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WO2019198104A1 - Adhésif incorporant des déchets cellulosiques non biodégradables - Google Patents

Adhésif incorporant des déchets cellulosiques non biodégradables Download PDF

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Publication number
WO2019198104A1
WO2019198104A1 PCT/IN2019/050297 IN2019050297W WO2019198104A1 WO 2019198104 A1 WO2019198104 A1 WO 2019198104A1 IN 2019050297 W IN2019050297 W IN 2019050297W WO 2019198104 A1 WO2019198104 A1 WO 2019198104A1
Authority
WO
WIPO (PCT)
Prior art keywords
solvent
butts
adhesive
waste
cigarette
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IN2019/050297
Other languages
English (en)
Inventor
Anmol Sanjiv JAISWAL
Vaishnavi Harish REWATKAR
Vivek Pralhadrao BHANGE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2019198104A1 publication Critical patent/WO2019198104A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J101/00—Adhesives based on cellulose, modified cellulose, or cellulose derivatives
    • C09J101/08—Cellulose derivatives
    • C09J101/10—Esters of organic acids
    • C09J101/12—Cellulose acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J189/00—Adhesives based on proteins; Adhesives based on derivatives thereof
    • C09J189/04—Products derived from waste materials, e.g. horn, hoof or hair
    • C09J189/06—Products derived from waste materials, e.g. horn, hoof or hair derived from leather or skin

Definitions

  • [001] Present invention in general relates to an adhesive which contains non - biodegradable cellulosic waste like degrading cigarette filter (butts), solvent like acetone for degradation and some additives for enhancement of property of the adhesive.
  • Cigarette butts has been used and recycled in numerous ways but not as adhesives; it possess some properties of adhesion which can encounter the properties of industrial glue or synthetic adhesives.
  • CN103275652A discloses method for preparing adhesive by taking waste polystyrene foam and wood powder as raw materials.
  • the invention discloses a method for preparing an adhesive by taking waste polystyrene foam and wood powder as raw materials. The method is characterized by comprising the following steps of adding the waste polystyrene foam to toluene, stirring, allowing the waste polystyrene foam to dissolve, adding the wood powder and kaolin to the solution, continuing to stir, discharging, packaging and obtaining the adhesive.
  • CN103980858A discloses biomass-based adhesive prepared by utilizing laccase activated cellulosic ethanol lignin, and method thereof.
  • the invention relates to a biomass-based adhesive prepared by utilizing laccase activated cellulosic ethanol lignin, and a method thereof.
  • the method is characterized by comprising the following steps: selecting and mixing the raw materials, regulating pH value, reacting for 4-7 hours at the temperature of 30-35DEG C, to obtain the biomass-based adhesive which comprises the following compositions: cellulosic ethanol lignin, laccase, tween 80, talc powder, water and an acetic acid-sodium acetate buffer solution.
  • CN104628970B discloses a method for preparing industrial gelatin skin collagen hydrolyzate group waste paper sizing agent.
  • CN102516909A disclose preparation method of pulping waste liquid adhesive.
  • the invention provides a preparation method of a pulping waste liquid adhesive and belongs to the technical field of adhesives.
  • the preparation method comprises the following steps of: firstly carrying out phenolic modification on pulping waste liquid at a temperature of 90-140 DEG C under the action of a basic catalyst and phenol by adopting a normal-pressure or high-pressure heating method; and then adding aldehyde and the basic catalyst into the pulping waste liquid subjected to the phenolic modification, reacting for 1.0-3.0 hours at a temperature of 55-70 DEG C under the condition of continuous agitation, adding urea accounting for 0.2-2.0 percent of the total weight of the phenol, aldehyde and the pulping waste liquid, raising the temperature to 80-95 DEG C, continuously reacting for 0.5-3.0 hours, stop heating when the viscosity conforms to the requirements, cooling to below 40 DEG C and discharging.
  • the invention has the beneficial effects that compared with a traditional phenolic resin adhesive, the prepared adhesive has the characteristics of lower production cost, low free phenol and free aldehyde content and environment friendliness; and in the preparation method, the pulping waste liquid is fully utilized, the pollution caused by the waste liquid to the environment is solved, and the resource utilization of the pulping waste liquid is realized.
  • Primary object of the present invention is to provide an adhesive which contains non -biodegradable cellulosic waste like degrading cigarette filter (butts), solvent like Acetone for degradation and some additives (Animal Glue).
  • Another object of the present invention is to enhance the property of the adhesive.
  • Yet another object of the present invention is to provide a solution for waste disposal of non-biodegradable cellulosic waste like cigarette filter.
  • the proposed novel mixture for the purpose comprises of a cellulosic waste generated from cigarette filter, a solvent for degradation of the waste i.e. acetone and some additives that are used to increase the adhesive properties of the product obtained.
  • a solvent for degradation of the waste i.e. acetone
  • some additives that are used to increase the adhesive properties of the product obtained.
  • the additive animal glue is added to the solution, stir the mixture for minimum 15-20 minutes and keep this mixture undisturbed for period of 20days.
  • Filtered solution is used in the preparation of adhesive and the un dissolved additive is further recycled in solvent mix preparation.
  • Thereafter for preparation of adhesive clean and dried cigarette butts are taken and weighed, an amount of solvent is measured and collected in a beaker/container.
  • Cigarette butts are added to the solvent which degraded the synthetic polymer (Cellulose Acetate).
  • the slurry formed is continuously stirred using a glass rod so as to prevent lump formation. After stirring the slurry, it is applied on different cellulosic materials to check its adhesive properties.
  • the present invention provides an adhesive made from non-biodegradable cellulosic waste.
  • the proposed novel mixture for the purpose incorporates a cellulosic waste generated from cigarette filter, a solvent for degradation of the waste i.e. acetone and some additives (Animal Glue) that are used to increase the adhesive properties of the product obtained.
  • the slurry obtained from degrading the cigarette filter (butts) with the help of acetone is able to encounter the standard properties of glue.
  • some additives are added such as animal glue.
  • the resultant mix is found to adhere different materials such as paper, cardboard, wood, metal, marble and acrylic sheets and has a capacity to substitute the commercial glue.
  • Step 1 Cleaning of Cigarette Butts
  • Step 2 Preparation of Solvent Mix
  • the solvent used for the degradation of cigarette waste can be taken in different combinations and concentration.
  • the solvent can be a single or a binary mixture.
  • the additive -“Animal glue” is added to the solution to enhance the stickiness of mixture (w/v). After addition, stir the mixture for minimum 15-20 minutes using mechanical stirrer or shaft. Keep this mixture undisturbed for period of 20days. Before using the solvent containing additive, shake the container/bottle properly and after 20 days extract the solvent using filter cloth. Filtered solution is used in the preparation of adhesive and the un dissolved additive is further recycled in solvent mix preparation.
  • Cigarette waste added in solvent mixture 12-28%.
  • Animal glue is a protein derived from the simple hydrolysis of collagen, which is a principal protein constituent of animal hide.
  • An interesting property of animal glue solution is that glue is transformed from a liquid to a gel state on cooling and reverting to a liquid on reheating. This property is of primary importance in many adhesive applications.
  • Animal glue is commercially available in a number of forms including the dry granulated products for use as hot glues, cold liquid glues for immediate use and a wide selection of composition glues in cake or jelly form.
  • Animal adhesives are of various kinds derived from skins and bones of the animals. The form is known as Hide glue and the latter as Bone glue.
  • Fish glue are derived from the skin of various fishes, casein glue is derived from casein obtained from milk of various animals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

La présente invention concerne un adhésif constitué de déchets cellulosiques non biodégradables. L'objet de la présente invention est d'améliorer la propriété adhésive. Le nouveau mélange proposé comprend un déchet cellulosique généré à partir de filtre de cigarette, un solvant pour la dégradation des déchets, c'est-à-dire l'acétone et certains additifs utilisés pour augmenter les propriétés adhésives du produit obtenu. La suspension concentrée obtenue à partir de la dégradation de filtre de cigarette (mégots) au moyen d'acétone a permis d'obtenir les propriétés standard d'une colle. Afin d'améliorer la propriété adhésive, certains additifs sont ajoutés, tels que de la colle animale. Par conséquent, il a été observé que le mélange résultant permet de coller différents matériaux tels que du papier, du carton, du bois et a une capacité à remplacer la colle commerciale.
PCT/IN2019/050297 2018-04-12 2019-04-10 Adhésif incorporant des déchets cellulosiques non biodégradables Ceased WO2019198104A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN201821013969 2018-04-12
IN201821013969 2018-04-12

Publications (1)

Publication Number Publication Date
WO2019198104A1 true WO2019198104A1 (fr) 2019-10-17

Family

ID=68164034

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2019/050297 Ceased WO2019198104A1 (fr) 2018-04-12 2019-04-10 Adhésif incorporant des déchets cellulosiques non biodégradables

Country Status (1)

Country Link
WO (1) WO2019198104A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110776846A (zh) * 2019-11-08 2020-02-11 海南蓝岛环保产业股份有限公司 一种利用酸碱溶液处理失效胶的方法
CN112322222A (zh) * 2020-11-12 2021-02-05 中国航发沈阳黎明航空发动机有限责任公司 一种耐高温有机蒸汽的封口胶的制备方法及使用方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3574153A (en) * 1967-07-06 1971-04-06 Nat Starch Chem Corp Water remoistenable hot melt adhesive compositions comprising mixtures of water soluble polymers with acid hydrolyzed polyvinyl acetate
US5504119A (en) * 1993-04-30 1996-04-02 Hoechst Celanese Corporation Recycling cellulose esters from the waste from cigarette manufacturing
US7560059B2 (en) * 2005-09-19 2009-07-14 Blake Burich Process and method for recycling cigarette butts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3574153A (en) * 1967-07-06 1971-04-06 Nat Starch Chem Corp Water remoistenable hot melt adhesive compositions comprising mixtures of water soluble polymers with acid hydrolyzed polyvinyl acetate
US5504119A (en) * 1993-04-30 1996-04-02 Hoechst Celanese Corporation Recycling cellulose esters from the waste from cigarette manufacturing
US7560059B2 (en) * 2005-09-19 2009-07-14 Blake Burich Process and method for recycling cigarette butts

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110776846A (zh) * 2019-11-08 2020-02-11 海南蓝岛环保产业股份有限公司 一种利用酸碱溶液处理失效胶的方法
CN112322222A (zh) * 2020-11-12 2021-02-05 中国航发沈阳黎明航空发动机有限责任公司 一种耐高温有机蒸汽的封口胶的制备方法及使用方法

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