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WO2018179893A1 - Film optique, et panneau avant d'un dispositif d'affichage d'image, dispositif d'affichage d'image, miroir à fonction d'affichage d'image, panneau tactile résistif et panneau tactile capacitif comprenant chacun ledit film optique - Google Patents

Film optique, et panneau avant d'un dispositif d'affichage d'image, dispositif d'affichage d'image, miroir à fonction d'affichage d'image, panneau tactile résistif et panneau tactile capacitif comprenant chacun ledit film optique Download PDF

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Publication number
WO2018179893A1
WO2018179893A1 PCT/JP2018/004448 JP2018004448W WO2018179893A1 WO 2018179893 A1 WO2018179893 A1 WO 2018179893A1 JP 2018004448 W JP2018004448 W JP 2018004448W WO 2018179893 A1 WO2018179893 A1 WO 2018179893A1
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WO
WIPO (PCT)
Prior art keywords
layer
resin film
group
film
image display
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2018/004448
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English (en)
Japanese (ja)
Inventor
高 玉田
啓吾 植木
福重　裕一
高田　勝之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujifilm Corp
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Fujifilm Corp
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Publication date
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Priority to JP2019508699A priority Critical patent/JP6802361B2/ja
Publication of WO2018179893A1 publication Critical patent/WO2018179893A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11—Anti-reflection coatings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G—PHYSICS
    • G06—COMPUTING OR CALCULATING; COUNTING
    • G06F—ELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/02—Details

Definitions

  • the present invention relates to an optical film, a front plate of an image display device having the optical film, an image display device, a mirror with an image display function, a resistive touch panel, and a capacitive touch panel.
  • Patent Document 1 describes a liquid crystal display device having a polarizing plate having a polarizing film and a pair of protective films sandwiching the polarizing film, and a cellulose acylate film is used as the protective film.
  • Patent Document 1 this cellulose acylate film has excellent front and thickness direction retardation, is thin enough to be handled during manufacturing and processing, and has a small change in viewing angle characteristics. It is said that the device can be realized.
  • Patent Document 2 includes a base material and a hard coat layer laminated on at least one surface of the base material as a hard coat film in which the occurrence of color unevenness is suppressed, and retardation in the in-plane direction is provided.
  • the hard coat film which is 6000 nm or more and 40000 nm or less is described.
  • JP2011-221545A Japanese Patent Laid-Open No. 2016-164641
  • the surface of the front panel of the touch panel may be keyed on a daily basis with a stylus pen, when using a resin film for the front panel, etc. It is important that this resin film is sufficiently filled.
  • the keystroke durability can be improved by increasing the thickness of the resin film.
  • the smoothness decreases, deforms, or becomes difficult to peel off from the carrier during the production of the thick film resin film.
  • it takes a considerable amount of time to form a thick resin film and in particular, in the case of solution casting, the drying process for removing the residual solvent becomes longer, which is a problem of production efficiency. Will also occur.
  • the manufacturing suitability itself tends to be improved by adopting a method in which resin films are bonded together to produce a single thick optical film. It has been found that it is difficult to obtain a durable optical film, and as a new problem, it has been found that interference unevenness due to bonding of a resin film occurs.
  • the present invention has been made in view of the above problems, and an optical film in which unevenness of interference is sufficiently suppressed, excellent in keystroke durability, and excellent in manufacturing suitability, and a front plate of an image display apparatus having the same
  • Another object of the present invention is to provide an image display device, a mirror with an image display function, a resistive touch panel, and a capacitive touch panel.
  • the inventors of the present invention have a specific tensile elastic modulus as these resin films in producing a single thick optical film by bonding resin films together.
  • the bonding between the resin films is performed through an adhesive layer in which the difference in tensile elastic modulus and the difference in refractive index between each resin film are within a specific range, thereby making the keystroke durability. It has been found that an optical film having excellent properties and interference unevenness is sufficiently suppressed can be obtained.
  • the present invention has been further studied based on these findings and has been completed.
  • the tensile elastic modulus EA of the first resin film (A), the tensile elastic modulus EB of the adhesive layer (B), and the tensile elastic modulus EC of the second resin film (C) are represented by the following formulas (3) to (7 )The filling,
  • Ew Ew ⁇ ⁇ w ⁇ dw
  • Ew, ⁇ w, and dw are the elastic modulus in the MD direction after holding the resin film at 60 ° C. and 90% relative humidity for 48 hours, the absolute value of the dimensional change rate in the MD direction, and the film thickness, respectively.
  • [10] [1] A front plate of an image display device comprising the optical film according to any one of [9].
  • [11] [10]
  • An image display device comprising the front plate according to [10] and an image display element.
  • the image display device according to [11] wherein the image display element is a liquid crystal display element.
  • the image display element is an organic electroluminescence display element.
  • a numerical range expressed using “to” means a range including numerical values described before and after “to” as a lower limit value and an upper limit value.
  • “(meth) acrylate” is used to mean one or both of acrylate and methacrylate.
  • (meth) acryloyl group” is used to mean one or both of an acryloyl group and a methacryloyl group.
  • “(Meth) acryl” is used to mean one or both of acrylic and methacrylic.
  • Each component described in this specification may be used alone or in combination of two or more different structures. Moreover, content of each component means those total content, when using 2 or more types from which a structure differs.
  • the weight average molecular weight (Mw) can be measured as a molecular weight in terms of polystyrene by GPC unless otherwise specified.
  • GPC device HLC-8220 manufactured by Tosoh Corporation
  • G3000HXL + G2000HXL is used as the column
  • the flow rate is 1 mL / min at 23 ° C.
  • detection is performed by RI.
  • the eluent can be selected from THF (tetrahydrofuran), chloroform, NMP (N-methyl-2-pyrrolidone), m-cresol / chloroform (manufactured by Shonan Wako Pure Chemical Industries, Ltd.) and dissolves.
  • the optical film of the present invention can be suitably used as a front plate of a touch panel, and can also be suitably used as an optical film such as a polarizing film, a retardation film, and a brightness enhancement film for liquid crystal display.
  • the optical film of the present invention has sufficiently reduced interference unevenness, excellent keystroke durability, and excellent manufacturing suitability. Further, the front plate, the image display device, the mirror with an image display function, the resistive touch panel and the capacitive touch panel of the image display device of the present invention have the optical film of the present invention, and interference unevenness is sufficiently suppressed. In addition, it exhibits excellent keying durability and is excellent in manufacturing suitability.
  • FIG. 5 is a schematic diagram illustrating an intersection between a first electrode 11 and a second electrode 21 in FIG. 4.
  • FIG. 5 is a schematic diagram showing an embodiment of a first dummy electrode 11A that the first conductive layer 8 in the active area S1 in FIG. 4 may have.
  • FIG. 1 A preferred embodiment of the optical film of the present invention is shown in FIG.
  • the optical film 4A shown in FIG. 1 includes a first resin film (A), an adhesive layer (B) disposed on one side of the first resin film (A), and an adhesive layer (B) disposed on the adhesive layer (B). It is an optical film having at least the second resin film (C) (indicated by reference numerals 1A, 2A, 1B in order in FIG. 1).
  • the refractive index nA of the first resin film (A), the refractive index nB of the adhesive layer (B), and the refractive index nC of the second resin film (C) are expressed by the following formula (1) and Satisfy (2).
  • the refractive index means the refractive index at 25 ° C. of light having a wavelength of 589 nm.
  • the tensile modulus means a tensile modulus at 25 ° C.
  • the thickness of the optical film that is, the total thickness of the first resin film (A), the adhesive layer (B), and the second resin film (C) is greater than 100 ⁇ m.
  • the optical film of this invention can implement
  • the optical film of the present invention is considered to be able to effectively suppress interface reflection and suppress interference unevenness by setting the difference in refractive index between the adjacent resin film and the adhesive layer to a specific value or less. It is done. Furthermore, since the optical film of the present invention is a laminate, the thickness of each film can be suppressed, so that it is excellent in production suitability.
  • the resin film and the adhesive layer may be isotropic or anisotropic.
  • a refractive index and a tensile elasticity modulus are calculated by the method of the below-mentioned Example description.
  • the refractive index of the resin film can be changed, for example, depending on the type of resin constituting the resin film, and generally the refractive index tends to increase by increasing the molecular weight and / or crystallinity of the resin. Moreover, the resin film can raise the refractive index of the extending
  • the refractive index nA of the first resin film (A) and the refractive index nC of the second resin film (C) are each independently preferably 1.45 to 1.62, from the viewpoint of further suppressing interference unevenness. 1.47 to 1.60 are more preferable, and 1.48 to 1.59 are more preferable.
  • the refractive index of the adhesive layer (B) (hereinafter also simply referred to as “adhesive layer”) can be changed, for example, depending on the type of resin constituting the adhesive layer, and generally increases the molecular weight and crystallinity of the resin. Therefore, the refractive index tends to increase.
  • the refractive index can be adjusted by adding fine particles as a constituent component of the adhesive layer.
  • the refractive index nB of the adhesive layer (B) is preferably 1.45 to 1.62, more preferably 1.47 to 1.60, and further preferably 1.48 to 1.59 from the viewpoint of further suppressing interference unevenness. preferable.
  • the lower limit is not particularly limited and is 0.00 or more.
  • the absolute value is not described, the same applies to the case of 0.02 or less, more preferably 0.01 or less, from the viewpoint of further suppressing interference unevenness.
  • the lower limit is not particularly limited and is 0.00 or more.
  • the tensile elastic modulus of the resin film can be changed depending on, for example, the type of resin constituting the resin film. Generally, the tensile elastic modulus tends to increase by increasing the molecular weight and / or crystallinity of the resin. Moreover, the resin film can increase the tensile elastic modulus in the stretching direction by stretching. Also when a resin film consists of a multilayer, it means the tensile elasticity modulus as a resin film.
  • the tensile elastic modulus EA at 25 ° C. of the first resin film (A) and the tensile elastic modulus EC at 25 ° C. of the second resin film (C) are each independently 2.
  • 5 GPa or more is preferable, 3.0 GPa or more is more preferable, 3.5 GPa or more is more preferable, and 4.0 GPa or more is most preferable.
  • the upper limit is not particularly limited, but 12.0 GPa or less is practical.
  • the tensile elastic modulus of the adhesive layer (B) (hereinafter also simply referred to as “adhesive layer”) can be changed, for example, depending on the type of resin constituting the adhesive layer, and generally increases the molecular weight and crystallinity of the resin. This tends to increase the tensile modulus.
  • the adhesive layer has a crosslinkable group, the tensile modulus can be increased by improving the degree of crosslinking of the adhesive layer by adding a crosslinking agent or the like.
  • the adhesive layer contains a polymerizable composition
  • the polymerizable group equivalent of the compound having a polymerizable group (the value obtained by dividing the molecular weight of this compound by the total number of polymerizable groups contained in this compound) is reduced.
  • the tensile modulus tends to be increased by improving the polymerization rate of the adhesive layer, adding a highly elastic substance (such as inorganic particles) to the adhesive layer, or adding a compound containing a rigid molecular structure (such as an adamantane skeleton).
  • the tensile elastic modulus EB at 25 ° C.
  • the adhesive layer (B) is preferably 2.5 GPa or more, more preferably 3.0 GPa or more, more preferably 3.5 GPa or more, from the viewpoint of further improving the keystroke durability.
  • the above is more preferable, 4.5 GPa or more is particularly preferable, and 5.0 GPa or more is most preferable.
  • the upper limit is not particularly limited, but 12.0 GPa or less is practical.
  • the absolute value of the difference between the tensile elastic modulus EC at 25 ° C. of the second resin film (C) and the tensile elastic modulus EB at 25 ° C. of the adhesive layer (B) represented by the above formula (4) (
  • 0.5 GPa or less is more preferable, 2.0 GPa or less is more preferable, 1.5 GPa or less is particularly preferable, and 1.0 GPa or less is most preferable.
  • the optical film of the present invention has at least a three-layer structure in which a first resin film (A), an adhesive layer (B), and a second resin film (C) are laminated, and each resin film (A) and ( C) and the adhesive layer (B) may be a single layer or multiple layers.
  • the thickness of the optical film of the present invention is preferably 120 ⁇ m or more, more preferably 150 ⁇ m or more, further preferably 180 ⁇ m or more, and further preferably 200 ⁇ m or more.
  • the upper limit is practically 320 ⁇ m or less.
  • the thickness of the resin film is preferably independently from 50 to 160 ⁇ m, more preferably from 60 to 160 ⁇ m, still more preferably from 80 to 160 ⁇ m, and particularly preferably from 100 to 160 ⁇ m, from the viewpoint of keystroke durability and manufacturability.
  • the total thickness of the first resin film and the second resin film is preferably 100 to 320 ⁇ m, more preferably 160 to 320 ⁇ m, and even more preferably 200 to 320 ⁇ m from the viewpoint of keystroke durability.
  • the thickness of the adhesive layer is preferably 10 nm or more from the viewpoint of adhering the first resin film and the second resin film, more preferably from 10 nm to 10 ⁇ m, more preferably from 10 nm to 5 ⁇ m, from the viewpoint of suppressing interference unevenness. 1 ⁇ m is more preferable.
  • the retardation in the in-plane direction at a wavelength of 550 nm of the optical film is preferably smaller than 6000 nm, preferably 1000 nm or less, more preferably 500 nm or less, and even more preferably 50 nm or less from the viewpoint of reducing interference unevenness.
  • the retardation in the in-plane direction of the optical film means that the linearly polarized light is incident on the optical film and the light passing through the optical film is converted into two linearly polarized light along the fast axis and the slow axis.
  • R (unit: nm) represented by the following formula (A) from the refractive index Nx at the fast axis, the refractive index Ny at the slow axis, and the thickness d (unit: nm) of the optical film. ).
  • R d ⁇ (Nx ⁇ Ny) (A)
  • the retardation in the in-plane direction at a wavelength of 550 nm in the present invention and the specification is measured by making light having a wavelength of 550 nm incident in the normal direction of the film or layer to be measured in KOBRA 21ADH (manufactured by Oji Scientific Instruments). .
  • the wavelength selection filter can be exchanged manually, or the measurement value can be converted by a program or the like.
  • the in-plane retardation can also be measured using AxoScan (AXOMETRICS).
  • Resin film (resin film material)
  • the material of the resin film used in the present invention is not particularly limited as long as it satisfies the above-mentioned refractive index definition and the above-described tensile elastic modulus definition when an optical film is formed.
  • the resin film examples include an acrylic resin film, a polycarbonate (PC) resin film, a cellulose ester resin film such as a cellulose acylate resin film (for example, a triacetyl cellulose (TAC) resin film), a polyethylene terephthalate (PET) resin film, A polyolefin resin film, a polyester resin film, and an acrylonitrile-butadiene-styrene copolymer film can be mentioned, and a film selected from an acrylic resin film, a cellulose ester resin film, a polyethylene terephthalate resin film, and a polycarbonate resin film is preferable. From the viewpoint of moisture permeability, a cellulose ester resin film is more preferable.
  • the acrylic resin film refers to a polymer or copolymer resin film formed from one or more compounds selected from the group consisting of acrylic acid esters and methacrylic acid esters.
  • An example of the acrylic resin film is a polymethyl methacrylate resin (PMMA) film.
  • the weight average molecular weight of the resin is preferably 10,000 to 1,000,000, more preferably 100,000 to 1,000,000 from the viewpoint of increasing the tensile modulus.
  • the structure of the resin film is not limited, and may be a single layer or a laminated film composed of two or more layers, but a laminated film of two or more layers is preferable.
  • the number of laminated films is preferably 2 to 10 layers, more preferably 2 to 5 layers, and even more preferably 2 or 3 layers.
  • a film having a composition different from that of the outer layer and a layer other than the outer layer (core layer or the like) is preferable.
  • the outer layers are preferably films having the same composition.
  • a film for example, Tac-a
  • a film with the same symbol (a or b) indicates a film having the same composition.
  • the resin film may contain an additive in addition to the above-described resin.
  • the additive include inorganic particles, matte particles, ultraviolet absorbers, fluorine-containing compounds, surface conditioners, leveling agents and the like described in the hard coat layer described later.
  • the melt film forming method described later as a resin melt obtained by mixing and melting the additive and the resin, and in the solution film forming method described later, the solvent (described in the hard coat described later), the resin and the above can be applied.
  • a dope liquid in which an additive is mixed it can be used for forming a resin film.
  • the thickness of the resin film hardly changes before and after the production of the optical film of the present invention.
  • the resin film used for this invention may have an easily bonding layer.
  • the easy-adhesion layer the contents of the polarizer-side easy-adhesion layer and the method for producing the polarizer-side easy-adhesion layer described in paragraphs 0098 to 0133 of JP-A-2015-224267 are described in the present specification in accordance with the present invention. Can be incorporated.
  • the easy adhesion layer is a layer constituting the resin film (A) or (C) in the optical film of the present invention, and the refractive index and tensile elastic modulus of the resin film (A) or (C) are the easy adhesion layer. Means the refractive index and tensile elastic modulus of the resin film (A) or (C).
  • the resin film may be formed by any method, and examples thereof include a melt film forming method and a solution film forming method.
  • melt film forming method smoothing>
  • the resin film is formed by the melt film forming method, it is preferable to include a melting step of melting the resin with an extruder, a step of extruding the molten resin from a die into a sheet shape, and a step of forming the film into a film shape.
  • a melt resin filtration step may be provided after the melt step, or cooling may be performed when extruding into a sheet.
  • the method for producing the resin film includes a melting step of melting the resin with an extruder, a filtration step of filtering the molten resin through a filtration device in which a filter is installed, and extruding the filtered resin from a die into a sheet shape, It has the film formation process which solidifies by cooling on a cooling drum, and shape
  • a resin film can be manufactured.
  • the pore size of the filter used in the molten resin filtration step is 1 ⁇ m or less, foreign matters can be sufficiently removed.
  • the method for forming a resin film can include the following steps.
  • the method for producing the resin film includes a melting step of melting the resin with an extruder. It is preferable to dry the resin or a mixture of the resin and the additive to a moisture content of 200 ppm or less, and then introduce the resin into a uniaxial (single uniaxial) or biaxial extruder and melt it. At this time, in order to suppress decomposition of the resin, it is also preferable to melt in nitrogen or vacuum.
  • the detailed conditions can be carried out according to these publications with the aid of Patent Nos. 4926661 ⁇ 0051> to ⁇ 0052> (US2013 / 0100378 publication ⁇ 0085> to ⁇ 0086>) and are described in these publications. The contents are incorporated herein.
  • the extruder is preferably a single screw kneading extruder. Furthermore, it is also preferable to use a gear pump in order to increase the delivery accuracy of the molten resin (melt).
  • the method for producing the resin film includes a filtration step of filtering the molten resin through a filtration device provided with a filter, and the pore size of the filter used in the filtration step is preferably 1 ⁇ m or less. Only one set of filtration devices having such a filter having a pore diameter range may be installed in the filtration step, or two or more sets may be installed.
  • the method for producing the resin film includes a film forming step of forming an unstretched resin film by extruding the filtered resin into a sheet form from a die and bringing the resin into close contact with a cooling drum to cool and solidify.
  • the melted (and kneaded) and filtered resin (melt containing resin) is extruded from the die into a sheet, it may be extruded as a single layer or multiple layers.
  • a layer containing an ultraviolet absorber and a layer not containing an ultraviolet absorber may be laminated.
  • a three-layer structure including an ultraviolet absorber as an inner layer suppresses deterioration of a polarizer due to ultraviolet rays. The bleed-out of the ultraviolet absorber can be suppressed, which is preferable.
  • the thickness of the inner layer of the obtained resin film with respect to the thickness of the entire layer is preferably 50% or more and 99% or less, more preferably 60% or more and 97% or less, and still more preferably Is 70% or more and 95% or less.
  • Such lamination can be performed by using a feed block die or a multi-manifold die.
  • a resin (melt containing resin) extruded from a die is extruded onto a cooling drum (casting drum), cooled and solidified, and an unstretched resin film (raw fabric) Is preferred.
  • the temperature of the resin extruded from the die is preferably 280 ° C. or higher and 320 ° C. or lower, and more preferably 285 ° C. or higher and 310 ° C. or lower. It is preferable that the temperature of the resin extruded from the die in the melting step is 280 ° C. or more, because the remaining melt of the raw material resin can be reduced and the generation of foreign matters can be suppressed. It is preferable that the temperature of the resin extruded from the die in the melting step is 320 ° C. or less because the decomposition of the resin can be reduced and the generation of foreign matters can be suppressed.
  • the temperature of the resin extruded from the die can be measured in a non-contact manner with a radiation thermometer (manufactured by Hayashi Denko, model number: RT61-2, used at an emissivity of 0.95).
  • the resin film it is preferable to use an electrostatic application electrode when the resin is brought into close contact with the cooling drum in the film forming step. Accordingly, the resin can be strongly adhered onto the cooling drum so that the film surface shape is not roughened.
  • the temperature of the resin when it is in close contact with the cooling drum is preferably 280 ° C. or higher.
  • the electrical conductivity of the resin is increased, the resin can be strongly adhered to the cooling drum by electrostatic application, and the film surface roughness can be suppressed.
  • the temperature of the resin when in close contact with the cooling drum can be measured in a non-contact manner with a radiation thermometer (manufactured by Hayashi Denko, model number: RT61-2, used at an emissivity of 0.95).
  • the method for producing the resin film includes a stretching step of uniaxially or biaxially stretching an unstretched resin film.
  • the longitudinal stretching step step of stretching in the same direction as the film transport direction
  • the resin film is heated and the roller group has a difference in peripheral speed (that is, the transport speed is different). Is stretched in the transport direction.
  • the preheating temperature in the longitudinal stretching step is preferably Tg ⁇ 40 ° C. or more and Tg + 60 ° C. or less, more preferably Tg ⁇ 20 ° C. or more and Tg + 40 ° C. or less, more preferably Tg or more, Tg + 30 ° C. with respect to the glass transition temperature (Tg) of the resin film.
  • the stretching temperature in the longitudinal stretching step is preferably Tg or more and Tg + 60 ° C. or less, more preferably Tg + 2 ° C. or more and Tg + 40 ° C. or less, and further preferably Tg + 5 ° C. or more and Tg + 30 ° C. or less.
  • the draw ratio in the machine direction is preferably 1.0 to 2.5 times, more preferably 1.1 to 2 times.
  • the lateral stretching is performed in the width direction by a lateral stretching step (step of stretching in a direction perpendicular to the film transport direction).
  • a tenter can be suitably used. The tenter grips both ends of the resin film in the width direction with clips and stretches in the transverse direction. By this transverse stretching, the tensile elastic modulus of the resin film in the optical film can be increased.
  • the transverse stretching is preferably carried out using a tenter, and the preferred stretching temperature is preferably Tg or more and Tg + 60 ° C. or less, more preferably Tg + 2 ° C. or more and Tg + 40 ° C. or less with respect to the glass transition temperature (Tg) of the resin film. More preferably, they are Tg + 4 degreeC or more and Tg + 30 degreeC or less.
  • the draw ratio is preferably 1.0 or more and 5.0 or less, and more preferably 1.1 or more and 4.0 or less. It is also preferable to relax in the longitudinal direction, the lateral direction, or both after the transverse stretching.
  • the variation of the thickness depending on the position in the width direction and the longitudinal direction is 10% or less, preferably 8% or less, more preferably 6% or less, further preferably 4% or less, and most preferably 2% or less. preferable.
  • the variation in thickness can be obtained as follows.
  • the stretched resin film is sampled 10 m (meter), 20% of both ends in the film width direction are removed, 50 points are sampled at equal intervals from the center of the film in the width direction and the longitudinal direction, and the thickness is measured.
  • Th TD-av A thickness average value Th TD-av , a maximum value Th TD-max , and a minimum value Th TD-min in the width direction are obtained, (Th TD-max -Th TD-min ) ⁇ Th TD-av ⁇ 100 [%] Is the variation in thickness in the width direction.
  • the thickness average value Th MD-av in the longitudinal direction, the maximum value Th MD-max , and the minimum value Th MD-min are obtained, (Th MD-max -Th MD-min ) ⁇ Th MD-av ⁇ 100 [%] Is the variation of the thickness in the longitudinal direction.
  • the above stretching process can improve the thickness accuracy of the resin film.
  • the stretched resin film can be wound into a roll in the winding process. At that time, the winding tension of the resin film is preferably 0.02 kg / mm 2 or less.
  • melt film formation is described in ⁇ 0134>- ⁇ 0148> of JP-A-2015-224267, and the stretching process is described in JP-A-2007-137028 in accordance with the present invention. It can be incorporated herein.
  • the first resin film (A) and the second resin film (C) are the same film, the point of further suppressing interference unevenness, and the optical film is difficult to bend, It is preferable from the point of showing superior keystroke durability.
  • the same film means that the resin materials constituting the resin film are the same (for example, both are TAC films).
  • the molecular weight of resin is the same, it is more preferable that the molecular weight and crystallinity degree of resin are the same, and it is still more preferable that the molecular weight, crystallinity degree, and extending
  • the first resin film (A) and the second resin film (C) have the same thickness.
  • “same” is not limited to being completely identical, but includes being substantially identical. Specifically, it is manufactured by the same manufacturing method (conditions such that the film thickness, stretching, and the like are the same), and errors that occur under these conditions are included.
  • ) between the refractive index nA of the first resin film (A) and the refractive index nC of the second resin film (C) is preferably small.
  • 03 or less is preferable, 0.02 or less is more preferable, and 0.01 or less is more preferable.
  • the lower limit is not particularly limited and is 0.00 or more.
  • ) between the tensile elastic modulus EA at 25 ° C. of the first resin film (A) and the tensile elastic modulus EC at 25 ° C. of the second resin film (C) is preferably small.
  • 4.0 GPa or less is preferable, 3.0 GPa or less is more preferable, 2.0 GPa or less is further preferable, and 1.0 GPa or less is particularly preferable.
  • the optical film of the present invention is represented by the following formula (8) of the first resin film (A) and the second resin film (C). It is preferable that the shrinkage force Fd (unit: 10 N / m) after the heat treatment represented by) is different from each other, and the shrinkage force Fw (unit: 10 N / m) after the wet heat treatment represented by the following formula (9) is mutually different. More preferably, the contraction force Fd and the contraction force Fw are more preferably different from each other.
  • the absolute value of the difference between the shrinkage force FdA after the heat treatment of the first resin film (A) and the shrinkage force FdC after the heat treatment of the second resin film (C) is 20 (10 N / m) or more. It is preferable that it is 30 (10 N / m) or more, and it is further more preferable that it is 50 (10 N / m) or more.
  • the absolute value of the difference between the shrinkage force FwA after the wet heat treatment of the first resin film (A) and the shrinkage force FwC after the wet heat treatment of the second resin film (C) is 20 (10 N / m) or more.
  • the heat treatment is a treatment for holding the resin film in an environment of 80 ° C. for 48 hours, and the wet heat treatment means a treatment for holding the film in an environment of 60 ° C. and 90% relative humidity for 48 hours.
  • Formula (8) Ed ⁇ ⁇ d ⁇ dd [In the formula, Ed, ⁇ d, and dd represent the elastic modulus in the MD direction, the absolute value of the dimensional change rate in the MD direction, and the film thickness, respectively, after holding the resin film in an environment of 80 ° C. for 48 hours. ]
  • the “MD (Machine Direction) direction” means the film conveying direction, and the above-described elastic modulus in the MD direction, the absolute value of the humidity dimensional change rate in the MD direction, and the film thickness are measured by the method described in the examples. Is.
  • One of the shrinkage forces Fw (unit: 10 N / m) is preferably 50 to 250, more preferably 70 to 230, and still more preferably 80 to 220. Further, of the first resin film (A) and the second resin film (C), the other shrinkage force Fw is preferably 30 to 250, more preferably 50 to 230, and 60 to 220. More preferably.
  • one of the first resin film (A) and the second resin film (C) has a shrinkage force Fd (unit: 10 N / m) of 20 to 200, preferably 30 to 180. More preferably, it is more preferably 40-170. Further, of the first resin film (A) and the second resin film (C), the other shrinkage force Fd is preferably 10 to 200, more preferably 20 to 180, and more preferably 30 to 170. More preferably.
  • An adhesive layer is a layer which plays the role which bonds resin films together, and adhere
  • the adhesive layer is preferably formed using a composition containing a component (adhesive) that exhibits adhesiveness by drying or reaction.
  • a component adheres to a curing reaction.
  • curable composition an adhesive layer formed using a composition containing a component that exhibits adhesiveness by a curing reaction
  • the adhesive layer may be a layer in which the resin accounts for 50% by mass or more, preferably 70% by mass or more of the layer.
  • the resin a single resin or a mixture of a plurality of resins may be used.
  • the proportion of the resin is the proportion of the resin mixture.
  • the resin mixture include a mixture of a certain resin and a resin having a structure obtained by modifying a part of the resin, a mixture of resins obtained by reacting different polymerizable compounds, and the like.
  • an adhesive having any appropriate property, form and adhesion mechanism can be used.
  • an adhesive for example, a water-soluble adhesive, an ultraviolet curable adhesive, an emulsion adhesive, a latex adhesive, a mastic adhesive, a multilayer adhesive, a paste adhesive, and a foam adhesive , Supported film adhesives, thermoplastic adhesives, hot melt adhesives, thermosetting adhesives, heat activated adhesives, heat seal adhesives, thermosetting adhesives, contact adhesives, pressure sensitive Adhesives, polymerization-type adhesives, solvent-type adhesives, solvent-active adhesives and the like can be mentioned, and water-soluble adhesives and UV-curable adhesives are preferred.
  • a water-soluble adhesive is preferably used in terms of excellent transparency, adhesiveness, workability, product quality and economy.
  • the water-soluble adhesive can contain natural or synthesized water-soluble components such as protein, starch, and synthetic resin.
  • the synthetic resin include resole resin, urea resin, melamine resin, polyethylene oxide resin, polyacrylamide resin, polyvinyl pyrrolidone resin, polyacrylic ester resin, polymethacrylic ester resin, polypolyvinyl alcohol resin, polyacrylic resin and cellulose. Derivatives.
  • a water-soluble adhesive containing a polyvinyl alcohol resin or a cellulose derivative is preferable in terms of excellent adhesiveness when the resin film is bonded. That is, the adhesive layer in the present invention preferably contains a polyvinyl alcohol resin or a cellulose derivative.
  • the cellulose derivative means a modified cellulose.
  • a cellulose derivative A well-known cellulose derivative can be used.
  • HEC hydroxyethyl cellulose
  • the weight average molecular weight of the resin is preferably 1000 or more, more preferably 10,000 or more, from the viewpoint of increasing the tensile modulus.
  • the upper limit is not particularly limited, but 1,000,000 or less is practical.
  • the adhesive layer preferably also contains inorganic fine particles from the viewpoint of adjusting the refractive index nB of the adhesive layer.
  • the average particle size of the inorganic fine particles is 0.2 ⁇ m or less, preferably 0.1 ⁇ m or less, and more preferably 0.06 ⁇ m or less. Although there is no restriction
  • the average particle diameter of the inorganic fine particles is a value measured by a transmission electron microscope. More specifically, for 100 inorganic fine particles randomly selected by HR-TEM (high resolution transmission electron microscope), the area occupied by the inorganic fine particles is obtained from the projected area by an image processing apparatus.
  • the total occupied area was divided by the number of selected inorganic fine particles (100), and the average value of the diameters of the circles corresponding to the obtained values (average circle equivalent diameter) was calculated.
  • the average particle size does not include the particle size of secondary particles formed by aggregation of primary particles.
  • the inorganic fine particles are preferably solid particles with clogged centers, for example, at least one metal selected from titanium, zirconium, aluminum, indium, zinc, tin, antimony, and the like. And fine particles made of a mixture thereof. Specifically, TiO 2, ZrO 2, Al 2 O 3, In 2 O 3, ZnO, SnO 2, Sb 2 O 3, ITO ( indium tin oxide) and SiO 2 and the like. TiO 2 and ZrO 2 are particularly preferable in terms of increasing the refractive index.
  • the surface of the inorganic fine particles is also preferably subjected to silane coupling treatment or titanium coupling treatment.
  • the surface treatment agent a surface treatment agent capable of introducing a functional group capable of reacting with the resin constituting the adhesive on the fine particle surface is used. Preferably used.
  • the inorganic fine particles are preferably hollow particles having a hollow structure.
  • the inorganic fine particles are preferably metal oxide fine particles, and at least the surface of the particles preferably contains a metal oxide containing silicon as a constituent component.
  • even core-shell particles whose surface is made of silicon dioxide may be particles in which silicon and other inorganic elements form a mixed crystal.
  • hollow silica particles are preferable from the viewpoint of lowering the refractive index.
  • the amount of these inorganic fine particles added is preferably 1 to 60% by mass, more preferably 3 to 40% by mass, and still more preferably 5 to 30% by mass, based on the total solid content of the adhesive layer.
  • Such inorganic fine particles have a particle size that is sufficiently smaller than the wavelength of light, so that scattering does not occur.
  • a dispersion in which the inorganic fine particles are dispersed in the adhesive constituting the adhesive layer is an optically uniform substance behave.
  • Components optionally contained in the composition containing the adhesive include cross-linking agents (boric acid and Safelink SPM-01 (trade name, manufactured by Nippon Synthetic Chemical Co., Ltd.)), and durability improvers (potassium iodide, etc.) It is done.
  • the adhesive layer can be formed, for example, by applying a coating solution containing an adhesive to at least one surface of the resin film and drying. Any appropriate method can be adopted as a method for preparing the coating solution.
  • a coating solution for example, a commercially available solution or dispersion may be used, a solvent may be further added to the commercially available solution or dispersion, and the solid content may be used by dissolving or dispersing in various solvents. Also good.
  • the adhesive layer may be a cured layer obtained by curing the active energy ray-curable composition.
  • the active energy ray-curable composition for forming the adhesive layer is a cationic polymerizable compound such as an epoxy compound, more specifically described in JP-A-2004-245925, as the active energy curable component.
  • numerator like this is preferable.
  • an epoxy compound for example, an aromatic polyhydroxy compound, which is a raw material of an aromatic epoxy compound represented by diglycidyl ether of bisphenol A, can be obtained by nuclear hydrogenation and glycidyl ether.
  • the active energy ray-curable composition for forming the adhesive layer comprises a cationic initiator or a Lewis acid upon irradiation with a polymerization initiator, for example, an active energy ray, in addition to a cationically polymerizable compound typified by an epoxy compound.
  • a photocationic polymerization initiator for initiating polymerization of the cationically polymerizable compound, and a photobase generator for generating a base upon irradiation with light may be contained.
  • the optical film of the present invention has at least two resin films and an adhesive layer for bonding the two resin films, but the resin film has a surface opposite to the surface having the adhesive layer (the other side). May also have an adhesive layer.
  • a known polarizing plate protective film can be provided on the other surface via an adhesive layer.
  • the compositions for forming the respective adhesive layers may be the same or different, but from the viewpoint of productivity, both surfaces are formed from the same composition. It is preferable to have an adhesive layer.
  • the surface to which the adhesive layer is applied may be subjected to a surface treatment such as saponification treatment, corona discharge treatment, or plasma treatment before the adhesion layer is applied.
  • the saponification treatment for example, adhesion of the cellulose ester resin film to a polarizer material such as polyvinyl alcohol can be enhanced by alkali saponification treatment.
  • the saponification method the methods described in JP-A-2007-86748, paragraph number ⁇ 0211> and paragraph number ⁇ 0212> can be used.
  • the alkali saponification treatment for the cellulose ester resin film is preferably performed in a cycle in which the film surface is immersed in an alkali solution, neutralized with an acidic solution, washed with water and dried.
  • the alkaline solution include potassium hydroxide solution and sodium hydroxide solution.
  • the concentration of hydroxide ions is preferably in the range of 0.1 to 5.0 mol / L, and more preferably in the range of 0.5 to 4.0 mol / L.
  • the alkaline solution temperature is preferably in the range of room temperature to 90 ° C, and more preferably in the range of 40 to 70 ° C.
  • a well-known method can be used for the method of bonding resin films together using an adhesive.
  • the resin film (C) or (A) is brought close to one surface of the strip-shaped long resin film (A) or (C) moving in the horizontal direction or the vertical direction, and the resin film Applying an adhesive to be the adhesive layer (B) between (A) and the resin film (C) and applying pressure with a pinch roll to bond the resin film (A) and the resin film (C) together it can.
  • the applied adhesive may be diluted with a solvent so that the material constituting the adhesive layer (B) can be applied. In that case, the solvent in the adhesive layer (B) is dried, and the adhesion between the resin film (A) and the resin film (C) is completed.
  • the drying temperature at this time depends on the solvent type in the adhesive layer (B) and the resin type and thickness of the resin film (A) and the resin film (C).
  • the solvent in the adhesive layer (B) is water. Is preferably 30 to 85 ° C., more preferably 45 to 80 ° C.
  • the adhesive agent which becomes an adhesive bond layer (B) is apply
  • the resin film (C) or (A) is brought close to the surface on which the adhesive layer (B) is formed at the same moving speed, and the resin film (A) and the resin film ( Between C), the solvent which swells an adhesive bond layer (B) is apply
  • the drying temperature at this time depends on the solvent type and the resin type and thickness of the resin film (A) and the resin film (C). For example, when the solvent is water, it is preferably 30 to 85 ° C., more preferably Is 45-80 ° C.
  • Hard coat layer (HC layer) In the present invention, from the viewpoint of surface hardness, at least one of the first resin film (A) and the second resin film (C) is the surface opposite to the side on which the adhesive layer (B) is provided. It is preferable to have a hard coat layer, and it is more preferable that either one of the resin films has.
  • the hard coat layer is not regarded as a layer constituting the resin film (A) or (C) in the optical film of the present invention, and the tensile elastic modulus and refractive index of the resin film (A) or (C) are: It means the tensile elastic modulus and refractive index of the resin film (A) or (C) that does not contain a hard coat layer.
  • the first resin film 1A, the adhesive layer 2A, and the second resin film 1B are laminated in this order, and the first resin film 1A is bonded.
  • the optical film 4B of this invention which has the hard-coat layer 3A in the surface on the opposite side to the surface which has layer 2A is mentioned.
  • the HC layer may be made of any material as long as the desired pencil hardness can be imparted to the optical film.
  • the optical film of the present invention also exhibits the effects of the present invention when it has an HC layer on at least one of the first resin film (A) and the second resin film (C).
  • this invention is not limited to the following aspect.
  • HC layer obtained by curing a curable composition for forming a hard coat layer (HC layer)
  • the HC layer used in the present invention can be obtained by curing the curable composition for forming an HC layer by irradiating it with active energy rays.
  • active energy rays refer to ionizing radiation, and include X-rays, ultraviolet rays, visible light, infrared rays, electron beams, ⁇ rays, ⁇ rays, ⁇ rays and the like.
  • the curable composition for HC layer formation used for forming the HC layer includes at least one component having a property of being cured by irradiation with active energy rays (hereinafter also referred to as “active energy ray curable component”).
  • the active energy ray-curable component is preferably at least one polymerizable compound selected from the group consisting of radical polymerizable compounds and cationic polymerizable compounds.
  • the “polymerizable compound” is a compound containing one or more polymerizable groups in one molecule.
  • the polymerizable group is a group that can participate in the polymerization reaction, and specific examples include groups contained in various polymerizable compounds described below.
  • the HC layer used in the present invention may have a single layer structure or a laminated structure of two or more layers, but an HC layer having a single layer structure or a laminated structure of two or more layers described in detail below is preferable.
  • the curable composition for forming an HC layer having a one-layer structure As a preferred embodiment of the curable composition for forming an HC layer having a one-layer structure, as a first embodiment, at least one polymerizable compound having two or more ethylenically unsaturated groups in one molecule is used.
  • the curable composition for HC layer formation containing can be mentioned.
  • An ethylenically unsaturated group means a functional group containing an ethylenically unsaturated double bond.
  • the 2nd aspect can mention the curable composition for HC layer formation containing an at least 1 type of radically polymerizable compound and an at least 1 type of cationically polymerizable compound.
  • the curable composition for HC layer formation of a 1st aspect examples include esters of polyhydric alcohol and (meth) acrylic acid [
  • esters of polyhydric alcohol and (meth) acrylic acid For example, ethylene glycol di (meth) acrylate, butanediol di (meth) acrylate, hexanediol di (meth) acrylate, 1,4-cyclohexanediacrylate, pentaerythritol tetra (meth) acrylate, pentaerythritol tri (meth) acrylate, Trimethylolpropane tri (meth) acrylate, trimethylolethane tri (meth) acrylate, dipentaerythritol tetra (meth) acrylate, dipentaerythritol penta (meth) acrylate.
  • Polymerization of the polymerizable compound having an ethylenically unsaturated group can be performed by irradiation with active energy rays in the presence of a radical photopolymerization initiator.
  • a radical photopolymerization initiator described later is preferably applied.
  • the content ratio of the radical photopolymerization initiator to the polymerizable compound having an ethylenically unsaturated group in the curable composition for HC layer formation the content of the radical photopolymerization initiator to the radical polymerizable compound described later is included. The description of the quantitative ratio is preferably applied.
  • the curable composition for forming an HC layer according to the second embodiment includes at least one radical polymerizable compound and at least one cationic polymerizable compound.
  • the HC layer forming curable composition more preferably contains a radical photopolymerization initiator and a cationic photopolymerization initiator.
  • this embodiment is referred to as a second embodiment (1).
  • the radical polymerizable compound preferably contains one or more urethane bonds in one molecule together with two or more radical polymerizable groups in one molecule.
  • this embodiment is referred to as a second embodiment (2).
  • the HC layer obtained by curing the curable composition for forming an HC layer of the second aspect (2) preferably has a structure derived from a) of 15 to 15 when the total solid content of the HC layer is 100% by mass. 70% by mass, 25-80% by mass of the structure derived from b), 0.1-10% by mass of c), and 0.1-10% by mass of d).
  • the HC layer-forming curable composition of the second embodiment (2) has the above a) when the total solid content of the HC layer-forming curable composition is 100% by mass.
  • the content is preferably 15 to 70% by mass.
  • the “alicyclic epoxy group” refers to a monovalent functional group having a cyclic structure in which an epoxy ring and a saturated hydrocarbon ring are condensed.
  • the curable composition for forming an HC layer according to the second embodiment includes at least one radical polymerizable compound and at least one cationic polymerizable compound.
  • the radically polymerizable compound in the second aspect (1) contains two or more radically polymerizable groups selected from the group consisting of an acryloyl group and a methacryloyl group in one molecule.
  • the radical polymerizable compound may contain, for example, 2 to 10 radical polymerizable groups selected from the group consisting of an acryloyl group and a methacryloyl group, preferably 2 to 6 in a molecule. Can do.
  • radical polymerizable compound a radical polymerizable compound having a molecular weight of 200 or more and less than 1000 is preferable.
  • molecular weight shall mean the weight average molecular weight measured in polystyrene conversion by gel permeation chromatography (GPC) about a multimer. The following measurement conditions can be mentioned as an example of the specific measurement conditions of a weight average molecular weight.
  • GPC device HLC-8120 (manufactured by Tosoh Corporation) Column: TSK gel Multipore HXL-M (manufactured by Tosoh, inner diameter 7.8 mm ⁇ column length 30.0 cm)
  • Eluent Tetrahydrofuran
  • the radical polymerizable compound preferably contains one or more urethane bonds in one molecule.
  • the number of urethane bonds contained in one molecule of the radical polymerizable compound is preferably 1 or more, more preferably 2 or more, more preferably 2 to 5, for example, 2 be able to.
  • a radically polymerizable compound containing two urethane bonds in one molecule a radically polymerizable group selected from the group consisting of an acryloyl group and a methacryloyl group is bonded to only one urethane bond directly or via a linking group. It may be bonded to two urethane bonds directly or via a linking group.
  • it is preferable that one or more radically polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group are bonded to two urethane bonds bonded via a linking group.
  • the radically polymerizable group selected from the group consisting of a urethane bond and an acryloyl group and a methacryloyl group may be directly bonded, and from the group consisting of a urethane bond and an acryloyl group and a methacryloyl group.
  • the linking group is not particularly limited, and examples thereof include a linear or branched saturated or unsaturated hydrocarbon group, a cyclic group, and a group composed of a combination of two or more thereof.
  • the number of carbon atoms of the hydrocarbon group is, for example, about 2 to 20, but is not particularly limited.
  • Examples of the cyclic structure contained in the cyclic group include an aliphatic ring (such as a cyclohexane ring) and an aromatic ring (such as a benzene ring and a naphthalene ring).
  • the above group may be unsubstituted or may have a substituent.
  • the group described may have a substituent or may be unsubstituted.
  • examples of the substituent include an alkyl group (for example, an alkyl group having 1 to 6 carbon atoms), a hydroxyl group, an alkoxy group (for example, an alkoxy group having 1 to 6 carbon atoms), a halogen atom (for example, a fluorine atom) , Chlorine atom, bromine atom), cyano group, amino group, nitro group, acyl group, carboxy group and the like.
  • the radically polymerizable compound described above can be synthesized by a known method. Moreover, it is also possible to obtain as a commercial item. For example, as an example of the synthesis method, an alcohol, a polyol, and / or a hydroxyl group-containing compound such as a hydroxyl group-containing (meth) acrylic acid is reacted with an isocyanate, or, if necessary, a urethane compound obtained by the above reaction ( The method of esterifying with (meth) acrylic acid can be mentioned. “(Meth) acrylic acid” means one or both of acrylic acid and methacrylic acid.
  • UV-1400B UV-1700B, UV-6300B, UV-7550B, UV-7600B, UV-7600B, Same UV-7605B, Same UV-7610B, Same UV-7620EA, Same UV-7630B, Same UV-7640B, Same UV-6 30B, UV-7000B, UV-7510B, UV-7461TE, UV-3000B, UV-3200B, UV-3210EA, UV-3310EA, UV-3310B, UV-3310B, UV-3500BA, UV-3500 3520TL, UV-3700B, UV-6100B, UV-6640B, UV-2000B,
  • purple light UV-2750B manufactured by Nippon Synthetic Chemical Industry Co., Ltd.
  • UL-503LN manufactured by Kyoeisha Chemical Co., Ltd.
  • Unidic 17-806 manufactured by Dainippon Ink & Chemicals, Inc., 17-813, V-4030, V-4000BA, and Daicel.
  • Examples include EB-1290K manufactured by UCB, Hicorp AU-2010 and AU-2020 manufactured by Tokushi.
  • the radical polymerizable compound containing one or more urethane bonds in one molecule has been described.
  • the compound may have no urethane bond.
  • the curable composition for HC layer formation of the second aspect (1) is added to a radical polymerizable compound containing two or more radical polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group in one molecule.
  • One or more radically polymerizable compounds other than the radically polymerizable compound may be contained.
  • a radical polymerizable compound containing two or more radically polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group in one molecule and one or more urethane bonds in one molecule is used as the first radical. Radical polymerization that does not correspond to the first radical polymerizable compound, regardless of whether or not two or more radical polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group are contained in one molecule.
  • the functional compound is referred to as “second radical polymerizable compound”.
  • the second radical polymerizable compound may or may not have one or more urethane bonds in one molecule.
  • first radical polymerizable compound / second radical polymerizable compound 3/1 to 1/30
  • the ratio is 2/1 to 1/20, more preferably 1/1 to 1/10.
  • Radical polymerizable compound containing two or more radical polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group of the curable composition for forming an HC layer of the second aspect (1) is preferably 30% by mass or more, more preferably 50% by mass or more, and further preferably 70% by mass or more with respect to 100% by mass of the total composition.
  • the content is preferably 98% by mass or less, more preferably 95% by mass or less, and still more preferably 90% by mass or less with respect to 100% by mass of the total composition.
  • the content of the first radical polymerizable compound of the curable composition for forming an HC layer of the second aspect (1) is preferably 30% by mass or more with respect to 100% by mass of the total composition. More preferably, it is 50 mass% or more, More preferably, it is 70 mass% or more.
  • the content of the first radical polymerizable compound is preferably 98% by mass or less, more preferably 95% by mass or less, and 90% by mass or less with respect to 100% by mass of the total composition. More preferably it is.
  • the second radical polymerizable compound is preferably a radical polymerizable compound having two or more radical polymerizable groups in one molecule and having no urethane bond.
  • the radically polymerizable group contained in the second radically polymerizable compound is preferably an ethylenically unsaturated group, and in one aspect, a vinyl group is preferable.
  • the ethylenically unsaturated group is preferably a radical polymerizable group selected from the group consisting of an acryloyl group and a methacryloyl group.
  • the second radical polymerizable compound preferably has at least one radical polymerizable group selected from the group consisting of an acryloyl group and a methacryloyl group in one molecule and does not have a urethane bond.
  • the second radical polymerizable compound includes one or more radical polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group in one molecule as radical polymerizable compounds, and radical polymerizable groups other than these. One or more of these can also be included.
  • the number of radical polymerizable groups contained in one molecule of the second radical polymerizable compound is preferably at least 2, more preferably 3 or more, and further preferably 4 or more.
  • the number of radical polymerizable groups contained in one molecule of the second radical polymerizable compound is, for example, 10 or less in one embodiment, but may be more than 10.
  • the second radical polymerizable compound is preferably a radical polymerizable compound having a molecular weight of 200 or more and less than 1000.
  • Examples of the second radical polymerizable compound include the following. However, the present invention is not limited to the following exemplified compounds.
  • a functional (meth) acrylate is mentioned.
  • Two or more kinds of the second radical polymerizable compounds may be used in combination.
  • a mixture “DPHA” manufactured by Nippon Kayaku Co., Ltd.
  • dipentaerythritol pentaacrylate and dipentaerythritol hexaacrylate can be preferably used.
  • polyester (meth) acrylate and epoxy (meth) acrylate having a weight average molecular weight of 200 to less than 1000 are also preferable.
  • Commercially available products include, as polyester (meth) acrylate, trade name Beam Set 700 series manufactured by Arakawa Chemical Industries, such as Beam Set 700 (6 functional), Beam Set 710 (4 functional), Beam Set 720 (3 functional), and the like. It is done.
  • epoxy (meth) acrylate trade name SP series made by Showa High Polymer, such as SP-1506, 500, SP-1507, 480, VR series, such as VR-77, trade name EA-, manufactured by Shin-Nakamura Chemical Co., Ltd. 1010 / ECA, EA-11020, EA-1025, EA-6310 / ECA and the like.
  • the second radical polymerizable compound examples include the following exemplary compounds A-9 to A-1. 1 can also be mentioned.
  • the curable composition for forming an HC layer according to the second aspect (2) which is a preferred aspect of the second aspect, comprises b) a radical polymerizable compound containing 3 or more ethylenically unsaturated groups in one molecule.
  • a radical polymerizable compound containing 3 or more ethylenically unsaturated groups in one molecule is also referred to as “component b” below.
  • component b) examples include esters of polyhydric alcohol and (meth) acrylic acid, vinylbenzene and its derivatives, vinyl sulfone, (meth) acrylamide, and the like.
  • a radical polymerizable compound containing three or more radical polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group in one molecule is preferable.
  • a specific example is an ester of polyhydric alcohol and (meth) acrylic acid, and a compound having three or more ethylenically unsaturated groups in one molecule.
  • a resin containing three or more radically polymerizable groups selected from the group consisting of acryloyl groups and methacryloyl groups in one molecule is also preferred.
  • the resin containing three or more radically polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group in one molecule include polyester resins, polyether resins, acrylic resins, epoxy resins, and urethane resins.
  • polymers such as polyfunctional compounds such as alkyd resins, spiroacetal resins, polybutadiene resins, polythiol polyene resins and polyhydric alcohols.
  • radical polymerizable compound containing 3 or more radical polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group in one molecule include the exemplified compounds shown in paragraph 0096 of JP-A-2007-256844. Etc.
  • radically polymerizable compounds containing 3 or more radically polymerizable groups selected from the group consisting of acryloyl group and methacryloyl group in one molecule include KAYARAD DPHA, DPHA-2C, and PET manufactured by Nippon Kayaku.
  • UV-1400B Purple light UV-1400B, UV-1700B, UV-6300B, UV-7550B, UV-7600B, UV-7605B, UV-7610B, UV-7620EA, UV-7630B, UV-7630B, UV-7640B UV-6630B, UV-7000B, UV-7510B, UV-7461TE, UV-3000B, UV-3200B, UV-3210EA, UV-3310EA, UV-3310EA, UV-3310B, UV-3500BA , UV-3520TL, UV-3700B, UV-6100B, UV-6640B, UV-2000B, UV-2010B, UV-2250EA, UV-2750B (manufactured by Nippon Synthetic Chemical), UL-503LN (Manufactured by Kyoeisha Chemical), Unidic 17-806, 17- 13, V-4030, V-4000BA (Dainippon Ink Chemical Co., Ltd.), EB-1290K, EB-220, EB-5129, EB-1830, EB-4358
  • the HC layer obtained by curing the curable composition for forming an HC layer of the second aspect (2) is preferably derived from the above a) when the total solid content of the HC layer is 100% by mass.
  • the structure may contain 15 to 70% by mass, the structure derived from the above b) from 25 to 80% by mass, the above c) from 0.1 to 10% by mass, and the d) from 0.1 to 10% by mass.
  • the structure derived from b) is preferably contained in an amount of 40 to 75% by mass, more preferably 60 to 75% by mass when the total solid content of the HC layer is 100% by mass.
  • the HC layer-forming curable composition of the second aspect (2) has a component b) of 40 to 75% by mass when the total solid content of the HC layer-forming curable composition is 100% by mass. %, Preferably 60 to 75% by mass.
  • the curable composition for forming an HC layer according to the second embodiment includes at least one radical polymerizable compound and at least one cationic polymerizable compound.
  • Any cationically polymerizable compound can be used without any limitation as long as it has a polymerizable group capable of cationic polymerization (cationic polymerizable group).
  • the number of cationically polymerizable groups contained in one molecule is at least one.
  • the cationic polymerizable compound may be a monofunctional compound containing one cationic polymerizable group in one molecule or a polyfunctional compound containing two or more.
  • the number of cationically polymerizable groups contained in the polyfunctional compound is not particularly limited, but is 2 to 6 per molecule, for example. Further, two or more cationically polymerizable groups contained in one molecule of the polyfunctional compound may be the same, or two or more kinds having different structures may be used.
  • the cationically polymerizable compound preferably has one or more radically polymerizable groups in one molecule together with the cationically polymerizable group.
  • the above description of the radically polymerizable compound can be referred to.
  • it is an ethylenically unsaturated group
  • the ethylenically unsaturated group is more preferably a radical polymerizable group selected from the group consisting of a vinyl group, an acryloyl group, and a methacryloyl group.
  • the number of radically polymerizable groups in one molecule of the cationically polymerizable compound having a radically polymerizable group is at least 1, preferably 1 to 3, and more preferably 1.
  • Preferred examples of the cationic polymerizable group include an oxygen-containing heterocyclic group and a vinyl ether group.
  • the cationically polymerizable compound may contain one or more oxygen-containing heterocyclic groups and one or more vinyl ether groups in one molecule.
  • the oxygen-containing heterocycle may be a single ring or a condensed ring. Those having a bicyclo skeleton are also preferred.
  • the oxygen-containing heterocycle may be a non-aromatic ring or an aromatic ring, and is preferably a non-aromatic ring.
  • Specific examples of the monocycle include an epoxy ring, a tetrahydrofuran ring, and an oxetane ring.
  • an oxabicyclo ring can be mentioned as what has a bicyclo skeleton.
  • the cationically polymerizable group containing an oxygen-containing heterocyclic ring is contained in the cationically polymerizable compound as a monovalent substituent or a divalent or higher polyvalent substituent.
  • the above condensed ring is a product in which one or more oxygen-containing heterocycles and one or more ring structures other than the oxygen-containing heterocycle are condensed, even if two or more oxygen-containing heterocycles are condensed.
  • the ring structure other than the oxygen-containing heterocycle include, but are not limited to, cycloalkane rings such as a cyclohexane ring.
  • the cationically polymerizable compound may contain a partial structure other than the cationically polymerizable group.
  • a partial structure is not particularly limited, and may be a linear structure, a branched structure, or a cyclic structure. These partial structures may contain one or more heteroatoms such as oxygen atoms and nitrogen atoms.
  • a compound containing a cyclic structure can be mentioned as the cationically polymerizable group or as a partial structure other than the cationically polymerizable group.
  • the cyclic structure contained in the cyclic structure-containing compound is, for example, one per molecule and may be two or more.
  • the number of cyclic structures contained in the cyclic structure-containing compound is, for example, 1 to 5 per molecule, but is not particularly limited.
  • a compound containing two or more cyclic structures in one molecule may contain the same cyclic structure, or may contain two or more types of cyclic structures having different structures.
  • cyclic structure contained in the cyclic structure-containing compound is an oxygen-containing heterocyclic ring. The details are as described above.
  • Cationic polymerizability obtained by dividing the molecular weight (hereinafter referred to as “B”) by the number of cationic polymerizable groups (hereinafter referred to as “C”) contained in one molecule of the cationic polymerizable compound.
  • the cation polymerizable group equivalent is preferably 50 or more.
  • requires a cationically polymerizable group equivalent can be an epoxy group (epoxy ring). That is, in one aspect, the cationically polymerizable compound is an epoxy ring-containing compound.
  • the epoxy ring-containing compound is obtained by dividing the molecular weight by the number of epoxy rings contained in one molecule from the viewpoint of improving the adhesion between the HC layer obtained by curing the HC layer forming curable composition and the resin film.
  • the epoxy group equivalent is preferably less than 150.
  • the epoxy group equivalent of an epoxy ring containing compound is 50 or more, for example.
  • the molecular weight of the cationic polymerizable compound is preferably 500 or less, and more preferably 300 or less.
  • the cationically polymerizable compound having a molecular weight in the above range tends to easily penetrate into the resin film, and can contribute to improving the adhesion between the HC layer obtained by curing the curable composition for HC layer formation and the resin film. I guess.
  • the curable composition for HC layer formation of the second aspect (2) includes a) an alicyclic epoxy group and an ethylenically unsaturated group, and the number of alicyclic epoxy groups contained in one molecule is one. And the number of ethylenically unsaturated groups contained in one molecule is 1, and the cationically polymerizable compound having a molecular weight of 300 or less is included.
  • the a) will be referred to as “a) component”.
  • Examples of the ethylenically unsaturated group include radical polymerizable groups including an acryloyl group, a methacryloyl group, a vinyl group, a styryl group, and an allyl group. Among them, an acryloyl group, a methacryloyl group, and C (O) OCH ⁇ CH 2 An acryloyl group and a methacryloyl group are more preferable.
  • the number of alicyclic epoxy groups and ethylenically unsaturated groups in one molecule is preferably one each.
  • the molecular weight of the component is 300 or less, preferably 210 or less, and more preferably 200 or less.
  • R represents a monocyclic hydrocarbon or a bridged hydrocarbon
  • L represents a single bond or a divalent linking group
  • Q represents an ethylenically unsaturated group.
  • R in the general formula (1) is a monocyclic hydrocarbon
  • the monocyclic hydrocarbon is preferably an alicyclic hydrocarbon, and more preferably an alicyclic group having 4 to 10 carbon atoms.
  • An alicyclic group having 5 to 7 carbon atoms is more preferable, and an alicyclic group having 6 carbon atoms is particularly preferable.
  • Preferable specific examples include a cyclobutyl group, a cyclopentyl group, a cyclohexyl group and a cycloheptyl group, and a cyclohexyl group is more preferable.
  • R in the general formula (1) is a bridged hydrocarbon
  • the bridged hydrocarbon is preferably a bicyclic bridged hydrocarbon (bicyclo ring) or a tricyclic bridged hydrocarbon (tricyclo ring).
  • Specific examples include bridged hydrocarbons having 5 to 20 carbon atoms, such as norbornyl group, bornyl group, isobornyl group, tricyclodecyl group, dicyclopentenyl group, dicyclopentanyl group, tricyclopentenyl group.
  • the divalent linking group is preferably a divalent aliphatic hydrocarbon group.
  • the carbon number of the divalent aliphatic hydrocarbon group is preferably in the range of 1 to 6, more preferably in the range of 1 to 3, and still more preferably 1.
  • the divalent aliphatic hydrocarbon group is preferably a linear, branched or cyclic alkylene group, more preferably a linear or branched alkylene group, and even more preferably a linear alkylene group.
  • Examples of Q include ethylenically unsaturated groups including an acryloyl group, a methacryloyl group, a vinyl group, a styryl group, and an allyl group.
  • an acryloyl group, a methacryloyl group, and C (O) OCH ⁇ CH 2 are preferable, and acryloyl More preferred are groups and methacryloyl groups.
  • component a) examples include various compounds exemplified in JP-A-10-17614, paragraph 0015, compounds represented by the following general formula (1A) or (1B), 1,2-epoxy-4- A vinyl cyclohexane etc. can be mentioned. Especially, the compound represented by the following general formula (1A) or (1B) is more preferable. In addition, the compound represented by the following general formula (1A) is also preferably an isomer thereof.
  • R 1 represents a hydrogen atom or a methyl group
  • L 2 represents a divalent aliphatic hydrocarbon group having 1 to 6 carbon atoms.
  • the carbon number of the divalent aliphatic hydrocarbon group represented by L 2 in the general formulas (1A) and (1B) is in the range of 1 to 6, and more preferably in the range of 1 to 3. More preferably, it has 1 carbon.
  • the divalent aliphatic hydrocarbon group is preferably a linear, branched or cyclic alkylene group, more preferably a linear or branched alkylene group, and even more preferably a linear alkylene group.
  • the HC layer obtained by curing the curable composition for forming an HC layer of the second aspect (2) preferably has a structure derived from a) of 15 to 15 when the total solid content of the HC layer is 100% by mass.
  • the content is preferably 70% by mass, more preferably 18 to 50% by mass, and still more preferably 22 to 40% by mass.
  • the HC layer-forming curable composition of the second aspect (2) is 15 to 70 masses when the a) component is 100 mass% of the total solid content of the HC layer-forming curable composition. %, Preferably 18 to 50% by mass, more preferably 22 to 40% by mass.
  • a nitrogen-containing heterocyclic ring As another example of the cyclic structure contained in the cyclic structure-containing compound, a nitrogen-containing heterocyclic ring can be mentioned.
  • the nitrogen-containing heterocyclic ring-containing compound is a preferred cationically polymerizable compound from the viewpoint of improving the adhesion between the HC layer obtained by curing the HC layer forming curable composition and the resin film.
  • the nitrogen-containing heterocycle-containing compound include isocyanurate rings (nitrogen-containing heterocycles contained in the exemplified compounds B-1 to B-3 described later) and glycoluril rings (nitrogen-containing heterocycles contained in the exemplified compound B-10 described later).
  • a compound having at least one nitrogen-containing heterocyclic ring selected from the group consisting of (ring) per molecule is preferable.
  • a compound containing an isocyanurate ring is a more preferable cationic polymerizable compound from the viewpoint of improving the adhesion between the HC layer obtained by curing the HC layer forming curable composition and the resin film.
  • the present inventors infer that this is because the isocyanurate ring is excellent in affinity with the resin constituting the resin film. From this point, a resin film including an acrylic resin film is more preferable, and a surface directly in contact with the HC layer obtained by curing the curable composition for forming an HC layer is more preferably an acrylic resin film surface.
  • an alicyclic structure can be exemplified.
  • the alicyclic structure include a cyclo ring, a dicyclo ring, and a tricyclo ring structure, and specific examples include a dicyclopentanyl ring and a cyclohexane ring.
  • the cationically polymerizable compound described above can be synthesized by a known method. Moreover, it is also possible to obtain as a commercial item.
  • cationic polymerizable compound containing an oxygen-containing heterocycle examples include, for example, 3,4-epoxycyclohexylmethyl methacrylate (commercially available product such as Daicel Cyclomer M100), 3,4-epoxy.
  • Cyclohexylmethyl-3 ′, 4′-epoxycyclohexanecarboxylate for example, commercially available products such as UVR6105 and UVR6110 manufactured by Union Carbide and CELLOXIDE 2021 manufactured by Daicel Chemical
  • bis (3,4-epoxycyclohexylmethyl) adipate for example, union car UVR6128 manufactured by Bite
  • vinyl cyclohexylene monoepoxide for example, CELLOXIDE 2000 manufactured by Daicel Chemical Industries
  • ⁇ -caprolactone-modified 3,4-epoxycyclohexylmethyl 3 ′, 4′-epoch Cycyclohexanecarboxylate for example, CELLOXIDE 2081 manufactured by Daicel Chemical Industries
  • 1-methyl-4- (2-methyloxiranyl) -7-oxabicyclo [4,1,0] heptane for example, CELLOXIDE 3000 manufactured by Daicel Chemical Industries
  • the cationic polymerizable compound containing a vinyl ether group examples include 1,4-butanediol divinyl ether, 1,6-hexanediol divinyl ether, nonanediol divinyl ether, and cyclohexanediol divinyl ether. , Cyclohexanedimethanol divinyl ether, triethylene glycol divinyl ether, trimethylolpropane trivinyl ether, pentaerythritol tetravinyl ether, and the like.
  • the cationically polymerizable compound containing a vinyl ether group those having an alicyclic structure are also preferable.
  • JP-A-8-143806, JP-A-8-283320, JP-A-2000-186079, JP-A-2000-327672, JP-A-2004-315778, Compounds exemplified in Kaikai 2005-29632 and the like can also be used.
  • exemplary compounds B-1 to B-14 are shown as specific examples of the cationically polymerizable compound, but the present invention is not limited to the following specific examples.
  • preferred embodiments of the HC layer forming curable composition include the following modes. It is more preferable to satisfy one or more of the following aspects, it is more preferable to satisfy two or more, still more preferable to satisfy three or more, and still more preferable to satisfy all. In addition, it is also preferable that one cationically polymerizable compound satisfy
  • a nitrogen-containing heterocyclic ring-containing compound is included.
  • the nitrogen-containing heterocycle of the nitrogen-containing heterocycle-containing compound is selected from the group consisting of an isocyanurate ring and a glycoluril ring.
  • the nitrogen-containing heterocyclic ring-containing compound is more preferably an isocyanurate ring-containing compound. More preferably, the isocyanurate ring-containing compound is an epoxy ring-containing compound containing one or more epoxy rings in one molecule.
  • the cationic polymerizable compound includes a cationic polymerizable compound having a cationic polymerizable group equivalent of less than 150.
  • an epoxy group-containing compound having an epoxy group equivalent of less than 150 is included.
  • the cationically polymerizable compound contains an ethylenically unsaturated group.
  • an oxetane ring-containing compound containing one or more oxetane rings in one molecule is included together with other cationically polymerizable compounds.
  • the oxetane ring-containing compound is a compound that does not contain a nitrogen-containing heterocycle.
  • the content of the cation polymerizable compound in the curable composition for forming an HC layer is preferably 10 parts by mass or more with respect to 100 parts by mass of the total content of the radical polymerizable compound and the cation polymerizable compound. Preferably it is 15 mass parts or more, More preferably, it is 20 mass parts or more. Further, the content of the cationic polymerizable compound in the curable composition for forming an HC layer is 50 parts by mass or less with respect to 100 parts by mass of the total content of the radical polymerizable compound and the cationic polymerizable compound. preferable.
  • the content of the cationic polymerizable compound in the curable composition for forming an HC layer is preferably 100 parts by mass of the total content of the first radical polymerizable compound and the cationic polymerizable compound. It is 0.05 mass part or more, More preferably, it is 0.1 mass part or more, More preferably, it is 1 mass part or more.
  • the content of the cationic polymerizable compound is preferably 50 parts by mass or less with respect to 100 parts by mass of the total content of the first radical polymerizable compound and the cationic polymerizable compound, and 40 masses. It is more preferable that the amount is not more than parts.
  • the compound which has both a cationically polymerizable group and a radically polymerizable group shall be classified into a cationically polymerizable compound, and shall prescribe
  • the curable composition for HC layer formation preferably contains a polymerization initiator, and more preferably contains a photopolymerization initiator.
  • the curable composition for forming an HC layer containing a radical polymerizable compound preferably contains a radical photopolymerization initiator, and the curable composition for forming an HC layer containing a cationic polymerizable compound contains a cationic photopolymerization initiator. It is preferable. Only one radical photopolymerization initiator may be used, or two or more radical photopolymerization initiators having different structures may be used in combination. The same applies to the cationic photopolymerization initiator. Hereafter, each photoinitiator is demonstrated one by one.
  • the radical photopolymerization initiator may be any radical photopolymerization initiator as long as it can generate a radical as an active species by light irradiation, and a known radical photopolymerization initiator can be used without any limitation. it can.
  • Specific examples include, for example, diethoxyacetophenone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, benzyldimethyl ketal, 4- (2-hydroxyethoxy) phenyl- (2-hydroxy-2-propyl) ) Ketone, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-2-morpholino (4-thiomethylphenyl) propan-1-one, 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) butanone, 2 -Hydroxy-2-methyl-1- [4- (1-methylvinyl) phenyl] propanone oligomer, 2-hydroxy-1- ⁇ 4- [4- (2-hydroxy-2-methyl-propionyl) -benzyl] Acetophenones such as phenyl ⁇ -2-methyl-propan-1-one; 1,2-octanedi 1- [4- (phenylthio)-, 2- (O-benzoyloxime)
  • Ruphosphine oxides and the like.
  • radical photopolymerization initiators and auxiliaries can be synthesized by known methods, and can also be obtained as commercial products.
  • the content of the radical photopolymerization initiator in the curable composition for forming an HC layer may be appropriately adjusted within a range in which the polymerization reaction (radical polymerization) of the radical polymerizable compound proceeds well, and is not particularly limited. Absent.
  • the amount is, for example, in the range of 0.1 to 20 parts by weight, preferably 0.5 to 10 parts by weight, more preferably 1 to 100 parts by weight of the radical polymerizable compound contained in the curable composition for forming an HC layer. It is in the range of ⁇ 10 parts by mass.
  • Any cationic photopolymerization initiator may be used as long as it can generate a cation as an active species by light irradiation, and any known cationic photopolymerization initiator can be used without any limitation. it can. Specific examples include known sulfonium salts, ammonium salts, iodonium salts (for example, diaryl iodonium salts), triaryl sulfonium salts, diazonium salts, iminium salts, and the like.
  • cationic photopolymerization initiators represented by formulas (25) to (28) shown in paragraphs 0050 to 0053 of JP-A-8-143806, paragraphs of JP-A-8-283320
  • the cationic photopolymerization initiator can be synthesized by a known method, and is also available as a commercial product. Examples of commercially available products include CI-1370, CI-2064, CI-2397, CI-2624, CI-2939, CI-2734, CI-2758, CI-2823, CI-2855, and CI-5102 manufactured by Nippon Soda.
  • PHOTOINITIATOR 2047 manufactured by Rhodia, UVI-6974, UVI-6990 manufactured by Union Carbide, and CPI-10P manufactured by San Apro can be used.
  • a diazonium salt, an iodonium salt, a sulfonium salt, and an iminium salt are preferable from the viewpoints of sensitivity of the photopolymerization initiator to light and stability of the compound. In terms of weather resistance, iodonium salts are most preferred.
  • iodonium salt-based cationic photopolymerization initiators include, for example, B2380 manufactured by Tokyo Chemical Industry, Midori Chemical BBI-102, WPI-113 manufactured by Wako Pure Chemical Industries, WPI-124 manufactured by Wako Pure Chemical Industries, Examples thereof include WPI-169 manufactured by Koyo Pure Chemical Industries, WPI-170 manufactured by Wako Pure Chemical Industries, and DTBPI-PFBS manufactured by Toyo Gosei.
  • the content of the cationic photopolymerization initiator in the curable composition for forming an HC layer may be appropriately adjusted within a range in which the polymerization reaction (cationic polymerization) of the cationic polymerizable compound proceeds favorably, and is not particularly limited. Absent. For example, it is in the range of 0.1 to 200 parts by weight, preferably 1 to 150 parts by weight, and more preferably 2 to 100 parts by weight with respect to 100 parts by weight of the cationically polymerizable compound.
  • photopolymerization initiators As other photopolymerization initiators, the photopolymerization initiators described in paragraphs 0052 to 0055 of JP-A-2009-204725 can also be mentioned, and the contents of this publication are incorporated in the present invention.
  • the curable composition for HC layer formation contains at least 1 type of component which has a property hardened
  • the curable composition for HC layer formation can contain the inorganic particle whose average primary particle diameter is less than 2 micrometers. From the viewpoint of improving the hardness of the front plate having the HC layer obtained by curing the curable composition for forming the HC layer (and further improving the hardness of the liquid crystal panel having the front plate), the curable composition for forming the HC layer and this composition are used.
  • the HC layer obtained by curing the material preferably contains inorganic particles having an average primary particle size of less than 2 ⁇ m.
  • the average primary particle size of the inorganic particles is preferably in the range of 10 nm to 1 ⁇ m, more preferably in the range of 10 nm to 100 nm, and still more preferably in the range of 10 nm to 50 nm.
  • the particles were observed with a transmission electron microscope (magnification 500,000 to 2,000,000 times), and 100 randomly selected particles (primary particles) were observed.
  • the average primary particle size is determined by the average value of the particle sizes.
  • examples of the inorganic particles include silica particles, titanium dioxide particles, zirconium oxide particles, and aluminum oxide particles. Of these, silica particles are preferred.
  • the surface of the inorganic particles is preferably treated with a surface modifier containing an organic segment in order to increase the affinity with the organic component contained in the HC layer forming curable composition.
  • a surface modifier those having a functional group capable of forming a bond with the inorganic particle or adsorbing to the inorganic particle and a functional group having high affinity with the organic component in the same molecule are preferable.
  • the surface modifier having a functional group capable of binding or adsorbing to inorganic particles include silane surface modifiers, metal alkoxide surface modifiers such as aluminum, titanium, and zirconium, phosphate groups, sulfate groups, sulfonate groups, and carboxyl groups.
  • a surface modifier having an anionic group such as an acid group is preferred.
  • the functional group having high affinity with the organic component include a functional group having hydrophilicity / hydrophobicity similar to that of the organic component, a functional group capable of being chemically bonded to the organic component, and the like.
  • a functional group that can be chemically bonded to an organic component is preferable, and an ethylenically unsaturated group or a ring-opening polymerizable group is more preferable.
  • a preferred inorganic particle surface modifier is a metal alkoxide surface modifier or a polymerizable compound having an anionic group and an ethylenically unsaturated group or ring-opening polymerizable group in the same molecule.
  • Specific examples of the surface modifier include the following exemplified compounds S-1 to S-8.
  • X represents a hydrogen atom or a methyl group
  • the surface modification of the inorganic particles with the surface modifier is preferably performed in a solution.
  • a surface modifier is present together, or after inorganic particles are mechanically dispersed, the surface modifier is added and stirred, or the inorganic particles are mechanically dispersed.
  • the surface may be modified before heating (if necessary, heated, dried and then heated, or changed in pH (power of hydrogen)), and then dispersed.
  • the solvent for dissolving the surface modifier an organic solvent having a large polarity is preferable. Specific examples include known solvents such as alcohols, ketones and esters.
  • the content of the inorganic particles is preferably 5 to 40% by mass and more preferably 10 to 30% by mass when the total solid content of the HC layer forming curable composition is 100% by mass.
  • the shape of the primary particles of the inorganic particles may be spherical or non-spherical, but the primary particles of the inorganic particles are preferably spherical, and in the HC layer obtained by curing the curable composition for HC layer formation, It is more preferable from the viewpoint of further improving the hardness that the inorganic particles (primary particles) are present as higher-order particles of non-spherical secondary particles or more connected to each other.
  • the inorganic particles include ELCOM V-8802 (spherical silica particles having an average primary particle size of 15 nm manufactured by JGC Catalysts and Chemicals), ELCOM V-8803 (deformed silica particles manufactured by JGC Catalysts and Chemicals), MiBK-SD ( (Spherical silica particles with an average primary particle size of 10-20 nm manufactured by Nissan Chemical Industries), MEK-AC-2140Z (spherical silica particles with an average primary particle size of 10-20 nm manufactured by Nissan Chemical Industries), MEK-AC-4130 (Nissan Chemical Industries) Spherical silica particles having an average primary particle size of 45 nm, MiBK-SD-L (spherical silica particles having an average primary particle size of 40 to 50 nm manufactured by Nissan Chemical Industries), MEK-AC-5140Z (average primary by Nissan Chemical Industries, Ltd.) And spherical silica particles having a particle diameter of 85 nm).
  • Matte particles mean particles having an average primary particle diameter of 2 ⁇ m or more, and may be inorganic particles, organic particles, or particles of an inorganic / organic composite material.
  • the shape of the mat particles may be spherical or non-spherical.
  • the average primary particle size of the mat particles is preferably in the range of 2 to 20 ⁇ m, more preferably in the range of 4 to 14 ⁇ m, and still more preferably in the range of 6 to 10 ⁇ m.
  • the mat particles include inorganic particles such as silica particles and TiO 2 particles, and organic particles such as crosslinked acrylic particles, crosslinked acrylic-styrene particles, crosslinked styrene particles, melamine resin particles, and benzoguanamine resin particles.
  • the mat particles are preferably organic particles, and more preferably crosslinked acrylic particles, crosslinked acrylic-styrene particles, and crosslinked styrene particles.
  • the mat particles preferably have a content per unit volume in the HC layer obtained by curing the curable composition for forming an HC layer of 0.10 g / cm 3 or more, and 0.10 g / cm 3 to 0.40 g / More preferably, it is cm 3 , and more preferably 0.10 g / cm 3 to 0.30 g / cm 3 .
  • the curable composition for HC layer formation contains a ultraviolet absorber.
  • the ultraviolet absorber include benzotriazole compounds and triazine compounds.
  • the benzotriazole compound is a compound having a benzotriazole ring, and specific examples include various benzotriazole ultraviolet absorbers described in paragraph 0033 of JP2013-111835A.
  • the triazine compound is a compound having a triazine ring, and specific examples thereof include various triazine-based UV absorbers described in paragraph 0033 of JP2013-111835A.
  • the content of the ultraviolet absorber in the resin film is, for example, about 0.1 to 10 parts by mass with respect to 100 parts by mass of the resin contained in the film, but is not particularly limited.
  • the UV absorber reference can also be made to paragraph 0032 of JP2013-111835A.
  • ultraviolet rays refer to light having an emission center wavelength in the wavelength band of 200 to 380 nm.
  • the curable composition for HC layer formation contains fluorine-containing compounds, such as a leveling agent and an antifouling agent.
  • a fluorine-containing polymer is preferably used.
  • a fluoroaliphatic group-containing polymer described in Japanese Patent No. 5175831 can be mentioned.
  • a fluoroaliphatic group-containing polymer having a fluoroaliphatic group-containing monomer represented by the general formula (1) constituting the fluoroaliphatic group-containing polymer and having a content of 50% by mass or less of the total polymerization units is used as a leveling agent. You can also.
  • the HC layer contains an antifouling agent, adhesion of fingerprints and dirt can be reduced, and the attached dirt can be easily wiped off. Further, it is possible to further improve the abrasion resistance by improving the slip property of the surface.
  • the content is preferably 0.01 to 7% by mass, preferably 0.05 to 5% by mass of the solid content of the curable composition for HC layer formation. % Is more preferable, and 0.1 to 2% by mass is more preferable.
  • the curable composition for HC layer formation may contain only 1 type of antifouling agents, and may contain 2 or more types. When 2 or more types are contained, it is preferable that the total amount becomes the said range.
  • the curable composition for HC layer formation can also be set as the structure which does not contain an antifouling agent substantially.
  • the antifouling agent preferably contains a fluorine-containing compound.
  • the fluorine-containing compound may be a monomer, oligomer, or polymer.
  • Fluorine-containing compound (fluorine-containing antifouling agent) as an antifouling agent forms a bond with other components in the HC layer (for example, a polysiloxane compound described later, a polymerizable monomer that is a constituent of a resin, or a resin).
  • it preferably has a substituent that contributes to compatibility. These substituents may be the same or different, and a plurality of substituents are preferable.
  • This substituent is preferably a polymerizable group, and may be any polymerizable reactive group exhibiting any one of radical polymerizable, cationic polymerizable, anionic polymerizable, polycondensable and addition polymerizable.
  • preferable substituents Includes acryloyl group, methacryloyl group, vinyl group, allyl group, cinnamoyl group, epoxy group, oxetanyl group, hydroxyl group, polyoxyalkylene group, carboxyl group, and amino group.
  • a radical polymerizable group is preferable, and an acryloyl group and a methacryloyl group are particularly preferable.
  • the fluorine-containing compound may be a polymer or an oligomer with a compound containing no fluorine atom.
  • the fluorine-containing antifouling agent is preferably a fluorine compound represented by the following general formula (F).
  • F fluorine compound represented by the following general formula (F).
  • R f is a (per) fluoroalkyl group or (per) fluoropolyether group
  • W is a single bond or linking group
  • R A is a polymerizable unsaturated group
  • n is an integer of 1 to 3.
  • M represents an integer of 1 to 3.
  • R A represents a polymerizable unsaturated group.
  • the polymerizable unsaturated group is preferably a group having an unsaturated bond that can cause a radical polymerization reaction by irradiation with an active energy ray such as an ultraviolet ray or an electron beam (that is, a radical polymerizable group).
  • an active energy ray such as an ultraviolet ray or an electron beam
  • examples include acryloyl group, (meth) acryloyloxy group, vinyl group, allyl group, (meth) acryloyl group, (meth) acryloyloxy group, and groups in which any hydrogen atom in these groups is substituted with a fluorine atom Is preferably used.
  • Rf represents a (per) fluoroalkyl group or a (per) fluoropolyether group.
  • “(per) fluoroalkyl group” represents at least one of a fluoroalkyl group and a perfluoroalkyl group
  • “(per) fluoropolyether group” means a fluoropolyether group and a perfluoropolyether group. Represents at least one of them. From the viewpoint of abrasion resistance, the fluorine content in R f is preferably higher.
  • the (per) fluoroalkyl group is preferably a group having 1 to 20 carbon atoms, more preferably a group having 1 to 10 carbon atoms.
  • the (per) fluoroalkyl group has a linear structure (for example, —CF 2 CF 3 , —CH 2 (CF 2 ) 4 H, —CH 2 (CF 2 ) 8 CF 3 , —CH 2 CH 2 (CF 2 ) 4 H) even in branched structures (eg —CH (CF 3 ) 2 , —CH 2 CF (CF 3 ) 2 , —CH (CH 3 ) CF 2 CF 3 , —CH (CH 3 ) (CF 2 ) 5 CF 2 H) even in an alicyclic structure (preferably a 5- or 6-membered ring, such as a perfluorocyclohexyl group and a perfluorocyclopentyl group and an alkyl group substituted with these groups) There may be.
  • the (per) fluoropolyether group refers to a case where the (per) fluoroalkyl group has an ether bond, and may be a monovalent or divalent group.
  • the fluoropolyether group include —CH 2 OCH 2 CF 2 CF 3 , —CH 2 CH 2 OCH 2 C 4 F 8 H, —CH 2 CH 2 OCH 2 CH 2 C 8 F 17 , —CH 2 CH 2 OCF 2 CF 2 OCF 2 CF 2 H, C 4-20 fluorocycloalkyl group having 4 or more fluorine atoms, and the like can be given.
  • perfluoropolyether group for example, — (CF 2 O) p — (CF 2 CF 2 O) q —, — [CF (CF 3 ) CF 2 O] p — [CF (CF 3 )] q -,-(CF 2 CF 2 CF 2 O) p -,-(CF 2 CF 2 O) p- and the like.
  • P and q each independently represents an integer of 0 to 20.
  • p + q is an integer of 1 or more.
  • the total of p and q is preferably 1 to 83, more preferably 1 to 43, and still more preferably 5 to 23.
  • the fluorine-containing antifouling agent particularly preferably has a perfluoropolyether group represented by — (CF 2 O) p — (CF 2 CF 2 O) q — from the viewpoint of excellent abrasion resistance.
  • the fluorine-containing antifouling agent preferably has a perfluoropolyether group and a plurality of polymerizable unsaturated groups in one molecule.
  • W represents a linking group.
  • W include an alkylene group, an arylene group, a heteroalkylene group, and a linking group obtained by combining these groups. These linking groups may further have an oxy group, a carbonyl group, a carbonyloxy group, a carbonylimino group, a sulfonamide group, and the like, and a functional group in which these groups are combined.
  • W is preferably an ethylene group, more preferably an ethylene group bonded to a carbonylimino group.
  • the fluorine atom content of the fluorine-containing antifouling agent is not particularly limited, but is preferably 20% by mass or more, more preferably 30 to 70% by mass, and further preferably 40 to 70% by mass.
  • fluorine-containing antifouling agents examples include R-2020, M-2020, R-3833, M-3833, Optool DAC (trade name) manufactured by Daikin Chemical Industries, Ltd., Dainippon Ink Co., Ltd. Mega-Fucks F-171, F-172, F-179A, RS-78, RS-90, defender MCF-300 and MCF-323 (named above) are not limited thereto.
  • the product of n and m (n ⁇ m) is preferably 2 or more, and more preferably 4 or more.
  • R f2 represents a fluorine atom or a fluoroalkyl group having 1 to 10 carbon atoms
  • R 11 represents a hydrogen atom or a methyl group
  • R 21 represents a single bond or an alkylene group
  • R 22 Represents a single bond or a divalent linking group
  • p is an integer indicating the degree of polymerization
  • the degree of polymerization p is k (k is an integer of 3 or more) or more.
  • R 22 represents a divalent linking group
  • examples of the divalent linking group include the same groups as those described above for W.
  • telomer type (meth) acrylate containing a fluorine atom in the general formula (F-1) examples include a (meth) acrylic acid part or a fully fluorinated alkyl ester derivative.
  • the compound represented by the general formula (F-1) depends on the conditions of telomerization and the separation conditions of the reaction mixture.
  • P in the group R f2 (CF 2 CF 2 ) p R 22 CH 2 CH 2 R 21 O— contains a plurality of fluorine-containing (meth) acrylic acid esters such as k, k + 1, k + 2,. There is.
  • Formula (F-2) F (CF 2 ) q —CH 2 —CHX—CH 2 Y (wherein q is an integer of 1 to 20, X and Y represent a (meth) acryloyloxy group or a hydroxyl group, and at least one of X and Y is ( (Meth) acryloyloxy group.)
  • the fluorine-containing (meth) acrylic acid ester represented by the general formula (F-2) has a fluoroalkyl group having 1 to 20 carbon atoms having a trifluoromethyl group (—CF 3 ) at its terminal. Even if the fluorine-containing (meth) acrylic acid ester is in a small amount, the trifluoromethyl group is effectively oriented on the surface.
  • Q is preferably 6 to 20, and more preferably 8 to 10, in terms of abrasion resistance and ease of production of the compound.
  • the fluorine-containing (meth) acrylic acid ester having a fluoroalkyl group having 8 to 10 carbon atoms is excellent in reducing the friction coefficient compared with other fluorine-containing (meth) acrylic acid esters having a fluoroalkyl group having a chain length. Excellent effect on abrasion due to the effect.
  • fluorine-containing (meth) acrylic acid ester represented by the general formula (F-2) include 1- (meth) acryloyloxy-2-hydroxy-4,4,5,5,6,6,7 , 7,8,8,9,9,10,10,11,11,12,12,13,13,13-heneicosafluorotridecane, 2- (meth) acryloyloxy-1-hydroxy-4, 4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-heneicosafluorotridecane and 1,2 -Bis (meth) acryloyloxy 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-hen Examples include eicosafluorotridecane.
  • the fluorine atom-containing monofunctional (meth) acrylate represented by the general formula (F-3) reacts with a fluorine atom-containing alcohol compound represented by the following general formula (FG-3) and a (meth) acrylic acid halide. Can be obtained.
  • fluorine atom-containing alcohol compound represented by the general formula (FG-3) include 1H, 1H-perfluoro-3,6-dioxaheptan-1-ol, 1H, 1H-perfluoro-3, 6-Dioxaoctane-1-ol, 1H, 1H-perfluoro-3,6-dioxadecan-1-ol, 1H, 1H-perfluoro-3,6,9-trioxadecan-1-ol, 1H, 1H- Perfluoro-3,6,9-trioxaundecan-1-ol, 1H, 1H-perfluoro-3,6,9-trioxatridecan-1-ol, 1H, 1H-perfluoro-3,6,9,12 -Tetraoxatridecan-1-ol, 1H, 1H-perfluoro-3,6,9,12-tetraoxatridecan-1-ol, 1H, 1H-perfluoro-3
  • Examples of the (meth) acrylic acid halide to be reacted with the fluorine atom-containing alcohol compound represented by the general formula (FG-3) include (meth) acrylic acid fluoride, (meth) acrylic acid chloride, and (meth) acrylic acid. Examples thereof include bromide and (meth) acrylic acid iodide. From the viewpoint of availability, (meth) acrylic acid chloride is preferred.
  • the compound represented by the general formula (F-3) ′ has the general formula (FG-3) ′: — (CX 6 2 CF 2 CF 2 O) — in the R f3 group, wherein X 6 is F or H) and a fluorine-containing unsaturated compound having 6 or more repeating units.
  • FG-3) ′ As a polymerizable unsaturated group of the said fluorine-containing polyether compound, what contains the following structures can be used preferably.
  • the fluorine-containing polyether compound represented by the general formula (F-3) ′ may have a plurality of polymerizable unsaturated groups.
  • a compound having a structure of —O (C ⁇ O) CF ⁇ CH 2 is preferable in that it has a particularly high polymerization (curing) reactivity and can efficiently obtain a cured product.
  • the fluorine-containing polyether compound represented by the above general formula (F-3) ′ contains 6 or more fluorine-containing polyether chains represented by the general formula (FG-3) ′ as repeating units in the R f3 group. It is important to be able to impart rub resistance. More specifically, a mixture containing 6 or more repeating units of a fluorine-containing polyether chain may be used, but when used in the form of a mixture, the fluorine-containing unsaturated compound having less than 6 repeating units and In the distribution with 6 or more fluorine-containing unsaturated compounds, it is preferable that the mixture has the highest abundance ratio of the fluorine-containing unsaturated compounds having 6 or more polyether chain repeating units.
  • the number of repeating units of the fluorine-containing polyether chain represented by the general formula (FG-3) ′ is preferably 6 or more, more preferably 10 or more, still more preferably 18 or more, and particularly preferably 20 or more. As a result, the dynamic friction coefficient can be reduced and the abrasion resistance can be improved.
  • the fluorine-containing polyether chain may be present at the end of the R f3 group or in the chain.
  • R f3 group is: Formula (c-4): R 4 — (CX 6 2 CF 2 CF 2 O) t — (R 5 ) e — (wherein X 6 is a fluorine-containing polyether chain represented by the formula (FG-3) ′, and R 4 is a hydrogen atom , A halogen atom, an alkyl group, a fluorine-containing alkyl group, an alkyl group containing an ether bond or a fluorine-containing alkyl group containing an ether bond, R 5 is a divalent or higher organic group, t is an integer of 6 to 66, and e is 0 or Represents a group represented by 1).
  • the R f3 group is a fluorine-containing organic group which is bonded to a reactive carbon-carbon double bond via a divalent or higher-valent organic group R 5 and further has R 4 at the terminal.
  • R 5 may be any organic group that can bind the fluorine-containing polyether chain represented by the general formula (FG-3) ′ to a reactive carbon-carbon double bond. Examples thereof include an alkylene group, a fluorine-containing alkylene group, an alkylene group containing an ether bond, and a fluorine-containing alkylene group containing an ether bond. Among these, a fluorine-containing alkylene group and a fluorine-containing alkylene group containing an ether bond are preferable in terms of transparency and low refractive index.
  • fluorine-containing polyether compound represented by the general formula (F-3) ′ compounds exemplified in a republished patent WO2003 / 022906 pamphlet are preferably used.
  • CH 2 ⁇ CF—COO—CH 2 CF 2 CF 2 — (OCF 2 CF 2 CF 2 ) 7 —OC 3 F 7 can be used particularly preferably.
  • R f1 represents a (per) fluoroalkyl group or (per) fluoropolyether group
  • W represents a linking group
  • R A represents a polymerizable unsaturated group
  • n represents 1 to 3.
  • n is preferably 2 to 3
  • m is preferably 1 to 3
  • n is 2 to 3
  • m is 2 Is more preferably 3
  • n is more preferably 3
  • m is more preferably 2 to 3.
  • R f1 may be monovalent to trivalent.
  • terminal groups are (C n F 2n + 1 )-, (C n F 2n + 1 O)-, (XC n F 2n O)-, (XC n F 2n + 1 )-(wherein X is A hydrogen atom, a chlorine atom, or a bromine atom, and n is preferably an integer of 1 to 10.
  • CF 3 O (C 2 F 4 O) p CF 2 —, C 3 F 7 O (CF 2 CF 2 CF 2 O) pCF 2 CF 2 —, C 3 F 7 O (CF (CF 3 ) CF 2 O) p CF (CF 3 ) —, F (CF (CF 3 ) CF 2 O) p CF (CF 3 ) — and the like can be preferably used.
  • the average value of p is 0-50.
  • the number is preferably 3 to 30, more preferably 3 to 20, and still more preferably 4 to 15.
  • R f1 is divalent, — (CF 2 O) q (C 2 F 4 O) r CF 2 —, — (CF 2 ) 3 O (C 4 F 8 O) r (CF 2 ) 3 —, —CF 2 O (C 2 F 4 O) r CF 2 —, —C 2 F 4 O (C 3 F 6 O) r C 2 F 4 —, —CF (CF 3 ) (OCF 2 CF (CF 3 ) ) s OC t F 2t O ( C F (CF 3) CF 2 O) r CF (CF 3) - and the like can be preferably used.
  • the average value of q, r, and s in the formula is 0-50. It is preferably 3 to 30, more preferably 3 to 20, and most preferably 4 to 15. t is an integer of 2 to 6.
  • Preferred specific examples and synthesis methods of the compound represented by formula (F-4) are described in International Publication No. 2005/113690.
  • F (CF (CF 3 ) CF 2 O) p CF (CF 3 ) — having an average value of p of 6 to 7 is referred to as “HFPO-”, and — (CF (CF 3 ) CF 2 O) p CF (CF 3 ) — having an average value of p of 6 to 7 is referred to as “—HFPO—” and represents a specific compound of the general formula (F-4), but is not limited thereto. It is not a thing.
  • the compound in which the polymerizable unsaturated group is a (meth) acryloyloxy group may have a plurality of (meth) acryloyloxy groups. Since the fluorine-containing antifouling agent has a plurality of (meth) acryloyloxy groups, when cured, it exhibits a three-dimensional network structure, a high glass transition temperature, and a low transferability of the antifouling agent. In addition, durability against repeated wiping of dirt can be improved. Furthermore, an HC layer excellent in heat resistance, weather resistance and the like can be obtained.
  • Specific examples of the compound represented by the general formula (F-5) include, for example, di (meth) acrylic acid-2,2,2-trifluoroethylethylene glycol, di (meth) acrylic acid-2,2 , 3,3,3-pentafluoropropylethylene glycol, di (meth) acrylic acid-2,2,3,3,4,4,4-heptafluorobutylethylene glycol, di (meth) acrylic acid-2,2 , 3,3,4,4,5,5,5-nonafluoropentylethylene glycol, di (meth) acrylic acid-2,2,3,3,4,4,5,5,6,6,6- Undecafluorohexylethylene glycol, di (meth) acrylic acid-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptylethylene glycol, di (meth) Acrylic acid-2,2, , 3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctylethylene glycol, di (meth)
  • di (meth) acrylic acid ester can be prepared by a known method as described in JP-A-6-306326.
  • diacrylic acid-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononylethylene glycol is preferred. Used.
  • the compound in which the polymerizable unsaturated group is a (meth) acryloyloxy group is a compound having a plurality of (per) fluoroalkyl groups or (per) fluoropolyether groups in one molecule. There may be.
  • the weight average molecular weight (Mw) of the fluorine-containing compound having a polymerizable unsaturated group can be measured using molecular exclusion chromatography such as gel permeation chromatography (GPC).
  • Mw of the fluorine-containing compound used in the present invention is preferably 400 or more and less than 50000, more preferably 400 or more and less than 30000, and still more preferably 400 or more and less than 25000. It is preferable for it to be at least the above lower limit value because the surface migration property of the antifouling agent in the HC layer becomes high.
  • the amount is less than the above upper limit value, the surface migration of the fluorine-containing compound is not hindered during the step of curing after applying the curable composition for forming the HC layer, and the uneven distribution on the surface of the HC layer is further prevented. It is preferable because it tends to occur uniformly and the abrasion resistance and film hardness are improved.
  • the fluorine-containing compound may be multimodal with respect to the weight average molecular weight.
  • the amount of the fluorine-containing compound added is preferably 0.01 to 5% by mass, more preferably 0.1 to 5% by mass, and more preferably 0.5 to 0.5% by mass with respect to the total solid content in the HC layer forming curable composition. 5% by mass is more preferable, and 0.5-2% by mass is particularly preferable.
  • the addition amount is equal to or more than the above upper limit value, the friction coefficient against steel wool can be reduced, and the abrasion resistance is further improved.
  • the addition amount is not more than the above lower limit value, a fluorine-containing compound that is insufficiently mixed with the polymerizable compound (resin component when forming the HC layer) in the curable composition for forming the HC layer is formed on the surface. This is preferable because it does not precipitate and suppresses whitening of the HC layer and generation of white powder on the surface.
  • the HC layer has a laminated structure of two or more layers, which will be described later, it means an addition amount in the curable composition for forming an HC layer that forms an HC layer containing a fluorine-containing compound.
  • the antifouling agent has a polymerizable group, it is treated as not corresponding to the polymerizable compounds 1 to 3 and the other polymerizable compounds.
  • a leveling agent and an antifouling agent described in (vi) other components described later can also be contained.
  • Antifouling agents that can be used in the present invention are not limited to the above-mentioned fluorine-containing compounds as long as they can impart antifouling properties, and compounds having a polysiloxane structure in their molecules (polysiloxane compounds) ) May be used, or these may be used in combination.
  • the polysiloxane compound is not particularly limited, and a compound having a polysiloxane structure in the molecule can be used.
  • the polysiloxane structure of the polysiloxane-containing compound may be linear, branched, or cyclic.
  • the above polysiloxane compound is preferably represented by the following general formula (F-6).
  • R a R A b SiO (4-ab) / 2 (In the formula, R is a hydrogen atom, a methyl group, an ethyl group, a propyl group, or a phenyl group, RA is an organic group containing a polymerizable unsaturated group, and 0 ⁇ a, 0 ⁇ b, a + b ⁇ 4 .)
  • a is preferably 1 to 2.75, more preferably 1 to 2.5, and if it is 1 or more, the synthesis of the compound is industrially easy, and if it is 2.75 or less, curability and film hardness are reduced. It becomes easy to balance.
  • the polymerizable unsaturated group in R A, the general formula (F) in R A similar polymerizable unsaturated group include, preferably (meth) acryloyl group, (meth ) An acryloyloxy group and a group in which any hydrogen atom in these groups is substituted with a fluorine atom.
  • the polysiloxane antifouling agent also preferably has a plurality of polymerizable unsaturated groups in one molecule from the viewpoint of film strength, and more preferably a polydimethylsiloxane having a plurality of polymerizable unsaturated groups in one molecule. .
  • the polysiloxane compound include those having a substituent at the terminal and / or side chain of a compound chain containing a plurality of dimethylsilyloxy units as repeating units.
  • the compound chain containing dimethylsilyloxy as a repeating unit may contain a structural unit other than dimethylsilyloxy.
  • These substituents may be the same or different, and a plurality of substituents are preferable.
  • This substituent is preferably a polymerizable group, and may be any polymerizable group indicating group that exhibits any of radical polymerizable, cationic polymerizable, anionic polymerizable, polycondensable and addition polymerizable.
  • substituents examples include (meth) acryloyl group, ((meth) acryloyloxy) group, vinyl group, allyl group, cinnamoyl group, epoxy group, oxetanyl group, hydroxyl group, fluoroalkyl group, polyoxyalkylene group, carboxyl group And groups containing an amino group and the like.
  • a radical polymerizable group is preferable, and a (meth) acryloyloxy group is particularly preferable from the viewpoint of improving the film hardness.
  • the number of substituents in the compound is preferably from 100 to 10000 g / mol as functional group equivalent from the viewpoint of film strength, more preferably from 100 to 3000 g / mol, still more preferably from 100 to 2000 g / mol, and from 100 to 1000 g / mol. Mol is particularly preferred.
  • the functional group equivalent to the above lower limit value or more, the polymerizable compound (resin component for forming the HC layer) in the curable composition for forming the HC layer is not more than necessary and is antifouling. It is preferable because the surface migration property of the agent in the HC layer is increased. It is preferable to make the functional group equivalent not more than the above upper limit value because the film hardness can be improved.
  • R A is preferably an organic group containing a (meth) acryloyl group, and the bond to the Si atom is more preferably a Si—O—C bond for ease of industrial synthesis.
  • b is preferably 0.4 to 0.8, more preferably 0.6 to 0.8.
  • a + b is preferably 3 to 3.7, more preferably 3 to 3.5. If it is at least the above lower limit value, the compound tends to be unevenly distributed on the surface of the HC layer, and if it is at most the above upper limit value, both the curability and the film hardness can be improved.
  • the polysiloxane compound preferably has 3 or more Si atoms in one molecule, and more preferably 3 to 40 Si atoms. When there are 3 or more Si atoms, the uneven distribution of the compound on the surface of the HC layer is promoted, and sufficient film hardness is more easily obtained.
  • the polysiloxane compound can be produced using a known method described in JP-A No. 2007-14584.
  • the additive having a polysiloxane structure include polysiloxane ⁇ for example, “KF-96-10CS”, “KF-100T”, “X-22-169AS”, “KF-102”, “X-22-3701IE”, “X-22-164”, “X-22-164A”, “X-22-164AS”, “X-22-164B”, “X-22-164C”, “X-22-5002”, “X -22-173B “,” X-22-174D ",” X-22-167B “,” X-22-161AS "(trade name), manufactured by Shin-Etsu Chemical Co., Ltd .;” AK-5 ", “AK-30”, “AK-32” (trade name), manufactured by Toa Gosei Co., Ltd .; “Silaplane FM0725”, “Silaplane FM0721” (trade name), manufactured by Chisso Corporation; DMS-U22
  • Molecular weight of polysiloxane compound 300 or more are preferable, as for the weight average molecular weight of a polysiloxane compound, 300 or more and 100,000 or less are more preferable, and 300 or more and 30000 or less are more preferable.
  • the weight average molecular weight of the polysiloxane compound is 300 or more, uneven distribution of the polysiloxane compound on the surface of the HC layer is promoted, and the abrasion resistance and hardness are further improved.
  • the addition amount of the polysiloxane compound is preferably 0.01 to 5% by mass, more preferably 0.1 to 5% by mass, and more preferably 0.5% by mass with respect to the total solid content in the HC layer forming curable composition. Is more preferably from 5 to 5% by weight, particularly preferably from 0.5 to 2% by weight.
  • the addition amount is not less than the above lower limit value, the adhesion resistance after keystroke can be further improved.
  • the addition amount is not more than the above upper limit value, the polysiloxane compound with insufficient mixing with the polymerizable compound (resin component when forming the HC layer) in the curable composition for forming the HC layer is formed on the surface.
  • the HC layer is not whitened or white powder is generated on the surface.
  • the HC layer has a laminated structure of two or more layers to be described later, it means an addition amount in the curable composition for forming the HC layer that forms the HC layer containing the polysiloxane compound.
  • the curable composition for HC layer formation contains a solvent.
  • a solvent an organic solvent is preferable, and one or more organic solvents can be mixed and used in an arbitrary ratio.
  • the organic solvent include alcohols such as methanol, ethanol, propanol, n-butanol and i-butanol; ketones such as acetone, methyl isobutyl ketone, methyl ethyl ketone and cyclohexanone; cellosolves such as ethyl cellosolve; toluene And aromatics such as xylene; glycol ethers such as propylene glycol monomethyl ether; acetates such as methyl acetate, ethyl acetate and butyl acetate; diacetone alcohol and the like.
  • cyclohexanone, methyl ethyl ketone, methyl isobutyl ketone, and methyl acetate are preferable, and it is more preferable to use cyclohexanone, methyl ethyl ketone, methyl isobutyl ketone, and methyl acetate in an arbitrary ratio.
  • the optical film excellent in abrasion resistance, punching property, and adhesiveness is obtained.
  • the amount of the solvent in the curable composition for forming the HC layer can be appropriately adjusted as long as the application suitability of the composition can be ensured.
  • the solvent can be 50 to 500 parts by mass, preferably 80 to 200 parts by mass with respect to 100 parts by mass of the total amount of the polymerizable compound and the photopolymerization initiator.
  • the solid content of the HC-forming curable composition is preferably 10 to 90% by mass, more preferably 50 to 80% by mass, and particularly preferably 65 to 75% by mass.
  • the curable composition for HC layer formation can contain 1 or more types of well-known additive in arbitrary quantity.
  • the additive include a surface conditioner, a leveling agent, a polymerization inhibitor, and a polyrotaxane.
  • a commercially available antifouling agent or an antifouling agent that can be prepared by a known method can also be included.
  • the additive is not limited to these, and various additives that can be generally added to the curable composition for HC layer formation can be used.
  • the curable composition for HC layer formation can also contain a well-known solvent in arbitrary amounts.
  • the curable composition for HC layer formation can be prepared by mixing the various components described above simultaneously or sequentially in an arbitrary order.
  • the preparation method is not particularly limited, and a known stirrer or the like can be used for the preparation.
  • the optical film of the present invention preferably has an embodiment in which the HC layer 3A in FIG. 2 has at least the first HC layer and the second HC layer in this order from the resin film 1A side. Even if the 1st HC layer is located in the surface of 1 A of resin films, you may have another layer in between. Similarly, even if the second HC layer is located on the surface of the first HC layer, another layer may be provided therebetween. From the viewpoint of improving the adhesion between the first HC layer and the second HC layer, the second HC layer is located on the surface of the first HC layer, that is, both layers are at least part of the film surface. It is preferable to contact.
  • the first HC layer and the second HC layer may be one layer or two or more layers, respectively, but one layer is preferable.
  • the antifouling agent is preferably contained at least in the HC layer farthest from the resin film, and may be contained only in the HC layer farthest from the resin film. More preferred.
  • the optical film of the present invention when used for a touch panel, the optical film is preferably arranged so that the second HC layer is on the front side of the image display element.
  • the second HC layer is preferably disposed on the surface side of the optical film, particularly on the outermost surface.
  • the first HC layer used in the present invention is formed from the first curable composition for HC layer formation.
  • the first curable composition for HC layer formation is different from the polymerizable compound 1 having a radical polymerizable group, and having a cationic polymerizable group and a radical polymerizable group in the same molecule, and different from the polymerizable compound 1.
  • the content of the polymerizable compound 2 is 51% by mass or more.
  • the first curable composition for HC layer formation may have another polymerizable compound different from the polymerizable compound 1 and the polymerizable compound 2.
  • the other polymerizable compound is preferably a polymerizable compound having a cationic polymerizable group.
  • the cationic polymerizable group has the same meaning as the cationic polymerizable group described in the polymerizable compound 2, and the preferred range is also the same.
  • a nitrogen-containing heterocyclic ring-containing compound containing a cationic polymerizable group is preferable as the other polymerizable compound.
  • the adhesiveness between the resin film and the first HC layer can be improved more effectively.
  • the nitrogen-containing heterocycle include isocyanurate rings (nitrogen-containing heterocycles contained in exemplified compounds B-1 to B-3 described later) and glycoluril rings (nitrogen-containing heterocycles contained in exemplified compound B-10 described later).
  • a nitrogen-containing heterocyclic ring selected from the group consisting of is exemplified, and an isocyanurate ring is more preferable.
  • the number of cationic groups possessed by other polymerizable compounds is preferably 1 to 10, more preferably 2 to 5.
  • the resin film is preferably a resin film including an acrylic resin film. By setting it as such a structure, it exists in the tendency for the adhesiveness of a resin film and a 1st HC layer to improve more.
  • Specific examples of the other polymerizable compounds include the above-described exemplary compounds B-1 to B-14, but the present invention is not limited to the specific examples described above.
  • the description of the above-mentioned polymerization initiator, inorganic particles, matte particles, ultraviolet absorbers, fluorine-containing compounds, solvents and other components can be preferably applied.
  • the first HC layer forming curable composition preferably includes a solvent
  • the second HC layer forming curable composition preferably includes an antifouling agent.
  • the thickness of the HC layer is preferably 3 ⁇ m to 100 ⁇ m, more preferably 5 ⁇ m to 70 ⁇ m, and even more preferably 10 ⁇ m to 50 ⁇ m.
  • the pencil hardness of the HC layer is preferably as high as possible, specifically 3H or higher, more preferably 5H or higher, and even more preferably 7H or higher.
  • the HC layer can be formed by applying the curable composition for forming the HC layer directly on the resin film or through another layer such as an easy-adhesion layer and irradiating with active energy rays.
  • the coating can be performed by a known coating method such as a dip coating method, an air knife coating method, a curtain coating method, a roller coating method, a die coating method, a wire bar coating method, or a gravure coating method.
  • the HC layer can also be formed as an HC layer having a laminated structure of two or more layers (for example, about 2 to 5 layers) by simultaneously or sequentially applying two or more kinds of compositions having different compositions.
  • An HC layer can be formed by irradiating the applied curable composition for forming an HC layer with active energy rays.
  • the curable composition for HC layer formation contains a radical polymerizable compound, a cationic polymerizable compound, a radical photopolymerization initiator, and a cationic photopolymerization initiator
  • the polymerization reaction of the radical polymerizable compound and the cationic polymerizable compound is performed.
  • Each can be initiated and advanced by the action of a radical photopolymerization initiator and a cationic photopolymerization initiator. What is necessary is just to determine the wavelength of the light to irradiate according to the kind of polymeric compound and polymerization initiator to be used.
  • Light sources for light irradiation include high-pressure mercury lamps that emit light in the 150 to 450 nm wavelength band, ultrahigh-pressure mercury lamps, carbon arc lamps, metal halide lamps, xenon lamps, chemical lamps, electrodeless discharge lamps, and LEDs (Light Emitting Diodes). Etc. Moreover, the light irradiation amount is generally in the range of 30 ⁇ 3000mJ / cm 2, preferably in the range of 100 ⁇ 1500mJ / cm 2. You may perform a drying process as needed in one or both before and after light irradiation. The drying process can be performed by blowing warm air, disposing in a heating furnace, conveying in the heating furnace, or the like. When the curable composition for HC layer formation contains a solvent, the heating temperature may be set to a temperature at which the solvent can be removed by drying, and is not particularly limited. Here, the heating temperature refers to the temperature of warm air or the atmospheric temperature in the heating furnace.
  • the optical film of the present invention may have a shock absorbing layer on the surface of the resin film opposite to the surface having the HC layer.
  • the impact absorbing layer absorbs the impact received from the HC layer side.
  • the optical film of the present invention is used as a front plate of an image display device, the image is disposed on the side opposite to the HC layer side. Damage to the display element can be prevented.
  • the shock absorbing layer material When the optical film of the present invention is used as a front plate of an image display device, the shock absorbing layer has transparency capable of ensuring the visibility of display contents, and is derived from pressing onto the front plate and collision.
  • the image display element may be made of resin or may be made of elastomer (including oil-extended rubber).
  • the resin include 1,2-polybutadiene resin, ethylene-vinyl acetate copolymer (abbreviated as “EVA”, usually containing 3% by mass or more of vinyl acetate units), polyolefin resin such as polyethylene, polyvinyl chloride, and the like.
  • Resin polystyrene resin, vinyl ester resin (excluding EVA), saturated polyester resin, polyamide resin, fluororesin (polyvinylidene fluoride, etc.), polycarbonate resin, polyacetal resin, urethane resin, epoxy resin, (meth) acrylic resin, unsaturated Examples thereof include polyester resins and silicon resins, and modified resins of these resins. Of these resins, urethane-modified polyester resins, urethane resins, (meth) acrylic resins, and the like are preferable.
  • Elastomers include conjugated diene block (co) polymers, acrylic block (co) polymers, styrene block (co) polymers, block copolymers of aromatic vinyl compounds and conjugated dienes, and conjugated diene blocks. Hydrogenated products of (co) polymers, hydrogenated products of block copolymers of aromatic vinyl compounds and conjugated dienes, ethylene- ⁇ -olefin copolymers, polar group modified olefin copolymers, polar group modified Elastomers composed of olefin copolymers and metal ions and / or metal compounds, nitrile rubbers such as acrylonitrile-butadiene rubber, butyl rubber, acrylic rubber, thermoplastic polyolefin elastomer (TPO), thermoplastic polyurethane elastomer ( TPU), thermoplastic polyester elastomer (TPEE), polyamide Elastomer (TPAE), thermoplastic elastomers such as diene-based elastomer (1,2-poly
  • These resins or elastomers can be composed of only the polymer when constituting the shock absorbing layer, but they are softeners, plasticizers, lubricants, crosslinking agents, crosslinking aids, photosensitizers, antioxidants. Agent, anti-aging agent, heat stabilizer, flame retardant, antibacterial agent, antifungal agent, weathering agent, UV absorber, tackifier, nucleating agent, pigment, dye, organic filler, inorganic filler, silane coupling agent.
  • a composition containing an additive such as a titanium coupling agent and another polymer may be used as a constituent material. That is, the shock absorbing layer may be configured using a resin composition or an elastomer composition.
  • the method for forming the impact absorbing layer is not particularly limited, and examples include a coating method, a casting method (solventless casting method and a solvent casting method), a pressing method, an extrusion method, an injection molding method, a casting method, and an inflation method. It is done. Specifically, a liquid material in which the shock absorbing material is dissolved or dispersed in a solvent, or a melt of a component constituting the shock absorbing material is prepared, and then the liquid material or the melt is applied to a resin film, Thereafter, the optical film on which the shock absorbing layer is laminated can be produced by removing the solvent if necessary.
  • the impact absorbing layer material is applied to the release treatment surface of the release sheet that has been subjected to the release treatment and dried in the same manner as described above to form a sheet having the impact absorbing layer, and the impact absorbing layer of this sheet is attached to the resin film.
  • an optical film on which a shock absorbing layer is laminated can be produced.
  • the shock absorbing layer When the shock absorbing layer is made of a resin, the shock absorbing layer may be made of an uncrosslinked resin, or at least partly made of a crosslinked resin.
  • the method for crosslinking the resin is not particularly limited, and examples thereof include means selected from electron beam irradiation, ultraviolet irradiation, and a method using a crosslinking agent (for example, an organic peroxide).
  • a crosslinking agent for example, an organic peroxide
  • the resulting shock absorbing layer before crosslinking can be crosslinked by the effect of a photosensitizer blended as necessary by irradiating ultraviolet rays with an ultraviolet irradiation device. it can. Furthermore, when a crosslinking agent is used, the obtained impact absorbing layer before crosslinking is usually heated in an air-free atmosphere, such as a nitrogen atmosphere, and an organic peroxide blended as necessary. The crosslinking can be formed by the effect of the crosslinking agent, and further the crosslinking aid.
  • the film thickness of the shock absorbing layer is preferably 5 ⁇ m or more, more preferably 10 ⁇ m or more, and further preferably 20 ⁇ m or more from the viewpoint of shock absorption.
  • the upper limit is practically 100 ⁇ m or less.
  • the optical film of the present invention has a shock absorbing layer
  • a protective layer on the surface of the shock absorbing layer opposite to the resin film.
  • the aforementioned HC layer and resin film can be used.
  • the resin film a film selected from an acrylic resin film, a cellulose ester resin film, a polyethylene terephthalate resin film and a polycarbonate resin film is preferable, and a cellulose ester resin film is more preferable.
  • an optical film having a shock absorbing layer (with a protective layer) can be bonded to an object to be bonded such as a polarizing film using water paste. The process of peeling off the protective layer at the time of joining can be omitted.
  • the cellulose ester resin film is excellent in moisture permeability, the amount of residual solvent in the shock absorbing layer can also be reduced.
  • An optical film provided with a resin film as a protective layer can be obtained by laminating a resin film on the surface of the shock absorbing layer.
  • a release layer can be provided between the resin film as the protective layer and the shock absorbing layer in order to facilitate the release of the resin film.
  • the method for providing the release layer is not particularly limited, and for example, the release layer can be provided by applying a release coating agent on at least one of the protective layer and the shock absorbing layer.
  • the type of the release coating agent is not particularly limited, and examples thereof include a silicone coating agent, an inorganic coating agent, a fluorine coating agent, and an organic-inorganic hybrid coating agent.
  • An optical film provided with a resin film (protective layer) and a release layer is usually obtained by providing a release layer on the surface of the resin film layer and then laminating it on the surface of the shock absorbing layer.
  • the release layer may be provided not on the surface of the resin film layer but on the surface of the shock absorbing layer.
  • Article having an optical film As an article containing the optical film of the present invention, in various industries including the home appliance industry, the electric / electronic industry, the automobile industry, and the housing industry, suppression of interference unevenness and keystroke durability and Examples include various articles that are required to be improved in production suitability. Specific examples include an image display device such as a touch sensor, a touch panel, and a liquid crystal display device, a window glass of an automobile, a window glass of a house, and the like.
  • an image display device such as a touch sensor, a touch panel, and a liquid crystal display device, a window glass of an automobile, a window glass of a house, and the like.
  • the optical film of the present invention is preferably used as an optical film used for a front plate for an image display device, and more preferably an optical film used for a front plate of an image display element of a touch panel.
  • the touch panel that can use the optical film of the present invention is not particularly limited, and can be appropriately selected according to the purpose. For example, a surface capacitive touch panel, a projected capacitive touch panel, a resistive touch panel Etc. Details will be described later. Note that the touch panel includes a so-called touch sensor.
  • the layer structure of the touch panel sensor electrode part in the touch panel is either a bonding method in which two transparent electrodes are bonded, a method in which transparent electrodes are provided on both surfaces of a single substrate, a single-sided jumper or a through-hole method, or a single-area layer method. But you can.
  • the image display device having the optical film of the present invention is an image display device having a front plate having the optical film of the present invention and an image display element.
  • the image display device can be used for an image display device such as a liquid crystal display (LCD), a plasma display panel, an electroluminescence display, a cathode tube display device, and a touch panel.
  • LCD liquid crystal display
  • plasma display panel a plasma display panel
  • electroluminescence display a cathode tube display device
  • a touch panel a touch panel.
  • the liquid crystal display device As the liquid crystal display device, a TN (Twisted Nematic) type, a STN (Super-Twisted Nematic) type, a TSTN (Triple Super Twisted Nematic) type, a multi-domain type, a VA (Vertical Alignment In) type, an IPS type, an IPS type OCB (Optically Compensated Bend) type etc. are mentioned.
  • the image display device preferably has improved brittleness and excellent handling properties, does not impair display quality due to surface smoothness and wrinkles, and can reduce light leakage during a wet heat test. That is, in the image display device having the optical film of the present invention, the image display element is preferably a liquid crystal display element.
  • an image display device having a liquid crystal display element there can be cited, for example, Sony P made by Sony Ericsson.
  • the image display element is preferably an organic electroluminescence (EL) display element.
  • EL organic electroluminescence
  • a known technique can be applied to the organic electroluminescence display element without any limitation.
  • Examples of the image display device having an organic electroluminescence display element include a product manufactured by Samsunung Corporation and GALAXY SII.
  • the image display element is preferably an in-cell touch panel display element.
  • the in-cell touch panel display element has a touch panel function built into the image display element cell.
  • publicly known techniques such as Japanese Unexamined Patent Application Publication No. 2011-76602 and Japanese Unexamined Patent Application Publication No. 2011-222009 can be applied without any limitation.
  • Examples of the image display device having the in-cell touch panel display element include Sony P. manufactured by Ericsson Corporation.
  • the image display element is preferably an on-cell touch panel display element.
  • the on-cell touch panel display element is one in which a touch panel function is arranged outside the image display element cell.
  • a known technique such as JP 2012-88683 A can be applied without any limitation.
  • Examples of the image display device having an on-cell touch panel display element include GALXY SII manufactured by SAMSUNG.
  • the touch panel having the optical film of the present invention is, for example, a touch panel including a touch sensor by bonding a touch sensor film to the optical film of the present invention.
  • the optical film of the present invention has an HC layer, it is preferable to attach a touch sensor film to the resin film surface opposite to the surface on which the HC layer is disposed.
  • a touch sensor film it is preferable that it is a conductive film in which the conductive layer was formed.
  • the conductive film is preferably a conductive film in which a conductive layer is formed on an arbitrary support.
  • the material of the conductive layer is not particularly limited, and for example, indium tin oxide (ITO), tin oxide and tin titanium oxide (ATO), copper, Examples thereof include silver, aluminum, nickel, chromium, and alloys thereof.
  • the conductive layer is preferably an electrode pattern. Moreover, it is also preferable that it is a transparent electrode pattern.
  • the electrode pattern may be a pattern of a transparent conductive material layer or a pattern of an opaque conductive material layer.
  • oxides such as ITO and ATO, silver nanowires, carbon nanotubes, and conductive polymers can be used.
  • the opaque conductive material layer is a metal layer.
  • the metal layer any metal having conductivity can be used, and silver, copper, gold, aluminum and the like are preferably used.
  • the metal layer may be a single metal or alloy, or may be one in which metal particles are bound by a binder. Further, blackening treatment or rust prevention treatment is applied to the metal surface as necessary. In the case of using a metal, it is possible to form a substantially transparent sensor portion and a peripheral wiring portion all together.
  • the conductive layer preferably includes a plurality of fine metal wires. It is preferable that the fine metal wire is made of silver or an alloy containing silver. There is no restriction
  • the conductive layer is made of an oxide.
  • the oxide is more preferably made of indium oxide containing tin oxide or tin oxide containing antimony.
  • a conductive layer in which a conductive layer consists of an oxide A well-known conductive layer can be used.
  • the conductive layer preferably includes a plurality of fine metal wires, and the fine metal wires are preferably arranged in a mesh shape or a random shape, and the fine metal wires are more preferably arranged in a mesh shape.
  • the fine metal wires are arranged in a mesh shape, and the fine metal wires are made of silver or an alloy containing silver.
  • the touch sensor film also preferably has a conductive layer on both sides.
  • the resistive touch panel having the optical film of the present invention is a resistive touch panel having a front plate having the optical film of the present invention.
  • the resistive touch panel has a basic configuration in which a conductive film of a pair of upper and lower substrates having a conductive film is arranged via a spacer so that the conductive films face each other.
  • the configuration of the resistive touch panel is known, and any known technique can be applied without any limitation in the present invention.
  • the capacitive touch panel having the optical film of the present invention is a capacitive touch panel having a front plate having the optical film of the present invention.
  • Examples of the capacitive touch panel system include a surface capacitive type and a projected capacitive type.
  • the projected capacitive touch panel has a basic configuration in which an X-axis electrode and a Y-axis electrode orthogonal to the X electrode are arranged via an insulator.
  • an aspect in which the X electrode and the Y electrode are formed on different surfaces on a single substrate, an aspect in which the X electrode, the insulator layer, and the Y electrode are formed in the above order on a single substrate.
  • Examples include an embodiment in which an X electrode is formed on one substrate and a Y electrode is formed on another substrate (in this embodiment, a configuration in which two substrates are bonded together is the above basic configuration).
  • the configuration of the capacitive touch panel is known, and any known technique can be applied without any limitation in the present invention.
  • FIG. 3 an example of a structure of embodiment of an electrostatic capacitance type touch panel is shown.
  • the touch panel 2 is used in combination with a display device.
  • the display device is arranged and used on the protective layer 7B side in FIG. 3, that is, on the display device side.
  • the optical film 4C side of the present invention is the viewing side (that is, the side on which the operator of the touch panel visually recognizes the image on the display device).
  • the optical film 4C of the present invention is used by being bonded to the conductive film 1 for a touch panel.
  • the conductive film 1 for a touch panel has a conductive member 6A (first conductive layer 8) and a conductive member 6B (second conductive layer 9) on both surfaces of a flexible transparent insulating substrate 5, respectively.
  • the conductive member 6A and the conductive member 6B constitute at least an electrode as a touch panel, a peripheral wiring, an external connection terminal, and a connector part, which will be described later. Moreover, as shown in FIG. 3, even if the transparent protective layer 7A and the protective layer 7B are disposed so as to cover the conductive member 6A and the conductive member 6B for the purpose of flattening or protecting the conductive members 6A and 6B. Good.
  • the optical film 4C may be provided with a decorative layer that shields a peripheral region S2 described later.
  • the material of the transparent insulating substrate 5 examples include glass, PET (polyethylene terephthalate), PEN (polyethylene naphthalate), COP (cycloolefin polymer), COC (cycloolefin polymer), PC (polycarbonate), and the like.
  • the thickness of the transparent insulating substrate 5 is preferably 20 to 200 ⁇ m.
  • An adhesive layer (not shown in the drawing) may be provided between the optical film 4C and the conductive film 1 for touch panel.
  • an optical transparent adhesive sheet Optical Clear Adhesive
  • an optical transparent adhesive resin Optical Clear Resin
  • the 8146 series manufactured by 3M can be preferably used as the optically transparent adhesive sheet.
  • a preferable value of the dielectric constant of the adhesive layer is 4.0 to 6.0, and more preferably 5.0 to 6.0.
  • the protective layer 7A and the protective layer 7B for example, organic films such as gelatin, acrylic resin, and urethane resin, and inorganic films such as silicon dioxide can be used.
  • the thickness is preferably 10 nm or more and 100 nm or less.
  • the relative dielectric constant is preferably 2.5 to 4.5.
  • the concentration of the halogen impurity in the protective layer 7A and the protective layer 7B is preferably 50 ppm or less, and more preferably contains no halogen impurity. According to this aspect, corrosion of the conductive member 6A and the conductive member 6B can be suppressed.
  • a transparent active area S ⁇ b> 1 is defined in the conductive film for touch panel 1, and a peripheral area S ⁇ b> 2 is defined outside the active area S ⁇ b> 1.
  • a first conductive layer 8 formed on the surface (first surface) of the transparent insulating substrate 5 and a second conductive layer 9 formed on the back surface (second surface) of the transparent insulating substrate 5 are provided. Are arranged so as to overlap each other. The first conductive layer 8 and the second conductive layer 9 are arranged in a state of being insulated from each other via the transparent insulating substrate 5.
  • the first conductive layer 8 on the surface of the transparent insulating substrate 5 extends in the first direction D1 and is arranged in parallel in the second direction D2 perpendicular to the first direction D1.
  • the second conductive layer 9 on the back surface of the transparent insulating substrate 5 forms a plurality of second electrodes 21 that respectively extend along the second direction D2 and are arranged in parallel in the first direction D1. Yes.
  • the plurality of first electrodes 11 and the plurality of second electrodes 21 constitute detection electrodes of the touch panel 2.
  • the electrode width of the first electrode 11 and the second electrode 21 is preferably 1 to 5 mm, and the pitch between the electrodes is preferably 3 to 6 mm.
  • first peripheral wirings 12 connected to the plurality of first electrodes 11 are formed on the surface of the transparent insulating substrate 5 in the peripheral region S2, and a plurality of first external connections are formed at the edge of the transparent insulating substrate 5.
  • Terminals 13 are arranged and first connector portions 14 are formed at both ends of each first electrode 11.
  • One end portion of the corresponding first peripheral wiring 12 is connected to the first connector portion 14, and the other end portion of the first peripheral wiring 12 is connected to the corresponding first external connection terminal 13.
  • a plurality of second peripheral wirings 22 connected to the plurality of second electrodes 21 are formed on the back surface of the transparent insulating substrate 5 in the peripheral region S2, and a plurality of second external wirings are formed at the edge of the transparent insulating substrate 5.
  • the connection terminals 23 are arranged and the second connector portions 24 are formed at both ends of the respective second electrodes 21.
  • One end portion of the corresponding second peripheral wiring 22 is connected to the second connector portion 24, and the other end portion of the second peripheral wiring 22 is connected to the corresponding second external connection terminal 23.
  • the conductive film 1 for a touch panel has a conductive member 6A including a first electrode 11, a first peripheral wiring 12, a first external connection terminal 13, and a first connector portion 14 on the surface of the transparent insulating substrate 5, and a transparent insulating substrate.
  • 5 has a conductive member 6 ⁇ / b> B including a second electrode 21, a second peripheral wiring 22, a second external connection terminal 23, and a second connector portion 24.
  • the first electrode 11 and the first peripheral wiring 12 are connected via the first connector portion 14, but the first electrode 11 and the first peripheral wiring 12 are not provided without providing the first connector portion 14.
  • the configuration may be such that the and are directly connected.
  • the second electrode 21 and the second peripheral wiring 22 may be directly connected without providing the second connector portion 24.
  • the widths of the first connector part 14 and the second connector part 24 are preferably not less than 1/3 of the width of the electrode to be connected and not more than the width of the electrode.
  • the shape of the first connector portion 14 and the second connector portion 24 may be a solid film shape, or may be a frame shape or a mesh shape as disclosed in International Publication WO2013 / 088905.
  • the first peripheral wiring 12 and the second peripheral wiring 22 preferably have a wiring width of 10 ⁇ m or more and 200 ⁇ m or less, and a minimum wiring interval (minimum wiring distance) of 20 ⁇ m or more and 100 ⁇ m or less.
  • Each peripheral wiring may be covered with a protective insulating film made of urethane resin, acrylic resin, epoxy resin or the like. By providing the protective insulating film, migration and rust of peripheral wiring can be prevented.
  • the insulating film does not contain a halogen impurity.
  • the thickness of the protective insulating film is preferably 1 to 20 ⁇ m.
  • the first external connection terminal 13 and the second external connection terminal 23 are formed with a terminal width larger than the wiring width of the first peripheral wiring 12 and the second peripheral wiring 22 for the purpose of improving electrical connection with the flexible wiring board.
  • the terminal width of the first external connection terminal 13 and the second external connection terminal 23 is preferably 0.1 mm to 0.6 mm, and the terminal length is preferably 0.5 mm to 2.0 mm.
  • the transparent insulating substrate 5 corresponds to a substrate having a first surface and a second surface facing the first surface, the first conductive layer 8 is disposed on the first surface (surface), and the second surface.
  • the second conductive layer 9 is disposed on the (back surface).
  • the transparent insulating substrate 5, the first conductive layer 8, and the second conductive layer 9 are shown in direct contact with each other, but the transparent insulating substrate 5, the first conductive layer 8, and the second conductive layer are shown.
  • one or more functional layers such as an adhesion reinforcing layer, an undercoat layer, a hard coat layer, and an optical adjustment layer can be formed.
  • FIG. 5 shows an intersection between the first electrode 11 and the second electrode 21.
  • the first electrode 11 disposed on the surface of the transparent insulating substrate 5 is formed by a mesh pattern M1 composed of the first thin metal wires 15, and the second electrode 21 disposed on the back surface of the transparent insulating substrate 5 is also It is formed by a mesh pattern M ⁇ b> 2 composed of the second fine metal wires 25.
  • a mesh pattern M ⁇ b> 2 composed of the second fine metal wires 25.
  • the second metal fine wire 25 is shown by a dotted line. It is formed with a line.
  • a pattern in which the same mesh (standard cell) as shown in FIG. It may be a regular hexagon or another polygon.
  • the narrow angle of the rhombus is preferably 20 ° or more and 70 ° or less from the viewpoint of reducing moire with the pixels of the display device.
  • the distance between mesh centers (mesh pitch) is preferably 100 to 600 ⁇ m from the viewpoint of visibility.
  • the mesh pattern M1 composed of the first fine metal wires 15 and the mesh pattern M2 composed of the second fine metal wires 25 have the same shape. Further, as shown in FIG. 5, the mesh pattern M1 made of the first fine metal wires 15 and the mesh pattern M2 made of the second fine metal wires 25 are shifted by a distance corresponding to half the mesh pitch, and the mesh pitch is viewed from the viewing side. It is preferable from a viewpoint of visibility to arrange
  • the shape of the mesh is a random pattern, or a regular cell that gives a randomness of about 10% to the pitch of a rhombus regular cell as disclosed in JP2013-214545A
  • a semi-random shape imparted with a certain randomness in the shape may also be used.
  • a dummy mesh pattern is formed between the first electrodes 11 adjacent to each other and between the second electrodes 21 adjacent to each other, insulated from the electrodes formed by the first metal thin wires 15 and the second metal thin wires 25, respectively. It may be.
  • the dummy mesh pattern is preferably formed in the same mesh shape as the mesh pattern forming the electrodes.
  • the method of bonding the touch panel 2 and the display device is a method of directly bonding using a transparent adhesive (direct bonding method) or a method of bonding only the periphery of the touch panel 2 and the display device using a double-sided tape ( There is an air gap method), but either method may be used.
  • a protective film may be separately provided on the conductive member 6B or the protective layer 7B.
  • the protective film for example, a PET film with a hard coat (thickness 20 to 150 ⁇ m) is used, and an optical transparent adhesive sheet (Optical Clear Adhesive) can be used to be attached to the conductive member 6B or the protective layer 7B. .
  • an optical transparent adhesive sheet (Optical Clear Adhesive) or an optical transparent adhesive resin (Optical Clear Resin) can be used, and the preferred thickness is 10 ⁇ m or more and 100 ⁇ m. It is as follows.
  • the optical transparent adhesive sheet for example, 8146 series manufactured by 3M Company can be preferably used.
  • the transparent dielectric used in the direct bonding method has a relative dielectric constant smaller than that of the transparent adhesive layer described above.
  • a preferable value of the relative dielectric constant of the transparent adhesive used in the direct bonding method is 2.0 to 3.0.
  • the visible light reflectance of each of the surface on the viewing side of the first metal fine wire 15 and the surface on the viewing side of the second metal fine wire 25 is 5% or less in that the effect of the present invention is more excellent. preferable. Furthermore, it is more preferable that it is less than 1%.
  • the visible light reflectance is measured as follows. First, using a UV-visible spectrophotometer V660 (single reflection measurement unit SLM-721) manufactured by JASCO Corporation, a reflection spectrum is measured at a measurement wavelength of 350 nm to 800 nm and an incident angle of 5 degrees. The regular reflection light of the aluminum vapor deposition plane mirror is used as the baseline. The Y value (color matching function JIS Z9701-1999) of the XYZ color system D65 light source 2 degree visual field is calculated from the obtained reflection spectrum using a color calculation program manufactured by JASCO Corporation, and is set as the visible light reflectance.
  • the first metal fine wire 15 and the second metal fine wire 25 As a material constituting the first metal fine wire 15 and the second metal fine wire 25, metals such as silver, aluminum, copper, gold, molybdenum, chromium, and alloys thereof can be used, and these can be used as a single layer or a laminate. Can be used. From the viewpoint of the appearance of fine metal wires and the reduction of moire, the first metal fine wires 15 and the second metal fine wires 25 preferably have a line width of 0.5 ⁇ m or more and 5 ⁇ m or less. The first metal fine wire 15 and the second metal fine wire 25 may be straight, broken, curved, or wavy.
  • the thickness of the 1st metal fine wire 15 and the 2nd metal fine wire 25 is 0.1 micrometer or more from a viewpoint of resistance value, and it is preferable that it is 3 micrometers or less from a viewpoint of the visibility from an oblique direction. More preferable thickness is 1/2 or less with respect to the line
  • a blackening layer may be provided on the viewing side of the first metal fine wire 15 and the second metal fine wire 25.
  • the conductive member 6 ⁇ / b> A including the first electrode 11, the first peripheral wiring 12, the first external connection terminal 13, and the first connector portion 14 can be formed of a material constituting the first metal thin wire 15. Therefore, the conductive members 6A including the first electrode 11, the first peripheral wiring 12, the first external connection terminal 13, and the first connector portion 14 are all formed of the same metal and with the same thickness, and can be formed simultaneously. The same applies to the conductive member 6B including the second electrode 21, the second peripheral wiring 22, the second external connection terminal 23, and the second connector portion 24.
  • the sheet resistance of the first electrode 11 and the second electrode 21 is preferably 0.1 ⁇ / ⁇ or more and 200 ⁇ / ⁇ or less, particularly 10 ⁇ / ⁇ or more and 100 ⁇ / ⁇ or less when used for a projected capacitive touch panel. It is preferable that
  • the first conductive layer 8 disposed on the surface of the transparent insulating substrate 5 in the active area S ⁇ b> 1 has a plurality of first electrodes disposed between the plurality of first electrodes 11.
  • One dummy electrode 11A may be provided. These first dummy electrodes 11 ⁇ / b> A are insulated from the plurality of first electrodes 11, and have a first mesh pattern M ⁇ b> 1 composed of a large number of first cells C ⁇ b> 1, similarly to the first electrode 11.
  • the first dummy electrode 11A adjacent to the first electrode 11 is electrically insulated by providing a disconnection having a width of 5 ⁇ m or more and 30 ⁇ m or less on a thin metal wire arranged along the continuous first mesh pattern M1. is doing.
  • the second conductive layer 9 disposed on the back surface of the transparent insulating substrate 5 in the active area S1 includes a plurality of second dummy electrodes respectively disposed between the plurality of second electrodes 21. You may have. These second dummy electrodes are insulated from the plurality of second electrodes 21 and, like the second electrodes 21, have a second mesh pattern M2 composed of a large number of second cells C2.
  • the second dummy electrode adjacent to the second electrode 21 is electrically insulated by providing a disconnection having a width of 5 ⁇ m or more and 30 ⁇ m or less on a thin metal wire arranged along the continuous second mesh pattern M2. ing.
  • a shape in which disconnection is formed only at the boundary line between the second electrode 21 and the first dummy electrode adjacent to the second electrode 21 may be formed. May be.
  • the conductive film 1 for a touch panel forms the conductive member 6 ⁇ / b> A including the first electrode 11, the first peripheral wiring 12, the first external connection terminal 13, and the first connector portion 14 on the surface of the transparent insulating substrate 5.
  • the conductive member 6 ⁇ / b> B including the second electrode 21, the second peripheral wiring 22, the second external connection terminal 23, and the second connector portion 24 is formed on the back surface of the transparent insulating substrate 5.
  • the 1st electrode 11 consists of the 1st conductive layer 8 in which the 1st metal fine wire 15 is arranged along the 1st mesh pattern M1, and the 2nd electrode 21 is the 2nd along the 2nd mesh pattern M2.
  • the second conductive layer 9 in which the fine metal wires 25 are arranged, and the first conductive layer 8 and the second conductive layer 9 are arranged so as to overlap each other in the active area S1 as shown in FIG. Shall be.
  • the formation method of these conductive members 6A and 6B is not particularly limited. For example, ⁇ 0067> to ⁇ 0083> in JP 2012-185813 A, ⁇ 0115> to ⁇ 0126> in JP 2014-209332 A, or ⁇ 0216> to ⁇ 0215 in JP 2015-5495 A.
  • the conductive members 6A and 6B can be formed by exposing and developing a photosensitive material having an emulsion layer containing a photosensitive silver halide salt as described in>.
  • a metal thin film is formed on each of the front and back surfaces of the transparent insulating substrate 5, and a resist is printed in a pattern on each metal thin film, or the resist applied on the entire surface is exposed and developed to be patterned,
  • These conductive members can also be formed by etching the metal in the opening.
  • a method of printing a paste containing fine particles of the material constituting the conductive member on the front and back surfaces of the transparent insulating substrate 5 and subjecting the paste to metal plating, and an ink containing fine particles of the material constituting the conductive member A method using an ink jet method using a liquid, a method of forming ink containing fine particles of a material constituting a conductive member by screen printing, a method of forming a groove in the transparent insulating substrate 5, and applying a conductive ink to the groove, A printing patterning method or the like can be used.
  • the conductive member 6 ⁇ / b> A including the first electrode 11, the first peripheral wiring 12, the first external connection terminal 13, and the first connector portion 14 is disposed on the surface of the transparent insulating substrate 5, and the transparent insulating substrate 5.
  • the conductive member 6 ⁇ / b> B including the second electrode 21, the second peripheral wiring 22, the second external connection terminal 23, and the second connector portion 24 is disposed on the back surface of the substrate, but is not limited thereto.
  • the conductive member 6A and the conductive member 6B may be arranged on one surface side of the transparent insulating substrate 5 via an interlayer insulating film. Furthermore, it can also be set as the structure of 2 sheets.
  • the conductive member 6A is disposed on the surface of the first transparent insulating substrate
  • the conductive member 6B is disposed on the surface of the second transparent insulating substrate
  • the first transparent insulating substrate and the second transparent insulating substrate are optically transparent. It can also be used by sticking together using an adhesive sheet (Optical Clear Adhesive).
  • the conductive member 6A and the conductive member 6B may be arranged on the surface of the optical film 4C shown in FIG. 3 via an interlayer insulating film.
  • the present invention can be applied to the electrode pattern shape disclosed in FIG. 7 or FIG. 20 of the published WO2013 / 094728, and can also be applied to the electrode patterns of capacitive touch panels having other shapes. Further, the present invention can also be applied to a touch panel having a configuration in which the detection electrode is only on one side of the substrate, such as an electrode configuration without an intersecting portion disclosed in US2012 / 0262414.
  • the touch panel can be used in combination with other functional films, and is a function for improving image quality that prevents azimuth using a substrate having a high retardation value disclosed in Japanese Patent Application Laid-Open No. 2014-13264.
  • a combination with a circularly polarizing plate for improving the visibility of an electrode of a film or a touch panel disclosed in Japanese Patent Application Laid-Open No. 2014-142462 is also possible.
  • the optical film of the present invention may have a reflective layer (a linearly polarized reflective layer or a circularly polarized reflective layer) on the surface of one resin film opposite to the surface having the adhesive layer.
  • a reflective layer a linearly polarized reflective layer or a circularly polarized reflective layer
  • Such an optical film is preferably used as an optical film used for a front plate of a mirror with an image display function by being combined with an image display element.
  • An adhesive layer may be provided between the optical film of the present invention and the reflective layer.
  • an optical transparent adhesive sheet Optical Clear Adhesive
  • an optical transparent adhesive resin Optical Clear Resin
  • the image display element used in the mirror with an image display function is not particularly limited, and examples thereof include an image display element suitably used in the above-described image display device.
  • the mirror with an image display function is configured by arranging an image display element on the side of the half mirror having the linearly polarized light reflecting layer or the circularly polarized light reflecting layer.
  • the half mirror and the image display element may be in direct contact, or another layer may be interposed between the half mirror and the image display element.
  • an air layer may exist between the image display element and the half mirror, or an adhesive layer may exist.
  • the surface on the half mirror side with respect to the image display element may be referred to as the front surface.
  • the mirror with an image display function can be used, for example, as a vehicle rearview mirror (inner mirror).
  • the mirror with an image display function may have a frame, a housing, a support arm for attaching to the vehicle body, and the like for use as a rearview mirror.
  • the mirror with an image display function may be formed for incorporation into a rearview mirror. In such a mirror with an image display function, it is possible to specify the vertical and horizontal directions during normal use.
  • the mirror with an image display function may be a plate shape or a film shape, and may have a curved surface.
  • the front surface of the mirror with an image display function may be flat or curved. It is possible to provide a wide mirror that can be viewed in a wide angle by making the convex curved surface the front side by curving. Such a curved front surface can be produced using a curved half mirror.
  • the curve may be in the vertical direction, the horizontal direction, or the vertical direction and the horizontal direction.
  • the curvature of the curvature may be 500 to 3000 mm, and more preferably 1000 to 2500 mm.
  • the radius of curvature is the radius of the circumscribed circle when the circumscribed circle of the curved portion is assumed in the cross section.
  • Reflection layer a reflective layer that can function as a transflective layer may be used. That is, at the time of image display, the reflective layer functions so that an image is displayed on the front surface of the mirror with an image display function by transmitting light emitted from a light source included in the image display element, while image non-display is performed. Sometimes, the reflection layer functions to reflect at least a part of incident light from the front surface direction and transmit the reflected light from the image display element so that the front surface of the mirror with an image display function becomes a mirror. That's fine.
  • a polarizing reflection layer is used as the reflection layer.
  • the polarization reflection layer may be a linear polarization reflection layer or a circular polarization reflection layer.
  • Linear polarization reflection layer Examples of the linearly polarized light reflecting layer include (i) a linearly polarized light reflecting plate having a multilayer structure, (ii) a polarizer formed by laminating thin films having different birefringence, (iii) a wire grid type polarizer, and (iv) a polarizing prism. And (v) a scattering anisotropic polarizing plate.
  • a multilayer laminated thin film in which dielectric materials having different refractive indexes are laminated on a support from an oblique direction by a vacuum vapor deposition method or a sputtering method can be mentioned.
  • the number of types is not limited to two or more. It may be.
  • the number of laminated layers is preferably 2 to 20 layers, more preferably 2 to 12 layers, still more preferably 4 to 10 layers, and particularly preferably 6 to 8 layers.
  • the method for forming the dielectric thin film is not particularly limited and may be appropriately selected depending on the purpose.
  • a vacuum vapor deposition method such as ion plating and ion beam
  • a physical vapor deposition method such as sputtering ( PVD method) and chemical vapor deposition method (CVD method).
  • the vacuum evaporation method or the sputtering method is preferable, and the sputtering method is particularly preferable.
  • a polarizer formed by laminating thin films having different birefringence for example, a polarizer described in JP-T-9-506837 can be used.
  • a polarizer can be formed using a wide variety of materials by processing under conditions selected to obtain a refractive index relationship.
  • one of the first materials needs to have a different refractive index than the second material in the chosen direction.
  • This refractive index difference can be achieved in a variety of ways, including stretching, extrusion, or coating during or after film formation.
  • a commercial product can be used as a polarizer in which thin films having different birefringence are laminated. Examples of the commercial product include DBEF (registered trademark) (manufactured by 3M).
  • a wire grid type polarizer is a polarizer that transmits one of polarized light and reflects the other by birefringence of a fine metal wire.
  • the wire grid polarizer is a periodic arrangement of metal wires, and is mainly used as a polarizer in the terahertz wave band. In order for the wire grid to function as a polarizer, the wire interval needs to be sufficiently smaller than the wavelength of the incident electromagnetic wave.
  • metal wires are arranged at equal intervals. The polarization component in the polarization direction parallel to the longitudinal direction of the metal wire is reflected by the wire grid polarizer, and the polarization component in the perpendicular polarization direction is transmitted through the wire grid polarizer.
  • wire grid polarizer Commercially available products can be used as the wire grid polarizer, and examples of commercially available products include wire grid polarizing filter 50 ⁇ 50, NT46-636 (trade name) manufactured by Edmund Optics.
  • the circularly polarized light reflecting layer examples include a circularly polarized light reflecting layer including a linearly polarized light reflecting plate and a quarter wavelength plate, and a circularly polarized light reflecting layer including a cholesteric liquid crystal layer (hereinafter, for the sake of distinction, “Pol ⁇ / 4 circularly polarized light reflecting layer “or” cholesteric circularly polarized light reflecting layer ").
  • the linearly polarized light reflecting plate and the quarter wavelength plate are arranged so that the slow axis of the ⁇ / 4 wavelength plate is 45 ° with respect to the polarized light reflecting axis of the linearly polarized light reflecting plate. Just do it.
  • the quarter wave plate and the linearly polarized light reflecting plate may be bonded by, for example, an adhesive layer.
  • the linearly polarized light reflecting plate is arranged so as to be a surface close to the image display element.
  • the quarter wavelength plate and the linearly polarized light reflecting plate are arranged in this order with respect to the optical film.
  • the light for image display from the image display element can be efficiently converted into circularly polarized light and emitted from the front surface of the mirror with an image display function.
  • the polarization reflection axis of the linearly polarized light reflecting plate may be adjusted so as to transmit this linearly polarized light.
  • the thickness of the Pol ⁇ / 4 circularly polarized light reflecting layer is preferably in the range of 2.0 ⁇ m to 300 ⁇ m, and more preferably in the range of 8.0 ⁇ m to 200 ⁇ m.
  • the linearly polarized light reflecting plate those described above as the linearly polarized light reflecting layer can be used.
  • the quarter wavelength plate a quarter wavelength plate described later can be used.
  • the cholesteric circularly polarized light reflection layer includes at least one cholesteric liquid crystal layer.
  • the cholesteric liquid crystal layer included in the cholesteric circularly polarized light reflection layer may be any layer that exhibits selective reflection in the visible light region.
  • the circularly polarized light reflecting layer may include two or more cholesteric liquid crystal layers, and may include other layers such as an alignment layer.
  • the circularly polarized light reflecting layer is preferably composed only of a cholesteric liquid crystal layer. Further, when the circularly polarized light reflection layer includes a plurality of cholesteric liquid crystal layers, it is preferable that they are in direct contact with adjacent cholesteric liquid crystal layers.
  • the circularly polarized light reflection layer includes three or more cholesteric liquid crystal layers such as three layers and four layers.
  • the thickness of the cholesteric circularly polarized light reflecting layer is preferably in the range of 2.0 ⁇ m to 300 ⁇ m, and more preferably in the range of 8.0 to 200 ⁇ m.
  • the “cholesteric liquid crystal layer” means a layer in which a cholesteric liquid crystal phase is fixed.
  • the cholesteric liquid crystal layer is sometimes simply referred to as a liquid crystal layer.
  • the cholesteric liquid crystal phase selectively reflects circularly polarized light of either right circularly polarized light or left circularly polarized light in a specific wavelength region and selectively transmits circularly polarized light of the other sense. It is known to show.
  • the circularly polarized light selective reflection is sometimes simply referred to as selective reflection.
  • films formed from a composition containing a polymerizable liquid crystal compound have been known as films containing a layer in which a cholesteric liquid crystal phase exhibiting circularly polarized light selective properties is fixed. You can refer to the law.
  • the cholesteric liquid crystal layer may be a layer in which the orientation of the liquid crystal compound in the cholesteric liquid crystal phase is maintained.
  • the polymerizable liquid crystal compound is placed in the orientation state of the cholesteric liquid crystal phase and then irradiated with ultraviolet rays.
  • Any layer may be used as long as it is polymerized and cured by heating or the like to form a layer having no fluidity, and at the same time, the layer is changed to a state in which the orientation is not changed by an external field or an external force.
  • the polymerizable liquid crystal compound may have a high molecular weight due to a curing reaction and may no longer have liquid crystallinity.
  • the central wavelength and the half width of selective reflection of the cholesteric liquid crystal layer can be obtained as follows.
  • the center wavelength and half width of selective reflection can be expressed by the following formula.
  • Center wavelength of selective reflection ( ⁇ 1 + ⁇ 2) / 2
  • Half width ( ⁇ 2- ⁇ 1)
  • center wavelength of selective reflection means the center wavelength when measured from the normal direction of the cholesteric liquid crystal layer.
  • the center wavelength of selective reflection can be adjusted by adjusting the pitch of the helical structure.
  • the n value and the P value it is possible to adjust the center wavelength ⁇ for selectively reflecting either the right circularly polarized light or the left circularly polarized light with respect to light having a desired wavelength.
  • n ⁇ P the center wavelength of selective reflection when a light ray passes at an angle of ⁇ 2 with respect to the normal direction of the cholesteric liquid crystal layer (the spiral axis direction of the cholesteric liquid crystal layer) is ⁇ d
  • ⁇ d n 2 ⁇ P ⁇ cos ⁇ 2
  • the center wavelength of selective reflection of the cholesteric liquid crystal layer included in the circularly polarized light reflecting layer it is possible to prevent the visibility of the image from being viewed obliquely. Also, the visibility of the image from an oblique direction can be intentionally reduced. This is useful because, for example, it is possible to prevent peeping in a smartphone or a personal computer.
  • the mirror with an image display function having the optical film of the present invention may appear in the image and the mirror reflection image viewed from an oblique direction.
  • the center wavelength of selective reflection in the infrared region is specifically 780 to 900 nm, preferably 780 to 850 nm.
  • the cholesteric liquid crystal layer having a central wavelength of selective reflection is provided in the infrared light region, it is preferable that the cholesteric liquid crystal layer having a central wavelength of selective reflection in the visible light region is closest to the image display element.
  • the pitch of the cholesteric liquid crystal phase depends on the type of chiral agent used together with the polymerizable liquid crystal compound or the concentration of the chiral agent, a desired pitch can be obtained by adjusting these.
  • a desired pitch can be obtained by adjusting these.
  • the circularly polarized light reflection layer has a cholesteric liquid crystal layer having a central wavelength of selective reflection in the red light wavelength region and a central wavelength of selective reflection in the green light wavelength region. It is preferable to include a cholesteric liquid crystal layer having a cholesteric liquid crystal layer having a central wavelength of selective reflection in the wavelength range of blue light.
  • the reflective layer is, for example, a cholesteric liquid crystal layer having a central wavelength of selective reflection in 400 nm to 500 nm, a cholesteric liquid crystal layer having a central wavelength of selective reflection in 500 nm to 580 nm, and a cholesteric liquid crystal having a central wavelength of selective reflection in 580 nm to 700 nm. It is preferable to include a layer.
  • the circularly polarized light reflection layer includes a plurality of cholesteric liquid crystal layers
  • the cholesteric liquid crystal layer closer to the image display element has a longer selective reflection center wavelength.
  • the central wavelength of selective reflection that each cholesteric liquid crystal layer has is 5 nm or more with the peak wavelength of light emission of the image display element It is preferable to make them different. This difference is more preferably 10 nm or more.
  • the wavelength of the light emission peak of the image display element can be confirmed by the emission spectrum when the image display element displays white.
  • the peak wavelength may be a peak wavelength in the visible light region of the emission spectrum.
  • the above-described red light emission peak wavelength ⁇ R, green light emission peak wavelength ⁇ G, and blue light emission peak wavelength ⁇ B of the image display element Any one or more selected from the group consisting of:
  • the selective reflection center wavelength of the cholesteric liquid crystal layer is different from the above-described red light emission peak wavelength ⁇ R, green light emission peak wavelength ⁇ G, and blue light emission peak wavelength ⁇ B of the image display element by 5 nm or more. It is preferable that the difference is 10 nm or more.
  • the central wavelength of selective reflection of all the cholesteric liquid crystal layers is different from the peak wavelength of light emitted from the image display element by 5 nm or more, preferably 10 nm or more. do it.
  • the image display element is a display element for full color display showing an emission peak wavelength ⁇ R for red light, an emission peak wavelength ⁇ G for green light, and an emission peak wavelength ⁇ B for blue light in the emission spectrum during white display.
  • the central wavelengths of all selective reflections of the cholesteric liquid crystal layer may be different from each other by ⁇ R, ⁇ G, and ⁇ B by 5 nm or more, preferably by 10 nm or more.
  • the central wavelength of selective reflection of the cholesteric liquid crystal layer to be used according to the emission wavelength range of the image display element and the usage mode of the circularly polarized light reflection layer, a bright image can be displayed with high light utilization efficiency.
  • the usage mode of the circularly polarized light reflecting layer include an incident angle of light to the circularly polarized light reflecting layer, an image observation direction, and the like.
  • each cholesteric liquid crystal layer a cholesteric liquid crystal layer whose spiral sense is either right or left is used.
  • the sense of reflected circularly polarized light in the cholesteric liquid crystal layer coincides with the sense of a spiral.
  • the spiral senses of the plurality of cholesteric liquid crystal layers may all be the same or different. That is, either the right or left sense cholesteric liquid crystal layer may be included, or both the right and left sense cholesteric liquid crystal layers may be included.
  • the spiral senses of the plurality of cholesteric liquid crystal layers are all the same.
  • the spiral sense at that time may be determined according to the sense of circularly polarized light of the sense obtained as each cholesteric liquid crystal layer that is emitted from the image display element and transmitted through the quarter-wave plate.
  • a cholesteric liquid crystal layer having a spiral sense that transmits the circularly polarized light of the sense obtained from the image display element and transmitted through the quarter-wave plate may be used.
  • ⁇ n can be adjusted by adjusting the kind of the polymerizable liquid crystal compound and the mixing ratio thereof, or by controlling the temperature at the time of fixing the alignment.
  • a plurality of cholesteric liquid crystal layers having the same period P and the same spiral sense may be stacked. By laminating cholesteric liquid crystal layers having the same period P and the same spiral sense, the circularly polarized light selectivity at a specific wavelength can be increased.
  • the half mirror may further include a quarter wavelength plate, a high Re (in-plane retardation) retardation film, a cholesteric circularly polarizing reflection layer, It is preferable that the 1 ⁇ 4 wavelength plate is included in this order.
  • a quarter-wave plate between the image display element and the cholesteric circularly polarized reflection layer in particular, the light from the image display element displaying an image by linearly polarized light is converted into circularly polarized light and reflected by cholesteric circularly polarized light. It is possible to enter the layer.
  • the light reflected by the circularly polarized light reflection layer and returning to the image display element side can be greatly reduced, and a bright image can be displayed.
  • a cholesteric circularly polarized light reflection layer can be configured not to generate sense circularly polarized light reflected to the image display element side by using a quarter wavelength plate, an image by multiple reflection between the image display element and the half mirror is possible. Display quality is unlikely to deteriorate. That is, for example, the central wavelength of selective reflection of the cholesteric liquid crystal layer included in the cholesteric circularly polarized light reflection layer is substantially the same as the emission peak wavelength of blue light in the emission spectrum when the image display element displays white (for example, the difference is less than 5 nm). Even in this case, the light emitted from the image display element can be transmitted to the front side without causing the circularly polarized light reflection layer to generate the sense circularly polarized light reflected to the image display side.
  • the quarter-wave plate used in combination with the cholesteric circularly polarized reflective layer is preferably angle-adjusted so that the image becomes brightest when bonded to the image display element. That is, the relationship between the polarization direction of the linearly polarized light (transmission axis) and the slow axis of the quarter-wave plate so that the linearly polarized light is transmitted best, particularly for an image display element displaying an image by linearly polarized light. Is preferably adjusted. For example, in the case of a single layer type quarter wave plate, it is preferable that the transmission axis and the slow axis form an angle of 45 °.
  • the light emitted from the image display element displaying an image by linearly polarized light is circularly polarized light of either right or left sense after passing through the quarter wavelength plate.
  • the circularly polarized light reflecting layer may be formed of a cholesteric liquid crystal layer having a twist direction that transmits the circularly polarized light having the above-described sense.
  • the quarter wavelength plate may be a retardation layer that functions as a quarter wavelength plate in the visible light region.
  • the quarter-wave plate include a single-layer quarter-wave plate and a broadband quarter-wave plate in which a quarter-wave plate and a half-wave retardation plate are stacked.
  • the front phase difference of the former 1 ⁇ 4 wavelength plate may be a length that is 1 ⁇ 4 of the emission wavelength of the image display element. Therefore, for example, when the emission wavelength of the image display element is 450 nm, 530 nm, and 640 nm, the wavelength of 450 nm is 112.5 nm ⁇ 10 nm, preferably 112.5 nm ⁇ 5 nm, more preferably 112.5 nm, and 530 nm.
  • reverse dispersion such that the phase difference is 160 nm ⁇ 10 nm, preferably 160 nm ⁇ 5 nm, more preferably 160 nm at a wavelength of 640 nm.
  • a retardation layer is most preferable as a quarter-wave plate, but a retardation plate having a small retardation wavelength dispersion or a forward dispersion retardation plate can also be used.
  • Reverse dispersion means the property that the absolute value of the phase difference becomes larger as the wavelength becomes longer, and “forward dispersion” means the property that the absolute value of the phase difference becomes larger as the wavelength becomes shorter.
  • the laminated quarter-wave plate is formed by laminating a quarter-wave plate and a half-wave retardation plate at an angle of 60 ° with the slow axis, and the side of the half-wave retardation plate is linearly polarized. It is arranged on the incident side and the slow axis of the half-wave retardation plate is used so as to cross 15 ° or 75 ° with respect to the polarization plane of the incident linearly polarized light. Can be suitably used because of its good resistance.
  • ⁇ / 4 wavelength plate is not particularly limited and may be appropriately selected depending on the purpose.
  • a quartz plate a stretched polycarbonate film, a stretched norbornene polymer film, a transparent film oriented containing inorganic particles having birefringence such as strontium carbonate, and an inorganic dielectric obliquely on a support
  • a deposited thin film For example, a deposited thin film.
  • ⁇ / 4 wavelength plate for example, (1) a birefringent film having a large retardation and a birefringence having a small retardation described in JP-A-5-27118 and JP-A-5-27119 A retardation film obtained by laminating the optical films so that their optical axes are orthogonal to each other, (2) a polymer film having a ⁇ / 4 wavelength at a specific wavelength described in JP-A-10-68816 And a retardation film which can be obtained by laminating a polymer film made of the same material and having a ⁇ / 2 wavelength at the same wavelength to obtain a ⁇ / 4 wavelength in a wide wavelength region, (3) JP-A-10-90521 (4) International Publication No.
  • a commercially available product can be used as the ⁇ / 4 wavelength plate. Examples of the commercially available product include Pure Ace (registered trademark) WR (polycarbonate film manufactured by Teijin Limited).
  • the quarter wavelength plate may be formed by aligning and fixing a polymerizable liquid crystal compound or a polymer liquid crystal compound.
  • a liquid crystal composition is applied to the surface of a temporary support, an alignment film, or a front plate, and a polymerizable liquid crystal compound in the liquid crystal composition is formed into a nematic alignment in a liquid crystal state, and then photocrosslinked. It can be formed by immobilization by thermal crosslinking. Details of the liquid crystal composition and the production method will be described later.
  • a quarter-wave plate is formed by applying a liquid crystal composition on a surface of a temporary support, an alignment film, or a front plate to form a nematic alignment in a liquid crystal state and then cooling the composition containing a polymer liquid crystal compound. It may be a layer obtained by immobilizing.
  • the ⁇ / 4 wave plate may be in direct contact with the cholesteric circularly polarized light reflection layer, may be adhered by an adhesive layer, and is preferably in direct contact.
  • a preparation material and a preparation method of a quarter-wave plate formed from a cholesteric liquid crystal layer and a liquid crystal composition will be described.
  • the material used for forming the quarter wavelength plate include a liquid crystal composition containing a polymerizable liquid crystal compound.
  • the material used for forming the cholesteric liquid crystal layer include a liquid crystal composition containing a polymerizable liquid crystal compound and a chiral agent (optically active compound).
  • the cholesteric liquid crystal layer as a temporary support, a support, an alignment film, a high Re retardation film, and a lower layer is prepared by mixing the liquid crystal composition, which is further mixed with a surfactant or a polymerization initiator as necessary, and dissolved in a solvent. Alternatively, it can be applied to a quarter wavelength plate or the like, and after alignment aging, the liquid crystal composition can be fixed by curing to form a cholesteric liquid crystal layer and / or a quarter wavelength plate.
  • a polymerizable rod-shaped liquid crystal compound may be used.
  • the polymerizable rod-like liquid crystal compound include rod-like nematic liquid crystal compounds.
  • rod-like nematic liquid crystal compounds include azomethines, azoxys, cyanobiphenyls, cyanophenyl esters, benzoic acid esters, cyclohexanecarboxylic acid phenyl esters, cyanophenylcyclohexanes, cyano-substituted phenylpyrimidines, alkoxy-substituted phenylpyrimidines.
  • Phenyldioxanes, tolanes and alkenylcyclohexylbenzonitriles are preferably used. Not only low-molecular liquid crystal compounds but also high-molecular liquid crystal compounds can be used.
  • the polymerizable liquid crystal compound can be obtained by introducing a polymerizable group into the liquid crystal compound.
  • the polymerizable group include an unsaturated polymerizable group, an epoxy group, and an aziridinyl group, preferably an unsaturated polymerizable group, and particularly preferably an ethylenically unsaturated polymerizable group.
  • the polymerizable group can be introduced into the molecule of the liquid crystal compound by various methods.
  • the number of polymerizable groups possessed by the polymerizable liquid crystal compound is preferably 1 to 6, more preferably 1 to 3. Examples of polymerizable liquid crystal compounds are described in Makromol. Chem. 190, 2255 (1989), Advanced Materials, 5, 107 (1993), US Pat. No.
  • the content of the polymerizable liquid crystal compound in the liquid crystal composition is preferably 80 to 99.9% by mass, and preferably 85 to 99% with respect to the solid content mass (mass excluding the solvent) of the liquid crystal composition. It is more preferably 5% by mass, particularly preferably 90 to 99% by mass.
  • the material used for forming the cholesteric liquid crystal layer preferably contains a chiral agent.
  • the chiral agent has a function of inducing a helical structure of a cholesteric liquid crystal phase.
  • the chiral agent may be selected according to the purpose because the helical sense or helical pitch induced by the compound is different.
  • the chiral agent is not particularly limited, and is a compound that is usually used (for example, Liquid Crystal Device Handbook, Chapter 3-4-3, TN, chiral agent for STN, 199 pages, Japan Society for the Promotion of Science, 142nd Committee, 1989. ), Isosorbide and isomannide derivatives can be used.
  • a chiral agent generally contains an asymmetric carbon atom, but an axially asymmetric compound or a planar asymmetric compound containing no asymmetric carbon atom can also be used as the chiral agent.
  • the axial asymmetric compound or the planar asymmetric compound include binaphthyl, helicene, paracyclophane, and derivatives thereof.
  • the chiral agent may have a polymerizable group. When both the chiral agent and the liquid crystal compound have a polymerizable group, they are derived from the repeating unit derived from the polymerizable liquid crystal compound and the chiral agent by a polymerization reaction between the polymerizable chiral agent and the polymerizable liquid crystal compound.
  • the polymerizable group possessed by the polymerizable chiral agent is preferably the same group as the polymerizable group possessed by the polymerizable liquid crystal compound. Therefore, the polymerizable group of the chiral agent is also preferably an unsaturated polymerizable group, an epoxy group or an aziridinyl group, more preferably an unsaturated polymerizable group, and an ethylenically unsaturated polymerizable group. Particularly preferred.
  • the chiral agent may be a liquid crystal compound.
  • the content of the chiral agent in the liquid crystal composition is preferably 0.01 mol% to 200 mol%, more preferably 1 mol% to 30 mol%, based on the amount of the polymerizable liquid crystal compound.
  • the liquid crystal composition used in the present invention preferably contains a polymerization initiator.
  • the polymerization initiator to be used is preferably a photopolymerization initiator that can start the polymerization reaction by ultraviolet irradiation.
  • photopolymerization initiators include ⁇ -carbonyl compounds (described in US Pat. No. 2,367,661 and US Pat. No. 2,367,670), acyloin ethers (described in US Pat. No. 2,448,828), ⁇ -hydrocarbons.
  • a substituted aromatic acyloin compound (described in US Pat. No.
  • the content of the photopolymerization initiator in the liquid crystal composition is preferably 0.1 to 20% by mass, more preferably 0.5% to 5% by mass with respect to the amount of the polymerizable liquid crystal compound. .
  • the liquid crystal composition may optionally contain a crosslinking agent in order to improve the film strength after curing and improve the durability.
  • a crosslinking agent one that can be cured by ultraviolet rays, heat, moisture, or the like can be suitably used.
  • polyfunctional acrylate compounds such as a trimethylol propane tri (meth) acrylate and a pentaerythritol tri (meth) acrylate
  • Glycidyl (meth) acrylate And epoxy compounds such as ethylene glycol diglycidyl ether
  • aziridine compounds such as 2,2-bishydroxymethylbutanol-tris [3- (1-aziridinyl) propionate] and 4,4-bis (ethyleneiminocarbonylamino) diphenylmethane
  • Isocyanate compounds such as methylene diisocyanate and biuret type isocyanate
  • vinyltrimethoxysilane and N- (2-amino) Chill) 3-aminopropyl alkoxysilane compounds such as trimethoxysilane.
  • the catalyst normally used can be used according to the reactivity of a crosslinking agent, and productivity can be improved in addition to film
  • the content of the crosslinking agent in the liquid crystal composition is preferably 3% by mass to 20% by mass, and more preferably 5% by mass to 15% by mass. When the content of the crosslinking agent is not less than the above lower limit, an effect of improving the crosslinking density can be obtained. Moreover, the stability of the layer formed can be maintained by setting it as the said upper limit or less.
  • an alignment control agent that contributes to stable or rapid planar alignment may be added.
  • the alignment control agent include fluorine (meth) acrylate polymers described in paragraphs [0018] to [0043] of JP-A-2007-272185 and paragraphs [0031] to [0034] of JP-A-2012-203237. And compounds represented by the formulas (I) to (IV) as described above.
  • 1 type may be used independently and 2 or more types may be used together.
  • the addition amount of the alignment control agent in the liquid crystal composition is preferably 0.01% by mass to 10% by mass, more preferably 0.01% by mass to 5% by mass with respect to the total mass of the polymerizable liquid crystal compound. 0.02% by mass to 1% by mass is particularly preferable.
  • the liquid crystal composition may contain at least one selected from a surfactant for adjusting the surface tension of the coating film to make the thickness uniform, and various additives such as a polymerizable monomer.
  • a polymerization inhibitor, an antioxidant, an ultraviolet absorber, a light stabilizer, a colorant, metal oxide fine particles, and the like may be added as long as the optical performance is not deteriorated. Can be added.
  • organic solvent is used preferably.
  • the organic solvent is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include ketones, alkyl halides, amides, sulfoxides, heterocyclic compounds, hydrocarbons, esters and ethers. It is done. These may be used individually by 1 type and may use 2 or more types together. Among these, ketones are particularly preferable in consideration of environmental load.
  • the method for applying the liquid crystal composition to the temporary support, the alignment film, the high Re retardation film, the quarter wavelength plate, and / or the lower cholesteric liquid crystal layer is not particularly limited and is appropriately selected according to the purpose.
  • wire bar coating method, curtain coating method, extrusion coating method, direct gravure coating method, reverse gravure coating method, die coating method, spin coating method, dip coating method, spray coating method and slide coating method etc. Is mentioned. It can also be carried out by transferring a liquid crystal composition separately coated on a support. The liquid crystal molecules are aligned by heating the applied liquid crystal composition.
  • cholesteric alignment may be performed, and in forming the quarter-wave plate, nematic alignment is preferable.
  • the heating temperature is preferably 200 ° C. or lower, and more preferably 130 ° C. or lower.
  • the heating temperature is preferably 25 ° C. to 120 ° C., more preferably 30 ° C. to 100 ° C.
  • the aligned liquid crystal compound can be further polymerized to cure the liquid crystal composition.
  • the polymerization may be either thermal polymerization or photopolymerization by light irradiation, but photopolymerization is preferred. It is preferable to use ultraviolet rays for light irradiation.
  • the irradiation energy is preferably 20mJ / cm 2 ⁇ 50J / cm 2, 100mJ / cm 2 ⁇ 1,500mJ / cm 2 is more preferable.
  • light irradiation may be performed under heating conditions or in a nitrogen atmosphere.
  • the irradiation ultraviolet wavelength is preferably 350 nm to 430 nm.
  • the polymerization reaction rate is preferably high from the viewpoint of stability, preferably 70% or more, and more preferably 80% or more.
  • the polymerization reaction rate can be determined by measuring the consumption ratio of the polymerizable functional group using an IR absorption spectrum.
  • each cholesteric liquid crystal layer is not particularly limited as long as it exhibits the above characteristics, but is preferably in the range of 1.0 to 150 ⁇ m, more preferably in the range of 2.5 to 100 ⁇ m.
  • the thickness of the quarter-wave plate formed from the liquid crystal composition is not particularly limited, but is preferably 0.2 to 10 ⁇ m, more preferably 0.5 to 2 ⁇ m.
  • Example> [Example 1] ⁇ 1.
  • Production of resin film> (1) Preparation of core layer cellulose acylate dope The following composition was put into a mixing tank and stirred to prepare a core layer cellulose acylate dope solution. ----------------------- Core layer cellulose acylate dope solution ---------------------------- -100 parts by mass of cellulose acetate having an acetyl substitution degree of 2.88 and a weight average molecular weight of 260,000-10 parts by mass of phthalate ester oligomer A having the following structure-4 parts by mass of compound (A-1) represented by the following formula I
  • Ultraviolet absorber represented by the following formula II (manufactured by BASF) 2.7 parts by mass / light stabilizer (manufactured by BASF, trade name: TINUVIN123) 0.18 parts by mass / N-alkenylpropylenediamine triacetic acid (Nagase Chem) Manufactured by Tex Co.
  • Phthalate oligomer A weight average molecular weight: 750
  • UV absorber represented by Formula II Formula II:
  • the thickness unevenness of the entire casting band was 0.5% or less.
  • An initial film was formed on the obtained cast film by applying quick dry air having a wind speed of 8 m / s, a gas concentration of 16%, and a temperature of 60 ° C. to the cast film surface. Thereafter, 140 ° C. drying air was blown from the upstream side of the upper part of the casting band. From the downstream side, 120 ° C. drying air and 60 ° C. drying air were blown. After the residual solvent amount was about 33% by mass, it was peeled off from the band. Next, both ends in the width direction of the obtained film were fixed with a tenter clip, and a film having a solvent residual amount of 3 to 15% by mass was dried while being stretched 1.06 times in the transverse direction.
  • Second resin film (C) A second resin film (C) having a thickness of 100 ⁇ m was produced by the same production method as that for the first resin film (A).
  • Epocross WS300 trade name (manufactured by Nippon Shokubai Co., Ltd.), oxazoline group-containing polymer HEC: hydroxyethyl cellulose, weight average molecular weight 74,000 Gohsenx Z410: trade name (manufactured by Nippon Synthetic Chemical Co., Ltd.), acetoacetyl-modified polyvinyl alcohol PVA-117H: Kuraray Poval PVA-117H (trade name, manufactured by Kuraray Co., Ltd.), polyvinyl alcohol
  • 2-EHGE 2-ethylhexyl glycidyl ether
  • CPI100P trade name (manufactured by San Apro), triarylsulfonium salt-based photoacid generator shown below
  • Thruria 2320 trade name (manufactured by Nikka Catalysts), hollow silica, average particle size 50 nm, solid content concentration 20.5 mass%. In the table, the blending mass ratio in terms of solid content is shown.
  • ZrO 2 Zirconium oxide, average particle size 4 nm
  • curable composition for forming hard coat layer > The components shown in Table 2 below were mixed and filtered through a polypropylene filter having a pore size of 10 ⁇ m to prepare curable compositions HC-1 and HC-2 for forming a hard coat layer (HC layer).
  • DPHA Mixture of dipentaerythritol pentaacrylate and dipentaerythritol hexaacrylate (manufactured by Nippon Kayaku Co., Ltd., trade name: KAYARAD DPHA) Cyclomer M100: 3,4-epoxycyclohexylmethyl methacrylate (Daicel, trade name)
  • HC layer On the surface of the resin film (A) opposite to the adhesive layer (B) of the laminate prepared above, the HC layer-forming curable composition HC-1 is applied and cured to form a hard coat layer. Formed.
  • the coating and curing methods were as follows. In the die coating method using the slot die described in Example 1 of Japanese Patent Application Laid-Open No. 2006-122889, the HC layer forming curable composition was applied at a conveyance speed of 30 m / min, and dried at an ambient temperature of 60 ° C. for 150 seconds. did.
  • the coated curable composition for forming an HC layer was cured to form a hard coat layer HC-1, and then wound up.
  • the HC layer forming curable composition HC-2 shown in Table 2 is applied to the surface of the hard coat layer HC-1 formed above, and dried and cured under the same conditions as the formation of the hard coat layer HC-1. Then, the second HC layer was formed, and the optical film of Example 1 was produced.
  • Example 2 to 4 The optical films of Examples 2 to 4 were prepared in the same manner as in Example 1 except that the adhesive layer forming solution A-2, A-5 or A-6 was used in place of the adhesive layer forming solution A-1. Produced.
  • Example 5 Examples except that an acrylic resin film prepared as described below was used as the resin films (A) and (C), and the adhesive layer forming solution A-4 was used instead of the adhesive layer forming solution A-1. 1 was used to produce an optical film of Example 5.
  • a pellet of Sumitomo Chemical Co., Ltd. acrylic resin (trade name: Sumipex EX) is put into a single screw extruder with an extrusion diameter of 65 mm, melted, melted and integrated by a multi-manifold system, and the film thickness of each layer after drying was controlled to be 5 ⁇ m / 90 ⁇ m / 5 ⁇ m, and extruded through a T-die having a set temperature of 260 ° C. The obtained film-like material was sandwiched between a pair of metal rolls and molded to produce an acrylic resin film having a thickness of 100 ⁇ m.
  • the acrylic resin film is described as PMMA.
  • Example 6 Examples except that the resin film (A) and (C) were prepared as follows and the adhesive layer forming solution A-7 was used instead of the adhesive layer forming solution A-1. 1 was used to produce the optical film of Example 6.
  • ⁇ Preparation of PET resin film> (1) Preparation of Composition for Easy Adhesion Layer Formation (1-1) Preparation of Polyester Resin A sulfonic acid aqueous dispersion of a polyester resin copolymerized with a polymerizable compound having the following composition was obtained.
  • the reaction liquid temperature was maintained at 60 ° C., trimethylbenzylammonium hydroxide as an isocyanurate conversion catalyst was added, and phosphoric acid was added to stop the reaction when the conversion to isocyanurate reached 48%. .
  • unreacted HDI was removed with the thin film distillation apparatus, and the isocyanate type compound a was obtained.
  • the obtained isocyanate compound a had a viscosity at 25 ° C. of 25,000 mPa ⁇ s, an isocyanate group content of 19.9% by mass, a number average molecular weight of 1080, and an average number of isocyanate groups of 5.1.
  • reaction solution temperature was cooled to 60 ° C., 72 parts by weight of diethyl malonate and 0.88 part by weight of a 28% by weight methanol solution of sodium methylate were added and maintained for 4 hours, and then 2-ethylhexyl acid phosphate 0. 86 parts by weight were added. Subsequently, 43.3 parts by mass of diisopropylamine was added, and the reaction solution temperature was maintained at 70 ° C. for 5 hours. This reaction solution was analyzed by gas chromatography, and it was confirmed that the reaction rate of diisopropylamine was 70% to obtain isocyanate compound A (solid content concentration 70% by mass, effective NCO group mass 5.3% by mass). .
  • an ethylene glycol solution of antimony trioxide was continuously supplied, and the reaction was conducted with stirring at a temperature in the reaction vessel of 250 ° C. and an average residence time of about 4.3 hours. At this time, antimony trioxide was continuously added so that the amount of Sb added was 150 mass ppm (mass parts per million) in terms of element.
  • This reaction product was transferred to a second esterification reaction vessel and reacted with stirring at a temperature in the reaction vessel of 250 ° C. and an average residence time of 1.2 hours.
  • the mixture was transferred to the second polycondensation reaction tank, and the reaction was carried out under stirring at a reaction tank temperature of 276 ° C., a reaction tank pressure of 5 torr (6.67 ⁇ 10 ⁇ 4 MPa) and a residence time of about 1.2 hours ( Polycondensation).
  • a reaction tank temperature of 276 ° C. a reaction tank pressure of 5 torr (6.67 ⁇ 10 ⁇ 4 MPa) and a residence time of about 1.2 hours ( Polycondensation).
  • it was further transferred to the third polycondensation reaction tank, and reacted under the conditions of a reaction tank temperature of 278 ° C., a reaction tank pressure of 1.5 torr (2.0 ⁇ 10 ⁇ 4 MPa) and a residence time of 1.5 hours ( Polycondensation) to obtain a reaction product (polyethylene terephthalate (PET)).
  • PET polyethylene terephthalate
  • composition for the second layer shown below By drying the composition for the second layer shown below until the water content becomes 20 mass ppm or less, and then charging it into the hopper of a uniaxial kneading extruder having a diameter of 50 mm and melting it at 300 ° C. with the extruder.
  • a resin melt was prepared for forming a second layer located between the first and third layers.
  • Raw material polyester 1 90 parts by weight UV absorber (2,2 '-(1,4-phenylene) bis (4H-3,1-benzoxazin-4-one)) 10 parts by weight Raw material polyester 2 10 parts by weight -------------------------------------------- After drying the raw material polyester 1 until the water content becomes 20 ppm by mass or less, it is put into a hopper of a uniaxial kneading extruder having a diameter of 30 mm, and melted at 300 ° C. by the extruder, whereby the first layer and the first layer A resin melt for forming the III layer was prepared.
  • the resin melt extruded from the extruder for layer II in the two-layer / three-layer merge block is the inner layer.
  • the resin melt extruded from the extruder for the I layer and the III layer was laminated so as to become an outer layer, and extruded from a die having a width of 120 mm into a sheet shape.
  • the molten resin sheet extruded from the die was extruded onto a cooling cast drum set at a surface temperature of 25 ° C., and was brought into close contact with the cooling cast drum using an electrostatic application method.
  • the film after cooling was peeled from the drum using a peeling roll disposed opposite to the cooling cast drum to obtain an unstretched film.
  • the discharge amount of each extruder was adjusted so that the ratio of the thicknesses of the I layer, the II layer, and the III layer was 10:80:10.
  • the unstretched film is heated using a heated roll group and an infrared heater so that the film surface temperature is 95 ° C., and then 4.0 rolls in the vertical direction from the film transport direction with the roll group having a difference in peripheral speed.
  • the resin film having a thickness of 100 ⁇ m was obtained by double-stretching.
  • Example 7 As the resin films (A) and (C), a polycarbonate film having a thickness of 100 ⁇ m (the retardation in the in-plane direction at 550 nm was 140 nm) produced by referring to Japanese Patent No. 3325560 [Example 3]. Then, an optical film of Example 7 was produced in the same manner as in Example 1 except that the adhesive layer forming solution A-8 was used instead of the adhesive layer forming solution A-1. In Table 3 below, the polycarbonate film is described as PC.
  • Example 8 As the resin film (C), the acrylic resin film (PMMA) prepared above was used, and the adhesive layer forming solution A-9 was used in place of the adhesive layer forming solution A-1. Thus, an optical film of Example 8 was produced.
  • Example 9 to 12 Optical films of Examples 9 to 12 were produced in the same manner as Example 2 except that the thickness of the adhesive layer (B) was changed to the thickness shown in Table 3 below.
  • each adhesive layer forming liquid used above was cast on a glass plate (thickness 1 mm) using an applicator so that the film thickness after drying was 20 ⁇ m, and the atmosphere After drying at a temperature of 80 ° C. for 10 minutes or more, it was peeled off from the glass plate. Using the obtained sample of the adhesive layer, it was tested and calculated in the same manner as the tensile modulus of the resin film.
  • the adhesive layer forming liquid was applied on the resin film (A), and the solvent was removed by drying treatment to form an adhesive layer having a thickness of 1 ⁇ m.
  • the surface refractive index of the obtained adhesive layer was measured by the same method as the refractive index of the resin film.
  • Thickness was measured by observing with a scanning electron microscope (SEM) by the following method. After exposing the cross section of each constituent member (resin film, adhesive layer and HC layer) or a member including each constituent member (for example, a liquid crystal panel or a part thereof) by an ordinary method such as ion beam or microtome, the exposed cross section The cross section was observed with SEM. In cross-sectional observation, various thicknesses were obtained as an arithmetic average of thicknesses at three equal points excluding both ends when the width direction of the member was equally divided into four.
  • SEM scanning electron microscope
  • the optical films of Examples and Comparative Examples are both a first HC layer (HC layer 1) having a thickness of 15 ⁇ m and a second film having a thickness of 5 ⁇ m on the first resin film (A).
  • the HC layer (HC layer 2) is provided in this order.
  • Particles (content%) of the adhesive layer (B) means the kind of particles contained in the adhesive layer (B) and the content mass% of particles in the solid content constituting the adhesive layer (B).
  • Thickness of the optical film means the total thickness of the resin film (A), the adhesive layer (B), and the resin film (C).
  • the optical films of Comparative Examples 1 to 4 are different in refractive index between the resin film (A) and the adhesive layer (B), and the resin film (C) and the adhesive layer (B).
  • the refractive index difference of each is greater than 0.03. All of the optical films of Comparative Examples 1 to 4 had large interference unevenness, and the suppression of interference unevenness was insufficient.
  • the refractive indexes of the resin film (A), the adhesive layer (B), and the resin film (C) satisfy the formulas (1) and (2), and the resin film (A), the adhesive layer (B), and the resin In each of the optical films of Examples 1 to 12 in which the tensile modulus of the film (C) satisfies the formulas (3) to (7) and the thickness of the optical film is greater than 100 ⁇ m, interference unevenness is sufficiently suppressed. In addition, the keystroke durability was excellent.
  • the optical film of the present invention When the optical film of the present invention is used for a front plate of an image display device, an image display device, a mirror with an image display function, a resistive touch panel, and a capacitive touch panel, the front plate or the like has uneven interference. It is sufficiently suppressed, exhibits excellent keying durability, and is considered excellent in manufacturing suitability.
  • Example 13 is the same as Example 3 except that Fujitac TDP40UT (trade name, manufactured by FUJIFILM Corporation, refractive index: 1.48, tensile elastic modulus: 5.4 MPa) is used as the resin film (C). An optical film was produced.
  • Fujitac TDP40UT trade name, manufactured by FUJIFILM Corporation, refractive index: 1.48, tensile elastic modulus: 5.4 MPa
  • Example 14 As in Example 3, except that Fujitac TG40UL (trade name, manufactured by FUJIFILM Corporation, refractive index: 1.48, tensile elastic modulus: 4.8 MPa) was used as the resin film (A). An optical film was produced.
  • Fujitac TG40UL trade name, manufactured by FUJIFILM Corporation, refractive index: 1.48, tensile elastic modulus: 4.8 MPa
  • Warpage Test pieces 101 to 103 having a size of 250 mm x 140 mm were cut out from the produced polarizing plates 101 to 103 so that the direction parallel to the absorption axis of the polarizing plate was a long side.
  • a test piece 104 having a size of 250 mm ⁇ 140 mm was cut out from the produced polarizing plate 104 so that the direction perpendicular to the absorption axis of the polarizing plate was a long side.
  • a glass plate (thickness: 0.3 mm) having a size of 255 mm ⁇ 150 mm was bonded to the surface of the obtained test pieces 101 to 103 on the ZRD 40 side via an acrylic adhesive (20 ⁇ m).
  • the test piece 104 was bonded to the surface of the glass plate opposite to the test pieces 101 to 103 via an adhesive. At this time, bonding was performed so that the absorption axes of the test pieces 101 to 103 and the absorption axis of the test piece 104 were orthogonal to each other, and the ZRD 40 side of the test piece 104 was opposed to the glass plate.
  • the obtained glass plate with a polarizing plate was subjected to a treatment for holding for 48 hours at 60 ° C. and a relative humidity of 90% (hereinafter also referred to as “wet heat treatment”), and then the amount of warpage of the square of the glass plate was measured.
  • the average value was calculated
  • heat treatment a treatment that is held at 80 ° C. for 48 hours
  • the film thickness was determined according to the method described in Test Example 5.
  • first resin film 1B second resin film 2A: adhesive layer 3A: hard coat layer (HC layer) 4A, 4B: Optical film 1: Conductive film for touch panel 2: Touch panel 4C: Optical film 5: Transparent insulating substrate 6A, 6B: Conductive member 7A, 7B: Protective layer 8: First conductive layer 9: Second conductive layer 11A: 1st dummy electrode 11: 1st electrode 12: 1st peripheral wiring 13: 1st external connection terminal 14: 1st connector part 15: 1st metal fine wire 21: 2nd electrode 22: 2nd peripheral wiring 23: 2nd exterior Connection terminal 24: 2nd connector part 25: 2nd metal fine wire C1: 1st cell C2: 2nd cell D1: 1st direction D2: 2nd direction M1: 1st mesh pattern M2: 2nd mesh pattern S1: Active area S2: peripheral area

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Theoretical Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Human Computer Interaction (AREA)
  • Laminated Bodies (AREA)
  • Liquid Crystal (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Electroluminescent Light Sources (AREA)
  • Polarising Elements (AREA)

Abstract

L'invention concerne : un film optique qui est suffisamment supprimé dans une irrégularité d'interférence, tout en ayant une excellente durabilité de codage et similaire; et un panneau avant d'un dispositif d'affichage d'image, un dispositif d'affichage d'image, un miroir ayant une fonction d'affichage d'image, un panneau tactile résistif et un panneau tactile capacitif, dont chacun comprend ce film optique. Ce film optique comprend au moins un premier film de résine, une couche adhésive qui est disposée sur une surface du premier film de résine, et un second film de résine qui est disposé sur la couche adhésive. Les indices de réfraction nA, nB et nC et les modules d'élasticité de traction EA, EB et EC du premier film de résine, de la couche adhésive et du second film de résine satisfont les formules ci-dessous; et l'épaisseur totale du premier film de résine, de la couche adhésive et du second film de résine est supérieure à 100 µm.|nA-nB|≤ 0,03 formule (1)|nC-nB|≤ 0,03 formule (2)|EA-EB|≤ 4,0 GPa formule (3)|EC-EB|≤ 4,0 GPa formule (4) 2,0 GPa ≤ EA formule (5) 2,0 GPa ≤ EB formule (6) 2,0 GPa ≤ EC formule (7)
PCT/JP2018/004448 2017-03-30 2018-02-08 Film optique, et panneau avant d'un dispositif d'affichage d'image, dispositif d'affichage d'image, miroir à fonction d'affichage d'image, panneau tactile résistif et panneau tactile capacitif comprenant chacun ledit film optique Ceased WO2018179893A1 (fr)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2018180746A1 (ja) * 2017-03-30 2019-11-07 富士フイルム株式会社 光学フィルムならびにこれを有する画像表示装置の前面板、画像表示装置、画像表示機能付きミラ−、抵抗膜式タッチパネルおよび静電容量式タッチパネル
WO2020162102A1 (fr) * 2019-02-05 2020-08-13 住友化学株式会社 Corps stratifié optique et dispositif d'affichage
CN111799543A (zh) * 2019-04-02 2020-10-20 东友精细化工有限公司 天线装置及包含其的显示装置
JP2022074108A (ja) * 2020-10-30 2022-05-17 大日本印刷株式会社 積層体および表示装置

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3110235B1 (fr) * 2020-05-18 2023-01-27 Wisetec Group Capteur d’appui securise et ecran tactile associe

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004070737A1 (fr) * 2003-02-03 2004-08-19 Bridgestone Corporation Film transparent electriquement conducteur, feuille transparente electriquement conductrice et panneau digital
JP2007233215A (ja) * 2006-03-03 2007-09-13 Nippon Zeon Co Ltd 偏光板
JP2011102003A (ja) * 2009-11-11 2011-05-26 Toray Ind Inc 導電積層体およびそれを用いてなるタッチパネル
JP2012091406A (ja) * 2010-10-27 2012-05-17 Daicel Corp 透明導電性積層フィルム及びタッチパネル
WO2013150892A1 (fr) * 2012-04-02 2013-10-10 日東電工株式会社 Feuille transparente et son procédé de fabrication
JP2014136386A (ja) * 2013-01-17 2014-07-28 Sekisui Chem Co Ltd 両面導電性フィルム、両面導電性フィルムロール及び両面導電性フィルムを含有するタッチパネル、並びに両面導電性フィルムの製造方法
WO2014171479A1 (fr) * 2013-04-16 2014-10-23 富士フイルム株式会社 Plaque polarisante et dispositif d'affichage d'image
JP2016114938A (ja) * 2014-12-11 2016-06-23 東友ファインケム株式会社Dongwoo Fine−Chem Co., Ltd. 偏光板

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101581800A (zh) * 2008-05-15 2009-11-18 甘国工 复合导电膜及使用该膜的触摸屏
JP5461640B2 (ja) * 2011-09-05 2014-04-02 日東電工株式会社 保護フィルムおよび保護フィルム付偏光板
TWI627068B (zh) * 2011-10-14 2018-06-21 Nitto Denko Corp 具有接著劑層之影像顯示裝置用單元及使用該單元的影像顯示裝置
JP2014012366A (ja) * 2012-07-04 2014-01-23 Mitsubishi Gas Chemical Co Inc 高弾性透明樹脂積層体の製造方法
JP2017033214A (ja) * 2015-07-31 2017-02-09 富士フイルム株式会社 タッチパネル部材及びその製造方法、タッチパネル、並びに、タッチパネル表示装置
US9959444B2 (en) * 2015-09-02 2018-05-01 Synaptics Incorporated Fingerprint sensor under thin face-sheet with aperture layer
WO2017047674A1 (fr) * 2015-09-18 2017-03-23 富士フイルム株式会社 Composé à cristaux liquides polymérisable, composition polymérisable, et film

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004070737A1 (fr) * 2003-02-03 2004-08-19 Bridgestone Corporation Film transparent electriquement conducteur, feuille transparente electriquement conductrice et panneau digital
JP2007233215A (ja) * 2006-03-03 2007-09-13 Nippon Zeon Co Ltd 偏光板
JP2011102003A (ja) * 2009-11-11 2011-05-26 Toray Ind Inc 導電積層体およびそれを用いてなるタッチパネル
JP2012091406A (ja) * 2010-10-27 2012-05-17 Daicel Corp 透明導電性積層フィルム及びタッチパネル
WO2013150892A1 (fr) * 2012-04-02 2013-10-10 日東電工株式会社 Feuille transparente et son procédé de fabrication
JP2014136386A (ja) * 2013-01-17 2014-07-28 Sekisui Chem Co Ltd 両面導電性フィルム、両面導電性フィルムロール及び両面導電性フィルムを含有するタッチパネル、並びに両面導電性フィルムの製造方法
WO2014171479A1 (fr) * 2013-04-16 2014-10-23 富士フイルム株式会社 Plaque polarisante et dispositif d'affichage d'image
JP2016114938A (ja) * 2014-12-11 2016-06-23 東友ファインケム株式会社Dongwoo Fine−Chem Co., Ltd. 偏光板

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2018180746A1 (ja) * 2017-03-30 2019-11-07 富士フイルム株式会社 光学フィルムならびにこれを有する画像表示装置の前面板、画像表示装置、画像表示機能付きミラ−、抵抗膜式タッチパネルおよび静電容量式タッチパネル
WO2020162102A1 (fr) * 2019-02-05 2020-08-13 住友化学株式会社 Corps stratifié optique et dispositif d'affichage
CN111799543A (zh) * 2019-04-02 2020-10-20 东友精细化工有限公司 天线装置及包含其的显示装置
US11973265B2 (en) 2019-04-02 2024-04-30 Dongwoo Fine-Chem Co., Ltd. Antenna device and display device including the same
JP2022074108A (ja) * 2020-10-30 2022-05-17 大日本印刷株式会社 積層体および表示装置
JP7750032B2 (ja) 2020-10-30 2025-10-07 大日本印刷株式会社 積層体および表示装置

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