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WO2018180514A1 - Composition de coloration capillaire - Google Patents

Composition de coloration capillaire Download PDF

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Publication number
WO2018180514A1
WO2018180514A1 PCT/JP2018/010098 JP2018010098W WO2018180514A1 WO 2018180514 A1 WO2018180514 A1 WO 2018180514A1 JP 2018010098 W JP2018010098 W JP 2018010098W WO 2018180514 A1 WO2018180514 A1 WO 2018180514A1
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WO
WIPO (PCT)
Prior art keywords
mass
hair
component
dye composition
hair dye
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2018/010098
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English (en)
Japanese (ja)
Inventor
長尾久美子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mandom Corp
Original Assignee
Mandom Corp
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Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=63677850&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2018180514(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Mandom Corp filed Critical Mandom Corp
Priority to JP2019509233A priority Critical patent/JP6719656B2/ja
Priority to KR1020197003415A priority patent/KR102131660B1/ko
Priority to CN201880003076.6A priority patent/CN109562039B/zh
Publication of WO2018180514A1 publication Critical patent/WO2018180514A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/432—Direct dyes

Definitions

  • the present invention relates to a hair dye composition.
  • This application claims the priority of Japanese Patent Application No. 2017-066452 for which it applied to Japan on March 29, 2017, and uses the content here.
  • an oxidation hair dye composed of a first agent containing an alkaline agent and an oxidation hair dye and a second agent containing hydrogen peroxide has been widely used. Yes.
  • these oxidative hair dyes exhibit an excellent dyeing effect and can be dyed to the desired hair color, but have the drawback that damage to the hair and scalp may occur.
  • the medicine since the medicine must be kept on the hair at the time of treatment and left for a long period of time, it is not only very troublesome when performing the treatment by itself, but also has the disadvantage that an irritating odor or skin irritation of the alkaline agent occurs. There is.
  • depending on the method of treatment there is a disadvantage that uneven dyeing occurs and it is difficult to dye uniformly.
  • hair dyes using basic dyes or HC dyes are known as treatment agents with little damage to hair and scalp.
  • color shampoo that can dye hair at the same time as shampoo at the time of hair washing, rinsing after hair washing, color rinse or color treatment that can dye hair at the same time as treatment are excellent in convenience, Furthermore, there is an advantage that the uniformity of dyeing is also excellent (see Patent Document 1).
  • the above-mentioned conventional hair dyes have a high dyeing property on the skin, i.e., they tend to color the skin when attached to the skin, especially in the case of color shampoos, color rinses and color treatments.
  • the dye concentration in the hair dye is lowered, the dyeability to hair is lowered.
  • the present condition is that the hair dye with high dyeing
  • the present invention has been made in view of the above prior art, and an object of the present invention is to provide a hair dye composition in which the dyeability to the skin is suppressed despite having sufficient dyeability for hair. Is to provide.
  • component A HC blue 16
  • component B one or more dyes selected from the group consisting of basic tea 16 and basic tea 17
  • component C HC
  • it has a sufficient dyeing property on the hair, even though it has sufficient dyeability. It was found that a hair dye composition having a suppressed dyeing property can be obtained.
  • the present invention has been completed based on these findings.
  • this invention provides the hair dye composition containing the following component A, the following component B, the following component C, and the following component D.
  • Component A HC Blue 16
  • Component B One or more dyes selected from the group consisting of basic tea 16 and basic tea 17
  • Component C One or more dyes selected from the group consisting of HC Yellow 4 and HC Yellow 2
  • Component D HC Blue 2
  • the content of Component A is preferably 0.05 to 3.0% by mass
  • the content of Component B is preferably 0.05 to 1.0% by mass
  • the content of Component C is Is preferably 0.01 to 0.5% by mass
  • the content of Component D is preferably 0.1 to 1.5% by mass.
  • the content of the HC yellow 2 in 100% by mass of the component C is preferably 50.0% by mass or more.
  • the hair dye composition is preferably a color rinse or a color treatment.
  • the hair dye composition preferably further contains the following component E.
  • Component E one or more components selected from the group consisting of cationic surfactants, cationic polymers, and silicone oils
  • the hair dye composition of the present invention has a sufficiently excellent hair dyeability. For this reason, when used as a color shampoo, color rinse or color treatment, the hair dyeing effect can be sufficiently exerted by a small number of uses. In addition, when used as a hair manicure, a sufficient dyeing effect can be obtained with a relatively short treatment time. Furthermore, the hair dye composition of the present invention has a low dyeing property to the skin and extremely little coloring of fingers and scalp during use.
  • the hair dye composition of the present invention is a composition used as a hair dye.
  • the hair dye include color rinse, color treatment, hair manicure, color shampoo and the like.
  • the hair dye composition of the present invention can be used for color rinsing, color treatment, or color shampoo from the viewpoint that hair can be easily dyed and the treatment time per time is short. Preferably there is.
  • the hair dye composition of the present invention is HC Blue 16, one or more dyes selected from the group consisting of basic tea 16 and basic tea 17, and one or more selected from the group consisting of HC Yellow 4 and HC Yellow 2. And at least HC Blue 2.
  • the “HC blue 16” may be referred to as “component A”.
  • the “one or more dyes selected from the group consisting of basic tea 16 and basic tea 17” may be referred to as “component B”.
  • the “one or more dyes selected from the group consisting of HC Yellow 4 and HC Yellow 2” may be referred to as “Component C”.
  • the “HC blue 2” may be referred to as “component D”.
  • the hair dye composition of the present invention contains at least Component A, Component B, Component C, and Component D.
  • the hair dye composition of the present invention may further contain components other than the above components A to D, which are essential components, depending on the application.
  • the hair dye composition of the present invention is further selected from the group consisting of a cationic surfactant, a cationic polymer, and a silicone oil. It is preferable to include one or more components.
  • the “one or more components selected from the group consisting of a cationic surfactant, a cationic polymer, and a silicone oil” may be referred to as “component E”.
  • the hair dye composition of the present invention may further contain components other than A to E (other components).
  • components other than A to E other components.
  • component A, component B, component C, component D, component E, and another component only 1 type may respectively be used and 2 or more types may be used.
  • Component A is HC Blue 16 and is a dye represented by the following formula (1).
  • Ingredient A has very low dyeability to the skin, although it is very excellent in dyeability to hair. For this reason, by using Component A, it is possible to obtain a hair dye composition that achieves both high dyeability on hair and inhibition of dyeing on the skin.
  • Component A has the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Volume 1, 2014, p. 1449): HC BLUE NO. 16, 1-propanaminium, 3-[[9,10-dihydro-4- (methylamino) -9,10-dioxo-1-anthracenyl] amino] -N, N-dimethyl -N-propyl-, bromide: 1-propanamine, 3-[[9,10-dihydro-4- (methylamino) -9,10-dioxo-1-anthracenyl] amino] -N, N-dimethyl-N-propyl -, Bromide.
  • Component A can be a commercially available product.
  • the product name "HC Blue No. 16" by the Altec Chemical company is mentioned, for example.
  • the content of Component A in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 0.05 to 3.0% by mass, more preferably 0.2 to 2.0% by mass, More preferably, it is 0.5 to 1.0% by mass. It is preferable for the content to be 0.05% by mass or more because the dyeing property for hair, particularly the effect of dyeing gray hair, is further improved. It is preferable for the content to be 3.0% by mass or less because safety is further improved. Moreover, since the color transfer to the towel, clothes, etc. by the dye which melt
  • Component B one or more dyes selected from the group consisting of basic tea 16 and basic tea 17
  • Component B is one or more dyes (at least one dye) selected from the group consisting of basic tea 16 and basic tea 17, that is, basic tea 16 and / or basic tea 17.
  • the basic tea 16 is a compound represented by an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th edition, Volume 1, 2014, p.
  • BASIC BROWN 16 Base Brown 16
  • the basic tea 17 is a compound represented by an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th edition, Volume 1, 2014, p.
  • BASIC BROWN 17 (Basic Brown 17), [ 8-[(4-Amino-3-nitrophenyl) azo] -7-hydroxy-2-naphthyl] trimethylammonium chloride: [8-[(4-Amino-3-nitrophenyl) azo] -7-hydroxy-2- naphthyl] trimethylammonium chloride.
  • component B only 1 type may be used and 2 or more types may be used.
  • Component B can be a commercially available product.
  • basic tea 16 for example, Sensitive Technologies Japan Co., Ltd. product name “ARIANOR MAHOGANY”; Hodogaya Chemical Co., Ltd. product name “AHC BROWN SP” can be mentioned.
  • ARIANOR SIENNA BROWN the product name "ARIANOR SIENNA BROWN” by Sensitive Technologies Japan Co., Ltd. is mentioned, for example.
  • the content of component B in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 0.05 to 1.0% by mass, more preferably 0.1 to 0.5% by mass. is there. It is preferable for the content to be 0.05% by mass or more because the dyeing property for hair, particularly the effect of dyeing gray hair, is further improved. It is preferable for the content to be 1.0% by mass or less because safety is further improved. Moreover, since the color transfer to the towel, clothes, etc. by the dye which melt
  • Component C One or more dyes selected from the group consisting of HC Yellow 4 and HC Yellow 2
  • Component C is one or more dyes (at least one dye) selected from the group consisting of HC Yellow 4 and HC Yellow 2, ie, HC Yellow 4 and / or HC Yellow 2.
  • the HC yellow 4 is an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th edition, Volume 1, 2014, p. 1455): HC YELLOW NO. 4-[[2- (2-hydroxyethoxy) -4-nitrophenyl] amino] ethanol: 2-[[2- (2-hydroxyethoxy) -4-nitrophenyl] amino] ethanol It is.
  • HC Yellow 2 is an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th edition, Volume 1, 2014, p. 1455): HC YELLOW NO. 2-[(2-Nitrophenyl) amino] ethanol: 2-[(2-Nitrophenyl) amino] ethanol.
  • component C only 1 type may be used and 2 or more types may be used.
  • Component C can be a commercially available product.
  • HC Yellow 4 for example, a trade name “COLOREX HCY4” manufactured by Telka Co., Ltd. may be mentioned.
  • HC Yellow 2 for example, a trade name “COLOREX HCY2” manufactured by Telka Co., Ltd. may be mentioned.
  • the content of component C in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 0.01 to 0.5% by mass, more preferably 0.01 to 0.2% by mass, More preferably, it is 0.02 to 0.1% by mass. It is preferable that the content is 0.01% by mass or more because fastness is further improved. It is preferable for the content to be 0.5% by mass or less because safety is further improved. Moreover, since the color transfer to the towel, clothes, etc. by the dye which melt
  • Component C is more preferable from the viewpoint of more excellent light resistance (light stability). That is, Component C preferably contains HC Yellow 2 as an essential component, and more preferably HC Yellow 2.
  • the content of HC Yellow 2 in 100% by mass of component C is preferably 50.0% by mass or more (that is, 50.0 to 100% by mass), more preferably 70.0% by mass or more, and still more preferably 90.0%. It is at least mass%.
  • component C consists solely of HC Yellow 2. It is preferable that Component C contains HC Yellow 2 as an essential component because yellow fading is further suppressed. In particular, in the case of a hair dye that has a gray color and is prepared using a yellow dye, the color change of the entire hair dye is large due to fading of the yellow component. It is valid.
  • Component D is HC Blue 2.
  • the HC Blue 2 is an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th edition, Volume 1, 2014, p. 1447): HC BLUE NO. 2,2 ′-[[4-[(2-hydroxyethyl) amino] -3-nitrophenyl] imino] bisethanol: 2,2 ′-[[4-[(2 -Hydroxyethyl) amino] -3-nitrophenyl] imino] bisethanol.
  • Component D can be a commercially available product.
  • the Telka company make and the brand name "COLOREX HCB2" are mentioned, for example.
  • the content of Component D in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 0.1 to 1.5% by mass, more preferably 0.2 to 1.5% by mass, More preferably, it is 0.5 to 1.0% by mass. It is preferable that the content is 0.1% by mass or more because fastness is further improved. Furthermore, since the dyeing speed can be adjusted appropriately by combining Component A and Component D as a blue dye, uneven dyeing with respect to damaged hair (for example, bleached hair) is less likely to occur. This is presumed to be due to the following reason.
  • component A Since component A is cationic, it has a fast dyeing speed and is excellent in fastness, but has a characteristic that it easily adsorbs to damaged hair and damaged sites and easily causes uneven dyeing.
  • component D since component D is nonionic, it has the property of being easily adsorbed uniformly regardless of the presence or absence of damage. It is preferable for the content to be 1.5% by mass or less because safety is further improved. Moreover, since the color transfer to the towel, clothes, etc. by the dye which melt
  • the hair dye composition of the present invention is classified into a total amount of component A and component B classified as basic dyes and HC dyes from the viewpoint of reducing color unevenness with respect to damaged hair such as bleached hair.
  • the total mass ratio of component C and component D [ ⁇ (content of component A) + (content of component B) ⁇ / ⁇ (content of component C) + (content of component D) ⁇ ]
  • it is preferably 0.1 to 10.0, and more preferably 0.5 to 5.0.
  • the hair dye composition of the present invention is any of color rinse, color treatment, and hair nail polish will be described.
  • Component E one or more components selected from the group consisting of cationic surfactants, cationic polymers, and silicone oils
  • the hair dye composition of the present invention preferably includes Component E.
  • Component E is one or more components (at least one component) selected from the group consisting of cationic surfactants, cationic polymers, and silicone oils.
  • component E is included, the effect of reducing the squeaky feeling during washing with the hair dye composition is preferred.
  • the component E only 1 type may be used and 2 or more types may be used.
  • Examples of the cationic surfactant include monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, trialkyl quaternary ammonium salts, monoalkyl ether quaternary ammonium salts, and alkyls. Examples include amines and fatty acid amidoamines.
  • Examples of the monoalkyl quaternary ammonium salt include lauryltrimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl (16,18) trimethylammonium chloride, Examples thereof include alkyl (20-22) trimethylammonium chloride, stearyldimethylbenzylammonium chloride, myristyldimethylbenzylammonium chloride, tri (polyoxyethylene) stearylammonium chloride, and di (polyoxyethylene) oleylmethylammonium chloride.
  • fatty acid amide amine examples include myristic acid dimethylaminoethylamide, myristic acid dimethylaminopropylamide, myristic acid diethylaminoethylamide, myristic acid diethylaminopropylamide, palmitic acid dimethylaminoethylamide, palmitic acid dimethylaminopropylamide, and palmitic acid.
  • the fatty acid amidoamine is preferably used as a salt with an organic acid and / or an inorganic acid.
  • the organic acid include lactic acid, malic acid, citric acid, tartaric acid, and acetic acid.
  • the inorganic acid include phosphoric acid, hydrochloric acid, sulfuric acid and the like. Of these, lactic acid is preferred.
  • the content of the organic acid and the inorganic acid is not particularly limited as long as it can neutralize the fatty acid amidoamine to be blended.
  • cationic surfactants monoalkyl quaternary ammonium salts and fatty acid amidoamines are preferable, and stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, and alkyl (16,18) trimethyl chloride are more preferable.
  • cationic polymer examples include quaternary nitrogen-containing cellulose ether derivatives such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl chloride chloride; O- [2-hydroxy chloride] Quaternary nitrogen-containing guar gum derivatives such as -3- (trimethylammonio) propyl] guar gum; cationic starch, diallyl quaternary ammonium salt polymer, diallyl quaternary ammonium salt / acrylamide copolymer, quaternization Examples thereof include polyvinylpyrrolidone derivatives, polyglycol polyamine condensates, adipic acid / dimethylaminohydroxypropylethylenetriamine copolymer, and cationized dextran.
  • quaternary nitrogen-containing cellulose ether derivatives such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl chloride chloride
  • O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride, diallyl quaternary ammonium salt polymer, diallyl quaternary ammonium salt / acrylamide copolymer are preferable, and more preferable.
  • Polydimethylmethylenepiperidinium chloride is preferable, and more preferable.
  • silicone oil examples include, for example, methyl polysiloxane, highly polymerized methyl polysiloxane having an average degree of polymerization of 650 to 7000, chain silicone such as methyl phenyl polysiloxane, methyl hydrogen polysiloxane, and dimethiconol; methyl cyclopolysiloxane, Cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane; aminopropylmethylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylmethyl Amino-modified silicone such as siloxane / dimethylsiloxane copolymer, carboxy-modified silicone, fatty acid-modified silicone, alcohol-modified
  • the content of component E in 100% by weight of the hair dye composition of the present invention is not particularly limited, but is preferably 0.5 to 10.0% by weight. More preferably, the content is 1.0 to 5.0% by mass. It is preferable for the content to be 0.5% by mass or more since the squeaky feeling is further reduced during washing with water. When the content exceeds 10.0% by mass, the component E is accumulated in the hair by continuous use, and the hair may become stiff. Content of the said component E is a total amount of content of all the components E in the hair dye composition of this invention.
  • the hair dye composition of the present invention preferably contains a polyhydric alcohol.
  • the polyhydric alcohol include ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, and mannitol. Sorbitol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol and the like.
  • the content of the polyhydric alcohol in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 0.5 to 10.0% by mass, more preferably 1 from the viewpoint of dye solubility. 0.0 to 5.0% by mass.
  • the content of the polyhydric alcohol is the total content of all the polyhydric alcohols in the hair dye composition of the present invention.
  • the hair dye composition of the present invention preferably contains a higher alcohol.
  • the higher alcohol include alcohols having 16 to 22 carbon atoms, such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, and behenyl alcohol.
  • the content of the higher alcohol in 100% by mass of the hair dye composition of the present invention is not particularly limited, but from the viewpoint of stability over time, 1.
  • the content is preferably 0 to 10.0% by mass, more preferably 3.0 to 8.0% by mass.
  • the content of the higher alcohol is the total content of all the higher alcohols in the hair dye composition of the present invention.
  • the hair dye composition of the present invention preferably contains a hydrocarbon oil.
  • the hydrocarbon oil include ⁇ -olefin oligomer, light isoparaffin, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, liquid isoparaffin, liquid paraffin and the like.
  • the content of the hydrocarbon oil in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is familiar to the hair dye composition at the time of application. From the viewpoint of ease, 0.5 to 10.0% by mass is preferable, and 1.0 to 5.0% by mass is more preferable.
  • the content of the hydrocarbon oil is a total content of all the hydrocarbon oils in the hair dye composition of the present invention.
  • the hair dye composition of the present invention may contain an ester compound in which the fatty acid moiety has 12 or less carbon atoms from the viewpoint of further improving the dyeability of the hair.
  • the ester compound include capric acid esters such as glyceryl caprate, caprylic acid ester, cetyl 2-ethylhexanoate, and isononyl isononanoate.
  • the content of the ester compound in 100% by mass of the hair dye composition of the present invention is not particularly limited, but from the viewpoint of dyeability, it is 0.5.
  • the content is preferably -5.0 mass%, more preferably 1.0-3.0 mass%.
  • Content of the said ester compound is a total amount of content of all the said ester compounds in the hair dye composition of this invention.
  • the hair dye composition of the present invention is any one of color rinse, color treatment, and hair nail polish
  • the hair dye composition of the present invention is a nonionic surfactant (nonion) from the viewpoint of stability over time. (Surfactant) may be included.
  • nonionic surfactant examples include polyoxyethylene fatty acid, glycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, polyoxy Examples include ethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyglycerin alkyl ether, polyoxyethylene (cured) castor oil, and fatty acid alkylolamide.
  • the content of the nonionic surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is stable over time. In view of the above, 0.5 to 10.0% by mass is preferable, and 1.0 to 5.0% by mass is more preferable.
  • the content of the nonionic surfactant is the total content of all the nonionic surfactants in the hair dye composition of the present invention.
  • the hair dye composition of the present invention contains water.
  • the water is not particularly limited, but purified water is preferable.
  • the content of water in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 50.0-90.0% by mass, more preferably 60.0-80.0% by mass. .
  • the hair dye composition of the present invention is any one of color rinse, color treatment, and hair nail polish
  • the hair dye composition of the present invention is a refreshing agent such as l-menthol, 1,8-cineole, camphor, etc.
  • Preservatives such as phenoxyethanol; vegetable oils such as olive oil, macadamia nut oil, and argan oil; hygroscopic agents such as silica; hyaluronic acid or derivatives thereof, collagen or derivatives thereof, amino acids or derivatives thereof, antioxidants, sequestering agents, vitamins , Extracts of animals and plants, pearling agents, coloring agents, fragrances and the like may be included.
  • the hair dye composition of the present invention is a color shampoo
  • the hair dye composition of the present invention is a color shampoo
  • the hair dye composition of the present invention is an anionic surfactant (anionic surfactant), a cationic surfactant, a nonionic interface from the viewpoint of detergency.
  • 1 or more surfactants (at least 1 surfactant) chosen from the group which consists of an active agent and an amphoteric surfactant are included.
  • nonionic surfactants and / or amphoteric surfactants are preferable from the viewpoint of improving the washability while maintaining dyeability.
  • the content of the surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 1.0 to 20.0% by mass, more preferably from the viewpoint of dyeability and detergency. 5.0 to 15.0% by mass.
  • the content of the surfactant is the total content of all the surfactants in the hair dye composition of the present invention.
  • anionic surfactant examples include alkyl sulfate salts such as sodium lauryl sulfate, triethanolamine lauryl sulfate, sodium myristyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate, sodium cetyl sulfate; sodium polyoxyethylene lauryl ether sulfate Polyoxyethylene alkyl ether sulfates such as sodium polyoxyethylene myristyl sulfate; ⁇ -olefin sulfonates such as sodium tetradecenesulfonate; sodium myristoyl methyl taurate, sodium palmitoyl methyl taurine, sodium stearoyl methyl taurine, oleoyl methyl N-acylmethyl taurine salts such as taurine sodium and palm oil fatty acid methyl taurine sodium; Sulfosuccinic acid alkyl salts such as dioctyl sodium and disodium sulf
  • anionic surfactants derived from amino acids such as N-acyl-N-methyl- ⁇ -alanine salt and N-acyl glutamate are preferred from the viewpoint of dyeability.
  • the content of the anionic surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited. In view of the above, 0.5 to 5.0% by mass is preferable, and 0.5 to 2.0% by mass is more preferable.
  • the content of the anionic surfactant is the total content of all anionic surfactants in the hair dye composition of the present invention.
  • amphoteric surfactant examples include alkylamide betaine type amphoteric surfactants such as lauric acid amidopropyl betaine and coconut oil fatty acid amidopropyl betaine; alkylglycine salt, carboxymethylglycine salt, N-acylaminoethyl-N- Glycine-type amphoteric surfactants such as 2-hydroxyethylglycine salt; Aminopropionic acid-type amphoteric surfactants such as alkylaminopropionate and alkyliminodipropionate; alkyldimethylaminoacetic acid betaine, alkylamidopropyldimethylaminoacetic acid Aminoacetic acid betaine-type amphoteric surfactants such as betaine and alkyldihydroxyethylaminoacetic acid betaine; N-alkyl-N, N-dimethylammonium-N-propylsulfonate, N-alkyl-N, N-di
  • alkylamide betaine type amphoteric surfactants are preferable from the viewpoint of detergency.
  • the content of the amphoteric surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited, but from the viewpoint of detergency, 1 It is preferably 0.0 to 20.0% by mass, more preferably 5.0 to 15.0% by mass.
  • the content of the amphoteric surfactant is the total content of all amphoteric surfactants in the hair dye composition of the present invention.
  • nonionic surfactant examples include nonionic surfactants exemplified as optional components when the hair dye composition of the present invention is any one of color rinse, color treatment, and hair nail polish.
  • fatty acid alkylolamide is preferable from the viewpoint of imparting viscosity.
  • the content of the nonionic surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited, but it is a viewpoint of imparting viscosity. Therefore, 0.5 to 10.0% by mass is preferable, and 1.0 to 5.0% by mass is more preferable.
  • the content of the nonionic surfactant is the total content of all the nonionic surfactants in the hair dye composition of the present invention.
  • the cationic surfactant examples include the cationic surfactants exemplified as Component E. Of these, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl (16,18) trimethylammonium chloride, and alkyl (20-22) trimethylammonium chloride are preferable from the viewpoint of improving the texture of the hair after use.
  • the hair dye composition of the present invention contains a cationic surfactant
  • the content of the cationic surfactant in 100% by mass of the hair dye composition of the present invention is not particularly limited. From the viewpoint of texture, it is preferably 0.1 to 5.0% by mass, more preferably 0.5 to 3.0% by mass.
  • the content of the cationic surfactant is the total content of all the cationic surfactants in the hair dye composition of the present invention.
  • the hair dye composition of the present invention contains water.
  • the water is not particularly limited, but purified water is preferable.
  • the content of water in 100% by mass of the hair dye composition of the present invention is not particularly limited, but is preferably 50.0-90.0% by mass, more preferably 60.0-80.0% by mass. .
  • the hair dye composition of the present invention comprises a refreshing agent such as l-menthol, 1,8-cineole and camphor; a preservative such as phenoxyethanol; olive oil, macadamia nut oil, Vegetable oils such as argan oil; hygroscopic agents such as silica; hyaluronic acid or derivatives thereof, collagen or derivatives thereof, amino acids or derivatives thereof, antioxidants, sequestering agents, vitamins, animal and plant extracts, pearling agents, coloring agents, It may contain a fragrance or the like.
  • a refreshing agent such as l-menthol, 1,8-cineole and camphor
  • a preservative such as phenoxyethanol
  • olive oil, macadamia nut oil, Vegetable oils such as argan oil
  • hygroscopic agents such as silica
  • hyaluronic acid or derivatives thereof collagen or derivatives thereof, amino acids or derivatives thereof, antioxidants, sequestering agents, vitamins, animal and plant extracts, pearl
  • the method for producing the hair dye composition of the present invention is not particularly limited, and can be produced according to a conventional method. Specific examples include the following methods. For example, in the case of color rinse or color treatment, gradually add an oil phase heated to 70-90 ° C. to an aqueous phase sufficiently heated to 70-90 ° C. and stir well for 5 minutes to emulsify. Do. After emulsification, the mixture is cooled to 20 to 40 ° C., and a dye dissolved in purified water is added thereto. After sufficiently uniformly stirring, a pH adjuster is added and sufficiently uniformly stirred to obtain a creamy hair dye composition.
  • the pH of the hair dye composition of the present invention is not particularly limited, but is preferably 4.0 to 8.0, more preferably 5.0 to 8.0 from the viewpoint of dyeability. Furthermore, from the viewpoint of the stability of the hair dye composition, the pH is preferably 6.5 or less. In particular, when the hair dye composition of the present invention is a color rinse, color treatment or hair nail polish, the pH is preferably 4.0 to 6.5, and when it is a color shampoo, the pH is preferably 5.0 to 6.5.
  • the dosage form of the hair dye composition of the present invention is not particularly limited, and examples thereof include liquid, viscous liquid, gel, emulsion, and cream. Among these, cream is preferable from the viewpoint of dyeability and texture.
  • the hair dye composition of the present invention can dye hair in gray, black, brown, green, blue-violet, and the like. More preferably, they are gray, black, and brown. For this reason, it can be used as a hair dye composition for white hair dyeing, fashion dyeing and the like, and from the viewpoint of color tone, it is preferably a hair dye composition for dyeing white hair.
  • the hair dye composition of the present invention is preferably a color rinse or a color treatment, a hair manicure or a color shampoo.
  • the above color shampoo is a hair cleaning agent used for shampooing, and can dye hair simultaneously with shampooing.
  • the color shampoo is applied to the hair and foamed to wash the hair, and then used after washing.
  • the above-mentioned color rinse and color treatment are hair treatment agents that are generally used during shampooing and are used after being washed and washed off.
  • the color rinse and the color treatment are used in such a usage method that after washing the hair with a shampoo, the color rinse or the color treatment is applied to the hair, and immediately after the application or for 3 to 10 minutes, the hair is conditioned.
  • the color rinse and color treatment may be used before washing the hair.
  • the above-mentioned color rinse and color treatment are applied by applying the color rinse or color treatment to wet hair, immediately after application or after having been acclimated to the hair for about 3 to 10 minutes, and then washing with shampoo. Used in
  • the hair nail polish is a hair treatment agent that is generally applied to dry hair.
  • the hair nail polish is used, for example, by applying hair nail polish to dry hair, leaving it for about 5 to 30 minutes after application, washing it off, and washing it with shampoo.
  • the compounding amount described in the table is the compounding amount of each component (that is, the compounding amount of the active ingredient in each raw material, so-called pure content), and is represented by “mass%” unless otherwise specified.
  • the blending amounts of the polydimethylmethylenepiperidinium chloride liquid and the aminoethylaminopropylsiloxane / dimethylsiloxane copolymer emulsion in the table are shown in the blending amount of the product itself.
  • Examples 1-1 to 1-17, Comparative Examples 1-1 to 1-10 Color rinse (or color treatment) According to the composition described in the table, each hair dye composition was prepared and subjected to the following evaluation tests 1 to 7. Each hair dye composition is a color rinse (or color treatment). The evaluation results are shown in the table.
  • Examples 2-1 to 2-11, Comparative Examples 2-1 to 2-2 Color Shampoo Each hair dye composition was prepared according to the composition shown in the table and subjected to the evaluation tests of Tests 1 to 7 below. Each hair dye composition is a color shampoo. The evaluation results are shown in the table.
  • the pH of each hair dye composition of Examples and Comparative Examples was measured using a pH meter (trade name “desktop pH meter F-74” manufactured by Horiba, Ltd.).
  • Test hair bundle an untreated white human hair bundle (manufactured by Beaulux, length 10 cm, weight 1 g) was used.
  • the evaluation hair bundle obtained above was observed, and the dyeability was evaluated according to the following criteria.
  • the dyeability was evaluated by four expert evaluators. ⁇ Evaluation criteria for dyeability> (Excellent): It is dye
  • the coated part was observed and evaluated according to the following criteria. In addition, evaluation of skin dirt was performed by four expert evaluators. ⁇ Evaluation criteria for skin dirt> ⁇ (Excellent): No skin dirt remains. ⁇ (good): Skin dirt remains slightly. X (defect): Skin dirt remains clearly.
  • Test 3 Evaluation of fastness
  • each evaluation hair bundle was thoroughly washed with 40 ° C. lukewarm water, and then thoroughly washed with a commercially available shampoo for 1 minute. Further, it was thoroughly rinsed with warm water at 40 ° C., towel-dried, and then sufficiently dried using a dryer.
  • the evaluation hair bundle obtained above was observed, and the fastness was evaluated according to the following criteria.
  • the robustness was evaluated by four expert evaluators. ⁇ Evaluation criteria for robustness> ⁇ (Good): Hair color fading after test is small. X (defect): The color of the hair is greatly lost after the test.
  • Test 4 Evaluation of Suppression of Discoloration when Extending the Standing Time
  • the evaluation hair bundle prepared in Test 4 is compared with the dyed color tone of the evaluation hair bundle prepared in Test 1, and the degree of color change suppression when the standing time is extended is compared. Evaluation was made according to the following criteria. The evaluation was performed by four expert evaluators. ⁇ Evaluation criteria for discoloration suppression during extended standing time> ⁇ (Good): The color tone of the evaluation hair bundle prepared in Test 4 has no change from the color tone of the evaluation hair bundle prepared in Test 1. X (defect): The color tone of the evaluation hair bundle prepared in Test 4 varies from the color tone of the evaluation hair bundle prepared in Test 1.
  • Example 1-1, Examples 1-10 to 1-14, Example 2-1, Example 2-4, Example 2-8, Example 2-9, and Comparative Examples 1-6 to 1- 10 and Comparative Example 2-1 and Comparative Example 2-2 were subjected to the evaluation test of Test 5 below.
  • the evaluation hair bundle obtained above was observed, and the light resistance was evaluated according to the following criteria.
  • the light resistance was evaluated by four expert evaluators.
  • ⁇ Evaluation criteria for light resistance> ⁇ (Good): The color tone of the evaluation hair bundle prepared in Test 5 has no or almost no change from the color tone of the evaluation hair bundle prepared in Test 1.
  • Example 1-13 As a result of the test 5 (evaluation of light resistance), the light resistance of Example 1-13 was slightly poor ( ⁇ ). Examples 1-14, Example 2-4, Comparative Examples 1-6 to 1-10, In Comparative Example 2-2, the light resistance was poor (x). Other examples and comparative examples had good light resistance ( ⁇ ).
  • the evaluation hair bundle obtained above was observed, and compared with the evaluation hair bundle prepared in Test 1, the stability was evaluated according to the following criteria.
  • the stability was evaluated by four expert evaluators.
  • ⁇ Stability evaluation criteria> ⁇ (Good): The color tone of the evaluation hair bundle prepared in Test 6 has no change from the color tone of the evaluation hair bundle prepared in Test 1.
  • Example 2-6, Example 2-10, and Comparative Example 1-8 have poor stability (x), and other examples and comparative examples have stability.
  • Example 1-1, Example 1-7, Example 2-1 and Example 2-11 were subjected to the evaluation test of Test 7 below.
  • Example 1-1 and Example 2-1 have good color unevenness with respect to damaged hair (O), and Examples 1-7 and Example 2-11 have poor color unevenness with respect to damaged hair (X). Met.
  • HC Blue 16 Product name “HC Blue No. 16”, manufactured by Altec Chemical Basic Blue 75: Hodogaya Chemical Co., Ltd., trade name “AHC BLUE SP” Basic tea 16: manufactured by Hodogaya Chemical Co., Ltd., trade name “AHC BROWN SP” Basic tea 17: manufactured by Sensitive Technologies Japan, Inc., trade name "ARIANOR SIENNA BROWN” HC Yellow 4: Made by Telka, trade name “COLOREX HCY4” HC Yellow 2: Made by Telka, trade name “COLOREX HCY2” HC Blue 2: Made by Telka, trade name “COLOREX HCB2” Alkyltrimethylammonium chloride: product name “GENAMIN KDMP-J” manufactured by Clariant Japan KK Stearyltrimethylammonium chloride: product name “Cootamine 86W” manufactured by Kao Corporation Polyoxyethylene cetyl ether (5EO): Aoki Yushi Kogyo
  • the hair dye composition of the present invention is a composition used as a hair dye.
  • the hair dye include color rinse, color treatment, hair manicure, color shampoo and the like.

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  • Life Sciences & Earth Sciences (AREA)
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Abstract

L'invention concerne une composition de coloration capillaire qui supprime l'affinité de coloration avec la peau, en dépit d'une affinité de coloration suffisante avec les cheveux. Cette composition de coloration capillaire comprend : le composant A, à savoir le bleu HC 16; le composant B, à savoir au moins un colorant choisi dans le groupe constitué par le brun basique 16 et le brun basique 17; composant C, à savoir au moins un colorant choisi dans le groupe constitué par le jaune HC 4 et le jaune HC 2; et le composant D, à savoir le bleu HC 2. De préférence, la teneur en composant A est de 0,05 à 3,0 % en masse, la teneur en composant B est de 0,05 à 1,0 % en masse, la teneur en composant C est de 0,01 à 0,5 % en masse, et la teneur en composant D est de 0,1 à 1,5 % en masse.
PCT/JP2018/010098 2017-03-29 2018-03-15 Composition de coloration capillaire Ceased WO2018180514A1 (fr)

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WO2024202359A1 (fr) * 2023-03-24 2024-10-03 株式会社ピュール Composition de shampooing colorant de type aérosol

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JP2014101292A (ja) * 2012-11-16 2014-06-05 Hoyu Co Ltd 染毛料組成物
JP2016501207A (ja) * 2012-11-30 2016-01-18 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンＨｅｎｋｅｌ ＡＧ ＆ Ｃｏ．ＫＧａＡ 特定のカチオン性染料、界面活性剤およびポリマーを含有する染料光沢剤

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JP2015140326A (ja) * 2014-01-30 2015-08-03 日本精化株式会社 染色した毛髪の褪色防止剤及びこれを用いた褪色防止方法
EP2979683B1 (fr) * 2014-07-30 2019-07-24 HCT - Hair Cosmetic Technology AG Colorants permanents pour cheveux basés sur un support de type crémeux et une combinaison de tris(hydroxyméthyl)aminomethane, au moins un acide aminé et une teinture oxydative
JP5817085B1 (ja) * 2015-01-09 2015-11-18 学校法人神奈川大学 染毛剤組成物
JP2016216431A (ja) * 2015-05-26 2016-12-22 ホーユー株式会社 毛髪化粧料組成物
JP2017031085A (ja) * 2015-07-31 2017-02-09 株式会社Ｂｅｒｒｙ２ 毛髪明度向上剤及び該毛髪明度向上剤を使用する毛髪色彩調整剤並びに毛髪の明度向上方法及び毛髪の色彩調整方法
JP6579870B2 (ja) * 2015-09-03 2019-09-25 株式会社 ナチュラル 染毛料の製造方法

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CA2613049A1 (fr) * 2007-11-30 2008-04-03 The Procter & Gamble Company Colorants pour fibres de keratine
JP2014101292A (ja) * 2012-11-16 2014-06-05 Hoyu Co Ltd 染毛料組成物
JP2016501207A (ja) * 2012-11-30 2016-01-18 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンＨｅｎｋｅｌ ＡＧ ＆ Ｃｏ．ＫＧａＡ 特定のカチオン性染料、界面活性剤およびポリマーを含有する染料光沢剤

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024202359A1 (fr) * 2023-03-24 2024-10-03 株式会社ピュール Composition de shampooing colorant de type aérosol
JP2024136384A (ja) * 2023-03-24 2024-10-04 株式会社ピュール エアゾール式カラーシャンプー組成物
JP7705665B2 (ja) 2023-03-24 2025-07-10 株式会社ピュール エアゾール式カラーシャンプー組成物

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JPWO2018180514A1 (ja) 2019-06-27
CN109562039B (zh) 2022-02-15

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