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WO2019239457A1 - Power generation unit with solid oxide fuel cell - Google Patents

Power generation unit with solid oxide fuel cell Download PDF

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Publication number
WO2019239457A1
WO2019239457A1 PCT/JP2018/022229 JP2018022229W WO2019239457A1 WO 2019239457 A1 WO2019239457 A1 WO 2019239457A1 JP 2018022229 W JP2018022229 W JP 2018022229W WO 2019239457 A1 WO2019239457 A1 WO 2019239457A1
Authority
WO
WIPO (PCT)
Prior art keywords
power generation
generation unit
fuel cell
fixing
solid oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2018/022229
Other languages
French (fr)
Japanese (ja)
Inventor
昌弘 臼田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Motor Co Ltd
Original Assignee
Nissan Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Motor Co Ltd filed Critical Nissan Motor Co Ltd
Priority to PCT/JP2018/022229 priority Critical patent/WO2019239457A1/en
Publication of WO2019239457A1 publication Critical patent/WO2019239457A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the present invention relates to a power generation unit held on a fixed plate connected to a vehicle body.
  • a mounting structure for mounting a power generation unit described in Patent Document 1 on a vehicle includes a fixed support portion in which one end plate in the stacking direction of the fuel cells is held by the vehicle via a rubber mount, and the other end plate Has a movable support portion held by the vehicle so as to be movable in the stacking direction via the rubber mount.
  • An object of the present invention is to provide a power generation unit capable of increasing the natural frequency and absorbing displacement due to thermal expansion.
  • the present invention for achieving the above object is a power generation unit held on a fixed plate connected to a vehicle body, and includes a solid oxide fuel cell, a gas processing unit, and a connecting portion.
  • the gas processing unit comprises: a fuel reformer that reforms fuel supplied to the solid oxide fuel cell; a combustor that burns unburned gas in the anode off-gas discharged from the solid oxide fuel cell; It includes three devices: a heat exchanger that exchanges heat between the exhaust gas discharged from the combustor and the oxidant gas supplied to the solid oxide fuel cell.
  • the connecting portion integrally connects a manifold formed on one end plate side of the solid oxide fuel cell and each manifold of the device in the gas processing unit.
  • the power generation unit includes a first fixing portion that fixes the other end plate side of the solid oxide fuel cell to the fixing plate in a rigid state.
  • the power generation unit includes a second fixing portion that fixes at least one of the at least one device and the connecting portion in the gas processing unit to the fixing plate in a rigid state.
  • the power generation unit includes a displacement absorbing unit that absorbs in one direction a displacement associated with thermal expansion of the device in the gas processing unit.
  • FIG. 7 is an exploded perspective view of the metal support cell assembly shown in FIG. 6.
  • FIG. 8 is a partial cross-sectional view of the metal support cell assembly taken along line 8-8 in FIG. It is sectional drawing which shows the connection structure of a connection part and a solid oxide fuel cell. It is sectional drawing which shows the connection structure of a connection part and a gas processing unit. It is a front view which shows the 1st fixing
  • FIG. 1 is a perspective view showing a state where a fixed plate 30 holding a power generation unit 10 is connected to a vehicle body, and FIG. 2 shows a gas processing unit 50 to which a connecting portion is connected and a solid oxide fuel cell 40.
  • FIGS. 3 and 4 are a top view and a front view showing the power generation unit 10 in which the solid oxide fuel cell 40 and the gas processing unit 50 of the first embodiment are fastened.
  • the power generation unit 10 is generally a power generation unit 10 held on a fixed plate 30 connected to a vehicle body, and is a solid oxide fuel cell ( SOFC) 40 (hereinafter also referred to as “SOFC 40”), a gas processing unit (GPU) 50 (hereinafter also referred to as “GPU 50”), and a connecting block 60 (corresponding to a connecting portion) that connects the SOFC 40 and GPU 50 in a rigid state.
  • SOFC 40 solid oxide fuel cell
  • GPU 50 gas processing unit
  • the GPU 50 includes three devices: a fuel reformer 51, a catalytic combustor 53 corresponding to a combustor, and a heat exchanger 52.
  • connection block 60 integrally connects the manifolds 41 a, 41 b, 41 c formed on the one end plate 108 side of the SOFC 40 and the respective manifolds 54 a, 54 b, 54 c of the devices 51, 52, 53 in the GPU 50.
  • the power generation unit 10 includes a first fixing portion 70 that fixes the other end plate 109 side of the SOFC 40 to the fixing plate 30 in a rigid state.
  • the power generation unit 10 includes a second fixing portion 80 that fixes at least one of the at least one device 51 (52, 53) and the connection block 60 in the GPU 50 to the fixing plate 30 in a rigid state.
  • the power generation unit 10 further includes a displacement absorbing unit 90 that absorbs the displacement accompanying the thermal expansion of the devices 51, 52, and 53 in the GPU 50 in one direction.
  • the second fixing unit 80 fixes one device (the fuel reformer 51) in the GPU 50 to the fixed plate 30 in a rigid state.
  • the displacement absorption part 90 absorbs the displacement accompanying the thermal expansion of each of the two devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50 in one direction. Details will be described below.
  • the fixing plate 30 is fixed in a rigid state by welding or bolt fastening to, for example, the side member 20 of the vehicle body.
  • the fixing plate 30 is fixed to the side member 20 at four points. The number of points to be fixed can be appropriately changed in consideration of the rigidity (natural frequency) required for the power generation unit 10.
  • the GPU 50 of the power generation unit 10 includes three devices: a fuel reformer 51, a catalytic combustor 53 corresponding to a combustor, and a heat exchanger 52.
  • the fuel reformer 51 reforms the fuel F supplied to the SOFC 40.
  • the catalytic combustor 53 burns unburned gas in the anode off gas AOG discharged from the SOFC 40.
  • the heat exchanger 52 exchanges heat between the exhaust gas EG discharged from the catalyst combustor 53 and the oxidant gas CG supplied to the SOFC 40.
  • the fuel reformer 51 is connected to a fuel F supply pipe 51a.
  • the heat exchanger 52 is connected to an oxidant gas CG supply pipe 52a and an exhaust pipe 52b that discharges the exhaust gas EG after heat exchange.
  • the catalyst combustor 53 and the heat exchanger 52 are connected by an introduction pipe 52 c that introduces the exhaust gas EG discharged from the catalyst combustor 53 into the heat exchanger 52.
  • the SOFC 40 has a manifold 41a for introducing a reformed fuel gas (anode gas AG) on the lower end plate 108 (corresponding to one end plate 108) side.
  • a manifold 41b for introducing a heated oxidant gas CG (cathode gas CG) is formed on the lower end plate 108 side.
  • a manifold 41c for leading the anode off gas AOG is formed on the lower end plate 108 side.
  • a manifold 54a for leading out the reformed anode gas AG is formed in the fuel reformer 51 of the GPU 50.
  • the heat exchanger 52 is formed with a manifold 54b for leading the heated cathode gas CG.
  • the catalyst combustor 53 is formed with a manifold 54c for introducing the anode off gas AOG.
  • the connecting block 60 includes first to third passage portions 61 that connect the manifolds 41a, 41b, and 41c formed on the lower end plate 108 side of the SOFC 40 and the manifolds 54a, 54b, and 54c of the equipment in the GPU 50, 62 and 63 are formed in a block shape.
  • the first passage 61 communicates the manifold 41 a of the SOFC 40 and the manifold 54 a of the fuel reformer 51.
  • the second passage 62 communicates the manifold 41b of the SOFC 40 and the manifold 54b of the heat exchanger 52.
  • the third passage portion 63 communicates the manifold 41 c of the SOFC 40 and the manifold 54 c of the catalytic combustor 53. As shown in FIG.
  • the anode gas AG flows through the first passage portion 61 as indicated by an arrow.
  • the cathode gas CG flows through the second passage portion 62 as indicated by an arrow.
  • the anode off gas AOG flows through the third passage portion 63 as indicated by an arrow.
  • the end face of the connecting block 60 on the SOFC 40 side is fixed to the SOFC 40 in a rigid state by welding or bolt fastening.
  • the end surface of the connection block 60 on the GPU 50 side is fixed to a rigid state by welding or bolt fastening to each device of the GPU 50.
  • connection block 60 integrally connects the manifolds 41a, 41b, 41c formed on the lower end plate 108 side of the SOFC 40 and the respective manifolds 54a, 54b, 54c of the devices 51, 52, 53 in the GPU 50. To do.
  • the SOFC 40 and the GPU 50 are connected in a rigid state.
  • FIG. 5 is an exploded perspective view showing the SOFC 40.
  • 6 is an exploded perspective view of the cell unit 100 shown in FIG.
  • FIG. 7 is an exploded perspective view of the metal support cell assembly 110 shown in FIG.
  • FIG. 8 is a partial cross-sectional view of the metal support cell assembly 110 taken along line 8-8 in FIG.
  • the XYZ orthogonal coordinate system is shown in FIGS.
  • the X axis and the Y axis indicate the horizontal direction, and the Z axis indicates an axis parallel to the vertical direction.
  • the SOFC 40 Solid Oxide Fuel Cell shown in the figure is a fuel cell using an oxide ion conductor such as stabilized zirconia as an electrolyte.
  • the SOFC 40 includes a fuel cell stack 40S configured by stacking a plurality of cell units 100 in the vertical direction, an upper current collector plate 106 stacked above the fuel cell stack 40S, and a fuel cell. And a lower current collecting plate 107 stacked below the stack 40S.
  • the upper current collecting plate 106, the fuel cell stack 40S, and the lower current collecting plate 107 are sandwiched between the upper end plate 109 and the lower end plate 108.
  • Each of the upper end plate 109 and the lower end plate 108 is fastened to the cover 105 with bolts.
  • the lower end plate 108 corresponds to one end plate 108
  • the upper end plate 109 corresponds to the other end plate 109.
  • the vertical direction of the fuel cell stack 40 ⁇ / b> S indicated by the Z axis in the drawing is also referred to as “stacking direction”.
  • main components of the SOFC 40 will be described.
  • the cell unit 100 includes a separator 120 that partitions and forms a flow path portion 121 for gas to flow between the metal support cell assembly 110 and the electrolyte electrode assembly 111, a current collecting auxiliary layer 140 are sequentially stacked.
  • a contact material that conducts and contacts the metal support cell assembly 110 and the current collecting auxiliary layer 140 may be disposed, or the current collecting auxiliary layer 140 may be omitted.
  • the cell unit 100 has a manifold part (not shown) for circulating and supplying the anode gas AG, and a plurality of seal parts 160 (FIG. 5) for sealing the periphery of the manifold part and restricting the gas flow. , (See FIG. 6).
  • the illustrated fuel cell stack 40S is configured as an open cathode structure in which cathode gas freely flows outside the cell unit 100 (a portion surrounded by a broken line in FIGS. 6 and 7).
  • the metal support cell assembly 110 includes a plurality of (two in the illustrated example) metal support cells (Metal-Supported Cells: MSC) 110M arranged in the longitudinal direction Y, and a metal. And a cell frame 113 that holds the outer periphery of the support cell 110M.
  • MSC Metal-Supported Cells
  • the metal support cell 110M supports the electrolyte electrode assembly 111 in which the electrolyte layer 111E is sandwiched between a pair of electrodes 111A and 111C from both sides, and the electrolyte electrode assembly 111 from one side in the vertical direction.
  • a metal support portion 112 made of metal.
  • the metal support cell 110M is excellent in mechanical strength, quick startability, and the like as compared with the electrolyte support cell and the electrode support cell.
  • Electrode electrode assembly 111 As shown in FIGS. 7 and 8, the electrolyte electrode assembly 111 is configured by sandwiching an electrolyte layer 111E from both sides by an anode layer 111A and a cathode layer 111C which are a pair of electrodes.
  • the electrolyte layer 111E transmits oxide ions from the cathode layer 111C toward the anode layer 111A.
  • the electrolyte layer 111E does not allow gas and electrons to pass while allowing oxide ions to pass through.
  • Examples of the material for forming the electrolyte layer 111E include solid oxide ceramics such as stabilized zirconia doped with yttria, neodymium oxide, samarium, gadolinium, and scandium.
  • the anode layer 111A is a fuel electrode, and reacts an anode gas AG (for example, hydrogen) with oxide ions to generate an oxide of the anode gas AG and take out electrons.
  • the anode layer 111A is resistant to a reducing atmosphere, transmits the anode gas AG, has high electrical (electron and ion) conductivity, and has a catalytic action that causes the anode gas AG to react with oxide ions.
  • Examples of the material for forming the anode layer 111A include a material in which a metal such as nickel and an oxide ion conductor such as yttria-stabilized zirconia are mixed.
  • the cathode layer 111C is an oxidizer electrode, and reacts cathode gas (for example, oxygen contained in air) with electrons to convert oxygen molecules into oxide ions.
  • the cathode layer 111C has resistance to an oxidizing atmosphere, allows the cathode gas to permeate, has high electrical (electron and ion) conductivity, and has a catalytic action to convert oxygen molecules into oxide ions.
  • Examples of the material for forming the cathode layer 111C include oxides made of lanthanum, strontium, manganese, cobalt, and the like.
  • Metal support part 112 As shown in FIG. 7 and FIG. 8, the metal support part 112 supports the electrolyte electrode assembly 111 from the anode layer 111A side. By supporting the electrolyte electrode assembly 111 with the metal support part 112, even when the surface pressure distribution is slightly biased in the electrolyte electrode assembly 111, the damage to the electrolyte electrode assembly 111 due to bending can be suppressed.
  • the metal support part 112 is a porous metal having gas permeability and electronic conductivity. Examples of the material for forming the metal support 112 include a corrosion resistant alloy, corrosion resistant steel, and stainless steel containing nickel and chromium.
  • the cell frame 113 holds the metal support cell 110M from the periphery.
  • the cell frame 113 has a plurality (two in the illustrated example) of openings 113 ⁇ / b> H arranged side by side along the longitudinal direction Y.
  • a metal support cell 110M is disposed in the opening 113H of the cell frame 113.
  • the outer periphery of the metal support cell 110M is joined to the inner edge of the opening 113H of the cell frame 113.
  • the cell frame 113 has anode gas inlets 113a, 113b, 113c through which the anode gas AG flows and anode gas outlets 113d, 113e.
  • Examples of the material for forming the cell frame 113 include a metal whose surface is subjected to an insulation treatment.
  • the separator 120 is disposed between the metal support cells 110M adjacent in the stacking direction Z.
  • the separator 120 has a flow path portion 121 in a region facing the electrolyte electrode assembly 111 of the metal support cell 110M.
  • the flow path part 121 has an uneven shape that partitions and forms a gas flow path between the flow path part 121 and the electrolyte electrode assembly 111.
  • the anode gas AG flows through the flow path part 121 facing the metal support part 112, and the cathode gas flows through the flow path part 121 facing the current collection auxiliary layer 140.
  • the flow path portion 121 of the separator 120 is formed in a substantially linear shape so that the concavo-convex shape extends in the short-side direction X. Thereby, the flow direction of the gas flowing along the flow path part 121 is the short direction X.
  • the separator 120 has anode gas inlets 120a, 120b, 120c through which the anode gas AG flows and anode gas outlets 120d, 120e. Examples of the material for forming the separator 120 include metal. Insulation treatment is applied to the region other than the flow path portion 121 of the separator 120.
  • the current collection auxiliary layer 140 is disposed between the metal support cell 110M and the separator 120, and forms an electric space between the metal support cell 110M and the separator 120 with a uniform surface pressure while forming a space through which the cathode gas passes.
  • Examples of the current collecting auxiliary layer 140 include a wire mesh expanded metal. Also, if this characteristic or function can be provided by other elements, it can be omitted.
  • the seal part 160 is formed from a material having heat resistance and sealability.
  • a material having heat resistance and sealability for example, thermiculite (registered trademark) whose main raw material is vermiculite (meteorite) can be mentioned.
  • FIG. 9 is a cross-sectional view showing a connection structure between the connection block 60 and the SOFC 40.
  • the connecting block 60 is overlapped with the lower end plate 108, and is welded and integrated from the inside of the first to third passage portions 61, 62, 63.
  • the SOFC 40 is formed by integrating the connection block 60 with the lower end plate 108 and then laminating the cell unit 100 on the lower end plate 108 with the connection block 60 integrated.
  • FIG. 10 is a cross-sectional view showing a connection structure between the connection block 60 and the GPU 50.
  • the GPU 50 has a flange member 55 in which manifolds 54a, 54b, 54c of the devices are formed.
  • the flange member 55 is integrally connected to each of the devices 51, 52, and 53 by welding.
  • the flange member 55 and the connection block 60 have a plurality of convex portions 55a and 60a for bolting each other.
  • the flange member 55 is bolted to the connection block 60 integrated with the SOFC 40 and the plurality of convex portions 55a and 60a.
  • a gasket (not shown) for sealing the gas flowing through the first to third passage portions 61, 62, 63 is interposed.
  • (First fixing portion 70) 11A and 11B are a front view and a side view showing the first fixing portion 70 that fixes the other end plate 109 (upper end plate 109) side of the SOFC 40 to the fixing plate 30 in a rigid state.
  • the power generation unit 10 includes a first fixing portion 70 that fixes the upper end plate 109 (corresponding to the other end plate 109) of the SOFC 40 to the fixing plate 30 in a rigid state.
  • the first fixing portion 70 includes a first bracket 71 that is fixed to the fixing plate 30 at a plurality of points, and a second bracket 72 that is fixed to the upper end plate 109 of the SOFC 40 at a plurality of points.
  • the first bracket 71 and the second bracket 72 are integrally formed and have an L shape as shown in FIG. 11A.
  • the first bracket 71 is bolted to the fixing plate 30 at two points (FIG. 11B).
  • the first bracket 71 is fixed via a heat insulating material 31 that blocks heat transfer from the SOFC 40 to the fixed plate 30.
  • the second bracket 72 is bolted to the upper end plate 109 at four points (FIG. 11B).
  • the number of points to be fixed can be one point. However, by using a plurality of fixing points, it is possible to resist the force in the rotational direction around the fixing points. Further, the number of points to be fixed can be appropriately changed in consideration of the rigidity (natural frequency) required for the power generation unit 10.
  • the first bracket 71 can be fixed to the fixed plate 30 by welding instead of bolt fastening.
  • (Second fixing portion 80) 12A and 12B are a front view and a side view showing the second fixing portion 80 that fixes the device in the GPU 50 to the fixing plate 30 in a rigid state.
  • the power generation unit 10 has a second fixing portion 80 that fixes one device in the GPU 50 to the fixing plate 30 in a rigid state.
  • the fuel reformer 51 is fixed to the fixed plate 30 in a rigid state by the second fixing portion 80.
  • the second fixing portion 80 includes a first plate 81 that is fixed to the fixing plate 30 at a plurality of points, a second plate 82 that is fixed to the lower surface side of the fuel reformer 51, and a first plate 81 A support 83 for connecting the second plate 82 is provided.
  • pillar 83 are integrally formed.
  • the first plate 81 is bolted to the fixed plate 30 at four points (FIG. 3).
  • the first plate 81 is fixed via a heat insulating material 31 that blocks heat transfer from the fuel reformer 51 to the fixed plate 30.
  • the second plate 82 is fixed to the lower surface of the fuel reformer 51 by welding. Further, the multipoint number for fixing the first plate 81 can be appropriately changed in consideration of the rigidity (natural frequency) required for the power generation unit 10.
  • the first plate 81 can be fixed to the fixed plate 30 by welding instead of bolt fastening.
  • the second plate 82 can be fixed to the lower surface of the fuel reformer 51 by bolt fastening instead of welding.
  • FIGS. 13A and 13B are a front view and a side view showing a displacement absorbing portion 90 that absorbs displacement due to thermal expansion in the devices 52 and 53 of the GPU 50 in one direction.
  • the power generation unit 10 has a displacement absorbing portion 90 that absorbs displacement due to thermal expansion in the two devices 52 and 53 of the GPU 50 in one direction.
  • the displacement accompanying thermal expansion is absorbed in one direction by the displacement absorbing unit 90.
  • the displacement accompanying the thermal expansion is absorbed in one direction by the displacement absorbing unit 90.
  • the displacement absorbing unit 90 includes a slider 91 that guides displacement along one direction of the devices 52 and 53.
  • the slider 91 is provided on a lower surface side of a pair of support legs 92 fixed to the fixed plate 30, a guide shaft 93 connected to the pair of support legs 92, and devices (catalyst combustor 53 and heat exchanger 52). And a guide bracket 94 fixed to the opposite side.
  • the pair of support legs 92 are separated along one direction in which thermal expansion is absorbed.
  • the guide shaft 93 extends along one direction that absorbs thermal expansion.
  • the guide shaft 93 is connected to the pair of support legs 92 through the guide bracket 94.
  • Each of the support legs 92 is bolted to the fixing plate 30 at two points (FIG. 3).
  • Each of the support legs 92 is fixed via a heat insulating material 31 that blocks heat transfer from the devices (catalyst combustor 53 and heat exchanger 52) to the fixed plate 30.
  • the guide bracket 94 is fixed to the lower surface of the equipment (catalyst combustor 53 and heat exchanger 52) by welding.
  • Each of the support legs 92 can be fixed to the fixing plate 30 by welding instead of bolt fastening.
  • the guide bracket 94 can be fixed to the lower surface of the device (catalyst combustor 53 and heat exchanger 52) by bolt fastening instead of welding.
  • the displacement absorber 90 absorbs the displacement accompanying the thermal expansion in a specific direction.
  • one direction is a horizontal direction and a direction in which the SOFC 40 and the GPU 50 face each other.
  • One direction is the left-right direction in the vehicle body.
  • one direction can be set to the front-rear direction in the vehicle body.
  • the forming material of the connection block 60, the first fixing portion 70, and the second fixing portion 80 is the same as the forming material of the fixing plate 30.
  • the forming material is, for example, a stainless material.
  • the material for forming the lower end plate 108 and the upper end plate 109 of the SOFC 40 may be the same as the material for forming the fixed plate 30.
  • the forming material of the fixing plate 30 and the forming material of each mount are the same material, the stress due to thermal expansion can be reduced. For this reason, the specification of a displacement absorption function can be simplified.
  • the SOFC 40 and the GPU 50 are connected in a rigid state via the connection block 60.
  • the SOFC 40 is fixed to the fixed plate 30 in a rigid state by the first fixing portion 70 on the upper end plate 109 side.
  • the fuel reformer 51 of the GPU 50 is fixed to the fixed plate 30 in a rigid state by the second fixing unit 80.
  • the devices 51, 52, and 53 of the SOFC 40 and the GPU 50 are at a high temperature.
  • the displacement accompanying the thermal expansion is guided and absorbed in one direction by the displacement absorbing portion 90 having the slider 91.
  • the power generation unit 10 Since the power generation unit 10 is held on the fixed plate 30 connected to the vehicle body, vibration associated with traveling is input.
  • the SOFC 40, the connection block 60, and the GPU 50 that are connected in the rigid state are fixed to the fixed plate 30 in the rigid state by the first fixing unit 70 and the second fixing unit 80. For this reason, the natural frequency of the power generation unit 10 increases, and the resonance frequency increases. As a result, it is possible to suppress the natural frequency of the power generation unit 10 from deviating (increasing) from the frequency range (less than 50 Hz) where the road load input is large, and the vibration caused by traveling adversely affecting the operation of the power generation unit 10. .
  • the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state can be improved.
  • the displacement absorbing portion 90 having the slider 91 guides and absorbs the displacement accompanying the thermal expansion of the devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50 in one direction. For this reason, even if each apparatus 51,52,53 of GPU50 is thermally expanded, the stress by thermal expansion can be reduced.
  • connection block 60 integrates manifolds 41a, 41b, 41c of the SOFC 40 and manifolds 54a, 54b, 54c of the devices 51, 52, 53 of the GPU 50. Thereby, the dimension between SOFC40 and GPU50 can be made small, and the whole power generation unit 10 can be reduced in size.
  • FIG. 14 is a diagram schematically showing an action when the SOFC 40 thermally expands during operation of the power generation unit 10.
  • the power generation unit 10 does not have a structure that absorbs the thermal expansion of the SOFC 40.
  • the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are provided with at least three fixed points.
  • the primary natural frequency can ensure sufficient rigidity.
  • the surface pressure sensitivity between the laminated layers particularly affects the primary mode.
  • the entire power generation unit 10 can be reduced in size.
  • the power generation unit 10 is the power generation unit 10 held on the fixed plate 30 connected to the vehicle body, and includes the SOFC 40 and the GPU 50.
  • the power generation unit 10 includes a connection block 60 that integrally connects the manifolds 41a, 41b, and 41c formed on the lower end plate 108 side of the SOFC 40 and the manifolds 54a, 54b, and 54c of the equipment in the GPU 50.
  • the power generation unit 10 includes a first fixing portion 70 that fixes the upper end plate 109 side of the SOFC 40 to the fixing plate 30 in a rigid state.
  • the power generation unit 10 includes a second fixing unit 80 that fixes the fuel reformer 51 in the GPU 50 to the fixed plate 30 in a rigid state.
  • the power generation unit 10 includes a displacement absorbing unit 90 that absorbs in one direction a displacement (elongation) associated with thermal expansion of the devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50.
  • the SOFC 40, the connection block 60, and the GPU 50 connected in a rigid state are fixed in a rigid state to the fixed plate 30 by the first fixing unit 70 and the second fixing unit 80.
  • the natural frequency of the power generation unit 10 increases, and the resonance frequency increases.
  • each device 51, 52, 53 of the GPU 50 is thermally expanded.
  • the stress due to thermal expansion can be reduced. Therefore, according to the first embodiment, it is possible to provide the power generation unit 10 that can increase the natural frequency and absorb the displacement due to thermal expansion.
  • the manifolds 41a, 41b, 41c of the SOFC 40 and the manifolds 54a, 54b, 54c of each device of the GPU 50 are integrated by the connecting block 60, the dimension between the SOFC 40 and the GPU 50 can be reduced, and the entire power generation unit 10 can be reduced. Can be miniaturized. In addition, the number of mounts can be minimized, and from this point, the entire power generation unit 10 can be downsized.
  • the connection block 60 includes first to third passage portions 61 that connect the manifolds 41a, 41b, and 41c formed on one end plate 108 side of the SOFC 40 and the manifolds 54a, 54b, and 54c of the equipment in the GPU 50.
  • , 62, 63 are formed in a block shape, and are welded and joined to one end plate 108 from the inside of the first to third passage portions 61, 62, 63.
  • the SOFC 40 is formed by stacking the cell unit 100 on one end plate 108 in which the connection block 60 is integrated.
  • This configuration allows the GPU 50 to be easily integrated into the SOFC 40.
  • the first fixing part 70 has a first bracket 71 fixed to the fixing plate 30 at a plurality of points.
  • This configuration makes it possible to increase the natural frequency of the SOFC 40.
  • the first fixing unit 70 has second brackets 72 that are fixed to the lower end plate 108 of the SOFC 40 at a plurality of points.
  • This configuration makes it possible to increase the natural frequency of the SOFC 40.
  • the displacement absorbing unit 90 has a slider 91 that guides displacement along one direction of the devices (catalytic combustor 53 and heat exchanger 52) in the GPU 50.
  • One direction is the horizontal direction and the direction in which the SOFC 40 and the GPU 50 face each other.
  • connection block 60 The forming material of the connection block 60, the first fixing portion 70, and the second fixing portion 80 is the same as the forming material of the fixing plate 30.
  • FIG. 15 is a side view showing a modified example of the first fixing portion 70.
  • the first fixing part 70 has a second bracket 72 that is bolted and fixed to the upper end plate 109 of the SOFC 40 at a plurality of points (four points) (FIG. 11B).
  • the first fixing unit 70 is not limited to this case.
  • the modified first fixing portion 70 has a second bracket 72 fixed to the upper end plate 109 of the SOFC 40 by welding 73.
  • the second bracket 72 is contacted so as to suppress the surface of the upper end plate 109, and the outer peripheral portion 72a is fixed by welding.
  • the size of the second bracket 72 is set to a size that can suppress the surface of the upper end plate 109 to the maximum. Welding the outer peripheral portion 72a is equivalent to fixing at a plurality of continuous points. For this reason, the natural frequency of the SOFC 40 can be further increased.
  • the modified second bracket 72 is fixed to the upper end plate 109 of the SOFC 40 by welding 73.
  • This configuration can further increase the natural frequency of the SOFC 40.
  • the second fixing unit 80 only needs to fix at least one of the at least one device 51, 52, 53 and the connection block 60 in the GPU 50 to the fixing plate 30 in a rigid state. Furthermore, the displacement absorption part 90 should just be what can absorb the displacement accompanying the thermal expansion of apparatus 51,52,53 in GPU50 in one direction.
  • the configuration of the second fixed portion 80 and the displacement absorbing portion 90 can be changed as appropriate as long as the effect of increasing the natural frequency of the power generation unit 10 and absorbing the displacement due to thermal expansion can be exhibited.
  • (Second Embodiment) 16 and 17 are a top view and a front view showing the power generation unit 10A of the second embodiment.
  • the connection block 60 is fixed to the fixed plate 30 in a rigid state by the second fixing portion 80.
  • the second fixing unit 80 is different from the first embodiment in which one device (the fuel reformer 51) in the GPU 50 is fixed to the fixing plate 30 in a rigid state.
  • all the devices (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) in the GPU 50 have a displacement absorbing unit 90 having a slider 91. This is different from the first embodiment in which one device (fuel reformer 51) in the GPU 50 is fixed to the fixed plate 30 in a rigid state.
  • the second fixing portion 80 has a flange portion 84 that fixes the connection block 60 to the fixing plate 30.
  • the flange portion 84 is fixed to the fixed plate 30 in a rigid state by welding.
  • the flange portion 84 can be fixed to the fixed plate 30 in a rigid state by bolt fastening instead of welding.
  • All the devices 51, 52, 53 in the GPU 50 are not directly fixed to the fixed plate 30 in a rigid state.
  • the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are rigidly fixed to the fixed plate 30 by the first fixing unit 70, and the connection block 60 is rigidly fixed to the fixed plate 30 by the second fixing unit 80. Fixed to state. For this reason, the natural frequency of the power generation unit 10A can be sufficiently increased.
  • All devices in the GPU 50 (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) have a displacement absorbing portion 90 having a slider 91.
  • the displacement accompanying the thermal expansion is guided and absorbed in one direction by the displacement absorbing portion 90 having the slider 91.
  • the operation of the second embodiment will be described. Since the power generation unit 10A is held on the fixed plate 30 connected to the vehicle body, vibration associated with traveling is input.
  • the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are fixed in a rigid state to the fixed plate 30 by the first fixing unit 70, and the connection block 60 is fixed to the fixed plate 30 by the second fixing unit 80. It is fixed. For this reason, the natural frequency of the power generation unit 10A increases and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10A deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10A.
  • the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state can be improved.
  • the displacement absorbing unit 90 having the slider 91 guides and absorbs the displacement accompanying the thermal expansion of the devices (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) in the GPU 50 in one direction. For this reason, even if each apparatus of GPU50 thermally expands, the stress by thermal expansion can be reduced.
  • the power generation unit 10 ⁇ / b> A of the second embodiment fixes the connection block 60 to the fixed plate 30 in the rigid state by the second fixing portion 80.
  • All the devices in the GPU 50 (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) have a displacement absorbing unit 90.
  • This configuration provides the same operational effects as the power generation unit 10A of the first embodiment. That is, the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are rigidly fixed to the fixed plate 30 by the first fixing unit 70 and the connection block 60 is rigidly fixed to the fixed plate 30 by the second fixing unit 80. Fixed to state. For this reason, the natural frequency of the power generation unit 10A increases and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10A deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10A.
  • the rigidity of the SOFC 40, the connection block 60, and the GPU 50 connected in a rigid state is improved. Since the displacement associated with the thermal expansion of the devices (fuel reformer 51, catalytic combustor 53, and heat exchanger 52) in the GPU 50 is absorbed in one direction by the displacement absorber 90, each device of the GPU 50 is thermally expanded. Also, stress due to thermal expansion can be reduced.
  • (Third embodiment) 18 and 19 are a top view and a front view showing the power generation unit 10B of the third embodiment.
  • the third embodiment is different from the first embodiment and the second embodiment in that the configuration of the displacement absorber 90 is modified.
  • the SOFC 40 is rigidly fixed to the fixed plate 30 by the first fixing portion 70.
  • the device (fuel reformer 51) is fixed to the fixed plate 30 in a rigid state by the second fixing portion 80.
  • the two devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50 have a displacement absorbing unit 90 having a slider 91. In each of the catalytic combustor 53 and the heat exchanger 52, the displacement accompanying the thermal expansion is guided and absorbed in one direction by the displacement absorbing portion 90 having the slider 91.
  • the displacement absorbing unit 90 is disposed between the equipment bodies 56a and 56b of the equipment (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 and the manifolds 54a and 54b of the equipment 51 and 52. And a bellows member 95 that expands and contracts along one direction. With respect to the heat exchanger 52, the displacement due to thermal expansion is absorbed in one direction by both the displacement absorbing portion 90 having the slider 91 and the displacement absorbing portion 90 having the bellows member 95.
  • the operation of the third embodiment will be described. Since the power generation unit 10B is held on the fixed plate 30 connected to the vehicle body, vibration associated with traveling is input. In the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state, the SOFC 40 is fixed in a rigid state to the fixed plate 30 by the first fixing unit 70, and one device (the fuel reformer 51) in the GPU 50 is the second fixing unit. 80 is fixed to the fixed plate 30 in a rigid state. For this reason, the natural frequency of the power generation unit 10B increases and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10B deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10B.
  • the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state can be improved.
  • the displacement absorbing portion 90 having the slider 91 guides and absorbs the displacement accompanying the thermal expansion of the devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50 in one direction.
  • the displacement absorption part 90 which has the bellows member 95 expands-contracts and absorbs the displacement accompanying the thermal expansion of the apparatus (fuel reformer 51 and the heat exchanger 52) in GPU50 in one direction. For this reason, even if each apparatus of GPU50 thermally expands, the stress by thermal expansion can be reduced.
  • the displacement absorbing unit 90 is disposed between the equipment body of the equipment (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 and the manifold of the equipment. And a bellows member 95 that expands and contracts along one direction.
  • the same effects as the power generation unit 10B of the first embodiment can be obtained. That is, the SOFC 40, the connection block 60, and the GPU 50 that are connected in the rigid state are fixed in the rigid state to the fixed plate 30 by the first fixing unit 70, and the device (fuel reformer 51) in the GPU 50 is the second fixing unit. 80 is fixed to the fixing plate 30 in a rigid state. For this reason, the natural frequency of the power generation unit 10B increases and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10B deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10B.
  • (Fourth embodiment) 20 and 21 are a top view and a front view showing the power generation unit 10C of the fourth embodiment.
  • the second fixing unit 80 only needs to fix at least one of the GPU 50 and at least one of the connecting blocks 60 to the fixing plate 30 in a rigid state.
  • the power generation unit 10 ⁇ / b> C of the fourth embodiment includes all the devices (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) in the GPU 50 by the second fixing unit 80. Both of the connecting blocks 60 are fixed to the fixing plate 30 in a rigid state.
  • the displacement absorbing unit 90 is disposed between the equipment bodies 56a and 56b of the equipment (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 and the manifolds 54a and 54b of the equipment 51 and 52. It has a bellows member 95 that expands and contracts along one direction.
  • the operation of the fourth embodiment will be described. Since the power generation unit 10C is held on the fixed plate 30 connected to the vehicle body, vibration associated with traveling is input.
  • the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are fixed in a rigid state to the fixed plate 30 by the first fixing unit 70, and the connection block 60 is fixed to the fixed plate 30 by the second fixing unit 80.
  • All the devices in the GPU 50 (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) are fixed to the fixed plate 30 in a rigid state by the second fixing unit 80.
  • the natural frequency of the power generation unit 10C increases, and the resonance frequency increases.
  • the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state can be improved.
  • the displacement absorbing portion 90 having the bellows member 95 absorbs the displacement accompanying the thermal expansion of the equipment (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 in one direction. For this reason, even if each apparatus 51 and 52 of GPU50 is thermally expanded, the stress by thermal expansion can be reduced.
  • the power generation unit 10 ⁇ / b> C of the fourth embodiment is configured such that both the equipment (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) and the connection block 60 in the GPU 50 are connected by the second fixing unit 80. Is fixed to the fixing plate 30 in a rigid state.
  • the displacement absorbing unit 90 is disposed between the device bodies 56a and 56b of the devices (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 and the manifolds 54a and 54b of the devices 51 and 52 along one direction. It has a bellows member 95 that expands and contracts.
  • the SOFC 40, the connection block 60, and the GPU 50 that are connected in the rigid state are fixed to the fixed plate 30 in the rigid state by the first fixing unit 70, and all the devices in the GPU 50 (the fuel reformer 51, the catalytic combustor). 53 and the heat exchanger 52) are fixed to the fixed plate 30 by the second fixing portion 80 in a rigid state, and the connecting block 60 is fixed to the fixing plate 30 by the second fixing portion 80 in a rigid state. For this reason, the natural frequency of the power generation unit 10C increases, and the resonance frequency increases.
  • the natural frequency of the power generation unit 10C deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10C. Since the natural frequency of the power generation unit 10C increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 connected in a rigid state is improved. Displacement (elongation) accompanying thermal expansion of the devices (catalytic combustor 53 and heat exchanger 52) in the GPU 50 is absorbed in one direction by the expansion and contraction of the bellows member 95. As a result, stress due to thermal expansion can be reduced.
  • Specific configurations of the first fixing unit 70 and the second fixing unit 80 are not limited to the above-described configurations.
  • the specific configuration of the first fixing unit 70 can be modified as appropriate as long as it exhibits the function of fixing the other end plate 109 side of the SOFC 40 to the fixing plate 30 in a rigid state.
  • the specific configuration of the second fixing unit 80 can be appropriately modified as long as it exhibits a function of fixing at least one of the at least one device 51, 52, 53 and the connection block 60 in the GPU 50 to the fixing plate 30 in a rigid state. Both different types of fastening methods such as bolt fastening and welded joints can be applied.
  • the number of fixed points is also arbitrary.
  • the specific configuration of the displacement absorbing portion 90 is not limited to this case.
  • the specific configuration of the displacement absorbing unit 90 can be appropriately modified as long as it exhibits the function of absorbing the displacement accompanying the thermal expansion of the device in the GPU 50 in one direction.
  • a damper using a spring or working fluid pressure can be used.

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Abstract

[Problem] To provide a power generation unit that increases the natural frequency and can absorb displacement due to thermal expansion. [Solution] In a power generation unit 10, a coupling block 60 integrally couples manifolds 41a, 41b, 41c on the side of one end plate 108 of a solid oxide fuel cell 40 with respective manifolds 54a, 54b, 54c of devices (a fuel reformer 51, a catalyst combustor 53, and a heat exchanger 52) in a gas processing unit (GPU) 50. The solid oxide fuel cell, the coupling block, and the GPU are coupled in a rigid state. Another end plate 109 side of the solid oxide fuel cell is secured in a rigid state to a securing plate 30 by a first securing section 70. The fuel reformer 51 of the GPU is secured in a rigid state to the securing plate 30 by a second securing section 80. Displacement absorption sections 90 absorb displacement associated with thermal expansion of the devices in the GPU 50 in one direction.

Description

固体酸化物形燃料電池を有する発電ユニットPower generation unit having a solid oxide fuel cell

 本発明は、車体に接続される固定プレート上に保持される発電ユニットに関する。 The present invention relates to a power generation unit held on a fixed plate connected to a vehicle body.

 燃料電池を有する発電ユニットを車体に搭載する場合において、燃料電池の熱膨張による伸びを規制し、走行に伴う振動入力に対して変位を規制する技術が知られている(特許文献1を参照)。特許文献1に記載された発電ユニットを車両に搭載するためのマウント構造は、燃料電池の積層方向の一方のエンドプレートがラバーマウントを介して車両に保持される固定支持部と、他方のエンドプレートがラバーマウントを介して積層方向に移動可能に車両に保持される可動支持部とを有している。 In a case where a power generation unit having a fuel cell is mounted on a vehicle body, a technology is known in which the expansion due to thermal expansion of the fuel cell is regulated and the displacement is regulated with respect to vibration input accompanying traveling (see Patent Document 1). . A mounting structure for mounting a power generation unit described in Patent Document 1 on a vehicle includes a fixed support portion in which one end plate in the stacking direction of the fuel cells is held by the vehicle via a rubber mount, and the other end plate Has a movable support portion held by the vehicle so as to be movable in the stacking direction via the rubber mount.

特開2001-143742号公報JP 2001-143742 A

 しかしながら、特許文献1に記載されたマウント構造にあっては、固定支持部と燃料電池との間に流体漏れ防止用のラバーを配置する構成となっている。このため、燃料電池の熱膨張による伸びを十分に規制することができず、燃料電池の固有振動数を上昇させることができない。燃料電池の固有振動数が、路面負荷入力の大きい周波数域から外れる(上昇する)ことができず、走行に伴う振動が燃料電池の作動に悪影響を及ぼす虞がある。 However, in the mount structure described in Patent Document 1, a rubber for preventing fluid leakage is arranged between the fixed support portion and the fuel cell. For this reason, the elongation due to the thermal expansion of the fuel cell cannot be sufficiently regulated, and the natural frequency of the fuel cell cannot be increased. The natural frequency of the fuel cell cannot deviate (increase) from the frequency range where the road load input is large, and the vibration associated with traveling may adversely affect the operation of the fuel cell.

 本発明の目的は、固有振動数を上昇させ、かつ、熱膨張による変位を吸収可能な発電ユニット提供することにある。 An object of the present invention is to provide a power generation unit capable of increasing the natural frequency and absorbing displacement due to thermal expansion.

 上記目的を達成するための本発明は、車体に接続される固定プレート上に保持される発電ユニットであって、固体酸化物形燃料電池と、ガスプロセッシングユニットと、連結部と、を有する。ガスプロセッシングユニットは、前記固体酸化物形燃料電池に供給する燃料を改質する燃料改質器、前記固体酸化物形燃料電池から排出されたアノードオフガス中の未燃ガスを燃焼する燃焼器および前記燃焼器から排出された排気ガスと前記固体酸化物形燃料電池に供給する酸化剤ガスとを熱交換する熱交換器の3つの機器を含んでいる。連結部は、前記固体酸化物形燃料電池の一方のエンドプレート側に形成されたマニホールドと、前記ガスプロセッシングユニットにおける前記機器のそれぞれのマニホールドとを一体的に連結する。発電ユニットは、前記固体酸化物形燃料電池の他方のエンドプレート側を前記固定プレートにリジッド状態に固定する第1固定部を有する。発電ユニットは、前記ガスプロセッシングユニットにおける少なくとも1つの前記機器および前記連結部の少なくとも一方を前記固定プレートにリジッド状態に固定する第2固定部を有する。発電ユニットは、前記ガスプロセッシングユニットにおける前記機器の熱膨張に伴う変位を一の方向において吸収する変位吸収部を有する。 The present invention for achieving the above object is a power generation unit held on a fixed plate connected to a vehicle body, and includes a solid oxide fuel cell, a gas processing unit, and a connecting portion. The gas processing unit comprises: a fuel reformer that reforms fuel supplied to the solid oxide fuel cell; a combustor that burns unburned gas in the anode off-gas discharged from the solid oxide fuel cell; It includes three devices: a heat exchanger that exchanges heat between the exhaust gas discharged from the combustor and the oxidant gas supplied to the solid oxide fuel cell. The connecting portion integrally connects a manifold formed on one end plate side of the solid oxide fuel cell and each manifold of the device in the gas processing unit. The power generation unit includes a first fixing portion that fixes the other end plate side of the solid oxide fuel cell to the fixing plate in a rigid state. The power generation unit includes a second fixing portion that fixes at least one of the at least one device and the connecting portion in the gas processing unit to the fixing plate in a rigid state. The power generation unit includes a displacement absorbing unit that absorbs in one direction a displacement associated with thermal expansion of the device in the gas processing unit.

発電ユニットが保持された固定プレートを車体に接続した状態を示す斜視図である。It is a perspective view which shows the state which connected the stationary plate with which the electric power generation unit was hold | maintained to the vehicle body. 連結部が接続されたガスプロセッシングユニットと、固体酸化物形燃料電池とを分離した状態において示す斜視図である。It is a perspective view shown in the state which isolate | separated the gas processing unit to which the connection part was connected, and the solid oxide fuel cell. 第1実施形態の固体酸化物形燃料電池とガスプロセッシングユニットとを締結した発電ユニットを示す上面図である。It is a top view which shows the electric power generation unit which fastened the solid oxide form fuel cell of 1st Embodiment, and the gas processing unit. 第1実施形態の発電ユニットを示す正面図である。It is a front view which shows the electric power generation unit of 1st Embodiment. 固体酸化物形燃料電池を示す分解斜視図である。It is an exploded perspective view showing a solid oxide fuel cell. 図5に示すセルユニットの分解斜視図である。It is a disassembled perspective view of the cell unit shown in FIG. 図6に示すメタルサポートセルアッセンブリーの分解斜視図である。FIG. 7 is an exploded perspective view of the metal support cell assembly shown in FIG. 6. 図6の8-8線に沿うメタルサポートセルアッセンブリーの部分断面図である。FIG. 8 is a partial cross-sectional view of the metal support cell assembly taken along line 8-8 in FIG. 連結部と固体酸化物形燃料電池との連結構造を示す断面図である。It is sectional drawing which shows the connection structure of a connection part and a solid oxide fuel cell. 連結部とガスプロセッシングユニットとの連結構造を示す断面図である。It is sectional drawing which shows the connection structure of a connection part and a gas processing unit. 固体酸化物形燃料電池の他方のエンドプレート側を固定プレートにリジッド状態に固定する第1固定部を示す正面図である。It is a front view which shows the 1st fixing | fixed part which fixes the other end plate side of a solid oxide fuel cell to a fixing plate in a rigid state. 第1固定部を示す側面図である。It is a side view which shows a 1st fixing | fixed part. ガスプロセッシングユニットにおける機器を固定プレートにリジッド状態に固定する第2固定部を示す正面図である。It is a front view which shows the 2nd fixing | fixed part which fixes the apparatus in a gas processing unit to a fixing plate in a rigid state. 第2固定部を示す側面図である。It is a side view which shows a 2nd fixing | fixed part. ガスプロセッシングユニットの機器における熱膨張に伴う変位を一の方向において吸収する変位吸収部を示す正面図である。It is a front view which shows the displacement absorption part which absorbs the displacement accompanying the thermal expansion in the apparatus of a gas processing unit in one direction. 変位吸収部を示す側面図である。It is a side view which shows a displacement absorption part. 固体酸化物形燃料電池の稼働時において、燃料電池スタックが熱膨張するときの作用を模式的に示す図である。It is a figure which shows typically an effect | action when a fuel cell stack thermally expands at the time of operation of a solid oxide fuel cell. 第1固定部の変形例を示す側面図である。It is a side view which shows the modification of a 1st fixing | fixed part. 第2実施形態の固体酸化物形燃料電池とガスプロセッシングユニットとを締結した発電ユニットを示す上面図である。It is a top view which shows the electric power generation unit which fastened the solid oxide form fuel cell and gas processing unit of 2nd Embodiment. 第2実施形態の発電ユニットを示す正面図である。It is a front view which shows the electric power generation unit of 2nd Embodiment. 第3実施形態の固体酸化物形燃料電池とガスプロセッシングユニットとを締結した発電ユニットを示す上面図である。It is a top view which shows the electric power generation unit which fastened the solid oxide fuel cell of 3rd Embodiment, and the gas processing unit. 第3実施形態の発電ユニットを示す正面図である。It is a front view which shows the electric power generation unit of 3rd Embodiment. 第4実施形態の固体酸化物形燃料電池とガスプロセッシングユニットとを締結した発電ユニットを示す上面図である。It is a top view which shows the electric power generation unit which fastened the solid oxide fuel cell of 4th Embodiment, and the gas processing unit. 第4実施形態の発電ユニットを示す正面図である。It is a front view which shows the electric power generation unit of 4th Embodiment.

 以下、添付した図面を参照しながら、本発明の実施形態を説明する。なお、以下の説明は特許請求の範囲に記載される技術的範囲や用語の意義を限定するものではない。また、図面の寸法比率は説明の都合上誇張されており、実際の比率とは異なる場合がある。 Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. In addition, the following description does not limit the meaning of the technical scope and terms described in the claims. In addition, the dimensional ratios in the drawings are exaggerated for convenience of explanation, and may differ from actual ratios.

 (第1実施形態)
 図1は、発電ユニット10が保持された固定プレート30を車体に接続した状態を示す斜視図、図2は、連結部が接続されたガスプロセッシングユニット50と、固体酸化物形燃料電池40とを分離した状態において示す斜視図、図3および図4は、第1実施形態の固体酸化物形燃料電池40とガスプロセッシングユニット50とを締結した発電ユニット10を示す上面図および正面図である。
(First embodiment)
FIG. 1 is a perspective view showing a state where a fixed plate 30 holding a power generation unit 10 is connected to a vehicle body, and FIG. 2 shows a gas processing unit 50 to which a connecting portion is connected and a solid oxide fuel cell 40. FIGS. 3 and 4 are a top view and a front view showing the power generation unit 10 in which the solid oxide fuel cell 40 and the gas processing unit 50 of the first embodiment are fastened.

 図1~図4に示すように、第1実施形態の発電ユニット10は、概説すると、車体に接続される固定プレート30上に保持される発電ユニット10であって、固体酸化物形燃料電池(SOFC)40(以下、「SOFC40」とも記す)と、ガスプロセッシングユニット(GPU)50(以下、「GPU50」とも記す)と、SOFC40とGPU50とをリジッド状態に連結する連結ブロック60(連結部に相当する)と、を有する。GPU50は、燃料改質器51、燃焼器に相当する触媒燃焼器53および熱交換器52の3つの機器を含んでいる。連結ブロック60は、SOFC40の一方のエンドプレート108側に形成されたマニホールド41a、41b、41cと、GPU50における機器51、52、53のそれぞれのマニホールド54a、54b、54cとを一体的に連結する。発電ユニット10は、SOFC40の他方のエンドプレート109側を固定プレート30にリジッド状態に固定する第1固定部70を有する。発電ユニット10は、GPU50における少なくとも1つの機器51(52、53)および連結ブロック60の少なくとも一方を固定プレート30にリジッド状態に固定する第2固定部80を有する。発電ユニット10はさらに、GPU50における機器51、52、53の熱膨張に伴う変位を一の方向において吸収する変位吸収部90を有する。第1実施形態においては、第2固定部80は、GPU50における1つの機器(燃料改質器51)を固定プレート30にリジッド状態に固定する。また、変位吸収部90は、GPU50における2つの機器(触媒燃焼器53および熱交換器52)のそれぞれの熱膨張に伴う変位を一の方向において吸収する。以下、詳述する。 As shown in FIGS. 1 to 4, the power generation unit 10 according to the first embodiment is generally a power generation unit 10 held on a fixed plate 30 connected to a vehicle body, and is a solid oxide fuel cell ( SOFC) 40 (hereinafter also referred to as “SOFC 40”), a gas processing unit (GPU) 50 (hereinafter also referred to as “GPU 50”), and a connecting block 60 (corresponding to a connecting portion) that connects the SOFC 40 and GPU 50 in a rigid state. And). The GPU 50 includes three devices: a fuel reformer 51, a catalytic combustor 53 corresponding to a combustor, and a heat exchanger 52. The connection block 60 integrally connects the manifolds 41 a, 41 b, 41 c formed on the one end plate 108 side of the SOFC 40 and the respective manifolds 54 a, 54 b, 54 c of the devices 51, 52, 53 in the GPU 50. The power generation unit 10 includes a first fixing portion 70 that fixes the other end plate 109 side of the SOFC 40 to the fixing plate 30 in a rigid state. The power generation unit 10 includes a second fixing portion 80 that fixes at least one of the at least one device 51 (52, 53) and the connection block 60 in the GPU 50 to the fixing plate 30 in a rigid state. The power generation unit 10 further includes a displacement absorbing unit 90 that absorbs the displacement accompanying the thermal expansion of the devices 51, 52, and 53 in the GPU 50 in one direction. In the first embodiment, the second fixing unit 80 fixes one device (the fuel reformer 51) in the GPU 50 to the fixed plate 30 in a rigid state. Moreover, the displacement absorption part 90 absorbs the displacement accompanying the thermal expansion of each of the two devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50 in one direction. Details will be described below.

 (固定プレート30)
 図1に示すように、固定プレート30は、車体の例えばサイドメンバー20に溶接接合あるいはボルト締結によってリジッド状態に固定されている。図示例では、固定プレート30は、4点においてサイドメンバー20に固定されている。固定する点数は、発電ユニット10に要求される剛性(固有振動数)を考慮して適宜変更できる。
(Fixing plate 30)
As shown in FIG. 1, the fixing plate 30 is fixed in a rigid state by welding or bolt fastening to, for example, the side member 20 of the vehicle body. In the illustrated example, the fixing plate 30 is fixed to the side member 20 at four points. The number of points to be fixed can be appropriately changed in consideration of the rigidity (natural frequency) required for the power generation unit 10.

 (ガスプロセッシングユニット(GPU)50)
 図3に示すように、発電ユニット10のGPU50は、燃料改質器51、燃焼器に相当する触媒燃焼器53および熱交換器52の3つの機器を含んでいる。燃料改質器51は、SOFC40に供給する燃料Fを改質する。触媒燃焼器53は、SOFC40から排出されたアノードオフガスAOG中の未燃ガスを燃焼する。熱交換器52は、触媒燃焼器53から排出された排気ガスEGとSOFC40に供給する酸化剤ガスCGとを熱交換する。
(Gas processing unit (GPU) 50)
As shown in FIG. 3, the GPU 50 of the power generation unit 10 includes three devices: a fuel reformer 51, a catalytic combustor 53 corresponding to a combustor, and a heat exchanger 52. The fuel reformer 51 reforms the fuel F supplied to the SOFC 40. The catalytic combustor 53 burns unburned gas in the anode off gas AOG discharged from the SOFC 40. The heat exchanger 52 exchanges heat between the exhaust gas EG discharged from the catalyst combustor 53 and the oxidant gas CG supplied to the SOFC 40.

 燃料改質器51は、燃料Fの供給管51aが接続されている。熱交換器52は、酸化剤ガスCGの供給管52aと、熱交換後の排気ガスEGを排出する排気管52bとが接続されている。触媒燃焼器53と熱交換器52との間は、触媒燃焼器53から排出された排気ガスEGを熱交換器52に導入する導入管52cによって接続されている。 The fuel reformer 51 is connected to a fuel F supply pipe 51a. The heat exchanger 52 is connected to an oxidant gas CG supply pipe 52a and an exhaust pipe 52b that discharges the exhaust gas EG after heat exchange. The catalyst combustor 53 and the heat exchanger 52 are connected by an introduction pipe 52 c that introduces the exhaust gas EG discharged from the catalyst combustor 53 into the heat exchanger 52.

 (連結ブロック60)
 図3に示すように、SOFC40は、下部エンドプレート108(一方のエンドプレート108に相当する)側に、改質された燃料ガス(アノードガスAG)を導入するマニホールド41aが形成されている。SOFC40は、下部エンドプレート108側に、加熱された酸化剤ガスCG(カソードガスCG)を導入するマニホールド41bが形成されている。SOFC40は、下部エンドプレート108側に、アノードオフガスAOGを導出するマニホールド41cが形成されている。
(Connection block 60)
As shown in FIG. 3, the SOFC 40 has a manifold 41a for introducing a reformed fuel gas (anode gas AG) on the lower end plate 108 (corresponding to one end plate 108) side. In the SOFC 40, a manifold 41b for introducing a heated oxidant gas CG (cathode gas CG) is formed on the lower end plate 108 side. In the SOFC 40, a manifold 41c for leading the anode off gas AOG is formed on the lower end plate 108 side.

 GPU50の燃料改質器51は、改質されたアノードガスAGを導出するマニホールド54aが形成されている。熱交換器52は、加熱されたカソードガスCGを導出するマニホールド54bが形成されている。触媒燃焼器53は、アノードオフガスAOGを導入するマニホールド54cが形成されている。 In the fuel reformer 51 of the GPU 50, a manifold 54a for leading out the reformed anode gas AG is formed. The heat exchanger 52 is formed with a manifold 54b for leading the heated cathode gas CG. The catalyst combustor 53 is formed with a manifold 54c for introducing the anode off gas AOG.

 連結ブロック60は、SOFC40の下部エンドプレート108側に形成されたマニホールド41a、41b、41cと、GPU50における機器のそれぞれのマニホールド54a、54b、54cとを連通する第1~第3の通路部61、62、63が形成されたブロック形状を有する。第1の通路部61は、SOFC40のマニホールド41aと燃料改質器51のマニホールド54aとを連通する。第2の通路部62は、SOFC40のマニホールド41bと熱交換器52のマニホールド54bとを連通する。第3の通路部63は、SOFC40のマニホールド41cと触媒燃焼器53のマニホールド54cとを連通する。図3に示すように、アノードガスAGは、矢印によって示されるように第1の通路部61を流れる。カソードガスCGは、矢印によって示されるように第2の通路部62を流れる。アノードオフガスAOGは、矢印によって示されるように第3の通路部63を流れる。 The connecting block 60 includes first to third passage portions 61 that connect the manifolds 41a, 41b, and 41c formed on the lower end plate 108 side of the SOFC 40 and the manifolds 54a, 54b, and 54c of the equipment in the GPU 50, 62 and 63 are formed in a block shape. The first passage 61 communicates the manifold 41 a of the SOFC 40 and the manifold 54 a of the fuel reformer 51. The second passage 62 communicates the manifold 41b of the SOFC 40 and the manifold 54b of the heat exchanger 52. The third passage portion 63 communicates the manifold 41 c of the SOFC 40 and the manifold 54 c of the catalytic combustor 53. As shown in FIG. 3, the anode gas AG flows through the first passage portion 61 as indicated by an arrow. The cathode gas CG flows through the second passage portion 62 as indicated by an arrow. The anode off gas AOG flows through the third passage portion 63 as indicated by an arrow.

 連結ブロック60におけるSOFC40側の端面は、SOFC40に溶接接合あるいはボルト締結によってリジッド状態に固定されている。連結ブロック60におけるGPU50側の端面は、GPU50の各機器に溶接接合あるいはボルト締結によってリジッド状態に固定されている。 The end face of the connecting block 60 on the SOFC 40 side is fixed to the SOFC 40 in a rigid state by welding or bolt fastening. The end surface of the connection block 60 on the GPU 50 side is fixed to a rigid state by welding or bolt fastening to each device of the GPU 50.

 このように連結ブロック60は、SOFC40の下部エンドプレート108側に形成されたマニホールド41a、41b、41cと、GPU50における機器51、52、53のそれぞれのマニホールド54a、54b、54cとを一体的に連結する。この連結ブロック60によって、SOFC40とGPU50とがリジッド状態に連結される。 In this way, the connection block 60 integrally connects the manifolds 41a, 41b, 41c formed on the lower end plate 108 side of the SOFC 40 and the respective manifolds 54a, 54b, 54c of the devices 51, 52, 53 in the GPU 50. To do. By this connection block 60, the SOFC 40 and the GPU 50 are connected in a rigid state.

 (固体酸化物形燃料電池(SOFC)40)
 次に、発電ユニット10のSOFC40について説明する。
(Solid oxide fuel cell (SOFC) 40)
Next, the SOFC 40 of the power generation unit 10 will be described.

 図5は、SOFC40を示す分解斜視図である。図6は、図5に示すセルユニット100の分解斜視図である。図7は、図6に示すメタルサポートセルアッセンブリー110の分解斜視図である。図8は、図6の8-8線に沿うメタルサポートセルアッセンブリー110の部分断面図である。なお、説明の便宜のため、XYZ直交座標系を図5~図8中に示す。X軸およびY軸は水平方向を示し、Z軸は上下方向に平行な軸を示している。 FIG. 5 is an exploded perspective view showing the SOFC 40. 6 is an exploded perspective view of the cell unit 100 shown in FIG. FIG. 7 is an exploded perspective view of the metal support cell assembly 110 shown in FIG. FIG. 8 is a partial cross-sectional view of the metal support cell assembly 110 taken along line 8-8 in FIG. For convenience of explanation, the XYZ orthogonal coordinate system is shown in FIGS. The X axis and the Y axis indicate the horizontal direction, and the Z axis indicates an axis parallel to the vertical direction.

 図示するSOFC40(Solid Oxide Fuel Cell)は、電解質として安定化ジルコニアなどの酸化物イオン導電体を用いた燃料電池である。 The SOFC 40 (Solid Oxide Fuel Cell) shown in the figure is a fuel cell using an oxide ion conductor such as stabilized zirconia as an electrolyte.

 図5に示すように、SOFC40は、複数のセルユニット100を上下方向に積層して構成された燃料電池スタック40Sと、燃料電池スタック40Sの上方に積層される上部集電板106と、燃料電池スタック40Sの下方に積層される下部集電板107とを有している。上部集電板106、燃料電池スタック40Sおよび下部集電板107は、上部エンドプレート109と下部エンドプレート108とによって挟み込まれている。上部エンドプレート109および下部エンドプレート108のそれぞれは、カバー105にボルトによって締結されている。下部エンドプレート108は一方のエンドプレート108に相当し、上部エンドプレート109は他方のエンドプレート109に相当する。以下、図中にZ軸で示す燃料電池スタック40Sの上下方向を「積層方向」とも称する。以下、SOFC40の主要な構成要素について説明する。 As shown in FIG. 5, the SOFC 40 includes a fuel cell stack 40S configured by stacking a plurality of cell units 100 in the vertical direction, an upper current collector plate 106 stacked above the fuel cell stack 40S, and a fuel cell. And a lower current collecting plate 107 stacked below the stack 40S. The upper current collecting plate 106, the fuel cell stack 40S, and the lower current collecting plate 107 are sandwiched between the upper end plate 109 and the lower end plate 108. Each of the upper end plate 109 and the lower end plate 108 is fastened to the cover 105 with bolts. The lower end plate 108 corresponds to one end plate 108, and the upper end plate 109 corresponds to the other end plate 109. Hereinafter, the vertical direction of the fuel cell stack 40 </ b> S indicated by the Z axis in the drawing is also referred to as “stacking direction”. Hereinafter, main components of the SOFC 40 will be described.

 [セルユニット100]
 図6に示すように、セルユニット100は、メタルサポートセルアッセンブリー110と、電解質電極接合体111との間にガスが流通するための流路部121を区画形成するセパレータ120と、集電補助層140と、を順に積層して構成される。なお、メタルサポートセルアッセンブリー110と集電補助層140との間に両者を導通接触させる接点材を配置してもよいし、集電補助層140を省く構造としてもよい。
[Cell unit 100]
As shown in FIG. 6, the cell unit 100 includes a separator 120 that partitions and forms a flow path portion 121 for gas to flow between the metal support cell assembly 110 and the electrolyte electrode assembly 111, a current collecting auxiliary layer 140 are sequentially stacked. In addition, a contact material that conducts and contacts the metal support cell assembly 110 and the current collecting auxiliary layer 140 may be disposed, or the current collecting auxiliary layer 140 may be omitted.

 セルユニット100は、アノードガスAGを流通させて供給および排出するためのマニホールド部(図示せず)と、マニホールド部の周囲を封止してガスの流れを制限する複数のシール部160(図5、図6を参照)と、をさらに有する。なお、図示する燃料電池スタック40Sは、セルユニット100の外側(図6および図7の破線囲み部分)をカソードガスが自由に流通するオープンカソード構造として構成している。 The cell unit 100 has a manifold part (not shown) for circulating and supplying the anode gas AG, and a plurality of seal parts 160 (FIG. 5) for sealing the periphery of the manifold part and restricting the gas flow. , (See FIG. 6). The illustrated fuel cell stack 40S is configured as an open cathode structure in which cathode gas freely flows outside the cell unit 100 (a portion surrounded by a broken line in FIGS. 6 and 7).

 図7および図8に示すように、メタルサポートセルアッセンブリー110は、長手方向Yに沿って複数(図示例では、2つ)並べて配置したメタルサポートセル(Metal-Supported Cell:MSC)110Mと、メタルサポートセル110Mの外周を保持するセルフレーム113と、を有する。 As shown in FIGS. 7 and 8, the metal support cell assembly 110 includes a plurality of (two in the illustrated example) metal support cells (Metal-Supported Cells: MSC) 110M arranged in the longitudinal direction Y, and a metal. And a cell frame 113 that holds the outer periphery of the support cell 110M.

 メタルサポートセル110Mは、電解質層111Eを両側から一対の電極であるアノード層111Aおよびカソード層111Cで挟持してなる電解質電極接合体111と、電解質電極接合体111を上下方向の一方側から支持する金属製のメタルサポート部112と、を有する。メタルサポートセル110Mは、電解質支持型セルや電極支持型セルに比べて機械的強度、急速起動性等に優れる。 The metal support cell 110M supports the electrolyte electrode assembly 111 in which the electrolyte layer 111E is sandwiched between a pair of electrodes 111A and 111C from both sides, and the electrolyte electrode assembly 111 from one side in the vertical direction. A metal support portion 112 made of metal. The metal support cell 110M is excellent in mechanical strength, quick startability, and the like as compared with the electrolyte support cell and the electrode support cell.

 [電解質電極接合体111]
 図7および図8に示すように、電解質電極接合体111は、電解質層111Eを両側から一対の電極であるアノード層111Aおよびカソード層111Cで挟持して構成される。
[Electrolyte electrode assembly 111]
As shown in FIGS. 7 and 8, the electrolyte electrode assembly 111 is configured by sandwiching an electrolyte layer 111E from both sides by an anode layer 111A and a cathode layer 111C which are a pair of electrodes.

 電解質層111Eは、カソード層111Cからアノード層111Aに向かって酸化物イオンを透過させるものである。電解質層111Eは、酸化物イオンを通過させつつ、ガスと電子を通過させない。電解質層111Eの形成材料は、例えば、イットリア、酸化ネオジム、サマリウム、ガドリニウム、スカンジウム等をドープした安定化ジルコニアなどの固体酸化物セラミックスが挙げられる。 The electrolyte layer 111E transmits oxide ions from the cathode layer 111C toward the anode layer 111A. The electrolyte layer 111E does not allow gas and electrons to pass while allowing oxide ions to pass through. Examples of the material for forming the electrolyte layer 111E include solid oxide ceramics such as stabilized zirconia doped with yttria, neodymium oxide, samarium, gadolinium, and scandium.

 アノード層111Aは、燃料極であって、アノードガスAG(例えば水素)と酸化物イオンを反応させて、アノードガスAGの酸化物を生成するとともに電子を取り出す。アノード層111Aは、還元雰囲気に耐性を有し、アノードガスAGを透過させ、電気(電子およびイオン)伝導度が高く、アノードガスAGを酸化物イオンと反応させる触媒作用を有する。アノード層111Aの形成材料は、例えば、ニッケル等の金属、イットリア安定化ジルコニア等の酸化物イオン伝導体を混在させたものが挙げられる。 The anode layer 111A is a fuel electrode, and reacts an anode gas AG (for example, hydrogen) with oxide ions to generate an oxide of the anode gas AG and take out electrons. The anode layer 111A is resistant to a reducing atmosphere, transmits the anode gas AG, has high electrical (electron and ion) conductivity, and has a catalytic action that causes the anode gas AG to react with oxide ions. Examples of the material for forming the anode layer 111A include a material in which a metal such as nickel and an oxide ion conductor such as yttria-stabilized zirconia are mixed.

 カソード層111Cは、酸化剤極であって、カソードガス(例えば空気に含まれる酸素)と電子を反応させて、酸素分子を酸化物イオンに変換する。カソード層111Cは、酸化雰囲気に耐性を有し、カソードガスを透過させ、電気(電子およびイオン)伝導度が高く、酸素分子を酸化物イオンに変換する触媒作用を有する。カソード層111Cの形成材料は、例えば、ランタン、ストロンチウム、マンガン、コバルト等からなる酸化物が挙げられる。 The cathode layer 111C is an oxidizer electrode, and reacts cathode gas (for example, oxygen contained in air) with electrons to convert oxygen molecules into oxide ions. The cathode layer 111C has resistance to an oxidizing atmosphere, allows the cathode gas to permeate, has high electrical (electron and ion) conductivity, and has a catalytic action to convert oxygen molecules into oxide ions. Examples of the material for forming the cathode layer 111C include oxides made of lanthanum, strontium, manganese, cobalt, and the like.

 [メタルサポート部112]
 図7および図8に示すように、メタルサポート部112は、電解質電極接合体111をアノード層111Aの側から支持するものである。メタルサポート部112によって電解質電極接合体111を支持することにより、電解質電極接合体111に面圧分布の偏りがわずかに生じた場合でも、曲げによる電解質電極接合体111の破損を抑制できる。メタルサポート部112は、ガス透過性および電子伝導性を有する多孔質の金属である。メタルサポート部112の形成材料は、例えば、ニッケルやクロムを含有する耐食合金や耐食鋼、ステンレス鋼などが挙げられる。
[Metal support part 112]
As shown in FIG. 7 and FIG. 8, the metal support part 112 supports the electrolyte electrode assembly 111 from the anode layer 111A side. By supporting the electrolyte electrode assembly 111 with the metal support part 112, even when the surface pressure distribution is slightly biased in the electrolyte electrode assembly 111, the damage to the electrolyte electrode assembly 111 due to bending can be suppressed. The metal support part 112 is a porous metal having gas permeability and electronic conductivity. Examples of the material for forming the metal support 112 include a corrosion resistant alloy, corrosion resistant steel, and stainless steel containing nickel and chromium.

 [セルフレーム113]
 図7および図8に示すように、セルフレーム113は、メタルサポートセル110Mを周囲から保持するものである。図7に示すように、セルフレーム113は、長手方向Yに沿って並べて配置された複数(図示例では、2つ)の開口部113Hを有する。セルフレーム113の開口部113Hには、メタルサポートセル110Mが配置される。メタルサポートセル110Mの外周は、セルフレーム113の開口部113Hの内縁に接合される。セルフレーム113は、図7に示すように、アノードガスAGが流通するアノードガス流入口113a、113b、113cおよびアノードガス流出口113d、113eを有している。セルフレーム113の形成材料は、例えば、表面に絶縁処理が施された金属が挙げられる。
[Cell frame 113]
As shown in FIGS. 7 and 8, the cell frame 113 holds the metal support cell 110M from the periphery. As shown in FIG. 7, the cell frame 113 has a plurality (two in the illustrated example) of openings 113 </ b> H arranged side by side along the longitudinal direction Y. A metal support cell 110M is disposed in the opening 113H of the cell frame 113. The outer periphery of the metal support cell 110M is joined to the inner edge of the opening 113H of the cell frame 113. As shown in FIG. 7, the cell frame 113 has anode gas inlets 113a, 113b, 113c through which the anode gas AG flows and anode gas outlets 113d, 113e. Examples of the material for forming the cell frame 113 include a metal whose surface is subjected to an insulation treatment.

 [セパレータ120]
 セパレータ120は、積層方向Zに隣り合うメタルサポートセル110M間に配置される。セパレータ120は、メタルサポートセル110Mの電解質電極接合体111と対向する領域に流路部121を有する。流路部121は、電解質電極接合体111との間にガスの流路を区画形成する凹凸形状を有している。メタルサポート部112に臨む流路部121にはアノードガスAGが流れ、集電補助層140に臨む流路部121にはカソードガスが流れる。
[Separator 120]
The separator 120 is disposed between the metal support cells 110M adjacent in the stacking direction Z. The separator 120 has a flow path portion 121 in a region facing the electrolyte electrode assembly 111 of the metal support cell 110M. The flow path part 121 has an uneven shape that partitions and forms a gas flow path between the flow path part 121 and the electrolyte electrode assembly 111. The anode gas AG flows through the flow path part 121 facing the metal support part 112, and the cathode gas flows through the flow path part 121 facing the current collection auxiliary layer 140.

 図6に示すように、セパレータ120の流路部121は、凹凸形状が短手方向Xに延在するように略直線状に形成されている。これにより、流路部121に沿って流れるガスの流れ方向は、短手方向Xである。セパレータ120は、アノードガスAGが流通するアノードガス流入口120a、120b、120cおよびアノードガス流出口120d、120eを有している。セパレータ120の形成材料は、例えば、金属が挙げられる。セパレータ120の流路部121以外の領域には、絶縁処理が施されている。 As shown in FIG. 6, the flow path portion 121 of the separator 120 is formed in a substantially linear shape so that the concavo-convex shape extends in the short-side direction X. Thereby, the flow direction of the gas flowing along the flow path part 121 is the short direction X. The separator 120 has anode gas inlets 120a, 120b, 120c through which the anode gas AG flows and anode gas outlets 120d, 120e. Examples of the material for forming the separator 120 include metal. Insulation treatment is applied to the region other than the flow path portion 121 of the separator 120.

 [集電補助層140]
 集電補助層140は、メタルサポートセル110Mとセパレータ120との間に配置され、カソードガスを通す空間を形成しつつ面圧を均等にして、メタルサポートセル110Mとセパレータ120との電気的な接触を補助する。集電補助層140は、金網状のエキスパンドメタルなどがあげられる。また、本特性や機能を他要素で持たせることができる場合、省くことも可能である。
[Current collection auxiliary layer 140]
The current collection auxiliary layer 140 is disposed between the metal support cell 110M and the separator 120, and forms an electric space between the metal support cell 110M and the separator 120 with a uniform surface pressure while forming a space through which the cathode gas passes. To assist. Examples of the current collecting auxiliary layer 140 include a wire mesh expanded metal. Also, if this characteristic or function can be provided by other elements, it can be omitted.

 [シール部160]
 シール部160は、耐熱性およびシール性を有する材料から形成される。このような材料としては、例えば、バーミキュライト(蛭石)を主原料とするサーミキュライト(登録商標)が挙げられる。
[Seal part 160]
The seal part 160 is formed from a material having heat resistance and sealability. As such a material, for example, thermiculite (registered trademark) whose main raw material is vermiculite (meteorite) can be mentioned.

 (連結ブロック60とSOFC40との連結構造)
 図9は、連結ブロック60とSOFC40との連結構造を示す断面図である。
(Connecting structure of connecting block 60 and SOFC 40)
FIG. 9 is a cross-sectional view showing a connection structure between the connection block 60 and the SOFC 40.

 図9に示すように、連結ブロック60は、下部エンドプレート108に重ねられ、第1~第3の通路部61、62、63の内部から溶接接合され一体化される。SOFC40は、連結ブロック60を下部エンドプレート108と一体化した後、連結ブロック60が一体化された下部エンドプレート108にセルユニット100を積層して形成される。 As shown in FIG. 9, the connecting block 60 is overlapped with the lower end plate 108, and is welded and integrated from the inside of the first to third passage portions 61, 62, 63. The SOFC 40 is formed by integrating the connection block 60 with the lower end plate 108 and then laminating the cell unit 100 on the lower end plate 108 with the connection block 60 integrated.

 (連結ブロック60とGPU50との連結構造)
 図10は、連結ブロック60とGPU50との連結構造を示す断面図である。
(Connecting structure of connecting block 60 and GPU 50)
FIG. 10 is a cross-sectional view showing a connection structure between the connection block 60 and the GPU 50.

 図10に示すように、GPU50は、機器のそれぞれのマニホールド54a、54b、54cが形成されたフランジ部材55を有する。フランジ部材55は、溶接によって機器51、52、53のそれぞれに一体的に連結されている。フランジ部材55および連結ブロック60は、相互をボルト締結するための複数の凸部55a、60aを有する。フランジ部材55は、SOFC40と一体化した連結ブロック60と、複数の凸部55a、60aにおいてボルト締結される。フランジ部材55と連結ブロック60との間には、第1~第3の通路部61、62、63を流れるガスをシールするガスケット(図示せず)が介装される。 As shown in FIG. 10, the GPU 50 has a flange member 55 in which manifolds 54a, 54b, 54c of the devices are formed. The flange member 55 is integrally connected to each of the devices 51, 52, and 53 by welding. The flange member 55 and the connection block 60 have a plurality of convex portions 55a and 60a for bolting each other. The flange member 55 is bolted to the connection block 60 integrated with the SOFC 40 and the plurality of convex portions 55a and 60a. Between the flange member 55 and the connection block 60, a gasket (not shown) for sealing the gas flowing through the first to third passage portions 61, 62, 63 is interposed.

 (第1固定部70)
 図11Aおよび図11Bは、SOFC40の他方のエンドプレート109(上部エンドプレート109)側を固定プレート30にリジッド状態に固定する第1固定部70を示す正面図および側面図である。
(First fixing portion 70)
11A and 11B are a front view and a side view showing the first fixing portion 70 that fixes the other end plate 109 (upper end plate 109) side of the SOFC 40 to the fixing plate 30 in a rigid state.

 図3、図11Aおよび図11Bに示すように、発電ユニット10は、SOFC40の上部エンドプレート109(他方のエンドプレート109に相当する)側を固定プレート30にリジッド状態に固定する第1固定部70を有する。第1固定部70は、固定プレート30に対して複数点において固定される第1ブラケット71と、SOFC40の上部エンドプレート109に対して複数点において固定される第2ブラケット72とを有する。第1ブラケット71および第2ブラケット72は一体的に形成され、図11Aに示すようにL字形状を有する。第1ブラケット71は、2点において固定プレート30にボルト締結される(図11B)。第1ブラケット71は、SOFC40から固定プレート30への伝熱を遮断する断熱材31を介して固定される。第2ブラケット72は、4点において上部エンドプレート109にボルト締結される(図11B)。固定する点数は1点とすることができる。だたし、固定点を複数にすることによって、固定点を中心とする回転方向の力に抗することができる。また、固定する多点数は、発電ユニット10に要求される剛性(固有振動数)を考慮して適宜変更できる。 As shown in FIGS. 3, 11A, and 11B, the power generation unit 10 includes a first fixing portion 70 that fixes the upper end plate 109 (corresponding to the other end plate 109) of the SOFC 40 to the fixing plate 30 in a rigid state. Have The first fixing portion 70 includes a first bracket 71 that is fixed to the fixing plate 30 at a plurality of points, and a second bracket 72 that is fixed to the upper end plate 109 of the SOFC 40 at a plurality of points. The first bracket 71 and the second bracket 72 are integrally formed and have an L shape as shown in FIG. 11A. The first bracket 71 is bolted to the fixing plate 30 at two points (FIG. 11B). The first bracket 71 is fixed via a heat insulating material 31 that blocks heat transfer from the SOFC 40 to the fixed plate 30. The second bracket 72 is bolted to the upper end plate 109 at four points (FIG. 11B). The number of points to be fixed can be one point. However, by using a plurality of fixing points, it is possible to resist the force in the rotational direction around the fixing points. Further, the number of points to be fixed can be appropriately changed in consideration of the rigidity (natural frequency) required for the power generation unit 10.

 第1ブラケット71は、ボルト締結に代えて、溶接によって固定プレート30に固定することができる。 The first bracket 71 can be fixed to the fixed plate 30 by welding instead of bolt fastening.

 (第2固定部80)
 図12Aおよび図12Bは、GPU50における機器を固定プレート30にリジッド状態に固定する第2固定部80を示す正面図および側面図である。
(Second fixing portion 80)
12A and 12B are a front view and a side view showing the second fixing portion 80 that fixes the device in the GPU 50 to the fixing plate 30 in a rigid state.

 図3、図12Aおよび図12Bに示すように、発電ユニット10は、GPU50における1つの機器を固定プレート30にリジッド状態に固定する第2固定部80を有する。図示例では、燃料改質器51は、第2固定部80によって固定プレート30にリジッド状態に固定される。第2固定部80は、固定プレート30に対して複数点において固定される第1プレート81と、燃料改質器51の下面側に対して固定される第2プレート82と、第1プレート81と第2プレート82とを連結する支柱83とを有する。第1プレート81、第2プレート82および支柱83は一体的に形成されている。第1プレート81は、4点において固定プレート30にボルト締結される(図3)。第1プレート81は、燃料改質器51から固定プレート30への伝熱を遮断する断熱材31を介して固定される。第2プレート82は、溶接によって燃料改質器51の下面に固定される。また、第1プレート81を固定する多点数は、発電ユニット10に要求される剛性(固有振動数)を考慮して適宜変更できる。 3, FIG. 12A and FIG. 12B, the power generation unit 10 has a second fixing portion 80 that fixes one device in the GPU 50 to the fixing plate 30 in a rigid state. In the illustrated example, the fuel reformer 51 is fixed to the fixed plate 30 in a rigid state by the second fixing portion 80. The second fixing portion 80 includes a first plate 81 that is fixed to the fixing plate 30 at a plurality of points, a second plate 82 that is fixed to the lower surface side of the fuel reformer 51, and a first plate 81 A support 83 for connecting the second plate 82 is provided. The 1st plate 81, the 2nd plate 82, and the support | pillar 83 are integrally formed. The first plate 81 is bolted to the fixed plate 30 at four points (FIG. 3). The first plate 81 is fixed via a heat insulating material 31 that blocks heat transfer from the fuel reformer 51 to the fixed plate 30. The second plate 82 is fixed to the lower surface of the fuel reformer 51 by welding. Further, the multipoint number for fixing the first plate 81 can be appropriately changed in consideration of the rigidity (natural frequency) required for the power generation unit 10.

 第1プレート81は、ボルト締結に代えて、溶接によって固定プレート30に固定することができる。第2プレート82は、溶接に代えて、ボルト締結によって燃料改質器51の下面に固定することができる。 The first plate 81 can be fixed to the fixed plate 30 by welding instead of bolt fastening. The second plate 82 can be fixed to the lower surface of the fuel reformer 51 by bolt fastening instead of welding.

 (変位吸収部90)
 図13Aおよび図13Bは、GPU50の機器52、53における熱膨張に伴う変位を一の方向において吸収する変位吸収部90を示す正面図および側面図である。
(Displacement absorber 90)
FIGS. 13A and 13B are a front view and a side view showing a displacement absorbing portion 90 that absorbs displacement due to thermal expansion in the devices 52 and 53 of the GPU 50 in one direction.

 図3、図13Aおよび図13Bに示すように、発電ユニット10は、GPU50の2つの機器52、53における熱膨張に伴う変位を一の方向において吸収する変位吸収部90を有する。図示例では、触媒燃焼器53は、熱膨張に伴う変位が変位吸収部90によって一の方向において吸収される。熱交換器52は、熱膨張に伴う変位が変位吸収部90によって一の方向において吸収される。変位吸収部90は、機器52、53の一の方向に沿う変位をガイドするスライダー91を有する。スライダー91は、固定プレート30に対して固定される一対の支持脚92と、一対の支持脚92に連結されたガイドシャフト93と、機器(触媒燃焼器53および熱交換器52)の下面側に対して固定されるガイドブラケット94とを有する。一対の支持脚92は、熱膨張を吸収する一の方向に沿って離間する。ガイドシャフト93は、熱膨張を吸収する一の方向に沿って伸びている。ガイドシャフト93は、ガイドブラケット94を挿通して一対の支持脚92に連結される。支持脚92のそれぞれは、2点において固定プレート30にボルト締結される(図3)。支持脚92のそれぞれは、機器(触媒燃焼器53および熱交換器52)から固定プレート30への伝熱を遮断する断熱材31を介して固定される。ガイドブラケット94は、溶接によって機器(触媒燃焼器53および熱交換器52)の下面に固定される。 As shown in FIG. 3, FIG. 13A and FIG. 13B, the power generation unit 10 has a displacement absorbing portion 90 that absorbs displacement due to thermal expansion in the two devices 52 and 53 of the GPU 50 in one direction. In the illustrated example, in the catalytic combustor 53, the displacement accompanying thermal expansion is absorbed in one direction by the displacement absorbing unit 90. In the heat exchanger 52, the displacement accompanying the thermal expansion is absorbed in one direction by the displacement absorbing unit 90. The displacement absorbing unit 90 includes a slider 91 that guides displacement along one direction of the devices 52 and 53. The slider 91 is provided on a lower surface side of a pair of support legs 92 fixed to the fixed plate 30, a guide shaft 93 connected to the pair of support legs 92, and devices (catalyst combustor 53 and heat exchanger 52). And a guide bracket 94 fixed to the opposite side. The pair of support legs 92 are separated along one direction in which thermal expansion is absorbed. The guide shaft 93 extends along one direction that absorbs thermal expansion. The guide shaft 93 is connected to the pair of support legs 92 through the guide bracket 94. Each of the support legs 92 is bolted to the fixing plate 30 at two points (FIG. 3). Each of the support legs 92 is fixed via a heat insulating material 31 that blocks heat transfer from the devices (catalyst combustor 53 and heat exchanger 52) to the fixed plate 30. The guide bracket 94 is fixed to the lower surface of the equipment (catalyst combustor 53 and heat exchanger 52) by welding.

 支持脚92のそれぞれは、ボルト締結に代えて、溶接によって固定プレート30に固定することができる。ガイドブラケット94は、溶接に代えて、ボルト締結によって機器(触媒燃焼器53および熱交換器52)の下面に固定することができる。 Each of the support legs 92 can be fixed to the fixing plate 30 by welding instead of bolt fastening. The guide bracket 94 can be fixed to the lower surface of the device (catalyst combustor 53 and heat exchanger 52) by bolt fastening instead of welding.

 変位吸収部90は、熱膨張に伴う変位を特定の一の方向において吸収する。ここに、一の方向は、水平方向、かつ、SOFC40とGPU50とが向かい合う方向である。一の方向は、車体において左右方向である。 The displacement absorber 90 absorbs the displacement accompanying the thermal expansion in a specific direction. Here, one direction is a horizontal direction and a direction in which the SOFC 40 and the GPU 50 face each other. One direction is the left-right direction in the vehicle body.

 なお、固定プレート30を車体に接続する形態によっては、一の方向を、車体において前後方向に設定することができる。 In addition, depending on the form in which the fixed plate 30 is connected to the vehicle body, one direction can be set to the front-rear direction in the vehicle body.

 連結ブロック60、第1固定部70および第2固定部80の形成材料は、固定プレート30の形成材料と同じである。形成材料は、例えば、ステンレス材料である。SOFC40の下部エンドプレート108および上部エンドプレート109の形成材料も、固定プレート30の形成材料と同じとすることができる。 The forming material of the connection block 60, the first fixing portion 70, and the second fixing portion 80 is the same as the forming material of the fixing plate 30. The forming material is, for example, a stainless material. The material for forming the lower end plate 108 and the upper end plate 109 of the SOFC 40 may be the same as the material for forming the fixed plate 30.

 固定プレート30の形成材料と、各マウント(連結ブロック60、第1固定部70および第2固定部80)の形成材料とが同種材であるため、熱膨張による応力を低減することができる。このため、変位吸収機能の仕様を簡素化できる。 Since the forming material of the fixing plate 30 and the forming material of each mount (the connecting block 60, the first fixing portion 70, and the second fixing portion 80) are the same material, the stress due to thermal expansion can be reduced. For this reason, the specification of a displacement absorption function can be simplified.

 (作用)
 第1実施形態の作用を説明する。第1実施形態の発電ユニット10は、SOFC40およびGPU50が連結ブロック60を介してリジッド状態に連結される。この状態において、SOFC40は、上部エンドプレート109側において第1固定部70によって固定プレート30にリジッド状態に固定される。GPU50の燃料改質器51は、第2固定部80によって固定プレート30にリジッド状態に固定される。発電ユニット10の稼働時において、SOFC40およびGPU50の各機器51、52、53は高温となる。GPU50における機器(触媒燃焼器53および熱交換器52)は、スライダー91を有する変位吸収部90によって、熱膨張に伴う変位が一の方向にガイドされて吸収される。
(Function)
The operation of the first embodiment will be described. In the power generation unit 10 of the first embodiment, the SOFC 40 and the GPU 50 are connected in a rigid state via the connection block 60. In this state, the SOFC 40 is fixed to the fixed plate 30 in a rigid state by the first fixing portion 70 on the upper end plate 109 side. The fuel reformer 51 of the GPU 50 is fixed to the fixed plate 30 in a rigid state by the second fixing unit 80. When the power generation unit 10 is in operation, the devices 51, 52, and 53 of the SOFC 40 and the GPU 50 are at a high temperature. In the GPU 50 (the catalyst combustor 53 and the heat exchanger 52), the displacement accompanying the thermal expansion is guided and absorbed in one direction by the displacement absorbing portion 90 having the slider 91.

 発電ユニット10は、車体に接続される固定プレート30上に保持されているため、走行に伴う振動が入力される。リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50が、第1固定部70および第2固定部80によって固定プレート30にリジッド状態に固定される。このため、発電ユニット10の固有振動数が上昇し、共振周波数が上昇する。この結果、発電ユニット10の固有振動数が、路面負荷入力の大きい周波数域(50Hz未満)から外れ(上昇し)、走行に伴う振動が発電ユニット10の作動に悪影響を及ぼすことを抑えることができる。 Since the power generation unit 10 is held on the fixed plate 30 connected to the vehicle body, vibration associated with traveling is input. The SOFC 40, the connection block 60, and the GPU 50 that are connected in the rigid state are fixed to the fixed plate 30 in the rigid state by the first fixing unit 70 and the second fixing unit 80. For this reason, the natural frequency of the power generation unit 10 increases, and the resonance frequency increases. As a result, it is possible to suppress the natural frequency of the power generation unit 10 from deviating (increasing) from the frequency range (less than 50 Hz) where the road load input is large, and the vibration caused by traveling adversely affecting the operation of the power generation unit 10. .

 発電ユニット10の固有振動数が上昇するため、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50の剛性を向上させることができる。 Since the natural frequency of the power generation unit 10 increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state can be improved.

 スライダー91を有する変位吸収部90は、GPU50における機器(触媒燃焼器53および熱交換器52)の熱膨張に伴う変位を一の方向にガイドして吸収する。このため、GPU50の各機器51、52、53が熱膨張しても、熱膨張による応力を低減することができる。 The displacement absorbing portion 90 having the slider 91 guides and absorbs the displacement accompanying the thermal expansion of the devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50 in one direction. For this reason, even if each apparatus 51,52,53 of GPU50 is thermally expanded, the stress by thermal expansion can be reduced.

 連結ブロック60は、SOFC40のマニホールド41a、41b、41cおよびGPU50の各機器51、52、53のマニホールド54a、54b、54cを一体化している。これによりSOFC40とGPU50との間の寸法を小さくでき、発電ユニット10の全体を小型化することができる。 The connection block 60 integrates manifolds 41a, 41b, 41c of the SOFC 40 and manifolds 54a, 54b, 54c of the devices 51, 52, 53 of the GPU 50. Thereby, the dimension between SOFC40 and GPU50 can be made small, and the whole power generation unit 10 can be reduced in size.

 図14は、発電ユニット10の稼働時において、SOFC40が熱膨張するときの作用を模式的に示す図である。 FIG. 14 is a diagram schematically showing an action when the SOFC 40 thermally expands during operation of the power generation unit 10.

 発電ユニット10には、SOFC40の熱膨張を吸収する構造を備えていない。しかしながら、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50は、少なくとも3点以上の固定点が設けられている。これによって、1次の固有振動数は十分な剛性を確保できる。また、SOFC40のような積層体においては、積層間の面圧感度は、1次モードに特に大きく影響する。下部エンドプレート108の剛性を連結ブロック60と一体化して高めることによって、クリープ寿命の成立する範囲において荷重を高めることによって耐振性を上げることができる。両集電板内は、膨張時に圧縮応力となるため、クリープの発生を抑制する。 The power generation unit 10 does not have a structure that absorbs the thermal expansion of the SOFC 40. However, the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are provided with at least three fixed points. Thereby, the primary natural frequency can ensure sufficient rigidity. Further, in a laminated body such as SOFC 40, the surface pressure sensitivity between the laminated layers particularly affects the primary mode. By increasing the rigidity of the lower end plate 108 integrally with the connecting block 60, the vibration resistance can be improved by increasing the load within the range in which the creep life is established. The inside of both current collector plates becomes a compressive stress during expansion, thereby suppressing the occurrence of creep.

 SOFC40の熱膨張を吸収する構造を設けず、マウント数を必要最小限のものとすることによって、発電ユニット10の全体を小型化することができる。 By not providing a structure for absorbing the thermal expansion of the SOFC 40 and minimizing the number of mounts, the entire power generation unit 10 can be reduced in size.

 以上説明したように、第1実施形態の発電ユニット10は、車体に接続される固定プレート30上に保持される発電ユニット10であって、SOFC40と、GPU50とを有する。発電ユニット10は、SOFC40の下部エンドプレート108側に形成されたマニホールド41a、41b、41cとGPU50における機器のそれぞれのマニホールド54a、54b、54cとを一体的に連結する連結ブロック60を有する。発電ユニット10は、SOFC40の上部エンドプレート109側を固定プレート30にリジッド状態に固定する第1固定部70を有する。発電ユニット10は、GPU50における燃料改質器51を固定プレート30にリジッド状態に固定する第2固定部80を有する。発電ユニット10は、GPU50における機器(触媒燃焼器53および熱交換器52)の熱膨張に伴う変位(伸び)を一の方向において吸収する変位吸収部90を有する。 As described above, the power generation unit 10 according to the first embodiment is the power generation unit 10 held on the fixed plate 30 connected to the vehicle body, and includes the SOFC 40 and the GPU 50. The power generation unit 10 includes a connection block 60 that integrally connects the manifolds 41a, 41b, and 41c formed on the lower end plate 108 side of the SOFC 40 and the manifolds 54a, 54b, and 54c of the equipment in the GPU 50. The power generation unit 10 includes a first fixing portion 70 that fixes the upper end plate 109 side of the SOFC 40 to the fixing plate 30 in a rigid state. The power generation unit 10 includes a second fixing unit 80 that fixes the fuel reformer 51 in the GPU 50 to the fixed plate 30 in a rigid state. The power generation unit 10 includes a displacement absorbing unit 90 that absorbs in one direction a displacement (elongation) associated with thermal expansion of the devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50.

 このように構成することによって、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50が、第1固定部70および第2固定部80によって固定プレート30にリジッド状態に固定される。このため、発電ユニット10の固有振動数が上昇し、共振周波数が上昇する。この結果、発電ユニット10の固有振動数が、路面負荷入力の大きい周波数域から外れ(上昇し)、走行に伴う振動が発電ユニット10の作動に悪影響を及ぼすことを抑えることができる。発電ユニット10の固有振動数が上昇するため、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50の剛性が向上する。GPU50における機器(触媒燃焼器53および熱交換器52)の熱膨張に伴う変位が変位吸収部90によって一の方向において吸収されるため、GPU50の各機器51、52、53が熱膨張しても、熱膨張による応力を低減することができる。したがって、第1実施形態によれば、固有振動数を上昇させ、かつ、熱膨張による変位を吸収可能な発電ユニット10を提供できる。 With this configuration, the SOFC 40, the connection block 60, and the GPU 50 connected in a rigid state are fixed in a rigid state to the fixed plate 30 by the first fixing unit 70 and the second fixing unit 80. For this reason, the natural frequency of the power generation unit 10 increases, and the resonance frequency increases. As a result, it is possible to suppress the natural frequency of the power generation unit 10 from deviating (rising) from the frequency range where the road surface load input is large, and the vibration accompanying the traveling adversely affecting the operation of the power generation unit 10. Since the natural frequency of the power generation unit 10 increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state is improved. Since displacement due to thermal expansion of the devices (catalyst combustor 53 and heat exchanger 52) in the GPU 50 is absorbed in one direction by the displacement absorbing unit 90, each device 51, 52, 53 of the GPU 50 is thermally expanded. The stress due to thermal expansion can be reduced. Therefore, according to the first embodiment, it is possible to provide the power generation unit 10 that can increase the natural frequency and absorb the displacement due to thermal expansion.

 さらに、連結ブロック60によって、SOFC40のマニホールド41a、41b、41cおよびGPU50の各機器のマニホールド54a、54b、54cが一体化するため、SOFC40とGPU50との間の寸法を小さくでき、発電ユニット10の全体を小型化することができる。また、マウント数を必要最小限のものとすることができ、この点からも発電ユニット10の全体を小型化することができる。 Furthermore, since the manifolds 41a, 41b, 41c of the SOFC 40 and the manifolds 54a, 54b, 54c of each device of the GPU 50 are integrated by the connecting block 60, the dimension between the SOFC 40 and the GPU 50 can be reduced, and the entire power generation unit 10 can be reduced. Can be miniaturized. In addition, the number of mounts can be minimized, and from this point, the entire power generation unit 10 can be downsized.

 連結ブロック60は、SOFC40の一方のエンドプレート108側に形成されたマニホールド41a、41b、41cと、GPU50における機器のそれぞれのマニホールド54a、54b、54cとを連通する第1~第3の通路部61、62、63が形成されたブロック形状を有し、一方のエンドプレート108に第1~第3の通路部61、62、63の内部から溶接接合され一体化されている。SOFC40は、連結ブロック60が一体化された一方のエンドプレート108にセルユニット100を積層して形成される。 The connection block 60 includes first to third passage portions 61 that connect the manifolds 41a, 41b, and 41c formed on one end plate 108 side of the SOFC 40 and the manifolds 54a, 54b, and 54c of the equipment in the GPU 50. , 62, 63 are formed in a block shape, and are welded and joined to one end plate 108 from the inside of the first to third passage portions 61, 62, 63. The SOFC 40 is formed by stacking the cell unit 100 on one end plate 108 in which the connection block 60 is integrated.

 このように構成することによって、SOFC40にGPU50を簡単に一体化させることができる。 This configuration allows the GPU 50 to be easily integrated into the SOFC 40.

 第1固定部70は、固定プレート30に対して複数点において固定される第1ブラケット71を有する。 The first fixing part 70 has a first bracket 71 fixed to the fixing plate 30 at a plurality of points.

 このように構成することによって、SOFC40の固有振動数を高めることができる。 This configuration makes it possible to increase the natural frequency of the SOFC 40.

 第1固定部70は、SOFC40の下部エンドプレート108に対して複数点において固定される第2ブラケット72を有する。 The first fixing unit 70 has second brackets 72 that are fixed to the lower end plate 108 of the SOFC 40 at a plurality of points.

 このように構成することによって、SOFC40の固有振動数を高めることができる。 This configuration makes it possible to increase the natural frequency of the SOFC 40.

 変位吸収部90は、GPU50における機器(触媒燃焼器53および熱交換器52)の一の方向に沿う変位をガイドするスライダー91を有する。 The displacement absorbing unit 90 has a slider 91 that guides displacement along one direction of the devices (catalytic combustor 53 and heat exchanger 52) in the GPU 50.

 このように構成することによって、GPU50における機器(触媒燃焼器53および熱交換器52)の熱膨張に伴う変位(伸び)がスライダー91によってガイドされて一の方向において吸収される。この結果、熱膨張による応力を低減することができる。 With this configuration, the displacement (elongation) associated with the thermal expansion of the equipment (catalytic combustor 53 and heat exchanger 52) in the GPU 50 is guided by the slider 91 and absorbed in one direction. As a result, stress due to thermal expansion can be reduced.

 一の方向は、水平方向、かつ、SOFC40とGPU50とが向かい合う方向である。 One direction is the horizontal direction and the direction in which the SOFC 40 and the GPU 50 face each other.

 このように構成することによって、GPU50における機器(触媒燃焼器53および熱交換器52)の熱膨張に伴う変位(伸び)を効果的に吸収できる。また、水平方向に吸収するので、吸収するためのスペースを垂直方向に設定する場合に比べて車室内空間を狭くすることがない。 With this configuration, it is possible to effectively absorb displacement (elongation) associated with thermal expansion of the devices (catalytic combustor 53 and heat exchanger 52) in the GPU 50. Moreover, since it absorbs in a horizontal direction, compared with the case where the space for absorption is set to the vertical direction, a vehicle interior space is not narrowed.

 連結ブロック60、第1固定部70および第2固定部80の形成材料は、固定プレート30の形成材料と同じである。 The forming material of the connection block 60, the first fixing portion 70, and the second fixing portion 80 is the same as the forming material of the fixing plate 30.

 このように構成することによって、固定プレート30の形成材料と、各マウント(連結ブロック60、第1固定部70および第2固定部80)の形成材料とが同種材であるため、熱膨張による応力を低減することができる。このため、変位吸収機能の仕様を簡素化できる。 With this configuration, since the forming material of the fixing plate 30 and the forming material of each mount (the connecting block 60, the first fixing portion 70, and the second fixing portion 80) are the same kind of material, stress due to thermal expansion Can be reduced. For this reason, the specification of a displacement absorption function can be simplified.

 (第1固定部70の変形例)
 図15は、第1固定部70の変形例を示す側面図である。
(Modification of the 1st fixing | fixed part 70)
FIG. 15 is a side view showing a modified example of the first fixing portion 70.

 第1実施形態において、第1固定部70は、SOFC40の上部エンドプレート109に対して複数点(4点)においてボルト締結して固定される第2ブラケット72を有している(図11B)。第1固定部70はこの場合に限定されるものではない。 In the first embodiment, the first fixing part 70 has a second bracket 72 that is bolted and fixed to the upper end plate 109 of the SOFC 40 at a plurality of points (four points) (FIG. 11B). The first fixing unit 70 is not limited to this case.

 図15に示すように、変形例の第1固定部70は、SOFC40の上部エンドプレート109に対して溶接73によって固定される第2ブラケット72を有している。第2ブラケット72は、上部エンドプレート109の面を抑えるように接触され、外周部72aを溶接接合によって固定されている。第2ブラケット72の大きさは上部エンドプレート109の面を最大に抑えることができる大きさに設定する。外周部72aを溶接接合することは、連続する複数点において固定することに相当する。このため、SOFC40の固有振動数をより高めることができる。 As shown in FIG. 15, the modified first fixing portion 70 has a second bracket 72 fixed to the upper end plate 109 of the SOFC 40 by welding 73. The second bracket 72 is contacted so as to suppress the surface of the upper end plate 109, and the outer peripheral portion 72a is fixed by welding. The size of the second bracket 72 is set to a size that can suppress the surface of the upper end plate 109 to the maximum. Welding the outer peripheral portion 72a is equivalent to fixing at a plurality of continuous points. For this reason, the natural frequency of the SOFC 40 can be further increased.

 以上説明したように、変形例の第2ブラケット72は、SOFC40の上部エンドプレート109に対して溶接73によって固定される。 As described above, the modified second bracket 72 is fixed to the upper end plate 109 of the SOFC 40 by welding 73.

 このように構成することによって、SOFC40の固有振動数をより高めることができる。 This configuration can further increase the natural frequency of the SOFC 40.

 (第2固定部80および変位吸収部90の改変について)
 第2固定部80は、GPU50における少なくとも1つの機器51、52、53および連結ブロック60の少なくとも一方を固定プレート30にリジッド状態に固定するものであれば足りる。さらに、変位吸収部90は、GPU50における機器51、52、53の熱膨張に伴う変位を一の方向において吸収するものであれば足りる。発電ユニット10の固有振動数を上昇させ、かつ、熱膨張による変位を吸収できるようにするという作用効果を発揮できる限りにおいて、第2固定部80および変位吸収部90の構成を適宜変更できる。具体的には、第2固定部80によって何れの部位を固定プレート30にリジッド状態に固定するのか、変位吸収部90によってGPU50における何れの機器の熱膨張による変位を吸収するのかは、上記の作用効果を発揮できる限りにおいて適宜変更できる。以下、第2~第4の実施形態を説明する。
(About modification of the second fixing portion 80 and the displacement absorbing portion 90)
The second fixing unit 80 only needs to fix at least one of the at least one device 51, 52, 53 and the connection block 60 in the GPU 50 to the fixing plate 30 in a rigid state. Furthermore, the displacement absorption part 90 should just be what can absorb the displacement accompanying the thermal expansion of apparatus 51,52,53 in GPU50 in one direction. The configuration of the second fixed portion 80 and the displacement absorbing portion 90 can be changed as appropriate as long as the effect of increasing the natural frequency of the power generation unit 10 and absorbing the displacement due to thermal expansion can be exhibited. Specifically, which part is fixed to the fixed plate 30 in a rigid state by the second fixing unit 80 and which displacement due to thermal expansion of the GPU 50 is absorbed by the displacement absorbing unit 90 depends on the above-described action. As long as the effect can be exhibited, it can be appropriately changed. Hereinafter, the second to fourth embodiments will be described.

 (第2実施形態)
 図16および図17は、第2実施形態の発電ユニット10Aを示す上面図および正面図である。
(Second Embodiment)
16 and 17 are a top view and a front view showing the power generation unit 10A of the second embodiment.

 図16および図17に示すように、第2実施形態の発電ユニット10Aは、第2固定部80によって連結ブロック60を固定プレート30にリジッド状態に固定している。この点において、第2固定部80がGPU50における1つの機器(燃料改質器51)を固定プレート30にリジッド状態に固定している第1実施形態と相違する。また、GPU50におけるすべての機器(燃料改質器51、触媒燃焼器53および熱交換器52)は、スライダー91を有する変位吸収部90を有する。この点において、GPU50における1つの機器(燃料改質器51)を固定プレート30にリジッド状態に固定した第1実施形態と相違する。 As shown in FIGS. 16 and 17, in the power generation unit 10 </ b> A of the second embodiment, the connection block 60 is fixed to the fixed plate 30 in a rigid state by the second fixing portion 80. In this respect, the second fixing unit 80 is different from the first embodiment in which one device (the fuel reformer 51) in the GPU 50 is fixed to the fixing plate 30 in a rigid state. Further, all the devices (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) in the GPU 50 have a displacement absorbing unit 90 having a slider 91. This is different from the first embodiment in which one device (fuel reformer 51) in the GPU 50 is fixed to the fixed plate 30 in a rigid state.

 第2実施形態において、第2固定部80は、連結ブロック60を固定プレート30に対して固定するフランジ部84を有する。フランジ部84は、溶接によって固定プレート30にリジッド状態に固定される。フランジ部84は、溶接に代えてボルト締結によって固定プレート30にリジッド状態に固定することができる。GPU50におけるすべての機器51、52、53は、直接的には、固定プレート30にリジッド状態に固定されていない。しかしながら、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50は、SOFC40が第1固定部70によって固定プレート30にリジッド状態に固定され、連結ブロック60が第2固定部80によって固定プレート30にリジッド状態に固定される。このため、発電ユニット10Aの固有振動数を十分に上昇させることができる。 In the second embodiment, the second fixing portion 80 has a flange portion 84 that fixes the connection block 60 to the fixing plate 30. The flange portion 84 is fixed to the fixed plate 30 in a rigid state by welding. The flange portion 84 can be fixed to the fixed plate 30 in a rigid state by bolt fastening instead of welding. All the devices 51, 52, 53 in the GPU 50 are not directly fixed to the fixed plate 30 in a rigid state. However, the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are rigidly fixed to the fixed plate 30 by the first fixing unit 70, and the connection block 60 is rigidly fixed to the fixed plate 30 by the second fixing unit 80. Fixed to state. For this reason, the natural frequency of the power generation unit 10A can be sufficiently increased.

 GPU50におけるすべての機器(燃料改質器51、触媒燃焼器53および熱交換器52)は、スライダー91を有する変位吸収部90を有する。燃料改質器51、触媒燃焼器53および熱交換器52のそれぞれは、スライダー91を有する変位吸収部90によって、熱膨張に伴う変位が一の方向にガイドされて吸収される。 All devices in the GPU 50 (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) have a displacement absorbing portion 90 having a slider 91. In each of the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52, the displacement accompanying the thermal expansion is guided and absorbed in one direction by the displacement absorbing portion 90 having the slider 91.

 第2実施形態の作用を説明する。発電ユニット10Aは、車体に接続される固定プレート30上に保持されているため、走行に伴う振動が入力される。リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50は、SOFC40が第1固定部70によって固定プレート30にリジッド状態に固定され、連結ブロック60が第2固定部80によって固定プレート30にリジッド状態に固定されている。このため、発電ユニット10Aの固有振動数が上昇し、共振周波数が上昇する。この結果、発電ユニット10Aの固有振動数が、路面負荷入力の大きい周波数域から外れ(上昇し)、走行に伴う振動が発電ユニット10Aの作動に悪影響を及ぼすことを抑えることができる。 The operation of the second embodiment will be described. Since the power generation unit 10A is held on the fixed plate 30 connected to the vehicle body, vibration associated with traveling is input. The SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are fixed in a rigid state to the fixed plate 30 by the first fixing unit 70, and the connection block 60 is fixed to the fixed plate 30 by the second fixing unit 80. It is fixed. For this reason, the natural frequency of the power generation unit 10A increases and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10A deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10A.

 発電ユニット10Aの固有振動数が上昇するため、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50の剛性を向上させることができる。 Since the natural frequency of the power generation unit 10A increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state can be improved.

 スライダー91を有する変位吸収部90は、GPU50における機器(燃料改質器51、触媒燃焼器53および熱交換器52)の熱膨張に伴う変位を一の方向にガイドして吸収する。このため、GPU50の各機器が熱膨張しても、熱膨張による応力を低減することができる。 The displacement absorbing unit 90 having the slider 91 guides and absorbs the displacement accompanying the thermal expansion of the devices (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) in the GPU 50 in one direction. For this reason, even if each apparatus of GPU50 thermally expands, the stress by thermal expansion can be reduced.

 以上説明したように、第2実施形態の発電ユニット10Aは、第2固定部80によって連結ブロック60を固定プレート30にリジッド状態に固定する。GPU50におけるすべての機器(燃料改質器51、触媒燃焼器53および熱交換器52)は変位吸収部90を有する。 As described above, the power generation unit 10 </ b> A of the second embodiment fixes the connection block 60 to the fixed plate 30 in the rigid state by the second fixing portion 80. All the devices in the GPU 50 (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) have a displacement absorbing unit 90.

 このように構成することによって、第1実施形態の発電ユニット10Aと同様の作用効果を奏する。すなわち、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50は、SOFC40が第1固定部70によって固定プレート30にリジッド状態に固定され、連結ブロック60が第2固定部80によって固定プレート30にリジッド状態に固定される。このため、発電ユニット10Aの固有振動数が上昇し、共振周波数が上昇する。この結果、発電ユニット10Aの固有振動数が、路面負荷入力の大きい周波数域から外れ(上昇し)、走行に伴う振動が発電ユニット10Aの作動に悪影響を及ぼすことを抑えることができる。発電ユニット10Aの固有振動数が上昇するため、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50の剛性が向上する。GPU50における機器(燃料改質器51、触媒燃焼器53および熱交換器52)の熱膨張に伴う変位が変位吸収部90によって一の方向において吸収されるため、GPU50の各機器が熱膨張しても、熱膨張による応力を低減することができる。 This configuration provides the same operational effects as the power generation unit 10A of the first embodiment. That is, the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are rigidly fixed to the fixed plate 30 by the first fixing unit 70 and the connection block 60 is rigidly fixed to the fixed plate 30 by the second fixing unit 80. Fixed to state. For this reason, the natural frequency of the power generation unit 10A increases and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10A deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10A. Since the natural frequency of the power generation unit 10A increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 connected in a rigid state is improved. Since the displacement associated with the thermal expansion of the devices (fuel reformer 51, catalytic combustor 53, and heat exchanger 52) in the GPU 50 is absorbed in one direction by the displacement absorber 90, each device of the GPU 50 is thermally expanded. Also, stress due to thermal expansion can be reduced.

 (第3実施形態)
 図18および図19は、第3実施形態の発電ユニット10Bを示す上面図および正面図である。
(Third embodiment)
18 and 19 are a top view and a front view showing the power generation unit 10B of the third embodiment.

 第3実施形態は、変位吸収部90の構成を改変した点において、第1実施形態および第2実施形態と相違する。 The third embodiment is different from the first embodiment and the second embodiment in that the configuration of the displacement absorber 90 is modified.

 図18および図19に示すように、第3実施形態の発電ユニット10Bは、第1実施形態と同様に、SOFC40が第1固定部70によって固定プレート30にリジッド状態に固定され、GPU50における1つの機器(燃料改質器51)が第2固定部80によって固定プレート30にリジッド状態に固定されている。また、第1実施形態と同様に、GPU50における2つの機器(触媒燃焼器53および熱交換器52)は、スライダー91を有する変位吸収部90を有する。触媒燃焼器53および熱交換器52のそれぞれは、スライダー91を有する変位吸収部90によって、熱膨張に伴う変位が一の方向にガイドされて吸収される。 As shown in FIGS. 18 and 19, in the power generation unit 10 </ b> B of the third embodiment, as in the first embodiment, the SOFC 40 is rigidly fixed to the fixed plate 30 by the first fixing portion 70. The device (fuel reformer 51) is fixed to the fixed plate 30 in a rigid state by the second fixing portion 80. Similarly to the first embodiment, the two devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50 have a displacement absorbing unit 90 having a slider 91. In each of the catalytic combustor 53 and the heat exchanger 52, the displacement accompanying the thermal expansion is guided and absorbed in one direction by the displacement absorbing portion 90 having the slider 91.

 第3実施形態ではさらに、変位吸収部90は、GPU50における機器(燃料改質器51および熱交換器52)の機器本体56a、56bと当該機器51、52のマニホールド54a、54bとの間に配置され一の方向に沿って伸縮するベローズ部材95を有する。熱交換器52については、スライダー91を有する変位吸収部90およびベローズ部材95を有する変位吸収部90の両者によって、熱膨張に伴う変位が一の方向において吸収される。 Further, in the third embodiment, the displacement absorbing unit 90 is disposed between the equipment bodies 56a and 56b of the equipment (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 and the manifolds 54a and 54b of the equipment 51 and 52. And a bellows member 95 that expands and contracts along one direction. With respect to the heat exchanger 52, the displacement due to thermal expansion is absorbed in one direction by both the displacement absorbing portion 90 having the slider 91 and the displacement absorbing portion 90 having the bellows member 95.

 第3実施形態の作用を説明する。発電ユニット10Bは、車体に接続される固定プレート30上に保持されているため、走行に伴う振動が入力される。リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50は、SOFC40が第1固定部70によって固定プレート30にリジッド状態に固定され、GPU50における1つの機器(燃料改質器51)が第2固定部80によって固定プレート30にリジッド状態に固定されている。このため、発電ユニット10Bの固有振動数が上昇し、共振周波数が上昇する。この結果、発電ユニット10Bの固有振動数が、路面負荷入力の大きい周波数域から外れ(上昇し)、走行に伴う振動が発電ユニット10Bの作動に悪影響を及ぼすことを抑えることができる。 The operation of the third embodiment will be described. Since the power generation unit 10B is held on the fixed plate 30 connected to the vehicle body, vibration associated with traveling is input. In the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state, the SOFC 40 is fixed in a rigid state to the fixed plate 30 by the first fixing unit 70, and one device (the fuel reformer 51) in the GPU 50 is the second fixing unit. 80 is fixed to the fixed plate 30 in a rigid state. For this reason, the natural frequency of the power generation unit 10B increases and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10B deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10B.

 発電ユニット10Bの固有振動数が上昇するため、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50の剛性を向上させることができる。 Since the natural frequency of the power generation unit 10B increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state can be improved.

 スライダー91を有する変位吸収部90は、GPU50における機器(触媒燃焼器53および熱交換器52)の熱膨張に伴う変位を一の方向にガイドして吸収する。また、ベローズ部材95を有する変位吸収部90は、GPU50における機器(燃料改質器51および熱交換器52)の熱膨張に伴う変位を一の方向に伸縮して吸収する。このため、GPU50の各機器が熱膨張しても、熱膨張による応力を低減することができる。 The displacement absorbing portion 90 having the slider 91 guides and absorbs the displacement accompanying the thermal expansion of the devices (the catalytic combustor 53 and the heat exchanger 52) in the GPU 50 in one direction. Moreover, the displacement absorption part 90 which has the bellows member 95 expands-contracts and absorbs the displacement accompanying the thermal expansion of the apparatus (fuel reformer 51 and the heat exchanger 52) in GPU50 in one direction. For this reason, even if each apparatus of GPU50 thermally expands, the stress by thermal expansion can be reduced.

 以上説明したように、第3実施形態の発電ユニット10Bは、変位吸収部90は、GPU50における機器(燃料改質器51および熱交換器52)の機器本体と当該機器のマニホールドとの間に配置され一の方向に沿って伸縮するベローズ部材95を有する。 As described above, in the power generation unit 10B of the third embodiment, the displacement absorbing unit 90 is disposed between the equipment body of the equipment (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 and the manifold of the equipment. And a bellows member 95 that expands and contracts along one direction.

 このように構成することによって、第1実施形態の発電ユニット10Bと同様の作用効果を奏する。すなわち、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50は、SOFC40が第1固定部70によって固定プレート30にリジッド状態に固定され、GPU50における機器(燃料改質器51)が第2固定部80によって固定プレート30にリジッド状態に固定される。このため、発電ユニット10Bの固有振動数が上昇し、共振周波数が上昇する。この結果、発電ユニット10Bの固有振動数が、路面負荷入力の大きい周波数域から外れ(上昇し)、走行に伴う振動が発電ユニット10Bの作動に悪影響を及ぼすことを抑えることができる。発電ユニット10Bの固有振動数が上昇するため、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50の剛性が向上する。GPU50における機器(触媒燃焼器53および熱交換器52)の熱膨張に伴う変位(伸び)がスライダー91によってガイドされて一の方向において吸収される。また、GPU50における機器(燃料改質器51および熱交換器52)の熱膨張に伴う変位(伸び)がベローズ部材95の伸縮によって一の方向において吸収される。この結果、熱膨張による応力を低減することができる。 By configuring in this way, the same effects as the power generation unit 10B of the first embodiment can be obtained. That is, the SOFC 40, the connection block 60, and the GPU 50 that are connected in the rigid state are fixed in the rigid state to the fixed plate 30 by the first fixing unit 70, and the device (fuel reformer 51) in the GPU 50 is the second fixing unit. 80 is fixed to the fixing plate 30 in a rigid state. For this reason, the natural frequency of the power generation unit 10B increases and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10B deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10B. Since the natural frequency of the power generation unit 10B increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state is improved. Displacement (elongation) accompanying thermal expansion of the equipment (catalytic combustor 53 and heat exchanger 52) in the GPU 50 is guided by the slider 91 and absorbed in one direction. Further, the displacement (elongation) associated with the thermal expansion of the devices (fuel reformer 51 and heat exchanger 52) in the GPU 50 is absorbed in one direction by the expansion and contraction of the bellows member 95. As a result, stress due to thermal expansion can be reduced.

 (第4実施形態)
 図20および図21は、第4実施形態の発電ユニット10Cを示す上面図および正面図である。
(Fourth embodiment)
20 and 21 are a top view and a front view showing the power generation unit 10C of the fourth embodiment.

 第2固定部80は、GPU50における少なくとも1つの機器および連結ブロック60の少なくとも一方を固定プレート30にリジッド状態に固定するものであれば足りる。 The second fixing unit 80 only needs to fix at least one of the GPU 50 and at least one of the connecting blocks 60 to the fixing plate 30 in a rigid state.

 図20および図21に示すように、第4実施形態の発電ユニット10Cは、第2固定部80によって、GPU50におけるすべての機器(燃料改質器51、触媒燃焼器53および熱交換器52)および連結ブロック60の両者を固定プレート30にリジッド状態に固定している。 As shown in FIGS. 20 and 21, the power generation unit 10 </ b> C of the fourth embodiment includes all the devices (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) in the GPU 50 by the second fixing unit 80. Both of the connecting blocks 60 are fixed to the fixing plate 30 in a rigid state.

 第4実施形態では、変位吸収部90は、GPU50における機器(燃料改質器51および熱交換器52)の機器本体56a、56bと当該機器51、52のマニホールド54a、54bとの間に配置され一の方向に沿って伸縮するベローズ部材95を有する。 In the fourth embodiment, the displacement absorbing unit 90 is disposed between the equipment bodies 56a and 56b of the equipment (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 and the manifolds 54a and 54b of the equipment 51 and 52. It has a bellows member 95 that expands and contracts along one direction.

 第4実施形態の作用を説明する。発電ユニット10Cは、車体に接続される固定プレート30上に保持されているため、走行に伴う振動が入力される。リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50は、SOFC40が第1固定部70によって固定プレート30にリジッド状態に固定され、連結ブロック60が第2固定部80によって固定プレート30にリジッド状態に固定され、GPU50におけるすべての機器(燃料改質器51、触媒燃焼器53および熱交換器52)が第2固定部80によって固定プレート30にリジッド状態に固定されている。このため、発電ユニット10Cの固有振動数が上昇し、共振周波数が上昇する。この結果、発電ユニット10Cの固有振動数が、路面負荷入力の大きい周波数域から外れ(上昇し)、走行に伴う振動が発電ユニット10Cの作動に悪影響を及ぼすことを抑えることができる。 The operation of the fourth embodiment will be described. Since the power generation unit 10C is held on the fixed plate 30 connected to the vehicle body, vibration associated with traveling is input. The SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state are fixed in a rigid state to the fixed plate 30 by the first fixing unit 70, and the connection block 60 is fixed to the fixed plate 30 by the second fixing unit 80. All the devices in the GPU 50 (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) are fixed to the fixed plate 30 in a rigid state by the second fixing unit 80. For this reason, the natural frequency of the power generation unit 10C increases, and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10C deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10C.

 発電ユニット10Cの固有振動数が上昇するため、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50の剛性を向上させることができる。 Since the natural frequency of the power generation unit 10C increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 that are connected in a rigid state can be improved.

 ベローズ部材95を有する変位吸収部90は、GPU50における機器(燃料改質器51および熱交換器52)の熱膨張に伴う変位を一の方向に伸縮して吸収する。このため、GPU50の各機器51、52が熱膨張しても、熱膨張による応力を低減することができる。 The displacement absorbing portion 90 having the bellows member 95 absorbs the displacement accompanying the thermal expansion of the equipment (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 in one direction. For this reason, even if each apparatus 51 and 52 of GPU50 is thermally expanded, the stress by thermal expansion can be reduced.

 以上説明したように、第4実施形態の発電ユニット10Cは、第2固定部80によってGPU50におけるすべての機器(燃料改質器51、触媒燃焼器53および熱交換器52)および連結ブロック60の両者を固定プレート30にリジッド状態に固定している。変位吸収部90は、GPU50における機器(燃料改質器51および熱交換器52)の機器本体56a、56bと当該機器51、52のマニホールド54a、54bとの間に配置され一の方向に沿って伸縮するベローズ部材95を有する。 As described above, the power generation unit 10 </ b> C of the fourth embodiment is configured such that both the equipment (the fuel reformer 51, the catalytic combustor 53, and the heat exchanger 52) and the connection block 60 in the GPU 50 are connected by the second fixing unit 80. Is fixed to the fixing plate 30 in a rigid state. The displacement absorbing unit 90 is disposed between the device bodies 56a and 56b of the devices (the fuel reformer 51 and the heat exchanger 52) in the GPU 50 and the manifolds 54a and 54b of the devices 51 and 52 along one direction. It has a bellows member 95 that expands and contracts.

 このように構成することによって、第1実施形態の発電ユニット10Cと同様の作用効果を奏する。すなわち、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50は、SOFC40が第1固定部70によって固定プレート30にリジッド状態に固定され、GPU50におけるすべての機器(燃料改質器51、触媒燃焼器53および熱交換器52)が第2固定部80によって固定プレート30にリジッド状態に固定され、連結ブロック60が第2固定部80によって固定プレート30にリジッド状態に固定される。このため、発電ユニット10Cの固有振動数が上昇し、共振周波数が上昇する。この結果、発電ユニット10Cの固有振動数が、路面負荷入力の大きい周波数域から外れ(上昇し)、走行に伴う振動が発電ユニット10Cの作動に悪影響を及ぼすことを抑えることができる。発電ユニット10Cの固有振動数が上昇するため、リジッド状態に連結されたSOFC40、連結ブロック60およびGPU50の剛性が向上する。GPU50における機器(触媒燃焼器53および熱交換器52)の熱膨張に伴う変位(伸び)がベローズ部材95の伸縮によって一の方向において吸収される。この結果、熱膨張による応力を低減することができる。 By configuring in this way, the same effects as the power generation unit 10C of the first embodiment can be obtained. That is, the SOFC 40, the connection block 60, and the GPU 50 that are connected in the rigid state are fixed to the fixed plate 30 in the rigid state by the first fixing unit 70, and all the devices in the GPU 50 (the fuel reformer 51, the catalytic combustor). 53 and the heat exchanger 52) are fixed to the fixed plate 30 by the second fixing portion 80 in a rigid state, and the connecting block 60 is fixed to the fixing plate 30 by the second fixing portion 80 in a rigid state. For this reason, the natural frequency of the power generation unit 10C increases, and the resonance frequency increases. As a result, it is possible to suppress that the natural frequency of the power generation unit 10C deviates (rises) from the frequency range where the road surface load input is large, and the vibration caused by traveling adversely affects the operation of the power generation unit 10C. Since the natural frequency of the power generation unit 10C increases, the rigidity of the SOFC 40, the connection block 60, and the GPU 50 connected in a rigid state is improved. Displacement (elongation) accompanying thermal expansion of the devices (catalytic combustor 53 and heat exchanger 52) in the GPU 50 is absorbed in one direction by the expansion and contraction of the bellows member 95. As a result, stress due to thermal expansion can be reduced.

 (その他の改変例)
 第1固定部70および第2固定部80の具体的な構成は上述した構成に限られない。第1固定部70の具体的な構成は、SOFC40の他方のエンドプレート109側を固定プレート30にリジッド状態に固定する機能を発揮する限りにおいて適宜改変できる。第2固定部80の具体的な構成は、GPU50における少なくとも1つの機器51、52、53および連結ブロック60の少なくとも一方を固定プレート30にリジッド状態に固定する機能を発揮する限りにおいて適宜改変できる。ボルト締結および溶接接合など異なる種類の固定方式の両者を適用することができる。固定点数も任意である。
(Other modifications)
Specific configurations of the first fixing unit 70 and the second fixing unit 80 are not limited to the above-described configurations. The specific configuration of the first fixing unit 70 can be modified as appropriate as long as it exhibits the function of fixing the other end plate 109 side of the SOFC 40 to the fixing plate 30 in a rigid state. The specific configuration of the second fixing unit 80 can be appropriately modified as long as it exhibits a function of fixing at least one of the at least one device 51, 52, 53 and the connection block 60 in the GPU 50 to the fixing plate 30 in a rigid state. Both different types of fastening methods such as bolt fastening and welded joints can be applied. The number of fixed points is also arbitrary.

 変位吸収部90がスライダー91またはベローズ部材95を有する形態について説明したが、変位吸収部90の具体的な構成はこの場合に限られない。変位吸収部90の具体的な構成は、GPU50における機器の熱膨張に伴う変位を一の方向において吸収する機能を発揮する限りにおいて適宜改変できる。例えば、スプリングや作動流体の圧力(油圧や空圧)を利用したダンパーを用いることができる。 Although the embodiment in which the displacement absorbing portion 90 has the slider 91 or the bellows member 95 has been described, the specific configuration of the displacement absorbing portion 90 is not limited to this case. The specific configuration of the displacement absorbing unit 90 can be appropriately modified as long as it exhibits the function of absorbing the displacement accompanying the thermal expansion of the device in the GPU 50 in one direction. For example, a damper using a spring or working fluid pressure (hydraulic pressure or pneumatic pressure) can be used.

10、10A、10B、10C 発電ユニット、
20  サイドメンバー、
30  固定プレート、
31  断熱材、
40  固体酸化物形燃料電池(SOFC)、
40S 燃料電池スタック、
41a、41b、41c マニホールド、
50  ガスプロセッシングユニット(GPU)、
51、52、53 機器、
51   燃料改質器、
51a  供給管、
52   熱交換器、
52a  供給管、
52b  排気管、
52c  導入管、
53   触媒燃焼器(燃焼器)、
54a、54b、54c マニホールド、
55   フランジ部材、
55a  凸部、
56a、56b 機器本体、
60   連結ブロック、
60a  凸部、
61   第1の通路部(通路部)、
62   第2の通路部(通路部)、
63   第3の通路部(通路部)、
70   第1固定部、
71   第1ブラケット、
72   第2ブラケット、
72a  外周部、
73   溶接、
80   第2固定部、
81   第1プレート、
82   第2プレート、
83   支柱、
84   フランジ部、
90   変位吸収部、
91   スライダー、
92   支持脚、
93   ガイドシャフト、
94   ガイドブラケット、
95   ベローズ部材、
100  セルユニット、
108  下部エンドプレート(一方のエンドプレート)、
109  上部エンドプレート(他方のエンドプレート)、
110  メタルサポートセルアッセンブリー、
110M メタルサポートセル、
111  電解質電極接合体、
111A アノード層、
111C カソード層、
111E 電解質層、
112  メタルサポート部、
113  セルフレーム、
AG   アノードガス、
AOG  アノードオフガス、
CG   酸化剤ガス、カソードガス、
EG   排気ガス。
10, 10A, 10B, 10C Power generation unit,
20 Side members,
30 fixed plate,
31 heat insulation,
40 Solid oxide fuel cell (SOFC),
40S fuel cell stack,
41a, 41b, 41c manifold,
50 Gas processing unit (GPU),
51, 52, 53 equipment,
51 Fuel reformer,
51a supply pipe,
52 heat exchanger,
52a supply pipe,
52b exhaust pipe,
52c introduction pipe,
53 Catalytic combustor (combustor),
54a, 54b, 54c manifold,
55 flange member,
55a convex part,
56a, 56b device main body,
60 connecting blocks,
60a convex part,
61 1st passage part (passage part),
62 second passage part (passage part),
63 3rd passage part (passage part),
70 first fixing part,
71 first bracket,
72 second bracket,
72a outer periphery,
73 welding,
80 second fixing part,
81 first plate,
82 second plate,
83 struts,
84 flange part,
90 displacement absorber,
91 slider,
92 support legs,
93 Guide shaft,
94 guide bracket,
95 Bellows member,
100 cell units,
108 Lower end plate (one end plate),
109 Upper end plate (the other end plate),
110 Metal support cell assembly,
110M metal support cell,
111 electrolyte electrode assembly,
111A anode layer,
111C cathode layer,
111E electrolyte layer,
112 Metal support part,
113 cell frames,
AG anode gas,
AOG anode off gas,
CG oxidant gas, cathode gas,
EG Exhaust gas.

Claims (9)

 車体に接続される固定プレート上に保持される発電ユニットであって、
 固体酸化物形燃料電池と、
 前記固体酸化物形燃料電池に供給する燃料を改質する燃料改質器、前記固体酸化物形燃料電池から排出されたアノードオフガス中の未燃ガスを燃焼する燃焼器および前記燃焼器から排出された排気ガスと前記固体酸化物形燃料電池に供給する酸化剤ガスとを熱交換する熱交換器の3つの機器を含むガスプロセッシングユニットと、
 前記固体酸化物形燃料電池の一方のエンドプレート側に形成されたマニホールドと、前記ガスプロセッシングユニットにおける前記機器のそれぞれのマニホールドとを一体的に連結する連結部と、
 前記固体酸化物形燃料電池の他方のエンドプレート側を前記固定プレートにリジッド状態に固定する第1固定部と、
 前記ガスプロセッシングユニットにおける少なくとも1つの前記機器および前記連結部の少なくとも一方を前記固定プレートにリジッド状態に固定する第2固定部と、
 前記ガスプロセッシングユニットにおける前記機器の熱膨張に伴う変位を一の方向において吸収する変位吸収部と、を有する発電ユニット。
A power generation unit held on a fixed plate connected to the vehicle body,
A solid oxide fuel cell;
A fuel reformer that reforms fuel supplied to the solid oxide fuel cell, a combustor that burns unburned gas in the anode off-gas discharged from the solid oxide fuel cell, and an exhaust gas discharged from the combustor. A gas processing unit including three devices of a heat exchanger for exchanging heat between the exhaust gas and the oxidant gas supplied to the solid oxide fuel cell;
A manifold formed integrally on one end plate side of the solid oxide fuel cell, and a connecting portion that integrally connects each manifold of the device in the gas processing unit;
A first fixing portion for fixing the other end plate side of the solid oxide fuel cell to the fixing plate in a rigid state;
A second fixing portion for fixing at least one of the device and the connecting portion in the gas processing unit to the fixing plate in a rigid state;
A power generation unit comprising: a displacement absorbing portion that absorbs in one direction a displacement associated with thermal expansion of the device in the gas processing unit.
 前記連結部は、前記固体酸化物形燃料電池の一方の前記エンドプレート側に形成された前記マニホールドと、前記ガスプロセッシングユニットにおける前記機器のそれぞれの前記マニホールドとを連通する通路部が形成されたブロック形状を有し、一方の前記エンドプレートに前記通路部の内部から溶接接合され一体化され、
 前記固体酸化物形燃料電池は、前記連結部が一体化された一方の前記エンドプレートにセルユニットを積層して形成される、請求項1に記載の発電ユニット。
The connecting portion is a block in which a passage portion is formed to connect the manifold formed on one end plate side of the solid oxide fuel cell and each manifold of the device in the gas processing unit. Having a shape, and being welded and joined to the one end plate from the inside of the passage portion,
2. The power generation unit according to claim 1, wherein the solid oxide fuel cell is formed by stacking a cell unit on one of the end plates integrated with the connecting portion.
 前記第1固定部は、前記固定プレートに対して複数点において固定される第1ブラケットを有する、請求項1または請求項2に記載の発電ユニット。 The power generation unit according to claim 1 or 2, wherein the first fixing portion has a first bracket fixed at a plurality of points with respect to the fixing plate.  前記第1固定部は、前記固体酸化物形燃料電池の他方の前記エンドプレートに対して複数点において固定される第2ブラケットを有する、請求項1~3のいずれか1項に記載の発電ユニット。 The power generation unit according to any one of claims 1 to 3, wherein the first fixing portion includes a second bracket fixed at a plurality of points to the other end plate of the solid oxide fuel cell. .  前記第2ブラケットは、前記固体酸化物形燃料電池の他方の前記エンドプレートに対して溶接によって固定される、請求項4に記載の発電ユニット。 The power generation unit according to claim 4, wherein the second bracket is fixed to the other end plate of the solid oxide fuel cell by welding.  前記変位吸収部は、前記ガスプロセッシングユニットにおける前記機器の前記一の方向に沿う変位をガイドするスライダーを有する、請求項1~5のいずれか1項に記載の発電ユニット。 The power generation unit according to any one of claims 1 to 5, wherein the displacement absorbing portion includes a slider for guiding a displacement along the one direction of the device in the gas processing unit.  前記変位吸収部は、前記ガスプロセッシングユニットにおける前記機器の機器本体と前記機器の前記マニホールドとの間に配置され前記一の方向に沿って伸縮するベローズ部材を有する、請求項1~6のいずれか1項に記載の発電ユニット。 The displacement absorbing portion has a bellows member disposed between the device main body of the device and the manifold of the device in the gas processing unit and extending and contracting along the one direction. The power generation unit according to Item 1.  前記一の方向は、水平方向、かつ、前記固体酸化物形燃料電池と前記ガスプロセッシングユニットとが向かい合う方向である、請求項1~7のいずれか1項に記載の発電ユニット。 The power generation unit according to any one of claims 1 to 7, wherein the one direction is a horizontal direction and a direction in which the solid oxide fuel cell and the gas processing unit face each other.  前記連結部、前記第1固定部および前記第2固定部の形成材料は、前記固定プレートの形成材料と同じである、請求項1~8のいずれか1項に記載の発電ユニット。 The power generation unit according to any one of claims 1 to 8, wherein a material for forming the connecting portion, the first fixing portion, and the second fixing portion is the same as a material for forming the fixing plate.
PCT/JP2018/022229 2018-06-11 2018-06-11 Power generation unit with solid oxide fuel cell Ceased WO2019239457A1 (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013070028A (en) * 2011-09-07 2013-04-18 Hitachi Automotive Systems Ltd Electronic controller
JP2016505200A (en) * 2013-02-04 2016-02-18 アーファオエル・リスト・ゲーエムベーハー Fuel cell system operable with hydrocarbons

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013070028A (en) * 2011-09-07 2013-04-18 Hitachi Automotive Systems Ltd Electronic controller
JP2016505200A (en) * 2013-02-04 2016-02-18 アーファオエル・リスト・ゲーエムベーハー Fuel cell system operable with hydrocarbons

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