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WO2019110092A1 - Composition de bulles - Google Patents

Composition de bulles Download PDF

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Publication number
WO2019110092A1
WO2019110092A1 PCT/EP2017/081580 EP2017081580W WO2019110092A1 WO 2019110092 A1 WO2019110092 A1 WO 2019110092A1 EP 2017081580 W EP2017081580 W EP 2017081580W WO 2019110092 A1 WO2019110092 A1 WO 2019110092A1
Authority
WO
WIPO (PCT)
Prior art keywords
exposing
atmosphere
weight
composition
become colourless
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2017/081580
Other languages
English (en)
Inventor
Jianing Chen
Liguan LIN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toys Trend Ltd
Original Assignee
Toys Trend Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toys Trend Ltd filed Critical Toys Trend Ltd
Priority to PCT/EP2017/081580 priority Critical patent/WO2019110092A1/fr
Publication of WO2019110092A1 publication Critical patent/WO2019110092A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0047—Other compounding ingredients characterised by their effect pH regulated compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Definitions

  • the present invention relates to a coloured bubble composition.
  • the present invention relates to an uniformly, non-toxic and washable coloured bubble composition which is excellent in formed richly and uniformly coloured bubbles and can become colourless itself along a brief environment exposure time.
  • Bubbles have been used on many occasions, from children's games to artistic expressions. Normally the have had a transparent colour.
  • compositions of coloured bubbles comprising at least water, a surfactant and a colorant.
  • the colorants are acid dyes, FD&C (food, drug and cosmetic) dyes, food dyes, polymeric dyes, pigments or a combination thereof.
  • Surfactants can be anionic surfactants, cationic surfactants, non-ionic surfactants and/or zwitter-ionic surfactants.
  • the composition can also comprise humectants, preservatives, fragrances, dye blockers or cleaners.
  • compositions obtained by this method provide a bubble that is a uniformly coloured, and are non-toxic and/or washable.
  • US patent 2012/003531 1A1 describes another composition to form coloured bubbles, which are obtained by mixing water, at least one humectant, and at least one water- soluble polymer to the mixture that may also function as a surfactant, a surfactant in addition to the water-soluble polymer and a colorant.
  • Surfactants can be anionic surfactants, cationic surfactants, non-ionic surfactants and/or zwitter-ionic surfactants.
  • Colorants are acid dyes, FD&C dyes, food dyes, polymeric dyes, fluorescent dyes, azo dyes pH indicator dyes, polymeric colorants or a combination thereof.
  • additives may be added to the composition including preservatives, fragrances, dye blockers, viscosity-inducing components, a suitable pH adjuster and/or small amount of organic solvents. That document also discloses a method to prepare the composition, that consist in mixing water, at least one humectant and at least one water soluble polymer to form a mixture and subsequently adding a colorant to the mixture. In an alternative method the mixture may be heated before adding the colorant, the humectant and the additional compounds.
  • the present invention discloses a composition that solves the problems mentioned above, and has a uniformly, non-toxic and washable coloured bubble composition which is excellent in formed richly and uniformly coloured bubbles and can turn into colourless by itself.
  • the present invention provides a composition for obtaining coloured bubbles, in which the colour fades away in the air so that they do not stain the surfaces on which they explode, thus being irrelevant the fact whether the surface is washable or not, such as that of a cloth.
  • a pH indicator causes the colour of the solution depending on the pH of the solution.
  • Other ways can be used to make colorant discolour in the air: oxidation bleaching with oxygen, photo degradation by sunlight and biodegradable by microorganisms, but these methods are too slow to be used as a substance for a toy, where the colour effect must be quickly obtained.
  • pH indicating dyes for obtaining coloured bubbles are normally not very soluble in water, and for the bubbles obtained to have a uniform and rich colour, a high concentration of the dye is necessary.
  • Alkanolamines are good solvents for some pH-indicating compounds. These compounds can increase the concentration of the pH indicator to form rich, uniformly coloured bubbles. Alkanolamines are also often used in industry as carbon dioxide absorbers. By absorbing carbon dioxide present in the air, they cause the pH of the mixture to decrease, causing the pH of the mixture to drop, thus causing the change of the colour of the pH indicator. In this way, afterfew minutes the colour effect of the pH indicator disappear because of the reduction of the pH value.
  • the concentration of the dye in the bubble wall is increased.
  • the mixture also contains a surfactant, for example, but not limited to, an anionic surfactant, cationic surfactant, non-ionic surfactant and zwitter-ionic surfactant.
  • a weakly cationic polymer with good compatibility with water, anionic and non- ionic surfactants avoid the necessity of heating the mixture to dissolve the compounds.
  • moisturizers it is not necessary to add moisturizers to the mixture, because adding humectants to the mixture will speed the discolouration of the bubble in the air.
  • the way to prepare the mixture is as follows. First, the pH indicator dye is dissolved in amino alcohol and a colour paste is formed. On the other hand, a mixture with purified water, some buffer solution and at least one preservative is formed. Then, at least one weakly cationic polymer and one surfactant are added to dissolve the mixture. Finally, the colour paste is added to the mixture.
  • the coloured bubble composition comprises water.
  • Water must be purified in order to prevent undesired substances from being found in it.
  • the amount of water from about 10% to 90% by weight, suitable ranges include from about 50% to 80% by weight, and in particular from 69.8% to 86.45% by weight.
  • a pH indicator causes the colour of the solution depending on the pH of the solution.
  • a solution with Phenolphthalein or its derivatives can change from colour to clear with the decrease of pH.
  • Representative examples include, but are not limited to, phenolphthalein, o-cresolpthalein, thymolphthalein or o Naphtholphthalein.
  • the amount of phenolphthalein or its derivatives from about 1 % to 15% by weight, suitable ranges include from about 2% to 10% by weight, and in particular from 4% to 8% by weight.
  • alkanolamines are good solvents for some pH-indicating compounds.
  • alkanolamines are good solvents for phenolphthalein and its derivatives. Adding alkanolamine compounds can increase the concentration of phenolphthalein or its derivatives to forme richly and uniformly coloured bubbles.
  • Representative examples of alkanolamine compounds include, but are not limited to, ethanolamine, diethanolamine, triethanolamine, propanol amine, Isopropanol amine and mixtures of these materials. Because of the non-toxicity of the product, the alkanolamine compounds is ethanolamine.
  • the amount of ethanolamine from about 0% to 10% by weight, suitable ranges include from about 0.1 % to 5% by weight, and particularly from 1 % to 3% by weight.
  • a Buffer Solution is used to maintain pH from 9 to 1 1.
  • the amount of Sodium Bicarbonate/Sodium Carbonate depends on the type of pH dye in a range from 0% to about 20% by weight, suitable ranges include from about 0.1 % to 15% by weight, and particularly from 1 % to 10% by weight.
  • a weakly cationic polymer is used to absorb the anionic colorant (phenolphthalein and its derivatives) to increase the concentration of colorant at the bubble wall.
  • the amount of the weakly cationic polymer from about 0.1 % to 5% by weight, suitable ranges include from about 0.2% to 2% by weight, and particularly from 0.5% to 1 % by weight.
  • the mixture also comprises preservatives.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition de bulles qui peut devenir incolore par exposition à l'atmosphère, qui comprend les composés suivants : de l'eau ; un tensioactif ; et un colorant ; un polymère ; des conservateurs. Cette composition est caractérisée en ce que le colorant est un colorant indicateur de pH anionique et le polymère est un polymère faiblement cationique ayant le pouvoir d'absorber le colorant anionique et en ce qu'elle comprend également une alcanolamine à double fonction : aider à solubiliser le colorant indicateur de pH et à absorber le dioxyde de carbone de l'air pour amener le pH du mélange à diminuer, de sorte que la couleur de l'indicateur de pH change.
PCT/EP2017/081580 2017-12-05 2017-12-05 Composition de bulles Ceased WO2019110092A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/EP2017/081580 WO2019110092A1 (fr) 2017-12-05 2017-12-05 Composition de bulles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2017/081580 WO2019110092A1 (fr) 2017-12-05 2017-12-05 Composition de bulles

Publications (1)

Publication Number Publication Date
WO2019110092A1 true WO2019110092A1 (fr) 2019-06-13

Family

ID=60935773

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2017/081580 Ceased WO2019110092A1 (fr) 2017-12-05 2017-12-05 Composition de bulles

Country Status (1)

Country Link
WO (1) WO2019110092A1 (fr)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2673640A1 (fr) * 1991-03-07 1992-09-11 Reckitt Colman Nouvelles compositions a usage menager, leur procede de preparation et leurs applications notamment dans le domaine de l'entretien menager.
US5929004A (en) * 1997-10-10 1999-07-27 No Touch North America Detergent for cleaning tire wheels and cleaning method
US20050076459A1 (en) * 2003-09-02 2005-04-14 Guardia Mario M. De La Compositions for neutralizing and coloring hair and methods thereof
WO2006105261A1 (fr) * 2005-03-29 2006-10-05 C2C Technologies Llc Compositions de nettoyage dotees d'un indicateur a changement de couleur
WO2006105191A2 (fr) * 2005-03-29 2006-10-05 C2C Technologies Llc Nouvelles compositions a indicateur changeant de couleur
US7910531B2 (en) 2004-06-17 2011-03-22 C2C Technologies Llc Composition and method for producing colored bubbles
US20120035311A1 (en) 2010-08-05 2012-02-09 Crayola, Llc Colored bubbles

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2673640A1 (fr) * 1991-03-07 1992-09-11 Reckitt Colman Nouvelles compositions a usage menager, leur procede de preparation et leurs applications notamment dans le domaine de l'entretien menager.
US5929004A (en) * 1997-10-10 1999-07-27 No Touch North America Detergent for cleaning tire wheels and cleaning method
US20050076459A1 (en) * 2003-09-02 2005-04-14 Guardia Mario M. De La Compositions for neutralizing and coloring hair and methods thereof
US7910531B2 (en) 2004-06-17 2011-03-22 C2C Technologies Llc Composition and method for producing colored bubbles
WO2006105261A1 (fr) * 2005-03-29 2006-10-05 C2C Technologies Llc Compositions de nettoyage dotees d'un indicateur a changement de couleur
WO2006105191A2 (fr) * 2005-03-29 2006-10-05 C2C Technologies Llc Nouvelles compositions a indicateur changeant de couleur
US20120035311A1 (en) 2010-08-05 2012-02-09 Crayola, Llc Colored bubbles

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ANONYMOUS: "colored_bubbles", INTERNET CITATION, 25 October 2006 (2006-10-25), XP002404490, Retrieved from the Internet <URL:http://www.geocities.com/bislz/index.html> [retrieved on 20061025] *
ANONYMOUS: "How To Make Colored Soap Bubbles", INTERNET CITATION, 25 October 2006 (2006-10-25), XP002404491, Retrieved from the Internet <URL:http://chemistry.about.com/od/chemistryhowtoguide/ht/colorbubble.htm> [retrieved on 20061025] *

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