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WO2018010151A1 - Preparation method for field effect transistor and field effect transistor - Google Patents

Preparation method for field effect transistor and field effect transistor Download PDF

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Publication number
WO2018010151A1
WO2018010151A1 PCT/CN2016/090084 CN2016090084W WO2018010151A1 WO 2018010151 A1 WO2018010151 A1 WO 2018010151A1 CN 2016090084 W CN2016090084 W CN 2016090084W WO 2018010151 A1 WO2018010151 A1 WO 2018010151A1
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Prior art keywords
dimensional material
channel
drain
source
field effect
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PCT/CN2016/090084
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French (fr)
Chinese (zh)
Inventor
赵冲
唐样洋
张臣雄
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Huawei Technologies Co Ltd
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Huawei Technologies Co Ltd
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Priority to CN201680087701.0A priority Critical patent/CN109478565A/en
Priority to PCT/CN2016/090084 priority patent/WO2018010151A1/en
Publication of WO2018010151A1 publication Critical patent/WO2018010151A1/en
Anticipated expiration legal-status Critical
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/40FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels
    • H10D30/47FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels having 2D charge carrier gas channels, e.g. nanoribbon FETs or high electron mobility transistors [HEMT]
    • H10D30/481FETs having two-dimensional material channels, e.g. transition metal dichalcogenide [TMD] FETs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof

Definitions

  • the invention relates to the field of field effect transistor technology development, in particular to a method for fabricating a field effect transistor and a field effect transistor.
  • Field effect transistors are voltage controlled devices that have been widely used in the microelectronics industry.
  • the field effect transistor includes a gate, a source, a drain, and a channel between the source and the drain. With the continuous development of the microelectronics industry, the size of the field effect transistor is getting smaller and smaller, and the size of the channel has been Entered the submicron and nanoscale range.
  • two-dimensional materials are currently used to fabricate the channel of a field effect transistor, and a channel made of a two-dimensional material can avoid short channel effects.
  • the two-dimensional material commonly used is graphene.
  • the flow of making a field effect transistor using graphene is as follows: First, graphene is grown on a metal substrate using a gas containing carbon, as shown in FIG. 1, and then the metal substrate is dissolved. And transferring the remaining graphene A onto the non-metal substrate 1, as shown in FIG.
  • the embodiment of the invention provides a method for fabricating a field effect transistor And field effect transistors.
  • the technical solution is as follows:
  • a method of fabricating a field effect transistor comprising:
  • a two-dimensional material on the two-dimensional material growth template using a gas, the two-dimensional material as a channel, the channel being electrically connected to the source and the drain, respectively, the gas including a composition An element of a two-dimensional material, the source and the drain for catalyzing the gas to decompose elements of the two-dimensional material during growth of the two-dimensional material, such that elements of the two-dimensional material Growing the two-dimensional material on the two-dimensional material growth template;
  • a gate insulating layer and a gate are formed on the channel.
  • the source and the drain are formed on the non-metal substrate first, and the two-dimensional material growth template is provided on the non-metal substrate, the atomic arrangement of the two-dimensional material growth template and the atom of the two-dimensional material
  • the arrangement structure is the same or similar.
  • the source and drain metals catalyze the gas to decompose the elements of the two-dimensional material, so that the elements of the two-dimensional material grow with the two-dimensional material growth template as a substrate.
  • a two-dimensional material is formed as a channel.
  • This method greatly reduces the defects of the grown two-dimensional material, so the conductivity of the two-dimensional material is better, so that it can be directly formed as a channel in the process of fabricating the field effect transistor.
  • the two-dimensional material eliminates the need to first grow a two-dimensional material on a metal substrate and then transfer the two-dimensional material onto a non-metallic substrate, avoiding the two-dimensional material during the transfer process and during the process of dissolving the metal substrate.
  • the problem of causing defects in two-dimensional materials improves the performance of field effect transistors using two-dimensional materials as channels.
  • the manufacturing method further includes:
  • first transition layer on the source surface and a second transition layer on the drain surface using the gas while growing the two-dimensional material, the first transition layer being respectively separated from the source by a chemical bond
  • the pole is electrically connected to the channel
  • the second transition layer is electrically connected to the drain and the channel by a chemical bond, respectively.
  • the source is electrically connected to the two-dimensional material as the channel through the first transition layer, and the first transition layer passes between the source and the two-dimensional material.
  • the chemical bonds are connected together such that the contact resistance between the source and the channel becomes small; since the drain is electrically connected to the two-dimensional material as a channel through the second transition layer, and the second transition layer and the drain and the two-dimensional
  • the materials are connected together by chemical bonds, so that the contact resistance between the drain and the channel becomes small, and the performance of the field effect transistor is further improved.
  • the second aspect of the first aspect In combination with the first aspect or the first possible implementation of the first aspect, the second aspect of the first aspect, the forming a source, a drain, and a two-dimensional material growth template on a non-metal substrate, including:
  • the two-dimensional material growth template Forming the two-dimensional material growth template, the first recessed region and the second recessed region on the non-metal substrate, the two-dimensional material growth template being located between the first recessed region and the second recessed region ;
  • the source is formed in the first recess region, and the drain is formed in the second recess region.
  • the two-dimensional material growth template is disposed in the first recessed region and the second recessed region by forming the first recessed region and the second recessed region on the non-metal substrate And a source is disposed in the first recessed region, and a drain is disposed in the second recessed region to expose the upper surface of the source and the upper surface of the drain.
  • the source When a gas is used to form a two-dimensional material, the source The upper surface and the metal on the upper surface of the drain catalyze the growth of the two-dimensional material, which facilitates the growth of the two-dimensional material on the two-dimensional material growth template to form a channel; meanwhile, the metal on the upper surface of the source Reacting with the gas to form a first transition layer, and the first transition layer is connected to the source and the channel by a chemical bond, the metal on the upper surface of the drain reacts with the gas to form a second transition layer, and the second transition layer and the drain and the trench The channels are connected by chemical bonds.
  • a source, a drain, and a two-dimensional material on a non-metal substrate Templates including:
  • the source and the drain are formed on the first substrate, and a portion of the first substrate between the source and the drain is used as the two-dimensional material growth template.
  • the two-dimensional material is graphene, transition metal Sulfide or black phosphorus.
  • the transition metal disulfide comprises molybdenum disulfide or tungsten disulfide.
  • the two-dimensional material growth template is nitrided boron.
  • the atomic arrangement of the two-dimensional material is the same or similar.
  • a seventh possible implementation due to the atomic arrangement of the two-dimensional material growth template
  • the atomic arrangement of the dimensional material is the same or similar, so that the elements of the two-dimensional material in the gas are grown by using a two-dimensional material growth template as a substrate, and finally a two-dimensional material is formed as a channel.
  • the defects of the material are greatly reduced, so the conductivity of the two-dimensional material is better, and the performance of the field effect transistor using the two-dimensional material as a channel is improved.
  • the atomic arrangement of the two-dimensional material is a hexagonal structure or a hexagonal structure.
  • the material of the channel is graphene
  • the channel is a single layer of graphene or a multilayer of graphene.
  • the carrier has a faster transmission speed in the single-layer graphene, and the mobility is larger, and the work of the field effect transistor The lower the power consumption; if the channel is a multilayer graphene, the number of carriers will be more and the conductivity will be better.
  • a field effect transistor comprising:
  • a non-metal substrate a source, a drain, a two-dimensional material growth template, a channel, a gate insulating layer, and a gate;
  • the source, the drain, and the two-dimensional material growth template are located on the non-metal substrate, and the two-dimensional material growth template is located between the source and the drain;
  • the channel is located on the two-dimensional material growth template, the material of the channel is a two-dimensional material, and the channel is electrically connected to the source and the drain, respectively;
  • the gate insulating layer is over the channel, and the gate is over the gate insulating layer.
  • the source and the drain are first formed on the non-metal substrate, and the two-dimensional material growth template is disposed on the non-metal substrate, the atomic arrangement of the two-dimensional material growth template and the atom of the two-dimensional material
  • the arrangement structure is the same or similar.
  • the source and drain metals catalyze the gas to decompose the elements of the two-dimensional material, so that the elements of the two-dimensional material grow with the two-dimensional material growth template as a substrate.
  • a two-dimensional material is formed as a channel.
  • This method greatly reduces the defects of the grown two-dimensional material, so the conductivity of the two-dimensional material is better, so that it can be directly formed as a channel in the process of fabricating the field effect transistor.
  • the two-dimensional material eliminates the need to first grow a two-dimensional material on a metal substrate and then transfer the two-dimensional material to a non-metallic substrate, thereby avoiding the two-dimensional material during the transfer process and during the process of dissolving the metal.
  • the problem of defects in the dimensional material improves the performance of field effect transistors using two-dimensional materials as the channel.
  • the field effect crystal further includes a first transition layer and a second transition layer;
  • the first transition layer is located on a surface of the source and is electrically connected to the source and the channel by a chemical bond, respectively;
  • the second transition layer is located on a surface of the drain and is electrically connected to the drain and the channel by a chemical bond, respectively.
  • the source is electrically connected to the two-dimensional material as the channel through the first transition layer, and the first transition layer is passed between the source and the two-dimensional material.
  • the chemical bonds are connected together such that the contact resistance between the source and the channel becomes small; since the drain is electrically connected to the two-dimensional material as a channel through the second transition layer, and the second transition layer and the drain and the two-dimensional
  • the materials are connected together by chemical bonds, so that the contact resistance between the drain and the channel becomes small, and the performance of the field effect transistor is further improved.
  • the field effect transistor further includes a channel protection layer, where the channel protection layer is located The channel is between the gate insulating layer.
  • a channel protective layer is provided between the two-dimensional material as the channel and the gate insulating layer, the gate insulating layer can be prevented from damaging the channel.
  • the non-metallic substrate Providing a first recessed area and a second recessed area
  • the two-dimensional material growth template is located between the first recessed region and the second recessed region, the source is located in the first recessed region, and the drain is located in the second recessed region.
  • the two-dimensional material growth template is disposed in the first recess region and the second recess region by forming the first recess region and the second recess region on the non-metal substrate And a source is disposed in the first recessed region, and a drain is disposed in the second recessed region to expose the upper surface of the source and the upper surface of the drain.
  • the source When a gas is used to form a two-dimensional material, the source The upper surface and the metal on the upper surface of the drain catalyze the growth of the two-dimensional material, which facilitates the growth of the two-dimensional material on the two-dimensional material growth template to form a channel; meanwhile, the metal on the upper surface of the source Reacting with the gas to form a first transition layer, and the first transition layer is connected to the source and the channel by a chemical bond, the metal on the upper surface of the drain reacts with the gas to form a second transition layer, and the second transition layer and the drain and the trench The channels are connected by chemical bonds.
  • the atomic arrangement of the two-dimensional material is a hexagonal structure.
  • the two-dimensional material is graphene, transition Metal disulfide or black phosphorus.
  • the two-dimensional material growth template is nitrided boron.
  • 1 to 3 are schematic structural views of a fabrication process of a field effect transistor of the prior art
  • FIG. 4 is a schematic structural diagram of a field effect transistor according to Embodiment 1 of the present invention.
  • FIG. 5 is a schematic structural view of a non-metal substrate and a two-dimensional material growth template according to Embodiment 1 of the present invention
  • FIG. 6 is a schematic structural diagram of another field effect transistor according to Embodiment 1 of the present invention.
  • FIG. 7 is a schematic structural diagram of still another field effect transistor according to Embodiment 1 of the present invention.
  • FIG. 8 is a schematic structural diagram of still another field effect transistor according to Embodiment 1 of the present invention.
  • FIG. 9 is a flow chart showing a method of fabricating a field effect transistor according to Embodiment 2 of the present invention.
  • FIG. 10 to FIG. 15 are schematic structural diagrams showing a manufacturing process of a method for fabricating a field effect transistor according to Embodiment 2 of the present invention.
  • FIG. 17 to FIG. 20 are structural diagrams showing a manufacturing process of a method of fabricating a field effect transistor according to Embodiment 3 of the present invention.
  • the two-dimensional material used as the channel of the field effect transistor is graphene
  • the substrate of the field effect transistor is mostly a non-metal substrate, such as a silicon dioxide substrate, and graphite formed directly on the silicon dioxide substrate.
  • the metal substrate can catalyze the growth of graphene, for example, if methane gas is used as growth.
  • the carbon source of graphene which catalyzes the decomposition of methane gas into active carbon atoms, and the active carbon atoms are more likely to grow into graphene on the surface of the metal substrate.
  • an embodiment of the present invention provides a Field effect transistor, the field effect transistor includes:
  • Non-metal substrate 1 source 2, drain 3, two-dimensional material growth template 7, channel 4, gate insulating layer 5 and gate 6;
  • the source 2, the drain 3 and the two-dimensional material growth template 7 are located on the non-metal substrate 1, and the two-dimensional material growth template 7 is located between the source 2 and the drain 3, and the atomic arrangement of the two-dimensional material growth template 7 is The atomic arrangement of the two-dimensional material is the same or similar;
  • the channel 4 is located on the two-dimensional material growth template 7, the material of the channel 4 is a two-dimensional material, and the channel 4 is electrically connected to the source 2 and the drain 3, respectively;
  • the gate insulating layer 5 is located above the trench 4, and the gate electrode 6 is located above the gate insulating layer 5.
  • the field effect transistor in the embodiment of the present invention first forms the source 2 and the drain 3 on the non-metal substrate 1, and the two-dimensional material growth template 7 is disposed on the non-metal substrate 1, and the template 7 is grown due to the two-dimensional material.
  • the atomic arrangement structure is the same as or similar to the atomic arrangement structure of the two-dimensional material.
  • the metal of the source 2 and the drain 3 catalyze the decomposition of the gas into the element of the two-dimensional material, so that the two-dimensional material
  • the element is grown by using a two-dimensional material growth template 7 as a substrate, and finally formed as a channel 4
  • the method makes the defects of the grown two-dimensional material greatly reduced, so the conductivity of the two-dimensional material is better, so that the two-dimensional material as the channel 4 can be directly formed in the process of fabricating the field effect transistor.
  • the two-dimensional material as the channel 4 may be graphene, or may be transition metal disulfide or black phosphorus, and the transition metal disulfide may include molybdenum disulfide or tungsten disulfide.
  • the metals of the source 2 and the drain 3 catalyze the gas to decompose the elements of the two-dimensional material, so that the elements of the two-dimensional material are grown on the two-dimensional material growth template 7.
  • a pole 3, and a two-dimensional material growth template 7 is also disposed between the source 2 and the drain 3.
  • the source 2 and the drain 3 catalyze the decomposition of methane gas into active carbon atoms and hydrogen atoms, so that the active carbon atoms are
  • the two-dimensional material grows on the template 7 to form graphene.
  • the two-dimensional material growth template 7 since the atomic arrangement structure of the two-dimensional material growth template 7 is the same as or similar to the atomic arrangement structure of the two-dimensional material, the two-dimensional material is grown by the two-dimensional material growth template 7 There are few defects.
  • the two-dimensional material growth template 7 may be a boron nitride having an atomic arrangement and a hexagonal structure. According to the actual situation, other materials having the same atomic arrangement structure as the hexagonal structure or materials similar to the hexagonal structure may be selected as the two-dimensional material growth template 7.
  • the material of the channel 4 when the material of the channel 4 is graphene, it may be a single layer of graphene, a double layer of graphene or a multilayer of graphene.
  • the carrier transport speed in the single-layer graphene is faster, the mobility is higher, and the power consumption of the field effect transistor is lower; if it is double-layer or multi-layer graphene, the carrier is The number will be more and the conductivity will be better.
  • the field effect transistor further includes a first transition layer 8 and a second transition layer 9;
  • the first transition layer 8 is located on the surface of the source 2 and is electrically connected to the source 2 and the channel 4 by chemical bonds, respectively;
  • the second transition layer 9 is located on the surface of the drain 3 and is electrically connected to the drain 3 and the channel 4 by chemical bonds, respectively. Pick up.
  • the source 2 is electrically connected to the two-dimensional material as the channel 4 through the first transition layer 8, and the first transition layer 8 and the source 2 and the two-dimensional material are connected by chemical bonds. Together, the contact resistance between the source 2 and the channel 4 becomes small; since the drain 3 is electrically connected to the two-dimensional material as the channel 4 through the second transition layer 9, and the second transition layer 9 and the drain The pole 3 and the two-dimensional material are connected together by chemical bonds, so that the contact resistance between the drain 3 and the channel 4 becomes small; in the prior structure, the source 2 and the drain 3 are deposited on As a two-dimensional material of the channel 4, the source 2 and the channel 4 are only in simple contact, so the contact resistance between the source 2 and the channel 4 is large, and the drain 3 and the channel 4 are also It is only a simple contact, so the contact resistance of the drain 3 and the channel 4 is large; and the total resistance of the field effect transistor is the contact resistance between the source 2 and the channel 4, the resistance of the channel 4, and the drain 3 The
  • the non-metal substrate 1 is provided with a first recessed region 10 and a second recessed region 11;
  • the two-dimensional material growth template 7 is located between the first recessed region 10 and the second recessed region 11, the source 2 is located in the first recessed region 10, and the drain 3 is located in the second recessed region 11.
  • the two-dimensional material growth template 7 is disposed between the first recessed region 10 and the second recessed region 11, And the source 2 is disposed in the first recessed region 10 to expose the upper surface of the source 2, and the drain 3 is disposed in the second recessed region 11, so that the upper surface of the drain 3 is exposed.
  • the upper surface of the source 2 and the metal of the upper surface of the drain 3 can catalyze the growth of the two-dimensional material, which facilitates the growth of the two-dimensional material on the two-dimensional material growth template 7 to form the channel 4.
  • the metal on the upper surface of the source 2 reacts with the gas to form the first transition layer 8 while catalyzing the growth of the two-dimensional material, and the first transition layer 8 is connected to the source 2 and the channel 4 by chemical bonds, and the drain 3 is The metal of the surface reacts with the gas to form the second transition layer 9 while catalyzing the growth of the two-dimensional material, and the second transition layer 9 is connected to the drain 3 and the channel 4 by chemical bonds.
  • graphene When graphene is selected as the material of channel 4, it may be selected by chemical vapor deposition or plasma enhanced chemical vapor deposition to grow graphene by gas, gas may be selected from methane CH 4 gas, or carbon-containing gas such as ethylene or acetylene may be selected. It is also possible to select a liquid containing carbon such as alcohol. In the process of chemical vapor deposition or plasma enhanced chemical vapor deposition, the alcohol can be first converted into a gas by adjusting the decomposition temperature, and graphene is grown by using an alcohol gas.
  • boron nitride is used as the two-dimensional material growth template, and when graphene is grown by methane, the upper surface of the source 2 located in the first recessed region 10 and the drain located in the second recessed region 11 The upper surface of the pole 3 is exposed, and the metal on the upper surface of the source 2 and the metal on the upper surface of the drain 3 catalyze the decomposition of methane gas into active carbon atoms, so that the upper surface of the source 2 and the upper surface of the source 2, the drain 3
  • the activity of the carbon atoms in the vicinity of the upper surface and the upper surface of the drain 3 is high, and thus it is advantageous for the carbon atoms to grow into graphene on the boron nitride to form the channel 4.
  • the metal on the upper surface of the source 2 reacts with the carbon in the gas to form the first transition layer 8
  • the metal on the upper surface of the drain 3 reacts with the carbon in the gas to form the second transition layer 9, wherein when the source 2
  • the materials of the first transition layer 8 and the second transition layer 9 are different, for example:
  • the first transition of the upper surface of the source 2 is Mo x C formed by the reaction of metal molybdenum and carbon, and the passage between Mo x C and the source 2, the drain 3 and the graphene as the channel 4 are passed. Chemically bonded so that the contact resistance between the source 2 and the graphene as the channel 4, and the contact resistance between the drain 3 and the graphene as the channel 4 are small;
  • the graphene is grown on the boron nitride.
  • the temperature is high, and the metal nickel is mixed into the source 2 and the drain 3 by the high temperature, and is integrated into the source after the growth of the graphene as the channel 4 is cooled.
  • the carbon in the pole 2 and the drain 3 is precipitated from the surfaces of the source 2 and the drain 3 to form graphene, that is, the material of the first transition layer 8 and the second transition layer 9 is graphene, but relative to the channel 4
  • the thickness of the graphene of the first transition layer 8 and the second transition layer 9 is thicker, so the number of carriers in the first transition layer 8 and the second transition layer 9 is larger, and the conductivity is more.
  • the connection of the source 2 and the graphene as the channel 4 through the first transition layer 8 can effectively reduce the contact resistance
  • the connection of the drain 3 and the graphene as the channel 4 through the second transition layer 9 can effectively reduce the contact resistance.
  • the thicker graphene and the source 2 are also connected by chemical bonds. Possible to reduce the channel between the source electrode 2 and 4 as graphene, The contact resistance between the drain 3 and the graphene as the channel 4.
  • the required temperatures are high, and the defects of the upper surfaces of the source 2 and the drain 3 are high at high temperatures.
  • the impurities and impurities are also reduced, and the contact resistance between the source 2 and the channel 4 and between the drain 3 and the channel 4 can be further reduced.
  • the metal of the source 2 and the drain 3 may also be a simple metal such as platinum, copper or nickel; or an alloy of different metals, such as an alloy of copper and tungsten, an alloy of copper and nickel, or different A layered stack of metals.
  • the field effect transistor may further include a channel protection layer 12 , and the channel protection layer 12 is located between the channel 4 and the gate insulating layer 5 .
  • the gate insulating layer 5 is a high dielectric material
  • the high dielectric material may include aluminum oxide Al 2 O 3 , hafnium hydroxide HfO 2 or antimony trioxide Y 2 O 3 , etc., in order to prevent the gate insulating layer 5 from being broken as a trench.
  • a two-dimensional material of the track 4 may be provided with a channel protective layer 12 between the two-dimensional material and the gate insulating layer 5, and the channel protective layer 12 may also cover the first transition layer 8 and the second transition layer 9 at the same time.
  • the first transition layer 8 and the second transition layer 9 also have a protective effect.
  • the material of the channel protective layer 12 may be selected from nitrogen.
  • boron nitride as the channel protective layer 12 can be grown using graphene as a growth template, and can also be utilized.
  • the prior art transfers boron nitride to graphene after growing boron nitride on other substrates.
  • the field effect transistor can also be designed as the structure shown in FIG. 7, that is:
  • a first substrate B is formed on the non-metal substrate 1, and the atomic arrangement structure of the first substrate B is the same as or similar to the atomic arrangement structure of the two-dimensional material;
  • the source 2 and the drain 3 are located on the first substrate B, and the first substrate B between the source 2 and the drain 3 is used as a two-dimensional material growth template 7;
  • the channel 4 is located on the two-dimensional material growth template 7, and the material of the channel 4 is a two-dimensional material;
  • the first transition layer 8 is located on the surface of the source 2, and is electrically connected to the source 2 and the channel 4 by a chemical bond
  • the second transition layer 9 is located on the surface of the drain 3, and is electrically connected to the drain 3 and the channel 4 by chemical bonds. connection;
  • the channel protection layer 12 is located above the channel 4, and the first transition layer 8 and the second transition layer 9 may also be covered;
  • the gate insulating layer 5 is located above the channel protective layer 12, and the gate electrode 6 is located above the gate insulating layer 5.
  • the field effect transistor can also be designed as shown in FIG. 8: namely:
  • the channel 4 is located on the two-dimensional material growth template 7, and the material of the channel 4 is a two-dimensional material;
  • the first transition layer 8 is located on the surface of the source 2, and is electrically connected to the source 2 and the channel 4 by a chemical bond
  • the second transition layer 9 is located on the surface of the drain 3, and is electrically connected to the drain 3 and the channel 4 by chemical bonds. connection;
  • the channel protection layer 12 is located above the channel 4, and the first transition layer 8 and the second transition layer 9 may also be covered;
  • the gate insulating layer 5 is located above the channel protective layer 12, and the gate electrode 6 is located above the gate insulating layer 5.
  • the field effect transistor in the embodiment of the present invention first forms the source 2 and the drain 3 on the non-metal substrate 1, and the two-dimensional material growth template 7 is disposed on the non-metal substrate 1, and the template 7 is grown due to the two-dimensional material.
  • the atomic arrangement structure is the same as or similar to the atomic arrangement structure of the two-dimensional material.
  • the two-dimensional material as the channel 4 can be formed directly in the process of fabricating the field effect transistor, without first growing the two-dimensional material on the metal substrate and transferring the two-dimensional material onto the non-metal substrate 1, avoiding the two-dimensional
  • the problem that the material causes defects in the two-dimensional material during the transfer process and in the process of dissolving the metal improves the performance of the field effect transistor using the two-dimensional material as the channel 4. Meanwhile, when a two-dimensional material as a channel is formed, a first transition layer 8 is formed over the source 2, and a pass between the first transition layer 8 and the source 2 and the two-dimensional material as the channel 4 is passed.
  • a second transition layer 9 is formed over the drain 3, and the second transition layer 9 and the drain 3 and the two-dimensional material as the channel 4 are connected by a chemical bond, the first transition layer 8
  • the contact resistance between the source 2 and the channel 4 can be effectively reduced, and the second transition layer 9 can effectively reduce the contact resistance between the drain 3 and the channel 4, thereby improving the field effect of using the two-dimensional material as the channel 4.
  • the performance of the transistor is
  • an embodiment of the present invention provides a method for fabricating a field effect transistor, the method comprising:
  • Step 101 A two-dimensional material growth template 7, a first recessed region 10 and a second recessed region 11 are disposed on the non-metal substrate 1, and the two-dimensional material growth template 7 is located between the first recessed region 10 and the second recessed region 11.
  • the atomic arrangement structure of the two-dimensional material growth template 7 is the same as or similar to the atomic arrangement structure of the two-dimensional material;
  • a two-dimensional material growth template 7 may be formed on the non-metal substrate 1, wherein the two-dimensional material growth template 7 may be formed on the metal substrate before being transferred to the non-metal liner.
  • the thickness may be between 10 nm and 11 nm, and it may be appropriately set according to actual conditions.
  • the first recessed region 10 and the second recessed region 11 are etched on the non-metal substrate 1 by electron beam exposure or ultraviolet exposure.
  • the material of the non-metal substrate 1 may be silicon, quartz, SOI (Silicon-On-Insulator, silicon on an insulating substrate) or silicon carbide.
  • the method of etching the first recessed region 10 and the second recessed region 11 may be selected according to actual conditions.
  • the etching method may select reactive ion etching.
  • an anti-etching protective glue may be applied on the two-dimensional material growth template 7 before the etching, for example, may be a photoresist.
  • the order of forming the first recessed region 10, the second recessed region 11, and the two-dimensional material growth template 7 is not limited, and the first recessed region 10 and the first may be formed on the non-metal substrate 1 first.
  • the second recessed region 11 further forms a two-dimensional material growth template 7 between the first recessed region 10 and the second recessed region 11.
  • Step 102 as shown in FIG. 12, forming a source 2 in the first recessed region 10, forming a drain 3 in the second recessed region 11;
  • the material of the source 2 and the drain 3 may be a simple metal, such as copper, nickel or platinum; or an alloy of copper and molybdenum, or an alloy of copper and nickel; or copper and molybdenum.
  • Layered stack in which copper is in the lower layer, molybdenum is in the upper layer, copper has a thickness of 10 nm, and molybdenum has a thickness of 90 nm. It can also be a layered stack of copper and tungsten.
  • the thickness of each layer of metal can also be designed according to actual conditions. It is not limited to this embodiment.
  • the method for fabricating the field effect transistor in which the material of the channel 4 is a two-dimensional material is to form the source 2 and the drain 3 on the non-metal substrate 1 first. Some first transfer the two-dimensional material to the non-metal substrate 1, and then form the source 2 and the drain 3 on the two-dimensional material. For example, transfer the fabricated graphene to the non-metal substrate 1, and then The source 2 and the drain 3 are formed on the metal substrate 1, and therefore, when forming the source 2 and the drain 3, it is necessary to consider whether the method used when forming the source 2 and the drain 3 may cause damage to the graphene. For example, the method of magnetron sputtering cannot be used at this time.
  • Forming source 2 and drain 3 because the energy of metal atoms forming source 2 and drain 3 during magnetron sputtering is higher, causing damage to graphene, causing source 2, drain 3 and graphene The quality of the contact position deteriorates, resulting in an increase in contact resistance; at the same time, the source 2 and the drain 3 cannot be formed by electroplating because the non-metal substrate 1 and graphene are also bubbled in the chemical solution during electroplating. , causing damage to graphene.
  • the source 2 and the drain 3 are formed first, and thus the method of forming the source 2 and the drain 3 is not limited, for example, a method of electron beam evaporation, a method of thermal evaporation, and magnetron sputtering. Method or method of plating.
  • Step 103 As shown in FIG. 13, a two-dimensional material is grown on the two-dimensional material growth template 7 using a gas, and a two-dimensional material is used as the channel 4, while the first transition layer 8 and the drain are grown on the surface of the source 2. 3 surface growth of the second transition layer 9, the first transition layer 8 is electrically connected to the source 2 and the channel 4 respectively by chemical bonds, and the second transition layer 9 is electrically connected to the drain 3 and the channel 4 by chemical bonds, respectively;
  • the gas comprises an element constituting a two-dimensional material
  • the source 2 and the drain 3 are used for catalyzing the decomposition of the element of the two-dimensional material in the process of growing the two-dimensional material, so that the element of the two-dimensional material is A two-dimensional material is grown on the two-dimensional material growth template 7.
  • the two-dimensional material may be grown on the two-dimensional material growth template 7 by a chemical vapor deposition method or a plasma enhanced chemical vapor deposition method.
  • the two-dimensional material may be graphene, or may be transition metal disulfide or black phosphorus, wherein the transition metal disulfide may include molybdenum disulfide or tungsten disulfide.
  • the gas may be selected from methane CH 4 gas, or a gas containing carbon such as ethylene or acetylene, or a liquid containing carbon such as alcohol, in chemical vapor deposition or plasma enhanced chemical vapor phase. During the deposition process, the alcohol can be first converted into a gas, and then the gas is used to grow graphene.
  • the powder of molybdenum and the gas containing sulfur may be selected.
  • the powder of molybdenum becomes gas and decomposes into molybdenum atoms, including The sulfur gas decomposes out the sulfur atom, and the sulfur atom reacts with the molybdenum atom to form molybdenum disulfide.
  • the upper surface of the source 2 and the drain 3 since the upper surfaces of the source 2 and the drain 3 are exposed, the upper surface of the source 2 and the metal of the upper surface of the drain 3 catalyze the growth of the two-dimensional material as the channel 4. The effect is beneficial to the growth of the two-dimensional material on the two-dimensional material growth template 7.
  • the methane CH 4 gas is selected as the carbon source to grow graphene
  • the metal on the upper surface of the source 2 and the drain 3 catalyzes the decomposition of the methane gas into active carbon atoms
  • the source 2 is The carbon atoms in the vicinity of the surface and the upper surface of the source 2, the upper surface of the drain 3, and the upper surface of the drain 3 are highly active, which facilitates the growth of graphene on the two-dimensional material growth template 7 to form the channel 4.
  • the material of the two-dimensional material growth template 7 can be selected according to the material of the two-dimensional material.
  • the two-dimensional material is graphene
  • the atomic arrangement structure of the graphene is a hexagonal structure
  • the atom can be selected.
  • the arrangement structure is also a hexagonal structure of boron nitride as a two-dimensional material growth template 7.
  • the atomic arrangement structure of the two-dimensional material growth template 7 is the same as or similar to the atomic arrangement structure of the two-dimensional material, when the gas is used to grow the two-dimensional material, the two-dimensional material grows the template by using the two-dimensional material.
  • the defects of the grown two-dimensional material are greatly reduced, so that the conductivity of the two-dimensional material is better, so that the two-dimensional material as the channel 4 can be formed directly in the process of fabricating the field effect transistor without first
  • the growth of the two-dimensional material on the metal substrate and the transfer of the two-dimensional material to the non-metal substrate 1 avoids the problem that the two-dimensional material causes defects in the two-dimensional material during the transfer process and in the process of dissolving the metal.
  • the performance of a field effect transistor using a two-dimensional material as the channel 4 is improved.
  • a two-dimensional material as the channel 4 is grown on the two-dimensional material growth template 7, while a first transition layer 8 is grown on the surface of the source 2 using a gas, and at the drain 3 A second transition layer 9 is grown on the surface.
  • the first transition layer 8 is electrically connected to the source 2 and the channel 4 by chemical bonds, respectively, and the second transition layer 9 is electrically connected to the drain 3 and the channel 4 by chemical bonds, respectively.
  • the source 2 and the drain 3 are layered stacked metal copper and metal molybdenum, the metal molybdenum reacts with carbon to form Mo x C, at this time the first transition layer 8 and the second
  • the material of the transition layer 9 is Mo x C, and the Mo x C is connected to the source 2, the drain 3, and the graphene as the channel 4 by chemical bonds;
  • the drain 3 is a layered metal copper and a metal nickel, the metal nickel is mixed with the carbon in the gas into the source 2 and the drain 3 under the action of high temperature, and is cooled during the growth of the graphene.
  • the carbon incorporated into the source 2 and the drain 3 is precipitated from the surfaces of the source 2 and the drain 3 to form graphene, that is, the material of the first transition layer 8 and the second transition layer 9 is graphene, but relative to As the graphene of the channel 4, the thickness of the graphene of the first transition layer 8 and the second transition layer 9 is thicker, and thus the number of carriers in the first transition layer 8 and the second transition layer 9 is more The conductivity is better, and at the same time, the thicker graphene and the source 2, the drain 3 and the graphene as the channel 4 are also connected by chemical bonds.
  • the source 2 is electrically connected to the two-dimensional material as the channel 4 through the first transition layer 8, and the first transition layer 8 and the source 2 and the two-dimensional material are connected by chemical bonds.
  • the drain 3 is electrically connected to the two-dimensional material as the channel 4 through the second transition layer 9, and the second transition layer 9 and the drain 3 and the two-dimensional material are connected by chemical bonds. So the first transition layer 8 and the second transition layer 9 can effectively reduce the contact resistance between the source 2 and the channel 4 and the contact resistance between the drain 3 and the channel 4, making the field effect transistor more excellent in use performance.
  • Step 104 As shown in FIG. 14, a channel protective layer 12 is formed on the trench 4.
  • the material of the channel protection layer 12 may be selected from boron nitride. If the two-dimensional material of the channel 4 is graphene, the atomic arrangement structure of the boron nitride is the same as that of the graphene. That is, all of them are hexagonal structures, so boron nitride as the channel protective layer 12 can be grown using graphene as a growth template, can be formed by chemical vapor deposition or plasma enhanced chemical vapor deposition, and can also utilize prior art. The boron nitride is transferred to the graphene after the boron nitride is grown on the other substrate.
  • the channel protective layer 12 can also cover the first transition layer 8 and the second transition layer 9 at the same time, while protecting the first transition layer 8 and the second transition layer 9 The role.
  • Step 105 As shown in FIG. 15, a gate insulating layer 5 is formed on the channel protective layer 12.
  • the gate insulating layer 5 may be formed by a method of atomic layer deposition, and the material of the gate insulating layer 5 may include aluminum oxide Al 2 O 3 , barium hydroxide HfO 2 or antimony trioxide Y 2 O 3 .
  • Step 106 As shown in FIG. 6, a gate electrode 6 is formed on the gate insulating layer 5.
  • the material of the gate electrode 6 may be gold, palladium or tungsten, or may be other metal materials, and may be selected according to actual conditions.
  • the field effect transistor in the embodiment of the present invention first forms the source 2 and the drain 3 on the non-metal substrate 1, and the two-dimensional material growth template 7 is disposed on the non-metal substrate 1, and the template 7 is grown due to the two-dimensional material.
  • the atomic arrangement structure is the same as or similar to the atomic arrangement structure of the two-dimensional material.
  • the two-dimensional material as the channel 4 can be formed directly in the process of fabricating the field effect transistor, without first growing the two-dimensional material on the metal substrate and transferring the two-dimensional material onto the non-metal substrate 1, avoiding the two-dimensional
  • the problem that the material causes defects in the two-dimensional material during the transfer process and in the process of dissolving the metal improves the performance of the field effect transistor using the two-dimensional material as the channel 4.
  • a first transition layer 8 is further formed on the source electrode 2, and the first transition layer 8 and the source electrode 2 and the two-dimensional material as the channel 4 are connected by a chemical bond.
  • a second transition layer 9 is also formed over the drain 3, and the second transition layer 9 and the drain 3 and the two-dimensional material as the channel 4 are connected by chemical bonds, and the first transition layer 8 can effectively reduce the source. Pole 2 and channel 4
  • the contact resistance between the second transition layer 9 can effectively reduce the contact resistance between the drain 3 and the channel 4, improving the performance of the field effect transistor using the two-dimensional material as the channel 4.
  • an embodiment of the present invention provides a method for fabricating a field effect transistor, the method comprising:
  • Step 201 As shown in FIG. 17, a first substrate B is formed on the non-metal substrate, and the atomic arrangement structure of the first substrate B is the same as or similar to the atomic arrangement structure of the two-dimensional material, on the first substrate B. a source 2 and a drain 3 are formed thereon, and a portion of the first substrate B between the source 2 and the drain 3 is grown as a two-dimensional material growth template 7;
  • the order of forming the source 2, the drain 3, and the first substrate B is not limited, and the source 2 and the drain 3 may be formed on the non-metal substrate 1 first, and then at the source.
  • a first substrate B is formed on the non-metal substrate 1 between the source 2 and the drain 3, and the first substrate on the surfaces of the source 2 and the drain 3 is etched away. B.
  • the first substrate B between the source 2 and the drain 3 is used as a two-dimensional material growth template 7.
  • Step 202 As shown in FIG. 18, a two-dimensional material is grown on the two-dimensional material growth template 7 using a gas, and the two-dimensional material is used as the channel 4, while the first transition layer 8 is grown on the surface of the source 2 using a gas and a second transition layer 9 is grown on the surface of the drain 3, and the first transition layer 8 is electrically connected to the source 2 and the two-dimensional material respectively by chemical bonds, and the second transition layer 9 is electrically connected to the drain 3 and the two-dimensional material through chemical bonds, respectively;
  • the gas includes an element constituting a two-dimensional material, and when a two-dimensional material is grown on the two-dimensional material growth template 7 using a gas, the metal of the source 2 and the drain 3 catalyze the decomposition of the gas into the two-dimensional material.
  • the element causes the element of the two-dimensional material to grow on the two-dimensional material growth template 7 to form the channel 4, and at the same time, since the atomic arrangement of the two-dimensional material growth template 7 is the same as that of the two-dimensional material of the channel 4 Or similarly, the defects of the two-dimensional material obtained by using the two-dimensional material growth template 7 as a substrate are greatly reduced, so that the conductivity of the two-dimensional material is relatively good, so that the method can be used directly in the field effect.
  • a two-dimensional material is formed as the channel 4, and it is not necessary to first grow the two-dimensional material on the metal substrate and then transfer the two-dimensional material to the non-metal substrate 1, thereby avoiding the two-dimensional material during the transfer process. And the problem of causing defects in the two-dimensional material in the process of dissolving the metal, improving the performance of the field effect transistor using the two-dimensional material as the channel 4.
  • the first transition layer 8 is grown on the surface of the source 2 and the second transition layer 9 is grown on the surface of the drain 3, because the source 2 is The two-dimensional material of the channel 4 is electrically connected through the first transition layer 8, and the first transition layer 8 and the source 2 and the two-dimensional material are connected by chemical bonds, and the drain 3 and the channel 4 are used as the channel 4.
  • the two-dimensional material is electrically connected through the second transition layer 9, and the second transition layer 9 and the drain 3 and the two-dimensional material are connected by chemical bonds, so the first transition layer 8 and the second transition layer 9 can
  • the contact resistance between the source 2 and the channel 4 and the contact resistance between the drain 3 and the channel 4 are effectively reduced, so that the performance of the field effect transistor is further improved.
  • Step 203 As shown in FIG. 19, a channel protective layer 12 is formed on the trench 4.
  • the material of the channel protection layer 12 may be selected from boron nitride. If the two-dimensional material of the channel 4 is graphene, the atomic arrangement structure of the boron nitride is the same as that of the graphene. That is, all of them are hexagonal structures, so boron nitride as the channel protective layer 12 can be grown using graphene as a growth template, can be formed by chemical vapor deposition or plasma enhanced chemical vapor deposition, and can also utilize prior art. The boron nitride is transferred to the graphene after the boron nitride is grown on the other substrate.
  • the channel protective layer 12 can also cover the first transition layer 8 and the second transition layer 9 at the same time, while protecting the first transition layer 8 and the second transition layer 9 The role.
  • Step 204 As shown in FIG. 20, a gate insulating layer 5 is formed on the channel protective layer 12.
  • the gate insulating layer 5 may be formed by a method of atomic layer deposition, and the material of the gate insulating layer 5 may include aluminum oxide Al 2 O 3 , barium hydroxide HfO 2 or antimony trioxide Y 2 O 3 .
  • Step 205 As shown in FIG. 7, a gate electrode 6 is formed on the gate insulating layer 5.
  • the material of the gate electrode 6 may be gold, palladium or tungsten, or may be other metal materials, and may be selected according to actual conditions.
  • the field effect transistor in the embodiment of the present invention first forms the source 2 and the drain 3 on the non-metal substrate 1, and the two-dimensional material growth template 7 is disposed on the non-metal substrate 1, and the template 7 is grown due to the two-dimensional material.
  • the atomic arrangement structure is the same as or similar to the atomic arrangement structure of the two-dimensional material.
  • the two-dimensional material as the channel 4 can be formed directly in the process of fabricating the field effect transistor, without first growing the two-dimensional material on the metal substrate and transferring the two-dimensional material onto the non-metal substrate 1, avoiding the two-dimensional
  • the problem of the material causing defects in the two-dimensional material during the transfer process and in the process of dissolving the metal improves the field effect transistor using the two-dimensional material as the channel 4.
  • a first transition layer 8 is formed on the source 2, and a chemical bond is formed between the first transition layer 8 and the source 2 and the two-dimensional material as the channel 4.
  • a second transition layer 9 is formed on the drain 3, and the second transition layer 9 and the drain 3 and the two-dimensional material as the channel 4 are connected by a chemical bond, and the first transition layer 8 can be Effectively reducing the contact resistance between the source 2 and the channel 4, the second transition layer 9 can effectively reduce the contact resistance between the drain 3 and the channel 4, and improve the field effect transistor using the two-dimensional material as the channel 4. Performance of use.

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Abstract

A preparation method for a field effect transistor and a field effect transistor, relating to the field of technological development of field effect transistors. The preparation method comprises: forming a source electrode (2), a drain electrode (3) and a two-dimensional material growth template (7) on a non-metal substrate (1); and using gas to grow a two-dimensional material on the two-dimensional material growth template (7), and using the two-dimensional material as a channel (4), wherein the source electrode (2) and the drain electrode (3) are used for catalysing the gas to decompose elements of the two-dimensional material, so that the elements of the two-dimensional material grow on the two-dimensional material growth template (7) to form the channel (4), and at the same time, the gas is used to grow a first transition layer (8) on a surface of the source electrode (2) and grow a second transition layer (9) on a surface of the drain electrode (3). A two-dimensional material acting as a channel (4) may be directly formed during the process of preparing a field effect transistor by means of the catalytic action of a source electrode (2) and a drain electrode (3), thereby omitting the transfer process of the two-dimensional material, and the channel (4) may be connected to the first transition layer (8) and the second transition layer (9) via a chemical bond, thereby reducing contact resistance between the source electrode (2), the drain electrode (3) and the channel (4).

Description

一种场效应晶体管的制作方法及场效应晶体管Field effect transistor manufacturing method and field effect transistor 技术领域Technical field

本发明涉及场效应晶体管技术开发领域,特别涉及一种场效应晶体管的制作方法及场效应晶体管。The invention relates to the field of field effect transistor technology development, in particular to a method for fabricating a field effect transistor and a field effect transistor.

背景技术Background technique

场效应晶体管是一种电压控制型器件,已被广泛应用于微电子行业中。场效应晶体管包括栅极、源极、漏极和位于源极与漏极之间的沟道,随着微电子行业的不断发展,场效应晶体管的尺寸也越来越小,沟道的尺寸已进入了亚微米和纳米尺度范围。Field effect transistors are voltage controlled devices that have been widely used in the microelectronics industry. The field effect transistor includes a gate, a source, a drain, and a channel between the source and the drain. With the continuous development of the microelectronics industry, the size of the field effect transistor is getting smaller and smaller, and the size of the channel has been Entered the submicron and nanoscale range.

场效应晶体管的沟道尺寸越小,就越容易出现短沟道效应,导致场效应晶体管的性能发生恶化。为了避免出现短沟道效应,目前使用二维材料来制作场效应晶体管的沟道,使用二维材料制作的沟道可以避免出现短沟道效应。目前较常用的二维材料为石墨烯,使用石墨烯制作场效应晶体管的流程如下:首先使用包含碳元素的气体在金属衬底上生长石墨烯,如图1所示,然后溶解掉金属衬底并将剩下的石墨烯A转移到非金属衬底1上,如图2所示,再在石墨烯A上沉积源极2和漏极3,源极2和漏极3之间存在间距并将源极2与漏极3之间的石墨烯A作为沟道4,如图3所示,最后在沟道4上沉积栅绝缘层5和栅极6,以形成场效应晶体管。The smaller the channel size of the field effect transistor, the more likely the short channel effect occurs, resulting in deterioration of the performance of the field effect transistor. In order to avoid short channel effects, two-dimensional materials are currently used to fabricate the channel of a field effect transistor, and a channel made of a two-dimensional material can avoid short channel effects. At present, the two-dimensional material commonly used is graphene. The flow of making a field effect transistor using graphene is as follows: First, graphene is grown on a metal substrate using a gas containing carbon, as shown in FIG. 1, and then the metal substrate is dissolved. And transferring the remaining graphene A onto the non-metal substrate 1, as shown in FIG. 2, depositing source 2 and drain 3 on the graphene A, and having a gap between the source 2 and the drain 3 and The graphene A between the source 2 and the drain 3 is taken as the channel 4, as shown in FIG. 3, and finally the gate insulating layer 5 and the gate 6 are deposited on the trench 4 to form a field effect transistor.

在实现本发明的过程中,发明人发现现有技术至少存在以下问题:In the process of implementing the present invention, the inventors have found that the prior art has at least the following problems:

由于需要将石墨烯即二维材料从金属衬底上转移到非金属衬底上,复杂的转移过程不可避免地带来二维材料的破损、褶皱以及二维材料上还残留了金属和溶剂等污染物,导致石墨烯的导电性能变差。Due to the need to transfer graphene, a two-dimensional material, from a metal substrate to a non-metallic substrate, complex transfer processes inevitably lead to damage, wrinkles, and residual metal and solvent contamination on the two-dimensional material. The material causes the conductivity of graphene to deteriorate.

发明内容Summary of the invention

为了解决由于石墨烯的转移以及石墨烯上残留的污染物而导致的石墨烯的导电性能变差,进而影响场效应晶体管的性能的问题,本发明实施例提供了一种场效应晶体管的制作方法及场效应晶体管。所述技术方案如下:In order to solve the problem that the conductivity of the graphene is deteriorated due to the transfer of graphene and the residual pollutants on the graphene, thereby affecting the performance of the field effect transistor, the embodiment of the invention provides a method for fabricating a field effect transistor And field effect transistors. The technical solution is as follows:

第一方面,提供了一种场效应晶体管的制作方法,所述制作方法包括: In a first aspect, a method of fabricating a field effect transistor is provided, the method comprising:

在非金属衬底上形成源极、漏极以及二维材料生长模板,所述二维材料生长模板位于所述源极和所述漏极之间;Forming a source, a drain, and a two-dimensional material growth template on the non-metal substrate, the two-dimensional material growth template being located between the source and the drain;

使用气体在所述二维材料生长模板上生长二维材料,将所述二维材料作为沟道,所述沟道分别与所述源极和所述漏极电连接,所述气体包括组成所述二维材料的元素,所述源极和所述漏极用于在生长所述二维材料的过程中催化所述气体分解出所述二维材料的元素,使所述二维材料的元素在所述二维材料生长模板上生长所述二维材料;Forming a two-dimensional material on the two-dimensional material growth template using a gas, the two-dimensional material as a channel, the channel being electrically connected to the source and the drain, respectively, the gas including a composition An element of a two-dimensional material, the source and the drain for catalyzing the gas to decompose elements of the two-dimensional material during growth of the two-dimensional material, such that elements of the two-dimensional material Growing the two-dimensional material on the two-dimensional material growth template;

在所述沟道上形成栅绝缘层和栅极。A gate insulating layer and a gate are formed on the channel.

在第一方面中,由于先在非金属衬底上形成源极和漏极,并且在非金属衬底上设置二维材料生长模板,二维材料生长模板的原子排列结构与二维材料的原子排列结构相同或者类似,在使用气体生长二维材料时,源极和漏极的金属会催化气体分解出二维材料的元素,使二维材料的元素以二维材料生长模板作为基底来生长,最终形成作为沟道的二维材料,此种方法使得生长出的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,如此可以直接在制作场效应晶体管的过程中形成作为沟道的二维材料,无需先在金属衬底上生长二维材料以及再将二维材料转移到非金属衬底上,避免了二维材料在转移的过程中以及在溶解金属衬底的过程中而导致二维材料产生缺陷的问题,提高了使用二维材料作为沟道的场效应晶体管的性能。In the first aspect, since the source and the drain are formed on the non-metal substrate first, and the two-dimensional material growth template is provided on the non-metal substrate, the atomic arrangement of the two-dimensional material growth template and the atom of the two-dimensional material The arrangement structure is the same or similar. When a gas is used to grow a two-dimensional material, the source and drain metals catalyze the gas to decompose the elements of the two-dimensional material, so that the elements of the two-dimensional material grow with the two-dimensional material growth template as a substrate. Finally, a two-dimensional material is formed as a channel. This method greatly reduces the defects of the grown two-dimensional material, so the conductivity of the two-dimensional material is better, so that it can be directly formed as a channel in the process of fabricating the field effect transistor. The two-dimensional material eliminates the need to first grow a two-dimensional material on a metal substrate and then transfer the two-dimensional material onto a non-metallic substrate, avoiding the two-dimensional material during the transfer process and during the process of dissolving the metal substrate. The problem of causing defects in two-dimensional materials improves the performance of field effect transistors using two-dimensional materials as channels.

结合第一方面,在第一方面的第一种可能的实现方式中,所述制作方法还包括:In conjunction with the first aspect, in a first possible implementation manner of the first aspect, the manufacturing method further includes:

在生长所述二维材料的同时使用所述气体在所述源极表面生长第一过渡层以及在所述漏极表面生长第二过渡层,所述第一过渡层通过化学键分别与所述源极和所述沟道电连接,所述第二过渡层通过化学键分别与所述漏极和所述沟道电连接。Forming a first transition layer on the source surface and a second transition layer on the drain surface using the gas while growing the two-dimensional material, the first transition layer being respectively separated from the source by a chemical bond The pole is electrically connected to the channel, and the second transition layer is electrically connected to the drain and the channel by a chemical bond, respectively.

在第一方面的第一种可能的实现方式中,因为源极与作为沟道的二维材料通过第一过渡层电连接,且第一过渡层与源极和二维材料之间均是通过化学键连接在一起的,使得源极与沟道之间的接触电阻变小;因为漏极与作为沟道的二维材料通过第二过渡层电连接,且第二过渡层与漏极和二维材料之间均是通过化学键连接在一起的,使得漏极与沟道之间的接触电阻变小,使场效应晶体管的使用性能更加优异。In a first possible implementation of the first aspect, the source is electrically connected to the two-dimensional material as the channel through the first transition layer, and the first transition layer passes between the source and the two-dimensional material. The chemical bonds are connected together such that the contact resistance between the source and the channel becomes small; since the drain is electrically connected to the two-dimensional material as a channel through the second transition layer, and the second transition layer and the drain and the two-dimensional The materials are connected together by chemical bonds, so that the contact resistance between the drain and the channel becomes small, and the performance of the field effect transistor is further improved.

结合第一方面或第一方面的第一种可能的实现方式,在第一方面的第二种 可能的实现方式中,所述在非金属衬底上形成源极、漏极以及二维材料生长模板,包括:In combination with the first aspect or the first possible implementation of the first aspect, the second aspect of the first aspect In a possible implementation manner, the forming a source, a drain, and a two-dimensional material growth template on a non-metal substrate, including:

在所述非金属衬底上设置所述二维材料生长模板、第一凹陷区和第二凹陷区,所述二维材料生长模板位于所述第一凹陷区和所述第二凹陷区之间;Forming the two-dimensional material growth template, the first recessed region and the second recessed region on the non-metal substrate, the two-dimensional material growth template being located between the first recessed region and the second recessed region ;

在所述第一凹陷区内形成所述源极,在所述第二凹陷区内形成所述漏极。The source is formed in the first recess region, and the drain is formed in the second recess region.

在第一方面的第二种可能的实现方式中,通过在非金属衬底上形成第一凹陷区和第二凹陷区,将二维材料生长模板设置在第一凹陷区和第二凹陷区之间,并在第一凹陷区内设置源极,第二凹陷区内设置漏极,可以使源极的上表面和漏极的上表面露出,如此,在使用气体形成二维材料时,源极的上表面和漏极的上表面的金属会对二维材料的生长起到催化作用,有利于二维材料在二维材料生长模板上生长,形成沟道;同时,源极上表面的金属会与气体反应生成第一过渡层,并且第一过渡层与源极、沟道通过化学键连接,漏极上表面的金属会与气体反应生成第二过渡层,并且第二过渡层与漏极、沟道通过化学键连接。In a second possible implementation manner of the first aspect, the two-dimensional material growth template is disposed in the first recessed region and the second recessed region by forming the first recessed region and the second recessed region on the non-metal substrate And a source is disposed in the first recessed region, and a drain is disposed in the second recessed region to expose the upper surface of the source and the upper surface of the drain. Thus, when a gas is used to form a two-dimensional material, the source The upper surface and the metal on the upper surface of the drain catalyze the growth of the two-dimensional material, which facilitates the growth of the two-dimensional material on the two-dimensional material growth template to form a channel; meanwhile, the metal on the upper surface of the source Reacting with the gas to form a first transition layer, and the first transition layer is connected to the source and the channel by a chemical bond, the metal on the upper surface of the drain reacts with the gas to form a second transition layer, and the second transition layer and the drain and the trench The channels are connected by chemical bonds.

结合第一方面或第一方面的第一种可能的实现方式,在第一方面的第三种可能的实现方式中,所述在非金属衬底上形成源极、漏极以及二维材料生长模板,包括:In combination with the first aspect or the first possible implementation of the first aspect, in a third possible implementation manner of the first aspect, the forming a source, a drain, and a two-dimensional material on a non-metal substrate Templates, including:

在所述非金属衬底上形成第一衬底;Forming a first substrate on the non-metal substrate;

在所述第一衬底上形成所述源极和所述漏极,并将所述第一衬底位于所述源极和所述漏极之间的部分作为所述二维材料生长模板。The source and the drain are formed on the first substrate, and a portion of the first substrate between the source and the drain is used as the two-dimensional material growth template.

结合第一方面或第一方面的第一种至第三种任一种可能的实现方式,在第一方面的第四种可能的实现方式中,所述二维材料为石墨烯、过渡金属二硫化物或黑磷。In combination with the first aspect or the first to third possible implementation manners of the first aspect, in the fourth possible implementation manner of the first aspect, the two-dimensional material is graphene, transition metal Sulfide or black phosphorus.

结合第一方面的第四种可能的实现方式,在第一方面的第五种可能的实现方式中,所述过渡金属二硫化物包括二硫化钼或二硫化钨。In conjunction with the fourth possible implementation of the first aspect, in a fifth possible implementation of the first aspect, the transition metal disulfide comprises molybdenum disulfide or tungsten disulfide.

结合第一方面或第一方面的第一种至第五种中的任一种可能的实现方式,在第一方面的第六种可能的实现方式中,所述二维材料生长模板为氮化硼。In conjunction with the first aspect, or any one of the first to fifth possible implementations of the first aspect, in a sixth possible implementation of the first aspect, the two-dimensional material growth template is nitrided boron.

结合第一方面或第一方面的第一种至第六种中的任一种可能的实现方式,在第一方面的第七种可能的实现方式中,所述二维材料的原子排列结构与所述二维材料生长模板的原子排列结构相同或相似。In conjunction with the first aspect, or any one of the first to sixth possible implementations of the first aspect, in a seventh possible implementation of the first aspect, the atomic arrangement of the two-dimensional material The atomic arrangement of the two-dimensional material growth template is the same or similar.

在第七种可能的实现方式中,由于二维材料生长模板的原子排列结构与二 维材料的原子排列结构相同或者类似,使该气体中的二维材料的元素以二维材料生长模板作为基底来生长,最终形成作为沟道的二维材料,此种方法使得生长出的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,提高了使用二维材料作为沟道的场效应晶体管的性能。In a seventh possible implementation, due to the atomic arrangement of the two-dimensional material growth template The atomic arrangement of the dimensional material is the same or similar, so that the elements of the two-dimensional material in the gas are grown by using a two-dimensional material growth template as a substrate, and finally a two-dimensional material is formed as a channel. The defects of the material are greatly reduced, so the conductivity of the two-dimensional material is better, and the performance of the field effect transistor using the two-dimensional material as a channel is improved.

结合第一方面的第七种可能的实现方式,在第一方面的第八种可能的实现方式中,所述二维材料的原子排列结构为六角结构或类似六角结构。In conjunction with the seventh possible implementation of the first aspect, in an eighth possible implementation of the first aspect, the atomic arrangement of the two-dimensional material is a hexagonal structure or a hexagonal structure.

结合第一方面或第一方面的第一种至第八种中的任一种可能的实现方式,在第一方面的第九种可能的实现方式中,当所述沟道的材料为石墨烯时,所述沟道为单层石墨烯或者多层石墨烯。With reference to the first aspect or any one of the first to eighth possible implementations of the first aspect, in the ninth possible implementation of the first aspect, when the material of the channel is graphene The channel is a single layer of graphene or a multilayer of graphene.

在第一方面的第九种可能的实现方式中,若所述沟道为单层石墨烯,载流子在单层石墨烯内的传输速度更快,迁移率越大,场效应晶体管的功耗越低;若所述沟道为多层石墨烯,载流子的数目会更多,导电性会更好。In a ninth possible implementation manner of the first aspect, if the channel is a single-layer graphene, the carrier has a faster transmission speed in the single-layer graphene, and the mobility is larger, and the work of the field effect transistor The lower the power consumption; if the channel is a multilayer graphene, the number of carriers will be more and the conductivity will be better.

第二方面,提供了一种场效应晶体管,所述场效应晶体管包括:In a second aspect, a field effect transistor is provided, the field effect transistor comprising:

非金属衬底、源极、漏极、二维材料生长模板、沟道、栅绝缘层和栅极;a non-metal substrate, a source, a drain, a two-dimensional material growth template, a channel, a gate insulating layer, and a gate;

所述源极、所述漏极以及所述二维材料生长模板位于所述非金属衬底上,所述二维材料生长模板位于所述源极和所述漏极之间;The source, the drain, and the two-dimensional material growth template are located on the non-metal substrate, and the two-dimensional material growth template is located between the source and the drain;

所述沟道位于所述二维材料生长模板上,所述沟道的材料为二维材料,且所述沟道分别与所述源极和所述漏极电连接;The channel is located on the two-dimensional material growth template, the material of the channel is a two-dimensional material, and the channel is electrically connected to the source and the drain, respectively;

所述栅绝缘层位于所述沟道之上,所述栅极位于所述栅绝缘层之上。The gate insulating layer is over the channel, and the gate is over the gate insulating layer.

在第二方面中,由于先在非金属衬底上形成源极和漏极,并且在非金属衬底上设置二维材料生长模板,二维材料生长模板的原子排列结构与二维材料的原子排列结构相同或者类似,在使用气体生长二维材料时,源极和漏极的金属会催化气体分解出二维材料的元素,使二维材料的元素以二维材料生长模板作为基底来生长,最终形成作为沟道的二维材料,此种方法使得生长出的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,如此可以直接在制作场效应晶体管的过程中形成作为沟道的二维材料,无需先在金属衬底上生长二维材料以及再将二维材料转移到非金属衬底上,避免了二维材料在转移的过程中以及在溶解金属的过程中而导致二维材料产生缺陷的问题,提高了使用二维材料作为沟道的场效应晶体管的性能。In the second aspect, since the source and the drain are first formed on the non-metal substrate, and the two-dimensional material growth template is disposed on the non-metal substrate, the atomic arrangement of the two-dimensional material growth template and the atom of the two-dimensional material The arrangement structure is the same or similar. When a gas is used to grow a two-dimensional material, the source and drain metals catalyze the gas to decompose the elements of the two-dimensional material, so that the elements of the two-dimensional material grow with the two-dimensional material growth template as a substrate. Finally, a two-dimensional material is formed as a channel. This method greatly reduces the defects of the grown two-dimensional material, so the conductivity of the two-dimensional material is better, so that it can be directly formed as a channel in the process of fabricating the field effect transistor. The two-dimensional material eliminates the need to first grow a two-dimensional material on a metal substrate and then transfer the two-dimensional material to a non-metallic substrate, thereby avoiding the two-dimensional material during the transfer process and during the process of dissolving the metal. The problem of defects in the dimensional material improves the performance of field effect transistors using two-dimensional materials as the channel.

结合第二方面,在第二方面的第一种可能的实现方式中,所述场效应晶体 管还包括第一过渡层和第二过渡层;In conjunction with the second aspect, in a first possible implementation of the second aspect, the field effect crystal The tube further includes a first transition layer and a second transition layer;

所述第一过渡层位于所述源极的表面且通过化学键分别与所述源极和所述沟道电连接;The first transition layer is located on a surface of the source and is electrically connected to the source and the channel by a chemical bond, respectively;

所述第二过渡层位于所述漏极的表面且通过化学键分别与所述漏极和所述沟道电连接。The second transition layer is located on a surface of the drain and is electrically connected to the drain and the channel by a chemical bond, respectively.

在第二方面的第一种可能的实现方式中,因为源极与作为沟道的二维材料通过第一过渡层电连接,且第一过渡层与源极和二维材料之间均是通过化学键连接在一起的,使得源极与沟道之间的接触电阻变小;因为漏极与作为沟道的二维材料通过第二过渡层电连接,且第二过渡层与漏极和二维材料之间均是通过化学键连接在一起的,使得漏极与沟道之间的接触电阻变小,使场效应晶体管的使用性能更加优异。In a first possible implementation of the second aspect, the source is electrically connected to the two-dimensional material as the channel through the first transition layer, and the first transition layer is passed between the source and the two-dimensional material. The chemical bonds are connected together such that the contact resistance between the source and the channel becomes small; since the drain is electrically connected to the two-dimensional material as a channel through the second transition layer, and the second transition layer and the drain and the two-dimensional The materials are connected together by chemical bonds, so that the contact resistance between the drain and the channel becomes small, and the performance of the field effect transistor is further improved.

结合第二方面或第二方面的第一种可能的实现方式,在第二方面的第二种可能的实现方式中,所述场效应晶体管还包括沟道保护层,所述沟道保护层位于所述沟道与所述栅绝缘层之间。In conjunction with the second aspect or the first possible implementation of the second aspect, in a second possible implementation manner of the second aspect, the field effect transistor further includes a channel protection layer, where the channel protection layer is located The channel is between the gate insulating layer.

在第二方面的第二种可能的实现方式中,由于在作为沟道的二维材料与栅绝缘层之间设置一层沟道保护层,可以防止栅绝缘层破坏沟道。In a second possible implementation of the second aspect, since a channel protective layer is provided between the two-dimensional material as the channel and the gate insulating layer, the gate insulating layer can be prevented from damaging the channel.

结合第二方面、第二方面的第一种可能的实现方式或第二方面的第二种可能的实现方式,在第二方面的第三种可能的实现方式中,所述非金属衬底上设有第一凹陷区和第二凹陷区;In conjunction with the second aspect, the first possible implementation of the second aspect, or the second possible implementation of the second aspect, in a third possible implementation of the second aspect, the non-metallic substrate Providing a first recessed area and a second recessed area;

所述二维材料生长模板位于所述第一凹陷区和所述第二凹陷区之间,所述源极位于所述第一凹陷区内,所述漏极位于所述第二凹陷区内。The two-dimensional material growth template is located between the first recessed region and the second recessed region, the source is located in the first recessed region, and the drain is located in the second recessed region.

在第二方面的第三种可能的实现方式中,通过在非金属衬底上形成第一凹陷区和第二凹陷区,将二维材料生长模板设置在第一凹陷区和第二凹陷区之间,并在第一凹陷区内设置源极,第二凹陷区内设置漏极,可以使源极的上表面和漏极的上表面露出,如此,在使用气体形成二维材料时,源极的上表面和漏极的上表面的金属会对二维材料的生长起到催化作用,有利于二维材料在二维材料生长模板上生长,形成沟道;同时,源极上表面的金属会与气体反应生成第一过渡层,并且第一过渡层与源极、沟道通过化学键连接,漏极上表面的金属会与气体反应生成第二过渡层,并且第二过渡层与漏极、沟道通过化学键连接。In a third possible implementation manner of the second aspect, the two-dimensional material growth template is disposed in the first recess region and the second recess region by forming the first recess region and the second recess region on the non-metal substrate And a source is disposed in the first recessed region, and a drain is disposed in the second recessed region to expose the upper surface of the source and the upper surface of the drain. Thus, when a gas is used to form a two-dimensional material, the source The upper surface and the metal on the upper surface of the drain catalyze the growth of the two-dimensional material, which facilitates the growth of the two-dimensional material on the two-dimensional material growth template to form a channel; meanwhile, the metal on the upper surface of the source Reacting with the gas to form a first transition layer, and the first transition layer is connected to the source and the channel by a chemical bond, the metal on the upper surface of the drain reacts with the gas to form a second transition layer, and the second transition layer and the drain and the trench The channels are connected by chemical bonds.

结合第二方面或第二方面的第一种至第三种中的任一种可能的实现方式, 在第二方面的第四种可能的实现方式中,所述二维材料的原子排列结构为六角结构。In combination with the second aspect or any of the possible implementations of any one of the first to third aspects of the second aspect, In a fourth possible implementation of the second aspect, the atomic arrangement of the two-dimensional material is a hexagonal structure.

结合第二方面或第二方面的第一种至第四种中的任一种可能的实现方式,在第二方面的第五种可能的实现方式中,所述二维材料为石墨烯、过渡金属二硫化物或黑磷。In combination with the second aspect or the possible implementation of any one of the first to fourth aspects of the second aspect, in the fifth possible implementation of the second aspect, the two-dimensional material is graphene, transition Metal disulfide or black phosphorus.

结合第二方面或第二方面的第一种至第五种中的任一种可能的实现方式,在第二方面的第六种可能的实现方式中,所述二维材料生长模板为氮化硼。In conjunction with the second aspect or the possible implementation of any one of the first to fifth aspects of the second aspect, in the sixth possible implementation of the second aspect, the two-dimensional material growth template is nitrided boron.

附图说明DRAWINGS

图1至图3是现有技术的场效应晶体管的制作过程的结构示意图;1 to 3 are schematic structural views of a fabrication process of a field effect transistor of the prior art;

图4是本发明实施例一示出的一种场效应晶体管的结构示意图;4 is a schematic structural diagram of a field effect transistor according to Embodiment 1 of the present invention;

图5至是本发明实施例一示出的非金属衬底与二维材料生长模板的结构示意图;5 is a schematic structural view of a non-metal substrate and a two-dimensional material growth template according to Embodiment 1 of the present invention;

图6是本发明实施例一示出的另一种场效应晶体管的结构示意图;6 is a schematic structural diagram of another field effect transistor according to Embodiment 1 of the present invention;

图7是本发明实施例一示出的又一种场效应晶体管的结构示意图;FIG. 7 is a schematic structural diagram of still another field effect transistor according to Embodiment 1 of the present invention; FIG.

图8是本发明实施例一示出的又一种场效应晶体管的结构示意图;FIG. 8 is a schematic structural diagram of still another field effect transistor according to Embodiment 1 of the present invention; FIG.

图9是本发明实施例二示出的一种场效应晶体管的制作方法的流程图;9 is a flow chart showing a method of fabricating a field effect transistor according to Embodiment 2 of the present invention;

图10至图15是本发明实施例二示出的一种场效应晶体管的制作方法的制作过程的结构示意图;10 to FIG. 15 are schematic structural diagrams showing a manufacturing process of a method for fabricating a field effect transistor according to Embodiment 2 of the present invention;

图16是本发明实施例三示出的另一种场效应晶体管的制作方法的流程图;16 is a flowchart of a method for fabricating another field effect transistor according to Embodiment 3 of the present invention;

图17至图20是本发明实施例三示出的一种场效应晶体管的制作方法的制作过程的结构示意图。17 to FIG. 20 are structural diagrams showing a manufacturing process of a method of fabricating a field effect transistor according to Embodiment 3 of the present invention.

其中,among them,

A石墨烯;A graphene;

B第一衬底;B first substrate;

1非金属衬底;2源极;3漏极;4沟道;5栅绝缘层;6栅极;1 non-metal substrate; 2 source; 3 drain; 4 channel; 5 gate insulating layer;

7二维材料生长模板;8第一过渡层;9第二过渡层;7 two-dimensional material growth template; 8 first transition layer; 9 second transition layer;

10第一凹陷区,11第二凹陷区;12沟道保护层。10 first recessed area, 11 second recessed area; 12 channel protective layer.

具体实施方式detailed description

为使本发明的目的、技术方案和优点更加清楚,下面将结合附图对本发明 实施方式作进一步地详细描述。In order to make the objects, technical solutions and advantages of the present invention more clear, the present invention will be described below with reference to the accompanying drawings. The embodiments are described in further detail.

实施例1Example 1

目前较常用的作为场效应晶体管的沟道的二维材料为石墨烯,场效应晶体管的衬底多为非金属衬底,例如二氧化硅衬底,直接在二氧化硅衬底上形成的石墨烯会有很多缺陷,使得作为沟道的石墨烯的导电性较差,进而影响到场效应晶体管的性能,而金属衬底对于石墨烯的生长可以起到催化作用,例如,若使用甲烷气体作为生长石墨烯的碳源,金属衬底会催化甲烷气体分解成活性的碳原子,活性的碳原子在金属衬底的表面更容易生长成石墨烯,因此,目前在使用石墨烯作为沟道时,会先在金属衬底上生长石墨烯,再在溶剂中将金属衬底腐蚀掉,最后将非金属衬底放入溶剂中将石墨烯捞取出来并进行烘干。在腐蚀金属衬底的过程中,溶剂或者未被完全腐蚀的金属会残留在石墨烯上,而且在石墨烯的转移过程中,会使石墨烯发生褶皱甚至破损,使得石墨烯的导电性变差,进而影响场效应晶体管性能。At present, the two-dimensional material used as the channel of the field effect transistor is graphene, and the substrate of the field effect transistor is mostly a non-metal substrate, such as a silicon dioxide substrate, and graphite formed directly on the silicon dioxide substrate. There are many defects in the olefin, which makes the graphene as a channel less conductive, which affects the performance of the field effect transistor. The metal substrate can catalyze the growth of graphene, for example, if methane gas is used as growth. The carbon source of graphene, which catalyzes the decomposition of methane gas into active carbon atoms, and the active carbon atoms are more likely to grow into graphene on the surface of the metal substrate. Therefore, when graphene is used as a channel, Graphene is first grown on a metal substrate, and then the metal substrate is etched away in a solvent. Finally, the non-metal substrate is placed in a solvent to remove the graphene and dry it. In the process of etching the metal substrate, the solvent or the metal which is not completely corroded may remain on the graphene, and during the transfer of the graphene, the graphene may be wrinkled or even damaged, so that the conductivity of the graphene is deteriorated. , which in turn affects the performance of the field effect transistor.

为了解决由于石墨烯的转移以及石墨烯上残留的污染物而导致的石墨烯的导电性能变差,进而影响场效应晶体管的性能的问题,如图4所示,本发明实施例提供了一种场效应晶体管,该场效应晶体管包括:In order to solve the problem that the conductivity of the graphene is deteriorated due to the transfer of the graphene and the residual contaminants on the graphene, thereby affecting the performance of the field effect transistor, as shown in FIG. 4, an embodiment of the present invention provides a Field effect transistor, the field effect transistor includes:

非金属衬底1、源极2、漏极3、二维材料生长模板7、沟道4、栅绝缘层5和栅极6;Non-metal substrate 1, source 2, drain 3, two-dimensional material growth template 7, channel 4, gate insulating layer 5 and gate 6;

源极2、漏极3以及二维材料生长模板7位于非金属衬底1上,二维材料生长模板7位于源极2和漏极3之间,二维材料生长模板7的原子排列结构与二维材料的原子排列结构相同或者类似;The source 2, the drain 3 and the two-dimensional material growth template 7 are located on the non-metal substrate 1, and the two-dimensional material growth template 7 is located between the source 2 and the drain 3, and the atomic arrangement of the two-dimensional material growth template 7 is The atomic arrangement of the two-dimensional material is the same or similar;

沟道4位于二维材料生长模板7上,沟道4的材料为二维材料,且沟道4分别与源极2和漏极3电连接;The channel 4 is located on the two-dimensional material growth template 7, the material of the channel 4 is a two-dimensional material, and the channel 4 is electrically connected to the source 2 and the drain 3, respectively;

栅绝缘层5位于沟道4之上,栅极6位于栅绝缘层5之上。The gate insulating layer 5 is located above the trench 4, and the gate electrode 6 is located above the gate insulating layer 5.

本发明实施例中的场效应晶体管通过先在非金属衬底1上形成源极2和漏极3,并且在非金属衬底1上设置二维材料生长模板7,由于二维材料生长模板7的原子排列结构与二维材料的原子排列结构相同或者类似,在使用气体生长二维材料时,源极2和漏极3的金属会催化气体分解出二维材料的元素,使二维材料的元素以二维材料生长模板7作为基底来生长,最终形成作为沟道4 的二维材料,此种方法使得生长出的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,如此可以直接在制作场效应晶体管的过程中形成作为沟道4的二维材料,无需先在金属衬底上生长二维材料以及再将二维材料转移到非金属衬底1上,避免了二维材料在转移的过程中以及在溶解金属的过程中而导致二维材料产生缺陷的问题,提高了使用二维材料作为沟道4的场效应晶体管的性能。The field effect transistor in the embodiment of the present invention first forms the source 2 and the drain 3 on the non-metal substrate 1, and the two-dimensional material growth template 7 is disposed on the non-metal substrate 1, and the template 7 is grown due to the two-dimensional material. The atomic arrangement structure is the same as or similar to the atomic arrangement structure of the two-dimensional material. When a two-dimensional material is grown using a gas, the metal of the source 2 and the drain 3 catalyze the decomposition of the gas into the element of the two-dimensional material, so that the two-dimensional material The element is grown by using a two-dimensional material growth template 7 as a substrate, and finally formed as a channel 4 The two-dimensional material, the method makes the defects of the grown two-dimensional material greatly reduced, so the conductivity of the two-dimensional material is better, so that the two-dimensional material as the channel 4 can be directly formed in the process of fabricating the field effect transistor. There is no need to first grow a two-dimensional material on a metal substrate and then transfer the two-dimensional material to the non-metal substrate 1, thereby avoiding the two-dimensional material being produced during the transfer process and in the process of dissolving the metal. The problem of defects improves the performance of field effect transistors using two-dimensional materials as the channel 4.

在本发明实施例中,作为沟道4的二维材料可以为石墨烯,也可以为过渡金属二硫化物或者黑磷,其中,过渡金属二硫化物可以包括二硫化钼或二硫化钨等。In the embodiment of the present invention, the two-dimensional material as the channel 4 may be graphene, or may be transition metal disulfide or black phosphorus, and the transition metal disulfide may include molybdenum disulfide or tungsten disulfide.

在本发明实施例中,在使用气体生长二维材料时,源极2和漏极3的金属会催化气体分解出二维材料的元素,使二维材料的元素在二维材料生长模板7上生长,形成沟道4,例如,若选择石墨烯作为沟道4,可以选择甲烷气体作为碳源,在生长石墨烯的过程中,由于先在非金属衬底1上形成了源极2和漏极3,并且源极2和漏极3之间还设有二维材料生长模板7,源极2和漏极3会催化甲烷气体分解成活性的碳原子和氢原子,使活性的碳原子在二维材料生长模板7上生长,最终形成石墨烯。In the embodiment of the present invention, when a two-dimensional material is grown using a gas, the metals of the source 2 and the drain 3 catalyze the gas to decompose the elements of the two-dimensional material, so that the elements of the two-dimensional material are grown on the two-dimensional material growth template 7. Growth, forming the channel 4, for example, if graphene is selected as the channel 4, methane gas can be selected as the carbon source, and in the process of growing graphene, the source 2 and the drain are formed on the non-metal substrate 1 first. a pole 3, and a two-dimensional material growth template 7 is also disposed between the source 2 and the drain 3. The source 2 and the drain 3 catalyze the decomposition of methane gas into active carbon atoms and hydrogen atoms, so that the active carbon atoms are The two-dimensional material grows on the template 7 to form graphene.

在本发明实施例中,由于二维材料生长模板7的原子排列结构与二维材料的原子排列结构相同或者类似,因此,二维材料的元素以二维材料生长模板7生长出的二维材料的缺陷会很少,例如,当沟道4的材料为石墨烯时,由于石墨烯的原子排列结构为六角结构,因此二维材料生长模板7可以为原子排列结构同样为六角结构的氮化硼,也可根据实际情况选择其他原子排列结构同样为六角结构的材料或者类似于六角结构的材料作为二维材料生长模板7。In the embodiment of the present invention, since the atomic arrangement structure of the two-dimensional material growth template 7 is the same as or similar to the atomic arrangement structure of the two-dimensional material, the two-dimensional material is grown by the two-dimensional material growth template 7 There are few defects. For example, when the material of the channel 4 is graphene, since the atomic arrangement of the graphene is a hexagonal structure, the two-dimensional material growth template 7 may be a boron nitride having an atomic arrangement and a hexagonal structure. According to the actual situation, other materials having the same atomic arrangement structure as the hexagonal structure or materials similar to the hexagonal structure may be selected as the two-dimensional material growth template 7.

在本发明实施例中,当沟道4的材料为石墨烯时,可以为单层石墨烯、双层石墨烯或者多层石墨烯。若为单层石墨烯,载流子在单层石墨烯内的传输速度更快,迁移率越大,场效应晶体管的功耗越低;若为双层或者多层石墨烯,载流子的数目会更多,导电性会更好。In the embodiment of the present invention, when the material of the channel 4 is graphene, it may be a single layer of graphene, a double layer of graphene or a multilayer of graphene. In the case of single-layer graphene, the carrier transport speed in the single-layer graphene is faster, the mobility is higher, and the power consumption of the field effect transistor is lower; if it is double-layer or multi-layer graphene, the carrier is The number will be more and the conductivity will be better.

如图4所示,在本发明实施例中,场效应晶体管还包括第一过渡层8和第二过渡层9;As shown in FIG. 4, in the embodiment of the present invention, the field effect transistor further includes a first transition layer 8 and a second transition layer 9;

第一过渡层8位于源极2的表面且通过化学键分别与源极2和沟道4电连接;The first transition layer 8 is located on the surface of the source 2 and is electrically connected to the source 2 and the channel 4 by chemical bonds, respectively;

第二过渡层9位于漏极3的表面且通过化学键分别与漏极3和沟道4电连 接。The second transition layer 9 is located on the surface of the drain 3 and is electrically connected to the drain 3 and the channel 4 by chemical bonds, respectively. Pick up.

在本发明实施例中,因为源极2与作为沟道4的二维材料通过第一过渡层8电连接,且第一过渡层8与源极2和二维材料之间均是通过化学键连接在一起的,使得源极2与沟道4之间的接触电阻变小;因为漏极3与作为沟道4的二维材料通过第二过渡层9电连接,且第二过渡层9与漏极3和二维材料之间均是通过化学键连接在一起的,使得漏极3与沟道4之间的接触电阻变小;而在现有结构中,源极2和漏极3是沉积在作为沟道4的二维材料上的,源极2与沟道4之间仅是单纯的接触,因此源极2与沟道4的接触电阻较大,漏极3与沟道4之间也仅是单纯的接触,因此漏极3与沟道4的接触电阻较大;而场效应晶体管的总电阻是源极2与沟道4之间的接触电阻、沟道4的电阻和漏极3与沟道4之间的接触电阻之和,如果源极2与沟道4之间的接触电阻、漏极3与沟道4之间的接触电阻过大,沟道4的电阻在总电阻中所占的比例很小时,场效应晶体管的栅极6对整个电路电流的调控作用会非常小,会影响场效应晶体管的使用性能;因此,通过设置第一过渡层8和第二过渡层9可以有效降低源极2与沟道4之间的接触电阻以及漏极3与沟道4之间的接触电阻,使场效应晶体管的使用性能更加优异。In the embodiment of the present invention, since the source 2 is electrically connected to the two-dimensional material as the channel 4 through the first transition layer 8, and the first transition layer 8 and the source 2 and the two-dimensional material are connected by chemical bonds. Together, the contact resistance between the source 2 and the channel 4 becomes small; since the drain 3 is electrically connected to the two-dimensional material as the channel 4 through the second transition layer 9, and the second transition layer 9 and the drain The pole 3 and the two-dimensional material are connected together by chemical bonds, so that the contact resistance between the drain 3 and the channel 4 becomes small; in the prior structure, the source 2 and the drain 3 are deposited on As a two-dimensional material of the channel 4, the source 2 and the channel 4 are only in simple contact, so the contact resistance between the source 2 and the channel 4 is large, and the drain 3 and the channel 4 are also It is only a simple contact, so the contact resistance of the drain 3 and the channel 4 is large; and the total resistance of the field effect transistor is the contact resistance between the source 2 and the channel 4, the resistance of the channel 4, and the drain 3 The sum of the contact resistances with the channel 4, if the contact resistance between the source 2 and the channel 4, the contact resistance between the drain 3 and the channel 4 is too large, the channel 4 The ratio of the resistance in the total resistance is very small, and the gate 6 of the field effect transistor has a very small regulation effect on the entire circuit current, which affects the performance of the field effect transistor; therefore, by setting the first transition layer 8 and the The second transition layer 9 can effectively reduce the contact resistance between the source 2 and the channel 4 and the contact resistance between the drain 3 and the channel 4, so that the performance of the field effect transistor is more excellent.

如图5所示,且参加图4,在本发明实施例中,非金属衬底1上设有第一凹陷区10和第二凹陷区11;As shown in FIG. 5, and participating in FIG. 4, in the embodiment of the present invention, the non-metal substrate 1 is provided with a first recessed region 10 and a second recessed region 11;

二维材料生长模板7位于第一凹陷区10和第二凹陷区11之间,源极2位于第一凹陷区10内,漏极3位于第二凹陷区11内。The two-dimensional material growth template 7 is located between the first recessed region 10 and the second recessed region 11, the source 2 is located in the first recessed region 10, and the drain 3 is located in the second recessed region 11.

本发明实施例中,通过在非金属衬底1上形成第一凹陷区10和第二凹陷区11,将二维材料生长模板7设置在第一凹陷区10和第二凹陷区11之间,并在第一凹陷区10内设置源极2,使源极2的上表面露出,第二凹陷区11内设置漏极3,使漏极3的上表面露出,如此,在使用气体形成二维材料时,源极2的上表面和漏极3的上表面的金属可以对二维材料的生长起到催化作用,有利于二维材料在二维材料生长模板7上生长,形成沟道4,同时,源极2上表面的金属在催化二维材料生长的同时会与气体反应生成第一过渡层8,并且第一过渡层8与源极2、沟道4通过化学键连接,漏极3上表面的金属在催化二维材料生长的同时会与气体反应生成第二过渡层9,并且第二过渡层9与漏极3、沟道4通过化学键连接。In the embodiment of the present invention, by forming the first recessed region 10 and the second recessed region 11 on the non-metal substrate 1, the two-dimensional material growth template 7 is disposed between the first recessed region 10 and the second recessed region 11, And the source 2 is disposed in the first recessed region 10 to expose the upper surface of the source 2, and the drain 3 is disposed in the second recessed region 11, so that the upper surface of the drain 3 is exposed. In the material, the upper surface of the source 2 and the metal of the upper surface of the drain 3 can catalyze the growth of the two-dimensional material, which facilitates the growth of the two-dimensional material on the two-dimensional material growth template 7 to form the channel 4. At the same time, the metal on the upper surface of the source 2 reacts with the gas to form the first transition layer 8 while catalyzing the growth of the two-dimensional material, and the first transition layer 8 is connected to the source 2 and the channel 4 by chemical bonds, and the drain 3 is The metal of the surface reacts with the gas to form the second transition layer 9 while catalyzing the growth of the two-dimensional material, and the second transition layer 9 is connected to the drain 3 and the channel 4 by chemical bonds.

下面以二维材料为石墨烯时进行举例说明: The following is an example of a two-dimensional material: graphene:

当选择石墨烯作为沟道4材料时,可选择化学气相沉积法或者等离子增强化学气相沉积法利用气体生长石墨烯,气体可选择甲烷CH4气体,也可以选择乙烯或者乙炔等包含碳元素的气体,也可以选择酒精等含有碳元素的液体,在化学气相沉积或者等离子增强化学气相沉积的过程中,可以通过调整分解温度使酒精会先转变成气体,再利用酒精气体生长石墨烯。若选择甲烷气体作为碳源,氮化硼作为二维材料生长模板,在利用甲烷生长石墨烯时,位于第一凹陷区10内的源极2的上表面和位于第二凹陷区11内的漏极3的上表面露出,源极2上表面的金属和漏极3上表面的金属会催化甲烷气体分解成活性的碳原子,因此源极2上表面以及源极2上表面附近、漏极3上表面以及漏极3上表面附近的碳原子的活性都很高,因此有利于碳原子在氮化硼上生长成石墨烯,形成沟道4。When graphene is selected as the material of channel 4, it may be selected by chemical vapor deposition or plasma enhanced chemical vapor deposition to grow graphene by gas, gas may be selected from methane CH 4 gas, or carbon-containing gas such as ethylene or acetylene may be selected. It is also possible to select a liquid containing carbon such as alcohol. In the process of chemical vapor deposition or plasma enhanced chemical vapor deposition, the alcohol can be first converted into a gas by adjusting the decomposition temperature, and graphene is grown by using an alcohol gas. If methane gas is selected as the carbon source, boron nitride is used as the two-dimensional material growth template, and when graphene is grown by methane, the upper surface of the source 2 located in the first recessed region 10 and the drain located in the second recessed region 11 The upper surface of the pole 3 is exposed, and the metal on the upper surface of the source 2 and the metal on the upper surface of the drain 3 catalyze the decomposition of methane gas into active carbon atoms, so that the upper surface of the source 2 and the upper surface of the source 2, the drain 3 The activity of the carbon atoms in the vicinity of the upper surface and the upper surface of the drain 3 is high, and thus it is advantageous for the carbon atoms to grow into graphene on the boron nitride to form the channel 4.

同时,源极2上表面的金属会与气体中的碳反应生成第一过渡层8,漏极3上表面的金属会与气体中的碳反应生成第二过渡层9,其中,当源极2、漏极3的金属材料不同时,生成的第一过渡层8和第二过渡层9的材料也是不同的,例如:At the same time, the metal on the upper surface of the source 2 reacts with the carbon in the gas to form the first transition layer 8, and the metal on the upper surface of the drain 3 reacts with the carbon in the gas to form the second transition layer 9, wherein when the source 2 When the metal materials of the drain 3 are different, the materials of the first transition layer 8 and the second transition layer 9 are different, for example:

当源极2和漏极3为层状堆叠的金属铜和金属钼,且源极2的上表面和漏极3的上表面露出的为金属钼时,则源极2上表面的第一过渡层8和漏极3上表面的第二过渡层9为金属钼和碳反应生成的MoxC,MoxC与源极2、漏极3以及作为沟道4的石墨烯之间均是通过化学键连接的,使得源极2与作为沟道4的石墨烯之间的接触电阻、漏极3与作为沟道4的石墨烯之间的接触电阻较小;When the source 2 and the drain 3 are layer-stacked metal copper and metal molybdenum, and the upper surface of the source 2 and the upper surface of the drain 3 are exposed of metal molybdenum, the first transition of the upper surface of the source 2 The second transition layer 9 on the upper surface of the layer 8 and the drain 3 is Mo x C formed by the reaction of metal molybdenum and carbon, and the passage between Mo x C and the source 2, the drain 3 and the graphene as the channel 4 are passed. Chemically bonded so that the contact resistance between the source 2 and the graphene as the channel 4, and the contact resistance between the drain 3 and the graphene as the channel 4 are small;

当源极2和漏极3为层状堆叠的金属铜和金属镍,且源极2的上表面和漏极3的上表面露出的为金属镍时,由于在氮化硼上生长石墨烯的过程中温度较高,金属镍在高温的作用下会将气体中的碳融入到源极2和漏极3中,而在生长完作为沟道4的石墨烯后的降温过程中,融入到源极2和漏极3中的碳会从源极2和漏极3的表面析出形成石墨烯,即第一过渡层8和第二过渡层9的材料为石墨烯,但相对于作为沟道4的石墨烯来说,第一过渡层8和第二过渡层9的石墨烯的厚度较厚,因此第一过渡层8和第二过渡层9内的载流子的数目更多,导电性更好,通过第一过渡层8连接源极2与作为沟道4的石墨烯可以有效降低接触电阻,通过第二过渡层9连接漏极3与作为沟道4的石墨烯可以有效降低接触电阻,同时,厚度较厚的石墨烯与源极2、漏极3和作为沟道4的石墨烯也是通过化学键连接的,可以降低源极2与作为沟道4的石墨烯之间、 漏极3与作为沟道4的石墨烯之间的接触电阻。When the source 2 and the drain 3 are layer-stacked metal copper and metallic nickel, and the upper surface of the source 2 and the upper surface of the drain 3 are exposed as metallic nickel, the graphene is grown on the boron nitride. During the process, the temperature is high, and the metal nickel is mixed into the source 2 and the drain 3 by the high temperature, and is integrated into the source after the growth of the graphene as the channel 4 is cooled. The carbon in the pole 2 and the drain 3 is precipitated from the surfaces of the source 2 and the drain 3 to form graphene, that is, the material of the first transition layer 8 and the second transition layer 9 is graphene, but relative to the channel 4 For the graphene, the thickness of the graphene of the first transition layer 8 and the second transition layer 9 is thicker, so the number of carriers in the first transition layer 8 and the second transition layer 9 is larger, and the conductivity is more. Preferably, the connection of the source 2 and the graphene as the channel 4 through the first transition layer 8 can effectively reduce the contact resistance, and the connection of the drain 3 and the graphene as the channel 4 through the second transition layer 9 can effectively reduce the contact resistance. At the same time, the thicker graphene and the source 2, the drain 3 and the graphene as the channel 4 are also connected by chemical bonds. Possible to reduce the channel between the source electrode 2 and 4 as graphene, The contact resistance between the drain 3 and the graphene as the channel 4.

在本发明实施例中,通过化学气相沉积法或者等离子增强化学气相沉积法生长石墨烯的过程中,所需的温度均较高,而在高温下源极2和漏极3的上表面的缺陷和杂质也会减少,可以进一步减小源极2与沟道4之间以及漏极3与沟道4之间的接触电阻。In the embodiment of the present invention, in the process of growing graphene by chemical vapor deposition or plasma enhanced chemical vapor deposition, the required temperatures are high, and the defects of the upper surfaces of the source 2 and the drain 3 are high at high temperatures. The impurities and impurities are also reduced, and the contact resistance between the source 2 and the channel 4 and between the drain 3 and the channel 4 can be further reduced.

其中,源极2和漏极3的金属还可以为金属单质,例如铂、铜或者镍等;也可以为不同金属的合金,例如铜和钨的合金、铜和镍的合金;也可以为不同金属的层状堆叠。The metal of the source 2 and the drain 3 may also be a simple metal such as platinum, copper or nickel; or an alloy of different metals, such as an alloy of copper and tungsten, an alloy of copper and nickel, or different A layered stack of metals.

如图6所示,在本发明实施例中,场效应晶体管还可以包括沟道保护层12,沟道保护层12位于沟道4与栅绝缘层5之间。As shown in FIG. 6 , in the embodiment of the present invention, the field effect transistor may further include a channel protection layer 12 , and the channel protection layer 12 is located between the channel 4 and the gate insulating layer 5 .

因为栅绝缘层5是高介电材料,该高介电材料可以包括氧化铝Al2O3、氢氧化铪HfO2或三氧化二钇Y2O3等,为了防止栅绝缘层5破坏作为沟道4的二维材料,可以在二维材料与栅绝缘层5之间设置一层沟道保护层12,该沟道保护层12也可以同时将第一过渡层8和第二过渡层9覆盖,对第一过渡层8和第二过渡层9也起到保护作用,在本发明实施例中,若作为沟道4的二维材料为石墨烯,则沟道保护层12的材料可以选择氮化硼,因为氮化硼的原子排列结构与石墨烯的原子排列结构相同,即都为六角排列结构,因此作为沟道保护层12的氮化硼可以以石墨烯作为生长模板生长,也可以利用现有技术在其他衬底上生长氮化硼后将氮化硼转移到石墨烯上。Since the gate insulating layer 5 is a high dielectric material, the high dielectric material may include aluminum oxide Al 2 O 3 , hafnium hydroxide HfO 2 or antimony trioxide Y 2 O 3 , etc., in order to prevent the gate insulating layer 5 from being broken as a trench. A two-dimensional material of the track 4 may be provided with a channel protective layer 12 between the two-dimensional material and the gate insulating layer 5, and the channel protective layer 12 may also cover the first transition layer 8 and the second transition layer 9 at the same time. The first transition layer 8 and the second transition layer 9 also have a protective effect. In the embodiment of the present invention, if the two-dimensional material as the channel 4 is graphene, the material of the channel protective layer 12 may be selected from nitrogen. Boron, since the atomic arrangement structure of boron nitride is the same as that of graphene, that is, it is a hexagonal arrangement structure, boron nitride as the channel protective layer 12 can be grown using graphene as a growth template, and can also be utilized. The prior art transfers boron nitride to graphene after growing boron nitride on other substrates.

在本发明实施例中,场效应晶体管也可以设计成如图7所示的结构,即:In the embodiment of the present invention, the field effect transistor can also be designed as the structure shown in FIG. 7, that is:

在非金属衬底1上形成有第一衬底B,第一衬底B的原子排列结构与二维材料的原子排列结构相同或者类似;A first substrate B is formed on the non-metal substrate 1, and the atomic arrangement structure of the first substrate B is the same as or similar to the atomic arrangement structure of the two-dimensional material;

源极2和漏极3位于第一衬底B上,在源极2和漏极3之间的第一衬底B作为二维材料生长模板7;The source 2 and the drain 3 are located on the first substrate B, and the first substrate B between the source 2 and the drain 3 is used as a two-dimensional material growth template 7;

沟道4位于二维材料生长模板7上,沟道4的材料为二维材料;The channel 4 is located on the two-dimensional material growth template 7, and the material of the channel 4 is a two-dimensional material;

第一过渡层8位于源极2的表面,且通过化学键与源极2和沟道4电连接,第二过渡层9位于漏极3的表面,且通过化学键与漏极3和沟道4电连接;The first transition layer 8 is located on the surface of the source 2, and is electrically connected to the source 2 and the channel 4 by a chemical bond, the second transition layer 9 is located on the surface of the drain 3, and is electrically connected to the drain 3 and the channel 4 by chemical bonds. connection;

沟道保护层12位于沟道4之上,同时也可以将第一过渡层8和第二过渡层9覆盖;The channel protection layer 12 is located above the channel 4, and the first transition layer 8 and the second transition layer 9 may also be covered;

栅绝缘层5位于沟道保护层12之上,栅极6位于栅绝缘层5之上。The gate insulating layer 5 is located above the channel protective layer 12, and the gate electrode 6 is located above the gate insulating layer 5.

在本发明实施例中,场效应晶体管也可以设计成如图8所示的结构:即: In the embodiment of the present invention, the field effect transistor can also be designed as shown in FIG. 8: namely:

在非金属衬底1上形成有源极2和漏极3,在源极2和漏极3之间形成有二维材料生长模板7;Forming a source 2 and a drain 3 on the non-metal substrate 1, and forming a two-dimensional material growth template 7 between the source 2 and the drain 3;

沟道4位于二维材料生长模板7上,沟道4的材料为二维材料;The channel 4 is located on the two-dimensional material growth template 7, and the material of the channel 4 is a two-dimensional material;

第一过渡层8位于源极2的表面,且通过化学键与源极2和沟道4电连接,第二过渡层9位于漏极3的表面,且通过化学键与漏极3和沟道4电连接;The first transition layer 8 is located on the surface of the source 2, and is electrically connected to the source 2 and the channel 4 by a chemical bond, the second transition layer 9 is located on the surface of the drain 3, and is electrically connected to the drain 3 and the channel 4 by chemical bonds. connection;

沟道保护层12位于沟道4的之上,同时也可以将第一过渡层8和第二过渡层9覆盖;The channel protection layer 12 is located above the channel 4, and the first transition layer 8 and the second transition layer 9 may also be covered;

栅绝缘层5位于沟道保护层12之上,栅极6位于栅绝缘层5之上。The gate insulating layer 5 is located above the channel protective layer 12, and the gate electrode 6 is located above the gate insulating layer 5.

本发明实施例中的场效应晶体管通过先在非金属衬底1上形成源极2和漏极3,并且在非金属衬底1上设置二维材料生长模板7,由于二维材料生长模板7的原子排列结构与二维材料的原子排列结构相同或者类似,在使用气体生长二维材料时,源极2和漏极3的金属会催化气体分解出二维材料的元素,使二维材料的元素以二维材料生长模板7作为基底来生长,最终形成作为沟道4的二维材料,此种方法使得生长出的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,如此可以直接在制作场效应晶体管的过程中形成作为沟道4的二维材料,无需先在金属衬底上生长二维材料以及再将二维材料转移到非金属衬底1上,避免了二维材料在转移的过程中以及在溶解金属的过程中而导致二维材料产生缺陷的问题,提高了使用二维材料作为沟道4的场效应晶体管的性能;同时,在形成作为沟道的二维材料时,在源极2之上还会形成第一过渡层8,第一过渡层8与源极2和作为沟道4的二维材料之间是通过化学键连接的,在漏极3之上还会形成第二过渡层9,第二过渡层9与漏极3和作为沟道4的二维材料之间是通过化学键连接的,第一过渡层8可以有效降低源极2与沟道4之间的接触电阻,第二过渡层9可以有效降低漏极3与沟道4之间的接触电阻,提高了使用二维材料作为沟道4的场效应晶体管的使用性能。The field effect transistor in the embodiment of the present invention first forms the source 2 and the drain 3 on the non-metal substrate 1, and the two-dimensional material growth template 7 is disposed on the non-metal substrate 1, and the template 7 is grown due to the two-dimensional material. The atomic arrangement structure is the same as or similar to the atomic arrangement structure of the two-dimensional material. When a two-dimensional material is grown using a gas, the metal of the source 2 and the drain 3 catalyze the decomposition of the gas into the element of the two-dimensional material, so that the two-dimensional material The element is grown by using the two-dimensional material growth template 7 as a substrate, and finally forms a two-dimensional material as the channel 4. This method greatly reduces the defects of the grown two-dimensional material, so the conductivity of the two-dimensional material is better. The two-dimensional material as the channel 4 can be formed directly in the process of fabricating the field effect transistor, without first growing the two-dimensional material on the metal substrate and transferring the two-dimensional material onto the non-metal substrate 1, avoiding the two-dimensional The problem that the material causes defects in the two-dimensional material during the transfer process and in the process of dissolving the metal improves the performance of the field effect transistor using the two-dimensional material as the channel 4. Meanwhile, when a two-dimensional material as a channel is formed, a first transition layer 8 is formed over the source 2, and a pass between the first transition layer 8 and the source 2 and the two-dimensional material as the channel 4 is passed. Chemically bonded, a second transition layer 9 is formed over the drain 3, and the second transition layer 9 and the drain 3 and the two-dimensional material as the channel 4 are connected by a chemical bond, the first transition layer 8 The contact resistance between the source 2 and the channel 4 can be effectively reduced, and the second transition layer 9 can effectively reduce the contact resistance between the drain 3 and the channel 4, thereby improving the field effect of using the two-dimensional material as the channel 4. The performance of the transistor.

实施例2Example 2

如图9所示,本发明实施例提供了一种场效应晶体管的制作方法,该制作方法包括:As shown in FIG. 9, an embodiment of the present invention provides a method for fabricating a field effect transistor, the method comprising:

步骤101:在非金属衬底1上设置二维材料生长模板7、第一凹陷区10和第二凹陷区11,二维材料生长模板7位于第一凹陷区10和第二凹陷区11之间, 二维材料生长模板7的原子排列结构与二维材料的原子排列结构相同或者类似;Step 101: A two-dimensional material growth template 7, a first recessed region 10 and a second recessed region 11 are disposed on the non-metal substrate 1, and the two-dimensional material growth template 7 is located between the first recessed region 10 and the second recessed region 11. , The atomic arrangement structure of the two-dimensional material growth template 7 is the same as or similar to the atomic arrangement structure of the two-dimensional material;

如图10所示,可以先在非金属衬底1上形成一层二维材料生长模板7,其中,二维材料生长模板7可以为先在金属衬底上形成后,再转移到非金属衬底1上,例如,厚度可以为10nm至11nm之间,也可以根据实际情况进行合理设置。As shown in FIG. 10, a two-dimensional material growth template 7 may be formed on the non-metal substrate 1, wherein the two-dimensional material growth template 7 may be formed on the metal substrate before being transferred to the non-metal liner. On the bottom 1, for example, the thickness may be between 10 nm and 11 nm, and it may be appropriately set according to actual conditions.

如图11所示,再通过电子束曝光或者紫外线曝光工艺在非金属衬底1上刻蚀出第一凹陷区10和第二凹陷区11。As shown in FIG. 11, the first recessed region 10 and the second recessed region 11 are etched on the non-metal substrate 1 by electron beam exposure or ultraviolet exposure.

在本发明实施例中,非金属衬底1的材料可以为硅、石英、SOI(Silicon-On-Insulator,绝缘衬底上的硅)或者碳化硅等。In the embodiment of the present invention, the material of the non-metal substrate 1 may be silicon, quartz, SOI (Silicon-On-Insulator, silicon on an insulating substrate) or silicon carbide.

在本发明实施例中,刻蚀第一凹陷区10和第二凹陷区11的方法可根据实际情况进行选择,例如若非金属衬底1的材料为硅,刻蚀方法可选择反应离子刻蚀,为了防止刻蚀过程中二维材料生长模板7受到破坏,可以在刻蚀之前在二维材料生长模板7上涂覆一层抗刻蚀的保护胶,例如可以为光刻胶。In the embodiment of the present invention, the method of etching the first recessed region 10 and the second recessed region 11 may be selected according to actual conditions. For example, if the material of the non-metal substrate 1 is silicon, the etching method may select reactive ion etching. In order to prevent the two-dimensional material growth template 7 from being damaged during the etching process, an anti-etching protective glue may be applied on the two-dimensional material growth template 7 before the etching, for example, may be a photoresist.

在本发明实施例中,不对形成第一凹陷区10、第二凹陷区11和二维材料生长模板7的顺序进行限制,也可以先在非金属衬底1上形成第一凹陷区10和第二凹陷区11,再在第一凹陷区10和第二凹陷区11之间形成二维材料生长模板7。In the embodiment of the present invention, the order of forming the first recessed region 10, the second recessed region 11, and the two-dimensional material growth template 7 is not limited, and the first recessed region 10 and the first may be formed on the non-metal substrate 1 first. The second recessed region 11 further forms a two-dimensional material growth template 7 between the first recessed region 10 and the second recessed region 11.

步骤102:如图12所示,在第一凹陷区10内形成源极2,在第二凹陷区11内形成漏极3;Step 102: as shown in FIG. 12, forming a source 2 in the first recessed region 10, forming a drain 3 in the second recessed region 11;

在本发明实施例中,源极2和漏极3的材料可以为金属单质,例如铜、镍或者铂;也可以为铜和钼的合金、或者铜和镍的合金;也可以为铜和钼的层状堆叠,其中,铜在下层,钼在上层,铜的厚度为10nm,钼的厚度为90nm,也可以为铜和钨的层状堆叠,每层金属的厚度也可根据实际情况进行设计,并不限定于本实施例。In the embodiment of the present invention, the material of the source 2 and the drain 3 may be a simple metal, such as copper, nickel or platinum; or an alloy of copper and molybdenum, or an alloy of copper and nickel; or copper and molybdenum. Layered stack, in which copper is in the lower layer, molybdenum is in the upper layer, copper has a thickness of 10 nm, and molybdenum has a thickness of 90 nm. It can also be a layered stack of copper and tungsten. The thickness of each layer of metal can also be designed according to actual conditions. It is not limited to this embodiment.

在本发明实施例中,相对现有的沟道4的材料为二维材料的场效应晶体管的制作方法来说,是先在非金属衬底1上形成源极2和漏极3,而现有的是先将二维材料转移到非金属衬底1上,再在二维材料上形成源极2和漏极3,例如,将制作好的石墨烯转移到非金属衬底1上,再在非金属衬底1上形成源极2和漏极3,因此在形成源极2和漏极3时,需要考虑到形成源极2和漏极3时所使用的方法是否会对石墨烯产生破坏,例如此时不能使用磁控溅射的方法 形成源极2和漏极3,因为磁控溅射过程中形成源极2和漏极3的金属原子的能量较高,会对石墨烯造成伤害,使源极2、漏极3与石墨烯相接触的位置质量变差,导致接触电阻增加;同时也不能使用电镀的方法形成源极2和漏极3,因为电镀的过程中非金属衬底1和石墨烯也会被泡在化学溶液中,对石墨烯造成伤害。而本发明实施例是先制作源极2和漏极3,因此形成源极2和漏极3的方法不会受到限制,例如可以通过电子束蒸发的方法、热蒸发的方法、磁控溅射的方法或者电镀的方法。In the embodiment of the present invention, the method for fabricating the field effect transistor in which the material of the channel 4 is a two-dimensional material is to form the source 2 and the drain 3 on the non-metal substrate 1 first. Some first transfer the two-dimensional material to the non-metal substrate 1, and then form the source 2 and the drain 3 on the two-dimensional material. For example, transfer the fabricated graphene to the non-metal substrate 1, and then The source 2 and the drain 3 are formed on the metal substrate 1, and therefore, when forming the source 2 and the drain 3, it is necessary to consider whether the method used when forming the source 2 and the drain 3 may cause damage to the graphene. For example, the method of magnetron sputtering cannot be used at this time. Forming source 2 and drain 3, because the energy of metal atoms forming source 2 and drain 3 during magnetron sputtering is higher, causing damage to graphene, causing source 2, drain 3 and graphene The quality of the contact position deteriorates, resulting in an increase in contact resistance; at the same time, the source 2 and the drain 3 cannot be formed by electroplating because the non-metal substrate 1 and graphene are also bubbled in the chemical solution during electroplating. , causing damage to graphene. In the embodiment of the present invention, the source 2 and the drain 3 are formed first, and thus the method of forming the source 2 and the drain 3 is not limited, for example, a method of electron beam evaporation, a method of thermal evaporation, and magnetron sputtering. Method or method of plating.

步骤103:如图13所示,使用气体在二维材料生长模板7上生长二维材料,并将二维材料作为沟道4,同时在源极2表面生长第一过渡层8以及在漏极3表面生长第二过渡层9,第一过渡层8通过化学键分别与源极2和沟道4电连接,第二过渡层9通过化学键分别与漏极3和沟道4电连接;Step 103: As shown in FIG. 13, a two-dimensional material is grown on the two-dimensional material growth template 7 using a gas, and a two-dimensional material is used as the channel 4, while the first transition layer 8 and the drain are grown on the surface of the source 2. 3 surface growth of the second transition layer 9, the first transition layer 8 is electrically connected to the source 2 and the channel 4 respectively by chemical bonds, and the second transition layer 9 is electrically connected to the drain 3 and the channel 4 by chemical bonds, respectively;

在本发明实施例中,气体包括组成二维材料的元素,源极2和漏极3用于在生长二维材料的过程中催化气体分解出二维材料的元素,使二维材料的元素在二维材料生长模板7上生长二维材料。In an embodiment of the invention, the gas comprises an element constituting a two-dimensional material, and the source 2 and the drain 3 are used for catalyzing the decomposition of the element of the two-dimensional material in the process of growing the two-dimensional material, so that the element of the two-dimensional material is A two-dimensional material is grown on the two-dimensional material growth template 7.

在本发明实施例中,可通过化学气相沉积的方法或者等离子增强化学气相沉积的方法利用气体在二维材料生长模板7上生长二维材料。In the embodiment of the present invention, the two-dimensional material may be grown on the two-dimensional material growth template 7 by a chemical vapor deposition method or a plasma enhanced chemical vapor deposition method.

在本发明实施例中,二维材料可以为石墨烯,也可以为过渡金属二硫化物或者黑磷,其中,过渡金属二硫化物可以包括二硫化钼或二硫化钨等。当二维材料为石墨烯时,气体可选择甲烷CH4气体,也可以选择乙烯或者乙炔等包含碳元素的气体,也可以选择酒精等含有碳元素的液体,在化学气相沉积或者等离子增强化学气相沉积的过程中,可以先使酒精会先转变成气体,再利用气体生长石墨烯。当二维材料为二硫化钼时,可以选择钼的粉末和含有硫元素的气体,在化学气相沉积或者等离子增强化学气相沉积的过程中,钼的粉末会变成气体,分解成钼原子,含硫的气体会分解出硫原子,硫原子和钼原子反应生成二硫化钼。In the embodiment of the present invention, the two-dimensional material may be graphene, or may be transition metal disulfide or black phosphorus, wherein the transition metal disulfide may include molybdenum disulfide or tungsten disulfide. When the two-dimensional material is graphene, the gas may be selected from methane CH 4 gas, or a gas containing carbon such as ethylene or acetylene, or a liquid containing carbon such as alcohol, in chemical vapor deposition or plasma enhanced chemical vapor phase. During the deposition process, the alcohol can be first converted into a gas, and then the gas is used to grow graphene. When the two-dimensional material is molybdenum disulfide, the powder of molybdenum and the gas containing sulfur may be selected. In the process of chemical vapor deposition or plasma enhanced chemical vapor deposition, the powder of molybdenum becomes gas and decomposes into molybdenum atoms, including The sulfur gas decomposes out the sulfur atom, and the sulfur atom reacts with the molybdenum atom to form molybdenum disulfide.

在本发明实施例中,由于源极2和漏极3的上表面露出,源极2的上表面和漏极3的上表面的金属会对作为沟道4的二维材料的生长起到催化作用,有利于二维材料在二维材料生长模板7上生长。例如,当二维材料为石墨烯时,选择甲烷CH4气体作为碳源生长石墨烯,源极2和漏极3上表面的金属会催化甲烷气体分解成活性的碳原子,因此源极2上表面以及源极2上表面附近、漏极3上表面以及漏极3上表面附近的碳原子的活性都很高,有利于石墨烯在二 维材料生长模板7上生长,形成沟道4。In the embodiment of the present invention, since the upper surfaces of the source 2 and the drain 3 are exposed, the upper surface of the source 2 and the metal of the upper surface of the drain 3 catalyze the growth of the two-dimensional material as the channel 4. The effect is beneficial to the growth of the two-dimensional material on the two-dimensional material growth template 7. For example, when the two-dimensional material is graphene, the methane CH 4 gas is selected as the carbon source to grow graphene, and the metal on the upper surface of the source 2 and the drain 3 catalyzes the decomposition of the methane gas into active carbon atoms, so the source 2 is The carbon atoms in the vicinity of the surface and the upper surface of the source 2, the upper surface of the drain 3, and the upper surface of the drain 3 are highly active, which facilitates the growth of graphene on the two-dimensional material growth template 7 to form the channel 4.

在本发明实施例中,二维材料生长模板7的材料可根据二维材料的材料而选择,例如,二维材料为石墨烯时,由于石墨烯的原子排列结构为六角结构,则可以选择原子排列结构同样为六角结构的氮化硼作为二维材料生长模板7。In the embodiment of the present invention, the material of the two-dimensional material growth template 7 can be selected according to the material of the two-dimensional material. For example, when the two-dimensional material is graphene, since the atomic arrangement structure of the graphene is a hexagonal structure, the atom can be selected. The arrangement structure is also a hexagonal structure of boron nitride as a two-dimensional material growth template 7.

在本发明实施例中,由于二维材料生长模板7的原子排列结构与二维材料的原子排列结构相同或者类似,在使用气体生长二维材料时,二维材料会以二维材料生长模板7作为基底来生长,使得生长出的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,如此可以直接在制作场效应晶体管的过程中形成作为沟道4的二维材料,无需先在金属衬底上生长二维材料以及再将二维材料转移到非金属衬底1上,避免了二维材料在转移的过程中以及在溶解金属的过程中而导致二维材料产生缺陷的问题,提高了使用二维材料作为沟道4的场效应晶体管的性能。In the embodiment of the present invention, since the atomic arrangement structure of the two-dimensional material growth template 7 is the same as or similar to the atomic arrangement structure of the two-dimensional material, when the gas is used to grow the two-dimensional material, the two-dimensional material grows the template by using the two-dimensional material. As a substrate to grow, the defects of the grown two-dimensional material are greatly reduced, so that the conductivity of the two-dimensional material is better, so that the two-dimensional material as the channel 4 can be formed directly in the process of fabricating the field effect transistor without first The growth of the two-dimensional material on the metal substrate and the transfer of the two-dimensional material to the non-metal substrate 1 avoids the problem that the two-dimensional material causes defects in the two-dimensional material during the transfer process and in the process of dissolving the metal. The performance of a field effect transistor using a two-dimensional material as the channel 4 is improved.

在本发明实施例中,如图13所示,在二维材料生长模板7上生长作为沟道4的二维材料的同时使用气体在源极2表面生长第一过渡层8以及在漏极3表面生长第二过渡层9,第一过渡层8通过化学键分别与源极2和沟道4电连接,第二过渡层9通过化学键分别与漏极3和沟道4电连接。In the embodiment of the present invention, as shown in FIG. 13, a two-dimensional material as the channel 4 is grown on the two-dimensional material growth template 7, while a first transition layer 8 is grown on the surface of the source 2 using a gas, and at the drain 3 A second transition layer 9 is grown on the surface. The first transition layer 8 is electrically connected to the source 2 and the channel 4 by chemical bonds, respectively, and the second transition layer 9 is electrically connected to the drain 3 and the channel 4 by chemical bonds, respectively.

例如:当二维材料为石墨烯,源极2和漏极3为层状堆叠的金属铜和金属钼时,金属钼会和碳反应生成MoxC,此时第一过渡层8和第二过渡层9的材料为MoxC,MoxC与源极2、漏极3以及作为沟道4的石墨烯之间均是通过化学键连接的;当二维材料为石墨烯,源极2和漏极3为层状堆叠的金属铜和金属镍时,金属镍在高温的作用下会将气体中的碳融入到源极2和漏极3中,而在生长完石墨烯后的降温过程中,融入到源极2和漏极3中的碳会从源极2和漏极3的表面析出形成石墨烯,即第一过渡层8和第二过渡层9的材料为石墨烯,但相对于作为沟道4的石墨烯来说,第一过渡层8和第二过渡层9的石墨烯的厚度较厚,因此第一过渡层8和第二过渡层9内的载流子的数目更多,导电性更好,同时,厚度较厚的石墨烯与源极2、漏极3和作为沟道4的石墨烯也是通过化学键连接的。For example, when the two-dimensional material is graphene, the source 2 and the drain 3 are layered stacked metal copper and metal molybdenum, the metal molybdenum reacts with carbon to form Mo x C, at this time the first transition layer 8 and the second The material of the transition layer 9 is Mo x C, and the Mo x C is connected to the source 2, the drain 3, and the graphene as the channel 4 by chemical bonds; when the two-dimensional material is graphene, the source 2 and When the drain 3 is a layered metal copper and a metal nickel, the metal nickel is mixed with the carbon in the gas into the source 2 and the drain 3 under the action of high temperature, and is cooled during the growth of the graphene. The carbon incorporated into the source 2 and the drain 3 is precipitated from the surfaces of the source 2 and the drain 3 to form graphene, that is, the material of the first transition layer 8 and the second transition layer 9 is graphene, but relative to As the graphene of the channel 4, the thickness of the graphene of the first transition layer 8 and the second transition layer 9 is thicker, and thus the number of carriers in the first transition layer 8 and the second transition layer 9 is more The conductivity is better, and at the same time, the thicker graphene and the source 2, the drain 3 and the graphene as the channel 4 are also connected by chemical bonds.

在本发明实施例中,因为源极2与作为沟道4的二维材料通过第一过渡层8电连接,且第一过渡层8与源极2和二维材料之间均是通过化学键连接在一起的,漏极3与作为沟道4的二维材料通过第二过渡层9电连接,且第二过渡层9与漏极3和二维材料之间均是通过化学键连接在一起的,所以第一过渡层 8和第二过渡层9可以有效降低源极2与沟道4之间的接触电阻以及漏极3与沟道4之间的接触电阻,使场效应晶体管的使用性能更加优异。In the embodiment of the present invention, since the source 2 is electrically connected to the two-dimensional material as the channel 4 through the first transition layer 8, and the first transition layer 8 and the source 2 and the two-dimensional material are connected by chemical bonds. Together, the drain 3 is electrically connected to the two-dimensional material as the channel 4 through the second transition layer 9, and the second transition layer 9 and the drain 3 and the two-dimensional material are connected by chemical bonds. So the first transition layer 8 and the second transition layer 9 can effectively reduce the contact resistance between the source 2 and the channel 4 and the contact resistance between the drain 3 and the channel 4, making the field effect transistor more excellent in use performance.

步骤104:如图14所示,在沟道4上形成沟道保护层12。Step 104: As shown in FIG. 14, a channel protective layer 12 is formed on the trench 4.

在本发明实施例中,沟道保护层12的材料可以选择氮化硼,若作为沟道4的二维材料为石墨烯,则因为氮化硼的原子排列结构与石墨烯的原子排列结构相同,即都为六角结构,因此作为沟道保护层12的氮化硼可以以石墨烯作为生长模板生长,可通过化学气相沉积的方法或者等离子增强化学气相沉积的方法形成,也可以利用现有技术在其他衬底上生长氮化硼后将氮化硼转移到石墨烯上。In the embodiment of the present invention, the material of the channel protection layer 12 may be selected from boron nitride. If the two-dimensional material of the channel 4 is graphene, the atomic arrangement structure of the boron nitride is the same as that of the graphene. That is, all of them are hexagonal structures, so boron nitride as the channel protective layer 12 can be grown using graphene as a growth template, can be formed by chemical vapor deposition or plasma enhanced chemical vapor deposition, and can also utilize prior art. The boron nitride is transferred to the graphene after the boron nitride is grown on the other substrate.

在本发明实施例中,如图14所示,沟道保护层12也可以同时将第一过渡层8和第二过渡层9覆盖,同时起到保护第一过渡层8和第二过渡层9的作用。In the embodiment of the present invention, as shown in FIG. 14, the channel protective layer 12 can also cover the first transition layer 8 and the second transition layer 9 at the same time, while protecting the first transition layer 8 and the second transition layer 9 The role.

步骤105:如图15所示,在沟道保护层12上形成栅绝缘层5。Step 105: As shown in FIG. 15, a gate insulating layer 5 is formed on the channel protective layer 12.

在本发明实施例中,栅绝缘层5可通过原子层沉积的方法形成,栅绝缘层5的材料可以包括氧化铝Al2O3、氢氧化铪HfO2或三氧化二钇Y2O3In the embodiment of the present invention, the gate insulating layer 5 may be formed by a method of atomic layer deposition, and the material of the gate insulating layer 5 may include aluminum oxide Al 2 O 3 , barium hydroxide HfO 2 or antimony trioxide Y 2 O 3 .

步骤106:如图6所示,在栅绝缘层5上形成栅极6。Step 106: As shown in FIG. 6, a gate electrode 6 is formed on the gate insulating layer 5.

在本发明实施例中,栅极6的材料可以为金、钯或者钨,也可以为其他金属材料,可根据实际情况进行选择。In the embodiment of the present invention, the material of the gate electrode 6 may be gold, palladium or tungsten, or may be other metal materials, and may be selected according to actual conditions.

本发明实施例中的场效应晶体管通过先在非金属衬底1上形成源极2和漏极3,并且在非金属衬底1上设置二维材料生长模板7,由于二维材料生长模板7的原子排列结构与二维材料的原子排列结构相同或者类似,在使用气体生长二维材料时,源极2和漏极3的金属会催化气体分解出二维材料的元素,使二维材料的元素以二维材料生长模板7作为基底来生长,最终形成作为沟道4的二维材料,此种方法使得生长出的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,如此可以直接在制作场效应晶体管的过程中形成作为沟道4的二维材料,无需先在金属衬底上生长二维材料以及再将二维材料转移到非金属衬底1上,避免了二维材料在转移的过程中以及在溶解金属的过程中而导致二维材料产生缺陷的问题,提高了使用二维材料作为沟道4的场效应晶体管的性能;同时,在形成二维材料时,在源极2之上还会形成第一过渡层8,第一过渡层8与源极2和作为沟道4的二维材料之间是通过化学键连接的,在漏极3之上还会形成第二过渡层9,第二过渡层9与漏极3和作为沟道4的二维材料之间是通过化学键连接的,第一过渡层8可以有效降低源极2与沟道4之 间的接触电阻,第二过渡层9可以有效降低漏极3与沟道4之间的接触电阻,提高了使用二维材料作为沟道4的场效应晶体管的使用性能。The field effect transistor in the embodiment of the present invention first forms the source 2 and the drain 3 on the non-metal substrate 1, and the two-dimensional material growth template 7 is disposed on the non-metal substrate 1, and the template 7 is grown due to the two-dimensional material. The atomic arrangement structure is the same as or similar to the atomic arrangement structure of the two-dimensional material. When a two-dimensional material is grown using a gas, the metal of the source 2 and the drain 3 catalyze the decomposition of the gas into the element of the two-dimensional material, so that the two-dimensional material The element is grown by using the two-dimensional material growth template 7 as a substrate, and finally forms a two-dimensional material as the channel 4. This method greatly reduces the defects of the grown two-dimensional material, so the conductivity of the two-dimensional material is better. The two-dimensional material as the channel 4 can be formed directly in the process of fabricating the field effect transistor, without first growing the two-dimensional material on the metal substrate and transferring the two-dimensional material onto the non-metal substrate 1, avoiding the two-dimensional The problem that the material causes defects in the two-dimensional material during the transfer process and in the process of dissolving the metal improves the performance of the field effect transistor using the two-dimensional material as the channel 4. Meanwhile, when a two-dimensional material is formed, a first transition layer 8 is further formed on the source electrode 2, and the first transition layer 8 and the source electrode 2 and the two-dimensional material as the channel 4 are connected by a chemical bond. A second transition layer 9 is also formed over the drain 3, and the second transition layer 9 and the drain 3 and the two-dimensional material as the channel 4 are connected by chemical bonds, and the first transition layer 8 can effectively reduce the source. Pole 2 and channel 4 The contact resistance between the second transition layer 9 can effectively reduce the contact resistance between the drain 3 and the channel 4, improving the performance of the field effect transistor using the two-dimensional material as the channel 4.

实施例3Example 3

如图16所示,本发明实施例提供了一种场效应晶体管的制作方法,该制作方法包括:As shown in FIG. 16, an embodiment of the present invention provides a method for fabricating a field effect transistor, the method comprising:

步骤201:如图17所示,在非金属衬底上1形成第一衬底B,第一衬底B的原子排列结构与二维材料的原子排列结构相同或者类似,在第一衬底B上形成源极2和漏极3,并将第一衬底B位于源极2和漏极3之间的部分作为二维材料生长模板7;Step 201: As shown in FIG. 17, a first substrate B is formed on the non-metal substrate, and the atomic arrangement structure of the first substrate B is the same as or similar to the atomic arrangement structure of the two-dimensional material, on the first substrate B. a source 2 and a drain 3 are formed thereon, and a portion of the first substrate B between the source 2 and the drain 3 is grown as a two-dimensional material growth template 7;

在本发明实施例中,不对形成源极2、漏极3和第一衬底B的顺序进行限制,也可以先在非金属衬底1上形成源极2和漏极3后,再在源极2、漏极3和位于源极2与漏极3之间的非金属衬底1上形成第一衬底B,并刻蚀掉位于源极2和漏极3表面上的第一衬底B,将源极2和漏极3之间的第一衬底B作为二维材料生长模板7。In the embodiment of the present invention, the order of forming the source 2, the drain 3, and the first substrate B is not limited, and the source 2 and the drain 3 may be formed on the non-metal substrate 1 first, and then at the source. a first substrate B is formed on the non-metal substrate 1 between the source 2 and the drain 3, and the first substrate on the surfaces of the source 2 and the drain 3 is etched away. B. The first substrate B between the source 2 and the drain 3 is used as a two-dimensional material growth template 7.

步骤202:如图18所示,使用气体在二维材料生长模板7上生长二维材料,并将二维材料作为沟道4,同时使用气体在源极2表面生长第一过渡层8以及在漏极3表面生长第二过渡层9,第一过渡层8通过化学键分别与源极2和二维材料电连接,第二过渡层9通过化学键分别与漏极3和二维材料电连接;Step 202: As shown in FIG. 18, a two-dimensional material is grown on the two-dimensional material growth template 7 using a gas, and the two-dimensional material is used as the channel 4, while the first transition layer 8 is grown on the surface of the source 2 using a gas and a second transition layer 9 is grown on the surface of the drain 3, and the first transition layer 8 is electrically connected to the source 2 and the two-dimensional material respectively by chemical bonds, and the second transition layer 9 is electrically connected to the drain 3 and the two-dimensional material through chemical bonds, respectively;

在本发明实施例中,气体包括组成二维材料的元素,使用气体在二维材料生长模板7上生长二维材料时,源极2和漏极3的金属会催化气体分解出二维材料的元素,使二维材料的元素在二维材料生长模板7上生长,形成沟道4,同时,由于二维材料生长模板7的原子排列结构与作为沟道4的二维材料的原子排列结构相同或者类似,二维材料的元素以二维材料生长模板7作为基底来生长得到的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,如此利用此种方法可以直接在制作场效应晶体管的过程中形成作为沟道4的二维材料,无需先在金属衬底上生长二维材料以及再将二维材料转移到非金属衬底1上,避免了二维材料在转移的过程中以及在溶解金属的过程中而导致二维材料产生缺陷的问题,提高了使用二维材料作为沟道4的场效应晶体管的性能。In the embodiment of the present invention, the gas includes an element constituting a two-dimensional material, and when a two-dimensional material is grown on the two-dimensional material growth template 7 using a gas, the metal of the source 2 and the drain 3 catalyze the decomposition of the gas into the two-dimensional material. The element causes the element of the two-dimensional material to grow on the two-dimensional material growth template 7 to form the channel 4, and at the same time, since the atomic arrangement of the two-dimensional material growth template 7 is the same as that of the two-dimensional material of the channel 4 Or similarly, the defects of the two-dimensional material obtained by using the two-dimensional material growth template 7 as a substrate are greatly reduced, so that the conductivity of the two-dimensional material is relatively good, so that the method can be used directly in the field effect. In the process of the transistor, a two-dimensional material is formed as the channel 4, and it is not necessary to first grow the two-dimensional material on the metal substrate and then transfer the two-dimensional material to the non-metal substrate 1, thereby avoiding the two-dimensional material during the transfer process. And the problem of causing defects in the two-dimensional material in the process of dissolving the metal, improving the performance of the field effect transistor using the two-dimensional material as the channel 4.

同时,在二维材料生长模板7上生长二维材料的同时使用气体在源极2表面生长第一过渡层8以及在漏极3表面生长第二过渡层9,因为源极2与作为 沟道4的二维材料通过第一过渡层8电连接,且第一过渡层8与源极2和二维材料之间均是通过化学键连接在一起的,漏极3与作为沟道4的二维材料通过第二过渡层9电连接,且第二过渡层9与漏极3和二维材料之间均是通过化学键连接在一起的,所以第一过渡层8和第二过渡层9可以有效降低源极2与沟道4之间的接触电阻以及漏极3与沟道4之间的接触电阻,使场效应晶体管的使用性能更加优异。At the same time, while the two-dimensional material is grown on the two-dimensional material growth template 7, the first transition layer 8 is grown on the surface of the source 2 and the second transition layer 9 is grown on the surface of the drain 3, because the source 2 is The two-dimensional material of the channel 4 is electrically connected through the first transition layer 8, and the first transition layer 8 and the source 2 and the two-dimensional material are connected by chemical bonds, and the drain 3 and the channel 4 are used as the channel 4. The two-dimensional material is electrically connected through the second transition layer 9, and the second transition layer 9 and the drain 3 and the two-dimensional material are connected by chemical bonds, so the first transition layer 8 and the second transition layer 9 can The contact resistance between the source 2 and the channel 4 and the contact resistance between the drain 3 and the channel 4 are effectively reduced, so that the performance of the field effect transistor is further improved.

步骤203:如图19所示,在沟道4上形成沟道保护层12。Step 203: As shown in FIG. 19, a channel protective layer 12 is formed on the trench 4.

在本发明实施例中,沟道保护层12的材料可以选择氮化硼,若作为沟道4的二维材料为石墨烯,则因为氮化硼的原子排列结构与石墨烯的原子排列结构相同,即都为六角结构,因此作为沟道保护层12的氮化硼可以以石墨烯作为生长模板生长,可通过化学气相沉积的方法或者等离子增强化学气相沉积的方法形成,也可以利用现有技术在其他衬底上生长氮化硼后将氮化硼转移到石墨烯上。In the embodiment of the present invention, the material of the channel protection layer 12 may be selected from boron nitride. If the two-dimensional material of the channel 4 is graphene, the atomic arrangement structure of the boron nitride is the same as that of the graphene. That is, all of them are hexagonal structures, so boron nitride as the channel protective layer 12 can be grown using graphene as a growth template, can be formed by chemical vapor deposition or plasma enhanced chemical vapor deposition, and can also utilize prior art. The boron nitride is transferred to the graphene after the boron nitride is grown on the other substrate.

在本发明实施例中,如图19所示,沟道保护层12也可以同时将第一过渡层8和第二过渡层9覆盖,同时起到保护第一过渡层8和第二过渡层9的作用。In the embodiment of the present invention, as shown in FIG. 19, the channel protective layer 12 can also cover the first transition layer 8 and the second transition layer 9 at the same time, while protecting the first transition layer 8 and the second transition layer 9 The role.

步骤204:如图20所示,在沟道保护层12上形成栅绝缘层5。Step 204: As shown in FIG. 20, a gate insulating layer 5 is formed on the channel protective layer 12.

在本发明实施例中,栅绝缘层5可通过原子层沉积的方法形成,栅绝缘层5的材料可以包括氧化铝Al2O3、氢氧化铪HfO2或三氧化二钇Y2O3In the embodiment of the present invention, the gate insulating layer 5 may be formed by a method of atomic layer deposition, and the material of the gate insulating layer 5 may include aluminum oxide Al 2 O 3 , barium hydroxide HfO 2 or antimony trioxide Y 2 O 3 .

步骤205:如图7所示,在栅绝缘层5上形成栅极6。Step 205: As shown in FIG. 7, a gate electrode 6 is formed on the gate insulating layer 5.

在本发明实施例中,栅极6的材料可以为金、钯或者钨,也可以为其他金属材料,可根据实际情况进行选择。In the embodiment of the present invention, the material of the gate electrode 6 may be gold, palladium or tungsten, or may be other metal materials, and may be selected according to actual conditions.

本发明实施例中的场效应晶体管通过先在非金属衬底1上形成源极2和漏极3,并且在非金属衬底1上设置二维材料生长模板7,由于二维材料生长模板7的原子排列结构与二维材料的原子排列结构相同或者类似,在使用气体生长二维材料时,源极2和漏极3的金属会催化气体分解出二维材料的元素,使二维材料的元素以二维材料生长模板7作为基底来生长,最终形成作为沟道4的二维材料,此种方法使得生长出的二维材料的缺陷大大减少,因此二维材料的导电性能比较好,如此可以直接在制作场效应晶体管的过程中形成作为沟道4的二维材料,无需先在金属衬底上生长二维材料以及再将二维材料转移到非金属衬底1上,避免了二维材料在转移的过程中以及在溶解金属的过程中而导致二维材料产生缺陷的问题,提高了使用二维材料作为沟道4的场效应晶体管 的性能;同时,在形成二维材料时,在源极2之上还会形成第一过渡层8,第一过渡层8与源极2和作为沟道4的二维材料之间是通过化学键连接的,在漏极3之上还会形成第二过渡层9,第二过渡层9与漏极3和作为沟道4的二维材料之间是通过化学键连接的,第一过渡层8可以有效降低源极2与沟道4之间的接触电阻,第二过渡层9可以有效降低漏极3与沟道4之间的接触电阻,提高了使用二维材料作为沟道4的场效应晶体管的使用性能。The field effect transistor in the embodiment of the present invention first forms the source 2 and the drain 3 on the non-metal substrate 1, and the two-dimensional material growth template 7 is disposed on the non-metal substrate 1, and the template 7 is grown due to the two-dimensional material. The atomic arrangement structure is the same as or similar to the atomic arrangement structure of the two-dimensional material. When a two-dimensional material is grown using a gas, the metal of the source 2 and the drain 3 catalyze the decomposition of the gas into the element of the two-dimensional material, so that the two-dimensional material The element is grown by using the two-dimensional material growth template 7 as a substrate, and finally forms a two-dimensional material as the channel 4. This method greatly reduces the defects of the grown two-dimensional material, so the conductivity of the two-dimensional material is better. The two-dimensional material as the channel 4 can be formed directly in the process of fabricating the field effect transistor, without first growing the two-dimensional material on the metal substrate and transferring the two-dimensional material onto the non-metal substrate 1, avoiding the two-dimensional The problem of the material causing defects in the two-dimensional material during the transfer process and in the process of dissolving the metal improves the field effect transistor using the two-dimensional material as the channel 4. At the same time, when forming a two-dimensional material, a first transition layer 8 is formed on the source 2, and a chemical bond is formed between the first transition layer 8 and the source 2 and the two-dimensional material as the channel 4. Connected, a second transition layer 9 is formed on the drain 3, and the second transition layer 9 and the drain 3 and the two-dimensional material as the channel 4 are connected by a chemical bond, and the first transition layer 8 can be Effectively reducing the contact resistance between the source 2 and the channel 4, the second transition layer 9 can effectively reduce the contact resistance between the drain 3 and the channel 4, and improve the field effect transistor using the two-dimensional material as the channel 4. Performance of use.

以上所述仅为本发明的较佳实施例,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。 The above are only the preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalents, improvements, etc., which are within the spirit and scope of the present invention, should be included in the protection of the present invention. Within the scope.

Claims (15)

一种场效应晶体管的制作方法,其特征在于,所述制作方法包括:A method for fabricating a field effect transistor, characterized in that the manufacturing method comprises: 在非金属衬底上形成源极、漏极以及二维材料生长模板,所述二维材料生长模板位于所述源极和所述漏极之间;Forming a source, a drain, and a two-dimensional material growth template on the non-metal substrate, the two-dimensional material growth template being located between the source and the drain; 使用气体在所述二维材料生长模板上生长二维材料,将所述二维材料作为沟道,所述沟道分别与所述源极和所述漏极电连接,所述气体包括组成所述二维材料的元素,所述源极和所述漏极用于在生长所述二维材料的过程中催化所述气体分解出所述二维材料的元素,使所述二维材料的元素在所述二维材料生长模板上生长所述二维材料;Forming a two-dimensional material on the two-dimensional material growth template using a gas, the two-dimensional material as a channel, the channel being electrically connected to the source and the drain, respectively, the gas including a composition An element of a two-dimensional material, the source and the drain for catalyzing the gas to decompose elements of the two-dimensional material during growth of the two-dimensional material, such that elements of the two-dimensional material Growing the two-dimensional material on the two-dimensional material growth template; 在所述沟道上形成栅绝缘层和栅极。A gate insulating layer and a gate are formed on the channel. 根据权利要求1所述的制作方法,其特征在于,所述制作方法还包括:The manufacturing method according to claim 1, wherein the manufacturing method further comprises: 在生长所述二维材料的同时使用所述气体在所述源极表面生长第一过渡层以及在所述漏极表面生长第二过渡层,所述第一过渡层通过化学键分别与所述源极和所述沟道电连接,所述第二过渡层通过化学键分别与所述漏极和所述沟道电连接。Forming a first transition layer on the source surface and a second transition layer on the drain surface using the gas while growing the two-dimensional material, the first transition layer being respectively separated from the source by a chemical bond The pole is electrically connected to the channel, and the second transition layer is electrically connected to the drain and the channel by a chemical bond, respectively. 根据权利要求1或2所述的制作方法,其特征在于,所述在非金属衬底上形成源极、漏极以及二维材料生长模板,包括:The method according to claim 1 or 2, wherein the forming a source, a drain, and a two-dimensional material growth template on the non-metal substrate comprises: 在所述非金属衬底上设置所述二维材料生长模板、第一凹陷区和第二凹陷区,所述二维材料生长模板位于所述第一凹陷区和所述第二凹陷区之间;Forming the two-dimensional material growth template, the first recessed region and the second recessed region on the non-metal substrate, the two-dimensional material growth template being located between the first recessed region and the second recessed region ; 在所述第一凹陷区内形成所述源极,在所述第二凹陷区内形成所述漏极。The source is formed in the first recess region, and the drain is formed in the second recess region. 根据权利要求1或2所述的制作方法,其特征在于,所述在非金属衬底上形成源极、漏极以及二维材料生长模板,包括:The method according to claim 1 or 2, wherein the forming a source, a drain, and a two-dimensional material growth template on the non-metal substrate comprises: 在所述非金属衬底上形成第一衬底;Forming a first substrate on the non-metal substrate; 在所述第一衬底上形成所述源极和所述漏极,并将所述第一衬底位于所述源极和所述漏极之间的部分作为所述二维材料生长模板。The source and the drain are formed on the first substrate, and a portion of the first substrate between the source and the drain is used as the two-dimensional material growth template. 根据权利要求1或2所述的制作方法,其特征在于,所述二维材料为石 墨烯、过渡金属二硫化物或黑磷。The manufacturing method according to claim 1 or 2, wherein the two-dimensional material is stone Moenol, transition metal disulfide or black phosphorus. 如权利要求5所述的制作方法,其特征在于,所述过渡金属二硫化物包括二硫化钼或二硫化钨。The method according to claim 5, wherein the transition metal disulfide comprises molybdenum disulfide or tungsten disulfide. 根据权利要求1或2所述的制作方法,其特征在于,所述二维材料生长模板为氮化硼。The manufacturing method according to claim 1 or 2, wherein the two-dimensional material growth template is boron nitride. 根据权利要求1或2所述的制作方法,其特征在于,所述二维材料的原子排列结构与所述二维材料生长模板的原子排列结构相同。The manufacturing method according to claim 1 or 2, wherein the atomic arrangement structure of the two-dimensional material is the same as the atomic arrangement structure of the two-dimensional material growth template. 根据权利要求8所述的制作方法,其特征在于,所述二维材料的原子排列结构为六角结构。The method according to claim 8, wherein the atomic arrangement of the two-dimensional material is a hexagonal structure. 一种场效应晶体管,其特征在于,所述场效应晶体管包括:A field effect transistor, characterized in that the field effect transistor comprises: 非金属衬底、源极、漏极、二维材料生长模板、沟道、栅绝缘层和栅极;a non-metal substrate, a source, a drain, a two-dimensional material growth template, a channel, a gate insulating layer, and a gate; 所述源极、所述漏极以及所述二维材料生长模板位于所述非金属衬底上,所述二维材料生长模板位于所述源极和所述漏极之间;The source, the drain, and the two-dimensional material growth template are located on the non-metal substrate, and the two-dimensional material growth template is located between the source and the drain; 所述沟道位于所述二维材料生长模板上,所述沟道的材料为二维材料,且所述沟道分别与所述源极和所述漏极电连接;The channel is located on the two-dimensional material growth template, the material of the channel is a two-dimensional material, and the channel is electrically connected to the source and the drain, respectively; 所述栅绝缘层位于所述沟道之上,所述栅极位于所述栅绝缘层之上。The gate insulating layer is over the channel, and the gate is over the gate insulating layer. 根据权利要求10所述的场效应晶体管,其特征在于,所述场效应晶体管还包括第一过渡层和第二过渡层;The field effect transistor according to claim 10, wherein the field effect transistor further comprises a first transition layer and a second transition layer; 所述第一过渡层位于所述源极的表面且通过化学键分别与所述源极和所述沟道电连接;The first transition layer is located on a surface of the source and is electrically connected to the source and the channel by a chemical bond, respectively; 所述第二过渡层位于所述漏极的表面且通过化学键分别与所述漏极和所述沟道电连接。The second transition layer is located on a surface of the drain and is electrically connected to the drain and the channel by a chemical bond, respectively. 根据权利要求10所述的场效应晶体管,其特征在于,所述场效应晶体 管还包括沟道保护层,所述沟道保护层位于所述沟道与所述栅绝缘层之间。The field effect transistor according to claim 10, wherein said field effect crystal The tube further includes a channel protective layer between the channel and the gate insulating layer. 根据权利要求10-12任一项权利要求所述的场效应晶体管,其特征在于,所述非金属衬底上设有第一凹陷区和第二凹陷区;The field effect transistor according to any one of claims 10 to 12, wherein the non-metal substrate is provided with a first recessed region and a second recessed region; 所述二维材料生长模板位于所述第一凹陷区和所述第二凹陷区之间,所述源极位于所述第一凹陷区内,所述漏极位于所述第二凹陷区内。The two-dimensional material growth template is located between the first recessed region and the second recessed region, the source is located in the first recessed region, and the drain is located in the second recessed region. 根据权利要求10-12所述的场效应晶体管,其特征在于,所述二维材料的原子排列结构为六角结构。The field effect transistor according to any one of claims 10-12, wherein the atomic arrangement of the two-dimensional material is a hexagonal structure. 根据权利要求10-12所述的场效应晶体管,其特征在于,所述二维材料为石墨烯、过渡金属二硫化物或黑磷。 A field effect transistor according to any of claims 10-12, wherein the two-dimensional material is graphene, transition metal disulfide or black phosphorus.
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