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WO2018191906A1 - Waste gas recovery, treatment and conversion system apparatus - Google Patents

Waste gas recovery, treatment and conversion system apparatus Download PDF

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Publication number
WO2018191906A1
WO2018191906A1 PCT/CN2017/081213 CN2017081213W WO2018191906A1 WO 2018191906 A1 WO2018191906 A1 WO 2018191906A1 CN 2017081213 W CN2017081213 W CN 2017081213W WO 2018191906 A1 WO2018191906 A1 WO 2018191906A1
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WIPO (PCT)
Prior art keywords
reactor
condenser
cooler
incinerator
exhaust gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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PCT/CN2017/081213
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French (fr)
Chinese (zh)
Inventor
聂庭森
聂庭江
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JIANGSU SHENJIANG ENVIRONMENT TECHNOLOGY Co Ltd
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JIANGSU SHENJIANG ENVIRONMENT TECHNOLOGY Co Ltd
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Priority to PCT/CN2017/081213 priority Critical patent/WO2018191906A1/en
Publication of WO2018191906A1 publication Critical patent/WO2018191906A1/en
Anticipated expiration legal-status Critical
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/69Sulfur trioxide; Sulfuric acid
    • C01B17/74Preparation
    • C01B17/76Preparation by contact processes
    • C01B17/80Apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases

Definitions

  • the utility model relates to a recycling processing device, in particular to an exhaust gas recovery and treatment conversion system device.
  • Viscose fiber will produce a large amount of H2S and CS2 gas in the production process; CS2 gas can be physically adsorbed; for the H2S gas, most plants currently use the alkali washing removal method; the removal efficiency is over 99%, but the alkali washing produces Sodium hydrosulfide is made into concentrates or wafers, and the market demand for this part is near saturation.
  • the object of the present invention is to provide an exhaust gas recovery and treatment conversion system device to solve the above-mentioned background art, the viscose fiber produced in the production process will generate a large amount of H2S and CS2 gas; wherein CS2 gas can be physically adsorbed; for H2S gas
  • CS2 gas can be physically adsorbed
  • H2S gas At present, most factories use the alkali washing removal method; the removal efficiency is over 99%, but the sodium hydrosulfide produced by the alkali washing is made into a concentrate or a wafer, and the market demand for this part is close to saturation.
  • an exhaust gas recovery and treatment conversion system device including an exhaust gas tank, an incinerator, an R-500 reactor, a C-300 condenser fan, a cooler, an R-200 reactor, sulfuric acid Reserve tank, cooler base, C-300 condenser, pipe, furnace door, cooling chamber, exhaust port, condensing pipe, drain port, combustion chamber, blast port, flamethrower, fan and drain tank, said waste gas tank
  • An incinerator is disposed on one side, one side of the incinerator is provided with an R-200 reactor, one end of the R-200 reactor is installed with a pipe, and one side of the R-200 reactor is provided with C-300 condensation
  • One side of the C-300 condenser is provided with a cooler, and the bottom end of the C-300 condenser is equipped with a C-300 condenser fan, and one side of the cooler is provided with an R-500 reactor.
  • the other side of the cooler is provided with a sulfuric acid storage tank
  • the bottom end of the cooler is provided with a cooler base
  • the front surface of the incinerator is provided with a furnace door
  • the top end of the incinerator is provided with an exhaust port.
  • a cooling chamber is installed below the exhaust port, and the front surface of the cooling chamber is disposed a condensing pipe, and a drain tank is disposed below the cooling chamber, a drain port is disposed on one side of the condensing pipe, and a combustion chamber is disposed at a lower end of the condensing pipe, a fan is installed at one end of the combustion chamber, and a lower end of the combustion chamber is installed A flamethrower is installed, and a fire exit is installed at the top of the flamethrower.
  • waste gas tank, the incinerator, the R-200 reactor, the C-300 condenser, the cooler, the R-500 reactor and the sulfuric acid storage tank are all connected in series by a pipe, and between the cooler and the sulfuric acid storage tank Also connected by pipes.
  • the inside of the exhaust gas tank stores sulfur-containing exhaust gas such as hydrogen sulfide, and both ends of the fan are fixedly installed at one end of the exhaust gas tank and one end of the incinerator.
  • cooling chamber and the drain tank are in communication through a conduit.
  • the R-200 reactor, the C-300 condenser fan, the cooler, the R-500 reactor, the C-300 condenser, the flamethrower and the fan are all electrically connected to an external power source.
  • the inside of the R-200 reactor contains a catalyst such as platinum.
  • the utility model achieves the beneficial effects that the utility model has the advantages of scientific and reasonable structure, safe and convenient use, and the exhaust gas containing H2S is firstly treated by high temperature treatment and oxygen oxidation into SO2 gas and water, which can be conveniently used.
  • the water is discharged and non-polluted, and the SO2 gas is further oxidized into a SO3 gas with a catalyst such as platinum.
  • the reaction is simple and efficient, and the problem of producing a plurality of sulfur-containing substances is avoided.
  • the SO3 gas and the water vapor are condensed into sulfuric acid during the cooling process, and are condensed into The benefits of high-temperature concentrated H2SO4, after cooling to the normal temperature of the finished product, solve the complicated operation problem.
  • part of the condensed tail gas can be further catalyzed into H2SO4, which avoids the problem of residual exhaust gas pollution to the external environment.
  • FIG. 1 is a schematic structural view of an apparatus for exhaust gas recovery and treatment conversion system of the present invention
  • Figure 2 is a schematic view showing the structure of the incinerator of the present invention.
  • an exhaust gas recovery and treatment conversion system device including an exhaust gas tank 1, an incinerator 2, an R-200 reactor 3, a C-300 condenser fan 4, and a cooler 5 , R-500 reactor 6, sulfuric acid storage tank 7, cooler base 8, C-300 condenser 9, pipeline 10, furnace door 11, cooling chamber 12, exhaust port 13, condensing pipe 14, drain port 15, combustion Room 16, blast port 17, flamethrower 18, fan 19 and drain tank 20, one side of waste gas tank 1
  • An incinerator 2 is provided, one side of the incinerator 2 is provided with an R-200 reactor 3, one end of the R-200 reactor 3 is provided with a pipe 10, and one side of the R-200 reactor 3 is provided with C-300 condensation a condenser 5 is disposed on one side of the C-300 condenser 9, and a C-300 condenser fan 4 is installed at the bottom end of the C-300 condenser 9, and an R-500 reaction is disposed on one side of the cooler 5
  • the exhaust gas tank 1, the incinerator 2, the R-200 reactor 3, the C-300 condenser 9, the cooler 5, the R-500 reactor 6 and the sulfuric acid The reserve tanks 7 are each connected in series by a pipe 10, and the cooler 5 and the sulfuric acid storage tank 7 are also connected by a pipe 10.
  • the inside of the exhaust gas tank 1 stores sulfur-containing exhaust gas such as hydrogen sulfide, and both ends of the fan 19 are fixedly installed at one end of the exhaust gas tank 1 and incinerated.
  • the cooling chamber 12 and the drain tank 20 are in communication through the conduit.
  • R-200 reactor 3, C-300 condenser fan 4, cooler 5, R-500 reactor 6, C-300 condenser 9, flamethrower 18 and fan 19 are electrically connected to external power sources.
  • the inside of the R-200 reactor 3 contains a catalyst such as platinum.
  • the exhaust gas recovery and treatment conversion system device converts the exhaust gas containing H2S into the incinerator 2 and is oxidized into SO2 gas.
  • the combustion chamber 16 in the incinerator 2 reacts the H2S heating with the oxygen to form the SO2 gas and the water vapor.
  • the water vapor is condensed into water droplets, and the water droplets flow from the cooling chamber 12 to the drain tank 20, and are discharged from the drain port 15, and the SO2 gas enters the exhaust port. 13.
  • the SO2 gas enters the R-200 reactor 3 and the catalyst such as platinum is further oxidized into SO3 gas, and the SO3 gas enters the C-300 condenser 9, and the SO3 gas is combined with the water vapor in the cooling process.
  • the high-temperature concentrated H2SO4 from the C-300 condenser 9 is cooled to the normal temperature acid by the cooling device, and some of the tail gas that has not been condensed enters the R-500 reactor and further catalyzed into H2SO4; the concentrated sulfuric acid can be directly used for the viscose Production is conducive to reducing the production cost of enterprises, increasing the market competitiveness of enterprises, and the processing effect and market prospects of by-products are very good.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)

Abstract

A waste gas recovery, treatment and conversion system apparatus, comprising: a waste gas canister (1), an incinerator (2), an R-200 reactor (3), a cooler (5), an R-500 reactor (6), a sulfuric acid storage canister (7), a C-300 condenser (9), a combustion chamber (16), and a water drainage tank (20). The incinerator (2) is provided at one side of the waste gas canister (1). The R-200 reactor (3) is provided at one side of the incinerator (2). A duct (10) is provided at one end of the R-200 reactor (3). The C-300 condenser (9) is provided at one side of the R-200 reactor (3). The cooler (5) is provided at one side of the C-300 condenser (9). A C-300 condenser fan (4) is provided at a bottom portion of the C-300 condenser (9). The R-500 reactor (6) is provided at one side of the cooler (5). Waste gas containing H2S is first treated under a high temperature and is oxidized with oxygen to form SO2 gas and water. The SO2 gas is then further oxidized in the presence of a catalyst, such as platinum, to form SO3 gas. The reaction is easy and highly efficient, preventing the issue of producing various sulfur-containing by-products. The SO3 gas binds to water vapor and is condensed into sulfuric acid during a cooling process. In addition, a part of tail gas that is condensed can be further catalyzed into H2SO4, preventing the issue of environmental pollution caused by the residual tail gas.

Description

废气回收治理转化系统装置Exhaust gas recovery and treatment conversion system device 技术领域Technical field

本实用新型涉及回收处理装置,具体为废气回收治理转化系统装置。The utility model relates to a recycling processing device, in particular to an exhaust gas recovery and treatment conversion system device.

背景技术Background technique

粘胶纤维在生产过程中会产生大量的H2S和CS2气体;其中CS2气体可以进行物理吸附处理;对于H2S气体目前大多数工厂采用的碱洗去除法;去除效率达99%以上,但碱洗产生的硫氢化钠都是制成浓缩液或晶片,这部分的市场需求已接近饱和。Viscose fiber will produce a large amount of H2S and CS2 gas in the production process; CS2 gas can be physically adsorbed; for the H2S gas, most plants currently use the alkali washing removal method; the removal efficiency is over 99%, but the alkali washing produces Sodium hydrosulfide is made into concentrates or wafers, and the market demand for this part is near saturation.

实用新型内容Utility model content

本实用新型的目的在于提供废气回收治理转化系统装置,以解决上述背景技术中提出的粘胶纤维在生产过程中会产生大量的H2S和CS2气体;其中CS2气体可以进行物理吸附处理;对于H2S气体目前大多数工厂采用的碱洗去除法;去除效率达99%以上,但碱洗产生的硫氢化钠都是制成浓缩液或晶片,这部分的市场需求已接近饱和的问题。The object of the present invention is to provide an exhaust gas recovery and treatment conversion system device to solve the above-mentioned background art, the viscose fiber produced in the production process will generate a large amount of H2S and CS2 gas; wherein CS2 gas can be physically adsorbed; for H2S gas At present, most factories use the alkali washing removal method; the removal efficiency is over 99%, but the sodium hydrosulfide produced by the alkali washing is made into a concentrate or a wafer, and the market demand for this part is close to saturation.

为实现上述目的,本实用新型提供如下技术方案:废气回收治理转化系统装置,包括废气罐、焚烧炉、R-500反应器、C-300冷凝器风机、冷却器、R-200反应釜、硫酸储备罐、冷却器底座、C-300冷凝器、管道、炉门、冷却室、排气口、冷凝管、排水口、燃烧室、喷火口、喷火器、风机和排水箱,所述废气罐的一侧设置有焚烧炉,所述焚烧炉的一侧设置有R-200反应器,所述R-200反应器的一端安装有管道,且R-200反应器的一侧设置有C-300冷凝器,所述C-300冷凝器的一侧设置有冷却器,且C-300冷凝器的底端安装有C-300冷凝器风机,所述冷却器的一侧设置有R-500反应釜,且冷却器的另一侧设置有硫酸储备罐,所述冷却器的底端设置有冷却器底座,所述焚烧炉的前表面设置有炉门,且焚烧炉的顶端设置有排气口,所述排气口的下方安装有冷却室,所述冷却室的前表面设置有冷凝管,且冷却室的下方设置有排水箱,所述冷凝管的一侧设置有排水口,且冷凝管的下端设置有燃烧室,所述燃烧室的一端安装有风机,且燃烧室的下端安装有喷火器,所述喷火器的顶端安装有喷火口。In order to achieve the above object, the utility model provides the following technical solutions: an exhaust gas recovery and treatment conversion system device, including an exhaust gas tank, an incinerator, an R-500 reactor, a C-300 condenser fan, a cooler, an R-200 reactor, sulfuric acid Reserve tank, cooler base, C-300 condenser, pipe, furnace door, cooling chamber, exhaust port, condensing pipe, drain port, combustion chamber, blast port, flamethrower, fan and drain tank, said waste gas tank An incinerator is disposed on one side, one side of the incinerator is provided with an R-200 reactor, one end of the R-200 reactor is installed with a pipe, and one side of the R-200 reactor is provided with C-300 condensation One side of the C-300 condenser is provided with a cooler, and the bottom end of the C-300 condenser is equipped with a C-300 condenser fan, and one side of the cooler is provided with an R-500 reactor. And the other side of the cooler is provided with a sulfuric acid storage tank, the bottom end of the cooler is provided with a cooler base, the front surface of the incinerator is provided with a furnace door, and the top end of the incinerator is provided with an exhaust port. a cooling chamber is installed below the exhaust port, and the front surface of the cooling chamber is disposed a condensing pipe, and a drain tank is disposed below the cooling chamber, a drain port is disposed on one side of the condensing pipe, and a combustion chamber is disposed at a lower end of the condensing pipe, a fan is installed at one end of the combustion chamber, and a lower end of the combustion chamber is installed A flamethrower is installed, and a fire exit is installed at the top of the flamethrower.

进一步的,所述废气罐、焚烧炉、R-200反应器、C-300冷凝器、冷却器、R-500反应釜和硫酸储备罐均由管道依次连接,且冷却器和硫酸储备罐之间也通过管道相连接。Further, the waste gas tank, the incinerator, the R-200 reactor, the C-300 condenser, the cooler, the R-500 reactor and the sulfuric acid storage tank are all connected in series by a pipe, and between the cooler and the sulfuric acid storage tank Also connected by pipes.

进一步的,所述废气罐的内部储存有硫化氢等含硫的废气,且风机的两端分别固定安装在废气罐一端和焚烧炉的一端。 Further, the inside of the exhaust gas tank stores sulfur-containing exhaust gas such as hydrogen sulfide, and both ends of the fan are fixedly installed at one end of the exhaust gas tank and one end of the incinerator.

进一步的,所述所述冷却室与排水箱通过导管相连通。Further, the cooling chamber and the drain tank are in communication through a conduit.

进一步的,所述R-200反应器、C-300冷凝器风机、冷却器、R-500反应釜、C-300冷凝器、喷火器和风机均与外界电源电性连接。Further, the R-200 reactor, the C-300 condenser fan, the cooler, the R-500 reactor, the C-300 condenser, the flamethrower and the fan are all electrically connected to an external power source.

进一步的,所述R-200反应器的内部含有铂金等催化剂。Further, the inside of the R-200 reactor contains a catalyst such as platinum.

与现有技术相比,本实用新型所达到的有益效果是:本实用新型结构科学合理,使用安全方便,含H2S的废气先通过高温处理与氧气氧化成SO2气体和水,可以很方便的将水排出且无污染,SO2气体再与铂金等催化剂进一步氧化成SO3气体,反应简易且高效,避免产生多种含硫物质的问题,SO3气体与水汽结合在降温过程中凝结成硫酸,有凝结成高温浓H2SO4的好处,再经过冷却至常温成品酸,解决了操作复杂的问题,此外被冷凝下来的部分尾气进可进一步催化成H2SO4,避免了残留尾气对外界环境污染的问题。Compared with the prior art, the utility model achieves the beneficial effects that the utility model has the advantages of scientific and reasonable structure, safe and convenient use, and the exhaust gas containing H2S is firstly treated by high temperature treatment and oxygen oxidation into SO2 gas and water, which can be conveniently used. The water is discharged and non-polluted, and the SO2 gas is further oxidized into a SO3 gas with a catalyst such as platinum. The reaction is simple and efficient, and the problem of producing a plurality of sulfur-containing substances is avoided. The SO3 gas and the water vapor are condensed into sulfuric acid during the cooling process, and are condensed into The benefits of high-temperature concentrated H2SO4, after cooling to the normal temperature of the finished product, solve the complicated operation problem. In addition, part of the condensed tail gas can be further catalyzed into H2SO4, which avoids the problem of residual exhaust gas pollution to the external environment.

附图说明DRAWINGS

附图用来提供对本实用新型的进一步理解,并且构成说明书的一部分,与本实用新型的实施例一起用于解释本实用新型,并不构成对本实用新型的限制。在附图中:The drawings are intended to provide a further understanding of the invention, and are intended to be a part of the description of the invention. In the drawing:

图1是本实用新型的废气回收治理转化系统装置结构示意图;1 is a schematic structural view of an apparatus for exhaust gas recovery and treatment conversion system of the present invention;

图2是本实用新型的焚烧炉结构示意图;Figure 2 is a schematic view showing the structure of the incinerator of the present invention;

图中:1-废气罐、2-焚烧炉、3-R-200反应器、4-C-300冷凝器风机、5-冷却器、6-R-500反应釜、7-硫酸储备罐、8-冷却器底座、9-C-300冷凝器、10-管道、11-炉门、12-冷却室、13-排气口、14-冷凝管、15-排水口、16-燃烧室、17-喷火口、18-喷火器、19-风机、20-排水箱。In the figure: 1 - exhaust gas tank, 2-incinerator, 3-R-200 reactor, 4-C-300 condenser fan, 5-cooler, 6-R-500 reactor, 7-sulfuric acid storage tank, 8 - cooler base, 9-C-300 condenser, 10-pipe, 11-furnace door, 12-cooling chamber, 13-exhaust port, 14-condensation tube, 15-drain port, 16-combustion chamber, 17- Fire vent, 18-spray, 19-fan, 20-drain.

具体实施方式detailed description

以下结合附图对本实用新型的优选实施例进行说明,应当理解,此处所描述的优选实施例仅用于说明和解释本实用新型,并不用于限定本实用新型。The preferred embodiments of the present invention are described with reference to the accompanying drawings, and the preferred embodiments described herein are intended to illustrate and explain the invention.

实施例1Example 1

请参阅图1-2,本实用新型提供一种技术方案:废气回收治理转化系统装置,包括废气罐1、焚烧炉2、R-200反应器3、C-300冷凝器风机4、冷却器5、R-500反应釜6、硫酸储备罐7、冷却器底座8、C-300冷凝器9、管道10、炉门11、冷却室12、排气口13、冷凝管14、排水口15、燃烧室16、喷火口17、喷火器18、风机19和排水箱20,废气罐1的一侧 设置有焚烧炉2,焚烧炉2的一侧设置有R-200反应器3,R-200反应器3的一端安装有管道10,且R-200反应器3的一侧设置有C-300冷凝器9,C-300冷凝器9的一侧设置有冷却器5,且C-300冷凝器9的底端安装有C-300冷凝器风机4,冷却器5的一侧设置有R-500反应釜6,且冷却器5的另一侧设置有硫酸储备罐7,冷却器5的底端设置有冷却器底座8,焚烧炉2的前表面设置有炉门11,且焚烧炉2的顶端设置有排气口13,排气口13的下方安装有冷却室12,冷却室12的前表面设置有冷凝管14,且冷却室12的下方设置有排水箱20,冷凝管14的一侧设置有排水口15,且冷凝管14的下端设置有燃烧室16,燃烧室16的一端安装有风机19,且燃烧室16的下端安装有喷火器18,喷火器18的顶端安装有喷火口17。Referring to FIG. 1-2, the utility model provides a technical solution: an exhaust gas recovery and treatment conversion system device, including an exhaust gas tank 1, an incinerator 2, an R-200 reactor 3, a C-300 condenser fan 4, and a cooler 5 , R-500 reactor 6, sulfuric acid storage tank 7, cooler base 8, C-300 condenser 9, pipeline 10, furnace door 11, cooling chamber 12, exhaust port 13, condensing pipe 14, drain port 15, combustion Room 16, blast port 17, flamethrower 18, fan 19 and drain tank 20, one side of waste gas tank 1 An incinerator 2 is provided, one side of the incinerator 2 is provided with an R-200 reactor 3, one end of the R-200 reactor 3 is provided with a pipe 10, and one side of the R-200 reactor 3 is provided with C-300 condensation a condenser 5 is disposed on one side of the C-300 condenser 9, and a C-300 condenser fan 4 is installed at the bottom end of the C-300 condenser 9, and an R-500 reaction is disposed on one side of the cooler 5 The kettle 6 is provided, and the other side of the cooler 5 is provided with a sulfuric acid storage tank 7, and the bottom end of the cooler 5 is provided with a cooler base 8, and the front surface of the incinerator 2 is provided with a furnace door 11, and the top end of the incinerator 2 is disposed There is an exhaust port 13, a cooling chamber 12 is disposed below the exhaust port 13, a front surface of the cooling chamber 12 is provided with a condenser tube 14, and a drain tank 20 is disposed below the cooling chamber 12, and one side of the condenser tube 14 is disposed The drain port 15 is provided with a combustion chamber 16 at the lower end of the condensing duct 14, a fan 19 is attached to one end of the combustion chamber 16, and a flame blaster 18 is attached to the lower end of the combustion chamber 16, and a lance 17 is attached to the tip end of the flame blaster 18.

为了废气可以依次进行有效处理,本实施例中,进一步的,废气罐1、焚烧炉2、R-200反应器3、C-300冷凝器9、冷却器5、R-500反应釜6和硫酸储备罐7均由管道10依次连接,且冷却器5和硫酸储备罐7之间也通过管道10相连接。In order to effectively treat the exhaust gas in this order, in the present embodiment, further, the exhaust gas tank 1, the incinerator 2, the R-200 reactor 3, the C-300 condenser 9, the cooler 5, the R-500 reactor 6 and the sulfuric acid The reserve tanks 7 are each connected in series by a pipe 10, and the cooler 5 and the sulfuric acid storage tank 7 are also connected by a pipe 10.

为了将硫化氢输送到焚烧炉中2,本实施例中,进一步的,废气罐1的内部储存有硫化氢等含硫的废气,且风机19的两端分别固定安装在废气罐1一端和焚烧炉2的一端。In the present embodiment, in the embodiment, further, the inside of the exhaust gas tank 1 stores sulfur-containing exhaust gas such as hydrogen sulfide, and both ends of the fan 19 are fixedly installed at one end of the exhaust gas tank 1 and incinerated. One end of the furnace 2.

为了快速有效的排出反应产物,本实施例中,进一步的,冷却室12与排水箱20通过导管相连通。In order to quickly and efficiently discharge the reaction product, in the present embodiment, further, the cooling chamber 12 and the drain tank 20 are in communication through the conduit.

为了正常工作,本实施例中,进一步的,R-200反应器3、C-300冷凝器风机4、冷却器5、R-500反应釜6、C-300冷凝器9、喷火器18和风机19均与外界电源电性连接。For normal operation, in this embodiment, further, R-200 reactor 3, C-300 condenser fan 4, cooler 5, R-500 reactor 6, C-300 condenser 9, flamethrower 18 and fan 19 are electrically connected to external power sources.

为了将SO2气体转化为SO3气体,本实施例中,进一步的,R-200反应器3的内部含有铂金等催化剂。In order to convert the SO 2 gas into the SO 3 gas, in the present embodiment, further, the inside of the R-200 reactor 3 contains a catalyst such as platinum.

工作原理:该种废气回收治理转化系统装置将含H2S的废气,先进入焚烧炉2被氧化成SO2气体,焚烧炉2内的燃烧室16将H2S加热与氧气反应成SO2气体和水蒸气,当SO2气体和水蒸气经过冷凝管14到冷凝室12冷却后,水蒸气冷凝成水滴,且水滴从冷却室12流到排水箱20中,再由排水口15排出,而SO2气体则进入排气口13,通往R-200反应器3中,SO2气体进入R-200反应器3与铂金等催化剂进一步氧化成SO3气体,SO3气体进入C-300冷凝器9,SO3气体与水汽结合在降温过程中凝结成硫酸,C-300冷凝器9出来的高温浓H2SO4经过冷却装置冷却至常温成品酸,没有被冷凝下来的部分尾气进入R-500反应釜进一步催化成H2SO4;浓硫酸可直接用于粘胶生产,有利于降低企业的生产成本,增加企业的市场竞争力,且处理效果、副产品市场前景都很好。 Working principle: The exhaust gas recovery and treatment conversion system device converts the exhaust gas containing H2S into the incinerator 2 and is oxidized into SO2 gas. The combustion chamber 16 in the incinerator 2 reacts the H2S heating with the oxygen to form the SO2 gas and the water vapor. After the SO2 gas and the water vapor are cooled by the condenser 14 to the condensation chamber 12, the water vapor is condensed into water droplets, and the water droplets flow from the cooling chamber 12 to the drain tank 20, and are discharged from the drain port 15, and the SO2 gas enters the exhaust port. 13. In the R-200 reactor 3, the SO2 gas enters the R-200 reactor 3 and the catalyst such as platinum is further oxidized into SO3 gas, and the SO3 gas enters the C-300 condenser 9, and the SO3 gas is combined with the water vapor in the cooling process. Condensed into sulfuric acid, the high-temperature concentrated H2SO4 from the C-300 condenser 9 is cooled to the normal temperature acid by the cooling device, and some of the tail gas that has not been condensed enters the R-500 reactor and further catalyzed into H2SO4; the concentrated sulfuric acid can be directly used for the viscose Production is conducive to reducing the production cost of enterprises, increasing the market competitiveness of enterprises, and the processing effect and market prospects of by-products are very good.

最后应说明的是:以上所述仅为本实用新型的优选实施例而已,并不用于限制本实用新型,尽管参照前述实施例对本实用新型进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换。凡在本实用新型的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本实用新型的保护范围之内。 Finally, it should be noted that the above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention, although the present invention has been described in detail with reference to the foregoing embodiments, for those skilled in the art It is still possible to modify the technical solutions described in the foregoing embodiments, or to replace some of the technical features. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and scope of the present invention are intended to be included within the scope of the present invention.

Claims (6)

废气回收治理转化系统装置,包括废气罐(1)、焚烧炉(2)、R-200反应器(3)、C-300冷凝器风机(4)、冷却器(5)、R-500反应釜(6)、硫酸储备罐(7)、冷却器底座(8)、C-300冷凝器(9)、管道(10)、炉门(11)、冷却室(12)、排气口(13)、冷凝管(14)、排水口(15)、燃烧室(16)、喷火口(17)、喷火器(18)、风机(19)和排水箱(20),其特征在于:所述废气罐(1)的一侧设置有焚烧炉(2),所述焚烧炉(2)的一侧设置有R-200反应器(3),所述R-200反应器(3)的一端安装有管道(10),且R-200反应器(3)的一侧设置有C-300冷凝器(9),所述C-300冷凝器(9)的一侧设置有冷却器(5),且C-300冷凝器(9)的底端安装有C-300冷凝器风机(4),所述冷却器(5)的一侧设置有R-500反应釜(6),且冷却器(5)的另一侧设置有硫酸储备罐(7),所述冷却器(5)的底端设置有冷却器底座(8),所述焚烧炉(2)的前表面设置有炉门(11),且焚烧炉(2)的顶端设置有排气口(13),所述排气口(13)的下方安装有冷却室(12),所述冷却室(12)的前表面设置有冷凝管(14),且冷却室(12)的下方设置有排水箱(20),所述冷凝管(14)的一侧设置有排水口(15),且冷凝管(14)的下端设置有燃烧室(16),所述燃烧室(16)的一端安装有风机(19),且燃烧室(16)的下端安装有喷火器(18),所述喷火器(18)的顶端安装有喷火口(17)。Exhaust gas recovery and treatment conversion system equipment, including waste gas tank (1), incinerator (2), R-200 reactor (3), C-300 condenser fan (4), cooler (5), R-500 reactor (6), sulfuric acid storage tank (7), cooler base (8), C-300 condenser (9), pipe (10), furnace door (11), cooling room (12), exhaust port (13) a condensing pipe (14), a drain port (15), a combustion chamber (16), a blast port (17), a flame igniter (18), a fan (19) and a drain tank (20), characterized in that: the waste gas tank One side of (1) is provided with an incinerator (2), one side of the incinerator (2) is provided with an R-200 reactor (3), and one end of the R-200 reactor (3) is installed with a pipe (10), and one side of the R-200 reactor (3) is provided with a C-300 condenser (9), and one side of the C-300 condenser (9) is provided with a cooler (5), and C The bottom end of the -300 condenser (9) is equipped with a C-300 condenser fan (4), one side of the cooler (5) is provided with an R-500 reactor (6), and the cooler (5) The other side is provided with a sulfuric acid storage tank (7), the bottom end of the cooler (5) is provided with a cooler base (8), and the front surface of the incinerator (2) is provided with a furnace door (11), and The top of the incinerator (2) is arranged with rows a gas port (13), below the exhaust port (13) is mounted with a cooling chamber (12), a front surface of the cooling chamber (12) is provided with a condensation tube (14), and a cooling chamber (12) is disposed below There is a drain tank (20), one side of the condensing pipe (14) is provided with a drain port (15), and a lower end of the condensing pipe (14) is provided with a combustion chamber (16), one end of the combustion chamber (16) A fan (19) is installed, and a flamethrower (18) is mounted at a lower end of the combustion chamber (16), and a fire exit port (17) is mounted at a top end of the flamethrower (18). 根据权利要求1所述的废气回收治理转化系统装置,其特征在于:所述废气罐(1)、焚烧炉(2)、R-200反应器(3)、C-300冷凝器(9)、冷却器(5)、R-500反应釜(6)和硫酸储备罐(7)均由管道(10)依次连接,且冷却器(5)和硫酸储备罐(7)之间也通过管道(10)相连接。The exhaust gas recovery treatment conversion system apparatus according to claim 1, characterized in that: the waste gas tank (1), the incinerator (2), the R-200 reactor (3), the C-300 condenser (9), The cooler (5), the R-500 reactor (6) and the sulfuric acid storage tank (7) are all connected in series by the pipe (10), and the cooler (5) and the sulfuric acid storage tank (7) are also passed through the pipe (10). ) connected. 根据权利要求1所述的废气回收治理转化系统装置,其特征在于:所述废气罐(1)的内部储存有硫化氢等含硫的废气,且风机(19)的两端分别固定安装在废气罐(1)一端和焚烧炉(2)的一端。The exhaust gas recovery and treatment conversion system device according to claim 1, wherein the exhaust gas tank (1) stores sulfur-containing exhaust gas such as hydrogen sulfide, and both ends of the fan (19) are fixedly installed in the exhaust gas. One end of the tank (1) and one end of the incinerator (2). 根据权利要求1所述的废气回收治理转化系统装置,其特征在于:所述冷却室(12)与排水箱(20)通过导管相连通。The exhaust gas recovery treatment conversion system apparatus according to claim 1, wherein said cooling chamber (12) communicates with a drain tank (20) through a conduit. 根据权利要求1所述的废气回收治理转化系统装置,其特征在于:所述R-200反应器(3)、C-300冷凝器风机(4)、冷却器(5)、R-500反应釜(6)、C-300冷凝器(9)、喷火器(18)和风机(19)均与外界电源电性连接。The exhaust gas recovery treatment conversion system device according to claim 1, characterized in that: the R-200 reactor (3), the C-300 condenser fan (4), the cooler (5), and the R-500 reactor (6) The C-300 condenser (9), the flamethrower (18) and the fan (19) are all electrically connected to the external power source. 根据权利要求1所述的废气回收治理转化系统装置,其特征在于:所述R-200反应器(3)的内部含有铂金等催化剂。 The exhaust gas recovery and treatment conversion system apparatus according to claim 1, wherein the inside of the R-200 reactor (3) contains a catalyst such as platinum.
PCT/CN2017/081213 2017-04-20 2017-04-20 Waste gas recovery, treatment and conversion system apparatus Ceased WO2018191906A1 (en)

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