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WO2019070568A3 - Lithium ion- or sodium ion-based internal hybrid electrochemical energy storage cell - Google Patents

Lithium ion- or sodium ion-based internal hybrid electrochemical energy storage cell Download PDF

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Publication number
WO2019070568A3
WO2019070568A3 PCT/US2018/053728 US2018053728W WO2019070568A3 WO 2019070568 A3 WO2019070568 A3 WO 2019070568A3 US 2018053728 W US2018053728 W US 2018053728W WO 2019070568 A3 WO2019070568 A3 WO 2019070568A3
Authority
WO
WIPO (PCT)
Prior art keywords
sodium
energy storage
storage cell
hybrid electrochemical
electrochemical energy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2018/053728
Other languages
French (fr)
Other versions
WO2019070568A2 (en
Inventor
Aruna Zhamu
Bor Z. Jang
Songhai Chai
Yen-Po Lin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanotek Instruments Inc
Original Assignee
Nanotek Instruments Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/722,497 external-priority patent/US20190103231A1/en
Priority claimed from US15/724,892 external-priority patent/US10707025B2/en
Priority claimed from US15/727,900 external-priority patent/US10566668B2/en
Priority claimed from US15/728,488 external-priority patent/US10727002B2/en
Application filed by Nanotek Instruments Inc filed Critical Nanotek Instruments Inc
Publication of WO2019070568A2 publication Critical patent/WO2019070568A2/en
Publication of WO2019070568A3 publication Critical patent/WO2019070568A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/04—Hybrid capacitors
    • H01G11/06—Hybrid capacitors with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/32—Carbon-based
    • H01G11/38—Carbon pastes or blends; Binders or additives therein
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/30—Electrodes characterised by their material
    • H01G11/50—Electrodes characterised by their material specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Materials Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Provided is an internal hybrid electrochemical cell comprising a pseudocapacitance-like cathode. The cathode active material contains a conductive carbon material or carbon nanosheets and a porphyrin compound, wherein the porphyrin compound is bonded to or supported by the carbon material to form a redox pair for pseudocapacitance; and also contains a battery-like anode active material selected from lithium metal, lithium metal alloy, a prelithiated anode active material, sodium metal, a sodium metal alloy, a sodium intercalation compound, a sodium-containing compound, and combinations thereof; and a lithium-containing or sodium-containing electrolyte in physical contact with the anode and the cathode.
PCT/US2018/053728 2017-10-02 2018-10-01 Lithium ion- or sodium ion-based internal hybrid electrochemical energy storage cell Ceased WO2019070568A2 (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US15/722,497 2017-10-02
US15/722,497 US20190103231A1 (en) 2017-10-02 2017-10-02 Internal hybrid electrochemical energy storage cell
US15/724,892 US10707025B2 (en) 2017-10-04 2017-10-04 Internal hybrid electrochemical energy storage cell having both high power and high energy density
US15/724,892 2017-10-04
US15/727,900 US10566668B2 (en) 2017-10-09 2017-10-09 Sodium ion-based internal hybrid electrochemical energy storage cell
US15/728,488 2017-10-09
US15/728,488 US10727002B2 (en) 2017-10-09 2017-10-09 Lithium ion-based internal hybrid electrochemical energy storage cell
US15/727,900 2017-10-09

Publications (2)

Publication Number Publication Date
WO2019070568A2 WO2019070568A2 (en) 2019-04-11
WO2019070568A3 true WO2019070568A3 (en) 2019-06-13

Family

ID=65994806

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2018/053728 Ceased WO2019070568A2 (en) 2017-10-02 2018-10-01 Lithium ion- or sodium ion-based internal hybrid electrochemical energy storage cell

Country Status (1)

Country Link
WO (1) WO2019070568A2 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109994732A (en) * 2019-04-15 2019-07-09 上海电气国轩新能源科技有限公司 The application of phenols lithium salt compound, lithium ion secondary battery and preparation method thereof
US11515564B2 (en) 2019-09-04 2022-11-29 The Regents Of The University Of Michigan Surface treatment of a solid electrolyte to lower the interfacial resistance between the solid electrolyte and an electrode
CN110817876B (en) * 2019-11-05 2022-09-27 武汉工程大学 A kind of preparation method and application of eggshell membrane-derived carbon/MXene/manganese dioxide composite material
CN112186150B (en) * 2020-09-16 2022-03-04 合肥国轩高科动力能源有限公司 A carbon-coated silicon/metal/carbon nanotube negative electrode composite material and preparation method
CN112390249A (en) * 2020-11-23 2021-02-23 陕西理工大学 Boron-doped graphene aerogel and preparation method and application thereof
CN112952055A (en) * 2021-01-15 2021-06-11 贵州民族大学 Two-dimensional structure selenium telluride modified carbon fiber electrode material and preparation method thereof
CN113105671A (en) * 2021-04-13 2021-07-13 浙江大学 Preparation method of graphene aerogel continuous curved surface network
CN113447550B (en) * 2021-06-22 2024-03-19 浙江理工大学 Preparation method of an electrochemical sensor modified electrode for detecting glucose, a degradation product of cotton and linen cultural relics
US20250002725A1 (en) * 2021-10-25 2025-01-02 Carnegie Mellon University Simple, scalable method for dispersing mxenes in nonpolar organic solvents
CN114388802B (en) * 2021-12-24 2023-03-10 合肥国轩高科动力能源有限公司 Lithium iron phosphate coated with single-atom-loaded nitrogen-phosphorus co-doped carbon composite material and its preparation method and application
CN114899432B (en) * 2022-05-11 2023-08-22 黑龙江哈船碳材料科技有限公司 Composite electrode material for direct sodium borohydride fuel cell and preparation method thereof
CN115162053B (en) * 2022-07-26 2023-08-29 陕西煤业化工技术研究院有限责任公司 A kind of high conductivity carbon fiber paper and preparation method thereof
CN117638015B (en) * 2022-08-17 2025-10-03 北京航空航天大学 Two-dimensional material-coated silicon composite material and preparation method thereof, negative electrode, lithium-ion battery and electric vehicle
CN116021007A (en) * 2022-12-25 2023-04-28 复旦大学 Sodium ion battery negative electrode pre-sodium agent and preparation method and application thereof
CN119081449B (en) * 2024-08-13 2025-11-18 同济大学 A tunable porphyrin-cadmium complex micene nanomaterial for nonlinear optical applications, its preparation and application
CN119029187B (en) * 2024-10-16 2025-01-28 四川柏盛聚能新能源科技有限公司 Silicon-carbon composite negative electrode material with elastic buffer structure and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130171502A1 (en) * 2011-12-29 2013-07-04 Guorong Chen Hybrid electrode and surface-mediated cell-based super-hybrid energy storage device containing same
US9437372B1 (en) * 2016-01-11 2016-09-06 Nanotek Instruments, Inc. Process for producing graphene foam supercapacitor electrode
US9564656B1 (en) * 2015-09-14 2017-02-07 Nanotek Instruments, Inc. Process for producing alkali metal or alkali-ion batteries having high volumetric and gravimetric energy densities
US9640334B2 (en) * 2010-01-25 2017-05-02 Nanotek Instruments, Inc. Flexible asymmetric electrochemical cells using nano graphene platelet as an electrode material
WO2017095512A1 (en) * 2015-12-03 2017-06-08 Angstron Materials, Inc. Chemical-free production of graphene materials
US9905373B2 (en) * 2016-01-04 2018-02-27 Nanotek Instruments, Inc. Supercapacitor having an integral 3D graphene-carbon hybrid foam-based electrode

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9640334B2 (en) * 2010-01-25 2017-05-02 Nanotek Instruments, Inc. Flexible asymmetric electrochemical cells using nano graphene platelet as an electrode material
US20130171502A1 (en) * 2011-12-29 2013-07-04 Guorong Chen Hybrid electrode and surface-mediated cell-based super-hybrid energy storage device containing same
US9564656B1 (en) * 2015-09-14 2017-02-07 Nanotek Instruments, Inc. Process for producing alkali metal or alkali-ion batteries having high volumetric and gravimetric energy densities
WO2017095512A1 (en) * 2015-12-03 2017-06-08 Angstron Materials, Inc. Chemical-free production of graphene materials
US9905373B2 (en) * 2016-01-04 2018-02-27 Nanotek Instruments, Inc. Supercapacitor having an integral 3D graphene-carbon hybrid foam-based electrode
US9437372B1 (en) * 2016-01-11 2016-09-06 Nanotek Instruments, Inc. Process for producing graphene foam supercapacitor electrode

Non-Patent Citations (3)

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Title
JAHAN ET AL.: "Electrocatalytically Active Graphene-Porphyrin MOF Composite for Oxygen Reduction Reaction", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 134, 22 March 2012 (2012-03-22), pages 6707 - 6713, XP55615169 *
YAMUNA ET AL.: "Synthesis, characterization, and nonlinear optical properties of graphene oxide functionalized with tetra-amino porphyrin", JOURNAL OF NANOPARTICLE RESEARCH, vol. 15, 10 January 2013 (2013-01-10), pages 1 - 9, XP55615171 *
ZUO ET AL., BATTERY-SUPERCAPACITOR HYBRID DEVICES: RECENT PROGRESS - AND FUTURE PROSPECTS, XP55615174 *

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