WO2020068463A1 - Appareil et procédés de fabrication de verre - Google Patents
Appareil et procédés de fabrication de verre Download PDFInfo
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- WO2020068463A1 WO2020068463A1 PCT/US2019/051217 US2019051217W WO2020068463A1 WO 2020068463 A1 WO2020068463 A1 WO 2020068463A1 US 2019051217 W US2019051217 W US 2019051217W WO 2020068463 A1 WO2020068463 A1 WO 2020068463A1
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- WIPO (PCT)
- Prior art keywords
- molten material
- vessel
- streams
- forming
- weirs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
- C03B17/064—Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/02—Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
Definitions
- the present disclosure relates generally to glass manufacturing apparatus and methods for manufacturing glass and, more particularly, to apparatus and methods for forming a glass ribbon from a quantity of molten material.
- Glass sheets are commonly employed in display applications, for example, liquid crystal displays (LCDs), electrophoretic displays (EPD), organic light emitting diode displays (OLEDs), plasma display panels (PDPs), or the like.
- LCDs liquid crystal displays
- EPD electrophoretic displays
- OLEDs organic light emitting diode displays
- PDPs plasma display panels
- Glass sheets are commonly fabricated by flowing molten material to a forming body whereby a glass ribbon may be formed by a variety of ribbon forming processes, for example, slot draw, float, down-draw, fusion down-draw, rolling, or up-draw.
- the glass ribbon may then be subsequently divided to provide sheet glass suitable for further processing into a desired display application including, but not limited to, a screen or cover glass for mobile devices, televisions, computers, tablets, and other display monitors.
- a glass manufacturing apparatus including a glass forming apparatus for forming a glass ribbon from a quantity of molten material. It is also known to separate a glass sheet from the glass ribbon.
- a method of forming a glass ribbon can include overflowing a first quantity of a molten material from a first trough of a first supply vessel over first corresponding weirs of the first supply vessel and then flowing first respective streams of the first quantity of the molten material along first outer surfaces of the first corresponding weirs.
- the method can include overflowing a second quantity of the molten material from a second trough of a forming vessel over second corresponding weirs of the forming vessel and then flowing second respective streams of the second quantity of the molten material along second outer surfaces of the second corresponding weirs.
- the molten material providing the first quantity and the molten material providing the second quantity can be the same or essentially the same composition.
- the method can include converging the first respective streams and the second respective streams and fusing the first respective streams and the second respective streams into third respective streams of a third quantity of the molten material.
- the method can include flowing the third respective streams along a pair of downwardly inclined converging surface portions of a forming wedge of the forming vessel, converging the third respective streams at a root of the forming vessel defined as an edge of the forming wedge along which the pair of downwardly inclined converging surface portions intersect, and fusing the third respective streams into a ribbon of the molten material at the root of the forming vessel, and drawing the ribbon of the molten material off the root into a glass ribbon.
- the method can further include drawing the glass ribbon along a draw plane in a draw direction.
- the draw plane can bisect the forming wedge through the root.
- the draw plane can bisect the supply vessel through the first trough.
- the draw direction can extend in the direction of gravity.
- the first outer surfaces of the first corresponding weirs of the first supply vessel can be arranged vertically above the second outer surfaces of the second corresponding weirs of the forming vessel relative to the direction of gravity.
- the first respective streams, the second respective streams, and the third respective streams can flow based, at least in part, on the force of gravity.
- the method can include providing the first quantity of the molten material from a first inlet conduit to the first trough of the first supply vessel and providing the second quantity of the molten material from a second inlet conduit to the second trough of the forming vessel.
- the first and second quantities of the molten material can be supplied from a single melting vessel. In other embodiments, the first and second quantities of the molten material can be supplied from a plurality of melting vessels. For example, in some embodiments, the first quantity of the molten material can be supplied from a first melting vessel and the second quantity of the molten material can be supplied from a second melting vessel.
- the method can include adjusting a flow rate of at least one of the first quantity of the molten material from the first inlet conduit to the first trough of the first supply vessel and the second quantity of the molten material from the second inlet conduit to the second trough of the forming vessel.
- the method can include overflowing a fourth quantity of the molten material from a third trough of a second supply vessel over third corresponding weirs of the third supply vessel and then flowing fourth respective streams of the fourth quantity of the molten material along third outer surfaces of the third corresponding weirs.
- a composition of the molten material providing the fourth quantity can be the same or essentially the same as the molten material providing the first and second quantities.
- the fourth quantity of the molten material can be supplied from the same melting vessel as the first and second quantities of the molten material. In other embodiments, the fourth quantity of the molten material can be supplied from a melting vessel different than the melting vessel supplying the first and second quantities of the molten material.
- the method can include converging the fourth respective streams and the first respective streams and fusing the fourth respective streams and the first respective streams into fifth respective streams of a fifth quantity of the molten material.
- the method can include converging the fifth respective streams and the second respective streams, and fusing the fifth respective streams and the second respective streams into sixth respective streams of a sixth quantity of the molten material, and flowing the sixth respective streams along the pair of downwardly inclined converging surface portions of the forming wedge of the forming vessel, converging the sixth respective streams at the root of the forming vessel, and fusing the sixth respective streams into the ribbon of the molten material at the root of the forming vessel.
- the third outer surfaces of the third corresponding weirs of the second supply vessel can be arranged vertically above the first outer surfaces of the first corresponding weirs of the first supply vessel relative to the direction of gravity, and the first outer surfaces of the first corresponding weirs of the first supply vessel can be arranged vertically above the second outer surfaces of the second corresponding weirs of the forming vessel relative to the direction of gravity.
- the method can include providing the fourth quantity of the molten material from a third inlet conduit to the third trough of the second supply vessel.
- the method can include adjusting a flow rate of the fourth quantity of the molten material from the third inlet conduit to the third trough of the second supply vessel.
- a glass forming apparatus for forming a glass ribbon according to the method can include the first supply vessel including the first trough, the first corresponding weirs, and the first outer surfaces of the first corresponding weirs.
- the apparatus can include the forming vessel including the second trough, the second corresponding weirs, and the second outer surfaces of the second corresponding weirs.
- the forming vessel can further include the forming wedge including the pair of downwardly inclined converging surface portions extending between opposed ends of the forming wedge, the pair of downwardly inclined converging surface portions intersecting along the edge of the forming wedge defining the root of the forming vessel.
- the first outer surfaces of the first corresponding weirs of the first supply vessel can be arranged vertically above the second outer surfaces of the second corresponding weirs of the forming vessel relative to the direction of gravity.
- FIG. 1 schematically illustrates an exemplary embodiment of a glass manufacturing apparatus in accordance with embodiments of the disclosure
- FIG. 2 shows a perspective cross-sectional view of the glass manufacturing apparatus along line 2-2 of FIG. 1 in accordance with embodiments of the disclosure
- FIG. 3 schematically illustrates an exemplary embodiment of the glass manufacturing apparatus of FIG. 1 including a plurality of supply vessels in accordance with embodiments of the disclosure
- FIG. 4 shows a cross-sectional view of the glass manufacturing apparatus including the plurality of supply vessels along line 4-4 of FIG. 3 in accordance with embodiments of the disclosure
- FIG. 5 shows an enlarged view of a portion of the glass manufacturing apparatus including the plurality of supply vessels taken at view 5 of FIG. 4 in accordance with embodiments of the disclosure.
- FIG. 6 shows an enlarged view taken at view 6 of FIG. 4 showing a portion of a glass ribbon formed in accordance with embodiments of the disclosure.
- a glass manufacturing apparatus can include a glass forming apparatus that forms a glass article (e.g., a glass ribbon and/or a glass sheet) from a quantity of molten material.
- the glass manufacturing apparatus can include a glass forming apparatus such as a slot draw apparatus, float bath apparatus, down-draw apparatus, up-draw apparatus, press-rolling apparatus, or other glass forming apparatus that forms a glass article.
- the glass article can be employed in a variety of display applications including, but not limited to, liquid crystal displays (LCDs), electrophoretic displays (EPD), organic light emitting diode displays (OLEDs), plasma display panels (PDPs), and other electronic displays.
- LCDs liquid crystal displays
- EPD electrophoretic displays
- OLEDs organic light emitting diode displays
- PDPs plasma display panels
- the present disclosure relates to glass manufacturing apparatus and methods for manufacturing glass. Methods and apparatus for manufacturing glass will now be described by way of exemplary embodiments for forming a glass ribbon from a quantity of molten material.
- an exemplary glass manufacturing apparatus 100 can include a glass melting and delivery apparatus 102 and a forming apparatus 101 including a forming vessel 140 designed to produce a glass ribbon 103 from a quantity of molten material 121.
- the glass ribbon 103 can include a central portion 152 disposed between opposite, relatively thick edge beads formed along a first outer edge 153 and a second outer edge 155 of the glass ribbon 103.
- a glass sheet 104 can be separated from the glass ribbon 103 along a separation path 151 by a glass separator 149 (e.g., scribe, score wheel, diamond tip, laser, etc.).
- the relatively thick edge beads formed along the first outer edge 153 and the second outer edge 155 can be removed to provide the central portion 152 as a high-quality glass sheet 104 having a uniform thickness.
- the glass melting and delivery apparatus 102 can include a melting vessel 105 oriented to receive batch material 107 from a storage bin 109.
- the batch material 107 can be introduced by a batch delivery device 111 powered by a motor 113.
- an optional controller 115 can be operated to activate the motor 113 to introduce a desired amount of batch material 107 into the melting vessel 105, as indicated by arrow 117.
- the melting vessel 105 can heat the batch material 107 to provide molten material 121.
- a melt probe 119 can be employed to measure a level of molten material 121 within a standpipe 123 and communicate the measured information to the controller 115 by way of a communication line 125.
- the glass melting and delivery apparatus 102 can include a first conditioning station including a fining vessel 127 located downstream from the melting vessel 105 and coupled to the melting vessel 105 by way of a first connecting conduit 129.
- molten material 121 can be gravity fed from the melting vessel 105 to the fining vessel 127 by way of the first connecting conduit 129.
- gravity can drive the molten material 121 through an interior pathway of the first connecting conduit 129 from the melting vessel 105 to the fining vessel 127.
- bubbles can be removed from the molten material 121 within the fining vessel 127 by various techniques.
- the glass melting and delivery apparatus 102 can further include a second conditioning station including a mixing chamber 131 that can be located downstream from the fining vessel 127.
- the mixing chamber 131 can be employed to provide a homogenous composition of molten material 121, thereby reducing or eliminating inhomogeneity that may otherwise exist within the molten material 121 exiting the fining vessel 127.
- the fining vessel 127 can be coupled to the mixing chamber 131 by way of a second connecting conduit 135.
- molten material 121 can be gravity fed from the fining vessel 127 to the mixing chamber 131 by way of the second connecting conduit 135.
- gravity can drive the molten material 121 through an interior pathway of the second connecting conduit 135 from the fining vessel 127 to the mixing chamber 131.
- the glass melting and delivery apparatus 102 can include a third conditioning station including a delivery vessel 133 that can be located downstream from the mixing chamber 131.
- the delivery vessel 133 can condition the molten material 121 to be fed into an inlet conduit 141.
- the delivery vessel 133 can function as an accumulator and/or flow controller to adjust and provide a consistent flow of molten material 121 to the inlet conduit 141.
- the mixing chamber 131 can be coupled to the delivery vessel 133 by way of a third connecting conduit 137.
- molten material 121 can be gravity fed from the mixing chamber 131 to the delivery vessel 133 by way of the third connecting conduit 137.
- gravity can drive the molten material 121 through an interior pathway of the third connecting conduit 137 from the mixing chamber 131 to the delivery vessel 133.
- a delivery pipe 139 can be positioned to deliver molten material 121 to forming apparatus 101, for example the inlet conduit 141 of the forming vessel 140.
- Forming apparatus 101 can comprise various embodiments of forming vessels in accordance with features of the disclosure including a forming vessel with a wedge for fusion drawing the glass ribbon, a forming vessel with a slot to slot draw the glass ribbon, or a forming vessel provided with press rolls to press roll the glass ribbon from the forming vessel.
- the forming vessel 140 shown and disclosed below can be provided to fusion draw molten material 121 off a bottom edge of a forming wedge 209, defined as an edge of the forming wedge along which the downwardly inclined converging surface portions intersect, and further defined as root 145, to produce a ribbon of molten material 121 that can be drawn into the glass ribbon 103.
- the molten material 121 can be delivered from the inlet conduit 141 to the forming vessel 140.
- the molten material 121 can then be formed into the glass ribbon 103 based at least in part on the structure of the forming vessel 140.
- the molten material 121 can be drawn off the bottom edge (e.g., root 145) of the forming vessel 140 along a draw path extending in a draw direction 154 of the glass manufacturing apparatus 100.
- edge directors 163, 164 can direct the molten material 121 off the forming vessel 140 and define, at least in part, a width“W” of the glass ribbon 103.
- the width“W” of the glass ribbon 103 can extend between the first outer edge 153 of the glass ribbon 103 and the second outer edge 155 of the glass ribbon 103.
- the width“W” of the glass ribbon 103 can be greater than or equal to about 20 mm, such as greater than or equal to about 50 mm, such as greater than or equal to about 100 mm, such as greater than or equal to about 500 mm, such as greater than or equal to about 1000 mm, such as greater than or equal to about 2000 mm, such as greater than or equal to about 3000 mm, such as greater than or equal to about 4000 mm, although other widths less than or greater than the widths mentioned above can be provided in further embodiments.
- the width“W” of the glass ribbon 103 can be from about 20 mm to about 4000 mm, such as from about 50 mm to about 4000 mm, such as from about 100 mm to about 4000 mm, such as from about 500 mm to about 4000 mm, such as from about 1000 mm to about 4000 mm, such as from about 2000 mm to about 4000 mm, such as from about 3000 mm to about 4000 mm, such as from about 20 mm to about 3000 mm, such as from about 50 mm to about 3000 mm, such as from about 100 mm to about 3000 mm, such as from about 500 mm to about 3000 mm, such as from about 1000 mm to about 3000 mm, such as from about 2000 mm to about 3000 mm, such as from about 2000 mm to about 2500 mm, and all ranges and subranges therebetween.
- FIG. 2 shows a cross-sectional perspective view of the forming apparatus 101 (e.g., forming vessel 140) along line 2-2 of FIG. 1.
- the forming vessel 140 can include a trough 201 oriented to receive the molten material 121 from the inlet conduit 141.
- a trough 201 oriented to receive the molten material 121 from the inlet conduit 141.
- cross- hatching of the molten material 121 is removed from FIG. 2 for clarity.
- the forming vessel 140 can further include the forming wedge 209 including a pair of downwardly inclined converging surface portions 207, 208 extending between opposed ends 210, 211 (See FIG. 1) of the forming wedge 209.
- the pair of downwardly inclined converging surface portions 207, 208 of the forming wedge 209 can converge along the draw direction 154 to intersect along the root 145 of the forming vessel 140.
- a draw plane 213 of the glass manufacturing apparatus 100 can extend through the root 145 along the draw direction 154.
- the glass ribbon 103 can be drawn in the draw direction 154 along the draw plane 213.
- the draw plane 213 can bisect the forming wedge 209 through the root 145 although, in some embodiments, the draw plane 213 can extend at other orientations relative to the root 145.
- the molten material 121 can flow in a direction 156 into and along the trough 201 of the forming vessel 140.
- the molten material 121 can then overflow from the trough 201 by simultaneously flowing over corresponding weirs 203, 204 and downward over the outer surfaces 205, 206 of the corresponding weirs 203, 204.
- Respective streams of molten material 121 can then flow along the downwardly inclined converging surface portions 207, 208 of the forming wedge 209 to be drawn off the root 145 of the forming vessel 140, where the flows converge and fuse into the glass ribbon 103.
- the glass ribbon 103 can then be drawn off the root 145 in the draw plane 213 along the draw direction 154.
- the glass separator 149 can then separate the glass sheet 104 from the glass ribbon 103 along the separation path 151.
- the separation path 151 can extend along the width“W” of the glass ribbon 103 between the first outer edge 153 and the second outer edge 155.
- the separation path 151 can extend perpendicular to the draw direction 154 of the glass ribbon 103.
- the draw direction 154 can define a direction along which the glass ribbon 103 can be drawn from the forming vessel 140.
- the glass ribbon 103 can be drawn from the root 145 with a first major surface 215 of the glass ribbon 103 and a second major surface 216 of the glass ribbon 103 facing opposite directions and defining a thickness“T” (e.g., average thickness) of the glass ribbon 103.
- the thickness “T’ of the glass ribbon 103 can be less than or equal to about 2 millimeters (mm), less than or equal to about 1 millimeter, less than or equal to about 0.5 millimeters, for example, less than or equal to about 300 micrometers (pm), less than or equal to about 200 micrometers, or less than or equal to about 100 micrometers, although other thicknesses may be provided in further embodiments.
- the thickness“T’ of the glass ribbon 103 can be from about 50 pm to about 750 pm, from about 100 pm to about 700 pm, from about 200 pm to about 600 pm, from about 300 pm to about 500 pm, from about 50 pm to about 500 pm, from about 50 pm to about 700 pm, from about 50 pm to about 600 pm, from about 50 pm to about 500 pm, from about 50 pm to about 400 pm, from about 50 pm to about 300 pm, from about 50 pm to about 200 pm, from about 50 pm to about 100 pm, including all ranges and subranges of thicknesses therebetween.
- the glass ribbon 103 can include a variety of compositions including, but not limited to, soda-lime glass, borosilicate glass, alumino-borosilicate glass, alkali-containing glass, or alkali-free glass.
- FIG. 3 shows an alternate exemplary embodiment of the glass manufacturing apparatus 100 and glass forming apparatus 101 including one or more supply vessels 300. While a plurality of supply vessels are shown in FIG. 3, it is to be understood that in some embodiments forming apparatus 101 can comprise a single supply vessel. However, for further discussion, a plurality of supply vessels will be described.
- a respective inlet conduit 341a, 341b, 341c, 341d can provide each supply vessel 309a, 309b, 309c, 309d of the plurality of supply vessels 300 with a corresponding quantity of molten material 321a, 321b, 321c, 321d.
- a single glass melting and delivery apparatus 102 can provide molten material 121 from delivery pipe 139 to inlet conduit 141.
- the glass melting and delivery apparatus 102 and/or the glass forming apparatus 101 can include a plurality of pipes (not shown) that define a plurality of fluid communication paths between the delivery pipe 139 and each of the inlet conduits 341a, 341b, 341c, 341d.
- the molten material 121 from the single glass melting and delivery apparatus 102 can flow from the delivery pipe 139 through the respective plurality of pipes, such as through a distribution manifold (not shown), to the corresponding plurality of inlet conduits 341a, 341b, 341c, 341d, thereby providing each supply vessel 309a, 309b, 309c, 309d of the plurality of supply vessels 300 with a corresponding quantity of molten material 321a, 321b, 321c, 321d.
- glass manufacturing apparatus 100 can comprise two or more glass melting and delivery apparatus 102 that can provide molten material 321a, 321b, 321c, 321d from the two or more glass melting and delivery apparatus 102 to the plurality of inlet conduits 341a, 341b, 341c, 341d of the supply vessels 309a, 309b, 309c, 309d through respective delivery pipes 139.
- molten material 321a, 321b, 321c, 321d from the two or more glass melting and delivery apparatus 102 to the plurality of inlet conduits 341a, 341b, 341c, 341d of the supply vessels 309a, 309b, 309c, 309d through respective delivery pipes 139.
- one or more glass melting and delivery apparatus 102 and/or a plurality of pipes can be provided, alone or in combination, to provide the inlet conduits 341a, 341b, 341c, 341d of the supply vessels 309a, 309b, 309c, 309d of the plurality of supply vessels 300 with molten material 321a, 321b, 321c, 321d as well as the inlet conduit 141 of the forming vessel 140 with molten material 121 without departing from the scope of the disclosure.
- the quantity of molten material 121 provided to the forming vessel 140 and/or the quantity of molten material 321a, 321b, 321c, 321d provided to the supply vessels 309a, 309b, 309c, 309d can be controlled independently and separately such that one or more of the forming vessel 140 and the supply vessels 309a, 309b, 309c, 309d can be selectively and independently provided with no molten material, the same quantity of molten material, and/or various quantities of molten material in accordance with embodiments of the disclosure.
- one supply vessel e.g., supply vessel 309a
- two supply vessels e.g., supply vessel 309a, 309b
- three supply vessels e.g., supply vessel 309a, 309b, 309c
- four supply vessels e.g., supply vessel 309a, 309b, 309c, 309d
- four supply vessels e.g., supply vessel 309a, 309b, 309c, 309d
- defining the plurality of supply vessels 300 can be provided with the forming vessel 140, to form the glass ribbon 103 without departing from the scope of the disclosure.
- each supply vessel 309a, 309b, 309c, 309d can include a respective trough 401a, 401b, 401c, 401d oriented to receive the molten material 321a, 321b, 321c, 321d from the respective inlet conduits 341a, 341b, 341c, 341d (FIG. 3).
- the supply vessels 309a, 309b, 309c, 309d can be arranged such that the respective molten material 321a, 321b, 321c, 321d flows in the same direction in troughs 401a, 401b, 401c, 401d.
- the supply vessels 309a, 309b, 309c, 309d can be arranged such that the respective molten material 321a, 321b, 321c, 321d can flow in different directions in troughs 401a, 401b, 401c, 401d relative to each other. For example, as illustrated in FIG.
- the orientations of the inlet conduits 341a, 341b, 341c, 341d of the supply vessels 309a, 309b, 309c, 309d of the plurality of supply vessels 300 alternate such that molten material in the troughs of any two vertically adjacent supply vessels (and/or the forming vessel 140) flows in opposite directions.
- the molten material 321a, 321b, 321c, 321d can then overflow from the troughs 401a, 401b, 401c, 401d by simultaneously flowing over corresponding weirs 403a, 404a, 403b, 404b, 403c, 404c, 403d, 404d and downward over the outer surfaces 405a, 406a, 405b, 406b, 405c, 406c, 405d, 406d, of the corresponding weirs 403a, 404a, 403b, 404b, 403c, 404c, 403d, 404d.
- the draw plane 213 can bisect the supply vessels 309a, 309b, 309c, 309d through the troughs 401a, 401b, 401c, 40 Id although, in some embodiments, the draw plane 213 can extend at other orientations relative to the troughs
- each supply vessel 309a, 309b, 309c, 309d can be spaced apart along the draw plane 213 in the draw direction 154.
- supply vessel 309a can be spaced a distance“dl” from forming wedge 209
- supply vessel 309b can be spaced a distance“d2” from supply vessel 309a
- supply vessel 309c can be spaced a distance“d3” from supply vessel 309b
- supply vessel 309d can be spaced a distance“d4” from supply vessel 309c.
- the distances“dl”,“d2”,“d3”,“d4” can be equal, however, in some embodiments, one or more of distances“dl”,“d2”,“d3”, or“d4” can be different.
- the supply vessels 309a, 309b, 309c, 309d can be fixedly or movable mounted to a frame or other support structure (not shown) to support the supply vessels 309a, 309b, 309c, 309d and define a relative positioning of the supply vessels 309a, 309b, 309c, 309d.
- the outer surfaces 405d, 406d of the corresponding weirs 403d, 404d of supply vessel 309d can be arranged vertically above (e.g., spaced distance“d4” from) the outer surfaces 405c, 406c of the corresponding weirs 403c, 404c of supply vessel 309c relative to the direction of gravity“g”.
- the outer surfaces 405c, 406c of the corresponding weirs 403c, 404c of supply vessel 309c can be arranged vertically above (e.g., spaced distance“d3” from) the outer surfaces 405b, 406b of the corresponding weirs 403b, 404b of supply vessel 309b relative to the direction of gravity“g”.
- the outer surfaces 405b, 406b of the corresponding weirs 403b, 404b of supply vessel 309b can be arranged vertically above (e.g., spaced distance“d2” from) the outer surfaces 405a, 406a of the corresponding weirs 403a, 404a of supply vessel 309a relative to the direction of gravity“g”.
- the outer surfaces 405a, 406a of the corresponding weirs 403a, 404a of supply vessel 309a can be arranged vertically above (e.g., spaced distance“dl” from) the outer surfaces 205, 206 of the corresponding weirs 203, 204 of forming vessel 140 relative to the direction of gravity“g”.
- respective streams of molten material 321a, 321b, 321c, 321d can then flow along the outer surfaces 405a, 406a, 405b, 406b, 405c, 406c, 405d, 406d, of the corresponding weirs 403a, 404a, 403b, 404b, 403c, 404c, 403d, 404d of each supply vessel 309a, 309b, 309c, 309d where the respective streams can merge and fuse together.
- the streams of molten material 32 ld can merge with the streams of molten material 32 lc, wherein the merged streams of molten material 32 ld and 32 lc can merge with the streams of molten material 32 lb, and wherein the merged streams of molten material 32 ld, 32 lc, and 32 ld can merge with the streams of molten material 32 la.
- each supply vessel 309a, 309b, 309c, 309d can include the same or similar features, although, in some embodiments, one or more supply vessels 309a, 309b, 309c, 309d can include one or more different features, including but not limited to different dimensions, sizes, shapes, and orientations, without departing form the scope of the disclosure.
- the molten material 121 can overflow from the trough 201 of the forming wedge 209 by simultaneously flowing over corresponding weirs 203, 204 and downward over the outer surfaces 205, 206 of the corresponding weirs 203, 204.
- the merged streams of molten material 321a, 321b, 321c, 32 ld from the supply vessels 309a, 309b, 309c, 309d can then fuse with molten material 121 from the forming vessel 140.
- the merged streams of molten material 121, 321a, 321b, 321c, 321d can then flow along the downwardly inclined converging surface portions 207, 208 of the forming wedge 209 and be drawn off the root 145 of the forming vessel 140, where the streams converge and fuse into the glass ribbon 103.
- the glass ribbon 103 (formed from the converged streams of molten material 121, 321a, 321b, 321c, 321d) can then be drawn off the root 145 of the forming wedge 209 in the draw plane 213 along the draw direction 154.
- FIG. 5 shows an enlarged view of a portion of the glass manufacturing apparatus 100 including the plurality of supply vessels 300 taken at view 5 of FIG. 4.
- supply vessel 309b can be spaced distance“d2” vertically above supply vessel 309a relative to the direction of gravity“g”.
- a stream 501 of molten material can flow along path 511 along the outer surface 406b of the corresponding weir 404b of supply vessel 309b.
- a stream 502 of molten material 321a can then overflow from the trough 401a by flowing along path 512 over corresponding weir 404a.
- the stream 501 along path 511 and the stream 502 along path 512 can merge at location 505, where stream 503 (defined by merged streams 501, 502) can flow downward along path 513 over the outer surface 406a of the corresponding weir 404a.
- Stream 503 flowing along path 513 can then merge with the flow of molten material 121 from forming vessel 140 to produce the glass ribbon 103 based at least in part on the structure of forming wedge 209 (FIG. 3 and FIG. 4).
- stream 503 flowing along path 513 can include merged streams of molten material 321d from supply vessel 309d, molten material 321c from supply vessel 309c, molten material 321b from supply vessel 309b, and molten material 321a from supply vessel 309a fused together as stream 503.
- stream 503 flowing along path 513 can include one or more merged streams of molten material from one or more of the plurality of supply vessels 300 fused together in accordance with embodiments of the disclosure.
- stream 503 flowing along path 513 merging with molten material 121 overflowing forming vessel 140 can include the respective streams of molten material flowing from one or more vessels of the plurality of supply vessels 300 positioned vertically above the forming vessel 140 relative to the direction of gravity“g”.
- one or more vessels of the plurality of supply vessels 300 can be provided with differing quantities of molten material, including no molten material (e.g., zero flow).
- the plurality of supply vessels 300 can include one or more active (e.g.
- stream 503 flowing along path 513 merging with molten material 121 overflowing forming vessel 140 can include the respective streams of molten material flowing from the one or more active vessels of the plurality of supply vessels 300 positioned vertically above the forming vessel 140 relative to the direction of gravity“g” defined by the one or more non-zero, positive quantity flows of molten material.
- FIG. 6 which shows an enlarged view taken at view 6 of FIG. 4 including a portion of the glass ribbon 103 formed in accordance with embodiments of the disclosure
- features of the disclosure can be provided to produce a glass ribbon 103 defining a continuous material composition from the first major surface 215 of the glass ribbon 103, through the thickness“T” of the glass ribbon 103, to the second major surface 216 of the glass ribbon 103.
- each supply vessel 309a, 309b, 309c, 309d of the plurality of supply vessels 300 can supply molten material 321a, 321b, 321c, 321d of the same material composition to the forming vessel 140 that can also include molten material 121 of the same material composition.
- the glass ribbon 103 produced with the forming wedge 209 can, therefore, be formed from one or more separate flows of molten material 121, 321a, 321b, 321c, 321d that fuse together to define the glass ribbon 103 having a single material composition with respect to a cross-section taken through the thickness“T” of the glass ribbon 103 and defined between the first major surface 215 and the second major surface 216, where the first major surface 215 and the second major surface 216 define outermost free surfaces of the glass ribbon 103.
- one or more features of the glass manufacturing apparatus 100 including the one or more glass melting and delivery apparatus 102 and the glass forming apparatus 101 including the forming vessel 140 and one or more supply vessels 300 can be provided, either alone in combination, to define apparatus and methods for producing the glass ribbon 103 in accordance with embodiments of the disclosure.
- features of the apparatus and steps of the methods of the disclosure can provide advantages that cannot otherwise be obtained by other apparatus and methods not including one or more features or steps of the disclosure.
- features of the disclosure can provide a relatively wide range of flow rates of molten material to produce the glass ribbon 103 than otherwise obtainable.
- the range of flow rates of molten material fusing together to form the glass ribbon 103 that are achievable by providing the forming vessel 140 and the plurality of supply vessels 300 (FIG. 3 and FIG. 4) are wider (e.g., larger) than the range of flow rates of molten material fusing together to form the glass ribbon 103 that are achievable by providing the forming vessel 140 with no supply vessels (FIG. 2).
- the ability to provide and control a wide range of flow rates of molten material fusing together to form the glass ribbon 103 can provide several advantages.
- the ability to provide and control a wide range of flow rates of molten material can provide a corresponding ability to provide and control features of the glass ribbon 103, including but not limited to, the size (e.g., thickness “T”, width “W”, length) of the glass ribbon 103.
- the ability to provide and control a wide range of flow rates of molten material can provide a corresponding ability to provide and control a wide range of draw speeds of the glass ribbon 103 along the draw plane 213 in the draw direction 154.
- providing and controlling a wide range of flow rates of molten material can enable faster draw speeds than previously attainable, thereby increasing the rate of production (e.g., output) of the glass forming apparatus 101, thus at least one of improving production efficiency or reducing manufacturing costs.
- draw speed of the glass ribbon 103 off the root 145 of the forming vessel 140 along the draw plane 213 in the draw direction 154 can be defined, at least in part, based on the flow rates (e.g., volume and/or speed) of molten material flowing, converging, and fusing together to form the glass ribbon 103.
- the range of flow rate of molten material 121 overflowing from the trough 201 by simultaneously flowing over corresponding weirs 203, 204 and downward over the outer surfaces 205, 206 of the corresponding weirs 203, 204 can be based on the flow rate of molten material 121 provided from inlet conduit 141 (FIG. 1).
- the flow rate of molten material 121 from inlet conduit 141 can be controlled (e.g., adjusted) by one or more of a flow valve, flow diverter, upstream quantity (e.g., volume) adjustment, or other flow control feature.
- the respective streams of molten material 121 flowing along the downwardly inclined converging surface portions 207, 208 of the forming wedge 209 that converge and fuse into the glass ribbon 103 to be drawn off the root 145 of the forming vessel 140 also have a flow rate defined as X +/- 10%.
- a flow rate of X +/- 10% can produce a glass ribbon 103 having desirable, predetermined characteristics and features.
- the glass ribbon 103 may include one or more undesirable characteristics or features.
- a flow rate of greater than X + 10% can create flow from the trough 201 simultaneously flowing over corresponding weirs 203, 204 and downward over the outer surfaces 205, 206 of the corresponding weirs 203, 204 that is inconsistent, stalled, and/or clogged (e.g., stopped or delayed from overflowing the weirs 203, 204), thereby producing a glass ribbon 103 with one or more undesirable characteristics or features (e.g., too thick, inconsistent thickness, bubbles, bulges, impurities, voids, etc.).
- undesirable characteristics or features e.g., too thick, inconsistent thickness, bubbles, bulges, impurities, voids, etc.
- the glass ribbon 103 may include one or more undesirable characteristics or features.
- a flow rate of less than X - 10% can create flow from the trough 201 simultaneously flowing over corresponding weirs 203, 204 and downward over the outer surfaces 205, 206 of the corresponding weirs 203, 204 that is inconsistent, intermittent, and/or broken (e.g., separated), thereby producing a glass ribbon 103 with one or more undesirable characteristics or features (e.g., too thin, inconsistent thickness, bubbles, bulges, impurities, voids, etc.).
- the range of flow rate of molten material 121 overflowing from the trough 201 by simultaneously flowing over corresponding weirs 203, 204 and downward over the outer surfaces 205, 206 of the corresponding weirs 203, 204 can be based on the flow rate of molten material 121 provided from inlet conduit 141.
- the flow rate of molten material 121 from inlet conduit 141 as well as the flow rate of molten material 321a, 321b, 321c, 321d from corresponding inlet conduits 341a, 341b, 341c, 341d can be controlled (e.g., adjusted) by one or more of a flow valve, flow diverter, upstream quantity (e.g., volume) adjustment, or other flow control feature.
- the respective streams of molten material 121, 321a, 321b, 321c, 321d flowing along the downwardly inclined converging surface portions 207, 208 of the forming wedge 209 that converge and fuse into the glass ribbon 103 to be drawn off the root 145 of the forming vessel 140 have a wide range of flow rates defined as X +/- 10% + Z(Y +/- 10), where Z corresponds to the number of supply vessels of the plurality of supply vessels 300.
- the number of supply vessels of the plurality of supply vessels 300 provided and/or operable at a specific time and/or during a predetermined duration of time can be selected such that the flow rate of molten material and, therefore, draw speeds of the glass ribbon 103 can be defined (e.g., controlled, adjusted, maintained) based on the number of supply vessels 300 including one or more (e.g., 1, 2, 3, 4, 5,... 10... 15, etc.) supply vessels 300 without departing from the scope of the disclosure.
- a flow rate of X +/- 10% with respect to forming vessel 140 and flow rates of Y +/- 10% with respect to each of the plurality of supply vessels 300 can produce a glass ribbon 103 having desirable, predetermined characteristics and features.
- draw speed of the glass ribbon 103 off the root 145 of the forming vessel 140 along the draw plane 213 in the draw direction 154 can be defined, at least in part, based on the flow rates (e.g., volume and/or speed) of molten material (e.g., molten material 121, 321a, 321b, 321c, 321d) flowing, converging, and fusing together to form the glass ribbon 103.
- flow rates e.g., volume and/or speed
- molten material e.g., molten material 121, 321a, 321b, 321c, 321d
- features in accordance with embodiments of the disclosure including a glass forming apparatus 101 including a forming vessel 140 and one or more supply vessels 300, can enable draw speeds (e.g., defined as a factor of X +/- 10% + Z(Y +/- 10%)) that are faster (e.g., a factor of Z(Y +/- 10%) faster) than previously attainable with, for example, a forming vessel 140 and no supply vessels, where draw speed can be defined as a factor of X +/- 10%.
- faster draw speeds can increase the rate of production (e.g., output) of the glass forming apparatus 101, thus at least one of improving production efficiency or reducing manufacturing costs.
- the flow rate of molten material 121 from inlet conduit 141 to trough 201 can be controlled (e.g., adjusted) to be X +/- 5%, X +/- 15%, X +/- 20%, X +/- 25%, etc., including all ranges and subranges therebetween, and the flow rates of molten material 321a, 321b, 321c, 321d from inlet conduits 341a, 341b, 341c, 341d to troughs 401a, 401b, 401c, 401d can be controlled (e.g., adjusted) to be Y +/- 5%, Y +/- 15%, Y +/- 20%, Y +/- 25%, etc., including all ranges and subranges therebetween, faster draw speeds defined over a wider range can be obtained.
- features in accordance with embodiments of the disclosure can, therefore, respectively, enable draw speeds (e.g., defined as a factor of X +/- 5% + Z(Y +/- 5%), X +/- 15% + Z(Y +/- 15%), X +/- 20% + Z(Y +/- 20%), X +/- 25% + Z(Y +/- 25%), etc., including all ranges and subranges therebetween) that are faster (e.g., a factor of Z(Y +/- 5%) faster, Z(Y +/- 15%) faster, Z(Y +/- 20%) faster, Z(Y +/- 25%) faster, etc., including all ranges and subranges therebetween) than previously attainable with, for example, a forming vessel 140 and no supply vessels, where draw speed can be defined as a factor of X +/- 10%.
- each supply vessel 309a, 309b, 309c, 309d of the plurality of supply vessels 300 can be operated independently such that the flow rates of molten material 321a, 321b, 321c, 321d from inlet conduits 341a, 341b, 341c, 341d to troughs 401a, 401b, 401c, 401d can be respectively controlled (e.g., adjusted) to be Ya +/- 10%, Yb +/- 10%, Yc +/- 10%, Yc +/- 10%, etc., including all ranges and subranges therebetween, for each respective supply vessel 309a, 309b, 309c, 309d of the plurality of supply vessels 300.
- the exemplary percentages and ranges of flow rates provide a relative comparison for explanatory purposes and, unless otherwise noted, should not be interpreted as a limiting numerical value.
- providing the plurality of supply vessels 300 and the forming vessel 140 can enable uninterrupted (i.e., continuous) operation of the glass forming apparatus 101 for long durations of time (e.g., on the order of 5, 10, 15, 20, 25, or more years).
- the usable or operational life of one or more components of the glass manufacturing apparatus 100 providing molten material 121 to the inlet conduit 141 of the forming vessel 140, 309b, 309c, 309d and molten material 321a, 321b, 321c, 321d to the inlet conduits 341a, 341b, 341c, 341d of each supply vessel 309a, 309b, 309c, 309d of the plurality of supply vessels 300 can be shorter than the usable or operational life of, for example, the supply vessels 309a, 309b, 309c, 309d and/or the forming vessel 140.
- one or more components of the glass manufacturing apparatus 100 providing a source or sources of molten material may wear or break and require repair or replacement prior to the forming vessel 140 and/or the plurality of supply vessels 300 reaching their respective ends of life (e.g., ends of usable operability). Accordingly, in some embodiments, by providing the plurality of supply vessels 300 and the forming vessel 140, the production of the glass ribbon 103 can continue uninterrupted, despite one or more components of the glass manufacturing apparatus 100 wearing or breaking and requiring repair or replacement.
- each supply vessel 309a, 309b, 309c, 309d can include a separate and independently adjustable source of molten material 321a, 321b, 321c, 321d, in some embodiments, the flow of molten material coming from one or more components that require repair or replacement can be stopped, and flow of molten material coming from one or more components that do not require repair or replacement can continue and/or be started.
- the one or more components that require repair or replacement can be repaired or replaced while the glass forming apparatus 101 continues to produce the glass ribbon 103 based, at least in part, on the supply of molten material coming from the one or more components that do not require repair or replacement.
- the present disclosure provides features that enable continuous, uninterrupted production of the glass ribbon 103 in accordance with embodiments of the disclosure.
- Embodiments and the functional operations described herein can be implemented in digital electronic circuitry, or in computer software, firmware, or hardware, including the structures disclosed in this specification and their structural equivalents, or in combinations of one or more of them.
- Embodiments described herein can be implemented as one or more computer program products, i.e., one or more modules of computer program instructions encoded on a tangible program carrier for execution by, or to control the operation of, data processing apparatus.
- the tangible program carrier can be a computer readable medium.
- the computer readable medium can be a machine-readable storage device, a machine-readable storage substrate, a memory device, or a combination of one or more of them.
- processor or“controller” can encompass all apparatus, devices, and machines for processing data, including by way of example a programmable processor, a computer, or multiple processors or computers.
- the processor can include, in addition to hardware, code that creates an execution environment for the computer program in question, e.g., code that constitutes processor firmware, a protocol stack, a database management system, an operating system, or a combination of one or more of them.
- a computer program (also known as a program, software, software application, script, or code) can be written in any form of programming language, including compiled or interpreted languages, or declarative or procedural languages, and it can be deployed in any form, including as a standalone program or as a module, component, subroutine, or other unit suitable for use in a computing environment.
- a computer program does not necessarily correspond to a file in a file system.
- a program can be stored in a portion of a file that holds other programs or data (e.g., one or more scripts stored in a markup language document), in a single file dedicated to the program in question, or in multiple coordinated files (e.g., files that store one or more modules, sub programs, or portions of code).
- a computer program can be deployed to be executed on one computer or on multiple computers that are located at one site or distributed across multiple sites and interconnected by a communication network.
- the processes described herein can be performed by one or more programmable processors executing one or more computer programs to perform functions by operating on input data and generating output.
- the processes and logic flows can also be performed by, and apparatus can also be implemented as, special purpose logic circuitry, e.g., an FPGA (field programmable gate array) or an ASIC (application specific integrated circuit) to name a few.
- FPGA field programmable gate array
- ASIC application specific integrated circuit
- processors suitable for the execution of a computer program include, by way of example, both general and special purpose microprocessors, and any one or more processors of any kind of digital computer.
- a processor will receive instructions and data from a read only memory or a random-access memory or both.
- the essential elements of a computer are a processor for performing instructions and one or more data memory devices for storing instructions and data.
- a computer will also include, or be operatively coupled to receive data from or transfer data to, or both, one or more mass storage devices for storing data, e.g., magnetic, magneto optical disks, or optical disks.
- mass storage devices for storing data, e.g., magnetic, magneto optical disks, or optical disks.
- a computer need not have such devices.
- a computer can be embedded in another device, e.g., a mobile telephone, a personal digital assistant (PDA), to name just a few.
- PDA personal digital assistant
- Computer readable media suitable for storing computer program instructions and data include all forms data memory including nonvolatile memory, media and memory devices, including by way of example semiconductor memory devices, e.g., EPROM, EEPROM, and flash memory devices; magnetic disks, e.g., internal hard disks or removable disks; magneto optical disks; and CD ROM and DVD- ROM disks.
- semiconductor memory devices e.g., EPROM, EEPROM, and flash memory devices
- magnetic disks e.g., internal hard disks or removable disks
- magneto optical disks e.g., CD ROM and DVD- ROM disks.
- the processor and the memory can be supplemented by, or incorporated in, special purpose logic circuitry.
- a computer having a display device, e.g., a CRT (cathode ray tube) or LCD (liquid crystal display) monitor, and the like for displaying information to the user and a keyboard and a pointing device, e.g., a mouse or a trackball, or a touch screen by which the user can provide input to the computer.
- a display device e.g., a CRT (cathode ray tube) or LCD (liquid crystal display) monitor
- a keyboard and a pointing device e.g., a mouse or a trackball, or a touch screen by which the user can provide input to the computer.
- Other kinds of devices can be used to provide for interaction with a user as well; for example, input from the user can be received in any form, including acoustic, speech, or tactile input.
- Embodiments described herein can be implemented in a computing system that includes a back end component, e.g., as a data server, or that includes a middleware component, e.g., an application server, or that includes a front end component, e.g., a client computer having a graphical user interface or a Web browser through which a user can interact with implementations of the subject matter described herein, or any combination of one or more such back end, middleware, or front end components.
- the components of the system can be interconnected by any form or medium of digital data communication, e.g., a communication network. Examples of communication networks include a local area network (“LAN”) and a wide area network (“WAN”), e.g., the Internet.
- LAN local area network
- WAN wide area network
- the computing system can include clients and servers.
- a client and server are generally remote from each other and typically interact through a communication network.
- the relationship of client and server arises by virtue of computer programs running on the respective computers and having a client-server relationship to each other.
- Ranges can be expressed herein as from“about” one particular value, and/or to “about” another particular value. When such a range is expressed, embodiments include from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by use of the antecedent “about,” it will be understood that the particular value forms another embodiment. It will be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint, and independently of the other endpoint. [0074] The terms“substantial,”“substantially,” and variations thereof as used herein are intended to note that a described feature is equal or approximately equal to a value or description.
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Abstract
La présente invention concerne un procédé de formation d'un ruban en verre comprenant le débordement d'un matériau fondu depuis un premier creux d'un premier récipient d'alimentation et ensuite l'écoulement des premiers courants du matériau fondu le long de premières surfaces externes de premiers déversoirs correspondants. Le procédé comprend le débordement du matériau fondu depuis un second creux d'un récipient de formation et l'écoulement des seconds courants du matériau fondu le long de secondes surfaces externes de seconds déversoirs correspondants. Le procédé comprend la fusion des premiers courants et des seconds courants et la fusion des premiers courants et des seconds courants en troisièmes courants. Le procédé comprend la convergence des troisièmes courants à une racine du récipient de formation, la fusion des troisièmes courants en un ruban du matériau fondu au niveau de la racine, et l'étirage du ruban en un ruban en verre. L'invention concerne également l'appareil de formation du ruban en verre.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201862736083P | 2018-09-25 | 2018-09-25 | |
| US62/736,083 | 2018-09-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2020068463A1 true WO2020068463A1 (fr) | 2020-04-02 |
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ID=69952483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2019/051217 Ceased WO2020068463A1 (fr) | 2018-09-25 | 2019-09-16 | Appareil et procédés de fabrication de verre |
Country Status (2)
| Country | Link |
|---|---|
| TW (1) | TW202019838A (fr) |
| WO (1) | WO2020068463A1 (fr) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009093550A1 (fr) * | 2008-01-21 | 2009-07-30 | Nippon Electric Glass Co., Ltd. | Procédé de fabrication de substrats de verre et substrats de verre |
| US20100281920A1 (en) * | 2007-12-25 | 2010-11-11 | Noritomo Nishiura | Process and apparatus for producing glass sheet |
| US20120047952A1 (en) * | 2010-08-30 | 2012-03-01 | Addiego William P | Creep-resistant zircon article and method of manufacturing same |
| US20150158753A1 (en) * | 2010-10-29 | 2015-06-11 | Corning Incorporated | Overflow down-draw with improved glass melt velocity and thickness distribution |
| US20150197442A1 (en) * | 2012-08-30 | 2015-07-16 | Corning Incorporated | Apparatus and methods of making a glass tube by drawing molten glass |
-
2019
- 2019-09-16 WO PCT/US2019/051217 patent/WO2020068463A1/fr not_active Ceased
- 2019-09-18 TW TW108133497A patent/TW202019838A/zh unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100281920A1 (en) * | 2007-12-25 | 2010-11-11 | Noritomo Nishiura | Process and apparatus for producing glass sheet |
| WO2009093550A1 (fr) * | 2008-01-21 | 2009-07-30 | Nippon Electric Glass Co., Ltd. | Procédé de fabrication de substrats de verre et substrats de verre |
| US20120047952A1 (en) * | 2010-08-30 | 2012-03-01 | Addiego William P | Creep-resistant zircon article and method of manufacturing same |
| US20150158753A1 (en) * | 2010-10-29 | 2015-06-11 | Corning Incorporated | Overflow down-draw with improved glass melt velocity and thickness distribution |
| US20150197442A1 (en) * | 2012-08-30 | 2015-07-16 | Corning Incorporated | Apparatus and methods of making a glass tube by drawing molten glass |
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| Publication number | Publication date |
|---|---|
| TW202019838A (zh) | 2020-06-01 |
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