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WO2018178443A1 - Procédé pour préparer des sucres monosaccharides à partir d'un résidu solide urbain - Google Patents

Procédé pour préparer des sucres monosaccharides à partir d'un résidu solide urbain Download PDF

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Publication number
WO2018178443A1
WO2018178443A1 PCT/ES2018/070213 ES2018070213W WO2018178443A1 WO 2018178443 A1 WO2018178443 A1 WO 2018178443A1 ES 2018070213 W ES2018070213 W ES 2018070213W WO 2018178443 A1 WO2018178443 A1 WO 2018178443A1
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WIPO (PCT)
Prior art keywords
stream
bio
waste
current
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/ES2018/070213
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English (en)
Spanish (es)
Inventor
Quang A. Nguyen
Ana Isabel VICENTE GARCÍA
Vanesa Ramos Garcés
Ignacio CARVAJO LUCENA
Cristina MONTEJO MENDEZ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Abengoa Bioenergia Nuevas Technologias SA
Original Assignee
Abengoa Bioenergia Nuevas Technologias SA
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Priority to PCT/ES2018/070213 priority Critical patent/WO2018178443A1/fr
Publication of WO2018178443A1 publication Critical patent/WO2018178443A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/60—Biochemical treatment, e.g. by using enzymes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B15/00—Combinations of apparatus for separating solids from solids by dry methods applicable to bulk material, e.g. loose articles fit to be handled like bulk material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/30—Destroying solid waste or transforming solid waste into something useful or harmless involving mechanical treatment
    • B09B3/35—Shredding, crushing or cutting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/70—Chemical treatment, e.g. pH adjustment or oxidation
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00—Preparation of compounds containing saccharide radicals
    • C12P19/02—Monosaccharides
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P19/00—Preparation of compounds containing saccharide radicals
    • C12P19/04—Polysaccharides, i.e. compounds containing more than five saccharide radicals attached to each other by glycosidic bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Definitions

  • the field of the invention relates generally to a process for the fractionation of solid waste and for the production of useful products and the recovery of recyclable materials from the different fractions. More particularly, the process of the present invention relates to the fractionation of a mixture of solid waste to provide a clean bio-waste stream suitable for conversion into monosaccharides and to provide recyclable streams that include high density polyethylene plastic and polyethylene terephthalate plastic.
  • MSW urban solid waste
  • RSUs comprise significant amounts of recyclable material including components such as cellular organic bio-wastes (such as food waste, garden waste, wood, paper and cardboard), plastic, glass, ferrous metals, and non-ferrous metals (such as aluminum).
  • cellular organic bio-wastes such as food waste, garden waste, wood, paper and cardboard
  • plastic glass
  • ferrous metals such as aluminum
  • non-ferrous metals such as aluminum
  • the prior art bio-waste fractions are typically impure and contaminated with various components, such as inhibitors of enzymatic hydrolysis and fermentation, which normally convert these cellulosic bio-waste fractions into not suitable for conversion into monosaccharides and fermentation products. optional at an acceptable rate and commercial performance.
  • the methods RSU fractionation of the prior art generally recovers value of organic bio-waste by incineration (energy recovery), gasification (by pyrolysis), or composting. Therefore, there is a need for systems and methods to form cellulosic bio-wastes from a mixture of solid wastes and that said cellulosic bio-wastes have sufficient purity to allow commercially acceptable rates of conversion into monosaccharides by enzymatic hydrolysis.
  • a method for preparing monosaccharide sugars from a mixture of urban solid waste comprises classifying the solid waste mixture into:
  • the first through current is separated by at least a sieve of openings between 170 mm and 380 mm in a second sinking current and a second through current,
  • stage (c) The second sinking current of stage (c) is separated and classified into a classification stage (d) to form:
  • step (b) a stream of fine material with a diameter smaller than the same opening as the screen described in step (b) comprising fermentable material enriched in organic matter
  • step (m) the metals present in the rolling stock of stage (d) are recovered obtaining a recyclable stream free of metals;
  • step (g) the current obtained after stages (e) and (f) is passed through a sieve of openings of 5 to 20 mm to form the third sinking current and a third through current;
  • step (h) a densimetric separation of the third through current is carried out to form a first light current and a first dense current;
  • step (i) the first light stream is separated by a sieve of openings between 25 and 50 mm to form a fourth sinking current and a fourth through current;
  • step (j) the recyclable plastic materials of the fourth through current are recovered by means of an optical separator to form a current
  • step (k) heavy inerts such as stones, sand, glass, etc. are removed. of the fourth sinking current to form a current which, after joining the rejection current obtained from step (j) and undergoing a size reduction process (I forms the clean bio-waste stream (step (I));
  • step (n) the bio-waste stream from step (I) is mixed with a solution of water, acid or base to form the stream of impregnated bio-waste;
  • step (o) it is subjected to the stream of bio-wastes impregnated from stage (n) at a temperature between 100 9 C and 250 e C and at a pressure between 100 kPa and 4,000 kPa for a time between 1 and 20 minutes; and subsequently the pressure is reduced to less than 35 kPa to form the pretreated bio-waste stream;
  • step (p) water, acid or base is added to the pretreated bio-waste stream of step (o) to form a pre-treated bio-waste suspension with pH and humidity conditions suitable for the following stages;
  • step (q) the pretreated bio-residue suspension of step (p) is contacted with an enzymatic cocktail comprising at least one cellulase enzyme so that after a residence time an enzyme hydrolyzate suspension comprising sugars is formed monosaccharides and non-fermentable material, where the non-fermentable material is removed from the enzyme hydrolyzate suspension during or after enzymatic hydrolysis in an optional step (r), resulting in a stream rich in fermentable material.
  • an enzymatic cocktail comprising at least one cellulase enzyme
  • stage (r) The stream rich in fermentable material obtained in stage (r) can be returned to stage (q) to reduce the viscosity of the mixture and increase the residence time of the fermentable material in that stage or be taken directly to a next stage (and ) which can be a yeast fermentation or alternatively a concentration step to produce a sugar syrup.
  • glass is recovered in an optical separator from the third sinking current of step (g) and / or the current comprising removed materials, after recovering non-ferrous materials, in the stage (k).
  • the second through current obtained in step (c) is carried, after passing through a manual triage to a density separation stage where a second light current and a second rich dense current are obtained.
  • a second light current and a second rich dense current are obtained.
  • non-combustible inert matter such as stones, metals, etc.
  • the second light stream enriched in combustible material is crushed at a later stage to give rise to a stream called solid recovered fuel (CSR) derived from waste and with high calorific value.
  • the enzymatic cocktail of step (q) further comprises at least one hemicellulase.
  • step (n) the bio-waste stream is impregnated with acid and in step (p) an aqueous solution of ammonia is added, resulting in a pre-treated bio-residue with a solids content of between 15-30% by weight, a pH between 4 and 6 and a temperature between 30 B C and 70 S C.
  • the acid is an inorganic acid and the pretreated bio-waste stream comprises from 0.01 to 0.15 kg of acid per kg of bio-residue on a dry basis.
  • step (n) the bio-waste stream is impregnated with base and in step (p) an acid solution is added, resulting in a pre-treated bio-residue with a solids content of between 20% and 30% by weight, a pH between 4 and 6 and a temperature between 30 and C and 70 e C.
  • the base is ammonia and the pretreated bio-waste stream comprises 0.1 to 2.5 kg of ammonia per kg of solid-base bio-residue.
  • the enzyme hydrolyzate suspension stream of step (q), during or after hydrolysis is dehydrated to form:
  • aqueous stream can be returned to stage (q) or sent to the fermentation stage (y).
  • the above aqueous stream is concentrated to form a syrup rich in monosaccharide sugars with a monosaccharide sugar content of more than 25% of the total sugars.
  • a yeast is added to the above aqueous stream or to the enzymatic hydrolyzate suspension stream of step (q) to transform the sugars into an organic compound selected from alcohols, preferably ethanol, or organic acids.
  • the yeast is Saccharomyces cerevisiae.
  • step (o) the stream of bio-waste impregnated from step (n) is contacted with steam at a temperature between 130 S C and 250 e C, preferably between 150 e C and 220 e C, and at a pressure of between 400 kPa and 1,570 kPa, preferably between 625 KPa and 1,450 kPa, for a time of between 1 minute to 5 minutes; Y
  • the pressure is reduced to a value between 1 to 35 kPa in a single stage;
  • the pressure is reduced to a pressure between 40% and 60% in a first stage of pressure reduction; said pressure is maintained for a period of time between 0.5 minutes to 20 minutes and subsequently the pressure is reduced to between 1 to 35 kPa in a second pressure reduction stage.
  • Fig. 1 is a block diagram of the separation and classification stages of the gross MSW and the cleaning and treatment of the bio-waste stream.
  • An integrated process is provided in the present invention to prepare monosaccharides from a classified solid waste mixture by enzymatic hydrolysis of classified (fractionated) bio-waste streams enriched in cellulosic components and comprising non-fermentable components.
  • a certain part of the non-fermentable material present in the solid waste mixture is carried out in an enzymatic hydrolysis in aqueous medium from which it is removed from the process with methods of classification by wet route.
  • the elimination of a certain part of the non-fermentable material in an aqueous medium fractionation stage together with the enzymatic hydrolysis stage allows an improved elimination efficiency compared to a dry solid classification stage, and allows the combination of the stages of classification of non-fermentable material and enzymatic hydrolysis thus providing greater efficiency of the classification process and greater performance due to the elimination of the need for one or more stages of classification of the non-fermentable material by dry route which are by other part necessary to eliminate the non-fermentable fraction.
  • the steps of classification (selection or separation) by dry route of the present invention to perform the fractionation of the solid waste mixture to form a stream of bio-waste enriched in cellulosic compounds for conversion into monosaccharides comprises combinations of fractionation techniques that include, but not limited to, manual separation, separation according to the size of the material, separation according to the density of the material, separation according to the dimension of the material, separation according to the optical properties of the material, and separation according to X-ray absorption properties of the material.
  • a certain portion of the non-fermentable material is sent to enzymatic hydrolysis together with the cellulose-rich bio-residue, where it is removed from the hydrolyzate during or after hydrolysis.
  • Said non-fermentable material includes, for example, wire, plastic, rope, sand, brick, metal objects, cork and the like.
  • the wet classification steps of the present invention include without limitation, at least one between flotation, foam removal, filtration, screening, hydraulic classification, rakes, removal of dense solids from a gutter of residual material leaving the bottom of the enzyme hydrolysis vessel, tweezers, waste hatches, and extraction tubes.
  • the complete processes of classification of the mixture of solid waste and generation of monosaccharides provide an efficient generation of several high-value recovered streams including sugar streams comprising glucose, xylose, and their combinations and recovered streams for recycling and reuse including classified plastics, paper, cardboard, beverage cartons, glass and / or metals.
  • plastics streams are also provided which can be classified according to the type of plastic, such as polyethylene terephthalate (“PET”), high density polyethylene (“HDPE”) and polyvinyl chloride (“ PVC “).
  • PET polyethylene terephthalate
  • HDPE high density polyethylene
  • PVC polyvinyl chloride
  • the present invention also provides a solid recovered fuel (“CSR”) that is suitable for use as a power source in steam generation boilers and cement production furnaces.
  • CSR solid recovered fuel
  • the present invention further provides the recovery of paper and cardboard suitable for sale as recyclable material.
  • solid waste mixture refers to a waste stream comprising bio-waste (for example, food waste and garden waste), inorganic materials (eg, dirt, stones and debris), mixing of plastics (for example, at least PET and HDPE), metals (for example, iron, steel, aluminum, brass and / or copper), fiber (for example, paper and cardboard (“P&C”)), glass, textiles, rubber and wood
  • bio-waste for example, food waste and garden waste
  • inorganic materials eg, dirt, stones and debris
  • plastics for example, at least PET and HDPE
  • metals for example, iron, steel, aluminum, brass and / or copper
  • fiber for example, paper and cardboard (“P&C”)
  • glass for example, textiles, rubber and wood
  • RSU refers to the solid waste mixture stream predominantly comprising a mixture of urban and commercial waste.
  • MSW typically include, without limitation, the components detailed in the following Table 1 (on a wet basis). ): Table 1
  • the mixture of solid waste and MSW can be further characterized as a mixture of (i) planar material (or two-dimensional components) such as paper, cardboard, plastic film and at least a part of the mixture of metal components and (ii) rolling stock ( or three-dimensional objects) such as bottles, cans, beverage cartons, inorganic material, glass, at least a part of the mixture of metal components, and a predominant part of the organic fraction.
  • planar material or two-dimensional components
  • rolling stock or three-dimensional objects
  • inorganic material such as bottles, cans, beverage cartons, inorganic material, glass, at least a part of the mixture of metal components, and a predominant part of the organic fraction.
  • bio-waste refers to a fractional stream enriched in organic material suitable for conversion to monosaccharides such as, for example, glucose and / or xylose.
  • the organic material includes, but is not limited to, starch, cellulose, lignocellulose and hemicellulose.
  • Bio-wastes are characterized by comprising at least 30% by weight, at least 35% by weight, at least 40% by weight, at least 45% by weight, at least 50% by weight, at least 55 % by weight, at least 60% by weight, at least 65% by weight, at least 70% by weight, at least 75% by weight, at least 80% by weight or at least 85% by weight organic material (ie "organic content"), and its ranges, such as from about 50 to about 85% by weight, or from about 60 to about 80% by weight of organic material.
  • organic material ie "organic content”
  • predominant As used in the present invention, "predominant”, “predominantly comprising” and “substantial” are defined as at least 50%, at least 75%, at least 90%, at least 95% or at least 99% as p / p%, p / v% ov / v%.
  • recyclable material or M.R refers to the components of the waste mix that have value and include, but are not limited to, paper, cardboard, metals, glass, beverage cartons, plastic, and combinations thereof.
  • enriched refers to a fractional process stream or a fractionated constituent that has a concentration of a cited component that is greater than the concentration of said component (i) in the process stream or in a constituent from which the fractionated process stream or fractionated constituent is produced or (i) in one or more streams divided simultaneously or one or more components split simultaneously.
  • the solid waste mixture can be pre-classified manually, and / or any of the different fractional waste streams can be further processed by manual sorting to recover dangerous objects and materials, removing objects that could damage the classification equipment of RSU and / or recover objects that are large and have a high recovery value.
  • Manual sorting can be carried out by personnel on one or more preclassification lines such as placing the waste on a sorting conveyor belt in which the preclassified objects are identified and removed. Examples of manually classified objects include electronic waste, structural steel, tires and tires, containers comprising pressurized compounds (eg, propane), concrete blocks, large rocks, pallets, cardboard, plaster, and the like.
  • hazardous waste such as solvent and chemical containers, paint cans and batteries are preferably removed before fractionation to avoid contamination of bio-waste and other materials from the waste mixture.
  • the solid waste mixture is classified in a first stage of fractionation by stepwise separation (eg screening) to form at least two dimensioned residual currents comprising a first sinking current (4) enriched in organic fiber compared to the solid waste mixture and a first through current (5) enriched in Rolling stock and combustible material (e.g. paper and cardboard) compared to the solid waste mix.
  • the sieve opening size may be between 60 mm and 100 mm, preferably between 70 mm and 90 mm, and more preferably approximately 80 mm.
  • Suitable screening devices include rotary trays, disc sieves, vibrating sieves and oscillating sieves, among others known to any person skilled in the art.
  • a rotary trommel type sieve typically comprises a perforated cylindrical drum or a cylindrical frame that holds a perforated sieve.
  • the trombone can be adequately raised at an angle at the end of the feed or at the end of the discharge, or it may be not raised (i.e. flat).
  • the size separation is achieved as the fed material moves in a spiral or otherwise as it advances inside the rotating drum / sieve, where the material of smaller size than the sieve openings passes through the sieve as a fraction sinking and the material larger than the sieve openings is retained if it moves forward as a through fraction.
  • an internal screw can optionally be used when the drum arrangement is flat or raised at an angle less than about 5 °.
  • the internal screw facilitates the movement of the objects inside the drum, forcing them into a spiral movement.
  • Any of the different trommel designs known in the art is suitable for practicing the different embodiments of the present invention.
  • a trommel having two or more concentric sieves with the thickest sieve located in the innermost section can be used.
  • the trailers can be arranged in series so that the screened and / or retained material exiting a first trommel can be subsequently fed to a second trombone or a series of trailers.
  • a trombone having at least two sections with different aperture sizes can be used, said trombone being optionally arranged in series with one or more additional frames as described above.
  • the sieve type can take different configurations.
  • the sieves can be suitably perforated plates or mesh sieves where the openings can have both square and round shapes.
  • Screen optimization can be based on one or more of the following variables: (i) the necessary dimension of the sieved product, (ii) the opening surface where a square opening provides a surface greater than a round opening having the same diameter that the length of the square opening, (iii) the degree of agitation of the material, (iv) the speed of rotation of the trommel, (v) feed rate, (vi) residence time of the material, (vii) angle of inclination of the drum, (viii) number and size of sieve openings, and (ix) feeding characteristics.
  • a size fractionation stage is associated with a cut size where fractional particles are characterized by a particle distribution.
  • the distribution often includes a number of particles or objects above or below a particular cut, such as a sieve having a fixed aperture size, such as 10 mm, 25 mm, 60 mm , 80 mm or 100 mm.
  • a cutting number (for example, 80 mm) generally means that at least 75% by weight, at least 80% by weight, at least 85% by weight, at least one 95% by weight, at least 95% by weight or at least 99% by weight of the particles or components are larger than the cut-off number (in the case of the through current) and at least 75% in weight, at least 80% by weight, at least 85% by weight or at least 90% by weight, at least 95% by weight or at least 99% by weight of the particles or components are smaller in size than the cutoff number (in the case of the sinking current).
  • an average particle size refers to a particle size distribution where at least 75% by weight, at least 80% by weight, at least 85% by weight or at least 90% by weight. weight, at least 95% by weight or at least 99% by weight of the particles or components pass through a sieve having a specific aperture size.
  • the dimensioned residual currents have a size distribution with a ratio between the small particles and the large particles, that is, the relationship between the particles above the cut and the particles below the cut, of less than 25, less than 20, less than 15, less than 10, less than 8, less than 6, or less than 4.
  • a density cut-off number means that at least 50% by weight, at least 60% by weight, at least 70% by weight, at least 80% by weight or at least one 90% by weight, such as from about 60% by weight to about 90% by weight or from about 60% by weight to about 75% by weight, of the particles or components have a density greater than the cutting number (in the case of a through current) and at least 50% by weight, at least 60% by weight, at least 70% by weight, at least 80% by weight or at least 90% by weight, such as approximately 60% by weight to approximately 90% by weight or from approximately 60% by weight to approximately 75% by weight, of the particles or components have a density less than the cutting number (in the case of a sinking current).
  • the screening of the first stage of fractionation by size can be used in series with at least a second stage of fractionation by size to form at least three sized fractional residual currents.
  • the second sieve opening in the second size fractionation stage is between 170 mm and 380 mm, preferably between 200 mm and 350 mm.
  • a current of size between approximately 80 and 200 mm is obtained, a second current of size between approximately 200 and 350 mm and a third current of size greater than approximately 350 mm. All of them are enriched in recyclable material with respect to the current that feeds the first stage of separation.
  • the current of between 200 and 350 mm will be enriched in recyclable material, while the current greater than 350 mm will contain large recyclable material, and will be rich in combustible material.
  • magnetic separation devices can be used at different points of the systems of the present invention to collect ferrous metals.
  • magnetic separators include magnetic drum, magnetic perpendicular tape, heads with magnetic pulleys, and the like. Suitable locations include, without limitation, the retaining and sieving outputs of the trombone and transport systems, heavy current outputs of the separation by density and transport systems, enzymatic hydrolysis vessel, and optical classification and X-ray classification systems.
  • one or more electrostatic separators for the isolation and separation of plastic components can be operated together with one or more of the systems described in the present invention, including air fractionation, fractionation sieves, transport systems and transfer of material, optical and X-ray classifiers, and bag opening devices.
  • Electrostatic separation systems are known in the art and are commercially available.
  • the separation is plastics according to the type can be carried out by electrostatic separation where a current comprising a mixture of plastics is electrostatically charged (for example by friction or application of a charge) resulting in a positively and negatively charged material, where the PE, PVC and PET plastics have a characteristic and different induced load. For example, PE and PET normally assume a positive charge and PVC normally assumes a negative charge.
  • the positively and negatively charged materials are passed through an electrostatic field formed by counter electrodes on opposite sides where the positively charged plastic migrates to the side of the negative electrode and the negatively charged plastic migrates to the side of the positive electrode resulting in the separation of the plastic by kind.
  • the manufacturers of electrostatic separation systems include Hitachi Zosen Corporation and others.
  • the first through current (5) is classified, as already described, to separate a stream of fine material (8) (rich in organic matter), a stream of planar material (10) composed of two-dimensional material (for example paper and cardboard (“P&C”)) and a stream of three-dimensional rolling stock (9) composed of plastics.
  • the second sinking current (6) of between 200 and 350 mm approximately, enriched in recyclable material is processed in a bag opening apparatus to release the components that can still be included inside before of additional classification.
  • any of the different process streams comprising a mixture of two-dimensional (planar) and three-dimensional (rolling) objects can be achieved by any of the different density separation techniques known in the technique such as ballistic separators or air separators (for example, linear air separators (pneumatic windshifters separators) and rotary air separators).
  • ballistic separators or air separators for example, linear air separators (pneumatic windshifters separators) and rotary air separators).
  • the classification of the currents enriched in recyclable material is carried out by ballistic separation with screening.
  • ballistic separation with screening separates feed streams based on their size, density and shape properties to form a first fraction comprising rolling objects (e.g., containers, plastic bottles, stone, boats and some metal objects ), a second fraction comprising flat materials (planar) and light materials (for example sheets, textiles, paper and cardboard), and a third fraction of fine material (for example, organic material, food and sand).
  • Said ballistic separators generally comprise an upward slope ramp from the feed end to the discharge end and additionally include a perforated conveyor.
  • the rolling material rotates in the direction of the point of least elevation at the end of the feed and forms the fraction of rolling stock
  • the fine material elements pass through the sieve and constitute the fraction of fine material
  • the light and flat density elements are transported to the exit to form the flat material stream.
  • air can be blown from the feed end to the discharge end to improve the separation efficiency of the flat material and the rolling stock
  • the conveyor can be vibrated or oscillated, optionally, to improve efficiency of separation of fine material.
  • the optimization of ballistic separation can be based on one or more of the following variables: (i) the desired particle size of the fine material, (ii) the location of the feed on the conveyor belt, (iii) the feed rate , (iv) the residence time of the material, (v) the angle of inclination of the conveyor belt, (vi) the number and size of the sieve opening, (vii) the feeding characteristics, (viii) the speed of the air and (ix) the degree of vibration or oscillation.
  • the opening of the ballistic sieve perforations may suitably be between 60 mm and 100 mm.
  • the openings can have both square and round shapes.
  • the size of the opening can be approximately 80 mm.
  • the fine material is an 80 mm through stream characterized by having an organic content of at least 40% by weight, at least 50% by weight or at least 60% by weight.
  • the recyclable material stream is characterized by a glass component and a mixed plastic component comprising PET and HDPE.
  • the recyclable material may further comprise a mixture of metals including aluminum, brass, copper, iron and steel.
  • the planar material stream is characterized by a P&C component.
  • the planar material stream is further characterized by having a combustible component that has a calorific value of at least about 15, 16 or 17 megajoules per kilogram on a dry basis (approximately 7,500 Btu per pound).
  • any of the different streams rich in combustible material (24), (25) or (34) within the scope of the present invention can optionally be conditioned to form CSR.
  • several streams rich in combustible material can be combined and processed.
  • the material is separated by air classification as described in the present invention (such as a linear air separator) to form a second light stream (26) and a second heavy or dense stream (27) in which the light stream is enriched in combustible material compared to heavy current.
  • the light stream is processed in a crushing step to further reduce the volume and particle size and form the CSR.
  • a typical average particle size is about 20 mm to about 50 mm.
  • the CSR can be optionally dried to increase the energy value per unit of weight.
  • the CSR is characterized by having a calorific value of between approximately 17 and approximately 30 megajoules per kilogram (from approximately 7,500 to approximately 13,000 Btu / lb) and less than approximately 25% by weight of water.
  • the CSR within the scope of the present invention can be suitably used as an energy source for boilers and cement production furnaces, or as a gasification substrate.
  • the paper and cardboard stream (38) obtained from the planar stream (10) can optionally be crushed before, after or in parallel with mixing with the aqueous solution (36).
  • the paper and cardboard stream (38) can be suitably combined with the clean bio-waste stream (20) generated from the stream enriched in organic matter in the first stage of size fractionation and the combination of streams can be subjected to impregnation with acid and pretreatment.
  • This pretreated stream (29) which comprises monosaccharides and soluble polysaccharides, can be contacted with a source of enzymes comprising cellulase.
  • the fractional recyclable material stream can be further classified by any optical classification system, X-ray separation, and combinations thereof to fractionate the recyclable material stream into a different streams of plastic material.
  • the recyclable material stream can be fractionated by optical classification and / or X-ray separation as described in the present invention, optionally with the additional combination of at least one manual classification stage, to isolate a number of streams rich in recyclable materials including a plastic film stream, a HDPE stream, a PET stream, and a stream of mixed plastics.
  • Other possible streams rich in recyclable materials generated from the fractional rolling stock stream may include, a stream of PVC plastic, a mixed metal stream, metal streams classified by alloy (e.g., aluminum, brass and copper), a stream of beverage cartons, a paper stream and / or a cardboard stream.
  • the residual material remaining after the fractionation of the rolling stock stream is enriched in combustible material compared to the different recovered streams, and can be sent to the CSR formation conditioner as described in the present invention.
  • the planar material stream generated in the two-dimensional / three-dimensional fractionation (eg ballistic separation) of the stream enriched in recyclable material generated in the first stage of size fractionation can optionally be classified by optical classification as has been described in the present invention to form a recovered P&C stream (38) and a stream rich in combustible material (34).
  • the stream rich in combustible material is sent to the conditioner as described herein. invention.
  • the P&C stream can have value as recovered stream or can be processed by cleaning bio-waste and milling as described in the present invention to form cellulosic material for conversion to monosaccharides.
  • Optical classifiers are known in the art and include, but are not limited to, near infrared (NIR) and color camera classifiers.
  • NIR near infrared
  • the optical classifier can be operated by scanning the intermediate waste stream in free fall by means of a camera sensor.
  • Other optical classifiers use near infrared and other scanning technologies to separate the desired materials from mixed currents.
  • the mixed plastic streams can be classified by the type of plastic based on the reaction principle of electrons in the material of the objects to be analyzed under infrared light, where the molecules in the object to be analyzed react with infrared light with an electronic excitation model characteristic of the composition of the material.
  • the infrared detector and the associated computer read and interpret the model, assign a type of material (for example, HDPE, PET or PVC plastic) according to the interpretation, and classify (separate) the objects based on the type of material.
  • a sensor such as a camera or light sensor detects a characteristic signal of the material to be separated and transmits the detection signals to a computer system where the signals are analyzed by running an algorithm in the computer system to determine the relative composition or identify the material with with respect to a pre-configured composition or relative value.
  • the computer system transmits an output signal to activate air jets to quickly eject the material while it is in free fall.
  • Any number of optical classifiers can be used in series or in parallel. The manufacturers of optical classifiers include TiTech Pellenc, MSS, NRT, and others.
  • X-ray classification systems are based on the measurement of X-ray absorptions in a material at different energy levels in order to determine the relative atomic density of the material. More particularly, the absorption of X-rays in a material is a function of the atomic density of the material and also a function of the energy of the incident X-rays where a given piece of material will absorb X-rays to varying degrees depending on the energy of the rays X incidents
  • An X-ray sensor detects a characteristic signal from the material a separating and transmitting the detection signals to a computer system where the signals are analyzed and an algorithm is executed in the computer system to determine the relative composition or identify the material with respect to a pre-configured composition or relative value.
  • the computer system transmits an output signal to activate air jets to quickly eject the material while it is in free fall.
  • This technology can evaluate the entire object and examines the entire object taking into account exterior and interior variations.
  • classification systems are described in US Patent No. Q. 7,564,943 and are commercially available, such as from National Recovery Technologies, LLC of Nashville, Tenn.
  • X-ray classifiers can be used in combination with optical classifiers.
  • a matrix of dual-energy X-ray detectors is placed below the surface of a conveyor belt used to transport mixed waste through a detection region located between a matrix of detectors and an X-ray tube.
  • Suitable detector matrices can be obtained from Elekon Industries (Torrance, Calif.) and X-ray tubes can be obtained from Lohmann X-ray (Leverkusan, Germany).
  • the X-ray tube is preferably a broadband source that radiates a sheet of X-rays preferably collided through the width of the conveyor belt along the array of dual-energy X-ray detectors such that X-rays They pass through this detector region and the conveyor belt before reaching the detectors.
  • the X-rays transmitted through it are detected by the array of dual-energy X-ray detectors at two different energy levels.
  • the detection signals are transmitted to a computer system and the signals are analyzed by running an algorithm in the computer system to determine the relative composition of the material with respect to a preconfigured relative composition.
  • a matrix of high-speed air ejectors is arranged downstream with respect to the detection region and is located across the path width of the materials discharged by the end of the conveyor belt.
  • the computer executes the algorithm of classification and selection of materials and, according to the results derived from the execution of the algorithm, the signals of the computer system select which air ejectors from the matrix of air ejectors will be activated and expelled, from this shape, the materials selected from the material flow of according to the calculated relative composition.
  • the sequence of detection, selection, and ejection can take place simultaneously on multiple paths along the width of the conveyor belt so that multiple samples of material can be analyzed and sorted at the same time.
  • Optical classification systems and X-ray classification systems can be configured to scan a stream of a waste mixture and determine if the material to be analyzed is a particular type of material such as plastic, paper, or glass, and recover (i) HDPE plastic, PET plastic, plastics n Q 3 to 7 and / or polyvinyl chloride (PVC) type plastics, (ii) glass and / or (iii) paper from a stream of a mixture of waste comprising organic particles and / or inorganic particles.
  • Optical sorting systems and X-ray sorting systems can be further configured to distinguish between types of plastics, such as HDPE plastic, PET plastic and PVC plastic so that a stream containing a mixture of plastics can be classified into streams According to the type of plastic.
  • an optical classification system or an X-ray classification system can use air directed towards the nozzles to expel the searched / identified material to produce one or more recycled such as recyclable PET, HDPE recycled, recyclable plastic film, plastic n and 3 to 7 recyclable recyclable glass and / or recyclable paper products products.
  • a waste mixture can be introduced into a conveyor, the speed of which is selected such that the waste mixture is thrown by the end of the conveyor.
  • the optical sensor or the X-ray system is programmed by a computer program in a computer system to detect the shape, type of material, color or translucency levels of particular objects.
  • the computer system connected to the optical sensor or X-ray system can be programmed to detect the type of plastic material associated with plastic bottles, such as PET, HDPE, and PVC.
  • Objects that have the preprogrammed material characteristics are detected by the optical sensors or the X-ray system when they pass through a beam of light or X-ray and the computer system connected to the sensor sends a signal that activates an air nozzle for ejection to high pressure.
  • any of the different currents generated in a first X-ray optical classification system can optionally be processed in at least one additional optical / X-ray classification system to produce any one of a stream of plastic material classified by type (for example, PET, HDPE or PVC), glass classified by color, paper.
  • the rest of the residual current from one or more optical / X-ray classifiers is typically a stream of particulate material rich in organic material.
  • the first sunken stream (4) from the first stage of fractionation enriched in bio-waste can be fractionated with a sieve and having a mesh size of about 5 mm to about 20 mm, about 5 mm at about 15 mm, from about 8 mm to about 12 mm, or about 10 mm to form (i) a third sunken stream (13) enriched in inert compounds and having an inorganic material content of at least 50% by weight , at least 55% by weight, or at least 60% by weight, such as about 65% by weight and an organic matter content of less than 50% by weight, less than 45% by weight or less than 40 % by weight, such as about 35% by weight and (ii) a third through stream (12) of crude bio-waste having an organic matter content of at least 40% by weight, at least 45% by weight, at least 50% by weight, at least one 55% by weight or at least 60% by weight and having an average particle size between about 5 mm and about 80 mm, between about 10 mm and about 80 mm
  • any of the different bio-waste streams can be processed by density separation to form a first or second dense rejection stream and an intermediate bio-waste stream.
  • the first dense rejection stream (15) is enriched in inorganic compounds, glass and metal, and has a high density in grams per cubic centimeter, compared to the intermediate bio-waste stream.
  • the first rejection stream can be purged from the process, or it can be further processed for the recovery of the metal and / or glass included by any of the different methods described in the present invention.
  • Suitable density separation methods are known in the art and include, without limitation, air separators such as linear air separators (available, for example, from Nihot) and rotary air separators.
  • Linear air separators separate a feed stream into light and heavy fractions where light materials are separated from heavy materials in a separation unit with air flow control.
  • the light materials are separated from the air stream in the separation unit and transported outside the separation unit and the heavy fraction is sunk into the separation unit.
  • the separation efficiency varies with the composition of the feed stream, but typically from about 70% by weight to about 80% by weight or from about 75% by weight to about 85% by weight of the inert material (eg, inorganic material ) is separated from the heavy fraction and at least 95% by weight or at least 98% by weight of the paper and the cardboard is separated from the light fraction.
  • the rotary air separation comprises a device that has an opening provided with a sleeve through which air is blown, the sleeve being surrounded by a cylindrical sieve that rotates past the opening.
  • the material to be separated is deposited on the sieve in the area of the sleeve opening, and the fine material is drawn through the sieve as a through stream (as allowed by the size of the sieve opening) and transported by flow of air to a first collection point.
  • the retained material is dragged into the sieve and transported through the sieve past the sleeve to the opposite side of the separator where it is collected at a second collection point.
  • Dense sieved material (such as gravel) is not transported through the sieve, but instead falls from the sieve on the side of the equipment feed and is collected at a third point.
  • the first light stream (14) is a stream enriched in bio-wastes in which the light stream can be fractionated with a sieve as described in the present invention and having a mesh size between 25 mm and 50 mm to form ( i) a fourth stream of sunken bio-waste (16) having an organic matter content of at least 65% by weight, at least 70% by weight, at least 75% by weight or at least 80% by weight, such as from about 70% by weight to about 85% by weight or from about 70% by weight to about 80% by weight and having a smaller average particle size of approximately 50 mm, and (ii) a fourth through-stream (17) comprising organic material and is enriched in recyclable material (for example, paper, cardboard, plastic, and combinations thereof) compared to the sunken bio-waste stream.
  • a fourth stream of sunken bio-waste (16) having an organic matter content of at least 65% by weight, at least 70% by weight, at least 75% by weight or at least 80% by weight, such as from about 70% by weight to about 85% by weight or
  • the fourth through current (17) can be classified by optical classification and / or classification by X-rays to recover a stream enriched in bio-waste (19) and a recovered current enriched in plastic (18), in comparison with the fourth through current (17).
  • the fourth sinking current (16) they are fractionated by optical or X-ray classification.
  • the classification by X-rays is used.
  • This classification system inerts of the fourth sinking current are eliminated. (16).
  • This inert current mainly composed of stones, bones, sands, is eliminated from the process.
  • the clean stream joins the stream rich in organic matter (19) and is subjected to a grinding process to reduce its size to an average particle size of less than approximately 25 mm.
  • the bio-waste stream (20) is the clean bio-waste stream for conversion into monosaccharides.
  • Said stream has an organic material content of about 70% by weight to about 90% by weight or from about 75% by weight to about 90% by weight.
  • the fourth through stream (17) enriched in recyclable material is further fractionated by optical classification to recover streams comprising a stream rich in organic material (19) and a stream of recirculation that is enriched in recyclable material (18).
  • paper, cardboard, glass, metals and / or plastics can be recovered as individual fractions or streams.
  • the current Rich in organic material is characterized by a particle size greater than 50 mm, and more preferably between 50 mm and 80 mm. This stream is preferably milled as described in the present invention to reduce the particle size to less than 25 mm.
  • the ground stream or not is then combined with the clean bio-waste stream for conversion into monosaccharides.
  • the stream enriched in recyclable material (18), or its individual fractions, are transported to the fractionation of recyclable material by ballistic separation by optical classification and manual classification as described in the present invention for the recovery or purification of plastics, metals, glass, paper and cardboard.
  • the crude bio-waste stream can be fractionated with a sieve having a mesh size between 5 mm and 20 mm, more preferably about 5 mm at approximately 15 mm to form a third sunken current (13) and a third current of bio-waste (12) and (ii) the third current of bio-waste (12) is fractionated by density separation to form a first dense rejection current ( 15) and a first stream of light bio-waste (14) as described in the present invention.
  • the first light bio-waste stream is fractionated with a sieve having a mesh size between 25 mm and 50 mm, to form a fourth sinking current and a fourth through current in which the fourth through current (17) is enriched in recyclable material compared to the fourth sunken current (16) and the fourth current Sunken (16) is enriched in bio-wastes compared to the fourth through current (17).
  • the fourth through current is fractionated by optical classification and / or X-ray classification to recover a stream rich in recyclable material from the fourth through current.
  • the recycled product streams comprising plastics, metals, glass, paper and / or cardboard can be generated by optical classification and / or X-ray classification, or the fourth clean through current (or fractions thereof) can be transported up to the fractionation of rolling stock by ballistic separation by optical classification and manual classification as described in the present invention for the recovery or purification of plastics, metals, glass, paper and cardboard.
  • Rejection currents from the bio-waste cleaning area; third Sink current (13) and current (22) can be sent to a glass recovery area.
  • These rejection currents which can have a glass content of between 10 and 40% by weight or between 20 and 50%, are divided by an optical separator or an X-ray separator generating at least two currents.
  • At this stage at least two currents are generated, one of them enriched in one or more types of glass when compared to the feed current and the other output current, having a glass content of between 50 and 99% by weight , preferably between 60 and 90% or between 70 and 80%.
  • the rejection fractions from the cleaning area of the bio-waste, enriched in one or more types of glass are subjected to a conditioning stage prior to the optical or X-ray separator.
  • This conditioning stage may comprise a density separation, a separation by size or a combination of both, thus increasing the percentage of glass that enters the recovery stage.
  • the streams enriched in bio-waste generated from the sunken stream of the first fractionation stage and having an average particle size greater than about 25 mm are preferably ground to reduce the particle size to less than about 25 mm to maximize the relationship between the surface area and the weight ratio to increase the efficiency of glucose hydrolysis.
  • Any suitable grinding device such as a chopper, hammer mill, crusher, knife mill, cutter, disc mill, centrifugal mill or homogenizer, can be used.
  • the recovered milled bio-waste stream is combined with the clean bio-waste stream and subsequently converted to glucose by hydrolysis.
  • the clean bio-waste stream may comprise an organic matter content of between 70% by weight to 90% by weight or preferably from 75% by weight to 90% by weight.
  • the clean bio-waste stream comprises a soluble organic component and an insoluble organic component.
  • the soluble organic component comprises from about 2% by weight to about 10% by weight of glucan, more preferably from about 2% by weight to about 5% by weight of glucan and from about 0.05% by weight to about 1% by weight.
  • the insoluble component comprises from about 5% by weight to about 20% by weight of glucan, preferably from about 8% by weight to about 20% by weight.
  • the clean bio-waste stream further comprises less than about 40% by weight of ash (inorganic materials), preferably less than about 35% by weight, 30% by weight, 25% by weight, 20% by weight or less than about 15% by weight of ash (inorganic materials).
  • the clean bio-waste stream generated from the sunken current of the first fractionation stage, the stream of fine material enriched in organic matter and / or stream of planar material (paper and cardboard) generated from the through-stream of the First fractionation stage, collectively referred to as "clean bio-waste,” can be converted by one or more hydrolysis steps to achieve an aqueous stream comprising glucose.
  • the glucose stream can be purified to remove impurities and C5 monosaccharides (eg, xylose).
  • the glucose stream can be contacted with a source of at least one fermentation organism to form a fermentation product.
  • the clean bio-waste is combined, or impregnated, with at least one aqueous stream with stirring to form a clean bio-waste suspension having a water content of between 50 to 90% in weight, preferably between 60 to 80% by weight, more preferably between 70 to 80% by weight.
  • the clean bio-residue can be impregnated with an acid to provide a pH of 1, 2, 3, 4, 5 or 6, and any of its intervals, to (i) favor the solubilization of at least a part of the starch, dextrin, disaccharides and / or monosaccharides contained in the bio-residue, (ii) to provide suitable conditions for cellulose, hemicellulose and lignocellulose and / or to sterilize the suspension.
  • dextrin refers to low molecular weight mixtures of glucose polymers produced by starch hydrolysis and bound by ⁇ -1, 4 and ⁇ -1, 6 bonds.
  • the acid concentration in the acid-impregnated clean bio-waste stream can be adjusted to between 0.01 and 0.15 kg of acid per kg of clean bio-residue on a solid base.
  • Mineral acids for example sulfuric acid and hydrochloric acid
  • organic acids may be used, and mineral acids are generally preferred.
  • the clean bio-waste can be optionally impregnated with a base.
  • the base is ammonia and the concentration of ammonia is adjusted to 0.1, 0.5, 1, 1, 5, 2 or 2.5 kg of ammonia per kg of clean bio-residue on a solid base, or adjusted between 0.1 and 2.5 kg of base per kg of clean bio-waste.
  • the concentration of water from the clean bio-waste is adjusted to between 0.3 and 2.5 kg of water per kg of clean bio-residue on a solid base, preferably between 1 and 2 kg of water per kg of clean bio-waste. in solid base.
  • the impregnation of the clean bio-waste can be carried out by any means known in the art to achieve a substantially homogeneous mixture, including stirred mixing tanks (followed by a dehydration stage), in-line mixers, kneading type mixers, paddle mixers , tape mixers.
  • the clean bio-wastes are sprayed with water (optionally comprising acid or base) with mixing in an elevated shear mixer, such as a belt mixer or a kneading type mixer.
  • the impregnated material is normally maintained for a sufficient period of time before pretreatment at elevated pressure and temperature (for example, such as by steam contact) to allow equilibrium of humidity and temperature, such as about 1 to 20 minutes.
  • a suspension comprising clean bio-waste, water (optionally comprising acid or base) is formed by mixing at a moisture content of at least 60% by weight, preferably between 70% by weight and 90% by weight. .
  • the suspension is then dehydrated to result in impregnated clean bio-waste.
  • the final moisture content of the impregnated clean bio-residue is between 20% by weight and 80% by weight, preferably between 30% by weight and 70% by weight, and more preferably between 40% by weight and 60% by weight.
  • bio-waste suspension or the bio-waste suspension with adjusted pH it is processed by at least one solid-liquid separation step to form a liquid stream comprising soluble components of bio-waste (for example, monosaccharides, disaccharides, dextrins and soluble starch) and a solid biomass stream comprising insoluble bio-waste (for example, cellulose, hemicellulose, lignocellulose, minor amounts of dextrin and insoluble starch).
  • soluble components of bio-waste for example, monosaccharides, disaccharides, dextrins and soluble starch
  • insoluble bio-waste for example, cellulose, hemicellulose, lignocellulose, minor amounts of dextrin and insoluble starch.
  • At least a part of the liquid stream can be recirculated to the impregnation step.
  • at least a part of the liquid stream may comprise at least a portion of an aqueous wash stream for washing the fine material with pre-treated organic fiber and the clean bio-waste streams (as described in the present invention).
  • at least a part of the liquid stream may comprise at least a portion of the aqueous wash stream for washing the stream of fine material enriched in bio-waste generated from the fractional stream enriched in rolling stock.
  • the pH of at least a portion of the liquid stream can be adjusted to a suitable range for enzymatic hydrolysis and sent to the enzymatic hydrolysis step (as described in the present invention).
  • the solid biomass stream (optionally impregnated with water, acid or base) is optionally contacted with steam at a high temperature and pressure followed by rapid depressurization at a stage of depressurization.
  • steam pretreatment to enhance the accessibility of cellulosic components of enzymes.
  • the solid biomass stream can be subjected to high pressure and temperature conditions to break the cellulose-hemicellulose and cellulose-hemicellulose-lignin complexes.
  • the pressure of the solid biomass stream is reduced and / or the treated food is discharged to a reduced pressure environment, such as atmospheric pressure, to generate a stream of solid biomass treated with treated steam , and evaporate quickly and vent the steam.
  • the change in pressure results in a rapid expansion of the material that therefore helps to crumble the structure of the biomass fiber that includes, for example, the links between lignin (if present) and hemicellulose and / or cellulose in the cellulose-hemicellulose or cellulose-hemicellulose-lignin complex (called collectively "cellulose complexes").
  • steam treatment normally dissociates cellulose from hemicellulose and lignin (if present) providing cellulose suitable for enzymatic hydrolysis of glucose.
  • Steam treatment normally dissociates hemicellulose from the complex, generally in the form of hemicellulose solubilized in a liquid phase of the treated cellulosic biomass.
  • a part of the hemicellulose contained in the cellulosic biomass such as from about 10% by weight to about 20% by weight, is solubilized in a liquid phase of the treated cellulosic biomass.
  • the steam treatment provides hemicellulose suitable for the enzymatic hydrolysis of the monosaccharides.
  • the solid biomass or the impregnated biomass can be contacted with steam at a temperature between 100 e C and 250 e C, preferably from 150 e C to 250 B C and more preferably from 175 e C to 220 e C, even more preferably from 175 ° C to 200 ° C and at a pressure of between 100 kPa and 4,000 kPa, preferably from 300 kPa to 2500 kPa, more preferably from 400 kPa to 1750 kPa, and even more preferably from 1000 kPa to 1400 kPa.
  • the total contact time is between 1 to 20 nm. In the case of high temperature and pressure, the total contact time is 1 to 5 minutes, and even more preferably 1 to 2 minutes.
  • the pressure is approximately 600 kPa and the contact time is approximately 8 minutes.
  • the pressure is reduced to less than about 35 kPa, for example 30 kPa, 25 kPa, 20 kPa, 15 kPa, 10 kPa or 5 kPa, slightly above the ambient pressure , or at about ambient pressure to form the steam-pretreated insoluble biomass (i) in a single stage of pressure reduction or (ii) from about 345 kPa to about 1380 kPa, from about 345 kPa to about 1205 kPa, of approximately 690 kPa to approximately 1380 kPa, from approximately 690 kPa to approximately 1205 kPa, from approximately 690 kPa to approximately 1035 kPa, or from approximately 1035 kPa to approximately 1205 kPa in a first stage of pressure reduction and maintain it for a period of time from about 0.5 minutes
  • the solid biomass stream (optionally impregnated with an acid or base) is It can be introduced into a container comprising a contact area for steam treatment.
  • the solid biomass stream is normally in the form of a suspension, or cake.
  • the solid biomass stream can be pressed to form a cake, or an agglomerate of treated solids for introduction into the steam treatment vessel.
  • the precise shape and configuration of the container are not very critical and can be selected by one skilled in the art depending on the specific circumstances (for example, the properties of the cellulosic biomass and the operating conditions).
  • the vessel includes an inlet for the introduction of the solid biomass stream and one or more outlets to release the treated cellulosic biomass and / or the various components generated during steam treatment.
  • a stream of steam or gas can be vented continuously or periodically from the steam pretreatment vessel to purge volatile organic compounds ("VOCs") generated as by-products of steam treatment of cellulose, hemicellulose and lignocellulose that are known to be fermentation and / or enzymatic inhibitor compounds.
  • VOCs volatile organic compounds
  • Such inhibitors include, for example, acetic acid, furfural and hydroxymethylfurfural ("HMF").
  • heating of the solid biomass stream can be carried out indirectly, such as by applying steam to a jacketed vessel.
  • the solid biomass stream is maintained at a target temperature and pressure, such as by controlling the pressure, for a time sufficient to provide adequate heating.
  • the solid biomass stream is released or transferred from the contact vessel to a receiving vessel having a reduced and controlled pressure.
  • the pressure and temperature of the container is reduced to an intermediate pressure and temperature and is maintained for a period of time in those conditions, followed by a reduction in pressure or by a pressure slightly higher than atmospheric pressure.
  • the pressure and temperature in the vessel is reduced at atmospheric pressure or at a pressure slightly higher than atmospheric pressure.
  • the sudden decrease in pressure during this release promotes the breakage of the cellulose complex. That is, the sudden decrease in pressure produces a rapid increase in the volume of steam and gases trapped inside the porous structure of the biomass which results in very fast incident gas velocities and / or rapid vaporization of the heated water that has either occupied or been forced into the fibrous structure.
  • the depressurization step generates a sudden vapor stream comprising various VOCs as described above.
  • the clean bio-residue is first impregnated with water before adding it to a pretreatment reactor.
  • the temperature can optionally be adjusted between 30 Q C and 80 Q C, preferably between 40 S C and 60 B C.
  • the clean bio-residue impregnated with water is then added to a pretreatment reactor.
  • the clean bio-waste impregnated with water can be subjected to a partial vacuum in the pretreatment reactor to remove at least part of the trapped air.
  • Anhydrous ammonia is preheated to provide the desired pressure and temperature.
  • the pressurized and heated ammonia is then added to the pretreatment reactor and contacted with the clean bio-residue impregnated with water.
  • the heat of dissolution of ammonia results in an increase in temperature.
  • a person skilled in the art can determine the selection of the combination of (1) temperature and pressure of the anhydrous ammonia and (2) the water content of the clean bio-waste pretreated with water and the temperature necessary to achieve a predetermined pressure and temperature range.
  • the contact time is properly between 5 and 20 minutes.
  • the temperature is suitably between 100 S C and 250 S C, preferably between 120 e C and 200 e C, more preferably between 140 S C and 180 9 C.
  • the pressure is suitably 300 gPa manometric at 2500 kPa gauge, preferably 500 kPa gauge to 2000 kPa gauge, of 700 kPa gauge to 1700 kPa gauge, or 850 kPa gauge to 1400 kPa gauge.
  • the pressure is released quickly after a suitable contact time to expand the cellulosic fibers.
  • the pretreated clean bio-residue is conditioned to form a suspension before coming into contact with a source of enzymes.
  • the pretreated clean biomass is contacted with a cooled aqueous stream, optionally comprising acid or base, to provide a suspension comprising stabilized monosaccharides, solubilized polysaccharides, insoluble compounds comprising cellulose, hemicellulose and / or lignocellulose, and non fermentable material.
  • a cooled aqueous stream may suitably be water with ammonia and, when base pretreatment is performed, such as the expansion of the fibers with ammonia, the cooled aqueous stream may suitably be a stream of mineral acid or an aqueous stream.
  • the cooled aqueous stream has a temperature less than 20 S C, less than 15 e C or less than 10 Q C;
  • the solids concentration of the pretreated clean bio-waste suspension is between 15% and 35% by weight, preferably between 20% by weight and 30% by weight, more preferably between 25% by weight and 35% by weight. weight;
  • the pH of the pretreated clean bio-waste suspension is between 4 and 6, preferably between 4.5 to 5.5;
  • the temperature of the pretreated clean bio-waste suspension is between 30 e C and 70 e C, preferably between 40 e C and 60 e C.
  • the pre-treated conditioned clean bio-waste comprising a non-fermentable component is combined with a source of enzymes comprising at least cellulase to generate a hydrolyzate comprising glucose and to remove at least one stream of non-fermentable material.
  • the non-fermentable material comprises a mixture of components including one or more of wire, plastic, rope, glass, dirt, concrete, brick, metal objects (eg staples, nuts, bolts, nails, etc.), and paper loads.
  • the non-fermentable components may comprise a mixture of milled and non-milled material.
  • at least a part of the non-fermentable material that comes from the through current of the first fractionation stage can be ground to produce pieces of wire, plastic, rope, glass, as well as others non fermentable materials.
  • At least a part of the non-fermentable material that comes from the sinking current of the first fractionation stage may not be ground and include pieces of wire, plastic and rope, fabrics (eg rags), as well as pieces of wire, plastic , rope, glass, and other non-fermentable material.
  • At least a part of the non-fermentable material normally comprises fillers and other compounds used in paper processing that are separated from paper and cardboard during pretreatment and enzymatic hydrolysis.
  • Paper fillers include clay (for example, kaolin clay - insoluble in water), calcium carbonate (slightly soluble in water and soluble in dilute acid) and other calcium-containing components, ink particles, titanium dioxide (insoluble in water and diluted acid), talc (insoluble in water and slightly soluble in dilute mineral acid), components containing magnesium, components containing sodium, components containing potassium, components containing phosphorus and components containing aluminum. These components can be collectively referred to as "ash.” Such ash particles normally have an average particle size in the range of about 1 micrometer to about 5 micrometers.
  • the paper also contains "adhesives” generally composed of polymeric aggregates and may include a mixture of, for example, glues, hot melt plastics, latex coatings and adhesives. Adhesives normally have an average particle size in the range of about 1 micrometer to about 100 micrometers.
  • the cellulosic component of paper and cardboard is generally characterized by an average fiber length of approximately 0.8 mm to approximately 1.2 mm for hardwood fibers, approximately 3 mm to approximately 7 mm for softwood fibers , and from about 1 mm to about 3 mm for non-wood vegetable fibers.
  • the non-fermentable material component is characterized by a density range. Some part of the components are less dense than the enzyme hydrolysis suspension and separate (float) to the surface. Examples of some of said components include plastics and adhesives. Some part of the components has approximately the same density as the enzyme suspension and tend to remain suspended in a stirred suspension of enzymatic hydrolysis. Examples of some of said components include dust and ashes (for example, ash components that have particle sizes of approximately 100 micrometers or less). Some part of the components has a higher density than the enzyme suspension and tend to separate (sink) towards the bottom of the enzyme hydrolysis suspension. Examples of some of said components include metals and rocks.
  • Cellulases are a class of enzymes produced mainly by fungi, bacteria, and protozoa that catalyze cellulolysis (hydrolysis) of cellulose into glucose, cellobiose, celotriose, celotetrose, celopentose, cellohexose, and longer chain celodextrins. Combinations of the three basic types of cellulases can be used. For example, endocellulases can be added to randomly hydrolyze the ⁇ -1, 4, -D-glycosidic bonds in order to disrupt the crystalline structure of the cellulose and expose the individual cellulose chains.
  • Exocellulases can be added to cleave two units (cellobiose), three units (celotriose), or four units (celotetrose) from the exposed chains, while ⁇ -glucosidase can be added to hydrolyze these compounds to glucose, which is available for fermentation .
  • suitable cellulases include, for example, Cellic ® CTec2, Cellic ® CTec3, CELLUCLAST ®, Celluzyme ®, CEREFLO ® and ULTRAFLO ® (available from Novozymes A / S), LA IN EX ®, SPEZYME ® CP (Genencor Int.
  • the liquid stream is preferably sterilized to destroy microbes before being combined with the steam from the pretreated solid biomass stream. Sterilization can be carried out by, for example, temperature treatment, UV radiation, or one of its combinations.
  • a suspension is formed from the pretreated clean bio-residue conditioned in favorable conditions for cellulase activity. More particularly, the pH and temperature of the suspension is adjusted as described above and the content of suspended solids is adjusted between 15% by weight and 35% by weight, preferably from 25% by weight to 30 % by weight, with one or more between process water or aqueous wash streams described in the present invention.
  • the cellulase load in the suspension can be suitably varied with the cellulose content, but the typical load can be expressed as between 5 mg to 50 mg of cellulase per gram of cellulose, more preferably between 10 mg to 30 mg. of cellulase per gram of cellulose. Expressed in another way, The cellulase load is about 5 to about 50 mg of enzymatic protein per gram of cellulose in the treated cellulosic biomass.
  • the cellulase can be combined with the treated biomass suspension by any means known in the art to achieve a substantially homogeneous mixture, including stirred mix tanks, in-line mixers, kneading type mixers, vane mixers, belt mixers, or in reactors of liquefaction such as reactors having at least one mixing section and at least one piston flow section.
  • the enzymatic hydrolysis reactor is normally a stirred vessel designed to maintain the biomass suspension-cellulase mixture at a temperature suitable for cellulose hydrolysis by means of cellulase, where the volume is sufficient to provide the necessary maintenance time for a Significant yield of hexose monosaccharide sugars derived from cellulose ("C6”), for example, glucose.
  • the enzymatic hydrolysis vessel can be isolated and / or heated with a heating jacket to maintain the hydrolysis temperature.
  • the cycle time of total enzymatic hydrolysis is 48 hours to 144 hours, and its intervals are within the scope of the present invention.
  • Glucose yields, based on the total cellulose content of the biomass suspension are normally from about 30% to about 90%, from about 40% to about 80% from about 30% to about 70% or from about 60% to approximately 75% of the theoretical value.
  • mixing with enzymes can be carried out in two stages.
  • the cellulase can be mixed with the biomass in a mixer particularly suitable for the processing of highly viscous materials, for example, a kneading type mixer, a paddle mixer ⁇ single or double shaft), or a mixer Tapes (single or double axis).
  • the high viscosity mixers are particularly suitable for the method of the present invention because the vigorous agitation of the cellulase with the viscous suspension of the treated biomass allows a rapid reduction of the viscosity in the subsequent liquefaction stage where the viscosity is reduced preferably at less than about 20,000 cP, less than approximately 15,000 cP, less than approximately 10,000 cP or even less than approximately 5000 cP.
  • the high viscosity mixer may optionally have a jacket to receive a cooling or heating medium in order to maintain the temperature of the treated biomass during the cellulase addition.
  • a cooling and heating means can be incorporated in the components of the internal mixer (such as in the rotation shafts, vanes) to further enhance the heat exchange.
  • the cellulase can be added by means of one or more addition points, for example, multiple spray nozzles, near the inlet of the treated biomass.
  • the treated biomass-cellulase mixture can be processed in a mixing tank or in a fiber liquefaction bioreactor.
  • the treated biomass-cellulase mixture can be processed in a fiber liquefaction bioreactor to further reduce the viscosity before transfer to a cellulose hydrolysis reactor.
  • the fiber liquefaction bioreactor can be either a continuous mixing design or a design with at least one continuous mixing section and at least one piston flow section.
  • two or more fiber liquefaction bioreactors can be operated in series.
  • the fiber liquefaction bioreactor comprises alternating mixing zones and proximal piston flow zones and the treated biomass-cellulase mixture flows both down through the tower by gravity or is moved up by pumping.
  • the treated biomass-cellulase mixture is normally processed in a fiber liquefaction bioreactor until the viscosity of the mixture is less than about 10,000 cP, less than about 9,000 cP, less than about 8,000 cP, less than about 7,000 cP or less of approximately 5000 cP where it is then transferred to a cellulose hydrolysis reactor.
  • Enzymatic hydrolysis proceeds with the parallel removal of non-fermentable material from the suspension.
  • Suitable disposal methods include, without limitation, flotation, foam removal, filtration, screening, hydraulic classification, rakes, removal of dense solids from a collapsible ramp of residual material leaving the bottom of the enzymatic hydrolysis vessel, tweezers, waste hatches, extraction tubes.
  • Non fermentable floating can be removed by foam removal.
  • Suitable foam removers with known in the art and include floating foam foam eliminators in which the floating material passes over a dam and is collected.
  • Other foam removers include oleophilic foam removers, where the floating material adheres to a rotating element, such as a drum or tape, in contact with the surface layer, and the material that adheres to the element is removed and collected.
  • Other additional foam removers include tube foam removers and membrane foam removers. Any of the different foam removers can be used together with a waste rake or other means to remove floating objects such as pieces of plastic and cloth.
  • the collected liquid fraction can be optionally processed in an oil concentrator or oil-water separator to remove residual aqueous material for recycling to the enzymatic hydrolysis vessel and / or process purge.
  • Foam removal can be used in conjunction with flotation to improve foam removal efficiency.
  • Flotation can be carried out suitably by bubbling pressurized air through the suspension to cause suspended non-fermentable particulate to float to the surface.
  • Flotation can also be carried out by dissolved gas flotation, where the dissolved gas is released at atmospheric pressure in the hydrolysis tank and can also be used to fractionate the suspended non-fermentable material and the gas can be air.
  • the gas is carbon dioxide generated during fermentation. It is believed that the use of residual fermentation gases comprising carbon monoxide for flotation improves glucose performance compared to air flotation by reducing oxidation of monosaccharides.
  • At least a part of the non-fermentable material may be suspended in the enzyme hydrolyzate suspension. At least a part of the suspended non-fermentable material can be removed by recirculation through a sieve or filter having openings of 2 mm to 30 mm, preferably 8 mm to 20 mm or 4 mm to 10 mm in which at least a part of the non-fermentable material is retained in the sieve or filter and is separated from the enzymatic suspension, in which the rest of the enzymatic suspension crosses the sieve.
  • the enzyme suspension filtrate that crosses the sieve can contain fine non-fermentable material such as ash, adhesive components and dust.
  • the coarse fraction may contain soluble sugars that can be recovered in a solid washing step.
  • the fine fraction is filtered a second time by a screen with mesh light between 1 mm and 0.1 mm, where the soluble fraction passes through the screen and non-fermentable solids, such as plastics and fibers, are retained in the sieve and / or pass through the sieve and are recycled to the enzyme hydrolysis vessel.
  • the fraction retained in the second screen comprises insoluble non-fermentable fine solids and may contain soluble monosaccharides, polysaccharides and enzyme.
  • the retained fraction can be washed with any of the aqueous streams obtained at some point in the process of the present invention to recover soluble sugars and enzyme.
  • suitable apparatus for liquid solid separation are the press filter, rotary filter, band filters, centrifuges or the combination thereof.
  • the enzyme hydrolysis vessel has a conical bottom with an outlet at the lower elevation and at least one outlet at a higher elevation, such as in the transition between the side wall and the conical bottom.
  • At least a part of the dense material can be removed from the enzyme hydrolysis vessel by passing the suspension through the outlet located in the lower elevation through a sieve having openings of 4 mm to 30 mm, preferably 4 mm to 20 mm or from 4 mm to approximately 10 mm to collect the dense non-fermentable material on the sieve as a through stream and recycle the filtrate into the enzyme hydrolysis vessel.
  • a conveyor with dehydration is used to remove dense (heavy) non-fermentable material from the outlet located at the bottom of the enzymatic hydrolysis vessel with a recycled aqueous stream for recovery.
  • the enzyme hydrolysis vessel comprises a cuvette with tweezers in the lower section into which the dense non-fermentable material is separated and a bucket elevator to remove the cuvette for cleaning.
  • auxiliary equipment can be used to remove the non-fermentable material from the enzyme hydrolysis vessel.
  • rakes can be used to remove debris such as wires, plastic, rope, cloth, etc.
  • additional enzymes such as a hemicellulase (for example, a xylanase to further hydrolyze the various types of hemicelluloses to xylose), an ⁇ -amylase (to liquefy free starch that is previously trapped in cellulose, hemicellulose and / or lignocellulosic matrices, a ⁇ -amylase, a glucoamylase (for converting the liquefied starch into C6 sugars), an arabinoxylanase, a pululanase, and / or a protease (to hydrolyze the peptide bonds and release embedded starch granules in the protein matrix) can be added to the treated cellulosic biomass to generate C6 sugars Additional and /
  • Non-limiting examples of C6 sugars include glucose, galactose, mannose, and fructose and non-limiting examples of C5 sugars include xylose, arabinose and ribose.
  • Optional enzymes may be mixed with the cellulosic biomass treated at any time during hydrolysis including with cellulase during a high viscosity mixture, in one or more locations of l bioreactor of liquefaction of fibers and / or in the cellulose hydrolysis reactor.
  • a hemicellulase refers to a polypeptide that can catalyze the hydrolysis of hemicellulose in small polysaccharides such as oligosaccharides, or monosaccharides including xylose and arabinose.
  • Hemicellulases include, for example, the following: endoxylanases, ⁇ -xylosidases, aL-arabinofuranosidases, ⁇ -D-glucuronidases, feruloyl esterases, coumarolyl esterases, ⁇ galactosidases, ⁇ -galactosidases, ⁇ -mannases, and ⁇ -mannosidases.
  • a xylanase can be obtained from any suitable source, including fungal and bacterial organisms, such as Aspergillus, Disporotrichum, Penicillium, Neurospora, Fusarium, Trichoderma, Humicola, Thermomyces, Myceliophtora, Crysosporium, and Bacillus.
  • fungal and bacterial organisms such as Aspergillus, Disporotrichum, Penicillium, Neurospora, Fusarium, Trichoderma, Humicola, Thermomyces, Myceliophtora, Crysosporium, and Bacillus.
  • xylanase preparations comprising xylanase include SHEARZYME®, BIOFEED WHEAT®, BIO-FEED Plus®L, ULTRAFLO®, VISCOZY E®, PENTOPAN MONO®BG, and PULPZYME®HC (Novozymes A / S), and LAMIN EX® and SPEZYME®CP (Genencor Int.)
  • An example of a hemicellulase suitable for use in the present invention includes VISCOZYME ® (available from Novozymes A / S, Denmark).
  • proteases for example, acidic, basic or neutral
  • proteases of, for example, Novozymes, Genencor and Solvay are commercially available. Examples include, for example, GC106 (available from Genencor International), AFP 2000 (available from Solvay Enzymes, Inc.), FermGen TM (which is an alkaline protease available from Genencor International), and Alcalase® (which is an acid protease available from Novozymes Corporation).
  • a commercially available pululanase is Promozyme® D2, available from Novozymes Corporation.
  • compositions comprising glucoamylase include: AMG 200L, AMG 300 L, AMG E, SAN® SUPER, SAN® EXTRA L, SPIRIZYME® PLUS, SPIRIZYME® FUEL, SPIRIZYME® FG and SPIRIZYME® E (all available from Novozymes); OPTIDEX® 300 and DISTILLASE® L-400 (available from Genencor Int.); and G-ZYME TM G900, G-ZYME TM 480 Ethanol and G990 ZR (available from Genencor Int.).
  • Examples of commercial acidic ⁇ -amylases of the invention include TERMAMYL ® SC, LIQUOZYME ® SC DS, LIQUOZYME ® SC 4X, and SAN TM SUPER (available all from Novozymes AJS, Denmark); and DEX-LO ® , SPEZYME ® FRED, SPEZYME ® AA, and SPEZYME ® DELTAAA (all available from Genencor).
  • multienzyme complexes containing multiple carbohydrases such as Viscozyme® L, available from Novozymes Corporation, containing arabanase, cellulase, ⁇ -glycanase, hemicellulase, and xylanase.
  • monosaccharides can be extracted or otherwise separated from hydrolyzed biomass.
  • Hydrolyzed biomass can be introduced into a sugar recovery apparatus comprising suitable solids / liquids separation equipment such as, for example, a sieve, filter, centrifuge, settler, percolator, extraction column, flotation vessel, or one of its combinations, to generate a liquid fraction comprising monosaccharide sugars and a solid fraction, where the solid fraction may suitably be in the form of a cake or suspension.
  • the solids fraction can be washed one or more times for the recovery of additional monosaccharides.
  • the monosaccharides can be recovered from the solid fraction by countercurrent contact of the solid fraction with a washing liquid in a suitable apparatus to form a washing current comprising the extracted monosaccharides.
  • the liquid fraction is combined with a liquid medium and / or the wash streams to form a monosaccharide fraction.
  • the precise composition of the liquid medium and the washing liquid are not strictly critical. However, in preferred embodiments of the present invention, the liquid medium and the washing liquid can process water if a relatively high purity monosaccharide fraction is desired.
  • the monosaccharide compositions comprise at least about 5% by weight, at least about 6% by weight, at least about 7% by weight, at least about 8% by weight, at least about 9% by weight. weight, or at least about 10% by weight of monosaccharides.
  • the residual solids fraction comprises a non-hydrolyzed cellulose, non-hydrolyzed hemicellulose, non-hydrolyzed lignocellulose, polysaccharides (eg, starch granules), entrained monosaccharides and lignin.
  • the residual solids fraction can be recycled properly for the recovery of sugars and sugary substrates.
  • the monosaccharide stream can be concentrated to produce a concentrate or syrup with a content of at least 25% by weight, at least 40% by weight or at least 60% by weight.
  • the methods for concentrating this current may be those known in the state of the art and include evaporators, reverse osmosis or the combination of these, among others.
  • This monosaccharide stream can be concentrated in two steps to solids concentrations from about 50% to about 70% by weight or about 40% to about 80% by weight. In a first step in the concentration of monosaccharides, it can be carried out at a temperature from about 50 Q C to about 100 S C or from 70 E C to about 80 S C. In another embodiment of the present invention either of the two evaporation stages or both are carried out under vacuum conditions.
  • Any of various streams of solid biomass treated with enzymes, suspension streams containing fermentable sugars and aqueous streams containing fermentable sugars can be used with suitable microorganisms as a substrate for the production of fermentation products.
  • suitable microorganisms A wide variety of fermentation microorganisms are known in the art, and others can be discovered, produced by mutation, or engineered by recombinant means. Fermentation microorganisms within the scope of the present invention include yeasts, bacteria, filamentous fungi, microalgae, and combinations thereof.
  • Examples of fermentation products within the scope of the present invention include, for example, acids, alcohols, alloys, alkenes, aromatics, aldehydes, ketones, triglycerides, fatty acids, biopolymers, proteins, peptides, amino acids, vitamins, antibiotics, pharmaceuticals, and combinations thereof.
  • Non-limiting examples of alcohols include methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propanediol, butanediol, glycerol, erythritol, xylitol, sorbitol, and combinations thereof.
  • Non-limiting examples of acids include acetic acid, lactic acid, propionic acid, 3-hydroxypropionic acid, butyric acid, gluconic acid, itaconic acid, citric acid, succinic acid, levulinic acid, and combinations thereof.
  • Non-limiting examples of amino acids include glutamic acid, aspartic acid, methionine, lysine, glycine, arginine, threonine, phenylalanine, tyrosine, and combinations thereof.
  • Other examples of fermentation products include methane, ethylene, acetone and industrial enzymes.
  • Fermentation organisms may be natural microorganisms or recombinant microorganisms, and include Escherichia, Zymomonas, Saccharomyces, Candida, Pichia, Streptomyces, Bacillus, Lactobacillus, and Clostridium.
  • the fermentation organism can be recombinant Escherichia coli, Zymomonas mobilis, Bacillus stearothermophilus, Saccharomyces cerevisiae, Clostridia thermocellum, Thermoanaerobacterium saccharolyticum, or Pichia stipites.
  • the microorganism is a microalgae, defined as a eukaryotic microbial organism that contains a chloroplast or plastid, and which is optionally capable of carrying out photosynthesis, or a prokaryotic microbial organism capable of carrying out the photosynthesis.
  • Microalgae include obligate photoautotrophs, which cannot metabolize a fixed carbon source as energy, as well as heterotrophs, which can only live from a fixed carbon source.
  • Microalgae include unicellular organisms that separate from sister cells that shorten after cell division, such as Chlamydomonas, as well as microbes such as, for example, Volvox, which is a simple multicellular photosynthetic microbe of two different cell types.
  • Microalgae include cells such as Chlorella, Dunaliella, and Prototheca. Microalgae also include other microbial photosynthetic organisms that exhibit cell-cell adhesion, such as Agmenellum, Anabaena, and Pyrobotrys. Microalgae also include forced heterotrophic microorganisms that have lost the ability to carry out photosynthesis, such as in certain species of dinoflagellated algae and Prototheca species. Non-limiting examples of fermentative organisms and their associated product include the following. The fermentation of carbohydrates to acetone, butanol and ethanol is known by: (i) Solventgenic Clostridia as described by Jones and Woods (1986) Microbiol. Rev.
  • Amino acid production has been carried out by fermentation using auxotrophic strains and resistant strains similar to Corynebacterium, Brevibacterium, and Serratia amino acids.
  • histidine production using a strain resistant to a histidine analog is described in Japanese Patent Publication N B 8596/81 and it is described to use a recombinant strain in EP 136359.
  • Production of tryptophan using a strain resistant to a tryptophan analog in Japanese patent publications Nos. 4505/72 and 1937/76.
  • Isoleucine production is described using a strain resistant to an isoleucine analog in Japanese Patent Publications Nos. 38995/72, 6237/76, 32070/79.
  • Phenylalanine production is described using a strain resistant to a phenylalanine analog in Japanese Patent Publication 10035/81 N s.
  • Tyrosine production has been described using a strain that requires tyrosine-resistant phenylalanine for growth (Agr. Chem. Soc. Japan 50 (1) R79-R87 (1976)), or a recombinant strain (EP263515, EP332234), and arginine production using a strain resistant to an L-arginine analogue (Agr. Biol. Chem. (1972) 36: 1675-1684, Japanese Patent Publications Nos. 37235/79 and 150381/82).
  • Croorganisms as described in United States Patents N Q 6,861,237, 6,777,207 and 6,228,630.
  • the production of triglycerides, fatty acids and fatty acid esters (e.g., biodiesel) by microalgae is also known as described in US Patents 7883882 N Q, 8,187,860, 8,278,090 and 8,222,010, and in published US patent applications numbers 20100303957, 20110047863 and 201 10250658.
  • suitable fermentation conditions can be carried out suitably by those skilled in the art based on (i) the identity of the microorganisms or a combination of microorganisms, (ii) the characteristics of the substrate medium for fermentation and ( iii) the associated fermentation product. Fermentation can be aerobic or anaerobic. Single and multistage fermentations are within the scope of the present invention.
  • the fermentation substrate medium may be supplemented with additional nutrients necessary for microbial growth. Supplements may include, for example, yeast extract, vitamins, growth promoters, specific amino acids, phosphate sources, nitrogen sources, chelating agents, salts, and trace elements.
  • the components necessary for the production of a specific product prepared by a specific microorganism, such as an antibiotic, may also be included.
  • the fermentation temperature can be any temperature suitable for the growth and production of the nutrients of the present invention, such as between about 20 B C to about 35 e C.
  • the pH of the fermentation can be adjusted or controlled by the addition of a acid or base to the fermentation mixture. In such cases, when ammonia is used to control the pH, it also conveniently serves as a source of nitrogen.
  • the fermentation mixture can optionally be maintained to have a dissolved oxygen content during the course of fermentation to maintain cell growth and to maintain a cellular metabolism for nutrient production.
  • the oxygen concentration of the fermentation medium can be controlled using known methods such as by the use of an oxygen electrode.
  • Oxygen can be added to the fermentation medium using methods known in the art such as by stirring and aeration of the medium by stirring, shaking or use of bubblers.
  • Fermentation can occur after enzymatic hydrolysis or it can occur concurrently with enzymatic hydrolysis by Saccharification and Simultaneous Fermentation (SSF).
  • SSF can maintain the levels of sugars produced by hydrolysis thereby reducing the potential inhibition of the product of enzymes from hydrolysis, reducing the availability of sugar for contaminating microorganisms, and improving the conversion of treated biomass to monosaccharides and / or oligosaccharides .
  • Hexose sugar-containing organisms include yeasts. Any variety of yeasts can be used as yeast in the present method. Typical yeasts include any of a variety of commercially available yeasts, such as commercial strains of Saccharomyces cerevisiae. Suitable commercially available strains include ETHANOL RED (available from Red Star / Lesaffre, USA); BioFenn HP and XR (available from North American Bioproducts); FALI (available from Fleischmann's Yeast); SUPERSTART (available from Lallemand); GERT STRy (available from Gert StrandAB, Sweden); FERMIOL (available from DSM Specialties); and Thennosac (available from Alltech).
  • ETHANOL RED available from Red Star / Lesaffre, USA
  • BioFenn HP and XR available from North American Bioproducts
  • FALI available from Fleischmann's Yeast
  • SUPERSTART available from Lallemand
  • GERT STRy available from Gert StrandAB, Sweden
  • FERMIOL available from D
  • the hexose terminating organism is a recombinant yeast that has at least one transgene that expresses an enzyme useful for converting mono and / or oligosaccharides into ethanol.
  • the fermentation medium has a pH of about 3.5 to about 6, about 3.5 to about 5 or about 4 to about 4.5. If a pH adjustment is required, mineral acids such as sulfuric acid, hydrochloric acid or nitric acid, or bases such as ammonia (ammonium hydroxide) or sodium hydroxide can be used.
  • additional nutrients can be added to enhance yeast proliferation.
  • Such nutrients include without limitation, free amino nitrogen (FAN), oxygen, phosphate, sulfate, magnesium, zinc, calcium, and vitamins such as inositol, pantothenic acid, and biotin.
  • FAN free amino nitrogen
  • Typical sources of FAN include urea, ammonium sulfate, ammonia, amino acids, and ⁇ -amino nitrogen groups of peptides and proteins.
  • the added FAN content is preferably from about 1.2 to about 6 mg N / g of starch, for example 1, 2, 2.4, 3.6, 4.8 or 6 mg N / g of starch.
  • urea it is preferred to add between about 2.4 to about 12 mg of urea per gram of starch, for example, 2.4, 4.8, 7.2, 9.6 or 12 mg of urea per gram of starch
  • Food yeasts that supply, for example, vitamins (such as vitamins B and biotin), minerals (such as magnesium and zinc salts and micronutrients and nutrients can be added to the fermentation medium)
  • Food yeasts can include an autolysed yeast and extracts of plants and are usually added at a concentration of about 0.01 to about 1 g / l, for example, about 0.05 to about 0.5 g / l ..
  • Bactericides can also be optionally added to the fermentation medium.
  • Typical bactericides include virginiamycin nisin, erythromycin, oleandomycin, fiavomycin, and penicillin G. In the case of virginiamycin, a concentration of about 1 ppm to about 10 ppm is preferred.
  • Suitable pentose sugar terming organisms include yeasts.
  • yeasts include Pachysolen tannophilus, Pichia stipites, Candida diddensü, Candida utilis, Candida tropicalis, Candida subtropicalis, Saccharomyces diastaticus, Saccharomycopsis fibuligera and Torula candida.
  • the pentose fermenting organism is a recombinant yeast that has at least one transgene that expresses an enzyme useful for converting mono and / or oligosaccharides into ethanol.
  • the genome of P. stipites can be incorporated into S. cerevisiae by a gene redistribution method to produce a hybrid yeast capable of producing bioethanol from xylose while retaining the ability to survive high concentrations of ethanol.
  • organisms capable of fermenting both hexose and pentose sugars are used to convert monosaccharides into ethanol.
  • organisms are strains of S. cerevisiae that have transgenes encoding one or more enzymes capable of converting pentose sugars to ethanol.
  • the source of the fermentation organism may optionally comprise at least one species of organism Cellulolytic capable of breaking down and metabolizing the non-hydrolyzed cellulose, hemicellulose and / or lignocellulose present in the ethanol fermentation medium.
  • Such cellulolytic organisms are known in the art and include Escherichia coli, Zymomonas mobilis, Bacillus stearothermophilus, Saccharomyces cerevisiae, Clostridia thermocellum, Thermoanaerobacterium saccharolyticum, Pichia stipites and Pachysolen tannophilus. Also within the scope of the present invention are cellulolytic bacteria that have one or more transgenes encoding the ethanol producing route.
  • the source of the fermentation organism further comprises at least one species of cellulolytic organism capable of breaking the non-hydrolyzed hemicellulose present in the combined liquefaction mixture adjusted and capable of synthesizing ethanol.
  • Fermentation products can be recovered using any of several methods known in the art.
  • fermentation products can be separated from other fermentation components by distillation (for example, azeotropic distillation liquid-liquid extraction, solid-liquid extraction, adsorption, gas entrainment, membrane evaporation, pervaporation, centrifugation, crystallization, filtration, microfiltration, nanofiltration, ion exchange, or electrodialysis).
  • distillation for example, azeotropic distillation liquid-liquid extraction, solid-liquid extraction, adsorption, gas entrainment, membrane evaporation, pervaporation, centrifugation, crystallization, filtration, microfiltration, nanofiltration, ion exchange, or electrodialysis.
  • methanol, ethanol, or other fermentation products that have sufficient volatility can be recovered from a fermentation mixture by distillation.
  • 1 -butanol can be isolated from a fermentation mixture using methods known in the art for acetone-butanol-ethanol (“ABE”) fermentations (see, for example, Dur
  • Microbiol. Biotechnol. 49: 639-648 (1998), Groot et al., Method. Biochem. 27: 61-75 (1992), and references cited therein), for example, by removing solids followed by isolation by distillation, liquid extraction - liquid, adsorption, gas entrainment, membrane evaporation, or pervaporation.
  • amino acids can be collected from the fermentation mixture by methods such as adsorption by ion exchange resin and / or crystallization.
  • One skilled in the art can carry out the selection of a suitable separation method for any particular fermentation product.
  • any of the rich organic fractions such as clean bio-waste, organic fiber, insoluble insulated biomass, streams rich in combustible material and / or CSR, can be converted into by-products by gasification methods or gas fermentation methods of gas synthesis known in the art.
  • gasification methods the rich organic fraction is heated at high temperature in an atmosphere with oxygen supply or in the essential absence of oxygen to produce synthesis gas (mainly hydrogen and carbon monoxide) which is subsequently reacted to form a stream of gas comprising one or more carbon compounds.
  • FT Fischer-Tropsch
  • H 2 and CO in synthesis gas are reacted on a catalyst (for example, iron or cobalt) to form a wide range of hydrocarbon chains of various lengths
  • a catalyst for example, iron or cobalt
  • the FT reaction is usually carried out at a pressure of about 20 bar to about 40 bar in a temperature range from both about 200 S C to about 250 Q C or from about 300 S C to about 350 e C.
  • They are generally used iron catalysts in the upper temperature range to produce olefins for a lighter gasoline product and catalysts of cobalt at a lower temperature range to produce longer chains that can be cracked to diesel.
  • the production of methanol from synthesis gas normally involves reacting CO, H 2 and a small amount of C0 2 on a zinc-copper oxide catalyst where the reaction takes place via reaction by displacement with water followed by hydrogenation of C0 2 .
  • the process is normally carried out at a pressure of about 50 to about 100 bar (10 MPa) and in a temperature range of about 220 Q C to about 300 S C.
  • the synthesis of mixed alcohols from synthesis gas It is similar to both FT and methanol synthesis that uses catalysts modified from those methods with the addition of alkali metals to promote the mixed alcoholic reaction, where the molar ratio of H 2 to CO is from about 1: 1 to about 1 , 2: 1.
  • synthesis gas fermentation methods a variety of microorganisms can use synthesis gas as a source of energy and carbon to produce fermentation products such as ethanol, butanol, acetate, formate and butyrate.
  • Such organisms include Acetobacterium woodii, Butyribacterium methylotrophicum, Clostridium carboxidivorans P7, Eubacter ⁇ um limosu, Moorella and Peptostreptococcus productus.
  • certain anaerobic microorganisms can produce ethanol and other useful CO products by fermentation.
  • Patent number 6,136,577 discloses a method and an apparatus for converting synthesis gas to ethanol using Clostridium Ijungdahlii ATCC 55988 and 55989 and N;
  • the US publication N s 20070275447 describes a bacterial species Clostridium carboxidivorans ⁇ clostridium, ATCC BAA-624, "P7") that can synthesize biofuels from synthesis gas; and the US patent.
  • No. 7,704,723 describes a bacterial species of Clostridium (Clostridium ragsdalei, ATCC BAA-622, "P11") that can synthesize biofuels from waste gases.
  • US publication 20140120591 describes a species of acidogenic Clostridium tyrobutyricum (ITRI04001) that can synthesize volatile fatty acids (e.g., formic acid, acetic acid, lactic acid, propanoic acid, butyric acid, and mixtures thereof) from synthesis gas
  • volatile fatty acids e.g., formic acid, acetic acid, lactic acid, propanoic acid, butyric acid, and mixtures thereof
  • the fermentation conditions are usually of atmospheric pressure at 2 bar (200 kPa), and at a temperature range of about 15 S C to about 55 S C, with the selection of specific conditions of the thermostat and pH depending on the fermenting microorganism.
  • Non-limiting embodiments of the present invention are plotted in Figure 1.
  • Figure 1 graphically represents, by means of a block diagram, the Separation and Classification area of the MSW as well as the Cleaning of the bio-waste, a previous step necessary to obtain a bio-residue rich in cellulosic compounds that will become monosaccharides.
  • the mixture of Urban Solid Waste (1) is optionally processed by a manual sorting stage, by manual triage (101) in which large or bulky waste and / or hazardous materials (MV) are removed, a current is obtained (2) rich in recyclable materials (MR) (such as paper and cardboard) and other current (3) that goes to the next stages.
  • manual triage (101) in which large or bulky waste and / or hazardous materials (MV) are removed, a current is obtained (2) rich in recyclable materials (MR) (such as paper and cardboard) and other current (3) that goes to the next stages.
  • MV large or bulky waste and / or hazardous materials
  • MR recyclable materials
  • the stream (3) is fractionated into a first sorting stage (102) (for example, trommel) having a sieve opening of about 60 mm to about 100 mm to form a first through current (5) rich in recyclable material and a first sinking current (4) rich in fermentable organic matter.
  • a first sorting stage (102) for example, trommel
  • the first pass-through current (5) can optionally be subjected to a new step of size classification by means of a trombone (103) to be divided into a second sinking current (6) of small size, and a second through current (7) of big size.
  • the stream (6) is subjected to a new separation stage in a ballistic separator (104), which separates the material according to its density, size and shape, being classified into a stream of fine material (8), a stream of rolling stock (9) and a stream of planar material (10).
  • the stream of fine material (8) is enriched in organic matter, while the stream of rolling stock (9) is enriched in recyclable plastic material and that of planar (10) is enriched in paper and cardboard among other two-dimensional materials.
  • the fine stream (8) joins the first sink current (4) to form the raw bio-waste stream and passes through a magnetic separator (105) and a Foucault separator (106) and the generated current (11) it can be fractionated with a trombone (107) to form a third sunken stream enriched with inert compounds (13) and a third through stream (12) that has at least 40% by weight of organic matter and also comprises a recyclable component It includes plastic.
  • the sinking current rich in inorganic material (13) can be purged from the process by a conditioning step (126) and the generated current (23) is divided by an optical separator (127) for the recovery of glass (v).
  • the third through current (12) is fractionated by density separation, into a densimetric (108) to form a first dense current (15) and a first light current (14).
  • the light stream (14) is fractionated with a trombone (110) to form a fourth sinking stream (16) enriched in bio-waste and a fourth through stream (17) enriched in recyclable material.
  • the fourth through current (17) is divided by optical system (1 13) into a stream rich in organic material (19) comprising plastics, metals, glass, paper and / or cardboard and in a recovered stream enriched in plastic (18) what happens to a system of recovery of recyclable material (1 14).
  • the first dense stream (15) is enriched in inorganic compounds, glass and metal is passed through a Foucault separator (109) to separate the metals from a stream (22) that is taken along with the stream (13) to a stage of conditioning (126).
  • the fourth sinking current (16) enriched in bio-wastes is fractionated using an X-ray classification system (11 1), inert (r) are eliminated, mainly composed of stones, bones or sands and the clean current joins the rich current in organic matter (19) and pass to a mill (112) to reduce its size to an average particle size of less than approximately 25 mm, giving rise to the bio-waste stream (20), a clean bio-waste stream for conversion into monosaccharides.
  • the rolling material stream (9) is subjected to a metal extraction passing through a magnetic separator (1 15) obtaining a stream of metal-free recyclable material (21) passing through a recyclable material recovery system (114), along with the current (18) above.
  • the rejection current (24) of said process can feed, together with the second through current (7), to the current (25) for obtaining CSR, by passing through a manual triage (116).
  • the stream (25) is separated by air classification as described in the present invention (such as a linear air separator) (117) to form a second light stream (26) and a second dense stream (27) in which The light stream is enriched in combustible material compared to the heavy stream.
  • the light stream (26) is processed in a crushing step (118) to further reduce the volume and particle size and form the CSR (35).
  • planar material stream (10) is passed through an optical separator (1 19) to obtain a stream (38) of paper and cardboard (P&C) and a remainder stream (34) enriched in planar combustible material.
  • the stream (10) can be crushed before, after or in parallel of the mixture with the aqueous solution (36).
  • the bio-waste stream (20) is the clean bio-waste stream for conversion into monosaccharides.
  • This clean bio-waste stream (20) comprises Fermentable material and is enriched in fermentable material.
  • the clean milled bio-waste stream is impregnated with a stream of water, acid (aqueous solution) or base (aqueous solution) (36) in an impregnation vessel (120) to form a stream of impregnated bio-waste (28) and is used directly as pretreatment feed (121) where it is pretreated at elevated pressure and temperature, such as by steam contact, followed by a rapid release of pressure to form the pretreated bio-waste (29).
  • the pretreated bio-waste stream (29) is conditioned (122) by mixing with an aqueous medium (39) to form an aqueous suspension of pre-treated bio-waste (30).
  • the aqueous medium (39) is a cooled base, such as aqueous ammonia.
  • the aqueous medium (39) is a cooled aqueous stream or a cooled acid, such as sulfuric acid.
  • the pretreated bio-residue suspension (30) is contacted with an enzyme source comprising at least one cellulase in an enzymatic hydrolysis vessel (123) to form an enzyme hydrolyzate suspension (31) comprising monosaccharide sugars.
  • a stream (37) comprising non-fermentable material is extracted from the contents of the enzymatic hydrolysis vessel (123) during or after hydrolysis by means of a non-fermentable material removal apparatus (125) representative of one or more unit operations of separation.
  • the non-fermentable material removal apparatus (125) may be integrated or external to the enzymatic hydrolysis vessel (123) and more than one non-fermentable material removal apparatus may be used.
  • a foam eliminator can be used to remove the non-fermentable material disposed as a floating layer on the contents of the enzymatic hydrolysis vessel, (ii) a sieve, sieve or filter located in a recirculation circuit or at the outlet to remove the non-fermentable material in suspension from the content of the enzyme hydrolysis vessel and / or (iii) a waste gutter or trap to remove the non-fermentable material disposed as a bottom layer in the enzyme hydrolysis vessel for disposal of the non-fermentable material.
  • the enzyme hydrolyzate suspension (31) can be combined with a yeast source in a fermentation vessel (124) to form a fermentation mixture (33) comprising ethanol.
  • the hydrolyzate (32) can be combined with a yeast source in a fermentation vessel (124) to form a fermentative mixture (33) comprising ethanol.

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  • Engineering & Computer Science (AREA)
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  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
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  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • Genetics & Genomics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

La présente invention concerne de manière générale des systèmes et procédés pour former des monosaccharides à partir d'un mélange de résidus solides. On utilise un procédé intégré pour classifier un mélange de résidus solides afin de générer divers courants riches en matières recyclables comprenant un ou plusieurs courants de plastique et un courant de biorésidu enrichi en composés cellulosiques et qui comprend des composants non fermentescibles. Le courant de biorésidu est prétraité dans des conditions de pression et température élevé et ensuite il est mis encontact avec une source d'enzymes qui comprend de la cellulase, une partie déterminée de la matière non fermentescible présente dans le mélange de résidus solides étant retirée du processus par des procédés de classification par voie humide pendant ou après hydrolyse enzymatique.
PCT/ES2018/070213 2017-03-28 2018-03-21 Procédé pour préparer des sucres monosaccharides à partir d'un résidu solide urbain Ceased WO2018178443A1 (fr)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI821503B (zh) * 2020-01-15 2023-11-11 隆順綠能科技股份有限公司 固體回收燃料的原料分選系統及其方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2324855T3 (es) * 2000-08-09 2009-08-18 Alliance For Sustainable Energy, Llc Hidrolisis con acido diluido/sal metalica de materiales lignocelulosicos.
GB2480318A (en) * 2010-05-14 2011-11-16 Advanced Recycling Tech A method of processing waste to produce a fuel product
US20120190102A1 (en) * 2010-01-25 2012-07-26 Organic Energy Corporation Systems and methods for processing mixed solid waste
US20140315258A1 (en) * 2013-03-14 2014-10-23 Abengoa Bioenergy New Technologies, Llc Methods for converting cellulosic waste to bioproducts
ES2565553A1 (es) * 2014-09-30 2016-04-05 Abengoa Bioenergia Nuevas Tecnologias, S.A. Sistemas y métodos para formar biorresiduo celulósico a partir de biorresiduo crudo
ES2565555A1 (es) * 2014-09-30 2016-04-05 Abengoa Bioenergía Nuevas Tecnologías, S.A. Sistemas y métodos para formar biorresiduo celulósico a partir de residuo sólido mezclado
ES2570278A2 (es) * 2013-03-14 2016-05-17 Abengoa Bioenergy New Tech Llc Procedimientos para convertir residuos celulosicos en bioproductos

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2324855T3 (es) * 2000-08-09 2009-08-18 Alliance For Sustainable Energy, Llc Hidrolisis con acido diluido/sal metalica de materiales lignocelulosicos.
US20120190102A1 (en) * 2010-01-25 2012-07-26 Organic Energy Corporation Systems and methods for processing mixed solid waste
GB2480318A (en) * 2010-05-14 2011-11-16 Advanced Recycling Tech A method of processing waste to produce a fuel product
US20140315258A1 (en) * 2013-03-14 2014-10-23 Abengoa Bioenergy New Technologies, Llc Methods for converting cellulosic waste to bioproducts
ES2570278A2 (es) * 2013-03-14 2016-05-17 Abengoa Bioenergy New Tech Llc Procedimientos para convertir residuos celulosicos en bioproductos
ES2565553A1 (es) * 2014-09-30 2016-04-05 Abengoa Bioenergia Nuevas Tecnologias, S.A. Sistemas y métodos para formar biorresiduo celulósico a partir de biorresiduo crudo
ES2565555A1 (es) * 2014-09-30 2016-04-05 Abengoa Bioenergía Nuevas Tecnologías, S.A. Sistemas y métodos para formar biorresiduo celulósico a partir de residuo sólido mezclado

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI821503B (zh) * 2020-01-15 2023-11-11 隆順綠能科技股份有限公司 固體回收燃料的原料分選系統及其方法

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