WO2018182255A1 - Anti-pollution cosmetic composition comprising spherical powder - Google Patents
Anti-pollution cosmetic composition comprising spherical powder Download PDFInfo
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- WO2018182255A1 WO2018182255A1 PCT/KR2018/003523 KR2018003523W WO2018182255A1 WO 2018182255 A1 WO2018182255 A1 WO 2018182255A1 KR 2018003523 W KR2018003523 W KR 2018003523W WO 2018182255 A1 WO2018182255 A1 WO 2018182255A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/022—Powders; Compacted Powders
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/025—Explicitly spheroidal or spherical shape
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Definitions
- an anti-pollution cosmetic composition having an excellent dustproof effect against fine dust and the like.
- the skin acts as a barrier between the organism and the environment in the outermost part of our body, which is in direct contact with dust, which often degrades when directly exposed to contamination.
- the fine dust is 20 times smaller than the pores, so it can easily penetrate the skin.
- air pollutants such as fine dust have been known to seriously affect skin health.
- premature aging, lack of moisture, fine lines and wrinkles, and irreversible skin damage in the long run can lead to serious illnesses such as skin cancer, as the skin loses its ability to protect itself from environmental factors. .
- the object of the present invention is to prevent contaminants from adhering to the skin.
- an object of the present invention is to improve the bone repelling effect of the cosmetic composition by including a high content of spherical powder.
- an object of the present invention is to prevent or minimize contamination of the skin due to fine dust.
- the present invention in the anti-pollution cosmetic composition, provides an anti-pollution cosmetic composition comprising at least 20% by weight of the spherical powder based on the total weight of the total composition.
- the anti-pollution cosmetic composition of the present invention can minimize the penetration of dust, in particular fine dust into the skin.
- the spherical powder contained in a high content to improve the applicability of the formulation to help apply evenly on the surface of the skin, the effect of filling the bone of the skin surface is also excellent, the surface coated with particles in the spherical powder
- the surface coated with particles in the spherical powder By forming three-dimensional fine protrusions on the surface, it is possible to minimize the adhesion of dust to the skin surface.
- the plate-shaped powder it is possible to prevent the dust from sticking to the skin during application and preventing the dust from penetrating into the skin.
- by preventing the penetration of fine dust it is possible to minimize the skin inflammation, heavy metal accumulation due to this, it is beneficial to skin health.
- FIG. 1A is a SEM photograph of artificial leather coated with the anti-pollution cosmetic composition of Example 1 of the present invention
- FIG. 1B is a SEM photograph of artificial leather coated with the cosmetic composition of Comparative Example 1. Taken under a microscope).
- Figure 2a is a photograph of the artificial leather surface coated with the anti-pollution cosmetic composition of Example 1 of the present invention with a digital camera
- Figure 2b is a photograph of the artificial leather surface coated with the cosmetic composition of Comparative Example 1 with a digital camera It is.
- 3A is a 3D scan photograph of a synthetic leather coated with the anti-pollution cosmetic composition of Example 1 of the present invention, and magnified by 50 times, and shows the difference in height in color
- FIG. 3B illustrates the cosmetic composition of Comparative Example 1
- the coated artificial leather is magnified 50 times by 3D scan, and the difference in height is expressed in color.
- Figure 4a is taken after 10 minutes convection of the artificial leather coated with oil and the anti-pollution cosmetic composition of Example 1 of the present invention in a fine dust convection box
- Figure 4b is a fine dust convection of artificial leather coated with oil only After the convection in the box for 10 minutes, it is taken
- Figs. 4c and 4d is taken after 10 minutes convection in artificial dust coated with the cosmetic composition of Comparative Examples 1 and 2 in a fine dust convection box.
- the term “anti-pollution” refers to preventing or minimizing the adhesion of contaminants, such as dust, to the skin, or the removal of contaminants adhering to the skin from the skin to penetrate the skin. I mean. That is, when the anti-pollution cosmetic composition of the present disclosure is applied to the skin, it is possible to minimize the adhesion of contaminants to the skin due to the excellent bone repelling effect, and compared to the plate-like powder, the dust is less at the time of application It can prevent dust from penetrating the skin.
- dust refers to particulates mixed in the air, and refers to suspended solids having a particle diameter of usually 10 mm or less. Particularly, when the particle diameter is 10 ⁇ m or less, it is also referred to as fine dust and when it is 0.1 ⁇ m or less, it is also referred to as ultra fine dust. Dust is a material including materials derived from nature such as sand, soil and pollen, or materials derived from industrial processes such as carbon, carbon combusted products, metal salts and heavy metals, and the like. The presence of dust can be fume, mist, smoke, steam or mist.
- particle group means a collection of single particles.
- particle diameter refers to a particle diameter
- average particle diameter of the first particle group to the second particle group refers to the diameter of each single particle belonging to the first particle group to the second particle group.
- the mean value, and the "average particle diameter" of the plate-shaped powder means the average value of the diagonal length of the widest cross section of the particle.
- the term “thickness” refers to the thickness of the vertical cross-section perpendicular to the widest cross-section of the particles of the plate-shaped powder, and refers to the shortest diameter.
- the present invention is an anti-pollution cosmetic composition comprising at least 20% by weight of spherical powder, based on the total weight of the total composition.
- Spherical powder is a powder that forms a spherical shape, it is included in the powder cosmetic composition to give a smooth and light texture.
- Spherical powder has the effect of diffusing light in all directions, and excellent effect of concealing the defects of the skin such as pores and acne traces compared to the flake powder.
- the powder cosmetic composition having a high proportion of spherical powder is effective for natural skin production, and has an effect of improving the holding force of the cosmetic film, and is suitable for fixing the cosmetic film and correcting makeup.
- the present inventors in the case of a cosmetic composition containing a large amount of spherical powder, to improve the applicability of the formulation to be uniformly applied on the surface of the skin, excellent effect of bridging the bone of the skin surface, the particles in the spherical powder It was confirmed that the anti-pollution effect is excellent by forming fine protrusions to prevent fine dust adhesion.
- the content of the spherical powder may be 20% by weight or more, for example, 25% by weight, 30% by weight, 35% by weight, 40% by weight, or 45% by weight or more, 50% by weight It may be less than or equal to%.
- the content is less than 20% by weight, the bone glendal effect is insignificant, the micro-protrusion is not sufficient enough that the anti-pollution effect may be insignificant, when the content is greater than 50% by weight due to the voids and repulsive force between the powder particles during manufacture It can be difficult to prepare with compressed powder formulations.
- the spherical powder includes a first particle group having an average particle diameter of less than 5 ⁇ m and a second particle group of 5 ⁇ m or more, and a weight ratio of the first particle group and the second particle group is 1: 1.1 to 1. May be eight.
- the weight ratio is within the above range, it helps the particles of different sizes to be applied uniformly and densely, and also has the effect of filling the bones on the surface of the skin, and forms fine protrusions on the surface of the applied skin to prevent adsorption of contaminants. It protects the skin.
- the particle size of the second particle group may be 50 ⁇ m or less, 45 ⁇ m or less, 40 ⁇ m or less, 35 ⁇ m or less, or 30 ⁇ m or less. If the particle size of the second particle group is out of the above range, there is a difficulty in compression molding, a problem may occur in the formulation stability, such as the formulation is broken when falling.
- the weight ratio is 1: 1.1 to 1: 7.6, 1: 1.2 to 1: 7.2, 1: 1.3 to 1: 6.8, 1: 1.4 to 1: 6.4, 1: 1.5 to 1: 6, 1: 1.6 to 1. : 5.6, 1: 1.7 to 1: 5.2, 1: 1.8 to 1: 4.8, 1: 1.9 to 1: 4.4, or 1: 2 to 1: 4, but is not limited thereto.
- the spherical powder includes a first particle group having an average particle diameter of less than 5 ⁇ m, a 2-1 particle group having a particle size of 5 ⁇ m or more and less than 10 ⁇ m, and a second particle group having a particle size of 10 ⁇ m or more.
- the weight ratio of the first particle group, the 2-1 particle group, and the 2-2 particle group may be 1: 0.6: 0.5 to 1: 3: 5.
- the particle diameter of the 2-2 particle group may be 50 ⁇ m or less, 45 ⁇ m or less, 40 ⁇ m or less, 35 ⁇ m or less, or 30 ⁇ m or less.
- the weight ratio is 1: 0.6: 0.5 to 1: 2.8: 4.8, 1: 0.65: 0.55 to 1: 2.6: 4.6, 1: 0.7: 0.6 to 1: 2.4: 4.4, 1: 0.75: 0.65 to 1: 2.2 : 4.2, 1: 0.8: 0.7 to 1: 2: 2: 4, 1: 0.85: 0.75 to 1: 1.8: 3.8, 1: 0.9: 0.8 to 1: 1.6: 3.6, 1: 0.95: 0.85 to 1: 1.4: 3.4 , 1: 1: 0.9 to 1: 1.2: 3.2, or 1: 1.05: 0.95 to 1: 1: 3, but is not limited thereto.
- the spherical powder may include one or more selected from the group consisting of inorganic particles, organic particles, and organic-inorganic composite particles.
- the inorganic particles preferably use silica.
- the silica is a porous spherical powder, has a high oil absorption, has an effect of maintaining the persistence of the makeup film, has a low refractive index, high transparency, and has the advantage of uniformly applying other powders.
- compression molding is difficult when using a high content of silica, it is preferable to use within 30% by weight of the total weight of the cosmetic composition, and more preferably within 20% by weight because it may dry the skin.
- the organic particles are, for example, polystyrene, polymethyl methacrylate, polyethylene, nylon 6, nylon 12, ethylene / acrylic acid copolymer, polymethyl methacrylate / ethylene glycol dimethacrylate copolymer, polyallyl methacrylate / Ethylene glycol dimethacrylate copolymer, ethylene glycol dimethacrylate / lauryl methacrylate copolymer, crosslinked acrylate / ethylhexyl acrylate copolymer, polyurethane, and combinations thereof.
- polymethylmethacrylate and ethylene / acrylic acid copolymers are preferable in terms of formability, light spreadability, and a boosting effect of the cosmetic film.
- the organic-inorganic composite particles may be, for example, polymethylsilsesquioxane, silicone resin powder, organic silicon particles, silica surface-treated with an organic material, and combinations thereof.
- the silicone resin powder may be specifically an organopolysiloxane elastomer powder coated with a silicone resin such as silsesquioxane resin, and more specifically, may be vinyl dimethicone / methicone silsesquioxane crosspolymer.
- the organic silicon particles may be, for example, methylsilanol / silicate crosspolymers, and the silica surface treated with the organic material may be, for example, silica coated with polydimethylsiloxane, but is not limited thereto.
- the spherical powder is used by mixing one or more kinds, the combination is not limited and may be various, but preferably includes one or more of inorganic particles, one or more of organic particles.
- the inorganic particles are preferably contained in 10 to 30% by weight, the organic particles in 5 to 20% by weight in the total composition.
- the above numerical range is satisfied, it can be molded into compressed powder formulations without wet molding and exhibits excellent drop stability.
- by including the inorganic and organic particles in the above numerical range can satisfy the weight ratio of the first particle group to the second particle group of the spherical powder.
- the spherical powder comprises inorganic particles and organic particles, wherein the inorganic particles are silica, and the organic particles may be an ethylene / acrylic acid copolymer.
- the spherical powder includes inorganic particles and organic particles, wherein the inorganic particles are silica, and the organic particles may be a combination of polymethylmethacrylate and ethylene / acrylic acid copolymer.
- the spherical powder may include one or more selected from the group consisting of silica, polymethylmethacrylate, and ethylene / acrylic acid copolymer.
- the cosmetic composition may further comprise a plate-like powder and an oil binder.
- the plate-shaped powder is to impart compression moldability, coverage, skin adhesion and adhesion properties
- the type of the plate-shaped powder is not particularly limited in the present invention may be used a plate-shaped powder commonly used in the art.
- the plate-shaped powder has an average thickness of 0.1 to 1.0 ⁇ m, an average particle diameter of 1 to 100 ⁇ m, and an aspect ratio obtained by dividing the average particle diameter by the average thickness is 10 or more, in terms of compression moldability, coverage, skin adhesion and usability. Do.
- the plate-like powder is talc, mica, boron nitride, barium sulfate, alumina sericite, kaolin, and Synthetic Fluorphlogopite may be one or more selected from the group consisting of, preferably talc is used.
- Talc has no elasticity and almost all kinds can be molded when the average particle size is less than 10 ⁇ m. Since talc has low powder blowing and strong drop stability after molding, it is suitable for implementing compressed powder formulations. The larger the size of the talc powder, the less dense the moldability is, and therefore, talc powder having an average particle size of 4 to 9 ⁇ m, more preferably 6 to 7 ⁇ m, is used.
- the content of the plate-like powder may be 40% by weight or more and less than 80% by weight based on the total weight of the total composition.
- the content of the plate-shaped powder is less than 40% by weight, it is difficult to be formulated into compressed powder, and when the content is 80% by weight or more, the content of the spherical powder is lowered, so that a cosmetic composition with less agglomeration can not be obtained. do.
- the oil binder is to increase the binding force between the powder particles
- the kind of the oil binder is not particularly limited in the present invention may be a plate-like powder commonly used in the art.
- the oil binder is hexyl laurate, dicaprylyl carbonate, diisostearyl malate, butylene glycol dicaprylate / dicaprate dicaprylate / dicaprate, Cetyl ethylhexanoate, Triethylhexanoin, Dicetearyl dimer dilinoleate, Caprylic / Capric triglyceride Triglyceride), ester-based oil selected from the group consisting of Polyglyceryl-2 Triisostearate and Pentaerythrityl Tetraisostearate; Hydrocarbon-based oils selected from the group consisting of polybutene, hydrogenated polyisobutene and phytosqualane; It may be at least one selected from the group consisting of silicone-based oils selected from the group consisting of phenyl trimethicone (Phenyl trimethicone) and dimethicone (Dimethicone). Among them, diisostearyl
- the content of the oil binder may be 5 to 20% by weight based on the total weight of the total composition, more preferably contained in 5 to 10% by weight. If the content of the oil binder is less than 5% by weight dry compression molding is difficult, there is a problem that the drop stability, the powder blowing phenomenon occurs, and if the content of the oil binder exceeds 20% by weight because the agglomeration of powder occurs Adjust appropriately within the range.
- the cosmetic composition according to the present invention may further comprise a pigment in order to compensate for the skin defects and give a bright color.
- a pigment in order to compensate for the skin defects and give a bright color.
- the kind of such pigments is not particularly limited, and white or colored inorganic or organic particles can be used as those commonly used in the art.
- Inorganic pigments include, for example, titanium dioxide, zirconium oxide or cerium oxide, surface treated or untreated, zinc oxide, iron oxide (black, yellow, or red), chromium oxide, manganese violet, ultramarine blue, chromium hydroxide hydrate ( chromium hydrate and ferric blue, aluminum powder and copper powder may be used.
- organic pigments examples include cochinyl extract dyes, azo dyes, anthraquinone dyes, indigo dyes, xanthene dyes, pyrene dyes, quinoline dyes, triphenylmethane dyes, and fluorane dyes.
- the content of such pigments is not particularly limited in the present invention, but may preferably be included in the range of 0.1 to 10% by weight of the total weight of the composition.
- the cosmetic composition is an oil and fat component, moisturizer, softener, surfactant, organic and inorganic pigment, organic powder, ultraviolet absorbent, preservative, thickener, fungicide, antioxidant, plant extract, pH adjuster, alcohol, pigment, flavoring, blood circulation It may further include any one or more of an accelerator, a cooling agent, a restriction agent.
- cosmetics may refer to any material that may have a medical function in addition to the cosmetic function.
- the cosmetic composition may be a compressed powder formulation, more specifically powder pact, foundation, two-way cake, eyebrow, eyeshadow ), A blusher, a highlighter, a concealer and other cosmetics with other functions.
- the particle diameter can be dust-proof fine dust 10 ⁇ m or less.
- the particle size is not limited and may be 100 ⁇ m or less, 90 ⁇ m or less, 70 ⁇ m or less, 50 ⁇ m or less, 30 ⁇ m or less, 20 ⁇ m or less, 15 ⁇ m or less, or 10 ⁇ m or less.
- the cosmetic composition according to the present invention is spherical powder of various sizes is smoothly applied on the skin to be excellent in bone repellent effect to dust the fine dust, it is possible to prevent the attachment of fine dust by forming a fine projection.
- the anti-pollution cosmetic composition of the present invention is prepared through mixing, grinding, filtration, and compression molding of raw materials.
- Mixing and pulverization is not particularly limited, and a general method used in the art may be used, and for example, a 'mixer for mixing contents using high speed rotation of an impeller' such as a food mixer or Henschel mixer may be used.
- a ball mill, a disintegrator in a crusher, a screen mill in an crusher, an atomizer; a hammer mill, a pin mill And it may be performed using any one selected from the group comprising an air jet mill (Air Jet Mill).
- the compression molding method is not particularly limited, and a general method used in the art can be used, and can be molded using, for example, a press machine.
- the cosmetic composition prepared by the above method may measure the hardness using a Teclock type A hardness meter. At this time, the cosmetic composition preferably has a hardness of 10 to 60, more preferably 30 to 50.
- Example 1 The cosmetic composition of Example 1, Example 2, Comparative Example 1 and Comparative Example 2 was prepared using the prescription of Table 1, and the particle groups of the spherical powder according to the formulation of Table 1 were analyzed, and the results were as shown in Table 2. .
- Prescription spherical powder content (% by weight) Spherical powder particle group (wt%) First particle group 2-1 particle group 2-2 particle group
- Example 1 After applying the cosmetic composition of Example 1 and the comparative example 1 to artificial leather, the surface was image
- White artificial leather was attached to the slide glass with a double-sided tape, and according to the content of Table 3 below, evenly spreading the artificial sebum or cosmetic composition with a spatula to prepare a skin replica test body.
- the artificial leather was placed in a fine dust convection box (75 cm X 75 cm X 100 cm), 0.5 g of carbon black was weighed into a convection box, and convection was performed for 10 minutes. Thereafter, the samples were taken out and surface blown, and the states before and after the convection test were compared.
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Abstract
Description
본 명세서에는 미세먼지 등에 대한 방진 효과가 우수한 안티-폴루션 화장료 조성물이 개시된다.Disclosed herein is an anti-pollution cosmetic composition having an excellent dustproof effect against fine dust and the like.
먼지가 체내에 쌓이면, 인체 면역력이 떨어지고 심장 질환이나 호흡기 질환과 같은 각종 질환을 유발할 수 있다. 심지어 기관지에 협착을 일으키기도 하고 장시간 흡입하면 천식이나 폐질환 유병률, 조기 사망률을 증가시킨다. When dust builds up in your body, your body's immunity is compromised and can cause a variety of conditions, such as heart disease and respiratory problems. Even bronchial stenosis and prolonged inhalation increase the prevalence of asthma and lung disease and early mortality.
피부는 먼지와 직접적으로 접촉하는 우리 몸의 가장 바깥쪽으로 유기체와 환경 사이의 장벽 역할을 하는데, 자주 직접적으로 오염에 노출 될 경우, 이 장벽 기능이 저하된다. 특히, 미세먼지는 모공보다 20배 더 작기 때문에 피부에 쉽게 침투할 수 있다. 실제로 미세먼지와 같은 대기 오염물질은 피부 건강에 심각한 영향을 주는 것으로 알려졌다. 단기적으로는 조기 노화, 수분 부족, 잔주름과 주름을 증가시키고, 장기적으로는 되돌릴 수 없는 피부 손상으로 인해 피부가 환경적 요소들로부터 몸을 보호하는 기능을 상실하면서 피부암과 같은 심각한 병을 초래할 수 있다.The skin acts as a barrier between the organism and the environment in the outermost part of our body, which is in direct contact with dust, which often degrades when directly exposed to contamination. In particular, the fine dust is 20 times smaller than the pores, so it can easily penetrate the skin. In fact, air pollutants such as fine dust have been known to seriously affect skin health. In the short term, premature aging, lack of moisture, fine lines and wrinkles, and irreversible skin damage in the long run can lead to serious illnesses such as skin cancer, as the skin loses its ability to protect itself from environmental factors. .
따라서, 피부에 해롭고 때로는 인체에 치명적인 장애를 일으키는 유해 물질인 먼지를 피부와 격리시키기 위한 화장료에 대한 연구가 필요하다.Therefore, there is a need for a study on cosmetics for isolating dust, which is a harmful substance that is harmful to skin and sometimes fatal to the human body, from dust.
일 측면에서, 본 발명의 목적은 오염물질이 피부에 부착되는 것을 방지하는 것이다.In one aspect, the object of the present invention is to prevent contaminants from adhering to the skin.
다른 측면에서, 본 발명의 목적은, 구상 파우더를 고함량으로 포함함으로써, 화장료 조성물의 골메꿈 효과를 향상시키는 것이다. In another aspect, an object of the present invention is to improve the bone repelling effect of the cosmetic composition by including a high content of spherical powder.
다른 측면에서, 본 발명의 목적은, 미세먼지로 인한 피부의 오염을 방지 또는 최소화하는 것이다.In another aspect, an object of the present invention is to prevent or minimize contamination of the skin due to fine dust.
일 측면에서, 본 발명은, 안티-폴루션 화장료 조성물에 있어서, 전체 조성물 총 중량을 기준으로 20 중량% 이상의 구상 파우더를 포함하는 안티-폴루션 화장료 조성물을 제공한다.In one aspect, the present invention, in the anti-pollution cosmetic composition, provides an anti-pollution cosmetic composition comprising at least 20% by weight of the spherical powder based on the total weight of the total composition.
일 측면에 있어서, 본 발명의 안티-폴루션 화장료 조성물은, 먼지, 특히 미세먼지가 피부로 침투하는 것을 최소화할 수 있다. 구체적으로, 고함량으로 포함된 구상 파우더는, 제형의 도포성을 향상시켜 피부 표면에서 균일하게 도포되도록 도와주며, 피부 표면의 골을 메꾸는 효과도 우수하고, 상기 구상 파우더 내 입자가 도포된 표면 상에 입체적인 미세 돌기를 형성하여, 먼지가 피부 표면에 부착되는 것을 최소화할 수 있다. 또한, 판상 파우더와 비교하여, 도포 시에 먼지가 덜 달라붙어 먼지가 피부로 침투하는 것을 방지할 수 있다. 특히, 미세먼지의 피부 침투를 방지하여, 이로 인한 피부 염증, 중금속 축적을 최소화할 수 있어서, 피부 건강에 유익하다.In one aspect, the anti-pollution cosmetic composition of the present invention can minimize the penetration of dust, in particular fine dust into the skin. Specifically, the spherical powder contained in a high content, to improve the applicability of the formulation to help apply evenly on the surface of the skin, the effect of filling the bone of the skin surface is also excellent, the surface coated with particles in the spherical powder By forming three-dimensional fine protrusions on the surface, it is possible to minimize the adhesion of dust to the skin surface. In addition, compared with the plate-shaped powder, it is possible to prevent the dust from sticking to the skin during application and preventing the dust from penetrating into the skin. In particular, by preventing the penetration of fine dust, it is possible to minimize the skin inflammation, heavy metal accumulation due to this, it is beneficial to skin health.
도 1a은 본 발명의 실시예 1의 안티-폴루션 화장료 조성물을 도포한 인조 피혁을 SEM(전자현미경)으로 촬영한 것이고, 도 1b는 비교예 1의 화장료 조성물을 도포한 인조 피혁을 SEM(전자현미경)으로 촬영한 것이다. FIG. 1A is a SEM photograph of artificial leather coated with the anti-pollution cosmetic composition of Example 1 of the present invention, and FIG. 1B is a SEM photograph of artificial leather coated with the cosmetic composition of Comparative Example 1. Taken under a microscope).
도 2a는 본 발명의 실시예 1의 안티-폴루션 화장료 조성물을 도포한 인조 피혁 표면을 디지털 카메라로 촬영한 것이고, 도 2b는 비교예 1의 화장료 조성물을 도포한 인조 피혁 표면을 디지털 카메라로 촬영한 것이다. Figure 2a is a photograph of the artificial leather surface coated with the anti-pollution cosmetic composition of Example 1 of the present invention with a digital camera, Figure 2b is a photograph of the artificial leather surface coated with the cosmetic composition of Comparative Example 1 with a digital camera It is.
도 3a은 본 발명의 실시예 1의 안티-폴루션 화장료 조성물을 도포한 인조 피혁을 3D 스캔 촬영하여 50배 확대하고, 높낮이의 차이를 색상으로 나타낸 것이고, 도 3b는 비교예 1의 화장료 조성물을 도포한 인조 피혁을 3D 스캔 촬영하여 50배 확대하고, 높낮이의 차이를 색상으로 나타낸 것이다. 3A is a 3D scan photograph of a synthetic leather coated with the anti-pollution cosmetic composition of Example 1 of the present invention, and magnified by 50 times, and shows the difference in height in color, and FIG. 3B illustrates the cosmetic composition of Comparative Example 1 The coated artificial leather is magnified 50 times by 3D scan, and the difference in height is expressed in color.
도 4a는 오일 및 본 발명의 실시예 1의 안티-폴루션 화장료 조성물을 도포한 인조 피혁을 미세먼지 대류 박스에 10분간 대류 후 촬영한 것이고, 도 4b는 오일만 도포한 인조 피혁을 미세먼지 대류 박스에 10분간 대류 후 촬영한 것이며, 도 4c 및 4d는 비교예 1 및 2의 화장료 조성물을 도포한 인조 피혁을 미세먼지 대류 박스에 10분간 대류 후 촬영한 것이다.Figure 4a is taken after 10 minutes convection of the artificial leather coated with oil and the anti-pollution cosmetic composition of Example 1 of the present invention in a fine dust convection box, Figure 4b is a fine dust convection of artificial leather coated with oil only After the convection in the box for 10 minutes, it is taken, Figs. 4c and 4d is taken after 10 minutes convection in artificial dust coated with the cosmetic composition of Comparative Examples 1 and 2 in a fine dust convection box.
용어 정의Term Definition
본 명세서에서 “안티-폴루션(anti-pollution)”이란, 먼지 등의 오염물질이 피부에 부착되는 것 또는 피부에 임시적으로 부착된 오염물질이 피부에서 제거되어 피부에 침투하는 것을 예방하거나, 최소화하는 것을 의미한다. 즉, 본 명세서의 안티-폴루션 화장료 조성물을 피부에 적용할 경우, 골메꿈 효과가 우수하여 피부에 오염물질이 부착되는 것을 최소화 할 수 있고, 판상 파우더와 비교하여, 도포 시에 먼지가 덜 달라붙어 먼지가 피부로 침투하는 것을 방지할 수 있다.As used herein, the term “anti-pollution” refers to preventing or minimizing the adhesion of contaminants, such as dust, to the skin, or the removal of contaminants adhering to the skin from the skin to penetrate the skin. I mean. That is, when the anti-pollution cosmetic composition of the present disclosure is applied to the skin, it is possible to minimize the adhesion of contaminants to the skin due to the excellent bone repelling effect, and compared to the plate-like powder, the dust is less at the time of application It can prevent dust from penetrating the skin.
본 명세서에서 “먼지”는, 대기 중에 섞여 있는 미립자를 총칭하는 것으로, 보통 10mm 이하의 입경을 가진 부유물질을 의미한다. 특히, 입경이 10㎛이하인 경우 미세먼지, 0.1㎛ 이하인 경우 극미세 먼지라고도 한다. 먼지는, 모래, 흙 및 꽃가루와 같은 자연에서 유래한 물질 또는 탄소, 탄소 연소물, 금속염 및 중금속과 같은 산업공정으로부터 유래한 물질 등을 포함하는 물질이다. 먼지의 존재 형태는 흄(fume), 미스트(mist), 연기, 증기 또는 연무일 수 있다. As used herein, the term “dust” refers to particulates mixed in the air, and refers to suspended solids having a particle diameter of usually 10 mm or less. Particularly, when the particle diameter is 10 μm or less, it is also referred to as fine dust and when it is 0.1 μm or less, it is also referred to as ultra fine dust. Dust is a material including materials derived from nature such as sand, soil and pollen, or materials derived from industrial processes such as carbon, carbon combusted products, metal salts and heavy metals, and the like. The presence of dust can be fume, mist, smoke, steam or mist.
본 명세서에서 “입자군”이란 단일 입자들의 집합을 의미한다. As used herein, the term "particle group" means a collection of single particles.
본 명세서에서 “입경”이란 입자의 직경을 의미하고, 제1 입자군 내지 제2-2 입자군의 “평균 입경”이란 1 입자군 내지 제2-2 입자군에 속하는 각각의 단일 입자의 지름의 평균값을 의미하며, 판상 파우더의 “평균 입경”이란 입자의 가장 넓은 단면의 대각선 길이의 평균값을 의미한다. As used herein, the term “particle diameter” refers to a particle diameter, and the “average particle diameter” of the first particle group to the second particle group refers to the diameter of each single particle belonging to the first particle group to the second particle group. The mean value, and the "average particle diameter" of the plate-shaped powder means the average value of the diagonal length of the widest cross section of the particle.
본 명세서에서 “두께”란 판상 파우더의 입자의 가장 넓은 단면을 기준으로 수직인 단면의 두꺼운 정도를 의미하는 것으로, 가장 짧은 직경을 말한다.As used herein, the term "thickness" refers to the thickness of the vertical cross-section perpendicular to the widest cross-section of the particles of the plate-shaped powder, and refers to the shortest diameter.
본 명세서에서, 어떤 부분이 어떤 구성 요소를 "포함"한다고 할 때, 이는 특별히 반대되는 기재가 없는 한 다른 구성 요소를 제외하는 것이 아니라 다른 구성 요소를 더 포함할 수 있는 것을 의미한다.In the present specification, when a part "includes" a certain component, it means that it may further include other components, without excluding the other components unless otherwise stated.
예시적인 구현예들의 설명Description of Example Embodiments
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 발명의 예시적인 구현예들에서는, 본 발명은 안티-폴루션 화장료 조성물에 있어서, 전체 조성물 총 중량을 기준으로 20 중량% 이상의 구상 파우더를 포함하는 안티-폴루션 화장료 조성물이다. In exemplary embodiments of the present invention, the present invention is an anti-pollution cosmetic composition comprising at least 20% by weight of spherical powder, based on the total weight of the total composition.
구상 파우더(spherical powder)는 입자의 형태가 구형을 이루는 파우더로, 파우더 화장료 조성물에 포함되어 매끄럽고 가벼운 감촉을 부여한다. 구상 파우더는 광을 모든 방향으로 확산하는 효과가 있어, 판상 파우더(flake powder)에 비하여 모공이나 여드름 흔적 등 피부의 결점을 은폐시켜주는 효과가 우수하다. 이에, 구상 파우더의 비율이 높은 파우더 화장료 조성물은 자연스러운 피부 연출에 효과적이며, 화장막의 유지력을 향상시키는 효과가 있어 화장막 고정용 및 수정 화장용으로 적합하다. Spherical powder (spherical powder) is a powder that forms a spherical shape, it is included in the powder cosmetic composition to give a smooth and light texture. Spherical powder has the effect of diffusing light in all directions, and excellent effect of concealing the defects of the skin such as pores and acne traces compared to the flake powder. Thus, the powder cosmetic composition having a high proportion of spherical powder is effective for natural skin production, and has an effect of improving the holding force of the cosmetic film, and is suitable for fixing the cosmetic film and correcting makeup.
나아가, 본 발명자들은 구상 파우더를 다량 함유하는 화장료 조성물의 경우, 제형의 도포성을 향상시켜 피부 표면에서 균일하게 도포되도록 도와주며, 피부 표면의 골을 메꾸는 효과도 우수하고, 구상 파우더 내 입자들이 미세 돌기를 형성하여 미세먼지 부착을 방지하여 안티-폴루션 효과가 우수하다는 것을 확인하였다Furthermore, the present inventors, in the case of a cosmetic composition containing a large amount of spherical powder, to improve the applicability of the formulation to be uniformly applied on the surface of the skin, excellent effect of bridging the bone of the skin surface, the particles in the spherical powder It was confirmed that the anti-pollution effect is excellent by forming fine protrusions to prevent fine dust adhesion.
일 구현예에서, 상기 구상 파우더의 함량은 20 중량% 이상일 수 있고, 예컨대, 25 중량% 이상, 30 중량% 이상, 35 중량% 이상, 40 중량% 이상, 또는 45 중량% 이상일 수 있으며, 50 중량% 이하일 수 있다. 상기 함량이 20 중량% 미만인 경우, 골메꿈 효과가 미미하고, 미세돌기 형성이 충분치 않아 안티-폴루션 효과가 미미할 수 있고, 50 중량% 초과인 경우 제조시 파우더 입자 간의 공극 및 반발력으로 인하여 팩트 타입의 압축 파우더 제형으로 제조하기 어려울 수 있다. In one embodiment, the content of the spherical powder may be 20% by weight or more, for example, 25% by weight, 30% by weight, 35% by weight, 40% by weight, or 45% by weight or more, 50% by weight It may be less than or equal to%. When the content is less than 20% by weight, the bone glendal effect is insignificant, the micro-protrusion is not sufficient enough that the anti-pollution effect may be insignificant, when the content is greater than 50% by weight due to the voids and repulsive force between the powder particles during manufacture It can be difficult to prepare with compressed powder formulations.
일 구현예에서, 상기 상기 구상 파우더는 평균 입경 5㎛ 미만의 제1 입자군과 5㎛ 이상의 제2 입자군을 포함하고, 상기 제1 입자군과 제2 입자군의 중량비는 1 : 1.1 내지 1 : 8일 수 있다. 중량비가 상기 범위 내인 경우, 서로 다른 사이즈의 입자가 촘촘하게 균일하게 도포되도록 도와주며, 피부 표면의 골을 메꾸는 효과도 우수하고, 도포된 피부 표면에 미세 돌기를 형성하여 오염 물질의 흡착을 방지하고 피부를 보호하는 효과가 있다. In one embodiment, the spherical powder includes a first particle group having an average particle diameter of less than 5 μm and a second particle group of 5 μm or more, and a weight ratio of the first particle group and the second particle group is 1: 1.1 to 1. May be eight. When the weight ratio is within the above range, it helps the particles of different sizes to be applied uniformly and densely, and also has the effect of filling the bones on the surface of the skin, and forms fine protrusions on the surface of the applied skin to prevent adsorption of contaminants. It protects the skin.
예컨대, 상기 제2 입자군의 입경은 50㎛ 이하, 45㎛ 이하, 40㎛ 이하, 35㎛ 이하, 또는 30㎛ 이하일 수 있다. 상기 제2 입자군의 입경이 상기 범위를 벗어나는 경우, 압축 성형 시 어려움이 있고, 낙하 시 제형이 깨지는 등 제형 안정성에 문제가 발생할 수 있다. For example, the particle size of the second particle group may be 50 μm or less, 45 μm or less, 40 μm or less, 35 μm or less, or 30 μm or less. If the particle size of the second particle group is out of the above range, there is a difficulty in compression molding, a problem may occur in the formulation stability, such as the formulation is broken when falling.
예컨대, 상기 중량비는 1 : 1.1 내지 1 : 7.6, 1 : 1.2 내지 1 : 7.2, 1 : 1.3 내지 1 : 6.8, 1 : 1.4 내지 1 : 6.4, 1 : 1.5 내지 1 : 6, 1 : 1.6 내지 1 : 5.6, 1 : 1.7 내지 1 : 5.2, 1 : 1.8 내지 1 : 4.8, 1 : 1.9 내지 1 : 4.4, 또는 1 : 2 내지 1 : 4일 수 있으나, 이에 제한되는 것은 아니다. For example, the weight ratio is 1: 1.1 to 1: 7.6, 1: 1.2 to 1: 7.2, 1: 1.3 to 1: 6.8, 1: 1.4 to 1: 6.4, 1: 1.5 to 1: 6, 1: 1.6 to 1. : 5.6, 1: 1.7 to 1: 5.2, 1: 1.8 to 1: 4.8, 1: 1.9 to 1: 4.4, or 1: 2 to 1: 4, but is not limited thereto.
일 구현예에서, 상기 구상 파우더는 평균 입경 5㎛ 미만의 제1 입자군, 5㎛ 이상 10㎛ 미만의 제2-1 입자군, 및 입경 10㎛ 이상의 제2-2 입자군을 포함하고, 상기 제1 입자군, 제2-1 입자군 및 제2-2 입자군의 중량비는 1 : 0.6 : 0.5 내지 1 : 3 : 5일 수 있다. 상기 제2-2 입자군의 입경은 50㎛ 이하, 45㎛ 이하, 40㎛ 이하, 35㎛ 이하, 또는 30㎛ 이하일 수 있다.In one embodiment, the spherical powder includes a first particle group having an average particle diameter of less than 5 μm, a 2-1 particle group having a particle size of 5 μm or more and less than 10 μm, and a second particle group having a particle size of 10 μm or more. The weight ratio of the first particle group, the 2-1 particle group, and the 2-2 particle group may be 1: 0.6: 0.5 to 1: 3: 5. The particle diameter of the 2-2 particle group may be 50 μm or less, 45 μm or less, 40 μm or less, 35 μm or less, or 30 μm or less.
예컨대, 상기 중량비는 1 : 0.6 : 0.5 내지 1 : 2.8 : 4.8, 1 : 0.65 : 0.55 내지 1 : 2.6 : 4.6, 1 : 0.7 : 0.6 내지 1 : 2.4 : 4.4, 1 : 0.75 : 0.65 내지 1 : 2.2 : 4.2, 1 : 0.8 : 0.7 내지 1 : 2 : 4, 1 : 0.85 : 0.75 내지 1 : 1.8 : 3.8, 1 : 0.9 : 0.8 내지 1 : 1.6 : 3.6, 1 : 0.95 : 0.85 내지 1 : 1.4 : 3.4, 1 : 1 : 0.9 내지 1 : 1.2 : 3.2, 또는 1 : 1.05 : 0.95 내지 1 : 1 : 3 일 수 있으나, 이에 제한되는 것은 아니다. For example, the weight ratio is 1: 0.6: 0.5 to 1: 2.8: 4.8, 1: 0.65: 0.55 to 1: 2.6: 4.6, 1: 0.7: 0.6 to 1: 2.4: 4.4, 1: 0.75: 0.65 to 1: 2.2 : 4.2, 1: 0.8: 0.7 to 1: 2: 2: 4, 1: 0.85: 0.75 to 1: 1.8: 3.8, 1: 0.9: 0.8 to 1: 1.6: 3.6, 1: 0.95: 0.85 to 1: 1.4: 3.4 , 1: 1: 0.9 to 1: 1.2: 3.2, or 1: 1.05: 0.95 to 1: 1: 3, but is not limited thereto.
일 구현예에서, 상기 구상 파우더는 무기 입자, 유기 입자 및 유무기 복합 입자로 이루어진 군에서 선택된 1종 이상을 포함할 수 있다. In one embodiment, the spherical powder may include one or more selected from the group consisting of inorganic particles, organic particles, and organic-inorganic composite particles.
상기 무기 입자는 바람직하기로 실리카를 사용한다. 상기 실리카는 다공질의 구상 파우더로서 흡유량이 높아 화장막의 지속성을 유지시키는 효과를 나타내며, 굴절률이 낮아 투명성이 높고, 다른 파우더를 고르게 도포시켜주는 장점이 있다. 다만, 실리카를 고함량 사용 시 압축 성형이 어려우며, 피부가 건조해질 수 있으므로 화장료 조성물 총 중량의 30 중량% 이내로 사용하는 것이 바람직하며, 보다 바람직하기로 20 중량% 이내로 사용한다.The inorganic particles preferably use silica. The silica is a porous spherical powder, has a high oil absorption, has an effect of maintaining the persistence of the makeup film, has a low refractive index, high transparency, and has the advantage of uniformly applying other powders. However, compression molding is difficult when using a high content of silica, it is preferable to use within 30% by weight of the total weight of the cosmetic composition, and more preferably within 20% by weight because it may dry the skin.
상기 유기 입자는 예를 들어 폴리스티렌, 폴리메틸메타크릴레이트, 폴리에틸렌, 나일론 6, 나일론 12, 에틸렌/아크릴산 코폴리머, 폴리메틸메타크릴레이트/에틸렌글리콜 디메타크릴레이트 코폴리머, 폴리알릴메타크릴레이트/에틸렌글리콜디메타크릴레이트 코폴리머, 에틸렌글리콜 디메타크릴레이트/라우릴메타크릴레이트 코폴리머, 가교 아크릴레이트/에틸헥실아크릴레이트 코폴리머, 폴리우레탄 및 이들의 조합을 들 수 있다. 이 중 압축 파우더 제형으로의 성형성, 가벼운 발림성 및 화장막의 부스팅 효과 확보 측면에서 폴리메틸메타크릴레이트 및 에틸렌/아크릴산 코폴리머가 바람직하다.The organic particles are, for example, polystyrene, polymethyl methacrylate, polyethylene,
상기 유무기 복합입자는 예를 들어 폴리메틸실세스퀴옥산, 실리콘레진 파우더, 유기 실리콘 입자, 유기물질로 표면 처리된 실리카 및 이들의 조합일 수 있다.The organic-inorganic composite particles may be, for example, polymethylsilsesquioxane, silicone resin powder, organic silicon particles, silica surface-treated with an organic material, and combinations thereof.
상기 실리콘 레진 파우더는 구체적으로 실세스퀴옥산 레진과 같은 실리콘 레진이 코팅된 유기폴리실록산 엘라스토머 파우더일 수 있으며, 보다 구체적으로 비닐 디메치콘/메치콘 실세스퀴옥산 크로스폴리머일 수 있다. 상기 유기 실리콘 입자는 예를 들어 메틸실란올/실리케이트 크로스폴리머일 수 있고, 상기 유기 물질로 표면 처리된 실리카는 예를 들어 표면이 폴리디메틸실록산으로 코팅된 실리카일 수 있으나, 이에 제한되지 않는다.The silicone resin powder may be specifically an organopolysiloxane elastomer powder coated with a silicone resin such as silsesquioxane resin, and more specifically, may be vinyl dimethicone / methicone silsesquioxane crosspolymer. The organic silicon particles may be, for example, methylsilanol / silicate crosspolymers, and the silica surface treated with the organic material may be, for example, silica coated with polydimethylsiloxane, but is not limited thereto.
본 발명에 따른 화장료 조성물에서 구상 파우더는 1종 이상을 혼합하여 사용되고, 그 조합은 제한되지 않으며 다양할 수 있으나, 바람직하기로 무기 입자 중 1종 이상, 유기 입자 중 1종 이상을 포함한다. 이때, 무기입자는 전체 조성물 내에서 10 내지 30 중량%, 유기 입자는 5 내지 20 중량%로 포함되는 것이 바람직하다. 상기 수치 범위를 만족할 때, 습식 성형에 의하지 않고도 압축 파우더 제형으로 성형될 수 있으며 우수한 낙하 안정도를 나타낸다. 또한, 상기 수치 범위로 무기 및 유기 입자를 포함함으로써 상기 구상 파우더의 제1 입자군 내지 제2-2 입자군의 중량비를 만족할 수 있다. In the cosmetic composition according to the present invention, the spherical powder is used by mixing one or more kinds, the combination is not limited and may be various, but preferably includes one or more of inorganic particles, one or more of organic particles. At this time, the inorganic particles are preferably contained in 10 to 30% by weight, the organic particles in 5 to 20% by weight in the total composition. When the above numerical range is satisfied, it can be molded into compressed powder formulations without wet molding and exhibits excellent drop stability. In addition, by including the inorganic and organic particles in the above numerical range can satisfy the weight ratio of the first particle group to the second particle group of the spherical powder.
일 구현예에서, 상기 구상 파우더는 무기 입자 및 유기 입자를 포함하며, 이때 무기 입자는 실리카이고, 유기 입자는 에틸렌/아크릴산 코폴리머일 수 있다.In one embodiment, the spherical powder comprises inorganic particles and organic particles, wherein the inorganic particles are silica, and the organic particles may be an ethylene / acrylic acid copolymer.
일 구현예에서, 상기 구상 파우더는 무기 입자 및 유기 입자를 포함하며, 이때 무기입자는 실리카이고, 유기입자는 폴리메틸메타크릴레이트 및 에틸렌/아크릴산 코폴리머의 조합일 수 있다.In one embodiment, the spherical powder includes inorganic particles and organic particles, wherein the inorganic particles are silica, and the organic particles may be a combination of polymethylmethacrylate and ethylene / acrylic acid copolymer.
일 구현예에서, 상기 구상 파우더는 실리카, 폴리메틸메타크릴레이트, 및 에틸렌/아크릴산 코폴리머로 이루어진 군에서 선택된 1종 이상을 포함할 수 있다. In one embodiment, the spherical powder may include one or more selected from the group consisting of silica, polymethylmethacrylate, and ethylene / acrylic acid copolymer.
일 구현예에서, 상기 화장료 조성물은 판상 파우더 및 오일 바인더를 더 포함할 수 있다. In one embodiment, the cosmetic composition may further comprise a plate-like powder and an oil binder.
상기 판상 파우더는 압축 성형성, 커버력, 피부 부착성 및 밀착 특성을 부여하기 위한 것으로서, 판상 파우더의 종류는 본 발명에서 특별히 한정하지 않으며 당 업계에서 통상 사용되는 판상 파우더가 사용될 수 있다.The plate-shaped powder is to impart compression moldability, coverage, skin adhesion and adhesion properties, the type of the plate-shaped powder is not particularly limited in the present invention may be used a plate-shaped powder commonly used in the art.
이때, 판상 파우더는 평균 두께가 0.1 내지 1.0 μm이고 평균 입자 직경이 1 내지 100 μm이며 평균 두께로 평균 입자 직경을 나눠 얻은 종횡비는 10 이상인 것이 압축 성형성, 커버력, 피부 부착성 및 사용감 측면에서 바람직하다. In this case, the plate-shaped powder has an average thickness of 0.1 to 1.0 μm, an average particle diameter of 1 to 100 μm, and an aspect ratio obtained by dividing the average particle diameter by the average thickness is 10 or more, in terms of compression moldability, coverage, skin adhesion and usability. Do.
일 구현예에서, 상기 판상 파우더는 탈크(Talc), 마이카(Mica), 보론나이트라이드(Boron nitride), 바륨설페이트(Barium sulfate), 알루미나(Alumina) 세리사이트(sericite), 카올린(Kaolin), 및 합성플루오르플로고파이트(Synthetic Fluorphlogopite)로 이루어지는 군에서 선택되는 1종 이상일 수 있으며, 바람직하기로 탈크를 사용한다. 탈크는 탄성이 없는 특징을 가지며 평균 입자 크기가 10 μm 이내인 경우 거의 모든 종류가 성형이 가능하고, 성형 이후 가루 날림이 적으며 낙하 안정성이 강하므로, 압축 파우더 제형을 구현하기에 적합하다. 탈크 파우더의 크기가 클수록 조밀함이 떨어져 성형성이 저하되므로, 바람직하기로 4 내지 9 μm, 보다 바람직하기로 6 내지 7 μm 의 평균 입자 크기를 갖는 탈크 파우더를 사용한다.In one embodiment, the plate-like powder is talc, mica, boron nitride, barium sulfate, alumina sericite, kaolin, and Synthetic Fluorphlogopite may be one or more selected from the group consisting of, preferably talc is used. Talc has no elasticity and almost all kinds can be molded when the average particle size is less than 10 μm. Since talc has low powder blowing and strong drop stability after molding, it is suitable for implementing compressed powder formulations. The larger the size of the talc powder, the less dense the moldability is, and therefore, talc powder having an average particle size of 4 to 9 μm, more preferably 6 to 7 μm, is used.
일 구현예에서, 상기 판상 파우더의 함량은 전체 조성물 총 중량을 기준으로 40 중량% 이상 80 중량% 미만일 수 있다. 판상 파우더의 함량이 40 중량% 미만이면 압축 파우더로 제형화 하기에 어려운 문제점이 있고, 80 중량% 이상인 경우, 구상 파우더의 함량이 낮아져 뭉침 현상이 적은 화장료 조성물을 얻을 수 없으므로 상기 범위 내에서 적절히 조절한다.In one embodiment, the content of the plate-like powder may be 40% by weight or more and less than 80% by weight based on the total weight of the total composition. When the content of the plate-shaped powder is less than 40% by weight, it is difficult to be formulated into compressed powder, and when the content is 80% by weight or more, the content of the spherical powder is lowered, so that a cosmetic composition with less agglomeration can not be obtained. do.
상기 오일 바인더는 파우더 입자간 결합력을 높이기 위한 것으로, 오일 바인더의 종류는 본 발명에서 특별히 한정하지 않으며 당 업계에서 통상 사용되는 판상 파우더가 사용될 수 있다.The oil binder is to increase the binding force between the powder particles, the kind of the oil binder is not particularly limited in the present invention may be a plate-like powder commonly used in the art.
일 구현예에서, 상기 오일 바인더는 헥실라우레이트(Hexyl laurate), 디카프릴릴카보네이트(Dicaprylyl carbonate),디이소스테아릴말레이트(Diisostearyl malate), 부틸렌글라이콜디카프릴레이트/디카프레이트(Butylene glycol dicaprylate/dicaprate), 세틸에칠헥사노에이트(Cetyl ethylhexanoate), 트리에칠헥사노인(Triethylhexanoin), 디세테아릴다이머디리놀리에이트(Dicetearyl dimer dilinoleate), 카프릴릭/카프릭트리글리세라이드(Caprylic/Capric Triglyceride), 폴리글리세릴-2트리이소스테아레이트(Polyglyceryl-2 Triisostearate) 및 펜타에리스리틸테트라이소스테아레이트(Pentaerythrityl Tetraisostearate)로 이루어진 군에서 선택된 에스테르계 오 일; 폴리부텐(Polybutene), 하이드로제네이티드폴리이소부텐(Hydrogenatedpolyisobutene) 및 식물성스쿠알란(Phytosqualane)으로 이루어진 군에서 선택된 탄화수소 계 오일; 페닐트리메치콘(Phenyl trimethicone) 및 디메치콘(Dimethicone)으로 이루어진 군에서 선택된 실리콘 계 오일로 이루어지는 군에서 선택되는 1종 이상일 수 있다. 이 중, 성형성과 사용감 측면에서 바람직하기로 디이소스테아릴말레이트 또는 디메치콘을 사용한다.In one embodiment, the oil binder is hexyl laurate, dicaprylyl carbonate, diisostearyl malate, butylene glycol dicaprylate / dicaprate dicaprylate / dicaprate, Cetyl ethylhexanoate, Triethylhexanoin, Dicetearyl dimer dilinoleate, Caprylic / Capric triglyceride Triglyceride), ester-based oil selected from the group consisting of Polyglyceryl-2 Triisostearate and Pentaerythrityl Tetraisostearate; Hydrocarbon-based oils selected from the group consisting of polybutene, hydrogenated polyisobutene and phytosqualane; It may be at least one selected from the group consisting of silicone-based oils selected from the group consisting of phenyl trimethicone (Phenyl trimethicone) and dimethicone (Dimethicone). Among them, diisostearyl maleate or dimethicone is preferably used in view of moldability and usability.
일 구현예에서, 상기 오일 바인더의 함량은 전체 조성물 총 중량을 기준으로 5 내지 20 중량%일 수 있고, 5 내지 10 중량%로 포함되는 것이 보다 바람직하다. 오일 바인더의 함량이 5 중량% 미만이면 건식 압축 성형이 어렵고, 낙하 안정성이 떨어지며, 가루 날림이 현상이 나타나는 문제가 있고, 오일 바인더의 함량이 20 중량%를 초과하면 파우더의 뭉침 현상이 발생하므로 상기 범위 내에서 적절히 조절한다.In one embodiment, the content of the oil binder may be 5 to 20% by weight based on the total weight of the total composition, more preferably contained in 5 to 10% by weight. If the content of the oil binder is less than 5% by weight dry compression molding is difficult, there is a problem that the drop stability, the powder blowing phenomenon occurs, and if the content of the oil binder exceeds 20% by weight because the agglomeration of powder occurs Adjust appropriately within the range.
한편, 본 발명에 따른 화장료 조성물은 피부 결점 보완 및 화사한 색감을 부여하기 위하여 안료를 더 포함할 수 있다. 이러한 안료의 종류는 특별히 한정되지 않으며, 백색 또는 유색의 무기 또는 유기 입자로서 당 업계에서 통상 사용되는 것을 사용할 수 있다.On the other hand, the cosmetic composition according to the present invention may further comprise a pigment in order to compensate for the skin defects and give a bright color. The kind of such pigments is not particularly limited, and white or colored inorganic or organic particles can be used as those commonly used in the art.
무기 안료로는 예를 들어 이산화티탄, 표면처리 되거나 표면처리 되지 않은 산화지르코늄 또는 산화세륨, 산화아연, 산화철(흑색, 황색, 또는 적색), 산화크롬, 망간 바이올렛, 울트라마린블루, 수산화크롬 수화물(chromium hydrate) 및 페릭블루(ferric blue), 알루미늄분말 및 구리분말이 사용될 수 있다.Inorganic pigments include, for example, titanium dioxide, zirconium oxide or cerium oxide, surface treated or untreated, zinc oxide, iron oxide (black, yellow, or red), chromium oxide, manganese violet, ultramarine blue, chromium hydroxide hydrate ( chromium hydrate and ferric blue, aluminum powder and copper powder may be used.
유기 안료로는 예를 들어 코치닐추출색소, 아조 염료, 안트라퀴논 염료, 인디고이드 염료, 크산텐 염료, 피렌 염료, 퀴놀린 염료, 트리페닐메탄 염료, 또는 플루오란 염료 등을 들 수 있다.Examples of the organic pigments include cochinyl extract dyes, azo dyes, anthraquinone dyes, indigo dyes, xanthene dyes, pyrene dyes, quinoline dyes, triphenylmethane dyes, and fluorane dyes.
이러한 안료의 함량은 본 발명에서 특별히 한정하지 않으나, 바람직하기로 조성물 총 중량의 0.1 내지 10 중량% 범위로 포함될 수 있다.The content of such pigments is not particularly limited in the present invention, but may preferably be included in the range of 0.1 to 10% by weight of the total weight of the composition.
이외에도, 상기 화장료 조성물은 유지 성분, 보습제, 연화제, 계면활성제, 유기 및 무기 안료, 유기분체, 자외선 흡수제, 방부제, 점증제, 살균제, 산화방지제, 식물 추출물, pH 조정제, 알코올, 색소, 향료, 혈행 촉진제, 냉감제, 제한(制汗)제 중 어느 하나 이상을 더 포함할 수 있다.In addition, the cosmetic composition is an oil and fat component, moisturizer, softener, surfactant, organic and inorganic pigment, organic powder, ultraviolet absorbent, preservative, thickener, fungicide, antioxidant, plant extract, pH adjuster, alcohol, pigment, flavoring, blood circulation It may further include any one or more of an accelerator, a cooling agent, a restriction agent.
본 명세서에서 "화장료"는, 미용 기능뿐만 아니라, 미용 기능 외에 추가적으로 의학적 기능을 가질 수 있는 모든 물질을 의미할 수 있다.As used herein, the term "cosmetics" may refer to any material that may have a medical function in addition to the cosmetic function.
일 구현예에서, 상기 화장료 조성물은 압축파우더 제형일 수 있고, 더욱 구체적으로 파우더 팩트(powder pact), 파운데이션(foundation), 투웨이 케이크(two-way cake), 아이브라우(eyebrow), 아이섀도우(eyeshadow), 볼연지(blusher), 하이라이터(highlighter), 컨실러(concealer) 및 기타의 기능을 가진 화장품일 수 있다. In one embodiment, the cosmetic composition may be a compressed powder formulation, more specifically powder pact, foundation, two-way cake, eyebrow, eyeshadow ), A blusher, a highlighter, a concealer and other cosmetics with other functions.
일 구현예에서, 상기 화장료 조성물은, 입경이 10㎛ 이하인 미세먼지를 방진할 수 있다. 입경 크기는, 제한되지 않고, 100㎛ 이하, 90㎛ 이하, 70㎛ 이하, 50㎛ 이하, 30㎛ 이하, 20㎛ 이하, 15㎛ 이하 또는 10㎛ 이하일 수 있다. 본 발명에 따른 화장료 조성물은 다양한 크기의 구상 파우더가 피부 상에 매끄럽게 도포되어 골메꿈 효과가 우수하여 미세 먼지를 방진할 수 있고, 미세 돌기를 형성함으로써 미세먼지의 부착 자체를 방지할 수 있다. In one embodiment, the cosmetic composition, the particle diameter can be dust-proof
안티-폴루션 화장료 조성물의 제조방법Method for preparing anti-pollution cosmetic composition
본 발명의 안티-폴루션 화장료 조성물은 원료의 혼합, 분쇄, 여과, 및 압축 성형 단계를 거쳐 제조된다.The anti-pollution cosmetic composition of the present invention is prepared through mixing, grinding, filtration, and compression molding of raw materials.
혼합 및 분쇄는 특별히 제한되지 않고, 당 업계에서 사용하는 일반적인 방법을 사용할 수 있으며, 예를 들어 푸드믹서, 헨셀믹서 등 '임펠러의 고속회전을 이용하여 내용물을 혼합하는 믹서기'를 사용할 수 있다. 또한, 볼밀(ball mill), 해쇄기 중 디스인테그레이터(disintegtator), 미분쇄기 중 스크린밀(screen mill; 아토마이저(atomizer); 해머밀(hammer mill)), 마멀분쇄기, 핀밀(pin mill) 및 공기 충돌 분쇄기(Air Jet Mill)를 포함하는 군으로부터 선택되는 어느 하나인 것을 이용하여 수행될 수 있다.Mixing and pulverization is not particularly limited, and a general method used in the art may be used, and for example, a 'mixer for mixing contents using high speed rotation of an impeller' such as a food mixer or Henschel mixer may be used. In addition, a ball mill, a disintegrator in a crusher, a screen mill in an crusher, an atomizer; a hammer mill, a pin mill And it may be performed using any one selected from the group comprising an air jet mill (Air Jet Mill).
압축 성형 방법은 특별히 제한되지 않고, 당 업계에서 사용하는 일반적인 방법을 사용할 수 있으며, 예를 들어 프레스기를 사용하여 성형할 수 있다.The compression molding method is not particularly limited, and a general method used in the art can be used, and can be molded using, for example, a press machine.
상기 방법에 의하여 제조된 화장료 조성물은 Teclock type A경도계를 이용하여 경도를 측정할 수 있다. 이때, 화장료 조성물은 경도가 10 내지 60인 것이 바람직하며, 30 내지 50인 것이 보다 바람직하다.The cosmetic composition prepared by the above method may measure the hardness using a Teclock type A hardness meter. At this time, the cosmetic composition preferably has a hardness of 10 to 60, more preferably 30 to 50.
이하, 하기의 실시예를 통하여 본 발명을 보다 구체적으로 설명한다. 그러나 하기의 실시에는 본 발명에 대한 이해를 돕기 위해 예시의 목적으로만 제공된 것일 뿐, 본 발명의 범주 및 범위가 이에 한정되지 않는다.Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the following practice is provided only for the purpose of illustration in order to help the understanding of the present invention, the scope and scope of the present invention is not limited thereto.
실시예 - 안티-폴루션 화장료 조성물의 제조Example-Preparation of Anti-Pollution Cosmetic Compositions
표 1의 처방으로 실시예 1, 실시예 2, 비교예 1 및 비교예 2의 화장료 조성물을 제조하였으며, 표 1의 처방에 따른 구상 파우더의 입자군을 분석한 결과, 표 2와 같은 결과로 나타났다.The cosmetic composition of Example 1, Example 2, Comparative Example 1 and Comparative Example 2 was prepared using the prescription of Table 1, and the particle groups of the spherical powder according to the formulation of Table 1 were analyzed, and the results were as shown in Table 2. .
1) 혼합기에 구상 파우더, 판상 파우더 및 기타 성분을 평량 후 2분 동안 혼합하였다.1) The spherical powder, plate powder and other ingredients were mixed in the mixer for 2 minutes after basis weight.
2) 오일 바인더 성분을 평량하여 70 ~ 80℃ 로 가열하였다.2) The oil binder component was weighed and heated to 70 to 80 ° C.
3) 상기 2)를 분무하며 헨셀믹서(500 ~ 1000 rpm)를 이용하여 1 ~ 2분 동안 혼합, 해쇄하였다.3) The sprayed 2) was mixed and disintegrated for 1 to 2 minutes using a Henschel mixer (500 to 1000 rpm).
4) 상기 3)을 고속(1500 ~ 2000 rpm)으로 하여 2분 동안 혼합하였다.4) Mixing 3) at high speed (1500 ~ 2000 rpm) for 2 minutes.
5) 상기 4)를 15마력으로 분쇄 후 여과하였다.5) The 4) was pulverized to 15 hp and filtered.
6) 금속 접시 위에 일정량 올려놓은 후 약 20 kgf/cm2 로 약 5초간 성형하여 파우더 팩트를 제조하였다.6) After placing a certain amount on a metal plate was molded for about 5 seconds at about 20 kgf / cm 2 to prepare a powder pact.
실험예Experimental Example
실험예 1- 골메꿈 효과 및 미세 돌기 형성 평가Experimental Example 1-Evaluation of Bone Glow Effect and Fine Projection Formation
실시예 1, 및 비교예 1의 화장료 조성물을 인조 피혁에 도포한 뒤, 표면을 SEM, 디지털 카메라 및 3D 스캔을 이용하여 촬영하였다. After applying the cosmetic composition of Example 1 and the comparative example 1 to artificial leather, the surface was image | photographed using SEM, a digital camera, and 3D scan.
도 1a, 1b, 2a 및 2b를 참조하면, 실시예 1의 화장료 조성물을 도포한 경우, 비교예 1의 화장료 조성물을 도포한 표면에 비하여, 보다 촘촘하게 인조 피혁의 골을 메꾸어 균일하고 매끈한 화장막을 구현한다는 사실을 확인할 수 있다. 따라서, 실제 피부에 도포시 피부골 사이로 오염물질이 부착되는 것을 막을 수 있다. Referring to Figure 1a, 1b, 2a and 2b, when the cosmetic composition of Example 1 is applied, compared to the surface coated with the cosmetic composition of Comparative Example 1, the bones of the artificial leather more closely filled to realize a uniform and smooth cosmetic film You can see that. Therefore, it is possible to prevent contaminants from adhering between the skin bones when applied to the actual skin.
또한, 도 3a 및 3b를 참조하면, 실시예 1의 화장료 조성물을 도포한 경우, 비교예 1의 화장료 조성물을 도포한 표면에 비하여, 피부 표면에 미세 돌기를 다수 형성하였다는 사실을 확인할 수 있다. 따라서, 편평한 면에 비하여 미세먼지가 부착되는 것 자체를 방지할 수 있다. 3A and 3B, when the cosmetic composition of Example 1 is applied, it can be confirmed that a large number of fine protrusions are formed on the surface of the skin as compared to the surface on which the cosmetic composition of Comparative Example 1 is applied. Therefore, it is possible to prevent the fine dust from adhering to the flat surface itself.
실험예 2 - 미세먼지 부착 방지 효과 평가Experimental Example 2-Evaluation of the prevention effect of fine dust
슬라이드 글라스에 하얀색 인조피혁을 양면 테이프로 붙이고, 하기 표 3의 함량에 따라 인공 피지 또는 화장료 조성물을 스페츌라로 고르게 펴발라 피부 모사 시험체를 준비하였다. White artificial leather was attached to the slide glass with a double-sided tape, and according to the content of Table 3 below, evenly spreading the artificial sebum or cosmetic composition with a spatula to prepare a skin replica test body.
미세먼지 대류 박스(75 cm X 75 cm X 100 cm) 내부에 상기 인조 피혁을 넣고, 카본블랙 0.5 g을 칭량하여 대류박스에 투입하여 10분간 대류를 실시하였다. 그 후, 샘플을 꺼내어 표면 블로잉(blowing)하고, 대류 시험 전, 후 상태를 비교하였다. The artificial leather was placed in a fine dust convection box (75 cm X 75
도 4b를 참조하면, 오일(피지모사)만 도포한 인조 피혁의 경우, 육안으로 카본 블랙이 달라붙는 것을 확인할 수 있다. 또한, 비교예 1 및 2의 화장료 조성물을 도포한 인조 피혁도 마찬가지로 큰 차이가 없는 것을 확인할 수 있다. 반면, 실시예 1의 화장료 조성물을 도포한 도 4a는 육안상으로 검은 부분이 거의 없음을 확인할 수 있다. 흑백 도면 상에서는 구별이 쉽지 않으나, 이미지 분석하여, 흰색과 검은색 영역을 비교한 확인 결과, 실시예 1의 화장료 조성물을 도포한 도 4a의 흰색의 intensity 값이 오일만 도포한 도 4b와 비교하여, 더 높아 카본블랙의 부착이 30% 감소하는 것을 확인할 수 있었다. Referring to FIG. 4B, in the case of artificial leather coated only with oil (sebum), it can be seen that carbon black adheres to the naked eye. Moreover, the artificial leather which apply | coated the cosmetic composition of Comparative Examples 1 and 2 can also confirm that there is no big difference similarly. On the other hand, Figure 4a applying the cosmetic composition of Example 1 can be seen that there is almost no black portion on the naked eye. On the black and white drawings, it is not easy to distinguish, but the image analysis, comparing the white and the black area, and as a result, the intensity value of the white of FIG. 4A to which the cosmetic composition of Example 1 is applied is compared with FIG. Higher carbon black adhesion was found to be reduced by 30%.
Claims (13)
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| KR1020170041950A KR102262308B1 (en) | 2017-03-31 | 2017-03-31 | Anti-pollution cosmetic composition comprising spherical powder |
| KR10-2017-0041950 | 2017-03-31 |
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| EP3981382A4 (en) * | 2019-06-06 | 2023-07-12 | Kao Corporation | METHOD FOR PREVENTING THE ADHESION OF AN ATMOSPHERIC TOXIC SUBSTANCE |
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| KR102127053B1 (en) | 2018-12-17 | 2020-06-25 | 한국세라믹기술원 | Preparation method for cosmetic composition comprising surface modified TiO2 and ZnO for blocking particulate matter |
| KR102151859B1 (en) | 2018-12-17 | 2020-09-03 | 한국세라믹기술원 | Preparation method for cosmetic composition comprising surface modified TiO2 and ZnO for cleaning particulate matter |
| KR102145941B1 (en) * | 2019-09-05 | 2020-08-19 | 주식회사 코스메카코리아 | cosmetic composition for preventing adhesion of particulated matter comprising marine derived materials powder |
| KR102462752B1 (en) * | 2020-07-22 | 2022-11-04 | 주식회사 코스메카코리아 | cosmetic composition for preventing adhesion of particulated matter comprising polyurethane dispersion solution |
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| KR20180111261A (en) | 2018-10-11 |
| TWI751317B (en) | 2022-01-01 |
| KR102262308B1 (en) | 2021-06-09 |
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