[go: up one dir, main page]

WO2018021110A1 - Agent d'amélioration de l'effet antimousse et composition d'agent de nettoyage moussante comprenant ledit agent d'amélioration de l'effet antimousse - Google Patents

Agent d'amélioration de l'effet antimousse et composition d'agent de nettoyage moussante comprenant ledit agent d'amélioration de l'effet antimousse Download PDF

Info

Publication number
WO2018021110A1
WO2018021110A1 PCT/JP2017/026084 JP2017026084W WO2018021110A1 WO 2018021110 A1 WO2018021110 A1 WO 2018021110A1 JP 2017026084 W JP2017026084 W JP 2017026084W WO 2018021110 A1 WO2018021110 A1 WO 2018021110A1
Authority
WO
WIPO (PCT)
Prior art keywords
detergent composition
mass
foam
sprayed
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2017/026084
Other languages
English (en)
Japanese (ja)
Inventor
大島　務
菅本　和志
中山　幸治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dainihon Jochugiku Co Ltd
Original Assignee
Dainihon Jochugiku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dainihon Jochugiku Co Ltd filed Critical Dainihon Jochugiku Co Ltd
Priority to JP2018529805A priority Critical patent/JP6960403B2/ja
Priority to CN201780044338.9A priority patent/CN109477039B/zh
Publication of WO2018021110A1 publication Critical patent/WO2018021110A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols

Definitions

  • the present invention relates to an antifoaming effect enhancer blended in a detergent composition used in the form of an aerosol when cleaning screen doors, air conditioner filters, and the like, and an effervescent detergent composition containing the same.
  • the foamable detergent composition improves the cleaning efficiency of the sprayed object by defoaming the foam after the sprayed foam adheres to the sprayed object and exhibits an excellent cleaning effect.
  • the adhering foam is further defoamed to further enhance the cleaning power. Furthermore, in the cleaning of screen doors and filters, considering that the wiping property affects the cleaning power and workability, it can be said that rapid defoaming further enhances the cleaning effect.
  • Patent Document 1 includes (A) a surfactant, (B) an oil agent, (C) ethanol and / or isopropyl alcohol (IPA), (D) A foaming detergent composition in which an aerosol container is filled with a glycol ether solvent having a solubility in water at 20 ° C. of 7% by mass or less, (E) a cleaning liquid containing water, and (F) a propellant.
  • a foamable detergent composition that improves the cleaning efficiency of a sprayed object by causing the foamed material sprayed from an aerosol container to adhere to the sprayed object and then defoaming within 30 seconds. ing.
  • Patent Document 1 most of the sprayed foam having a sufficient foaming force adheres and exhibits an excellent cleaning effect without penetrating through a screen door or a filter. By defoaming, the cleaning efficiency of the sprayed object can be increased.
  • Patent Document 1 that defoams within 30 seconds after adhering a foam to an object to be sprayed does not necessarily have a sufficient defoaming effect, and it disappears more quickly.
  • an effervescent detergent composition that has improved wiping properties and cleaning efficiency by foaming.
  • the present invention provides an antifoaming effect enhancer capable of improving the defoaming effect of a foam attached to an object to be sprayed, and an effervescent detergent composition containing the same. Objective.
  • the present invention provides at least one selected from organic acids and / or salts of organic acids, wherein (A) a surfactant and (B) a C 10 -C 18 paraffinic hydrocarbon (C) ethanol and / or isopropyl alcohol, (D) a glycol ether solvent having a solubility in water at 20 ° C. of 7% by mass or less, and (E) a cleaning liquid containing water, and (F) a propellant.
  • the foamed foam composition of the foamable detergent composition which is blended in the foamable detergent composition filled in an aerosol container and sprayed from the aerosol container, is attached to the object to be sprayed, and then the foam is defoamed.
  • An antifoaming effect enhancer characterized by shortening the time within a predetermined time.
  • the present invention is characterized in that in the antifoaming effect enhancer having the above-described configuration, the defoaming time is shortened within 20 seconds.
  • the present invention is also characterized in that the organic acid is one or more selected from citric acid, malic acid, and succinic acid in the antifoaming effect enhancer having the above-described configuration.
  • the present invention is characterized in that in the defoaming effect enhancer having the above-described configuration, the blending amount of the organic acid and / or salt of the organic acid with respect to the cleaning liquid is 0.5% by mass or more and 5% by mass or less.
  • the present invention also includes (A) a surfactant, (B) a C 10 -C 18 paraffin hydrocarbon, (C) ethanol and / or isopropyl alcohol, and (D) water solubility at 20 ° C. of 7% by mass or less.
  • a foaming detergent composition comprising an aerosol container filled with a cleaning liquid containing a glycol ether solvent and (E) water, and (F) a propellant, and (G) an antifoaming effect.
  • the foam of the foamable detergent composition sprayed from the aerosol container is attached to the spray object. It is the foaming detergent composition which improved the washing
  • the present invention is characterized in that, in the foamable detergent composition having the above-described configuration, the antifoaming effect enhancer is at least one selected from a salt of citric acid, malic acid, and succinic acid.
  • the present invention is characterized in that, in the foamable detergent composition having the above-described configuration, a blending amount of the organic acid and / or salt of the organic acid with respect to the cleaning liquid is 0.5% by mass or more and 5% by mass or less.
  • the foamability which adhered to the spraying object by using 1 or more types of the salt of an organic acid and / or an organic acid as an antifoaming effect enhancer of a foamable detergent composition can be improved, and after the sprayed foam adheres to the spray object and exhibits an excellent cleaning effect, the defoaming time of the foam is predetermined. By shortening within the time, the cleaning efficiency of the spray object can be increased. Therefore, it is possible to easily and inexpensively produce a foaming detergent composition having both high cleaning performance and cleaning efficiency.
  • the foam adhering to the spray target object by shortening the defoaming time of a foam within 20 second.
  • the foam can be quickly defoamed to more effectively increase the cleaning efficiency of the sprayed object.
  • the antifoaming effect enhancer of the said 1st or 2nd structure by using 1 or more types chosen from the salt of a citric acid, malic acid, and a succinic acid.
  • the defoaming effect of the foam attached to the spray object can be remarkably improved, and a foaming detergent composition excellent in safety can be produced easily and at low cost.
  • cleaning liquid is 0.5.
  • the content of the organic acid and / or the salt of the organic acid is necessary and sufficient to sufficiently improve the defoaming effect of the foam attached to the spray object.
  • the foamable detergent composition having both the adherence of the sprayed foam to the sprayed object and the rapid defoaming property of the attached foam can be produced.
  • a foaming detergent composition obtained by filling an aerosol container with a cleaning liquid containing a glycol ether solvent having a solubility in water of 7% by mass or less, and (E) water, and (F) a propellant, (G) As a defoaming effect enhancer, one or more selected from organic acids and / or salts of organic acids are blended in the cleaning liquid, so that most of the foamed foamed detergent composition is sprayed.
  • a foaming detergent composition that can improve the cleaning efficiency of the sprayed object by quickly defoaming the foam within 20 seconds after adhering to the surface and exhibiting an excellent cleaning effect. It becomes a thing.
  • the foamable detergent composition of the said 5th structure 1 or more types chosen from the salt of a citric acid, malic acid, and a succinic acid are mix
  • the blending amount of the organic acid and / or the salt of the organic acid with respect to the cleaning liquid is 0.5% by mass or more.
  • the foamable detergent composition of the present invention comprises (A) a surfactant, (B) a C 10 -C 18 paraffinic hydrocarbon, (C) ethanol and / or isopropyl alcohol (IPA), (D) at 20 ° C.
  • An aerosol container is filled with a glycol ether solvent having a solubility in water of 7% by mass or less, (G) an organic acid and / or a salt of an organic acid, and (E) a cleaning solution containing water, and (F) a propellant. It is a thing.
  • Nonionic surfactants include, for example, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, palm Examples include oil fatty acid diethanolamide, polyoxyethylene polyoxypropylene alkyl ether, fatty acid alkanolamide, and alkylamine oxide.
  • anionic surfactant examples include fatty acid soap, alkylbenzene sulfonate, linear alkylbenzene sulfonate, alkyl sulfate, ⁇ -olefin sulfonate, alkyl phosphate ester salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene Examples thereof include ethylene alkyl phenyl ether sulfate and polyoxyethylene alkyl ether phosphate.
  • amphoteric surfactants examples include alkylcarboxybetaine type, alkylaminocarboxylic acid type, and alkylimidazoline type. From the viewpoint of foamability and detergency, alkylamine oxide surfactants and alkylcarboxybetaine type amphoteric surfactants are preferred, and alkylamine oxide surfactants are more preferred.
  • cationic fungicides examples include gemini-type quaternary ammonium salts such as 1,4-bis (3,3 ′-(1-decylpyridinium) methyloxy) butane dibromide, benzalkonium chloride, didecyldimethyl chloride Ammonium, benzethonium chloride, polyhexamethylene biguanide salt, polyhexamethylene guanidine salt, polylysine and the like can be mentioned. These surfactants can be used in combination of one or more, and are preferably blended in the cleaning liquid in an amount of 0.5 to 5.0% by mass. In this range, the adhesion to the network surface is excellent. .
  • the C 10 -C 18 paraffinic hydrocarbon of component (B) includes IP solvent 1620, IP solvent 2028, IP solvent 2835 (manufactured by Idemitsu Kosan Co., Ltd.), Isopar A, Isopar C, Isopar D, Isopar E, Isopar Paraffin hydrocarbons such as G, Isopar H, Isopar K, Isopar L, Isopar M (above, manufactured by TonenGeneral Sekiyu KK), Neothiozole and the like can be mentioned, and these can be used alone or in combination of two or more. Of these, isoparaffinic hydrocarbons are preferably used.
  • the paraffinic hydrocarbon is preferably blended in the cleaning liquid in an amount of 0.5 to 3.0% by mass. In this range, the antifoaming property and the initial foaming property are also excellent.
  • Component (C) ethanol and / or isopropyl alcohol (IPA), can be used alone or in combination, and is preferably blended in the cleaning solution in an amount of 2.0 to 20% by mass. In this range, there are advantages such as sufficient detergency and foam performance and just good foam scattering.
  • IPA isopropyl alcohol
  • component (D) is a glycol ether solvent having a solubility in water at 20 ° C. of 7% by mass or less.
  • component (D) is a glycol ether solvent having a solubility in water at 20 ° C. of 7% by mass or less.
  • a glycol ether solvent having a solubility in water at 20 ° C. of 7% by mass or less a compound of the general formula I (In Formula I, R 1 represents a C 3 -C 6 alkyl group or an optionally substituted phenyl group, R 2 represents a C 2 -C 3 alkyl group, and m is an integer of 1 to 3). .) Are preferably used.
  • Examples of the compound of general formula I include, but are not limited to, phenoxyethanol, propylene glycol monobutyl ether, dipropylene glycol monobutyl ether, tripropylene glycol monobutyl ether and the like. Of these, phenoxyethanol is most preferred from the standpoints of solubility and ease of formulation.
  • the glycol ether solvent having a solubility in water at 20 ° C. of 7% by mass or less is preferably blended in the cleaning liquid in an amount of 0.1 to 5.0% by mass. If the amount is less than 0.1% by mass, a problem may occur in the defoaming property, whereas if it exceeds 5.0% by mass, the initial foaming may be affected.
  • the cleaning liquid of the foamable detergent composition of the present invention contains (E) water and component (G) organic acid and / or salt of organic acid.
  • the organic acid and / or salt of the organic acid blended in the foamable sterilizing composition of the present invention is obtained by attaching a foam of the foamable sterilizing composition sprayed from an aerosol container to an object to be sprayed. Used as a defoaming effect enhancer for shortening the defoaming time of the body.
  • a salt of an organic acid is added to a detergent composition as a pH adjusting agent or a chelating agent, but as a defoaming effect enhancer that shortens the defoaming time of the foam of the foamable sterilizing composition. It is a knowledge discovered for the first time by the present inventors to act.
  • the blending amount of the organic acid and / or salt of the organic acid in the foamable detergent composition of the present invention is not particularly limited, but if the blending amount is too small, the defoaming effect may not be sufficiently enhanced. On the other hand, even if there are too many compounding quantities, the improvement effect is not seen.
  • the blending amount of the organic acid and / or salt of the organic acid is preferably blended in the range of 0.1% by mass or more and 10% by mass or less with respect to the whole foaming detergent composition, and as shown in Examples described later, It is more preferable to add the salt of the organic acid in the range of 0.5% by mass or more and 5% by mass or less with respect to the whole foaming detergent composition.
  • organic acid used as the defoaming effect enhancer in the present invention include citric acid, malic acid, succinic acid, lactic acid, ethylenediaminetetraacetic acid (EDTA) and the like.
  • organic acid salt include sodium salts and potassium salts of the above organic acids. These compounds may be used alone or in combination of two or more.
  • a salt of an organic acid that makes the cleaning solution weakly alkaline.
  • salts of organic acids they are particularly widely used as chemical products, are easily available, have high safety, and exhibit a high defoaming effect when combined with a glycol ether solvent.
  • Acid, malic acid, and succinic acid salts are more preferred.
  • other types of antifoaming agents such as fatty acid ester antifoaming agents, higher alcohol antifoaming agents, and polyether antifoaming agents may be added as long as the effects of the present invention are not hindered. .
  • the cleaning liquid of the foamable detergent composition of the present invention in which the above components are blended is filled in an aerosol container together with (F) a propellant.
  • the propellant should be mainly LPG with a pressure of 0.23 to 0.50 MPa at 20 ° C.
  • DME dimethyl ether
  • compressed gas nitrogen, carbon dioxide, etc.
  • the mixing ratio of the cleaning liquid and the propellant in the foamable detergent composition is appropriately 50 to 85% by volume / 15 to 50% by volume.
  • the spray button used in the present invention may be any button that forms bubbles, but the distance from the stem to the tip of the nozzle is preferably 5 to 50 mm. If it exceeds 50 mm, there is a risk of inconvenience such as an increase in the number of afterdraws in which bubbles accumulate in the vicinity of the nozzle nozzle.
  • an inorganic antibacterial agent an organic antibacterial agent, an algaeproof agent, a rust inhibitor, a chelating agent, a pH adjuster, a rust inhibitor (as required) Sodium benzoate, etc.), disinfectant, deodorant, insect repellent, fragrance and the like may be appropriately blended within a range not impairing the effects of the present invention.
  • an organic acid is added as an antifoaming effect enhancer, the cleaning liquid becomes acidic. Therefore, the pH of the cleaning liquid is adjusted to about 6.0 to 8.0 by adding a pH adjuster.
  • a highly safe foaming detergent composition can be obtained.
  • the foaming detergent composition of the present invention By applying or spraying the foaming detergent composition of the present invention thus obtained to a screen door or a filter, most of the sprayed foam adheres without penetrating the screen door or the filter, and has an excellent cleaning effect.
  • the cleaning efficiency of the sprayed object can be increased by quickly defoaming the foam after it is exhibited.
  • the foamable detergent composition of the present invention comprises (A) a surfactant, (B) a C 10 -C 18 paraffinic hydrocarbon, (C) ethanol and / or isopropyl alcohol, (D) water at 20 ° C. (E) A cleaning liquid in which a glycol ether solvent having a solubility in a solvent of 7% by mass or less, (G) an organic acid and / or a salt of an organic acid is mixed in (E) water, and (F) an aerosol container is filled together with a propellant. It is a very simple composition. Therefore, the manufacturing is simple and the safety is extremely high.
  • test solution (A) 2.0% by mass of lauryldimethylamine oxide (trade name: Kadenax DM12D-W, manufactured by Lion Specialty Chemicals) as a surfactant, (B) IP as a C 10 -C 18 paraffinic hydrocarbon Solvent 2028 (C 10 -C 12 isoparaffin, manufactured by Idemitsu Kosan Co., Ltd.) 1.0 mass%, (C) 95% ethanol (manufactured by Wako Pure Chemical Industries, Ltd.) 10 mass%, (D) Solubility in water at 20 ° C.
  • lauryldimethylamine oxide trade name: Kadenax DM12D-W, manufactured by Lion Specialty Chemicals
  • IP IP as a C 10 -C 18 paraffinic hydrocarbon Solvent 2028 (C 10 -C 12 isoparaffin, manufactured by Idemitsu Kosan Co., Ltd.) 1.0 mass%
  • C 95% ethanol (manufactured by Wako Pure Chemical Industries, Ltd.)
  • the pressure of LPG at this time was 0.29 MPa (20 ° C.). Further, a wide-angle mechanical blur button (hole diameter: 0.5 mm, manufactured by Mitani Valve Co., Ltd.) was used as the injection button.
  • the cleaning liquid was put in an aerosol container together with LPG and DME as propellants to prepare foaming detergent compositions (Inventions 1 to 8) having the compositions shown in Table 1.
  • each component obtained by adding trisodium phosphate to the above components was blended at a blending ratio (% by mass) shown in Table 2, and purified water was added to obtain 100% by mass to obtain a cleaning liquid.
  • the cleaning liquid was put in an aerosol container together with LPG and DME as propellants to prepare foaming detergent compositions (Comparative Examples 1 to 5) having the compositions shown in Table 2.
  • the following detergency tests and foam performance tests were conducted using the foaming detergent compositions of the present inventions 1 to 8 and Comparative Examples 1 to 5. The results are shown in Table 3.
  • the foaming detergent composition of the present invention is used for screen doors and air conditioner filters, and is also used for cleaning window glass, ventilation fans, toilets, bathtubs, automobiles, etc. It can be suitably used in the field of agents, insect repellents and the like.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un agent améliorant l'effet antimousse qui est une ou plusieurs substances choisies parmi des acides organiques et/ou des sels d'acides organiques, et qui est mélangé dans une composition d'agent de nettoyage moussante obtenue par remplissage d'un récipient aérosol avec (A) un tensioactif, (B) un hydrocarbure de paraffine en C10-C18, (C) de l'éthanol et/ou de l'alcool isopropylique, (D) un solvant d'éther de glycol présentant une solubilité de 7 % en masse ou moins dans l'eau à 20 °C, (E) un liquide de nettoyage comprenant de l'eau et (F) un propulseur. Cet agent d'amélioration de l'effet de démoussage raccourcit le temps de déformation d'un corps de type mousse de la composition d'agent de nettoyage moussante pulvérisée à partir du récipient aérosol à une période prédéterminée ou moins, après que le corps de type mousse a adhéré à un objet de pulvérisation.
PCT/JP2017/026084 2016-07-26 2017-07-19 Agent d'amélioration de l'effet antimousse et composition d'agent de nettoyage moussante comprenant ledit agent d'amélioration de l'effet antimousse Ceased WO2018021110A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2018529805A JP6960403B2 (ja) 2016-07-26 2017-07-19 消泡効果増強剤およびそれを含有する発泡性洗剤組成物
CN201780044338.9A CN109477039B (zh) 2016-07-26 2017-07-19 消泡效果增强剂和含有它的发泡性洗涤剂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016146246 2016-07-26
JP2016-146246 2016-07-26

Publications (1)

Publication Number Publication Date
WO2018021110A1 true WO2018021110A1 (fr) 2018-02-01

Family

ID=61016217

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2017/026084 Ceased WO2018021110A1 (fr) 2016-07-26 2017-07-19 Agent d'amélioration de l'effet antimousse et composition d'agent de nettoyage moussante comprenant ledit agent d'amélioration de l'effet antimousse

Country Status (3)

Country Link
JP (1) JP6960403B2 (fr)
CN (1) CN109477039B (fr)
WO (1) WO2018021110A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020189919A (ja) * 2019-05-22 2020-11-26 大日本除蟲菊株式会社 発泡性洗剤組成物
JP2022014891A (ja) * 2020-07-07 2022-01-20 大日本除蟲菊株式会社 発泡性薬効付与組成物、及びそれを用いた薬効付与方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110314418A (zh) * 2019-08-05 2019-10-11 陶从丰 消泡组合物
CN110923474A (zh) * 2019-12-19 2020-03-27 新邵辰州锑业有限责任公司 用于硫化锑矿矿浆电解工艺的泡沫抑制剂

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1450580A (en) * 1973-01-22 1976-09-22 Dow Corning Ltd Detergents containing foam control substances
JP2005325304A (ja) * 2004-05-17 2005-11-24 Kao Corp 表面改質処理方法
JP2008106156A (ja) * 2006-10-25 2008-05-08 Dainippon Jochugiku Co Ltd アフタードローを抑えたエアゾール用発泡性洗剤組成物
JP2009013321A (ja) * 2007-07-06 2009-01-22 Dainippon Jochugiku Co Ltd アフタードローを抑えたエアゾール用発泡性洗剤組成物
JP2013181153A (ja) * 2012-03-05 2013-09-12 Dainippon Jochugiku Co Ltd 発泡性洗剤組成物
JP2014040454A (ja) * 2009-09-28 2014-03-06 Ecolab Inc スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2715175C (fr) * 2008-03-28 2017-11-21 Ecolab Inc. Acides peroxycarboxyliques sulfures, leur preparation et leurs procedes d'utilisation en tant qu'agents de blanchiment et antimicrobiens
CN102407033B (zh) * 2011-06-29 2013-09-25 南京四新科技应用研究所有限公司 一种颗粒消泡剂的制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1450580A (en) * 1973-01-22 1976-09-22 Dow Corning Ltd Detergents containing foam control substances
JP2005325304A (ja) * 2004-05-17 2005-11-24 Kao Corp 表面改質処理方法
JP2008106156A (ja) * 2006-10-25 2008-05-08 Dainippon Jochugiku Co Ltd アフタードローを抑えたエアゾール用発泡性洗剤組成物
JP2009013321A (ja) * 2007-07-06 2009-01-22 Dainippon Jochugiku Co Ltd アフタードローを抑えたエアゾール用発泡性洗剤組成物
JP2014040454A (ja) * 2009-09-28 2014-03-06 Ecolab Inc スルホペルオキシカルボン酸、それらの製造方法並びに漂白剤及び殺菌剤としての使用方法
JP2013181153A (ja) * 2012-03-05 2013-09-12 Dainippon Jochugiku Co Ltd 発泡性洗剤組成物

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020189919A (ja) * 2019-05-22 2020-11-26 大日本除蟲菊株式会社 発泡性洗剤組成物
JP7280744B2 (ja) 2019-05-22 2023-05-24 大日本除蟲菊株式会社 発泡性洗剤組成物
JP2023106471A (ja) * 2019-05-22 2023-08-01 大日本除蟲菊株式会社 発泡性洗剤組成物
JP7538560B2 (ja) 2019-05-22 2024-08-22 大日本除蟲菊株式会社 発泡性洗剤組成物
JP2022014891A (ja) * 2020-07-07 2022-01-20 大日本除蟲菊株式会社 発泡性薬効付与組成物、及びそれを用いた薬効付与方法
JP7695831B2 (ja) 2020-07-07 2025-06-19 大日本除蟲菊株式会社 発泡性薬効付与組成物、及びそれを用いた薬効付与方法

Also Published As

Publication number Publication date
JPWO2018021110A1 (ja) 2019-05-09
CN109477039B (zh) 2021-10-08
CN109477039A (zh) 2019-03-15
JP6960403B2 (ja) 2021-11-05

Similar Documents

Publication Publication Date Title
CN102858932B (zh) 手洗用餐具清洁剂组合物
JP5951437B2 (ja) 発泡性洗剤組成物
JP5977086B2 (ja) 発泡洗浄剤組成物及び洗浄方法
JP6029231B2 (ja) 発泡性洗剤組成物
JP5764654B2 (ja) 液体洗浄剤
JP6960403B2 (ja) 消泡効果増強剤およびそれを含有する発泡性洗剤組成物
JP2019006998A (ja) 洗浄製品
JP5367243B2 (ja) 家庭用業務用兼用濃縮中性洗浄剤組成物
JP5592782B2 (ja) 食品加工設備及び／又は調理設備用洗浄剤組成物
JP7538560B2 (ja) 発泡性洗剤組成物
JP5924982B2 (ja) 発泡性洗剤組成物
JP3255637B1 (ja) 液体洗浄剤組成物
JP2007077290A (ja) Ｃｉｐ用脱臭剤組成物
JP4896453B2 (ja) 除菌洗浄剤
JP5334384B2 (ja) アフタードローを抑えたエアゾール用発泡性洗剤組成物
CN116323884B (zh) 硬表面清洁组合物
EP4594456A1 (fr) Compositions de nettoyage de surfaces dures contenant des rhamnolipides et un co-tensioactif d'esters alkyliques sulfonés
JPS62286000A (ja) 起泡性液体洗浄剤組成物
JP5231731B2 (ja) アフタードローを抑えたエアゾール用発泡性洗剤組成物
JP2002348600A (ja) 水性洗浄剤組成物
HK40000651A (en) Defoaming effect enhancing agent and foaming detergent composition containing it
HK40000651B (zh) 消泡效果增强剂和含有它的发泡性洗涤剂组合物
JP3980447B2 (ja) 硬質表面用洗浄剤組成物
JP2002194388A (ja) 液体洗浄剤組成物
JP5208407B2 (ja) 硬表面用洗浄剤組成物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17834118

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2018529805

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17834118

Country of ref document: EP

Kind code of ref document: A1