: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen fuel cell unit; or hydrogen hydrate fuel cell unit;

(3)氢循环的太阳能储能与氢气水合物内燃机：太阳能水解氢单元，氢气溶入氢水合物，氢气内燃机单元；或氢水合物内燃机单元；(3) Hydrogen cycle solar energy storage and hydrogen hydrate internal combustion engine: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen internal combustion engine unit; or hydrogen hydrate internal combustion engine unit;

(4)太阳能水解氢发生器结构：水净化单元，去离子净化单元，太阳能水解氢发生器核心单元，太阳能水解氢发生器的伺服系统；(4) Structure of solar hydrogen hydrolysis hydrogen generator: water purification unit, deionization purification unit, solar hydrogen hydrolysis hydrogen generator core unit, servo system of solar hydrogen hydrolysis hydrogen generator;

(5)氢气水合物溶液采用氢表面活性剂的水溶液；(5) The hydrogen hydrate solution uses an aqueous solution of a hydrogen surfactant;

(6)氢气的水合物溶液存储器的结构，自然扩散：产生的氢气由氢表面活性剂的水溶液底部通入，或氢气由氢气与氢气水合物的界面扩散，氢气通过自然扩散实现氢气溶 解到氢表面活性剂的水溶液中；(6) The structure of hydrogen hydrate solution storage, natural diffusion: the generated hydrogen is introduced from the bottom of the aqueous solution of hydrogen surfactant, or the hydrogen diffuses from the interface of hydrogen and hydrogen hydrate, and hydrogen dissolves into hydrogen through natural diffusion Surfactant in aqueous solution;

(7)氢气的水合物溶液存储器的结构，泵驱动扩散：通过泵的循环推动，将氢气溶解到氢表面活性剂的水溶液中；(7) The structure of hydrogen hydrate solution storage, pump-driven diffusion: through the circulation of the pump, the hydrogen is dissolved into the aqueous solution of hydrogen surfactant;

(8)氢气的水合物析氢，氢气进入燃料电池发电：减压析氢；加温析氢；添加氢表面活性剂反应物析氢；析出的氢气进入燃料电池，氢气与空气反应实现氢燃料电池发电；(8) Hydrogen evolution of hydrogen hydrate, hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution; the precipitated hydrogen enters the fuel cell, hydrogen reacts with air to realize hydrogen fuel cell power generation;

(9)氢气的水合物直接进入燃料电池发电：氢气的水合物溶液(605)，循环流入氢气的水合物直接进入燃料电池与空气中的氧气，反应发电；或氢气的水合物溶液(605)，循环流入氢气的水合物直接进入燃料电池与外加氧气，反应发电；(9) Hydrogen hydrate directly enters the fuel cell for power generation: Hydrogen hydrate solution (605), circulating hydrogen hydrate directly enters the fuel cell and oxygen in the air, reacts to generate electricity; or hydrogen hydrate solution (605) , Hydrate circulated into hydrogen directly into the fuel cell and external oxygen, reaction power generation;

(10)氢循环的太阳能储能与应用系统同时提供氢气燃烧系统和燃料电池发电系统；(10) The solar energy storage and application system of the hydrogen cycle provide both a hydrogen combustion system and a fuel cell power generation system;

(11)氢循环的太阳能储能和燃料电池发电系统组成微网；(11) The solar energy storage and fuel cell power generation system of the hydrogen cycle form a microgrid;

(12)氢循环的太阳能储能和燃料电池发电系统组成并网发电，加入大电网；(12) The solar energy storage and fuel cell power generation systems of the hydrogen cycle form grid-connected power generation and join the large power grid;

(13)励电电源：用氢燃料电池产生的电，为系统提供控制电源，或偏置电压，或配置电流；(13) Excitation power supply: the power generated by the hydrogen fuel cell is used to provide control power, or bias voltage, or configuration current for the system;

(14)氢水合物内燃机：利用现有的柴油机，氢气的水合物溶液代替柴油；或者利用现有的汽油机，氢气及水合物溶液代替汽油；(14) Hydrogen hydrate internal combustion engine: use the existing diesel engine, hydrogen hydrate solution to replace diesel; or use the existing gasoline engine, hydrogen and hydrate solution to replace gasoline;

(15)氢气内燃机：或者利用现有的柴油机，将析出的氢气代 替柴油；或者利用现有的汽油机，将析出的氢气代替汽油；(15) Hydrogen internal combustion engine: Either use the existing diesel engine to replace the precipitated hydrogen with diesel; or use the existing gasoline engine to replace the precipitated hydrogen with gasoline;

(16)氢气燃烧炉的结构，自然燃烧：利用管道或压力罐输送氢气；氢气在燃烧炉中自然燃烧；利用管道或压力罐输送氢水合物；氢水合物在燃烧炉中自然燃烧；(16) The structure of a hydrogen combustion furnace, natural combustion: use pipelines or pressure tanks to transport hydrogen; hydrogen burns naturally in the furnace; use pipelines or pressure tanks to transport hydrogen hydrate; hydrogen hydrate naturally burns in the furnace;

(17)利用氢检测传感器，检测氢水合物的含氢量：检测氢气的水合物溶液存储器(001)中的氢含量；或检测氢气的水合物溶液输入管(206)中的氢含量；或检测氢气的水合物溶液回流管输入管(205)中的氢含量；或检测太阳能水解氢发生器(401)中的氢含量；或检测太阳能水解氢发生器场(402)中的氢含量；或检测氢水合物传输网络(403)中的氢含量；或检测氢气水合物加注站(404)中的氢含量；或检测氢气水合物管道系统(405)中的氢含量；或检测氢气水合物移动加注车(406)中的氢含量；或检测氢气加注机中的氢气水合物中的氢含量；或检测车辆氢水合物中箱中的氢含量；或检测燃气中的氢含量。(17) Use a hydrogen detection sensor to detect the hydrogen content of hydrogen hydrate: detect the hydrogen content in the hydrogen hydrate solution storage (001); or detect the hydrogen content in the hydrogen hydrate solution input pipe (206); or Detecting the hydrogen content in the inlet pipe (205) of the hydrate solution of the hydrogen gas; or detecting the hydrogen content in the solar hydrolyzed hydrogen generator (401); or detecting the hydrogen content in the solar hydrolyzed hydrogen generator field (402); or Detecting the hydrogen content in the hydrogen hydrate transmission network (403); or detecting the hydrogen content in the hydrogen hydrate filling station (404); or detecting the hydrogen content in the hydrogen hydrate piping system (405); or detecting the hydrogen hydrate The hydrogen content in the mobile filling vehicle (406); or the hydrogen content in the hydrogen hydrate in the hydrogen filling machine; or the hydrogen content in the tank in the hydrogen hydrate of the vehicle; or the hydrogen content in the fuel gas.

优选实例2Preferred example 2

如图4所示，太阳能水解氢发生器结构包括：连接外来水管(301)，水过滤单元(302)，去离子水单元(303)，水箱(304)，连接水箱(304)与太阳能水解氢发生器核心单元(312)连接水管(305)，上层透光电极板(306)，上层透光板(307)，水溶液 (310)，催化剂层(311)，下层电极板(309)，下层支撑板(308)，下端板(313)，上端板(314)，伺服系统(315)；As shown in FIG. 4, the structure of the solar hydrolyzed hydrogen generator includes: connecting an external water pipe (301), a water filtering unit (302), a deionized water unit (303), a water tank (304), and connecting the water tank (304) to solar hydrolyzed hydrogen The generator core unit (312) is connected to the water pipe (305), upper transparent electrode plate (306), upper transparent plate (307), aqueous solution (310), catalyst layer (311), lower electrode plate (309), lower support Board (308), lower end board (313), upper end board (314), servo system (315);

连接外来水管(301)可连接自来水，或井水，或其它水箱的水；The external water pipe (301) can be connected to tap water, well water, or other water tanks;

水过滤单元(302)通过连接外来水管(301)连接外来水源，水过滤单元(302)将过滤的水连接送至去离子水单元(303)；水过滤单元(302)内装活性炭滤芯，或分子筛滤芯，或海绵滤芯，或纤维素滤芯，将水中的颗粒物，或生物滤去；The water filtration unit (302) is connected to the external water source by connecting the external water pipe (301), and the water filtration unit (302) sends the filtered water to the deionized water unit (303); the water filtration unit (302) contains an activated carbon filter element, or molecular sieve The filter element, or the sponge filter element, or the cellulose filter element, filters out the particulate matter in the water, or the organism;

去离子水单元(303)接收水过滤单元(302)的水，去离子后，将去离子水送到水箱(304)；去离子水单元(303)内装离子交换树脂，或离子交换剂，或离子交换分子筛，或离子过滤膜；将水中的离子去掉；The deionized water unit (303) receives water from the water filtration unit (302), and after deionization, sends the deionized water to the water tank (304); the deionized water unit (303) contains ion exchange resin, or ion exchanger, or Ion exchange molecular sieve, or ion filter membrane; remove ions in water;

水箱(304)利用重力势能，或利用水泵将去离子水送至太阳能水解氢发生器核心单元(312)；The water tank (304) uses gravity potential energy, or uses a water pump to send deionized water to the core unit (312) of the solar hydrogen hydrolysis generator;

太阳能水解氢发生器核心单元(312)包括：上层透光电极板(306)，上层透光板(307)，水溶液(310)，催化剂层(311)，下层电极板(309)，下层支撑板(308)，下端板(313)，上端板(314)；The core unit (312) of the solar hydrolyzed hydrogen generator includes: an upper light-transmitting electrode plate (306), an upper light-transmitting plate (307), an aqueous solution (310), a catalyst layer (311), a lower electrode plate (309), and a lower support plate (308), lower end plate (313), upper end plate (314);

太阳能水解氢发生器核心单元(312)中的上层透光电极板(306)，下层电极板(309)，连接外接单元，对太阳能水解氢发生器核心单元加上一个电压，促进水光解的完成；The upper transparent electrode plate (306) and the lower electrode plate (309) in the core unit (312) of the solar hydrogen hydrolysis hydrogen generator are connected to an external unit, and a voltage is applied to the core unit of the solar hydrogen hydrogen generator to promote water photolysis carry out;

上层透光板(307)，下层支撑板(308)，下端板(313)，上 端板(314)提供对太阳能水解氢发生器核心单元(312)支撑，形成一个容器，存储待光解的水；为催化剂层(311)提供支撑；The upper light-transmitting plate (307), the lower support plate (308), the lower end plate (313), and the upper end plate (314) provide support to the solar hydrolytic hydrogen generator core unit (312), forming a container to store the water to be photolyzed ; Provide support for the catalyst layer (311);

上层透光电极板(306)，上层透光板(307)是两个单独的部件；或上层透光电极板(306)，上层透光板(307)是同一部件，ITO板，或FTO板，或镀金属膜玻璃板；Upper transparent electrode plate (306), upper transparent plate (307) are two separate components; or upper transparent electrode plate (306), upper transparent plate (307) are the same component, ITO plate, or FTO plate , Or metal plated glass plate;

下层电极板(309)，下层支撑板(308)是两个独立部件；或下层电极板(309)，下层支撑板(308)是同一部件，金属板，或石墨板，或镀导电层的高分子板，或镀导电层非金属材料板；The lower electrode plate (309) and the lower support plate (308) are two independent components; or the lower electrode plate (309) and the lower support plate (308) are the same component, metal plate, or graphite plate, or the height of the conductive layer Molecular plate, or non-metallic material plated with conductive layer;

上层透光电极板(306)构成一个电极，下层电极板(309)构成另外一个电极；在上层透光电极板(306)和下层电极板(309)加上电压即构成一个电场，为催化剂层(311)提供一个偏置电压，或偏置电流，或电场场强；The upper light-transmitting electrode plate (306) constitutes an electrode, and the lower electrode plate (309) constitutes another electrode; applying voltage to the upper light-transmitting electrode plate (306) and the lower electrode plate (309) constitutes an electric field, which is a catalyst layer (311) Provide a bias voltage, or bias current, or electric field strength;

催化剂层(311)将水在太阳光和催化剂共同作用下，将水水解为氢气和氧气；或在太阳光、催化剂和电场的共同作用下，将水水解为氢气和氧气；The catalyst layer (311) hydrolyzes water to hydrogen and oxygen under the combined action of sunlight and catalyst; or hydrolyzes water to hydrogen and oxygen under the combined action of sunlight, catalyst and electric field;

伺服系统(315)控制太阳能水解氢发生器核心单元(312)，使太阳能水解氢发生器核心单元(312)跟踪太阳光，使太阳能水解氢发生器核心单元(312)垂直接收太阳光线，使太阳能水解氢发生器核心单元(312)得到最多的太阳光辐射；The servo system (315) controls the solar hydrolyzed hydrogen generator core unit (312), causes the solar hydrolyzed hydrogen generator core unit (312) to track sunlight, and enables the solar hydrolyzed hydrogen generator core unit (312) to vertically receive solar light, so that solar energy The core unit (312) of the hydrolyzed hydrogen generator gets the most solar radiation;

优选实例3Preferred example 3

氢气的水合物溶液存储器的结构，自然扩散：对较小的太阳 能水解氢系统，可采用氢气在水合物中自然扩散；Hydrogen hydrate solution storage structure, natural diffusion: For smaller solar energy hydrolyzed hydrogen systems, hydrogen can be used to diffuse naturally in the hydrate;

氢气的水合物溶液存储器的结构，泵驱动扩散：如图6所示，氢气的水合物溶液存储箱(601)，氢气输入管(602)，扩散泵(603)，未溶解的氢气(604)，氢气的水合物溶液(605)，单向阀(606)；电阻丝(607)；氢气抽气机(608)；Structure of hydrogen hydrate solution storage, pump-driven diffusion: As shown in Figure 6, hydrogen hydrate solution storage tank (601), hydrogen input pipe (602), diffusion pump (603), undissolved hydrogen (604) , Hydrogen hydrate solution (605), one-way valve (606); resistance wire (607); hydrogen aspirator (608);

氢气输入管(602)连接氢气传输管(203)，将氢气输入到氢气的水合物溶液存储箱(601)中，单向阀(606)控制太阳能水解氢发生器(202)产生的氢气可通入到氢气的水合物溶液存储箱(601)中，同时阻止氢气的水合物溶液(605)中的水合物溶液回流到氢气的水合物溶液存储箱(601)中；未溶解的氢气(604)经过扩散泵(603)输入到氢气的水合物溶液存储箱(601)的底部，未溶解的氢气经过扩散泵(603)不断的单向抽取，将氢气不断溶解到氢气水合物溶液中；The hydrogen inlet pipe (602) is connected to the hydrogen transmission pipe (203), and the hydrogen is input into the hydrogen hydrate solution storage tank (601), and the one-way valve (606) controls the hydrogen produced by the solar hydrolyzed hydrogen generator (202) to pass through Into the hydrogen hydrate solution storage tank (601), while preventing the hydrate solution in the hydrogen hydrate solution (605) from flowing back into the hydrogen hydrate solution storage tank (601); undissolved hydrogen (604) Input to the bottom of the hydrogen hydrate solution storage tank (601) through the diffusion pump (603), the undissolved hydrogen is continuously pumped unidirectionally through the diffusion pump (603) to continuously dissolve the hydrogen into the hydrogen hydrate solution;

对氢气的水合物溶液存储箱(601)加压强时增加氢气在氢气的水合物溶液(605)溶解度，从而实现更多的氢气溶解在氢气的水合物溶液(605)中。When the hydrogen hydrate solution storage tank (601) is pressurized, the solubility of hydrogen in the hydrogen hydrate solution (605) is increased, so that more hydrogen is dissolved in the hydrogen hydrate solution (605).

优选实例4Preferred example 4

氢气的水合物析氢，氢气进入燃料电池发电：减压析氢；加温析氢；添加氢表面活性剂反应物析氢；Hydrogen evolution of hydrogen hydrate, hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution;

如图6所示，减压析氢：用氢气抽气机(608)抽去部分氢气后，氢气在氢气水合物溶液(605)溶解度将减少，从而有更多的 氢气析出氢气的水合物溶液(605)，放出氢气；As shown in Figure 6, decompression hydrogen evolution: After part of the hydrogen is pumped out with a hydrogen aspirator (608), the solubility of hydrogen in the hydrogen hydrate solution (605) will decrease, so that more hydrogen will evolve out of the hydrogen hydrate solution ( 605), release hydrogen gas;

加热析氢：电阻丝(607)通电时对氢气的水合物溶液(605)加热，氢气在氢气的水合物溶液(605)溶解度将减少，从而有更多的氢气析出氢气的水合物溶液(605)，放出氢气；Heating hydrogen evolution: When the resistance wire (607) is energized, the hydrogen hydrate solution (605) is heated, and the solubility of hydrogen in the hydrogen hydrate solution (605) will be reduced, so that more hydrogen precipitates hydrogen hydrate solution (605) , Emit hydrogen;

在氢气水合物溶液(605)中加入与氢表面活性剂功能团的反应物，减少氢表面活性剂的有效量，从而使氢气在氢气水合物溶液(605)中的氢气溶解度降低，放出氢气，实现析氢。Add the reactant with the hydrogen surfactant functional group to the hydrogen hydrate solution (605) to reduce the effective amount of the hydrogen surfactant, thereby reducing the solubility of hydrogen in the hydrogen hydrate solution (605) and releasing the hydrogen. Achieve hydrogen evolution.

优选实例5Preferred example 5

氢气的水合物溶液(605)，循环流入氢气的水合物直接流入氢燃料电池与空气中的氧气，反应发电；或氢气水合物溶液(605)，循环流入氢气燃料电池与外加氧气反应发电。Hydrogen hydrate solution (605), the hydrate circulating into the hydrogen directly flows into the hydrogen fuel cell and oxygen in the air to react to generate electricity; or the hydrogen hydrate solution (605), circulating into the hydrogen fuel cell to react with the added oxygen to generate electricity.

优选实例6Preferred example 6

励电电源：用氢燃料电池产生的电，为系统提供控制和偏置电压、或配置电流；利用氢燃料电池发出的电力为氢循环的太阳能储能的控制系统，如伺服系统(315)，温度传感器、氢气的水合物溶液存储箱(601)的电阻丝(607)提供电源；为氢燃料电池提供偏置电流、极板的加热提供电源；Excitation power supply: The electricity generated by the hydrogen fuel cell provides control and bias voltage, or configuration current for the system; the control system of solar energy storage using the power generated by the hydrogen fuel cell for the hydrogen cycle, such as the servo system (315), The temperature sensor and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the electrode plate;

或利用外加电源由市电整流稳压得到的电源，或电池，为系统提供控制和偏置电压、或配置电流；利用氢燃料电池发出的电力为氢循环的太阳能储能的控制系统，如伺服系统(315)，温度 传感器、氢气的水合物溶液存储箱(601)的电阻丝(607)提供电源；为氢燃料电池提供偏置电流、极板的加热提供电源。Or use an external power source obtained from the rectification and stabilization of commercial power, or a battery, to provide control and bias voltage, or configure current for the system; use the power generated by the hydrogen fuel cell to control the solar energy storage system of the hydrogen cycle, such as servo The system (315), the temperature sensor, and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the plate.

优选实例7Preferred example 7

利用现有的柴油机，氢气的水合物溶液代替柴油，第三冲程喷入氢气的水合物溶液，氢气及水合物中的表面活性剂和空气中的氧气混合燃烧，推动活塞做功；Using the existing diesel engine, the hydrogen hydrate solution replaces the diesel, the hydrogen hydrate solution is injected into the third stroke, the hydrogen and the surfactant in the hydrate are mixed with the oxygen in the air to promote the piston to do work;

或者利用现有的汽油机，氢气及水合物溶液代替汽油，第一冲程吸入氢气的水合物溶液，第三冲程火花塞点火，氢气及水合物中的表面活性剂和空气的混合物燃烧，推动活塞做功；Or use the existing gasoline engine, hydrogen and hydrate solution to replace gasoline, inhale hydrogen hydrate solution in the first stroke, spark plug ignition in the third stroke, the mixture of surfactant and air in the hydrogen and hydrate burns, and push the piston to do work;

或者利用现有的柴油机，利用减压析出，或加温析氢，或反应析氢的氢气代替柴油，第三冲程喷入氢气，氢气和空气的混合物燃烧，推动活塞做功；Or use the existing diesel engine, use decompression precipitation, or heating hydrogen evolution, or reaction hydrogen evolution hydrogen instead of diesel, inject hydrogen in the third stroke, the mixture of hydrogen and air burns, and push the piston to do work;

或者利用现有的汽油机，将利用减压析出，或加温析氢，或反应析氢，析出的氢气代替汽油，第一冲程喷入氢气，第三冲程火花塞点火氢气和空气的混合物燃烧，推动活塞做功。Or use the existing gasoline engine, which will use vacuum decompression, hydrogenation by heating, or hydrogen evolution by reaction, and the precipitated hydrogen will replace gasoline. Hydrogen is injected in the first stroke, and the mixture of hydrogen and air is burned by the spark plug in the third stroke to promote the piston to work. .

优选实例8Preferred example 8

利用管道或压力罐输送氢气或氢气水合液；氢气燃烧炉利用现有的燃料炉，自然燃烧：管道或压力罐连接燃气灶，利用管道或压力罐连接燃气灶输送氢气或氢气水合液；Use pipelines or pressure tanks to transport hydrogen or hydrogen hydration liquid; hydrogen combustion furnaces use existing fuel furnaces to burn naturally: pipelines or pressure tanks connect to gas stoves, and pipelines or pressure tanks connect to gas stoves to transport hydrogen or hydrogen hydration liquids;

管道内压缩氢气或压力罐的压缩氢气经过减压阀连接燃气 灶，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水；Compressed hydrogen in the pipeline or compressed hydrogen in the pressure tank is connected to the gas stove through the pressure reducing valve. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use, while releasing pure water without pollution;

或管道内压缩氢水合物或压力罐的氢水合物经过减压阀连接燃气灶，氢气水合物经过减压析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水；Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the gas stove through the pressure reducing valve. The hydrogen hydrate precipitates hydrogen after decompression. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use and released at the same time. Pure water without pollution;

或管道内压缩氢水合物或压力罐的氢水合物连接加热器，加热器加热氢水合物，氢气水合物经过加热析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水；Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the heater. The heater heats the hydrogen hydrate. The hydrogen hydrate precipitates hydrogen after heating. After ignition, the hydrogen and the oxygen in the air burn to obtain thermal energy for human use. At the same time, release pure water without pollution;

或管道内压缩氢水合物或压力罐的氢水合物连接反应器，反应器中氢水合物中加入氢表面活性剂反应物，氢气水合物经过添加氢表面活性剂反应物析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水。Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the reactor, the hydrogen hydrate reactant is added to the hydrogen hydrate in the reactor, and the hydrogen hydrate precipitates hydrogen gas by adding the hydrogen surfactant reactant and is ignited. Hydrogen and oxygen in the air are burned to obtain heat energy for human use, while releasing pure water without pollution.

虽然结合附图对本发明的实施方式进行说明，但本领域普通技术人员可以在所附权利要求的范围内作出各种变形或修改，也可以本设计中的一部分。Although the embodiments of the present invention are described with reference to the drawings, those of ordinary skill in the art may make various variations or modifications within the scope of the appended claims, or may be a part of the design.

Claims (8)

基于氢循环的太阳能制氢、储氢与应用系统，其特征是：The solar hydrogen production, hydrogen storage and application system based on the hydrogen cycle is characterized by: 太阳光解水生成氢气，将太阳能存储在氢气的化学能中；氢气通过管道或压力罐输送，或氢溶解于氢水合物中通过管道或压力罐输送；溶解于氢水合物中的氢通过减压析氢，或加热析氢，或加氢水合物表面活性剂的反应物析氢，简称反应析氢；氢气或氢水合物通过燃气灶与空气中的氧气燃烧生产水，放出热量供生活或工业使用；氢气或氢水合物通过管道或压力罐输送到车辆上或工厂，供内燃机使用，为汽车或机器提供动力；氢气或氢水合物通过管道或压力罐输送到车辆上，或供工厂的氢燃料电池发电，供生活，或工业，或汽车动力使用；形成基于氢循环的太阳能储能，使用的清洁能源循环系统；Hydrogen is generated by sunlight decomposing water, and the solar energy is stored in the chemical energy of hydrogen; hydrogen is transported through pipelines or pressure tanks, or hydrogen dissolved in hydrogen hydrate is transported through pipelines or pressure tanks; hydrogen dissolved in hydrogen hydrates is reduced by Hydrogen evolution by pressurization, or hydrogen evolution by heating, or hydrogenation reaction of hydrogenated hydrate surfactants, referred to as reaction hydrogen evolution; hydrogen or hydrogen hydrate produces water by burning gas stoves with oxygen in the air, releasing heat for domestic or industrial use; hydrogen Or hydrogen hydrate is delivered to vehicles or factories through pipelines or pressure tanks for internal combustion engines to power cars or machines; hydrogen or hydrogen hydrate is delivered to vehicles through pipelines or pressure tanks or hydrogen fuel cells in factories are used to generate electricity , For life, or industry, or automotive power use; to form a solar energy storage based on hydrogen cycle, using a clean energy cycle system; 氢小循环：家庭屋顶太阳能制氢，氢水合物储氢，管道或压力输送氢气或氢水合物罐连接燃气灶燃烧取热，管道输氢或连接燃料电池发电，供家庭使用；或燃料电池并网发电，售电给大电网；或加入家用汽车使用，或售给加氢站，或售给收购槽车；Hydrogen small cycle: solar energy hydrogen production on home roof, hydrogen hydrate storage, pipeline or pressure delivery of hydrogen or hydrogen hydrate tank connected to gas stove to burn for heat, pipeline hydrogen transmission or connected fuel cell for power generation, for household use; or fuel cell and Generate electricity from the grid and sell it to a large power grid; or use it in a family car, or sell it to a hydrogen refueling station, or sell it to a tanker; 氢大循环：太阳能水解氢发生器，太阳能水解氢发生器场，产生的氢气通过氢水合物输运网络运输到氢气水合物加注站，或运输到氢气水合物管道系统，或运输到氢气水合物移动加注车；氢水合物传输网络是管道输送；或氢水合物传输网络车辆运输；用户端包括燃气灶，燃料电池，氢内燃机；Hydrogen cycle: solar hydrolyzed hydrogen generator, solar hydrolyzed hydrogen generator field, the generated hydrogen is transported to the hydrogen hydrate filling station through the hydrogen hydrate transportation network, or to the hydrogen hydrate pipeline system, or to the hydrogen hydration Mobile refueling vehicle; hydrogen hydrate transmission network is pipeline transportation; or hydrogen hydrate transmission network vehicle transportation; user terminal includes gas stove, fuel cell, hydrogen internal combustion engine; 太阳能水解及氢水合物存储单元；氢气的水合物溶液存储器 (001)，太阳能水解氢发生器(003)，氢气传输管(002)，水合物氢含量测试单元(004)；实现太阳能水解制氢，氢溶解于氢水合物；Solar Hydrolysis and Hydrogen Hydrate Storage Unit; Hydrogen Hydrate Solution Storage (001), Solar Hydrogen Hydrogen Generator (003), Hydrogen Transmission Tube (002), Hydrate Hydrogen Content Test Unit (004); Realize Solar Hydrogen Production , Hydrogen dissolved in hydrogen hydrate; 太阳能水解制氢、氢存储、燃气炉小循环；氢气的水合物溶液存储器(101)，太阳能水解氢发生器(102)，氢气传输管(103)，氢气燃烧炉(104)，氢气的水合物溶液输入管(106)，氢气的水合物溶液回流管输入管(105)；Solar hydrolysis hydrogen production, hydrogen storage, gas furnace small cycle; hydrogen hydrate solution storage (101), solar hydrogen hydrolysis generator (102), hydrogen transmission tube (103), hydrogen combustion furnace (104), hydrogen hydrate Solution inlet pipe (106), hydrogen hydrate solution return pipe inlet pipe (105); 太阳能水解氢发生器(102)中的水在太阳光的照射下，光解为氢气和氧气，氧气直接排放到空气中；产生的氢气通过氢气传输管(103)，送到氢气的水合物溶液存储器(101)，氢气溶解到氢气的水合物溶液中，实现氢气的存储；Under the irradiation of sunlight, the water in the solar hydrolyzed hydrogen generator (102) is photolyzed into hydrogen and oxygen, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (103) Storage (101), where hydrogen gas is dissolved into a hydrate solution of hydrogen gas to realize storage of hydrogen gas; 当氢气燃烧炉(104)需要燃烧氢气时，启动氢气燃烧炉(104)的循环泵，氢气的水合物溶液通过氢气的水合物溶液输入管(106)，将氢气的水合物溶液存储器(101)中的氢气的水合物溶液，送到氢气燃烧炉(104)析出氢气，氢气在氢气燃烧炉(104)与空气中的氧气燃烧，产生热量，供人类使用；析出了氢气的水合物溶液存储器在循环泵的作用下，通过氢气的水合物溶液回流管输入管(105)回到氢气的水合物溶液存储器(101)；When the hydrogen combustion furnace (104) needs to burn hydrogen, the circulation pump of the hydrogen combustion furnace (104) is started, the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (106), and the hydrogen hydrate solution storage (101) The hydrogen hydrate solution in the hydrogen is sent to the hydrogen combustion furnace (104) to precipitate hydrogen. The hydrogen burns with the oxygen in the air in the hydrogen combustion furnace (104) to generate heat for human use; the hydrate solution of the precipitated hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (101) through the hydrogen hydrate solution return pipe inlet pipe (105); 太阳能水解制氢、储能、燃料电池小循环；氢气的水合物溶液存储器(201)，太阳能水解氢发生器(202)，氢气传输管(203)，氢气燃烧电池(204)，氢气的水合物溶液输入管(206)，氢气的水合物溶液回流管输入管(205)；Solar hydrolysis hydrogen production, energy storage, fuel cell small cycle; hydrogen hydrate solution storage (201), solar hydrogen hydrolysis generator (202), hydrogen transmission tube (203), hydrogen combustion cell (204), hydrogen hydrate Solution inlet pipe (206), hydrogen hydrate solution return pipe inlet pipe (205); 太阳能水解氢发生器(202)中的水在太阳光的照射下，光解为氢气和氧气，氧气直接排放到空气中；产生的氢气通过氢气传输管(203)，送到氢气的水合物溶液存储器(201)，氢气溶解到氢气的水合物溶液中，实现氢气的存储；The water in the solar hydrogen hydrolysis generator (202) is photolyzed into hydrogen and oxygen under the irradiation of sunlight, and the oxygen is directly discharged into the air; the generated hydrogen is sent to the hydrogen hydrate solution through the hydrogen transmission tube (203) The storage (201), hydrogen gas is dissolved into the hydrogen hydrate solution to realize the storage of hydrogen gas; 当氢气燃料电池(204)需要氢气时，启动氢气燃料电池(204)的循环泵，氢气的水合物溶液通过氢气的水合物溶液输入管(206)，将氢气的水合物溶液存储器(201)中的氢气的水合物溶液，送到氢气燃料电池(204)析出氢气，氢气燃烧在氢气燃料电池(204)与空气中的氧气燃烧，产生热量，供人类使用；析出了氢气的水合物溶液存储器在循环泵的作用下，通过氢气的水合物溶液回流管输入管(205)回到氢气的水合物溶液存储器(201)；When the hydrogen fuel cell (204) needs hydrogen, start the circulation pump of the hydrogen fuel cell (204), the hydrogen hydrate solution passes through the hydrogen hydrate solution input pipe (206), and the hydrogen hydrate solution storage (201) The hydrogen hydrate solution is sent to the hydrogen fuel cell (204) to precipitate hydrogen. The hydrogen is burned in the hydrogen fuel cell (204) and the oxygen in the air burns to generate heat for human use; the hydrate solution storage of the hydrogen is stored in Under the action of the circulation pump, it returns to the hydrogen hydrate solution storage (201) through the hydrogen hydrate solution return pipe inlet pipe (205); 太阳能水解制氢、储氢、输运、应用大循环；太阳能水解氢发生器(401)，太阳能水解氢发生器场(402)，氢水合物传输网络(403)，氢气水合物加注站(404)，氢气水合物管道系统(405)，氢气水合物移动加注车(406)；Solar hydrolysis hydrogen production, hydrogen storage, transportation, application of large cycles; solar hydrogen hydrolysis generator (401), solar hydrogen hydrolysis generator field (402), hydrogen hydrate transmission network (403), hydrogen hydrate filling station ( 404), hydrogen hydrate pipeline system (405), hydrogen hydrate mobile filling vehicle (406); 太阳能水解氢发生器(401)为小型的太阳能水解氢发生器，可以放在能得到阳光照射的地方；太阳能水解氢发生器场(402)为大型的太阳能水解氢发生器的阵列，能产生大量的氢气；The solar hydrolyzed hydrogen generator (401) is a small solar hydrolyzed hydrogen generator, which can be placed in a place where it can get sunlight; the solar hydrolyzed hydrogen generator field (402) is an array of large-scale solar hydrolyzed hydrogen generators, which can produce Of hydrogen 太阳能水解氢发生器(401)，太阳能水解氢发生器场(402)产生的氢气通过氢水合物传输网络(403)运输到氢气水合物加注站(404)，或运输到氢气水合物管道系统(405)，或运输到氢气水合物移动加注车(406)；The hydrogen produced by the solar hydrolyzed hydrogen generator (401) and the solar hydrolyzed hydrogen generator field (402) is transported to the hydrogen hydrate filling station (404) through the hydrogen hydrate transmission network (403) or to the hydrogen hydrate pipeline system (405), or transport to the mobile filling vehicle for hydrogen hydrate (406); 氢水合物传输网络(403)是管道输送；或氢水合物传输网络(403)车辆运输；或氢气的压力罐运输；或氢气的管道运输；Hydrogen hydrate transmission network (403) is pipeline transportation; or hydrogen hydrate transmission network (403) vehicle transportation; or hydrogen pressure tank transportation; or hydrogen pipeline transportation; 创新点：Innovation: (1)氢循环的太阳能储能与氢气燃烧系统：太阳能水解氢单元，氢气溶入氢水合物，氢气水合物燃烧炉单元，或氢燃烧炉单元；(1) Hydrogen cycle solar energy storage and hydrogen combustion system: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen hydrate combustion furnace unit, or hydrogen combustion furnace unit; (2)氢循环的太阳能储能与氢气燃料电池系统：太阳能水解氢单元，氢气溶入氢水合物，氢气燃料电池单元；或氢水合物燃料电池单元；(2) Hydrogen cycle solar energy storage and hydrogen fuel cell system: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen fuel cell unit; or hydrogen hydrate fuel cell unit; (3)氢循环的太阳能储能与氢气水合物内燃机：太阳能水解氢单元，氢气溶入氢水合物，氢气内燃机单元；或氢水合物内燃机单元；(3) Hydrogen cycle solar energy storage and hydrogen hydrate internal combustion engine: solar hydrolyzed hydrogen unit, hydrogen dissolved in hydrogen hydrate, hydrogen internal combustion engine unit; or hydrogen hydrate internal combustion engine unit; (4)太阳能水解氢发生器结构：水净化单元，去离子净化单元，太阳能水解氢发生器核心单元，太阳能水解氢发生器的伺服系统；(4) Structure of solar hydrogen hydrolysis hydrogen generator: water purification unit, deionization purification unit, solar hydrogen hydrolysis hydrogen generator core unit, servo system of solar hydrogen hydrolysis hydrogen generator; (5)氢气水合物溶液采用氢表面活性剂的水溶液；(5) The hydrogen hydrate solution uses an aqueous solution of a hydrogen surfactant; (6)氢气的水合物溶液存储器的结构，自然扩散：产生的氢气由氢表面活性剂的水溶液底部通入，或氢气由氢气与氢气水合物的界面扩散，氢气通过自然扩散实现氢气溶解到氢表面活性剂的水溶液中；(6) The structure of hydrogen hydrate solution storage, natural diffusion: the generated hydrogen is introduced from the bottom of the aqueous solution of hydrogen surfactant, or the hydrogen diffuses from the interface of hydrogen and hydrogen hydrate, and hydrogen dissolves into hydrogen through natural diffusion Surfactant in aqueous solution; (7)氢气的水合物溶液存储器的结构，泵驱动扩散：通过泵的循环推动，将氢气溶解到氢表面活性剂的水溶液中；(7) The structure of hydrogen hydrate solution storage, pump-driven diffusion: through the circulation of the pump, the hydrogen is dissolved into the aqueous solution of hydrogen surfactant; (8)氢气的水合物析氢，氢气进入燃料电池发电：减压析氢；加温析氢；添加氢表面活性剂反应物析氢；析出的氢气进入燃料电池，氢气与空气反应实现氢燃料电池发电；(8) Hydrogen evolution of hydrogen hydrate, hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution; the precipitated hydrogen enters the fuel cell, hydrogen reacts with air to realize hydrogen fuel cell power generation; (9)氢气的水合物直接进入燃料电池发电：氢气的水合物溶液(605)，循环流入氢气的水合物直接进入燃料电池与空气中的氧气，反应发电；或氢气的水合物溶液(605)，循环流入氢气的水合物直接进入燃料电池与外加氧气，反应发电；(9) Hydrogen hydrate directly enters the fuel cell for power generation: Hydrogen hydrate solution (605), circulating hydrogen hydrate directly enters the fuel cell and oxygen in the air, reacts to generate electricity; or hydrogen hydrate solution (605) , Hydrate circulated into hydrogen directly into the fuel cell and external oxygen, reaction power generation; (10)氢循环的太阳能储能与应用系统同时提供氢气燃烧系统和燃料电池发电系统；(10) The solar energy storage and application system of the hydrogen cycle provide both a hydrogen combustion system and a fuel cell power generation system; (11)氢循环的太阳能储能和燃料电池发电系统组成微网；(11) The solar energy storage and fuel cell power generation system of the hydrogen cycle form a microgrid; (12)氢循环的太阳能储能和燃料电池发电系统组成并网发电，加入大电网；(12) The solar energy storage and fuel cell power generation systems of the hydrogen cycle form grid-connected power generation and join the large power grid; (13)励电电源：用氢燃料电池产生的电，为系统提供控制电源，或偏置电压，或配置电流；(13) Excitation power supply: the power generated by the hydrogen fuel cell is used to provide control power, or bias voltage, or configuration current for the system; (14)氢水合物内燃机：利用现有的柴油机，氢气的水合物溶液代替柴油；或者利用现有的汽油机，氢气及水合物溶液代替汽油；(14) Hydrogen hydrate internal combustion engine: use the existing diesel engine, hydrogen hydrate solution to replace diesel; or use the existing gasoline engine, hydrogen and hydrate solution to replace gasoline; (15)氢气内燃机：或者利用现有的柴油机，将析出的氢气代替柴油；或者利用现有的汽油机，将析出的氢气代替汽油；(15) Hydrogen internal combustion engine: either use the existing diesel engine to replace the hydrogen produced by diesel; or use the existing gasoline engine to replace the hydrogen produced by gasoline; (16)氢气燃烧炉的结构，自然燃烧：利用管道或压力罐输送 氢气；氢气在燃烧炉中自然燃烧；利用管道或压力罐输送氢水合物；氢水合物在燃烧炉中自然燃烧；(16) The structure of hydrogen combustion furnace, natural combustion: use pipeline or pressure tank to transport hydrogen; hydrogen burns naturally in combustion furnace; use pipeline or pressure tank to transport hydrogen hydrate; hydrogen hydrate naturally burns in combustion furnace; (17)利用氢检测传感器，检测氢水合物的含氢量：检测氢气的水合物溶液存储器(001)中的氢含量；或检测氢气的水合物溶液输入管(206)中的氢含量；或检测氢气的水合物溶液回流管输入管(205)中的氢含量；或检测太阳能水解氢发生器(401)中的氢含量；或检测太阳能水解氢发生器场(402)中的氢含量；或检测氢水合物传输网络(403)中的氢含量；或检测氢气水合物加注站(404)中的氢含量；或检测氢气水合物管道系统(405)中的氢含量；或检测氢气水合物移动加注车(406)中的氢含量；或检测氢气加注机中的氢气水合物中的氢含量；或检测车辆氢水合物中箱中的氢含量；或检测燃气中的氢含量。(17) Use a hydrogen detection sensor to detect the hydrogen content of hydrogen hydrate: detect the hydrogen content in the hydrogen hydrate solution storage (001); or detect the hydrogen content in the hydrogen hydrate solution input pipe (206); or Detecting the hydrogen content in the inlet pipe (205) of the hydrate solution of the hydrogen gas; or detecting the hydrogen content in the solar hydrolyzed hydrogen generator (401); or detecting the hydrogen content in the solar hydrolyzed hydrogen generator field (402); or Detecting the hydrogen content in the hydrogen hydrate transmission network (403); or detecting the hydrogen content in the hydrogen hydrate filling station (404); or detecting the hydrogen content in the hydrogen hydrate piping system (405); or detecting the hydrogen hydrate The hydrogen content in the mobile filling vehicle (406); or the hydrogen content in the hydrogen hydrate in the hydrogen filling machine; or the hydrogen content in the tank in the hydrogen hydrate of the vehicle; or the hydrogen content in the fuel gas. 根据权利要求1所述的基于氢循环的太阳能制氢、储氢与应用系统，其特征是：The solar hydrogen production, hydrogen storage and application system based on the hydrogen cycle according to claim 1, characterized in that: 太阳能水解氢发生器结构包括：连接外来水管(301)，水过滤单元(302)，去离子水单元(303)，水箱(304)，连接水箱(304)与太阳能水解氢发生器核心单元(312)连接水管(305)，上层透光电极板(306)，上层透光板(307)，水溶液(310)，催化剂层(311)，下层电极板(309)，下层支撑板(308)，下端板(313)，上端板(314)，伺服系统(315)；The structure of the solar hydrolyzed hydrogen generator includes: connecting an external water pipe (301), a water filtering unit (302), a deionized water unit (303), a water tank (304), connecting the water tank (304) and a solar hydrolytic hydrogen generator core unit (312) ) Connect water pipe (305), upper transparent electrode plate (306), upper transparent plate (307), aqueous solution (310), catalyst layer (311), lower electrode plate (309), lower support plate (308), lower end Board (313), upper end board (314), servo system (315); 连接外来水管(301)可连接自来水，或井水，或其它水箱的水；The external water pipe (301) can be connected to tap water, well water, or other water tanks; 水过滤单元(302)通过连接外来水管(301)连接外来水源，水过滤单元(302)将过滤的水连接送至去离子水单元(303)；水过滤单元(302)内装活性炭滤芯，或分子筛滤芯，或海绵滤芯，或纤维素滤芯，将水中的颗粒物，或生物滤去；The water filtration unit (302) is connected to the external water source by connecting the external water pipe (301), and the water filtration unit (302) sends the filtered water to the deionized water unit (303); the water filtration unit (302) contains an activated carbon filter element, or molecular sieve The filter element, or the sponge filter element, or the cellulose filter element, filters out the particulate matter in the water, or the organism; 去离子水单元(303)接收水过滤单元(302)的水，去离子后，将去离子水送到水箱(304)；去离子水单元(303)内装离子交换树脂，或离子交换剂，或离子交换分子筛，或离子过滤膜；将水中的离子去掉；The deionized water unit (303) receives water from the water filtration unit (302), and after deionization, sends the deionized water to the water tank (304); the deionized water unit (303) contains ion exchange resin, or ion exchanger, or Ion exchange molecular sieve, or ion filter membrane; remove ions in water; 水箱(304)利用重力势能，或利用水泵将去离子水送至太阳能水解氢发生器核心单元(312)；The water tank (304) uses gravity potential energy, or uses a water pump to send deionized water to the core unit (312) of the solar hydrogen hydrolysis generator; 太阳能水解氢发生器核心单元(312)包括：上层透光电极板(306)，上层透光板(307)，水溶液(310)，催化剂层(311)，下层电极板(309)，下层支撑板(308)，下端板(313)，上端板(314)；The core unit (312) of the solar hydrolyzed hydrogen generator includes: an upper light-transmitting electrode plate (306), an upper light-transmitting plate (307), an aqueous solution (310), a catalyst layer (311), a lower electrode plate (309), and a lower support plate (308), lower end plate (313), upper end plate (314); 太阳能水解氢发生器核心单元(312)中的上层透光电极板(306)，下层电极板(309)，连接外接单元，对太阳能水解氢发生器核心单元加上一个电压，促进水光解的完成；The upper transparent electrode plate (306) and the lower electrode plate (309) in the core unit (312) of the solar hydrogen hydrolysis hydrogen generator are connected to an external unit, and a voltage is applied to the core unit of the solar hydrogen hydrogen generator to promote water photolysis carry out; 上层透光板(307)，下层支撑板(308)，下端板(313)，上端板(314)提供对太阳能水解氢发生器核心单元(312)支撑，形成一个容器，存储待光解的水；为催化剂层(311)提供支撑；The upper light-transmitting plate (307), the lower support plate (308), the lower end plate (313), and the upper end plate (314) provide support to the solar hydrolytic hydrogen generator core unit (312), forming a container to store the water to be photolyzed ; Provide support for the catalyst layer (311); 上层透光电极板(306)，上层透光板(307)是两个单独的部件；或上层透光电极板(306)，上层透光板(307)是同一部件，ITO板，或FTO板，或镀金属膜玻璃板；Upper transparent electrode plate (306), upper transparent plate (307) are two separate components; or upper transparent electrode plate (306), upper transparent plate (307) are the same component, ITO plate, or FTO plate , Or metal plated glass plate; 下层电极板(309)，下层支撑板(308)是两个独立部件；或下层电极板(309)，下层支撑板(308)是同一部件，金属板，或石墨板，或镀导电层的高分子板，或镀导电层非金属材料板；The lower electrode plate (309) and the lower support plate (308) are two independent components; or the lower electrode plate (309) and the lower support plate (308) are the same component, metal plate, or graphite plate, or the height of the conductive layer Molecular plate, or non-metallic material plated with conductive layer; 上层透光电极板(306)构成一个电极，下层电极板(309)构成另外一个电极；在上层透光电极板(306)和下层电极板(309)加上电压即构成一个电场，为催化剂层(311)提供一个偏置电压，或偏置电流，或电场场强；The upper light-transmitting electrode plate (306) constitutes an electrode, and the lower electrode plate (309) constitutes another electrode; applying voltage to the upper light-transmitting electrode plate (306) and the lower electrode plate (309) constitutes an electric field, which is a catalyst layer (311) Provide a bias voltage, or bias current, or electric field strength; 催化剂层(311)将水在太阳光和催化剂共同作用下，将水水解为氢气和氧气；或在太阳光、催化剂和电场的共同作用下，将水水解为氢气和氧气；The catalyst layer (311) hydrolyzes water to hydrogen and oxygen under the combined action of sunlight and catalyst; or hydrolyzes water to hydrogen and oxygen under the combined action of sunlight, catalyst and electric field; 伺服系统(315)控制太阳能水解氢发生器核心单元(312)，使太阳能水解氢发生器核心单元(312)跟踪太阳光，使太阳能水解氢发生器核心单元(312)垂直接收太阳光线，使太阳能水解氢发生器核心单元(312)得到最多的太阳光辐射。The servo system (315) controls the solar hydrolyzed hydrogen generator core unit (312), causes the solar hydrolyzed hydrogen generator core unit (312) to track sunlight, and enables the solar hydrolyzed hydrogen generator core unit (312) to vertically receive solar light, so that solar energy The hydrolyzed hydrogen generator core unit (312) gets the most solar radiation. 根据权利要求1所述的基于氢循环的太阳能制氢、储氢与应用系统，其特征是：The solar hydrogen production, hydrogen storage and application system based on the hydrogen cycle according to claim 1, characterized in that: 氢气的水合物溶液存储器的结构，自然扩散：对较小的太阳能水解氢系统，可采用氢气在水合物中自然扩散；Hydrogen hydrate solution storage structure, natural diffusion: For smaller solar hydrolyzed hydrogen systems, hydrogen can be naturally diffused in the hydrate; 氢气的水合物溶液存储器的结构，泵驱动扩散：如图6所示，氢气的水合物溶液存储箱(601)，氢气输入管(602)，扩散泵(603)，未溶解的氢气(604)，氢气的水合物溶液(605)，单向阀(606)；电阻丝(607)；氢气抽气机(608)；Structure of hydrogen hydrate solution storage, pump-driven diffusion: As shown in Figure 6, hydrogen hydrate solution storage tank (601), hydrogen input pipe (602), diffusion pump (603), undissolved hydrogen (604) , Hydrogen hydrate solution (605), one-way valve (606); resistance wire (607); hydrogen aspirator (608); 氢气输入管(602)连接氢气传输管(203)，将氢气输入到氢气的水合物溶液存储箱(601)中，单向阀(606)控制太阳能水解氢发生器(202)产生的氢气可通入到氢气的水合物溶液存储箱(601)中，同时阻止氢气的水合物溶液(605)中的水合物溶液回流到氢气的水合物溶液存储箱(601)中；未溶解的氢气(604)经过扩散泵(603)输入到氢气的水合物溶液存储箱(601)的底部，未溶解的氢气经过扩散泵(603)不断的单向抽取，将氢气不断溶解到氢气水合物溶液中；The hydrogen inlet pipe (602) is connected to the hydrogen transmission pipe (203), and the hydrogen is input into the hydrogen hydrate solution storage tank (601), and the one-way valve (606) controls the hydrogen produced by the solar hydrolyzed hydrogen generator (202) to pass through Into the hydrogen hydrate solution storage tank (601), while preventing the hydrate solution in the hydrogen hydrate solution (605) from flowing back into the hydrogen hydrate solution storage tank (601); undissolved hydrogen (604) Input to the bottom of the hydrogen hydrate solution storage tank (601) through the diffusion pump (603), the undissolved hydrogen is continuously pumped unidirectionally through the diffusion pump (603) to continuously dissolve the hydrogen into the hydrogen hydrate solution; 对氢气的水合物溶液存储箱(601)加压强时增加氢气在氢气的水合物溶液(605)溶解度，从而实现更多的氢气溶解在氢气的水合物溶液(605)中。When the hydrogen hydrate solution storage tank (601) is pressurized, the solubility of hydrogen in the hydrogen hydrate solution (605) is increased, so that more hydrogen is dissolved in the hydrogen hydrate solution (605). 根据权利要求1所述的基于氢循环的太阳能制氢、储氢与应用系统，其特征是：The solar hydrogen production, hydrogen storage and application system based on the hydrogen cycle according to claim 1, characterized in that: 氢气的水合物析氢，氢气进入燃料电池发电：减压析氢；加温析氢；添加氢表面活性剂反应物析氢；Hydrogen evolution of hydrogen hydrate, hydrogen enters the fuel cell for power generation: decompression hydrogen evolution; heating hydrogen evolution; adding hydrogen surfactant reactant hydrogen evolution; 减压析氢：用氢气抽气机(608)抽去部分氢气后，氢气在氢气水合物溶液(605)溶解度将减少，从而有更多的氢气析出氢气 的水合物溶液(605)，放出氢气；Hydrogen evolution under reduced pressure: After removing part of the hydrogen with a hydrogen aspirator (608), the solubility of hydrogen in the hydrogen hydrate solution (605) will be reduced, so that more hydrogen will evolve out of the hydrogen hydrate solution (605) and hydrogen will be released; 加热析氢：电阻丝(607)通电时对氢气的水合物溶液(605)加热，氢气在氢气的水合物溶液(605)溶解度将减少，从而有更多的氢气析出氢气的水合物溶液(605)，放出氢气；Heating hydrogen evolution: When the resistance wire (607) is energized, the hydrogen hydrate solution (605) is heated, and the solubility of hydrogen in the hydrogen hydrate solution (605) will be reduced, so that more hydrogen precipitates hydrogen hydrate solution (605) , Emit hydrogen; 在氢气水合物溶液(605)中加入与氢表面活性剂功能团的反应物，减少氢表面活性剂的有效量，从而使氢气在氢气水合物溶液(605)中的氢气溶解度降低，放出氢气，实现析氢。Add the reactant with the hydrogen surfactant functional group to the hydrogen hydrate solution (605) to reduce the effective amount of the hydrogen surfactant, thereby reducing the solubility of hydrogen in the hydrogen hydrate solution (605) and releasing the hydrogen. Achieve hydrogen evolution. 根据权利要求1所述的基于氢循环的太阳能制氢、储氢与应用系统，其特征是：The solar hydrogen production, hydrogen storage and application system based on the hydrogen cycle according to claim 1, characterized in that: 氢气的水合物溶液(605)，循环流入氢气的水合物直接流入氢燃料电池与空气中的氧气，反应发电；或氢气水合物溶液(605)，循环流入氢气燃料电池与外加氧气反应发电。Hydrogen hydrate solution (605), the hydrate circulating into the hydrogen directly flows into the hydrogen fuel cell and oxygen in the air to react to generate electricity; or the hydrogen hydrate solution (605), circulating into the hydrogen fuel cell to react with the added oxygen to generate electricity. 根据权利要求1所述的基于氢循环的太阳能制氢、储氢与应用系统，其特征是：The solar hydrogen production, hydrogen storage and application system based on the hydrogen cycle according to claim 1, characterized in that: 励电电源：用氢燃料电池产生的电，为系统提供控制和偏置电压、或配置电流；利用氢燃料电池发出的电力为氢循环的太阳能储能的控制系统，如伺服系统(315)，温度传感器、氢气的水合物溶液存储箱(601)的电阻丝(607)提供电源；为氢燃料电池提供偏置电流、极板的加热提供电源；Excitation power supply: The electricity generated by the hydrogen fuel cell provides control and bias voltage, or configuration current for the system; the control system of solar energy storage using the power generated by the hydrogen fuel cell for the hydrogen cycle, such as the servo system (315), The temperature sensor and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the electrode plate; 或利用外加电源由市电整流稳压得到的电源，或电池，为系 统提供控制和偏置电压、或配置电流；利用氢燃料电池发出的电力为氢循环的太阳能储能的控制系统，如伺服系统(315)，温度传感器、氢气的水合物溶液存储箱(601)的电阻丝(607)提供电源；为氢燃料电池提供偏置电流、极板的加热提供电源。Or use an external power source obtained from the rectification and stabilization of commercial power, or a battery, to provide control and bias voltage, or configure current for the system; use the power generated by the hydrogen fuel cell to control the solar energy storage system of the hydrogen cycle, such as servo The system (315), the temperature sensor, and the resistance wire (607) of the hydrogen hydrate solution storage tank (601) provide power; provide the bias current for the hydrogen fuel cell, and provide power for the heating of the electrode plate. 根据权利要求1所述的基于氢循环的太阳能制氢、储氢与应用系统，其特征是：The solar hydrogen production, hydrogen storage and application system based on the hydrogen cycle according to claim 1, characterized in that: 利用现有的柴油机，氢气的水合物溶液代替柴油，第三冲程喷入氢气的水合物溶液，氢气及水合物中的表面活性剂和空气中的氧气混合燃烧，推动活塞做功；Using the existing diesel engine, the hydrogen hydrate solution replaces the diesel, the hydrogen hydrate solution is injected into the third stroke, the hydrogen and the surfactant in the hydrate are mixed with the oxygen in the air to promote the piston to do work; 或者利用现有的汽油机，氢气及水合物溶液代替汽油，第一冲程吸入氢气的水合物溶液，第三冲程火花塞点火，氢气及水合物中的表面活性剂和空气的混合物燃烧，推动活塞做功；Or use the existing gasoline engine, hydrogen and hydrate solution to replace gasoline, inhale hydrogen hydrate solution in the first stroke, spark plug ignition in the third stroke, the mixture of surfactant and air in the hydrogen and hydrate burns, and push the piston to do work; 或者利用现有的柴油机，利用减压析出，或加温析氢，或反应析氢的氢气代替柴油，第三冲程喷入氢气，氢气和空气的混合物燃烧，推动活塞做功；Or use the existing diesel engine, use decompression precipitation, or heating hydrogen evolution, or reaction hydrogen evolution hydrogen instead of diesel, inject hydrogen in the third stroke, the mixture of hydrogen and air burns, and push the piston to do work; 或者利用现有的汽油机，将利用减压析出，或加温析氢，或反应析氢，析出的氢气代替汽油，第一冲程喷入氢气，第三冲程火花塞点火氢气和空气的混合物燃烧，推动活塞做功。Or use the existing gasoline engine, which will use vacuum decompression, hydrogenation by heating, or hydrogen evolution by reaction, and the precipitated hydrogen will replace gasoline. Hydrogen is injected in the first stroke, and the mixture of hydrogen and air is burned by the spark plug in the third stroke to promote the piston to work. . 根据权利要求1所述的基于氢循环的太阳能制氢、储氢与应用系统，其特征是：The solar hydrogen production, hydrogen storage and application system based on the hydrogen cycle according to claim 1, characterized in that: 利用管道或压力罐输送氢气或氢气水合液；氢气燃烧炉利用现有的燃料炉，自然燃烧：管道或压力罐连接燃气灶，利用管道或压力罐连接燃气灶输送氢气或氢气水合液；Use pipelines or pressure tanks to transport hydrogen or hydrogen hydration liquid; hydrogen combustion furnaces use existing fuel furnaces to burn naturally: pipelines or pressure tanks connect to gas stoves, and pipelines or pressure tanks connect to gas stoves to transport hydrogen or hydrogen hydration liquids; 管道内压缩氢气或压力罐的压缩氢气经过减压阀连接燃气灶，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水；Compressed hydrogen in the pipeline or compressed hydrogen in the pressure tank is connected to the gas stove through the pressure reducing valve. After ignition, the hydrogen and the oxygen in the air are burned to obtain heat energy for human use, while releasing pure water without pollution; 或管道内压缩氢水合物或压力罐的氢水合物经过减压阀连接燃气灶，氢气水合物经过减压析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水；Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the gas stove through the pressure reducing valve. The hydrogen hydrate precipitates hydrogen after decompression. After ignition, the hydrogen and the oxygen in the air are burned to obtain thermal energy for human use and released at the same time. Pure water without pollution; 或管道内压缩氢水合物或压力罐的氢水合物连接加热器，加热器加热氢水合物，氢气水合物经过加热析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水；Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the heater. The heater heats the hydrogen hydrate. The hydrogen hydrate precipitates hydrogen after heating. After ignition, the hydrogen and the oxygen in the air burn to obtain thermal energy for human use. At the same time, release pure water without pollution; 或管道内压缩氢水合物或压力罐的氢水合物连接反应器，反应器中氢水合物中加入氢表面活性剂反应物，氢气水合物经过添加氢表面活性剂反应物析出氢气，经点火，氢气与空气中的氧气燃烧获得热能，供人类使用，同时放出无污染的纯水。Or the compressed hydrogen hydrate in the pipeline or the hydrogen hydrate in the pressure tank is connected to the reactor, the hydrogen hydrate reactant is added to the hydrogen hydrate in the reactor, and the hydrogen hydrate precipitates hydrogen gas by adding the hydrogen surfactant reactant and is ignited. Hydrogen and oxygen in the air are burned to obtain heat energy for human use, while releasing pure water without pollution.
PCT/CN2018/113246 2018-10-30 2018-11-01 Hydrogen cycle-based solar hydrogen production, storage and application system Ceased WO2020087425A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201811281124.6 2018-10-30
CN201811281124.6A CN111129551A (en) 2018-10-30 2018-10-30 Solar hydrogen production, storage and application system based on hydrogen circulation

Publications (1)

Publication Number Publication Date
WO2020087425A1 true WO2020087425A1 (en) 2020-05-07

Family

ID=70462913

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2018/113246 Ceased WO2020087425A1 (en) 2018-10-30 2018-11-01 Hydrogen cycle-based solar hydrogen production, storage and application system

Country Status (2)

Country Link
CN (1) CN111129551A (en)
WO (1) WO2020087425A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12447609B2 (en) * 2022-01-11 2025-10-21 Omron Corporation Manufacturing system

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101841277A (en) * 2009-03-17 2010-09-22 无锡尚弗能源科技有限公司 Renewable energy source energy storage hydrogen storage comprehensive generating system
WO2010142004A8 (en) * 2009-06-10 2011-11-24 Katholieke Universiteit Leuven Controlled biosecure aquatic farming system in a confined environment
CN103422112A (en) * 2013-06-21 2013-12-04 高幼苏 Method and system for preparing hydrogen and carrying out combined water supply and power supply
CN103523750A (en) * 2013-09-27 2014-01-22 湖北洛克泰克仪器有限公司 Reaction device and method for hydrogen production through photocatalytic water splitting
CN103601148A (en) * 2013-10-31 2014-02-26 苏长华 Solar energy-normal pressure direct current glow plasma water photolysis hydrogen production method and device
US8691068B1 (en) * 2007-11-09 2014-04-08 University Of Central Florida Research Foundation, Inc. Solar metal sulfate-ammonia based thermochemical water splitting cycle for hydrogen production
CN104815597A (en) * 2015-05-10 2015-08-05 福建师范大学泉港石化研究院 Small-size integrated water photolysis hydrogen production reaction device

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8691068B1 (en) * 2007-11-09 2014-04-08 University Of Central Florida Research Foundation, Inc. Solar metal sulfate-ammonia based thermochemical water splitting cycle for hydrogen production
CN101841277A (en) * 2009-03-17 2010-09-22 无锡尚弗能源科技有限公司 Renewable energy source energy storage hydrogen storage comprehensive generating system
WO2010142004A8 (en) * 2009-06-10 2011-11-24 Katholieke Universiteit Leuven Controlled biosecure aquatic farming system in a confined environment
CN103422112A (en) * 2013-06-21 2013-12-04 高幼苏 Method and system for preparing hydrogen and carrying out combined water supply and power supply
CN103523750A (en) * 2013-09-27 2014-01-22 湖北洛克泰克仪器有限公司 Reaction device and method for hydrogen production through photocatalytic water splitting
CN103601148A (en) * 2013-10-31 2014-02-26 苏长华 Solar energy-normal pressure direct current glow plasma water photolysis hydrogen production method and device
CN104815597A (en) * 2015-05-10 2015-08-05 福建师范大学泉港石化研究院 Small-size integrated water photolysis hydrogen production reaction device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12447609B2 (en) * 2022-01-11 2025-10-21 Omron Corporation Manufacturing system

Also Published As

Publication number Publication date
CN111129551A (en) 2020-05-08

Similar Documents

Publication Publication Date Title
CN110342461A (en) A kind of reactor assembly and its starting method based on formic acid cracking hydrogen
CN102167285A (en) Portable, safe and controllable hydrolysis hydrogen-producing device
US9991536B2 (en) Self-supplied hydrogen fuel cell system and working method thereof
CN102777285A (en) Fuel supply system
CN202855854U (en) Solid oxide fuel cell system
US20100264021A1 (en) Hydrogen-oxygen mixed gas generating system
CN201373545Y (en) Hydrogen-oxygen water heater
CN111412380B (en) An integrated system of hydrogen production, storage, use and transportation
CN107099812A (en) A kind of apparatus for electrolyzing and with the device remove carbon combustion-supporting system
CN105347300B (en) A kind of quick cold start-up hydrogen from methyl alcohol machine system
CN110228791A (en) It is a kind of for removing the device of micro formic acid and steam in formic acid hydrogen production reaction product
US20130140189A1 (en) Compact electric appliance for providing gas for combustion
CN115021418A (en) Container type renewable energy electricity, heat and hydrogen co-production energy storage system and working method
CN105024088B (en) Vehicle-mounted high-temperature fuel cell cold starting system and working method thereof
WO2020087425A1 (en) Hydrogen cycle-based solar hydrogen production, storage and application system
CN116161619A (en) Online hydrogen production system for methanol of hydrogen diesel locomotive
CN112349926A (en) Vehicle-mounted fuel cell system capable of being started quickly
IE20150359A1 (en) A hydrogen reformer electrolysis device to improve combustion efficiency, fuel efficiency and emisions reduction on internal combustion engines.
CN212893903U (en) Solid hydrogen generating device
CN116025469A (en) A peak-shaving system for hydrogen production by electrolysis coupled with a gas-fired power station
CN115417376A (en) Device for removing trace formic acid and water vapor in formic acid hydrogen production reaction product
CN209352982U (en) A kind of apparatus for electrolyzing and carbon combustion-supporting system is removed equipped with the device
CN209838528U (en) Environment-friendly and safe hydrogen-oxygen separation device for automobile, ship and household fuel
CN201246786Y (en) Novel combustion stove
CN206412418U (en) A kind of water hydrogen generator

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18938253

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 18938253

Country of ref document: EP

Kind code of ref document: A1