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WO2019112340A1 - Nondegradable sewage/wastewater preprocessing system - Google Patents

Nondegradable sewage/wastewater preprocessing system Download PDF

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Publication number
WO2019112340A1
WO2019112340A1 PCT/KR2018/015425 KR2018015425W WO2019112340A1 WO 2019112340 A1 WO2019112340 A1 WO 2019112340A1 KR 2018015425 W KR2018015425 W KR 2018015425W WO 2019112340 A1 WO2019112340 A1 WO 2019112340A1
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Prior art keywords
membrane
water
sludge
flat membrane
wastewater
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Ceased
Application number
PCT/KR2018/015425
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French (fr)
Korean (ko)
Inventor
김창용
노종범
김세영
구건우
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08Flat membrane modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/0009Settling tanks making use of electricity or magnetism
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/003Sedimentation tanks provided with a plurality of compartments separated by a partition wall
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/24Feed or discharge mechanisms for settling tanks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D21/00Separation of suspended solid particles from liquids by sedimentation
    • B01D21/24Feed or discharge mechanisms for settling tanks
    • B01D21/245Discharge mechanisms for the sediments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08Flat membrane modules
    • B01D63/082Flat membrane modules comprising a stack of flat membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/484Treatment of water, waste water, or sewage with magnetic or electric fields using electromagnets
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/15Treatment of sludge; Devices therefor by de-watering, drying or thickening by treatment with electric, magnetic or electromagnetic fields; by treatment with ultrasonic waves
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/20By influencing the flow
    • B01D2321/2033By influencing the flow dynamically
    • B01D2321/2058By influencing the flow dynamically by vibration of the membrane, e.g. with an actuator
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus

Definitions

  • the present invention relates to a waste water pre-treatment system, and more particularly, to a micro-substance filtration tank having a high-speed solid-liquid separator and a membrane unit, in which an electrolytic apparatus and an electro-
  • the present invention relates to a detoxifying wastewater pretreatment system capable of efficiently purifying wastewater by combining the membrane unit and effectively using the filtration unit for a long time by effectively performing backwashing of the membrane unit.
  • Conventional wastewater treatment methods include contact oxidation, merged septic tanks, and high efficiency merged septic tanks.
  • the operation cost is high because the power consumption is relatively large and the high moisture content waste sludge is generated.
  • the concentration of organic matter in the treated water is high and often does not satisfy the treatment water quality standard.
  • pin floc phenomenon occurs or microorganisms die The water quality of the treated water is deteriorated, and there is an inconvenience that the microorganism must be reused.
  • Patent Document 1 Korean Patent No. 10-0882452 (Feb. 2, 2009)
  • Patent Document 2 Korean Patent No. 10-0974076 (July 29, 2010)
  • Patent Document 3 Korean Patent No. 10-0970797 (2010.07.09)
  • Another object of the present invention is to provide a degradable wastewater pre-treatment system that can effectively use a filtration device for a long time by effectively performing backwashing of a membrane unit.
  • the present invention provides an electrolytic wastewater pretreatment system according to the present invention, comprising: an electrocoagulant for electrochemically treating contaminants in wastewater; A solid-liquid separator for treating residues, sediments or suspended matters from the treated water pretreated from the electrolytic apparatus, and a solid-liquid separator connected to the solid- A waste water pre-treatment system comprising a micro-substance filtration tank capable of filtration and purification,
  • the solid-liquid separator includes a main body having an inlet portion for introducing wastewater into one side portion thereof and a first sludge discharge port for discharging the settling sludge on a bottom surface thereof; A separation membrane member extending from a center of the bottom of the main body to an upper portion thereof for partitioning the inside of the main body into a first compartment and a second compartment; A moving path formed on the upper side of the separation membrane member and through which the treated water moves; And an opening / closing lid which is located at an upper portion of the main body and which can be opened / closed by a hinge rotatably coupled to a hinge portion at one side,
  • the microfilter filtration tank comprises: a housing having a second sludge discharge port for discharging sludge at a lower portion thereof; And a membrane unit installed inside the housing.
  • opening / closing lid portion is installed to be inclined at an upper portion of the main body.
  • a sensing sensor for sensing opening / closing of the opening / closing lid is further provided at one end of the opening / closing lid,
  • connection passage is further provided with a solenoid valve electrically connected to the detection sensor to limit the flow of the process water.
  • a plurality of electromagnets for collecting sludge containing a metal component are further provided on the bottom surface of the housing.
  • the membrane unit may include: a water tank in which filtered water or washing water can be filled; An outlet for discharging the filtered water stored in the water tank or filling the water tank with washing water; A plurality of membrane flat membrane modules installed elongate from the top to the bottom of the water tank to filter the treated water; A support frame for supporting each of the membrane flat membrane modules; A first flow pipe installed to communicate with the water tank; A second flow pipe coupled to the support frame; And a plurality of acid pipes installed in the second flow pipe so as to face the membrane flat membrane module.
  • the air diffusing pipe is formed in a venturi pipe structure.
  • the vibration member may include: a bearing installed above and below the inner wall of the second flow pipe; A rotating shaft rotatably mounted on the bearing; And an eccentric rotation body integrally installed at the center of the rotation shaft.
  • a first horizontal moving device installed adjacent to an upper side of the membrane flat membrane module to horizontally move the upper side of the membrane flat membrane module horizontally;
  • a second horizontal moving device installed adjacent to a lower side of the membrane flat membrane module to horizontally move the lower side of the membrane flat membrane module horizontally;
  • a driving device interlocked with the first horizontal moving device and the second horizontal moving device to move the first horizontal moving device and the second horizontal moving device to the left and right, respectively.
  • the first horizontal movement device includes: an upper locating bar installed laterally on an upper side of each membrane flat membrane module; And an upper support rod for connecting the upper locating bars longitudinally from both sides,
  • the second horizontally moving device includes: a lower locating bar installed laterally on a lower side of each of the membrane flat membrane modules; And a lower support rod for connecting the lower locating bars longitudinally from both sides.
  • first horizontal moving device and the second horizontal moving device are set to be located at different positions from each other by the driving device.
  • the upper position movement bar and the lower position movement bar each have a pair of operation bar structures for inserting the membrane flat membrane module.
  • the upper position movement bar and the lower position movement bar each have one operation bar structure installed in contact with the membrane flat membrane module.
  • An electrocoagulation device for electrochemically treating contaminants in wastewater prior to the solid-liquid separator; And an electrolytic apparatus for decomposing and treating the pollutant by the oxidation and reduction reaction of the treated water treated with pollutants from the electrocoagulant,
  • the electrocoagulation device and the electrolytic device are each composed of two chambers in one unit.
  • the wastewater can be efficiently purified by combining the treatment section in which the electrolytic apparatus and the electrocoagulation apparatus are arranged in parallel, and the micro-substance filtration tank equipped with the high-speed solid-liquid separator and the membrane unit.
  • the floating sludge and the precipitated sludge are primarily removed through the solid-liquid separator, and the treated water containing the fine material is removed through the membrane unit and the electromagnet to effectively purify the wastewater. have.
  • the foreign matter adhering to the membrane can be easily cleaned through the operation of the air diffuser and the operation of the eccentric rotation body.
  • FIG. 1 is a cross-sectional view of a non-degradable wastewater treatment system according to the present invention
  • FIG. 2 is an enlarged view of the solid-liquid separator shown in FIG. 1;
  • FIG. 3 is an enlarged view showing an enlarged view of the micro-substance filtration tank in FIG.
  • Fig. 4 is a cross-sectional view showing another embodiment of the membrane unit used in the micro-substance filtration tank of Fig. 3;
  • main body 111 main body 111:
  • first sludge discharge port 120 separation membrane member
  • moving passage 130 opening / closing lid
  • Detection sensor 140 Solenoid valve
  • connection flow passage 200 micro-substance filtration tank
  • housing 220 electromagnet
  • bearing 255 eccentric rotation body
  • FIG. 1 is an enlarged cross-sectional view of a non-degradable wastewater treatment system according to the present invention
  • FIG. 2 is an enlarged view of the solid-liquid separator in FIG. 1
  • FIG. 3 is an enlarged view of the micro- .
  • the pre-treatment system of the present invention includes an electrocoagulant 400 for electrochemically treating contaminants in wastewater, a treatment for treating contaminants from the electrocoagulant 400 An electrolytic apparatus 500 for decomposing and treating contaminants by oxidation and reduction of water, a method for treating residues, sediments, or suspended matters from the pretreatment water from the electrocoagulant 400 and the electrolytic apparatus 500 And a micro-substance filtration tank 200 connected to the solid-liquid separator 100 and capable of filtering and purifying micro-substances.
  • the electrocoagulation device 400 and the electrolytic device 500 are pretreatment devices for filtering wastewater.
  • the electrocoagulation reaction of the electrocoagulation device 400 is a method of treating contaminants by accelerating the precipitation of the ionic substance into a salt and the growth of floc by the exchange of electrons emitted from the electrode, ) Is a method of treating pollutants by decomposing various pollutants by oxidation and reduction reactions that occur when DC power is supplied to the wastewater.
  • the electrocoagulation device 400 includes a tank filled with raw wastewater and filled with water, an electrocoagulation control panel installed in the tank, and a power supply device for supplying power to the electrocoagulation control panel.
  • the polarity of the power supplied from the power supply device can be automatically changed to the opposite polarity depending on the situation, and the aggregate can be formed or the aggregate can be separated and discharged.
  • the electrocoagulation apparatus 400 supplies DC power to the inside of the apparatus,
  • the mixture produced in this process produces a naturally occurring electrocoagulant and the aluminum or iron oxide electrode is reused.
  • the resulting chlorine can oxidize the organic compounds and acts as a powerful oxidizer that can promote electrode reactions.
  • the cathode causes a chemical reaction at the high pH value by the hydroxide ion during hydrogen gas production.
  • Al 3 + (aq) and OH - ions produced by the above electrode reaction form various ions.
  • Al (OH) 2 +, Al (OH) 2 +, Al 2 (OH) 2 4 +, Al (OH) 4 -, Al 6 (OH) 15 3 +, Al 7 (OH) 17 4 +, Al 8 (OH) 20 4+ , Al 13 O 4 (OH) 24 7 + , Al 13 (OH) 34 5 + are finally converted to Al (OH) 3 by the precipitation dynamics of the compound.
  • the electrolytic apparatus 500 is provided with electrodes 510 and 520 for treating pollutants by electrolyzing the polluted-treatment-treated water from the electrocoagulation apparatus 400.
  • the electrolysis of the organic material is oxidized at the anode but the indirect oxidation by intermediate products such as hypochlorous acid produced by the direct oxidation which oxidizes the organic matter and the electrolysis of chlorine, Can be distinguished.
  • the organic material (R) reacts with hydroxide ions adsorbed on the oxidizing anode and decomposes into carbon dioxide, water or hydrogen ions.
  • the electrochemical reaction of the organic material removed by indirect oxidation occurs simultaneously with anodic oxidation of chlorine during electrolysis and hypochlorous acid is formed on the electrode surface.
  • connection passage 150 The solid-liquid separator 100 and the micro-substance filtration tank 200 are connected to each other by a connection passage 150, and a solenoid valve 140 for opening and closing the passage is installed in the connection passage 150.
  • the connection passage 150 is preferably connected to the lower end of the solid-liquid separator 100.
  • the solid-liquid separator 100 includes a main body 110 having an inlet portion 111 through which wastewater flows into the one side portion and a first sludge discharge port 113 through which bottom side a sedimentation sludge 70 is discharged do.
  • the main body 110 includes a separation membrane member 120 extending from the center of the bottom portion to the top thereof.
  • the separation membrane member 120 is a partition wall structure necessary for solid-liquid separation.
  • the interior of the body 110 is divided into a first compartment 161 and a second compartment 163.
  • a moving passage 125 is formed on the upper side of the separation membrane member 120.
  • the moving passage 125 is formed in the second compartment 163 with treated water primarily sludge- Can be moved.
  • an opening / closing lid 130 is hingedly coupled to the hinge 133.
  • the opening and closing lid 130 may be inclined to the main body 110.
  • the rear wall of the main body 110 is disposed higher than the front wall so that the opening / As shown in FIG.
  • a sensing sensor 135 may be installed at one end of the opening / closing lid 130 to detect opening / closing of the opening / closing lid 130.
  • the sensing sensor 135 is electrically connected to a solenoid valve 140 installed in the connection passage 150.
  • the solenoid valve 140 is opened so that the treated water filled in the second compartment 163 flows into the connecting passage 150 To the microfilter filtration tank 200 via the second filter (not shown).
  • the detection sensor 135 senses the closing of the opening / closing lid 130
  • the solenoid valve 140 is closed to close the connecting flow channel 150.
  • the connection passage 150 is closed, the wastewater and process water are filled in the solid-liquid separator 100, and a high-pressure pressure is generated inside the main body 110 at the same time.
  • floating sludge 80 such as impurities floating in water in the wastewater filled in the first compartment 161 floats to the top, and such as debris or sediment sludge sinks to the bottom surface .
  • the floating sludge 80 pushes the opening / closing lid 130 and is discharged to the outside, and the settling sludge 70 can be discharged to the outside through the first sludge discharging opening 113.
  • the floating sludge 80 and the settling sludge 70 can be primarily removed from the wastewater, and the fine material from which the large sludges have been removed is transferred to the micro-substance filtering tank 200 together with the treated water And then filtered to obtain purified water.
  • the microfilter filtration tank 200 includes a housing 210 having a second sludge discharge port 215 for discharging sludge thereunder.
  • the second sludge outlet 215 is preferably formed in a funnel shape to facilitate discharge of the sludge.
  • a plurality of electromagnets 220 may be installed on the inclined bottom surface of the housing 210.
  • the electromagnet 220 serves to collect sludge containing a metal component such as iron contained in the treated water.
  • the metal-containing sludge collected in the electromagnet 220 may be discharged together with sludges desorbed from the membrane flat membrane module by removing magnetism during backwashing of the membrane flat membrane module.
  • a membrane unit 30 is installed in the housing 210.
  • the membrane unit 30 includes a water tank 10 through which filtered water or washing water can be filled and an inlet 11 for discharging filtered water stored in the water tank 10 or filling the water tank 10 with washing water .
  • the membrane unit (30) of the present invention includes a plurality of membrane flat membrane modules (31) extended from the upper part to the lower part of the water tank (10).
  • each membrane flat membrane module 31 is installed to be supported by a separate support frame.
  • a plurality of air diffusers 13 are installed on the lower side of the membrane flat membrane module 31.
  • the air diffusers 13 are preferably installed adjacent to the lower side of the membrane flat membrane module 31.
  • the air diffusing pipe 13 is installed in the second flow pipe 15 so that the air introduced from the outside can be blown into the membrane unit 30. The air thus blown can clean the membrane flat membrane module 31 and at the same time maintain the water dissolved oxygen amount of the water tank equipped with the water treatment device.
  • the air diffusing pipe 13 is formed of a venturi pipe structure 18 so that the water droplets can be ejected in the form of a fine bubble.
  • a plurality of vibration members 250 may be installed in the second flow pipe 282 provided with the air diffuser 13.
  • the membrane unit 30 to which the second flow pipe 282 is connected is vibrated by causing the vibration member 250 to vibrate in the second flow pipe 282, The foreign substances adhered to the surface of the substrate can be easily dropped.
  • the vibration member 250 is installed inside the second flow pipe 282 and includes a bearing 253 installed above and below the inner wall of the second flow pipe 282, And an eccentric rotation body 255 integrally provided at the center of the rotation shaft.
  • the eccentric rotation body 255 is rotated by the water pressure, and the rotation shaft 251 coupled thereto is rotated, and the vibration by the eccentric rotation body 255 is generated . Then, the second flow pipe 282 vibrates, and the membrane unit 30 to which the second flow pipe 282 is coupled vibrates.
  • the air diffuser 13 and the vibrating member 250 do not operate when the membrane unit 30 performs a normal purification and filtration operation and perform backwashing to remove foreign substances adhered to the membrane flat membrane module 31 And only when it is done.
  • the three-way valve 285 is opened to both sides and the backwash water is supplied to the first flow pipe 281 and the second flow pipe 282.
  • the backwash water supplied to the first flow pipe 281 is supplied to the inside of the membrane flat membrane module 31 via the water tank 10 and passes through the micropores of the membrane module 31 to the microfluidic filtration tank 200, .
  • the foreign matter adhering to the membrane flat membrane module 31 can be primarily removed by the action of the reverse water wash.
  • the circulating water supplied to the second flow pipe 282 is blown out in the form of fine bubbles through the air diffuser 13 to remove foreign substances and the vibrating member 250 is operated to move the membrane unit 30, So that foreign matter can be removed.
  • the foreign substance can be removed secondarily through the acid pipe 13 and the vibration member 250.
  • FIG. 4 is a cross-sectional view of a membrane unit according to another embodiment of the present invention.
  • a first horizontal moving device 40 is installed on the upper side of the membrane flat membrane module 31
  • a second horizontal movement device 50 is installed on the lower side of the second horizontal movement device 31.
  • the first horizontally moving device 40 includes an upper locating bar 41 installed laterally on the upper side of each membrane flat membrane module 31 and a plurality of upper locating bars 41 extending in the longitudinal direction And an upper support rod 43 for connecting the upper support rod 43 and the upper support rod 43 to each other.
  • the upper locating bar 41 has a pair of operating bar structures, and the membrane flat membrane module 31 can be configured to be sandwiched between the pair of operating bars.
  • each of the plurality of membrane flat membrane modules 31 is positioned by the upper locating bar 41 into which they are inserted, and can take the same shape at the same time.
  • the second horizontal movement device 50 includes a lower position movement bar 51 installed laterally on the lower side of each membrane flat membrane module 31, and a plurality of lower position movement bars 51 on both sides And a lower support rod 53 which is connected in a longitudinal direction.
  • the lower position shifting bar 51 has a pair of operating bar structures, and the membrane flat membrane module 31 may be configured to be sandwiched between the pair of operating bars.
  • each of the plurality of membrane flat membrane modules 31 is positioned by the lower locating bar 51 into which they are inserted, and can assume the same shape at the same time.
  • the first horizontal moving device 40 and the second horizontal moving device 50 are connected to the driving device 23 and can translate, respectively.
  • the first horizontal moving device 40 and the second horizontal moving device 50 It is preferable that the horizontal movement devices 50 are set to be located at mutually different positions.
  • the second horizontal moving device 50 is moved by the driving device 23 to the membrane flat membrane module 31 To be pulled and positioned.
  • the membrane flat membrane module 31 can finally be bent in a zigzag form.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

Disclosed is a nondegradable sewage/wastewater preprocessing system. The present invention provides a nondegradable sewage/wastewater preprocessing system comprising: a solid/liquid separator for processing remnants, sediments, or floating materials of sewage/wastewater; and micromaterial filtering tank connected to the solid/liquid separator by a connection channel such that micromaterials can be filtered and refined. The solid/liquid separator comprises: a body having an entrance portion provided in one side portion thereof so as to introduce sewage/wastewater and having a first sludge discharge port provided in the bottom surface thereof so as to discharge precipitated sludge; a separating film member installed to extend from the center of the bottom portion of the body to the upper portion thereof such that the interior of the body is delimited into a first compartment and a second compartment; a movement channel formed near the upper portion of the separation film member such that treated water moves along the same; and an opening/closing cover portion positioned on the upper portion of the body, one side of the opening/closing cover portion being coupled to a hinge portion to be able to hinge/rotate such that the same can be opened/closed. The micromaterial filtering tank comprises: a housing having a second sludge discharge port provided in the lower portion thereof so as to discharge sludge; and a membrane unit installed inside the housing.

Description

난분해성 오폐수 전처리시스템Degradable wastewater treatment system

본 발명은 난분해성 오폐수 전처리시스템에 관한 것으로, 보다 구체적으로는 주 처리 장치로서 전기분해장치와 전기응집장치가 하나의 유닛에 병렬로 구성되며, 고속 고액분리기와 멤브레인 유닛이 구비된 미세물질 여과조를 결합시킴으로써 오폐수를 효율적으로 정화시킬 수 있으며, 멤브레인 유닛의 역세척을 효과적으로 수행함으로써 오랫동안 지속적으로 여과장치를 사용할 수 있도록 한 난분해성 오폐수 전처리시스템에 관한 것이다.More particularly, the present invention relates to a waste water pre-treatment system, and more particularly, to a micro-substance filtration tank having a high-speed solid-liquid separator and a membrane unit, in which an electrolytic apparatus and an electro- The present invention relates to a detoxifying wastewater pretreatment system capable of efficiently purifying wastewater by combining the membrane unit and effectively using the filtration unit for a long time by effectively performing backwashing of the membrane unit.

기존의 오·폐수처리방식은 장치가 복잡하고 운전이 까다로워 유지관리 하는데에 전문적인 지식을 요구하며 동력비나 인건비등 유지관리비용이 상대적으로 높은 단점이 있다. 또한 처리수 수질도 만족할 만한 수준에 이르지 못하고 있는 실정이다.Conventional waste and wastewater treatment methods have a disadvantage in that they require expert knowledge for maintenance due to complicated equipment and difficult operation, and maintenance costs such as power costs and labor costs are relatively high. In addition, the quality of treated water is not satisfactory.

종래의 오·폐수처리법으로는 접촉산화법, 합병정화조, 고효율합병정화조 등이 주로 이용되어 왔다. 접촉산화법의 경우는 동력소모가 상대적으로 많고 높은 함수율의 폐슬러지가 발생하기 때문에 운전비용이 높은 단점이 있다. 또한 처리수의 유기물농도가 높아 처리수 수질기준을 만족시키지 못하는 경우가 종종 발생하며 오·폐수의 유입이 불규칙적이거나 1∼2주일간 유입되지 않고 공폭기되는 경우에는 핀플록현상이 일어나거나 미생물이 사멸되는 현상이 발생하게 되어 처리수의 수질이 악화될 뿐아니라 미생물식종을 다시 해야하는 불편함이 있다. 합병정화조 및 고효율합병 정화조의 경우는 침전분리 및 유량조정기능을 개량한 접촉산화법을 유리섬유 강화플라스틱(FRP) 탱크로 일체화하여 규모를 축소시킨 장점은 있으나, 이들 또 한 유지관리시 전문적인 지식이 필요하며 동력비나 소음문제, 폐슬러지 처리문제 등으로 운전비용이 높은 단점이 있다.Conventional wastewater treatment methods include contact oxidation, merged septic tanks, and high efficiency merged septic tanks. In the case of the contact oxidation method, the operation cost is high because the power consumption is relatively large and the high moisture content waste sludge is generated. In addition, the concentration of organic matter in the treated water is high and often does not satisfy the treatment water quality standard. In the case where the inflow of waste water and wastewater is irregular or the air is not introduced for 1 to 2 weeks, pin floc phenomenon occurs or microorganisms die The water quality of the treated water is deteriorated, and there is an inconvenience that the microorganism must be reused. In the case of the combined septic tank and the high-efficiency merged septic tank, there is an advantage that the contact oxidation method improved the sediment separation and flow adjustment function by integrating the glass-reinforced plastic (FRP) tank into a small size, And there is a disadvantage that the operation cost is high due to problems of power and noise, disposal of waste sludge, and the like.

[선행기술문헌][Prior Art Literature]

[특허문헌][Patent Literature]

(특허문헌 1) 1. 대한민국 등록특허 제10-0882452호 (2009.02.02)(Patent Document 1) 1. Korean Patent No. 10-0882452 (Feb. 2, 2009)

(특허문헌 2) 2. 대한민국 등록특허 제10-0974076호 (2010.07.29)(Patent Document 2) 2. Korean Patent No. 10-0974076 (July 29, 2010)

(특허문헌 3) 3. 대한민국 등록특허 제10-0970797호 (2010.07.09)(Patent Document 3) 3. Korean Patent No. 10-0970797 (2010.07.09)

본 발명의 목적은 상기 문제점을 해결하기 위하여 안출된 것으로, 간편한 시스템 구성으로 보다 효율적인 처리를 위해 전기분해장치와 전기응집장치가 병렬로 구성되며, 고속 고액분리기와 멤브레인 유닛이 구비된 미세물질 여과조를 결합시킴으로써 오폐수를 효율적으로 정화시킬 수 있는 난분해성 오폐수 전처리시스템을 제공하는 데 있다.It is an object of the present invention to provide a micro-substance filtration tank having a high-speed solid-liquid separator and a membrane unit in parallel with an electrolytic device and an electrocoagulation device for more efficient treatment in a simple system configuration. Which is capable of effectively purifying wastewater by combining the wastewater and the waste water.

본 발명의 다른 목적은 멤브레인 유닛의 역세척을 효과적으로 수행함으로써 오랫동안 지속적으로 여과장치를 사용할 수 있도록 한 난분해성 오폐수 전처리시스템을 제공하는 데 있다.Another object of the present invention is to provide a degradable wastewater pre-treatment system that can effectively use a filtration device for a long time by effectively performing backwashing of a membrane unit.

상기 목적을 달성하기 위하여, 본 발명에 따른 난분해성 오폐수 전처리시스템은, 전기 화학적으로 폐수 중의 오염물을 처리하는 전기응집장치, 상기 전기응집장치로부터 오염물이 처리된 처리수를 산화 및 환원 반응에 의해 오염물질을 분해하여 처리하는 전기분해장치, 상기 전기응집장치 및 상기 전기분해장치로부터 전처리된 처리수로부터 찌꺼기, 침전물 또는 부유물을 처리하는 고액분리기, 및 연결유로에 의해 상기 고액분리기에 연결되어 미세물질을 여과하고 정제할 수 있는 미세물질 여과조를 포함하는 난분해성 오폐수 전처리시스템에 있어서,In order to achieve the above object, the present invention provides an electrolytic wastewater pretreatment system according to the present invention, comprising: an electrocoagulant for electrochemically treating contaminants in wastewater; A solid-liquid separator for treating residues, sediments or suspended matters from the treated water pretreated from the electrolytic apparatus, and a solid-liquid separator connected to the solid- A waste water pre-treatment system comprising a micro-substance filtration tank capable of filtration and purification,

상기 고액분리기는, 일측부에 오폐수가 유입되는 입구부와, 바닥면에는 침전슬러지를 배출하기 위한 제 1슬러지배출구를 구비하는 본체; 상기 본체의 내부를 제 1격실과 제 2격실로 구획하기 위하여, 상기 본체의 바닥부 중앙으로부터 상부까지 연장되어 설치되는 분리막부재; 상기 분리막부재의 상부측에 형성되어 처리수가 이동하는 이동유로; 및 상기 본체의 상부에 위치하고 일측이 힌지부에 힌지 회동가능하게 결합되어 개폐될 수 있는 개폐덮개부;를 포함하고,The solid-liquid separator includes a main body having an inlet portion for introducing wastewater into one side portion thereof and a first sludge discharge port for discharging the settling sludge on a bottom surface thereof; A separation membrane member extending from a center of the bottom of the main body to an upper portion thereof for partitioning the inside of the main body into a first compartment and a second compartment; A moving path formed on the upper side of the separation membrane member and through which the treated water moves; And an opening / closing lid which is located at an upper portion of the main body and which can be opened / closed by a hinge rotatably coupled to a hinge portion at one side,

상기 미세물질 여과조는, 하부에 슬러지를 배출하기 위한 제 2슬러지 배출구를 구비하는 하우징; 및 상기 하우징의 내부에 설치되는 멤브레인 유닛;을 포함하는 것을 특징으로 한다.The microfilter filtration tank comprises: a housing having a second sludge discharge port for discharging sludge at a lower portion thereof; And a membrane unit installed inside the housing.

상기 개폐덮개부는 상기 본체의 상부에 경사지도록 설치되는 것을 특징으로 한다.And the opening / closing lid portion is installed to be inclined at an upper portion of the main body.

상기 개폐덮개부의 일단에는 상기 개폐덮개부의 개폐를 감지하기 위한 감지센서가 더 설치되고,A sensing sensor for sensing opening / closing of the opening / closing lid is further provided at one end of the opening / closing lid,

상기 연결유로에는 처리수의 유동을 제한하기 위하여 상기 감지센서와 전기적으로 연결되는 솔레노이드밸브가 더 설치되는 것을 특징으로 한다.The connection passage is further provided with a solenoid valve electrically connected to the detection sensor to limit the flow of the process water.

상기 하우징의 바닥면에는 금속성분이 함유된 슬러지를 포집하기 위한 복수의 전자석을 더 설치하는 것을 특징으로 한다.And a plurality of electromagnets for collecting sludge containing a metal component are further provided on the bottom surface of the housing.

상기 멤브레인 유닛은, 여과수나 세정수가 충진될 수 있는 물탱크; 상기 물탱크에 저장된 여과수를 배출하거나 물탱크에 세정수를 충진하기 위한 출입구; 처리수를 여과하기 위해 상기 물탱크의 상부로부터 하부로 길게 설치되는 복수의 복수의 멤브레인 평막 모듈; 상기 각각의 멤브레인 평막 모듈을 지지하기 위한 지지프레임; 상기 물탱크와 연통하도록 설치되는 제 1유로관; 상기 지지프레임에 결합되는 제 2유로관; 및 상기 멤브레인 평막 모듈을 향하도록 상기 제 2유로관에 설치되는 복수의 산기관;을 포함하는 것을 특징으로 한다.The membrane unit may include: a water tank in which filtered water or washing water can be filled; An outlet for discharging the filtered water stored in the water tank or filling the water tank with washing water; A plurality of membrane flat membrane modules installed elongate from the top to the bottom of the water tank to filter the treated water; A support frame for supporting each of the membrane flat membrane modules; A first flow pipe installed to communicate with the water tank; A second flow pipe coupled to the support frame; And a plurality of acid pipes installed in the second flow pipe so as to face the membrane flat membrane module.

상기 산기관은 그 내부가 벤츄리관 구조로 형성되는 것을 특징으로 한다.And the air diffusing pipe is formed in a venturi pipe structure.

상기 멤브레인 유닛을 진동시키기 위하여 제 2유로관의 내부에 진동부재를 더 포함하며, Further comprising a vibrating member inside the second flow path tube for vibrating the membrane unit,

상기 진동부재는, 상기 제 2유로관 내벽 상하에 설치되는 베어링; 상기 베어링에 상하로 회전가능하게 설치되는 회전축; 및 상기 회전축의 중앙에 일체로 설치되는 편심회전체를 포함하는 것을 특징으로 한다.The vibration member may include: a bearing installed above and below the inner wall of the second flow pipe; A rotating shaft rotatably mounted on the bearing; And an eccentric rotation body integrally installed at the center of the rotation shaft.

상기 복수의 멤브레인 평막 모듈을 지그재그로 벤딩되도록 설치하기 위하여,In order to install the plurality of membrane flat membrane modules in a zigzag manner,

상기 멤브레인 평막 모듈의 상부쪽을 좌우로 수평이동시키기 위해 상기 멤브레인 평막 모듈의 상부쪽에 인접하여 설치되는 제 1수평이동장치; 상기 멤브레인 평막 모듈의 하부쪽을 좌우로 수평이동시키기 위해 상기 멤브레인 평막 모듈의 하부쪽에 인접하여 설치되는 제 2수평이동장치; 및 상기 제 1수평이동장치와 제 2수평이동장치를 좌우로 이동시키기 위해 그들과 각각 연동된 구동장치;를 더 포함하는 것을 특징으로 한다.A first horizontal moving device installed adjacent to an upper side of the membrane flat membrane module to horizontally move the upper side of the membrane flat membrane module horizontally; A second horizontal moving device installed adjacent to a lower side of the membrane flat membrane module to horizontally move the lower side of the membrane flat membrane module horizontally; And a driving device interlocked with the first horizontal moving device and the second horizontal moving device to move the first horizontal moving device and the second horizontal moving device to the left and right, respectively.

상기 제 1수평이동장치는, 각각의 멤브레인 평막 모듈의 상부쪽에 횡방향으로 설치되는 상부 위치이동바; 및 상기 상부 위치이동바들을 양측에서 종방향으로 길게 연결하는 상부지지로드;를 포함하고,The first horizontal movement device includes: an upper locating bar installed laterally on an upper side of each membrane flat membrane module; And an upper support rod for connecting the upper locating bars longitudinally from both sides,

상기 제 2수평이동장치는, 각각의 멤브레인 평막 모듈의 하부쪽에 횡방향으로 설치되는 하부 위치이동바; 및 상기 하부 위치이동바들을 양측에서 종방향으로 길게 연결하는 하부지지로드;를 포함하는 것을 특징으로 한다.The second horizontally moving device includes: a lower locating bar installed laterally on a lower side of each of the membrane flat membrane modules; And a lower support rod for connecting the lower locating bars longitudinally from both sides.

상기 제 1수평이동장치와 제 2수평이동장치는 상기 구동장치에 의해 상호간에 다른 위치에 위치하도록 설정되는 것을 특징으로 한다.And the first horizontal moving device and the second horizontal moving device are set to be located at different positions from each other by the driving device.

상기 상부 위치이동바와 하부 위치이동바는 각각 멤브레인 평막 모듈이 삽입될 수 있도록 한 쌍의 작동바 구조를 갖는 것을 특징으로 한다.The upper position movement bar and the lower position movement bar each have a pair of operation bar structures for inserting the membrane flat membrane module.

상기 상부 위치이동바와 하부 위치이동바는 각각 멤브레인 평막 모듈에 접하여 설치되는 하나의 작동바 구조를 갖는 것을 특징으로 한다.The upper position movement bar and the lower position movement bar each have one operation bar structure installed in contact with the membrane flat membrane module.

상기 고액분리기 이전에, 전기 화학적으로 폐수 중의 오염물을 처리하는 전기응집장치; 및 상기 전기응집장치로부터 오염물이 처리된 처리수를 산화 및 환원 반응에 의해 오염물질을 분해하여 처리하는 전기분해장치;를 더 포함하며,An electrocoagulation device for electrochemically treating contaminants in wastewater prior to the solid-liquid separator; And an electrolytic apparatus for decomposing and treating the pollutant by the oxidation and reduction reaction of the treated water treated with pollutants from the electrocoagulant,

상기 전기응집장치와 전기분해장치는 하나의 유닛에 두 개의 챔버로 구성되는 것을 특징으로 한다.The electrocoagulation device and the electrolytic device are each composed of two chambers in one unit.

본 발명에 따르면, 전기분해장치와 전기응집장치가 병렬로 구성된 처리부와, 고속 고액분리기와 멤브레인 유닛이 구비된 미세물질 여과조를 결합시킴으로써 오폐수를 효율적으로 정화시킬 수 있는 효과가 있다.According to the present invention, there is an effect that the wastewater can be efficiently purified by combining the treatment section in which the electrolytic apparatus and the electrocoagulation apparatus are arranged in parallel, and the micro-substance filtration tank equipped with the high-speed solid-liquid separator and the membrane unit.

본 발명에 따르면, 1차적으로 고액분리기를 통해서 부상슬러지와 침전슬러지를 제거하고, 2차적으로 미세물질이 함유된 처리수를 멤브레인 유닛과 전자석을 통해서 제거함으로써, 오폐수를 효과적으로 정화시킬 수 있는 장점이 있다.According to the present invention, the floating sludge and the precipitated sludge are primarily removed through the solid-liquid separator, and the treated water containing the fine material is removed through the membrane unit and the electromagnet to effectively purify the wastewater. have.

본 발명에 따르면, 미세물질 여과조의 멤브레인 유닛을 유지세정을 위하여 역세척을 할 때 산기관의 동작과 편심 회전체의 작동을 통해서 멤브레인에 부착된 이물질을 용이하게 세정할 수 있는 효과가 있다.According to the present invention, when the membrane unit of the microfluidic filtration tank is backwashed for the purpose of maintenance cleaning, the foreign matter adhering to the membrane can be easily cleaned through the operation of the air diffuser and the operation of the eccentric rotation body.

도 1은 본 발명에 따른 난분해성 오폐수 전처리시스템의 단면도이다.BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross-sectional view of a non-degradable wastewater treatment system according to the present invention; FIG.

도 2는 도 1에서 고액분리기를 확대하여 도시한 확대도이다.FIG. 2 is an enlarged view of the solid-liquid separator shown in FIG. 1; FIG.

도 3은 도 1에서 미세물질 여과조를 확대하여 도시한 확대도이다.FIG. 3 is an enlarged view showing an enlarged view of the micro-substance filtration tank in FIG.

도 4는 도 3의 미세물질 여과조에 사용되는 멤브레인 유닛의 다른 실시예를 도시한 단면도이다.Fig. 4 is a cross-sectional view showing another embodiment of the membrane unit used in the micro-substance filtration tank of Fig. 3;

[부호의 설명][Description of Symbols]

10: 물탱크 11: 출입구10: water tank 11: entrance

13: 산기관 15: 공기유로13: diffuser 15: air flow

20: 지지프레임 30: 멤브레인 유닛20: support frame 30: membrane unit

31: 멤브레인 평막 모듈 40: 제 1수평이동장치31: membrane flat membrane module 40: first horizontal moving device

41: 상부 위치이동바 43: 상부지지로드41: upper locating bar 43: upper retaining rod

50: 제 2수평이동장치 51: 하부 위치이동바50: second horizontal moving device 51: lower position moving bar

53: 하부지지로드 100: 고액분리기53: lower support rod 100: solid-liquid separator

110: 본체 111: 입구부110: main body 111:

113: 제 1슬러지배출구 120: 분리막부재113: first sludge discharge port 120: separation membrane member

125: 이동유로 130: 개폐덮개부125: moving passage 130: opening / closing lid

135: 감지센서 140: 솔레노이드밸브135: Detection sensor 140: Solenoid valve

150: 연결유로 200: 미세물질 여과조150: connection flow passage 200: micro-substance filtration tank

210: 하우징 220: 전자석210: housing 220: electromagnet

250: 진동부재 251: 회전축250: Oscillating member 251:

253: 베어링 255: 편심회전체253: bearing 255: eccentric rotation body

이하, 첨부된 도면을 참조하여 본 발명에 따른 난분해성 오폐수 전처리시스템에 대하여 상세히 설명한다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명에 따른 난분해성 오폐수 전처리시스템의 단면도이고, 도 2는 도 1에서 고액분리기를 확대하여 도시한 확대도이며, 도 3은 도 1에서 미세물질 여과조를 확대하여 도시한 확대도이다.FIG. 1 is an enlarged cross-sectional view of a non-degradable wastewater treatment system according to the present invention, FIG. 2 is an enlarged view of the solid-liquid separator in FIG. 1, and FIG. 3 is an enlarged view of the micro- .

도 1 내지 도 3에 도시된 바와 같이, 본 발명에 따른 난분해성 오폐수 전처리시스템은 전기 화학적으로 폐수 중의 오염물을 처리하는 전기응집장치(400), 상기 전기응집장치(400)로부터 오염물이 처리된 처리수를 산화 및 환원 반응에 의해 오염물질을 분해하여 처리하는 전기분해장치(500), 상기 전기응집장치(400) 및 상기 전기분해장치(500)로부터 전처리된 처리수로부터 찌꺼기, 침전물 또는 부유물을 처리하는 고액분리기(100), 및 상기 고액분리기(100)에 연결되어 미세물질을 여과하고 정제할 수 있는 미세물질 여과조(200)를 포함한다.As shown in FIGS. 1 to 3, the pre-treatment system of the present invention includes an electrocoagulant 400 for electrochemically treating contaminants in wastewater, a treatment for treating contaminants from the electrocoagulant 400 An electrolytic apparatus 500 for decomposing and treating contaminants by oxidation and reduction of water, a method for treating residues, sediments, or suspended matters from the pretreatment water from the electrocoagulant 400 and the electrolytic apparatus 500 And a micro-substance filtration tank 200 connected to the solid-liquid separator 100 and capable of filtering and purifying micro-substances.

상기 전기응집장치(400)와 전기분해장치(500)는 오폐수를 여과하기 위한 전처리장치이다. 상기 전기응집장치(400)의 전기응집 반응은 전극에서 방출되는 전자의 교환에 의해 이온성 물질의 염으로의 석출 및 floc의 성장을 가속화함으로써 오염물질을 처리하는 방법이고, 상기 전기분해장치(500)의 전기분해 반응은 폐수에 직류전원을 통전 시킬 때 발생하는 산화 및 환원 반응에 의해 각종 오염물질을 분해함으로써 오염물질을 처리하는 방법이다.The electrocoagulation device 400 and the electrolytic device 500 are pretreatment devices for filtering wastewater. The electrocoagulation reaction of the electrocoagulation device 400 is a method of treating contaminants by accelerating the precipitation of the ionic substance into a salt and the growth of floc by the exchange of electrons emitted from the electrode, ) Is a method of treating pollutants by decomposing various pollutants by oxidation and reduction reactions that occur when DC power is supplied to the wastewater.

상기 전기응집장치(400)는 오폐수 원수가 유입되어 충진되는 탱크와, 그 내부에 설치되는 전기응집 제어패널, 및 상기 전기응집 제어패널에 전원을 공급하기 위한 전원공급장치를 포함한다. 상기 전원공급장치로부터 공급되는 전원의 극성은 상황에 따라서 자동으로 반대의 극성으로 바뀔 수 있으며, 이를 통해서 응집물이 형성되거나, 응집물을 분리시켜 배출할 수 있는 것이다.The electrocoagulation device 400 includes a tank filled with raw wastewater and filled with water, an electrocoagulation control panel installed in the tank, and a power supply device for supplying power to the electrocoagulation control panel. The polarity of the power supplied from the power supply device can be automatically changed to the opposite polarity depending on the situation, and the aggregate can be formed or the aggregate can be separated and discharged.

상기 전기응집장치(400)는 내부에 DC전원을 공급함으로써, The electrocoagulation apparatus 400 supplies DC power to the inside of the apparatus,

a) 전극표면에서의 전기화학 반응a) electrochemical reaction at the electrode surface

b) 액상에서의 응집 형성b) Formation of coagulation in liquid phase

c) 응집물에서 용해성 콜로이달 오염물의 흡착 후 침전 혹은 부상에 의한 제거 등과 같은 과정을 통해서 오염물질을 제거할 수 있는 것이다.c) It is possible to remove contaminants through processes such as sedimentation or removal by float after adsorption of soluble colloidal contaminants in the agglomerates.

상기 공정에서 발생하는 혼합물은 자연상태의 전기응집 화합물을 만들어 내며 알루미늄 혹은 철 산화전극은 다시 사용된다.The mixture produced in this process produces a naturally occurring electrocoagulant and the aluminum or iron oxide electrode is reused.

전극의 주요 화학 반응은 The main chemical reactions of the electrode

Al --> Al3+(aq) + 3 e- (양극)Al -> Al 3+ (aq) + 3 e - (anode)

3H2O + 3 e- --> 3/2H2 + 3OH- (음극)3H 2 O + 3 e - -> 3 / 2H 2 + 3OH - (cathode)

양극의 포텐션이 충분히 높다면 폐수 내에 존재하고 있는 유기화합물 및 염소이온의 직접 산화 같은 2차 반응이 일어날 수 있습니다. If the anode potential is high enough, secondary reactions such as direct oxidation of organic compounds and chlorine ions present in the wastewater can occur.

2Cl- --> Cl2 + 2e- 2Cl - -> Cl 2 + 2e -

생성된 염소는 유기화합물을 산화시킬 수 있고 전극반응을 촉진시킬 수 있는 강력한 산화제로 작용합니다. 또한, 음극은 높은 pH 값에서 수소가스 생성 중 수산화 이온에 의해 화학반응을 일으킵니다.The resulting chlorine can oxidize the organic compounds and acts as a powerful oxidizer that can promote electrode reactions. In addition, the cathode causes a chemical reaction at the high pH value by the hydroxide ion during hydrogen gas production.

2Al + 6H2O + 2OH- --> 2Al(OH)4- + 3H2 2Al + 6H 2 O + 2OH - -> 2Al (OH) 4- + 3H 2

상기의 전극반응에 의해 생성된 Al3 +(aq) 및 OH- 이온은 다양한 이온들을 형성하게 됩니다. Al(OH)2 +, Al(OH)2 +, Al2(OH)2 4 +, Al(OH)4 -, Al6(OH)15 3 +, Al7(OH)17 4 +, Al8(OH)20 4+ , Al13O4(OH)24 7 + , Al13(OH)34 5 + 와 같이 형성된 이온들은 화합물의 침전역학에 의해 최종적으로 Al(OH)3 로 변환됩니다.Al 3 + (aq) and OH - ions produced by the above electrode reaction form various ions. Al (OH) 2 +, Al (OH) 2 +, Al 2 (OH) 2 4 +, Al (OH) 4 -, Al 6 (OH) 15 3 +, Al 7 (OH) 17 4 +, Al 8 (OH) 20 4+ , Al 13 O 4 (OH) 24 7 + , Al 13 (OH) 34 5 + are finally converted to Al (OH) 3 by the precipitation dynamics of the compound.

다른 한편으로 전기적으로 발생한 철 이온은 수산화 및 고분자형 이온들과 함께 pH의 범위에 따라 다양한 이온들을 형성하고 FeOH2 +, Fe(OH)2 +, Fe2(OH)2 4 +, Fe(OH)4 -, Fe(H2O)2 +, Fe(H2O)5OH2 +, Fe(H2O)4(OH)2 +, Fe(H2O)8(OH)2 4 +, Fe2(H2O)6(OH)4 4 + ㅇ와 같이 형성된 이온들은 최종적으로 Fe(OH)3로 변환됩니다. Ferrous ions generated by the electrical on the other hand, to form a variety of ions, depending on the range of pH with hydroxide and polymer type ion FeOH 2 +, Fe (OH) 2 +, Fe 2 (OH) 2 4 +, Fe (OH ) 4 -, H 2 O ( Fe) 2 +, Fe (H 2 O) 5 OH 2 +, H 2 O (Fe) 4 (OH) 2 +, Fe (H 2 O) 8 (OH) 2 4 + , And Fe 2 (H 2 O) 6 (OH) 4 4 + ㅇ ultimately convert to Fe (OH) 3 .

또한, 상기 전기분해장치(500)는 상기 전기응집장치(400)로부터 오염물질 처리가 완료된 처리수를 전기분해하여 오염물질을 처리하는 것으로서, 전극(510, 520)이 설치되어 있다.In addition, the electrolytic apparatus 500 is provided with electrodes 510 and 520 for treating pollutants by electrolyzing the polluted-treatment-treated water from the electrocoagulation apparatus 400.

유기물질의 전기분해는 양극에서 산화되지만 물의 전기분해에 의한 수산화 이온이 전극표면에 흡착되어 유기물을 산화하는 직접산화와 염소의 전기분해에 의해 생성된 하이포아염소산 등의 중간산물에 의한 간접산화로 구분 할 수 있다.The electrolysis of the organic material is oxidized at the anode but the indirect oxidation by intermediate products such as hypochlorous acid produced by the direct oxidation which oxidizes the organic matter and the electrolysis of chlorine, Can be distinguished.

① 직접산화① direct oxidation

유기물질(R)은 산화성 양극에 흡착된 수산화 이온과 반응하여 이산화탄소, 물 혹은 수소이온으로 분해된다.The organic material (R) reacts with hydroxide ions adsorbed on the oxidizing anode and decomposes into carbon dioxide, water or hydrogen ions.

R + MOx[OH]2 → CO2 + zH+ + ze- + MOx (MOx: 양극) R + MOx [OH] 2 → CO 2 + zH + + ze- + MOx (MOx: anode)

② 간접산화② indirect oxidation

간접산화로 제거되는 유기물질의 전기 화학반응은 전기 분해중 염소의 양극산화가 동시에 발생하며 하이포아 염소산이 전극표면에 형성된다.The electrochemical reaction of the organic material removed by indirect oxidation occurs simultaneously with anodic oxidation of chlorine during electrolysis and hypochlorous acid is formed on the electrode surface.

음극에서 발생하는 수소에 의하여 수중의 유기물질이 환원되기도 하며 산화형 색소 등은 쉽게 환원되어 무색이 된다.Organic substances in the water are reduced by hydrogen generated in the cathode, and oxidized pigments are easily reduced and become colorless.

또한, 상기 고액분리기(100)와 미세물질 여과조(200)는 연결유로(150)에 의해 연결되며, 상기 연결유로(150)에는 유로의 개폐를 위한 솔레노이드밸브(140)가 설치된다. 상기 연결유로(150)는 상기 고액분리기(100)의 하단으로부터 연결되는 것이 바람직하다.The solid-liquid separator 100 and the micro-substance filtration tank 200 are connected to each other by a connection passage 150, and a solenoid valve 140 for opening and closing the passage is installed in the connection passage 150. The connection passage 150 is preferably connected to the lower end of the solid-liquid separator 100.

상기 고액분리기(100)는 일측부에 오폐수가 유입되는 입구부(111)를 구비하고 바닥면에는 침전슬러지(70)를 배출하기 위한 제 1슬러지배출구(113)를 구비하는 본체(110)를 포함한다. The solid-liquid separator 100 includes a main body 110 having an inlet portion 111 through which wastewater flows into the one side portion and a first sludge discharge port 113 through which bottom side a sedimentation sludge 70 is discharged do.

상기 본체(110)는 그 바닥부 중앙으로부터 상부까지 연장되어 설치되는 분리막부재(120)를 포함한다. 상기 분리막부재(120)는 격벽 구조로서 고액분리를 하기 위해 필요한 것이며, 본체(110)의 내부를 제 1격실(161)과 제 2격실(163)로 구획을 하고 있다. 상기 분리막부재(120)의 상부측에는 이동유로(125)가 형성되어 있으며, 상기 이동유로(125)는 상기 제 1격실(161)에서 1차적으로 슬러지들이 걸러진 처리수를 제 2격실(163)로 이동시킬 수 있다.The main body 110 includes a separation membrane member 120 extending from the center of the bottom portion to the top thereof. The separation membrane member 120 is a partition wall structure necessary for solid-liquid separation. The interior of the body 110 is divided into a first compartment 161 and a second compartment 163. A moving passage 125 is formed on the upper side of the separation membrane member 120. The moving passage 125 is formed in the second compartment 163 with treated water primarily sludge- Can be moved.

상기 본체(110)의 상부에는 개폐덮개부(130)가 힌지부(133)에 힌지 회동가능하게 결합되어 있다. 상기 개폐덮개부(130)는 상기 본체(110)에 경사지도록 설치되는 것이 바람직한데, 상기 본체(110)의 후방벽이 전방벽보다 높게 배치되어 있어서 상기 개폐덮개부(130)가 상기 본체(110)의 상부에 설치될 수 있다.On the upper portion of the main body 110, an opening / closing lid 130 is hingedly coupled to the hinge 133. The opening and closing lid 130 may be inclined to the main body 110. The rear wall of the main body 110 is disposed higher than the front wall so that the opening / As shown in FIG.

또한, 상기 개폐덮개부(130)의 일단에는 상기 개폐덮개부(130)의 개폐를 감지하기 위한 감지센서(135)를 설치할 수 있다. 상기 감지센서(135)는 상기 연결유로(150)에 설치된 솔레노이드밸브(140)와 전기적으로 연결되어 있다.In addition, a sensing sensor 135 may be installed at one end of the opening / closing lid 130 to detect opening / closing of the opening / closing lid 130. The sensing sensor 135 is electrically connected to a solenoid valve 140 installed in the connection passage 150.

즉, 상기 감지센서(135)가 상기 개폐덮개부(130)의 개방을 감지하게 되면, 상기 솔레노이드밸브(140)를 열어주어서, 상기 제 2격실(163)에 충진되어 있던 처리수가 연결유로(150)를 경유하여 미세물질 여과조(200)로 이동하게 된다. 반대로, 상기 감지센서(135)가 상기 개폐덮개부(130)의 폐쇄를 감지하게 되면, 상기 솔레노이드밸브(140)를 닫아서, 상기 연결유로(150)를 폐쇄시키게 된다. 이렇게 연결유로(150)가 폐쇄되면, 상기 고액분리기(100) 내부에 오폐수 및 처리수가 충진되게 되고, 충진됨과 동시에 본체(110) 내부에 고압의 압력이 생성되는 것이다.That is, when the sensing sensor 135 senses the opening of the opening / closing lid 130, the solenoid valve 140 is opened so that the treated water filled in the second compartment 163 flows into the connecting passage 150 To the microfilter filtration tank 200 via the second filter (not shown). On the contrary, when the detection sensor 135 senses the closing of the opening / closing lid 130, the solenoid valve 140 is closed to close the connecting flow channel 150. When the connection passage 150 is closed, the wastewater and process water are filled in the solid-liquid separator 100, and a high-pressure pressure is generated inside the main body 110 at the same time.

이런 상황에서, 상기 제 1격실(161) 내부에 충진된 오폐수에서 물에 뜨는 불순물들과 같은 부상슬러지(80)는 상부로 부유하게 되고, 찌꺼기나 침전슬러지와 같은 것들은 바닥면으로 가라앉게 되는 것이다.In such a situation, floating sludge 80 such as impurities floating in water in the wastewater filled in the first compartment 161 floats to the top, and such as debris or sediment sludge sinks to the bottom surface .

결국, 부상슬러지(80)는 상기 개폐덮개부(130)를 밀고 올라가서 외부로 배출되고, 상기 침전슬러지(70)는 제 1슬러지배출구(113)을 통해서 외부로 배출될 수 있는 것이다.As a result, the floating sludge 80 pushes the opening / closing lid 130 and is discharged to the outside, and the settling sludge 70 can be discharged to the outside through the first sludge discharging opening 113.

이와 같이, 고액분리기(100)에서는 오폐수 중에서 부상슬러지(80)와 침전슬러지(70)가 1차로 제거될 수 있고, 큰 슬러지들이 제거된 미세물질은 처리수와 함께 미세물질 여과조(200)로 이송되어 2차로 여과됨으로써 정제수를 얻을 수 있는 것이다.Thus, in the solid-liquid separator 100, the floating sludge 80 and the settling sludge 70 can be primarily removed from the wastewater, and the fine material from which the large sludges have been removed is transferred to the micro-substance filtering tank 200 together with the treated water And then filtered to obtain purified water.

또한, 상기 미세물질 여과조(200)는 하부에 슬러지를 배출하기 위한 제 2슬러지 배출구(215)가 형성된 하우징(210)을 포함한다. 상기 제 2슬러지 배출구(215)는 슬러지의 배출을 용이하게 하기 위하여 깔대기 모양으로 형성되는 것이 바람직하다.In addition, the microfilter filtration tank 200 includes a housing 210 having a second sludge discharge port 215 for discharging sludge thereunder. The second sludge outlet 215 is preferably formed in a funnel shape to facilitate discharge of the sludge.

상기 하우징(210)의 경사진 바닥면에는 전자석(220)이 복수개 설치될 수 있다. 상기 전자석(220)은 처리수 중에 포함되어 있는 철과 같은 금속성분이 함유된 슬러지를 포집하는 역할을 한다. 상기 전자석(220)에 포집된 금속함유 슬러지들은 멤브레인 평막모듈의 역세척 시에 자성을 제거함으로써 멤브레인 평막모듈에서 탈리된 슬러지들과 함께 배출시킬 수 있다.A plurality of electromagnets 220 may be installed on the inclined bottom surface of the housing 210. The electromagnet 220 serves to collect sludge containing a metal component such as iron contained in the treated water. The metal-containing sludge collected in the electromagnet 220 may be discharged together with sludges desorbed from the membrane flat membrane module by removing magnetism during backwashing of the membrane flat membrane module.

도 3에 도시된 바와 같이, 상기 하우징(210)의 내부에는 멤브레인 유닛(30)이 설치된다.As shown in FIG. 3, a membrane unit 30 is installed in the housing 210.

상기 멤브레인 유닛(30)은 여과수나 세정수가 충진될 수 있는 물탱크(10) 및 상기 물탱크(10)에 저장된 여과수를 배출하거나 물탱크(10)에 세정수를 충진하기 위한 출입구(11)를 포함한다.The membrane unit 30 includes a water tank 10 through which filtered water or washing water can be filled and an inlet 11 for discharging filtered water stored in the water tank 10 or filling the water tank 10 with washing water .

본 발명의 멤브레인 유닛(30)은 복수의 멤브레인 평막 모듈(31)이 상기 물탱크(10)의 상부로부터 하부로 길게 설치되는 것을 포함한다. The membrane unit (30) of the present invention includes a plurality of membrane flat membrane modules (31) extended from the upper part to the lower part of the water tank (10).

즉, 상기 각각의 멤브레인 평막 모듈(31)의 하측부는 별도의 지지프레임에 지지되도록 설치된다.That is, the lower portion of each membrane flat membrane module 31 is installed to be supported by a separate support frame.

상기 멤브레인 평막 모듈(31)의 하측부에는 복수의 산기관(13)이 설치되는데, 상기 산기관(13)은 상기 멤브레인 평막 모듈(31)의 하부측에 인접하게 설치되는 것이 바람직하다. 상기 산기관(13)은 제2유로관(15)에 설치되어서 외부로부터 유입된 공기를 멤브레인 유닛(30)으로 분출시킬 수 있는 것이다. 이렇게 분출된 공기는 멤브레인 평막 모듈(31)을 세척할 수도 있고, 동시에 수처리 장치가 설치된 수조의 물 용존 산소량을 유지시킬 수도 있는 것이다.A plurality of air diffusers 13 are installed on the lower side of the membrane flat membrane module 31. The air diffusers 13 are preferably installed adjacent to the lower side of the membrane flat membrane module 31. [ The air diffusing pipe 13 is installed in the second flow pipe 15 so that the air introduced from the outside can be blown into the membrane unit 30. The air thus blown can clean the membrane flat membrane module 31 and at the same time maintain the water dissolved oxygen amount of the water tank equipped with the water treatment device.

상기 산기관(13)은 그 내부 구조가 벤츄리관 구조(18)로 형성됨으로써, 물방울을 미세한 버블 형태로 분출할 수 있도록 하는 것이 바람직하다. It is preferable that the air diffusing pipe 13 is formed of a venturi pipe structure 18 so that the water droplets can be ejected in the form of a fine bubble.

상기 산기관(13)이 설치된 제 2유로관(282)의 내부에는 다수의 진동부재(250)가 설치될 수 있다. 상기 진동부재(250)가 제 2유로관(282)의 내부에서 진동을 발생시킴으로써, 상기 제 2유로관(282)이 연결된 멤브레인유닛(30)이 진동하게 되고, 그에 따라 멤브레인 평막모듈(31)에 부착된 이물질들이 용이하게 떨어질 수 있는 것이다.A plurality of vibration members 250 may be installed in the second flow pipe 282 provided with the air diffuser 13. The membrane unit 30 to which the second flow pipe 282 is connected is vibrated by causing the vibration member 250 to vibrate in the second flow pipe 282, The foreign substances adhered to the surface of the substrate can be easily dropped.

상기 진동부재(250)는 제 2유로관(282)의 내부에 설치되는 것으로서, 제 2유로관(282) 내벽 상하에 설치되는 베어링(253), 상기 베어링(253)에 상하로 회전가능하게 설치되는 회전축(251) 및 상기 회전축의 중앙에 일체로 설치되는 편심회전체(255)를 포함한다.The vibration member 250 is installed inside the second flow pipe 282 and includes a bearing 253 installed above and below the inner wall of the second flow pipe 282, And an eccentric rotation body 255 integrally provided at the center of the rotation shaft.

따라서, 역세수가 공급될 때 수압에 의해서 상기 편심회전체(255)가 회전을 하게 되고, 그에 결합된 상기 회전축(251)이 회전을 하게 되면서, 편심회전체(255)에 의한 진동이 발생하게 된다. 그러면, 상기 제 2유로관(282)이 진동하게 되고, 그가 결합된 멤브레인 유닛(30)이 진동하게 되는 것이다.Accordingly, when the backwash water is supplied, the eccentric rotation body 255 is rotated by the water pressure, and the rotation shaft 251 coupled thereto is rotated, and the vibration by the eccentric rotation body 255 is generated . Then, the second flow pipe 282 vibrates, and the membrane unit 30 to which the second flow pipe 282 is coupled vibrates.

상기 산기관(13)이나 상기 진동부재(250)는 멤브레인 유닛(30)이 정상적인 정화 및 여과 동작을 할 때에는 작동을 하지 않고, 멤브레인 평막모듈(31)에 부착된 이물질을 제거하기 위하여 역세척을 수행할 때에만 작동을 시키는 것이다.The air diffuser 13 and the vibrating member 250 do not operate when the membrane unit 30 performs a normal purification and filtration operation and perform backwashing to remove foreign substances adhered to the membrane flat membrane module 31 And only when it is done.

즉, 역세척을 위해서 상기 삼방밸브(285)를 양측으로 개방하여 제 1유로관(281)과 제 2유로관(282)으로 역세수가 공급된다. 제 1유로관(281)으로 공급된 역세수는 물탱크(10)를 경유하여 멤브레인 평막모듈(31)의 내부로 공급되어 멤브레임 모듈(31)의 미세공을 통과해 미세물질 여과조(200) 내부로 배출된다. 이러한 역세수의 작용에 의해서 상기 멤브레인 평막모듈(31)에 부착된 이물질들이 1차적으로 제거될 수 있는 것이다.That is, in order to backwash, the three-way valve 285 is opened to both sides and the backwash water is supplied to the first flow pipe 281 and the second flow pipe 282. The backwash water supplied to the first flow pipe 281 is supplied to the inside of the membrane flat membrane module 31 via the water tank 10 and passes through the micropores of the membrane module 31 to the microfluidic filtration tank 200, . The foreign matter adhering to the membrane flat membrane module 31 can be primarily removed by the action of the reverse water wash.

또한, 제 2유로관(282)로 공급된 역세수는 산기관(13)을 통해서 미세 버블 형태로 분출이되어서 이물질을 제거할 수 있고, 상기 진동부재(250)를 작동시켜서 멤브레인 유닛(30)에 진동을 가함으로써 이물질을 제거할 수 있다. 이렇게 산기관(13)과 진동부재(250)를 통해서 2차적으로 이물질을 제거할 수 있는 것이다.The circulating water supplied to the second flow pipe 282 is blown out in the form of fine bubbles through the air diffuser 13 to remove foreign substances and the vibrating member 250 is operated to move the membrane unit 30, So that foreign matter can be removed. The foreign substance can be removed secondarily through the acid pipe 13 and the vibration member 250.

도 4는 본 발명의 다른 실시예에 따른 멤브레인 유닛을 도시한 단면도이다.4 is a cross-sectional view of a membrane unit according to another embodiment of the present invention.

도 4에 도시된 바와 같이, 상기 복수의 멤브레인 평막 모듈(31)을 지그재그로 벤딩되도록 설치하기 위하여, 멤브레인 평막 모듈(31)의 상부쪽에 제 1수평이동장치(40)가 설치되고, 멤브레인 평막 모듈(31)의 하부쪽에 제 2수평이동장치(50)가 설치된다.As shown in FIG. 4, in order to zigzag bend the plurality of membrane flat membrane modules 31, a first horizontal moving device 40 is installed on the upper side of the membrane flat membrane module 31, And a second horizontal movement device 50 is installed on the lower side of the second horizontal movement device 31.

상기 제 1수평이동장치(40)는 각각의 멤브레인 평막 모듈(31)의 상부쪽에 횡방향으로 설치되는 상부 위치이동바(41)와, 복수의 상기 상부 위치이동바(41)들을 양측에서 종방향으로 길게 연결하는 상부지지로드(43)를 포함한다.The first horizontally moving device 40 includes an upper locating bar 41 installed laterally on the upper side of each membrane flat membrane module 31 and a plurality of upper locating bars 41 extending in the longitudinal direction And an upper support rod 43 for connecting the upper support rod 43 and the upper support rod 43 to each other.

이때, 상기 상부 위치이동바(41)는 한 쌍의 작동바 구조를 갖는 것으로서, 상기 멤브레인 평막 모듈(31)이 상기 한 쌍의 작동바 사이에 끼워지는 형태로 구성될 수 있다.At this time, the upper locating bar 41 has a pair of operating bar structures, and the membrane flat membrane module 31 can be configured to be sandwiched between the pair of operating bars.

이렇게 하면, 상기 복수의 멤브레인 평막 모듈(31) 각각은 그들이 삽입된 상부 위치이동바(41)에 의해 위치가 결정되며, 동시에 동일한 형태를 취할 수 있는 것이다.In this way, each of the plurality of membrane flat membrane modules 31 is positioned by the upper locating bar 41 into which they are inserted, and can take the same shape at the same time.

마찬가지로, 상기 제 2수평이동장치(50)는 각각의 멤브레인 평막 모듈(31)의 하부쪽에 횡방향으로 설치되는 하부 위치이동바(51)와, 복수의 상기 하부 위치이동바(51)들을 양측에서 종방향으로 길게 연결하는 하부지지로드(53)를 포함한다.Similarly, the second horizontal movement device 50 includes a lower position movement bar 51 installed laterally on the lower side of each membrane flat membrane module 31, and a plurality of lower position movement bars 51 on both sides And a lower support rod 53 which is connected in a longitudinal direction.

이때, 상기 하부 위치이동바(51)는 한 쌍의 작동바 구조를 갖는 것으로서, 상기 멤브레인 평막 모듈(31)이 상기 한 쌍의 작동바 사이에 끼워지는 형태로 구성될 수 있다.At this time, the lower position shifting bar 51 has a pair of operating bar structures, and the membrane flat membrane module 31 may be configured to be sandwiched between the pair of operating bars.

이렇게 하면, 상기 복수의 멤브레인 평막 모듈(31) 각각은 그들이 삽입된 하부 위치이동바(51)에 의해 위치가 결정되며, 동시에 동일한 형태를 취할 수 있는 것이다.In this way, each of the plurality of membrane flat membrane modules 31 is positioned by the lower locating bar 51 into which they are inserted, and can assume the same shape at the same time.

이런 구조에서, 상기 제 1수평이동장치(40)와 제 2수평이동장치(50)는 각각 구동장치(23)에 연결되어 병진운동할 수 있으며, 상기 제 1수평이동장치(40)와 제 2수평이동장치(50)는 상호간에 다른 위치에 위치하도록 설정되는 것이 바람직하다.In this structure, the first horizontal moving device 40 and the second horizontal moving device 50 are connected to the driving device 23 and can translate, respectively. The first horizontal moving device 40 and the second horizontal moving device 50 It is preferable that the horizontal movement devices 50 are set to be located at mutually different positions.

즉, 제 1수평이동장치(40)가 구동장치(23)에 의해서 멤브레인 평막 모듈(31)을 밀어서 위치시키면, 제 2수평이동장치(50)는 구동장치(23)에 의해서 멤브레인 평막 모듈(31)을 잡아당겨서 위치시키도록 설정되는 것이다.That is, when the first horizontal moving device 40 pushes and places the membrane flat membrane module 31 by the driving device 23, the second horizontal moving device 50 is moved by the driving device 23 to the membrane flat membrane module 31 To be pulled and positioned.

이렇게 하면, 최종적으로 상기 멤브레인 평막 모듈(31)은 지그재그 형태로 벤딩되어 위치할 수 있는 것이다.In this way, the membrane flat membrane module 31 can finally be bent in a zigzag form.

또한, 멤브레인 평막 모듈(31)의 효과적인 세척을 위해서 구동장치(23)를 반대로 작동시켜서 상기 제 1수평이동장치(40)과 제 2수평이동장치(50)의 상호간의 위치를 변경시킬 수도 있는 것이다.It is also possible to reverse the position of the first horizontal moving device 40 and the second horizontal moving device 50 by operating the driving device 23 in reverse for effective cleaning of the membrane flat membrane module 31 .

한편, 본 발명은 상술한 실시 예 및 첨부된 도면에 의해 한정되는 것이 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위 안에서 예시되지 않은 여러 가지 변형과 응용이 가능함은 물론 구성요소의 치환 및 균등한 타실시 예로 변경할 수 있으므로 본 발명의 특징에 대한 변형과 응용에 관계된 내용은 본 발명의 범위 내에 포함되는 것으로 해석되어야 할 것이다.While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (13)

전기 화학적으로 폐수 중의 오염물을 처리하는 전기응집장치, 상기 전기응집장치로부터 오염물이 처리된 처리수를 산화 및 환원 반응에 의해 오염물질을 분해하여 처리하는 전기분해장치, 상기 전기응집장치 및 상기 전기분해장치로부터 전처리된 처리수로부터 찌꺼기, 침전물 또는 부유물을 처리하는 고액분리기, 및 연결유로에 의해 상기 고액분리기에 연결되어 미세물질을 여과하고 정제할 수 있는 미세물질 여과조를 포함하는 난분해성 오폐수 전처리시스템에 있어서,An electrolytic apparatus for decomposing pollutants by oxidizing and reducing the treated water treated with pollutants from the electrocoagulant; and an electrolytic apparatus for electrolyzing the electrolytic water A solid-liquid separator for treating debris, sediment or suspended matter from the treated water pretreated from the apparatus, and a micro-substance filtration tank connected to the solid-liquid separator by the connection channel for filtration and purification of the micro-substance, As a result, 상기 고액분리기는,The solid- 일측부에 오폐수가 유입되는 입구부와, 바닥면에는 침전슬러지를 배출하기 위한 제 1슬러지배출구를 구비하는 본체;A main body having an inlet portion through which wastewater flows into the one side portion and a first sludge discharge port through which bottomsurface sludge is discharged; 상기 본체의 내부를 제 1격실과 제 2격실로 구획하기 위하여, 상기 본체의 바닥부 중앙으로부터 상부까지 연장되어 설치되는 분리막부재;A separation membrane member extending from a center of the bottom of the main body to an upper portion thereof for partitioning the inside of the main body into a first compartment and a second compartment; 상기 분리막부재의 상부측에 형성되어 처리수가 이동하는 이동유로; 및A moving path formed on the upper side of the separation membrane member and through which the treated water moves; And 상기 본체의 상부에 위치하고 일측이 힌지부에 힌지 회동가능하게 결합되어 개폐될 수 있는 개폐덮개부;를 포함하고,And an opening / closing lid which is located at an upper portion of the main body and which can be opened / closed by a hinge rotatably coupled to a hinge portion at one side, 상기 미세물질 여과조는,The micro- 하부에 슬러지를 배출하기 위한 제 2슬러지 배출구를 구비하는 하우징; 및And a second sludge discharge port for discharging the sludge to a lower portion thereof; And 상기 하우징의 내부에 설치되는 멤브레인 유닛;을 포함하는 것을 특징으로 하는 난분해성 오폐수 전처리시스템.And a membrane unit installed inside the housing. 제 1항에 있어서,The method according to claim 1, 상기 개폐덮개부는 상기 본체의 상부에 경사지도록 설치되는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. Wherein the opening / closing lid is installed on an upper portion of the main body in an inclined manner. 제 1항에 있어서,The method according to claim 1, 상기 개폐덮개부의 일단에는 상기 개폐덮개부의 개폐를 감지하기 위한 감지센서가 더 설치되고,A sensing sensor for sensing opening / closing of the opening / closing lid is further provided at one end of the opening / closing lid, 상기 연결유로에는 처리수의 유동을 제한하기 위하여 상기 감지센서와 전기적으로 연결되는 솔레노이드밸브가 더 설치되는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. Wherein the connection passage is further provided with a solenoid valve electrically connected to the detection sensor to limit the flow of the process water. 제 1항에 있어서,The method according to claim 1, 상기 하우징의 바닥면에는 금속성분이 함유된 슬러지를 포집하기 위한 복수의 전자석을 더 설치하는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. And a plurality of electromagnets for collecting sludge containing a metallic component are further provided on the bottom surface of the housing. 제 1항에 있어서,The method according to claim 1, 상기 멤브레인 유닛은,The membrane unit comprises: 여과수나 세정수가 충진될 수 있는 물탱크;A water tank in which filtered water or washing water can be filled; 상기 물탱크에 저장된 여과수를 배출하거나 물탱크에 세정수를 충진하기 위한 출입구;An outlet for discharging the filtered water stored in the water tank or filling the water tank with washing water; 처리수를 여과하기 위해 상기 물탱크의 상부로부터 하부로 길게 설치되는 복수의 복수의 멤브레인 평막 모듈;A plurality of membrane flat membrane modules installed elongate from the top to the bottom of the water tank to filter the treated water; 상기 각각의 멤브레인 평막 모듈을 지지하기 위한 지지프레임;A support frame for supporting each of the membrane flat membrane modules; 상기 물탱크와 연통하도록 설치되는 제 1유로관;A first flow pipe installed to communicate with the water tank; 상기 지지프레임에 결합되는 제 2유로관; 및A second flow pipe coupled to the support frame; And 상기 멤브레인 평막 모듈을 향하도록 상기 제 2유로관에 설치되는 복수의 산기관;을 포함하는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. And a plurality of acid pipes installed in the second flow pipe so as to face the membrane flat membrane module. 제 5항에 있어서,6. The method of claim 5, 상기 산기관은 그 내부가 벤츄리관 구조로 형성되는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. Wherein the acid furnace is formed with a venturi pipe structure inside thereof. 제 5항에 있어서,6. The method of claim 5, 상기 멤브레인 유닛을 진동시키기 위하여 제 2유로관의 내부에 진동부재를 더 포함하며,Further comprising a vibrating member inside the second flow path tube for vibrating the membrane unit, 상기 진동부재는The vibrating member 상기 제 2유로관 내벽 상하에 설치되는 베어링;A bearing installed above and below the inner wall of the second flow pipe; 상기 베어링에 상하로 회전가능하게 설치되는 회전축; 및A rotating shaft rotatably mounted on the bearing; And 상기 회전축의 중앙에 일체로 설치되는 편심회전체를 포함하는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. And an eccentric rotation body integrally installed at the center of the rotary shaft. 제 5항에 있어서,6. The method of claim 5, 상기 복수의 멤브레인 평막 모듈을 지그재그로 벤딩되도록 설치하기 위하여,In order to install the plurality of membrane flat membrane modules in a zigzag manner, 상기 멤브레인 평막 모듈의 상부쪽을 좌우로 수평이동시키기 위해 상기 멤브레인 평막 모듈의 상부쪽에 인접하여 설치되는 제 1수평이동장치; A first horizontal moving device installed adjacent to an upper side of the membrane flat membrane module to horizontally move the upper side of the membrane flat membrane module horizontally; 상기 멤브레인 평막 모듈의 하부쪽을 좌우로 수평이동시키기 위해 상기 멤브레인 평막 모듈의 하부쪽에 인접하여 설치되는 제 2수평이동장치; 및A second horizontal moving device installed adjacent to a lower side of the membrane flat membrane module to horizontally move the lower side of the membrane flat membrane module horizontally; And 상기 제 1수평이동장치와 제 2수평이동장치를 좌우로 이동시키기 위해 그들과 각각 연동된 구동장치;를 더 포함하는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. Further comprising a drive unit interlocked with the first horizontal movement unit and the second horizontal movement unit to move the first horizontal movement unit and the second horizontal movement unit to the left and right, respectively. 제 8항에 있어서,9. The method of claim 8, 상기 제 1수평이동장치는,Wherein the first horizontal movement device comprises: 각각의 멤브레인 평막 모듈의 상부쪽에 횡방향으로 설치되는 상부 위치이동바; 및An upper locating bar disposed transversely to an upper side of each membrane flat membrane module; And 상기 상부 위치이동바들을 양측에서 종방향으로 길게 연결하는 상부지지로드;를 포함하고,And an upper support rod for connecting the upper locating bars longitudinally from both sides, 상기 제 2수평이동장치는,Wherein the second horizontal movement device comprises: 각각의 멤브레인 평막 모듈의 하부쪽에 횡방향으로 설치되는 하부 위치이동바; 및A lower locating bar installed transversely below the respective membrane flat membrane modules; And 상기 하부 위치이동바들을 양측에서 종방향으로 길게 연결하는 하부지지로드;를 포함하는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. And a lower support rod for connecting the lower locating bars longitudinally from both sides in a longitudinal direction. 제 9항에 있어서,10. The method of claim 9, 상기 제 1수평이동장치와 제 2수평이동장치는 상기 구동장치에 의해 상호간에 다른 위치에 위치하도록 설정되는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. Wherein the first horizontal moving device and the second horizontal moving device are set to be located at different positions by the driving device. 제 9항에 있어서,10. The method of claim 9, 상기 상부 위치이동바와 하부 위치이동바는 각각 멤브레인 평막 모듈이 삽입될 수 있도록 한 쌍의 작동바 구조를 갖는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. Wherein the upper locating bar and the lower locating bar each have a pair of operating bar structures for inserting the membrane flat membrane module. 제 9항에 있어서,10. The method of claim 9, 상기 상부 위치이동바와 하부 위치이동바는 각각 멤브레인 평막 모듈에 접하여 설치되는 하나의 작동바 구조를 갖는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. Wherein the upper position movement bar and the lower position movement bar each have one operation bar structure installed in contact with the membrane flat membrane module. 제 1항 내지 제 12항 중 어느 한 항에 있어서,13. The method according to any one of claims 1 to 12, 상기 고액분리기 이전에,Prior to the solid-liquid separator, 전기 화학적으로 폐수 중의 오염물을 처리하는 전기응집장치; 및An electrocoagulation device for electrochemically treating contaminants in wastewater; And 상기 전기응집장치로부터 오염물이 처리된 처리수를 산화 및 환원 반응에 의해 오염물질을 분해하여 처리하는 전기분해장치;를 더 포함하며,And an electrolytic device for decomposing and treating the pollutant by the oxidation and reduction reaction of the treated water treated with pollutants from the electrocoagulation device, 상기 전기응집장치와 전기분해장치는 하나의 유닛에 두 개의 챔버로 구성되는 것을 특징으로 하는 난분해성 오폐수 전처리시스템. Wherein the electrocoagulation device and the electrolytic device are composed of two chambers in one unit.
PCT/KR2018/015425 2017-12-06 2018-12-06 Nondegradable sewage/wastewater preprocessing system Ceased WO2019112340A1 (en)

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