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WO2018008479A1 - Composition de revêtement - Google Patents

Composition de revêtement Download PDF

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Publication number
WO2018008479A1
WO2018008479A1 PCT/JP2017/023618 JP2017023618W WO2018008479A1 WO 2018008479 A1 WO2018008479 A1 WO 2018008479A1 JP 2017023618 W JP2017023618 W JP 2017023618W WO 2018008479 A1 WO2018008479 A1 WO 2018008479A1
Authority
WO
WIPO (PCT)
Prior art keywords
zeolite
coating composition
mol
type
odor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2017/023618
Other languages
English (en)
Japanese (ja)
Inventor
麻由佳 石川
重人 今
佐藤　弘一
晋也 川上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Paint Co Ltd
Original Assignee
Nippon Paint Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Paint Co Ltd filed Critical Nippon Paint Co Ltd
Publication of WO2018008479A1 publication Critical patent/WO2018008479A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/22—Type X
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols

Definitions

  • the present invention relates to a coating composition. More specifically, the present invention relates to a coating composition that can reduce the odor emitted by the coating composition itself as compared with the conventional case.
  • a typical example of the paint is an aqueous emulsion resin paint composition.
  • the interior coating of a living space or the like is desired to be odorless from the viewpoint of the owner and the painter as compared with the outdoors, and therefore, an aqueous emulsion resin coating composition is used.
  • the unreacted monomer derived from the emulsion resin composition contained in the conventional aqueous emulsion resin coating composition, the high boiling point volatile organic compound contained in the film-forming aid, and the trace amount of volatile components are in a liquid state. Because it emits odor from the water-based emulsion resin coating composition or when the coating composition after coating volatilizes in the air in the process of forming a dry coating film, it is not in a comfortable state for the owner or the painter . Therefore, reduction of the odor emitted from the coating composition itself is demanded.
  • a method for reducing the amount of volatile organic compounds in the film-forming aid for example, see Patent Document 1.
  • a method for reducing the odor of ammonia or the like drifting in the living space a method of adding an inorganic porous material to the aqueous paint resin composition and adsorbing the odor to the porous material is known (for example, , See Patent Document 2).
  • the present invention has been made in view of the above problems, and it is an object of the present invention to provide a coating composition capable of reducing the odor emitted by the coating composition itself as compared with the conventional art.
  • the present invention is a coating composition
  • a coating composition comprising a resin emulsion composition (a) and an inorganic porous pigment (b) made of zeolite, wherein the silica / alumina (mol / mol) ratio in the zeolite is 15 or more. And providing a coating composition having a zeolite content of 0.1 to 500 parts by mass with respect to 100 parts by mass of the solid content of the resin emulsion composition (a).
  • the silica / alumina (mol / mol) ratio in the zeolite is preferably 30 or more.
  • the zeolite of the present invention preferably has at least one crystal structure selected from the group consisting of X-type, beta-type, MFI-type, ferrierite-type, mordenite-type, L-type and Y-type.
  • the zeolite of the present invention is preferably an ion exchange type zeolite ion-exchanged with a metal ion other than proton or alkali metal.
  • the present invention it is possible to provide a coating composition capable of reducing the odor emitted from the coating composition itself as compared with the conventional case.
  • the coating composition according to the present embodiment includes a resin emulsion composition (a) and an inorganic porous pigment (b).
  • the resin emulsion composition (a) is a component that functions as a binder.
  • a synthetic resin emulsion comprising a resin component such as a vinyl acetate resin emulsion, a vinyl chloride resin emulsion, an epoxy resin emulsion, an acrylic resin emulsion, a urethane resin emulsion, an acrylic silicon resin emulsion, a fluororesin emulsion, or a composite system thereof.
  • a resin component such as a vinyl acetate resin emulsion, a vinyl chloride resin emulsion, an epoxy resin emulsion, an acrylic resin emulsion, a urethane resin emulsion, an acrylic silicon resin emulsion, a fluororesin emulsion, or a composite system thereof.
  • the resin emulsion composition (a) according to this embodiment is not particularly limited, but an acrylic resin emulsion is preferably used.
  • the acrylic resin emulsion according to this embodiment can be obtained by a known polymerization method such as an emulsion polymerization method using a (meth) acrylic acid ester monomer as a medium.
  • the form of the resin emulsion composition (a) is not particularly limited, and may be either a one-component type or a two-component type.
  • Examples of the (meth) acrylic acid ester monomer according to this embodiment include methyl (meth) acrylate, ethyl (meth) acrylate, isopropyl (meth) acrylate, (meth) acrylate-n-propyl, ( (Meth) acrylic acid-i-butyl, (meth) acrylic acid-n-butyl, (meth) acrylic acid-t-butyl, (meth) acrylic acid-sec-butyl, (meth) acrylic acid isobutyl, (meth) acrylic 2-ethylhexyl acid, n-hexyl (meth) acrylate, cyclohexyl (meth) acrylate, octyl (meth) acrylate, lauryl (meth) acrylate, stearyl (meth) acrylate, myristyl (meth) acrylate , Palmitic acid (meth) acrylate, glycidyl (meth) acryl
  • the glass transition temperature (Tg) of the resin emulsion composition (a) is preferably ⁇ 50 to 50 ° C. from the viewpoint of physical properties of the coating film.
  • Tg glass transition temperature of the emulsion resin
  • a good coating film can be formed in a room temperature environment when coating the interior surface of a building.
  • the acid value of the resin emulsion composition (a) is preferably 5 to 25, more preferably 10 to 20. If it is less than 5, sufficient curing of the coating film may not be obtained, and if it exceeds 25, storage stability may be deteriorated.
  • the pH of the resin emulsion composition (a) is preferably used within the range of 5 to 10 by neutralizing with a base as necessary from the viewpoint of stability. Neutralization is performed by adding amines such as ammonia and dimethylethanolamine, sodium hydroxide, potassium hydroxide and the like.
  • the solid content of the paint containing the resin emulsion composition (a) is preferably 1 to 90% by mass. When the solid content of the coating is within this range, it is possible to prevent the coating film from being lost due to the contraction of the coating film in the drying process after coating. A more preferable coating solid content is 10 to 50% by mass.
  • the viscosity of the resin emulsion composition (a) is preferably 50 to 10,000 mPa ⁇ s, more preferably 300 to 8,000 mPa ⁇ s under the same conditions.
  • the said viscosity means the value measured using the E-type viscosity meter, for example.
  • examples of the inorganic compound having voids capable of retaining odor components and the like in the porous portion include activated carbon, activated alumina, silica gel, hydroxyapatite, and phosphoric acid.
  • activated carbon activated alumina
  • silica gel silica gel
  • hydroxyapatite and phosphoric acid.
  • Zirconium, titanium phosphate, potassium titanate, hydrous bismuth, hydrous zirconium, hydrotalcite and the like can be mentioned.
  • zeolite is used.
  • the inorganic porous pigment (b) is an odor of the coating composition itself due to volatilization of the unreacted monomer contained in the coating composition and the volatile organic compound contained in the film-forming aid, and the adsorption site after coating.
  • Ammonia and formaldehyde in the air can be adsorbed according to the unfilled amount.
  • the inorganic porous pigment (b) is added to the coating composition at a predetermined weight, it can adsorb the odor before and after coating and provide a coating composition having a high odor control effect.
  • both natural zeolite and artificially produced synthetic zeolite can be used, and it is particularly preferable to use synthetic zeolite in view of ease of ion exchange and the like.
  • a zeolite having at least one crystal structure selected from the group consisting of X-type, beta-type, MFI-type, ferrierite-type, mordenite-type, L-type and Y-type is preferably used.
  • Adsorbable odor components vary depending on the crystal structure of the zeolite. Therefore, it is more preferable that two or more kinds of crystal structures are selected from the above crystal structures.
  • a commercially available product can also be used for the zeolite according to the present embodiment.
  • X type zeolite is manufactured by Tosoh Corporation: F9 series
  • beta type zeolite is manufactured by Tosoh Corporation: HSZ900 series
  • MFI type zeolite is manufactured by Tosoh Corporation: HSZ800 series
  • ferrilite type is manufactured by Tosoh Corporation.
  • HSZ700 series mordenite type manufactured by Tosoh Corporation: HSZ600 series
  • Y type zeolite can be used HSZ300 series.
  • any conventionally known method can be applied.
  • a method of obtaining a synthetic zeolite by crystallizing a composition containing a silica source, an alumina source, a quaternary ammonium salt, an alkali source and water is known. Specifically, pure water, sodium hydroxide, zeolite, and seed crystal zeolite are added to a 35% quaternary ammonium salt aqueous solution, and the raw material composition is crystallized by stirring at 150 ° C. for 8 days. The crystals are recovered after solid-liquid separation and pure water washing, and dried at 110 ° C. to obtain a synthetic zeolite.
  • the ion exchange site may have alkali metal ions. Therefore, from the viewpoint of suppressing odor, this ion exchange site contains at least one ion exchange species selected from the group consisting of protons and metal ions other than alkali metals such as Cu ions, Ag ions, and Au ions. It is preferable. In particular, from the viewpoint of suppressing odor, zeolite substituted with metal ions such as Cu, Ag and Au capable of adsorbing odor components and decomposing odor components is more preferable. Ion exchange can be performed by a known method.
  • any conventionally known method can be applied to the ion exchange in the zeolite of the present embodiment.
  • protons (H + ) to the ion exchange site of Y-type zeolite
  • the proton is calcined.
  • Type Y zeolite is obtained.
  • metal ions such as Cu
  • Y type zeolite in which Cu ions are present at the ion exchange site is obtained.
  • the odor components released from the coating composition include those derived from organic solvents.
  • the silica / alumina (mol / mol) ratio of zeolite is 15 or more. Adjusted to As the silica / alumina (mol / mol) ratio increases, the nature of the zeolite itself becomes hydrophobic. Thereby, it becomes possible to adsorb more odor components than water molecules at the adsorption point in the zeolite. Therefore, the silica / alumina (mol / mol) ratio of zeolite is more preferably adjusted to 30 or more.
  • the silica / alumina ratio is adjusted to 5000 or more, the adsorption point of the odor component in the zeolite is extremely reduced, and the adsorption amount is reduced. For this reason, the silica / alumina ratio is preferably 5000 or less.
  • the adjustment of the silica / alumina (mol / mol) ratio of the zeolite can be carried out, for example, by adjusting the mixing ratio of the raw material composition of the zeolite in the above-mentioned production stage. It can be performed by hydrothermal treatment or the like. For example, in the case of zeolite after commercialization, there are known methods such as hydrothermal treatment method, mineral acid treatment method, silicon substitution method and EDTA treatment to remove aluminum ions and increase the silica / alumina (mol / mol) ratio. Yes.
  • silica / alumina (mol / mol) ratio In order to reduce the silica / alumina (mol / mol) ratio, a method is known in which zeolite is brought into contact with an aluminum source, washed with ion-exchanged water, and dried. In the present embodiment, the adjustment of the silica / alumina (mol / mol) ratio is not limited to these, and any known method can be applied.
  • the dispersed particle size of the zeolite is preferably in the range of 0.1 to 100 ⁇ m. Since zeolite is a granular substance, when the dispersed particle size is larger than 100 ⁇ m, the appearance of irregularities based on zeolite appears in the coating film, and the design of the coating film deteriorates. On the other hand, when the dispersed particle size of the zeolite is smaller than 0.1 ⁇ m, the zeolite is buried in the coating film, and the pores of the zeolite may not be exposed on the coating film surface.
  • content of an inorganic porous pigment (b) is 0.1 mass part with respect to 100 mass parts of solid content of a resin emulsion composition (a). -500 parts by mass.
  • content of an inorganic porous pigment (b) is less than 0.1 mass part, the preferable odor suppression effect is not acquired about the coating film formed.
  • content of an inorganic porous pigment (b) exceeds 500 mass parts, the viscosity of a coating composition becomes high too much and it becomes difficult to form a coating film.
  • the addition of an inorganic porous pigment (b) exceeding the necessary amount leads to unnecessary cost increase. Therefore, the content of the inorganic porous pigment (b) is preferably 1 part by mass to 500 parts by mass.
  • the coating composition which concerns on this embodiment may contain the other component as needed.
  • the coating composition is a known color pigment, extender pigment, aggregate, fiber, plasticizer, preservative, ordinarily used as a component other than the above-described resin emulsion composition (a) or inorganic porous pigment (b).
  • Antifungal agents, antifoaming agents, viscosity modifiers, leveling agents, pigment dispersants, anti-settling agents, anti-sagging agents, matting agents, UV absorbers, light stabilizers, antioxidants, antibacterial agents, adsorbents, photocatalysts Etc. can be blended alone or in combination.
  • coloring pigments titanium oxide, zinc oxide, carbon black, lamp black, bone black, graphite, black iron oxide, copper chrome black, cobalt black, copper manganese iron black, molybdate orange, permanent red, permanent carmine, Anthraquinone red, perylene red, quinacridone red, ferric oxide, yellow iron oxide, titanium yellow, first yellow, chrome green, ocher, ultramarine, bitumen, cobalt green, cobalt blue and other inorganic color pigments, azo, naphthol Organic color pigments such as pyrazolone, anthraquinone, perylene, quinacridone, benzimidazole, phthalocyanine, disazo, isoindolinone, quinophthalone, pearl pigment, aluminum pigment, Genera or glass flakes or a resin film coated with a metal oxide, hologram pigments, bright pigments such as cholesteric crystal polymer pigments, fluorescent pigments, phosphorescent pigments, and the like.
  • Body pigments include heavy calcium carbonate, light calcium carbonate, clay, kaolin, talc, barium carbonate, white carbon, diatomaceous earth, cold water stone, china clay, barite powder, barium sulfate, precipitated barium sulfate, silica sand, Examples thereof include quartzite powder, quartz powder, resin beads, glass beads, and hollow balloons.
  • the coating composition according to the present embodiment forms a dense coating film, is excellent in initial drying properties, durability, and film-forming properties. Therefore, depending on the application, a top coating material, an intermediate coating material, an undercoat It is also possible to apply to materials. Thereby, the coating composition which concerns on this embodiment can absorb each component, such as ammonia and formaldehyde emitted from coating compositions other than this invention.
  • the resin emulsion composition (a), the inorganic porous pigment (b) and other components are respectively disperser, ball mill, S.I. G. It can be prepared by mixing with a mill, roll mill, planetary mixer or the like.
  • a coating composition can be prepared by mixing a predetermined amount of the resin emulsion composition (a), the inorganic porous pigment (b), and other components.
  • the method of forming a coating film with the coating composition according to the present embodiment is not particularly limited.
  • the coating method generally used in (1) can be mentioned. These coating methods can be appropriately selected depending on the object to be coated and the application.
  • the coating composition according to this embodiment can be applied to the exterior and interior surfaces of buildings.
  • buildings For example, mortar, concrete, gypsum board, siding board, extrusion board, slate board, asbestos cement board, fiber-mixed cement board, calcium silicate board, ALC board, metal, wood, glass, ceramics, fired
  • the present invention can be applied to a substrate such as a tile, porcelain tile, plastic plate, wallpaper, and synthetic resin, or a coating film formed on the substrate.
  • the present invention will be described in more detail based on examples, but the present invention is not limited thereto. Unless otherwise specified, the unit is based on mass.
  • zeolite (b-1) 189 g of amorphous aluminosilicate, 1.4 g of solid sodium hydroxide, 3.5 g of solid potassium hydroxide, and 480 g of 20% aqueous solution of tetraethylammonium hydroxide were stirred and mixed for 30 minutes to obtain a raw material for ⁇ -type zeolite.
  • the raw material slurry was crystallized at 150 ° C. for 96 hours.
  • the slurry mixture after crystallization was subjected to solid-liquid separation, washed with a sufficient amount of pure water, and dried at 110 ° C.
  • the dry powder was then fired at 600 ° C. under air flow.
  • a beta zeolite having a silica / alumina (mol / mol) ratio of 36 was obtained.
  • the obtained beta-type zeolite was immersed in a solvent whose aluminum concentration was adjusted so that the silica / alumina (mol / mol) ratio was 30, and then washed with ion-exchanged water and dried to obtain silica / alumina (mol / Mol) zeolite (b-1) adjusted to 30 was obtained.
  • X-type zeolite was obtained using the same procedure as for zeolite (b-1) except that X-type zeolite (F-9: dispersion particle size 10 ⁇ m) manufactured by Tosoh Corporation was used as the seed crystal of X-type zeolite. Thereafter, the silica / alumina (mol / mol) ratio was adjusted to 15 to obtain zeolite (b-2).
  • MFI-type zeolite was obtained using the same procedure as that for zeolite (b-1) except that MFI-type zeolite manufactured by Tosoh Corporation (HSZ800: dispersion particle size 10 ⁇ m) was used as a seed crystal of MFI-type zeolite. Thereafter, the silica / alumina (mol / mol) ratio was adjusted to 100 to obtain zeolite (b-3).
  • X-type zeolite was obtained using the same procedure as that for zeolite (b-1), except that X-type zeolite (F-9: dispersed particle size 5 ⁇ m) manufactured by Tosoh Corporation was used as a seed crystal of the X-type zeolite. Thereafter, the silica / alumina (mol / mol) ratio was adjusted to 100, and further, ion exchange with Cu was performed and washed to obtain zeolite (b-4).
  • zeolite (b-5) X-type zeolite was obtained using the same method as zeolite (b-1) except that X-type zeolite manufactured by Tosoh Corporation (F-9: dispersion particle size 5 ⁇ m) was used as the seed crystal of X-type zeolite. Thereafter, the silica / alumina (mol / mol) ratio was adjusted to 5 to obtain zeolite (b-5).
  • Example 1 The coating composition of Example 1 was obtained by thoroughly stirring the mixture using a disper for 2 hours. Similarly to Example 1, each zeolite shown in Table 2 was mixed at a predetermined ratio with respect to 100 parts by mass of the solid content of the acrylic resin emulsion (a), and the coating compositions of each Example and Comparative Example were mixed. Obtained.
  • the coating composition of Examples 1 to 5 containing at least 1 part by mass of zeolite (b-1) in the coating composition is zeolite (b-1).
  • the coating composition of the comparative example 2 which is less than 1 mass part it turned out that it is excellent in the result of an odor evaluation test. From this result, it was confirmed that the odor is suppressed when the resin emulsion composition (a) contains 1 part by mass or more, particularly 15 parts by mass or more of the inorganic porous pigment (b).
  • the inorganic porous pigment (b) is in the range of 0.1 to 500 parts by mass with respect to 100 parts by mass of the solid content of the resin emulsion composition (a). It was confirmed that an inhibitory effect was obtained and a practical coating composition could be obtained.
  • Example 8 confirmed that the coating composition containing two types of zeolite (b-1) and zeolite (b-3) was excellent in the odor evaluation test.
  • Example 9 From Example 9, it was confirmed that the coating composition containing zeolite (b-4) ion-exchanged with Cu ions was excellent in the odor evaluation test.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)

Abstract

La présente invention décrit une composition de revêtement qui émet elle-même encore moins d'odeur par rapport à celles classiques. La présente invention décrit une composition de revêtement comprenant une composition d'émulsion de résine (a) et un pigment poreux inorganique (b) comprenant une zéolite, la zéolite présentant un rapport silice/alumine (mol/mol) de 15 ou plus et la teneur de la zéolite étant de 0,1 à 500 parties en masse pour 100 parties en masse des constituants solides de la composition d'émulsion de résine (a).
PCT/JP2017/023618 2016-07-05 2017-06-27 Composition de revêtement Ceased WO2018008479A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016-133459 2016-07-05
JP2016133459A JP6799401B2 (ja) 2016-07-05 2016-07-05 塗料組成物

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WO2018008479A1 true WO2018008479A1 (fr) 2018-01-11

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4473068A4 (fr) * 2022-01-31 2025-11-19 Heubach Holding Switzerland Ltd Couche de réception d'encre pigmentée pour panneaux de construction décoratifs

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3063996B1 (fr) * 2017-03-17 2022-01-14 Arkema France Procede de synthese de cristaux de zeolithe avec agent d'ensemencement
JP7406354B2 (ja) * 2019-11-20 2023-12-27 東ソー・シリカ株式会社 水性塗料用表面処理沈降シリカ

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09249824A (ja) * 1996-03-18 1997-09-22 Sharp Corp 光触媒を用いた空気浄化塗料
WO1998012048A1 (fr) * 1996-09-20 1998-03-26 Hitachi, Ltd. Film photocatalytique fin et articles pourvus de ce film
JP2009516056A (ja) * 2005-11-17 2009-04-16 ビーエーエスエフ、カタリスツ、エルエルシー 低温使用用の改良された炭化水素吸着スラリー極薄塗料
JP2015120808A (ja) * 2013-12-20 2015-07-02 株式会社池田工業 壁紙塗料
JP2015147204A (ja) * 2014-01-08 2015-08-20 三菱化学株式会社 多孔質支持体−ゼオライト膜複合体の製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09249824A (ja) * 1996-03-18 1997-09-22 Sharp Corp 光触媒を用いた空気浄化塗料
WO1998012048A1 (fr) * 1996-09-20 1998-03-26 Hitachi, Ltd. Film photocatalytique fin et articles pourvus de ce film
JP2009516056A (ja) * 2005-11-17 2009-04-16 ビーエーエスエフ、カタリスツ、エルエルシー 低温使用用の改良された炭化水素吸着スラリー極薄塗料
JP2015120808A (ja) * 2013-12-20 2015-07-02 株式会社池田工業 壁紙塗料
JP2015147204A (ja) * 2014-01-08 2015-08-20 三菱化学株式会社 多孔質支持体−ゼオライト膜複合体の製造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4473068A4 (fr) * 2022-01-31 2025-11-19 Heubach Holding Switzerland Ltd Couche de réception d'encre pigmentée pour panneaux de construction décoratifs

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JP6799401B2 (ja) 2020-12-16
JP2018002928A (ja) 2018-01-11

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