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WO2019000394A1 - Composition de nettoyage sans sulfates - Google Patents

Composition de nettoyage sans sulfates Download PDF

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Publication number
WO2019000394A1
WO2019000394A1 PCT/CN2017/091098 CN2017091098W WO2019000394A1 WO 2019000394 A1 WO2019000394 A1 WO 2019000394A1 CN 2017091098 W CN2017091098 W CN 2017091098W WO 2019000394 A1 WO2019000394 A1 WO 2019000394A1
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WO
WIPO (PCT)
Prior art keywords
composition
weight
carbon atoms
fatty acid
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2017/091098
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English (en)
Inventor
Yixi ZHOU
Yanan YUE
Haidong JIA
Yue Liu
Alia ZHAO
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LOreal SA
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LOreal SA
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Priority to PCT/CN2017/091098 priority Critical patent/WO2019000394A1/fr
Publication of WO2019000394A1 publication Critical patent/WO2019000394A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients

Definitions

  • the present invention relates to personal cleansing compositions. More particularly, the invention relates to a sulfate-free cleansing composition, for example a shampoo, having improved conditioning properties as well as usage qualities.
  • rheology modifiers in order to thicken the product.
  • the addition of the rheology modifiers can adversely impact the properties of the composition such as cleansing properties, foaming properties, rinsibility, by decreasing the foam and ease of distribution of the composition.
  • cleansing compositions for application to sensitized hair, i.e., hair which is damaged or weakened, in particular through the chemical action of environmental agents and/or of hair treatments such as permanent-waving, dyeing or bleaching
  • these compositions conditioning agents are known to introduce into these compositions conditioning agents.
  • the main purpose of these conditioning agents is to rectify or limit the undesirable effects induced by the various treatments or types of attach to which the hair fibers are more or less repeatedly subjected to and, of course, they can also improve the cosmetic behavior of natural hair.
  • the conditioning agents most commonly used to date in shampoos are cationic polymers, silicones and/or silicone derivatives which impart to washed, dry or wet hair a disentangling, softness and a smoothness which are markedly enhanced in comparison to what can be obtained with corresponding cleansing compositions which do not contain them.
  • the composition has pleasant esthetic properties such as a transparent appearance.
  • composition of the present invention is formulated to solve the above mentioned needs.
  • aqueous cleansing composition comprising:
  • the composition of the present invention is transparent.
  • the present invention is also directed to a process for cleansing a keratinous substrate involving contacting the keratinous substrate with the above-disclosed composition.
  • the present invention is also directed to a method of cleansing and conditioning a keratinous substrate involving contacting the keratinous substrate with the above-disclosed composition.
  • compositions of the invention provide not only good cleansing of keratinous substrates, but also create good and luxuriously feeling foam, while at the same time imparting good conditioning properties onto the substrate.
  • the compositions of the invention remain stable even at elevated (e.g. 45°C) or reduced temperatures (e.g. 4°C) .
  • ranges provided are meant to include every specific range within, and combination of sub ranges between, the given ranges.
  • a range from 1 to 5 includes 1, 2, 3, 4, and 5 as well as 1-4, 2-4, 1-3, etc.
  • At least one means one or more and thus includes individual components as well as mixtures/combinations.
  • Constanting means imparting to hair at least one property chosen from compatibility, manageability, moisture-retentivity, luster, shine, and softness. The state of conditioning is evaluated by measuring, and comparing the ease of combing of the treated hair in contrast with the untreated hair.
  • “Stable over time” is understood to mean compositions of the present invention which, after storage at all temperatures between 4°C and 45°C for 2 months, do not exhibit any macroscopic change in colour, smell or viscosity, any variation in pH or any variation in microscopic appearance.
  • the term “transparent” is understood to mean a composition having a turbidity of less than 200 NTU (Nephelometric Turbidity Units) at 25°C and preferably of less than 150 NTU at 25°C, more preferably less than or equal to 100 NTU at 25°C, measured with a 2100N Turbidimeter machine from HACH, wherein the sample cells for turbidity testing are made of quartz glass with reference Cat. 2084900.
  • NTU Nephelometric Turbidity Units
  • keratin fibers include but are not limited to, skin, hair, lips, eyelashes and nails.
  • a Preferred keratinous substrate is hair.
  • the present invention relates to a cleansing composition
  • a cleansing composition comprising:
  • compositions of the present invention comprise at least one anionic surfactant that is not an alkyl sulfate or alkyl ether sulfate.
  • anionic surfactant that is not an alkyl sulfate or alkyl ether sulfate.
  • These surfactants can be chosen from salts, for example, alkali metal salts such as sodium salts, ammonium salts, amine salts, amino alcohol salts and alkaline-earth metal salts.
  • composition of the present invention is essentially free of sulfate-based surfactant.
  • essentially free of sulfate-based surfactant and “essentially sulfate free” refer to the contents of sulfate-based surfactants in the composition of the present invention. “Essentially free of sulfate-based surfactant” means that, while it prefers that no sulfate-based surfactants be present in the composition, it is possible to have very small amounts of sulfate-based surfactants in the composition of the invention, provided that these amounts do not materially affect the advantageous properties of the composition.
  • “essentially free of sulfate-based surfactant” means that the sulfate-based surfactants can be present in the composition at an amount of less than 2.0%by weight, typically less than 1.5%by weight, typically less than 1.0%by weight, typically less than 0.5%by weight, typically less than 0.1%by weight, and more typically 0%by weight, based on the total weight of the composition.
  • these surfactants can be chosen from salts, for example, alkali metal salts such as sodium salts, ammonium salts, amine salts, amino alcohol salts and alkaline-earth metal salts.
  • alkali metal salts such as sodium salts, ammonium salts, amine salts, amino alcohol salts and alkaline-earth metal salts.
  • alkaline-earth metal salts include magnesium salts of the following types of compounds: acyl isethionates, acyl glycianates, acyl taurates, acyl amino acids, acyl sarcosinates, sulfosuccinates, sulfonates, and sulfoacetates, the alkyl and acyl groups of all these compounds comprising from 6 to 24 carbon atoms (saturated or unsaturated, linear or branched) .
  • Non-limiting examples of acyl amino acids useful in the compositions of the invention include those having the following formula (I) :
  • R is a linear or branched, saturated or unsaturated C 8 -C 16 and more preferentially C 12 -C 18 alkyl chain;
  • X is an organic cation, for instance an alkanolamine such as triethanolamine, or a mineral cation, for instance an alkali metal such as sodium or potassium, or alternatively ammonia.
  • radicals R mention may be made of stearyl, myristyl, oleyl, lauryl and cocoyl.
  • N-acyl sarcosinates that may be used according to the invention, mention may be made of sodium lauroyl sarcosinate (INCI name: Sodium lauroyl sarcosinate) sold under the name Sarkosyl NL by the company Ciba or sold under the name Oramix L by the company SEPPIC, or sold under the name Amin LS30L by the company Guangzhou Tinci Materials; sodium myristoyl sarcosinate (INCI name: Sodium myristoyl sarcosinate) sold under the name Nikkol Sarcosinate by the company Nikkol, sodium palmitoyl sarcosinate (INCI name: Sodium palmitoyl sarcosinate) sold under the name Nikkol Sarcosinate by the company Nikkol.
  • sodium lauroyl sarcosinate INCCI name: Sodium lauroyl sarcosinate
  • Sarkosyl NL by the company Ciba
  • Oramix L by the
  • Non-limiting examples oftaurates useful in the compositions of the invention include those having the following formula (II) :
  • R is selected from H or an alkyl chain that has 1-24 carbon atoms, said chain being saturated or unsaturated, linear or branched.
  • a particular taurate that can be used in the current compositions is sodium methyl cocoyl taurate.
  • Non-limiting examples of isethionates useful in the compositions of the invention include those having the formulas (III) or (IV) below:
  • R is selected from H or an alkyl chain that has 1-24 carbon atoms, said chain being saturated or unsaturated, linear or branched.
  • Particular isethionates that can be used in the current compositions include, for example, sodium cocoyl isethionate, sodium lauroyl methyl isethionate, and mixtures thereof.
  • Non-limiting examples of sulfosuccinates useful in the compositions of the invention include those having the following formula (V) :
  • R is selected from H or an alkyl chain that has 1-24 carbon atoms, said chain being saturated or unsaturated, linear or branched.
  • a particular sulfosuccinate that can be used in the current compositions is disodium laureth sulfosuccinate.
  • Non-limiting examples of sulfonates useful in the compositions of the invention include those having the following formula (VI) :
  • R is selected from H or an alkyl chain that has 1-24 carbon atoms, said chain being saturated or unsaturated, linear or branched.
  • a particular sulfonate that can be used in the current compositions is sodium C 14- 16 olefin sulfonate.
  • Non-limiting examples of sulfoacetates useful in the compositions of the invention include those having the following formula (VII) :
  • R is as defined above for the sulfonates.
  • a particular sulfoacetate that can be used in the current compositions is sodium lauryl sulfoacetate.
  • the anionic surfactant that is most preferred in the present invention is acyl amino acids useful in the compositions of the invention include those having the following formula (I) as described above, more preferably N-acyl sarcosinates, even more preferably sodium lauroyl sarcosinate (INCI name: Sodium lauroyl sarcosinate) .
  • the at least one anionic surfactant is present in a total amount ranging from 1%to 15%by weight, preferably from 2%to 13%by weight, more preferably from 4%to 12%by weight, based on the total weight of the composition.
  • composition according to the invention comprises one or more amphoteric or zwitterionic surfactants as defined hereinafter.
  • amphoteric or zwitterionic surfactants capable of being used in the present invention can in particular be derivatives of optionally quaternized secondary or tertiary aliphatic amines comprising at least one anionic group, such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group, and in which the aliphatic group or at least one of the aliphatic groups is a linear or branched chain comprising from 8 to 22 carbon atoms.
  • alkylbetaines mentions may be made of behenylbetaine, cetyl betaine, cocoylbetaine, decylbetaine.
  • cocoylbetaine is preferred, for example the products sold by the company Rhodia under the tradename BB/FLA.
  • R a represents a C 10 -C 30 alkyl or alkenyl group derived from an acid R a -COOH preferably present in hydrolysed coconut oil, or a heptyl, nonyl or undecyl group,
  • R b represents a ⁇ -hydroxyethyl group
  • R c represents a carboxymethyl group
  • n 0, 1 or 2;
  • Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group.
  • X' represents the-CH 2 -COOH, CH 2 -COOZ’ , -CH 2 CH 2 -COOH, or-CH 2 CH 2 -COOZ’ group, or a hydrogen atom
  • Y' represents–COOH, –COOZ’ , or the-CH 2 -CHOH-SO 3 H or-CH 2 -CHOH-SO 3 Z’ group,
  • Z’ represents an ion resulting from an alkali metal or alkaline-earth metal, such as sodium, potassium or magnesium; an ammonium ion; or an ion resulting from an organic amine and in particular from an amino alcohol, such as monoethanolamine, diethanolamine and triethanolamine, monoisopropanolamine, diisopropanolamine or triisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, 3-propanediol and tris (hydroxymethyl) aminomethane,
  • an alkali metal or alkaline-earth metal such as sodium, potassium or magnesium
  • an ammonium ion or an ion resulting from an organic amine and in particular from an amino alcohol, such as monoethanolamine, diethanolamine and triethanolamine, monoisopropanolamine, diisopropanolamine or triisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino
  • Ra' represents a C 10 -C 30 alkyl or alkenyl group of an acid R a’ COOH preferably present in hydrolysed linseed oil or coconut oil, or an alkyl group, in particular a C 17 group, and its iso form, or an unsaturated C 17 group,
  • n 1 or 2
  • Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group.
  • cocoamphodiacetate sold by the company Rhodia under the trade name C2M concentrate or under the trade name Miranol Ultra C 32 and the product sold by the company Chimex under the trade name Chimexane HA.
  • R a represents a C 10 -C 30 alkyl or alkenyl group of an acid
  • R a” -C (O) OH which is preferably present in hydrolysed linseed oil or coconut oil;
  • Y'’ represents the group–C (O) OH, -C (O) OZ” , -CH 2 -CH (OH) -SO 3 H or the group-CH 2 -CH (OH) -SO 3 -Z” , with Z” representing a cationic counterion resulting from an alkali metal or alkaline-earth metal, such as sodium, an ammonium ion or an ion resulting from an organic amine;
  • R d and R e represent, independently of each other, a C 1 -C 4 alkyl or hydroxyalkyl radical; and n and n' denote, independently of each other, an integer ranging from 1 to 3.
  • Mention may in particular be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and sold by the company Chimex under the name Chimexane HB.
  • amphoteric or zwitterionic surfactants are chosen from betaines.
  • amphoteric or zwitterionic surfactants are chosen from (C 8 -C 20 ) alkylbetaines, such as cocoyl betaine.
  • composition according to the invention preferably comprises the amphoteric or zwitterionic surfactant (s) in an amount ranging from 0.01%to 20%by weight, in particular from 0.1%to 10%by weight and better still from 0.15%to 5%by weight, relative to the total weight of the composition.
  • composition of the present invention comprises at least one nonionic surfactant chosen from alkanolamides of C 6 -C 30 fatty acids.
  • Such surfactants can be chosen from mono-alkanolamides and di-alcanolamides of formula (A) ,
  • R 1 is a linear or branched, saturated or unsaturated hydrocarbon group having 6 to 30 carbon atoms
  • R 2 and R 3 independently, is hydrogen or a linear or branched, saturated or unsaturated alkanol group having 1 to 10 carbon atoms, provided that only one ofR 2 or R 3 is hydrogen.
  • Examples of this type of surfactants can be mentioned are lauric acid monoethanolamide, lauric acid diethanolamide, lauric acid monopropanolamide, lauric acid monoisopropanolamide, myristic acid monoethanolamide, myristic acid diethanolamide, palmitic acid monoethanolamide, stearic acid monoethanolamide (stearamide MEA) , oleic acid monoethanolamide, oleic acid diethanolamide, oleic acid monoisopropanolamide, coconut oil fatty acid monoethanolamide (cocamide MEA) , coconut oil fatty acid monopropanolamide, coconut oil fatty acid monoisopropanolamide (cocamide MIPA) , erucic acid diethanolamide, palm vegetable oil fatty acid monoethanolamide, or a mixture thereof.
  • R 1 is a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 18 carbon atoms
  • R 2 and R 3 independently, is hydrogen or a linear or branched, saturated or unsaturated alkanol group having 2 to 5 carbon atoms, provided that only one ofR 2 or R 3 is hydrogen.
  • R 2 is hydrogen
  • R 3 is a linear or branched, saturated alkanol group having 2 to 5 carbon atoms.
  • the suitable alkanolamide of C 6 -C 30 fatty acids of formula (A) is chosen from coconut oil fatty acid monoethanolamide (INCI: cocamide MEA or cocamide monoethanolamine) , coconut oil fatty acid monoisopropanolamide (INCI: cocamide MIPA or cocamide mono-isopropanolamine) , or a mixture thereof.
  • coconut oil fatty acid monoethanolamide sold under the name 100 by the company COGNIS (BASF)
  • coconut oil fatty acid monoisopropanolamide sold under the tradename CIS by the company Innospec Active Chemicals.
  • said alkanolamide of C 6 -C 30 fatty acids is cocamide mono-isopropanolamine.
  • the alkanolamide of C 6 -C 30 fatty acids according to the present invention presents in an amount ranging from 0.5%to 10%by weight, more preferably from 0.1%to 5%by weight, based on the total weight of the composition.
  • the composition comprises at least one fatty acid ester of glycerol and/or of polyglycerol.
  • the fatty acid ester (s) of polyglycerol is (are) chosen from esters resulting from the reaction of polyglycerol comprising from 2 to 12 glycerol units, preferably from 3 to 10 glycerol units, and of at least one fatty acid containing from 8 to 24 carbon atoms, preferably from 8 to 22 carbon atoms, better still from 10 to 20 carbon atoms and even better still from 10 to 18 carbon atoms.
  • the fatty acids containing from 8 to 24 carbon atoms may be linear or branched, and saturated or unsaturated.
  • the fatty acids may be chosen from oleic acid, stearic acid, isostearic acid, lauric acid, palmitic acid, myristic acid, linoleic acid, capric acid and caprylic acid, or mixtures thereof.
  • the fatty acid esters of polyglycerol can be chosen from monoesters, diesters, triesters and tetraesters, polyesters and mixtures thereof. Use is preferably made of esters with a low degree of esterification, for instance fatty acid monoesters, diesters or triesters of polyglycerol, or a mixture.
  • the fatty acid ester of polyglycerol can be in the form of a mixture of esters with a low degree of esterification, for instance a mixture of monoester and diester or a mixture of monoester, diester and triester.
  • the fatty acid ester of polyglycerol is chosen from esters resulting from the reaction of polyglycerol comprising from 3 to 10 glycerol units and of at least one fatty acid containing from 8 to 20 carbon atoms, preferably from 10 to 18 carbon atoms, such as oleic acid or linoleic acid.
  • polyglyceryl-2 distearate in particular as sold by NIHON EMULSION under the name Emalex PGSA
  • polyglyceryl-10 decastearate in particular as sold by TAIYO KAGAKU under the name Sunsoft Q-1810S
  • glyceryl oleate in particular as soldby COGNIS under the name 90-O 18
  • glyceryl stearate in particular as sold by COGNIS under the name Cutina GMS V
  • polyglyceryl-5 hexastearate in particular as sold by TAIYO KAGAKU under the name Sunsoft A-186E
  • polyglyceryl-10 pentaoleate in particular as sold by TAIYO KAGAKU under the name Sunsoft Q-175S
  • polyglyceryl-10 pentastearate in particular as sold by TAIYO KAGAKU under the name Sunsoft Q-185S
  • glyceryl caprylate/caprate in particular as sold by ST
  • the fatty acid which is suitable for the reaction with the ester (s) of polyglycerol comprises at least one hydroxyl group.
  • the fatty acid which is suitable for the reaction with the ester (s) of polyglycerol is a polyacid comprising at least one hydroxyl group.
  • the fatty acid ester of the present invention is chosen from esters resulting from the reaction of polyglycerol comprising from 3 to 10 glycerol units and of at least one fatty acid containing from 8 to 20 carbon atoms, for example glyceryl oleate.
  • the fatty acid ester (s) (d) is (are) present in the composition ranging from 0.05%to 20%by weight, preferably from 0.1%to 10%by weight, more preferably 0.5%to 5%by weight, relative to the total weight of the composition.
  • composition according to the invention comprises an aqueous phase.
  • the aqueous phase is a continuous phase.
  • the aqueous phase of the present invention comprises water.
  • the aqueous phase may also comprise water-miscible organic solvents (at room temperature of20-25°C) , for instance polyols such as C 2 -C 6 polyols, more particularly glycerin, hexylene glycol; glycol ethers (especially containing from 3 to 16 carbon atoms) such as mono-, di-or tripropylene glycol (C 1 -C 4 ) alkyl ethers, mono-, di-or triethylene glycol (C 1 -C 4 ) alkyl ethers, and mixtures thereof.
  • polyols such as C 2 -C 6 polyols, more particularly glycerin, hexylene glycol
  • glycol ethers especially containing from 3 to 16 carbon atoms
  • the amount of the aqueous phase is from 85%to 99.9%, preferably from 90%to 99.5%in weight based on the total weight of the composition.
  • composition according to the present invention comprises at least one oily phase.
  • the oily phase of the present invention is a dispersed phase.
  • the oily phase of the present invention comprises at least one oil.
  • oil means any fatty substance that is in liquid form at room temperature (20-25°C) and at atmospheric pressure (760 mmHg) .
  • the oil included in the oily phase suitable for preparing the compositions according to the invention may comprise hydrocarbon-based oils, silicone oils, fluoro oils or non-fluoro oils, or mixtures thereof.
  • the composition of the present invention comprises hydrocarbon-based oils.
  • the oils may be volatile or non-volatile.
  • composition of the present invention is silicone-free.
  • silicone-free means the composition of the present invention comprising no silicone or comprising silicone in an amount no more than 1%by weight of silicones relative to the total composition.
  • the composition may contain no more than 0.5%by weight, more preferably no more than 0.2%by weight, of silicones relative to the total weight of the composition.
  • composition of the present invention does not contain silicone.
  • non-volatile oil means oil that remains on the keratin materials at room temperature (20-25°C) and atmospheric pressure (760 mmHg) . More specifically, non-volatile oil has an evaporation rate strictly less than 0.01 mg/cm2/min.
  • volatile oil means any non-aqueous medium that is capable of evaporating on contact with the keratin materials in less than one hour, at room temperature (20-25°C) and atmospheric pressure (760 mmHg) .
  • the volatile oil is a cosmetic volatile oil, which is liquid at room temperature. More specifically, a volatile oil has an evaporation rate of between 0.01 and 200 mg/cm2/min, limits included.
  • the amount of the oily phase is from 0.1%to 15%, preferably from 0.5%to 5%in weight based on the total weight of the composition.
  • the composition of the present invention is transparent.
  • the turbidity of the composition of the present invention is less than or equal to 100 NTU at 25°C, measured with a 2100N Turbidimeter machine from HACH, preferably is less than or equal to 80NTU at 25°C.
  • the composition has a pH value of less than or equal to 6, preferably from 3.5 to 5.8, more preferably from4 to 5.6, even more preferably from 5 to 5.6.
  • the composition of the present invention has a viscosity from 3000 mPa ⁇ s to 20000 mPa ⁇ s, measured using Brookfield viscometer at 50 RPM using spindle T-C.
  • the composition of the present invention has a viscosity of from 4000 mPa ⁇ s to 15000 mPa ⁇ s, preferably from 5000 mPa ⁇ s to 12000 mPa ⁇ s, measured using Brookfield viscometer at 50 RPM using spindle T-C.
  • composition of the present disclosure may additionally include any other adjuvant or additive that is usually used in the field of self-cleaning products, in particular shampoos.
  • additives include cationic polymers, pH adjusting agents, preserving agents, sequestrants and chelators, consistency regulators, thickeners, antioxidants, fragrances, dyestuffs such as soluble dyes and pigments, optical brighteners, electrolytes and stabilizers, plant extracts, proteins, amino acids, vitamins, glycols, emollients, derivatives of the foregoing, and mixtures thereof. Additional examples of additives may be found in the International Cosmetic Ingredient Dictionary and Handbook (9 th ed. 2002, as subsequent editions) .
  • Suitable examples of the cationic polymers include, for example, cationic gum derivatives, such as for example gum derivatives, including particularly guar hydroxypropyltrimonium chloride, and mixtures thereof.
  • the pH adjusting agent is used in an amount from 0.01%to 8%by weight, preferably from 0.05%to 5%by weight, more preferably from 0.1%to 2%by weight, relative to the total weight of the composition.
  • the present invention relates to a transparent cleansing composition
  • a transparent cleansing composition comprising, relative to the total weight of the composition:
  • esters resulting from the reaction of polyglycerol comprising from 3 to 10 glycerol units and of at least one fatty acid containing from 8 to 20 carbon atoms.
  • Another aspect of the invention is a process for washing and/or conditioning keratin fibers, especially the hair, comprising the steps of applying to said fibers the composition of the invention, and then rinsing with water after an optional period of exposure.
  • Yet another aspect of the present invention is the use of the above composition of the invention for washing and/or conditioning keratin fibers, especially hair.
  • Comparative formula contains coco-glucoside, instead of COCAMIDE MIPA, both of which are nonionic surfactants.
  • Stability was evaluated by storing the formulas for 2 months at 4°C, 20°C, and 45°C for 2 months.
  • Foaming property of the formulas were conducted as follow: 4 gram of formula was ment of the volume of foam after mixing in kitchen blender for 1 minute was conducted.
  • Test formula was randomly applied side by side to one half of the head and compared to the standard on the remaining half. This test protocol was used to evaluate foam, detergency, and conditioning of the hair. The scales for measuring these parameters ranged between 1 to 5, wherein 1 is poor, and 5 is superior and very good effect; and 3 is acceptable effect.
  • the invention formulas D and F present very good cosmetic properties, such as conditioning of the hair, and foaming property. Besides, the invention formulas D and F, comparing to the comparative formula D’ , have improved usage qualities, thanks to the increased viscosities. Lastly, the invention formulas D and F have pleasant transparent appearance, whereas the comparative formula D’ is not transparent.
  • the invention formulas D and F are stable, after storage 2 months under different temperatures.

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  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition de nettoyage comprenant (a) au moins un tensioactif anionique qui n'est pas un sulfate d'alkyle ou un sulfate d'éther d'alkyle ; (b) au moins un tensioactif amphotère ou zwitterionique ; (c) au moins un alcanolamide d'acides gras en C6-C30 ; et (d) au moins un ester d'acide gras de glycérol et de polyglycérol. Des procédés de nettoyage et de conditionnement des cheveux utilisant lesdites compositions et des procédés de fabrication desdites compositions sont en outre décrits.
PCT/CN2017/091098 2017-06-30 2017-06-30 Composition de nettoyage sans sulfates Ceased WO2019000394A1 (fr)

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PCT/CN2017/091098 WO2019000394A1 (fr) 2017-06-30 2017-06-30 Composition de nettoyage sans sulfates

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WO2019000394A1 true WO2019000394A1 (fr) 2019-01-03

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020176376A1 (fr) * 2019-02-28 2020-09-03 L'oreal Compositions cosmétiques à base de plantes
US11123276B2 (en) 2018-02-28 2021-09-21 L'oreal Cosmetic compositions
WO2022128441A1 (fr) * 2020-12-18 2022-06-23 Unilever Ip Holdings B.V. Composition de nettoyage
US11376207B2 (en) 2017-10-31 2022-07-05 L'oreal Hair care compositions
WO2023275299A1 (fr) * 2021-07-02 2023-01-05 Unilever Ip Holdings B.V. Ester comprenant une composition de tensioactif concentrée hydratable
US12311045B2 (en) 2020-06-30 2025-05-27 L'oreal Natural non-sulfate rinse-off cleansing compositions with high oil loading, and methods of use

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005092275A1 (fr) * 2004-03-26 2005-10-06 L'oreal Composition cosmetique comprenant un dendrimere a chaînes grasses peripheriques, un tensioactif et un agent cosmetique, et ses utilisations
CN101084870A (zh) * 2007-06-22 2007-12-12 昆明理工大学 一种乳化盐型中草药发用洗护乳液及其制备方法
WO2015071298A2 (fr) * 2013-11-13 2015-05-21 L'oreal Composition moussante comprenant au moins un surfactant de type glycinate
CN106236690A (zh) * 2016-08-31 2016-12-21 福建省梦娇兰日用化学品有限公司 一种含多种植物成分的氨基酸洁面膏
CN106580726A (zh) * 2016-11-11 2017-04-26 珠海伊斯佳科技股份有限公司 一种含氨基酸的无硅油洗发水及其制备方法
CN106667797A (zh) * 2016-12-30 2017-05-17 广州市科能化妆品科研有限公司 具有自防腐功能的温和洗发水组合物
CN106726919A (zh) * 2016-12-16 2017-05-31 广东宝贝儿婴童用品股份有限公司 一种不含二噁烷的婴幼儿氨基酸草本组合物及其制备

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005092275A1 (fr) * 2004-03-26 2005-10-06 L'oreal Composition cosmetique comprenant un dendrimere a chaînes grasses peripheriques, un tensioactif et un agent cosmetique, et ses utilisations
CN101084870A (zh) * 2007-06-22 2007-12-12 昆明理工大学 一种乳化盐型中草药发用洗护乳液及其制备方法
WO2015071298A2 (fr) * 2013-11-13 2015-05-21 L'oreal Composition moussante comprenant au moins un surfactant de type glycinate
CN106236690A (zh) * 2016-08-31 2016-12-21 福建省梦娇兰日用化学品有限公司 一种含多种植物成分的氨基酸洁面膏
CN106580726A (zh) * 2016-11-11 2017-04-26 珠海伊斯佳科技股份有限公司 一种含氨基酸的无硅油洗发水及其制备方法
CN106726919A (zh) * 2016-12-16 2017-05-31 广东宝贝儿婴童用品股份有限公司 一种不含二噁烷的婴幼儿氨基酸草本组合物及其制备
CN106667797A (zh) * 2016-12-30 2017-05-17 广州市科能化妆品科研有限公司 具有自防腐功能的温和洗发水组合物

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11376207B2 (en) 2017-10-31 2022-07-05 L'oreal Hair care compositions
US11123276B2 (en) 2018-02-28 2021-09-21 L'oreal Cosmetic compositions
WO2020176376A1 (fr) * 2019-02-28 2020-09-03 L'oreal Compositions cosmétiques à base de plantes
US12311045B2 (en) 2020-06-30 2025-05-27 L'oreal Natural non-sulfate rinse-off cleansing compositions with high oil loading, and methods of use
WO2022128441A1 (fr) * 2020-12-18 2022-06-23 Unilever Ip Holdings B.V. Composition de nettoyage
WO2023275299A1 (fr) * 2021-07-02 2023-01-05 Unilever Ip Holdings B.V. Ester comprenant une composition de tensioactif concentrée hydratable

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