WO2019004369A1 - 吸収性物品用シート及び吸収性物品 - Google Patents
吸収性物品用シート及び吸収性物品 Download PDFInfo
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- WO2019004369A1 WO2019004369A1 PCT/JP2018/024642 JP2018024642W WO2019004369A1 WO 2019004369 A1 WO2019004369 A1 WO 2019004369A1 JP 2018024642 W JP2018024642 W JP 2018024642W WO 2019004369 A1 WO2019004369 A1 WO 2019004369A1
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- Prior art keywords
- sheet
- woven fabric
- absorbent article
- entangled
- fibers
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
- A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
- A61F13/51401—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/512—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its apertures, e.g. perforations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
- A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/02—Cotton wool; Wadding
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
- D04H1/495—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet for formation of patterns, e.g. drilling or rearrangement
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N3/00—Investigating strength properties of solid materials by application of mechanical stress
- G01N3/56—Investigating resistance to wear or abrasion
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/36—Textiles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
- A61F2013/15284—Properties of the article, e.g. stiffness or absorbency characterized by quantifiable properties
- A61F2013/15406—Basis weight
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
- A61F2013/15284—Properties of the article, e.g. stiffness or absorbency characterized by quantifiable properties
- A61F2013/15422—Density
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
- A61F2013/51002—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads with special fibres
- A61F2013/51019—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads with special fibres being cellulosic material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
- A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
- A61F13/51401—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
- A61F2013/51439—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material being foams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2555/00—Personal care
- B32B2555/02—Diapers or napkins
Definitions
- the present disclosure relates to an absorbent article sheet and an absorbent article.
- Nonwoven fabrics of various configurations have been proposed as sheets constituting absorbent articles such as sanitary napkins, disposable diapers, and incontinence pads, that is, sheets for absorbent articles.
- Patent Document 1 is a non-woven fabric containing 50% by mass or more of a non-heat-bonding hydrophilic fiber in a surface sheet of an absorbent article, in which ridges and ridges extending in the longitudinal direction are formed. In the middle area between the top area of the ridge and the bottom area of the recess, the density is determined by the density of the top area and the density of the bottom area. It is also described to form with non-woven fabric which is low. The same document describes an example using a non-woven fabric of 100% cotton fiber which is a non-heat-bonding hydrophilic fiber as a surface sheet.
- Fuzz may be a problem with sheets that come in contact with the user's skin, such as the top sheet of the absorbent article, or sheets that come into contact with the user's clothing, such as the back sheet of the absorbent article. Fuzz tends to give the user the feeling that the product is unsanitary. In addition, when the fluff is entangled to form a pill or the fluff is dropped, the touch may be deteriorated or the adhesion of fibers to clothes may be noticeable. Fuzz is likely to occur when fibers are entangled or bonded poorly.
- An object of the present disclosure is to provide a sheet for an absorbent article which is resistant to fuzzing and fuzzing and is excellent in design.
- An absorbent article sheet comprising a non-woven fabric comprising cellulosic fibers in an amount of more than 90% by mass, wherein the fibers are entangled,
- the non-woven fabric has a plurality of first entangled parts separated from each other and a plurality of second entangled parts separated from each other,
- the first entangled portion is a regular pattern formed of a plurality of high fiber density regions (hereinafter, “high density region”) and a plurality of low fiber density regions (hereinafter, “low density region”).
- the regular pattern has substantially the same low density regions arranged in a staggered or grid pattern
- Each of the first entangled parts extends along the longitudinal direction or the lateral direction of the non-woven fabric
- Each of the second entangled parts extends along the longitudinal or lateral direction of the non-woven fabric
- the first entangled portion and the second entangled portion are alternately arranged,
- the total area of the first entangled portion occupies 20% or more of the whole nonwoven fabric,
- the basis weight of the non-woven fabric is greater than 30 g / m 2 ,
- the amount of fuzz according to the following test is 1.0 mg or less Provided is a sheet for an absorbent article.
- Circumferential movement is performed 2 sets clockwise, and 2 sets counterclockwise as 4 sets.
- the peripheral movement speed at this time is about 3 seconds per one movement.
- (A) to (B) are plan views schematically showing an example of the non-woven fabric according to an example of the present embodiment in which substantially the same low density regions are arranged in a zigzag or lattice, and (C) shows two types. It is a top view which shows typically the nonwoven fabric of an example of this embodiment by which approximately the same low density field of each was arranged in zigzag form, respectively. It is a top view explaining the pitch and space
- a sheet for an absorbent article (hereinafter, also simply referred to as a "sheet") is used as a member in direct contact with skin or the like as in a sanitary napkin or a surface sheet of a disposable diaper, the sheet is made of non-woven fabric containing a large amount of cellulose fibers. May be configured.
- Cellulosic fibers are, for example, natural cellulosic fibers such as cotton and regenerated fibers such as viscose rayon. These fibers are considered to be gentle to the skin and delicate zone and difficult to irritate. Also, cellulosic fibers, particularly when they are natural fibers, give the sheet a unique feel and feel. Therefore, the absorbent article in which the sheet
- a sheet that directly contacts skin or the like is often configured using a non-woven fabric produced by a method of interlacing fibers with a high-pressure fluid flow (also referred to as "spun lace method").
- spunlace method a relatively soft non-woven fabric can be obtained.
- the non-woven fabric produced by the spunlace method has a problem that fuzzing or fuzzing (fuzz falling off from the non-woven fabric) easily occurs due to fibrillation of fibers and / or protrusion of fiber ends.
- natural fibers such as cotton are not uniform in fiber length, and the ends of fibers with short fiber length are prone to fuzzing and fuzzing.
- a method of suppressing fuzz and fuzz of the non-woven fabric produced by the spun lace method there is a method of bonding the fibers or a method of strengthening the interlacing of the fibers.
- Cellulosic fibers generally do not have adhesive properties. Therefore, in order to suppress fuzz and fuzzing of non-woven fabric using cellulose fibers by adhesion, heat adhesive fibers are mixed and heat adhesion fibers are melted or softened by heat treatment to form adhesion points, Alternatively, it is necessary to form an adhesion point with a binder. However, the bonding points formed by the heat-adhesive fibers and the binder harden the feel of the non-woven fabric and impair the unique feel of the cellulose-based fibers. In addition, when the cellulosic fiber is a natural fiber, the appeal point is "natural", and when the amount of the heat-adhesive fiber or the binder is increased to suppress fuzz and fuzz, this appeal point is Is weakened.
- the present inventors examined a configuration of a sheet preferably comprising a non-woven fabric consisting only of cellulosic fibers, having a good formation even if the basis weight is reduced to a certain extent, and being resistant to fuzzing and fuzzing. did.
- the present inventors have an entangled portion having a regular pattern formed of a portion with high fiber density and a portion with low fiber density, and an entangled portion with relatively uniform fiber density. It has been found that, according to the arrangement in which the stripe pattern is formed, fuzzing and fuzzing are suppressed. Such a configuration suppresses fuzzing and fuzzing, which is considered to be due to the fibers being tightly entangled in the entangled portion when forming a regular pattern.
- the inventors of the present invention can also suppress fuzzing and fuzzing more by setting the proportion of the entangled portion having a regular pattern in the non-woven fabric to a predetermined range and setting the basis weight larger than a predetermined value. I found it.
- the present inventors have found that a nonwoven fabric having a specific regular pattern has improved water absorbency.
- the present inventors also found that the nonwoven fabric of such a structure exhibits the outstanding design effect.
- a sheet for an absorbent article of the present embodiment and an absorbent article using the same will be described.
- the sheet for an absorbent article of the present embodiment is An absorbent article sheet comprising a non-woven fabric comprising cellulosic fibers in an amount of more than 90% by mass, wherein the fibers are entangled,
- the non-woven fabric has a plurality of first entangled parts separated from each other and a plurality of second entangled parts separated from each other,
- the first entangled portion is a regular pattern formed of a plurality of high fiber density regions (hereinafter, “high density region”) and a plurality of low fiber density regions (hereinafter, “low density region”).
- the regular pattern has substantially the same low density regions arranged in a staggered or grid pattern
- Each of the first entangled parts extends along the longitudinal direction or the lateral direction of the non-woven fabric
- Each of the second entangled parts extends along the longitudinal or lateral direction of the non-woven fabric
- the first entangled portion and the second entangled portion are alternately arranged,
- the total area of the first entangled portion occupies 20% or more of the whole nonwoven fabric,
- the basis weight of the non-woven fabric is greater than 30 g / m 2 ,
- the amount of fuzz according to the following test is 1.0 mg or less It is a sheet
- Circumferential movement is performed 2 sets clockwise, and 2 sets counterclockwise as 4 sets.
- the peripheral movement speed at this time is about 3 seconds per one movement.
- Cellulose fiber The cellulose-based fiber contained in the nonwoven fabric (hereinafter, also simply referred to as "nonwoven fabric") contained in the sheet for an absorbent article of the present embodiment will be described.
- a cellulose fiber used by this embodiment -Natural fibers derived from plants such as cotton (cotton), linen, ramie, jute, and hemp-Rayon and polynozic obtained by the viscose method; cupra obtained by the copper ammonia method; cupra obtained by the solvent spinning method Regenerated fibers such as cellulose fibers (Lyocel (registered trademark) and Tencel (registered trademark) of Lentzing Co., Ltd.)
- Semi-synthetic fibers such as cellulose fibers-acetate fibers obtained by a melt spinning method can be mentioned.
- the cellulosic fibers are not particularly limited, and one or more of these fibers may be optionally selected.
- cotton is used.
- Cotton is a natural fiber and is suitable for constructing a sheet in contact with the skin because it is less irritating to the skin.
- Cotton may have water repellency.
- the water repellent cotton may be, for example, cotton wax adhered, or a cotton with cotton wax removed by scouring bleaching and a water repellent may be adhered.
- Cotton wax is a natural wax attached to cotton. By appropriately selecting the conditions of the scouring and bleaching treatment, a desired amount of cotton wax can be left on the cotton, and desired water repellency can be obtained.
- a method of attaching a water repellent to cotton from which cotton wax has been removed for example, there is a method of applying a commercially available water repellent to one surface of a nonwoven fabric produced by a spunlace method and then drying it.
- the application may be performed by any method, for example, using a gravure coater, a reverse roll coater, a kiss coater or the like.
- Cotton having water repellency has a property of floating on the surface of water for a relatively long time, when put into water, because it is difficult to absorb water.
- the water-repellent cotton one having water-repellency that does not sink for 30 seconds or more when introduced into water is preferably used.
- the use of cotton having water repellency can further reduce the amount of regurgitation of the obtained nonwoven fabric.
- the use of a water repellent fiber tends to reduce the liquid absorption speed of the non-woven fabric, but the non-water repellent fiber of the present embodiment using a water repellent fiber uses a non-water repellent fiber It can be as high as or higher than that of the nonwoven fabric of this embodiment. This is considered to be due to the nonwoven fabric of the present embodiment having a region with a low fiber density.
- the cotton having water repellency is cotton wax-adhered cotton, cotton wax imparts a good touch to the non-woven fabric.
- the fineness of the cellulose-based fiber is not particularly limited, and may be, for example, 0.6 dtex to 5.6 dtex, particularly 1.4 dtex to 4.4 dtex, and more particularly 1.7 dtex to 3.3 dtex. If the fineness is too small, the non-woven fabric may be too soft and handling may be reduced, and if it is too large, the feel of the non-woven fabric may be reduced. In addition, the fineness of a natural fiber can be calculated according to the method by JIS L 1019 7.4.1 micronaire (the same applies to the following).
- the fiber length of the cellulose-based fiber is not particularly limited, and may be appropriately selected according to the method of manufacturing the non-woven fabric and the like.
- the fiber length of the cellulose-based fiber may be, for example, 25 mm to 100 mm, and in particular, 30 mm to 70 mm.
- the fiber lengths need not all be the same.
- natural fibers derived from plants such as cotton are generally supplied in a form in which the fiber length is not constant, but such forms may be used in the present embodiment.
- the non-woven fabric may contain other fibers other than cellulosic fibers.
- the other fibers may be, for example, one or more fibers selected from natural fibers that are not cellulosic fibers (for example, wool, silk, etc.) and synthetic fibers made of thermoplastic synthetic resin.
- the other fiber is a synthetic fiber, the thermoplastic resin is not particularly limited.
- the synthetic fiber may be a single fiber composed of one or more thermoplastic resins selected from the above, or may be a conjugate fiber composed of two or more components (also referred to as “sections”).
- each component may be composed of one thermoplastic resin, or a mixture of two or more thermoplastic resins.
- the composite fiber may be, for example, a core-sheath composite fiber, a sea-island composite fiber, a split composite fiber, or a side-by-side composite fiber.
- the core-sheath type composite fiber may be an eccentric core-sheath type composite fiber in which the center of the core component and the center of the sheath component do not coincide in the fiber cross section, and the concentric core in which the center of the core component and the center of the sheath component coincide in the fiber cross section It may be sheath type composite fiber.
- the fineness of the other fibers is not particularly limited, and may be, for example, 1.4 dtex to 7.8 dtex, in particular 2.2 dtex to 6.7 dtex, and more particularly 3.3 dtex to 5.6 dtex. If the fineness is too small, the non-woven fabric may be too soft and handling may be reduced, and if it is too large, the feel of the non-woven fabric may be reduced.
- the fiber length of the other fibers is not particularly limited, and may be appropriately selected according to the method of manufacturing the non-woven fabric and the like.
- the fiber length of the other fibers may for example be 25 mm to 100 mm, in particular 30 mm to 70 mm.
- the fiber lengths need not all be the same.
- the nonwoven comprises cellulosic fibers in an amount greater than 90% by weight.
- Cellulosic fibers give the nonwoven fabric a unique feel and feel, and are used to make the nonwoven fabric hypoallergenic. If the proportion of the cellulose fiber is 90% by mass or less, the touch and feel of the cellulose fiber may not be sufficiently obtained in the non-woven fabric, and the proportion of the other fibers is increased to increase the irritation to the skin. Sometimes. In particular, 95% by mass or more, more particularly 100% by mass of cellulosic fibers may be contained. When the non-woven fabric consists only of cellulosic fibers, the effect of using cellulosic fibers can be maximized.
- the non-woven fabric contains other fibers other than the cellulosic fibers
- the other fibers are contained in a proportion of 10% by mass or less.
- the proportion of the other fibers exceeds 10% by mass, the effect due to the inclusion of the cellulosic fibers may not be sufficiently obtained.
- Other fibers may in particular be included in a proportion of up to 5% by weight.
- the fibers may be bonded by the other fibers.
- fuzzing of the non-woven fabric can be suppressed.
- the feel of the non-woven fabric may become hard due to adhesion, and the adhesion portion may give irritation to the skin, when using the non-woven fabric as a member such as a surface sheet where the feeling of touch is important, Is preferably not adhered.
- cotton with cotton wax When cotton with cotton wax is used, fibers may not be sufficiently entangled when manufacturing a non-woven fabric by a method manufacturing method using a high pressure fluid (in particular, high pressure water) described later. In that case, cotton from which cotton wax has been removed may be mixed in order to improve the entanglement of the fibers.
- the cotton wax-removed cotton may be contained in the non-woven fabric in a proportion of 70% or less based on 100% of the total weight of this and cotton wax-adhered cotton.
- the nonwoven fabric has a plurality of spaced apart first interlacing portions and a plurality of spaced apart second interlacing portions.
- the first intertwined portion is a portion where fibers are intertwined and extends along the longitudinal direction or the transverse direction of the nonwoven fabric.
- to extend along the longitudinal direction or lateral direction of the nonwoven fabric means that the longitudinal direction of the first entangled portion is the longitudinal direction (also referred to as "MD direction”) or the transverse direction (also referred to as "CD direction”) of the nonwoven fabric.
- MD direction longitudinal direction
- CD direction transverse direction
- the first entangled portion may meander.
- the first entangled portion when the first entangled portion meanders between two straight lines parallel to the longitudinal direction of the nonwoven fabric, the first entangled portion extends along the longitudinal direction of the nonwoven fabric. In this case, the longitudinal direction of the first entangled portion is taken as the longitudinal direction for convenience.
- the first entangled portion when the first entangled portion meanders between two straight lines parallel to the lateral direction of the non-woven fabric, the first entangled portion extends along the lateral direction of the non-woven fabric. In this case, the longitudinal direction of the first entangled portion is taken as the lateral direction for convenience.
- the first entangled portion has a low density region and a high density region.
- the low density area forms a regular pattern.
- the regular pattern refers to a pattern formed by arranging a high density area or a low density area according to a certain rule.
- the regular pattern can improve the design of the non-woven fabric.
- the regular pattern can be formed by disposing the web on a regularly arranged support at least one selected from a convex portion, a concave portion and an opening, as described later, and applying a high pressure fluid.
- the low density region may be a portion where the thickness is not different from the high density region (that is, the low density region and the high density region may not have unevenness) or may be a recess. Alternatively, it may be an opening.
- a high pressure fluid a high pressure gas such as compressed air, a high pressure liquid such as high pressure water
- the fiber web located on the intersection of the two is moved by the action of the high pressure fluid to move the fibers to the surroundings and rearrange (hereinafter, also simply referred to as "moving").
- the area per low density region is mainly determined by the thickness of the yarn constituting the fabric.
- the low density region may be formed by a formed body or a spiral net having at least one selected from a convex portion, a concave portion and an opening.
- the low density region may have an area of, for example, 0.03 mm 2 to 20 mm 2 , in particular, an area of 0.1 mm 2 to 10 mm 2 , and more particularly, 0.7 mm 2. It may have an area of ⁇ 5.0 mm 2 . If the low density region is too small, the low density region may not be sufficiently recognized, and the design effect may not be sufficiently exhibited. If the low density area is too large, the nonwoven fabric is likely to be deformed or broken such as elongation, twisting, tearing, etc., resulting in poor handleability. If the low density region is too large, it may be difficult to recognize as a low density region, and the design effect may not be sufficiently exhibited.
- Low-density region is a small region of fiber density than at least the high-density region, for example, it may have a fiber density of 0g / cm 3 ⁇ 0.080g / cm 3, in particular, 0g / cm 3 ⁇ 0. may have a fiber density of 070g / cm 3, more particularly, it may have a fiber density of 0g / cm 3 ⁇ 0.05g / cm 3.
- Zero fiber density means that the low density region is an aperture. When the fiber density in the low density region is large and the difference between that in the high density region is small, it is difficult to recognize the pattern, and a sufficient design effect may not be exhibited.
- each low density area in one first intertwined part or one non-woven fabric do not have to be the same.
- one low density region may be an opening, and another low density region may not be an opening.
- the regular pattern has substantially the same low density regions (hereinafter also referred to as “low density regions A”) arranged in a zigzag or grid pattern.
- substantially the same low density region refers to those having substantially the same shape and area.
- substantially the same low density region means one derived from projections, recesses or openings of the same shape and area regularly formed on a support used in forming a pattern with a high pressure fluid .
- low density regions having areas different from one another by, for example, about 30%, particularly about 20% are regarded as low density regions A.
- one low density region A may be an opening and another low density region A may be a recess.
- FIGS. 1A and 1B are plan views schematically showing an example in which the low density regions A are arranged in a zigzag and lattice, respectively.
- the low density area A is shown by the code
- the shape of the low density region A is not limited to this, and may be a circle, a polygon (for example, triangle, rectangle, square, rhombus), a star or the like.
- two or more low density regions A may be formed.
- the regular pattern has elliptical low density areas A10 arranged in a zigzag manner and circular low density areas A20 arranged in a zigzag manner. You may
- the low density region of a certain shape and dimension and all the low density regions which are substantially identical to and adjacent to the low density region have either a staggered arrangement or a lattice arrangement. Therefore, one low density area b (which is substantially the same as the low density area a) adjacent to a certain low density area a has a lattice-like relationship with the low density area a, and another adjacent low density area a When c (which is substantially the same as the low density region a) is in a staggered arrangement relationship with the low density region a, in the present embodiment, substantially the same low density regions arranged in a zigzag or lattice are formed. It is not considered to have been done.
- the regular pattern may have other low density regions as long as the low density regions A arranged in a zigzag or grid form are formed.
- low density regions of different sizes and / or shapes may be formed between adjacent low density regions A and low density regions A.
- the pitch between the low density regions A is not particularly limited, and may be, for example, 0.1 mm to 50 mm, particularly 0.5 mm to 30 mm, more particularly 1 mm to 10 mm in at least one direction. May be there.
- the pitch corresponds to the distance between the centers of gravity of adjacent low density regions A in one first entangled portion.
- the spacing between the low density regions A may be, for example, 0.1 mm to 50 mm in at least one direction, in particular 0.5 mm to 30 mm, and more particularly 1.0 mm to 10 mm. May be there.
- the interval means one arbitrary point on the outer periphery (outline) of one low density region A and the outer periphery of another low density region A adjacent to the low density region A in one first entangled portion. Out of the line segments connecting any one point on the contour), it refers to the shortest line segment.
- the pitch and spacing between the low density regions A may not be constant.
- the pitch (a1, a2 in the figure) and the interval (b1, b2 in the figure) differ depending on the direction.
- the low density region A is, for example, 7.0% to 25%, particularly 7.5%, of the total area of the total nonwoven fabric (ie, the total area of the low density regions A in the nonwoven fabric). It may be formed to occupy% -20%, more particularly 8.0% -15%. When the ratio (area ratio) occupied by the low density region A is within this range, it is possible to increase the liquid absorption speed of the non-woven fabric, combined with the low density regions being arranged in a zigzag or lattice shape. .
- the high density regions are formed between the low density regions or around the low density regions.
- the high density area is, as described above, an area in which the moved fibers are closely gathered when the fibers are moved by the action of high pressure fluid to form a low density area.
- the high density region has a higher fiber density than the low density region, and may for example have a fiber density of 0.01 g / cm 3 to 0.30 g / cm 3 , in particular 0.03 g / cm 3 to may have a fiber density of 0.20 g / cm 3, more particularly, it may have a fiber density of 0.05g / cm 3 ⁇ 0.15g / cm 3.
- the high density region may for example have a thickness of 0.05 mm to 5.0 mm, in particular 0.10 mm to 3.0 mm, more particularly 0.2 mm to 2.0 mm.
- a fiber density is calculated
- each first entangled portion may be, for example, 3 mm to 200 mm, in particular 3 mm to 50 mm, more particularly 5 mm to 50 mm, still more particularly 5 to 30 mm Or may be 5 mm to 15 mm.
- the width of the first entangled portion refers to the dimension in the direction orthogonal to the direction in which the first entangled portion extends. In one first confounding portion, the width may or may not be constant.
- first entangled parts of different widths there may be first entangled parts of different widths.
- the first interlacing portions having a narrow width for example, 2 mm to 5 mm
- the first entangled portions having a wide width for example, 6 mm to 15 mm
- the first entangled portion of narrow width for example, 2 mm to 3 mm
- the first entangled portion of medium width for example, 4 to 5 mm
- the first entangled portion of large width for example, 6 to 15 mm
- It may be arranged in the order of medium / thick or thin / thick / medium.
- the combined area of the first entangled parts accounts for 20% or more of the whole nonwoven fabric, preferably 25% or more, more preferably 30% or more, and most preferably 40% or more.
- the fibers are entangled relatively firmly, so the first entangled portion is a portion responsible for fluff suppression and fluff loss suppression of the non-woven fabric. Therefore, if the ratio of the first entangled portion to the non-woven fabric is small, fuzzing and fuzzing are likely to occur.
- the upper limit of the combined area of the first entangled parts is, for example, 65%, in particular 60%, more particularly 55%, and even more particularly 53%. When the ratio of the area of the first entangled part is too large, the amount of liquid reversion may increase when the non-woven fabric is used as the surface sheet of the absorbent article, or the strength of the non-woven fabric may decrease.
- the first entangled portion may be straight or serpentine.
- the meandering length (that is, wavelength) per cycle may be 5 mm or more.
- the length of the meandering per cycle is determined as follows. i) As shown in FIG. 3, a direction parallel to a straight line orthogonal to the length direction 31 of the first interlaced portion 42 is taken as an orthogonal direction, a direction extending to the “+” side is taken as a positive orthogonal direction 32a, “- The direction extending to the “side” is the negative orthogonal direction 32 b.
- distance 1 of straight line 33 and straight line 34 be the length of meandering per 1 cycle.
- draw straight lines 33, 34 orthogonal to the length direction 31 at the midpoint of the straight-ahead portion in FIG. 3, reference numeral 41 denotes a second entangled portion formed between the first entangled portions 42.
- the upper limit of the wavelength may be 200 mm.
- the wavelength is in particular 10 mm to 150 mm, more in particular 30 mm to 100 mm.
- the meandering of the first entangled portion preferably has an amplitude of 1 mm or more.
- the amplitude is determined as follows. i) As shown in FIG. 3, let g be a point on the straight line 33 described above and equally divide the width of the first entangled portion 42. ii) Draw a straight line 35 orthogonal to the length direction 31 at a point i at which the progression of the meandering of the first interlaced part 42 which has progressed in the positive orthogonal direction 32a changes to the negative orthogonal direction 32b; A point located on the upper side and equally dividing the width of the first entangled portion 42 is h.
- a distance j between a straight line 36 including point g and parallel to the length direction 31 and a straight line 37 including point i and parallel to the length direction is an amplitude.
- the upper limit of the amplitude may be 200 mm.
- the amplitude is in particular 2 mm to 150 mm, more in particular 5 mm to 100 mm and even more in particular 10 mm to 50 mm.
- the meandering of the first confounding portion may be different in length per period from one cycle to another, or may be different in amplitude like an attenuation wave, and these meanders are regularly repeated. May be
- a preferred meandering configuration is a configuration in which the meandering length per cycle is the same and the amplitudes are the same, that is, repetition of the same pattern.
- the ratio (wavelength / amplitude) of the ratio of the length (wavelength) to the amplitude per period of meandering (wavelength / amplitude) may be, for example, 1 to 15, particularly 1.5 to 12, and more particularly 2 to It may be eight. When the value of the ratio of wavelength to amplitude is less than 1 or more than 15, it may be difficult to recognize that the first confounding part is meandering.
- the phases of the meandering of the adjacent first interlacing portions are the same. The phase of meandering of adjacent first interlacing portions may be shifted.
- the width X (hereinafter also referred to simply as “width X”) at the turning point of the meander is It may be different from the width Y (hereinafter also referred to simply as “width Y”) of the other parts.
- the width X may be smaller than the width Y.
- the second entangled portion is an entangled portion independent of the first entangled portion, and the state of fiber entanglement in the second entangled portion is different from the state of fiber entangled in the first entangled portion. Moreover, in the present embodiment, the first entangled portion and the second entangled portion are alternately arranged. Therefore, the second entangled portion forms a stripe-shaped pattern (in the case where the first entangled portion is meandering, a meandering stripe-shaped pattern) together with the first interlaced portion.
- the second entangled part has no pattern, i.e. is plain. If the second entangled part is formed by the entanglement process using the high pressure fluid flow, thin streaks may be formed at the location where the high pressure fluid flow hits. The second entangled portion in which such streaks are formed is regarded as plain.
- the second entangled portion does not have a pattern and has a relatively uniform fiber density
- the liquid return is further suppressed.
- “Liquid return” means that the liquid which once passed through the top sheet exudes again to the surface of the top sheet. If the second entangled portion also has a pattern, a high density region will be present throughout the nonwoven fabric. The high density region is a portion that easily holds the liquid, and the held liquid is likely to be pushed back by pressure, so if the high density region exists over the entire non-woven fabric, the liquid return amount of the non-woven fabric may be large.
- the second entangled portion may have a higher fiber density than the low density region at the first entangled portion and may have a lower fiber density than the high density region at the first entangled portion.
- the second entangled portion may for example have a fiber density of 0.01 g / cm 3 to 0.20 g / cm 3 , in particular having a fiber density of 0.03 g / cm 3 to 0.15 g / cm 3 More particularly, it may have a fiber density of 0.05 g / cm 3 to 0.13 g / cm 3 .
- the second entangled portion may for example have a thickness of 0.05 mm to 3.0 mm, in particular 0.1 mm to 2.5 mm, more particularly 0.2 mm to 1.8 mm.
- the fiber density of the second entangled portion and the fiber density of the high density region of the first entangled portion are at least 1 / 1.03 (second entangled portion / second It may have a ratio of 1) (a high density region of a confounding portion), and may have a ratio of 1 / 1.05 or more.
- the ratio of the fiber density of the low density region to the fiber density of the second entangled portion is, for example, 1 / 1.03 or more (the low density region of the first entangled portion Or as a second entangled portion), and in particular, may be 1 / 1.05 or more.
- the density difference between the low density area of the first entangled portion and the second entangled portion and / or the density difference between the high density area of the second entangled portion and the first entangled portion is small, the first entangled portion and the second entangled portion In some cases, it is not possible to distinguish clearly from the department, and the design effect may not be sufficiently exhibited.
- each second entanglement may be, for example, 3 mm to 200 mm, in particular 3 mm to 50 mm, more particularly 5 mm to 50 mm, still more particularly 5 mm to 30 mm Or may be 5 mm to 15 mm.
- the width of the second entangled portion refers to the dimension in the direction orthogonal to the length direction of the second entangled portion.
- the second interlacing portions having a narrow width (for example, 2 mm to 5 mm) and the second entangled portions having a large width (for example, 6 mm to 15 mm) may be alternately arranged.
- the second entangled portion of narrow width (for example, 2 mm to 3 mm), the second entangled portion of medium width (for example, 4 to 5 mm), and the second entangled portion of large width (for example, 6 to 15 mm) It may be arranged in the order of medium / thick or thin / thick / medium.
- the width of the first entangled part and the width of the second entangled part may be the same or different. You may When the first entangled portion has the same width as the second entangled portion, the ratio of the area of the first entangled portion to the non-woven fabric is 50%. When the first entangled portion and the second entangled portion have different widths, the width of the first entangled portion with respect to the second entangled portion may be, for example, 0.25 or more, particularly 0.5 or more, more particularly 0 .9 or more.
- the second intertwining portions having different widths may be combined with the first intertwining portions having different widths.
- first entangled portion and the second entangled portion may be lined up.
- first entangled portion and the second entangled portion You may line up.
- the first entangled portion and the second entangled portion may be lined up like thin (first) / thin (second) / thin (first) / thick (second).
- the "thick”, “medium”, and “thin” are used to indicate the magnitude relation of the width for the same entangled portion. Therefore, the "thick" of the first entangled portion and the "thick” of the second entangled portion may not have the same width.
- a combination such as 2) is included in the combination of thick (first) / thick (second) / thin (first) / thin (second), 7 mm (first) / 5 mm (second) / 5 mm (first) / 3 mm (first)
- a combination such as 2) is included.
- the second entangled portion adjacent between the first entangled portions also meanders.
- the length and amplitude of the meandering per cycle of the second confounding part are determined by those of the first confounding part. Therefore, the description of the length and amplitude of the meandering per cycle of the second confounding portion is omitted here.
- seat for absorbent articles of this embodiment has a fabric weight larger than 30 g / m ⁇ 2 >. If the fabric weight is 30 g / m 2 or less, fuzzing and fuzzing tend to occur, and the formation of the nonwoven fabric tends to deteriorate.
- the basis weight of the non-woven fabric may be, for example, 32 g / m 2 or more and 60 g / m 2 or less, in particular 33 g / m 2 or more and 50 g / m 2 or less, and more particularly 34 g / m 2 or more and 45 g / m 2 It may be the following.
- the liquid return amount may be large.
- air permeability may fall.
- the specific volume of the non-woven fabric is not particularly limited, and may be appropriately selected depending on the application and the like.
- Specific volume of the nonwoven fabric for example, be less 0.5 cm 3 / g or more 2.0 cm 3 / g, may be especially 0.7 cm 3 / g or more 1.6 cm 3 / g or less, and more particularly It may be 0.8 cm 3 / g or more and 1.5 cm 3 / g or less.
- the specific volume can be determined from the basis weight and thickness of the nonwoven fabric, where the thickness of the nonwoven fabric is to be measured under a load of 2.94 cN per 1 cm 2 of sample.
- the air permeability and cushioning properties of the non-woven fabric tend to improve, but if it is too large, the liquid tends to collect in the non-woven fabric and the amount of liquid return increases when the non-woven fabric is used as a surface sheet. Sometimes.
- seat for absorbent articles of this embodiment is hard to produce fuzz by having several 1st entangled part which has a regular pattern.
- the non-woven fabric is provided as having a fluff amount of 1.0 mg or less measured by the following method.
- the amount of fuzz may in particular be less than or equal to 1.0 mg, more particularly less than or equal to 0.8 mg, and even more particularly less than or equal to 0.5 mg.
- the non-woven fabric having a small amount of fuzz is a non-woven fabric that is hard to cause fuzz and fuzz, and gives the user a clean impression.
- the generation of fluff due to entanglement of the fluff is also suppressed, so that a smooth touch feeling is given to the user.
- the non-woven fabric with a small amount of fuzz can reduce the amount of fibers adhering to the clothes when in contact with the clothes of the user.
- the non-woven fabric constituting the absorbent article sheet of the present embodiment is a non-woven fabric having no first entangled portion when the liquid absorption speed is evaluated by the runoff value in the direction orthogonal to the extending direction of the first entangled portion and the second entangled portion. And a higher liquid absorption speed as compared to the nonwoven fabric without the second entangled portion.
- seat for absorbent articles of this embodiment has a higher liquid absorption speed compared with the nonwoven fabric which does not have the low density area
- the runoff value is specifically measured by the following procedure.
- (I) Prepare a sample.
- (Ii) Prepare a slope with a horizontal plane and an angle of 30 degrees, and on top of the slope, prepare a stack of two sheets of filter paper (Lister Paper (Grade 989, 10 cm ⁇ 10 cm)) as an absorber.
- the sample is placed and fixed so that it does not overlap over the same area or larger than the size of the sample, and the sample is placed and fixed on it.
- the runoff value is obtained by determining the distance between the position and the position where saline is dropped on the surface of the non-woven fabric sample, that is, the longest distance through which the water droplets of saline flow on the surface of the non-woven fabric sample.
- Three samples are prepared for one non-woven fabric, and the values obtained by repeating the above (i) to (iii) three times are averaged, and the average value is used for evaluation as the run-off value of the non-woven fabric.
- the non-woven fabric has a configuration in which the first entangled portion and the second entangled portion are alternately arranged. Therefore, when the liquid flows along the direction orthogonal to the direction in which the first and second interlacing portions extend, the boundary between the two interlacing portions prevents the progress of the liquid, and the liquid flows in the thickness direction of the nonwoven fabric. It is thought that it becomes easy to go along.
- the low density region and all the same low density regions adjacent thereto have a relationship of either a staggered arrangement or a lattice arrangement, the liquid passes through the first entangled portion, The low density region and the high density region in the first entangled portion are alternately and regularly passed. As a result, it is assumed that the fluid absorption speed can be further reduced by the regular change of the liquid flow speed.
- Non-woven fabric for example, Producing a fibrous web containing 90% by mass or more of cellulosic fibers, Subjecting the fiber web to high pressure fluid flow confounding treatment; It is manufactured by a manufacturing method including forming a first entangled portion having a regular pattern by partially entangling with a high pressure fluid.
- the part in which the 1st entangled part was not formed turns into a 2nd entangled part.
- the fibrous web is supported on the support having at least one selected from a convex portion, a concave portion and an opening portion for forming a low density region (hereinafter referred to as (Also referred to as “patterned support”), which is carried out by acting high pressure fluid only on the part of the web where the first entanglement is to be formed.
- patterned support a low density region corresponding to the shape of the patterned support is formed, and between the low density regions, a high density region is formed by the fibers moved to the periphery in forming the low density region.
- the high pressure fluid includes high pressure gas such as compressed air and high pressure liquid such as high pressure water.
- the high pressure liquid is preferably used in that a non-woven fabric having an excellent feel can be obtained, and an excess oil adhering to the fiber can be removed.
- hydroentangling treatment using high pressure water as high pressure fluid is often used.
- the hydroentanglement process is preferably used in terms of ease of implementation and the like. Below, the manufacturing method at the time of using high pressure water (it is also only called a "water flow" in the following) as a high pressure fluid is demonstrated.
- a water flow entanglement treatment for entangling the fibers over the entire fiber web is performed.
- the first hydroentanglement treatment is carried out by mounting the web on a support and injecting a water stream.
- the water flow may be a columnar water flow.
- the first hydroentangling process is for forming the second entangled portion.
- the second entangled portion preferably has a uniform texture with less density. Therefore, in the first hydroentangling process, it is preferable to use a relatively fine-grained support, for example, a plain weave support of 80 mesh to 100 mesh.
- water pressure of 1MPa to 15MPa water pressure is applied to the front and back sides of the web from the nozzles provided with orifices with a hole diameter of 0.05mm to 0.5mm at intervals of 0.3mm to 1.5mm. It may be implemented by injecting ⁇ 5 times.
- the water pressure is preferably 1 MPa to 10 MPa, more preferably 1 MPa to 7 MPa.
- the distance between the nozzles and the web may for example be 5 mm to 100 mm, in particular 10 mm to 50 mm.
- the water pressure, the number of jets, the transport speed, etc. are selected so that the total of energy (E) applied to the web by high pressure water is 25 Wh / kg / m to 100 Wh / kg / m. May be implemented. E is obtained by the following equation.
- E W ⁇ N ⁇ T / (M ⁇ U ⁇ 60)
- E Energy applied in 1 hour per 1 m width to non-woven fabric per 1 kg (Wh / kg / m)
- W Power of fluid per nozzle (W)
- N Number of orifices opened per m width to the nozzle
- T Number of injections
- M Weight per unit area of high-speed water flow treatment (g / m 2 )
- U Transport speed (m / min) W in the above equation (power of fluid per orifice of the nozzle) is determined by the following equation.
- W P1 ⁇ (F / 100) ⁇ 0.163)
- W Power of fluid per orifice of nozzle (W)
- P1 Water pressure (kgf / cm 2 )
- F Flow rate of water discharged from one orifice of the nozzle (cm 3 / min)
- second hydroentanglement process for forming a first interlacing portion is performed.
- the web after the first hydroentanglement treatment hereinafter also referred to as "primary processed web” is disposed on the patterning support and the water stream is applied to the web It carries out so that it may contact only the part which should form the 1st confounding part.
- a method of partially applying a stream of water to the web for example, a method of using a nozzle in which an orifice group consisting of one or more orifices is provided at a predetermined distance, and a hole having a hole, which is not permeable to high pressure fluid except the hole.
- a method of arranging a member hereinafter simply referred to as "perforated member" between the nozzle and the web.
- the patterned support may have protrusions. In that case, when a stream of water hits the fibers located on the convex portions, the fibers move to the periphery to rearrange the fibers, and a low density region is formed at the position corresponding to the convex portions.
- the patterned support may have a recess.
- the fibers at the periphery of the recess move to move to the recess and are rearranged at the recess to form a high density region at a position corresponding to the recess and form a low density region around the recess .
- the high density region may be three-dimensional.
- the patterned support may have an opening, in which case the fibers around the opening move to move to the opening and rearrange at the opening to open the opening.
- a high density region is formed at the corresponding position, and a low density region is formed around the opening.
- the high density region may be three-dimensional depending on the shape of the opening and the like.
- the patterned support may have two or more selected from projections, recesses and openings.
- the patterned support may be a woven fabric, a punched plate-like member, or a spiral net made of a natural resin, a synthetic resin, or a metal.
- the patterned support may have one or more regularly selected ones or more selected from the convex portions, the concave portions and the openings, and have a regular pattern. With such a patterned support, a plurality of low density regions can be gathered to form a regular pattern.
- convex portions having substantially the same shape and area are regularly provided, and in particular, pattern formation arranged in a zigzag or lattice A support is preferably used.
- the patterned support may be, for example, a monofilament having a fiber diameter of about 0.1 mm to 1.2 mm, a warp density of 10 yarns / inch to 30 yarns / inch, and a weft density of 10 yarns / inch to 30 yarns / It may be plain woven fabric, cedar woven fabric, rattan woven fabric, and satin woven fabric woven in inches.
- the intersection of the weft yarn and the warp yarn becomes a convex portion, enabling the formation of a low density region.
- the thickness of the yarn constituting the fabric determines the area per low density region
- the warp / weft density of the fabric determines the spacing and pitch of the low density region Be done.
- a plain woven fabric in which warp and weft yarns are woven as a single monofilament.
- the highest part of the intersections of the warp and weft is a convex portion and is arranged in a zigzag, so if such a plain weave is used, the corresponding portion It is possible to form low density regions A arranged in a staggered manner.
- the patterned support may be a protrusion and / or a recess, for example, a truncated cone, a cone, a truncated pyramid or a pyramid, or a recess formed by cutting the surface of a metal plate or the like.
- a portion other than the convex portion and / or the concave portion may be, for example, a plate-like member (for example, a metal plate) in which an opening having a small size is formed to ensure water permeability.
- the patterned support may be a spiral net.
- the orifice group is provided over a section corresponding to the width of the first interlaced portion.
- the distance between the orifice groups corresponds to the width of the second entangled portion.
- Such a nozzle may be a nozzle designed to apply water flow over the entire surface, and the orifice may be plugged in a section corresponding to the second entangled portion.
- One orifice group preferably comprises two or more orifices. If the number of orifices is two or more, regular patterns can be formed more clearly in the first entangled portion.
- the distance between adjacent orifices in the orifice group may be, for example, 0.2 mm to 1.5 mm.
- the perforated member is not particularly limited as long as it is a member having a plurality of holes.
- the material may be made of synthetic resin or metal.
- the shape may be appropriately selected in accordance with the device of the hydroentanglement treatment such as a plate shape or a roll shape.
- the plurality of holes included in the hole forming member are formed along a direction orthogonal to the direction in which the first entangled portion extends.
- One hole may have a dimension of, for example, 2 mm or more, in particular in a dimension of 3 mm to 50 mm, more in particular in a dimension of 5 mm to 30 mm, in a direction orthogonal to the direction in which the first entangled part extends.
- holes of different sizes are formed in one perforated member depending on the width of the first entangled portion to be obtained.
- the distance between adjacent holes included in the perforated member may be, for example, 2 mm or more, in particular 3 mm to 50 mm, and more particularly 5 mm to 30 mm.
- the distance between the adjacent holes determines the width of the second entangled portion, and is accordingly selected according to the width of the second entangled portion to be obtained.
- the shape of the hole is not particularly limited, and may be, for example, a polygon such as a circle, a semicircle, an ellipse, a triangle or a square, a star polygon, a cross, a slit such as a straight line or a curved line, or the like.
- the nozzle is not particularly limited, and the same one as described in connection with the first hydroentangling process may be used.
- the distance between the perforated member and the nozzle may be, for example, 1 mm or more. If the distance between the perforated member and the nozzle is less than 1 mm, the perforated member may come in contact with the nozzle, and one or both may be damaged. On the other hand, the distance between the perforated member and the nozzle may be, for example, 30 mm or less. If the distance between the perforated member and the orifice exceeds 30 mm, the energy of the water flow may be reduced and a regular pattern may not be formed well.
- the distance between the perforated member and the primary processing web may be, for example, 5 mm to 50 mm. If the distance between the perforated member and the primary processing web is more than 50 mm, the energy of the water flow may be reduced and a regular pattern may not be formed well.
- the water pressure range that may be used in the second hydroentangling process is as described in relation to the first hydroentangling process.
- the first interlacing portion is usually formed by injecting the water flow only once to one surface of the primary processing web.
- the pressure in the second hydroentangling process may be, in particular, 1 MPa to 15 MPa, and more particularly, 2 MPa to 10 MPa.
- the water pressure, the number of injections and the transfer speed (the total of energy (E) applied to the primary processed web by high pressure water is 20 Wh / kg / m to 200 Wh / kg / m
- the speed of the patterned support or the like may be selected and implemented.
- the method of obtaining E is as described in relation to the first water flow confounding process.
- the plurality of first entangled parts And a plurality of second intertwined portions extend linearly in the longitudinal direction or in the lateral direction of the nonwoven fabric.
- a non-woven fabric having a serpentine structure is obtained.
- “vibration” means to reciprocate the nozzle or the perforated member along a certain direction.
- the “vibration” includes not only reciprocation on a straight line, but also reciprocation along an elliptical orbit whose major axis is a fixed direction.
- the vibration direction of the nozzle or the perforated member may be appropriately selected from the longitudinal direction (MD direction), the lateral direction (CD direction), the oblique direction, etc. of the web.
- the “oblique direction” means a direction that forms an angle in the range of more than 0 degrees and less than 90 degrees with the longitudinal direction or the lateral direction along the surface direction of the web.
- the vibration direction is preferably a direction that forms an angle that is greater than 0 degrees and less than or equal to 45 degrees with the lateral direction or the lateral direction.
- the amplitude of the vibration of the nozzle or perforated member is approximately the same as the amplitude of the first entanglement in the resulting nonwoven. Therefore, the amplitude of the vibration of the nozzle or the perforated member is determined according to the amplitude of the first entangled portion to be obtained.
- the vibrating speed of the nozzle or the perforated member and the advancing speed of the patterned support determine the meandering length per cycle of the first entangled portion. Therefore, the vibration speed of the nozzle or the perforated member is determined according to the meandering length per cycle of the first interlacing portion to be obtained, taking into consideration also the advancing speed of the patterned support.
- the vibration speed of the perforated member can be increased to about 100 m / min. Then, by increasing the vibration speed of the perforated member, it is possible to increase the difference between the width X at the turning point of the interlacing portion such as the first entangled portion and the second entangled portion and the width Y at other points. .
- the web after the completion of the second water flow entangling treatment may be subjected to a drying treatment for removing water and used as it is as a non-woven fabric.
- the dried web (non-woven fabric) may be wound up as needed.
- the nonwoven fabric is cut into a predetermined size when used as a sheet for an absorbent article.
- the drying process heats the fibers with each other by the low melting point resin. It may also serve as a heat bonding process for bonding.
- the heat bonding treatment is preferably performed at a temperature at which the lowest melting point of the thermoplastic resins constituting the surface of the synthetic fiber is melted or softened.
- the dried web may be further subjected to a water repelling treatment to adhere a water repellant to the fibers.
- the water repellant process may be performed, for example, when using cotton from which much of the cotton wax has been removed by the scouring and bleaching process as the cellulosic fiber.
- the water repellent finish is carried out so that, for example, 0.5 to 5 parts by mass of a commercially available water repellent (for example, a fiber treatment agent for imparting water repellency to fibers) adheres to 100 parts by mass of the non-woven fabric.
- the non-woven fabric described above constitutes a sheet for an absorbent article.
- the non-woven fabric may constitute an absorbent article sheet alone, or may be combined with other non-woven fabrics or films to constitute an absorbent article sheet.
- the sheet for absorbent articles is a surface sheet
- the nonwoven fabric may be used as it is as a sheet for absorbent articles.
- the sheet for absorbent articles may be provided in the form which integrated a nonwoven fabric and a liquid impervious film.
- the sheet for an absorbent article of the present embodiment can be used as a member constituting an absorbent article.
- the sheet for an absorbent article of the present embodiment is a top sheet (also referred to as a top sheet) of the absorbent article, an intermediate sheet, a sheet covering an absorbent core (also referred to as an SAP sheet or a core wrap sheet), It can be used as a member that constitutes a back sheet or the like.
- the back sheet is provided opposite to the liquid impermeable sheet provided on the opposite side to the top sheet through the absorber, and constitutes the exposed surface on the opposite side to the top sheet of the absorbent article. Point to a sheet. Therefore, the back sheet is a part that touches the clothes of the user.
- the absorbent article sheet is used as a back sheet, the non-woven fabric and the liquid impermeable sheet may be integrated.
- the sheet for an absorbent article of the present embodiment uses a non-woven fabric containing more than 90% by mass of cellulose fibers, it is preferable to use it for the surface sheet in order to take advantage of the unique touch of the cellulose fibers.
- Absorbent articles include, for example, disposable diapers (for infants, including nursing care), sanitary napkins, incontinence pads, and the like. An absorbent article is not limited to these,
- seat for absorbent articles of this embodiment can be used for arbitrary articles
- An absorbent article is described as another embodiment of the present disclosure.
- One example of the absorbent article of the present embodiment is an absorbent article having a surface sheet, a liquid impermeable sheet, and an absorbent body disposed between the surface sheet and the liquid impermeable sheet, and the surface It is an absorbent article, which is a sheet for an absorbent article of the embodiment described above.
- Another example of the present embodiment is a surface sheet, a liquid impermeable sheet, an absorber disposed between the surface sheet and the liquid impermeable sheet, and a surface of the liquid impermeable sheet on the absorber side Is an absorbent article having an opposite surface and a back sheet disposed opposite to the absorbent article, wherein the top sheet or back sheet is the absorbent article sheet of the embodiment described above, is there.
- the surface sheet has a role of capturing excrement fluid and rapidly moving the captured excrement fluid to the absorber side.
- the topsheet is the sheet for the absorbent article of the above-described embodiment, it can give the user a good feeling of touch, and the user's eyes may be touched when worn. Good design effects are exhibited.
- the liquid impermeable sheet is, for example, a resin film.
- the liquid impermeable sheet may be breathable or may not be breathable.
- the absorbent is, for example, a polymeric absorbent (also referred to as SAP, which is generally in the form of powder), ground pulp, a fiber assembly, and an absorbent core composed of one or more members selected from films. , And may be covered with a core wrap sheet selected from non-woven fabrics and films. Alternatively, the absorbent may not be covered by the core wrap sheet, but may consist of only the absorbent core.
- SAP polymeric absorbent
- SAP ground pulp
- fiber assembly a fiber assembly
- an absorbent core composed of one or more members selected from films.
- the absorbent may be covered with a core wrap sheet selected from non-woven fabrics and films.
- the absorbent may not be covered by the core wrap sheet, but may consist of only the absorbent core.
- the back sheet When the back sheet is provided, the back sheet may be the absorbent article sheet of the embodiment described above.
- the back sheet may be integrated with the liquid impermeable sheet by an adhesive or the like. Since the back sheet is a portion easy for a person who picks up the absorbent article to touch, when it is the absorbent article sheet of the embodiment described above, it brings a good touch to the person who picks up the hand, and , I feel the design.
- the back sheet is the absorbent article sheet of the embodiment described above, the amount of fluff attached to the clothes can be reduced.
- the absorbent article of the present embodiment may have an intermediate sheet between the top sheet and the absorber.
- the intermediate sheet allows the excretory fluid absorbed from the surface sheet to be rapidly transferred to the absorber while diffusing, so that the excretory fluid is absorbed in a wider area of the absorber, the surface sheet and the absorption It is provided between the body.
- the intermediate sheet may be, for example, a non-woven fabric comprising hydrophilic fibers and hydrophobic fibers.
- the absorbent articles include, for example, disposable diapers, sanitary napkins, incontinence pads and the like, but the absorbent articles of the present embodiment are not limited thereto.
- Plain weave support A Plain weave A: Plain weave net of a warp (monofilament) wire diameter 0.7 mm, weft (monofilament) 0.7 mm, weave density 25/25 (bottles / inch) plain weave net D
- Plain weave D A plain weave net of warp yarn (monofilament) wire diameter 0.9 mm, weft yarn (monofilament) wire diameter 1.0 mm, weave density 9/10 (book / inch), and two warp yarns are the same. We lined up in the state and threw in one weft
- Example 1 Using only cotton (trade name: MSD, manufactured by Marusan Sangyo Co., Ltd.) with a fineness of 1.0 dtex to 5.0 dtex and a fiber length of 10 mm to 60 mm, a parallel web of 35 g / m 2 in aiming was prepared.
- the hydroentangling process (first hydroentangling process) was performed over the entire web.
- the web In the first hydroentangling process, the web is mounted on a 90 mesh plain weave support made of monofilaments having a diameter of 0.132 mm, and the web is prepared using nozzles provided with orifices with a hole diameter of 0.12 mm at intervals of 0.6 mm.
- the columnar water flow of 2 MPa was injected once on one side of the surface, the columnar water flow of 4 MPa on the other side, and the columnar water flow of 2 MPa on the one side.
- the speed of the support at this time was 4 m / min, and the distance between the nozzle and the web was 10 mm.
- a water flow entanglement process for forming a first entangled portion was performed.
- the second hydroentangling treatment was performed by placing the web after the first hydroentangling treatment on the plain weave support A.
- the same nozzle as that used in the first hydroentangling process was used.
- An acrylic resin perforated member having a thickness of 5 mm was disposed between the nozzle and the non-woven fabric, and a water stream was allowed to pass through the hole of the perforated member to form a second entangled portion.
- the first intertwining portions having a width of 6 mm are formed every 12 mm (that is, the second intertwining portions having a width of 12 mm and the first intertwining portions having a width of 6 mm are formed in stripes)
- An acrylic resin perforated member having a hole of 6 mm wide ⁇ 6 mm long was used.
- the pressure of the columnar water flow was 2 MPa, and the columnar water flow was injected once to one side of the web.
- the nozzle was not vibrated and the support was run at a speed of 4 m / min.
- the distance between the nozzle and the web was 30 mm and the distance between the perforated member and the web was 5 mm.
- the water entanglement was partially implemented because the columnar water flow only passed through the holes of the perforated member and hit the web on the support.
- the highest portions of the woven intersections form substantially the same convex portions, and the convex portions are arranged in a zigzag manner.
- the fibers on the convex portion move to the periphery by the water flow to form the low density region A arranged in a zigzag, and at the same time, the moved fibers are entangled to form a high density region, and a regular pattern is formed.
- the moved fibers are entangled to form a high density region, and a regular pattern is formed.
- the obtained non-woven fabric had a 6 mm wide first entangled portion having a regular pattern and a plain 12 mm wide second entangled portion.
- the regular pattern of the first entangled portion was one having an elliptical low density region A with a major axis of 1.2 mm and a minor axis of 0.7 mm arranged in a staggered manner. Most of the low density region A was an opening.
- the low density regions A were arranged in a staggered manner with a pitch of 3 mm in the longitudinal direction and a pitch of 2 mm in the lateral direction, a spacing of 2 mm in the longitudinal direction and a spacing of 1 mm in the transverse direction, a pitch of 2 mm in the diagonal direction, and a spacing of 1 mm in the diagonal direction.
- the porosity of the whole nonwoven fabric was 9.20%.
- Example 2 In the second entanglement process, using an acrylic resin perforated member (5 mm in thickness) provided with a hole of 6 mm in width ⁇ 6 mm in length so that the first entangled portion of 6 mm in width is formed every 6 mm
- a nonwoven fabric was obtained in the same manner as in Example 1 except for the above.
- the obtained non-woven fabric had a 6 mm wide first entangled portion having a regular pattern, and a plain solid 6 mm wide second entangled portion.
- the regular pattern of the obtained nonwoven fabric was the same as that of Example 1, and the porosity of the whole nonwoven fabric was 13.90%.
- Example 3 The target weight was 40 g / m 2.
- a water flow of 2 MPa water pressure was injected on one side, a water flow of 4 MPa water pressure was injected on the other side, and the water pressure on one side
- a nonwoven fabric was obtained in the same manner as in Example 1 except that a water flow of 2 MPa was injected.
- the regular pattern and opening ratio of the obtained non-woven fabric were the same as those of Example 1.
- Example 4 The target weight was 40 g / m 2.
- a water flow of 2 MPa water pressure was injected on one side, a water flow of 4 MPa water pressure was injected on the other side, and the water pressure on one side
- a perforated member made of acrylic resin provided with a hole of width 6 mm ⁇ length 6 mm so that a water flow of 2 MPa is injected, and in the second intermingling process, first interlacing portions of 6 mm width are formed every 6 mm
- a nonwoven fabric was obtained in the same manner as in Example 1 except that (thickness 5 mm) was used.
- the regular pattern of the obtained nonwoven fabric was the same as that of Example 1, and the porosity of the whole nonwoven fabric was 13.90%.
- Example 5 The target weight was 45 g / m 2.
- a water flow of 2 MPa water pressure was injected to one side, a water flow of 4 MPa water pressure was injected to the other side, and the water pressure to one side
- a nonwoven fabric was obtained in the same manner as in Example 1 except that a water flow of 2 MPa was injected.
- the regular pattern and opening ratio of the obtained non-woven fabric were the same as those of Example 1.
- Example 6 The target weight was 45 g / m 2.
- a water flow of 2 MPa water pressure was injected to one side, a water flow of 4 MPa water pressure was injected to the other side, and the water pressure to one side
- a perforated member made of acrylic resin provided with a hole of width 6 mm ⁇ length 6 mm so that a water flow of 2 MPa is injected, and in the second intermingling process, first interlacing portions of 6 mm width are formed every 6 mm
- a nonwoven fabric was obtained in the same manner as in Example 1 except that (thickness 5 mm) was used.
- the regular pattern of the obtained nonwoven fabric was the same as that of Example 1, and the porosity of the whole nonwoven fabric was 13.90%.
- Example 1 A nonwoven fabric was obtained in the same manner as in Example 4 except that the second hydroentangling treatment was not performed.
- the non-woven fabric was plain over the entire surface and did not have the first entangled portion.
- a nonwoven fabric was obtained in the same manner as in Example 4, except that the water flow was injected over the entire surface without using a perforated member.
- This non-woven fabric had a regular pattern having low density regions A and high density regions arranged in a zigzag manner over the entire surface, and did not have a second entangled portion.
- the shape and size of the low density regions A arranged in a staggered manner, and the spacing and pitch between the low density regions A are the same as those of the low density regions A formed in the first entangled portion of the first embodiment.
- the porosity of the whole nonwoven fabric was 28.00%.
- the target weight was 40 g / m 2.
- a water flow of 2 MPa water pressure was injected on one side
- a water flow of 2 MPa water pressure was injected on the other side
- water pressure on one side A non-woven fabric was obtained in the same manner as in Example 1, except that a water flow of 2 MPa was injected and the plain weave support D was used in the second hydroentangling treatment.
- the hole area ratio of the whole nonwoven fabric was 5.97%.
- the non-woven fabric obtained in Comparative Example 3 had a regular pattern as shown in FIG. 5 at the first entangled portion. As shown in FIG. 5, three substantially identical low density regions 10 are arranged in the lateral direction of the non-woven fabric to form one group, and the groups 100 are arranged in a zigzag manner. Therefore, in Comparative Example 3, a certain low density region and all the same low density regions adjacent thereto do not have a relationship of either a staggered arrangement or a lattice arrangement.
- the thickness was measured using a thickness measuring machine (trade name: THICKNESS GAUGE model CR-60A, manufactured by Daiei Kagaku Seiki Mfg. Co., Ltd.) under a load of 2.94 cN per 1 cm 2 of the sample.
- the specific volume was calculated from the basis weight and the thickness.
- (Run off value) It measured according to the following procedures.
- (I) Prepare a sample.
- (Ii) Prepare a slope with a horizontal plane and an angle of 30 degrees, and on top of the slope, prepare a stack of two sheets of filter paper (Lister Paper (Grade 989, 10 cm ⁇ 10 cm)) as an absorber. The sample is placed and fixed so that it does not overlap over the same area or larger than the size of the sample, and the sample is placed and fixed on it. Arrange so as to be orthogonal to (Iii) 1.0 g of 0.90% saline (colored with blue dye) at 37 ° C.
- the runoff value is obtained by determining the distance between the position and the position where saline is dropped on the surface of the non-woven fabric sample, that is, the longest distance through which the water droplets of saline flow on the surface of the non-woven fabric sample.
- Three samples are prepared for one non-woven fabric, and the values obtained by repeating the above (i) to (iii) three times are averaged, and the average value is used for evaluation as the run-off value of the non-woven fabric.
- Example 7 Using only cotton (trade name: MSD, manufactured by Marusan Sangyo Co., Ltd.) with a fineness of 1.0 dtex to 5.0 dtex and a fiber length of 10 mm to 60 mm, a parallel web of 35 g / m 2 in aiming was prepared.
- the hydroentangling process (first hydroentangling process) was performed over the entire web.
- the web In the first hydroentangling treatment, the web is placed on a 90 mesh plain weave support of monofilaments having a diameter of 0.132 mm, and the total energy (E) applied to the web by high pressure water is 74.7 Wh / kg / hour. It carried out so that it might become m.
- the distance between the nozzle and the web was 30 mm.
- a water flow entanglement process for forming a first entangled portion was performed.
- the second hydroentangling treatment was performed by placing the web after the first hydroentangling treatment on the plain weave support A.
- the same nozzle as that used in the first hydroentangling process was used.
- An acrylic resin perforated member having a thickness of 5 mm was disposed between the nozzle and the non-woven fabric, and a water stream was allowed to pass through the hole of the perforated member to form a second entangled portion.
- the first intertwining portions having a width of 6 mm are formed every 12 mm (that is, the second intertwining portions having a width of 12 mm and the first intertwining portions having a width of 6 mm are formed in stripes)
- An acrylic resin perforated member having a hole of 6 mm wide ⁇ 6 mm long was used.
- the second hydroentangling treatment was performed such that the total of energy (E) applied to the web by high pressure water was 32.8 Wh / kg / m.
- E energy
- the perforated member was vibrated at an amplitude of 30 mm and a vibration velocity of 10.5 m / min along the lateral direction of the web. The distance between the web and the perforated member was 5 mm.
- the hydroentanglement was partially performed.
- the low density regions A arranged in a staggered manner are formed, and at the same time, the moved fibers are entangled to form high density regions, and regular patterns are formed.
- the first entangled portion and the second entangled portion meandered.
- the obtained non-woven fabric had a 6 mm wide first entangled portion having a regular pattern and a plain 12 mm wide second entangled portion.
- the regular pattern of the first entangled portion was one having an elliptical low density region A with a major axis of 1.2 mm and a minor axis of 0.7 mm arranged in a staggered manner. Most of the low density region A was an opening.
- the low density regions A were arranged in a staggered manner with a pitch of 3 mm in the longitudinal direction and a pitch of 2 mm in the lateral direction, a spacing of 2 mm in the longitudinal direction and a spacing of 1 mm in the transverse direction, a pitch of 2 mm in the diagonal direction, and a spacing of 1 mm in the diagonal direction.
- the meandering length per cycle of the first interlaced portion was 105 mm, and the amplitude was 15 mm.
- the porosity of the whole nonwoven fabric was 9.20%.
- Example 8 Except that the aiming weight was 40 g / m 2 and the first hydroentangling treatment was performed so that the sum of the energy (E) applied to the web by high pressure water was 39.6 Wh / kg / m, A nonwoven fabric was obtained in the same manner as in Example 7.
- Example 9 Non-woven fabric in the same manner as in Example 7 except that the first hydroentangling treatment was performed such that the total of the energy (E) applied to the web with high pressure water was 52.8 Wh / kg / m. I got
- the thickness, specific volume, fuzz amount, and breaking strength of the nonwoven fabrics of Examples 7 to 9 and Comparative Examples 4 to 5 were evaluated.
- the evaluation results are shown in Table 2.
- the thickness evaluation method is as described above.
- the amount of fuzz and the breaking strength were evaluated by the methods described below.
- the evaluation results are shown in Table 2.
- Table 2 the evaluation results of Comparative Examples 2 and 3 are also shown.
- Circumferential movement is performed 2 sets clockwise, and 2 sets counterclockwise as 4 sets.
- the peripheral movement speed at this time is about 3 seconds per one movement.
- the nonwoven fabric of Comparative Example 2 did not have the first entangled portion, and thus exhibited the largest amount of fuzz.
- the non-woven fabric of Comparative Example 3 exhibited a small amount of fuzzing because a regular pattern was formed on the entire surface, but a high density area was formed over the entire surface, so a large liquid return compared to the non-woven fabric of the example. Showed the amount. Further, it was confirmed that the fuzzing amount of Comparative Example 3 was the same as or only slightly smaller than that of Examples 7 to 9, and the presence of the second confounding portion did not significantly reduce the fuzzing.
- the sheet for an absorbent article of the present embodiment is a sheet with high design effect in which fuzzing and fuzzing are suppressed despite containing cellulose fiber in an amount of more than 90% by mass. Therefore, the sheet for an absorbent article of the present embodiment is, for example, an absorbent article having a top sheet, a back sheet, and an absorber disposed between the top sheet and the back sheet, as a top sheet or a back sheet. It is preferably used.
- the present disclosure includes a sheet for an absorbent article and an absorbent article of the following aspects.
- An absorbent article sheet comprising a non-woven fabric comprising cellulosic fibers in an amount of more than 90% by mass, wherein the fibers are entangled,
- the non-woven fabric has a plurality of first entangled parts separated from each other and a plurality of second entangled parts separated from each other,
- the first entangled portion is a regular pattern formed of a plurality of high fiber density regions (hereinafter, “high density region”) and a plurality of low fiber density regions (hereinafter, “low density region”).
- the regular pattern has substantially the same low density regions arranged in a staggered or grid pattern
- Each of the first entangled parts extends along the longitudinal direction or the lateral direction of the non-woven fabric
- Each of the second entangled parts extends along the longitudinal or lateral direction of the non-woven fabric
- the first entangled portion and the second entangled portion are alternately arranged,
- the total area of the first entangled portion occupies 20% or more of the whole nonwoven fabric,
- the basis weight of the non-woven fabric is greater than 30 g / m 2 ,
- the amount of fuzz according to the following test is 1.0 mg or less Absorbent article sheet.
- Circumferential movement is performed 2 sets clockwise, and 2 sets counterclockwise as 4 sets.
- the peripheral movement speed at this time is about 3 seconds per one movement.
- Aspect 2 The sheet for an absorbent article according to aspect 1, wherein the fibers are not bonded to each other.
- An absorbent article comprising: a back sheet disposed opposite to the absorbent article, wherein the top sheet or the back sheet is a sheet for an absorbent article according to any one of aspects 1 to 8.
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Abstract
Description
セルロース系繊維を90質量%よりも多い量で含み、繊維同士が交絡してなる不織布を含む吸収性物品用シートであって、
前記不織布が、複数の互いに離間した第1交絡部と、複数の互いに離間した第2交絡部とを有し、
前記第1交絡部はそれぞれ、複数の繊維密度の高い領域(以下、「高密度領域」)と複数の繊維密度の低い領域(以下、「低密度領域」)とで形成された規則的な模様を有し、前記規則的な模様は、千鳥状または格子状に配置された略同一の低密度領域を有し、
前記第1交絡部はそれぞれ、不織布の縦方向または横方向に沿って延び、
前記第2交絡部はそれぞれ、不織布の縦方向または横方向に沿って延び、
前記第1交絡部と前記第2交絡部は交互に配置されており、
前記第1交絡部を合わせた面積が不織布全体の20%以上を占めており、
前記不織布の目付が30g/m2よりも大きく、
以下の試験による毛羽抜け量が1.0mg以下である、
吸収性物品用シートを提供する。
(毛羽抜け量測定試験)
a)ウレタンフォーム(ブリヂストン(株)製、商品名モルトプレンMF30、厚さ5mm)で表面を覆った円盤(直径70mm、350g)を、回転軸が円盤中心から20mmずれた位置となるように回転軸に取り付ける。
b)不織布の下面に、上記と同じウレタンフォームを敷き、不織布の上面が露出面となるように、不織布を台上に固定する。
c)不織布の上に前記円盤を載せる。このとき、不織布に加わる荷重は円盤の自重のみとする。
d)回転軸を回転させて、円盤を不織布上で周動させる。周動は時計周りに2回転、反時計周りに2回転を1セットとして、4セット行う。このときの周動速度は1周動あたり約3秒である。
e)4セットの周動後、不織布から抜け落ちて、円盤を覆っているウレタンフォームの表面に付着した繊維を集める。
f)前記a)~e)の操作をn=30枚の不織布について行う。30枚の不織布それぞれについて、抜け落ちた繊維の質量を測定し、その平均値を毛羽抜け量とする。
生理用ナプキンや紙おむつの表面シートのように、吸収性物品用シート(以下、単に「シート」とも呼ぶ)が皮膚等と直接接触する部材として用いられる場合、セルロース系繊維を多く含む不織布によりシートを構成することがある。セルロース系繊維は、例えば、コットンのような天然セルロース系繊維、およびビスコースレーヨンのような再生繊維である。これらの繊維は、皮膚およびデリケートゾーンに優しく、刺激を与えにくいとされている。また、セルロース系繊維は、特に天然繊維である場合には、独特の触感および風合いをシートに与える。よって、セルロース系繊維を使用したシートが組み込まれた吸収性物品は、セルロース系繊維が用いられていることを、製品の有利な特徴として積極的に表示して販売することができる。
以下、本実施形態の吸収性物品用シートおよびこれを用いた吸収性物品を説明する。
セルロース系繊維を90質量%よりも多い量で含み、繊維同士が交絡してなる不織布を含む吸収性物品用シートであって、
前記不織布が、複数の互いに離間した第1交絡部と、複数の互いに離間した第2交絡部とを有し、
前記第1交絡部はそれぞれ、複数の繊維密度の高い領域(以下、「高密度領域」)と複数の繊維密度の低い領域(以下、「低密度領域」)とで形成された規則的な模様を有し、前記規則的な模様は、千鳥状または格子状に配置された略同一の低密度領域を有し、
前記第1交絡部はそれぞれ、不織布の縦方向または横方向に沿って延び、
前記第2交絡部はそれぞれ、不織布の縦方向または横方向に沿って延び、
前記第1交絡部と前記第2交絡部は交互に配置されており、
前記第1交絡部を合わせた面積が不織布全体の20%以上を占めており、
前記不織布の目付が30g/m2よりも大きく、
以下の試験による毛羽量が1.0mg以下である、
吸収性物品用シートである。
(毛羽抜け量測定試験)
a)ウレタンフォーム(ブリヂストン(株)製、商品名モルトプレンMF30、厚さ5mm)で表面を覆った円盤(直径70mm、350g)を、回転軸が円盤中心から20mmずれた位置となるように回転軸に取り付ける。
b)不織布の下面に、上記と同じウレタンフォームを敷き、不織布の上面が露出面となるように、不織布を台上に固定する。
c)不織布の上に前記円盤を載せる。このとき、不織布に加わる荷重は円盤の自重のみとする。
d)回転軸を回転させて、円盤を不織布上で周動させる。周動は時計周りに2回転、反時計周りに2回転を1セットとして、4セット行う。このときの周動速度は1周動あたり約3秒である。
e)4セットの周動後、不織布から抜け落ちて、円盤を覆っているウレタンフォームの表面に付着した繊維を集める。
f)前記a)~e)の操作をn=30枚の不織布について行う。30枚の不織布それぞれについて、抜け落ちた繊維の質量を測定し、その平均値を毛羽抜け量とする。
本実施形態の吸収性物品用シートに含まれる不織布(以下、単に「不織布」とも呼ぶ)に含まれるセルロース系繊維を説明する。
本実施形態で用いられるセルロース系繊維としては、
-綿(コットン)、リネン、ラミー、ジュート、およびヘンプ等の植物に由来する天然繊維
-ビスコース法で得られる、レーヨンおよびポリノジック;銅アンモニア法で得られる、キュプラ;ならびに溶剤紡糸法で得られるセルロース繊維(レンツィング社のリヨセル(登録商標)およびテンセル(登録商標)等)等の再生繊維
-溶融紡糸法で得られるセルロース繊維
-アセテート繊維等の半合成繊維
が挙げられる。本実施形態では、セルロース系繊維は特に限定されず、これらの繊維から1または複数のものを任意に選択してよい。
不織布には、セルロース系繊維以外の他の繊維が含まれていてよい。他の繊維は、例えば、セルロース系繊維でない天然繊維(例えば羊毛、シルク等)、および熱可塑性合成樹脂からなる合成繊維から選ばれる一または複数の繊維であってよい。他の繊維が合成繊維である場合、熱可塑性樹脂は特に限定されず、例えば、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリトリメチレンテレフタレート、ポリエチレンナフタレート、ポリ乳酸、ポリブチレンサクシネートおよびその共重合体等のポリエステル系樹脂;ポリプロピレン、ポリエチレン(高密度ポリエチレン、低密度ポリエチレン、直鎖状低密度ポリエチレン等を含む)、ポリブテン-1、プロピレンを主たる成分とするプロピレン共重合体(プロピレン-エチレン共重合体、プロピレン-ブテン-1-エチレン共重合体を含む)、およびエチレン-酢酸ビニル共重合体等のポリオレフィン系樹脂;ナイロン6、ナイロン12およびナイロン66のようなポリアミド系樹脂;アクリル系樹脂;ポリカーボネート、ポリアセタール、ポリスチレンおよび環状ポリオレフィンなどのエンジニアリング・プラスチック、ならびにそれらのエラストマーから任意に選択される。
続いて、本実施形態の吸収性物品用シートに含まれる不織布の構成を説明する。
[繊維の割合等]
不織布は、セルロース系繊維を90質量%よりも多い量で含む。セルロース系繊維は、不織布に独特の触感および風合いを与え、また、不織布を低刺激性のものとするために用いられる。セルロース系繊維の割合が90質量%以下であると、不織布においてセルロース系繊維の触感および風合いが十分に得られないことがあり、また、他の繊維の割合が大きくなって皮膚に対する刺激が大きくなることがある。セルロース系繊維は、特に95質量%以上、より特には100質量%含まれてよい。不織布がセルロース系繊維のみからなる場合には、セルロース系繊維を使用することによる効果を最大限に得ることができる。
不織布は、複数の互いに離間した第1交絡部と、複数の互いに離間した第2交絡部とを有する。
第1交絡部は繊維同士が交絡してなる部分であり、不織布の縦方向または横方向に沿って延びている。ここで、不織布の縦方向または横方向に沿って延びるとは、第1交絡部の長さ方向が、不織布の縦方向(「MD方向」ともいう)または横方向(「CD方向」ともいう)と平行であることをいう。したがって、複数の第1交絡部が、例えば縦方向に沿って延びる場合、それらは横方向に沿って並ぶこととなり、例えば横方向に沿って延びる場合、それらは縦方向に沿って並ぶこととなる。
第1交絡部が蛇行している場合、1周期当たりの蛇行の長さ(すなわち波長)は5mm以上であってよい。1周期当たりの蛇行の長さは、次のようにして求める。
i)図3に示すように、第1交絡部42の長さ方向31と直交する直線と平行な方向を直交方向とし、「+」の側に延びる方向を正の直交方向32aとし、「-」の側に延びる方向を負の直交方向32bとする。
ii)負の直交方向32bに向かって進んでいた第1交絡部42の蛇行の進行(第1交絡部42は幅を有するので、幅方向の一方の端部(図では左側端部)の進行に着目する)が、正の直交方向32aに変わる箇所eで、長さ方向31と直交する直線33を引く。
iii)前記eの箇所から、正の直交方向32aに向かって進んでいた第1交絡部42の蛇行が、負の直交方向32bに進行した後、さらに正の直交方向32aに変わる箇所fで、長さ方向31と直交する直線34を引く。
iv)直線33と直線34の距離lを、1周期あたりの蛇行の長さとする。
第1交絡部42の蛇行の進行が負の直交方向32bから正の直交方向32aに変わる箇所において、第1交絡部42が長さ方向31で直進する場合(例えば矩形波のような蛇行である場合)は、その直進部分の中点で長さ方向31と直交する直線33、34を引く。なお、図3において、符号41は、第1交絡部42間に形成された第2交絡部を示す。
i)図3に示すように、上述した直線33上にあり、第1交絡部42の幅を等分する点をgとする。
ii)正の直交方向32aに向かって進んでいた第1交絡部42の蛇行の進行が、負の直交方向32bに変わる箇所iで、長さ方向31と直交する直線35を引き、当該直線35上にあり、第1交絡部42の幅を等分する点をhとする。
iii)点gを含み、長さ方向31と平行である直線36と、点iを含み、長さ方向と平行である直線37との間の距離jを、振幅とする。
振幅の上限値は200mmであってよい。振幅は、特に2mm~150mmであり、より特には5mm~100mmであり、さらにより特には10mm~50mmである。
本実施形態の吸収性物品用シートを構成する不織布は、30g/m2よりも大きい目付を有する。目付が30g/m2以下であると、毛羽立ちおよび毛羽抜けが生じやすく、また、不織布の地合が悪くなる傾向にある。不織布の目付は、例えば、32g/m2以上60g/m2以下であってよく、特に33g/m2以上50g/m2以下であってよく、より特には34g/m2以上45g/m2以下であってよい。不織布の目付が大きすぎると、不織布内に液体が溜まりやすく、不織布を表面シートとして用いる場合には液戻り量が大きくなることがある。また、不織布の目付が大きすぎると、通気性が低下することがある。
本実施形態の吸収性物品用シートを構成する不織布は、規則的な模様を有する複数の第1交絡部を有することによって、毛羽立ちが生じにくい。具体的には、不織布は、以下の方法で測定される毛羽抜け量が1.0mg以下であるものとして提供される。
(毛羽抜け量測定試験)
a)ウレタンフォーム(ブリヂストン(株)製、商品名モルトプレンMF30、厚さ5mm)で表面を覆った円盤(直径70mm、350g)を、回転軸が円盤中心から20mmずれた位置となるように回転軸に取り付ける。
b)不織布の下面に、上記と同じウレタンフォームを敷き、不織布の上面が露出面となるように、不織布を台上に固定する。
c)不織布の上に前記円盤を載せる。このとき、不織布に加わる荷重は円盤の自重のみとする。
d)回転軸を回転させて、円盤を不織布上で周動させる。周動は時計周りに2回転、反時計周りに2回転を1セットとして、4セット行う。このときの周動速度は1周動あたり約3秒である。
e)4セットの周動後、不織布から抜け落ちて、円盤を覆っているウレタンフォームの表面に付着した繊維を集める。
f)前記a)~e)の操作をn=30枚の不織布について行う。30枚の不織布それぞれについて、抜け落ちた繊維の質量を測定し、その平均値を毛羽抜け量とする。
本実施形態の吸収性物品用シートを構成する不織布は、第1交絡部および第2交絡部が延びる方向と直交する方向のランオフ値によって吸液速度を評価すると、第1交絡部のない不織布、および第2交絡部のない不織布と比較して、より高い吸液速度を示す。また、本実施形態の吸収性物品用シートを構成する不織布は、規則的な模様が千鳥状または格子状に配置された低密度領域Aを有しない不織布と比較して、より高い吸液速度を示す。
(i)試料を用意する。
(ii)水平面と30度の角度を有する斜面を準備し、その斜面上に、ろ紙(Lister Paper(Grade989、10cm×10cm)を2枚重ねたものを吸収体として準備する。吸収体を、試料の寸法と同じか、それよりも広い面積にわたって、重ならないように敷きつめる。その上に試料を載せて固定する。試料は、第1交絡部および第2交絡部の延びる方向が斜面の傾斜方向と直交するように配置する。
(iii)試料の上端から1cm下方の位置に、37℃の0.90%生理食塩水(青色染料で着色)を、マイクロチューブポンプまたはビュレットから、1.0g/30secの速度で、1.0gまたは3.0g滴下する。全ての生理食塩水が不織布サンプルに吸収され、生理食塩水の水滴が不織布サンプル表面から消えたときの生理食塩水の先端の位置を測定する。当該位置と生理食塩水を不織布サンプル表面に滴下した位置との間の距離、即ち生理食塩水の水滴が不織布サンプル表面を流れた最長の距離を求めて、ランオフの値を得る。
一つの不織布について、3つの試料を用意して、前記(i)~(iii)を3回繰り返して得られた値を平均し、平均値を当該不織布のランオフ値として評価に利用する。
不織布は、例えば、
セルロース系繊維を90質量%以上含む繊維ウェブを作製すること、
繊維ウェブの全体にわたって高圧流体流による交絡処理を施すこと、
部分的に高圧流体による交絡処理を施して、規則的な模様を有する第1交絡部を形成すること
を含む製造方法により製造される。
E=W×N×T/(M×U×60)
E:1kg当たりの不織布に対し、1m幅当たりに1時間で印加するエネルギー(Wh/kg/m)
W:ノズル1孔当たりの流体の仕事率(W)
N:ノズルに1m幅当たりに開いているオリフィス数
T:噴射回数
M:高速水流処理対象の目付(g/m2)
U:搬送速度(m/分)
上記式におけるW(ノズルの1オリフィス当たりの流体の仕事率)は、下記の式によって求められる。
W=P1×(F/100)×0.163)
W:ノズルの1オリフィス当たりの流体の仕事率(W)
P1:水圧(kgf/cm2)
F:ノズルの一つのオリフィスから吐出される水の流量(cm3/分)
EおよびWの決定方法についての詳細は、特許第4893256号公報に記載されている。
あるいはまた、パターン形成支持体は、スパイラルネットであってよい。
前記において説明した不織布は、吸収性物品用シートを構成する。不織布は単独で吸収性物品用シートを構成してよく、あるいは他の不織布またはフィルム等と組み合わされて吸収性物品用シートを構成してよい。吸収性物品用シートが表面シートである場合には、不織布をそのまま吸収性物品用シートとして用いてよい。吸収性物品用シートは、不織布と液不透過性のフィルムとを一体化した形態で提供されてよい。
本実施形態の吸収性物品用シートは、吸収性物品を構成する部材として使用することができる。例えば、本実施形態の吸収性物品用シートは、吸収性物品の表面シート(トップシートとも称される)、中間シート、吸収コアを被覆するシート(SAPシート、コアラップシートとも称される)、バックシート等を構成する部材として用いることができる。ここで、バックシートとは、吸収体を介して表面シートとは反対側に設けられる液不透過性シートと対向して設けられ、吸収性物品の表面シートとは反対側の露出面を構成するシートを指す。したがって、バックシートは、使用者の衣服に触れる部分となる。吸収性物品用シートがバックシートとして用いられる場合には、不織布と液不透過性シートとが一体化されていてよい。
本開示の別の実施形態として、吸収性物品を説明する。本実施形態の吸収性物品の一例は、表面シートと、液不透過性シートと、表面シートと液不透過性シートとの間に配置される吸収体とを有する吸収性物品であって、表面シートが先に説明した実施形態の吸収性物品用シートである、吸収性物品である。本実施形態の別の例は、表面シートと、液不透過性シートと、表面シートと液不透過性シートとの間に配置される吸収体と、液不透過性シートの吸収体側の表面とは反対側の表面と対向して配置されるバックシートとを有する吸収性物品であって、表面シートまたはバックシートが、先に説明した実施形態の吸収性物品用シートである、吸収性物品である。
・平織支持体A(平織A):経糸(モノフィラメント)の線径0.7mm、緯糸(モノフィラメント)の線径0.7mm、織り密度25/25(本/inch)の平織りネット
・平織支持体D(平織D):経糸(モノフィラメント)の線径0.9mm、緯糸(モノフィラメント)の線径1.0mm、織り密度9/10(本/inch)の平織りネットであって、経糸を2本ずつ同じ状態に並べて緯糸を1本ずつ打ち込んだもの
繊度1.0dtex~5.0dtex、繊維長10mm~60mmのコットン(商品名MSD、丸三産業(株)製)のみを用いて、狙い目付け35g/m2のパラレルウェブを作製した。このウェブの全体にわたって、水流交絡処理(第1水流交絡処理)を実施した。第1水流交絡処理は、ウェブを、線径0.132mmのモノフィラメントからなる90メッシュ平織りの支持体に載せて、孔径0.12mmのオリフィスが0.6mm間隔で設けられたノズルを用いて、ウェブの一方の面に2MPaの柱状水流を1回噴射し、他方の面に4MPaの柱状水流を1回噴射し、さらに前記一方の面に2MPaの柱状水流を1回噴射して実施した。このときの支持体の速度は、4m/分であり、ノズルとウェブとの間の距離は10mmであった。
第2交絡処理において、幅6mmの第1交絡部が6mmおきに形成されるように、幅6mm×長さ6mmの穴を設けたアクリル樹脂製の穴あき部材(厚さ5mm)を使用したこと以外は、実施例1と同様の手順で不織布を得た。得られた不織布は、規則的な模様を有する幅6mmの第1交絡部と、無地の幅6mmの第2交絡部とを有するものであった。得られた不織布の規則的な模様は実施例1のそれと同じであり、不織布全体の開孔率は13.90%であった。
狙い目付けを40g/m2としたこと、第1水流交絡処理の際に、一方の面に水圧2MPaの水流を噴射し、他方の面に水圧4MPaの水流を噴射し、さらに一方の面に水圧2MPaの水流を噴射したことを除いては、実施例1と同様の手順で不織布を得た。得られた不織布の規則的な模様および開孔率は、実施例1のそれらと同じであった。
狙い目付けを40g/m2としたこと、第1水流交絡処理の際に、一方の面に水圧2MPaの水流を噴射し、他方の面に水圧4MPaの水流を噴射し、さらに一方の面に水圧2MPaの水流を噴射したこと、および第2交絡処理において、幅6mmの第1交絡部が6mmおきに形成されるように、幅6mm×長さ6mmの穴を設けたアクリル樹脂製の穴あき部材(厚さ5mm)を使用したこと以外は実施例1と同様の手順で不織布を得た。得られた不織布の規則的な模様は実施例1のそれと同じであり、不織布全体の開孔率は13.90%であった。
狙い目付けを45g/m2としたこと、第1水流交絡処理の際に、一方の面に水圧2MPaの水流を噴射し、他方の面に水圧4MPaの水流を噴射し、さらに一方の面に水圧2MPaの水流を噴射したことを除いては、実施例1と同様の手順で不織布を得た。得られた不織布の規則的な模様および開孔率は、実施例1のそれらと同じであった。
狙い目付けを45g/m2としたこと、第1水流交絡処理の際に、一方の面に水圧2MPaの水流を噴射し、他方の面に水圧4MPaの水流を噴射し、さらに一方の面に水圧2MPaの水流を噴射したこと、および第2交絡処理において、幅6mmの第1交絡部が6mmおきに形成されるように、幅6mm×長さ6mmの穴を設けたアクリル樹脂製の穴あき部材(厚さ5mm)を使用したこと以外は実施例1と同様の手順で不織布を得た。得られた不織布の規則的な模様は実施例1のそれと同じであり、不織布全体の開孔率は13.90%であった。
第2水流交絡処理を実施しなかったことを除いては、実施例4と同様の手順で不織布を得た。この不織布は全面にわたって無地であり、第1交絡部を有していなかった。
第2水流交絡処理において、穴あき部材を使用せずに、全面にわたって水流を噴射したことを除いては、実施例4と同様の手順で不織布を得た。この不織布は全面にわたって、千鳥状に配置された低密度領域Aと高密度領域とを有する規則的な模様を有しており、第2交絡部を有していなかった。千鳥状に配置された低密度領域Aの形状および寸法、ならびに低密度領域A間の間隔およびピッチは、実施例1の第1交絡部に形成された低密度領域Aのそれらと同じである。不織布全体の開孔率は28.00%であった。
狙い目付けを40g/m2としたこと、第1水流交絡処理の際に、一方の面に水圧2MPaの水流を噴射し、他方の面に水圧2MPaの水流を噴射し、さらに一方の面に水圧2MPaの水流を噴射したこと、および第2水流交絡処理の際に、平織支持体Dを用いたことを除いては、実施例1と同様の手順で不織布を得た。不織布全体の開孔率は5.97%であった。
厚さは、厚み測定機(商品名 THICKNESS GAUGE モデル CR-60A (株)大栄科学精器製作所製)を用い、試料1cm2あたり2.94cNの荷重を加えた状態で測定した。比容積は、目付と厚さから計算して求めた。
以下の手順に従って測定した。
(i)試料を用意する。
(ii)水平面と30度の角度を有する斜面を準備し、その斜面上に、ろ紙(Lister Paper(Grade989、10cm×10cm)を2枚重ねたものを吸収体として準備する。吸収体を、試料の寸法と同じか、それよりも広い面積にわたって、重ならないように敷きつめる。その上に試料を載せて固定する。試料は、第1交絡部および第2交絡部の延びる方向が斜面の傾斜方向と直交するように配置する。
(iii)試料の上端から1cm下方の位置に、37℃の0.90%生理食塩水(青色染料で着色)を、マイクロチューブポンプまたはビュレットから、1.0g/30secの速度で、1.0gまたは3.0g滴下する。全ての生理食塩水が不織布サンプルに吸収され、生理食塩水の水滴が不織布サンプル表面から消えたときの生理食塩水の先端の位置を測定する。当該位置と生理食塩水を不織布サンプル表面に滴下した位置との間の距離、即ち生理食塩水の水滴が不織布サンプル表面を流れた最長の距離を求めて、ランオフの値を得る。
一つの不織布について、3つの試料を用意して、前記(i)~(iii)を3回繰り返して得られた値を平均し、平均値を当該不織布のランオフ値として評価に利用する。
繊度1.0dtex~5.0dtex、繊維長10mm~60mmのコットン(商品名MSD、丸三産業(株)製)のみを用いて、狙い目付け35g/m2のパラレルウェブを作製した。このウェブの全体にわたって、水流交絡処理(第1水流交絡処理)を実施した。第1水流交絡処理は、ウェブを、線径0.132mmのモノフィラメントからなる90メッシュ平織りの支持体に載せて、高圧水によりウェブに印加されるエネルギー(E)の総和が74.7Wh/kg/mとなるように実施した。ノズルとウェブとの間の距離は30mmであった。
狙い目付けを40g/m2とし、第1水流交絡処理を、高圧水によりウェブに印加されるエネルギー(E)の総和が39.6Wh/kg/mとなるように実施したことを除いては、実施例7と同様の手順で不織布を得た。
第1水流交絡処理を、高圧水によりウェブに印加されるエネルギー(E)の総和が52.8Wh/kg/mとなるように実施したことを除いては、実施例7と同様の手順で不織布を得た。
狙い目付を30g/m2としたこと、第1水流交絡処理を、高圧水によりウェブに印加されるエネルギー(E)の総和が21.9Wh/kg/mとなるように実施したことを除いては、実施例1と同様の手順で不織布を得た。なお、狙い目付けを30g/m2とした場合には、第1水流交絡処理の条件を実施例7で用いた条件と同じにすると、高圧水の大きなエネルギーのために地合が乱れ、不織布の外観が著しく悪くなった。
狙い目付を30g/m2としたこと、第1水流交絡処理を、高圧水によりウェブに印加されるエネルギー(E)の総和が18.8Wh/kg/mとなるように実施したことを除いては、実施例1と同様の手順で不織布を得た。
a)ウレタンフォーム(ブリヂストン(株)製、商品名モルトプレンMF30、厚さ5mm)で表面を覆った円盤(直径70mm、350g)を、回転軸が円盤中心から20mmずれた位置となるように回転軸に取り付ける。
b)不織布の下面に、上記と同じウレタンフォームを敷き、不織布の上面が露出面となるように、不織布を台上に固定する。
c)不織布の上に前記円盤を載せる。このとき、不織布に加わる荷重は円盤の自重のみとする。
d)回転軸を回転させて、円盤を不織布上で周動させる。周動は時計周りに2回転、反時計周りに2回転を1セットとして、4セット行う。このときの周動速度は1周動あたり約3秒である。
e)4セットの周動後、不織布から抜け落ちて、円盤を覆っているウレタンフォームの表面に付着した繊維を集める。
f)前記a)~e)の操作をn=30枚の不織布について行う。30枚の不織布それぞれについて、抜け落ちた繊維の質量を測定し、その平均値を毛羽抜け量とする。
JIS L 1096 6.12.1 A法(ストリップ法)に準じて、定速緊張形引張試験機を用いて、試料片の幅5cm、つかみ間隔10cm、引張速度30±2cm/分の条件で引張試験に付し、切断時の荷重値(破断強度)を測定した。引張試験は、不織布の縦方向(MD方向)および横方向(CD方向)を引張方向として実施した。評価結果はいずれも3点の試料について測定した値の平均で示している。
(態様1)
セルロース系繊維を90質量%よりも多い量で含み、繊維同士が交絡してなる不織布を含む吸収性物品用シートであって、
前記不織布が、複数の互いに離間した第1交絡部と、複数の互いに離間した第2交絡部とを有し、
前記第1交絡部はそれぞれ、複数の繊維密度の高い領域(以下、「高密度領域」)と複数の繊維密度の低い領域(以下、「低密度領域」)とで形成された規則的な模様を有し、前記規則的な模様は、千鳥状または格子状に配置された略同一の低密度領域を有し、
前記第1交絡部はそれぞれ、不織布の縦方向または横方向に沿って延び、
前記第2交絡部はそれぞれ、不織布の縦方向または横方向に沿って延び、
前記第1交絡部と前記第2交絡部は交互に配置されており、
前記第1交絡部を合わせた面積が不織布全体の20%以上を占めており、
前記不織布の目付が30g/m2よりも大きく、
以下の試験による毛羽抜け量が1.0mg以下である、
吸収性物品用シート。
(毛羽抜け量測定試験)
a)ウレタンフォーム(ブリヂストン(株)製、商品名モルトプレンMF30、厚さ5mm)で表面を覆った円盤(直径70mm、350g)を、回転軸が円盤中心から20mmずれた位置となるように回転軸に取り付ける。
b)不織布の下面に、上記と同じウレタンフォームを敷き、不織布の上面が露出面となるように、不織布を台上に固定する。
c)不織布の上に前記円盤を載せる。このとき、不織布に加わる荷重は円盤の自重のみとする。
d)回転軸を回転させて、円盤を不織布上で周動させる。周動は時計周りに2回転、反時計周りに2回転を1セットとして、4セット行う。このときの周動速度は1周動あたり約3秒である。
e)4セットの周動後、不織布から抜け落ちて、円盤を覆っているウレタンフォームの表面に付着した繊維を集める。
f)前記a)~e)の操作をn=30枚の不織布について行う。30枚の不織布それぞれについて、抜け落ちた繊維の質量を測定し、その平均値を毛羽抜け量とする。
(態様2)
繊維同士が接着されていない、態様1の吸収性物品用シート。
(態様3)
前記セルロース系繊維がコットンである、態様1または2の吸収性物品用シート。
(態様4)
前記セルロース系繊維が、撥水性を有するコットンである、態様1または2の吸収性物品用シート。
(態様5)
前記セルロース系繊維のみからなる、態様1~4のいずれかの吸収性物品用シート。
(態様6)
前記略同一の低密度領域が開孔部である、態様1~5のいずれかの吸収性物品用シート。
(態様7)
前記低密度領域は一つあたり、0.1mm2~10mm2の面積を有している、態様1~6のいずれかの吸収性物品用シート。
(態様8)
前記第1交絡部の幅が、5mm~50mmであり、前記第2交絡部の幅が、5mm~50mmである、態様1~7のいずれかの吸収性物品用シート。
(態様9)
前記吸収性物品用シートは表面シートまたはバックシートである、態様1~8いずれかの吸収性物品用シート。
(態様10)
表面シートと、液不透過性シートと、前記表面シートと前記液不透過性シートとの間に配置される吸収体とを有する吸収性物品であって、前記表面シートが態様1~8のいずれかの吸収性物品用シートである、吸収性物品。
(態様11)
表面シートと、液不透過性シートと、前記表面シートと前記液不透過性シートとの間に配置される吸収体と、前記液不透過性シートの前記吸収体側の表面とは反対側の表面と対向して配置されるバックシートとを有する吸収性物品であって、前記表面シートまたは前記バックシートが、態様1~8のいずれかの吸収性物品用シートである、吸収性物品。
20 低密度領域A
31 第1交絡部が蛇行している方向
32 第1交絡部が蛇行している方向と直交する方向
41 第1交絡部
42 第2交絡部
Claims (11)
- セルロース系繊維を90質量%よりも多い量で含み、繊維同士が交絡してなる不織布を含む吸収性物品用シートであって、
前記不織布が、複数の互いに離間した第1交絡部と、複数の互いに離間した第2交絡部とを有し、
前記第1交絡部はそれぞれ、複数の繊維密度の高い領域(以下、「高密度領域」)と複数の繊維密度の低い領域(以下、「低密度領域」)とで形成された規則的な模様を有し、前記規則的な模様は、千鳥状または格子状に配置された略同一の低密度領域を有し、
前記第1交絡部はそれぞれ、不織布の縦方向または横方向に沿って延び、
前記第2交絡部はそれぞれ、不織布の縦方向または横方向に沿って延び、
前記第1交絡部と前記第2交絡部は交互に配置されており、
前記第1交絡部を合わせた面積が不織布全体の20%以上を占めており、
前記不織布の目付が30g/m2よりも大きく、
以下の試験による毛羽抜け量が1.0mg以下である、
吸収性物品用シート。
(毛羽抜け量測定試験)
a)ウレタンフォーム(ブリヂストン(株)製、商品名モルトプレンMF30、厚さ5mm)で表面を覆った円盤(直径70mm、350g)を、回転軸が円盤中心から20mmずれた位置となるように回転軸に取り付ける。
b)不織布の下面に、上記と同じウレタンフォームを敷き、不織布の上面が露出面となるように、不織布を台上に固定する。
c)不織布の上に前記円盤を載せる。このとき、不織布に加わる荷重は円盤の自重のみとする。
d)回転軸を回転させて、円盤を不織布上で周動させる。周動は時計周りに2回転、反時計周りに2回転を1セットとして、4セット行う。このときの周動速度は1周動あたり約3秒である。
e)4セットの周動後、不織布から抜け落ちて、円盤を覆っているウレタンフォームの表面に付着した繊維を集める。
f)前記a)~e)の操作をn=30枚の不織布について行う。30枚の不織布それぞれについて、抜け落ちた繊維の質量を測定し、その平均値を毛羽抜け量とする。 - 繊維同士が接着されていない、請求項1に記載の吸収性物品用シート。
- 前記セルロース系繊維がコットンである、請求項1または2に記載の吸収性物品用シート。
- 前記セルロース系繊維が、撥水性を有するコットンである、請求項1または2に記載の吸収性物品用シート。
- 前記セルロース系繊維のみからなる、請求項1~4のいずれか1項に記載の吸収性物品用シート。
- 前記略同一の低密度領域が開孔部である、請求項1~5のいずれか1項に記載の吸収性物品用シート。
- 前記低密度領域は一つあたり、0.1mm2~10mm2の面積を有している、請求項1~6のいずれか1項に記載の吸収性物品用シート。
- 前記第1交絡部の幅が、5mm~50mmであり、前記第2交絡部の幅が、5mm~50mmである、請求項1~7のいずれか1項に記載の吸収性物品用シート。
- 前記吸収性物品用シートは表面シートまたはバックシートである、請求項1~8のいずれか1項に記載の吸収性物品用シート。
- 表面シートと、液不透過性シートと、前記表面シートと前記液不透過性シートとの間に配置される吸収体とを有する吸収性物品であって、前記表面シートが請求項1~8のいずれか1項に記載の吸収性物品用シートである、吸収性物品。
- 表面シートと、液不透過性シートと、前記表面シートと前記液不透過性シートとの間に配置される吸収体と、前記液不透過性シートの前記吸収体側の表面とは反対側の表面と対向して配置されるバックシートとを有する吸収性物品であって、前記表面シートまたは前記バックシートが、請求項1~8のいずれか1項に記載の吸収性物品用シートである、吸収性物品。
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| EP18824215.0A EP3646835B8 (en) | 2017-06-30 | 2018-06-28 | Sheet for absorbent article, and absorbent article |
| US16/626,400 US20200155374A1 (en) | 2017-06-30 | 2018-06-28 | Sheet for absorbent article and absorbent article |
| CN201880043102.8A CN110831558A (zh) | 2017-06-30 | 2018-06-28 | 吸收性物品用片及吸收性物品 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2018/024642 Ceased WO2019004369A1 (ja) | 2017-06-30 | 2018-06-28 | 吸収性物品用シート及び吸収性物品 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20200155374A1 (ja) |
| EP (1) | EP3646835B8 (ja) |
| JP (1) | JP7112636B2 (ja) |
| CN (1) | CN110831558A (ja) |
| TW (1) | TWI770213B (ja) |
| WO (1) | WO2019004369A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021123819A (ja) * | 2020-02-04 | 2021-08-30 | ダイワボウホールディングス株式会社 | 対人用拭き取りシート用不織布及びその製造方法、並びに対人用拭き取りシート |
| JP7212804B1 (ja) | 2022-01-31 | 2023-01-25 | 大王製紙株式会社 | 使い捨て着用物品 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102020119388B4 (de) * | 2020-07-22 | 2023-08-17 | Delfortgroup Ag | Plissiertes filtermaterial für rauchartikel |
| US12325938B2 (en) * | 2021-05-28 | 2025-06-10 | Nike, Inc. | Nonwoven entanglement system and methods of manufacture |
| US12342885B2 (en) | 2021-05-28 | 2025-07-01 | Nike, Inc. | Nonwoven textile with non-linear entangled seams suitable for garments |
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| JPH10280260A (ja) * | 1997-04-04 | 1998-10-20 | Daiwabo Co Ltd | 開孔不織布 |
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| JP2010106430A (ja) * | 2009-12-25 | 2010-05-13 | Kao Corp | 吸収性物品の表面シート |
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- 2018-06-28 CN CN201880043102.8A patent/CN110831558A/zh active Pending
- 2018-06-28 EP EP18824215.0A patent/EP3646835B8/en active Active
- 2018-06-28 US US16/626,400 patent/US20200155374A1/en not_active Abandoned
- 2018-06-28 JP JP2019527027A patent/JP7112636B2/ja active Active
- 2018-06-29 TW TW107122556A patent/TWI770213B/zh active
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| JPH03137258A (ja) * | 1989-10-20 | 1991-06-11 | Kao Corp | 不織布 |
| JPH10280260A (ja) * | 1997-04-04 | 1998-10-20 | Daiwabo Co Ltd | 開孔不織布 |
| JPH1193055A (ja) * | 1997-09-12 | 1999-04-06 | Oji Paper Co Ltd | 水解性不織布およびその製造方法 |
| JP4893256B2 (ja) | 2006-11-17 | 2012-03-07 | 東レ株式会社 | 流体交絡不織布の製造方法およびそれによって得られた流体交絡不織布からなる皮革様シートの製造方法 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021123819A (ja) * | 2020-02-04 | 2021-08-30 | ダイワボウホールディングス株式会社 | 対人用拭き取りシート用不織布及びその製造方法、並びに対人用拭き取りシート |
| JP7503911B2 (ja) | 2020-02-04 | 2024-06-21 | 大和紡績株式会社 | 対人用拭き取りシート用不織布及びその製造方法、並びに対人用拭き取りシート |
| JP7212804B1 (ja) | 2022-01-31 | 2023-01-25 | 大王製紙株式会社 | 使い捨て着用物品 |
| JP2023111158A (ja) * | 2022-01-31 | 2023-08-10 | 大王製紙株式会社 | 使い捨て着用物品 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3646835A4 (en) | 2021-03-17 |
| TW201906591A (zh) | 2019-02-16 |
| EP3646835B8 (en) | 2023-06-07 |
| JPWO2019004369A1 (ja) | 2020-04-30 |
| EP3646835A1 (en) | 2020-05-06 |
| TWI770213B (zh) | 2022-07-11 |
| EP3646835B1 (en) | 2023-05-03 |
| US20200155374A1 (en) | 2020-05-21 |
| JP7112636B2 (ja) | 2022-08-04 |
| CN110831558A (zh) | 2020-02-21 |
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